Cosmetic

Abstract

To provide a cosmetic exhibiting excellent post-application moisturizing sensation and allowing suppression of brightness variation of an applied film before and after drying.SOLUTION: A cosmetic comprising the following components (A)-(F): (A) a metal oxide whose surface is coated with a hydrophobically surface-treated agent, (B) a metal oxide whose surface is coated with an acylated amino acid or a salt thereof, (C) a metal oxide whose surface is coated with a phospholipid, (D) a polyhydric alcohol, (E) an oily agent that is liquid at 25°C, and (F) a colored pigment whose surface is coated with a hydrophobically surface-treated agent, wherein the component (A) excludes the components (B) and (C), the metal oxides of the components (A), (B), and (C) may be the same or different and each include one or more pigments selected from titanium oxide and zinc oxide, and the component (F) excludes the components (A), (B), and (C).SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a cosmetic preparation. [Background technology]

[0002] Pigments are used to color cosmetics or topical skin preparations. Among pigments, metal oxides used in cosmetics can color cosmetics to brighten their appearance, change the color of skin, lips, and nails to enhance a specific impression, and correct imperfections such as blemishes and freckles. In this context, technology for precisely controlling the color of cosmetics is important. In particular, after applying cosmetics to skin or lips, aggregation and localization of metal oxides can occur within the applied film, causing changes in brightness and hue. Therefore, it is important to suppress this color change and realize a color consistent with the intended appearance. Specifically, for example, Patent Document 1 discloses a water-in-oil emulsion makeup cosmetic that suppresses color change immediately after application by treating a metal oxide with a metal soap, combining it with an ester oil or the like, and using a metal soap-treated metal oxide in an amount of 50 mass % or more of the total amount of white pigment and colored pigment. On the other hand, in cosmetics or topical skin preparations, polyhydric alcohols are also used to impart an emollient effect because they have the function of retaining moisture in the skin or lips. Technologies have been disclosed regarding cosmetics that suppress changes in appearance color and applied color, and cosmetics that impart an emollient effect using polyhydric alcohols. Specifically, for example, Patent Document 2 discloses a technique in which a moist feeling is obtained after application by blending polyglycerin fatty acid ester, polyethylene hydrogenated castor oil, and a specific polyhydric alcohol. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Laid-Open No. 2009-269881 [Patent Document 2] Japanese Patent Publication No. 2023-180033 Summary of the Invention [Problem to be solved by the invention]

[0004] However, for example, the technology for inhibiting color change immediately after application, as in Patent Document 1, is insufficient in its effect of inhibiting color change when a large amount of polyhydric alcohol is blended. Also, for example, the technology for achieving a moisturizing feeling, as in Patent Document 2, is a technology related to a cosmetic composition with a transparent appearance that contains a small amount of pigment, and no effect of inhibiting color change before and after drying of the applied film has been found when a sufficient amount of metal oxide is blended. When a cosmetic composition containing a large amount of polyhydric alcohol also contains a large amount of pigment, the polyhydric alcohol does not dissolve in the oil and forms a localized coating film, making the pigment more likely to aggregate during application, resulting in larger differences in brightness and hue before and after drying of the coating film compared to when the cosmetic composition does not contain a large amount of polyhydric alcohol. Therefore, the inventors have an objective to provide a cosmetic composition that provides an excellent moisturizing feeling after application while suppressing the difference in brightness before and after drying of the coating film. [Means for solving the problem]

[0005] As a result of further intensive research, the present inventors have found that by combining a polyhydric alcohol, an oil agent that is liquid at 25°C, and a color pigment that contains a surface-coated metal oxide having specific surface properties and is further surface-coated with a hydrophobic surface treatment agent, it is possible to achieve an excellent moisturizing feel after application while suppressing the difference in brightness of the applied film before and after drying.

[0006] That is, the means for solving the above problems of the present invention include the following aspects. [1] The following components (A) to (F); (A) Metal oxide surface-coated with a hydrophobic surface treatment agent (B) Metal oxide surface-coated with an acylated amino acid or its salt (C) Metal oxide surface coated with phospholipid (D) Polyhydric alcohol (E) An oil that is liquid at 25°C (F) Colored pigments coated with a hydrophobic surface treatment agent Contains The component (A) is excluding the component (B) and the component (C), The metal oxides of the components (A), (B), and (C) may be the same or different, and each metal oxide is a pigment containing one or more metal oxides selected from titanium oxide and zinc oxide; The component (F) is a component other than the components (A), (B), and (C). Cosmetics are provided. [2] The present invention provides a cosmetic according to [1], wherein the metal oxides of the components (A), (B), and (C) have an average particle size of 100 to 1000 nm. [3] The present invention provides a cosmetic composition according to [1] or [2], wherein the hydrophobic surface treatment agent of component (A) is one or more selected from the group consisting of triethoxycaprylylsilane, polyglycerol fatty acid ester, dimethylpolysiloxane, and fatty acid or salt thereof. [4] The cosmetic preparation according to [1] or [2], wherein the acylated amino acid or its salt of component (B) is one or more selected from acylated glutamic acid or its salt, or acylated aspartic acid or its salt. [5] The cosmetic composition according to [1] or [2], wherein the component (D) is one or more selected from the group consisting of glycerin, 1,3-butylene glycol, diglycerin, and tripropylene glycol. [6] The cosmetic composition according to [1] or [2], wherein the mass of the component (D) is 3 to 13 mass %. [7] The cosmetic preparation according to [1] or [2], wherein the mass ratio of the components (A), (B), and (C) is (A):(B):(C)=0.3-15:0.3-15:0.5-20. [8] The mass percentage of each (MO) of the component (A), the component (B), and the component (C) relative to the total (MO) contained in the cosmetic, where (MO) is the total mass percentage of the pure titanium oxide and zinc oxide; [(MO) of component (A)] / [total (MO) in the cosmetic] and [(MO) of component (B)] / [total (MO) in the cosmetic] are 0.15 to 0.4, The cosmetic according to [1] or [2] is provided, wherein the ratio of (MO) of component (C) to the total (MO) in the cosmetic is 0.25 to 0.7. That is why. [9] The cosmetic preparation according to [1] or [2], wherein the component (F) is one or more selected from the group consisting of yellow iron oxide, black iron oxide, iron oxide such as red iron oxide, black titanium oxide, ultramarine, Prussian blue, chromium oxide, chromium hydroxide, manganese oxide, carbon black, and tar dyes.

[10] The cosmetic composition according to [1] or [2], wherein the component (E) is one or more selected from the group consisting of phenyl-modified silicone, alkyl-modified silicone, hydrocarbon oil, and ester oil.

[11] The cosmetic according to [1] or [2] is provided, wherein the cosmetic is a water-in-oil cosmetic.

[12] The cosmetic according to [1] or [2], wherein the cosmetic is a makeup cosmetic.

[13] The following components (D)~(F), (A2)~(C2); (D) Polyhydric alcohol (E) An oil that is liquid at 25°C (F) Colored pigments coated with a hydrophobic surface treatment agent (A2) A metal oxide surface-coated with a hydrophobic surface treatment agent, which disperses in component (E) when added to a two-phase liquid in which the mass ratio of component (D) to component (E) is 1:1. (B2) A metal oxide surface-coated with a hydrophobic surface treatment agent, which disperses at the interface between component (D) and component (E) when added to a two-phase liquid in which the mass ratio of component (D) to component (E) is 1:1. (C2) A metal oxide surface-coated with a hydrophobic surface treatment agent that disperses in component (D) when added to a two-phase liquid in which the mass ratio of component (D) to component (E) is 1:1. Contains the metal oxides of the components (A2), (B2), and (C2) may be the same or different, and each metal oxide is a pigment containing one or more metal oxides selected from titanium oxide and zinc oxide; The present invention provides a cosmetic in which the component (F) excludes the components (A2), (B2), and (C2). [Effects of the Invention]

[0007] According to the present invention, it is possible to provide a cosmetic that has an excellent moisturizing feeling after application and can suppress the difference in brightness between before and after drying of the applied film. [Brief explanation of the drawings]

[0008] [Figure 1] This is an image showing the properties of component (A2), component (B2), and component (C2). An image of a No. 8 standard bottle containing 20 g of component (D) glycerin, with a dispersion of components (E)(E1):(E2)=1:1 ((E1) isotridecyl isononanoate, (E2) methyl trimethicone) (total 20 g) and 1 g of each of the above components (A), (B), and (C) poured into the top, and the image was left to stand for one hour. DETAILED DESCRIPTION OF THE INVENTION

[0009] Preferred embodiments of the present invention will be described in detail. However, the present invention is not limited to the following preferred embodiments and can be freely modified within the scope of the present invention. In this specification, percentages are expressed by mass unless otherwise specified. Furthermore, in this specification, when a numerical range is expressed using "to," the range includes both ends. Furthermore, the upper limit (or less) and the lower limit (or more) of each numerical range (to) can be arbitrarily combined as desired. Furthermore, the "average particle size" in this specification refers to the number-average particle size (D50) obtained by observing the surface condition using a scanning electron microscope (JEOL, JSM-7800prime) and measuring with an image analyzer (Luzex AP, Nireco Corporation). In the case of asymmetric shapes, the median diameter D50 obtained from the distribution of the largest particle major diameter is defined as the average particle size in this specification. Note that 1 μm may also be expressed as 1,000 nm.

[0010] <Pigments containing one or more selected from titanium oxide and zinc oxide> The "component (A) metal oxide surface-coated with a hydrophobic surface treatment agent," "component (B) metal oxide surface-coated with an acylated amino acid or its salt," and "component (C) metal oxide surface-coated with a phospholipid" used in the present invention are metal oxides coated with specific hydrophobic surface treatment agents. The components (A), (B), and (C) used in the present invention are each metal oxides coated with a hydrophobic surface treatment agent, which is particularly an organic substance. Examples of "metal oxides" that are typically used in cosmetics and the like include titanium oxide, iron oxide, cerium oxide, zirconium oxide, and zinc oxide. However, the metal oxides of components (A), (B), and (C) may be the same or different, and the metal oxides that are the bases of components (A), (B), and (C) used in the present invention are pigments containing one or more types selected from titanium oxide and zinc oxide.

