Herbicidal malonamides containing fused ring systems

Abstract

The present invention relates to a compound represented by formula (I) [Formula 1] JPEG2024532425000131.jpg15118, where the variables are as defined in the claims and herein. and compositions comprising these compounds. The invention also relates to the use of said malonamide compounds or the corresponding compositions for controlling undesirable vegetation. Furthermore, the invention relates to a method for applying said malonamide compounds or the corresponding compositions.

Description

[Technical Field]

[0001] The present invention relates to malonamide compounds containing fused ring systems and compositions containing the same. The present invention also relates to the use of malonamide compounds containing fused ring systems or corresponding compositions for controlling undesirable vegetation. Furthermore, the present invention relates to methods of applying malonamide compounds containing fused ring systems or corresponding compositions. [Background technology]

[0002] There is a continuing need for new herbicides that are highly active and selective, yet substantially non-toxic to humans and animals, particularly for the purpose of controlling undesirable vegetation in crops.

[0003] WO 2012 / 130798, WO 2014 / 04882, WO 2014 / 048882, WO 2018 / 228985, WO 2018 / 228986, WO 2019 / 034602, WO 2019 / 145245, WO 2020 / 114932, WO 2020 / 114934 and WO 2020 / 182723 describe 3-phenylisoxazoline-5-carboxamides and their use as herbicides.

[0004] WO 87 / 05898 describes the use of malonic acid derivatives to retard plant growth.

[0005] US Pat. No. 3,072,473 also describes malonic acid derivatives as plant growth regulators.

[0006] Prior art compounds often have poor selectivity resulting in poor herbicidal activity, especially at low application rates, and / or poor compatibility with crop plants. Summary of the Invention [Problem to be solved by the invention]

[0007] It is therefore an object of the present invention to provide further malonamide compounds which have strong herbicidal activity, especially at low application rates, sufficiently low toxicity to humans and animals, and / or high compatibility with crop plants. The malonamide compounds should also exhibit a broad spectrum of activity against many different undesirable plants. [Means for solving the problem]

[0008] These and further objects are achieved by compounds of formula (I) as defined below, including agriculturally acceptable salts, stereoisomers and tautomers thereof.

[0009] Thus, the present invention provides a compound of formula (I) [ka] wherein the substituents have the following meanings: Q is a bicyclic or tricyclic aromatic or partially aromatic fused ring system formed from s carbon atoms, t nitrogen atoms, n sulfur atoms and n oxygen atoms, wherein a carbon or sulfur ring atom carries p oxo groups and the ring contains k substituents R Q1 and n substituents R Q2 having; R Q1 is halogen, nitro, hydroxyl, cyano, (C1-C3)-alkyl, (C1-C3)-haloalkyl, hydroxy-(C1-C3)-alkyl, (C3-C5)-cycloalkyl, (C1-C3)-alkoxy, (C1-C3)-haloalkoxy, (C2-C3)-alkenyl, (C2-C3)-haloalkenyl, (C2-C3)-alkynyl or (C2-C3)-haloalkynyl; R Q2is phenyl-(C1-C3)-alkyl, (C1-C4)-alkylcarbonyl, aminocarbonyl, (C1-C4)-alkylaminocarbonyl, di-(C1-C4-alkyl)aminocarbonyl, (C1-C4)-alkoxycarbonyl, benzyloxycarbonyl, fluorenyloxycarbonyl, allyloxycarbonyl, (C1-C3)-alkoxy-(C1-C3)-alkyl, (C1-C3)-alkylthio, (C1-C3)-alkylsulfinyl, (C1-C3)-alkylsulfonyl or phenylsulfonyl, in which the aliphatic or aromatic moiety in the last-mentioned 14 radicals is substituted by m radicals selected from the group consisting of fluorine, chlorine, bromine, cyano and (C1-C2)-alkoxy; R 1 is hydrogen, (C1-C3)-alkyl, (C1-C3)-haloalkyl, (C3-C4)-cycloalkyl, (C2-C3)-alkenyl, (C2-C3)-haloalkenyl, (C2-C3)-alkynyl, (C2-C3)-haloalkynyl, (C1-C3)-alkoxy-(C1-C3)-alkyl, (C1-C3)-alkoxy, (C1-C3)-haloalkoxy or (C1-C3)-alkoxy-(C1-C3)-alkoxy; R 2 is (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C3-C6)-alkenyl, (C3-C6)-alkynyl or (C1-C3)-alkoxy-(C1-C3)-alkyl, in which the aliphatic or cycloaliphatic moiety in the last five groups is substituted by m groups selected from the group consisting of fluorine, chlorine, bromine, iodine, hydroxyl and cyano; R 3is hydrogen, halogen, cyano, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C1-C6)-cyanoalkyl, (C1-C3)-hydroxyalkyl, (C1-C3)-alkoxy-(C1-C3)-alkyl, (C1-C3)-haloalkoxy-(C1-C3)-alkyl, (C3-C6)-cycloalkyl, (C3-C6)-alkenyl, (C2-C6)-alkynyl , (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, (C1-C3)-cyanoalkoxy, (C1-C3)-alkoxy-(C1-C3)-alkoxy, (C3-C6)-cycloalkoxy, (C3-C5)-cycloalkyl-(C1-C3)-alkoxy, (C3-C6)-alkenyloxy, (C3-C6)-alkynyloxy or (C1-C3)-alkylthio; R 4 is hydrogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C1-C3)-alkoxy-(C1-C3)-alkyl, (C3-C4)-cycloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy or (C1-C3)-alkoxy-(C1-C3)-alkoxy; X is a bond (X 0 ) or (X 1 ), (X 2 ), (X 3 ), (X 4 ), (X 5 ) and (X 6 ): [ka] is a divalent entity selected from the group consisting of R 5 , R 6 , R 7 , R 8 , R 9 and R 10 are each independently and independently at each occurrence hydrogen, fluorine, chlorine, bromine, iodine, hydroxyl, cyano, COR e ,CONR b Rd , N.R. b CO2R e , R a (C1-C6)-Alkyl, (C3-C5)-cycloalkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, phenyl, imidazolyl, each of which is substituted by m radicals selected from the group consisting of fluorine, chlorine, bromine, iodine, hydroxyl and cyano; (C1-C6)-alkoxy, (C3-C6)-cycloalkoxy, (C3-C6)-alkenyloxy, (C3-C6)-alkynyloxy, (C1-C3)-alkylthio, (C1-C3)-alkylsulfinyl or (C1-C3)-alkylsulfonyl, in which the aliphatic or cycloaliphatic moiety in the last seven radicals is substituted by m radicals selected from the group consisting of fluorine, chlorine, bromine, iodine, cyano and (C1-C2)-alkoxy; Y is hydrogen, cyano, hydroxyl, Z; (C1-C 12 )-alkyl, (C3-C8)-cycloalkyl, (C2-C 12 )-alkenyl or (C 12 )-alkynyl, and the last four aliphatic or cycloaliphatic groups are fluorine, chlorine, bromine, iodine, cyano, hydroxyl, OR d , Z, OZ, NHZ, S(O) n R a , SO2NR b R d , SO2NR b COR e , CO2R e ,CONR b R h , C.O.R. b ,CONR e SO2R a , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b SO2NR bR e , OCONR b R e , OCSNR b R e , POR f R f and C(R b )=NOR e substituted with m groups selected from the group consisting of: Z is formed from r carbon atoms, k nitrogen atoms, n sulfur atoms and n oxygen atoms, and is COR e ,CONR b R h , S(O) n R a , SO2NR b R d , SO2NR b COR e , C.O.R. b ,CONR e SO2R a , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b SO2NR b R e , OCONR b R e , OCSNR b R e , POR f R f and C(R b )=NOR e , R a , R c , R e and R f and wherein the sulfur and carbon ring atoms bear n oxo groups; R ais (C1-C6)-alkyl, (C2-C4)-alkynyl or (C3-C6)-cycloalkyl, wherein the last three aliphatic or cycloaliphatic groups are substituted by m groups selected from the group consisting of fluorine, chlorine, bromine, iodine, cyano, hydroxy and (C1-C3)-alkoxy; R b are hydrogen or independently R a has one of the given meanings; R c is fluorine, chlorine, bromine, iodine, cyano, hydroxyl; (C1-C6)-alkoxy, (C3-C6)-alkenyloxy or (C3-C6)-alkynyloxy, in which the aliphatic moieties in the last three groups are substituted by m groups selected from the group consisting of fluorine, chlorine, bromine, cyano and (C1-C2)-alkoxy; R d is hydrogen, (C1-C6)-alkyl, (C2-C4)-alkenyl, (C2-C4)-alkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C3)-alkyl, phenyl-(C1-C3)-alkyl or furanyl-(C1-C3)-alkyl, and the aliphatic, cycloaliphatic, aromatic or heteroaromatic moiety in the last seven groups mentioned is fluorine, chlorine, bromine, cyano, COR a ,CONR b R h , (C1-C2)-alkoxy, (C1-C3)-alkylthio, (C1-C3)-alkylsulfinyl, (C1-C3)-alkylsulfonyl, phenylthio, phenylsulfinyl and phenylsulfonyl; R e are independently d has one of the given meanings: R f is (C1-C3)-alkyl or (C1-C3)-alkoxy; R his hydrogen, (C1-C6)-alkyl, (C1-C2)-alkoxy, (C3-C6)-cycloalkyl, (C2-C4)-alkenyl, (C2-C4)-alkynyl or (C1-C6)-alkoxycarbonyl-(C1-C6)-alkyl, and the aliphatic or cycloaliphatic moiety in the last six groups is fluorine, chlorine, bromine, cyano, COR a and (C1-C2)-alkoxy; each k is independently 0, 1, 2, 3, or 4; each m is independently 0, 1, 2, 3, 4, or 5; each n is independently 0, 1, or 2; each p is independently 0, 1, or 2; each r is independently 1, 2, 3, 4, 5, 6, 7, or 8; each s is independently 5, 6, 7, 8, 9, 10, 11, 12, 13, or 14; each t is independently 0, 1, 2, 3, or 4 and agriculturally acceptable salts, stereoisomers and tautomers thereof, comprising the following compounds: N-[(S)-5-(2-hydroxy-ethyl)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl]-2-methoxy-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; 2-Ethoxy-N-[(S)-5-(2-hydroxy-ethyl)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl]-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; (S or R)-2-ethoxy-N-[(S)-5-(2-hydroxy-ethyl)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl]-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; 2-Methoxy-N-[(S)-5-(2-methoxy-ethyl)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl]-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; N-((6R,7S)-2-fluoro-6-methyl-8-oxo-6,7,8,9-tetrahydro-5-oxa-9-aza-benzocyclohepten-7-yl)-2-methoxy-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; 2-Methoxy-N-((6R,7S)-6-methyl-8-oxo-3-trifluoromethyl-6,7,8,9-tetrahydro-5-oxa-9-aza-benzocyclohepten-7-yl)-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; (-)-2-Methoxy-N-((S)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl)-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; N-((S)-5-cyclopropylmethyl-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl)-2-methoxy-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; 2-Methoxy-N-((S)-5-methyl-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl)-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide and agriculturally acceptable salts, stereoisomers and tautomers thereof, excluding the compounds and agriculturally acceptable salts, stereoisomers and tautomers thereof.

[0010] The present invention also relates to compositions comprising at least one compound of formula (I) and at least one adjuvant customarily used for formulating crop protection compounds.

[0011] The present invention also provides a combination comprising at least one compound of formula (I) (component A) and at least one further compound selected from a herbicidal compound B (component B; different from component A) and an antidote C (component C).

[0012] The present invention further relates to the use of a compound of formula (I) or said composition for controlling undesired vegetation and to a method for controlling undesired vegetation, which method comprises applying a herbicidally effective amount of at least one compound of formula (I) or said composition to a plant, its seeds and / or its habitat. DETAILED DESCRIPTION OF THE INVENTION

[0013] Definition: Depending on the type of substituents, the compounds of formula (I) may have one or more centers of chirality, in which case they may exist as a mixture of enantiomers or diastereomers, but also in the form of pure enantiomers or pure diastereomers. The present invention provides both pure enantiomers or pure diastereomers of the compounds of formula I and their mixtures, as well as the use of pure enantiomers or pure diastereomers of the compounds of formula I or their mixtures according to the invention. Suitable compounds of formula I also include all possible geometric stereoisomers (cis / trans isomers) and their mixtures, as specific forms of diastereomers. Cis / trans isomers may exist with respect to alkenes, carbon-nitrogen double bonds, nitrogen-sulfur double bonds, amide groups, or cyclic, non-aromatic moieties. The term "stereoisomer" encompasses both optical isomers, such as enantiomers or diastereomers (the latter existing due to the presence of one or more stereocenters in the molecule), and geometric isomers (cis / trans isomers). By way of example, a stereocenter may be present at X 1 ~X 6 R in 5 and R 6 However, of course, R 5 and R 6 Another example of a stereogenic center is OR 2 and R 3is an atom having the formula:

[0014] When the herbicidal compound B and / or antidote C have one or more asymmetric centers, they may also exist as enantiomers or diastereomers, and it is possible to use both the pure enantiomers and diastereomers or mixtures thereof.

[0015] When the compounds of formula (I), herbicidal compound B, and / or antidote C described herein have an ionizable functional group, they may be utilized in the form of their agriculturally acceptable salts. Suitable salts are generally salts of their cations and acid addition salts of their acids, where the cations and anions, respectively, do not adversely affect the activity of the active compounds.

[0016] Preferred cations are ions of alkali metals, preferably lithium, sodium and potassium, ions of alkaline earth metals, preferably calcium and magnesium, and ions of transition metals, preferably manganese, copper, zinc and iron, as well as ammonium and substituted ammonium in which one to four hydrogen atoms are replaced by C1-C4-alkyl, hydroxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkyl, hydroxy-C1-C4-alkoxy-C1-C4-alkyl, phenyl or benzyl, preferably ammonium, methylammonium, isopropylammonium, dimethylammonium, diethylammonium, diisopropylammonium, trimethylammonium, triethylammonium, tris(isopropyl)ammonium, heptylammonium, dodecylammonium, tetradecylammonium, tetramethyl ... and tris(2-hydroxyethyl)ammonium (trolamine salt), tris(2-hydroxypropyl)ammonium, benzyltrimethylammonium, benzyltriethylammonium, N,N,N-trimethylethanolammonium (choline salt), further phosphonium ions, sulfonium ions, preferably tri(C1-C4-alkyl)sulfonium, for example trimethylsulfonium and sulfoxonium ions, preferably tri(C1-C4-alkyl)sulfoxonium, and finally salts of polybasic amines such as N,N-bis-(3-aminopropyl)methylamine and diethylenetriamine.

[0017] Useful anions of acid addition salts are primarily chloride, bromide, fluoride, iodide, hydrogen sulfate, methyl sulfate, sulfate, dihydrogen phosphate, hydrogen phosphate, nitrate, bicarbonate, carboxylate, hexafluorosilicate, hexafluorophosphate, benzoate, and also anions of C1-C4-alkanoic acids, preferably formate, acetate, propionate and butyrate.

[0018] Compound (I) may exist in different tautomeric forms. For example, the keto form N(R 1 )-C(=O)-C(OR 2 )(R 3 )-C(=O)-N(R 4 ) is R 3 is hydrogen, its enol form N(R 1 )-C(OH)=C(OR 2 )-C(=O)-N(R 4 ) and N(R 1 )-C(=O)-C(OR 2 )=C(OH)-N(R 4 ) can be in equilibrium with

[0019] The same applies when ring Z contains a C(=O) group as a ring member adjacent to a CH ring member.

[0020] R Q1 is hydroxyl, then ring Q can also exist in the corresponding keto form. For example, if Q contains a fused pyridine ring bearing an OH group at the 2-position relative to the nitrogen ring atom, then ring Q can exist as its tautomeric form, 1,2-dihydropyridin-2-one (fused to another ring, of course).

[0021] Furthermore, when ring Z is a lactam, i.e., contains an amide group (= an unsubstituted secondary nitrogen ring atom adjacent to a carbon ring atom bearing an oxo group) as a ring member, this ring moiety -N(H)-C(=O)- can be in equilibrium with its tautomer -N=C(OH)-.

[0022] The two amide groups -N(R 1 )-C(=O)-C(OR 2 )(R 3 )-C(=O)-N(R 4 )-, R 1 and R 4 The same applies when one or both of are hydrogen.

[0023] R 1 is hydrogen, the malonamide moiety is -N(H)-C(=O)-C(OR 2 )(R 3 )-C(=O)-N(R 4 )- or -N=C(OH)-C(OR 2 )(R 3 )-C(=O)-N(R 4 )—or as a mixture of the two forms.

[0024] R 4 If only N is hydrogen, the malonamide moiety is -N(R 1 )-C(=O)-C(OR 2 )(R 3 )-C(=O)-N(H)- or -N(R 1 )-C(=O)-C(OR 2 )(R 3 )—C(OH)═N— or a mixture of these two forms.

[0025] R 1 and R 4 are hydrogen, the malonamide moiety is -N(H)-C(=O)-C(OR 2 )(R 3 )-C(=O)-N(H)-, or -N=C(OH)-C(OR 2 )(R 3 )-C(=O)-N(H)-, or -N(H)-C(=O)-C(OR 2 )(R 3 )-C(OH)=N-, or -N=C(OH)-C(OR 2 )(R 3 )—C(OH)═N— or a mixture of two, three or all four of the forms shown above.

[0026] The amount of one or the other tautomer present depends on the complete molecular structure and is also strongly dependent on the surrounding conditions (presence or absence of solvent, type of solvent, pH, temperature, etc.).

[0027] The term "undesirable vegetation" ("weeds") is understood to include any vegetation growing on non-crop land or on the crop plant site or location of sown crops and other desired crops. Vegetation is any vegetation other than the sown crop or desired crop (if present), including their germinated seeds, emerged seedlings, and established vegetation. Weeds, broadly defined, are plants that are considered undesirable in a particular location.

[0028] The organic moieties mentioned in the definitions of the variables above, like the term halogen, are generic to a list of individual members of that group. n ~C m indicates in each case the possible number of carbon atoms in the group.

[0029] The term halogen in each case denotes fluorine, bromine, chlorine or iodine, in particular fluorine, chlorine or bromine.

[0030] The term "partially or fully halogenated" means that one or more, for example 1, 2, 3, 4, or 5, or all, of the hydrogen atoms of a given group have been replaced by halogen atoms, particularly fluorine or chlorine. Partially or fully halogenated groups are also referred to hereinafter as "halo groups." For example, partially or fully halogenated alkyls are also referred to as haloalkyls.

[0031] As used herein, the term "alkyl" (and other groups that contain an alkyl group, such as the alkyl portions of alkoxy, alkylamino, dialkylamino, alkylcarbonyl, alkoxycarbonyl, alkylthio, alkylsulfonyl, and alkoxyalkyl) generally refers to an alkyl group containing, in each instance, 1 to 12 carbon atoms (=C1 to C6 12-alkyl), often denotes a straight-chain or branched alkyl group having 1 to 6 carbon atoms (=C1-C6-alkyl), in particular 1 to 4 carbon atoms (=C1-C4-alkyl), in particular 1 to 3 carbon atoms (=C1-C3-alkyl) or 1 or 2 carbon atoms (=C1-C2-alkyl). C1-C2-alkyl is methyl or ethyl. C1-C3-alkyl is methyl, ethyl, n-propyl or isopropyl. Examples of C1-C4-alkyl are methyl, ethyl, n-propyl, isopropyl, n-butyl, 2-butyl (=sec-butyl), isobutyl and tert-butyl. Examples of C1-C6-alkyl, in addition to those mentioned for C1-C4-alkyl, are n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, n-hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl and 1-ethyl-2-methylpropyl. Examples of C1-C8-alkyl, in addition to those mentioned for C1-C6-alkyl, are n-heptyl, 1-methylhexyl, 2-methylhexyl, 3-methylhexyl, 4-methylhexyl, 5-methylhexyl, 1-ethylpentyl, 2-ethylpentyl, 3-ethylpentyl, n-octyl, 1-methylheptyl, 2-methylheptyl, 1-ethylhexyl, 2-ethylhexyl, 1,2-dimethylhexyl, 1-propylpentyl and 2-propylpentyl. 12 Examples of -alkyl, in addition to those mentioned for C1-C8-alkyl, are nonyl, decyl, 2-propylheptyl, 3-propylheptyl, undecyl, dodecyl and positional isomers thereof.

[0032] As used herein, the term "haloalkyl" (and the haloalkyl moieties of other groups containing a haloalkyl group, such as haloalkoxy, haloalkylthio, haloalkylcarbonyl, haloalkylsulfonyl, and haloalkylsulfinyl) may also be referred to as "partially or fully halogenated alkyl," in each case referring to a straight-chain or branched alkyl group, as defined above, typically having 1 to 6 carbon atoms (=C1-C6-haloalkyl), more often 1 to 3 carbon atoms (=C1-C3-haloalkyl), in which the hydrogen atoms of the group are partially or fully replaced by halogen atoms. Preferred haloalkyl moieties are selected from C1-C3-haloalkyl, especially C1-C2-haloalkyl, and especially fluorinated C1-C2-alkyl. Examples of C1-C2-haloalkyl include fluoromethyl, difluoromethyl, trifluoromethyl, chloromethyl, dichloromethyl, trichloromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, bromomethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, pentafluoroethyl, 1-chloroethyl, 2-chloroethyl, 2,2-dichloroethyl, 2,2,2-trichloroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 1-bromoethyl, etc. Examples of C1-C3-haloalkyl, in addition to those mentioned for C1-C2-haloalkyl, are 1-fluoropropyl, 2-fluoropropyl, 3-fluoropropyl, 3,3-difluoropropyl, 3,3,3-trifluoropropyl, heptafluoropropyl, 1,1,1-trifluoroprop-2-yl, 3-chloropropyl, etc.

[0033] The term "hydroxyalkyl" denotes in each case a straight-chain or branched alkyl group, as defined above, usually having 1 to 6 carbon atoms (=C1-C6-hydroxyalkyl), more often 1 to 3 carbon atoms (=C1-C3-hydroxyalkyl), in which one hydrogen atom is replaced by a hydroxyl group. Examples are hydroxymethyl, 1-hydroxyethyl, 2-hydroxyethyl, 1-hydroxypropyl, 2-hydroxypropyl, 3-hydroxypropyl, 1-hydroxy-2-propyl, etc.

[0034] The term "cyanoalkyl" denotes in each case a straight-chain or branched alkyl group, as defined above, usually having 1 to 6 carbon atoms (=C1-C6-cyanoalkyl), more often 1 to 3 carbon atoms (=C1-C3-cyanoalkyl), in which one hydrogen atom is replaced by a cyano group, e.g., cyanomethyl, 1-cyanoethyl, 2-cyanoethyl, 1-cyanopropyl, 2-cyanopropyl, 3-cyanopropyl, 1-cyano-2-propyl, etc.

[0035] As used herein, the term "alkenyl" refers, in each instance, to an alkyl group having 2 to 12 carbon atoms (=C2 to C4). 12-alkenyl), preferably a monounsaturated straight-chain or branched hydrocarbon group having 2 to 6 carbon atoms (=C2-C6-alkenyl), for example 3 to 6 carbon atoms (=C3-C6-alkenyl), in particular 2 to 4 carbon atoms (=C2-C4-alkenyl) or 2 or 3 carbon atoms (=C2-C3-alkenyl) and a double bond in any position; for example, C2-C3-alkenyl, for example ethenyl, 1-propenyl, 2-propenyl or 1-methylethenyl; C2-C4-alkenyl, for example ethenyl, 1-propenyl, 2-propenyl, 1-methylethenyl alkenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl-1-propenyl, 2-methyl-1-propenyl, 1-methyl-2-propenyl or 2-methyl-2-propenyl; C2-C6-alkenyl, for example ethenyl, 1-propenyl, 2-propenyl, 1-methylethenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl-1-propenyl, 2-methyl-1-propenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 1-methyl-1-butenyl , 2-methyl-1-butenyl, 3-methyl-1-butenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl, 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl-1-propenyl, 1-ethyl-2-propenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl-1-pentenyl, 2-methyl-1-pentenyl nyl, 3-methyl-1-pentenyl, 4-methyl-1-pentenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1-methyl-3-pentenyl, 2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1-dimethyl-3-butenyl, 1,2-dimethyl-1-butenyl, 1,2-dimethyl-2-butenyl, 1,2-dimethyl-3-butenyl, 1,3-dimethyl-1-butenyl, 1,3-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl, 2,2-dimethyl-3-butenyl, 2,3-dimethyl-1-butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 3,3-dimethyl-1-butenyl, 3,3-dimethyl-2-butenyl thenyl, 1-ethyl-1-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl, 2-ethyl-1-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl, 1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl, 1-ethyl-2-methyl-1-propenyl, 1-ethyl-2-methyl-2-propenyl, and the like, or C2 to C6, 12 -alkenyl, for example the radicals mentioned for C2-C6-alkenyl and also 1-pentenyl, 2-pentenyl, 3-pentenyl, 1-octenyl, 2-octenyl, 3-octenyl, 4-octenyl, nonenyl, decenyl, undecenyl, dodecenyl, etc., and positional isomers thereof.

[0036] Examples of C3-C6-alkenyl are those mentioned for C2-C6-alkenyl, except ethenyl.

[0037] As used herein, the term "haloalkenyl" is also expressed as "alkenyl substituted with halogen," and the haloalkenyl moiety in haloalkenyloxy and the like refers to an unsaturated linear or branched hydrocarbon group having 2 to 6 (=C-C-haloalkenyl), 2 to 4 (=C-C-haloalkenyl), or 2 to 3 (=C-C-haloalkenyl) carbon atoms and a double bond at any position, in which some or all of the hydrogen atoms in these groups have been replaced by the above-mentioned halogen atoms, particularly fluorine, chlorine and bromine, for example, chlorovinyl, chloroallyl, etc.

[0038] As used herein, the term "alkynyl" refers to an alkyl group having 2 to 12 carbon atoms (=C2 to C4). 12-alkynyl), often an unsaturated linear or branched hydrocarbon radical having 2 to 6 carbon atoms (=C2-C6-alkynyl), preferably 2 to 4 carbon atoms (=C2-C4-alkynyl) or 2 to 3 carbon atoms (=C2-C3-alkynyl) and a triple bond in any position; for example, C2-C3-alkynyl, such as ethynyl, 1-propynyl or 2-propynyl; C2-C4-alkynyl, such as ethynyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl, etc.; C2-C6-alkynyl, such as ethynyl, 1-propynyl, 2-propynyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl, 1-pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-2-butynyl, 1-methyl-3-butynyl nyl, 2-methyl-3-butynyl, 3-methyl-1-butynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 1-hexynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl, 1-methyl-2-pentynyl, 1-methyl-3-pentynyl, 1-methyl-4-pentynyl, 2-methyl-3-pentynyl, 2-methyl-4-pentynyl, 3-methyl-1-pentynyl, 3 -methyl-4-pentynyl, 4-methyl-1-pentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl-2-butynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 3,3-dimethyl-1-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl, 2-ethyl-3-butynyl, 1-ethyl-1-methyl-2-propynyl, and the like.

