Pest control agent composition and pest control method
The combination of an aryltetrahydropyridine compound and a known pesticide enhances pest control efficacy by addressing resistance issues, offering robust synergistic effects against diverse pests.
Patent Information
- Application Number
- JP2025047556
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2024-05-15
- Filing Date
- 2025-03-21
- Publication Date
- 2025-11-28
AI Technical Summary
Long-term use of insecticides leads to the emergence of pests and harmful organisms that have acquired resistance, necessitating the development of new pesticides with excellent pest control effects.
A pesticide composition comprising an aryltetrahydropyridine compound and a known compound with insecticidal, acaricidal, nematicidal, molluscicidal, fungicidal, or bactericidal activity, which exhibits synergistic pest control effects, including treating seeds with both compounds simultaneously or in close temporal proximity.
The composition demonstrates excellent synergistic control against various pests, including those resistant to existing agents, providing effective pest control methods.
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Abstract
Description
[Technical Field]
[0001] The present invention relates to a pesticide composition comprising an aryltetrahydropyridine compound represented by formula (1) and an active ingredient of a known pesticide, and a pest control method using these two ingredients. [Background technology]
[0002] The aryltetrahydropyridine compound represented by formula (1), which is the first active ingredient compound in the composition of the present invention, is a known compound and is known to exhibit pest control activity (for example, Patent Documents 1, 2 and 3).
[0003] Furthermore, the second active ingredient compounds in the composition of the present invention, which have insecticidal activity, acaricidal activity, nematicidal activity, molluscicidal activity, fungicidal activity, or bactericidal activity, are all known (e.g., Non-Patent Document 1). [Prior art documents] [Patent documents]
[0004] [Patent Document 1] International Publication No. 2021 / 261562 [Patent Document 2] International Publication No. 2023 / 127806 [Patent Document 3] International Publication No. 2024 / 048778 [Non-patent literature]
[0005] [Non-Patent Document 1] The Pesticide Manual, 19th Edition, 2021 Summary of the Invention [Problem to be solved by the invention]
[0006] However, long-term use of insecticides can lead to the emergence of pests and harmful organisms that have acquired resistance to existing insecticides, and therefore there is a constant demand for the development of new pesticides that have excellent pest control effects. [Means for solving the problem]
[0007] As a result of intensive research aimed at solving the above problems, the present inventors have found that a composition containing an aryltetrahydropyridine compound (active ingredient A) represented by the following formula (1) according to the present invention and a certain known compound (active ingredient B) having insecticidal, acaricidal, nematicidal, molluscicidal, fungicidal or bactericidal activity exhibits excellent pest control activity that cannot be predicted from the use of each compound alone, and have completed the present invention.
[0008] That is, the present invention relates to the following compositions (1) and (2) (hereinafter referred to as the composition of the present invention), and the control methods (3) and (4) (hereinafter referred to as the method of the present invention).
[0009] [1] A pesticide composition comprising a compound selected from the following active ingredient A and a compound selected from the following active ingredient B. 1) Active ingredient A: An aryltetrahydropyridine compound or a salt thereof represented by the following formula (1):
[0010] Formula (1):
[0011] [ka]
[0012] [In the formula, Q represents Q-1, Q-2, Q-3, Q-4 or Q-12,
[0013] [ka]
[0014] Z 1 represents a halogen atom, Z 3 represents a C1-C6 alkyl group, J represents J-1 or J-2;
[0015] [ka]
[0016] A 1 represents a nitrogen atom, G represents G-1 or G-3;
[0017] [ka]
[0018] Z 2 represents a halogen atom or halo(C1-C6)alkyl; R 1 represents a halogen atom or halo(C1-C6)alkyl; R 2 represents a hydrogen atom, R 3 represents a hydrogen atom, X represents an oxygen atom; Y represents an oxygen atom; t3 represents an integer of 0, 1, 2, or 3; t4 represents an integer of 0, 1, 2, 3, or 4; and t5 represents an integer of 0, 1, 2, 3, 4 or 5. An aryltetrahydropyridine compound or a salt thereof, represented by the following formula: 2) Active ingredient B: A compound selected from the following active ingredients: Abamectin, acephate, acequinocyl, acetamiprid, acrinathrin, acinonapyr, afidopyropen, afoxolaner, alanycarb, aldicarb, allethrin, alpha-cypermethrin, alpha-endosulfan, amidoflumet, amitraz, azamethiphos, azinphos-ethyl, azinphos-methyl, azocyclotin, Bacillus thuringiensis thuringiensis, bendiocarb, benfluthrin, benfuracarb, bensultap, benzoximate, benzpyrimoxan, beta-cyfluthrin, beta-cypermethrin, bifenazate, bifenthrin, bioallethrin, bioresmethrin smethrin), bistrifluron, bisulflufen, broflanilide, bromopropylate, buprofezin, butocarboxim, carbaryl, carbofuran, carbosulfan, cartap, thionomethionate, chlorantraniliprole,Chlorethoxyfos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormephos, chlorobezilate, chloroprallethrin, chlorpyrifos, chlorpyrifos-methyl, chromafenozide fenozide, clofentezine, clothianidin, cyanophos, cyantraniliprole, cybenzoxasulfyl, cyclaniliprole, cycloprothrin, cyenopyrafen, cyetpyrafen, cyflumetofen ofen, cyfluthrin, cyhalodiamide, cyhalothrin, cyhexatine, cypermethrin, cyphenothrin, cyproflanilide, cyromazine, deltamethrin, diacloden, diafenthiuron, diazinon ( diazinon), dichlorvos (dichlorvos), dichloromezotiaz (dicloromezotiaz), dicofol (dicofol), dienochlor (dienochlor), diflovidazin (diflovidazin), diflubenzuron (diflubenzuron), dimefluthrin (dimefluthrin), dimethoate (dimethoate), dimethylvinphos (dimethylvinphos), dipropylidaz (dimpropyridaz), dinotefuran (dinotefuran),Diofenolan, disulfoton, DNOC, dT-80-phthalthrin, emamectin benzoate, empenthrin, endosulfan, EPN, epsilon-metofluthrin, epsilon-momfluorothrin, esfenvalerate, ethifencarb, ethiprole, etofenprox, etoxazole, etrimfos, Febantel, fenazaquin, fenbutatin oxide oxide), fenitrothion, fenmezoditiaz, fenobucarb, fenothiocarb, fenoxycarb, fenpropathrin, fenpyroximate, fenthion, fenvalerate, fipronil, flometoquin, flonicamid, fluacrylamide, Fluacrypyrim, fluazuron, flubendiamide, fluchlordiniliprole, flucycloxuron, flucythrinate, flufenerim, flufenoxuron, flufenprox, flufiprole, fluhexafon, flumethrin,Flupentiofenox, flupyradifurone, flupyrimin, flupyroxystrobin, fluralaner, fluvalinate, fluxametamide, fonophos, formetanate, formothion, furathiocarb b), gamma-cyhalothrin, halfenprox, halofenozide, heptafluthrin, hexaflumuron, hexythiazox, hydramethylnon, imidacloprid, imiprothrin, indazapyroxamet, indoxa indoxacarb, indoxacarb-MP, isocycloseram, isofenphos, isoflualanam, isoprocarb, isoxathion, kappa-bifenthrin, kappa-tefluthrin, lambda-cyhalothrin, ledpr ona (ledprona), lepimectin, lufenuron, malathion, meperfluthrin, metaflumizone, metalcarb, metaldehyde, methacrifos, methamidophos, methidathion, methomyl, methoprene,Methoxychlor, methoxyfenozide, methyl bromide bromide, metofluthrin, milbemectin, momfluorothrin, monocrotophos, muscalure, nicofluprole, nitenpyram, novaluron, noviflumuron, omethoate, oxazosulfyl, oxydemeton-methyl, oxydeprofos, parathion, parathion-methyl, pentachlorophenol, permethrin, phenothrin, phenthoate, phorate, phosalone, phosmet Phosmet, phosphamidon, phoxim, pioxaniliprole, piperflanilide, pirimicarb, pirimiphos-methyl, praziquantel, profenofos, profluthrin, propafos aphos, propargite, prothiofos, protrifenbute, pyflubumide, pymetrozine, pyraclofos, pyrafluprole, pyrethrins, pyridaben, pyridalyl, pyrifluquinazon,Pyrimidifen, pyriprole, pyriproxyfen, resmethrin, rotenone, silafluofen, spidoxamat, spinetoram, spinosad, spirobudifen, spirodiclofen, spiromesifen, Spiropidione, spirotetramat, spiromesifen, sulfiflumin, sulfotep, sulfoxaflor, sulprofos, tau-fluvalinate, tebufenozide, tebufenpyrad, teflubenzuron, tef Tefluthorin, terbufos, tetrachlorantraniliprole, tetrachlorvinphos, tetramethrin, tetramethylfluthrin, tetraniliprole, thiacloprid, thiamethoxam, thiocyclam m), thiodicarb, thiofanox, thiometon, thiolanthraniliprole, tolfenpyrad, tralomethrin, transfluthrin, triazamate, triazuron, trichlorfon, triflumezopyrim,Triflumuron, tyclopyrazoflor, vamidothion, zeta-cypermethrin. [2] The active ingredient B is selected from the group consisting of chlorpyrifos, phenthoate, bifenthrin, cypermethrin, etofenprox, lambda-cyhalothrin, acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, and the like. yram, Thiacloprid, Thiamethoxam, Sulfoxaflor, Flupyradifurone, Triflumezopyrim, Fenmezoditiaz, Spinetoram, Spinosad, Ethiprole, Fipronil, Broflanilide, Fluxame Fluxametamide, Isocycloseram, Abamectin, Emamectin-Benzoate, Chlorantraniliprole, Cyantraniliprole, Flubendiamide, Cyclaniliprole, Tetraniliprole, Pyridaben ben), cyenopyrafen, methoxyfenozide, lufenuron, buprofezin, etoxazole, benzpyrimoxan, pymetrozine, flonicamid, dimpropyridaz, spiromesifen, spirotetramat,The pesticide composition according to the above [1], wherein the active ingredient is selected from indoxacarb, pyridalyl, amitraz, bifenazate, and flupentiofenox. [3] A method for controlling pests by treating the active ingredient A described in [1] above and the active ingredient B described in [1] or [2] above simultaneously or in close temporal proximity. [4] The control method according to [3] above, which comprises treating seeds with the active ingredient A according to [1] above and the active ingredient B according to [1] or [2] above simultaneously or in close temporal proximity. [Effects of the Invention]
[0019] The composition and method of the present invention exhibit excellent synergistic control effects against various pests, and also exhibit sufficient synergistic control effects against pests that have acquired resistance to existing pest control agents.
