Surface light-emitting device and display device

Abstract

To provide a surface light-emitting device having good light extraction efficiency even when an LED bare chip is used.SOLUTION: A surface light-emitting device has a support substrate, a light-emitting diode substrate having light-emitting diode elements arranged on a one side surface of the support substrate, and a sealing member which is arranged on the surface on the side of the light-emitting diode elements of the light-emitting diode substrate and seals the light-emitting diode elements. The light-emitting diode elements are bare chips that have a transparent base material composed of an inorganic material, and a light-emitting layer formed on a one side surface of the transparent base material, where the transparent base material is exposed to the surface. The sealing member is brought into contact with a surface opposite to a surface where the light-emitting layer of the transparent base material is formed and side faces. The sealing member has a haze value of 4% or more; its thickness is thicker than thicknesses of the light-emitting diode elements; the sealing member is composed of an olefinic resin; and the sealing member has tensile elastic modulus at room temperature (25°C) of 5.0×107 Pa or more and 1.0×109 Pa or less.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present disclosure relates to a surface-emitting device and a display device using the same. [Background technology]

[0002] In recent years, in the field of display devices, there is a demand for higher quality displays. Display devices using light-emitting diode elements have the advantages of high brightness and high contrast, and have attracted attention, and their development is underway. For example, development of backlights using light-emitting diode elements is underway as backlights for use in liquid crystal display devices. The backlights are also called mini-LED backlights (in the following description, "light-emitting diode" may be referred to as "LED").

[0003] Here, LED backlights are broadly divided into direct-light type and edge-light type. In small and medium-sized display devices such as mobile terminals such as smartphones, edge-light type LED backlights are usually used, but from the standpoint of brightness, the use of direct-light type LED backlights is being considered. On the other hand, in large display devices such as large-screen LCD TVs, direct-light type LED backlights are often used.

[0004] Direct-type LED backlights have a structure in which multiple LED elements are arranged on a substrate. In such direct-type LED backlights, by independently controlling multiple LED elements, it is possible to achieve so-called local dimming, which adjusts the brightness of each area of ​​the LED backlight according to the brightness and darkness of the displayed image. This makes it possible to significantly improve the contrast of the display device and reduce power consumption. [Prior art documents] [Patent documents]

[0005] [Patent Document 1] International Publication No. 2013 / 018902 Summary of the Invention [Problem to be solved by the invention]

[0006] In surface emitting devices such as direct-type LED backlights, a diffusion plate or a transmissive reflector (hereinafter, diffusion member) is arranged above the LED elements in order to suppress unevenness in brightness. In order to suppress unevenness in brightness, it is necessary to arrange the LED elements and the diffusion member apart from each other. For this reason, in the past, pins or spacers have been arranged to maintain a predetermined distance between the LED elements and the diffusion member (for example, Patent Document 1). FIG. 12(a) shows a conventional LED backlight 60 in which a pin 65 is arranged to ensure a distance d between an LED element 63 on a support substrate 62 and a diffusion member 66. FIG. 12(b1) shows a conventional LED backlight 61 in which a spacer 67 is arranged between a support substrate 62 and a diffusion member 66, and FIG. 12(b2) is a schematic plan view of the spacer 67.

[0007] Furthermore, in order to achieve higher definition image quality and to meet the demands of making the display device itself thinner, the LED elements used in the above LED backlights may be so-called bare chips (hereinafter sometimes referred to as LED bare chips), in which the LED elements themselves are not protected by a sealing material or the like.

[0008] Thus, when an LED bare chip is used as an LED element, if the above-mentioned pins or spacers are arranged, there is a problem that the light extraction efficiency of the LED element is not improved significantly.

[0009] The present disclosure has been made in consideration of the above problems, and has as its main object to provide a surface emitting device that has good light extraction efficiency even when using LED bare chips. [Means for solving the problem]

[0010] In order to achieve the above-mentioned object, the inventors conducted intensive research and discovered that the decrease in light extraction efficiency in the bare chip is due to the fact that the transparent base material used in the bare chip, such as sapphire, has a relatively high refractive index, which results in a large difference in refractive index between the transparent base material and the surrounding air.As a result, the reflectance of light emitted from the light-emitting layer is increased at the interface between the transparent base material and the surrounding air, resulting in a decrease in the light extraction efficiency, which led to the invention.

[0011] That is, the present disclosure provides a surface-emitting device having a supporting substrate, a light-emitting diode substrate having a light-emitting diode element arranged on one surface of the supporting substrate, and a sealing member arranged on the surface of the light-emitting diode substrate facing the light-emitting diode element and sealing the light-emitting diode element, wherein the light-emitting diode element is a bare chip having a transparent substrate made of an inorganic material and a light-emitting layer formed on one surface of the transparent substrate, and the transparent substrate is exposed on a surface thereof, the sealing member is in contact with a surface of the transparent substrate opposite to the surface on which the light-emitting layer is formed, and with a side surface, and the sealing member has a haze value of 4% or more and a thickness greater than that of the light-emitting diode element.

[0012] The present disclosure also provides a display device including a display panel and the above-described surface-emitting device disposed on a rear surface of the display panel. Effect of the Invention

[0013] The present disclosure provides an effect of providing a surface emitting device for use in a display device or the like, which has good light extraction efficiency even when an LED bare chip is used. [Brief description of the drawings]

[0014] [Figure 1] 1 is a schematic cross-sectional view illustrating a surface emitting device according to the present disclosure. [Diagram 2] 1 is a schematic cross-sectional view showing an example of an LED bare chip in the present disclosure. [Diagram 3]5A to 5C are process diagrams illustrating an example of a method for forming a sealing member according to the present disclosure. [Figure 4] 3 is a schematic cross-sectional view illustrating the structure of a sealing member of a surface emitting device according to the present disclosure. [Diagram 5] 4 is a schematic cross-sectional view showing an example of a second diffusing member. FIG. [Figure 6] 1 is a schematic cross-sectional view showing an example of a surface emitting device including a second diffusing member according to the present disclosure. [Figure 7] 1 is a graph illustrating a transmitted light intensity distribution. [Figure 8] 3A and 3B are a schematic plan view and a cross-sectional view showing an example of a first embodiment of a reflective structure of a second diffusing member. [Figure 9] 5A and 5B are a schematic plan view and a cross-sectional view showing an example of a second embodiment of the reflective structure of the second diffusing member. [Figure 10] 11 is a schematic cross-sectional view showing another example of the second embodiment of the reflective structure of the second diffusing member. FIG. [Figure 11] FIG. 1 is a schematic diagram illustrating an example of a display device according to the present disclosure. [Figure 12] 1 is a schematic cross-sectional view of a conventional LED backlight. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0015] The following describes the embodiments of the present disclosure with reference to the drawings. However, the present disclosure can be implemented in many different forms, and is not to be interpreted as being limited to the description of the embodiments exemplified below. In addition, in order to make the explanation clearer, the drawings may show the width, thickness, shape, etc. of each member as compared to the embodiments, but these are merely examples and do not limit the interpretation of the present disclosure. In this specification and each figure, the same reference numerals are used to designate elements similar to those described above with respect to the previously-mentioned figures, and detailed descriptions may be omitted as appropriate.

[0016] In this specification, when expressing an aspect in which another component is placed on a certain component, the term "on the face side" is used, unless otherwise specified, to include both a case in which another component is placed directly above or below a certain component so as to be in contact with the certain component, and a case in which another component is placed above or below a certain component with another component in between.

[0017] In addition, in this specification, the terms "sheet," "film," "plate," and the like are not distinguished from one another solely on the basis of differences in name. For example, the term "sheet" is used to include members also known as films and plates. Hereinafter, the surface emitting device of the present disclosure and the display device using the same will be described in detail.

[0018] A. Surface light emitting device The surface-emitting device of the present disclosure is a surface-emitting device having a support substrate, a light-emitting diode substrate having a light-emitting diode element arranged on one surface of the support substrate, and a sealing member arranged on the surface of the light-emitting diode substrate facing the light-emitting diode element and sealing the light-emitting diode element, wherein the light-emitting diode element is a bare chip having a transparent substrate made of an inorganic material and a light-emitting layer formed on one surface of the transparent substrate, the transparent substrate being exposed on a surface thereof, the sealing member being in contact with a surface of the transparent substrate opposite to the surface on which the light-emitting layer is formed, and with a side surface, and the sealing member has a haze value of 4% or more and a thickness greater than a thickness of the light-emitting diode element.

[0019] Fig. 1 is a schematic cross-sectional view showing an example of a surface emitting device of the present disclosure. As illustrated in Fig. 1, the surface emitting device 1 has a support substrate 2, an LED substrate 4 having an LED bare chip 3 arranged on one side of the support substrate 2, a sealing member 5 arranged on the side of the LED substrate 4 facing the LED bare chip 3 and sealing the LED element 3, and a diffusing member 6 arranged on the side of the sealing member 5 opposite the LED substrate 4. The sealing member 5 in the present disclosure has a haze value of 4% or more and a thickness d that is greater than the thickness of the LED element 3.

[0020] As illustrated in FIG. 2, the LED bare ship 3 is composed of a transparent substrate 31 made of sapphire or the like, a light-emitting layer 32 formed on the transparent substrate 31, electrodes 33, 33 that pass current through the light-emitting layer, and a passivation layer 34 that protects the light-emitting layer 33.

[0021] As shown in FIGS. 1 and 2, the sealing member 5 is formed so as to contact the surface of the transparent base material 31 opposite to the surface on which the light emitting layer 32 is formed, and the side surfaces.

[0022] As described above, in the case of using an LED bare chip as an LED element in a conventional surface light emitting device, the side and top of the LED bare chip are in contact with air. In this case, as shown in FIG. 2, depending on the light emission direction from the light emitting layer 32, the light L emitted from the light emitting layer 32 may be reflected by the side of the transparent base material 31 made of sapphire or the like, and may also be reflected by the top surface of the transparent base material 31, and may ultimately be absorbed by the light emitting surface of the light emitting layer 32. For this reason, in such a surface light emitting device, there may be a problem in the efficiency of extracting light from the LED bare chip.

[0023] In the present disclosure, the sealing member 5 is disposed so as to contact the surface of the transparent base material 31 opposite to the surface on which the light emitting layer 32 is formed, i.e., the upper surface, and the side surface of the transparent base material 31, thereby reducing the difference in refractive index with the constituent material of the transparent base material 31 compared to the case where the transparent base material 31 is in contact with air. This makes it possible to reduce the reflectance of the light L emitted from the light emitting layer 32 reflected at the upper surface and side surface of the transparent base material 31, and as a result of repeated reflection, it is possible to reduce the amount of light L absorbed in the transparent base material 31 and the light emitting layer 32, etc. As a result, the surface emitting device of the present disclosure has the effect of being able to improve the extraction efficiency of light from the light emitting layer 32. Hereinafter, the surface emitting device of the present disclosure will be described in detail with respect to each of its components.

[0024] 1. LED board The LED substrate in the present disclosure is a member having a support substrate and a plurality of LED elements arranged on one side of the support substrate. The LED element in the present disclosure is a bare chip (hereinafter sometimes referred to as an LED bare chip) having a transparent substrate made of an inorganic material and a light-emitting layer formed on one side of the transparent substrate, with the transparent substrate exposed on the surface.

[0025] (1) LED bare chip The LED bare chip used in the present disclosure is a member disposed on one side of the support substrate, and functions as a light source. Such an LED bare chip can be, for example, the one illustrated in FIG. 2 above, and has at least a transparent base material and a light-emitting layer, and usually has an electrode for passing electricity through the light-emitting layer. The light emitted by the light-emitting layer is emitted to the outside through the transparent base material.

[0026] a) Transparent base material The transparent substrate used in the LED bare chip is not particularly limited as long as it is generally made of an inorganic material. However, it is preferable that the transparent substrate is one in which crystal growth of the material constituting the light-emitting layer described later is possible. Specifically, sapphire (Al 2 O 3 ), silicon carbide, silicon, etc. Among them, sapphire is preferably used.

[0027] The lower limit of the refractive index of the transparent substrate used in the present disclosure is usually 1.4 or more, preferably 1.5 or more. On the other hand, the upper limit of the refractive index of the transparent substrate is usually 2.5 or less, preferably 2.0 or less. This is because the above-mentioned problems arise when the transparent substrate is made of a material having a refractive index within the above range.

[0028] The refractive index of the transparent substrate can be measured by an Abbe refractometer.

[0029] The transparent substrate is usually shaped like a rectangular parallelepiped or a cylindrical shape, but the surface on the side on which the light-emitting layer is not formed may be shaped so as to reduce the reflectance.

[0030] In the present disclosure, the surface (sometimes referred to as the upper surface) of the transparent substrate opposite to the surface on which the light-emitting layer is formed and the side surface of the transparent substrate are in contact with a sealing member described later. By being disposed in contact with the sealing member in this manner, as described above, it is possible to reduce the reflectance of the light generated from the light-emitting layer at the interface of the transparent substrate, and it is possible to improve the extraction efficiency of the light emitted from the light-emitting layer.