[0039] As used herein, the term "haloalkynyl", also expressed as "alkynyl substituted with halogen", refers to an unsaturated linear or branched hydrocarbon group (as defined above) usually having 2 to 6 carbon atoms (=C2-C6-haloalkynyl), preferably 2 to 4 carbon atoms (=C2-C4-haloalkynyl) or 2 or 3 carbon atoms (=C2-C3-haloalkynyl) and a triple bond at any position, in which some or all of the hydrogen atoms of these groups have been replaced by the above-mentioned halogen atoms, particularly fluorine, chlorine and bromine.

[0040] As used herein (and in other groups containing cycloalkyl groups, such as the cycloalkyl moiety of cycloalkoxy and cycloalkylalkyl), the term "cycloalkyl" denotes, in each case, a monocyclic or bicyclic saturated cycloaliphatic group, typically having 3 to 6 carbon atoms (=C3-C6-cycloalkyl), 3 to 5 carbon atoms (=C3-C5-cycloalkyl), or 3 to 4 carbon atoms (=C3-C4-cycloalkyl) as the (only) ring member. Examples of monocyclic saturated cycloaliphatic groups having 3 or 4 carbon atoms include cyclopropyl and cyclobutyl. Examples of monocyclic saturated cycloaliphatic groups having 3 to 5 carbon atoms include cyclopropyl, cyclobutyl, and cyclopentyl. Examples of monocyclic saturated cycloaliphatic groups having 3 to 6 carbon atoms include cyclopropyl, cyclobutyl, cyclopentyl, and cyclohexyl. C5-C6-cycloalkyl is cyclopentyl or cyclohexyl. Examples of bicyclic groups having 5 or 6 carbon atoms include bicyclo[1.1.1]pentyl and bicyclo[2.1.1]hexyl. Preferably, the cycloalkyl is monocyclic.

[0041] As used herein (and in the halocycloalkyl moiety of other groups that contain halocycloalkyl groups), the term "halocycloalkyl" denotes a monocyclic or bicyclic cycloaliphatic group, typically having 3 to 8 carbon atoms ("C3-C8-halocycloalkyl"), preferably 3 to 5 carbon atoms ("C3-C5-halocycloalkyl"), in each case in which at least one, e.g., 1, 2, 3, 4 or 5, of the hydrogen atoms has been replaced by a halogen, in particular fluorine or chlorine. Examples are 1- and 2-fluorocyclopropyl, 1,2-, 2,2- and 2,3-difluorocyclopropyl, 1,2,2-trifluorocyclopropyl, 2,2,3,3-tetrafluorocyclopropyl, 1- and 2-chlorocyclopropyl, 1,2-, 2,2- and 2,3-dichlorocyclopropyl, 1,2,2-trichlorocyclopropyl, 2,2,3,3-tetrachlorocyclopropyl, 1-, 2- and 3-fluorocyclopentyl, 1,2-, 2,2-, 2,3-, 3,3-, 3,4-, 2,5-difluorocyclopentyl, 1-, 2- and 3-chlorocyclopentyl, 1,2-, 2,2-, 2,3-, 3,3-, 3,4-, 2,5-dichlorocyclopentyl, and the like.

[0042] As used herein, the term "alkoxy" denotes in each case a straight-chain or branched alkyl group, usually having 1 to 6 carbon atoms (=C1-C6-alkoxy), preferably 1 to 3 carbon atoms (=C1-C3-alkoxy), in particular 1 or 2 carbon atoms (=C1-C2-alkoxy), which is attached to the remainder of the molecule via an oxygen atom. C1-C2-alkoxy is methoxy or ethoxy. C1-C3-alkoxy is furthermore, for example, n-propoxy or 1-methylethoxy (isopropoxy). C1-C6-Alkoxy further includes, for example, butoxy, 1-methylpropoxy (sec-butoxy), 2-methylpropoxy (isobutoxy) or 1,1-dimethylethoxy (tert-butoxy), pentoxy, 1-methylbutoxy, 2-methylbutoxy, 3-methylbutoxy, 1,1-dimethylpropoxy, 1,2-dimethylpropoxy, 2,2-dimethylpropoxy, 1-ethylpropoxy, hexoxy, 1-methylpentoxy, 2-methylpropoxy, 1-methylpentoxy, 2-methylpropoxy, 1-methyleth ... ethylpentoxy, 3-methylpentoxy, 4-methylpentoxy, 1,1-dimethylbutoxy, 1,2-dimethylbutoxy, 1,3-dimethylbutoxy, 2,2-dimethylbutoxy, 2,3-dimethylbutoxy, 3,3-dimethylbutoxy, 1-ethylbutoxy, 2-ethylbutoxy, 1,1,2-trimethylpropoxy, 1,2,2-trimethylpropoxy, 1-ethyl-1-methylpropoxy or 1-ethyl-2-methylpropoxy.

[0043] As used herein, the term "haloalkoxy" denotes a straight-chain or branched alkoxy group, in each case as defined above, having 1 to 6 carbon atoms (=C1-C6-haloalkoxy), preferably 1 to 3 carbon atoms (=C1-C3-haloalkoxy), in particular 1 or 2 carbon atoms (=C1-C2-haloalkoxy), in which the hydrogen atoms are partially or fully replaced by halogen atoms, in particular fluorine atoms (in which case the group is also referred to as fluorinated alkoxy). C1-C2-Haloalkoxy is, for example, OCH2F, OCHF2, OCF3, OCH2Cl, OCHCl2, OCCl3, chlorofluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethoxy, 2-fluoroethoxy, 2-chloroethoxy, 2-bromoethoxy, 2-iodoethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro-2-fluoroethoxy, 2-chloro-2,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy or OC2F5. C1-C3-Haloalkoxy is furthermore, for example, 2-fluoropropoxy, 3-fluoropropoxy, 2,2-difluoropropoxy, 2,3-difluoropropoxy, 2-chloropropoxy, 3-chloropropoxy, 2,3-dichloropropoxy, 2-bromopropoxy, 3-bromopropoxy, 3,3,3-trifluoropropoxy, 3,3,3-trichloropropoxy, OCH2-C2F5, OCF2-C2F5, 1-(CH2F)-2-fluoroethoxy, 1-(CH2Cl)-2-chloroethoxy or 1-(CH2Br)-2-bromoethoxy. C1-C6-Haloalkoxy is furthermore, for example, 4-fluorobutoxy, 4-chlorobutoxy, 4-bromobutoxy or nonafluorobutoxy, 5-fluoropentoxy, 5-chloropentoxy, 5-bromopentoxy, 5-iodopentoxy, undecafluoropentoxy, 6-fluorohexoxy, 6-chlorohexoxy, 6-bromohexoxy, 6-iodohexoxy or dodecafluorohexoxy.

[0044] The term "cyanoalkoxy" denotes in each case a straight-chain or branched alkyl group, as defined above, usually having 1 to 6 carbon atoms (=C1-C6-cyanoalkoxy), more often 1 to 3 carbon atoms (=C1-C3-cyanoalkoxy), in which one hydrogen atom is replaced by a cyano group. Examples are cyanomethoxy, 1-cyanoethoxy, 2-cyanoethoxy, 1-cyanopropoxy, 2-cyanopropoxy, 3-cyanopropoxy, 1-cyano-2-propoxy, etc.

[0045] The term "alkenyloxy" denotes an alkenyl group as defined above which is bonded to the rest of the molecule via an oxygen atom. C2-C6-alkenyloxy is a C2-C6-alkenyl group as defined above which is bonded to the rest of the molecule via an oxygen atom. C3-C6-alkenyloxy is a C3-C6-alkenyl group as defined above which is bonded to the rest of the molecule via an oxygen atom.

[0046] The term "haloalkenyloxy" denotes a haloalkenyl group as defined above which is bonded to the rest of the molecule via an oxygen atom. C2-C6-haloalkenyloxy is a C2-C6-haloalkenyl group as defined above which is bonded to the rest of the molecule via an oxygen atom. C3-C6-haloalkenyloxy is a C3-C6-haloalkenyl group as defined above which is bonded to the rest of the molecule via an oxygen atom.

[0047] The term "alkynyloxy" denotes an alkynyl group as defined above which is bonded to the rest of the molecule via an oxygen atom. C2-C6-alkynyloxy is a C2-C6-alkynyl group as defined above which is bonded to the rest of the molecule via an oxygen atom. C3-C6-alkynyloxy is a C3-C6-alkynyl group as defined above which is bonded to the rest of the molecule via an oxygen atom.

[0048] The term "haloalkynyloxy" denotes a haloalkynyl group as defined above which is bonded to the rest of the molecule via an oxygen atom. C2-C6-haloalkynyloxy is a C2-C6-haloalkynyl group as defined above which is bonded to the rest of the molecule via an oxygen atom. C3-C6-haloalkynyloxy is a C3-C6-haloalkynyl group as defined above which is bonded to the rest of the molecule via an oxygen atom.

[0049] The term "cycloalkoxy" denotes a cycloalkyl group as defined above, which is bonded to the rest of the molecule via an oxygen atom. C3-C6-cycloalkoxy is a C3-C6-cycloalkyl group as defined above, which is bonded to the rest of the molecule via an oxygen atom. Examples of C3-C6-cycloalkoxy include cyclopropoxy, cyclobutoxy, cyclopentoxy and cyclohexoxy.

[0050] The term "C1-C3-alkoxy-C1-C3-alkyl" refers to an alkyl group having 1 to 3 carbon atoms as defined above, in which one hydrogen atom is replaced by a C1-C3-alkoxy group as defined above. Examples include methoxymethyl, ethoxymethyl, propoxymethyl, isopropoxymethyl, 1-methoxyethyl, 1-ethoxyethyl, 1-propoxyethyl, 1-isopropoxyethyl, 2-methoxyethyl, 2-ethoxyethyl, 2-propoxyethyl, 2-isopropoxyethyl, 1-methoxypropyl, 1-ethoxypropyl, 1-propoxypropyl, 1-isopropoxypropyl, 2-methoxypropyl, 2-ethoxypropyl, 2-propoxypropyl, 2-isopropoxypropyl, 3-methoxypropyl, 3-ethoxypropyl, 3-propoxypropyl, 3-isopropoxypropyl, etc.

[0051] The term "C3-C5-cycloalkyl-C1-C3-alkyl" refers to an alkyl group having 1 to 3 carbon atoms as defined above, in which one hydrogen atom is replaced by a C3-C5-cycloalkyl group as defined above. Examples include cyclopropylmethoxy, cyclobutylmethoxy, cyclopentylmethoxy, 1-cyclopropylethoxy, 2-cyclopropylethoxy, 1-cyclobutylethoxy, 2-cyclobutylethoxy, 1-cyclopentylethoxy, 2-cyclopentylethoxy, 1-cyclopropylpropoxy, 2-cyclopropylpropoxy, 3-cyclopropylpropoxy, 1-cyclobutylpropoxy, 2-cyclobutylpropoxy, 3-cyclobutylpropoxy, 1-cyclopentylpropoxy, 2-cyclopentylpropoxy, 3-cyclopentylpropoxy, etc.

[0052] As used herein, the term "alkoxy-alkoxy" refers to an alkoxy group as defined above in which one hydrogen atom is replaced by another alkoxy group as defined above. As used herein, the term "C1-C3-alkoxy-C1-C3-alkoxy" refers to an alkoxy group having 1 to 3 carbon atoms as defined above in which one hydrogen atom is replaced by a C1-C3-alkoxy group as defined above. Examples include methoxymethoxy, ethoxymethoxy, propoxymethoxy, isopropoxymethoxy, 1-methoxyethoxy, 1-ethoxyethoxy, 1-propoxyethoxy, 1-isopropoxyethoxy, 2-methoxyethoxy, 2-ethoxyethoxy, 2-propoxyethoxy, 2-isopropoxyethoxy, 1-methoxypropoxy, 1-ethoxypropoxy, 1-propoxypropoxy, 1-isopropoxypropoxy, 2-methoxypropoxy, 2-ethoxypropoxy, 2-propoxypropoxy, 2-isopropoxypropoxy, 3-methoxypropoxy, 3-ethoxypropoxy, 3-propoxypropoxy, 3-isopropoxypropoxy, and the like.

[0053] As used herein, the term "alkylthio" (including alkylsulfanyl, "alkyl-S" or "alkyl-S(O) k " (where k is also 0)) denotes in each case a linear or branched saturated alkyl group as defined above, which usually contains 1 to 6 carbon atoms (=C1-C6-alkylthio), preferably 1 to 3 carbon atoms (=C1-C3-alkylthio), and is bonded via a sulfur atom at any position of the alkyl group. C1-C2-Alkylthio is methylthio or ethylthio. C1-C3-Alkylthio is furthermore, for example, n-propylthio or 1-methylethylthio (isopropylthio). C1-C6-Alkylthio is furthermore, for example, butylthio, 1-methylpropylthio (sec-butylthio), 2-methylpropylthio (isobutylthio), 1,1-dimethylethylthio (tert-butylthio), pentylthio, 1-methylbutylthio, 2-methylbutylthio, 3-methylbutylthio, 1,1-dimethylpropylthio, 1,2-dimethylpropylthio, 2,2dimethylpropylthio, 1-ethylpropylthio, hexylthio, 1-methylpentylthio, 2-methylpentylthio, 3-methylpentylthio, 4-methylpentylthio, 1,1-dimethylbutylthio, 1,2-dimethylbutylthio, 1,3-dimethylbutylthio, 2,2-dimethylbutylthio, 2,3-dimethylbutylthio, 3,3-dimethylbutylthio, 1-ethylbutylthio, 2-ethylbutylthio, 1,1,2-trimethylpropylthio, 1,2,2-trimethylpropylthio, 1-ethyl-1methylpropylthio or 1-ethyl-2-methylpropylthio.

[0054] As used herein, the term "haloalkylthio" refers to an alkylthio group as defined above in which the hydrogen atoms are partially or fully substituted by fluorine, chlorine, bromine, and / or iodine. C1-C2-haloalkylthio is, for example, SCH2F, SCHF2, SCF3, SCH2Cl, SCHCl2, SCCl3, chlorofluoromethylthio, dichlorofluoromethylthio, chlorodifluoromethylthio, 2-fluoroethylthio, 2-chloroethylthio, 2-bromoethylthio, 2-iodoethylthio, 2,2-difluoroethylthio, 2,2,2-trifluoroethylthio, 2-chloro-2-fluoroethylthio, 2-chloro-2,2-difluoroethylthio, 2,2-dichloro-2-fluoroethylthio, 2,2,2-trichloroethylthio, or SC2F5. C1-C4-Haloalkylthio is furthermore, for example, 2-fluoropropylthio, 3-fluoropropylthio, 2,2-difluoropropylthio, 2,3-difluoropropylthio, 2-chloropropylthio, 3-chloropropylthio, 2,3-dichloropropylthio, 2-bromopropylthio, 3-bromopropylthio, 3,3,3-trifluoropropylthio, 3,3,3-trichloropropylthio, SCH2-C2F5, SCF2-C2F5, 1-(CH2F)-2-fluoroethylthio, 1-(CH2Cl)-2-chloroethylthio, 1-(CH2Br)-2-bromoethylthio, 4-fluorobutylthio, 4-chlorobutylthio, 4-bromobutylthio or nonafluorobutylthio. C1-C6-Haloalkylthio is furthermore, for example, 5-fluoropentylthio, 5-chloropentylthio, 5-bromopentylthio, 5-iodopentylthio, undecafluoropentylthio, 6-fluorohexylthio, 6-chlorohexylthio, 6-bromohexylthio, 6-iodohexylthio or dodecafluorohexylthio.

[0055] "Alkylsulfinyl" and "Alkyl-S(O) k" (where k is 1) are equivalent and, as used herein, denote an alkyl group as defined above bonded via a sulfinyl [S(O)] group. For example, the term "C1-C2-alkylsulfinyl" denotes a C1-C2-alkyl group as defined above bonded via a sulfinyl [S(O)] group. The term "C1-C3-alkylsulfinyl" denotes a C1-C3-alkyl group as defined above bonded via a sulfinyl [S(O)] group. The term "C1-C6-alkylsulfinyl" denotes a C1-C6-alkyl group as defined above bonded via a sulfinyl [S(O)] group. C1-C2-Alkylsulfinyl is methylsulfinyl or ethylsulfinyl. C1-C3-Alkylsulfinyl is furthermore, for example, n-propylsulfinyl or 1-methylethylsulfinyl (isopropylsulfinyl). C1-C6-Alkylsulfinyl further includes, for example, butylsulfinyl, 1-methylpropylsulfinyl (sec-butylsulfinyl), 2-methylpropylsulfinyl (isobutylsulfinyl), 1,1-dimethylethylsulfinyl (tert-butylsulfinyl), pentylsulfinyl, 1-methylbutylsulfinyl, 2-methylbutylsulfinyl, 3-methylbutylsulfinyl, 1,1-dimethylpropylsulfinyl, 1,2-dimethylpropylsulfinyl, 2,2-dimethylpropylsulfinyl, 1-ethylpropylsulfinyl, hexylsulfinyl, 1-methylpentylsulfinyl, phenylsulfinyl, 2-methylpentylsulfinyl, 3-methylpentylsulfinyl, 4-methylpentylsulfinyl, 1,1-dimethylbutylsulfinyl, 1,2-dimethylbutylsulfinyl, 1,3-dimethylbutylsulfinyl, 2,2-dimethylbutylsulfinyl, 2,3-dimethylbutylsulfinyl, 3,3-dimethylbutylsulfinyl, 1-ethylbutylsulfinyl, 2-ethylbutylsulfinyl, 1,1,2-trimethylpropylsulfinyl, 1,2,2-trimethylpropylsulfinyl, 1-ethyl-1-methylpropylsulfinyl or 1-ethyl-2-methylpropylsulfinyl.

[0056] "Alkylsulfonyl" and "Alkyl-S(O) k The terms "C1-C2-alkylsulfonyl" (where k is 2) are equivalent and, as used herein, denote an alkyl group as defined above bonded via a sulfonyl [S(O)2] group. The term "C1-C2-alkylsulfonyl" denotes a C1-C2-alkyl group as defined above bonded via a sulfonyl [S(O)2] group. The term "C1-C3-alkylsulfonyl" denotes a C1-C3-alkyl group as defined above bonded via a sulfonyl [S(O)2] group. The term "C1-C6-alkylsulfonyl" denotes a C1-C6-alkyl group as defined above bonded via a sulfonyl [S(O)2] group. C1-C2-alkylsulfonyl is methylsulfonyl or ethylsulfonyl. C1-C3-alkylsulfonyl is furthermore, for example, n-propylsulfonyl or 1-methylethylsulfonyl (isopropylsulfonyl). C1-C6-Alkylsulfonyl further includes, for example, butylsulfonyl, 1-methylpropylsulfonyl (sec-butylsulfonyl), 2-methylpropylsulfonyl (isobutylsulfonyl), 1,1-dimethylethylsulfonyl (tert-butylsulfonyl), pentylsulfonyl, 1-methylbutylsulfonyl, 2-methylbutylsulfonyl, 3-methylbutylsulfonyl, 1,1-dimethylpropylsulfonyl, 1,2-dimethylpropylsulfonyl, 2,2-dimethylpropylsulfonyl, 1-ethylpropylsulfonyl, hexylsulfonyl, 1-methylpentylsulfonyl, butylsulfonyl, 2-methylpentylsulfonyl, 3-methylpentylsulfonyl, 4-methylpentylsulfonyl, 1,1-dimethylbutylsulfonyl, 1,2-dimethylbutylsulfonyl, 1,3-dimethylbutylsulfonyl, 2,2-dimethylbutylsulfonyl, 2,3-dimethylbutylsulfonyl, 3,3-dimethylbutylsulfonyl, 1-ethylbutylsulfonyl, 2-ethylbutylsulfonyl, 1,1,2-trimethylpropylsulfonyl, 1,2,2-trimethylpropylsulfonyl, 1-ethyl-1-methylpropylsulfonyl or 1-ethyl-2-methylpropylsulfonyl.

[0057] The substituent "oxo" replaces a CH2 group with a C(=O) group.

[0058] The radical suffix "-carbonyl" indicates that the radical is attached to the remainder of the molecule via a carbonyl (C=O) group, as in, for example, alkylcarbonyl, haloalkylcarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkoxycarbonyl, and haloalkoxycarbonyl.

[0059] The term "alkylcarbonyl" denotes an alkyl group as defined above, which is bonded to the rest of the molecule via a carbonyl [C(=O)] group. C1-C3-alkylcarbonyl is a C1-C3-alkyl group as defined above, which is bonded to the rest of the molecule via a carbonyl [C(=O)] group. C1-C4-alkylcarbonyl is a C1-C4-alkyl group as defined above, which is bonded to the rest of the molecule via a carbonyl [C(=O)] group. Examples of C1-C3-alkylcarbonyl are acetyl (methylcarbonyl), propionyl (ethylcarbonyl), propylcarbonyl, isopropylcarbonyl. Examples of C1-C4-alkylcarbonyl are acetyl (methylcarbonyl), propionyl (ethylcarbonyl), propylcarbonyl, isopropylcarbonyl, n-butylcarbonyl, etc.

[0060] The term "alkoxycarbonyl" denotes a haloalkyl group as defined above, which is bonded to the rest of the molecule via a carbonyl [C(=O)] group. C1-C3-alkoxycarbonyl is a C1-C3-alkoxy group as defined above, which is bonded to the rest of the molecule via a carbonyl [C(=O)] group. Examples of C1-C3-alkoxycarbonyl are methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl and isopropoxycarbonyl. C1-C6-alkoxycarbonyl refers to a C1-C6-alkoxy group as defined above, which is bonded to the rest of the molecule via a carbonyl [C(=O)] group. Examples of C1-C6-alkoxycarbonyl, in addition to those listed for C1-C3-alkoxycarbonyl, are n-butoxycarbonyl, sec-butoxycarbonyl, isobutoxycarbonyl, tert-butoxycarbonyl, pentoxycarbonyl and hexylcarbonyl.

[0061] The term "alkoxycarbonyl-alkyl" denotes an alkyl group as defined above, in which one hydrogen atom is replaced by an alkoxycarbonyl group as defined above. C1-C6-alkoxycarbonyl-C1-C6-alkyl is a C1-C6-alkyl group as defined above, in which one hydrogen atom is replaced by a C1-C6-alkoxycarbonyl group as defined above.

[0062] Aminocarbonyl refers to the group H2NC(O)-.

[0063] The term "C1-C4-alkylaminocarbonyl" denotes the group C1-C4-alkyl-N(H)-C(O)-. Examples thereof are methylaminocarbonyl, ethylaminocarbonyl, propylaminocarbonyl, isopropylaminocarbonyl, n-butylaminocarbonyl, sec-butylaminocarbonyl, isobutylaminocarbonyl and tert-butylaminocarbonyl.

[0064] The term "di-(C1-C4-alkyl)aminocarbonyl" denotes the group (C1-C4-alkyl)N-C(O)-. Examples are dimethylaminocarbonyl, diethylaminocarbonyl, ethylmethylaminocarbonyl, dipropylaminocarbonyl, diisopropylaminocarbonyl, methylpropylaminocarbonyl, methylisopropylaminocarbonyl, ethylpropylaminocarbonyl, ethylisopropylaminocarbonyl, n-butyl-methylaminocarbonyl, n-butyl-ethylaminocarbonyl, n-butyl-propylaminocarbonyl, di-n-butylaminocarbonyl, 2-butyl-methylaminocarbonyl, 2-butyl-ethylaminocarbonyl, 2-butyl-propylaminocarbonyl, isobutyl-methylaminocarbonyl, ethyl-isobutylaminocarbonyl, isobutyl-propylaminocarbonyl, tert-butyl-methylaminocarbonyl, tert-butyl-ethylaminocarbonyl, tert-butyl-propylaminocarbonyl and the like.

[0065] Benzyloxycarbonyl is also known as the group Cbz or Z, fluorenyloxycarbonyl is also known as Fmoc, and allyloxycarbonyl is also known as Alloc.

[0066] Phenyl-(C1-C3-alkyl) is a C1-C3-alkyl group as defined above in which one hydrogen atom is replaced by a phenyl ring (i.e. the bond to the rest of the molecule is via the alkyl group). Examples are benzyl, 1-phenylethyl, 2-phenylethyl, 1-phenylpropyl, 2-phenylpropyl, 3-phenylpropyl or 2-phenyl-2-propyl.

[0067] Furanyl-(C1-C3-alkyl) is a C1-C3-alkyl group as defined above in which one hydrogen atom is replaced by a 2- or 3-furanyl ring (i.e. the bond to the rest of the molecule is via the alkyl group). Examples are furan-2-yl-methyl, furan-3-yl-methyl, 1-(furan-2-yl)-ethyl, 1-(furan-3-yl)-ethyl, 2-(furan-2-yl)-ethyl, 2-(furan-3-yl)-ethyl.

[0068] Phenylthio is a phenyl ring attached to the rest of the molecule via an S atom.

[0069] Phenylsulfinyl is a phenyl ring attached to the rest of the molecule via an S(O) group.

[0070] Phenylsulfonyl is a phenyl ring attached to the rest of the molecule via an S(O)2 group.

[0071] In the context of this invention, a bicyclic ring includes two rings that share at least one ring atom in common. This term includes condensed (fused) ring systems in which two rings share two adjacent ring atoms, as well as spiro systems in which the rings share only one ring atom and bridged systems in which the rings share at least three ring atoms in common. Unless otherwise specified, a bicyclic ring may be a carbocyclic ring containing only carbon atoms as ring members, as well as a heterocyclic ring containing at least one heteroatom or group of heteroatoms selected from N, O, S, S(O), and S(O)2 as a ring member. Further details are provided below.

[0072] A polycyclic ring contains three or more rings, each of which shares at least one ring atom with at least one other ring in the polycyclic ring system. The rings can be fused, spiro-linked, or bridged; mixed systems (e.g., one ring is spiro-linked to a fused system, or a bridged system is fused to another ring) are also possible. Unless otherwise specified, a polycyclic ring can be carbocyclic, containing only carbon atoms as ring members, or heterocyclic, containing at least one heteroatom or heteroatom group selected from N, O, S, S(O), and S(O)2 as a ring member. Further details are provided below.

[0073] Z is a 3-, 4-, 5-, 6-, 7-, or 8-membered saturated, partially unsaturated, fully unsaturated, or aromatic monocyclic, bicyclic, or polycyclic ring (excluding phenyl) formed from r carbon atoms (r=1-8), k nitrogen atoms (k=0-4), n sulfur atoms, and n oxygen atoms, with n oxo groups (n=0-2) attached to the sulfur carbon ring atoms. A carbon ring atom can, of course, have zero or only one oxo group. When a sulfur atom contains one or two oxo groups, the resulting heteroatom groups S(O) and S(O)2 become ring members.