[0011] The "pigment containing one or more elements selected from titanium oxide and zinc oxide" used in the present invention may contain, on the surface or inside of the metal oxide, oxides of one or more elements selected from Al (aluminum), Mg (magnesium), Sn (tin), Co (cobalt), Fe (iron), Si (silicon), Zn (zinc), Ti (titanium), and Ce (cerium), and preferably refers to a metal oxide particle containing these inorganic components (elements) such as Al. Hereinafter, this will be referred to as a "powder containing titanium oxide and zinc oxide." The mass content (pure mass %) of "titanium oxide and zinc oxide" in the particles is not particularly limited, but preferably the "powder containing titanium oxide and zinc oxide" contains 60 mass % or more of "titanium oxide and zinc oxide" in the pigment particles. The mass percent pure content can be obtained by measuring a sample prepared using a common method using ICP (Inductively Coupled Plasma; ARCOS (Spectro GmbH, Germany)) optical emission spectrometry, but in the case of commercially available products, the content can also be determined from the content listed on the SDS.

[0012] The mass content of "titanium oxide and zinc oxide" used in the present invention is considered to be the pure content mass %. [The total amount of the pure content mass % of titanium oxide and zinc oxide] will be referred to below as (MO): (short for Metal Oxide). Furthermore, the mass content of the "powder containing titanium oxide and zinc oxide" is considered to be the mass content excluding the organic hydrophobic surface treatment agent. Furthermore, the mass content of each of the components (A), (B), and (C) is considered to be that of a metal oxide powder coated with each hydrophobic surface treatment agent. Furthermore, the "powder containing titanium oxide and zinc oxide" may be an iron oxide-coated metal oxide whose surface is coated with iron oxide or hydroxide, or an iron-doped metal oxide in which iron is doped inside a metal oxide. Examples of the iron oxide or hydroxide include iron oxide-coated titanium oxide or iron oxide-coated zinc oxide, in which the surface of titanium oxide or zinc oxide is coated with iron oxide, and iron-doped titanium oxide or iron-doped zinc oxide, in which the inside of titanium oxide or zinc oxide is doped with iron. Furthermore, the powder may be coated with silicon oxide or hydroxide, or aluminum oxide or hydroxide. It is particularly preferable to include titanium oxide, but this is not particularly limited.

[0013] The shape of the "powder containing titanium oxide and zinc oxide" used in the present invention, and the shapes of the components (A), (B), and (C) are not particularly limited as long as they are those typically used in cosmetics, such as spherical, plate-like, and needle-like shapes, and any of these shapes can be used, and one or more types may be combined. The average particle size of each of the components (A), (B), and (C) used in the present invention refers to the average particle size of pigment particles in the "powder containing titanium oxide and zinc oxide," which is the size determined by the matrix other than the organic hydrophobic surface treatment agent. For example, the average particle size of each of the components (A), (B), and (C) can be obtained by measuring the "powder containing titanium oxide and zinc oxide" before hydrophobic treatment. However, when each of the components (A), (B), and (C) is used as pigment particles and further used as a composite powder with "other powders," the average particle size of the "other powders" is not taken into consideration, and the average particle size of the "powder containing titanium oxide and zinc oxide" before hydrophobic treatment is used.

[0014] Commercially available titanium oxide powders for use in the present invention include TIPAQUE CR-50 (manufactured by Ishihara Sangyo Kaisha, Ltd., average particle size 0.25 μm), TIPAQUE PFC 407 (manufactured by Ishihara Sangyo Kaisha, Ltd., average particle size 0.25 μm), FTL-100 (manufactured by Ishihara Sangyo Kaisha, needle-shaped, fiber length 0.168 μm, fiber diameter 0.13 μm), MP-1133 (manufactured by Teika Co., Ltd., average particle size 0.25 μm), MP-100 (manufactured by Teika Co., Ltd., average particle size 1 μm), ST-705SA (manufactured by Titanium Kogyo Co., Ltd., sea urchin-shaped, average particle size 0.25 μm), and SOLAVEIL XTP-1 (manufactured by Croda Co., Ltd., average particle size 0.14 μm). Examples of zinc oxide include XZ-300F (manufactured by Sakai Chemical Industry Co., Ltd., hexagonal plate shape, average particle diameter 300 nm) and XZ-1000F (manufactured by Sakai Chemical Industry Co., Ltd., hexagonal plate shape, average particle diameter 1000 nm).

[0015] The total average particle size (further average value of each average particle size) of the "powder containing titanium oxide and zinc oxide" used in the present invention is preferably 100 nm or more, more preferably 150 nm or more, and even more preferably 200 nm or more, as a preferred lower limit, and preferably 1000 nm or less, more preferably 500 nm or less, and even more preferably 400 nm or less, as a preferred upper limit. A preferred range is preferably 100 to 1000 nm, more preferably 150 to 500 nm, and even more preferably 200 to 400 nm. This range is preferred because it results in a small difference in brightness between before and after drying of the coating film. The total average particle size of the base particles is calculated as the weighted average particle size of the average particle size of the pigment particles of the "powder containing titanium oxide and zinc oxide" [the sum of each (average particle size x content) / the sum of each content].

[0016] Each component will be specifically described below. <Component (A)> Component (A) used in the present invention refers to titanium oxide and zinc oxide coated with a hydrophobic surface treatment agent, excluding components (B) and (C). In the present invention, "surface-coated with a hydrophobic surface treatment agent" refers to a material that primarily floats on the water when component (A) is dispersed in water at 25°C and stirred at 1,000 rpm for 5 minutes using a Desper agitator, but this is not particularly limited. Furthermore, component (A) is preferably one that disperses in component (E) when added to a two-phase liquid in which components (D) and (E) are mixed in a 1:1 mass ratio. A material that falls within this definition is referred to as component (A2). The hydrophobic surface treatment agent is not particularly limited, but may be solid, semi-solid, or liquid at room temperature, and may be chemically or physically adsorbed so as to be reactive with the surfaces of titanium oxide and zinc oxide. There are no particular limitations on the hydrophobic surface treatment agent, as long as it is coated with a hydrophobic surface treatment agent other than components (B) and (C). Examples of hydrophobic surface treatment agents include silicone compounds, treatment agents having an aliphatic group having 8 to 24 carbon atoms, coupling agents having an aliphatic group having 8 to 24 carbon atoms, specifically silane-based coupling agents such as alkylalkoxysilane treatment, aluminum-based coupling agents, titanium-based coupling agents, fatty acids or salts thereof, fatty acid esters, etc. These may be used alone or in combination of two or more. Examples of silicone compounds include dimethylpolysiloxane, dimethiconol, and methylhydrogenpolysiloxane. Examples of surface treatment agents having a structure with a fatty group having 8 to 24 carbon atoms include hydrocarbons, polyethylene oxide, fatty acids or salts thereof (e.g., stearic acid, isostearic acid, zinc stearate, magnesium stearate, zinc myristate, and zinc laurate), fatty acid esters (e.g., vegetable oils, animal oils, glycerin fatty acid esters, polyglycerin fatty acid esters, and polysaccharide fatty acid esters (e.g., dextrin fatty acid esters and inulin fatty acid esters)), fatty acid amides, and ceramides. Examples of coupling agents include triethoxycaprylylsilane, aminopropyltriethoxysilane, and isopropyl titanium triisostearate. Examples of commercially available products include OTS (triethoxycaprylylsilane) treatment, ITT (isopropyl titanium triisostearate) treatment, S-STM, MST (magnesium stearate) treatment, PGQ (polyglyceryl-2 tetraisostearate) treatment, etc. (manufactured by Daito Chemical Industry Co., Ltd.), ALT (triethoxycaprylylsilane) treatment, SA (dimethicone) treatment, MI treatment (aluminum dimyristate) treatment, etc. (manufactured by Miyoshi Chemical Industry Co., Ltd.), but are not limited to these. Specific raw materials for component (A) include OTS-2 TiO2 MP-1133 (triethoxycaprylylsilane 2% treated titanium dioxide, aluminum hydroxide 2.6% treated titanium dioxide (average particle size 270 nm)), ITT-1 TiO2 CR-50 (isopropyl titanium triisostearate 2% treated titanium dioxide, aluminum hydroxide 3% treated titanium dioxide (average particle size 250 nm)), PGQ-2 TiO2 R250 (polyglyceryl-2 tetraisostearate 2% treated titanium dioxide, aluminum hydroxide 3% treated titanium dioxide (average particle size 250 nm)) (all manufactured by Daito Chemical Industry Co., Ltd.), ALT-TSR-10 (triethoxycaprylylsilane treated titanium dioxide, aluminum hydroxide treated titanium dioxide), SA Examples include CR-50 (2% dimethicone treatment, aluminum hydroxide-treated titanium oxide (average particle size 250 nm), talc 19.6%) (all manufactured by Miyoshi Chemicals Co., Ltd.), and XZ-300F-LP (0.75% hydrogen dimethicone-treated hexagonal plate-shaped zinc oxide (average particle size 0.3 μm)) (manufactured by Sakai Chemical Industry Co., Ltd.).

[0017] The hydrophobic surface treatment agent of component (A) used in the present invention is not particularly limited, but is preferably one or more selected from triethoxycaprylylsilane, polyglycerin fatty acid ester, dimethylpolysiloxane, and fatty acid or its salt, and more preferably triethoxycaprylylsilane. Two or more may be used in combination. This treatment agent is preferred because it results in a small difference in brightness between the coated film before and after drying.

[0018] The content of the hydrophobic surface treatment agent in component (A) used in the present invention is preferably 0.1% by mass (hereinafter referred to as %) or more, more preferably 0.2% or more, and even more preferably 0.3% or more, relative to the amount of component (A). The upper limit is preferably 5% or less, more preferably 4% or less, and even more preferably 3% or less. The range is preferably 0.1 to 5%, more preferably 0.2 to 4%, and even more preferably 0.3 to 3%. This range is more preferable in that the difference in brightness between before and after drying of the coating film is small.