[0020] Therefore, the present invention can provide useful novel pesticide compositions and effective pest control methods using them. DETAILED DESCRIPTION OF THE INVENTION
[0021] The aryltetrahydropyridine compound represented by formula (1) (hereinafter also referred to as "compound (1)"), which is the active ingredient A of the composition and method of the present invention, will be described in detail below.
[0022] Compound (1) may exist as a tautomer represented by the following formula, and compound (1) includes all tautomers or a mixture of tautomers containing any ratio.
[0023] [ka]
[0024] Compound (1) may exist as E- and Z-geometric isomers depending on the type of substituent, and compound (1) encompasses a mixture containing these E-, Z-, or E- and Z-isomers in any ratio.
[0025] Furthermore, compound (1) exists in optically active forms due to the presence of one or more asymmetric carbon atoms or asymmetric sulfur atoms, and compound (1) includes all optically active forms and racemic forms.
[0026] Compound (1) may have tautomers depending on the type of substituent, and compound (1) includes all tautomers or a mixture of tautomers containing any ratio.
[0027] Furthermore, compound (1) may exist as one or more rotational isomers due to restricted bond rotation caused by steric hindrance between substituents, and compound (1) encompasses all rotational isomers or a mixture of diastereomers containing all rotational isomers in any ratio.
[0028] Among Compound (1), those which can be converted into salts by a conventional method include salts of hydrohalic acids such as hydrofluoric acid, hydrochloric acid, hydrobromic acid, and hydroiodic acid; salts of inorganic acids such as nitric acid, sulfuric acid, phosphoric acid, chloric acid, and perchloric acid; salts of sulfonic acids such as methanesulfonic acid, ethanesulfonic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, and p-toluenesulfonic acid; salts of carboxylic acids such as formic acid, acetic acid, propionic acid, trifluoroacetic acid, fumaric acid, tartaric acid, oxalic acid, maleic acid, malic acid, succinic acid, benzoic acid, mandelic acid, ascorbic acid, lactic acid, gluconic acid, and citric acid; salts of amino acids such as glutamic acid and aspartic acid; salts of alkali metals such as lithium, sodium, and potassium; salts of alkaline earth metals such as calcium, barium, and magnesium; aluminum salts; and quaternary ammonium salts such as tetramethylammonium salt, tetrabutylammonium salt, and benzyltrimethylammonium salt.
[0029] Next, specific examples of each substituent shown in this specification are shown below, where n- means normal, i- means iso, s- means secondary, and tert- means tertiary.
[0030] As used herein, the term "halogen atom" includes a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. The term "halo" also refers to these halogen atoms.
[0031] In this specification, "C a ~C b The term "alkyl" refers to a linear or branched hydrocarbon group having a to b carbon atoms, and specific examples thereof include methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, s-butyl, tert-butyl, n-pentyl, 1,1-dimethylpropyl, and n-hexyl, each of which is selected within the range of the number of carbon atoms specified.
[0032] As used herein, "halo(C a ~C bThe notation "alkyl" represents a linear or branched hydrocarbon group having a to b carbon atoms in which hydrogen atoms bonded to the carbon atoms are optionally substituted with halogen atoms, and in this case, when the alkyl group is substituted with two or more halogen atoms, the halogen atoms may be the same or different from each other. Examples of alkyl groups include fluoromethyl, chloromethyl, bromomethyl, iodomethyl, difluoromethyl, dichloromethyl, trifluoromethyl, chlorodifluoromethyl, trichloromethyl, bromodifluoromethyl, 1-fluoroethyl, 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2,2-trichloroethyl, 2-bromo-2,2-difluoroethyl, 1,1,2,2-tetrafluoroethyl, 2-chloro-1,1,2-trifluoroethyl, 2-chloro-1,1,2,2-tetrafluoroethyl, pentafluoroethyl, 2,2-difluoro Specific examples include propyl, 3,3,3-trifluoropropyl, 3-bromo-3,3-difluoropropyl, 2,2,3,3-tetrafluoropropyl, 2,2,3,3,3-pentafluoropropyl, 1,1,2,3,3,3-hexafluoropropyl, heptafluoropropyl, 2,2,2-trifluoro-1-(methyl)ethyl, 2,2,2-trifluoro-1-(trifluoromethyl)ethyl, 1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl, 2,2,3,4,4,4-hexafluorobutyl, 2,2,3,3,4,4,4-heptafluorobutyl, nonafluorobutyl, and the like, and the number of carbon atoms is selected within the range specified for each.
[0033] Compound (1) used as the active ingredient A in the composition and method of the present invention can be produced in accordance with the method described in WO 2024 / 048778 and the like.
[0034] Examples of compound (1) used as active ingredient A in the composition and method of the present invention are shown in Tables 1 and 2. However, compound (1) used as active ingredient A in the present invention is not limited to these.
[0035] Examples of compound (1) used as active ingredient A in the composition and method of the present invention are shown in Tables 1 to 3. However, compound (1) used as active ingredient A in the present invention is not limited to these.
[0036] In the table, Q-1, Q-2, Q-3, Q-4 and Q-12a represent the following structures, respectively.
[0037] [ka]
[0038] In addition, the descriptions G-1 and G-3 in the table represent the following structures, respectively.
[0039] [ka]
[0040] The numbers in the structural formula above indicate the substituents (Z 1 ) t2 , (Z 1 ) t3 , (Z 1 ) t4 , (Z 1 ) t5 or (Z 2 ) t4 For example, in the table, "Q-1(4-F)" represents "4-fluorophenyl", and "Q-4" or the like, which has no description of the substituent, represents unsubstituted.
[0041] Also, "mp" represents the melting point (unit: °C).
[0042] [Table 1]
[0043] [ka]
[0044] ———————————————————————————————— No. R 1 Q G m.p.(℃) ———————————————————————————————— 1-01 Cl Q-3(3-F) G-1(4-F) 187-189 1-02 Cl Q-3(4-F) G-3(3-Cl) 162-164 1-03 CF3Q-4 G-1(4-F) 194-196 1-04 CF3Q-3 G-3(3-F) 151-153 1-05 CF3Q-2(4-F) G-1(4-F) 174-176 1-06 CF3Q-4(4-Cl) G-3(3-F) 154-156 1-06 CF3Q-4(4-Cl) G-3(3-F) 154-156 1-13 Cl Q-3(4-F,6-F) G-3(3-F) 199-201 1-14 Cl Q-4(4-Br) G-3(3-F) 154-156 1-15 Cl Q-12a G-3(3-F) 217-219 1-16 CF3Q-3(4-F) G-3(3-F) 169-171 1-17 Cl Q-3(3-Cl) G-3(3-F) 211-213 1-18 CF3Q-3 G-1(4-F) 136-138 1-19 CF3Q-3(6-F) G-3(3-F) 99-101 ———————————————————————————————— [Table 2]
[0045]
Chemical formula
[0046] ———————————————————————————————— No. Q G m.p.(℃) ------------------------------------------------------------------ 1-07 Q-2(4-F) G-3(3-F) 216-218 1-08 Q-1(4-F) G-3(3-Cl) 196-198 1-09 Q-3(4-F) G-3(3-F) 159-161 1-10 Q-3(4-F) G-3(3-Cl) 174-177 1-11 Q-3(4-F) G-1(4-F) 214-216 1-12 Q-2(4-Cl) G-3(3-CF3) 179-181 1-20 Q-3(4-F) G-3(3-Cl,6-F) 209-211 1-21 Q-3(4-F) G-3(3-CHF2) 181-183 1-22 Q-3(4-F) G-1(2-Cl) 99-101 ---------------------------------------------------------------------------------- [Table 3]
[0047] [ka]
[0048] ------------------------------------------------------------------ No. QG mp(℃) ------------------------------------------------------------------ 1-23 Q-3(4-F) G-3(3-Cl) 201-203 1-24 Q-3(4-F) G-3(3-F) 166-168 ------------------------------------------------------------------ The active ingredient A in the composition and method of the present invention can be used alone or in a mixture of two or more kinds, and the ratio in the case of mixing can also be freely selected.