[0074] Thus, ring Z can be a carbocyclic ring (i.e., containing only carbon atoms as ring members; r is 3 to 8, and k and n as the number of O and S ring atoms is 0) or a heterocyclic ring (i.e., also containing at least one N, O, and / or S as ring member atom; thus, r is 1 to 7, and at least one of n as the number of O and S ring atoms and / or k is 1).

[0075] An unsaturated carbocycle contains at least one CC double bond. An unsaturated heterocycle contains at least one CC and / or CN and / or NN double bond. A partially unsaturated carbocycle contains fewer CC double bonds than the maximum allowed by the ring size. A partially unsaturated heterocycle contains fewer CC and / or CN and / or NN double bonds than the maximum allowed by the ring size. A fully (or maximally) unsaturated carbocycle contains as many conjugated CC double bonds as the ring size allows, with the exception that phenyl is not included in the definition of Z. A fully (or maximally) unsaturated heterocycle contains as many conjugated CC and / or CN and / or NN double bonds as the ring size allows. Maximum unsaturated 5- or 6-membered heteromonocycles are generally aromatic. Exceptions are maximum unsaturated 6-membered rings containing O, S, SO, and / or SO as ring members, such as pyran and thiopyran, which are not aromatic.

[0076] Examples of 3-, 4-, 5-, 6-, 7- or 8-membered saturated monocyclic carbocyclic rings Z are cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl and cyclooctyl.

[0077] Examples of 3-, 4-, 5-, 6-, 7- or 8-membered partially or fully unsaturated monocyclic carbocycles Z are cycloprop-1-enyl, cycloprop-2-enyl, cyclobut-1-enyl, cyclobut-2-enyl, cyclobutadienyl, cyclopent-1-enyl, cyclopent-2-enyl, cyclopent-3-enyl, cyclopenta-1,3-dienyl, cyclopenta-1,4-dienyl, cyclopenta-2,4-dienyl, cyclohex-1-enyl, cyclohex-2-enyl, Cyclohex-3-enyl, cyclohexa-1,3-dienyl, cyclohexa-1,4-dienyl, cyclohexa-1,5-dienyl, cyclohexa-2,4-dienyl, cyclohexa-2,5-dienyl, cyclohept-1-enyl, cyclohept-2-enyl, cyclohept-3-enyl, cyclohept-4-enyl, cyclohepta-1,3-dienyl, cyclohepta-1,4-dienyl, cyclohepta-1,5-dienyl, cyclohepta-1,6-dienyl, cyclo cyclohepta-2,4-dienyl, cyclohepta-2,5-dienyl, cyclohepta-2,6-dienyl, cyclohepta-3,5-dienyl, cyclohepta-1,3,5-trienyl, cyclooct-1-enyl, cyclooct-2-enyl, cyclooct-3-enyl, cyclooct-4-enyl, cyclooct-5-enyl, cyclooct-6-enyl, cyclooct-7-enyl, cycloocta-1,3-dienyl, cycloocta-1,4-dienyl, cycloocta -1,5-dienyl, cycloocta-1,6-dienyl, cycloocta-1,7-dienyl, cycloocta-2,4-dienyl, cycloocta-2,5-dienyl, cycloocta-2,6-dienyl, cycloocta-2,7-dienyl, cycloocta-3,5-dienyl, cycloocta-3,6-dienyl, cycloocta-1,3,5-trienyl, cycloocta-1,3,7-trienyl, cycloocta-2,4,6-trienyl, and cyclooctatetraenyl.

[0078] Examples of 3-, 4-, 5-, 6-, 7- or 8-membered saturated, partially unsaturated, fully unsaturated or aromatic heterocycles Z are shown below.

[0079] 3-, 4-, 5-, 6-, 7- or 8-membered saturated monocyclic heterocycles: for example, oxiran-2-yl, thiiran-2-yl, aziridin-1-yl, aziridin-2-yl, oxetan-2-yl, oxetan-3-yl, thietan-2-yl, thietan-3-yl, 1-oxothietan-2-yl, 1-oxothietan-3-yl, 1,1-dioxothietan-2-yl, 1,1-dioxothietan-3-yl, azetidin-1-yl, azetidin-2-yl, azetidin-3-yl, tetrahydrofuran-2-yl, tetrahydrofuran-3 ... tetrahydrothien-2-yl, tetrahydrothien-3-yl, 1-oxotetrahydrothien-2-yl, 1,1-dioxotetrahydrothien-2-yl, 1-oxotetrahydrothien-3-yl, 1,1-dioxotetrahydrothien-3-yl, 1,3-dioxolan-2-yl, 1,3-dioxolan-4-yl, 1,3-dithiolan-2-yl, 1,3-dithiolan-4-yl, 1,3-oxathiolan-2-yl, 1,3-oxathiolan-4-yl, 1,3-oxathiolan-5-yl, pyrrolidin-1-yl, pyrrolidin 2-yl, pyrrolidin-3-yl, pyrazolidin-1-yl, pyrazolidin-3-yl, pyrazolidin-4-yl, pyrazolidin-5-yl, imidazolidin-1-yl, imidazolidin-2-yl, imidazolidin-4-yl, oxazolidin-2-yl, oxazolidin-3-yl, oxazolidin-4-yl, oxazolidin-5-yl, isoxazolidin-2-yl, isoxazolidin-3-yl, isoxazolidin-4-yl, isoxazolidin-5-yl, thiazolidin-2-yl, thiazolidin-3-yl, thiazolidin-3-yl, thiazolidin-4-yl 4-oxodiazolidin-yl, thiazolidin-5-yl, isothiazolidin-2-yl, isothiazolidin-3-yl, isothiazolidin-4-yl, isothiazolidin-5-yl, 1,2,4-oxadiazolidin-3-yl, 1,2,4-oxadiazolidin-5-yl, 1,2,4-thiadiazolidin-3-yl, 1,2,4-thiadiazolidin-5-yl, 1,3,4-oxadiazolidin-2-yl, 1,3,4-thiadiazolidin-2-yl, 1,2,4-triazolidin-1-yl, 1,2,4-triazolidin-3-yl, 1,2,4-Triazolidin-4-yl, 2-tetrahydropyranyl, 3-tetrahydropyranyl, 4-tetrahydropyranyl, 1,3-dioxan-2-yl, 1,3-dioxan-5-yl, 1,4-dioxan-2-yl, piperidin-1-yl, piperidin-2-yl, piperidin-3-yl, piperidin-4-yl, hexahydropyridazin-1-yl, hexahydropyridazin-3-yl, hexahydropyridazin-4-yl, hexahydropyrimidin-1-yl, hexahydropyrimidin 1,3,5-hexahydrotriazin-1-yl, 1,3,5-hexahydrotriazin-2-yl, 1,2,4-hexahydrotriazin-1-yl, 1,2,4-hexahydrotriazin-2-yl, 1,2,4-hexahydrotriazin-3-yl, 1,2,4-hexahydrotriazin-4-yl, 1,2,4-hexahydrotriazin-5-yl yl, 1,2,4-hexahydrotriazin-6-yl, morpholin-2-yl, morpholin-3-yl, morpholin-4-yl, thiomorpholin-2-yl, thiomorpholin-3-yl, thiomorpholin-4-yl, 1-oxothiomorpholin-2-yl, 1-oxothiomorpholin-3-yl, 1-oxothiomorpholin-4-yl, 1,1-dioxothiomorpholin-2-yl, 1,1-dioxothiomorpholin-3-yl, 1,1-dioxothiomorpholin-4-yl, azepan-1 -, -2-, -3- or -4-yl, oxepan-2-, -3-, -4- or -5-yl, hexahydro-1,3-diazepinyl, hexahydro-1,4-diazepinyl, hexahydro-1,3-oxazepinyl, hexahydro-1,4-oxazepinyl, hexahydro-1,3-dioxepinyl, hexahydro-1,4-dioxepinyl, oxocane, thiocane, azocanyl, [1,3]diazocanyl, [1,4]diazocanyl, [1,5]diazocanyl, [1,5]oxazocanyl, etc.

[0080] 3-, 4-, 5-, 6-, 7- or 8-membered partially unsaturated monocyclic heterocycles: 2,3-dihydrofuran-2-yl, 2,3-dihydrofuran-3-yl, 2,4-dihydrofuran-2-yl, 2,4-dihydrofuran-3-yl, 2,3-dihydrothien-2-yl, 2,3-dihydrothien-3-yl, 2,4-dihydrothien-2-yl, 2,4-dihydrothien-3-yl, 2-pyrrolin-2-yl, 2-pyrrolin-3-yl, 3-pyrrolin-2-yl, 3-pyrrolin-3-yl, 2-isoxazolin-3-yl, 3-isoxazoline Isoxazolin-3-yl, 4-isoxazolin-3-yl, 2-isoxazolin-4-yl, 3-isoxazolin-4-yl, 4-isoxazolin-4-yl, 2-isoxazolin-5-yl, 3-isoxazolin-5-yl, 4-isoxazolin-5-yl, 2-isothiazolin-3-yl, 3-isothiazolin-3-yl, 4-isothiazolin-3-yl, 2-isothiazolin-4-yl, 3-isothiazolin-4-yl, 4-isothiazolin-4-yl, 2-isothiazolin-5-yl, 3-isothiazolin-5-yl , 4-isothiazolin-5-yl, 2,3-dihydropyrazol-1-yl, 2,3-dihydropyrazol-2-yl, 2,3-dihydropyrazol-3-yl, 2,3-dihydropyrazol-4-yl, 2,3-dihydropyrazol-5-yl, 3,4-dihydropyrazol-1-yl, 3,4-dihydropyrazol-3-yl, 3,4-dihydropyrazol-4-yl, 3,4-dihydropyrazol-5-yl, 4,5-dihydropyrazol-1-yl, 4,5-dihydropyrazol-3-yl, 4,5-dihydro pyrazol-4-yl, 4,5-dihydropyrazol-5-yl, 2,3-dihydrooxazol-2-yl, 2,3-dihydrooxazol-3-yl, 2,3-dihydrooxazol-4-yl, 2,3-dihydrooxazol-5-yl, 3,4-dihydrooxazol-2-yl, 3,4-dihydrooxazol-3-yl, 3,4-dihydrooxazol-4-yl, 3,4-dihydrooxazol-5-yl, 3,4-dihydrooxazol-2-yl, 3,4-dihydrooxazol-3-yl, 3,4-dihydrooxazol-4-yl, 2-, 3-, 4-, 5- or 6-di- or tetrahydropyridinyl, 3-di- or tetrahydropyridazinyl, 4-di- or tetrahydropyridazinyl, 2-di- or tetrahydropyrimidinyl, 4-di- or tetrahydropyrimidinyl, 5-di- or tetrahydropyrimidinyl, di- or tetrahydropyrazinyl, 1,3,5-di- or tetrahydrotriazin-2-yl, 1,2,4-di- or tetrahydrotriazin-3-yl, 2 ,3,4,5-tetrahydro[1H]azepin-1-, -2-, -3-, -4-, -5-, -6- or -7-yl, 3,4,5,6-tetrahydro[2H]azepin-2-, -3-, -4-, -5-, -6- or -7-yl, 2,3,4,7-tetrahydro[1H]azepin-1-, -2-, -3-, -4-, -5-, -6- or -7-yl, 2,3,6,7-tetrahydro[1H]azepin-1-, -2-, -3-, -4-, -5-, -6- or -7-yl, tetrahydro[1H]azepin-1-, -2-, -3-, -4-, -5-, -6- or -7-yl, Hydroxepinyl, for example 2,3,4,5-tetrahydro[1H]oxepin-2-, -3-, -4-, -5-, -6- or -7-yl, 2,3,4,7-tetrahydro[1H]oxepin-2-, -3-, -4-, -5-, -6- or -7-yl, 2,3,6,7-tetrahydro[1H]oxepin-2-, -3-, -4-, -5-, -6- or -7-yl, tetrahydro-1,3-diazepinyl, tetrahydro-1,4-diazepinyl, tetrahydro-1,3-oxepinyl Oxazepinyl, tetrahydro-1,4-oxazepinyl, tetrahydro-1,3-dioxepinyl, tetrahydro-1,4-dioxepinyl, 1,2,3,4,5,6-hexahydroazocine, 2,3,4,5,6,7-hexahydroazocine, 1,2,3,4,5,8-hexahydroazocine, 1,2,3,4,7,8-hexahydroazocine, 1,2,3,4,5,6-hexahydro-[1,5]diazocine, 1,2,3,4,7,8-hexahydro-[1,5]diazocine, etc.

[0081] Maximum unsaturated (non-aromatic) monocyclic heterocycles of 3, 4, 5, 6, 7 or 8 members: pyran-2-yl, pyran-3-yl, pyran-4-yl, thiopyran-2-yl, thiopyran-3-yl, thiopyran-4-yl, 1-oxothiopyran-2-yl, 1-oxothiopyran-3-yl, 1-oxothiopyran-4-yl, 1,1-dioxothiopyran-2-yl, 1,1-dioxothiopyran-3-yl, 1,1-dioxothiopyran-4-yl, 2H-oxazin-2-yl, 2H-oxazin-3-yl, 2H-oxazine -4-yl, 2H-oxazin-5-yl, 2H-oxazin-6-yl, 4H-oxazin-3-yl, 4H-oxazin-4-yl, 4H-oxazin-5-yl, 4H-oxazin-6-yl, 6H-oxazin-3-yl, 6H-oxazin-4-yl, 7H-oxazin-5-yl, 8H-oxazin-6-yl, 2H-1,3-oxazin-2-yl, 2H-1,3-oxazin-4-yl, 2H-1,3-oxazin-5-yl, 2H-1,3-oxazin-6-yl, 4H-1,3-oxazin-2- yl, 4H-1,3-oxazin-4-yl, 4H-1,3-oxazin-5-yl, 4H-1,3-oxazin-6-yl, 6H-1,3-oxazin-2-yl, 6H-1,3-oxazin-4-yl, 6H-1,3-oxazin-5-yl, 6H-1,3-oxazin-6-yl, 2H-1,4-oxazin-2-yl, 2H-1,4-oxazin-3-yl, 2H-1,4-oxazin-5-yl, 2H-1,4-oxazin-6-yl, 4H-1,4-oxazin-2-yl, 4H-1,4-oxazin-3 -yl, 4H-1,4-oxazin-4-yl, 4H-1,4-oxazin-5-yl, 4H-1,4-oxazin-6-yl, 6H-1,4-oxazin-2-yl, 6H-1,4-oxazin-3-yl, 6H-1,4-oxazin-5-yl, 6H-1,4-oxazin-6-yl, 1,4-dioxin-2-yl, 1,4-oxathiin-2-yl, 1H-azepine, 1H-[1,3]-diazepine, 1H-[1,4]-diazepine, [1,3]diazocine, [1,5]diazocine, [1,5]diazocine and the like.

[0082] 5- or 6-membered monocyclic aromatic heterocycles: for example, 2-furyl, 3-furyl, 2-thienyl, 3-thienyl, 1-pyrrolyl, 2-pyrrolyl, 3-pyrrolyl, 1-pyrazolyl, 3-pyrazolyl, 4-pyrazolyl, 5-pyrazolyl, 1-imidazolyl, 2-imidazolyl, 4-imidazolyl, 5-imidazolyl, 2-oxazolyl, 4-oxazolyl, 5-oxazolyl, 3-isoxazolyl, 4-isoxazolyl, 5-isoxazolyl, 2-thiazolyl, 4-thiazolyl Zolyl, 5-thiazolyl, 3-isothiazolyl, 4-isothiazolyl, 5-isothiazolyl, 1,3,4-triazol-1-yl, 1,3,4-triazol-2-yl, 1,3,4-triazol-3-yl, 1,2,3-triazol-1-yl, 1,2,3-triazol-2-yl, 1,2,3-triazol-4-yl, 1,2,5-oxadiazol-3-yl, 1,2,3-oxadiazol-4-yl, 1,2,3-oxadiazol-5-yl, 1, 3,4-Oxadiazol-2-yl, 1,2,5-thiadiazol-3-yl, 1,2,3-thiadiazol-4-yl, 1,2,3-thiadiazol-5-yl, 1,4,3-thiadiazol-2-yl, 1,2,3,4-tetrazol-1-yl, 1,2,3,4-tetrazol-2-yl, 1,2,3,4-[1H]-tetrazol-5-yl, 1,2,3,4-[2H]-tetrazol-5-yl, 2-pyridinyl, 3-pyridinyl, 4-pyridinyl, 1-oxo 1-oxopyridin-2-yl, 1-oxopyridin-3-yl, 1-oxopyridin-4-yl, 3-pyridazinyl, 4-pyridazinyl, 2-pyrimidinyl, 4-pyrimidinyl, 5-pyrimidinyl, 2-pyrazinyl, 1,3,5-triazin-2-yl, 1,2,4-triazin-3-yl, 1,2,4-triazin-5-yl, 1,2,3,4-tetrazin-1-yl, 1,2,3,4-tetrazin-2-yl, 1,2,3,4-tetrazin-5-yl and the like.

[0083] The bicyclic ring has 4 to 8 members, preferably 5 to 8 members.

[0084] Examples of 5-8 membered bicyclic saturated spirocyclic carbocycles include spiro[2.2]pentyl, spiro[2.3]hexyl, spiro[2.4]heptyl, spiro[3.3]heptyl, spiro[4.4]nonyl, spiro[5.5]undecyl, and the like.

[0085] Examples of 5-8 membered bicyclic saturated fused carbocycles include bicyclo[3.1.0]hexyl, bicyclo[3.2.0]heptyl, bicyclo[3.3.0]octyl, 1,2,3,3a,4,5,6,6a-octahydropentalenyl, bicyclo[4.2.0]octyl, and the like.

[0086] Examples of 5-8 membered bicyclic saturated bridged carbocycles include bicyclo[1.1.1]pentyl, bicyclo[2.1.1]hexyl, bicyclo[2.2.1]heptyl, bicyclo[3.1.1]heptyl, bicyclo[2.2.2]octyl, bicyclo[3.2.1]octyl, and the like.

[0087] An example of a 5-8 membered polycyclic saturated carbocycle is cubyl.

[0088] An example of a 5-8 membered partially unsaturated bicyclic bridged carbocycle is bicyclo[2.2.2]oct-2-enyl.

[0089] Examples of 5- to 8-membered bicyclic saturated fused heterocycles are shown below. [ka]

[0090] Examples of 5-8 membered bicyclic saturated spirocyclic heterocycles are shown below. [ka]

[0091] Examples of 5- to 8-membered bicyclic saturated bridged heterocycles are shown below. [ka]

[0092] Examples of 5- to 8-membered partially unsaturated bicyclic bridged heterocycles are shown below. [ka]

[0093] In the structures shown above, # represents the point of attachment to the rest of the molecule. The point of attachment is not limited to the ring on which it is shown, but can be on either of the two rings, and on a carbon ring atom or a nitrogen ring atom. When a ring has one or more substituents, these can be attached to a carbon ring atom and / or a nitrogen ring atom.

[0094] Q is a bicyclic or tricyclic aromatic or partially aromatic fused ring system formed from s carbon atoms, t nitrogen atoms, n sulfur atoms, and n oxygen atoms. The ring can be carbocyclic, containing only carbon atoms as ring members, or heterocyclic, containing at least one N, O, and / or S atom as a ring member. The carbon or sulfur ring atoms of Q have p oxo groups. A carbon ring atom can, of course, have only zero or one oxo group, but a sulfur ring atom can have zero, one, or two oxo groups, thus forming the ring members -S-, -S(=O)-, or -S(=O)2-.

[0095] Aromatic fused ring systems are aromatic throughout. In partially aromatic fused ring systems, an aromatic ring is fused to a non-aromatic ring.

[0096] Examples of bicyclic or tricyclic carbocyclic aromatic ring systems are naphthyl, anthracenyl and phenanthrenyl.

[0097] Examples of bicyclic or tricyclic carbocyclic partly aromatic ring systems are indanyl, indenyl, tetralinyl, 1,2-dihydrotetralinyl, 1,4-dihydrotetralinyl, 9H-fluorenyl and 9,10-dihydroanthracenyl.

[0098] Examples of bicyclic or tricyclic heteroaromatic ring systems are indolyl, 2H-isoindolyl, benzofuranyl, benzothiophenyl, benzimidazolyl, 1H-indazolyl, 1,3-benzoxazolyl, 1,2-benzoxazolyl, 1,3-benzothiazolyl, 1,2-benzothiazolyl, quinolinyl, isoquinolinyl, quinoxalinyl, cinnolinyl, quinazolinyl, 1,8-naphthyridinyl, 1,5-naphthyridinyl, 1H-pyrrolo[3,2-b]pyridinyl, 1H-pyrrolo[3,2-C]pyridinyl, dibenzofuranyl, dibenzothiophenyl, 9H-carbazolyl, acridinyl, phenazinyl, and the like.

[0099] Examples of bicyclic or tricyclic heterocyclic partially aromatic ring systems are 2,3-dihydrobenzofuranyl, 1,3-dihydroisobenzofuranyl, 2,3-dihydrobenzothiophenyl, 1-oxo-2,3-dihydrobenzothiophenyl, 1,1-dioxo-2,3-dihydrobenzothiophenyl, 1,3-dihydro-2-benzothiophenyl, 2-oxo-1,3-dihydro-2-benzothiophenyl, 2,2-dioxo-1,3-dihydro-2-benzothiophenyl, indolinyl, isoindolinyl, 1,3-benzodioxolyl, 1,3-benzodithiolyl, 1-oxo-1,3-benzodithiolyl, 1,1-dioxo-1,3-benzodithiolyl, 1,3-dihydro-2-benzothiophenyl, Examples include oxo-1,3-benzodithiolyl, 1,1,3,3-tetraoxo-1,3-benzoxathiolyl, 2,3-dihydro-1H-benzimidazolyl, 2,3-dihydro-1H-indazolyl, 2,3-dihydro-1,3-benzoxazolyl, 2,3-dihydro-1,2-benzoxazolyl, 2,3-dihydro-1,3-benzothiazolyl, 2,3-dihydro-1,2-benzothiazolyl, chromanyl, isochromanyl, 4H-1,3-benzodioxinyl, 2,3-dihydro-1,4-benzodioxinyl, 4H-chromenyl, 2H-chromenyl, 1,2,3,4-tetrahydroquinolinyl, and 1,2,3,4-tetrahydroisoquinolinyl.

[0100] The following statements regarding preferred embodiments of the variables (substituents) of the compounds of formula I are valid on their own and preferably in combination with one another and with their stereoisomers, tautomers or salts. The following statements regarding preferred embodiments of the variables are valid on their own and preferably in combination with one another, where applicable, with respect to the compounds of formula I and the uses and methods according to the invention and the compositions according to the invention.

[0101] Preferably, R 1 is selected from the group consisting of hydrogen, (C1-C3)-alkyl, (C3-C4)-cycloalkyl, (C1-C3)-haloalkyl, (C2-C3)-alkenyl, (C2-C3)-alkynyl, (C1-C3)-alkoxy-(C1-C3)-alkyl. More preferably, R 1 is hydrogen, (C1-C3)-alkyl or (C1-C3)-alkoxy-(C1-C3)-alkyl, in particular hydrogen, methyl or methoxymethyl. In particular R 1 is hydrogen or (C1-C3)-alkyl. In particular, R 1 is hydrogen.

[0102] Preferably, R 4 is selected from the group consisting of hydrogen, (C1-C6)-alkyl and (C3-C6)-cycloalkyl. More preferably, R 4 is hydrogen or (C1-C3)-alkyl. In particular, R 4 is hydrogen.

[0103] Preferably, R 1 is hydrogen or (C1-C3)-alkyl; and R 4 is hydrogen or (C1-C3)-alkyl.

[0104] More preferably, R 1 and R 4 are both hydrogen.

[0105] Preferably, R 2is selected from the group consisting of (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C3-C6)-alkenyl, (C3-C6)-alkynyl and (C1-C3)-alkoxy-(C1-C3)-alkyl, each substituted by m groups selected from the group consisting of fluorine, chlorine, bromine, iodine, hydroxyl and cyano. More preferably, R 2 is (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C3-C6)-cycloalkyl, (C3-C6)-alkenyl or (C3-C6)-alkynyl. More preferably, R 2 is (C1-C6)-alkyl, for example (C1-C4)-alkyl. In particular, R 2 is methyl or ethyl, especially methyl.

[0106] Preferably, R 3 is selected from the group consisting of hydrogen, halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C3-C6)-cycloalkyl, (C1-C6)-alkoxy, (C3-C6)-cycloalkoxy, (C1-C6)-haloalkoxy, (C3-C6)-alkenyloxy and (C3-C6)-alkynyloxy. More preferably, R 3 is hydrogen, halogen, (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, (C3-C6)-cycloalkoxy, (C3-C6)-alkenyloxy or (C3-C6)-alkynyloxy. 3 is hydrogen or halogen; in particular hydrogen or fluorine, especially hydrogen.

[0107] Divalent group (X 1 )~(X 6 ), the intramolecular orientation is as depicted, with the left arrow representing the bond to the adjacent nitrogen atom and the right arrow representing the bond to Y.

[0108] X is bonded ("X 0 "), compound (I) can also be shown as follows: [ka]

[0109] X is the formula (X 1 ), compound (I) can also be represented as follows: [ka]

[0110] X is the formula (X 2 ), compound (I) can also be represented as follows: [ka]

[0111] X is the formula (X 3 ), compound (I) can also be represented as follows: [ka]

[0112] X is the formula (X 4 ), compound (I) can also be represented as follows: [ka]

[0113] X is the formula (X 5 ), compound (I) can also be represented as follows: [ka]

[0114] X is the formula (X 6 ), compound (I) can also be represented as follows: [ka]

[0115] Divalent group (X 1 )~(X 6 ) in R 5 ~R 10 are each independently and independently at each occurrence preferably hydrogen, fluorine, chlorine, bromine, iodine, hydroxyl, cyano, COR e ,CONR b R d (C1-C6)-alkyl, (C3-C5)-cycloalkyl, (C2-C6)-alkenyl, each independently substituted by m fluorine atoms; (C1-C6)-alkoxy, (C3-C6)-cycloalkoxy, (C2-C6)-alkenyloxy, (C2-C6)-alkynyloxy, (C1-C3)-alkylsulfinyl, (C1-C3)-alkylsulfonyl and (C1-C3)-alkylthio, wherein the aliphatic or cycloaliphatic moieties in the last seven groups are each independently substituted by m fluorine atoms.

[0116] More preferably, R 5 ~R 10 are each independently and independently at each occurrence hydrogen, fluorine, chlorine, bromine, iodine, hydroxyl, cyano, COR e ,CONR b R d (C1-C6)-alkyl, (C3-C5)-cycloalkyl, (C2-C6)-alkenyl, each independently substituted by m fluorine atoms; (C1-C6)-alkoxy, (C3-C6)-cycloalkoxy, (C2-C6)-alkenyloxy and (C2-C6)-alkynyloxy, wherein the aliphatic or cycloaliphatic moieties in the last four groups are each independently substituted by m fluorine atoms.