[0031] Here, it is preferable that the upper surface of the transparent base material and the sealing member are in contact with each other over the entire surfaces. Furthermore, there are no particular limitations on the contact between the side surface of the transparent substrate and the sealing member as long as they are in contact, but it is preferable that they are in contact over 90% or more of the area of ​​the side surface, and it is particularly preferable that they are in contact over 99% or more of the area.

[0032] The ratio of the area of ​​the transparent base material that is in contact with the sealing member, that is, the coverage rate by the sealing member, is measured by the following method. First, 10 LED bare chips covered with a sealing material are cut out from the surface light emitting device. Next, the LED bare chips covered with the sealing material are cut using a microtome. The transparent base material of the cut LED bare chips is observed with a scanning electron microscope (SEM) to determine the coverage rate of the sealing material. The average of the determined coverage rates is regarded as the ratio of the area of ​​the transparent base material in contact with the sealing material.

[0033] b) Light-emitting layer The light-emitting layer used in the above LED bare chip is not particularly limited as long as it is a material normally used in LED bare chips, and examples thereof include gallium nitride, indium gallium nitride, aluminum gallium nitride, aluminum gallium arsenide, gallium arsenide phosphide, gallium phosphide, zinc selenide, aluminum gallium indium phosphide, etc.

[0034] When the LED element is in the form of an LED bare chip as disclosed herein, the light-emitting layer may be, for example, a blue light-emitting layer, an ultraviolet light-emitting layer, or an infrared light-emitting layer, because it can emit white light by combining it with a wavelength conversion material.

[0035] In the present disclosure, the blue light emitting layer or the ultraviolet light emitting layer is preferable. The blue light emitting layer can be combined with, for example, a yellow phosphor, or with a red phosphor and a green phosphor to generate white light. The ultraviolet light emitting layer can be combined with, for example, a red phosphor, a green phosphor, and a blue phosphor to generate white light.

[0036] In the present disclosure, it is particularly preferable that the light emitting layer of the LED bare chip is a blue light emitting layer, because this allows the surface emitting device of the present disclosure to emit white light with high luminance.

[0037] c)Other In addition, electrodes, a protective layer (passivation layer), and the like are usually disposed on the LED bare chip.

[0038] The LED bare chips are usually arranged at equal intervals on one side of a supporting substrate, which will be described later. The LED bare chips are arranged so that the transparent base material is on the opposite side to the supporting substrate. In other words, the LED bare chips are arranged in the order of the supporting substrate, the electrodes (if necessary), the light-emitting layer, and the transparent base material.

[0039] The size and arrangement density of the LED bare chips are appropriately selected depending on the application and size of the surface light emitting device of the present disclosure.

[0040] As for the specific size of the LED bare chip, when the LED bare chip is rectangular, the lower limit of the length of one side is preferably 0.01 mm or more, more preferably 0.05 mm or more, and particularly preferably 0.1 mm or more. On the other hand, the upper limit of the length of one side is preferably 2 mm or less, more preferably 1 mm or less, and particularly preferably 0.5 mm or less. When the LED bare chip is circular, elliptical, polygonal, or the like, it is preferable that the maximum diameter is within the above range.

[0041] The small size of the LED bare chips allows the LED bare chips to be arranged at high density, i.e., the interval (pitch) between the LED bare chips can be made small, and the distance between the LED substrate and the diffusion member can be shortened, i.e., the thickness of the sealing member can be made thin, which allows for a thinner and lighter product.

[0042] (2) Support substrate The supporting substrate used in the present disclosure is a member that supports the above-mentioned LED bare chip, sealing member, diffusion member, and the like.

[0043] The supporting substrate may be transparent or opaque. The supporting substrate may be flexible or rigid. The material of the supporting substrate may be an organic material, an inorganic material, or a composite material in which both an organic material and an inorganic material are combined.

[0044] When the material of the support substrate is an organic material, a resin substrate can be used as the support substrate. On the other hand, when the material of the support substrate is an inorganic material, a ceramic substrate or a glass substrate can be used as the support substrate. When the material of the support substrate is a composite material, a glass epoxy substrate can be used as the support substrate. In addition, for example, a metal core substrate can be used as the support substrate. A printed circuit board on which a circuit is formed by printing can also be used as the support substrate.

[0045] The thickness of the supporting substrate is not particularly limited, and is appropriately selected depending on the presence or absence of flexibility or rigidity, the application and size of the surface emitting device of the present disclosure, and the like.

[0046] (3)Other The LED substrate in the present disclosure is not particularly limited as long as it has the above-mentioned support substrate and LED bare chip, and can have a necessary configuration as appropriate. Such configurations can include, for example, a wiring portion, a terminal portion, an insulating layer, a reflective layer, a heat dissipation member, etc. Each configuration can be the same as that used in a known LED substrate.

[0047] The wiring portion is electrically connected to the LED bare chip. The wiring portion is usually arranged in a pattern. The wiring portion can be arranged on a support substrate via an adhesive layer. For example, a metal material or a conductive polymer material can be used as the material of the wiring portion.

[0048] The wiring portion is electrically connected to the electrodes of the LED bare chip by a joint portion corresponding to the electrodes of the LED bare chip. The material of the joint portion may be, for example, a bonding agent having a conductive material such as a metal or a conductive polymer, or a solder.

[0049] A reflective layer can be arranged on the surface of the support substrate on which the LED bare chip is arranged, except for the LED bare chip mounting area. For example, the light reflected by the second layer of the diffusing member can be reflected by the reflective layer of the support substrate and can be made to enter the first layer of the diffusing member again, thereby improving the light utilization efficiency.

[0050] The reflective layer can be the same as the reflective layer generally used in the LED substrate. Specifically, the reflective layer can be a white resin film containing metal particles, inorganic particles or pigment and resin, a metal film, a porous film, etc. The thickness of the reflective layer is not particularly limited as long as it can obtain a desired reflectance, and can be appropriately set. The LED substrate can be formed by a known method.

[0051] 2. Sealing member The sealing member in the present disclosure has a haze value of 4% or more and a thickness greater than that of the LED element. The sealing member is optically transparent and is disposed on the light emitting surface side of the LED substrate.

[0052] (1) Characteristics of sealing materials (a) Haze value The haze value of the sealing member in the present disclosure is 4% or more, preferably 8% or more, more preferably 10% or more, and particularly preferably 12% or more. By setting it in the above range, the heat resistance of the sealing member against heat generation from LEDs and the like can be improved. Furthermore, if it is less than the above value, brightness unevenness cannot be suppressed. On the other hand, the upper limit is not particularly limited, but is, for example, 85% or less, preferably 60% or less, and more preferably 30% or less. By setting it in the above range, light loss in the sealing member is less likely to occur.

[0053] In this specification, the haze value is the value of the sealing member as a whole, and can be measured by cutting the sealing member out of the surface emitting device and using a haze meter (HM-150, manufactured by Murakami Color Research Laboratory) according to a method conforming to JIS K7136:2000.

[0054] The method of adjusting the haze value to obtain the above-mentioned haze value is not particularly limited, but includes a method of utilizing the degree of crystallinity of the resin, a method of changing the content of fine particles in the resin, etc. Among them, the method of adjusting the crystallinity of the resin is preferable. This is because, when the haze value is increased by increasing the crystallinity of the resin, the effect of reducing the straight transmitted light can be obtained.

[0055] (b) Thickness The thickness of the sealing member in the present disclosure may be any thickness as long as it is thicker than the LED element, and specifically, the thickness is preferably 50 μm or more, more preferably 80 μm or more, and particularly preferably 200 μm or more. On the other hand, the thickness of the sealing member is preferably 800 μm or less, more preferably 750 μm or less, and particularly preferably 700 μm or less.

[0056] In this specification, the "thickness" can be measured using a known measurement method capable of measuring sizes on the order of μm. Specifically, a contact-type film thickness measuring device (Mitutoyo thickness gauge 547-301) can be used. The same applies to the measurement of sizes such as "size".

[0057] If the thickness is smaller than the above range, the thickness is insufficient and the light emitted from the LED element cannot be diffused over the entire light-emitting surface, making it impossible to improve the in-plane uniformity of brightness.

[0058] (c) Refractive index The refractive index of the sealing member in the present disclosure is preferably close to the refractive index of the transparent base material of the LED bare chip. Specifically, the lower limit of the refractive index is preferably 1.1 or more, more preferably 1.2 or more, and particularly preferably 1.4 or more. On the other hand, the upper limit of the refractive index is preferably 2.5 or less, more preferably 2.5 or less, and particularly preferably 1.8 or less. The method for measuring the refractive index is the same as that explained in the section on the transparent substrate above, and therefore the explanation thereof will be omitted here.

[0059] (d) Total light transmittance The sealing member in the present disclosure is not particularly limited as long as it can function as a surface emitting device, but it is preferably 70% or more, and more preferably 80% or more. The total light transmittance of the sealing member can be measured, for example, by a method in accordance with JIS K7361-1:1997.

[0060] (2) Sealing material The material contained in the sealing member in the present disclosure is not particularly limited as long as it has the above-mentioned haze value, but is preferably a thermoplastic resin, etc. By using a thermoplastic resin, for example, the haze value can be adjusted to be higher than when a thermosetting resin is used, and further, the sealing member can be formed at a low temperature.

[0061] In addition, when the sealing member contains a thermoplastic resin, a sheet-like sealing member (hereinafter, sometimes referred to as a sealing member sheet) made of a sealing material composition containing a thermoplastic resin can be used. FIG. 3 is a process diagram showing an example of a method for forming a sealing member in the present disclosure. For example, as shown in FIG. 3(a), an LED substrate 4 and a sealing member sheet 5a on one surface are prepared, and the sealing member sheet 5a is laminated on the surface of the LED substrate 4 facing the LED element 3, and then the sealing member sheet 5a is pressed against the LED substrate 4 by, for example, a vacuum lamination method, to form a sealing member 5 sealing the LED element 3, as shown in FIG. 3(b).

[0062] This allows the upper and side surfaces of the transparent base material of the LED element (LED bare chip) 3 to be tightly attached to the sealing member 5.

[0063] When the sealing member contains a curable resin such as a thermosetting resin or a photocurable resin, a liquid sealing material is usually used. When a liquid sealing material is used, the thickness of the end portion may be thicker or thinner than that of the center portion due to surface tension or other factors. In addition, in the case of a curable resin, the volume of the resin may shrink during curing, and as a result, the thickness of the sealing member may become uneven between the center and the end portions after curing. If the thickness of the sealing member is not uniform in this way, brightness unevenness may occur.

[0064] In contrast, when a sheet-like sealing material is used, it is possible to avoid surface irregularities on the sealing member, such as the occurrence of thickness distribution in the coating film due to surface tension and the occurrence of thickness distribution due to thermal or optical shrinkage, which occur when a liquid sealing material is used. Therefore, a sealing member with good flatness can be obtained, and a display device of higher quality can be provided.

[0065] (a) Thermoplastic resin In the present disclosure, examples of the thermoplastic resin that can be used include olefin-based resins, polyvinyl acetate (EVA), and polyvinyl butyral-based resins.

[0066] Among them, the thermoplastic resin is preferably an olefin resin. This is because the olefin resin is particularly unlikely to produce components that deteriorate the LED substrate and has a low melt viscosity, so that the LED element can be well sealed. Among the olefin resins, polyethylene resins, polypropylene resins, and ionomer resins are preferable.

[0067] Here, the polyethylene resin in this specification includes not only ordinary polyethylene obtained by polymerizing ethylene, but also resins obtained by polymerizing a compound having an ethylenically unsaturated bond such as an α-olefin, resins obtained by copolymerizing a plurality of different compounds having an ethylenically unsaturated bond, and modified resins obtained by grafting another chemical species onto these resins.

[0068] In particular, in terms of obtaining the above-mentioned haze value, the sealing member according to the present disclosure has a lower limit of density of 0.870 g / cm 3 It is preferable to use the above polyethylene resin as the base resin, and particularly preferable to use a polyethylene resin having a density of 0.890 g / cm 3 It is preferable that the polyethylene resin used as the base resin is one having a density of 0.930 g / cm or more. 3 The following polyethylene resins are preferably used as the base resin, particularly 0.930 g / cm 3It is preferable to use the following polyethylene-based resin as the base resin: When the sealing member is a multi-layer member as described below, it is preferable to use a polyethylene-based resin having the above density as the base resin for the core layer.

[0069] 4, the core layer refers to a core layer in the case where the sealing member 5 is a multi-layer resin layer including a core layer 51 and a skin layer 52 disposed on at least one surface of the core layer 51. The base resin refers to a resin that occupies 50 parts by mass or more when the total amount of resin components contained in the layer is 100 parts by mass.

[0070] As the α-olefin resin, a silane copolymer (hereinafter also referred to as "silane copolymer") obtained by copolymerizing an α-olefin and an ethylenically unsaturated silane compound as a comonomer can be preferably used. By using such a resin, higher adhesion between the LED substrate and the sealing member can be obtained. As the silane copolymer, the one described in JP 2018-50027 A can be used.

[0071] As the polyethylene-based resin, polyethylene derived from biomass (hereinafter, sometimes referred to as biomass polyethylene) may be used. By using biomass polyethylene, the environmental load of the sealing member can be reduced.