[0049] The active ingredient B in the composition and method of the present invention is a compound known to have insecticidal, acaricidal, nematicidal, molluscicidal, fungicidal or bactericidal activity, and is a compound selected from the following active ingredient groups B1 to B-XV, specific examples of which are shown in the following Tables 4 to 18 together with their compound numbers. Active ingredients BI group [Table 4] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- A01 Acephate A02 Cadusafos A03 Chlorpyrifos A04 Diazinon A05 Dichlorvos A06 Dimethoate A07 EPN A08 Malathion A09 Methamidophos A10 Parathion-methyl A11 Phenthoate A12 Phorate A13 Phosmet A14 Phoxim A15 Profenofos A16 Terbufos A17 Fenitrothion ---------------------------------------------------------------------------------- Active ingredients B-II group [Table 5] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- B01 Aldicarb B02 Benfuracarb B03 Carbaryl B04 Carbofuran B05 Carbosulfan B06 Methomyl B07 Pirimicarb B08 Thiodicarb B09 Alanycarb ---------------------------------------------------------------------------------- Active ingredients B-III group [Table 6] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- C01 Acrinathrin C02 Bifenthrin C03 Cyfluthrin C04 Cypermethrin C05 Deltamethrin C06 Esfenvalerate C07 Etofenprox C08 Permethrin C09 Tefluthrin C10 Lambda-Cyhalothrin C11 tau-Fluvalinate C12 Silafluofen ---------------------------------------------------------------------------------- Active ingredients B-IV group [Table 7] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- D01 Bensultap D02 Cartap D03 Thiocyclam ---------------------------------------------------------------------------------- Active ingredients BV group [Table 8] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- E01 Acetamiprid E02 Clothianidin E03 Dinotefuran E04 Imidacloprid E05 Nitenpyram E06 Thiacloprid E07 Thiamethoxam E08 Sulfoxaflor E09 Flupyradifurone E10 Triflumezopyrim E11 Dichloromezotiaz E12 Flupyrimin E13 Fenmezoditiaz ---------------------------------------------------------------------------------- Active ingredients B-VI group [Table 9] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- F01 Spinetoram F02 Spinosad ---------------------------------------------------------------------------------- Active ingredients B-VII group [Table 10] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- G01 Ethiprole G02 Fipronil G03 Broflanilide G04 Fluxametamide G05 Nicofluprole G06 Cyproflanilide G07 Isocycloseram G08 Fluralaner ---------------------------------------------------------------------------------- Active ingredients B-VIII group [Table 11] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- H01 Abamectin H02 Emamectin benzoate H03 Lepimectin H04 Milbemectin ---------------------------------------------------------------------------------- Active ingredients B-IX group [Table 12] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- I01 Chlorantraniliprole I02 Cyantraniliprole I03 Flubendiamide I04 Cyclaniliprole I05 Tetraniliprole I06 Cyhalodiamide I07 Thiorantraniliprole I08 Tetrachlorantraniliprole ---------------------------------------------------------------------------------- Active ingredient BX group [Table 13] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- J01 Diafenthiuron J02 Fenpyroximate J03 Pyridaben J04 Tolfenpyrad J05 Cyenopyrafen J06 Cyflumetofen J07 Pyflubumide J08 Hydramethylnon J09 Acequinocyl J10 Chlorfenapyr J11 flometoquin J12 Cyetpyrafen J13 Pyrimidifen ---------------------------------------------------------------------------------- Active ingredients B-XI group [Table 14] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- K01 Pyriproxyfen K02 Methoxyfenozide K03 Diflubenzuron K04 Flufenoxuron K05 Lufenuron K06 Novaluron K07 Teflubenzuron K08 Buprofezin K09 Hexythiazox K10 Etoxazole K11 Benzpyrimoxan K12 Chromafenozide K13 Chlorfluazuron K14 Hexythiazox K15 Tebfenozide ---------------------------------------------------------------------------------- Active ingredients B-XII group [Table 15] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- L01 Bacillus thuringensis L02 Bacillus sphaericus ---------------------------------------------------------------------------------- Active ingredients B-XIII group [Table 16] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- M01 Pymetrozine M02 Pyrifluquinazon M03 Afidopyropen M04 Flonicamid M05 Dimpropyridaz ---------------------------------------------------------------------------------- Active ingredients B-XIV group [Table 17] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- N01 Spirodiclofen N02 Spiromesifen N03 Spirotetramat N04 Spidoxamat N05 Spiropidione N06 Spirobudifen ---------------------------------------------------------------------------------- Active ingredients B-XV group [Table 18] ---------------------------------------------------------------------------------- No. Compound name (common name) ---------------------------------------------------------------------------------- O01 Indoxacarb O02 Metaflumizone O03 Cyromazine O04 Azadirachtin O05 Pyridalyl O06 Amitraz O07 Bifenazate O08 Flupentiofenox O09 Metaldehyde O10 Oxazosulfyl O11 Acinonapyr O12 Cybenzoxasulfyl O13 Indazapyroxamet O14 Tyclopyrazoflor O15 Thiapyrachlor O16 NK-518 (Test name) O17 NI-40 (Test name) O18 NNI-2101 (Test name) O19 SYJ-293 (Test name) O20 MIE-2110 (Test name) ---------------------------------------------------------------------------------- In the composition and method of the present invention, the active ingredient B can be used alone or in combination of two or more kinds, and the ratio of the mixtures can also be freely selected.