[0117] In particular, R 5 ~R 10 are each independently and independently at each occurrence hydrogen, fluorine, chlorine, CO2R e ,CONR b Rd , (C1-C6)-alkyl substituted by m fluorine atoms and (C1-C6)-alkoxy substituted by m fluorine atoms.

[0118] In particular, R 5 ~R 10 are each independently and independently at each occurrence hydrogen, halogen, (C1-C6)-alkyl, (C1-C3)-alkoxy and COR e More particularly, R 5 ~R 10 is independently at each occurrence and independently at each occurrence hydrogen or (C1-C6)-alkyl, in particular hydrogen or methyl.

[0119] A suitable divalent group (X 1 )~(X 6 Non-exhaustive examples of ) are CH, CHCH, CH(CH), CHCHCH, CH(CHCH), CH(CHCH), CH(CH)CH, C(CH), C(CH)CH, C(iPr)CH, CH(CHiPr)CH, CHCH=CH, C(CH)C≡C, CH(CF)CH, CH(CH)CHO, CHCHO, CH(cPr)CHO, CH(CHOCH), CH(CHCHSCH), CH(COOH), CH(COOCH), CH(COOH)CH, CH(COOCH)CH, CHC(OH)(CF), CH(CONHCH), CH(CONHCH)CH and CHCHCONHCH. cPr is cyclopropyl; iPr is isopropyl.

[0120] In a preferred embodiment, X is a bond or a divalent unit (X 1 In the latter case, preferably, R 5 and R 6 are each independently hydrogen or (C1-C6)-alkyl, more preferably hydrogen or methyl. Even more preferably, R 5 and R 6 One of R is hydrogen and the other is hydrogen or methyl. 5 and R6 One of the groups is hydrogen and the other is methyl, so X 1 is specifically CH(CH3).

[0121] Y is preferably hydrogen, cyano, hydroxyl, Z; (C1-C 12 )-alkyl, (C3-C8)-cycloalkyl, (C2-C 12 )-alkenyl and (C2-C 12 )-alkynyl, and the aliphatic or cycloaliphatic moieties in the last four groups are each independently selected from the group consisting of fluorine, chlorine, bromine, iodine, cyano, hydroxyl, Z, COR e and CONR b R h is substituted with m groups selected from the group consisting of:

[0122] More preferably, Y is hydrogen, cyano, hydroxyl, Z, (C1-C 12 aliphatic or cycloaliphatic moieties in the last two groups are each independently selected from the group consisting of fluorine, COR e and CONR b R h is substituted with m groups selected from the group consisting of:

[0123] In another more preferred embodiment, Y is (C1 to C 12 )-alkyl, (C3-C8)-cycloalkyl, (C2-C 12 )-alkenyl and (C2-C 12 )-alkynyl, and the aliphatic or cycloaliphatic moieties in the last four groups are each independently selected from fluorine, chlorine, bromine, iodine, cyano, hydroxyl, OR, d , Z, OZ, NHZ, S(O) n R a , SO2NR b R d , SO2NR b COR e , CO2R e ,CONR bR h , C.O.R. b ,CONR e SO2R a , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b SO2NR b R e , OCONR b R e , OCSNR b R e , POR f R f and C(R b )=NOR e More preferably, Y is substituted with m groups selected from the group consisting of (C1 to C 12 )-alkyl, (C3-C8)-cycloalkyl, (C2-C 12 )-alkenyl and (C2-C 12 )-alkynyl, and the aliphatic or cycloaliphatic moieties in the last four groups are each independently selected from the group consisting of fluorine and COR e is substituted with m groups selected from the group consisting of:

[0124] In particular, Y is Z, (C1~C 12 aliphatic or cycloaliphatic moieties in the last two groups are each independently selected from the group consisting of fluorine, (C1-C2)-alkoxy, COR e and CONR b R h More particularly, Y is substituted by Z and m groups COR e (C1 to C 12 In this context, m is preferably 1 or 2, in particular 1.

[0125] In one preferred embodiment, Y is Z.

[0126] Representative, non-exhaustive examples of (non-phenyl) 3-, 4-, 5-, 6-, 7-, or 8-membered saturated, partially unsaturated, fully unsaturated, or aromatic monocyclic, bicyclic, or polycyclic rings Z are the following structures (and of course also the exemplary rings defined above): [ka] [ka]

[0127] The ring may be further substituted as defined above. The arrow or # represents the bond / point of attachment to Y (or NR4 if Y is a bond).

[0128] Z is preferably formed from r carbon atoms and n oxygen atoms, each of which is represented by COR e ,CONR b R h , S(O) n R a , SO2NR b R d , SO2NR b COR e , C.O.R. b ,CONR e SO2R a , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b SO2NR b R e , OCONR b R e , OCSNR b R e , POR f Rf and C(R b )=NOR e , R a , R c , R e and R f and a carbon atom carrying n oxo groups, and wherein the carbon atom is formed from r carbon atoms and n oxygen atoms ... the carbon atom is formed e ,CONR b R h , R a , R c , R e and R f Preferred are 4-, 5- or 6-membered saturated, partially unsaturated or fully unsaturated monocyclic rings (excluding phenyl), including aromatic rings, substituted by m groups from the group consisting of: and the carbon atoms carrying n oxo groups.

[0129] In another preferred embodiment, Z is formed from r carbon atoms, n nitrogen atoms, n sulfur atoms and n oxygen atoms, and is COR e ,CONR b R h ,CONR e SO2R a , R a , R c , R e and R f and wherein the sulfur and carbon atoms have n oxo groups, and the ring is formed from r carbon atoms, n nitrogen atoms, n sulfur atoms, and n oxygen atoms, and is selected from the group consisting of 3-, 4-, 5-, or 6-membered saturated, partially unsaturated, fully unsaturated, or aromatic rings, excluding phenyl, substituted by m groups selected from the group consisting of e ,CONR b R h , R a , R c , R e and R fand the sulfur and carbon atoms bear n oxo groups.

[0130] More preferably, Z is COR e ,CONR b R h , S(O) n R a , SO2NR b R d , SO2NR b COR e , C.O.R. b ,CONR e S(O)R a ,CONR e SO2R a ,CONR b1 SO2NR b2 R b3 , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b1 SO2NR b2 R e , OCONR b R e , OCSNR b R e , POR f R f , C(R b )=NOR e , R a , R c , R e and R fand the carbon ring atoms bear n oxo groups. In this context, m is preferably 0, 1, 2 or 3, more preferably 1 or 2, especially 1, and in this context, n is preferably 0 or 1, especially 0. More preferably, the 3-, 4-, 5- or 6-membered saturated, partially unsaturated or fully unsaturated monocyclic carbocyclic ring Z is COR e ,CONR b R h , S(O) n R a , SO2NR b R d , SO2NR b COR e , C.O.R. b ,CONR e S(O)R a ,CONR e SO2R a ,CONR b1 SO2NR b2 R b3 , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b1 SO2NR b2 R e , OCONR b R e , OCSNR b R e , POR f R f and C(R b )=NOR e m groups selected from the group consisting of and m groups R a , R c , R e and R fm1 has one of the meanings given for m, preferably 0, 1, 2 or 3, more preferably 1 or 2, in particular 1; and m2 has one of the meanings given for m, preferably 0, 1 or 2, in particular 0. Further preferably, the 3-, 4-, 5- or 6-membered saturated, partially unsaturated or fully unsaturated monocyclic carbocyclic ring Z is substituted by COR e ,CONR b R h , S(O) n R a , SO2NR b R d , SO2NR b COR e , C.O.R. b ,CONR e S(O)R a ,CONR e SO2R a ,CONR b1 SO2NR b2 R b3 , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b1 SO2NR b2 R e , OCONR b R e , OCSNR b R e , POR f R f and C(R b )=NOR e wherein m1 has one of the meanings given for m and is preferably 0, 1, 2 or 3, more preferably 1 or 2, especially 1.

[0131] More preferably, Z is COR e ,CONR b R h ,CONR eSO2R a , R a , R c , R e and R f and m groups selected from the group consisting of: e ,CONR b R h and CONR e SO2R a m groups selected from the group consisting of and R a , R c , R e and R f wherein m1 has one of the meanings given for m and is preferably 0, 1, 2 or 3, more preferably 1 or 2, in particular 1; and m2 has one of the meanings given for m and is preferably 0, 1 or 2, in particular 0. Further preferably, the 5- or 6-membered saturated or partially unsaturated carbocyclic ring Z is substituted by m groups selected from the group consisting of COR e ,CONR b R h and CONR e SO2R a and m1 has one of the meanings given for m and is preferably 0, 1, 2 or 3, more preferably 1 or 2, in particular 1 (and the group R a , R c , R e and R f (not replaced by ).

[0132] Examples of 5- or 6-membered saturated or partially unsaturated carbocyclic rings are cyclopentyl, cyclopent-1-en-1-yl, cyclopent-2-en-1-yl, cyclopent-3-en-1-yl, cyclopenta-1,3-dien-1-yl, cyclopenta-1,4-dien-1-yl, cyclopenta-2,4-dien-1-yl, cyclohexyl, cyclohex-1-en-1-yl, cyclohex-2-en-1-yl, cyclohex-3-en-1-yl, cyclohexa-1,3-dien-1-yl, cyclohexa-1,4-dien-1-yl, cyclohexa-1,5-dien-1-yl, cyclohexa-2,4-dien-1-yl and cyclohexa-2,5-dien-1-yl. Of these, cyclopentyl, cyclopent-1-en-1-yl, cyclopent-2-en-1-yl, cyclopent-3-en-1-yl and cyclohexyl are preferred, with cyclopent-2-en-1-yl being a specific example.

[0133] Non-exhaustive examples of such rings include the following structures: [ka] [ka]

[0134] In the above structure, # represents the point of attachment to the rest of the molecule, and R x is CO2R e ,CONR b R h ,CONR e SO2R a , R a , R c , R e or R f The ring may further have one or two substituents at any position selected from F, CN, methyl, CF3 or methoxy. More preferably, R x is CO2R e ,CONR b R h or CONR e SO2R a represents CO2Re In this context, R e is preferably hydrogen or (C1-C6)-alkyl, more preferably (C1-C4)-alkyl.

[0135] Thus, even more preferably, Z is a group selected from m groups COR e is a 5- or 6-membered saturated or partially unsaturated carbocyclic ring substituted by R e is hydrogen or (C1-C6)-alkyl, preferably (C1-C4)-alkyl. In this context, m is preferably 1 or 2, more preferably 1. Examples of such rings are R x CO2R e represents R e is the above structure in which is hydrogen or (C1-C6)-alkyl, preferably (C1-C4)-alkyl.

[0136] In particular, Z is a group consisting of m groups COR e is a 5- or 6-membered partially unsaturated carbocyclic ring substituted by R e is hydrogen or (C1-C6)-alkyl, preferably (C1-C4)-alkyl. In this context, m is preferably 1 or 2, more preferably 1.

[0137] More particularly, Z is a group COR e is a 5-membered partially unsaturated carbocyclic ring substituted by R e is hydrogen or (C1-C6)-alkyl, preferably (C1-C4)-alkyl. Examples of such rings are: [ka] (In the formula, R x is CO2R e represents R e is hydrogen or (C1-C6)-alkyl) is.

[0138] In particular, Z is [ka] (In the formula, R x is CO2R e represents R e is hydrogen or (C1-C6)-alkyl, in particular (C1-C4)-alkyl) is.

[0139] In another preferred embodiment, Z is COR e ,CONR b R h , S(O) n R a , SO2NR b R d , SO2NR b COR e , C.O.R. b ,CONR e S(O)R a ,CONR e SO2R a ,CONR b1 SO2NR b2 R b3 , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b1 SO2NR b2 R e , OCONR b R e , OCSNR b R e , POR f R f and C(R b )=NOR eand the carbon ring atoms bear n oxo groups. In this context, m is preferably 1 or 2, more preferably 1. In this context, n is preferably 0 or 1, in particular 0. More preferably, Z contains one oxygen atom as a ring member and m groups COR e In this context, R is a saturated or partially unsaturated 5- or 6-membered heterocycle substituted by e is preferably hydrogen, (C1-C6)-alkyl or (C3-C6)-cycloalkyl; in particular hydrogen or (C1-C6)-alkyl, in this connection m is preferably 1 or 2, more preferably 1. Thus, more particularly, Z contains one oxygen atom as a ring member and m groups COR e a saturated or partially unsaturated 5- or 6-membered heterocycle substituted by R e is hydrogen, (C1-C6)-alkyl or (C3-C6)-cycloalkyl; in particular hydrogen or (C1-C6)-alkyl, and m is 1 or 2, preferably 1. More particularly, Z contains one oxygen atom as a ring member and m groups COR e is a saturated or partially unsaturated 5-membered heterocycle substituted by R e is hydrogen or (C1-C6)-alkyl, in which context m is preferably 1 or 2, more preferably 1. In particular, Z contains one oxygen atom as a ring member and one group CO2R e and Re is hydrogen or (C1-C6)-alkyl.

[0140] Examples of 3-, 4-, 5- or 6-membered saturated, partially unsaturated or fully unsaturated heterocyclic rings containing one or two oxygen atoms as ring members are oxiran-2-yl, oxetan-2-yl, oxetan-3-yl, tetrahydrofuran-2-yl, tetrahydrofuran-3-yl, 1,3-dioxolan-2-yl, 1,3-dioxolan-4-yl, tetrahydropyran-2-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1,3-dioxan-2-yl, 1,3-dioxan-4-yl, 1,3-dioxan-5-yl, 1,4-dioxan-2-yl, 2,3-dihydrofuran-2-yl. , 2,3-dihydrofuran-3-yl, 2,5-dihydrofuran-2-yl, 2,5-dihydrofuran-3-yl, 3,6-dihydro-2H-pyran-2-yl, 3,6-dihydro-2H-pyran-3-yl, 3,6-dihydro-2H-pyran-4-yl, 3,6-dihydro-2H-pyran-5-yl, 3,6-dihydro-2H-pyran-6-yl, 3,4-dihydro-2H-pyran-2-yl, 3,4-dihydro-2H-pyran-3-yl, 3,4-dihydro-2H-pyran-4-yl, 3,4-dihydro-2H-pyran-5-yl or 3,4-dihydro-2H-pyran-6-yl.

[0141] Examples of saturated or partially unsaturated 5- or 6-membered heterocyclic rings containing one oxygen atom as a ring member are tetrahydrofuran-2-yl, tetrahydrofuran-3-yl, tetrahydropyran-2-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 2,3-dihydrofuran-2-yl, 2,3-dihydrofuran-3-yl, 2,5-dihydrofuran-2-yl, 2,5-dihydrofuran-3-yl, 3,6-dihydro-2H-pyran-2-yl, 2,3-dihydrofuran-3-yl, 2,5-dihydrofuran-2-yl, 2,5-dihydrofuran-3-yl, 3,6-dihydro-2H-pyran-2-yl, 2,3-dihydro-3-pyran-2-yl, 2,5-dihydro-3-pyran-2 ...3-dihydro-3-pyran-2-yl, 2 -yl, 3,6-dihydro-2H-pyran-3-yl, 3,6-dihydro-2H-pyran-4-yl, 3,6-dihydro-2H-pyran-5-yl, 3,6-dihydro-2H-pyran-6-yl, 3,4-dihydro-2H-pyran-2-yl, 3,4-dihydro-2H-pyran-3-yl, 3,4-dihydro-2H-pyran-4-yl, 3,4-dihydro-2H-pyran-5-yl or 3,4-dihydro-2H-pyran-6-yl.

[0142] Examples of saturated or partially unsaturated 5-membered heterocycles containing one oxygen atom as a ring member are tetrahydrofuran-2-yl, tetrahydrofuran-3-yl, 2,3-dihydrofuran-2-yl, 2,3-dihydrofuran-3-yl, 2,5-dihydrofuran-2-yl or 2,5-dihydrofuran-3-yl.

[0143] Non-exhaustive examples of saturated or partially unsaturated five-membered heterocycles containing one oxygen atom as a ring member are the following structures: [ka]

[0144] In the above structure, the wavy line represents the point of attachment to the rest of the molecule, and the arrow represents the substituent CO2R e ,CONR b R h ,CONR e SO2R a , R a , R c , R e or R f The substituent preferably represents a point of attachment to COR. e ,CONR b R h or CONR e SO2R a and CO2R in particular e In this regard, R e is preferably hydrogen or (C1-C6)-alkyl.

[0145] Of the above rings, the following structures are preferred. [ka] Here again, the wavy line represents the point of attachment to the rest of the molecule, and the arrow represents the substituent COR e ,CONR b R h ,CONR e SO2R a , R a , R c , R e or R fThe substituent preferably represents a point of attachment to COR. e ,CONR b R h or CONR e SO2R a and CO2R in particular e In this regard, R e is preferably hydrogen or (C1-C6)-alkyl.

[0146] Preferably, however, ring Z is a carbocyclic ring.

[0147] In another preferred embodiment, Y is S(O) n R a , SO2NR b R d , SO2NR b COR e , CO2R e ,CONR b R h , C.O.R. b ,CONR e SO2R a , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b SO2NR b R e , OCONR b R e , OCSNR b R e , POR f R f and C(R b )=NOR e More preferably, Y is (C1-C8)-alkyl substituted by m groups selected from the group consisting of: e is (C1-C4)-alkyl substituted by R eis hydrogen or (C1-C6)-alkyl and m is 1 or 2. More preferably, Y is a group CO2R e is (C1-C4)-alkyl substituted by R e is hydrogen or (C1-C6)-alkyl, and R e is preferably (C1-C4)-alkyl.

[0148] In a preferred embodiment, X is a bond and Y is Z, where Z has one of the general or preferred meanings given above.

[0149] In another preferred embodiment, X is a divalent unit (X 1 ) and R 5 and R 6 is as defined above and is in particular independently hydrogen or (C1-C6)-alkyl; and Y is S(O) n R a , SO2NR b R d , SO2NR b COR e , CO2R e ,CONR b R h , C.O.R. b ,CONR e SO2R a , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b SO2NR b R e , OCONR b R e , OCSNR b R e , POR f R f and C(R b )=NOR eand m groups selected from the group consisting of (C1-C8)-alkyl substituted with m groups.

[0150] In another preferred embodiment, X is a bond; and Y is S(O) n R a , SO2NR b R d , SO2NR b COR e , CO2R e ,CONR b R h , C.O.R. b ,CONR e SO2R a , N.R. b R e , N.R. b COR e , N.R. b CONR e R e , N.R. b CO2R e , N.R. b SO2R e , N.R. b SO2NR b R e , OCONR b R e , OCSNR b R e , POR f R f and C(R b )=NOR e and m groups selected from the group consisting of (C1-C8)-alkyl.

[0151] More preferably, X is a divalent unit (X 1 ) and R 5 and R 6 is independently hydrogen or methyl; and Y is CO2R e ,CONR b R h and CONR e SO2R aand m groups selected from the group consisting of (C1-C4)-alkyl substituted with m groups.

[0152] In this context, Y preferably represents m groups COR e is (C1-C4)-alkyl substituted by R e is hydrogen or (C1-C6)-alkyl, and R e is preferably (C1-C4)-alkyl.

[0153] In this context, m is preferably 1.

[0154] In another more preferred embodiment, X is a bond; and Y is CO2R e ,CONR b R h and CONR e SO2R a and m groups selected from the group consisting of:

[0155] In this context, Y preferably represents m groups COR e is (C1-C6)-alkyl substituted by R e is hydrogen or (C1-C6)-alkyl, and R e is preferably (C1-C4)-alkyl.

[0156] In this context, m is preferably 1.

[0157] In this latter alternative more preferred embodiment, (C1-C6)-alkyl in Y is preferably COR e ,CONR b R h and CONR e SO2R a a group -C(R 51 )(R 61 )-C1-C4-alkyl, and R 51and R 61 is independently hydrogen or methyl.

[0158] In this context, Y is more preferably a group selected from m groups COR e A group -C(R 51 )(R 61 )-C1-C4-alkyl, and R e is hydrogen or (C1-C6)-alkyl, and R e is preferably (C1-C4)-alkyl; and R 51 and R 61 is independently hydrogen or methyl.

[0159] In this context, m is preferably 1.

[0160] Even more preferably, X is a divalent unit (X 1 ) and R 5 and R 6 one of is hydrogen and the other is hydrogen or methyl, preferably methyl; and Y is m (preferably 1) groups COR e is (C1-C4)-alkyl substituted by R e is hydrogen or (C1-C6)-alkyl, and R e is preferably (C1-C4)-alkyl.

[0161] In Q, the sum of t nitrogen atoms, n sulfur atoms and n oxygen ring members is preferably 0, 1, 2 or 3.

[0162] Q is preferably 8-14-membered; more preferably 9-14-membered; that is, the sum of s, t, and n is preferably 8-14, more preferably 9-14.

[0163] Q is preferably a bicyclic or tricyclic aromatic or partially aromatic fused ring system, at least one of the fused rings being a phenyl ring. Examples of such rings include naphthyl, anthracenyl, phenanthrenyl, indanyl, indenyl, tetralinyl, 1,2-dihydrotetralinyl, 1,4-dihydrotetralinyl, 9H-fluorenyl, 9,10-dihydroanthracenyl, indolyl, 2H-isoindolyl, benzofuranyl, benzothiophenyl, benzimidazolyl, 1H-indazolyl, 1,3-benzoxazolyl, 1,2-benzoxazolyl, 1,3-benzothiazolyl, and 1,2-benzothiazolyl. , quinolinyl, isoquinolinyl, quinoxalinyl, cinnolinyl, quinazolinyl, dibenzofurayl, dibenzothiophenyl, 9H-carbazolyl, acridinyl, phenazinyl, 2,3-dihydrobenzofuranyl, 1,3-dihydroisobenzofuranyl, 2,3-dihydrobenzothiophenyl, 1-oxo-2,3-dihydrobenzothiophenyl, 1,1-dioxo-2,3-dihydrobenzothiophenyl, 1,3-dihydro-2-benzothiophenyl, 2-oxo-1,3- Dihydro-2-benzothiophenyl, 2,2-dioxo-1,3-dihydro-2-benzothiophenyl, indolinyl, isoindolinyl, 1,3-benzodioxolyl, 1,3-benzodithiolyl, 1-oxo-1,3-benzodithiolyl, 1,1-dioxo-1,3-benzodithiolyl, 1,3-dioxo-1,3-benzodithiolyl, 1,1,3,3-tetraoxo-1,3-benzoxathiolyl, 2,3-dihydro-1H-benzimidazolyl, 2,3-dihydro-1 H-indazolyl, 2,3-dihydro-1,3-benzoxazolyl, 2,3-dihydro-1,2-benzoxazolyl, 2,3-dihydro-1,3-benzothiazolyl, 2,3-dihydro-1,2-benzothiazolyl, chromanyl, isochromanyl, 4H-1,3-benzodioxinyl, 2,3-dihydro-1,4-benzodioxinyl, 4H-chromenyl, 2H-chromenyl, 1,2,3,4-tetrahydroquinolinyl and 1,2,3,4-tetrahydroisoquinolinyl.

[0164] Preferably, the ring Q contains k substituents R Q1 and n substituents RQ2 It has.

[0165] R Q1 is preferably selected from the group consisting of halogen, cyano, (C1-C3)-alkyl, (C1-C3)-haloalkyl, (C1-C3)-alkoxy and (C1-C3)-haloalkoxy, more preferably halogen or (C1-C3)-alkyl.

[0166] R Q2 is preferably phenyl-(C1-C3)-alkyl, (C1-C4)-alkylcarbonyl, (C1-C4)-alkylaminocarbonyl, di-(C1-C4-alkyl)aminocarbonyl, (C1-C4)-alkoxycarbonyl, benzyloxycarbonyl, fluorenyloxycarbonyl, allyloxycarbonyl or (C1-C3)-alkoxy-(C1-C3)-alkyl, more preferably benzyl, acetyl, methylaminocarbonyl, dimethylaminocarbonyl, tert-butoxycarbonyl or methoxymethyl.

[0167] k is preferably 0, 1, 2 or 3, and more preferably 0, 1 or 2.

[0168] n is preferably 0 or 1.

[0169] More preferably, Q is selected from rings of formulae Q1 to Q16. [ka] During the ceremony, In Q1, A is CH2, NR q , O, S, S(O) or S(O)2; and B is CH2, NR q , O, S, S(O) or S(O)2; In Q2, A is NR q , O, S, S(O) or S(O)2; In Q3, A is CH2, C(=O), NR q, O, S, S(O) or S(O)2; and B is CH2, C(=O), NR q , O, S, S(O) or S(O)2; In Q4, A is CH2, NR q , O, S, S(O) or S(O)2; and B is CH2, NR q , O, S, S(O) or S(O)2; In Q5, A is CH or N; and B is CH2, NR q , O, S, S(O) or S(O)2; In Q6, A is CH or N; and B is CH2, NR q , O, S, S(O) or S(O)2; In Q7, B is CH2, NR q , O, S, S(O) or S(O)2; In Q8, B is CH2, NR q , O, S, S(O) or S(O)2; In Q10, the dashed line indicates a single or double bond; A is NR q or O; B is O; and D: When the dashed line indicates a single bond, CH2, NR q or O; if the dashed line represents a double bond, it is CH or N; In Q11, the dashed line represents a single or double bond; A is NR q or O; and B is O; In Q12, A is CH or N; and B is CH or N; In Q15, A is CH2, C(=O), NR q , O, S, S(O) or S(O)2; and B is CH2, C(=O), NR q , O, S, S(O) or S(O)2; and In Q16, A is CH2, C(=O), NR q , O, S, S(O) or S(O)2; and R q is hydrogen, (C1-C3)-alkyl, (C1-C3)-haloalkyl, (C1-C3)-alkoxy, (C1-C3)-haloalkoxy, phenyl-(C1-C3)-alkyl, (C1-C4)-alkylcarbonyl or (C1-C4)-alkoxycarbonyl; and # is NR 1 It is the connection point to

[0170] Q1 to Q16 are k substituents R Q1 R Q1 is preferably selected from the group consisting of halogen, cyano, (C1-C3)-alkyl, (C1-C3)-haloalkyl, (C1-C3)-alkoxy and (C1-C3)-haloalkoxy, more preferably selected from halogen and (C1-C3)-alkyl; k is preferably 0, 1, 2 or 3, more preferably 0, 1 or 2.

[0171] More preferably, Q is a bicyclic fused ring system of formula Q1 to Q13, in particular of formula Q1, Q2, Q5 or Q12.

[0172] In Q1, A and B are preferably O; In Q2, A is preferably S, S(O) or S(O)2; more preferably S(O)2; In Q5, A is preferably CH or N, and B is preferably NR q , O or S; In Q12, A and B are preferably CH.

