Forward osmosis membrane module and manufacturing method therefor

Abstract

To provide a forward osmosis membrane module configured from a forward osmosis membrane having a separation function layer on a surface of a hollow fiber-like forward osmosis membrane that is excellent in physical durability, and stably exhibits high performance, and a method for manufacturing the same.SOLUTION: Provided a forward osmosis membrane module configured from a plurality of hollow fiber-like forward osmosis membranes. The forward osmosis membrane is provided with a separation function layer on a surface of a hollow fiber support membrane having a porous support body. A membrane area of the forward osmosis membrane module is 0.1 m2 or more. In the porous support body, a void ratio of a compact layer from a boundary face between the porous support body and the separation function layer to 1.0 μm is 40% or less. An average thickness of the separation function layer is 2.0 μm or less, and a variation coefficient of the average thickness of the separation function layer in a radial direction and a lengthwise direction of the forward osmosis membrane module is 30% or less.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present invention relates to a forward osmosis membrane module and a manufacturing method thereof. [Background technology]

[0002] Forward osmosis is known as a method for concentrating a raw liquid. In forward osmosis, the raw liquid and a draw solution having a higher osmotic pressure than the raw liquid are placed adjacent to each other via a forward osmosis membrane, thereby transferring a solvent from the raw liquid to the draw solution. The driving force of forward osmosis is the osmotic pressure difference between the raw liquid and the draw solution. Therefore, unlike existing concentration techniques such as distillation and reverse osmosis, forward osmosis does not require heating or high pressure, and is expected to be able to concentrate the raw liquid without losing valuable components in the raw liquid.

[0003] Forward osmosis is similar to reverse osmosis in that it uses a semipermeable membrane to preferentially pass the solvent over the solute. However, forward osmosis uses an osmotic pressure difference to pass the solvent from the dilute solution (feedstock) to the concentrated solution (draw solution), which differs from reverse osmosis in that it uses pressure on the concentrated solution to counter the osmotic pressure difference to pass water from the concentrated solution to the dilute solution.

[0004] Membranes suitable for forward osmosis are designed to have a large amount of solvent passing from the feed solution to the draw solution (permeability) and a small diffusion of the components in the draw solution into the feed solution (salt back diffusion). However, it is generally not easy to achieve both high permeability and low salt back diffusion, and there is a trade-off between improving one performance and sacrificing the other.

[0005] From the viewpoint of the differences between forward osmosis and reverse osmosis, or from the viewpoint of designing membranes suitable for forward osmosis, composite semipermeable membranes comprising a substrate or support membrane and a separation functional layer provided thereon, and composite semipermeable membrane modules comprising a plurality of composite semipermeable membranes have been proposed.

[0006] For example, Patent Document 1 describes that a composite membrane having a polysulfone membrane with a specific average pore size, average porosity, and metaphenylenediamine diffusivity and a separation functional membrane provided thereon can reduce the economic burden or the burden on waste liquid treatment, and can have both a high salt rejection rate and high water permeability, mainly in reverse osmosis.

[0007] Patent Document 2 describes that in a composite semipermeable membrane comprising a substrate, a porous support provided on the substrate, and a separation functional layer provided on the porous support, the porous support is designed to have a dense layer in contact with the separation functional layer and a macrovoid layer located between the dense layer and the substrate, the major axis and thickness of the pores of the dense layer are controlled, and the macrovoid ratio of the macrovoid layer is controlled, so that the composite semipermeable membrane can maintain water permeability even when operated under high pressure. It is not clear whether the composite semipermeable membrane described in Patent Document 2 is suitable for forward osmosis or reverse osmosis, but it is considered to be suitable for reverse osmosis from the recommended operating pressure and the description of the examples.

[0008] Patent Document 3 describes that in a composite hollow fiber membrane comprising a hollow fiber-shaped porous support membrane and a semipermeable membrane layer containing a crosslinked polyamide polymer formed from a polyfunctional amine compound and a polyfunctional acid halide compound, a gradient is provided in the pore size from one of the inner and outer surfaces of the hollow fiber-shaped porous support membrane to the other, the fractional particle size of the hollow fiber-shaped porous support membrane is adjusted, a crosslinked hydrophilic resin is contained in at least the dense surface having smaller pores of the inner and outer surfaces of the hollow fiber-shaped porous support membrane, and a semipermeable membrane layer is brought into contact with the dense surface of the support layer, thereby enabling separation to be performed favorably in a forward osmosis method and also resulting in excellent durability of the composite hollow fiber membrane.

[0009] In Patent Document 4, from the viewpoints of practicality and durability in actual concentration operations, the salt back-diffusion amount and water permeability under specific conditions are investigated for a forward osmosis membrane having a separating active layer made of a high molecular weight polymer on the surface of a microporous support membrane, and a forward osmosis membrane module incorporating the forward osmosis membrane is also proposed. [Prior art documents] [Patent documents]

[0010] [Patent Document 1] JP 2011-194272 A [Patent Document 2] JP 2018-039003 A [Patent Document 3] International Publication No. 2019 / 131304 [Patent Document 4] International Publication No. 2020 / 241860 Summary of the Invention [Problem to be solved by the invention]

[0011] In forward osmosis treatment, a solvent is present on both the separation function layer side and the porous support membrane side of the forward osmosis treatment device including a composite semipermeable membrane. Therefore, when the forward osmosis treatment device is operating, system pressure may be suddenly applied in a direction that would peel the separation function layer from the porous support membrane, for example, a direction approximately perpendicular to the water permeation direction, a direction approximately parallel to the interface between the separation function layer and the porous support membrane, or a direction opposite to the water permeation direction, which may cause peeling of the separation function layer.

[0012] However, in the past, it was thought that in order to improve the water permeability of the forward osmosis membrane, it was necessary to improve the porosity or surface opening rate inside the porous support membrane. Therefore, in order to demonstrate the practical utility of a forward osmosis treatment device equipped with a forward osmosis membrane module, there remained an issue with the pressure resistance of the forward osmosis membrane module when a positive pressure is applied to the porous support membrane side.

[0013] In addition, even forward osmosis membrane modules, which have been believed to have a certain level of pressure resistance, still have room for improvement in durability. For example, there has been a demand for a forward osmosis membrane and a forward osmosis membrane module including the same that can continue to exhibit high performance while enduring pressure (e.g., 50 kPa or more) that can easily be applied due to the head of the system or erroneous operation.

[0014] Furthermore, a composite forward osmosis membrane obtained by using a hollow fiber membrane as a support membrane and coating its surface with a separation functional layer is often used as a forward osmosis membrane module incorporating multiple composite forward osmosis membranes. If there is variation in the length of each hollow fiber forward osmosis membrane, part or all of the separation functional layer will peel off from the weakest part when pressure is applied, which is a problem in that the module as a whole will not be able to demonstrate high performance.

[0015] In view of the above background, the present invention aims to provide a forward osmosis membrane module composed of a forward osmosis membrane having a separation functional layer on the surface of a hollow fiber forward osmosis membrane, which has excellent physical durability and exhibits stable high performance, and a method for producing the same. [Means for solving the problem]

[0016] The present inventors have found that the above-mentioned problems can be solved by specifying the porosity of the hollow fiber support membrane, the average thickness of the separation functional layer, and the coefficient of variation of the average thickness of the separation functional layer in a forward osmosis membrane module equipped with a composite forward osmosis membrane, and have completed the present invention. Therefore, one example of the embodiment of the present invention is shown below. <1> A forward osmosis membrane module comprising a plurality of hollow fiber forward osmosis membranes, The forward osmosis membrane has a separation functional layer provided on the surface of a hollow fiber support membrane having a porous support, The membrane area of ​​the forward osmosis membrane module is 0.1 m 2 That's all. the hollow fiber support membrane has a dense layer having a porosity of 40% or less at a position up to 1.0 μm in a depth direction from the interface between the porous support and the separation functional layer, The average thickness of the separation functional layer is 2.0 μm or less, and The forward osmosis membrane module, wherein the coefficient of variation of the average thickness of the separation functional layer in the radial direction and the longitudinal direction of the forward osmosis membrane module is 30% or less. <2> 2. The forward osmosis membrane module according to item 1, wherein the coefficient of variation of the average thickness of the separation functional layer is 25% or less. <3> 3. The forward osmosis membrane module according to item 1 or 2, wherein the coefficient of variation of the average thickness of the separation functional layer is 20% or less. <4> 4. The forward osmosis membrane module according to any one of items 1 to 3, wherein the separation functional layer has an uneven structure. <5> 5. The forward osmosis membrane module according to any one of items 1 to 4, wherein the dense layer has a porosity of 5% or more. <6> 6. The forward osmosis membrane module according to any one of items 1 to 5, wherein the dense layer has a porosity of 9% or more and 25% or less. <7> 7. The forward osmosis membrane module according to any one of items 1 to 6, wherein the separation functional layer has an average thickness of 0.05 μm or more. <8> 8. The forward osmosis membrane module according to any one of items 1 to 7, wherein the average thickness of the separation functional layer is 0.2 to 0.8 μm. <9> 9. The forward osmosis membrane module according to any one of items 1 to 8, wherein the dense layer has a separation functional layer component that has entered into the pores of the dense layer. <10> 10. The forward osmosis membrane module according to any one of items 1 to 9, wherein the separation functional layer is provided on the inner surface of the hollow fiber support membrane. <11> 11. The forward osmosis membrane module according to any one of items 1 to 10, wherein the hollow fiber support membrane is composed only of the porous support and the separation functional layer. <12> 12. The forward osmosis membrane module according to any one of items 1 to 11, wherein the porous support contains polysulfone or polyethersulfone as a main component. <13> The process is as follows: (I) a separation function layer forming step of providing a separation function layer on a surface of a hollow fiber support membrane having a porous support to prepare a hollow fiber forward osmosis membrane module having a hollow fiber forward osmosis membrane; (II) a liquid sealing step of sealing and holding a liquid at least on the surface side of the hollow fiber forward osmosis membrane module on which the separation functional layer is formed; (III) a heat treatment step of heating the hollow fiber forward osmosis membrane module and the liquid to 50° C. or higher; A method for producing a forward osmosis membrane module, comprising: <14> The membrane area of ​​the forward osmosis membrane module is 0.1 m 2 Item 14. The method for producing a forward osmosis membrane module according to Item 13. <15> Item 15. The method for producing a forward osmosis membrane module according to Item 13 or 14, wherein in the separation function layer formation step (I), the hollow fiber support membrane has a dense layer at a position up to 1.0 μm in a depth direction from the interface between the porous support and the separation function layer, and the dense layer has a porosity of 40% or less. <16> Item 16. The method for producing a forward osmosis membrane module according to item 15, wherein in the separation functional layer forming step (I), the dense layer has a porosity of 10 to 40%. <17> 17. The method for producing a forward osmosis membrane module according to any one of items 13 to 16, wherein in the separation functional layer forming step (I), the porous support contains polysulfone or polyethersulfone as a main component. <18> In the separation functional layer forming step (I), The separation functional layer is a membrane containing a polymer of at least one first monomer selected from polyfunctional amines and at least one second monomer selected from polyfunctional acid halides; and forming a liquid membrane of a first solution containing one of the first monomer and the second monomer on the inner surface of the hollow fiber support membrane, and then creating a pressure difference between the inside and outside of the hollow fiber support membrane such that (inner pressure)>(outer pressure), and then contacting a second solution containing the other of the first monomer and the second monomer with the liquid membrane of the first solution; Item 18. A method for producing a forward osmosis membrane module according to any one of Items 13 to 17. <19> Item 19. The method for producing a forward osmosis membrane module according to Item 18, wherein the pressure difference is generated by reducing pressure on the outside of the hollow fiber support membrane. <20> Item 19. The method for producing a forward osmosis membrane module according to Item 18, wherein the pressure difference is generated by applying different pressures to both the outside and the inside of the hollow fiber support membrane. <21> 21. The method for producing a forward osmosis membrane module according to any one of items 18 to 20, wherein the pressure difference is 10 to 90 kPa. <22> 22. The method for producing a forward osmosis membrane module according to any one of items 13 to 21, wherein in the liquid sealing step (II), the liquid is placed and held inside and outside the hollow fiber forward osmosis membrane. <23> 23. The method for producing a forward osmosis membrane module according to any one of items 13 to 22, wherein in the liquid sealing step (II), the liquid is filled and retained in the hollow fiber forward osmosis membrane by pressurizing the liquid. <24> 24. The method for producing a forward osmosis membrane module according to any one of items 13 to 23, wherein in the liquid sealing step (II), the liquid is water. <25> 25. The method for producing a forward osmosis membrane module according to any one of items 13 to 24, wherein in the liquid sealing step (II), the forward osmosis membrane module is immersed in the liquid. <26> 25. The method for producing a forward osmosis membrane module according to any one of items 13 to 24, wherein in the liquid sealing step (II), the liquid is sealed in the forward osmosis membrane module. <27> 27. The method for producing a forward osmosis membrane module according to any one of items 13 to 26, wherein in the heat treatment step (III), the forward osmosis membrane module and the liquid are heated to 100° C. or higher. <28> 28. The method for producing a forward osmosis membrane module according to any one of items 13 to 27, wherein in the heat treatment step (III), the forward osmosis membrane module and the liquid are heated to 121° C. or higher. <29> 29. The method for producing a forward osmosis membrane module according to any one of items 13 to 28, wherein in the heat treatment step (III), the forward osmosis membrane module and the liquid are heated to a temperature in the range of 145° C. or lower. <30> 30. The method for producing a forward osmosis membrane module according to any one of items 13 to 29, wherein the heat treatment step (III) comprises continuing to raise the temperature under pressure in a temperature range equal to or higher than the boiling point of the liquid. Effect of the Invention