[0072] Biomass-derived ethylene can be produced using biomass-derived ethanol as a raw material. In particular, it is preferable to use biomass-derived fermented ethanol obtained from a plant raw material. The plant raw material is not particularly limited, and any conventionally known plant can be used. Examples of the plant raw material include corn, sugarcane, beet, and manioc.

[0073] Fermented ethanol derived from biomass refers to ethanol produced by contacting a culture solution containing a carbon source obtained from a plant raw material with an ethanol-producing microorganism or a product derived from the crushed microorganism, and then purifying the ethanol. Conventionally known methods such as distillation, membrane separation, and extraction can be applied to purify ethanol from the culture solution. For example, there is a method of adding benzene, cyclohexane, etc., and removing water by azeotropy or membrane separation.

[0074] In recent years, with the growing demand for the creation of a recycling-oriented society, there is a desire to move away from fossil fuels in the materials field, just as there is in energy, and the use of biomass has attracted attention. Biomass is an organic compound that is photosynthesized from carbon dioxide and water, and by using it, it becomes carbon dioxide and water again, making it a so-called carbon-neutral renewable energy. Recently, the practical application of biomass plastics made from these biomass raw materials has progressed rapidly, and attempts are being made to produce various resins from biomass raw materials.

[0075] In the present disclosure, the biomass polyethylene is preferably contained in the sealing member in an amount of 20% by mass or more, and more preferably 50% by mass or more. By setting the amount in the above range, the environmental load can be effectively reduced. Whether or not the sealing material contains biomass polyethylene and its content can be measured in accordance with ISO 16620-2 Method C (AMS method for Carbon-14 (radioactive carbon) analysis).

[0076] (b) Melting point The melting point of the thermoplastic resin used in the present disclosure is not particularly limited as long as it can seal the LED element, but for example, the lower limit of the melting point is preferably 90° C. or higher. On the other hand, the upper limit of the melting point is preferably 135° C. or lower, and more preferably 120° C. or lower. If it is within the above range, it is possible to suppress softening of the sealing member due to heat generation during LED light emission.

[0077] The melting point of the thermoplastic resin can be measured by differential scanning calorimetry (DSC), for example, in accordance with the method for measuring transition temperature of plastics (JISK7121:2012). When multiple thermoplastic resins are included, the melting point is the temperature at the apex of the melting peak with the largest heat of fusion. When the sealing member is a multi-layer member as described below, it is preferable to use a thermoplastic resin as the base resin of the core layer that has the above melting point.

[0078] (c) Melt mass flow rate (MFR) In addition, the thermoplastic resin used in the present disclosure is preferably one that has a melt viscosity that, when heated, enables it to conform to the unevenness of the LED elements and other components arranged on one side of the LED substrate and to penetrate into gaps.

[0079] Specifically, the melt mass flow rate (MFR) of the thermoplastic resin used is preferably 0.5 g / 10 min or more and 40 g / 10 min or less, more preferably 2.0 g / 10 min or more and 40 g / 10 min or less, and even more preferably 2.0 g / 10 min or more and 20 g / 10 min or less. By having the MFR in the above range, it is possible for the resin to penetrate into the gaps between the LED elements and the like, to exhibit sufficient sealing performance, and furthermore, to provide a sealing member having excellent adhesion to the LED substrate.

[0080] In this specification, MFR refers to the value measured at 190°C under a load of 2.16 kg (A method) according to JIS K7210-1:2014. However, for polypropylene resin, MFR refers to the MFR value measured at 230°C under a load of 2.16 kg (A method) according to JIS K7210-1:2014.

[0081] When the sealing member is a multi-layer member as described below, the MFR is measured using the above-mentioned measurement method while all layers are in a multi-layered state in which they are laminated together, and the measured value obtained is the MFR value of the multi-layer sealing member.

[0082] (d) Elastic modulus In addition, the thermoplastic resin in the present disclosure has a tensile modulus of elasticity of 5.0×10 at room temperature (25° C.). 7 Pa or more, 1.0×10 9 It is preferable that the elastic modulus is 100 Pa or less. It is possible to exhibit sufficient adhesion to the LED substrate, and it is a sealing member with excellent impact resistance, for example, when an impact is applied to the surface light emitting device from the outside. When the sealing member is a multi-layer member as described later, it is preferable to use a thermoplastic resin having the above elastic modulus as the base resin of the core layer.

[0083] The above tensile modulus was measured under the following conditions in accordance with JISK7161-1:2014 Plastics - Determination of tensile properties - Part 1: General rules (kikakurui.com). Sample width: 10mm ·Distance between gauge lines: 50mm Pulling speed: 100mm / min As a measuring device, a Tensilon universal material testing machine RTG-1210 (A&D Co., Ltd.) can be used.

[0084] In addition to the above-mentioned thermoplastic resin, additives such as an antioxidant and a light stabilizer may be added to the sealing member.

[0085] (3) Structure of sealing material The sealing member in the surface emitting device of the present disclosure may be a single-layer member in which the sealing member 5 is composed of a single resin layer, as shown in Fig. 1, or may be a multi-layer member in which multiple resin layers (two layers in Fig. 4(a) and three layers in Fig. 4(b)) including a core layer 51 and a skin layer 52 disposed on at least one surface of the core layer 51 are laminated, as shown in Fig. 4. In the present disclosure, any of a single layer, two layers, or three layers is preferable.

[0086] In the case where the sealing member in the present disclosure is a multi-layer member having a two-layer structure including a core layer and a skin layer disposed on the LED substrate side of the core layer, the thickness ratio of the skin layer to the core layer, where the skin layer / core layer is a, is preferably such that the lower limit of a is 0.10 or more, more preferably 0.17 or more, while the upper limit of a is preferably 10 or less, more preferably 2 or less.

[0087] Furthermore, when the sealing member of the present disclosure is a multilayer member having a three-layer structure, when one skin layer is the first skin layer and the other skin layer is the second skin layer, and when the film thickness ratio of the first skin layer to the core layer to the second skin layer is the first skin layer / core layer (b) and the second skin layer / core layer (c), the lower limit of each of b and c is preferably 0.10 or more, and more preferably 0.13 or more. On the other hand, the upper limit is preferably 1.0 or less, and more preferably 0.5 or less.

[0088] When the sealing member in the present disclosure is a multi-layer member, the core layer and the skin layer preferably have, as base resins, the above-mentioned thermoplastic resins having different density ranges, melting points, etc. This is because it becomes easy to ensure the above-mentioned haze value in the core layer while ensuring adhesion and molding properties to the LED substrate in the skin layer.

[0089] In the case of the multilayer member, it is possible to use a material that is usually expensive but has good adhesion and molding properties that allow it to enter into gaps between LED elements, etc., for the skin layer located on the LED substrate side of the multilayer member. In the multilayer member, the material constituting the skin layer located on the LED substrate side is not particularly limited as long as it has high adhesion and high molding properties, but in the case of the thermoplastic resin, it is preferable to use, for example, the above-mentioned silane copolymer. In addition, in the case of the thermoplastic resin, it is also preferable that the material contains the above-mentioned olefin resin and a silane coupling agent. In addition, additives such as antioxidants and light stabilizers may be added to this layer.

[0090] (4) Preferred sealing materials The sealing member in the present disclosure is preferably a multi-layer member composed of a plurality of layers including a core layer and a skin layer disposed on at least one of the outermost surfaces. The core layer has a density of 0.900 g / cm 3 More than 0.930g / cm 3 The following polyethylene resin is preferably used as the base resin: For the skin layer, density 0.875 g / cm 3 More than 0.910g / cm 3 It is preferable to use a polyethylene-based resin having a density of 0.1 to 100 nm or less and a lower density than the base resin for the core layer as the base resin.

[0091] As the base resin for the core layer, low-density polyethylene resin (LDPE), linear low-density polyethylene resin (LLDPE), or metallocene linear low-density polyethylene resin (M-LLDPE) can be preferably used. Among them, from the viewpoint of long-term reliability, low-density polyethylene resin (LDPE) can be particularly preferably used as the base resin for the core layer. Also, as mentioned above, biomass polyethylene may be used.

[0092] The lower limit of the density of the polyethylene resin used as the base resin for the core layer is 0.900 g / cm 3 On the other hand, the upper limit of the density is preferably 0.930 g / cm 3 More preferably, it is 0.920 g / cm 3 By setting the density of the base resin for the core layer in the above range, the haze value of the sealing member in the present disclosure can be set to the above specific value or more. In addition, the sealing member can be provided with necessary and sufficient heat resistance without undergoing a crosslinking treatment.

[0093] The melting point of the polyethylene resin used as the base resin for the core layer is preferably 90°C or more and 135°C or less, and more preferably 90°C or more and 115°C or less. By setting the melting point within the above range, the heat resistance and molding characteristics of the sealing member can be maintained within a preferred range. It is possible to increase the melting point of the sealing member to about 165°C by adding a high melting point resin such as polypropylene to the sealing material composition for the core layer. In this case, the polypropylene is preferably contained in an amount of 5% by mass or more and 40% by mass or less with respect to the total resin components of the core layer.

[0094] The polypropylene contained in the core layer is preferably a homopolypropylene (homoPP) resin. HomoPP is a polymer consisting of only polypropylene alone and has a high degree of crystallinity, and therefore has higher rigidity than block PP or random PP. By using this as an additive resin to the encapsulant composition for the core layer, the dimensional stability of the encapsulating member can be improved. In addition, the homoPP used as an additive resin to the encapsulant composition for the core layer preferably has an MFR of 5 g / 10 min or more and 125 g / 10 min or less at 230° C. and a load of 2.16 kg (A method) measured in accordance with JIS K7210-1:2014. If the MFR is too small, the molecular weight becomes too large and the rigidity becomes too high, making it difficult to ensure the desired sufficient flexibility of the encapsulating material composition, whereas if the MFR is too large, the flowability during heating is not sufficiently suppressed, making it impossible to impart sufficient heat resistance and dimensional stability to the encapsulating material sheet.

[0095] The lower limit of the MFR of the polyethylene resin used as the base resin for the core layer at 190°C and a load of 2.16 kg (A method) is preferably 1.0 g / 10 min or more, more preferably 1.5 g / 10 min or more. On the other hand, the upper limit of the MFR is preferably 7.5 g / 10 min or less, more preferably 6.0 g / 10 min or less. By setting the MFR of the base resin for the core layer within the above range, the heat resistance and molding properties of the sealing member can be maintained within a preferred range. In addition, the processing suitability during film formation can be sufficiently improved, which contributes to improving the productivity of the sealing member.

[0096] The lower limit of the content of the base resin relative to the total resin components of the core layer is preferably 70% by mass or more, and particularly preferably 90% by mass or more. On the other hand, the upper limit of the content of the base resin is preferably 99% by mass or less. As long as the content of the base resin is within the above range, other resins may be contained.

[0097] As the base resin for the skin layer of the sealing member, a low-density polyethylene resin (LDPE), a linear low-density polyethylene resin (LLDPE), or a metallocene linear low-density polyethylene resin (M-LLDPE) can be preferably used, as in the sealing material composition for the core layer. Among them, from the viewpoint of molding characteristics, a metallocene linear low-density polyethylene resin (M-LLDPE) can be particularly preferably used as the sealing material composition for the skin layer. Also, as described above, biomass polyethylene may be used.

[0098] The lower limit of the density of the polyethylene resin used as the base resin for the skin layer is 0.875 g / cm 3 On the other hand, the upper limit of the density of the polyethylene resin is preferably 0.910 g / cm or more. 3 More preferably, 0.899 g / cm 3 By setting the density of the base resin for the skin layer within the above range, the adhesion of the sealing member can be maintained within a preferred range.

[0099] The lower limit of the melting point of the polyethylene resin used as the base resin for the skin layer is preferably 50° C. or higher, and more preferably 55° C. or higher. Meanwhile, the upper limit of the melting point is preferably 100° C. or lower, and more preferably 95° C. or lower. By keeping the melting point within the above range, the adhesion of the sealing member can be further reliably improved.

[0100] The lower limit of the MFR of the polyethylene resin used as the base resin for the skin layer at 190°C and a load of 2.16 kg (method A) is preferably 1.0 g / 10 min or more, more preferably 1.5 g / 10 min or more. On the other hand, the upper limit of the MFR is preferably 7.0 g / 10 min or less, more preferably 6.0 g / 10 min or less. By setting the MFR of the base resin for the skin layer within the above range, the adhesion of the sealing member can be maintained within a more preferable range. In addition, the processability during film formation can be sufficiently improved, contributing to improving the productivity of the sealing member.

[0101] The lower limit of the content of the base resin relative to the total resin components for the skin layer is preferably 60% by mass or more, and particularly preferably 90% by mass or more. On the other hand, the upper limit of the content of the base resin is preferably 99% by mass or less. As long as the content of the base resin is within the above range, other resins may be contained.

[0102] It is more preferable that all the above-described sealing material compositions contain a certain amount of a silane copolymer obtained by copolymerizing an α-olefin and an ethylenically unsaturated silane compound as a comonomer, if necessary. Such a graft copolymer increases the degree of freedom of the silanol group that contributes to the adhesive force, and therefore can improve the adhesiveness of the sealing member to other members.