[0173] Preferably, the rings Q1, Q2, Q5 and Q12 each contain k substituents R Q1 R Q1 is selected from the group consisting of halogen and (C1-C3)-alkyl; more preferably halogen; and k is 0, 1 or 2. qis preferably hydrogen or (C1-C3)-alkyl; more preferably (C1-C3)-alkyl.

[0174] In a preferred embodiment, Q is a bicyclic fused ring system of formula Q1 to Q13; rings Q1 to Q13 are each a bicyclic fused ring system of formula Q1 to Q13, each ring containing k substituents R Q1 R Q1 is selected from the group consisting of halogen, cyano, (C1-C3)-alkyl, (C1-C3)-haloalkyl, (C1-C3)-alkoxy and (C1-C3)-haloalkoxy; k is 0, 1, 2 or 3; R 1 is hydrogen; R 2 is (C1-C6)-alkyl; R 3 is hydrogen or halogen; R 4 is hydrogen; X is a bond; and Y is Z; Z is a group COR e is a 5- or 6-membered saturated or partially unsaturated carbocyclic ring substituted by R e is hydrogen or (C1-C6)-alkyl and m is 1 or 2; or X is a divalent unit (X 1 ) and R 5 and R 6 are, independently of one another, hydrogen or (C1-C6)-alkyl; and Y is m radicals COR e is (C1-C4)-alkyl substituted by R e is (C1-C6)-alkyl and m is 1 or 2.

[0175] In a more preferred embodiment, Q is a bicyclic fused ring system of formula Q1 to Q13; rings Q1 to Q13 are each a bicyclic fused ring system of formula Q1 to Q13, each ring containing k substituents R Q1 R Q1 is selected from the group consisting of halogen, cyano, (C1-C3)-alkyl, (C1-C3)-haloalkyl, (C1-C3)-alkoxy and (C1-C3)-haloalkoxy; R qis hydrogen or (C1-C3)-alkyl; k is 0, 1, 2 or 3; R 1 is hydrogen; R 2 is (C1-C6)-alkyl; R 3 is hydrogen or halogen; R 4 is hydrogen; X is a bond; and Y is Z; Z is a group COR e is a 5- or 6-membered saturated or partially unsaturated carbocyclic ring substituted by R e is hydrogen or (C1-C6)-alkyl and m is 1 or 2; or X is a divalent unit (X 1 ) and R 5 and R 6 are, independently of one another, hydrogen or (C1-C6)-alkyl; and Y is m radicals COR e is (C1-C4)-alkyl substituted by R e is (C1-C6)-alkyl and m is 1 or 2.

[0176] Even more preferably, Q is a bicyclic fused ring system of formula Q1, Q2, Q5 or Q12; in Q1, A and B are O; in Q2, A is S, S(O) or S(O)2, preferably S(O)2; in Q5, A is CH or N and B is NR q , O or S; and in Q12, A and B are CH; rings Q1, Q2, Q5 and Q12 have k substituents RQ1; R Q1 is selected from the group consisting of halogen and (C1-C3)-alkyl; R q is hydrogen or (C1-C3)-alkyl; k is 0, 1 or 2; R 1 is hydrogen; R 2 is methyl or ethyl; R 3 is hydrogen; R 4is hydrogen; X is a bond; and Y is Z; Z is a group COR e is a 5-membered partially unsaturated carbocyclic ring substituted by R e is (C1-C6)-alkyl; or X is a divalent unit (X 1 ) and R 5 and R 6 are, independently of one another, hydrogen or methyl; and Y is a group COR e is (C1-C4)-alkyl substituted by R e is (C1-C6)-alkyl.

[0177] In particular, Q is a bicyclic fused ring system of formula Q1, Q2, Q5 or Q12; in Q1, A and B are O; in Q2, A is S, S(O) or S(O)2; in Q5, A is CH or N and B is NR q , O or S; rings Q1, Q2, Q5 and Q12 are each independently selected from k substituents R Q1 R Q1 is selected from the group consisting of halogen and (C1-C3)-alkyl; k is 0, 1 or 2; R 1 is hydrogen; R 2 is methyl or ethyl; R 3 is hydrogen; R 4 is hydrogen; X is a bond; and Y is Z; Z is a group COR e is a 5-membered partially unsaturated carbocyclic ring substituted by R e is (C1-C6)-alkyl.

[0178] Particularly preferably, Q is a bicyclic fused ring system of formula Q1, Q2, Q5 or Q12; in Q1, A and B are O; in Q2, A is S(O)2; in Q5, A is CH or N and B is NR q, O or S; rings Q1, Q2, Q5 and Q12 are each independently selected from k substituents R Q1 R Q1 is a halogen; R q is (C1-C3)-alkyl; k is 0, 1 or 2; R 1 is hydrogen; R 2 is methyl; R 3 is hydrogen; R 4 is hydrogen; X is a bond; and Y is Z; Z is a group COR e is a 5-membered partially unsaturated carbocyclic ring substituted by R e is (C1-C4)-alkyl; or X is a divalent unit (X 1 ) and R 5 and R 6 one of which is hydrogen and the other is hydrogen or methyl, preferably methyl; and Y is one group COR e is (C1-C4)-alkyl substituted by R e is (C1-C4)-alkyl.

[0179] In the above specific and particular embodiments, the 5-membered partially unsaturated carbocyclic ring Z is preferably ring Z10 (shown below), with # indicating the point of attachment to the rest of the molecule.

[0180] R 1 and R 4 is hydrogen and R 2 , R 3 Particularly preferred are compounds (I) in which the combinations of X and Y have the meanings defined in each row of Table A below.

[0181] [Table 1]

[0182] [Table 2]

[0183]

Table 3

[0184]

Table 4

[0185]

Table 5

[0186]

Table 6

[0187]

Table 7

[0188]

Table 8

[0189]

Table 9

[0190]

Table 10

[0191]

Table 11

[0192]

Table 12

[0193]

Table 13

[0194]

Table 14

[0195]

Table 15

[0196] Table 16

[0197] Table 17

[0198]

Table 18

[0199] Table 19

[0200] Table 20

[0201] Table 21

[0202] Table 22

[0203] Table 23

[0204] Table 24

[0205] Table 25

[0206] Table 26

[0207] Table 27

[0208] Table 28

[0209] Table 29

[0210]

Table 30

[0211] Table 31

[0212] Table 32

[0213] Table 33

[0214] Table 34

[0215] Table 35

[0216] Table 36

[0217] Table 37

[0218] Table 38

[0219] Table 39

[0220] Table 40

[0221] Table 41

[0222] Table 42

[0223] Table 43

[0224] Table 44

[0225] Table 45

[0226] Table 46

[0227] Table 47

[0228] Table 48

[0229] Table 49

[0230]

Table 50

[0231] Table 51

[0232] Table 52

[0233] Table 53

[0234] Table 54

[0235] Table 55

[0236] Table 56

[0237] Table 57

[0238] Table 58

[0239] Table 59

[0240] Table 60

[0241] Table 61

[0242] Table 62

[0243] Table 63

[0244] Table 64

[0245] Table 65

[0246] Table 66

[0247] Table 67

[0248] Table 68

[0249] Table 69

[0250] Table 70

[0251] Table 71

[0252] Table 72

[0253] Table 73

[0254] Table 74

[0255] Table 75

[0256] [Table 76]

[0257] [Table 77]

[0258] [Table 78]

[0259] [Table 79]

[0260] [Table 80]

[0261] [ka]

[0262] In Z1 to Z39, # is NR 4 indicates the attachment point to

[0263] Of the rings Z1 to Z39, ring Z10 is particularly preferred.

[0264] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.1, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0265] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.1, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0266] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.1, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0267] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.1, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0268] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.1, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0269] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.1, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0270] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.1, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0271] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.1, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0272] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.1, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0273] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.1, and R q13 is CH3 and Rq11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0274] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.2, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0275] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.2, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0276] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.2, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0277] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.2, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0278] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.2, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0279] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.2, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0280] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.2, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0281] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.2, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0282] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.2, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0283] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.2, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0284] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 0, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0285] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 0, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0286] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 0, and Rq11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0287] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 0, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0288] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 0, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0289] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 0, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0290] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 0, and R q12 is CH3 and R q11 and Rq13 Further compounds (I) in which is H are particularly preferred.

[0291] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 0, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0292] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 0, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0293] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 0, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0294] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 1, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0295] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 1, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0296] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 1, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0297] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 1, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0298] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 1, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0299] For a single compound, R 1and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 1, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0300] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 1, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0301] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 1, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0302] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 1, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0303] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 1, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0304] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 2, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0305] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 2, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0306] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 2, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0307] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 2, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0308] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 2, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0309] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 2, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0310] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 2, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0311] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 2, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0312] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 2, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0313] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.3, n is 2, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0314] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 0, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0315] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 0, and Rq11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0316] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 0, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0317] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 0, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0318] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 0, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0319] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 0, and R q12 is Cl and R q11 and Rq13 Further compounds (I) in which is H are particularly preferred.

[0320] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 0, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0321] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 0, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0322] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 0, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0323] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 0, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0324] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 1, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0325] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 1, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0326] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 1, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0327] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 1, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0328] For a single compound, R1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 1, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0329] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 1, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0330] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 1, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0331] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 1, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0332] For a single compound, R 1 and R 4 is hydrogen and R 2, R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 1, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0333] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 1, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0334] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 2, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0335] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 2, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0336] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 2, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0337] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 2, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0338] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 2, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0339] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 2, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0340] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 2, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0341] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 2, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0342] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 2, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0343] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.4, n is 2, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0344] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and Rq is H and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0345] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is H and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0346] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is H and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0347] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is H and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0348] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and Rq is H and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0349] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is H and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0350] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is H and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0351] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is H and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0352] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is H and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0353] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is H and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0354] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is CH3 and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0355] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is CH3 and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0356] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is CH3 and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0357] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is CH3 and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0358] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is CH3 and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0359] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is CH3 and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0360] For a single compound, R 1 and R 4 is hydrogen and R2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is CH3H and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0361] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is CH3 and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0362] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is CH3 and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0363] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.5, and R q is CH3 and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0364] For a single compound, R 1 and R4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is H and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0365] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is H and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0366] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is H and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0367] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is H and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0368] For a single compound, R 1 and R4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is H and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0369] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is H and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0370] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is H and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0371] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is H and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0372] For a single compound, R 1and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is H and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0373] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is H and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0374] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is CH3 and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0375] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is CH3 and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0376] For a single compound, R1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is CH3 and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0377] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is CH3 and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0378] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is CH3 and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0379] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is CH3 and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0380] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is CH3H and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0381] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is CH3 and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0382] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is CH3 and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0383] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.6, and R q is CH3 and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0384] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is H and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0385] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is H and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0386] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is H and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0387] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is H and R q11 is CH3 and Rq12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0388] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is H and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0389] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is H and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0390] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is H and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0391] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is H and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0392] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is H and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0393] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is H and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0394] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is F and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0395] For a single compound, R1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is F and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0396] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is F and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0397] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is F and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0398] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is F and R q12 is F and R q11 and R q13Further compounds (I) in which is H are particularly preferred.

[0399] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is F and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0400] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is F and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0401] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is F and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0402] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and Rq15 is F and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0403] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is F and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0404] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is CH3 and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0405] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is CH3 and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0406] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is CH3 and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0407] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is CH3 and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0408] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is CH3 and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0409] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is CH3 and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0410] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is CH3 and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0411] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is CH3 and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0412] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is CH3 and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0413] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.7, and R q14 and R q15 is CH3 and R q13is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0414] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is H and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0415] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is H and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0416] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is H and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0417] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is H and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0418] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is H and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0419] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is H and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0420] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is H and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0421] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is H and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0422] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is H and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0423] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is H and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0424] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is F and R q11 , R q12 and R q13Further compounds (I) in which is H are particularly preferred.

[0425] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is F and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0426] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is F and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0427] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is F and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0428] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and Rq15 is F and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0429] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is F and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0430] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is F and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0431] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is F and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0432] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is F and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0433] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is F and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0434] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is CH3 and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0435] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is CH3 and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0436] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is CH3 and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0437] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is CH3 and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0438] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is CH3 and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0439] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is CH3 and R q12 is Cl and R q11and R q13 Further compounds (I) in which is H are particularly preferred.

[0440] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is CH3 and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0441] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is CH3 and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0442] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is CH3 and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0443] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.8, and R q14 and R q15 is CH3 and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0444] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.9, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0445] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.9, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0446] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.9, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0447] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.9, and Rq11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0448] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.9, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0449] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.9, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0450] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.9, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0451] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.9, and R q13 is F and R q11 and R q12Further compounds (I) in which is H are particularly preferred.

[0452] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.9, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0453] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.9, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0454] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.10, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0455] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.10, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0456] For a single compound, R1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.10, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0457] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.10, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0458] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.10, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0459] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.10, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0460] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.10, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0461] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.10, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0462] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.10, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0463] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.10, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0464] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.11, and R q11 , R q12and R q13 Further compounds (I) in which is H are particularly preferred.

[0465] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.11, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0466] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.11, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0467] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.11, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0468] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.11, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0469] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.11, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0470] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.11, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0471] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.11, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0472] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.11, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0473] For a single compound, R 1 and R 4 is hydrogen and R2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.11, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0474] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.12, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0475] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.12, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0476] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.12, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0477] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.12, and Rq11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0478] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.12, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0479] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.12, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0480] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.12, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0481] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.12, and R q13 is F and R q11 and R q12Further compounds (I) in which is H are particularly preferred.

[0482] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.12, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0483] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.12, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0484] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.13, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0485] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.13, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0486] For a single compound, R1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.13, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0487] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.13, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0488] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.13, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0489] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.13, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0490] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.13, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0491] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.13, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0492] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.13, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0493] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.13, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0494] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.14, and R q11 , R q12and R q13 Further compounds (I) in which is H are particularly preferred.

[0495] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.14, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0496] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.14, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0497] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.14, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0498] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.14, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0499] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.14, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0500] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.14, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0501] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.14, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0502] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.14, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0503] For a single compound, R 1 and R 4 is hydrogen and R2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.14, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0504] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.15, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0505] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.15, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0506] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.15, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0507] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.15, and Rq11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0508] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.15, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0509] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.15, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0510] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.15, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0511] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.15, and R q13 is F and R q11 and R q12Further compounds (I) in which is H are particularly preferred.

[0512] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.15, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0513] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.15, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0514] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.16, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0515] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.16, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0516] For a single compound, R1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.16, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0517] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.16, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0518] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.16, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0519] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.16, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0520] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.16, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0521] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.16, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0522] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.16, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0523] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.16, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0524] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is H and Rq11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0525] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is H and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0526] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is H and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0527] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is H and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0528] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R qis H and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0529] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is H and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0530] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is H and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0531] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is H and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0532] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and Rq is H and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0533] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is H and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0534] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is CH3 and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0535] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is CH3 and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0536] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is CH3 and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0537] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is CH3 and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0538] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is CH3 and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0539] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is CH3 and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0540] For a single compound, R 1 and R 4 is hydrogen and R2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is CH3 and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0541] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is CH3 and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0542] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is CH3 and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0543] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.17, and R q is CH3 and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0544] For a single compound, R 1 and R4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is H and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0545] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is H and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0546] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is H and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0547] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is H and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0548] For a single compound, R 1and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is H and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0549] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is H and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0550] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is H and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0551] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is H and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0552] For a single compound, R1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is H and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0553] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is H and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0554] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is CH3 and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0555] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is CH3 and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0556] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is CH3 and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0557] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is CH3 and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0558] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is CH3 and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0559] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is CH3 and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0560] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is CH3 and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0561] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is CH3 and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0562] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is CH3 and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0563] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.18, and R q is CH3 and R q13 is CH3 and R q11 and R q12Further compounds (I) in which is H are particularly preferred.

[0564] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is H and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0565] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is H and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0566] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is H and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0567] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is H and R q11 is CH3 and R q12 and Rq13 Further compounds (I) in which is H are particularly preferred.

[0568] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is H and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0569] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is H and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0570] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is H and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0571] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is H and R q13 is F and Rq11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0572] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is H and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0573] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is H and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0574] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is CH3 and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0575] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is CH3 and R q11is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0576] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is CH3 and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0577] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is CH3 and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0578] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is CH3 and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0579] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R qis CH3 and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0580] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is CH3 and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0581] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is CH3 and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0582] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is CH3 and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0583] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.19, and R q is CH3 and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0584] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is H and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0585] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is H and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0586] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is H and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0587] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is H and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0588] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is H and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0589] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is H and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0590] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is H and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0591] For a single compound, R 1 and R 4 is hydrogen and R2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is H and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0592] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is H and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0593] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is H and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0594] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is CH3 and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0595] For a single compound, R 1 and R 4is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is CH3 and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0596] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is CH3 and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0597] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is CH3 and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0598] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is CH3 and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0599] For a single compound, R 1and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is CH3 and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0600] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is CH3 and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0601] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is CH3 and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0602] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is CH3 and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0603] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.20, and R q is CH3 and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0604] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.21, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0605] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.21, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0606] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.21, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0607] For a single compound, R 1 and R 4 is hydrogen and R2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.21, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0608] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.21, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0609] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.21, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0610] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.21, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0611] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.21, and Rq13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0612] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.21, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0613] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.21, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0614] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.22, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0615] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.22, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0616] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.22, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0617] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.22, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0618] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.22, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0619] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.22, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0620] For a single compound, R 1 and R4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.22, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0621] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.22, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0622] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.22, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0623] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.22, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0624] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.23, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0625] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.23, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0626] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.23, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0627] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.23, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0628] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.23, and R q12 is F and R q11and R q13 Further compounds (I) in which is H are particularly preferred.

[0629] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.23, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0630] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.23, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0631] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.23, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0632] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.23, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0633] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.23, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0634] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.24, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0635] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.24, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0636] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.24, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0637] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.24, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0638] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.24, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0639] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.24, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0640] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.24, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0641] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.24, and R q13is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0642] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.24, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0643] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.24, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0644] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.25, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0645] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.25, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0646] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.25, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0647] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.25, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0648] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.25, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0649] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.25, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0650] For a single compound, R 1 and R 4is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.25, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0651] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.25, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0652] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.25, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0653] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.25, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0654] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.26, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0655] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.26, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0656] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.26, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0657] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.26, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0658] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.26, and R q12 is F and R q11and R q13 Further compounds (I) in which is H are particularly preferred.

[0659] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.26, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0660] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.26, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0661] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.26, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0662] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.26, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0663] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.26, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0664] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.27, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0665] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.27, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0666] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.27, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0667] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.27, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0668] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.27, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0669] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.27, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0670] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.27, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0671] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.27, and R q13is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0672] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.27, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0673] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.27, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0674] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.28, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0675] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.28, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0676] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.28, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0677] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.28, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0678] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.28, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0679] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.28, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0680] For a single compound, R 1 and R 4is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.28, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0681] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.28, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0682] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.28, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0683] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.28, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0684] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.29, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0685] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.29, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0686] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.29, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0687] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.29, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0688] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.29, and R q12 is F and R q11and R q13 Further compounds (I) in which is H are particularly preferred.

[0689] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.29, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0690] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.29, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0691] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.29, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0692] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.29, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0693] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.29, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0694] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.30, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0695] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.30, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0696] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.30, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0697] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.30, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0698] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.30, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0699] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.30, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0700] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.30, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0701] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.30, and R q13is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0702] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.30, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0703] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.30, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0704] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.31, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0705] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.31, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0706] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.31, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0707] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.31, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0708] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.31, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0709] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.31, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0710] For a single compound, R 1 and R 4is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.31, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0711] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.31, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0712] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.31, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0713] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.31, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0714] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.32, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0715] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.32, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0716] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.32, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0717] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.32, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0718] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.32, and R q12 is F and R q11and R q13 Further compounds (I) in which is H are particularly preferred.

[0719] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.32, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0720] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.32, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0721] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.32, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0722] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.32, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0723] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.32, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0724] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.33, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0725] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.33, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0726] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.33, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0727] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.33, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0728] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.33, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0729] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.33, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0730] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.33, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0731] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.33, and R q13is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0732] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.33, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0733] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.33, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0734] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.34, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0735] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.34, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0736] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.34, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0737] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.34, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0738] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.34, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0739] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.34, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0740] For a single compound, R 1 and R 4is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.34, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0741] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.34, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0742] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.34, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0743] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.34, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0744] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.35, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0745] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.35, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0746] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.35, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0747] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.35, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0748] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.35, and R q12 is F and R q11and R q13 Further compounds (I) in which is H are particularly preferred.

[0749] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.35, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0750] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.35, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0751] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.35, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0752] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.35, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0753] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.35, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0754] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.36, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0755] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.36, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0756] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.36, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0757] For a single compound, R 1 and R 4 is hydrogen and R 2 , R3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.36, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0758] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.36, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0759] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.36, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0760] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.36, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0761] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.36, and R q13is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0762] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.36, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0763] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.36, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0764] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.37, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0765] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.37, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0766] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.37, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0767] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.37, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0768] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.37, and R q12 is F and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0769] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.37, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0770] For a single compound, R 1 and R 4is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.37, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0771] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.37, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0772] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.37, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0773] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.37, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0774] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3and -XY has one of the meanings defined in a single row of Table A, and Q is Q.38, and R q11 , R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0775] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.38, and R q11 is F and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0776] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.38, and R q11 is Cl and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0777] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.38, and R q11 is CH3 and R q12 and R q13 Further compounds (I) in which is H are particularly preferred.

[0778] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.38, and R q12 is F and R q11and R q13 Further compounds (I) in which is H are particularly preferred.

[0779] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.38, and R q12 is Cl and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0780] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.38, and R q12 is CH3 and R q11 and R q13 Further compounds (I) in which is H are particularly preferred.

[0781] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.38, and R q13 is F and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0782] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.38, and R q13 is Cl and R q11 and R q12 Further compounds (I) in which is H are particularly preferred.

[0783] For a single compound, R 1 and R 4 is hydrogen and R 2 , R 3 and -XY has one of the meanings defined in a single row of Table A, and Q is Q.38, and R q13 is CH3 and R q11 and R q12 Further compounds (I) in which is H are particularly preferred. [ka] [ka] [ka]

[0784] The # in the above rings Q.1 to Q.38 is NR 1 indicates the attachment point to

[0785] The compounds of formula (I) according to the invention can be prepared by standard processes of organic chemistry, for example the following processes: [ka]

[0786] The compounds of formula (I) can be prepared according to methods described in the prior art or methods analogous thereto, the synthesis utilizing commercially available starting materials or starting materials that can be prepared according to conventional procedures starting from readily available compounds.

[0787] Compounds of formula (I) can be prepared from carboxylic acids (III) and commercially available amines (II) using an organic base and a coupling reagent. Thus, compounds of formula (I) can be synthesized from the corresponding carboxylic acid (1 equivalent) using a coupling reagent (1-2 equivalents), such as T3P (propanephosphonic anhydride) or HATU (O-(7-azabenzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate), an organic base (1-3 equivalents), and an amine (II) (1-3 equivalents). The reaction is typically carried out in an organic solvent. Preferably, an aprotic organic solvent is used. Most preferably, tetrahydrofuran (THF), N,N-dimethylformamide (DMF), or acetonitrile (ACN) is used. The reaction is carried out at a temperature between 0°C and reflux. Preferably, the reaction is carried out at room temperature. Preferably, the organic base is triethylamine or N,N-diisopropylethylamine.

[0788] [ka] Carboxylic acids (III) are commercially available or can be prepared from the corresponding esters (IV) (where R P is alkyl or benzyl). P When R is alkyl, the ester (IV) can be cleaved using aqueous alkali metal hydroxide. Preferably, lithium hydroxide, sodium hydroxide, or potassium hydroxide (1-2 equivalents) is utilized. The reaction is typically carried out in a mixture of water and an organic solvent. Preferably, the organic solvent is THF, methanol, or acetonitrile. The reaction is carried out at a temperature between 0°C and 100°C. Preferably, the reaction is carried out at room temperature. When R in (IV) is P When is benzyl, the ester can be cleaved using palladium on charcoal (0.001 to 1 equivalent) and hydrogen gas as a catalyst at temperatures between 0°C and reflux. Preferably, the reaction is carried out at room temperature. Typically, an organic solvent is used. Preferably, THF, methanol, or ethanol is used.

[0789] [ka] Compounds of formula (IV) can be prepared from carboxylic acids (VI) and commercially available amines (V) using a base and a coupling reagent. Thus, compounds of formula (IV) can be synthesized from the corresponding carboxylic acid (1 equivalent) using a coupling reagent (1-2 equivalents), such as T3P (propanephosphonic anhydride) or HATU (O-(7-azabenzotriazol-1-yl)-N,N,N,N-tetramethyluronium hexafluorophosphate), an organic base (1-3 equivalents), and an amine (V) (1-3 equivalents). The reaction is typically carried out in an organic solvent. Preferably, an aprotic organic solvent is used. Most preferably, tetrahydrofuran (THF), N,N-dimethylformamide (DMF), or acetonitrile (ACN) is used. The reaction is carried out at a temperature between 0°C and reflux. Preferably, the reaction is carried out at room temperature. Preferably, the organic base is triethylamine or N,N-diisopropylethylamine.

[0790] [ka] Carboxylic acids (VI) can be prepared from the corresponding diesters by selective cleavage of one ester group. q When is an alkyl ester, selective ester cleavage can be achieved using an aqueous base. Preferably, an alkali metal hydroxide is used. Most preferably, lithium hydroxide, sodium hydroxide, or potassium hydroxide is used. The reaction is typically carried out in a mixture of water and an organic solvent. Preferably, THF, methanol, or acetonitrile is used. The reaction is carried out at a temperature between 0°C and 100°C, preferably at room temperature.

[0791] Alternatively, trimethyltin hydroxide (e.g., 1 equivalent) in 1,2-dichloroethane at room temperature to reflux, preferably under reflux, can be used (described in Angew. Chem. Int. Ed., 2005, 44:1378-1382). q When is benzyl, the ester can be cleaved using palladium on charcoal (0.001 to 1 equivalent) and hydrogen gas as a catalyst at temperatures between 0°C and reflux. Preferably, the reaction is carried out at room temperature. Typically, an organic solvent is used. Preferably, THF, methanol, or ethanol is used.

[0792] [ka] The diester (VII) is commercially available or can be prepared from the corresponding diazo compound (VIII) by the addition of rhodium tetraacetate ([Rh(OAc)2]2) (0.001-0.1 equivalents) and the alcohol HO-R. 7 and the alkoxy malonate (VII) (R 8 =H) is obtained. The reaction is typically carried out in an organic solvent, preferably toluene, at a temperature between 0°C and 100°C. Preferably, the reaction is carried out at 60°C as described in Angew. Chem. Int. Ed. 2014, 53, 14230-14234. If the diazo compound (VIII) is not commercially available, it can be prepared as described in Angew. Chem. Int. Ed. 2014, 53, 14230-14234.