[0019] The content of component (A) used in the present invention is not particularly limited, but the lower limit of the total amount of the cosmetic is preferably 0.3% or more, more preferably 0.5% or more, and even more preferably 1.0% or more. The upper limit is preferably 15% or less, more preferably 11% or less, and even more preferably 7% or less. The range is preferably 0.3 to 15%, more preferably 0.5 to 11%, and even more preferably 1.0 to 7%. This range is preferable in that it provides a moisturizing feel after application and minimizes the difference in brightness between before and after drying of the applied coating film.

[0020] <Ingredient (B)> Component (B) used in the present invention is a metal oxide, titanium oxide or zinc oxide, surface-coated with an acylated amino acid or its salt. The acylated amino acid is an amino acid in which the hydrogen atom of the amino group is substituted with an acyl group, and the acyl group is saturated or unsaturated, linear, or cyclic, having 1 to 22 carbon atoms. Examples of such amino acids include N-acetylglutamic acid, N-lauroylglutamic acid, disodium N-lauroylglutamate, magnesium N-palmitoylglutamate, N-myristylalanine, N-N-oleylthreonine, N-cinnamoylglycine, N-nicotinoylglutamic acid, disodium stearoylglutamate, and disodium cocoylglutamate. It is preferable that component (B) disperses at the interface between components (D) and (E) when added to a two-phase liquid in which the mass ratio of components (D) and (E) is 1:1. A component (B) that fits this definition is referred to as component (B2). When the hydrophobic surface treatment agents of components (A) and (C) and the hydrophobic surface treatment agent of component (B) are used in combination for simultaneous treatment, it is preferable to consider them as (B). Specific examples of commercially available surface treatment products include, but are not limited to, NAI (N-lauroyl-L-glutamic acid disodium) treatment, NHS (NAI + HS: isostearyl sebacate) treatment, CAI (cocoyl glutamic acid disodium) treatment, LP (palmitoyl proline, palmitoyl sarcosine sodium, palmitoyl glutamic acid magnesium, palmitic acid) treatment (all manufactured by Miyoshi Chemicals Co., Ltd.), ASL (lauroyl glutamic acid, lysine, magnesium chloride) treatment, ASI (lauroyl aspartic acid sodium, zinc chloride) treatment, and LL (lauroyl lysine) treatment (manufactured by Daito Chemical Industry Co., Ltd.). Commercially available products for component (B) include NAI-treated powders (manufactured by Miyoshi Chemicals) such as NAI-C47051-10 (3% disodium glutamate, titanium dioxide treated with approximately 3% aluminum hydroxide), NAI-PFC407 (3% disodium glutamate, titanium dioxide treated with approximately 3% aluminum hydroxide), and NAI-MP-1133 (3% disodium glutamate, titanium dioxide treated with approximately 3% aluminum hydroxide), ASL (sodium dilauroyl glutamate lysine, magnesium chloride)-treated powders such as ASL-1 TiO2 MP-1133, ASI (isopropyl titanium triisostearate, sodium lauroyl aspartate)-treated powders such as ASI TiO2 TiO2 CR-50, and LL (lauroyl lysine)-treated powders (manufactured by Daito Chemical Industry Co., Ltd.) such as LL-TiO2CR-50.

[0021] The acylated amino acid or salt thereof of component (B) used in the present invention is not particularly limited, but is preferably acylated glutamic acid or a salt thereof, or acylated aspartic acid or a salt thereof. Acylated glutamic acid or a salt thereof is particularly preferred. This treatment agent is preferred because it results in a small difference in brightness between the coated film before and after drying.

[0022] The surface coating amount of the acylated amino acid or its salt in component (B) used in the present invention is preferably 0.1% or more, more preferably 0.2% or more, and even more preferably 0.3% or more, relative to the amount of component (B). The upper limit is preferably 5% or less, more preferably 4% or less, and even more preferably 3% or less. The range is preferably 0.1 to 5%, more preferably 0.2 to 4%, and even more preferably 0.3 to 3%. This range is more preferable in that the difference in brightness between before and after drying of the coating film is small.

[0023] The content of component (B) used in the present invention, relative to the total amount of the cosmetic, is preferably 0.3% or more, more preferably 0.5% or more, and even more preferably 1.0% or more. The upper limit is preferably 15% or less, more preferably 11% or less, and even more preferably 7% or less. The range is preferably 0.3 to 15%, more preferably 0.5 to 11%, and even more preferably 1.0 to 7%. This range is preferable in that it provides a moisturizing feel after application and minimizes the difference in brightness between before and after drying of the applied film.

[0024] <Component (C)> Component (C) used in the present invention is titanium oxide and zinc oxide surface-coated with a phospholipid. Phospholipids have a structure in which a fatty acid and a phosphoric acid are bonded to a central skeleton of glycerin or sphingosine, and an alcohol is further ester-bonded to the phosphoric acid. There are many types of phospholipids, depending on the type of fatty acid and alcohol, or they may be polymers having a 2-methacryloyloxyethyl phosphorylcholine skeleton. The phospholipid is not particularly limited as long as it is one that is commonly used in cosmetics. Examples include glycerophospholipids such as phosphatidylcholine (i.e., lecithin), phosphatidylethanolamine, phosphatidylserine, phosphatidylinositol, phosphatidylglycerol, diphosphatidylglycerol, and phosphatidic acid. Lysophospholipids and cyclic phospholipids are also acceptable. These may be used singly or in combination. Furthermore, purified or hydrogenated phospholipids (e.g., hydrogenated soybean phospholipids) may also be included. Component (C) is preferably one that disperses in component (D) when added to a two-phase liquid in which components (D) and (E) are mixed in a 1:1 mass ratio. A component that falls within this definition is designated component (C2). A component containing phosphatidylcholine is particularly preferred. When components (A) and (C) are used together as hydrophobic surface treatment agents for simultaneous treatment, it is preferable to consider them as component (C).

[0025] The surface coating amount of the phospholipid in component (C) used in the present invention is preferably 0.1% or more, more preferably 0.2% or more, and even more preferably 0.3% or more, relative to the amount of component (C). The upper limit is preferably 5% or less, more preferably 4% or less, and even more preferably 3% or less. The range is preferably 0.1 to 5%, more preferably 0.2 to 4%, and even more preferably 0.3 to 3%. This range is more preferable in that the difference in brightness between before and after drying of the coating film is small.

[0026] The content of component (C) used in the present invention, relative to the total amount of the cosmetic, is preferably 0.5% or more, more preferably 0.8% or more, and even more preferably 1.5% or more. The upper limit is preferably 20% or less, more preferably 15% or less, and even more preferably 10% or less. The range is preferably 0.5 to 20%, more preferably 0.8 to 15%, and even more preferably 1.0 to 10%. This range is preferable in that it provides a moisturizing feel after application and minimizes the difference in brightness between before and after drying of the coating film.

[0027] The method for surface-treating the pigment particles of the "powder containing titanium oxide and zinc oxide" of each of the components (A), (B), and (C) used in the present invention is not particularly limited, and any known treatment method conventionally used to modify powders used in makeup cosmetics can be used. For example, wet methods using a solvent or dry methods in the gas phase can be used. Mixing with a volatile solvent or oil, followed by dispersion or drying to obtain a fine powder, is particularly preferred. Specific examples of volatile solvents include alcohol solvents such as isopropyl alcohol, hydrocarbon solvents such as hexane and isododecane, and volatile silicone solvents such as dimethicone. Wet methods using these solvents result in a uniform surface treatment and improved dispersibility. Specifically, in the case of wet methods, it is preferable to dissolve a hydrophobic surface treatment agent in a solvent, add the "powder containing titanium oxide and zinc oxide," and uniformly mix and disperse or wet the powder using a mixer such as a Henschel mixer, kneader, ultramixer, bead mill, or roll mill. There are no particular limitations on the method, which involves adding the resulting mixture to a cosmetic as a dispersion without recovering the solvent, or recovering or evaporating the solvent, drying the mixture to homogenize it, and then pulverizing the resulting mixture. When pulverizing the resulting mixture in a dry state, examples of the pulverizing method include devices such as a jetmizer, atomizer, grinder, etc., which are commonly used to disintegrate granulated powders.

[0028] The total mass content of the components (A), (B), and (C) used in the present invention is preferably 1.5% or more, more preferably 3.0% or more, and even more preferably 5.0% or more as a suitable lower limit, and is preferably 45% or less, more preferably 30% or less, and even more preferably 20% or less as an upper limit. A suitable numerical value is 1.5 to 45%, more preferably 3.0 to 30%, and more preferably 5.0 to 20%.

[0029] With respect to the mass ratio of the components (A), (B), and (C) used in the present invention, the preferred ratio (A):(B):(C) is in the range of 0.3-15:0.3-15:0.5-20. The same applies to the preferred ratio (A2):(B2):(C2) with respect to the mass ratio of the components (A2), (B2), and (C2) used in the present invention. This range is preferred in that it results in a small difference in brightness between the coated film before and after drying.

[0030] The total mass % of the pure titanium oxide and zinc oxide used in the present invention is defined as (MO), and the mass ratio of each of the (MO) components (A), (B), and (C) to the total (MO) contained in the cosmetic is: The ratios of [(MO) of component (A)] / [total (MO) in the cosmetic] and [(MO) of component (B)] / [total (MO) in the cosmetic] are preferably at least 0.15, more preferably at least 0.20, and even more preferably at least 0.25, and are preferably at most 0.4. Also, a ratio of 0.15 to 0.4 is preferred, with a ratio of 0.2 to 0.4 being more preferred. This range is preferred because it results in a small difference in brightness between the coated film before and after drying. Furthermore, the ratio (MO) of component (C) / total (MO) in the cosmetic is preferably at least 0.25, more preferably at least 0.30, and even more preferably at least 0.35, while the upper limit is preferably at most 0.7, more preferably at most 0.6. The range is more preferably 0.25 to 0.7, and more preferably 0.3 to 0.6. This range is preferred because it results in a small difference in brightness between the coated film before and after drying.