[0103] The silane copolymer can be, for example, the silane copolymer described in JP-A-2003-46105. By using the silane copolymer as a component of the sealing material composition, it is possible to obtain a sealing member that is excellent in strength, durability, and other properties, and is also excellent in weather resistance, heat resistance, water resistance, light resistance, and other properties, and further has extremely excellent heat fusion properties without being affected by manufacturing conditions such as heat and pressure bonding when arranging the sealing member, and can be obtained stably and at low cost.

[0104] As the silane copolymer, any of random copolymer, alternating copolymer, block copolymer and graft copolymer can be preferably used, but graft copolymer is more preferable, and graft copolymer in which polyethylene for polymerization is main chain and ethylenically unsaturated silane compound is polymerized as side chain is more preferable.Such graft copolymer has high degree of freedom of silanol group that contributes to adhesive force, so that it can improve adhesiveness of sealing member.

[0105] The lower limit of the content of the ethylenically unsaturated silane compound when forming the copolymer of α-olefin and ethylenically unsaturated silane compound is, for example, preferably 0.001% by mass or more, more preferably 0.01% by mass or more, and particularly preferably 0.05% by mass or more, based on the total copolymer mass.On the other hand, the upper limit of the content of the ethylenically unsaturated silane compound is preferably 15% by mass or less, more preferably 10% by mass or less, and particularly preferably 5% by mass or less.When the content of the ethylenically unsaturated silane compound constituting the copolymer of α-olefin and ethylenically unsaturated silane compound is high, mechanical strength and heat resistance are excellent, but when the content is excessive, tensile elongation and heat fusion tend to be inferior.

[0106] The lower limit of the content of the silane copolymer in the encapsulant composition for the core layer relative to the total resin components of the encapsulant composition is preferably 0% by mass or more. On the other hand, the upper limit is preferably 20% by mass or less. The lower limit of the content of the silane copolymer in the encapsulant composition for the skin layer relative to the total resin components of the encapsulant composition is preferably 5% by mass or more. On the other hand, the upper limit is preferably 40% by mass or less. In particular, it is more preferable that the encapsulant composition for the skin layer contains 5% by mass or more of the silane copolymer. The lower limit of the silane modification amount in the silane copolymer is preferably 0.1% by mass or more. On the other hand, the upper limit of the silane modification amount in the silane copolymer is preferably about 2.0% by mass or less. The preferred content range of the silane copolymer in the encapsulant composition is based on the premise that the silane modification amount is within this range, and it is desirable to finely adjust it appropriately according to the variation of this modification amount.

[0107] All layers of the sealing member may contain additives such as antioxidants and light stabilizers. In addition, an adhesion improver can be added as appropriate. By adding an adhesion improver, the adhesion durability with other members can be made higher. As the adhesion improver, a known silane coupling agent can be used, but vinyl trimethoxy silane having a vinyl group, vinyl triethoxy silane, a silane coupling agent having an epoxy group, or a silane coupling agent having a mercapto group can be particularly preferably used.

[0108] (5) Method for forming sealing member As described above, the sealing member in the present disclosure can be formed using a sealing member sheet composed of a sealing material composition containing the above-mentioned thermoplastic resin and other components. The sealing member sheet is prepared by molding an sealing material composition into a sheet shape by a conventionally known method.

[0109] When the sealing member is a multilayer member, a multilayer film having a two-layer structure consisting of a core layer and a skin layer disposed on one surface of the core layer can be formed with a predetermined thickness using each sealing material composition for the core layer and the skin layer, thereby producing a sealing member 5 having a two-layer structure consisting of a core layer 51 and a skin layer 52, for example, as shown in Figure 4(a). Alternatively, a multilayer film having a three-layer structure in which skin layers are disposed on both surfaces of the core layer can be produced, thereby producing a sealing member 5 having a three-layer structure consisting of a skin layer 52, a core layer 51, and a skin layer 52, for example, as shown in Figure 4(b).

[0110] 3. Diffusion material The surface emitting device of the present disclosure may have a diffusing member. The diffusing member is disposed on the surface side of the sealing member opposite to the LED substrate side. The diffusing member is not particularly limited as long as it has a function of diffusing the light emitted from the LED element and uniformly emitting it in the surface direction, and examples of the diffusing member include the following first diffusing member, second diffusing member, and third diffusing member.

[0111] (1) First diffusing member The first diffusion member usually has at least a resin layer in which a diffusion agent is dispersed. The diffusion member may be, for example, a resin sheet in which a diffusion agent is dispersed, or a laminate having a resin layer in which a diffusion agent is dispersed on a transparent substrate, but the former is more preferable. The resin contained in the resin layer is not particularly limited as long as it can disperse the diffusion agent, but is preferably a thermoplastic resin. This is because the diffusion member can be formed using a resin sheet in which a diffusion agent is dispersed, and therefore the flatness can be improved.

[0112] The thermoplastic resin used for the diffusing member is not particularly limited as long as it has high light transmittance, and any resin that is generally used in the field of display devices can be used.

[0113] The material of the diffusing agent is not particularly limited as long as it can diffuse the light from the LED element, and may be, for example, an organic material or an inorganic material. When the material of the diffusing agent is an organic material, for example, polymethyl methacrylate (PMMA) can be mentioned. On the other hand, when the material of the diffusing agent is an inorganic material, for example, TiO 2 , SiO 2 , Al 2 O 3 , silicon, etc.

[0114] The refractive index of the diffusing agent is not particularly limited as long as it can diffuse the light from the LED element, but is, for example, 1.4 or more and 2 or less. Such a refractive index can be measured by an Abbe refractometer. The shape of the diffusing agent can be, for example, particulate. The average particle size of the diffusing agent is, for example, 1 μm or more and 100 μm or less.

[0115] The proportion of the diffusing agent in the diffusing member is not particularly limited as long as it can diffuse the light from the LED element, and is, for example, 40% by weight or more and 60% by weight or less.

[0116] (2) Second diffusion member The second diffusion member is a member having a first layer and a second layer in this order from the LED substrate side, the first layer having light transmittance and light diffusibility, the second layer having a reflectance that increases as the absolute value of the incident angle of light to the surface of the second layer on the first layer side decreases, and a transmittance that increases as the absolute value of the incident angle of light to the surface of the second layer on the first layer side increases. In the present disclosure, by having the above-mentioned diffusion member, it is possible to further improve the in-plane uniformity of luminance and achieve a thin structure. In addition, it is also possible to reduce costs and power consumption.

[0117] The second diffusing member will be described below with reference to the drawings. FIG. 5 is a schematic cross-sectional view showing an example of the second diffusing member. As illustrated in FIG. 5, the diffusing member 11 has a first layer 12 and a second layer 13 in this order. The first layer 12 has light transmissivity and light diffusivity, and transmits and diffuses light L1 and L2 incident from the surface 12A of the first layer 12 opposite to the surface of the first layer 12. The reflectance of the second layer 13 increases as the absolute value of the incident angle of light to the surface 13A of the second layer 13 on the first layer 12 side decreases, and the transmittance increases as the absolute value of the incident angle of light to the surface 13A of the second layer 13 on the first layer 12 side increases. Therefore, the second layer 13 can reflect light L1 incident on the surface 13A of the second layer 13 on the first layer 12 side at a low incident angle θ1, and transmit light L2 incident on the surface 13A of the second layer 13 on the first layer 2 side at a high incident angle θ2. The low incidence angle refers to an incidence angle whose absolute value is small, and the high incidence angle refers to an incidence angle whose absolute value is large.

[0118] Fig. 6 is a schematic cross-sectional view showing an example of a surface emitting device of the present disclosure including the second diffusion member shown in Fig. 5. As illustrated in Fig. 6, a surface emitting device 10 has an LED substrate 4 having LED elements 3 arranged on one surface of a support substrate 2, a sealing member 5 arranged on the surface of the LED substrate 4 facing the LED elements 3 and sealing the LED elements 3, and a diffusion member 11 arranged on the surface of the sealing member 5 opposite the LED substrate 4. The diffusion member 11 is arranged such that a surface 11A on the first layer 12 side faces the sealing member 5.

[0119] As shown in Fig. 5, light incident from surface 11A of diffusing member 11 on the first layer 12 side is diffused by the first layer 12, and light L1 incident at a low incident angle θ1 on surface 13A of second layer 13 on the first layer 12 side of the light transmitted through the first layer 12 and diffused can be reflected by surface 13A of second layer 13 on the first layer 12 side and diffused by being incident again on the first layer 12. Light L2, L2' incident at a high incident angle θ2 on surface 13A of second layer 13 on the first layer 12 side of the light transmitted through the first layer 12 and diffused can be transmitted through the second layer 13 and emitted from surface 11B of diffusing member 11 on the second layer 13 side.

[0120] Furthermore, by combining the first layer and the second layer, light incident from the surface of the diffusing member on the first layer side, particularly light incident from the surface of the diffusing member on the first layer side at a low incident angle, can be diffused by passing through the first layer many times, and can be emitted from the surface of the diffusing member on the second layer side at a high emission angle. Therefore, a surface emitting device (particularly a direct type LED backlight) having such a diffusing member can diffuse the light emitted from the LED elements over the entire light emitting surface, and the in-plane uniformity of brightness can be further improved.

[0121] In addition, by combining the first and second layers, light incident at a low angle from the first layer surface of the diffusing member can be transmitted through the first layer multiple times, making it possible to lengthen the optical path length from when the light enters the first layer surface of the diffusing member until it exits from the second layer surface of the diffusing member. This makes it possible for a portion of the light emitted from the LED element and then exiting from the second layer surface of the diffusing member to be emitted from a position away from the LED element in the in-plane direction, rather than directly above the LED element.

[0122] a) 1st layer The first layer in the present disclosure is a member disposed on one side of the second layer described below, and has light transmissivity and light diffusivity. The light transmissivity of the first layer is, for example, preferably a total light transmittance of 50% or more, more preferably 70% or more, and particularly preferably 90% or more. When the total light transmittance of the first layer is within the above range, the brightness of the surface emitting device of the present disclosure can be increased.

[0123] The total light transmittance of the first layer can be measured, for example, by a method in accordance with JIS K7361-1:1997.

[0124] The light diffusion of the first layer may be, for example, a light diffusion that randomly diffuses light, or a light diffusion that mainly diffuses light in a specific direction. The light diffusion that mainly diffuses light in a specific direction is a property that deflects light, that is, a property that changes the traveling direction of light. When the light diffusion of the first layer is a light diffusion that randomly diffuses light, for example, the diffusion angle of light incident on the first layer may be 10° or more, 15° or more, or 20° or more. In addition, the diffusion angle of light incident on the first layer may be, for example, 85° or less, 60° or less, or 50° or less. When the diffusion angle is within the above range, the in-plane uniformity of the luminance of the surface emitting device of the present disclosure can be further improved.

[0125] Here, the diffusion angle will be explained. Fig. 7 is a graph illustrating the transmitted light intensity distribution, and is a diagram for explaining the diffusion angle. In this specification, the diffusion angle α is defined as the full width at half maximum (FWHM), which is the difference between two angles at which the maximum transmitted light intensity Imax of the light emitted from the other surface of the first layer when light is perpendicularly incident on one surface of the first layer constituting the diffusion member is half.

[0126] The diffusion angle can be measured using a goniophotometer or a goniospectrophotometer. For example, a goniophotometer (GP-200) manufactured by Murakami Color Research Laboratory can be used to measure the diffusion angle.

[0127] The first layer is not particularly limited as long as it has the above-mentioned light transmission and light diffusion properties, and examples thereof include a transmission type diffraction grating, a microlens array, a diffusion agent-containing resin film containing a diffusion agent and a resin, and the like. Specifically, when the first layer has a light diffusion property that mainly diffuses light in a specific direction, examples thereof include a transmission type diffraction grating and a microlens array. On the other hand, when the first layer has a light diffusion property that randomly diffuses light, examples thereof include a diffusion agent-containing resin film. Among them, from the viewpoint of light diffusion properties, a transmission type diffraction grating and a microlens array are preferable. Note that a transmission type diffraction grating is also called a transmission type diffractive optical element (DOE; Diffractive Optical Elements).

[0128] When the first layer is a transmission type diffraction grating, the transmission type diffraction grating is not particularly limited as long as it has the above-mentioned light transmittance and light diffusion. The pitch of the transmission type diffraction grating, etc., is adjusted appropriately as long as the above-mentioned light transmittance and light diffusion are obtained. Specifically, when the wavelength output by the LED element is a single color such as red, green, or blue, it is possible to effectively bend the light from the LED element by setting the pitch according to each wavelength.

[0129] The material constituting the transmission type diffraction grating may be any material that can provide a transmission type diffraction grating having the above-mentioned light transmittance and light diffusion properties, and may be any material that is generally used for transmission type diffraction gratings. The method for forming the transmission type diffraction grating may be the same as the method for forming a general transmission type diffraction grating.

[0130] When the first layer is a microlens array, the microlens array is not particularly limited as long as it has the above-mentioned light transmittance and light diffusion properties. The shape, pitch, size, etc. of the microlenses are appropriately adjusted as long as they can obtain the above-mentioned light transmittance and light diffusion properties. The material constituting the microlens may be a material that can obtain a microlens having the above-mentioned light transmittance and light diffusion properties, and may be a material generally used for a microlens. In addition, the method of forming the microlens may be the same as the method of forming a general microlens.