[0793] [ka] Alternatively, the diester (VII) can be synthesized from the commercially available monoester (XI), a base, and chloroformate (XII) (1-3 equivalents) as described in Bioorganic & Medicinal Chemistry Letters, 12(11), 1501-1505; 2002. The reaction is typically carried out in an organic solvent, preferably tetrahydrofuran. The preferred temperature range is -78°C to 25°C. Preferably, the reaction is warmed from -78°C to 25°C over 16 hours. Preferably, lithium diisopropylamide (1 equivalent) is used as the base.

[0794] Instead, R 8 The diester (VII) in which is fluorine can be prepared from the corresponding non-fluorinated malonate using 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor) as described in WO 12 / 129384. Water and / or an organic solvent can be used. Preferably, the reaction is carried out in acetonitrile. The reaction is carried out using 1 to 4 equivalents of 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (Selectfluor) at temperatures between 0°C and reflux, preferably 60°C. Alternatively, N-fluorobenzenesulfonimide (CAS 133745-75-2) can be utilized (see, for example, Differding, E., & Ofner, H. (1991). N-Fluorobenzenesulfonimide: A practical reagent for electrophilic fluorinations. Synlett, 1991 (03)) 187-189).

[0795] [ka] Amines of formula (XIII) are commercially available or can be prepared from lactams (XIV), which can be prepared by alkylation as described in Org. Process Res. Dev. 2018, 22, 337-343, and commercially available alcohols (XV), using thionyl chloride (2 equivalents) as described in Tetrahedron Lett. 2001, 42, 1347-1350. This reaction is typically carried out in the coupling alcohol (XV) as the solvent. This reaction is carried out at temperatures between 0°C and reflux. Preferably, this reaction is carried out at room temperature.

[0796] In order to broaden the spectrum of action, the compounds of formula (I) can be mixed with many representatives of other herbicidal or growth-regulating active ingredients, and then applied simultaneously. Suitable ingredients for combination include, for example, acetamide, amide, aryloxyphenoxypropionate, benzamide, benzofuran, benzoic acid, benzothiadiazinon, bipyridinium, carbamate, chloroacetamide, chlorocarboxylic acid, cyclohexanedione, dinitroaniline, dinitrophenol, diphenyl ether, glycine, imidazolinone, isoxazole, isoxazolidinone, nitrile, N-phenylphthalimide, oxadiazole, oxazolidinedione, oxyacetamide, phenoxycarboxylic acid, phenylcarbamate, phenylpyrazole ... Herbicides from the classes of zolines, phenylpyridazines, phosphinates, phosphoramidates, phosphorodithioates, phthalamates, pyrazoles, pyridazinones, pyridines, pyridinecarboxylic acids, pyridinecarboxamides, pyrimidinediones, pyrimidinyl (thio)benzoates, quinolinecarboxylic acids, semicarbazones, sulfonylaminocarbonyltriazolinones, sulfonylureas, tetrazolinones, thiadiazoles, thiocarbamates, triazines, triazinones, triazoles, triazolinones, triazolocarboxamides, triazolopyrimidines, triketones, uracils, and ureas.

[0797] It may be more advantageous to apply the compound of formula (I) alone or in combination with other herbicides or in the form of a mixture with other crop protection agents, such as agents for controlling pests or plant pathogenic fungi or bacteria.It is also interesting that it is compatible with the mineral salt solution used to treat nutrient and trace element deficiencies.Other additives, such as non-phytotoxic oils and concentrated oils, may also be added.

[0798] In one embodiment of the invention, the combination according to the invention comprises at least one compound of formula (I) (compound A or component A) and at least one further active compound selected from herbicides B (compound B), preferably herbicides B of classes b1) to b15) and antidotes C (compound C).

[0799] In another embodiment of the invention, the combination according to the invention comprises at least one compound of formula (I) and at least one further active compound B (herbicide B).

[0800] Examples of herbicides B which can be used in combination with compounds A of formula (I) according to the invention are:

[0801] b1) From the group of the lipid biosynthesis inhibitors: ACC inhibitor herbicides, such as alloxydim, alloxydim sodium, butroxydim, clethodim, clodinafop, clodinafop propargyl, cycloxydim, cyhalofop, cyhalofop butyl, diclofop, diclofop methyl, fenoxaprop, fenoxaprop ethyl, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop, fluazifop-butyl, fluazifop-P, fluazifop-P-butyl, haloxyfop, haloxyfop-methyl, haloxyfop-P, haloxyfop 4-(4'-chloro-4-cyclopropyl-2'-fluoro[1,1'-biphenyl]-3-yl)-5-hydroxy-2,2,6,6-tetramethyl-2H-pyran-3(6H)-one (CAS 1312337-72-6); 4-(2',4' -Dichloro-4-cyclopropyl[1,1'-biphenyl]-3-yl)-5-hydroxy-2,2,6,6-tetramethyl-2H-pyran-3(6H)-one (CAS 1312337-45-3); 4-(4'-chloro-4-ethyl-2'-fluoro[1,1'-biphenyl]-3-yl)-5-hydroxy-2,2,6,6-tetramethyl-2H-pyran-3(6H)-one (CAS 1033757-93-5); 4-(2',4'-dichloro-4-ethyl[1,1'-biphenyl]-3-yl)-2,2,6,6-tetramethyl- 2H-Pyran-3,5(4H,6H)-dione (CAS 1312340-84-3); 5-(acetyloxy)-4-(4'-chloro-4-cyclopropyl-2'-fluoro[1,1'-biphenyl]-3-yl)-3,6-dihydro-2,2,6,6-tetramethyl-2H-pyran-3-one (CAS 1312337-48-6); 5-(acetyloxy)-4-(2',4'-dichloro-4-cyclopropyl-[1,1'-biphenyl]-3-yl)-3,6-dihydro-2,2,6,6-tetramethyl-2H-pyran-3-one;5-(acetyloxy)-4-(4'-chloro-4-ethyl-2'-fluoro[1,1'-biphenyl]-3-yl)-3,6-dihydro-2,2,6,6-tetramethyl-2H-pyran-3-one (CAS 1312340-82-1); 5-(acetyloxy)-4-(2',4'-dichloro-4-ethyl[1,1'-biphenyl]-3-yl)-3,6-dihydro-2,2,6,6-tetramethyl-2H-pyran-3-one (C AS1033760-55-2; 4-(4'-chloro-4-cyclopropyl-2'-fluoro[1,1'-biphenyl]-3-yl)-5,6-dihydro-2,2,6,6-tetramethyl-5-oxo-2H-pyran-3-yl carbonate methyl ester (CAS1312337-51-1); 4-(2',4'-dichloro-4-cyclopropyl-[1,1'-biphenyl]-3-yl)-5,6-dihydro-2,2,6,6-tetramethyl 4-(4'-chloro-4-ethyl-2'-fluoro[1,1'-biphenyl]-3-yl)-5,6-dihydro-2,2,6,6-tetramethyl-5-oxo-2H-pyran-3-ylcarbonic acid methyl ester (CAS 1312340-83-2); 4-(2',4'-dichloro-4-ethyl[1,1'-biphenyl]-3-yl)-5,6-dihydro-2,2,6,6 - tetramethyl-5-oxo-2H-pyran-3-ylcarbonic acid methyl ester (CAS 1033760-58-5); non-ACC inhibitor herbicides such as benfuresate, butyrate, cycloate, dalapon, dimepiperate, EPTC, esprocarb, ethofumesate, flupropanate, molinate, orbencarb, pebulate, prosulfocarb, TCA, thiobencarb, thiocarbazyl, triallate and vernolate;

[0802] b2) From the group of ALS inhibitors: Sulfonylureas, such as amidosulfuron, azimsulfuron, bensulfuron, bensulfuron-methyl, chlorimuron, chlorimuron-ethyl, chlorsulfuron, cyclosulfuron, cyclosulfamuron, ethametsulfuron, ethametsulfuron-methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, flupyrsulfuron-methyl-sodium, foramsulfuron, halosulfuron, halosulfuron-methyl, imazosulfuron, iodosulfuron, iodosulfuron-methyl-sodium , Iofensulfuron, Iofensulfuron-sodium, Mesosulfuron, Metazosulfuron, Metsulfuron, Metsulfuron-methyl, Nicosulfuron, Orthosulfamuron, Oxasulfuron, Primisulfuron, Primisulfuron-methyl, Propyrisulfuron, Prosulfuron, Pyrazosulfuron, Pyrazosulfuron-ethyl, Rimsulfuron, Sulfometuron, Sulfometuron-methyl, Sulfosulfuron, Thifensulfuron, Thifensulfuron-methyl, Triasulfuron, Tribenuron, Tribenuron-methyl imidazolinones such as imazamethabenz, imazamethabenz-methyl, imazamox, imazapic, imazapyr, imazaquin and imazethapyr, triazolopyrimidine herbicides and sulfonanilides such as cloransulam, cloransulam-methyl, diclosulam, flumetsulam, florasulam, metosulam, penoxulam, pyrimisulfan and pyroxsulam, pyrimidinylbenzoates such as bispyribac, bispyribac-methyl, bispyrimidine benzoates such as bispyribac, bispyrimidine benzoates such as bispyrimidine benzoates ... Pyribac-sodium, Pyribenzoxim, Pyriftalid, Pyriminobac, Pyriminobac-methyl, Pyrithiobac, Pyrithiobac-sodium, 4-[[[2-[(4,6-dimethoxy-2-pyrimidinyl)oxy]phenyl]methyl]amino]benzoic acid-1-methylethyl ester (CAS 420138-41-6), 4-[[[2-[(4,6-dimethoxy-2-pyrimidinyl)oxy]phenyl]methyl]amino]benzoic acid propyl ester (CAS 420138-40-5), N-(4-bromophenyl)-2-[(4,

[0023] 6-dimethoxy-2-pyrimidinyl)oxy]benzenemethanamine (CAS 420138-01-8), sulfonylaminocarbonyltriazolinone herbicides, such as flucarbazone, flucarbazone sodium, propoxycarbazone, propoxycarbazone sodium, thiencarbazone, and thiencarbazone methyl; and triafamone. Of these, a preferred embodiment of the present invention relates to a composition comprising at least one imidazolinone herbicide.

[0803] b3) From the group of photosynthetic inhibitors: Amicarbazones, inhibitors of photosystem II, such as 1-(6-tert-butylpyrimidin-4-yl)-2-hydroxy-4-methoxy-3-methyl-2H-pyrrol-5-one (CAS 1654744-66-7), 1-(5-tert-butylisoxazol-3-yl)-2-hydroxy-4-methoxy-3-methyl-2H-pyrrol-5-one (CAS 1637455-12-9), 1- (5-tert-butylisoxazol-3-yl)-4-chloro-2-hydroxy-3-methyl-2H-pyrrol-5-one (CAS 1637453-94-1), 1-(5-tert-butyl-1-methyl-pyrazol-3-yl)-4-chloro-2-hydroxy-3-methyl-2H-pyrrol-5-one (CAS 1654057-29-0), 1-(5-tert-butyl-1-methyl-pyrazol-3-yl)-4-chloro-2-hydroxy-3-methyl-2H-pyrrol-5-one (CAS 2023785-78-4), 4-hydroxy-1,5-dimethyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one; Zolidin-2-one (CAS 2023785-79-5), 5-ethoxy-4-hydroxy-1-methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one (CAS 1701416-69-4), 4-hydroxy-1-methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one (CAS 1708087-22-2), 4-hydroxy-1,5-dimethyl-3-[1-methyl-5-(trifluoromethyl)pyrazol-3-yl]imidazolidin-2-one (CAS2023785-80-8), 1-(5-tert-butylisoxazol-3-yl)-4-ethoxy-5-hydroxy-3-methyl-imidazolidin-2-one (CAS1844836-64-1), triazine herbicides such as chlorotriazine, triazinones, triazinediones, methylthiotriazines, and pyridazinones, for example ametryn, atrazine, chloridazon, cyanazine, desmetryn, dimethametryn, hexazinone, metribuzin, prometon, prometryn, propazine, simazine, simetryn, terbumeton, terbuthylazine, terbutryn, and trietazine, aryl ureas, for example chlorbromuron, chlorotoluron, chloroxuron, Dimefron, diuron, fluometuron, isoproturon, isouron, linuron, metamitron, methabenzthiazuron, metobenzuron, metoxuron, monolinuron, nebron, siduron, tebuthiuron, and thiadiazuron, phenylcarbamates such as desmedipham, carbutilate, phenmedipham, and phenmedipham-ethyl, nitrile herbicides such as bromofenoxim, bromoxynil, and its salts and esters, and ioxynil and its salts and esters, uracils such as bromacil, lenacil, and terbacil, as well as bentazone and bentazone sodium, pyridate, pyridafol, pentanochlor, and propanil, and inhibitors of photosystem I such as diquat, diquat dibromide, paraquat, paraquat dichloride, and paraquat dimethyl sulfate. Of these, a preferred embodiment of the present invention relates to a composition comprising at least one aryl urea herbicide. Among these, equally preferred embodiments of the present invention relate to compositions containing at least one triazine herbicide. Among these, equally preferred embodiments of the present invention relate to compositions containing at least one nitrile herbicide.

[0804] b4) From the group of the protoporphyrinogen-IX oxidase inhibitors: Acifluorfen, acifluorfen-sodium, azafenidin, bencarbazone, benzfendizone, bifenox, butafenacil, carfentrazone, carfentrazone-ethyl, chlormethoxyfen, chlorphthalim, cinidon-ethyl, cyclopyranyl, fluazolate, flufurenpyr, flufurenpyr-ethyl, flumiclorac, flumiclorac-pentyl, flumioxazin, fluroglicofen, fluroglicofen-ethyl, fluthiacet, fluthiacet-methyl, fomesafen, halosafen, lac tofen, oxadiargyl, oxadiazon, oxyfluorfen, pentoxazone, profluazole, pyraclonil, pyraflufen, pyraflufen-ethyl, saflufenacil, sulfentrazone, thidiazimine, thiafenacil, trifludimoxadine, ethyl [3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate (CAS 353292-31-6; S-3100), N-ethyl- 3-(2,6-dichloro-4-trifluoromethylphenoxy)-5-methyl-1H-pyrazole-1-carboxamide (CAS 452098-92-9), N-tetrahydrofurfuryl-3-(2,6-dichloro-4-trifluoromethylphenoxy)-5-methyl-1H-pyrazole-1-carboxamide (CAS 915396-43-9), N-ethyl-3-(2-chloro-6-fluoro-4-trifluoromethylphenoxy)-5-methyl-1H-pyrazole-1-carboxamide (CAS 452099-05-7), N-tetrahydrofurfuryl Fluoryl-3-(2-chloro-6-fluoro-4-trifluoromethylphenoxy)-5-methyl-1H-pyrazole-1-carboxamide (CAS 452100-03-7), 3-[7-fluoro-3-oxo-4-(prop-2-ynyl)-3,4-dihydro-2H-benzo[1,4]oxazin-6-yl]-1,5-dimethyl-6-thioxo-[1,3,5]triazinane-2,4-dione (CAS 451484-50-7), 2-(2,2,7-trifluoro-3-oxo-4-prop-2-ynyl-3,4-dihydro-2H-benzo[1,4]oxazin-6-yl)-4,5,6,7-tetrahydro-isoindole-1,3-dione (CAS 1300118-96-0), 1-methyl-6-trifluoromethyl-3-(2,2,7-trifluoro-3-oxo-4-prop-2-ynyl-3,4-dihydro-2H-benzo[1,4]oxazin-6-yl)-1H-pyrimidine-2,4-dione (CAS 1304113-05-0), methyl(E)-4-[2-chloro-5-[4-chloro-5-(difluoromethoxy)-1H-methyl-pyrazol-3-yl]-4-fluoro 2-[2-chloro-5-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]-4-fluorophenoxy]-2-methoxy-acetic acid methyl ester (CAS 1970221-16-9), 2-[2-[[ 3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-acetic acid methyl ester (CAS 2158274-96-3), 2-[2-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]acetic acid ethyl ester (CAS 158274-50-9), 2-[[3-[2 -chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy] methyl ester (CAS 2271389-22-9), 2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1,2,4-triazol-1-yl]-4-fluoro-phenoxy]-2-pyridyl]oxy] ethyl ester (CAS 2230679-62-4), 2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-Dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]acetic acid methyl ester (CAS 2158275-73-9), 2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]acetic acid ethyl ester (CAS 2158274-56-5), 2-[2-[[3-chloro-6-[3,6-dihydro -3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]phenoxy]-N-(methylsulfonyl)-acetamide (CAS 2158274-53-2), 2-[[3-[[3-chloro-6-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-5-fluoro-2-pyridinyl]oxy]-2-pyridinyl]oxy]-N-(methylsulfonyl)-acetamide (CAS 2158276-22-1).

[0805] b5) From the group of bleaching herbicides: PDS inhibitors: beflubutamide, diflufenican, fluridone, flurochloridone, flurtamone, norflurazon, picolinafen, and 4-(3-trifluoromethylphenoxy)-2-(4-trifluoromethylphenyl)pyrimidine (CAS 180608-33-7), HPPD inhibitors: benzobicyclon, benzofenap, bicyclopyrone, clomazone, fenquinotrione, isoxaflutole, mesotrione, oxotrione (CAS 1486617-21-3), pyrasulfotole, and pyrazolidine nate, pyrazoxyfene, sulcotrione, tefuryltrione, tembotrione, tolpyralate, topramezone, whitening agents, those with unknown mode of action: aclonifen, amitrole, flumeturon, 2-chloro-3-methylsulfanyl-N-(1-methyltetrazol-5-yl)-4-(trifluoromethyl)benzamide (CAS 1361139-71-0), bixuzolone and 2-(2,5-dichlorophenyl)methyl-4,4-dimethyl-3-isoxazolidinone (CAS 81778-66-7).

[0806] b6) From the group of the EPSP synthase inhibitors: Glyphosate, glyphosate isopropylammonium, glyphosate potassium salt and glyphosate trimesium salt (sulfosate).

[0807] b7) From the group of the glutamine synthetase inhibitors: Viranafos (Bialaphos), Viranafos sodium, Glufosinate, Glufosinate P and Glufosinate ammonium.

[0808] b8) From the group of the DHP synthase inhibitors: Ashram.

[0809] b9) From the group of the mitotic inhibitors: Compounds of the K1 group: dinitroanilines such as benfluralin, butralin, dinitramine, ethalfuralin, fluchloralin, oryzalin, pendimethalin, prodiamine and trifluralin, phosphoramidates such as amiprophos, amiprophos-methyl and butamifos, benzoic acid herbicides such as chlorthal, chlorthal-dimethyl, pyridines such as dithiopyr and thiazopyr, benzamides such as propyzamide and tebutam; compounds of the K2 group: carbetamide, chlorpropham, flamprop, flamprop-isopropyl, flamprop-methyl, flamprop-M-isopropyl, flamprop-M-methyl and propham, of which compounds of the K1 group, in particular dinitroaniline, are preferred.

[0810] b10) From the group of VLCFA inhibitors: Chloroacetamides such as acetochlor, alachlor, amidochlor, butachlor, dimethachlor, dimethenamid, dimethenamid-P, metazachlor, metolachlor, metolachlor-S, petoxamide, pretilachlor, propachlor, propisochlor and thenylchlor, oxyacetanilides such as flufenacet and mefenacet, acetanilides such as diphenamide, naproanilide, napropamide and napropamide-M, tetrazolinones such as fentrazamide and other herbicides such as anilophos, cafenstrole, fenoxasulfone, ipfencarbazone, piperophos, pyroxasulfone and isoxazoline compounds of the formulae II.1, II.2, II.3, II.4, II.5, II.6, II.7, II.8 and II.9. [ka] Isoxazoline compounds of formula (III) are known in the art, for example from WO 2006 / 024820, WO 2006 / 037945, WO 2007 / 071900 and WO 2007 / 096576; among the VLCFA inhibitors, chloroacetamides and oxyacetamides are preferred.

[0811] b11) From the group of the cellulose biosynthesis inhibitors: Chlorthiamid, dichlobenil, flupoxam, indaziflam, isoxaben, triaziflam and 1-cyclohexyl-5-pentafluorophenyloxy-1 4 -[1,2,4,6]thiatriazin-3-ylamine (CAS 175899-01-1).

[0812] b12) From the group of the uncoupler herbicides: Dinoseb, dinoterb and DNOC and their salts.

[0813] b13) From the group of the auxin herbicides: 2,4-D and its salts and esters, such as Clasiphos, 2,4-DB and its salts and esters, aminocyclopyrachlor and its salts and esters, aminopyralid and its salts, such as aminopyralid dimethylammonium, aminopyralid-tris(2-hydroxypropyl)ammonium and its ester, benazolin, benazolin ethyl, chloramben and its salts and esters, clomeprop, clopyralid and its salts and esters, dicamba and its salts and esters, dichlorprop and its salts and esters, dichlorprop-P and its salts and esters, furopyrauxifen, fluroxypyr, fluroxypyr-butomethyl, fluroxypyr-meptyl , halauxifene and its salts and esters (CAS 943832-60-8); MCPA and its salts and esters, MCPA-thioethyl, MCPB and its salts and esters, mecoprop and its salts and esters, mecoprop-P and its salts and esters, picloram and its salts and esters, quinclorac, quinmerac, TBA(2,3,6) and its salts and esters, triclopyr and its salts and esters, florpilauxifene, florpilauxifene-benzyl (CAS 1390661-72-9) and 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)picolinic acid (CAS 1629965-65-6).

[0814] b14) From the group of the auxin transport inhibitors: diflufenzopyr, diflufenzopyr sodium, naptalam and naptalam sodium.

[0815] b15) From the group of the other herbicides: bromobutide, chlorflurenol, chlorflurenol methyl, cinmethylin, cumyluron, cyclopyrimorate (CAS 499223-49-3) and its salts and esters, dalapon, dazomet, difenzoquat, difenzoquat methylsulfate, dimethipine, DSMA, dymron, endothal and its salts, etobenzanide, flurenol, flurenol butyl, flurprimidol, fosamine, fosamine ammonium, indanofan, maleic hydrazide, mefluidide, metam, methiozoline, methyl azide, methyl bromide, methyldymron, methyl iodide, MSMA, oleic acid, oxaziclomefone, pelargonic acid, pyributicarb, quinoclamine, tetflupyrolimet and tridiphane.

[0816] Furthermore, it may be useful to apply the compound of formula (I) in combination with a safener. A safener is a compound that prevents or reduces damage to useful plants without significantly affecting the herbicidal action of the compound of formula (I) on undesirable vegetation. It can be applied either before sowing (planting) the useful plants (for example, seed treatment, shoot or seedling), or as a pre-emergence or post-emergence application. The safener and the compound of formula (I) and optionally herbicide B can be applied simultaneously or successively.

[0817] In another embodiment of the invention, the combination according to the invention comprises at least one compound of formula (I) and at least one safener C (component C).

[0818] Examples of antidotes are, for example, (quinoline-8-oxy)acetic acid, 1-phenyl-5-haloalkyl-1H-1,2,4-triazole-3-carboxylic acid, 1-phenyl-4,5-dihydro-5-alkyl-1H-pyrazole-3,5-dicarboxylic acid, 4,5-dihydro-5,5-diallyl-3-isoxazolecarboxylic acid, dichloroacetamide, α-oximinophenylacetonitrile, acetophenoxime, 4,6-dihalo-2-phenylpyrimidine, N-[[4-(aminocarbonyl)phenyl]sulfonyl]-2-benzoic acid amide, 1,8-naphthalene anhydride, 2-halo-4-(haloalkyl)-5-thiazolecarboxylic acid, phosphothiolates and N-alkyl-O-phenylcarbamates and agriculturally acceptable salts and agriculturally acceptable derivatives thereof, such as amides, esters and thioesters, provided that they contain an acid group.

[0819] Examples of antidote compounds C are benoxacor, cloquintocet, siometrinil, cyprosulfamide, dichlormid, dicyclonone, dietholate, fenchlorazole, fenclorim, flurazole, fluxofenim, furilazole, isoxadifen, mefenpyr, mephenate, naphthalic anhydride, oxabetrinil, 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3), 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine (R-29148, CAS 52836-31-4), metcamifen, and BPCMS (CAS 54091-06-4).

[0820] The active compounds B and C of groups b1) to b15) are known herbicides and antidotes, see, for example, The Compendium of Pesticide Common Names (http: / / www.alanwood.net / pesticides / ); Farm Chemicals Handbook 2000 volume 86, Meister Publishing Company, 2000; B. Hock, C. Fedtke, R.R. Schmidt, Herbizide [Herbicides], Georg Thieme Verlag, Stuttgart 1995; W.H.Ahrens, Herbicide Handbook, 7th edition, Weed Science Society of America, 1994; and K.K. Hatzios, Herbicide Handbook, Supplement for the 7th edition, Weed Science Society of America, 1998. 2,2,5-Trimethyl-3-(dichloroacetyl)-1,3-oxazolidine [CAS number 52836-31-4] is also known as R-29148. 4-(Dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane [CAS number 71526-07-3] is also known as AD-67 and MON4660.

[0821] The assignment of active compounds to each mechanism of action is based on current knowledge. If an active compound applies to several mechanisms of action, it is assigned to only one mechanism of action.

[0822] The present invention also relates to a formulation comprising at least an adjuvant and at least one compound of formula (I) according to the invention.

[0823] The formulations contain a pesticidally effective amount of a compound of formula (I). The term "effective amount" refers to an amount of a combination or compound of formula (I) that is sufficient to control undesired plants, particularly undesired vegetation in crops (i.e., cultivated plants), without causing substantial damage to the treated crop plants. Such amounts can vary within a wide range and depend on various factors, such as the undesired vegetation to be controlled, the treated crop plants or materials, climatic conditions, and the particular compound of formula (I) used.

[0824] The compounds of formula (I), their salts, amides, esters or thioesters can be converted into conventional formulation types, such as solutions, emulsions, suspensions, dusts, powders, pastes, granules, presses, capsules and mixtures thereof. Examples of formulation types are suspensions (e.g., SC, OD, FS), emulsifiable concentrates (e.g., EC), emulsions (e.g., EW, EO, ES, ME), capsules (e.g., CS, ZC), pastes, lozenges, wettable powders or dusts (e.g., WP, SP, WS, DP, DS), presses (e.g., BR, TB, DT), granules (e.g., WG, SG, GR, FG, GG, MG), insecticides (e.g., LN) and gel formulations (e.g., GF) for the treatment of plant seedlings such as seeds. These and further formulation types are described in "Catalogue of pesticide formulation types and international coding system", Technical Monograph No. 2, 6 th As defined in CropLife International, Ed. May 2008.

[0825] The formulations can be prepared in a known manner, for example as described in Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.

[0826] Suitable auxiliaries are solvents, liquid carriers, solid carriers or extenders, surfactants, dispersants, emulsifiers, wetting agents, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesives, thickeners, moisturizing agents, repellents, attractants, feeding stimulants, compatibilizers, bactericides, antifreeze agents, antifoaming agents, colorants, tackifiers and binders.