[0031] <Ingredient (D)> Component (D) used in the present invention is a polyhydric alcohol. Component (D) is a glycol having two or more hydroxyl groups, and glycols having 3 to 12 carbon atoms are more preferred. There are no particular limitations on the component (D) as long as it is one typically used in cosmetic compositions, and it can be contained alone or in combination of two or more. Specific examples include glycerin, diglycerin, 1,3-butylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, 1,2-pentanediol, pentylene glycol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, sorbitol, xylitol, raffinose, glucose, and maltitol. Other examples include polyoxyethylene methyl glucoside and polyethylene glycol. In particular, in the case of glycols containing polyethylene glycol chains, a degree of polymerization of 20 or less is preferred, but this is not particularly limited.

[0032] The component (D) used in the present invention is not particularly limited, but among glycols having 3 to 12 carbon atoms, glycerin, 1,3-butylene glycol, diglycerin, and tripropylene glycol are more preferred. Glycerin is particularly preferred. This component is more preferred because it provides an excellent moisturizing feeling after application.

[0033] The content of component (D) used in the present invention, relative to the total amount of the cosmetic, is preferably 3% or more as a lower limit, more preferably 4% or more, and even more preferably 5% or more. This range is more preferable in that it provides an excellent moisturizing feeling after application. The upper limit is preferably 13% or less, more preferably 10% or less, even more preferably 9% or less, and even more preferably 8% or less. The range is preferably 3 to 13%, more preferably 4 to 10%, and even more preferably 5 to 9%. This range is more preferable in that it provides a small difference in brightness between before and after drying of the coating film.

[0034] The mass ratio of component (D) to the total mass (MO) of all titanium oxide and zinc oxide pigments contained in the cosmetic used in the present invention, (D) / [total (MO) in the cosmetic], is preferably 0.1 or more, more preferably 0.3 or more, and even more preferably 0.5 or more, as a lower limit. This range is preferable in terms of providing an excellent moisturizing feeling after application. The upper limit is preferably 3.0 or less, more preferably 2.0 or less, and even more preferably 1.0 or less. This range does not particularly affect the difference in brightness of the applied film before and after drying, but is more preferable in terms of cosmetic durability.

[0035] <Ingredient (E)> The oil agent (E) used in the present invention that is liquid at 25°C is not particularly limited as long as it is one that is normally incorporated into cosmetics, and can be appropriately selected and obtained. Examples include hydrocarbon oils, ester oils, higher alcohols having 12 to 22 carbon atoms, fatty acids having 12 to 22 carbon atoms, and silicone oils, and one or a combination of two or more types can be contained. There is no particular limit as to whether it is volatile or non-volatile. An oil agent having a fatty group having 6 or more carbon atoms is referred to as (E1), and an oil agent that does not have a fatty group having 6 or more carbon atoms is referred to as (E2). The hydrocarbon oil is (E1), and examples of non-volatile oils include liquid paraffin, liquid isoparaffin, heavy liquid isoparaffin, squalane, pristane, squalene, etc. The volatile hydrocarbon oil is a hydrocarbon oil having a boiling point of 260°C or less at normal pressure, and is not particularly limited, and examples thereof include hydrocarbons having a side chain such as isooctane, isododecane, isohexadecane, isoeicosaene, etc., isoparaffin, or a mixture thereof, isobutene, n-butene, etc., polymerized or copolymerized (the degree of polymerization is preferably 4 to 6), and then hydrogenated, and the like, and one or more types can be used in combination as necessary. The ester oil is (E1), and examples thereof include isononyl isononanoate, isotridecyl isononanoate, octyldodecyl myristate, isopropyl myristate, isocetyl myristate, isostearyl myristate, octyldodecyl myristate, isopropyl isostearate, oleyl oleate, octyldodecyl ricinoleate, 2-ethylhexyl p-methoxycinnamate, tocopherol acetate, alkyl benzoates such as alkyl benzoates (C12 to C15), and isopropyl palmitate. Examples of suitable oils include monoester oils such as isopropyl, ethylhexyl palmitate, and 2-hexyldecyl palmitate, diester oils such as di-2-ethylhexyl sebacate, diisopropyl sebacate, diethylene glycol dicaprate, neopentyl glycol dicaprate, neopentyl glycol di-2-ethylhexanoate, and diisostearyl malate, triester oils such as glyceryl tri-2-ethylhexanoate and caprylic / capric triglyceride, and ethylhexyl salicylate. Commercially available oils include Salacos 913 (manufactured by Nisshin Oillio Co., Ltd.), UVINUL MC80 (manufactured by BASF), Crodamol OSU (manufactured by Croda Japan), and Finsolv TN (manufactured by Innospec Performance Chemicals Europe Limited). The higher alcohol having 12 to 22 carbon atoms is (E1), and examples thereof include oleyl alcohol, 2-decyltetradecynol, dodecanol, isostearyl alcohol, and octyldodecanol. The fatty acid having 12 to 22 carbon atoms is (E1), and examples thereof include oleic acid, isostearic acid, linoleic acid, and linolenic acid. Silicone oils are (E2), and examples thereof include linear silicone oils (volatile and non-volatile) such as dimethylpolysiloxane, as well as branched silicones such as methyl trimethicone (volatile). Examples of (E1) include phenyl-modified silicones (non-volatile), alkyl-modified silicones, and dimethyl diethyl benzal malonate (non-volatile). Commercially available products include KF-96A-6CS (Shin-Etsu Chemical Co., Ltd.) as a dimethylpolysiloxane and Silicone SH556FLUID (Dow Corning Toray Co., Ltd.) as a phenyl-modified silicone. In particular, oils (E1) having a fatty group having 6 or more carbon atoms are preferred, and specifically, from the viewpoint of achieving an excellent difference in brightness between before and after drying of the coated film, one or more oils selected from phenyl-modified silicones, alkyl-modified silicones, hydrocarbon oils, and ester oils are preferred. Note that (E1) may be used in combination with silicone oil, which is oils (E2) that do not have a fatty group having 6 or more carbon atoms.

[0036] The content of component (E) used in the present invention is not particularly limited, but the lower limit of the total amount of the cosmetic is preferably 5% or more, more preferably 10% or more, and even more preferably 15% or more. The upper limit is preferably 65% ​​or less, more preferably 55% or less, and even more preferably 45% or less. The range is preferably 5 to 65%, more preferably 10 to 55%, and even more preferably 15 to 45%. This range is more preferable because it provides excellent moisturizing feeling after application and a small difference in brightness between before and after drying of the applied film.

[0037] <Component (F)> The color pigment of component (F) surface-coated with a hydrophobic surface treatment agent refers to a pigment other than components (A), (B), and (C). In the present invention, when "surface-coated with a hydrophobic surface treatment agent," component (F) is dispersed in water at 25°C and stirred at 1,000 rpm for 5 minutes using a Desper, it is preferably one that mainly floats in the water, but this is not particularly limited. The shape is not particularly limited, such as plate-like, spindle-like, or needle-like; particle size (e.g., fine particles, spherical, granular, or pigment-grade); particle structure (e.g., porous, non-porous, or hollow); and examples include inorganic powders, organic powders, and composite powders. Specific examples include iron oxides such as yellow iron oxide, black iron oxide, and red iron oxide; inorganic metal oxides such as black titanium oxide, chromium oxide, chromium hydroxide, manganese oxide, aluminum oxide, cerium oxide, and zirconium oxide; colored inorganic pigments such as ultramarine and Prussian blue; and organic pigments such as carmine, carbon black, and tar dyes. Particularly preferred is one or more selected from yellow iron oxide, black iron oxide, iron oxide such as red iron oxide, black titanium oxide, ultramarine, Prussian blue, chromium oxide, chromium hydroxide, manganese oxide, carbon black, and tar dyes. The hydrophobic surface treatment agent for component (F) may be the same as the hydrophobic treatment agent for components (A), (B), and (C). Examples of hydrophobic surface treatment agents include silicone compounds, treatment agents having an aliphatic group with 8 to 24 carbon atoms, and coupling agents having an aliphatic group with 8 to 24 carbon atoms, specifically silane-based, aluminum-based, and titanium-based coupling agents such as alkylalkoxysilane treatment, acylated amino acids or salts thereof, phospholipids, fatty acids or salts thereof, and fatty acid esters. These may be used alone or in combination. Among these, the hydrophobic surface treatment agent is preferably the same as the hydrophobic treatment agent for components (A), (B), and (C), and preferably has the properties of (A2), (B2), and (C2). Furthermore, the hydrophobic surface treatment agent is more preferably in the range of (A2) and (B2), but is not particularly limited. It may be appropriately selected depending on the surface properties of the color pigment that is the base of component (F). Furthermore, the surface coating method for the hydrophobic surface treatment agent of component (F) may be the same as that for the components (A), (B) and (C).

[0038] The content of component (F) used in the present invention, relative to the total amount of the cosmetic, is preferably 0.01% or more, more preferably 0.1% or more, and even more preferably 0.2% or more. The upper limit is preferably 15% or less, more preferably 10% or less, and even more preferably 7% or less. The range is preferably 0.01 to 15%, more preferably 0.1 to 10%, and even more preferably 0.2 to 7%. This range is preferable in terms of the moisturizing feeling after application and the small difference in brightness between before and after drying of the applied film.

[0039] In addition to the above components (A) to (E), the cosmetic of the present invention may contain, as appropriate, components commonly used in cosmetics, such as oily components as base materials or emollient components, powders, surfactants for powder dispersion or for adjusting texture, ultraviolet absorbers, moisturizers, anti-fading agents, antioxidants, anti-foaming agents, cosmetic ingredients, preservatives, fragrances, etc., within a range that does not impair the effects of the present invention.