[0017] According to the present invention, it is possible to provide a forward osmosis membrane module that is excellent in physical durability and exhibits stable high performance, and a method for producing the same. [Brief description of the drawings]

[0018] [Figure 1] FIG. 1 is a schematic cross-sectional view of one embodiment of a forward osmosis membrane module. [Diagram 2] FIG. 2 is a schematic diagram showing an example of the configuration of an apparatus for forming a separation functional layer on a porous support membrane module. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0019] Hereinafter, an embodiment of the present invention (hereinafter, referred to as "the present embodiment") will be described in detail as a non-limiting example.

[0020] <Forward osmosis membrane module> The forward osmosis membrane module according to the present embodiment can be suitably used for concentrating, for example, liquid food or pharmaceutical solutions. By using the forward osmosis membrane according to the present embodiment, the object to be concentrated can be concentrated at a high rate without heating, and furthermore, non-heating high-concentration is possible, which prevents deterioration of components or inclusion of foreign matter while highly suppressing the outflow or inflow of solutes. Furthermore, the forward osmosis membrane module according to the present embodiment can be suitably used for, for example, desalination of seawater, desalination of brackish water, treatment of produced water discharged from gas fields such as shale gas or oil fields, concentration of fertilizer solutions, or dilution applications using a desired concentrate as a draw solution, in addition to applications such as dehydration.

[0021] The forward osmosis membrane of this embodiment has a separation functional layer provided on the surface of a hollow fiber support membrane having a porous support body, and more specifically, is composed of a separation functional layer composed of a semipermeable membrane that allows only specific substances to pass through, and a porous support membrane that physically supports the separation functional layer on the surface of the hollow fiber support membrane, specifically the inner surface or outer surface.

[0022] The forward osmosis membrane module of this embodiment is composed of a plurality of hollow fiber forward osmosis membranes. The hollow fiber forward osmosis membranes have a separation function layer provided on the surface of a hollow fiber support membrane having a porous support, and the membrane area of ​​the forward osmosis membrane module is 0.1 m. 2 That's all, and from a practical standpoint, 0.1m 2 More than 1,000m 2 The membrane area is preferably less than or equal to the above. Details of the membrane area will be described later.

[0023] In order to prevent the separation functional layer formed on the surface of the hollow fiber support membrane from being damaged during contact with guide rolls, handling during module formation, etc., the forward osmosis membrane module of this embodiment is preferably produced by first modularizing the porous hollow fiber support membrane and then forming the separation functional layer on the inside or outside of the hollow fiber support membrane. By going through such a process, it is possible to prevent the formed separation functional layer from being damaged.

[0024] The larger the water permeability of the forward osmosis membrane module of the present embodiment, the more preferable it is. However, in order to secure the same or higher water permeability as currently commercially available membranes using a module with the same space occupancy volume, a water permeability of 4 kg / (m 2 In addition, when the raw water to be treated is passed through under conditions with as little pressure loss as possible, the raw water must be dried up and sedimentation must be avoided, so the permeability must be 200 kg / (m 2 × hr) or less. In this embodiment, the water permeability of the forward osmosis membrane can be measured by the method described in the Examples.

[0025] In this specification, the water permeability of a hollow fiber membrane module means the amount of water that moves from the raw water to be treated to a draw solution due to osmotic pressure when the raw water and a draw solution having a higher concentration are placed across a forward osmosis membrane, and is expressed by the following formula (1): F = L / (M × H) (1) {where F is the water permeability (kg / (m 2 × hr), L is the amount of water permeated (kg), and M is the internal surface area of ​​the membrane (m 2 ), H is time (hr)} It is defined by:

[0026] It is preferable that the back diffusion of salt (salt back diffusion amount) in the forward osmosis membrane module of this embodiment is as small as possible. If the back diffusion of salt is large, it may cause contamination of the raw water or lead to a loss of the derived solute. From this viewpoint, the back diffusion of salt in the forward osmosis membrane module of this embodiment is set to be as small as possible based on the above-mentioned water permeation amount (kg / m 2 / hr), the reverse diffusion of salt in the forward osmosis membrane is preferably 0.1% or less, more preferably 0.05% or less, and even more preferably 0.02% or less. In this embodiment, the reverse diffusion of salt in the forward osmosis membrane can be measured by the method described in the Examples.

[0027] In this specification, the back diffusion of salt in a forward osmosis membrane module refers to the amount of salt that moves from the draw solution to the raw water to be treated when the raw water and the draw solution having a higher concentration are placed across the forward osmosis membrane, and is expressed by the following mathematical formula (2): RSF = G / (M × H) (2) where RSF is the back diffusion of salt (g / (m 2 × hr), G is the amount of salt that permeates (g), and M is the membrane area (m 2 ), H is time (hr)} It is defined by:

[0028] The draw solution is a solution that exhibits a higher osmotic pressure than the raw water containing the substances to be separated and has the function of moving water from the raw water through a semipermeable membrane. This draw solution exhibits a high osmotic pressure by containing a high concentration of a draw solute.

[0029] The derivative solute may be, for example: Salts that are readily soluble in water, such as sodium chloride, potassium chloride, sodium sulfate, sodium thiosulfate, sodium sulfite, ammonium chloride, ammonium sulfate, and ammonium carbonate; Alcohols such as methanol, ethanol, 1-propanol, and 2-propanol; Glycols such as ethylene glycol and propylene glycol; Polymers such as polyethylene oxide and propylene oxide; Copolymers of the monomers constituting the above polymers; etc.

[0030] The hollow fiber support membrane in this embodiment has a porous support, which may be a membrane for supporting the separation functional layer, and preferably does not itself exhibit substantial separation performance for the object to be separated. Any porous support may be used, including a known microporous hollow fiber support membrane.

[0031] From the viewpoint of stably achieving high performance in the forward osmosis membrane module and excellent physical durability, the hollow fiber support membrane preferably has the above-mentioned separation functional layer on its inner surface and / or is preferably composed of only a porous support and a separation functional layer, and more preferably does not include a substrate such as a nonwoven fabric in the constituent members. When the substrate is not included, there is no concern that the substrate will peel off or crack from the porous support due to insufficient adhesion or difference in dimensional change due to temperature at the interface between the porous support and the substrate when subjected to high temperature loading. This tendency is more pronounced at higher temperatures. In general, the substrate is often a porous body with a pore size larger than that of the porous support or the separation functional layer, and further often contains a material different from that of the porous support as a main component. The pore size of the substrate is generally about 0.1 μm to 100 μm, and is more generally evaluated by basis weight or air permeability, with a basis weight of 20 g / m 2 ~150g / m 2 The air permeability measured by the Frazier method is about 0.5cc / (cm 2 ×sec)~30cc / (cm 2 × sec).

[0032] The hollow fiber support membrane in this embodiment has a dense layer with a porosity of 40% or less at a position up to 1.0 μm in the depth direction from the interface between the porous support and the separation functional layer. The forward osmosis membrane module tends to suppress peeling of the separation functional layer even if a system pressure or a back pressure is applied in a direction different from the stacking direction of the forward osmosis membrane (generally meaning the membrane thickness direction) during module operation due to the dense layer with a specific porosity in this way, and thus has excellent physical durability while exhibiting stable high performance. Furthermore, if the dense layer has a porosity in this range, it is easy to reduce the average thickness of the separation functional layer described later, and as a result, the forward osmosis performance can be improved. In terms of being able to ensure adhesion while uniformly distributing pressure and being more susceptible to the effects of the heat treatment process described later, the porosity of the dense layer is more preferably 25% or less, and even more preferably 20% or less. More specifically, the forward osmosis membrane module according to the present embodiment is practical because the module as a whole can withstand the pressure (i.e., back pressure) on the side peeling off the separation functional layer and has high forward osmosis performance (i.e., high water permeability flux and low salt reverse diffusion RSF). From the viewpoint of ensuring forward osmosis performance, particularly water permeability, the porosity of the dense layer is preferably 5% or more, more preferably 5 to 40%, and particularly preferably 9 to 25%. When the porosity of the dense layer is within the above numerical range, the dense layer into which the separation functional layer is embedded is easily formed, and the above-mentioned adhesion is more easily ensured. Furthermore, by heating the forward osmosis membrane in which the separation functional layer is embedded in the dense layer in the presence of a liquid described later, the reaction (crosslinking reaction, etc.) of the separation functional layer is promoted in the pores of the dense layer, and the adhesion is particularly enhanced. This effect tends to be promoted more as the temperature during the heat treatment is higher.