[0827] Suitable solvents and liquid carriers are water and organic solvents, such as medium to high boiling fractions of mineral oils, e.g., kerosene, light oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e.g., toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, e.g., ethanol, propanol, butanol, benzyl alcohol, cyclohexanol; glycols; DMSO; ketones, e.g., cyclohexanone; esters, e.g., lactate esters, carbonate esters, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonate esters; amines; amides, e.g., N-methylpyrrolidone, fatty acid dimethylamide; and mixtures thereof.

[0828] Suitable solid carriers or extenders are mineral earths such as silicates, silica gel, talc, kaolin, limestone, lime, chalk, clay, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides such as cellulose, starch; fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea; products of plant origin such as grain flour, bark flour, wood flour, nut shell flour and mixtures thereof.

[0829] Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifiers, dispersants, solubilizers, wetting agents, penetration enhancers, protective colloids, or adjuvants. Examples of surfactants are listed in McCutcheon's, Vol. 1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Edition or North American Edition).

[0830] Suitable anionic surfactants are alkali salts, alkaline earth salts, or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulfonates include alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignin sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalene and alkylnaphthalenes, sulfosuccinates, or sulfosuccinamates. Examples of sulfates include sulfates of fatty acids and oils, ethoxylated alkylphenols, alcohols, ethoxylated alcohols, or fatty acid esters. Examples of phosphates include phosphoric acid esters. Examples of carboxylates include alkyl carboxylates and carboxylated alcohols or alkylphenol ethoxylates.

[0831] Suitable nonionic surfactants include alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof. Examples of alkoxylates include compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids, or fatty acid esters alkoxylated with 1 to 50 equivalents. Ethylene oxide and / or propylene oxide, preferably ethylene oxide, can be used for alkoxylation. Examples of N-substituted fatty acid amides include fatty acid glucamides or fatty acid alkanolamides. Examples of esters include fatty acid esters, glycerin esters, or monoglycerides. Examples of sugar-based surfactants include sorbitan, ethoxylated sorbitan, sucrose and glucose esters, or alkyl polyglucosides. Examples of polymeric surfactants include homopolymers or copolymers of vinylpyrrolidone, vinyl alcohol, or vinyl acetate.

[0832] Suitable cationic surfactants are quaternary surfactants, such as quaternary ammonium compounds having one or two hydrophobic groups or salts of long-chain primary amines. Suitable amphoteric surfactants are alkylbetaines and imidazolines. Suitable block polymers are AB or ABA type block polymers containing polyethylene oxide and polypropylene oxide blocks, or ABC type block polymers containing alkanol, polyethylene oxide, and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybasics. Examples of polyacids are alkali metal salts of polyacrylic acid or polyacid comb polymers. Examples of polybasics are polyvinylamine or polyethyleneamine.

[0833] Suitable adjuvants are compounds that themselves have negligible or even no pesticidal activity, but enhance the biological performance of the compound of formula (I) on the target. Examples include surfactants, mineral or vegetable oils, and other adjuvants. Further examples are described in Knowles, Adjuvants and Additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.

[0834] Suitable thickening agents are polysaccharides (eg xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or unmodified), polycarboxylates and silicates.

[0835] Suitable fungicides are bronopol and isothiazolinone derivatives, such as alkylisothiazolinones and benzisothiazolinones.

[0836] Suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerin.

[0837] Suitable antifoaming agents are silicones, long chain alcohols and salts of fatty acids.

[0838] Suitable colorants (e.g., red, blue, or green) are low-water-soluble pigments and water-soluble dyes, examples of which are inorganic colorants (e.g., iron oxide, titanium oxide, ferricyanide) and organic colorants (e.g., alizarin, azo, and phthalocyanine colorants).

[0839] Suitable tackifiers or binders are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylates, biological or synthetic waxes and cellulose ethers.

[0840] Examples of formulation types and methods for their preparation are as follows:

[0841] i) Water-soluble concentrate (SL, LS) 10 to 60% by weight of a compound of formula (I) according to the invention or a combination comprising at least one compound of formula (I) (component A) and at least one further compound selected from herbicidal compound B (component B) and antidote C (component C), and 5 to 15% by weight of a wetting agent (e.g., alcohol alkoxylate) are dissolved in the remaining amount of water and / or a water-soluble solvent (e.g., alcohol) up to 100% by weight. The active substance dissolves upon dilution with water.

[0842] ii) Dispersed concentrate (DC) 5 to 25% by weight of a compound of formula (I) according to the invention or a combination comprising at least one compound of formula (I) (component A) and at least one further compound selected from herbicidal compound B (component B) and antidote C (component C), and 1 to 10% by weight of a dispersant (for example, polyvinylpyrrolidone) are dissolved in a remaining amount up to 100% by weight of an organic solvent (for example, cyclohexanone). Upon dilution with water, a dispersion is obtained.

[0843] iii) Emulsifiable concentrate (EC) 15 to 70% by weight of a compound of formula (I) according to the present invention or a combination comprising at least one compound of formula (I) (component A) and at least one further compound selected from herbicidal compound B (component B) and antidote C (component C), and 5 to 10% by weight of an emulsifier (e.g., calcium dodecylbenzenesulfonate, castor oil ethoxylate) are dissolved in a water-insoluble organic solvent (e.g., aromatic hydrocarbon) with the remaining amount being up to 100% by weight. Upon dilution with water, an emulsion is obtained.

[0844] iv) Emulsions (EW, EO, ES) 5 to 40% by weight of a compound of formula (I) or a combination comprising at least one compound of formula (I) (component A) and at least one further compound selected from herbicide compound B (component B) according to the present invention and safener C (component C), and 1 to 10% by weight of an emulsifier (e.g., calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in 20 to 40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbon). This mixture is introduced into 100% water (remaining amount up to 100% by weight) using an emulsifier to form a homogeneous emulsion. Dilution with water results in an emulsion.

[0845] v) Suspension (SC, OD, FS) In a stirred ball mill, 20 to 60% by weight of a compound of formula (I) according to the invention or a combination comprising at least one compound of formula (I) (component A) and at least one further compound selected from herbicidal compound B (component B) and antidote C (component C) is ground to a finely divided active substance suspension with the addition of 2 to 10% by weight of dispersants and wetting agents (e.g., sodium lignosulfonate and alcohol ethoxylates), 0.1 to 2% by weight of a thickener (e.g., xanthan gum), and the remaining amount of water up to 100% by weight. Upon dilution with water, a stable suspension of the active substance is obtained. For FS-type formulations, up to 40% by weight of a binder (e.g., polyvinyl alcohol) is added.

[0846] vi) Water-dispersible granules and water-soluble granules (WG, SG) 50 to 80% by weight of a compound of formula (I) according to the invention or a combination comprising at least one compound of formula (I) (component A) and at least one further compound selected from herbicidal compound B (component B) and antidote C (component C) is finely ground with the addition of dispersants and wetting agents (e.g., sodium lignosulfonate and alcohol ethoxylate) in a remaining amount up to 100% by weight, and prepared as water-dispersible or water-soluble granules by means of technical equipment (e.g., extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance.

[0847] vii) Water-dispersible and water-soluble powders (WP, SP, WS) 50-80% by weight of a compound of formula (I) according to the present invention or a combination comprising at least one compound of formula (I) (component A) and at least one further compound selected from herbicidal compound B (component B) and antidote C (component C) is ground in a rotor-stator mill with the addition of 1-5% by weight of a dispersant (e.g., sodium lignosulfonate), 1-3% by weight of a wetting agent (e.g., alcohol ethoxylate), and 100% by weight of a solid carrier (e.g., silica gel). Dilution with water gives a stable dispersion or solution of the active substance.

[0848] viii) Gel (GW, GF) In a stirred ball mill, 5 to 25% by weight of a compound of formula (I) according to the invention or a combination comprising at least one compound of formula (I) (component A) and at least one further compound selected from herbicidal compound B (component B) and antidote C (component C) is ground with 3 to 10% by weight of a dispersant (e.g., sodium lignosulfonate), 1 to 5% by weight of a thickener (e.g., carboxymethylcellulose), and the remaining amount of water up to 100% by weight to obtain a fine suspension of the active substance. Upon dilution with water, a stable suspension of the active substance is obtained.

[0849] iv) Microemulsion (ME) To 5-20% by weight of a compound of formula (I) or a combination comprising at least one compound of formula (I) (component A) and at least one further compound selected from herbicide compound B (component B) and safener C (component C) according to the invention, 5-30% by weight of a blend of organic solvents (e.g., fatty acid dimethylamide and cyclohexanone), 10-25% by weight of a blend of surfactants (e.g., alcohol ethoxylate and arylphenol ethoxylate), and water to make up 100%. The mixture is stirred for 1 hour, and a thermodynamically stable microemulsion spontaneously forms.

[0850] iv) Microcapsules (CS) An oil phase containing 5 to 50% by weight of a compound of formula (I) or a combination comprising at least one compound of formula (I) (component A) and at least one additional compound selected from herbicide compound B (component B) and safener C (component C) according to the present invention, 0 to 40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbon), and 2 to 15% by weight of an acrylic monomer (e.g., methyl methacrylate, methacrylic acid, and di- or triacrylate) is dispersed in an aqueous solution of a protective colloid (e.g., polyvinyl alcohol). Radical polymerization is initiated with a radical initiator to form microcapsules of poly(meth)acrylate. Alternatively, an oil phase containing 5 to 50% by weight of a compound of formula (I) according to the present invention, 0 to 40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbon), and an isocyanate monomer (e.g., diphenylmethene-4,4'-diisocyanate) is dispersed in an aqueous solution of a protective colloid (e.g., polyvinyl alcohol). Polyurea microcapsules are formed by adding a polyamine (e.g., hexamethylenediamine). The amount of the monomer is 1-10% by weight. The weight % is based on the total CS formulation.

[0851] ix) Powder (DP, DS) 1-10% by weight of a compound of formula (I) or a combination of at least one compound of formula (I) (component A) with at least one further compound selected from herbicide compound B (component B) and safener C (component C) according to the invention is finely ground and intimately mixed with a solid carrier (e.g. finely divided kaolin) to make up 100% by weight.

[0852] x) Granules (GR, FG) 0.5 to 30% by weight of a compound of formula (I) or a combination of at least one compound of formula (I) (component A) with at least one further compound selected from herbicide compound B (component B) and safener C (component C) according to the invention is finely ground and combined with a total of 100% by weight of a solid carrier (e.g., silicate). Granulation is carried out by extrusion, spray drying or fluidized bed.

[0853] xi) Liquid formulations for microdispersion (UL) 1 to 50% by weight of a compound of formula (I) or a combination of at least one compound of formula (I) (component A) with at least one further compound selected from a herbicide compound B (component B) according to the invention and a safener C (component C) is dissolved in an organic solvent (e.g., an aromatic hydrocarbon) to make up 100% by weight.

[0854] Formulations of types i) to xi) may optionally contain further adjuvants, such as 0.1 to 1% by weight of a bactericide, 5 to 15% by weight of an antifreeze agent, 0.1 to 1% by weight of an antifoaming agent and 0.1 to 1% by weight of a colorant.

[0855] The formulations and / or combinations generally contain 0.01 to 95% by weight, preferably 0.1 to 90% by weight, in particular 0.5 to 75% by weight, of a compound of formula (I).

[0856] The compound of formula (I) is used with a purity of 90% to 100%, preferably 95% to 100% (according to NMR spectrum).

[0857] For the treatment of plant seeds, especially seeds, seed treatment solutions (LS), emulsions (SE), flowable formulations (FS), dry seed treatment powders (DS), wettable powders for seed treatment (WS), water-soluble powders for seed treatment (SS), seed treatment emulsions (ES), emulsifiable concentrates (EC) and gel formulations (GF) are usually used. The formulations in question are diluted 2 to 10 times to obtain ready-to-use preparations with an active substance concentration of 0.01 to 60% by weight, preferably 0.1 to 40% by weight.

[0858] Methods of applying the compounds of formula (I), formulations and / or combinations thereof to plant seeds, particularly seeds, include dressing, covering, pelleting, dusting, dipping and furrow application to the seeds. Preferably, the compounds of formula (I), formulations and / or combinations thereof are applied to the plant seeds by methods that do not induce germination, such as seed dressing, pelleting, coating and dusting, respectively.

[0859] To the compounds of formula (I), formulations and / or combinations containing them, various types of oils, wetting agents, adjuvants, fertilizers or micronutrients and further pesticides (e.g. herbicides, insecticides, fungicides, growth regulators, antidotes) can be added as premixes or, if appropriate, not added until just before use (tank mix). These agents can be mixed with the formulations according to the invention in a weight ratio of 1:100 to 100:1, preferably 1:10 to 10:1.

[0860] The user typically applies the compounds of formula (I) according to the invention, formulations and / or combinations containing them from a pre-dosing device, a knapsack sprayer, a spray tank, a spray plane or an irrigation device. Typically, the formulation is brought to the desired application concentration with water, buffers and / or further adjuvants, thus obtaining a ready-to-use spray solution or a formulation according to the invention. Typically, 20 to 2000 liters, preferably 50 to 400 liters, of ready-to-use spray solution are applied per hectare of agriculturally useful area.

[0861] According to one embodiment, either the individual or partially premixed components of the formulation according to the invention, for example the components comprising a compound of formula (I) and optionally an active substance from group B and / or C, are mixed by the user in a spray tank, and further auxiliaries and additives may be added, if appropriate.

[0862] In a further embodiment, the individual components of the formulation according to the invention, such as parts of a kit or parts of a two- or three-component mixture, can be mixed by the user himself in a spray tank, and further auxiliaries can be added if appropriate.

[0863] In a further embodiment, either the individual or partially premixed components of the formulation according to the invention, e.g. components comprising a compound of formula (I) and optionally an active substance from group B and / or C, can be applied together (e.g. after a tank mix) or sequentially.

[0864] The compounds of formula (I) are suitable as herbicides, either on their own or in suitable combination with at least one further compound selected from herbicidally active compound B (component B) and antidote C (component C).

[0865] The compounds of formula (I) or formulations and / or combinations containing the compounds of formula (I) are highly effective in controlling undesirable vegetation in non-crop lands, especially at high application rates. They act against broadleaf weeds and grass weeds in crops such as wheat, rice, corn, soybeans and cotton without causing significant damage to the crop plants. This effect is mainly observed at low application rates.

[0866] The compounds of the present invention are useful, for example, for controlling the following weeds: representative examples include velvetleaf (Abutilon theophrasti) (ABUTH), black-grass (Alopercurus myosuroides) (ALOMY), redroot pigweed (Amaranthus retroflexus) (AMARE), common branweed (Apera spica-venti) (APESV), wild oat (Avena fatua) (AVEFA), barnyardgrass (Echinocloa crus-galli) (ECHCG), foxtail (Setaria faberi) (SETFA), and green foxtail (Setaria viridis) (SETVI).

[0867] The compounds of formula (I) or formulations and / or combinations containing them are applied to plants primarily by spraying the leaves, where application can be carried out by conventional spraying techniques using, for example, water as a carrier, a spray volume of about 100 to 1000 l / ha (e.g., 300 to 400 l / ha). The compounds of formula (I) or formulations and / or combinations containing them can also be applied by low-volume or ultra-low-volume methods or in the form of fine particles.

[0868] Application of the compounds of formula (I) or formulations and / or combinations comprising them may be carried out before, during and / or after the emergence of the undesired vegetation, preferably during and / or after the emergence.

[0869] The application of the compounds of formula (I) or the formulations and / or combinations may be carried out before or during sowing.

[0870] The compounds of formula (I) or formulations and / or combinations containing them can be applied pre-emergence, post-emergence, or pre-planting or together with the seeds of crop plants. It is also possible to apply the compounds of formula (I) or formulations and / or combinations containing them by applying the seeds of crop plants pre-treated with the compounds of formula (I) or formulations and / or combinations containing them. If the active ingredient is poorly tolerated by a particular crop plant, the combination can be sprayed with the aid of a spraying device, avoiding contact with the leaves of sensitive crop plants as much as possible, but using application techniques (post-direct, lay-by) that allow the active ingredient to reach the leaves of underlying undesirable vegetation or the bare soil surface.

[0871] In a further embodiment, the compound of formula (I) or the formulations and / or combinations comprising them can be applied by treating seeds. Seed treatment essentially includes all procedures known to those skilled in the art (seed dressing, seed coating, seed dusting, seed soaking, seed film coating, seed multi-coating, seed envelopment, seed dripping and seed pelleting) based on the compound of formula (I) or the formulations and / or combinations prepared therefrom. Here, the combination can be applied diluted or undiluted.

[0872] The term "seed" includes all kinds of seeds, such as corn, seeds, fruits, tubers, seedlings and similar forms. Preferably, the term seed here describes corn and seeds. The seeds used can be seeds of the above-mentioned crop plants, but can also be seeds of transgenic plants or plants obtained by conventional breeding methods.

[0873] When employed in plant protection, the application rates of the active substance without formulation auxiliaries, i.e. the compound of formula (I), component B and, where appropriate, component C, are, depending on the type of effect desired, between 0.001 and 2 kg, preferably between 0.005 and 2 kg, more preferably between 0.05 and 0.9 kg, in particular between 0.1 and 0.75 kg per hectare.

[0874] In another embodiment of the invention, the application rates of the compound of formula (I), component B and, where appropriate, component C, are from 0.001 to 3 kg / ha, preferably from 0.005 to 2.5 kg / ha and in particular from 0.01 to 2 kg / ha of active substance (as).

[0875] In another preferred embodiment of the present invention, the application rate of the compounds of formula (I) according to the present invention (total amount of the compounds of formula (I)) is 0.1 g / ha to 3000 g / ha, preferably 10 g / ha to 1000 g / ha, depending on the target to be controlled, the season, the target plant, and the growth stage.

[0876] In another preferred embodiment of the present invention, the application rate of the compound of formula (I) is in the range of 0.1 g / ha to 5000 g / ha, preferably in the range of 1 g / ha to 2500 g / ha or 5 g / ha to 2000 g / ha.

[0877] In another preferred embodiment of the present invention, the application rate of the compound of formula (I) is 0.1 to 1000 g / ha, preferably 1 to 750 g / ha, more preferably 5 to 500 g / ha.

[0878] The required application rate of herbicidal compound B is generally in the range of 0.0005 kg / ha to 2.5 kg / ha, preferably in the range of 0.005 kg / ha to 2 kg / ha or 0.01 kg / ha to 1.5 kg / h as.

[0879] The required application rate of Antidote C is generally in the range of 0.0005 kg / ha to 2.5 kg / ha, preferably in the range of 0.005 kg / ha to 2 kg / ha or 0.01 kg / ha to 1.5 kg / h as.

[0880] In the treatment of plant seeds, for example by dusting, coating or irrigating the seeds, it is generally necessary to use an amount of active substance of 0.1 to 1000 g, preferably 1 to 1000 g, more preferably 1 to 100 g, and most preferably 5 to 100 g per 100 kilograms of plant seeds (preferably seeds).

[0881] In another embodiment of the invention, for treating seeds, the application rate of active substances, i.e. the compound of formula (I), component B and, where appropriate, component C, is generally employed in an amount of 0.001 to 10 kg per 100 kg of seeds.

[0882] When used in the protection of materials or stored products, the amount of active substance applied depends on the type of application area and the desired effect. Amounts customarily applied in the protection of materials are 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of active substance per cubic meter of treated material.

[0883] In the case of the combinations according to the invention, it is immaterial whether the compound of formula (I) and the further component B and / or component C are formulated and applied together or applied separately.

[0884] When applied separately, the order in which the applications are carried out is not important: it is only necessary that the compound of formula (I) and the further component B and / or component C are applied within a time frame that allows the simultaneous action of the active ingredients on the plant, preferably within a time frame of at most 14 days, in particular at most 7 days.

[0885] Depending on the method of application, the compounds of formula (I) or formulations and / or combinations containing them may additionally be applied to more crop plants to eliminate undesirable vegetation. Examples of suitable crops include: onion (Allium cepa), pineapple (Ananas comosus), groundnut (Arachis hypogaea), asparagus (Asparagus officinalis), oats (Avena sativa), beet (Beta vulgaris spec. altissima), beet (Beta vulgaris spec. rapa), rapeseed (Brassica napus var. napus), rutabaga (Brassica napus var. napobrassica), and winter tuna rape (Brassica rapa var.silvestris, kale (Brassica oleracea), black mustard (Brassica nigra), tea plant (Camellia sinensis), safflower (Carthamus tinctorius), pecan (Carya illinoinensis), lemon (Citrus limon), orange (Citrus sinensis), Arabica coffee (Coffea arabica), Robusta coffee (Coffea canephora), Liberica coffee (Coffea liberica), cucumber (Cucumis sativus), corngrass (Cynodon dactylon), wild carrot (Daucus carota), oil palm (Elaeis guineensis), wild strawberry (Fragaria vesca), soybean (Glycine max), and upland cotton (Gossypium hirsutum, green cotton (Gossypium arboreum), Asiatic cotton (Gossypium herbaceum), Gossypium vitifolium, sunflower (Helianthus annuus), rubber tree (Hevea brasiliensis), barley (Hordeum vulgare), hops (Humulus lupulus), sweet potato (Ipomoea batatas), oak walnut (Juglans regia), lentil (Lens culinaris), flax (Linum usitatissimum), tomato (Lycopersicon lycopersicum), apple (Malus spec.), cassava (Manihot esculenta), alfalfa (Medicago sativa), musa (Musa spec.), tobacco (Nicotiana tabacum) (N. rustica), olive (Olea europaea), rice (Oryza sativa), lima bean (Phaseolus lunatus), common bean (Phaseolus vulgaris), Norway spruce (Picea abies), pine (Pinus spec.), pistachio (Pistacia vera), pea (Pisum sativum), sweet cherry (Prunus avium), peach (Prunus persica), pear (Pyrus communis), apricot (Prunus armeniaca), black cherry (Prunus cerasus), almond (Prunus dulcis) and plum (Prunus domestica), Ribes sylvestre, castor bean (Ricinus communis), sugarcane (Saccharum officinarum), rye (Secale cereale), white mustard (Sinapis alba), potato (Solanum tuberosum), sorghum (Sorghum bicolor (S. vulgare)), cocoa (Theobroma cacao) cacao), red clover (Trifolium pratense), bread wheat (Triticum aestivum), triticale (Triticale), durum wheat (Triticum durum), broad beans (Vicia faba), European grape (Vitis vinifera), and corn (Zea mays).

[0886] Preferred crops include peanut (Arachis hypogaea), sugar beet (Beta vulgaris spec. altissima), rapeseed (Brassica napus var. napus), kale (Brassica oleracea), lemon (Citrus limon), orange (Citrus sinensis), coffee (Coffea arabica), coffee (Coffea canephora), coffee (Coffea liberica), corngrass (Cynodon dactylon), soybean (Glycine max), upland cotton (Gossypium hirsutum), green cotton (Gossypium arboreum), and Asiatic cotton (Gossypium herbaceum, Gossypium vitifolium, sunflower (Helianthus annuus), barley (Hordeum vulgare), oak walnut (Juglans regia), lentil (Lens culinaris), flax (Linum usitatissimum), tomato (Lycopersicon lycopersicum), apple (Malus spec.), alfalfa (Medicago sativa), tobacco (Nicotiana tabacum), olive (Olea europaea), rice (Oryza sativa), lima bean (Phaseolus lunatus), common bean (Phaseolus vulgaris), pistachio (Pistacia vera), pea (Pisum sativum), almond (Prunus dulcis), sugarcane (Saccharum officinarum), rye (Secale cereale), potato (Solanum tuberosum), sorghum (Sorghum bicolor (s. grugare (s.vulgare), triticale (Triticale), bread wheat (Triticum aestivum), durum wheat (Triticum durum), broad beans (Vicia faba), European grape (Vitis vinifera), and corn (Zea mays).

[0887] Particularly preferred crops are cereals, corn, soybeans, rice, rapeseed, cotton, potato, peanut or perennial crops.

[0888] The compounds of formula (I) according to the present invention or formulations and / or combinations comprising them may also be used in crops that have been modified by mutagenesis or genetic engineering in order to provide the plants with new traits or to modify traits that are already present.

[0889] As used herein, the term "crop" also includes (crop) plants that have been modified by mutagenesis or genetic engineering to provide the plant with new traits or to modify traits that are already present.

[0890] Mutagenesis includes techniques of random mutagenesis using X-rays or mutagenic chemicals, but also techniques of targeted mutagenesis to generate mutations at specific loci in the plant genome, which often use oligonucleotides or proteins such as CRISPR / Cas, zinc finger nucleases, TALENs, or meganucleases to achieve the targeted effect.

[0891] Genetic engineering typically uses recombinant DNA technology to create modifications in plant genomes that are not readily obtainable through breeding, mutation, or natural recombination in natural environments. Typically, one or more genes are incorporated into a plant's genome to add or improve traits. These incorporated genes are also known in the art as transgenes, and plants containing such transgenes are called transgenic plants. The plant transformation process typically involves several transformation events, each with a different genomic locus at which the transgene is integrated. Plants containing a particular transgene at a particular genomic locus are typically described as containing a particular "event" and are referred to by the name of the particular event. Traits introduced or modified in plants include herbicide tolerance, insect resistance, increased yield, and tolerance to biotic conditions such as drought, among others.

[0892] Herbicide tolerance has been engineered using mutations and genetic modification. Plants that have been made tolerant to acetolactate synthase (ALS)-inhibiting herbicides by traditional mutagenesis and breeding methods include plant varieties marketed under the name Clearfield®. However, most herbicide tolerance traits have been engineered using transgenes.

[0893] Herbicide tolerance has been engineered to glyphosate, glufosinate, 2,4-D, dicamba, oxynil herbicides such as bromoxynil and ioxynil, sulfonylurea herbicides, ALS inhibitors, and 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors such as isoxaflutole and mesotrione.

[0894] Transgenes used to provide herbicide tolerance traits include: tolerance to glyphosate: cp4 epsps, epsps grg23ace5, mepsps, 2mepsps, gat4601, gat4621, and goxv247; tolerance to glufosinate: pat and bar; tolerance to 2,4-D: aad-1 and aad-12; tolerance to dicamba: dmo; tolerance to oxynil herbicides: bxn; tolerance to sulfonylurea herbicides: zm-hra, csr1-2, gm-hra, S4-HrA; tolerance to ALS inhibitor herbicides: csr1-2; tolerance to HPPD inhibitors: hppdPF, W336, and adhppd-03.

[0895] Transgenic corn events containing herbicide tolerance genes include, but are not limited to, DAS40278, MON801, MON802, MON809, MON810, MON832, MON87411, MON87419, MON87427, MON88017, MON89034, NK603, GA21, MZHG0JG, HCEM485, VCO-φ1981-5, 676, 678, 680, 33121, 4114, 59122, 98140, Bt10, Bt176, CBH-351, DBT418, DLL25, MS3, MS6, MZIR098, T25, TC1507, and TC6275.