[0040] Oily components other than component (E) include solid oils and semi-solid oils such as higher alcohols, fluorinated oils, and oily gelling agents, regardless of their origin (animal oil, vegetable oil, synthetic oil, etc.). Specific examples include higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, and behenyl alcohol, silicones such as (dimethicone / vinyl dimethicone) crosspolymer and stearyl dimethicone, and oily gelling agents such as dextrin fatty acid esters, inulin fatty acid esters, sucrose fatty acid esters, and calcium stearate.

[0041] Powders other than components (A), (B), (C), and (F) are not particularly limited by shape (e.g., plate-like, spindle-like, or needle-like); particle size (e.g., fine particles, spherical, granular, or pigment-grade); or particle structure (e.g., porous, nonporous, or hollow). Examples include inorganic powders, organic powders, and composite powders. Specific examples include inorganic powders such as mica, talc, synthetic fluorophlogopite, silica, boron nitride, barium sulfate, and bismuth oxychloride; and organic powders such as magnesium stearate, zinc stearate, N-acyl lysine, cellulose, starch, and silk. One or more of these powders may be used. Furthermore, these powders may be used as composites of one or more of these powders, or may be surface-coated by known methods using a triethoxyalkylsilane treatment agent, an organic titanate treatment agent, a silicone treatment agent, a metal soap, a surfactant, an oil, a hydrocarbon, or the like.

[0042] The surfactant may be any surfactant commonly used in cosmetics, including nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, etc. The present invention may further contain a combination of one or more surfactants selected from component (G) silicone surfactants, sugar fatty acid esters, glycerin fatty acid esters, polyglycerin fatty acid esters, surfactants having a hydroxy fatty acid group, etc. Among these, silicone surfactants and surfactants having a hydroxy fatty acid group are preferred. Examples of silicone surfactants include polyether-modified silicones having polyether chains as hydrophilic groups and polyglycerin-modified silicones having polyglycerin chains as hydrophilic groups, and may be graft copolymers having organopolysiloxane groups as the main chain and hydrophilic groups as the side chains, linear block copolymers or crosslinked polymers in which organopolysiloxane groups and hydrophilic groups are alternately bonded, or graft copolymers having acrylic polymer main chains and organopolysiloxane groups as the side chains. The organopolysiloxane groups may be linear or branched, and may be co-modified with organic groups such as alkyl groups or fluorine-substituted alkyl groups. Commercially available products include KF-6028P (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-6105 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-6019 (manufactured by Shin-Etsu Chemical Co., Ltd.), ABIL EM 90 (manufactured by EVONIC GOLDSCHMIDT), ABIL EM 97S (manufactured by EVONIC GOLDSCHMIDT), KP-578 (manufactured by Shin-Etsu Chemical Co., Ltd.), and ES-5600 (manufactured by Dow-Toray Industries, Inc.). Commercially available surfactants having a hydroxy fatty acid group include Salacos HS-6C (manufactured by Nisshin Oillio Co., Ltd.) and CITHROL DPHS-SO-(JP) (manufactured by Croda). Among these, (acrylates / ethylhexyl acrylate / dimethicone methacrylate) copolymer, polyhydroxystearic acid, and PEG-30 dipolyhydroxystearate are particularly preferred, as they produce a coating film with a small difference in brightness before and after drying.

[0043] Examples of ultraviolet absorbers that are solid at 25°C include diethylaminohydroxybenzoylhexyl benzoate, methylenebisbenzotriazolyltetramethylbutylphenol, 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine, and 4-tert-butyl-4'-methoxydibenzoylmethane. Examples of moisturizers include proteins, mucopolysaccharides, collagen, elastin, and keratin. Examples of antioxidants include α-tocopherol and ascorbic acid. Examples of cosmetic ingredients include vitamins, anti-inflammatory agents, and herbal medicines. Examples of preservatives include parahydroxybenzoates and phenoxyethanol.

[0044] The formulation of the cosmetic of the present invention is not particularly limited, but is preferably a water-in-oil emulsion cosmetic, an oil-in-water emulsion cosmetic, an oil-based cosmetic, a powder cosmetic, a solid powder cosmetic, an aqueous cosmetic, a solid powder cosmetic, a powder cosmetic, or the like. In addition, the cosmetic may contain an aqueous component or an oil component that evaporates. Specifically, water-in-oil cosmetics, oil-based cosmetics, and oil-in-water emulsion cosmetics are preferred, with water-in-oil emulsion cosmetics being particularly preferred, as they are easy to incorporate with component (D) and component (E) and provide an excellent moisturizing feeling after application.

[0045] The cosmetic of the present invention is not particularly limited and can be used as skin care cosmetics such as lotions, emulsions, creams, etc., cleansing cosmetics such as sunscreens, facial cleansers, makeup cleansers, etc., hair cosmetics such as shampoos, rinses, conditioners, etc., lip cosmetics such as lipsticks, lip glosses, etc., and makeup cosmetics such as foundations, concealers, blushers, face powders, eyeliners, eye colors, mascara, eyebrow pencils, nail polishes, etc. In particular, the cosmetic of the present invention can be suitably used as color-imparting makeup cosmetics because the color change of the applied film before and after drying is minimal. Furthermore, in the case of items where the change is easily visible to the naked eye until a coating film is formed on the skin, for example, an item that is spread on the skin with the fingers, the color change is easily visible and the effect of the present invention can be clearly confirmed, and base makeup cosmetics that are applied over a wide area are preferably used because the change is easier to see visually.

[0046] The present invention includes the following aspects as means for solving the above problems. [1] The following components (A) to (F); (A) Metal oxide surface-coated with a hydrophobic surface treatment agent (B) Metal oxide surface-coated with an acylated amino acid or its salt (C) Metal oxide surface coated with phospholipid (D) Polyhydric alcohol (E) An oil that is liquid at 25°C (F) Colored pigments coated with a hydrophobic surface treatment agent Contains The component (A) is excluding the component (B) and the component (C), The metal oxides of the components (A), (B), and (C) may be the same or different, and each metal oxide is a pigment containing one or more metal oxides selected from titanium oxide and zinc oxide; The component (F) is a component other than the components (A), (B), and (C). Cosmetics are provided. [2] The present invention provides a cosmetic according to [1], wherein the metal oxides of the components (A), (B), and (C) have an average particle size of 100 to 1000 nm. [3] The cosmetic preparation according to [1] or [2], wherein the hydrophobic surface treatment agent of component (A) is one or more selected from the group consisting of triethoxycaprylylsilane, polyglycerol fatty acid ester, dimethylpolysiloxane, and fatty acid or a salt thereof.

[14] The cosmetic preparation according to any one of [1] to [3], wherein the acylated amino acid or a salt thereof of component (B) is one or more selected from the group consisting of acylated glutamic acid or a salt thereof, and acylated aspartic acid or a salt thereof.

[15] The cosmetic preparation according to any one of [1] to [3] and

[14] , wherein the component (D) is one or more selected from glycerin, 1,3-butylene glycol, diglycerin, and tripropylene glycol.

[16] The cosmetic preparation according to any one of [1] to [3],

[14] and

[15] , wherein the mass of the component (D) is 3 to 13 mass %.

[17] The cosmetic preparation according to any one of [1] to [3] and

[14] to

[16] , wherein the mass ratio of the components (A), (B), and (C) is (A):(B):(C)=0.3-15:0.3-15:0.5-20.

[18] The mass percentage of each (MO) of the component (A), the component (B), and the component (C) relative to the total (MO) contained in the cosmetic, where (MO) is the total mass percentage of the pure titanium oxide and zinc oxide; [(MO) of component (A)] / [total (MO) in the cosmetic] and [(MO) of component (B)] / [total (MO) in the cosmetic] are 0.15 to 0.4, The cosmetic preparation according to any one of [1] to [3] and

[14] to

[17] is provided, wherein [(MO) of component (C)] / [total (MO) in the cosmetic preparation] is 0.25 to 0.7.

[19] The cosmetic preparation according to any one of [1] to [3] and

[14] to

[18] , wherein the component (F) is one or more selected from yellow iron oxide, black iron oxide, iron oxide such as red iron oxide, black titanium oxide, ultramarine, Prussian blue, chromium oxide, chromium hydroxide, manganese oxide, carbon black, and tar dyes.

[20] The cosmetic preparation according to any one of [1] to [3] and

[14] to

[19] , wherein the component (E) is one or more selected from the group consisting of phenyl-modified silicone, alkyl-modified silicone, hydrocarbon oil, and ester oil.

[21] The cosmetic according to any one of [1] to [3] and

[14] to

[20] is provided, wherein the cosmetic is a water-in-oil cosmetic.

[22] The cosmetic according to any one of [1] to [3] and

[14] to

[21] is provided, wherein the cosmetic is a makeup cosmetic. [Example]

[0047] The present invention will be described in detail below with reference to examples, but the present invention is not limited to these examples. [Examples 1 to 28 and Comparative Examples 1 to 10: Liquid Foundation] Liquid foundations having the formulations shown in Tables 1 to 3 below were prepared according to the manufacturing method described below, and the moisturizing feeling after application and the brightness difference after drying of the applied film were evaluated using the evaluation methods described below. The results are also shown in Tables 1 to 3.