[0033] The porosity can be calculated, for example, using an image obtained by a microscope. In the case of a cross-sectional image obtained using a scanning electron microscope, for example, a specimen can be prepared and observed as follows. The membrane sample is immersed in pure water, frozen using liquid nitrogen, and then dried by freeze-drying. The dried sample is cut or cut by broad ion beam (BIB) processing, preferably by BIB processing, to prepare a cross section perpendicular to the membrane surface direction. The obtained cross section is thinly coated with platinum, platinum / palladium, osmium tetroxide, or osmium, preferably osmium, to prepare an observation sample. The cross section of the observation sample is observed at an acceleration voltage of 1 to 6 kV, preferably 1 kV. The observation magnification may be any magnification that allows observation of the contact interface between the porous support and the separating functional layer, or the vicinity of the surface of the support membrane, and is preferably 5,000 to 100,000 times, and more preferably 50,000 times.

[0034] In this embodiment, the contact interface between the porous support of the forward osmosis membrane and the separating functional layer can be specifically confirmed, for example, as follows. An example of the method is to import an image of a cross section of a forward osmosis membrane taken by a scanning electron microscope into a suitable image processing software and process the image. An example of the image processing software is ImageJ (developed by the National Institutes of Health, USA). The SEM image imported into ImageJ is binarized by a known binarization method, preferably Otsu's method, appropriately selected based on the obtained image. In the entire binarized image obtained, the average brightness in the horizontal direction to the membrane surface is calculated for each predetermined distance (for example, 1 pixel) from the membrane surface toward the depth direction. The average brightness is compared from the surface of the separation functional layer toward the support membrane side, and the horizontal direction of the part with the highest average brightness can be the contact interface between the porous support of the forward osmosis membrane and the separation functional layer. Furthermore, even if the contact interface between the porous support of the forward osmosis membrane and the separation functional layer is wavy, the contact interface between the porous support of the forward osmosis membrane and the separation functional layer can be unambiguously identified by the above-mentioned method, unless the forward osmosis membrane is intentionally bent for observation. In addition, some porous supports may have macrovoids near the surface. A macrovoid is a void (large gap) with a long diameter of 1.0 μm or more. When a cross-sectional image having a macrovoid is binarized, the pore structure seen in the void (the structure seen further inside the cross-sectional image) may be selected instead of the void itself. In this embodiment, since the pore structure from the interface between the porous support and the separation functional layer to 1.0 μm in the depth direction is important, in an image in which a macrovoid exists, it is preferable to paint the macrovoid black before binarizing.

[0035] In general, the dense layer into which the separation functional layer has entered is naturally formed in the form that the separation functional layer component enters the pores of the porous support when interfacial polymerization is performed on the porous support using the interfacial polymerization method described later. The thickness of the region can be, for example, a thickness of 1 to 250 nm from the contact interface between the porous support and the separation functional layer. In this embodiment, in the thickness direction of the forward osmosis membrane, the separation functional layer component is preferably entered into the pores of the porous support by 1 nm or more, more preferably 10 nm or more, even more preferably 30 nm to 250 nm, and particularly preferably 40 nm to 200 nm. In addition, if the separation functional layer component enters the pores of the porous support in the thickness direction to a range of up to 250 nm, a dense layer in which the separation functional layer has entered the pores can be formed by a method of impregnating the porous support with a first monomer solution and then applying a second monomer solution in the interfacial polymerization method described later. In particular, by using a method in which the first monomer solution described below is permeated into the porous support and then the pressure is reduced to allow the solution to further permeate into the porous support, the permeation range can be expanded and controlled further beyond the above-mentioned thickness direction range.

[0036] More specifically, the dense layer in which the separation functional layer has penetrated into the pores can be confirmed, for example, by using an image obtained by the above-mentioned microscope. When the separation functional layer can be confirmed visually, the length from the contact interface between the porous support of the forward osmosis membrane and the separation functional layer to the end of the penetration of the separation functional layer can be regarded as the thickness of the dense layer in which the separation functional layer has penetrated.

[0037] As a simple example, when a scanning electron microscope image taken at 50,000x magnification is observed from the contact interface between the dense layer and the separation functional layer to 1.0 μm in the depth direction, and the depth direction is divided into 20 parts at 0.05 μm each, in the divided dense layers until the porosity of each of the 20 divided dense layers (divided dense layers) is 0.25 times or more the porosity up to 1.0 μm, the length from the depthwise end of the divided dense layer to the contact interface between the porous support and the separation functional layer can be defined as the thickness of the dense layer region into which the separation functional layer has penetrated.

[0038] From the same viewpoint as above, the inner surface of the hollow fiber support membrane preferably has micropores with a pore size of 0.001 μm or more and 0.1 μm or less, more preferably 0.003 μm or more and 0.05 μm or less, and even more preferably 0.003 μm or more and 0.01 μm or less.

[0039] On the other hand, in the position of the porous support more than 1.0 μm in the depth direction from the interface between the porous support and the separation functional layer, for example, at the position up to the outer surface, in order to reduce the permeation resistance of the permeating fluid, it is preferable that the structure of the porous support is as sparse as possible while maintaining strength. The sparse structure in this portion is preferably, for example, a net-like structure, a finger-like void structure, or a mixed structure thereof.

[0040] In this embodiment, the permeability, which is expressed by the amount of pure water that permeates a certain effective membrane area (e.g., inner surface area or outer surface area) in a certain time when a certain pressure is applied to the hollow fiber support membrane, is preferably 100 kg / m 2 / hr / 100kPa or more, preferably 200kg / m 2 If the permeability of the support membrane is too low, the permeability of the obtained hollow fiber forward osmosis membrane module is also likely to be low.

[0041] The permeability of the support membrane is preferably as high as possible without impairing the mechanical strength of the support membrane. Generally, the higher the permeability, the lower the mechanical strength. Therefore, the permeability of the hollow fiber support membrane in this embodiment is preferably 50,000 kg / m 2 / hr / 100kPa or less, preferably 10,000kg / m 2 / hr / 100kPa or less is a guideline.

[0042] Any material can be used for such a hollow fiber support membrane as long as it can be formed into a porous support. However, when manufacturing a composite membrane by the preferred manufacturing method of this embodiment, it is necessary that the material is not chemically damaged by the monomer solution used. Therefore, from the viewpoints of chemical resistance, membrane formability, durability, etc., the material for the hollow fiber support membrane is preferably at least one selected from polysulfone, polyethersulfone, polyacrylonitrile, polyethylene, polypropylene, polyamide, polyvinylidene fluoride, and cellulose acetate as the main component, and from the viewpoint of controlling the pore size of the support membrane or forward osmosis membrane, it is more preferable to contain polysulfone or polyethersulfone as the main component. Here, a certain member containing a specific material as the main component means that the specific material is contained in an amount of 50% by mass or more based on the mass of the member. From the same viewpoint, the porous support preferably contains polysulfone or polyethersulfone as the main component, and more preferably contains 50% by mass or more of polysulfone or polyethersulfone based on the mass of the porous support.

[0043] The fiber diameter size of the hollow fiber support membrane used in this embodiment is not particularly limited, but considering the membrane production stability, ease of handling, membrane area when made into a module, etc., the outer diameter is preferably in the range of 100 μm to 3,000 μm and the inner diameter is preferably in the range of 30 μm to 2,500 μm, and the outer diameter is more preferably in the range of 200 μm to 1,500 μm and the inner diameter is more preferably in the range of 50 μm to 1,000 μm. Such a hollow fiber support membrane can be produced by a known dry / wet membrane production method, melt membrane production method, wet membrane production method, etc., using a material selected from the above materials.

[0044] The forward osmosis membrane of the present embodiment can be used as a membrane module (forward osmosis membrane module) having a plurality of membranes. The shape of the membrane module is not particularly limited, but generally, a section where liquid contacts only one surface side of the membrane and a section where liquid contacts only the other surface side of the membrane are separated by an adhesive resin that fixes the membrane to the module housing. Taking a hollow fiber membrane as an example, a section where liquid contacts only the inner surface side of the membrane and a section where liquid contacts only the outer surface side of the membrane are separated. The size of the module housing is not particularly specified, but for example, a cylindrical housing with a diameter of 0.5 inches to 20 inches and a length of 4 cm to 10 m can be used. In addition, a module can be formed by using an adhesive such as a urethane-based or epoxy-based adhesive as the adhesive resin. The adhesive is solidified so as not to block the holes of each hollow fiber, thereby ensuring the flowability of the hollow fibers.

[0045] The forward osmosis membrane module (hollow fiber membrane module) 1 shown in FIG. 1 has a structure in which a fiber bundle consisting of a plurality of hollow fibers 4 is filled in a cylindrical body, and both ends of the hollow fiber bundle are fixed to the cylinder with adhesive fixing parts 5, 6. The cylindrical body has outer conduits 2, 3 on its side and is sealed by headers 7, 8. Here, the adhesive fixing parts 5, 6 are each solidified so as not to block the pores of the hollow fibers. The headers 7, 8 have inner conduits 9, 10, respectively, which communicate with the inside (hollow part) of the hollow fibers 4 but do not communicate with the outside. These conduits allow liquid to be introduced into the inside of the hollow fibers 4 or liquid to be removed. The outer conduits 2, 3 each communicate with the outside of the hollow fibers 4 but do not communicate with the inside.

[0046] This hollow fiber membrane module 1 has a structure in which the liquid flowing inside and the liquid flowing outside are in contact only via the hollow fibers 4 (forward osmosis membrane).

[0047] In this specification, the membrane area of ​​the forward osmosis membrane module (hollow fiber membrane module) 1 means the effective membrane surface area, and may be the effective membrane surface area of ​​either the inner surface or the outer surface. As shown in FIG. 1, the hollow fiber membrane module 1 has an effective membrane area portion 20 as a portion that performs a separation function. In FIG. 1, the effective membrane area portion 20 is a portion that substantially performs a separation function, excluding the adhesive fixing portions 5 and 6 of the portion filled with the hollow fiber bundle. In the case of hollow fibers having a separation function layer on the inner surface (not shown), the effective membrane area is calculated based on the total inner surface area of ​​the hollow fibers, and can be expressed, for example, by (inner circumference of hollow fibers) x (length from adhesive layer to adhesive layer of the module) x (number of hollow fiber membranes). In the case of hollow fibers having a separation functional layer disposed on the outer surface (not shown), the effective membrane area is calculated based on the total outer surface area of ​​the hollow fibers, and can be expressed, for example, as (outer circumference of hollow fibers) × (length from adhesive layer to adhesive layer of module) × (number of hollow fiber membranes). The membrane area of ​​the forward osmosis membrane module can be measured by the method described in the Examples, and can be considered to be approximately equal to the effective membrane area of ​​the support membrane module.