[0131] When the first layer is a diffusing agent-containing resin film, the diffusing agent-containing resin film is not particularly limited as long as it has the above-mentioned light transmittance and light diffusibility.

[0132] The first layer may have a structure capable of exhibiting light diffusion properties, and may exhibit light diffusion properties in the entire layer, or may exhibit light diffusion properties on a surface. Examples of those that exhibit light diffusion properties on a surface include a relief type diffraction grating and a microlens array. On the other hand, examples of those that exhibit light diffusion properties in the entire layer include a volume type diffraction grating and a resin film containing a diffusing agent. Examples of methods for laminating the first layer and the second layer include a method of bonding the first layer and the second layer via an adhesive layer or a pressure-sensitive adhesive layer, and a method of directly forming the first layer on one surface of the second layer. Examples of methods for directly forming the first layer on one surface of the second layer include a printing method, resin shaping using a mold, and the like.

[0133] b) Second layer The second layer in the present disclosure is a member that is disposed on one side of the first layer, and has an incidence angle dependency of reflectance such that the reflectance increases as the absolute value of the incidence angle of light with respect to the surface of the second layer facing the first layer decreases, and an incidence angle dependency of transmittance such that the transmittance increases as the absolute value of the incidence angle of light with respect to the surface of the second layer facing the first layer increases.

[0134] The second layer has an incidence angle dependency of reflectance such that the reflectance increases as the absolute value of the incidence angle of light on the surface of the second layer on the first layer side decreases. That is, the reflectance of light incident at a low incidence angle on the surface of the second layer on the first layer side is greater than the reflectance of light incident at a high incidence angle on the surface of the second layer on the first layer side. In particular, it is preferable that the reflectance of light incident at a low incidence angle on the surface of the second layer on the first layer side is large.

[0135] Specifically, the lower limit of the regular reflectance of visible light incident on the surface of the second layer on the first layer side at an incident angle within ±60° is preferably 50% or more, more preferably 80% or more, and particularly preferably 90% or more. On the other hand, the upper limit of the regular reflectance of visible light is preferably less than 100%. It is preferable that the regular reflectance of visible light satisfies the above range at all incident angles within the incident angle of ±60°. By having the regular reflectance within the above range, the in-plane uniformity of the luminance of the surface emitting device of the present disclosure can be further improved.

[0136] Furthermore, the lower limit of the average regular reflectance of visible light incident on the surface of the second layer on the first layer side at an incident angle within ±60° is, for example, preferably 80% or more, and more preferably 90% or more. On the other hand, the upper limit of the average regular reflectance is preferably 99% or less, and more preferably 97% or less. The average regular reflectance refers to the average regular reflectance of visible light at each incident angle. By having the average regular reflectance within the above range, the in-plane uniformity of the luminance of the surface emitting device of the present disclosure can be further improved.

[0137] The lower limit of the regular reflectance of visible light incident on the surface of the second layer on the first layer side at an incident angle of 0° (normally incident) is, for example, preferably 80% or more, more preferably 90% or more, and particularly preferably 95% or more. On the other hand, the upper limit of the regular reflectance is preferably less than 100%. By having the regular reflectance in the above range, the in-plane uniformity of the luminance of the surface emitting device of the present disclosure can be further improved.

[0138] In this specification, "visible light" refers to light having a wavelength of 380 nm or more and 780 nm or less. The regular reflectance can be measured using a goniophotometer or a goniospectrophotometer. The regular reflectance can be measured using a goniophotometer (goniophotometer) GP-200 manufactured by Murakami Color Research Laboratory Co., Ltd.

[0139] The second layer has a transmittance dependency on the incident angle such that the transmittance increases as the absolute value of the incident angle of light to the surface of the second layer on the first layer side increases. That is, the transmittance of light incident at a high incident angle to the surface of the second layer on the first layer side is greater than the transmittance of light incident at a low incident angle to the surface of the second layer on the first layer side. In particular, the transmittance of light incident at a high incident angle to the surface of the second layer on the first layer side is preferably large. Specifically, the total light transmittance of light incident at an incident angle of 70° or more and less than 90° to the surface of the second layer on the first layer side is preferably 30% or more, more preferably 40% or more, and particularly preferably 50% or more. It is preferable that the total light transmittance satisfies the above range at all incident angles of 70° or more and less than 90°. In addition, it is preferable that the total light transmittance satisfies the above range when the absolute value of the incident angle is 70° or more and less than 90°. By the total light transmittance being in the above range, the in-plane uniformity of the luminance of the surface emitting device of the present disclosure can be further improved.

[0140] The total light transmittance of the second layer can be measured using a goniophotometer or a goniospectrophotometer according to a method conforming to JIS K7361-1: 1997. For example, an ultraviolet-visible-near infrared spectrophotometer V-7200 manufactured by JASCO Corporation can be used to measure the total light transmittance.

[0141] The second layer is not particularly limited as long as it has the above-mentioned reflectance and transmittance dependence on the incident angle, and various configurations having the above-mentioned reflectance and transmittance dependence on the incident angle can be adopted. Examples of the second layer include a dielectric multilayer film, a reflection structure having a patterned first reflection film and a patterned second reflection film in order from the first layer side, the openings of the first reflection film and the openings of the second reflection film being positioned so as not to overlap in a plan view, and the first reflection film and the second reflection film being spaced apart in the thickness direction, and a reflection type diffraction grating.

[0142] Hereinafter, the case where the second layer is a dielectric multilayer film, a reflecting structure, or a reflecting diffraction grating will be described.

[0143] i) Dielectric multilayer film When the second layer is a dielectric multilayer film, examples of the dielectric multilayer film include a multilayer film of an inorganic compound in which inorganic layers having different refractive indices are alternately laminated, and a multilayer film of a resin in which resin layers having different refractive indices are alternately laminated.

[0144] (Multilayer film of inorganic compounds) When the dielectric multilayer film is a multilayer film of an inorganic compound in which inorganic layers having different refractive indices are alternately stacked, the multilayer film of the inorganic compound is not particularly limited as long as it has the above-mentioned incidence angle dependence of reflectance and transmittance.

[0145] Among the inorganic layers having different refractive indices, the inorganic compound contained in the high refractive index inorganic layer having a high refractive index may have a refractive index of, for example, 1.7 or more, and may be 1.7 or more and 2.5 or less. Examples of such inorganic compounds include those containing titanium oxide, zirconium oxide, tantalum pentoxide, niobium pentoxide, lanthanum oxide, yttrium oxide, zinc oxide, zinc sulfide, or indium oxide as the main component, with small amounts of titanium oxide, tin oxide, cerium oxide, or the like.

[0146] Among the inorganic layers having different refractive indices, the inorganic compound contained in the low refractive index inorganic layer may have a refractive index of, for example, 1.6 or less, and may be 1.2 or more and 1.6 or less. Examples of such inorganic compounds include silica, alumina, lanthanum fluoride, magnesium fluoride, and sodium aluminum hexafluoride.

[0147] The number of stacked high refractive index inorganic layers and low refractive index inorganic layers is adjusted appropriately as long as the above-mentioned reflectance and transmittance are dependent on the incidence angle. Specifically, the total number of stacked high refractive index inorganic layers and low refractive index inorganic layers can be 4 or more. In addition, the upper limit of the total number of stacked layers is not particularly limited, but since the number of stacked layers increases, the number of steps increases, for example, it can be 24 or less.

[0148] The thickness of the inorganic compound multilayer film may be, for example, 0.5 μm to 10 μm, as long as the above-mentioned dependence of reflectance and transmittance on the incidence angle is obtained. Examples of the method for forming the inorganic compound multilayer film include a method in which high refractive index inorganic layers and low refractive index inorganic layers are alternately laminated by a CVD method, a sputtering method, a vacuum deposition method, a wet coating method, or the like.

[0149] (multi-layer resin film) When the dielectric multilayer film is a resin multilayer film in which resin layers having different refractive indices are alternately laminated, the resin multilayer film is not particularly limited as long as it has the above-mentioned incidence angle dependence of reflectance and transmittance.

[0150] Examples of the resin constituting the resin layer include thermoplastic resins and thermosetting resins. Among them, thermoplastic resins are preferred because of their good moldability.

[0151] The resin layer may contain various additives, such as antioxidants, antistatic agents, crystal nucleating agents, inorganic particles, organic particles, viscosity reducers, heat stabilizers, lubricants, infrared absorbers, ultraviolet absorbers, and doping agents for adjusting the refractive index.

[0152] Examples of the thermoplastic resin that can be used include olefin resins, alicyclic polyolefin resins, polyamide resins, aramid resins, polyester resins, polycarbonate resins, polyarylate resins, polyacetal resins, polyphenylene sulfide resins, fluororesins, acrylic resins, methacrylic resins, polyacetal resins, polyglycolic acid resins, and polylactic acid resins.

[0153] Examples of the polyolefin resin include polyethylene, polypropylene, polystyrene, and polymethylpentene. Examples of the polyamide resin include nylon 6 and nylon 66. Examples of the polyester resin include polyethylene terephthalate, polybutylene terephthalate, polypropylene terephthalate, polybutyl succinate, and polyethylene-2,6-naphthalate. Examples of the fluororesin include tetrafluoroethylene resin, trifluoroethylene resin, trifluorochloroethylene resin, tetrafluoroethylene-hexafluoropropylene copolymer, and vinylidene fluoride resin.

[0154] In the present disclosure, among these, polyester is more preferable from the viewpoints of strength, heat resistance, and transparency.

[0155] In this specification, polyester refers to homopolyesters or copolymer polyesters that are polycondensates of dicarboxylic acid component skeletons and diol component skeletons. Examples of homopolyesters include polyethylene terephthalate, polypropylene terephthalate, polybutylene terephthalate, polyethylene-2,6-naphthalate, poly-1,4-cyclohexanedimethylene terephthalate, and polyethylene diphenyl ester. Among them, polyethylene terephthalate is preferred because it is inexpensive and can be used in a wide variety of applications.

[0156] In this specification, the copolymer polyester is defined as a polycondensate consisting of at least three or more components selected from the following components having a dicarboxylic acid skeleton and components having a diol skeleton. Examples of the components having a dicarboxylic acid skeleton include terephthalic acid, isophthalic acid, phthalic acid, 1,4-naphthalenedicarboxylic acid, 1,5-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, 4,4-diphenyldicarboxylic acid, 4,4-diphenylsulfonedicarboxylic acid, adipic acid, sebacic acid, dimer acid, cyclohexanedicarboxylic acid, and ester derivatives thereof. Examples of the components having a glycol skeleton include ethylene glycol, 1,2-propanediol, 1,3-butanediol, 1,4-butanediol, 1,5-pentanediol, diethylene glycol, polyalkylene glycol, 2,2-bis(4-β-hydroxyethoxyphenyl)propane, isosorbate, 1,4-cyclohexanedimethanol, and spiroglycol.

[0157] Among the resin layers having different refractive indices, the difference in the in-plane average refractive index between the high refractive index resin layer and the low refractive index resin layer is preferably 0.03 or more, more preferably 0.05 or more, and even more preferably 0.1 or more. If the difference in the in-plane average refractive index is too small, sufficient reflectance may not be obtained. Here, the in-plane average refractive index is the refractive index in a direction parallel to the surface of the laminated film.

[0158] In addition, the difference between the in-plane average refractive index and the thickness direction refractive index of the high refractive index resin layer is preferably 0.03 or more, and the difference between the in-plane average refractive index and the thickness direction refractive index of the low refractive index resin layer is preferably 0.03 or less. In this case, even if the incident angle increases, the reflectance of the reflection peak is unlikely to decrease.

[0159] As a preferred combination of the high refractive index resin used in the high refractive index resin layer and the low refractive index resin used in the low refractive index resin layer, firstly, the absolute value of the difference in SP value between the high refractive index resin and the low refractive index resin is preferably 1.0 or less. When the absolute value of the difference in SP value is within the above range, interlayer peeling is unlikely to occur. The above SP value is estimated by the Fedors method.

[0160] In this case, it is more preferable that the high refractive index resin and the low refractive index resin have the same basic skeleton. Here, the basic skeleton refers to the repeating unit that constitutes the resin. For example, when one of the resins is polyethylene terephthalate, the basic skeleton is ethylene terephthalate. For example, when one of the resins is polyethylene, the basic skeleton is ethylene. If the high refractive index resin and the low refractive index resin are resins containing the same basic skeleton, peeling between the layers is further prevented.

[0161] Secondly, as a preferred combination of the high refractive index resin used in the high refractive index resin layer and the low refractive index resin used in the low refractive index layer, the difference in glass transition temperature between the high refractive index resin and the low refractive index resin is preferably 20° C. or less. If the difference in glass transition temperature is too large, the thickness uniformity may be poor when forming a laminated film of the high refractive index resin layer and the low refractive index resin layer. In addition, overstretching may occur when forming the laminated film.