[0896] Transgenic soybean events containing herbicide tolerance genes include, but are not limited to, GTS 40-3-2, MON87705, MON87708, MON87712, MON87769, MON89788, A2704-12, A2704-21, A5547-127, A5547-35, DP356043, DAS44406-6, DAS68416-4, DAS-81419-2, GU262, SYHTφH2, W62, W98, FG72, and CV127.

[0897] Transgenic cotton events containing herbicide resistance genes include, but are not limited to, 19-51a, 31707, 42317, 81910, 281-24-236, 3006-210-23, BXN10211, BXN10215, BXN10222, BXN10224, MON1445, MON1698, MON88701, MON88913, GHB119, GHB614, LLCotton25, T303-3, and T304-40.

[0898] Transgenic canola events containing herbicide tolerance genes include, but are not limited to, MON88302, HCR-1, HCN10, HCN28, HCN92, MS1, MS8, PHY14, PHY23, PHY35, PHY36, RF1, RF2, and RF3.

[0899] Insect resistance has primarily been achieved by introducing bacterial genes encoding insecticidal proteins into plants. The most frequently used transgenes are Bacillus species toxin genes and their synthetic variants, such as cry1A, cry1Ab, cry1Ab-Ac, cry1Ac, cry1A.105, cry1F, cry1Fa2, cry2Ab2, cry2Ae, mcry3A, ecry3.1Ab, cry3Bb1, cry34Ab1, cry35Ab1, cry9C, vip3A(a), and vip3Aa20. However, plant-derived genes have also been introduced into other plants, particularly genes encoding protease inhibitors such as CpTI and pinII. Another approach involves using transgenes to produce double-stranded RNA in plants to target and downregulate insect genes. An example of such a transgene is dvsnf7.

[0900] Transgenic corn events containing genes for insecticidal proteins or double-stranded RNA include, but are not limited to, Bt10, Bt11, Bt176, MON801, MON802, MON809, MON810, MON863, MON87411, MON88017, MON89034, 33121, 4114, 5307, 59122, TC1507, TC6275, C...

Claims

1. Formula (I) 【Chemical 1】 wherein the substituents have the following meanings: Q is a bicyclic or tricyclic aromatic or partially aromatic fused ring system formed from s carbon atoms, t nitrogen atoms, n sulfur atoms and n oxygen atoms, said carbon or sulfur ring atoms carrying p oxo groups, and the ring is substituted with k substituents R Ｑ１ and n substituents R Ｑ２ having R Ｑ１ is a halogen, nitro, hydroxyl, cyano, (C １ ~C ３ )-alkyl, (C １ ~C ３ )-haloalkyl, hydroxy-(C １ ~C ３ )-alkyl, (C ３ ~C ５ )-cycloalkyl, (C １ ~C ３ )-alkoxy, (C １ ~C ３ )-haloalkoxy, (C ２ ~C ３ )-alkenyl, (C ２ ~C ３ )-haloalkenyl, (C ２ ~C ３ )-alkynyl or (C ２ ~C ３ )-haloalkynyl; R Ｑ２ is phenyl-(C １ ~C ３ )-alkyl, (C １ ~C ４ )-alkylcarbonyl, aminocarbonyl, (C １ ~C ４ )-alkylaminocarbonyl, di-(C １ ~C ４ -alkyl)aminocarbonyl, (C １ ~C ４ )-alkoxycarbonyl, benzyloxycarbonyl, fluorenyloxycarbonyl, allyloxycarbonyl, (C １ ~C ３ )-alkoxy-(C １ ~C ３ )-alkyl, (C １ ~C ３ )-alkylthio, (C １ ~C ３ )-alkylsulfinyl, (C １ ~C ３ )-alkylsulfonyl or phenylsulfonyl, and the aliphatic or aromatic moiety in the last-mentioned 14 groups is selected from fluorine, chlorine, bromine, cyano and (C １ ~C ２ )-alkoxy; R １ is hydrogen, (C １ ~C ３ )-alkyl, (C １ ~C ３ )-haloalkyl, (C ３ ~C ４ )-cycloalkyl, (C ２ ~C ３ )-alkenyl, (C ２ ~C ３ )-haloalkenyl, (C ２ ~C ３ )-alkynyl, (C ２ ~C ３ )-haloalkynyl, (C １ ~C ３ )-alkoxy-(C １ ~C ３ )-alkyl, (C １ ~C ３ )-alkoxy, (C １ ~C ３ )-haloalkoxy or (C １ ~C ３ )-alkoxy-(C １ ~C ３ )-alkoxy; R ２ is (C １ ~C ６ )-alkyl, (C ３ ~C ６ )-cycloalkyl, (C ３ ~C ６ )-alkenyl, (C ３ ~C ６ )-alkynyl or (C １ ~C ３ )-alkoxy-(C １ ~C ３ )-alkyl, wherein the aliphatic or cycloaliphatic moieties in the last five groups are substituted with m groups selected from the group consisting of fluorine, chlorine, bromine, iodine, hydroxyl and cyano; R ３ is hydrogen, halogen, cyano, (C １ ~C ６ )-alkyl, (C １ ~C ６ )-haloalkyl, (C １ ~C ６ )-cyanoalkyl, (C １ ~C ３ )-hydroxyalkyl, (C １ ~C ３ )-alkoxy-(C １ ~C ３ )-alkyl, (C １ ~C ３ )-haloalkoxy-(C １ ~C ３ )-alkyl, (C ３ ~C ６ )-cycloalkyl, (C ３ ~C ６ )-alkenyl, (C ２ ~C ６ )-alkynyl, (C １ ~C ６ )-alkoxy, (C １ ~C ６ )-haloalkoxy, (C １ ~C ３ )-cyanoalkoxy, (C １ ~C ３ )-alkoxy-(C １ ~C ３ )-alkoxy, (C ３ ~C ６ )-cycloalkoxy, (C ３ ~C ５ )-cycloalkyl-(C １ ~C ３ )-alkoxy, (C ３ ~C ６ )-alkenyloxy, (C ３ ~C ６ )-alkynyloxy or (C １ ~C ３ )-alkylthio; R ４ is hydrogen, (C １ ~C ６ )-alkyl, (C １ ~C ６ )-haloalkyl, (C １ ~C ３ )-alkoxy-(C １ ~C ３ )-alkyl, (C ３ ~C ４ )-cycloalkyl, (C ２ ~C ６ )-alkenyl, (C ２ ~C ６ )-haloalkenyl, (C ２ ~C ６ )-alkynyl, (C ２ ~C ６ )-haloalkynyl, (C １ ~C ６ )-alkoxy, (C １ ~C ６ )-haloalkoxy or (C １ ~C ３ )-alkoxy-(C １ ~C ３ )-alkoxy; X is a bond (X ０ ) or (X １ ), (X ２ ), (X ３ ), (X ４ ), (X ５ ) and (X ６ ): 【Chemistry 2】 is a divalent entity selected from the group consisting of R ５ , R ６ , R ７ , R ８ , R ９ and R １０ are each independently and independently at each occurrence hydrogen, fluorine, chlorine, bromine, iodine, hydroxyl, cyano, CO ２ R ｅ , C.O.R. ｂ R ｄ , N.R. ｂ CO ２ R ｅ , R ａ substituted by m groups selected from the group consisting of fluorine, chlorine, bromine, iodine, hydroxyl and cyano (C １ ~C ６ )-alkyl, (C ３ ~C ５ )-cycloalkyl, (C ２ ~C ６ )-alkenyl, (C ２ ~C ６ )-alkynyl, phenyl, imidazolyl; (C １ ~C ６ )-alkoxy, (C ３ ~C ６ )-cycloalkoxy, (C ３ ~C ６ )-alkenyloxy, (C ３ ~C ６ )-alkynyloxy, (C １ ~C ３ )-alkylthio, (C １ ~C ３ )-alkylsulfinyl or (C １ ~C ３ )-alkylsulfonyl, and the aliphatic or cycloaliphatic moieties in the last seven groups are fluorine, chlorine, bromine, iodine, cyano and (C １ ~C ２ )-alkoxy; Y is hydrogen, cyano, hydroxyl, Z; １ ~C １２ )-alkyl, (C ３ ~C ８ )-cycloalkyl, (C ２ ~C １２ )-alkenyl or (C ２ ~C １２ )-alkynyl, and the last four aliphatic or cycloaliphatic groups are fluorine, chlorine, bromine, iodine, cyano, hydroxyl, OR ｄ ,Z,OZ,NHZ,S(O) ｎ R ａ , S.O. ２ NR ｂ R ｄ , S.O. ２ NR ｂ COR ｅ , CO ２ R ｅ , C.O.R. ｂ R ｈ , C.O.R. ｂ , C.O.R. ｅ SO ２ R ａ , N.R. ｂ R ｅ , N.R. ｂ COR ｅ , N.R. ｂ CONR ｅ R ｅ , N.R. ｂ CO ２ R ｅ , N.R. ｂ SO ２ R ｅ , N.R. ｂ SO ２ NR ｂ R ｅ , OCONR ｂ R ｅ , OCSNR ｂ R ｅ , P.O.R. ｆ R ｆ and C(R ｂ ) = NOR ｅ substituted with m groups selected from the group consisting of: Z is formed from r carbon atoms, k nitrogen atoms, n sulfur atoms and n oxygen atoms, and CO ２ R ｅ , C.O.R. ｂ R ｈ , S(O) ｎ R ａ , S.O. ２ NR ｂ R ｄ , S.O. ２ NR ｂ COR ｅ , C.O.R. ｂ , C.O.R. ｅ SO ２ R ａ , N.R. ｂ R ｅ , N.R. ｂ COR ｅ , N.R. ｂ CONR ｅ R ｅ , N.R. ｂ CO ２ R ｅ , N.R. ｂ SO ２ R ｅ , N.R. ｂ SO ２ NR ｂ R ｅ , OCONR ｂ R ｅ , OCSNR ｂ R ｅ , P.O.R. ｆ R ｆ and C(R ｂ ) = NOR ｅ , R ａ , R ｃ , R ｅ and R ｆ wherein the sulfur and carbon ring atoms bear n oxo groups; R ａ is (C １ ~C ６ )-alkyl, (C ２ ~C ４ )-alkynyl or (C ３ ~C ６ )-cycloalkyl, wherein the last three aliphatic or cycloaliphatic groups are fluorine, chlorine, bromine, iodine, cyano, hydroxy, and (C １ ~C ３ )-alkoxy; R ｂ are hydrogen or independently R ａ has one of the meanings given for R ｃ represents fluorine, chlorine, bromine, iodine, cyano, hydroxyl; １ ~C ６ )-alkoxy, (C ３ ~C ６ )-alkenyloxy or (C ３ ~C ６ )-alkynyloxy, and the aliphatic moieties in the last three groups are fluorine, chlorine, bromine, cyano and (C １ ~C ２ )-alkoxy; R ｄ is hydrogen, (C １ ~C ６ )-alkyl, (C ２ ~C ４ )-alkenyl, (C ２ ~C ４ )-alkynyl, (C ３ ~C ６ )-cycloalkyl, (C ３ ~C ６ )-cycloalkyl-(C １ ~C ３ )-alkyl, phenyl-(C １ ~C ３ )-alkyl or furanyl-(C １ ~C ３ )-alkyl, and the aliphatic, cycloaliphatic, aromatic or heteroaromatic moiety in the last seven groups is selected from the group consisting of fluorine, chlorine, bromine, cyano, CO ２ R ａ , C.O.R. ｂ R ｈ , (C １ ~C ２ )-alkoxy, (C １ ~C ３ )-alkylthio, (C １ ~C ３ )-alkylsulfinyl, (C １ ~C ３ )-substituted by m groups selected from the group consisting of alkylsulfonyl, phenylthio, phenylsulfinyl, and phenylsulfonyl; R ｅ are independently R ｄ has one of the given meanings: R ｆ is (C １ ~C ３ )-alkyl or (C １ ~C ３ )-alkoxy; R ｈ is hydrogen, (C １ ~C ６ )-alkyl, (C １ ~C ２ )-alkoxy, (C ３ ~C ６ )-cycloalkyl, (C ２ ~C ４ )-alkenyl, (C ２ ~C ４ )-alkynyl or (C １ ~C ６ )-alkoxycarbonyl-(C １ ~C ６ )-alkyl, and the aliphatic or cycloaliphatic moieties in the last six groups are fluorine, chlorine, bromine, cyano, CO ２ R ａ and (C １ ~C ２ )-alkoxy; each k is independently 0, 1, 2, 3, or 4; each m is independently 0, 1, 2, 3, 4, or 5; each n is independently 0, 1, or 2; each p is independently 0, 1, or 2; each r is independently 1, 2, 3, 4, 5, 6, 7, or 8; each s is independently 5, 6, 7, 8, 9, 10, 11, 12, 13, or 14; each t is independently 0, 1, 2, 3, or 4 and agriculturally acceptable salts, stereoisomers and tautomers thereof, comprising the following compounds: N-[(S)-5-(2-hydroxy-ethyl)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl]-2-methoxy-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; 2-Ethoxy-N-[(S)-5-(2-hydroxy-ethyl)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl]-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; (S or R)-2-ethoxy-N-[(S)-5-(2-hydroxy-ethyl)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl]-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; 2-Methoxy-N-[(S)-5-(2-methoxy-ethyl)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl]-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; N-((6R,7S)-2-fluoro-6-methyl-8-oxo-6,7,8,9-tetrahydro-5-oxa-9-aza-benzocyclohepten-7-yl)-2-methoxy-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; 2-Methoxy-N-((6R,7S)-6-methyl-8-oxo-3-trifluoromethyl-6,7,8,9-tetrahydro-5-oxa-9-aza-benzocyclohepten-7-yl)-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; (-)-2-Methoxy-N-((S)-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl)-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; N-((S)-5-cyclopropylmethyl-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl)-2-methoxy-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide; 2-Methoxy-N-((S)-5-methyl-6-oxo-6,7-dihydro-5H-dibenzo[b,d]azepin-7-yl)-N'-(2,2,3,3,3-pentafluoro-propyl)-malonamide and the agriculturally acceptable salts, stereoisomers and tautomers thereof, excluding the compounds and the agriculturally acceptable salts, stereoisomers and tautomers thereof.

2. The above substituents have the following meanings: R １ is hydrogen or (C １ ~C ３ )-alkyl; and R ４ is hydrogen or (C １ ~C ３ )-alkyl; Preferably, R １ and R ４ The compound of claim 1 , wherein is hydrogen.

3. The following conditions a) and b): a) R ２ is (C １ ~C ６ )-alkyl, (C １ ~C ６ )-haloalkyl, (C ３ ~C ６ )-cycloalkyl, (C ３ ~C ６ )-alkenyl or (C ３ ~C ６ )-alkynyl; b) R ３ is hydrogen, halogen, (C １ ~C ６ )-alkyl, (C ３ ~C ６ )-cycloalkyl, (C １ ~C ６ )-alkoxy, (C １ ~C ６ )-haloalkoxy, (C ３ ~C ６ )-cycloalkoxy, (C ３ ~C ６ )-alkenyloxy or (C ３ ~C ６ )-alkynyloxy 2. The compound of claim 1, wherein one or both of the following apply:

4. The following conditions a) and b): a) R ２ is (C １ ~C ６ )-alkyl; b) R ３ is hydrogen or halogen 4. The compound of claim 3, wherein one or both of the following apply:

5. R ２ is methyl or ethyl; preferably methyl; and R ３ The compound of claim 4 , wherein is hydrogen.

6. X is a bond; and Y is Z; Z is CO ２ R ｅ , C.O.R. ｂ R ｈ , S(O) ｎ R ａ , S.O. ２ NR ｂ R ｄ , S.O. ２ NR ｂ COR ｅ , C.O.R. ｂ , C.O.R. ｅ S(O)R ａ , C.O.R. ｅ SO ２ R ａ , C.O.R. ｂ１ SO ２ NR ｂ２ R ｂ３ , N.R. ｂ R ｅ , N.R. ｂ COR ｅ , N.R. ｂ CONR ｅ R ｅ , N.R. ｂ CO ２ R ｅ , N.R. ｂ SO ２ R ｅ , N.R. ｂ１ SO ２ NR ｂ２ R ｅ , OCONR ｂ R ｅ , OCSNR ｂ R ｅ , P.O.R. ｆ R ｆ , C(R ｂ ) = NOR ｅ , R ａ , R ｃ , R ｅ and R ｆ wherein the carbon ring atoms carry n oxo groups; Z is preferably CO ２ R ｅ , C.O.R. ｂ R ｈ , S(O) ｎ R ａ , S.O. ２ NR ｂ R ｄ , S.O. ２ NR ｂ COR ｅ , C.O.R. ｂ , C.O.R. ｅ S(O)R ａ , C.O.R. ｅ SO ２ R ａ , C.O.R. ｂ１ SO ２ NR ｂ２ R ｂ３ , N.R. ｂ R ｅ , N.R. ｂ COR ｅ , N.R. ｂ CONR ｅ R ｅ , N.R. ｂ CO ２ R ｅ , N.R. ｂ SO ２ R ｅ , N.R. ｂ１ SO ２ NR ｂ２ R ｅ , OCONR ｂ R ｅ , OCSNR ｂ R ｅ and P.O.R. ｆ R ｆ , C(R ｂ ) = NOR ｅ m groups selected from the group consisting of and R ａ , R ｃ , R ｅ and R ｆ 10. The compound of claim 1, wherein m is substituted with m groups selected from the group consisting of:

7. Z is m groups CO ２ R ｅ is a 5- or 6-membered saturated or partially unsaturated carbocyclic ring substituted by R ｅ is hydrogen or (C １ ~C ６ )-alkyl; Z is preferably m groups CO ２ R ｅ is a 5- or 6-membered partially unsaturated carbocyclic ring substituted by R ｅ is hydrogen or (C １ ~C ６ )-alkyl; Z is more preferably one group CO ２ R ｅ is a 5-membered partially unsaturated carbocyclic ring substituted by R ｅ is hydrogen or (C １ ~C ６ 7. The compound of claim 6, wherein the aryl group is aryl.

8. X is a divalent unit (X １ ) and R ５ and R ６ are as defined in claim 1 and in particular independently hydrogen or (C １ ~C ６ )-alkyl; and Y is S(O) ｎ R ａ , S.O. ２ NR ｂ R ｄ , S.O. ２ NR ｂ COR ｅ , CO ２ R ｅ , C.O.R. ｂ R ｈ , C.O.R. ｂ , C.O.R. ｅ SO ２ R ａ , N.R. ｂ R ｅ , N.R. ｂ COR ｅ , N.R. ｂ CONR ｅ R ｅ , N.R. ｂ CO ２ R ｅ , N.R. ｂ SO ２ R ｅ , N.R. ｂ SO ２ NR ｂ R ｅ , OCONR ｂ R ｅ , OCSNR ｂ R ｅ , P.O.R. ｆ R ｆ and C(R ｂ ) = NOR ｅ (C １ ~C ８ )-alkyl; Y is preferably m groups CO ２ R ｅ (C １ ~C ４ )-alkyl, and R ｅ is hydrogen or (C １ ~C ６ 2. The compound of claim 1, wherein the aryl group is aryl.

9. X is a divalent unit (X １ ) and R ５ and R ６ is hydrogen and the other is hydrogen or methyl; and Y is m groups CO ２ R ｅ (C １ ~C ４ )-alkyl, and R ｅ is hydrogen or (C １ ~C ６ 9. The compound according to claim 8, wherein m is 1.

10. 2. The compound of claim 1, wherein m is 1 or 2, preferably 1.

11. 2. The compound of claim 1, wherein Q contains one nitrogen atom and zero or one oxygen atoms as ring members and is not a seven-membered heterocycle fused to one or two phenyl rings.

12. Q is a bicyclic or tricyclic aromatic or partially aromatic fused ring system, wherein at least one of the fused rings is a phenyl ring; The ring Q is a ring having k substituents R Ｑ１ and n substituents R Ｑ２ having R Ｑ１ is a halogen, cyano, (C １ ~C ３ )-alkyl, (C １ ~C ３ )-haloalkyl, (C １ ~C ３ )-alkoxy and (C １ ~C ３ )-haloalkoxy, and R Ｑ２ is phenyl-(C １ ~C ３ )-alkyl, (C １ ~C ４ )-alkylcarbonyl, (C １ ~C ４ )-alkylaminocarbonyl, di-(C １ ~C ４ -alkyl)aminocarbonyl, (C １ ~C ４ )-alkoxycarbonyl, benzyloxycarbonyl, fluorenyloxycarbonyl, allyloxycarbonyl or (C １ ~C ３ )-alkoxy-(C １ ~C ３ 2. The compound of claim 1, wherein k is 0, 1, 2 or 3 and n is 0 or 1.

13. Q is a group represented by the formula Q1 to Q16 【Chemistry 3】 (In the formula, In Q1, A is CH ２ , N.R. ｑ , O, S, S(O) or S(O) ２ and B is CH ２ , N.R. ｑ , O, S, S(O) or S(O) ２ and In Q2, A is NR ｑ , O, S, S(O) or S(O) ２ and In Q3, A is CH ２ , C(=O), NR ｑ , O, S, S(O) or S(O) ２ and B is CH ２ , C(=O), NR ｑ , O, S, S(O) or S(O) ２ and In Q4, A is CH ２ , N.R. ｑ , O, S, S(O) or S(O) ２ and B is CH ２ , N.R. ｑ , O, S, S(O) or S(O) ２ and In Q5, A is CH or N; and B is CH ２ , N.R. ｑ , O, S, S(O) or S(O) ２ and In Q6, A is CH or N; and B is CH ２ , N.R. ｑ , O, S, S(O) or S(O) ２ and In Q7, B is CH ２ , N.R. ｑ , O, S, S(O) or S(O) ２ and In Q8, B is CH ２ , N.R. ｑ , O, S, S(O) or S(O) ２ and In Q10, the dashed line represents a single bond or a double bond; A is NR ｑ or O; B is O; and When the dashed line represents a single bond, D represents CH ２ , N.R. ｑ or O; and when the dashed line represents a double bond, it is CH or N; In Q11, the dashed line represents a single bond or a double bond; A is NR ｑ or O; and B is O; In Q12, A is CH or N; and B is CH or N; In Q15, A is CH ２ , C(=O), NR ｑ , O, S, S(O) or S(O) ２ and B is CH ２ , C(=O), NR ｑ , O, S, S(O) or S(O) ２ and In Q16, A is CH ２ , C(=O), NR ｑ , O, S, S(O) or S(O) ２ and R ｑ is hydrogen, (C １ ~C ３ )-alkyl, (C １ ~C ３ )-haloalkyl, (C １ ~C ３ )-alkoxy, (C １ ~C ３ )-haloalkoxy, phenyl-(C １ ~C ３ )-alkyl, (C １ ~C ４ )-alkylcarbonyl or (C １ ~C ４ )-alkoxycarbonyl; and # is NR １ (which is the connection point to is selected from the rings Rings Q1 to Q16 each have k substituents R Ｑ１ having R Ｑ１ is a halogen, cyano, (C １ ~C ３ )-alkyl, (C １ ~C ３ )-haloalkyl, (C １ ~C ３ )-alkoxy and (C １ ~C ３ )-haloalkoxy; k is 0, 1, 2, or 3; 13. The compound of claim 12, wherein Q is preferably a bicyclic fused ring system of formula Q1 to Q13.

14. Q is a bicyclic fused ring system of formula Q1, Q2, Q5 or Q12; Preferably, Q is a bicyclic fused ring system of formula Q1, Q2, Q5 or Q12, where in Q1, A and B are O; and in Q2, A is S, S(O) or S(O). ２ , preferably S(O) ２ and in Q5, A is CH or N and B is NR ｑ , O or S; and in Q12, A and B are CH; rings Q1, Q2, Q5 and Q12 are each independently selected from k substituents R Ｑ１ having R Ｑ１ is a halogen and (C １ ~C ３ )-alkyl; R ｑ is hydrogen or (C １ ~C ３ )-alkyl; and k is 0, 1 or 2.

15. Q is a bicyclic fused ring system of formula Q1 to Q13; rings Q1 to Q13 are each a bicyclic fused ring system of formula Q1 to Q13, each ring containing k substituents R Ｑ１ having R Ｑ１ is a halogen, cyano, (C １ ~C ３ )-alkyl, (C １ ~C ３ )-haloalkyl, (C １ ~C ３ )-alkoxy and (C １ ~C ３ )-haloalkoxy; R ｑ is hydrogen or (C １ ~C ３ )-alkyl; k is 0, 1, 2 or 3; R １ is hydrogen; R ２ is (C １ ~C ６ )-alkyl; R ３ is hydrogen or halogen; R ４ is hydrogen; X is a bond; and Y is Z; Z is a group CO ２ R ｅ is a 5- or 6-membered saturated or partially unsaturated carbocyclic ring substituted by R ｅ is hydrogen or (C １ ~C ６ )-alkyl and m is 1 or 2; or X is a divalent unit (X １ ) and R ５ and R ６ are each independently hydrogen or (C １ ~C ６ )-alkyl; and Y is m groups CO ２ R ｅ (C １ ~C ４ )-alkyl, and R ｅ is hydrogen or (C １ ~C ６ 2. The compound of claim 1, wherein m is 1 or 2.

16. Q is a bicyclic fused ring system of formula Q1, Q2, Q5 or Q12; in Q1, A and B are O; in Q2, A is S, S(O) or S(O) ２ , preferably S(O) ２ and in Q5, A is CH or N and B is NR ｑ , O or S; and in Q12, A and B are CH; rings Q1, Q2, Q5 and Q12 are each independently selected from k substituents R Ｑ１ having R Ｑ１ is a halogen and (C １ ~C ３ )-alkyl; R ｑ is hydrogen or (C １ ~C ３ )-alkyl; k is 0, 1 or 2; R １ is hydrogen; R ２ is methyl or ethyl; R ３ is hydrogen; R ４ is hydrogen; X is a bond; and Y is Z; Z is a group CO ２ R ｅ is a 5-membered partially unsaturated carbocyclic ring substituted by R ｅ is (C １ ~C ６ )-alkyl; or X is a divalent unit (X １ ) and R ５ and R ６ are, independently of one another, hydrogen or methyl; and Y is a group CO ２ R ｅ (C １ ~C ４ )-alkyl, and R ｅ is (C １ ~C ６ 16. The compound of claim 15, wherein the aryl group is aryl.

17. 10. A composition comprising at least one compound according to claim 1 and at least one adjuvant customarily used for formulating crop protection compounds.

18. 20. The composition of claim 17, further comprising an herbicide.

19. Use of a compound according to any one of claims 1 to 16 or a composition according to claim 17 or 18 for controlling undesired vegetation.

20. 19. A method for controlling undesirable vegetation, comprising applying to the plant, its seeds and / or its habitat a herbicidally effective amount of at least one compound according to any one of claims 1 to 16 or a composition according to claim 17 or 18.

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