[0048] The hollow fiber membrane module 1 preferably includes a conduit that communicates with the inside (hollow portion) of the hollow fiber bundle but not with the outside, and a conduit that communicates with the outside of the hollow fiber bundle but not with the inside. This configuration makes it possible to place the inside and outside of the hollow fiber bundle under different pressures, and is suitable for use in forming a separation functional layer in this embodiment (described later).

[0049] The separation function layer is disposed on the porous support of the support membrane and essentially performs the function of separating solutes in the forward osmosis membrane, more specifically, the function of separating solutes such as ions dissolved in the raw liquid from the solvent in the raw liquid.

[0050] The separation functional layer according to the present embodiment has an average thickness of 2.0 μm or less, and a coefficient of variation of the average thickness in the radial and longitudinal directions of the forward osmosis membrane module of 30% or less, thereby achieving both performance stability and physical durability. The average thickness of the separation functional layer is preferably 0.05 μm or more from the viewpoint of ensuring a thickness that does not cause defects in the layer, and more preferably 0.2 to 0.8 μm from the viewpoint of achieving both a thickness that is unlikely to cause defects and water permeability. From the viewpoint of further improving the physical durability of the forward osmosis membrane module, the coefficient of variation of the average thickness of the separation functional layer is preferably 25% or less, more preferably 20% or less. When the coefficient of variation of the average thickness of the separation functional layer is within the above numerical range, even if a back pressure is applied to the forward osmosis membrane module, the pressure can be evenly distributed, and as a result, peeling or damage of the separation functional layer can be prevented.

[0051] In this specification, the variation in the average thickness of the separation functional layer in each hollow fiber forward osmosis membrane in the forward osmosis membrane module is expressed as a coefficient of variation, which is the standard deviation of the average thickness divided by the average value of the average thickness, and is expressed as a percentage (%).

[0052] The average thickness of the separation functional layer is measured by microscopic observation. Specifically, for example, the separation membrane is embedded in a resin, and then cut to prepare ultrathin slices. The obtained slices are stained and observed with a transmission electron microscope (TEM) or a scanning electron microscope (SEM). A preferred method for measuring the thickness of the membrane is to import an image of a cross section of the separation functional layer in the thickness direction taken with a scanning electron microscope into a suitable image processing software and process the image. An example of the image processing software is ImageJ (developed by the National Institutes of Health). The outline of the separation functional layer is extracted from the SEM image imported into ImageJ, and the inside is filled in to calculate the area of ​​the separation functional layer, which can be converted into the average thickness of the separation functional layer in one image using a calibration curve prepared in advance.

[0053] In this embodiment, a preferred method for measuring the coefficient of variation of the average thickness of the separation functional layer is as follows. The hollow fiber membrane is divided into three equal parts in the longitudinal direction to obtain three samples. A cross section perpendicular to the membrane surface direction (longitudinal direction) is obtained at any location of these three samples, preferably at a portion where each sample is divided into two equal parts in the longitudinal direction, and observed under a microscope to measure the average thickness of the separation functional layer in each image. This operation is performed for three forward osmosis membranes or three forward osmosis membranes cut out from one forward osmosis membrane module, and the average thickness of the separation functional layer is measured in a total of nine images. The nine average thickness values ​​obtained are used to calculate the average value of the average thickness and the standard deviation of the average thickness, and the coefficient of variation is calculated from these values. When cutting out three forward osmosis membranes from one forward osmosis membrane module, it is preferable to cut them out from three locations in the radial direction of the forward osmosis membrane module: the outer periphery, the middle, and the center. By using such a cutting method, the variation of the entire module can be evaluated. In the case of a flat forward osmosis membrane, the membrane can be divided into nine parts to obtain nine samples, and a cross section can be obtained from the center of each sample, followed by microscopic observation.

[0054] The field of view of the microscope image when measuring the average thickness etc. of the separation functional layer is preferably about 5 to 100 μm, more preferably 5 to 50 μm, even more preferably 5 to 20 μm, and most preferably 13 μm, in cross-sectional width (length in a direction parallel to the interface between the support membrane and the separation functional layer). The magnification of the microscope image is preferably 5,000 times to 30,000 times, and more preferably 10,000 times.

[0055] In the forward osmosis membrane of this embodiment, the structures of the support membrane and the separation functional layer are preferably uniform within the above-mentioned range. If the structures of the separation functional layer and the support membrane located close to the separation functional layer are uniform, the expected function and physical durability can be exhibited in any part of the separation functional layer. In general, when a part of the forward osmosis membrane in a forward osmosis membrane module is defective, the performance of the entire module is often significantly reduced. In this respect, it is also preferable that the forward osmosis membrane is uniform throughout the entire module. For example, in the case of a hollow fiber forward osmosis membrane, the structure of the forward osmosis membrane is preferably more uniform in at least one of the circumferential and longitudinal directions, more preferably more uniform in both the circumferential and longitudinal directions, and particularly preferably more uniform in all parts of the membrane when the hollow fibers are bundled together to form a module.

[0056] In this embodiment, the coefficient of variation of the average thickness of the separation functional layer from the outermost part to the center of the hollow fibers in a forward osmosis membrane module in which multiple hollow fiber-shaped forward osmosis membranes are composited, and the coefficient of variation of the average thickness of the separation functional layer from one end to the other end of the hollow fibers in the module are each preferably 0 to 30%, more preferably 25% or less, and even more preferably 0 to 20%.

[0057] More specifically, the thickness, average thickness, and coefficient of variation thereof of the separation functional layer can be obtained by the method described in the Examples. In the forward osmosis membrane module in which a plurality of hollow fiber forward osmosis membranes are combined in this embodiment, the average thickness of the separation functional layer at each location in the module varies little. Therefore, the performance variation between modules is also small and favorable. The performance referred to here is physical durability, water permeability, and salt back diffusion.

[0058] The separation functional layer according to this embodiment has substantial separation performance, can be made of a polymer, can be a thin film, and can be formed by an interfacial polymerization reaction.

[0059] In the case where the separation functional layer is a membrane made of a high molecular weight polymer, the thinner the membrane is, the more preferable it is if there are no pinholes. However, in order to maintain mechanical strength and chemical resistance, it is necessary to provide an appropriate thickness. Therefore, in consideration of the membrane formation stability, permeability, etc., the thickness of the membrane made of a high molecular weight polymer is preferably 0.2 to 2.0 μm, more preferably 0.2 to 1.0 μm, and even more preferably 0.2 to 0.8 μm.

[0060] Examples of the polymer include: At least one first monomer selected from polyfunctional amines; at least one second monomer selected from the group consisting of polyfunctional acid halides; More specifically, for example, the following polymer is preferable: and polyamides obtained by interfacial polycondensation reaction of polyfunctional amines and polyfunctional acid halides. The separation performance when a membrane containing or made of such a polymer is used as the separation functional layer refers to the performance of separating pure water from solutes such as ions dissolved therein.

[0061] The types and combinations of the first and second monomers, and the type of the solvent (described later) used are not particularly limited as long as both monomers undergo a polymerization reaction immediately at the interface to form a polymer. However, it is preferable that at least one of the first and second monomers contains a reactive compound having three or more reactive groups. This allows a thin film made of a polymer having a three-dimensional structure to be formed, which is more preferable from the viewpoint of film strength.

[0062] The polyfunctional amines include polyfunctional aromatic amines, polyfunctional aliphatic amines, monomers having a plurality of reactive amino groups, and prepolymers thereof.

[0063] The polyfunctional aromatic amine is an aromatic amino compound having two or more amino groups in one molecule, and more specifically, for example, m-phenylenediamine, p-phenylenediamine, 3,3'-diaminodiphenylmethane, 4,4'-diaminodiphenylamine, 4,4'-diaminodiphenylether, 3,4'-diaminodiphenylether, 3,3'-diaminodiphenylamine, 3,5-diaminobenzoic acid, 4,4'-diaminodiphenylsulfone, 3,3'-diaminodiphenylsulfone, 3,4'-diaminodiphenylsulfone, 1,3,5,-triaminobenzene, 1,5-diaminonaphthalene, etc., can be used alone or in mixture. In the present invention, one or more selected from m-phenylenediamine and p-phenylenediamine are particularly preferably used.

[0064] The polyfunctional aliphatic amine is an aliphatic amino compound having two or more amino groups in one molecule, and more specifically, for example, primary amines having a cyclohexane ring, such as 1,3-diaminocyclohexane, 1,4-diaminocyclohexane, 4,4'-bis(paraaminocyclohexyl)methane, 1,3-bis-(aminomethyl)cyclohexane, 2,4-bis-(aminomethyl)cyclohexane, and 1,3,5-triaminocyclohexane; Secondary amines containing a piperazine ring, such as piperazine, 2-methylpiperazine, ethylpiperazine, and 2,5-dimethylpiperazine; Secondary amines containing a piperidine ring, such as 1,3-bis(4-piperidyl)methane, 1,3-bis(4-piperidyl)propane, and 4,4'-bipiperidine; Others such as amines with both primary and secondary amino groups, such as 4-(aminomethyl)piperidine; Ethylenediamine, propylenediamine, 1,2-propanediamine, 1,2-diamino-2-methylpropane, 2,2-dimethyl-1,3-propanediamine, tris(2-aminoethyl)amine, N,N'-dimethylethylenediamine, N,N'-dimethylpropanediamine, etc.; These may be used alone or in mixture. Mixtures of these polyfunctional aliphatic amines and the above-mentioned polyfunctional aromatic amines may also be used.

[0065] Examples of the monomer having a plurality of reactive amino groups include polyethyleneimine, amine-modified polyepichlorohydrin, aminated polystyrene, etc. As the prepolymer, for example, a prepolymer composed of one or more selected from piperazine, 4-(aminomethyl)piperidine, ethylenediamine, and 1,2-diamino-2-methylpropane is preferably used.

[0066] Examples of the polyfunctional halide include polyfunctional aromatic acid halides, polyfunctional aliphatic acid halides, etc. These may have a functionality of 2 or more so that they can react with the polyfunctional amine to form a polymer.

[0067] The polyfunctional aromatic acid halide is an aromatic acid halide compound having two or more acid halide groups in one molecule.Specific examples include trimesic acid halide, trimellitic acid halide, isophthalic acid halide, terephthalic acid halide, pyromellitic acid halide, benzophenonetetracarboxylic acid halide, biphenyldicarboxylic acid halide, naphthalenedicarboxylic acid halide, pyridinedicarboxylic acid halide, and benzenedisulfonic acid halide, and these can be used alone or in mixture.In this embodiment, trimesic acid chloride alone, or a mixture of trimesic acid chloride and isophthalic acid chloride, or a mixture of trimesic acid chloride and terephthalic acid chloride is preferably used.