[0048] [Table 1] *1: OTS-2 TiO2 MP-1133 (manufactured by Daito Chemical Industry Co., Ltd.) *2:MPY-1133EX (manufactured by Teika) *3: ITT-2 TiO2 CR-50 (manufactured by Daito Chemical Industry Co., Ltd.) *4: MST-1 TiO2 R250 (manufactured by Daito Kasei Kogyo Co., Ltd.) *5: PGQ TiO2 R250 (manufactured by Daito Chemical Industry Co., Ltd.) *7: NAI-Titanium MP-1133 (manufactured by Miyoshi Chemicals) *8:CR-50 (Ishihara Sangyo Co., Ltd.) *9:MP-1133 (manufactured by Teika) *10:XZ-300F (Sakai Chemical Industry Co., Ltd.) *11: OTS-2 RED R-516P (manufactured by Daito Kasei Kogyo Co., Ltd.) *12: OTS-2 YELLOW YP-1200P (manufactured by Daito Kasei Kogyo Co., Ltd.) *13: OTS-2 BLACK BL-100P (manufactured by Daito Kasei Kogyo Co., Ltd.) *17: KF-6028 (Shin-Etsu Chemical Co., Ltd.) *18: KF-6038 (Shin-Etsu Chemical Co., Ltd.) *19:ABIL EM-90 (EVONIC) *20: KF-56 (Shin-Etsu Chemical Co., Ltd.) *21: Silicone TMF-1.5 (Shin-Etsu Chemical Co., Ltd.) *22: BENTONE38V BC (manufactured by Elementis) *23: BENTONE 27V (manufactured by Elementis) *24: SR1000 (manufactured by Momentive Performance Materials Japan) *25: Cosme Silica CQ4 (Fuji Silysia Chemical) *26: CELLULOBEADS D-5 (manufactured by Daito Kasei Kogyo Co., Ltd.) *27: PDM-10L (manufactured by Topy Industries) [Table 2] *28:TPG-H (ADEKA) [Table 3] *6: LL-VSTAL TiO2 250 (manufactured by Daito Kasei Kogyo Co., Ltd.) *14:RED R-516P (manufactured by Titanium Industries Co., Ltd.) *15: YELLOW YP-1200P (manufactured by Titanium Industries) *16:BLACK BL-100P (Titanium Industries Co., Ltd.)

[0049] (Manufacturing method: Tables 1 to 3) (Only the ingredients with the listed numbers should be blended.) A. Uniformly disperse components (1) to (18), components (19) to (23), and components (27) and (28) using a roll mill. Add components (24) to (26) and components (29) to (32) to BA and mix and disperse uniformly using a Desper. C. Dissolve ingredients (33) to (38) at 25°C. C was added to DB and emulsified using a triple mixer to obtain a water-in-oil emulsion liquid foundation.

[0050] (Evaluation method) The following evaluation items were evaluated by the following methods. (Evaluation item) Moisturizing sensation after application <Evaluation and Judgment Criteria>: Evaluation of moisturizing feeling after application Twenty cosmetic expert evaluators conducted a sensory evaluation of the moisturizing sensation when each cosmetic product was applied to the skin. They conducted a questionnaire to assess whether or not the cosmetic product felt moisturized after application, and rated it on a 5-point scale from A to E as shown below. A: 18-20 people felt that they had a moisturizing effect. B: 15-17 people felt that they had a moisturizing effect. C: 11 to 14 people felt that they had a moisturizing effect. D: 6 to 10 people felt that they had a moisturizing effect. E: 0-5 people felt that they had a moisturizing effect

[0051] (Evaluation item) Difference in brightness before and after drying of the coating film The liquid foundations of Examples 1 to 28 and Comparative Examples 1 to 10 were applied to black artificial leather with a doctor blade to a thickness of 200 μm, and the lightness values ​​were measured immediately after application and after one hour of drying using a contact colorimeter. The difference between the lightness L(0) immediately after application and the lightness L(1) one hour after application, L(1) - L(0), was taken as the lightness difference ΔL, and the range of its absolute value was evaluated as follows: <Evaluation and Judgment Criteria>: Difference in brightness before and after drying of the coating film 5-point rating and evaluation criteria A: Absolute value of ΔL is less than 1.5: Excellent B: Absolute value of ΔL is 1.5 or more and less than 3.0: Fairly good C: Absolute value of ΔL is 3.0 or more and less than 4.5: Neither D: Absolute value of ΔL is 4.5 or more and less than 6.0: Slightly poor E: Absolute value of ΔL is 6.0 or more: Defective

[0052] As is clear from the results in Table 1, the liquid foundations of Examples 1 to 28 of the present invention were superior to the liquid foundations of Comparative Examples 1 to 10 in terms of moisturizing feeling after application and difference in brightness before and after drying of the applied film. On the other hand, in Comparative Examples 1 to 3, in which the titanium oxide surface-coated with component (A) hydrophobic surface treatment agent was replaced with no surface treatment agent or with only titanium oxide treated simultaneously with the surface treatment agent (A) and the surface treatment agent (B), it was considered that component (A) was not contained, and although the moisturizing feeling after application was excellent, the difference in brightness between before and after drying of the applied film was large, and a satisfactory result was not obtained. Furthermore, in Comparative Examples 4 and 5, in which titanium oxide surface-coated with (B) an acylated amino acid or its salt was replaced with (A), or replaced with (C) without blending (B), the moisturizing feeling after application was excellent, but the difference in brightness between before and after drying of the applied film was large, and no satisfactory results were obtained. Furthermore, in Comparative Examples 6 and 7, in which titanium oxide surface-coated with (C) phospholipid was replaced with (A), or replaced with (B) without blending (C), the moisturizing feeling after application was slightly reduced, and the difference in brightness between before and after drying of the applied film was large, and a satisfactory result was not obtained. In addition, in Comparative Example 8, in which (D) polyhydric alcohol was replaced with purified water, the difference in brightness between before and after drying of the coating film was small, and the color was realized as expected, but the moisturizing feeling after application was not satisfactory. Furthermore, in Comparative Examples 9 and 10, which did not contain component (F) or which replaced it with iron oxide that was not surface-coated with a hydrophobic surface treatment agent, the moisturizing feeling after application was excellent, but the difference in brightness between before and after drying of the applied film was large, and a satisfactory result was not obtained.

[0053] Example 29: Water-in-oil sunscreen cosmetic (Component) (%) 1. (A) Pigment-grade zinc oxide treated with 2% silicone (average particle size 100-450nm) (*29) 1.0 2. (B) Pigment-grade titanium dioxide treated with 3% stearoyl glutamic acid disodium (average particle size 100-450 nm) (*7) 1.0 3. (C) Titanium oxide (average particle size 250 nm)*8 treated with 0.5% unhydrogenated lecithin 1.8 4. (F) Triethoxycaprylylsilane-treated red iron oxide (*11) 0.1 5. (F) Triethoxycaprylylsilane-treated yellow iron oxide (*12) 0.3 6. (F) Triethoxycaprylylsilane-treated black iron oxide (*13) 0.1 7. (E1) Isotridecyl isononanoate 4.0 8. (E1) Isohexadecane 3.0 9. Cetyl lactate (*30) 4.0 10. (G) (Acrylates / Ethylhexyl Acrylate / Dimethicone Methacrylate) Copolymer (*31) 1.0 11. (E2) Dimethylpolysiloxane (viscosity at 25°C 2mm 2 / sec) 5.0 12. (E2) Dimethylpolysiloxane (viscosity at 25°C 6mm) 2 / sec) 5.0 13. (E1) Ethylhexyl methoxycinnamate 5.0 14. Diethylaminohydroxybenzoylhexyl benzoate 2.0 15. Trimethylsiloxysilicate (*24) 2.0 16.(G) PEG-30 Dipolyhydroxystearate(*32) 3.0 17.(G) Sorbitan sesquiisostearate 0.5 18. (G) Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (*15) 2.0 19. Cellulose (*33) 5.0 20. Silica (*34) 2.0 21. Boron nitride 1.5 22. Remaining purified water 23. Hyaluronic Acid 0.01 24. Xanthan gum 0.01 25. 40% water dispersion of methylenebisbenzotriazolyltetramethylbutylphenol (*35) 8.0 26. Ethanol 5.0 27.(D) 1,3-butylene glycol 8.0 *29:XZ-300F-LP (Sakai Chemical Industry Co., Ltd.) *30: CERAPHYL 28 (Ashland) *31: KP-578 (Shin-Etsu Chemical Co., Ltd.) *32:CITHROL DPHS-SO-(JP) (manufactured by Croda) *33: CELLULOBEARDS D-30 (manufactured by Daito Kasei Kogyo Co., Ltd.) *34:HCS160M5 (JGC Catalysts and Chemicals) *35: K22-M40 (manufactured by Dai Nippon Kasei Co., Ltd.)

[0054] (Manufacturing method) (1): Disperse ingredients 1 to 10 evenly with a roller. (2): Add ingredients 11 to 21 to (1) and disperse uniformly. (3): Components 21 to 27 were added to (2) and emulsified using a triple mixer to obtain a water-in-oil sunscreen cosmetic.

[0055] The water-in-oil sunscreen cosmetic of Example 29 was excellent in "moisturizing feeling after application" and "difference in brightness before and after drying of the applied film."

[0056] Example 30: Water-in-oil sunscreen cosmetic (non-chemical) (Component) (%) 1. Triethoxycaprylylsilane-treated fine particle zinc oxide (*36) 3.0 2. (A) Pigment-grade titanium dioxide treated with 1% magnesium stearate (average particle size 100-450 nm) (*3) 1.0 3. (B) Pigment-grade titanium dioxide treated with 3% stearoyl glutamic acid disodium (average particle size 100-450 nm) (*7) 1.0 4. (C) Titanium oxide (average particle size 250 nm)*8 treated with 0.5% unhydrogenated lecithin 5.8 5. (F) Triethoxycaprylylsilane-treated red iron oxide (*11) 0.1 6. (F) Triethoxycaprylylsilane-treated yellow iron oxide (*12) 0.3 7. (F) Triethoxycaprylylsilane-treated black iron oxide (*13) 0.1 8. (E1) Cetyl ethylhexanoate 6.0 9. (E1) Isotridecyl isononanoate 4.0 10.(E1) Isododecane 10.0 11. (E2) Dimethylpolysiloxane (viscosity at 25°C 2mm 2 / sec) 10.0 12. Lauroyl Lysine (*37) 5.0 13. Amodimethicone-distearyldimonium chloride treated silica (*38) 2.0 14.(G) Bis(PEG / PPG-14 / 14) Dimethicone(*39) 1.5 15.(G) Cetyl PEG / PPG-10 / 1 Dimethicone (*19) 0.2 16.(G) Sorbitan sesquiisostearate 0.5 17. Trimethylsiloxysilicate (Methyltrimethicone 40% Solution) (*40) 2.0 18. Remaining purified water 19. Tocopherol 0.01 20.(D) 1,3-butylene glycol 5.0 21.(D) Glycerin 5.0 *36: MZX-304OTS (manufactured by Teika) *37: Amihope LL (manufactured by Ajinomoto Co., Inc.) *38:TMS-05DCA (manufactured by Teika) *39:ABIL EM 97S (EVONIK) *40: KF-7312T (methyl trimethicone 40% solution) (manufactured by Shin-Etsu Chemical Co., Ltd.)