[0162] It is also preferred that the high refractive index resin is polyethylene terephthalate or polyethylene naphthalate, and the low refractive index resin is polyester containing spiroglycol. Here, polyester containing spiroglycol refers to a copolyester copolymerized with spiroglycol, a homopolyester, or a polyester blended with them. Polyester containing spiroglycol is preferred because it is less likely to be overstretched during molding and less likely to peel off between layers due to its small difference in glass transition temperature from polyethylene terephthalate or polyethylene naphthalate.

[0163] More preferably, the high refractive index resin is polyethylene terephthalate or polyethylene naphthalate, and the low refractive index resin is a polyester containing spiroglycol and cyclohexanedicarboxylic acid. When the low refractive index resin is a polyester containing spiroglycol and cyclohexanedicarboxylic acid, the difference in in-plane refractive index between the polyester and polyethylene terephthalate or polyethylene naphthalate is large, so that a high reflectance is easily obtained. In addition, the difference in glass transition temperature between the polyester and polyethylene terephthalate or polyethylene naphthalate is small, and the adhesiveness is also excellent, so that the polyester is unlikely to be overstretched during molding, and is unlikely to peel off between layers.

[0164] It is also preferred that the high refractive index resin is polyethylene terephthalate or polyethylene naphthalate, and the low refractive index resin is a polyester containing cyclohexane dimethanol. Here, the polyester containing cyclohexane dimethanol refers to a copolyester copolymerized with cyclohexane dimethanol, a homopolyester, or a polyester blended with them. Polyester containing cyclohexane dimethanol is preferred because it is less likely to be overstretched during molding and less likely to peel off between layers due to its small difference in glass transition temperature from polyethylene terephthalate and polyethylene naphthalate. In this case, it is more preferred that the low refractive index resin is an ethylene terephthalate polycondensate in which the copolymerization amount of cyclohexane dimethanol is 15 mol% or more and 60 mol% or less.

[0165] By doing so, the ethylene terephthalate polycondensate has high reflectivity, but the change in optical properties due to heating or aging is small, and peeling between layers is also unlikely to occur. The ethylene terephthalate polycondensate having the copolymerization amount of cyclohexanedimethanol within the above range adheres very strongly to polyethylene terephthalate. In addition, the cyclohexanedimethanol group has a geometric isomer such as a cis isomer or a trans isomer, and a conformational isomer such as a chair isomer or a boat isomer, so that even when co-stretched with polyethylene terephthalate, it is unlikely to be oriented and crystallized, has a high reflectance, has even less change in optical properties due to heat history, and is unlikely to break during film formation.

[0166] In the above-mentioned resin multilayer film, there may be a portion having a structure in which high-refractive index resin layers and low-refractive index resin layers are alternately laminated in the thickness direction. In other words, it is preferable that the arrangement order of the high-refractive index resin layers and low-refractive index resin layers in the thickness direction is not random, and the arrangement order of the resin layers other than the high-refractive index resin layers and low-refractive index resin layers is not particularly limited. In addition, when the above-mentioned resin multilayer film has a high-refractive index resin layer, a low-refractive index resin layer, and other resin layers, the arrangement order of them is A(BCA), where A is the high-refractive index resin layer, B is the low-refractive index resin layer, and C is the other resin layers. n , A(BCBA) n , A(BABCBA) n It is more preferable that the layers are laminated in a regular sequence such as A(BCA) where n is the number of repeating units. n In the case of n=3, it represents layers stacked in the thickness direction in the order ABCABCABCA.

[0167] The number of layers of the high refractive index resin layer and the low refractive index resin layer may be appropriately adjusted as long as the above-mentioned dependence of the reflectance and the transmittance on the incident angle is obtained. Specifically, the high refractive index resin layer and the low refractive index resin layer may be alternately laminated in 30 layers or more, and may be laminated in 200 layers or more. The total number of layers of the high refractive index resin layer and the low refractive index resin layer may be, for example, 600 layers or more. If the number of layers is too small, sufficient reflectance may not be obtained. In addition, the desired reflectance can be easily obtained by the number of layers being within the above range. In addition, the upper limit of the total number of layers is not particularly limited, but considering the increase in size of the device and the decrease in lamination accuracy due to the number of layers becoming too large, it can be, for example, 1500 layers or less.

[0168] Furthermore, the multilayer film of the resin preferably has a surface layer containing polyethylene terephthalate or polyethylene naphthalate having a thickness of 3 μm or more on at least one side, and more preferably has the above surface layer on both sides. The thickness of the surface layer is more preferably 5 μm or more. By having the above surface layer, the surface of the multilayer film of the resin can be protected.

[0169] Examples of methods for producing the above-mentioned resin multilayer film include a co-extrusion method, etc. Specifically, reference can be made to the method for producing a laminated film described in JP-A-2008-200861.

[0170] As the multilayer film of the above resin, a commercially available laminate film can be used, and specific examples thereof include PICASUS (registered trademark) manufactured by Toray Industries, Inc. and ESR manufactured by 3M.

[0171] ii) Reflective structure The reflective structure has, in order from the first layer side, a patterned first reflective film and a patterned second reflective film, the openings of the first reflective film and the openings of the second reflective film are positioned so that they do not overlap in a planar view, and the first reflective film and the second reflective film are arranged apart in the thickness direction.

[0172] The reflection structure has two aspects. The first aspect of the reflection structure has a transparent substrate, a patterned first reflection film arranged on one surface of the transparent substrate, and a patterned second reflection film arranged on the other surface of the transparent substrate, the openings of the first reflection film and the openings of the second reflection film are positioned so as not to overlap in a plan view, and the first reflection film and the second reflection film are arranged apart in the thickness direction. The second aspect of the reflection structure has a transparent substrate, a patterned convex portion arranged on one surface of the transparent substrate and having light transmission, a patterned first reflection film arranged on the surface opposite to the transparent substrate side of the convex portion, and a patterned second reflection film arranged on the openings of the convex portion on one surface of the transparent substrate, the openings of the first reflection film and the openings of the second reflection film are positioned so as not to overlap in a plan view, and the first reflection film and the second reflection film are arranged apart in the thickness direction. Each aspect will be described below.

[0173] (First embodiment of the reflective structure) A first embodiment of the reflective structure in the present disclosure has a transparent substrate, a patterned first reflective film disposed on one surface of the transparent substrate, and a patterned second reflective film disposed on the other surface of the transparent substrate, the openings of the first reflective film and the openings of the second reflective film being positioned so as not to overlap in a plan view, and the first reflective film and the second reflective film being spaced apart in the thickness direction. In the case of the reflective structure of this embodiment, a first layer is disposed on the surface of the reflective structure facing the first reflective film in the second diffusing member.

[0174] 8(a) and (b) are schematic plan and cross-sectional views showing an example of the reflection structure of this embodiment, in which FIG. 8(a) is a plan view of the reflection structure seen from the surface on the first reflection film side, and FIG. 8(b) is a cross-sectional view of line AA in FIG. 8(a). As shown in FIG. 8(a) and (b), the reflection structure 20 has a transparent substrate 21, a patterned first reflection film 22 arranged on one surface of the transparent substrate 21, and a second reflection film 24 arranged on the other surface of the transparent substrate 21. The openings 23 of the first reflection film 22 and the openings 25 of the second reflection film 24 are positioned so as not to overlap in a plan view. In addition, the first reflection film 22 and the second reflection film 24 are arranged on both sides of the transparent substrate 21, respectively, and are arranged apart in the thickness direction. In FIG. 8(a), the openings of the second reflection film are indicated by dashed lines.

[0175] In such a reflective structure, the patterned first and second reflective films are laminated, and the openings of the first and second reflective films are positioned so as not to overlap in a plan view, so that when a diffusing member having the reflective structure of this embodiment is used in a surface-emitting device, at least one of the first reflective film 22 and the second reflective film 24 is always present directly above the LED element. Therefore, light L11 incident at a low incident angle on the surface of the reflective structure 20 on the first reflective film 22 side, i.e., the surface 13A on the side where the first layer (not shown) of the reflective structure 20 (second layer) is disposed, can be reflected by the first reflective film 22 and the second reflective film 24.

[0176] In addition, since the openings of the first reflecting film and the openings of the second reflecting film are positioned so as not to overlap in a plan view, and the first reflecting film and the second reflecting film are arranged apart in the thickness direction, the light L12, L13 incident at a high incident angle on the surface of the reflecting structure 20 on the first reflecting film 22 side, i.e., the surface 13A on the side on which the first layer (not shown) of the reflecting structure 20 (second layer) is arranged, can be emitted from the opening 23 of the first reflecting film 22 and the opening 25 of the second reflecting film 24. As a result, a part of the light emitted from the LED element and then emitted from the surface on the second layer side of the diffusing member can be emitted from a position away from the LED element in the in-plane direction, rather than directly above the LED element. Therefore, the in-plane uniformity of the luminance can be improved.

[0177] The first and second reflective films may be general reflective films, such as metal films, dielectric multilayer films, etc. The metal film may be made of a metal material used in general reflective films, such as aluminum, gold, silver, and alloys thereof. The dielectric multilayer film may be made of a material used in general reflective films, such as inorganic compound multilayer films in which zirconium oxide and silicon oxide are alternately laminated. The materials contained in the first and second reflective films may be the same or different from each other.

[0178] The pitch of the openings of the first and second reflective films may be set appropriately depending on the light distribution characteristics, size, pitch and shape of the LED elements in the surface emitting device in which the diffusing member of this embodiment is used, the distance between the LED substrate and the diffusing member, etc. The pitch of the openings of the first and second reflective films may be the same or different from each other.

[0179] The pitch of the openings in the first reflective film may be, for example, larger than the size of the LED elements. Specifically, the pitch of the openings in the first reflective film can be set to be not less than 0.1 mm and not more than 20 mm.

[0180] In addition, the pitch of the openings of the second reflective film is not particularly limited as long as it can suppress brightness unevenness, but it is preferably equal to or smaller than the pitch of the openings of the first reflective film, and is preferably smaller than the pitch of the openings of the first reflective film. Specifically, the pitch of the openings of the second reflective film can be 0.1 mm or more and 2 mm or less. By making the pitch of the openings of the second reflective film fine as described above, the pattern of the second reflective film and the openings of the second reflective film can be made difficult to see, and surface emission without unevenness can be achieved.

[0181] The pitch of the openings in the first reflective film refers to the distance P1 between the centers of the openings 23 in the adjacent first reflective film 22, as shown in Fig. 8(a), for example. The pitch of the openings in the second reflective film refers to the distance P2 between the centers of the openings 25 in the adjacent second reflective film 24, as shown in Fig. 8(a), for example.

[0182] The size of the openings of the first and second reflective films is set appropriately according to the light distribution characteristics, size, pitch, and shape of the LED elements, the distance between the LED substrate and the diffusing member, etc., as long as the above-mentioned dependence of reflectance and transmittance on the incident angle is obtained. The size of the openings of the first and second reflective films may be the same or different from each other.

[0183] Specifically, when the opening of the first reflective film has a rectangular shape, the size of the opening can be set to a length of 0.1 mm or more and 5 mm or less.

[0184] The size of the opening of the second reflective film is not particularly limited as long as it can suppress the unevenness of the brightness, but it is preferably equal to or smaller than the size of the opening of the first reflective film, and is preferably smaller than the size of the opening of the first reflective film. Specifically, when the shape of the opening of the second reflective film is rectangular, the length of the opening of the second reflective film can be 0.05 mm or more and 2 mm or less. By making the size of the opening of the second reflective film fine as described above, the pattern of the part of the second reflective film and the part of the opening of the second reflective film can be made difficult to see, and uneven surface emission can be achieved.

[0185] The size of the opening of the first reflective film refers to the length x1 of the opening 23 of the first reflective film 22 when the opening of the first reflective film has a rectangular shape, as shown in Fig. 8(a). The size of the opening of the second reflective film refers to the length x2 of the opening 25 of the second reflective film 24, as shown in Fig. 8(a).

[0186] The shape of the openings of the first and second reflective films can be any shape, such as a rectangle or a circle. The thickness of the first and second reflective films can be adjusted appropriately as long as the above-mentioned incidence angle dependence of the reflectance and transmittance is obtained. Specifically, the thickness of the first and second reflective films can be 0.05 μm or more and 100 μm or less.

[0187] The first and second reflective films may be formed on the surface of a transparent substrate, or may be sheet-shaped reflective films. The method of forming the first and second reflective films is not particularly limited as long as it can form a patterned reflective film on the surface of the transparent substrate, and examples of the method include sputtering and vacuum deposition. In addition, when the first and second reflective films are sheet-shaped reflective films, examples of the method of forming the openings include a method of forming a plurality of through holes by punching or the like. In this case, examples of the method of laminating the transparent substrate and the sheet-shaped reflective film include a method of laminating the sheet-shaped reflective film to the transparent substrate via an adhesive layer or a pressure-sensitive adhesive layer.

[0188] The transparent substrate in the reflective structure of this embodiment is a member that supports the above-mentioned first reflective film and second reflective film, and is also a member for arranging the first reflective film and the second reflective film at a distance from each other in the thickness direction.