[0068] The polyfunctional aliphatic acid halide is an aliphatic acid halide compound having two or more acid halide groups in one molecule.Specific examples thereof include alicyclic polyfunctional acid halide compounds such as cyclobutanedicarboxylic acid halide, cyclopentanedicarboxylic acid halide, cyclopentanetricarboxylic acid halide, cyclopentanetetracarboxylic acid halide, cyclohexanedicarboxylic acid halide, and cyclohexanetricarboxylic acid halide; Examples of the polyfunctional aliphatic acid halide include propane tricarboxylic acid halide, butane tricarboxylic acid halide, pentane tricarboxylic acid halide, succinic acid halide, glutaric acid halide, etc. These may be used alone or in mixture, and a mixture of these polyfunctional aliphatic halides and the above-mentioned polyfunctional aromatic acid halides may be used.

[0069] Examples of the polyfunctional isocyanate include ethylene diisocyanate, propylene diisocyanate, benzene diisocyanate, toluene diisocyanate, naphthalene diisocyanate, and methylene bis(4-phenyl isocyanate). The first monomer and the second monomer as described above are each dissolved in an appropriate solvent and subjected to interfacial polymerization as a solution.

[0070] In this specification, the first solution refers to a solution containing a monomer that the hollow fiber support membrane will come into contact with first, and the second solution refers to a solution containing a monomer that will come into contact with the support membrane after the first solution has come into contact with the support membrane and will react with the monomer in the first solution to form a polymer. One of the first and second monomers is contained in the first solution, and the other is contained in the second solution. Either monomer may be contained in either solution, but an embodiment in which both monomers are contained in one solution is not preferred.

[0071] The solvents for the first solution and the second solution are not particularly limited as long as they dissolve the monomers contained therein, form a liquid-liquid interface when the two solutions come into contact, and do not damage the microporous hollow fiber support membrane. Examples of such solvents include water and alcohols, either alone or in mixture, for the first solution, and hydrocarbon solvents such as n-hexane, cyclohexane, n-heptane, n-octane, n-nonane, and n-decane, either alone or in mixture, for the second solution. By selecting such a solvent, the first solution and the second solution become immiscible, and the interfacial polymerization proceeds as expected.

[0072] It is preferable to select the first monomer as the monomer contained in the first solution, and the second monomer as the monomer contained in the second solution. The concentrations of these reactive compounds contained in the first solution and the second solution vary depending on the type of monomer, the partition coefficient to the solvent, etc., and are not particularly limited, and should be appropriately set by a person skilled in the art.

[0073] For example, in the case where an aqueous m-phenylenediamine solution is used as the first solution and an n-hexane solution of trimesoyl chloride is used as the second solution, the procedure is as follows: The concentration of m-phenylenediamine is preferably 0.1 to 10% by mass, more preferably 0.5 to 5% by mass. The concentration of trimesoyl chloride is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass. If the concentration of these solutions is too low, the formation of the thin film by interfacial polymerization is incomplete, and defects are likely to occur, resulting in a decrease in separation performance. Conversely, if the concentration is too high, the thin film formed becomes too thick, resulting in a decrease in permeation performance, and the amount of residual unreacted substances in the membrane increases, which may have an adverse effect on membrane performance. In the case where an acid is generated during the interfacial polymerization reaction, an alkali may be added as an acid scavenger to the first or second solution. In addition, a surfactant for improving wettability with the microporous hollow fiber support membrane, a catalyst for accelerating the reaction, etc. may be added as necessary.

[0074] Examples of the acid scavenger include, for example, caustic alkali such as sodium hydroxide; Sodium phosphates, such as trisodium phosphate; Carbonates of soda, such as sodium carbonate; Examples of the surfactant include tertiary amines such as trimethylamine, triethylamine, and triethylenediamine. Examples of the surfactant include sodium lauryl sulfonate and sodium laurylbenzenesulfonate. Examples of the catalyst include dimethylformamide. These can be contained in the first solution or the second solution in advance.

[0075] In this specification, the inside of the hollow fiber may be abbreviated as "inside", and the space between the outside of the hollow fiber and the tube may be abbreviated as "outside". The hollow fiber membrane module in this embodiment is structured so that the liquid flowing inside and the liquid flowing outside are in contact only through the hollow fiber membrane. Also, as shown in Figure 1, a pressure difference can be created between the inside and outside of the hollow fiber by applying different pressures to the outer conduits 2 and 3 and the inner conduits 9 and 10, respectively.

[0076] In this embodiment, the inside of a porous hollow fiber support membrane module is filled with a first solution containing one of the first monomer and the second monomer, followed by creating a pressure difference between the inside and outside. Thereafter, a second solution containing the other of the first monomer and the second monomer and immiscible with the first solution is passed through the module, thereby causing a reaction between the first monomer and the second monomer on the inner surface of the porous hollow fiber support membrane to form a thin film made of or containing a high molecular weight polymer, thereby producing the desired forward osmosis membrane module.

[0077] The method of creating a pressure difference between the inside and the outside is arbitrary, for example: How to reduce pressure both internally and externally; A method in which the outside is reduced pressure and the inside is at atmospheric pressure; A method in which the outside is atmospheric pressure and the inside is pressurized; How to apply pressure both internally and externally; In this embodiment, it is preferable to set the pressure on the outside lower than the pressure on the inside.

[0078] It is believed that by creating a pressure difference as described above (inner pressure > outer pressure) after filling the inside with the first solution, excess first solution penetrates into the fine pores of the support membrane, and a thin film of the first solution of relatively uniform thickness is formed on the inner surface of the support membrane throughout the entire module.

[0079] In this embodiment, the thickness of the membrane made of a polymer as a separation functional layer formed on the inner surface of the microporous hollow fiber support membrane of the composite hollow fiber module is closely related to the thickness of the liquid membrane of the first solution. The thickness of this liquid membrane can be adjusted by the pressure difference between the inside and outside of the module, the time for maintaining the pressure difference, the amount of surfactant added to the first solution, the structure of the support membrane, and the like. In this regard, the thickness, average thickness, and coefficient of variation of the average thickness of the separation functional layer are preferably adjusted as described above. In order to form a separation functional layer with an adjusted average thickness and its coefficient of variation, the pressure difference between the inside and outside is preferably 1 to 500 kPa, more preferably 5 to 300 kPa, and even more preferably 10 to 100 kPa. The time for maintaining the pressure difference is preferably 1 to 100 minutes, and more preferably 10 to 50 minutes. The amount of surfactant added to the first solution is preferably 0.01 to 1 mass % relative to the total amount of the first solution, and more preferably 0.05 to 0.5 mass %.

[0080] The greater the pressure difference and the longer the pressure difference is maintained, the thinner the liquid film of the first solution will be, and vice versa. If the liquid film is too thin, even slight variations in thickness can cause areas where the liquid film is not formed, resulting in defects in the separation functional layer. Also, if the liquid film is too thick, sufficient permeability may not be obtained.

[0081] In the manufacturing method of the forward osmosis composite hollow fiber membrane module in this embodiment, the pressure difference between the inside and outside is uniform from the outermost part to the center of the hollow fibers in the module, and is also uniform from one end to the other end of the hollow fibers in the module. This makes the thickness of the liquid membrane of the first solution formed at each location uniform, and the thickness of the separation functional layer made of a polymer formed based on this liquid membrane is also uniform. Therefore, the variation in the water permeation rate of the liquid at each location is reduced, and the composite hollow fiber membrane module can exhibit stable and high performance.

[0082] According to the conventional method of forming a liquid membrane of the first solution inside the hollow fibers by passing high-pressure air, the longer the module is and the larger the diameter of the module is, the greater the variation in the average thickness of the separation functional layer at each point. In contrast, in the method of manufacturing a forward osmosis membrane module according to the present embodiment, the average thickness of the separation functional layer at each point is substantially uniform. Furthermore, the larger the size of the module is, the more pronounced the effect of the present invention is, and although not limited thereto, it is practically convenient for the module length to be 50 mm or more and 3000 mm or less and the module diameter to be 50 mm or more and 500 mm or less.

[0083] The separation functional layer in the forward osmosis membrane module of this embodiment has a large number of fine irregularities on its surface. The degree of irregularities on the surface of the separation functional layer can be estimated by the ratio L2 / L1 of the length L1 of the interface between the separation functional layer and the hollow fiber support membrane and the length L2 of the separation functional layer surface in a scanning electron microscope image of a cross section of the separation functional layer in the thickness direction. In the composite hollow fiber membrane module of this embodiment, the ratio L2 / L1 in the cross section image of the separation functional layer is preferably 1.1 to 5.0, more preferably 1.15 to 4.0, and even more preferably 1.2 to 3.0. The ratio L2 / L1 can be evaluated using a scanning electron microscope image of the cross section of a hollow fiber membrane sample.

[0084] The present inventors speculate as follows about the mechanism by which the surface of the separation functional layer according to the present embodiment has such a fine uneven shape, however, the present invention is not limited to the following theory. The separation functional layer in the composite hollow fiber membrane module of this embodiment is preferably formed by interfacial polymerization. In interfacial polymerization, when the liquid film of the first monomer solution formed on the hollow fiber surface comes into contact with the second monomer solution, it is believed that the two are not compatible with each other and polymerization proceeds at the interface to form a polymerized layer. As a result, it is believed that the formed separation functional layer has a shape with many fine projections and recesses on the surface. If the separation functional layer is formed by a method other than interfacial polymerization, it is difficult to form a separation functional layer with a shape with many fine projections and recesses on the surface.

[0085] (Uneven structure of separation functional layer) In the forward osmosis membrane of the present embodiment, the separation functional layer preferably has an uneven structure with an arithmetic mean height (Sa) of 40 nm or more. The separation functional layer having an "uneven structure" means that the outermost surface of the separation functional layer, i.e., the surface of the separation functional layer opposite to the surface in contact with the support membrane, has multiple convex and concave portions, which are present repeatedly. The arithmetic mean height (Sa) of this uneven structure being 40 nm or more means that when the surface roughness of the outermost surface of the separation functional layer is measured, the arithmetic mean height (Sa) defined by ISO 25178 is 40 nm or more. The arithmetic mean height (Sa) of the uneven structure of the separation functional layer is preferably 60 nm or more, more preferably 100 nm or more, from the viewpoint of ensuring water permeability while increasing adhesion to the porous support. In addition, in practical use, depending on the properties of the liquid passing through the forward osmosis membrane, there is a possibility that a substance that is easily caught in the uneven structure of the separation functional layer and adheres to the membrane surface may be mixed in. In such a case, from the viewpoint of reducing adhesion, the arithmetic mean height (Sa) of the separation functional layer is preferably 300 nm or less, more preferably 200 nm or less, and even more preferably 150 nm or less.

[0086] The arithmetic mean height (Sa) of the relief structure of the separation functional layer can be analyzed by an atomic force microscope (AFM). Specifically, under conditions in which the forward osmosis membrane does not dry out, the surface of the separation functional layer is exposed as an observation sample, and AFM observation is performed. The measurement conditions are, for example, as follows. Measurement mode: QNM in fluid (measurement in pure water) Field of view size: 3μm square Probe used: OLTESPA For example, under the above-mentioned conditions, the outermost surface of the separation functional layer is scanned to measure the arithmetic mean height (Sa), and the average value of nine samples is suitably evaluated.