[0057] (Manufacturing method) (1): Disperse ingredients 1 to 11 evenly using a roller. (2): Add ingredients 12 to 17 to (1) and disperse evenly. (3): Components 18 to 21 were added to (2) and emulsified using a triple mixer to obtain a water-in-oil sunscreen cosmetic.

[0058] The water-in-oil sunscreen cosmetic of Example 30 was excellent in "moisturizing feeling after application" and "difference in brightness before and after drying of the applied film."

[0059] Example 31: Water-in-oil liquid foundation (Component) (%) 1. (A) Pigment-grade titanium dioxide treated with 1% magnesium stearate (average particle size 100-450 nm) (*3) 3.0 2. (B) Pigment-grade titanium dioxide treated with 3% stearoyl glutamic acid disodium (average particle size 100-450 nm) (*7) 4.0 3. (C) Titanium oxide (average particle size 250 nm)*8 treated with 0.5% unhydrogenated lecithin 6.4 4. Dimethicone-treated titanium dioxide microparticles (*41) 3.0 5. (F) Red iron oxide treated with 2Na stearoyl glutamate 0.5 6. (F) Yellow iron oxide treated with disodium stearoyl glutamate (*42) 1.5 7. (F) Black iron oxide treated with disodium stearoyl glutamate (*43) 0.2 8. (E1) Octyl palmitate 6.0 9. (E1) Triethylhexanoin (*44) 2.0 10. (E1) Diphenylsiloxyphenyl Trimethicone (*20) 7.0 11. (E1) Isotridecyl isononanoate 1.0 12.(E2) Methyl Trimethicone 5.0 13. (E1) Hydrogenated polyisobutene (*45) 10.0 14.(G) Bis(PEG / PPG-14 / 14) Dimethicone(*39) 1.0 15. (G) PEG-9 Polydimethylsiloxyethyl Dimethicone (*17) 0.5 16. Cellulose (*33) 2.0 17. Disteardimonium Hectorite (*22) 1.0 18. Stearalkonium Hectorite (*23) 0.5 20. Remaining purified water 21. Phenoxyethanol 0.2 22. Methylparaben 0.1 23.(D) Glycerin 3.0 24.Fragrance 0.2 *41: MZY-505M (manufactured by Teika) *42: NAI-C339001-10 (Miyoshi Chemicals Co., Ltd.) *43:NAI-C337001-10 (manufactured by Miyoshi Kasei Co., Ltd.) *44: MYRITOL GTEH (manufactured by BASF) *45: IP Solvent 1620MU (Idemitsu Kosan Co., Ltd.)

[0060] (Manufacturing method) (1): Disperse ingredients 1 to 9 evenly using a roller. (2): Add ingredients 10 to 19 to (1) and disperse evenly. (3): Components 20 to 24 were added to (2) and emulsified using a triple mixer to obtain a water-in-oil liquid foundation.

[0061] The water-in-oil liquid foundation of Example 31 was excellent in "moisturizing feeling after application" and "difference in brightness before and after drying of the applied film."

[0062] Example 32: Oil-in-water foundation (Component) (%) 1. (A) Titanium dioxide treated with 3.8% isostearic acid (average particle size 270 nm) (*2) 1.0 2. (B) Pigment-grade titanium dioxide treated with 5% disodium cocoyl glutamate (average particle size 100-450 nm) 1.0 3. (C) Titanium oxide (average particle size 250 nm)*8 treated with 0.5% hydrogenated lecithin (Recinol S-10EZ) 1.8 4. (F) Red iron oxide treated with 2Na stearoyl glutamate 0.5 5. (F) Yellow iron oxide treated with disodium stearoyl glutamate (*42) 1.5 6. (F) Disodium stearoyl glutamate treated black iron oxide (*43) 0.2 7. (E1) Ethylhexyl methoxycinnamate 6.0 8. Diethylaminohydroxybenzoylhexyl benzoate 1.5 9. (Acrylates / Dimethicone) Copolymer 2.0 10.(G) Bis(PEG / PPG-14 / 14) Dimethicone(*39) 0.3 11. Stearic acid 1.0 12.(G) Glyceryl stearate 0.2 13.(G) Sorbitan sesquioleate 0.4 14. Cetearyl Alcohol 0.2 15. Behenyl alcohol 0.2 16.(G) Polysorbate 80 0.5 17. (G) Triceteareth-4 phosphate 0.1 18. Silica (*46) 2.0 19. Remaining purified water 20. Carbomer 0.5 21. Xanthan gum 0.1 22. Hydroxymethylpropylcellulose 0.2 23.(D) 1,3-butylene glycol 10.0 24.(D) Methylgluceth-10 4.0 25.(D) Glycerin 1.0 26. Phenoxyethanol 0.2 27.(D)DPG 3.0 28. Ascorbic acid 0.001 *46: God Ball G-6C (manufactured by Suzuki Oil Co., Ltd.)

[0063] (Manufacturing method) (1): Disperse ingredients 1 to 7 evenly using a roller. (2): Add ingredients 8 to 17 to (1) and disperse uniformly at 80°C. (3): Components 18 to 28 were uniformly dispersed in (2) at 80°C, and (2) was added and emulsified using a triple mixer to obtain an oil-in-water liquid foundation.

[0064] The oil-in-water liquid foundation of Example 32 was excellent in "moisturizing feeling after application" and "difference in brightness before and after drying of the applied film."

[0065] Example 33: Water-in-oil stick concealer (Component) (%) 1. (A) Titanium dioxide treated with 2% triethoxycaprylylsilane (average particle size 270 nm) (*1) 6.0 2. (B) Pigment-grade titanium dioxide treated with 5% disodium cocoyl glutamate (average particle size 250 nm) 6.0 3. (C) Titanium oxide (average particle size 250 nm)*8 treated with 0.5% unhydrogenated lecithin 12.0 4. (F) Red iron oxide treated with 2Na stearoyl glutamate 1.0 5. (F) Yellow iron oxide treated with disodium stearoyl glutamate (*42) 3.0 6. (F) Disodium stearoyl glutamate treated black iron oxide (*43) 0.5 7. (E) 2-Ethylhexyl 2-ethylhexanoate 6.0 8. (G) PEG-9 Polydimethylsiloxyethyl Dimethicone (*17) 0.5 9. (G) Sorbitan sesquiisostearate 1.0 10. (E2) Dimethylpolysiloxane (viscosity at 25°C 6mm 2 / sec) 15.0 11. (E1) Octyldodecanol 5.0 12. (E1) Squalane 2.0 13. Paraffin / microcrystalline wax mixture (*47) 5.0 14. Rice Wax 2.0 15. Safflower Wax 2.0 16. Carnauba Wax 1.0 18. Silica (*48) 2.5 19.(D) 1,3-butylene glycol 5.0 20.(D) Glycerin 3.0 21. (D) Ethylhexylglycerin 0.5 22. Chlorphenesin 0.1 23. Remaining purified water *47: JNP-81 (Nippon Natural Products Co., Ltd.) *48: Sunsphere NP-100 (AGC Si-Tech)

[0066] (Manufacturing method) (1): Disperse ingredients 1 to 9 evenly using a roller. (2): Add ingredients 10 to 18 to (1) and disperse uniformly at 90°C. (3): Components 19 to 23 were uniformly dissolved at 90°C, added to (2), emulsified using a triple mixer, and filled into an airtight stick container to obtain a water-in-oil stick concealer.

[0067] The oil-in-water stick concealer of Example 33 was excellent in "moisturizing feeling after application" and "difference in brightness before and after drying of the applied film."

[0068] Example 34: Oily solid concealer (Component) (%) 1. (A) Titanium dioxide treated with 2% isopropyl titanium triisostearate (average particle size 250 nm) (*3) 6.0 2. (B) Titanium dioxide treated with 3% stearoyl glutamic acid disodium (average particle size 270 nm) (*7) 6.0 3. (C) Titanium oxide (average particle size 250 nm)*8 treated with 0.5% hydrogenated lecithin (Recinol S-10EZ) 12.0 4. (F) Red iron oxide treated with 2Na stearoyl glutamate 1.0 5. (F) Yellow iron oxide treated with disodium stearoyl glutamate (*42) 3.0 6. (F) Disodium stearoyl glutamate treated black iron oxide (*43) 0.5 7. (E1) 2-Ethylhexyl 2-ethylhexanoate 6.0 8. (G) Cetyl PEG / PPG-10 / 1 Dimethicone (*19) 0.7 9. (G) Sorbitan sesquiisostearate 1.0 10.(E1) Alkyl benzoate (C12-15)(*49) 5.0 11. (E1) Octyldodecanol 10.0 12. (E1) Squalane remaining amount 13. Paraffin / microcrystalline wax mixture (*47) 5.0 14. Rice Wax 2.0 15. Safflower Wax 2.0 16. Carnauba Wax 1.0 17. Silica (*25) 2.5 18.(D) Glycerin 5.0 19. Chlorphenesin 0.1 *49:FINSOLV TN (manufactured by INNOSPEC ACTIVE CHEMICALS)

[0069] (Manufacturing method) (1): Disperse ingredients 1 to 9 evenly using a roller. (2): Add ingredients 10 to 19 to (1) and disperse uniformly at 90°C. (3): (2) was poured into a metal dish at 90°C to obtain an oily solid concealer.

[0070] The oil-in-water stick concealer of Example 34 was excellent in "moisturizing feeling after application" and "difference in brightness before and after drying of the applied film."