[0189] The transparent substrate has optical transparency, and the optical transparency of the transparent substrate is preferably such that the total light transmittance of the transparent substrate is, for example, 80% or more, and more preferably 90% or more. The total light transmittance of the transparent substrate can be measured, for example, by a method in accordance with JIS K7361-1:1997.

[0190] The material constituting the transparent substrate may be any material having the total light transmittance described above, and examples of such materials include resins such as polyethylene terephthalate, polycarbonate, acrylic, cycloolefin, polyester, polystyrene, and acrylic styrene, and glasses such as quartz glass, Pyrex (registered trademark), and synthetic quartz.

[0191] The thickness of the transparent base material is preferably such that the light L12 incident at a high incident angle on the surface of the reflection structure 20 on the first reflection film 22 side, i.e., the surface 13A on the side where the first layer (not shown) of the reflection structure 20 (second layer) is arranged, can be emitted from the opening 23 of the first reflection film 22 and the opening 25 of the second reflection film 24, as shown in FIG. 8(b), and is appropriately set according to the pitch and size of the openings of the first reflection film and the second reflection film, the thickness of the first reflection film and the second reflection film, etc. Specifically, the lower limit of the thickness of the transparent base material can be 0.05 mm or more, and preferably 0.1 mm or more. On the other hand, the upper limit of the thickness can be 2 mm or less, and preferably 0.1 mm or more and 0.5 mm or less.

[0192] (Second embodiment of the reflective structure) A second embodiment of the reflective structure has a transparent substrate, a patterned convex portion having light transparency and disposed on one surface of the transparent substrate, a patterned first reflective film disposed on the surface opposite to the transparent substrate side of the convex portion, and a patterned second reflective film disposed at the opening of the convex portion on one surface of the transparent substrate, the opening of the first reflective film and the opening of the second reflective film being positioned so as not to overlap in a plan view, and the first reflective film and the second reflective film being disposed apart in the thickness direction. In the case of the reflective structure of this embodiment, a first layer is disposed on the surface side of the reflective structure facing the first reflective film in the second diffusing member.

[0193] 9(a) and (b) are schematic plan views and cross-sectional views showing an example of a second embodiment of the reflective structure of the present disclosure, in which FIG. 9(a) is a plan view of the reflective structure seen from the surface on the first reflective film side, and FIG. 9(b) is a cross-sectional view of line AA in FIG. 9(a). As shown in FIG. 9(a) and (b), the reflective structure 20 has a transparent substrate 21, a patterned convex portion 26 having light transmission arranged on one surface of the transparent substrate 21, a patterned first reflective film 22 arranged on the surface opposite to the transparent substrate 21 side surface of the convex portion 26, and a patterned second reflective film 24 arranged at the opening of the convex portion 26 on one surface of the transparent substrate 21. The opening 23 of the first reflective film 22 and the opening 25 of the second reflective film 24 are positioned so as not to overlap in a plan view. In addition, the first reflective film 22 and the second reflective film 24 are separated by the convex portion 26 and arranged apart in the thickness direction.

[0194] In such a reflective structure, the patterned first and second reflective films are laminated, and the openings of the first and second reflective films are positioned so as not to overlap in a plan view, so that in a surface emitting device (particularly, an LED backlight) using a diffusing member having the reflective structure of this embodiment, at least one of the first and second reflective films is always present directly above the LED element. Therefore, as in the first embodiment of the reflective structure, for example, as shown in FIG. 9(b), light L11 incident at a low incident angle on the surface of the reflective structure 20 on the first reflective film 22 side, i.e., the surface 13A on the side where the first layer (not shown) of the reflective structure 20 (second layer) is arranged, can be reflected by the first reflective film 22 and the second reflective film 24.

[0195] In addition, the openings of the first reflecting film and the openings of the second reflecting film are positioned so as not to overlap in a plan view, and the first reflecting film and the second reflecting film are arranged apart in the thickness direction, so that the light L12 incident at a high incident angle on the surface of the reflecting structure 20 on the first reflecting film 22 side, i.e., the surface 13A on the side on which the first layer (not shown) of the reflecting structure 20 (second layer) is arranged, can be emitted from the side surface of the convex portion 26 and the opening 25 of the second reflecting film 24. As a result, a part of the light emitted from the LED element and then emitted from the surface on the second layer side of the diffusing member can be emitted from a position away from the LED element in the in-plane direction, rather than directly above the LED element. Therefore, the in-plane uniformity of the luminance can be improved. In addition, in this embodiment, since the convex portion is provided, self-alignment of the openings of the first reflecting film and the second reflecting film is possible, and the manufacturing cost can be reduced.

[0196] The material of the first reflective film and the second reflective film, the pitch of the openings in the first reflective film and the second reflective film, the size of the openings in the first reflective film and the second reflective film, the shape of the openings in the first reflective film and the second reflective film, the thickness of the first reflective film and the second reflective film, and the method of forming the first reflective film and the second reflective film may be the same as in the first embodiment. Moreover, the transparent substrate may be the same as that of the first embodiment.

[0197] The convex portion in the reflection structure of this embodiment is a member for disposing the first reflection film and the second reflection film at a distance in the thickness direction. The convex portion has light transmittance. The light transmittance of the convex portion is preferably, for example, 80% or more, and more preferably 90% or more. The total light transmittance of the convex portion can be measured, for example, by a method in accordance with JIS K7361-1:1997.

[0198] The material for forming the convex portions may be any material that can form patterned convex portions and has the above-mentioned total light transmittance, and examples of such materials include thermosetting resins and electron beam curable resins.

[0199] The height of the convex portion is preferably such that the light L12 incident at a high incident angle on the surface of the reflection structure 20 on the first reflection film 22 side, i.e., the surface 13A on the side where the first layer (not shown) of the reflection structure 20 (second layer) is arranged, can be emitted from the side surface of the convex portion 26 and the opening 25 of the second reflection film 24, as shown in FIG. 9(b), and is appropriately set according to the pitch and size of the openings of the first reflection film and the second reflection film, the thickness of the first reflection film and the second reflection film, etc. Specifically, the lower limit of the height of the convex portion can be 0.05 mm or more, and preferably 1 mm or more. On the other hand, the upper limit of the height of the convex portion can be 2 mm or less, and preferably 0.5 mm or less.

[0200] The pitch, size and planar shape of the convex portions can be the same as the pitch, size and shape of the openings of the second reflective film. The surface of the convex portions may be a smooth surface as shown in Fig. 9(b), or may be a rough surface as shown in Fig. 10(a). When the surface of the convex portions is a rough surface, the convex portions can be given light diffusibility.

[0201] The shape of the surface of the convex portion may be flat as shown in Fig. 9(b) or curved as shown in Fig. 10(b). When the surface of the convex portion is curved, the convex portion can be provided with light diffusing properties.

[0202] The method for forming the convex portions is not particularly limited as long as it is a method capable of forming patterned convex portions, and examples thereof include a printing method and resin shaping using a mold.

[0203] iii) Reflective diffraction grating When the second layer is a reflective diffraction grating, the reflective diffraction grating is not particularly limited as long as it has the above-mentioned incidence angle dependence of reflectance and transmittance.

[0204] The pitch of the reflective diffraction grating is adjusted as appropriate so long as the above-mentioned reflectance and transmittance are dependent on the incident angle. Specifically, when the wavelength of the LED element is a single color such as red, green, or blue, the light of the LED element can be effectively reflected by setting the pitch according to each wavelength.

[0205] The material constituting the reflective diffraction grating may be any material that can provide a reflective diffraction grating having the above-mentioned incidence angle dependency of reflectance and transmittance, and may be any material that is generally used for reflective diffraction gratings. The method for forming the reflective diffraction grating may be the same as the method for forming a general reflective diffraction grating.

[0206] (3) Third diffusion member The third diffusion member may be, for example, a resin plate having a light-transmitting resin such as polystyrene (PS) or polycarbonate, and may have a large number of voids inside or an uneven surface. Any of the types commonly used in the field of display devices may be used.

[0207] (4) Wavelength conversion material In the surface emitting device of the present disclosure, for example, a wavelength conversion member may be arranged on the side of the diffusing member opposite the LED substrate side, or a wavelength conversion member may be arranged on the LED substrate side of the diffusing member.

[0208] The wavelength conversion member is a member that contains a phosphor that absorbs the light emitted from the LED element and emits excitation light. The wavelength conversion member has the function of generating white light when combined with the LED substrate.

[0209] The wavelength conversion member usually has at least a wavelength conversion layer containing a phosphor and a resin. The wavelength conversion member may be, for example, a wavelength conversion layer alone, or a laminate having a wavelength conversion layer on one side of a transparent substrate. Among them, a wavelength conversion layer alone is preferred from the viewpoint of thinning. More preferably, a sheet-shaped wavelength conversion member is used.

[0210] The phosphor can be appropriately selected according to the color of light emitted from the LED element, and examples thereof include blue phosphor, green phosphor, red phosphor, yellow phosphor, etc. For example, when the LED element is a blue LED element, the phosphor may be a green phosphor and a red phosphor, or a yellow phosphor. Also, when the LED element is an ultraviolet LED element, the phosphor may be a red phosphor, a green phosphor, and a blue phosphor.

[0211] As the phosphor, for example, a phosphor used in a wavelength conversion member of an LED backlight can be used. Also, quantum dots can be used as the phosphor. The content of the phosphor in the wavelength conversion member layer is not particularly limited as long as it can generate the desired white light, and can be the same as the content of the phosphor in the wavelength conversion member of a general LED backlight.

[0212] The resin contained in the wavelength conversion member is not particularly limited as long as it can disperse the phosphor. The resin may be the same as the resin used in the wavelength conversion member of a general LED backlight, and examples of the resin include thermosetting resins such as silicone resins and epoxy resins.

[0213] The thickness of the wavelength conversion member is not particularly limited as long as it can generate the desired white light when used in a surface emitting device, and can be, for example, 10 μm or more and 1000 μm or less.

[0214] (5) Other optical components In the surface emitting device of the present disclosure, for example, an optical member may be further disposed on the side of the diffusing member opposite to the side of the LED substrate. Examples of the optical member include a prism sheet and a reflective polarizing sheet.

[0215] a) Prism sheet The prism sheet in the present disclosure has a function of concentrating incident light and intensively improving the brightness in the front direction. The prism sheet is, for example, a transparent resin substrate on one side of which a prism pattern containing acrylic resin or the like is arranged. As the prism sheet, for example, a brightness enhancement film BEF series manufactured by 3M Company can be used.

[0216] b) Reflective polarizing sheet The reflective polarizing sheet in the present disclosure has a function of transmitting only a first linearly polarized component (e.g., P-polarized light) and reflecting a second linearly polarized component (e.g., S-polarized light) that is orthogonal to the first linearly polarized component without absorbing it. The second linearly polarized component reflected by the reflective polarizing sheet is reflected again and enters the reflective polarizing sheet again in a depolarized state (a state containing both the first linearly polarized component and the second linearly polarized component). Thus, the reflective polarizing sheet transmits the first linearly polarized component of the light that reenters the sheet, and reflects again the second linearly polarized component that is orthogonal to the first linearly polarized component.

[0217] By repeating the above process, about 70% to 80% of the light emitted from the second layer is output as the first linearly polarized light component. Therefore, when the surface-emitting device of the present disclosure is used in a display device, by matching the polarization direction of the first linearly polarized light component (transmission axis component) of the reflective polarizing sheet with the transmission axis direction of the polarizing plate of the display panel, all of the light emitted from the surface-emitting device can be used for image formation on the display panel. Therefore, even if the light energy input from the LED element is the same, it is possible to form an image with higher brightness than when the reflective polarizing sheet is not provided.

[0218] Examples of the reflective polarizing sheet include the DBEF series brightness enhancement film manufactured by 3M Co., Ltd. In addition, examples of the reflective polarizing sheet that can be used include the WRPS high brightness polarizing sheet manufactured by Shinwha Intertek Co., Ltd., wire grid polarizer, and the like.

[0219] 4.Applications The use of the surface emitting device according to the present disclosure is not particularly limited, but it can be suitably used in a display device. It can also be used in a lighting device or the like.

[0220] B.Display device The present disclosure provides a display device including a display panel and the above-described surface-emitting device disposed on a rear surface of the display panel.

[0221] 11 is a schematic diagram showing an example of a display device according to the present disclosure. As shown in the example of FIG. 11, a display device 100 includes a display panel 31 and a surface emitting device 1 according to the present disclosure disposed on the rear surface of the display panel 31.

[0222] According to the present disclosure, by using the above-described surface-emitting device, it is possible to improve the in-plane uniformity of luminance while achieving a thin display device, thereby obtaining a high-quality display device.

[0223] 1. Surface light emitting device The surface emitting device in the present disclosure is similar to that described in the above section "A. Surface emitting device."

[0224] 2. Display panel The display panel in the present disclosure is not particularly limited, and examples thereof include a liquid crystal panel.

[0225] The present disclosure is not limited to the above-described embodiments. The above-described embodiments are merely examples, and anything that has substantially the same configuration as the technical idea described in the claims of the present disclosure and exhibits similar effects is included in the technical scope of the present disclosure. EXAMPLES

[0226] Hereinafter, experimental examples relating to a sealing member will be shown, followed by examples and comparative examples of the present disclosure, to explain the present disclosure in further detail.