[0087] <Manufacturing method for forward osmosis membrane module> The method for producing a forward osmosis membrane module according to the present embodiment includes, for example, the following steps: (I) a separation function layer forming step of providing a separation function layer on the surface of a hollow fiber support membrane using a plurality of hollow fiber support membranes having a porous support to prepare a hollow fiber forward osmosis membrane module having a hollow fiber forward osmosis membrane; (II) a liquid sealing step of sealing and holding a liquid at least on the surface side of the hollow fiber forward osmosis membrane module on which the separation functional layer is formed; (III) a heat treatment step of heating the hollow fiber forward osmosis membrane module and the liquid to 50°C or higher; Includes.

[0088] When the manufacturing method of a forward osmosis membrane module includes a separation functional layer forming step (I), a liquid sealing step (II), and a heat treatment step (III), the obtained forward osmosis membrane module tends to exhibit stable high performance and have excellent physical durability, and in particular, the back pressure resistance described above is enhanced.

[0089] The method for producing a forward osmosis membrane module according to this embodiment and each step included therein will be described below with reference to FIG.

[0090] 2, a porous hollow fiber supported membrane module 11 in which a first solution is filled inside the hollow fiber supported membrane has a piping from a second solution storage tank 14 connected to its inside inlet, and a pump 16 for pressure-feeding the second solution connected midway. A piping 18 from a reaction wastewater storage tank 17 is connected to the inside outlet, and an inner pressure regulator 12 for controlling the pressure inside the hollow fibers of the porous hollow fiber supported membrane module 11 is connected from the tank. An end cap 19 is fitted into the lower conduit on the outside of the porous hollow fiber supported membrane module 11, and an outer pressure regulator 13 for controlling the outer pressure is connected to the upper conduit.

[0091] The membrane area of ​​the porous hollow fiber support membrane module 11 is set to 0.1 m from the viewpoint of adjusting the membrane area of ​​the obtained forward osmosis membrane module to be within the above numerical range. 2 More preferably, it is equal to or greater than this.

[0092] In the separation function layer forming step (I), a separation function layer is provided on the surface of the hollow fiber support membrane, and the hollow fiber support membrane is preferably configured to have a dense layer with a porosity of 40% or less at a position up to 1.0 μm in the depth direction from the interface between the porous support and the separation function layer, and more preferably the dense layer has a porosity of 10 to 40%. By configuring the hollow fiber support membrane and the separation function layer in this way, it is possible to achieve both physical durability and performance stability of the obtained forward osmosis membrane module.

[0093] The material of the porous support constituting the hollow fiber support membrane and the material of the separation functional layer are as described above. Among them, from the viewpoints of reducing the coefficient of variation of the average thickness of the separation functional layer, making the overall structure of the module uniform, and improving the forward osmosis performance, the back pressure resistance, and the practicality, it is preferable to form the separation functional layer as a polymer of at least one first monomer selected from polyfunctional amines and at least one second monomer selected from polyfunctional acid halides. From the same viewpoint, it is more preferable to form a liquid membrane of a first solution containing one of the first monomer and the second monomer on the inner surface of the hollow fiber support membrane, and then, after creating a pressure difference between the inside and outside of the hollow fiber support membrane so that (inside pressure)>(outside pressure), to bring the liquid membrane of the first solution into contact with the second solution containing the other of the first monomer and the second monomer.

[0094] From the viewpoints of practicality and productivity and of suppressing the occurrence of defects in the membrane or module, the pressure difference is preferably within a range of 10 to 90 kPa, and / or the pressure difference is preferably generated by any of the following methods: (Ia) applying a vacuum to the outside of the hollow fiber support membrane; or (Ib) Both the outside and inside of the hollow fiber support membrane are pressurized with different pressures.

[0095] In the liquid sealing step (II), in the hollow fiber forward osmosis membrane module, a liquid is sealed and held at least on the surface side where the separation functional layer is formed, preferably, from the viewpoint of uniform heating and cooling, the liquid is filled and held inside and outside the hollow fiber forward osmosis membrane, and more preferably, from the viewpoint of uniform heating and cooling and filling the membrane part with the liquid, the liquid is pressurized to fill and hold the hollow fiber forward osmosis membrane. As the above liquid, in connection with the subsequent water washing step, water is preferred, and for example, pure water may be used.

[0096] In the liquid sealing step (II), the hollow fiber forward osmosis membrane module is preferably immersed in a liquid such as water from the viewpoint of preventing housing deformation during heat sterilization after installation in an apparatus by heating the entire module, or is preferably sealed with a liquid such as water from the viewpoint of saving liquid and economic efficiency. The liquid sealing step (II) can be performed, for example, by passing liquid through a liquid tank or by immersing the module in a liquid tank (for example, a water tank).

[0097] In the heat treatment step (III), the forward osmosis membrane module and liquid such as water are heated to 50°C or higher, preferably 100°C or higher from the viewpoint of improving the forward osmosis performance, and more preferably 121°C or higher from the viewpoint of further improving the forward osmosis performance. The upper limit of the temperature to which the module and liquid are heated may be a temperature at which the members do not melt, for example, in the range of 145°C or lower. The heat treatment step (III) can be performed, for example, in a high-pressure steam sterilizer (autoclave). By sealing the liquid and then heating, the forward osmosis membrane and / or the forward osmosis membrane module can be prevented from being suddenly deformed, while the forward osmosis membrane can receive the effect of improving the performance of the forward osmosis membrane by the heat treatment.

[0098] In the heat treatment step (III), from the viewpoint of suppressing or preventing bumping and suppressing the occurrence of membrane defects, it is preferable to continue the above-mentioned temperature increase under pressure in a temperature range equal to or higher than the boiling point of the liquid such as water. The pressurization in the heat treatment step (III) can be carried out, for example, by continuing the pressurization shown in the above (Ib).

[0099] Furthermore, when the heat treatment step (III) is performed in a state where a part of the forward osmosis membrane is in contact with the liquid by the liquid sealing step (II), preferably in a state where 40% or more or 80% or more of the entire surface area of ​​the forward osmosis membrane is in contact with the liquid, and more preferably in a state where 80 to 100% of the entire surface area of ​​the forward osmosis membrane is in contact with the liquid, excessive evaporation of the liquid from the forward osmosis membrane can be prevented when the forward osmosis membrane is cooled after the heat treatment step (III). This prevents the pores of the support membrane and / or separation functional layer of the forward osmosis membrane from drying, and as a result, the water permeability of the forward osmosis membrane can be maintained at a high level. Furthermore, when the liquid is sealed in the membrane module, uniform heating and cooling are performed throughout the membrane module, and the resulting separation functional layer is more likely to be uniform.

[0100] As an example of a method for producing a forward osmosis membrane module including the above steps (I) to (III), the following procedure can be carried out.

[0101] First, each pipe is connected to a porous hollow fiber support membrane module 11 in which the inside of the porous hollow fiber support membrane is filled with a first solution. Next, a pressure difference is created between the inside and outside (i.e., a pressure difference between the inside and outside of the hollow fiber support membrane) by an inner pressure regulator 12 and an outer pressure regulator 13 (inner pressure > outer pressure). At this time, the excess first solution in the inner hollow fiber enters the micropores due to the pressure difference (it may also seep out to the outside), and a liquid membrane of uniform thickness is formed inside the hollow fiber.

[0102] Next, the second solution in the storage tank 14 is pumped to the inside of the hollow fiber and brought into contact with the liquid membrane of the first solution. This contact causes interfacial polymerization of both monomers, and a thin film made of a high molecular weight polymer is formed as a separation functional layer on the inside of the porous hollow fiber support membrane. When the second solution is pumped, there is a risk that the pressure on the inside may fluctuate, but this pressure fluctuation is suppressed by the function of the inner pressure control device 12. In this way, when performing interfacial polymerization, it is preferable to maintain a preset pressure difference between the inside and outside.

[0103] As described above, a thin film made of a polymer is formed on the inside of the porous hollow fiber support membrane by interfacial polymerization of the first monomer and the second monomer, thereby producing the forward osmosis membrane module of this embodiment.

[0104] In the forward osmosis membrane module of this embodiment, the thickness of the liquid film of the first monomer solution for forming a polymer by interfacial polymerization is uniform at the outer periphery and center of the module and at the top and bottom of the module, so that the module has a uniform layer of polymer. Since the interfacial polymerization proceeds at the interface between the first monomer solution and the second monomer solution, the surface of the layer formed from the polymer has many fine irregularities.

[0105] Furthermore, the forward osmosis membrane module is held with a liquid sealed at least on the surface side on which the separation functional layer is formed, and is then subjected to a liquid sealing step (II).

[0106] Furthermore, the forward osmosis membrane module, together with the enclosed liquid, is heated to 50° C. or higher and subjected to a heat treatment step (IIII).

[0107] The forward osmosis membrane module obtained by the above-mentioned manufacturing method has a membrane area of ​​0.1 m as described above. 2 It is adjusted above. EXAMPLES

[0108] The present invention will be described in detail below with reference to examples, but the present invention is not limited to these examples. Unless otherwise specified, operations were performed at 25°C.

[0109] <Electron microscope observation, measurement of the porosity of the dense layer, measurement of the average thickness and coefficient of variation of the separation functional layer, and measurement of the membrane area of ​​the porous hollow fiber support membrane module> The porous hollow fiber support membrane module or hollow fiber forward osmosis membrane module was disassembled, and one hollow fiber was sampled from each of three locations in the radial direction of the module: the center, the 50% position of the radius, and the outermost periphery. Each hollow fiber was cut into three equal parts in the length direction to obtain nine samples. Each of these hollow fiber samples was treated in the following manner to prepare hollow fiber cross-section samples. For the flat forward osmosis membrane, each side of the forward osmosis membrane was divided into nine parts so as to divide it into three equal parts, and cross-sectional samples were similarly prepared from the nine samples. For each sample, a scanning electron microscope was used to photograph the area near the interface where the porous support and the separation functional layer were in contact, and the obtained images (cross-sectional images) were analyzed to distinguish between the dense layer of the porous support in the support membrane and areas other than the dense layer, and the position and porosity of the dense layer were determined. The thickness and porosity of the dense layer of the porous support membrane were measured after it was made into a forward osmosis membrane. It was confirmed that the measured values ​​were the same within the error range even when the support membrane was measured alone.