[0050] Next, examples of combinations of the first active ingredient A and the second active ingredient B of the composition of the present invention are given below. In the notation below, for example, the notation "1-01 + (A01)" indicates a combination in which the active ingredient A is the compound No. 1-01 in Table 1, and the active ingredient B is Acephate No. A01 in Table 4.
[0051] Example of compound combination: 「1-01+(A01)」、「1-01+(A02)」、「1-01+(A03)」、「1-01+(A04)」、「1-01+(A05)」、「1-01+(A06)」、「1-01+(A07)」、「1-01+(A08)」、「1-01+(A09)」、「1-01+(A10)」、「1-01+(A11)」、「1-01+(A12)」、「1-01+(A13)」、「1-01+(A14)」、「1-01+(A15)」、「1-01+(A16)」、「1-01+(A17)」、「1-01+(B01)」、「1-01+(B02)」、「1-01+(B03)」、「1-01+(B04)」、「1-01+(B05)」、「1-01+(B06)」、「1-01+(B07)」、「1-01+(B08)」、「1-01+(B09)」、「1-01+(C01)」、「1-01+(C02)」、「1-01+(C03)」、「1-01+(C04)」、「1-01+(C05)」、「1-01+(C06)」、「1-01+(C07)」、「1-01+(C08)」、「1-01+(C09)」、「1-01+(C10)」、「1-01+(C11)」、「1-01+(C12)」、「1-01+(D01)」、「1-01+(D02)」、「1-01+(D03)」、「1-01+(E01)」、「1-01+(E02)」、「1-01+(E03)」、「1-01+(E04)」、「1-01+(E05)」、「1-01+(E06)」、「1-01+(E07)」、「1-01+(E08)」、「1-01+(E09)」、「1-01+(E10)」、「1-01+(E11)」、「1-01+(E12)」、「1-01+(E13)」、「1-01+(F01)」、「1-01+(F02)」、「1-01+(G01)」、「1-01+(G02)」、「1-01+(G03)」、「1-01+(G04)」、「1-01+(G05)」、「1-01+(G06)」、「1-01+(G07)」、「1-01+(G08)」、「1-01+(H01)」、「1-01+(H02)」、「1-01+(H03)」、「1-01+(H04)」、「1-01+(I01)」、「1-01+(I02)」、「1-01+(I03)」、「1-01+(I04)」、「1-01+(I05)」、「1-01+(I06)」、「1-01+(I07)」、「1-01+(I08)」、「1-01+(J01)」、「1-01+(J02)」、「1-01+(J03)」、「1-01+(J04)」、「1-01+(J05)」、「1-01+(J06)」、「1-01+(J07)」、「1-01+(J08)」、「1-01+(J09)」、「1-01+(J10)」、「1-01+(J11)」、「1-01+(J12)」、「1-01+(J13)」、「1-01+(K01)」、「1-01+(K02)」、「1-01+(K03)」、「1-01+(K04)」、「1-01+(K05)」、「1-01+(K06)」、「1-01+(K07)」、「1-01+(K08)」、「1-01+(K09)」、「1-01+(K10)」、「1-01+(K11)」、「1-01+(K12)」、「1-01+(K13)」、「1-01+(K14)」、「1-01+(K15)」、「1-01+(L01)」、「1-01+(L02)」、「1-01+(M01)」、「1-01+(M02)」、「1-01+(M03)」、「1-01+(M04)」、「1-01+(M05)」、「1-01+(M06)」、「1-01+(M07)」、「1-01+(M08)」、「1-01+(N01)」、「1-01+(N02)」、「1-01+(N03)」、「1-01+(N04)」、「1-01+(N05)」、「1-01+(N06)」、「1-01+(O01)」、「1-01+(O02)」、「1-01+(O03)」、「1-01+(O04)」、「1-01+(O05)」、「1-01+(O06)」、「1-01+(O07)」、「1-01+(O08)」、「1-01+(O09)」、「1-01+(O10)」、「1-01+(O11)」、「1-01+(O12)」、「1-01+(O13)」、「1-01+(O14)」、「1-01+(O15)」、「1-01+(O16)」、「1-01+(O17)」、「1-02+(A01)」、「1-02+(A02)」、「1-02+(A03)」、「1-02+(A04)」、「1-02+(A05)」、「1-02+(A06)」、「1-02+(A07)」、「1-02+(A08)」、「1-02+(A09)」、「1-02+(A10)」、「1-02+(A11)」、「1-02+(A12)」、「1-02+(A13)」、「1-02+(A14)」、「1-02+(A15)」、「1-02+(A16)」、「1-02+(A17)」、「1-02+(B01)」、「1-02+(B02)」、「1-02+(B03)」、「1-02+(B04)」、「1-02+(B05)」、「1-02+(B06)」、「1-02+(B07)」、「1-02+(B08)」、「1-02+(B09)」、「1-02+(C01)」、「1-02+(C02)」、「1-02+(C03)」、「1-02+(C04)」、「1-02+(C05)」、「1-02+(C06)」、「1-02+(C07)」、「1-02+(C08)」、「1-02+(C09)」、「1-02+(C10)」、「1-02+(C11)」、「1-02+(C12)」、「1-02+(D01)」、「1-02+(D02)」、「1-02+(D03)」、「1-02+(E01)」、「1-02+(E02)」、「1-02+(E03)」、「1-02+(E04)」、「1-02+(E05)」、「1-02+(E06)」、「1-02+(E07)」、「1-02+(E08)」、「1-02+(E09)」、「1-02+(E10)」、「1-02+(E11)」、「1-02+(E12)」、「1-02+(E13)」、「1-02+(F01)」、「1-02+(F02)」、「1-02+(G01)」、「1-02+(G02)」、「1-02+(G03)」、「1-02+(G04)」、「1-02+(G05)」、「1-02+(G06)」、「1-02+(G07)」、「1-02+(G08)」、「1-02+(H01)」、「1-02+(H02)」、「1-02+(H03)」、「1-02+(H04)」、「1-02+(I01)」、「1-02+(I02)」、「1-02+(I03)」、「1-02+(I04)」、「1-02+(I05)」、「1-02+(I06)」、「1-02+(I07)」、「1-02+(I08)」、「1-02+(J01)」、「1-02+(J02)」、「1-02+(J03)」、「1-02+(J04)」、「1-02+(J05)」、「1-02+(J06)」、「1-02+(J07)」、「1-02+(J08)」、「1-02+(J09)」、「1-02+(J10)」、「1-02+(J11)」、「1-02+(J12)」、「1-02+(J13)」、「1-02+(K01)」、「1-02+(K02)」、「1-02+(K03)」、「1-02+(K04)」、「1-02+(K05)」、「1-02+(K06)」、「1-02+(K07)」、「1-02+(K08)」、「1-02+(K09)」、「1-02+(K10)」、「1-02+(K11)」、「1-02+(K12)」、「1-02+(K13)」、「1-02+(K14)」、「1-02+(K15)」、「1-02+(L01)」、「1-02+(L02)」、「1-02+(M01)」、「1-02+(M02)」、「1-02+(M03)」、「1-02+(M04)」、「1-02+(M05)」、「1-02+(M06)」、「1-02+(M07)」、「1-02+(M08)」、「1-02+(N01)」、「1-02+(N02)」、「1-02+(N03)」、「1-02+(N04)」、「1-02+(N05)」、「1-02+(N06)」、「1-02+(O01)」、「1-02+(O02)」、「1-02+(O03)」、「1-02+(O04)」、「1-02+(O05)」、「1-02+(O06)」、「1-02+(O07)」、「1-02+(O08)」、「1-02+(O09)」、「1-02+(O10)」、「1-02+(O11)」、「1-02+(O12)」、「1-02+(O13)」、「1-02+(O14)」、「1-02+(O15)」、「1-02+(O16)」、「1-02+(O17)」、「1-03+(A01)」、「1-03+(A02)」、「1-03+(A03)」、「1-03+(A04)」、「1-03+(A05)」、「1-03+(A06)」、「1-03+(A07)」、「1-03+(A08)」、「1-03+(A09)」、「1-03+(A10)」、「1-03+(A11)」、「1-03+(A12)」、「1-03+(A13)」、「1-03+(A14)」、「1-03+(A15)」、「1-03+(A16)」、「1-03+(A17)」、「1-03+(B01)」、「1-03+(B02)」、「1-03+(B03)」、「1-03+(B04)」、「1-03+(B05)」、「1-03+(B06)」、「1-03+(B07)」、「1-03+(B08)」、「1-03+(B09)」、「1-03+(C01)」、「1-03+(C02)」、「1-03+(C03)」、「1-03+(C