[0227] A. Experimental Example (Experimental Example 1) As shown in Fig. 1, a surface emitting device 1 was manufactured having a support substrate 2, a light emitting diode substrate 4 having a light emitting diode element 3, a sealing member A (thickness 450 µm) 5, a diffusing member A 6, and a wavelength conversion member. The haze value, layer structure, density, and transmittance at a wavelength of 450 nm of the sealing member A are shown in Table 1. The evaluation results of brightness unevenness evaluated by the following method are shown in Table 2.

[0228] The materials used are as follows: Light emitting diode board The LED chips B0815ACQ0 (chip size 0.2 mm × 0.4 mm, manufactured by Genelights) were arranged in a square shape with a pitch of 6 mm on a supporting substrate (reflectance 95%). Here, a square arrangement means an arrangement in which the LED chips are arranged in a lattice pattern. Diffusion material A (diffusion plate) 55K3 (made by Entire) Wavelength conversion material (QD) QF-6000 (Showa Denko Materials)

[0229] The thickness of the sealing member and the optical properties shown in Table 1 are values ​​measured on the sealing member sample after sandwiching the sealing member sheet between ETFE films (thickness 100 μm) and performing heat treatment by vacuum lamination. The optical properties were measured by peeling off the ETFE film and measuring only the sealing member sample. The vacuum lamination conditions were as follows.

[0230] (Vacuum lamination conditions) (a) Vacuuming: 5.0 minutes (b) Pressurization: Pressurization was applied from 0 kPa to 100 kPa over 5 seconds. (c) Pressure retention: (100 kPa): 7 minutes (d) Temperature: 150℃

[0231] (Experimental Example 2) The occurrence of luminance unevenness was evaluated in the same manner as in Example 1, except that the following diffusing member B was used instead of the diffusing member A. The results are shown in Table 2. Diffusion material B A second diffusion member having a prism structure in which a prism surface is formed on the light-emitting diode element side as a first layer and a dielectric multilayer film as a second layer.

[0232] (Experimental Examples 3 and 4) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that sealing member B (thickness 450 μm) shown in Table 1 was used instead of sealing member A. The thickness ratio between the skin layer and the core layer was 0.18 when expressed as skin layer / core layer. The above thickness ratio is the same for sealing members D to K shown below.

[0233] (Experimental Examples 5 and 6) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that sealing member D (thickness: 450 μm) shown in Table 1 was used instead of sealing member A.

[0234] (Experimental Examples 7 and 8) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that sealing member E (thickness: 450 μm) shown in Table 1 was used instead of sealing member A. The sealing member E used KS340T (trade name, biomass polyethylene content: 0 mass%) manufactured by Japan Polyethylene Co., Ltd. as the skin layer and SEB853 (trade name, biomass polyethylene content: 95 mass%) manufactured by Braskem Co., Ltd. as the core layer. The biomass polyethylene content of the sealing member was 74 mass%.

[0235] (Experimental Examples 9 and 10) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that sealing member F (thickness: 450 μm) shown in Table 1 was used instead of sealing member A. The sealing member F used KS340T (trade name, biomass polyethylene content: 0 mass%) manufactured by Japan Polyethylene Co., Ltd. as the skin layer and SLL118 (trade name, biomass polyethylene content: 87 mass%) manufactured by Braskem Co., Ltd. as the core layer. The biomass polyethylene content of the sealing member was 68 mass%.

[0236] (Experimental Examples 11 and 12) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that sealing member G (thickness: 450 μm) shown in Table 1 was used instead of sealing member A. The sealing member G used SLL118 (trade name, biomass polyethylene content: 87% by mass) manufactured by Braskem as the skin layer, and Sumikathene L420 (trade name, biomass polyethylene content: 0% by mass) manufactured by Sumitomo Chemical Co., Ltd. as the core layer. The biomass polyethylene content of the sealing member was 19% by mass.

[0237] (Experimental Examples 13 and 14) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that sealing member H (thickness: 450 μm) shown in Table 1 was used instead of sealing member A. The sealing member H used Braskem's SLL118 (trade name, biomass polyethylene content: 87% by mass) as the skin layer and Braskem's SEB853 (trade name, biomass polyethylene content: 95% by mass) as the core layer. The biomass polyethylene content of the sealing member was 93% by mass.

[0238] (Experimental Examples 15 and 16) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that sealing member I (thickness: 450 μm) shown in Table 1 was used instead of sealing member A. The skin layer was used on the LED chip side. The sealing member I used KS340T (trade name, biomass polyethylene content: 0 mass%) manufactured by Japan Polyethylene Co., Ltd. as the skin layer and SEB853 (trade name, biomass polyethylene content: 95 mass%) manufactured by Braskem Co., Ltd. as the core layer. The biomass polyethylene content of the sealing member was 84 mass%.

[0239] (Experimental Examples 17 and 18) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that sealing member J (thickness: 450 μm) shown in Table 1 was used instead of sealing member A. The skin layer was used on the LED chip side. The sealing member J used Braskem's SLL118 (trade name, biomass polyethylene content: 87% by mass) as the skin layer and Braskem's SEB853 (trade name, biomass polyethylene content: 95% by mass) as the core layer. The biomass polyethylene content of the sealing member was 94% by mass.

[0240] (Experimental Examples 19 and 20) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that sealing member K (thickness: 450 μm) shown in Table 1 was used instead of sealing member A. The skin layer was used on the LED chip side. The sealing member K used KS340T (trade name, biomass polyethylene content: 0 mass%) manufactured by Japan Polyethylene Co., Ltd. as the skin layer and SLL118 (trade name, biomass polyethylene content: 87 mass%) manufactured by Braskem Co., Ltd. as the core layer. The biomass polyethylene content of the sealing member was 77 mass%.

[0241] (Comparative Experimental Examples 1 and 2) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that a pin was provided between the diffusing member and the light-emitting diode substrate instead of the sealing member A. The results are shown in Table 2. In this case, the distance between the light-emitting diode element and the diffusing member was 500 μm.

[0242] (Comparative Experimental Examples 3 and 4) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that a Si cured product (thickness: 450 μm) using a highly transparent potting-type liquid silicone composition was provided instead of the sealing material A. The results are shown in Table 2.

[0243] (Comparative Experimental Examples 5 and 6) The occurrence of luminance unevenness was evaluated in the same manner as in Examples 1 and 2, except that sealing member C (thickness: 450 μm) shown in Table 1 was used instead of sealing member A. The results are shown in Table 2.

[0244] [Table 1]

[0245] [Luminance unevenness evaluation method] The brightness of the obtained surface emitting device was measured using a two-dimensional color luminance meter CA2000 when the LED was emitting light, and the brightness unevenness was evaluated. The brightness unevenness index was judged as follows based on the uniformity value.

[0246] [Evaluation Criteria] Uniformity = Minimum front luminance / Maximum front luminance A: Uniformity is 0.9 or more B: Uniformity is 0.8 or more and less than 0.9 C: Uniformity is less than 0.8

[0247] [Table 2]

[0248] The surface-emitting devices (Examples 1 to 20) of the present disclosure were able to suppress the occurrence of brightness unevenness, whereas comparative experimental examples 1 and 2 in which pins were provided instead of sealing member A, comparative experimental examples 3 and 4 in which a cured liquid Si product was used, and comparative experimental examples 5 and 6 in which a sealing member C with a low haze value was used were unable to suppress the occurrence of brightness unevenness.

[0249] B. Working Example Example 1 As shown in FIG. 3(a), an LED substrate was prepared in which an LED bare chip was disposed on a supporting base material. The LED bare chips used were 0815TCQ0 S44D / 45A / B / C / D-4C / 4D / 5A / 5B (0815 model) (manufactured by Genelights).The supporting substrate was a resin substrate on which a reflective sheet (QE59 (manufactured by Toray), 60μm thick, 97% reflectivity) was laminated, with holes drilled to make the LED areas as openings, and the LED bare chips were arranged at 4mm pitch to create an LED substrate.

[0250] By pressing a sealing material sheet onto the above LED substrate as shown in Fig. 3(b), an LED substrate A was produced in which the LED bare chip was sealed with the sealing material as shown in Fig. 3(b). The sealing material used was the sealing material B used in the above experimental example.

[0251] The transparent base material of the LED bare chip was sapphire and had a refractive index of 1.76. The refractive index of the sealing material B was 1.48. The coverage of the surface of the transparent base material of the LED bare chip opposite to the surface on which the light emitting layer was formed and the side surfaces by the sealing material was 100%. The method for measuring the coverage was the same as that explained in the section "A. Surface-emitting device 1. LED substrate (1) LED bare chip a) Transparent substrate."

[0252] Comparative Example 1 An LED substrate B was formed by using the same LED bare chip as in Example 1 and a support substrate on which a reflective sheet was laminated, and by arranging the LED bare chip on the support substrate.

[0253] (evaluation) The LED substrate A sealed with the sealing member and the LED substrate B were used to measure the light extraction efficiency. The measurement method is as follows. The average luminance of a fixed area of ​​30 mm was measured from the front using a two-dimensional color luminance meter CA2000 (Konica Minolta). The distance from the objective lens to the substrate surface was 30 cm.

[0254] As a result of the measurement, the light extraction efficiency of LED substrate A sealed with a sealing member was 110%, assuming that LED substrate B had a light extraction efficiency of 100%.

[0255] In addition, the present disclosure provides, for example, the following inventions.

[0256] [1] a light emitting diode substrate having a support substrate and a light emitting diode element disposed on one surface side of the support substrate; a sealing member disposed on a surface of the light-emitting diode substrate on the side of the light-emitting diode element and sealing the light-emitting diode element, the light-emitting diode element is a bare chip having a transparent base material made of an inorganic material and a light-emitting layer formed on one surface of the transparent base material, the transparent base material being exposed on a surface thereof; the sealing member is in contact with a surface of the transparent substrate opposite to a surface on which the light-emitting layer is formed, and with a side surface; The surface emitting device, wherein the sealing member has a haze value of 4% or more and a thickness greater than a thickness of the light emitting diode element. [2] The surface emitting device according to [1], wherein the sealing member is in contact with 90% or more of the side surfaces of the transparent base material. [3] The transparent substrate is sapphire (Al 2 O 3 ) The surface emitting device according to [1] or [2]. [4] The surface emitting device according to any one of [1] to [3], wherein the sealing member has a thickness of 50 μm or more and 800 μm or less. [5] The surface emitting device according to any one of [1] to [4], wherein the sealing member contains a thermoplastic resin. [6] The sealing member has a density of 0.870 g / cm 3 More than 0.930g / cm 3 A surface emitting device according to any one of [1] to [5], which has the following polyethylene resin as a base resin: [7] The surface emitting device according to any one of [1] to [6], wherein the sealing member has a core layer and a skin layer disposed on at least one surface side of the core layer. [8] The surface emitting device according to any one of [1] to [7], further comprising a diffusion member disposed on a surface of the sealing member opposite the light emitting diode substrate. [9] A display panel; A display device comprising: a surface emitting device according to any one of [1] to [8], which is disposed on a rear surface of the display panel. [Explanation of symbols]

[0257] 1, 10 ... Surface emitting device 2 … Support substrate 3 ... LED element (LED bare chip) 4 ... LED board 5 … Sealing member 6 … Diffusion material 100…Display device

Claims

1. a light emitting diode substrate having a support substrate and a light emitting diode element disposed on one surface side of the support substrate; a sealing member disposed on a surface of the light-emitting diode substrate on the side of the light-emitting diode element and sealing the light-emitting diode element, the light-emitting diode element is a bare chip having a transparent base material made of an inorganic material and a light-emitting layer formed on one surface of the transparent base material, the transparent base material being exposed on a surface thereof; the sealing member is in contact with a surface of the transparent base material opposite to a surface on which the light-emitting layer is formed, and with a side surface; the sealing member has a haze value of 4% or more and a thickness greater than a thickness of the light-emitting diode element; Furthermore, the sealing member is made of an olefin-based resin, The sealing member has a tensile modulus of elasticity of 5.0×10 at room temperature (25° C.). ７ Pa or more, 1.0×10 ９ The surface emitting device has a surface emitting coefficient of thermal expansion (Tc) of 1.0 Pa or less.

2. The surface emitting device according to claim 1 , wherein the sealing member is in contact with 90% or more of the side surfaces of the transparent base material.

3. The transparent substrate is sapphire (Al ２ O ３ 2. The surface emitting device according to claim 1, wherein the surface emitting device comprises:

4. The surface emitting device according to claim 1 , wherein the sealing member has a thickness of 50 μm or more and 800 μm or less.

5. The sealing member has a density of 0.870 g / cm ３ 0.930g / cm or more ３ 2. The surface emitting device according to claim 1, comprising the following polyethylene resin as a base resin:

6. The surface emitting device according to claim 1 , wherein the sealing member has a core layer and a skin layer disposed on at least one surface side of the core layer.

7. The surface emitting device according to claim 1 , further comprising a diffusion member disposed on a surface of the sealing member opposite to the light emitting diode substrate.

8. A display panel; A display device comprising: the surface emitting device according to any one of claims 1 to 7, which is disposed on a rear surface of the display panel.

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