[0110] Cross-sectional images of each sample were obtained as follows. The sample was immersed in pure water in a special glass container, frozen using liquid nitrogen, and then dried using the freeze-drying method. A cross section perpendicular to the membrane direction was prepared for the dried sample using the Broad Ion Beam (BIB) processing method (processing device: E-3500, Hitachi High-Tech Corporation), and a thin coating of osmium was applied to prepare an observation sample. Images of the observation sample were taken using a scanning electron microscope (S-4800, Hitachi High-Tech Corporation) under the following conditions. Acceleration voltage: 1.0 kV Emission current: 10μA Probe current:Normal Detector:Upper Magnification: 10,000x (to calculate the average thickness and coefficient of variation of the separation functional layer), or 50,000x (to calculate the porosity of the dense layer) Number of pixels: 1280 x 960 Working distance: 5.0mm Image processing software: ImageJ (developed by the National Institutes of Health, USA)

[0111] The observation field was determined so that an area of ​​13 μm (calculation of the average thickness and coefficient of variation of the separation functional layer) or 2.5 μm (calculation of the porosity of the dense layer) in the direction of the membrane surface of the sample was included within the field of view. The cross-sectional images were acquired as 8-bit grayscale images under conditions where the brightness value was not saturated and the contrast was as high as possible. The porosity of the dense layer of the porous support and the average thickness and coefficient of variation of the separation functional layer were calculated using image processing software (ImageJ; developed by the National Institutes of Health, USA).

[0112] <Average thickness and coefficient of variation of separation functional layer> The cross-sectional image was imported into image processing software, binarized using Otsu's method, the outline of the separation functional layer was extracted, and the inside was filled in to calculate the area of ​​the separation functional layer in the cross-sectional image. The obtained area value was converted to the average thickness of the separation functional layer in one image using a calibration curve prepared in advance. The average value of the nine samples was then taken as the average thickness of the separation functional layer, and the standard deviation and coefficient of variation were calculated.

[0113] <Calculation of void ratio of dense layer> The cross-sectional image was imported into image processing software, binarized by Otsu's method, and the porosity (unit: %) was calculated by dividing the area of ​​the void portion by the remaining area at a position 1.0 μm in the depth direction from the interface between the porous support and the separation functional layer to obtain a percentage. Note that the threshold value for binarization was determined automatically, but when the portion where the macrovoids existed could not be binarized appropriately, the macrovoid portion of the cross-sectional image was painted black before image processing. The average value of the nine samples was determined as the porosity from the interface between the porous support and the separation functional layer to 1.0 μm in the depth direction.

[0114] <Thickness of dense layer containing separation functional layer> The image used in calculating the porosity of the dense layer was used to estimate the thickness of the separation functional layer extending in the depth direction from the interface between the porous support and the separation functional layer.

[0115] In all of the Examples and Comparative Examples, the separation functional layer was visually confirmed, so the length from the contact interface between the porous support of the forward osmosis membrane and the separation functional layer to the end of the penetration of the separation functional layer was taken as the thickness of the dense layer into which the separation functional layer penetrated. As a result, in all of Examples 1 to 11 and Comparative Examples 1 to 6, a thickness of 50 nm or more of the dense layer into which the separation functional layer penetrated was observed. In Example 1, the maximum thickness was 120 nm.

[0116] Furthermore, in scanning electron microscope images, when the depth direction was observed from the contact interface between the dense layer and the separation functional layer to 1.0 μm, and the depth direction was divided into 20 parts at 0.05 μm intervals, in the divided dense layers where the porosity of each of the 20 divided dense layers (divided dense layers) was at least 0.25 times the porosity up to 1.0 μm, even when the length from the depth-wise end of the divided dense layer to the contact interface between the porous support and the separation functional layer was defined as the thickness of the region of the dense layer into which the separation functional layer has penetrated, a thickness of the dense layer into which the separation functional layer has penetrated of 50 nm or more was observed in all of Examples 1 to 11 and Comparative Examples 1 to 6.

[0117] [Rough structure of separation functional layer] The arithmetic mean height (Sa) of the uneven structure of the separation functional layer was analyzed by the following method using an atomic force microscope (AFM). In the case of hollow fiber forward osmosis membranes, one forward osmosis membrane each (three in total) was taken from three locations in the radial direction of the forward osmosis membrane module, namely, the outer periphery, the middle, and the center, while the membrane was wet with pure water, and each was cut into three equal parts in the longitudinal direction to obtain nine samples. The center of each sample was cut open diagonally to expose the surface of the separation functional layer, and the obtained surface of the separation functional layer was observed. In the case of a flat forward osmosis membrane, each side of the forward osmosis membrane was divided into 9 equal parts, and 9 samples were obtained. The surface of the separation functional layer was observed at the center of each sample. In both the case of the hollow fiber forward osmosis membrane and the flat sheet forward osmosis membrane, the measured values were calculated as the average values for 9 samples. Observation and calculation of the arithmetic mean height were performed using an atomic force microscope under the following conditions. Measurement mode: QNM in fluid (measurement in pure water) Field of view size: 3 μm square Probe used: OLTESPA When the arithmetic mean height (Sa) calculated as the average value of 9 samples was 40 nm or more, it was assumed that the separation functional layer had an uneven structure. When this arithmetic mean height (Sa) was less than 40 nm, it was assumed that the separation functional layer did not have an uneven structure. All of the forward osmosis membranes in the following examples and comparative examples had an uneven structure.

[0118] [Dimensions of the support membrane] As the dimensions of the support membrane, for the hollow fiber support membrane, the inner diameter, outer diameter, and membrane thickness were measured, and for the flat sheet support membrane, the membrane thickness was measured. In the case of the hollow fiber support membrane, measurement was performed using an optical microscope photograph (cross-sectional image) of a cross-section obtained by cutting in a plane perpendicular to the membrane surface direction (longitudinal direction). The outer diameter and inner diameter of this cross-sectional image were measured using a scale. Also, the membrane thickness was calculated by dividing the difference between the outer diameter and the inner diameter by 2. The outer diameter and inner diameter referred to here are the outer diameter and inner diameter of the hollow fiber, respectively. In the case of the flat sheet support membrane, measurement was performed using an optical microscope photograph (cross-sectional image) of a cross-section obtained by cutting in a plane perpendicular to the membrane surface direction. The membrane thickness of this cross-sectional image was measured using a scale. In this example, the inner diameter, outer diameter, and membrane thickness of the support membrane were measured in the state after forming the forward osmosis membrane. It has been confirmed that even when measured in the state of only the support membrane, the values are the same within the error range.

[0119] <Evaluation after the DS pressure fluctuation test (0 kPa ←→ 100 kPa)> First, a feed solution (FS) tank and a feed solution line connecting the feed solution tank to the forward osmosis membrane module were prepared. The above-mentioned pump was installed on the feed solution line to supply the feed solution from the feed solution tank to the forward osmosis membrane module prepared in the examples and comparative examples. A draw solution (DS) tank and a draw solution line connecting the draw solution tank to the forward osmosis membrane module were prepared. A balance was installed under each tank. The above-mentioned pump was installed on the draw solution line to supply the draw solution from the draw solution tank to the forward osmosis membrane module. The above-mentioned back pressure valve was installed on the feed solution and draw solution lines to physically pressurize the feed solution and draw solution and adjust the physical pressure difference between the feed solution and draw solution. In addition, the above-mentioned pressure sensor was installed on the feed solution and draw solution lines to measure the physical pressure of the feed solution and draw solution. Furthermore, a motor was connected to rotate the back pressure valve in order to control the back pressure valve.

[0120] For the forward osmosis membrane modules produced in the examples and comparative examples, a pressure fluctuation test was performed while performing forward osmosis treatment under the following conditions, and then the forward osmosis membrane performance was evaluated, the water permeability (Flux) and salt back diffusion rate (RSF) were obtained, and the salt permeability (RSF / Flux) was calculated.

[0121] Pressure Fluctuation Test Raw material liquid: Purified water, 25℃, membrane surface linear velocity approximately 3.0cm / sec Draw solution: 3.5% by mass sodium chloride aqueous solution, 25°C, membrane surface linear speed approx. 3.0 cm / sec Physical pressure difference: 100 kPa (0 kPa ←→ 100 kPa). The back pressure valve was repeatedly opened and closed every 5 seconds for a total of 2,000 times, with the porous support side being the positive side, and a pressure load of 100 kPa was applied. Temperature: The temperature was adjusted in advance using a double-pipe heat exchanger and a temperature-control chiller. Operation time: Forward osmosis treatment was carried out until the above 2,000 pressure loads were completed. The forward osmosis operation was carried out while adding a saturated aqueous sodium chloride solution to the draw solution to maintain the concentration of the draw solution constant.

[0122] Evaluation of forward osmosis membrane performance The forward osmosis membrane module after the pressure fluctuation test was washed with water for at least 1 hour, and the forward osmosis membrane performance was evaluated under the following conditions. The water permeability (Flux) and salt back diffusion rate (RSF) were determined, and the salt permeability (RSF / Flux) was calculated. Raw material liquid: Purified water, 25℃, linear speed approximately 3.0cm / sec Draw solution: 3.5% by weight sodium chloride aqueous solution, 25°C, linear speed approximately 3.0 cm / sec Transmembrane pressure difference: 20kPa Driving time: 1 hour The forward osmosis operation was carried out while adding a saturated aqueous sodium chloride solution to the draw solution to maintain the concentration of the draw solution constant. The transmembrane pressure difference was set by operating the back pressure valve on the draw solution side so that the draw solution side (the support membrane side of the forward osmosis membrane) was positive (high pressure).

[0123] Dyeing area evaluation For each forward osmosis membrane module after the pressure fluctuation test, a dye solution of Blue Black (PILOT) diluted 5 times with pure water (purified water) was passed only on the side where the separation functional layer was present, and a dyeing test was performed for 1 hour by applying a pressure of 100 kPa (at this time, the separation functional layer side was under high pressure). After that, the forward osmosis membrane module was disassembled, and the porous support membrane side of all membranes (the side opposite the separation functional layer where the dye solution was passed) was observed, and the number of dyed areas of 2 mm or more was evaluated using the following index. AA: None A: 1 to 5 locations B: 6 to 10 locations C: 10 or more locations A small number of stained areas is an indicator that the function of the separation functional layer is not impaired.

[0124] <Example 1> (Production of porous hollow fiber support membrane) A uniform polymer solution consisting of 19% by mass of polysulfone (PSf; Solvay Specialty polymers, Udel-P3500), 61% by mass of N-methyl-2-pyrrolidone (Fujifilm Wako Pure Chemical Industries, Ltd.), and 20% by mass of tetraethylene glycol (Tokyo Chemical Industry Co., Ltd.) was prepared as a spinning dope. The dope was filled into a wet hollow fiber spinning machine equipped with a double spinneret. The dope at 35°C and an internal coagulation liquid (water) at 20°C were discharged from the double spinneret, and the dope was run for 250 mm in air with a relative humidity of 98% and adjusted to 30°C. The dope was then coagulated in a coagulation bath (external coagulation liquid) filled with water at 30°C, and wound up at a tension of 25 g using a free roll as a turn roll to obtain a hollow fiber support membrane. The obtained hollow fiber support membrane had an outer diameter of 1.02 mm, an inner diameter of 0.62 mm, and a membrane thickness of 0.20 mm.