04)」、「1-03+(C05)」、「1-03+(C06)」、「1-03+(C07)」、「1-03+(C08)」、「1-03+(C09)」、「1-03+(C10)」、「1-03+(C11)」、「1-03+(C12)」、「1-03+(D01)」、「1-03+(D02)」、「1-03+(D03)」、「1-03+(E01)」、「1-03+(E02)」、「1-03+(E03)」、「1-03+(E04)」、「1-03+(E05)」、「1-03+(E06)」、「1-03+(E07)」、「1-03+(E08)」、「1-03+(E09)」、「1-03+(E10)」、「1-03+(E11)」、「1-03+(E12)」、「1-03+(E13)」、「1-03+(F01)」、「1-03+(F02)」、「1-03+(G01)」、「1-03+(G02)」、「1-03+(G03)」、「1-03+(G04)」、「1-03+(G05)」、「1-03+(G06)」、「1-03+(G07)」、「1-03+(G08)」、「1-03+(H01)」、「1-03+(H02)」、「1-03+(H03)」、「1-03+(H04)」、「1-03+(I01)」、「1-03+(I02)」、「1-03+(I03)」、「1-03+(I04)」、「1-03+(I05)」、「1-03+(I06)」、「1-03+(I07)」、「1-03+(I08)」、「1-03+(J01)」、「1-03+(J02)」、「1-03+(J03)」、「1-03+(J04)」、「1-03+(J05)」、「1-03+(J06)」、「1-03+(J07)」、「1-03+(J08)」、「1-03+(J09)」、「1-03+(J10)」、「1-03+(J11)」、「1-03+(J12)」、「1-03+(J13)」、「1-03+(K01)」、「1-03+(K02)」、「1-03+(K03)」、「1-03+(K04)」、「1-03+(K05)」、「1-03+(K06)」、「1-03+(K07)」、「1-03+(K08)」、「1-03+(K09)」、「1-03+(K10)」、「1-03+(K11)」、「1-03+(K12)」、「1-03+(K13)」、「1-03+(K14)」、「1-03+(K15)」、「1-03+(L01)」、「1-03+(L02)」、「1-03+(M01)」、「1-03+(M02)」、「1-03+(M03)」、「1-03+(M04)」、「1-03+(M05)」、「1-03+(M06)」、「1-03+(M07)」、「1-03+(M08)」、「1-03+(N01)」、「1-03+(N02)」、「1-03+(N03)」、「1-03+(N04)」、「1-03+(N05)」、「1-03+(N06)」、「1-03+(O01)」、「1-03+(O02)」、「1-03+(O03)」、「1-03+(O04)」、「1-03+(O05)」、「1-03+(O06)」、「1-03+(O07)」、「1-03+(O08)」、「1-03+(O09)」、「1-03+(O10)」、「1-03+(O11)」、「1-03+(O12)」、「1-03+(O13)」、「1-03+(O14)」、「1-03+(O15)」、「1-03+(O16)」、「1-03+(O17)」、「1-04+(A01)」、「1-04+(A02)」、「1-04+(A03)」、「1-04+(A04)」、「1-04+(A05)」、「1-04+(A06)」、「1-04+(A07)」、「1-04+(A08)」、「1-04+(A09)」、「1-04+(A10)」、「1-04+(A11)」、「1-04+(A12)」、「1-04+(A13)」、「1-04+(A14)」、「1-04+(A15)」、「1-04+(A16)」、「1-04+(A17)」、「1-04+(B01)」、「1-04+(B02)」、「1-04+(B03)」、「1-04+(B04)」、「1-04+(B05)」、「1-04+(B06)」、「1-04+(B07)」、「1-04+(B08)」、「1-04+(B09)」、「1-04+(C01)」、「1-04+(C02)」、「1-04+(C03)」、「1-04+(C04)」、「1-04+(C05)」、「1-04+(C06)」、「1-04+(C07)」、「1-04+(C08)」、「1-04+(C09)」、「1-04+(C10)」、「1-04+(C11)」、「1-04+(C12)」、「1-04+(D01)」、「1-04+(D02)」、「1-04+(D03)」、「1-04+(E01)」、「1-04+(E02)」、「1-04+(E03)」、「1-04+(E04)」、「1-04+(E05)」、「1-04+(E06)」、「1-04+(E07)」、「1-04+(E08)」、「1-04+(E09)」、「1-04+(E10)」、「1-04+(E11)」、「1-04+(E12)」、「1-04+(E13)」、「1-04+(F01)」、「1-04+(F02)」、「1-04+(G01)」、「1-04+(G02)」、「1-04+(G03)」、「1-04+(G04)」、「1-04+(G05)」、「1-04+(G06)」、「1-04+(G07)」、「1-04+(G08)」、「1-04+(H01)」、「1-04+(H02)」、「1-04+(H03)」、「1-04+(H04)」、「1-04+(I01)」、「1-04+(I02)」、「1-04+(I03)」、「1-04+(I04)」、「1-04+(I05)」、「1-04+(I06)」、「1-04+(I07)」、「1-04+(I08)」、「1-04+(J01)」、「1-04+(J02)」、「1-04+(J03)」、「1-04+(J04)」、「1-04+(J05)」、「1-04+(J06)」、「1-04+(J07)」、「1-04+(J08)」、「1-04+(J09)」、「1-04+(J10)」、「1-04+(J11)」、「1-04+(J12)」、「1-04+(J13)」、「1-04+(K01)」、「1-04+(K02)」、「1-04+(K03)」、「1-04+(K04)」、「1-04+(K05)」、「1-04+(K06)」、「1-04+(K07)」、「1-04+(K08)」、「1-04+(K09)」、「1-04+(K10)」、「1-04+(K11)」、「1-04+(K12)」、「1-04+(K13)」、「1-04+(K14)」、「1-04+(K15)」、「1-04+(L01)」、「1-04+(L02)」、「1-04+(M01)」、「1-04+(M02)」、「1-04+(M03)」、「1-04+(M04)」、「1-04+(M05)」、「1-04+(M06)」、「1-04+(M07)」、「1-04+(M08)」、「1-04+(N01)」、「1-04+(N02)」、「1-04+(N03)」、「1-04+(N04)」、「1-04+(N05)」、「1-04+(N06)」、「1-04+(O01)」、「1-04+(O02)」、「1-04+(O03)」、「1-04+(O04)」、「1-04+(O05)」、「1-04+(O06)」、「1-04+(O07)」、「1-04+(O08)」、「1-04+(O09)」、「1-04+(O10)」、「1-04+(O11)」、「1-04+(O12)」、「1-04+(O13)」、「1-04+(O14)」、「1-04+(O15)」、「1-04+(O16)」、「1-04+(O17)」、「1-05+(A01)」、「1-05+(A02)」、「1-05+(A03)」、「1-05+(A04)」、「1-05+(A05)」、「1-05+(A06)」、「1-05+(A07)」、「1-05+(A08)」、「1-05+(A09)」、「1-05+(A10)」、「1-05+(A11)」、「1-05+(A12)」、「1-05+(A13)」、「1-05+(A14)」、「1-05+(A15)」、「1-05+(A16)」、「1-05+(A17)」、「1-05+(B01)」、「1-05+(B02)」、「1-05+(B03)」、「1-05+(B04)」、「1-05+(B05)」、「1-05+(B06)」、「1-05+(B07)」、「1-05+(B08)」、「1-05+(B09)」、「1-05+(C01)」、「1-05+(C02)」、「1-05+(C03)」、「1-05+(C04)」、「1-05+(C05)」、「1-05+(C06)」、「1-05+(C07)」、「1-05+(C08)」、「1-05+(C09)」、「1-05+(C10)」、「1-05+(C11)」、「1-05+(C12)」、「1-05+(D01)」、「1-05+(D02)」、「1-05+(D03)」、「1-05+(E01)」、「1-05+(E02)」、「1-05+(E03)」、「1-05+(E04)」、「1-05+(E05)」、「1-05+(E06)」、「1-05+(E07)」、「1-05+(E08)」、「1-05+(E09)」、「1-05+(E10)」、「1-05+(E11)」、「1-05+(E12)」、「1-05+(E13)」、「1-05+(F01)」、「1-05+(F02)」、「1-05+(G01)」、「1-05+(G02)」、「1-05+(G03)」、「1-05+(G04)」、「1-05+(G05)」、「1-05+(G06)」、「1-05+(G07)」、「1-05+(G08)」、「1-05+(H01)」、「1-05+(H02)」、「1-05+(H03)」、「1-05+(H04)」、「1-05+(I01)」、「1-05+(I02)」、「1-05+(I03)」、「1-05+(I04)」、「1-05+(I05)」、「1-05+(I06)」、「1-05+(I07)」、「1-05+(I08)」、「1-05+(J01)」、「1-05+(J02)」、「1-05+(J03)」、「1-05+(J04)」、「1-05+(J05)」、「1-05+(J06)」、「1-05+(J07)」、「1-05+(J08)」、「1-05+(J09)」、「1-05+(J10)」、「1-05+(J11)」、「1-05+(J12)」、「1-05+(J13)」、「1-05+(K01)」、「1-05+(K02)」、「1-05+(K03)」、 