[0071] Example 35: Water-in-oil liquid cheek (Component) (%) 1. (A) Titanium dioxide treated with 2% triethoxycaprylylsilane (average particle size 270 nm) (*1) 1.0 2. (B) Titanium dioxide treated with 3% stearoyl glutamic acid disodium (average particle size 270 nm) (*7) 1.0 3. (C) Titanium oxide (average particle size 250 nm)*8 treated with 0.5% unhydrogenated lecithin 2.0 4. (F) Red iron oxide treated with 2Na stearoyl glutamate 2.0 5. (F) Yellow iron oxide treated with disodium stearoyl glutamate (*42) 2.0 6. (F) Disodium stearoyl glutamate treated black iron oxide (*43) 0.5 7. Red 226 0.5 7. (E1) 2-Ethylhexyl 2-ethylhexanoate 6.0 8. (G) PEG-9 Polydimethylsiloxyethyl Dimethicone (*17) 0.5 9. (G) Sorbitan sesquiisostearate 1.0 10. (E1) Diphenylsiloxyphenyl Trimethicone (*20) 8.0 11. (E1) Isotridecyl isononanoate 1.0 12.(E2) Methyl Trimethicone 5.0 13.(E1) Isododecane 10.0 14.(G) Bis(PEG / PPG-14 / 14) Dimethicone(*39) 1.0 15. Polymethylsilsesquioxane powder 5.0 16. Cellulose (*33) 2.0 17. Disteardimonium Hectorite (*22) 1.0 18. Stearalkonium Hectorite (*23) 0.5 19. Remaining purified water 20. Phenoxyethanol 0.2 21. Methylparaben 0.1 22.(D) Glycerin 3.0 23.Fragrance 0.2

[0072] (Manufacturing method) (1): Disperse ingredients 1 to 9 evenly using a roller. (2): Add ingredients 10 to 18 to (1) and disperse evenly. (3): Components 19 to 23 were mixed uniformly, added to (2), emulsified using a triple mixer, and filled into a glass container with an applicator to obtain a water-in-oil liquid blush.

[0073] The water-in-oil liquid cheek of Example 35 was excellent in "moisturizing feeling after application" and "difference in brightness before and after drying of the applied film."

[0074] Example 36: Oil-based liquid rouge (Component) (%) 1. (A) 2% isopropyl titanium triisostearate treated titanium dioxide (Average particle size 250nm)(*3) 1.0 2. (B) Titanium dioxide treated with 3% stearoyl glutamate disodium (Average particle diameter 270nm)(*7) 1.0 3. (C) Titanium oxide (average particle size 250 nm)*8 Treated with 0.5% unhydrogenated lecithin 2.0 4. (F) Red iron oxide treated with 2Na stearoyl glutamate 0.5 5. (F) Yellow iron oxide treated with disodium stearoyl glutamate (*42) 0.8 6. (F) Stearoyl glutamic acid disodium treated black iron oxide (*43) 0.1 7. Red 202 0.5 8. Red 226 0.2 9. Red 104 0.1 10. Yellow 4 0.3 11. Dextrin palmitate (*50) 1.0 12. Inulin stearate (*51) 1.0 13. (E1) Neopentyl glycol dicaprate 8.0 14. (E1) Polyglyceryl-2 triisostearate remaining amount 15. (E1) Diisostearyl Malate (*52) 3.0 16. (G) PEG-9 Polydimethylsiloxyethyl Dimethicone (*17) 0.5 17.(E1) Isododecane 10.0 18. Dextrin Isostearate (*53) 2.0 19.BHT 0.02 20.(D) Glycerin 20.0 21.Fragrance 0.2 *50: Leopard KL2 (manufactured by Chiba Flour Mills) *51: Leopard ISK2 (manufactured by Chiba Flour Mills) *52: Himalate DIS (Kyushu Alcohol Kogyo Co., Ltd.) *53: Unifilma HVY (manufactured by Chiba Flour Mills)

[0075] (Manufacturing method) (1): Heat ingredients 1 to 16 to 90°C and disperse evenly using a roller. (2): Components 17 to 21 were added to (1) and mixed uniformly, and the mixture was filled into a container with an applicator to obtain an oil-based liquid rouge.

[0076] The oil-based liquid rouge of Example 36 was excellent in "moisturizing feeling after application" and "difference in brightness before and after drying of the applied film."

[0077] Example 37: Oily stick lipstick (Component) (%) 1. (A) 2% isopropyl titanium triisostearate treated titanium dioxide (Average particle size 250nm)(*3) 1.0 2. (B) Titanium dioxide treated with 3% stearoyl glutamate disodium (Average particle diameter 270nm)(*7) 1.0 3. (C) Titanium oxide (average particle size 250 nm)*8 Treated with 0.5% unhydrogenated lecithin 2.0 4. (F) Red iron oxide treated with 2Na stearoyl glutamate 0.3 5. (F) Yellow iron oxide treated with disodium stearoyl glutamate (*42) 0.8 6. (F) Stearoyl glutamic acid disodium treated black iron oxide (*43) 0.1 7. Red 202 0.1 8. Red 218 0.1 9. Yellow 4 0.1 10. Synthetic Wax 4.0 11. Microcrystalline Wax 4.0 12. Dimer Dilinoleic Acid (Phytosteryl / Isostearyl / Cetyl / Stearyl / Behenyl) (*54) 10.0 13. (E1) Polyglyceryl-2 triisostearate remaining amount 14. (E1) Diisostearyl Malate (*52) 3.0 15. (G) PEG-9 Polydimethylsiloxyethyl Dimethicone (*17) 0.5 16.(E1) Triethylhexanoin (*44) 10.0 17.(E1) Isododecane 20.0 18. Silica dimethyl silylate (*55) 2.0 19.BHT 0.02 20.(D) Glycerin 5.0 21.Fragrance 0.2 *54:PLANDOOL-S (Nippon Fine Chemical) *55: AEROSIL R-976S (Nippon Aerosil)

[0078] (Manufacturing method) (1): Heat ingredients 1 to 16 to 110°C and disperse evenly using a roller. (2): Components 17 to 21 were added to (1) and mixed uniformly, and the mixture was filled into a stick container to obtain an oily stick lipstick.

[0079] The oily stick lipstick of Example 37 was excellent in "moisturizing feeling after application" and "difference in brightness before and after drying of the applied film."

Claims

1. The following components (A) to (F): (A) Metal oxide surface-coated with a hydrophobic surface treatment agent (B) Metal oxide surface-coated with an acylated amino acid or its salt (C) Metal oxide surface-coated with phospholipid (D) Polyhydric alcohol (E) An oil solution that is liquid at 25°C (F) Color pigments surface-coated with hydrophobic surface treatment agents Contains The component (A) is excluding the component (B) and the component (C), The metal oxides of the components (A), (B), and (C) may be the same or different, and each metal oxide is a pigment containing one or more metal oxides selected from titanium oxide and zinc oxide; The component (F) is a component other than the components (A), (B), and (C). Cosmetics.

2. 2. The cosmetic according to claim 1, wherein the total average particle size of said component (A), said component (B), and said component (C) is 100 to 1,000 nm.

3. 3. The cosmetic preparation according to claim 1, wherein the hydrophobic surface treatment agent of component (A) is one or more selected from the group consisting of triethoxycaprylylsilane, polyglycerin fatty acid ester, dimethylpolysiloxane, and fatty acid or salt thereof.

4. 3. The cosmetic preparation according to claim 1, wherein the acylated amino acid or salt thereof of component (B) is one or more selected from the group consisting of acylated glutamic acid or a salt thereof, and acylated aspartic acid or a salt thereof.

5. 3. The cosmetic according to claim 1, wherein the component (D) is one or more selected from the group consisting of glycerin, 1,3-butylene glycol, diglycerin, and tripropylene glycol.

6. 3. The cosmetic according to claim 1, wherein the content by mass of the component (D) is 3 to 13% by mass.

7. 3. The cosmetic preparation according to claim 1, wherein the mass ratio of the components (A), (B), and (C) is (A):(B):(C)=0.3-15:0.3-15:0.5-20.

8. The total mass % pure content of titanium oxide and zinc oxide is defined as (MO), and the mass ratio of each of (MO) of the component (A), the component (B), and the component (C) is relative to the total (MO) contained in the cosmetic; [(MO) of component (A)] / [total (MO) in the cosmetic] and [(MO) of component (B)] / [total (MO) in the cosmetic] are 0.15 to 0.4, [(MO) of component (C)] / [total (MO) in the cosmetic] is 0.25 to 0.7 The cosmetic according to claim 1 or 2.

9. 3. The cosmetic according to claim 1, wherein the component (F) is one or more selected from the group consisting of yellow iron oxide, black iron oxide, iron oxide such as red iron oxide, black titanium oxide, ultramarine, Prussian blue, chromium oxide, chromium hydroxide, manganese oxide, carbon black, and tar dyes.

10. 3. The cosmetic preparation according to claim 1, wherein the component (E) is one or more selected from the group consisting of phenyl-modified silicones, alkyl-modified silicones, hydrocarbon oils, and ester oils.

11. The cosmetic according to claim 1 or 2, wherein the cosmetic is a water-in-oil cosmetic.

12. The cosmetic according to claim 1 or 2, wherein the cosmetic is a makeup cosmetic.

13. The following components (D) to (F), (A2) to (C2); (D) Polyhydric alcohol (E) An oil solution that is liquid at 25°C (F) Color pigments surface-coated with hydrophobic surface treatment agents (A2) A metal oxide surface-coated with a hydrophobic surface treatment agent, which disperses in component (E) when added to a two-phase liquid containing component (D) and component (E) in a mass ratio of 1:

1. (B2) A metal oxide surface-coated with a hydrophobic surface treatment agent, which disperses at the interface between component (D) and component (E) when added to a two-phase liquid in which the mass ratio of component (D) to component (E) is 1:

1. (C2) A metal oxide surface-coated with a hydrophobic surface treatment agent, which disperses in component (D) when added to a two-phase liquid in which the mass ratio of component (D) to component (E) is 1:

1. Contains the metal oxides of the components (A2), (B2), and (C2) may be the same or different, and each metal oxide comprises one or more metal oxides selected from titanium oxide and zinc oxide; A cosmetic preparation in which the component (F) excludes the components (A2), (B2), and (C2).

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