[0125] (Fabrication of supported membrane module) 1,200 porous hollow fiber support membranes were packed into a cylindrical plastic housing with a diameter of 5 cm and a length of 50 cm, and fixed with adhesive. The housing was opened to give an effective length of 430 mm and an effective inner membrane surface area of ​​1.0 m. 2 A supported membrane module as shown in Fig. 1 was produced. In the module of Fig. 1, the hollow part of each hollow fiber passes through adhesive fixing parts 5 and 6, and the hollow part communicates with outer conduits 9 and 10. Meanwhile, inner conduits 2 and 3 communicate with the space outside the hollow fibers, but do not communicate with the hollow part of the hollow fibers. Therefore, by applying different pressures or reduced pressures to the outer conduits 9 and 10 and the inner conduits 2 and 3, a pressure difference can be created between the inside and outside of the hollow fibers.

[0126] (Formation of separation functional layer) An aqueous solution containing 2% by mass of m-phenylenediamine and 0.15% by mass of sodium lauryl sulfate (first solution) was passed through the inner surface side of the hollow fibers of the support membrane module for 20 minutes. After that, the solution was removed, and the hollow fibers were attached to the device shown in FIG. 2 while the inside of the hollow fibers were wet with the first solution. The degree of vacuum (absolute pressure) was adjusted using the inner pressure regulator 12 and the outer pressure regulator 13 to set the inner pressure to 101 kPaA, the outer pressure to 11 kPaA, and the inner / outer pressure difference to 90 kPa, so that the outside was reduced in pressure during polymerization. Excessive first solution was removed by flowing air at a flow rate of 210 cm / sec for 1 minute, and then an n-hexane solution (second solution) containing 0.23 mass% of 1,3,5-trimesoyl chloride was passed through for 2 minutes to form a separation functional layer on the inner surface of the hollow fiber by interfacial polymerization, and excess n-hexane solution was removed by flowing nitrogen gas at a flow rate of 210 cm / sec for 1 minute. Furthermore, the inside of the hollow fiber was washed by flowing warm water at 45° C. for 30 minutes at a flow rate of 5 cm / sec. Next, with the module still holding the liquid, the module was placed in an autoclave in an open state (abbreviated as method "AC" in Table 1) and cured (moist heat treatment) under conditions of a cure temperature of 121°C and a cure time of 60 minutes. Furthermore, by washing the heat-wet treated module with water at 20°C for more than 30 minutes, the effective length was increased to 430 mm and the membrane area to 1.0 m. 2 In addition, in the forward osmosis membrane obtained in Example 1, the arithmetic mean height (Sa) of the separation functional layer was 132 nm.

[0127] <Examples 2 to 11, Comparative Examples 1 to 6> As shown in Table 1, the evaluation was carried out under the same conditions as in Example 1, except for changing the material of the porous hollow fiber support membrane, the physical properties of the dense layer, the position of the separation functional layer, the polymerization conditions, the average thickness and its coefficient of variation, the curing conditions, the membrane area of ​​the module, etc.

[0128] More specifically, in Example 4, 240 porous hollow fiber support membranes were packed into a cylindrical plastic housing, with an effective inner membrane surface area of ​​0.2 m. 2 A supported membrane module was fabricated. In Example 6, a hollow fiber spinning dope containing 19 mass % polyethersulfone (PES; Ultrason E2020P, manufactured by BASF) and 20 mass % tetraethylene glycol was prepared. In Example 7, a hollow fiber spinning dope containing 21 mass % PSf and 20 mass % tetraethylene glycol was prepared and used, and the internal coagulation liquid was passed through the module at 5°C, so that the difference between the dope temperature and the internal coagulation liquid temperature (dope temperature - internal coagulation liquid temperature) was set to 30°C.

[0129] In Example 9, a hollow fiber spinning dope containing 20 mass % PSf and 20 mass % tetraethylene glycol was prepared and used, and the internal coagulation liquid was passed through the module at 5°C, so that the difference between the dope temperature and the internal coagulation liquid temperature (dope temperature - internal coagulation liquid temperature) was set to 30°C.

[0130] In Example 10, the internal coagulation liquid was passed through the module at 15°C, so that the difference between the temperature of the raw liquid and the temperature of the internal coagulation liquid (raw liquid temperature - internal coagulation liquid temperature) was set to 20°C, and 120 porous hollow fiber support membranes were packed into a cylindrical plastic housing, and the effective inner membrane surface area was 0.1 m. 2 A supported membrane module was fabricated.

[0131] In Example 11, a hollow fiber spinning solution containing 19% by mass of polyethersulfone (PES; Ultrason E2020P manufactured by BASF) and 20% by mass of tetraethylene glycol was prepared, and the internal coagulation liquid was passed through the module at 30°C, so that the difference between the temperature of the solution and the temperature of the internal coagulation liquid (solution temperature - internal coagulation liquid temperature) was set to 5°C.

[0132] In Comparative Example 1, 18 mass% of hydroxide-terminated polyethersulfone (PES-OH; BASF, Ultrason E2020PSR) and 20 mass% of tetraethylene glycol were dissolved in N,N-dimethylacetamide (DMAc) to prepare a hollow fiber spinning solution, and 50 mass% of tetraethylene glycol was also added to the internal coagulation solution as an additive.

[0133] In Comparative Example 6, a hollow fiber spinning stock solution consisting of 19 mass% polysulfone (PSf; Solvay Specialty polymers, Udel-P3500) and 81 mass% N-methyl-2-pyrrolidone (Fujifilm Wako Pure Chemical Industries, Ltd.) was prepared and used, and 20 mass% tetraethylene glycol was also added as an additive to the internal coagulation liquid. Furthermore, the internal coagulation liquid was passed through the module at 35°C, so that the difference between the stock solution temperature and the internal coagulation liquid temperature (stock solution temperature - internal coagulation liquid temperature) was set to 0°C.

[0134] In Comparative Example 5, the base material was a polyester nonwoven fabric (air permeability: 3 cc / (cm 2 A 20 wt % N,N-dimethylformamide (DMF) solution of polysulfone was cast onto a substrate at 25°C to a thickness of 190 μm (× sec), and the substrate was immersed in a coagulation liquid at 25°C and left for 20 minutes to produce a 200 μm-thick flat support membrane consisting of a laminate of a polyester nonwoven fabric substrate and a polysulfone porous support. The surface of this support membrane facing the polysulfone porous support was contacted with an aqueous solution (first solution) containing 2.0% by mass of m-phenylenediamine and 0.15% by mass of sodium lauryl sulfate for 20 minutes. After that, air was passed over the surface of the first solution coating to remove excess solution. Next, an n-hexane solution (second solution) containing 0.23% by mass of 1,3,5-trimesoyl chloride was contacted with the first solution coating for 2 minutes, and a separation functional layer was formed on the surface of the flat membrane support membrane by interfacial polymerization, forming a separation functional layer on the porous support. After that, nitrogen gas was passed over the surface on which the separation functional layer was formed to remove excess second solution, and then hot water at 45°C was passed over the surface on which the separation functional layer image was formed for 30 minutes. The obtained membrane was then placed in an autoclave, and high-temperature steam at 121°C was passed over it for 60 minutes, followed by washing with water at 20°C for 30 minutes to obtain a flat forward osmosis membrane. The obtained forward osmosis membrane was cut to a predetermined size and placed in a housing so that the membrane area was 1.0 m 2 A flat membrane cell was prepared. Unlike hollow fibers, the position of the separation functional layer in flat membranes is indicated by the front and back. Here, the back refers to the side that was in contact with the nonwoven fabric when the support membrane was produced, and the front refers to the side that was in more contact with the coagulation liquid.

[0135] Furthermore, in Examples 2 to 7 and Examples 9 to 11, the modules washed with warm water were cured by either placing the entire module in an autoclave while immersed in a water bath at 45°C or below, or by placing the module in an autoclave while water at 45°C or below was sealed in the module (at least in the initial state, 70% or more of the space on the separation functional layer side was filled with water and sealed to prevent liquid spillage) (method abbreviated as "water immersion AC" in Table 1).

[0136] In Comparative Examples 3 and 4, curing by AC or water immersion AC was not performed, and after removing excess n-hexane solution with nitrogen gas, the module was dried and cured for 20 minutes at temperatures of 50°C and 125°C, respectively.

[0137] The measurement results and evaluation results of Examples 1 to 11 and Comparative Examples 1 to 6 are shown in Table 1.

[0138] [Table 1] [Explanation of symbols]

[0139] 1. Hollow fiber membrane module 2 Outer conduit 3 Outer conduit 4 Hollow Fiber 5 Adhesive fixing part 6 Adhesive fixing part 7. Header 8. Header 9 Inner Conduit 10 Inner Conduit 11 Porous hollow fiber supported membrane module 12 Internal pressure regulator 13 External pressure regulator 14 Second solution storage tank 15 Second solution delivery pipe 16 Second solution delivery pump 17 Second solution drain tank 18 Second solution drainage pipe 19 End Cap 20 Effective membrane area

Claims

1. A forward osmosis membrane module comprising a plurality of hollow fiber forward osmosis membranes, The forward osmosis membrane has a separation functional layer provided on the surface of a hollow fiber support membrane having a porous support, The membrane area of ​​the forward osmosis membrane module is 0.1 m ２ That's all. the hollow fiber support membrane has a dense layer having a porosity of 9% or more and 25% or less at a position up to 1.0 μm in a depth direction from the interface between the porous support and the separation functional layer, The average thickness of the separation functional layer is 2.0 μm or less, and A forward osmosis membrane module, wherein the separation functional layer has a coefficient of variation of an average thickness of the separation functional layer in the radial direction and the longitudinal direction of the forward osmosis membrane module of 25% or less.

2. The forward osmosis membrane module according to claim 1 , wherein the coefficient of variation of the average thickness of the separation functional layer is 20% or less.

3. The forward osmosis membrane module according to claim 1 or 2, wherein the separation functional layer has an uneven structure.

4. A forward osmosis membrane module as described in claim 1 or 2, wherein the porosity of the dense layer is 9% or more and 19% or less.

5. The forward osmosis membrane module according to claim 1 or 2, wherein the separation functional layer has an average thickness of 0.05 μm or more.

6. The forward osmosis membrane module according to claim 1 or 2, wherein the average thickness of the separation functional layer is 0.2 to 0.8 μm.

7. The forward osmosis membrane module according to claim 1 or 2, wherein the dense layer has a separation functional layer component that has penetrated into the pores of the dense layer.

8. The forward osmosis membrane module according to claim 1 or 2, wherein the separation functional layer is provided on an inner surface of the hollow fiber support membrane.

9. 3. The forward osmosis membrane module according to claim 1, wherein the hollow fiber support membrane is composed only of the porous support and the separation functional layer.

10. The forward osmosis membrane module according to claim 1 or 2, wherein the porous support contains polysulfone or polyethersulfone as a main component.

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