「1-05+(K04)」、「1-05+(K05)」、「1-05+(K06)」、「1-05+(K07)」、「1-05+(K08)」、「1-05+(K09)」、「1-05+(K10)」、「1-05+(K11)」、「1-05+(K12)」、「1-05+(K13)」、「1-05+(K14)」、「1-05+(K15)」、「1-05+(L01)」、「1-05+(L02)」、「1-05+(M01)」、「1-05+(M02)」、「1-05+(M03)」、「1-05+(M04)」、「1-05+(M05)」、「1-05+(M06)」、「1-05+(M07)」、「1-05+(M08)」、「1-05+(N01)」、「1-05+(N02)」、「1-05+(N03)」、「1-05+(N04)」、「1-05+(N05)」、「1-05+(N06)」、「1-05+(O01)」、「1-05+(O02)」、「1-05+(O03)」、「1-05+(O04)」、「1-05+(O05)」、「1-05+(O06)」、「1-05+(O07)」、「1-05+(O08)」、「1-05+(O09)」、「1-05+(O10)」、「1-05+(O11)」、「1-05+(O12)」、「1-05+(O13)」、「1-05+(O14)」、「1-05+(O15)」、「1-05+(O16)」、「1-05+(O17)」、「1-06+(A01)」、「1-06+(A02)」、「1-06+(A03)」、「1-06+(A04)」、「1-06+(A05)」、「1-06+(A06)」、「1-06+(A07)」、「1-06+(A08)」、「1-06+(A09)」、「1-06+(A10)」、「1-06+(A11)」、「1-06+(A12)」、「1-06+(A13)」、「1-06+(A14)」、「1-06+(A15)」、「1-06+(A16)」、「1-06+(A17)」、「1-06+(B01)」、「1-06+(B02)」、「1-06+(B03)」、「1-06+(B04)」、「1-06+(B05)」、「1-06+(B06)」、「1-06+(B07)」、「1-06+(B08)」、「1-06+(B09)」、「1-06+(C01)」、「1-06+(C02)」、「1-06+(C03)」、「1-06+(C04)」、「1-06+(C05)」、「1-06+(C06)」、「1-06+(C07)」、「1-06+(C08)」、「1-06+(C09)」、「1-06+(C10)」、「1-06+(C11)」、「1-06+(C12)」、「1-06+(D01)」、「1-06+(D02)」、「1-06+(D03)」、「1-06+(E01)」、「1-06+(E02)」、「1-06+(E03)」、「1-06+(E04)」、「1-06+(E05)」、「1-06+(E06)」、「1-06+(E07)」、「1-06+(E08)」、「1-06+(E09)」、「1-06+(E10)」、「1-06+(E11)」、「1-06+(E12)」、「1-06+(E13)」、「1-06+(F01)」、「1-06+(F02)」、「1-06+(G01)」、「1-06+(G02)」、「1-06+(G03)」、「1-06+(G04)」、「1-06+(G05)」、「1-06+(G06)」、「1-06+(G07)」、「1-06+(G08)」、「1-06+(H01)」、「1-06+(H02)」、「1-06+(H03)」、「1-06+(H04)」、「1-06+(I01)」、「1-06+(I02)」、「1-06+(I03)」、「1-06+(I04)」、「1-06+(I05)」、「1-06+(I06)」、「1-06+(I07)」、「1-06+(I08)」、「1-06+(J01)」、「1-06+(J02)」、「1-06+(J03)」、「1-06+(J04)」、「1-06+(J05)」、「1-06+(J06)」、「1-06+(J07)」、「1-06+(J08)」、「1-06+(J09)」、「1-06+(J10)」、「1-06+(J11)」、「1-06+(J12)」、「1-06+(J13)」、「1-06+(K01)」、「1-06+(K02)」、「1-06+(K03)」、「1-06+(K04)」、「1-06+(K05)」、「1-06+(K06)」、「1-06+(K07)」、「1-06+(K08)」、「1-06+(K09)」、「1-06+(K10)」、「1-06+(K11)」、「1-06+(K12)」、「1-06+(K13)」、「1-06+(K14)」、「1-06+(K15)」、「1-06+(L01)」、「1-06+(L02)」、「1-06+(M01)」、「1-06+(M02)」、「1-06+(M03)」、「1-06+(M04)」、「1-06+(M05)」、「1-06+(M06)」、「1-06+(M07)」、「1-06+(M08)」、「1-06+(N01)」、「1-06+(N02)」、「1-06+(N03)」、「1-06+(N04)」、「1-06+(N05)」、「1-06+(N06)」、「1-06+(O01)」、「1-06+(O02)」、「1-06+(O03)」、「1-06+(O04)」、「1-06+(O05)」、「1-06+(O06)」、「1-06+(O07)」、「1-06+(O08)」、「1-06+(O09)」、「1-06+(O10)」、「1-06+(O11)」、「1-06+(O12)」、「1-06+(O13)」、「1-06+(O14)」、「1-06+(O15)」、「1-06+(O16)」、「1-06+(O17)」、「1-07+(A01)」、「1-07+(A02)」、「1-07+(A03)」、「1-07+(A04)」、「1-07+(A05)」、「1-07+(A06)」、「1-07+(A07)」、「1-07+(A08)」、「1-07+(A09)」、「1-07+(A10)」、「1-07+(A11)」、「1-07+(A12)」、「1-07+(A13)」、「1-07+(A14)」、「1-07+(A15)」、「1-07+(A16)」、「1-07+(A17)」、「1-07+(B01)」、「1-07+(B02)」、「1-07+(B03)」、「1-07+(B04)」、「1-07+(B05)」、「1-07+(B06)」、「1-07+(B07)」、「1-07+(B08)」、「1-07+(B09)」、「1-07+(C01)」、「1-07+(C02)」、「1-07+(C03)」、「1-07+(C04)」、「1-07+(C05)」、「1-07+(C06)」、「1-07+(C07)」、「1-07+(C08)」、「1-07+(C09)」、「1-07+(C10)」、「1-07+(C11)」、「1-07+(C12)」、「1-07+(D01)」、「1-07+(D02)」、「1-07+(D03)」、「1-07+(E01)」、「1-07+(E02)」、「1-07+(E03)」、「1-07+(E04)」、「1-07+(E05)」、「1-07+(E06)」、「1-07+(E07)」、「1-07+(E08)」、「1-07+(E09)」、「1-07+(E10)」、「1-07+(E11)」、「1-07+(E12)」、「1-07+(E13)」、「1-07+(F01)」、「1-07+(F02)」、「1-07+(G01)」、「1-07+(G02)」、「1-07+(G03)」、「1-07+(G04)」、「1-07+(G05)」、「1-07+(G06)」、「1-07+(G07)」、「1-07+(G08)」、「1-07+(H01)」、「1-07+(H02)」、「1-07+(H03)」、「1-07+(H04)」、「1-07+(I01)」、「1-07+(I02)」、「1-07+(I03)」、「1-07+(I04)」、「1-07+(I05)」、「1-07+(I06)」、「1-07+(I07)」、「1-07+(I08)」、「1-07+(J01)」、「1-07+(J02)」、「1-07+(J03)」、「1-07+(J04)」、「1-07+(J05)」、「1-07+(J06)」、「1-07+(J07)」、「1-07+(J08)」、「1-07+(J09)」、「1-07+(J10)」、「1-07+(J11)」、「1-07+(J12)」、「1-07+(J13)」、「1-07+(K01)」、「1-07+(K02)」、「1-07+(K03)」、「1-07+(K04)」、「1-07+(K05)」、「1-07+(K06)」、「1-07+(K07)」、「1-07+(K08)」、「1-07+(K09)」、「1-07+(K10)」、「1-07+(K11)」、「1-07+(K12)」、「1-07+(K13)」、「1-07+(K14)」、「1-07+(K15)」、「1-07+(L01)」、「1-07+(L02)」、「1-07+(M01)」、「1-07+(M02)」、「1-07+(M03)」、「1-07+(M04)」、「1-07+(M05)」、「1-07+(M06)」、「1-07+(M07)」、「1-07+(M08)」、「1-07+(N01)」、「1-07+(N02)」、「1-07+(N03)」、「1-07+(N04)」、「1-07+(N05)」、「1-07+(N06)」、「1-07+(O01)」、「1-07+(O02)」、「1-07+(O03)」、「1-07+(O04)」、「1-07+(O05)」、「1-07+(O06)」、「1-07+(O07)」、「1-07+(O08)」、「1-07+(O09)」、「1-07+(O10)」、「1-07+(O11)」、「1-07+(O12)」、「1-07+(O13)」、「1-07+(O14)」、「1-07+(O15)」、「1-07+(O16)」、「1-07+(O17)」、「1-08+(A01)」、「1-08+(A02)」、「1-08+(A03)」、「1-08+(A04)」、「1-08+(A05)」、「1-08+(A06)」、「1-08+(A07)」、「1-08+(A08)」、「1-08+(A09)」、「1-08+(A10)」、「1-08+(A11)」、「1-08+(A12)」、「1-08+(A13)」、「1-08+(A14)」、「1-08+(A15)」、「1-08+(A16)」、「1-08+(A17)」、「1-08+(B01)」、「1-08+(B02)」、「1-08+(B03)」、「1-08+(B04)」、「1-08+(B05)」、「1-08+(B06)」、「1-08+(B07)」、「1-08+(B08)」、「1-08+(B09)」、「1-08+(C01)」、「1-08+(C02)」、「1-08+(C03)」、「1-08+(C04)」、「1-08+(C05)」、「1-08+(C06)」、「1-08+(C07)」、「1-08+(C08)」、「1-08+(C09)」、「1-08+(C10)」、「1-08+(C11)」、「1-08+(C12)」、「1-08+(D01)」、「1-08+(D02)」、「1-08+(D03)」、「1-08+(E01)」、「1-08+(E02)」、「1-08+(E03)」、「1-08+(E04)」、「1-08+(E05)」、「1-08+(E06)」、「1-08+(E07)」、「1-08+(E08)」、「1-08+(E09)」、「1-08+(E10)」、「1-08+(E11)」、「1-08+(E12)」、「1-08+(E13)」、「1-08+(F01)」、「1-08+(F02)」、「1-08+(G01)」、「1-08+(G02)」、「1-08+(G03)」、「1-08+(G04)」、「1-08+(G05)」、「1-08+(G06)」、「1-08+(G07)」、「1-08+(G08)」、「1-08+(H01)」、「1-08+(H02)」、「1-08+(H03)」、「1-08+(H04)」、「1-08+(I01)」、「1-08+(I02)」、「1-08+(I03)」、「1-08+(I04)」、「1-08+(I05)」、「1-08+(I06)」、「1-08+(I07)」、「1-08+(I08)」、「1-08+(J01)」、「1-08+(J02)」、「1-08+(J03)」、「1-08+(J04)」、「1-08+(J05)」、「1-08+(J06)」、「1-08+(J07)」、「1-08+(J08)」、「1-08+(J09)」、「1-08+(J10)」、「1-08+(J11)」、「1-08+(J12)」、「1-08+(J13)」、「1-08+(K01)」、「1-08+(K02)」、「1-08+(K03)」、「1-08+(K04)」、「1-08+(K05)」、「1-08+(K06)」、「1-08+(K07)」、「1-08+(K08)」、「1-08+(K09)」、「1-08+(K10)」、「1-08+(K11)」、「1-08+(K12)」、「1-08+(K13)」、「1-08+(K14)」、「1-08+(K15)」、「1-08+(L01)」、「1-08+(L02)」、「1-08+(M01)」、「1-08+(M02)」、「1-08+(M03)」、「1-08+(M04)」、「1-08+(M05)」、「1-08+(M06)」、「1-08+(M07)」、「1-08+(M08)」、「1-08+(N01)」、「1-08+(N02)」、「1-08+(N03)」、「1-08+(N04)」、「1-08+(N05)」、「1-08+(N06)」、「1-08+(O01)」、「1-08+(O02)」、「1-08+(O03)」、「1-08+(O04)」、「1-08+(O05)」、「1-08+(O06)」、「1-08+(O07)」、「1-08+(O08)」、「1-08+(O09)」、「1-08+(O10)」、「1-08+(O11)」、「1-08+(O12)」、「1-08+(O13)」、「1-08+(O14)」、「1-08+(O15)」、「1-08+(O16)」、「1-08+(O17)」、「1-09+(A01)」、「1-09+(A02)」、「1-09+(A03)」、「1-09+(A04)」、「1-09+(A05)」、「1-09+(A06)」、「1-09+(A07)」、「1-09+(A08)」、「1-09+(A09)」、「1-09+(A10)」、「1-09+(A11)」、「1-09+(A12)」、「1-09+(A13)」、「1-09+(A14)」、「1-09+(A15)」、「1-09+(A16)」、「1-09+(A17)」、「1-09+(B01)」、「1-09+(B02)」、「1-09+(B03)」、「1-09+(B04)」、「1-09+(B05)」、「1-09+(B06)」、「1-09+(B07)」、「1-09+(B08)」、「1-09+(B09)」、「1-09+(C01)」、「1-09+(C02)」、「1-09+(C03)」、「1-09+(C04)」、「1-09+(C05)」、「1-09+(C06)」、「1-09+(C07)」、「1-09+(C08)」、「1-09+(C09)」、「1-09+(C10)」、「1-09+(C11)」、「1-09+(C12)」、「1-09+(D01)」、「1-09+(D02)」、「1-09+(D03)」、「1-09+(E01)」、「1-09+(E02)」、「1-09+(E03)」、「1-09+(E04)」、「1-09+(E05)」、「1-09+(E06)」、「1-09+(E07)」、「1-09+(E08)」、「1-09+(E09)」、「1-09+(E10)」、「1-09+(E11)」、「1-09+(E12)」、「1-09+(E13)」、「1-09+(F01)」、「1-09+(F02)」、「1-09+(G01)」、「1-09+(G02)」、「1-09+(G03)」、「1-09+(G04)」、「1-09+(G05)」、「1-09+(G06)」、「1-09+(G07)」、「1-09+(G08)」、「1-09+(H01)」、「1-09+(H02)」、「1-09+(H03)」、「1-09+(H04)」、「1-09+(I01)」、「1-09+(I02)」、「1-09+(I03)」、「1-09+(I04)」、「1-09+(I05)」、「1-09+(I06)」、「1-09+(I07)」、「1-09+(I08)」、「1-09+(J01)」、「1-09+(J02)」、「1-09+(J03)」、「1-09+(J04)」、「1-09+(J05)」、「1-09+(J06)」、「1-09+(J07)」、「1-09+(J08)」、「1-09+(J09)」、「1-09+(J10)」、「1-09+(J11)」、「1-09+(J12)」、「1-09+(J13)」、「1-09+(K01)」、「1-09+(K02)」、「1-09+(K03)」、「1-09+(K04)」、「1-09+(K05)」、「1-09+(K06)」、「1-09+(K07)」、「1-09+(K08)」、「1-09+(K09)」、「1-09+(K10)」、「1-09+(K11)」、「1-09+(K12)」、「1-09+(K13)」、「1-09+(K14)」、「1-09+(K15)」、「1-09+(L01)」、「1-09+(L02)」、「1-09+(M01)」、「1-09+(M02)」、「1-09+(M03)」、「1-09+(M04)」、「1-09+(M05)」、「1-09+(M06)」、「1-09+(M07)」、「1-09+(M08)」、「1-09+(N01)」、「1-09+(N02)」、「1-09+(N03)」、「1-09+(N04)」、「1-09+(N05)」、「1-09+(N06)」、「1-09+(O01)」、「1-09+(O02)」、「1-09+(O03)」、「1-09+(O04)」、「1-09+(O05)」、「1-09+(O06)」、「1-09+(O07)」、「1-09+(O08)」、「1-09+(O09)」、「1-09+(O10)」、「1-09+(O11)」、「1-09+(O12)」、「1-09+(O13)」、「1-09+(O14)」、「1-09+(O15)」、「1-09+(O16)」、「1-09+(O17)」、「1-10+(A01)」、「1-10+(A02)」、「1-10+(A03)」、「1-10+(A04)」、「1-10+(A05)」、「1-10+(A06)」、「1-10+(A07)」、「1-10+(A08)」、「1-10+(A09)」、「1-10+(A10)」、「1-10+(A11)」、「1-10+(A12)」、「1-10+(A13)」、「1-10+(A14)」、「1-10+(A15)」、「1-10+(A16)」、「1-10+(A17)」、「1-10+(B01)」、「1-10+(B02)」、「1-10+(B03)」、「1-10+(B04)」、「1-10+(B05)」、「1-10+(B06)」、「1-10+(B07)」、「1-10+(B08)」、「1-10+(B09)」、「1-10+(C01)」、「1-10+(C02)」、「1-10+(C03)」、「1-10+(C04)」、「1-10+(C05)」、「1-10+(C06)」、「1-10+(C07)」、「1-10+(C08)」、「1-10+(C09)」、「1-10+(C10)」、「1-10+(C11)」、「1-10+(C12)」、「1-10+(D01)」、「1-10+(D02)」、「1-10+(D03)」、「1-10+(E01)」、「1-10+(E02)」、「1-10+(E03)」、「1-10+(E04)」、「1-10+(E05)」、「1-10+(E06)」、 「1-10+(E07)」、「1-10+(E08)」、「1-10+(E09)」、「1-10+(E10)」、「1-10+(E11)」、「1-10+(E12)」、「1-10+(E13)」、「1-10+(F01)」、「1-10+(F02)」、「1-10+(G01)」、「1-10+(G02)」、「1-10+(G03)」、「1-10+(G04)」、「1-10+(G05)」、「1-10+(G06)」、「1-10+(G07)」、「1-10+(G08)」、「1-10+(H01)」、「1-10+(H02)」、「1-10+(H03)」、「1-10+(H04)」、「1-10+(I01)」、「1-10+(I02)」、「1-10+(I03)」、「1-10+(I04)」、「1-10+(I05)」、「1-10+(I06)」、「1-10+(I07)」、「1-10+(I08)」、「1-10+(J01)」、「1-10+(J02)」、「1-10+(J03)」、「1-10+(J04)」、「1-10+(J05)」、「1-10+(J06)」、「1-10+(J07)」、「1-10+(J08)」、「1-10+(J09)」、「1-10+(J10)」、「1-10+(J11)」、「1-10+(J12)」、「1-10+(J13)」、「1-10+(K01)」、「1-10+(K02)」、「1-10+(K03)」、「1-10+(K04)」、「1-10+(K05)」、「1-10+(K06)」、「1-10+(K07)」、「1-10+(K08)」、「1-10+(K09)」、「1-10+(K10)」、「1-10+(K11)」、「1-10+(K12)」、「1-10+(K13)」、「1-10+(K14)」、「1-10+(K15)」、「1-10+(L01)」、「1-10+(L02)」、「1-10+(M01)」、「1-10+(M02)」、「1-10+(M03)」、「1-10+(M04)」、「1-10+(M05)」、「1-10+(M06)」、「1-10+(M07)」、「1-10+(M08)」、「1-10+(N01)」、「1-10+(N02)」、「1-10+(N03)」、「1-10+(N04)」、「1-10+(N05)」、「1-10+(N06)」、「1-10+(O01)」、「1-10+(O02)」、「1-10+(O03)」、「1-10+(O04)」、「1-10+(O05)」、「1-10+(O06)」、「1-10+(O07)」、「1-10+(O08)」、「1-10+(O09)」、「1-10+(O10)」、「1-10+(O11)」、「1-10+(O12)」、「1-10+(O13)」、「1-10+(O14)」、「1-10+(O15)」、「1-10+(O16)」、「1-10+(O17)」、「1-11+(A01)」、「1-11+(A02)」、「1-11+(A03)」、「1-11+(A04)」、「1-11+(A05)」、「1-11+(A06)」、「1-11+(A07)」、「1-11+(A08)」、「1-11+(A09)」、「1-11+(A10)」、「1-11+(A11)」、「1-11+(A12)」、「1-11+(A13)」、「1-11+(A14)」、「1-11+(A15)」、「1-11+(A16)」、「1-11+(A17)」、「1-11+(B01)」、「1-11+(B02)」、「1-11+(B03)」、「1-11+(B04)」、「1-11+(B05)」、「1-11+(B06)」、「1-11+(B07)」、「1-11+(B08)」、「1-11+(B09)」、「1-11+(C01)」、「1-11+(C02)」、「1-11+(C03)」、「1-11+(C04)」、「1-11+(C05)」、「1-11+(C06)」、「1-11+(C07)」、「1-11+(C08)」、「1-11+(C09)」、「1-11+(C10)」、「1-11+(C11)」、「1-11+(C12)」、「1-11+(D01)」、「1-11+(D02)」、「1-11+(D03)」、「1-11+(E01)」、「1-11+(E02)」、「1-11+(E03)」、「1-11+(E04)」、「1-11+(E05)」、「1-11+(E06)」、「1-11+(E07)」、「1-11+(E08)」、「1-11+(E09)」、「1-11+(E10)」、「1-11+(E11)」、「1-11+(E12)」、「1-11+(E13)」、「1-11+(F01)」、「1-11+(F02)」、「1-11+(G01)」、「1-11+(G02)」、「1-11+(G03)」、「1-11+(G04)」、「1-11+(G05)」、「1-11+(G06)」、「1-11+(G07)」、「1-11+(G08)」、「1-11+(H01)」、「1-11+(H02)」、「1-11+(H03)」、「1-11+(H04)」、「1-11+(I01)」、「1-11+(I02)」、「1-11+(I03)」、「1-11+(I04)」、「1-11+(I05)」、「1-11+(I06)」、「1-11+(I07)」、「1-11+(I08)」、「1-11+(J01)」、「1-11+(J02)」、「1-11+(J03)」、「1-11+(J04)」、「1-11+(J05)」、「1-11+(J06)」、「1-11+(J07)」、「1-11+(J08)」、「1-11+(J09)」、「1-11+(J10)」、「1-11+(J11)」、「1-11+(J12)」、「1-11+(J13)」、「1-11+(K01)」、「1-11+(K02)」、「1-11+(K03)」、「1-11+(K04)」、「1-11+(K05)」、「1-11+(K06)」、「1-11+(K07)」、「1-11+(K08)」、「1-11+(K09)」、「1-11+(K10)」、「1-11+(K11)」、「1-11+(K12)」、「1-11+(K13)」、「1-11+(K14)」、「1-11+(K15)」、「1-11+(L01)」、「1-11+(L02)」、「1-11+(M01)」、「1-11+(M02)」、「1-11+(M03)」、「1-11+(M04)」、「1-11+(M05)」、「1-11+(M06)」、「1-11+(M07)」、「1-11+(M08)」、「1-11+(N01)」、「1-11+(N02)」、「1-11+(N03)」、「1-11+(N04)」、「1-11+(N05)」、「1-11+(N06)」、「1-11+(O01)」、「1-11+(O02)」、「1-11+(O03)」、「1-11+(O04)」、「1-11+(O05)」、「1-11+(O06)」、「1-11+(O07)」、「1-11+(O08)」、「1-11+(O09)」、「1-11+(O10)」、「1-11+(O11)」、「1-11+(O12)」、「1-11+(O13)」、「1-11+(O14)」、「1-11+(O15)」、「1-11+(O16)」、「1-11+(O17)」、「1-12+(A01)」、「1-12+(A02)」、「1-12+(A03)」、「1-12+(A04)」、「1-12+(A05)」、「1-12+(A06)」、「1-12+(A07)」、「1-12+(A08)」、「1-12+(A09)」、「1-12+(A10)」、「1-12+(A11)」、「1-12+(A12)」、「1-12+(A13)」、「1-12+(A14)」、「1-12+(A15)」、「1-12+(A16)」、「1-12+(A17)」、「1-12+(B01)」、「1-12+(B02)」、「1-12+(B03)」、「1-12+(B04)」、「1-12+(B05)」、「1-12+(B06)」、「1-12+(B07)」、「1-12+(B08)」、「1-12+(B09)」、「1-12+(C01)」、「1-12+(C02)」、「1-12+(C03)」、「1-12+(C04)」、「1-12+(C05)」、「1-12+(C06)」、「1-12+(C07)」、「1-12+(C08)」、「1-12+(C09)」、「1-12+(C10)」、「1-12+(C11)」、「1-12+(C12)」、「1-12+(D01)」、「1-12+(D02)」、「1-12+(D03)」、「1-12+(E01)」、「1-12+(E02)」、「1-12+(E03)」、「1-12+(E04)」、「1-12+(E05)」、「1-12+(E06)」、「1-12+(E07)」、「1-12+(E08)」、「1-12+(E09)」、「1-12+(E10)」、「1-12+(E11)」、「1-12+(E12)」、「1-12+(E13)」、「1-12+(F01)」、「1-12+(F02)」、「1-12+(G01)」、「1-12+(G02)」、「1-12+(G03)」、「1-12+(G04)」、「1-12+(G05)」、「1-12+(G06)」、「1-12+(G07)」、「1-12+(G08)」、「1-12+(H01)」、「1-12+(H02)」、「1-12+(H03)」、「1-12+(H04)」、「1-12+(I01)」、「1-12+(I02)」、「1-12+(I03)」、「1-12+(I04)」、「1-12+(I05)」、「1-12+(I06)」、「1-12+(I07)」、「1-12+(I08)」、「1-12+(J01)」、「1-12+(J02)」、「1-12+(J03)」、「1-12+(J04)」、「1-12+(J05)」、「1-12+(J06)」、「1-12+(J07)」、「1-12+(J08)」、「1-12+(J09)」、「1-12+(J10)」、「1-12+(J11)」、「1-12+(J12)」、「1-12+(J13)」、「1-12+(K01)」、「1-12+(K02)」、「1-12+(K03)」、「1-12+(K04)」、「1-12+(K05)」、「1-12+(K06)」、「1-12+(K07)」、「1-12+(K08)」、「1-12+(K09)」、「1-12+(K10)」、「1-12+(K11)」、「1-12+(K12)」、「1-12+(K13)」、「1-12+(K14)」、「1-12+(K15)」、「1-12+(L01)」、「1-12+(L02)」、「1-12+(M01)」、「1-12+(M02)」、「1-12+(M03)」、「1-12+(M04)」、「1-12+(M05)」、「1-12+(M06)」、「1-12+(M07)」、「1-12+(M08)」、「1-12+(N01)」、「1-12+(N02)」、「1-12+(N03)」、「1-12+(N04)」、「1-12+(N05)」、「1-12+(N06)」、「1-12+(O01)」、「1-12+(O02)」、「1-12+(O03)」、「1-12+(O04)」、「1-12+(O05)」、「1-12+(O06)」、「1-12+(O07)」、「1-12+(O08)」、「1-12+(O09)」、「1-12+(O10)」、「1-12+(O11)」、「1-12+(O12)」、「1-12+(O13)」、「1-12+(O14)」、「1-12+(O15)」、「1-12+(O16)」、「1-12+(O17)」、「1-13+(A01)」、「1-13+(A02)」、「1-13+(A03)」、「1-13+(A04)」、「1-13+(A05)」、「1-13+(A06)」、「1-13+(A07)」、「1-13+(A08)」、「1-13+(A09)」、「1-13+(A10)」、「1-13+(A11)」、「1-13+(A12)」、「1-13+(A13)」、「1-13+(A14)」、「1-13+(A15)」、「1-13+(A16)」、「1-13+(A17)」、「1-13+(B01)」、「1-13+(B02)」、「1-13+(B03)」、「1-13+(B04)」、「1-13+(B05)」、「1-13+(B06)」、「1-13+(B07)」、「1-13+(B08)」、「1-13+(B09)」、「1-13+(C01)」、「1-13+(C02)」、「1-13+(C03)」、「1-13+(C04)」、「1-13+(C05)」、「1-13+(C06)」、「1-13+(C07)」、「1-13+(C08)」、「1-13+(C09)」、「1-13+(C10)」、「1-13+(C11)」、「1-13+(C12)」、「1-13+(D01)」、「1-13+(D02)」、「1-13+(D03)」、「1-13+(E01)」、「1-13+(E02)」、「1-13+(E03)」、「1-13+(E04)」、「1-13+(E05)」、「1-13+(E06)」、「1-13+(E07)」、「1-13+(E08)」、「1-13+(E09)」、「1-13+(E10)」、「1-13+(E11)」、「1-13+(E12)」、「1-13+(E13)」、「1-13+(F01)」、「1-13+(F02)」、「1-13+(G01)」、「1-13+(G02)」、「1-13+(G03)」、「1-13+(G04)」、「1-13+(G05)」、「1-13+(G06)」、「1-13+(G07)」、「1-13+(H01)」、「1-13+(H02)」、「1-13+(H03)」、「1-13+(H04)」、「1-13+(I01)」、「1-13+(I02)」、「1-13+(I03)」、「1-13+(I04)」、「1-13+(I05)」、「1-13+(I06)」、「1-13+(I07)」、「1-13+(I08)」、「1-13+(J01)」、「1-13+(J02)」、「1-13+(J03)」、「1-13+(J04)」、「1-13+(J05)」、「1-13+(J06)」、「1-13+(J07)」、「1-13+(J08)」、「1-13+(J09)」、「1-13+(J10)」、「1-13+(J11)」、「1-13+(J12)」、「1-13+(J13)」、「1-13+(K01)」、「1-13+(K02)」、「1-13+(K03)」、「1-13+(K04)」、「1-13+(K05)」、「1-13+(K06)」、「1-13+(K07)」、「1-13+(K08)」、「1-13+(K09)」、「1-13+(K10)」、「1-13+(K11)」、「1-13+(K12)」、「1-13+(K13)」、「1-13+(K14)」、「1-13+(K15)」、「1-13+(L01)」、「1-13+(L02)」、「1-13+(M01)」、「1-13+(M02)」、「1-13+(M03)」、「1-13+(M04)」、「1-13+(M05)」、「1-13+(M06)」、「1-13+(M07)」、「1-13+(M08)」、「1-13+(N01)」、「1-13+(N02)」、「1-13+(N03)」、「1-13+(N04)」、「1-13+(N05)」、「1-13+(N06)」、「1-13+(O01)」、「1-13+(O02)」、「1-13+(O03)」、「1-13+(O04)」、「1-13+(O05)」、「1-13+(O06)」、「1-13+(O07)」、「1-13+(O08)」、「1-13+(O09)」、「1-13+(O10)」、「1-13+(O11)」、「1-13+(O12)」、「1-13+(O13)」、「1-13+(O14)」、「1-13+(O15)」、「1-13+(O16)」、「1-13+(O17)」、「1-14+(A01)」、「1-14+(A02)」、「1-14+(A03)」、「1-14+(A04)」、「1-14+(A05)」、「1-14+(A06)」、「1-14+(A07)」、「1-14+(A08)」、「1-14+(A09)」、「1-14+(A10)」、「1-14+(A11)」、「1-14+(A12)」、「1-14+(A13)」、「1-14+(A14)」、「1-14+(A15)」、「1-14+(A16)」、「1-14+(A17)」、「1-14+(B01)」、「1-14+(B02)」、「1-14+(B03)」、「1-14+(B04)」、「1-14+(B05)」、「1-14+(B06)」、「1-14+(B07)」、「1-14+(B08)」、「1-14+(B09)」、「1-14+(C01)」、「1-14+(C02)」、「1-14+(C03)」、「1-14+(C04)」、「1-14+(C05)」、「1-14+(C06)」、「1-14+(C07)」、「1-14+(C08)」、「1-14+(C09)」、「1-14+(C10)」、「1-14+(C11)」、「1-14+(C12)」、「1-14+(D01)」、「1-14+(D02)」、「1-14+(D03)」、「1-14+(E01)」、「1-14+(E02)」、「1-14+(E03)」、「1-14+(E04)」、「1-14+(E05)」、「1-14+(E06)」、「1-14+(E07)」、「1-14+(E08)」、「1-14+(E09)」、「1-14+(E10)」、「1-14+(E11)」、「1-14+(E12)」、「1-14+(E13)」、「1-14+(F01)」、「1-14+(F02)」、「1-14+(G01)」、「1-14+(G02)」、「1-14+(G03)」、「1-14+(G04)」、「1-14+(G05)」、「1-14+(G06)」、「1-14+(G07)」、「1-14+(H01)」、「1-14+(H02)」、「1-14+(H03)」、「1-14+(H04)」、「1-14+(I01)」、「1-14+(I02)」、「1-14+(I03)」、「1-14+(I04)」、「1-14+(I05)」、「1-14+(I06)」、「1-14+(I07)」、「1-14+(I08)」、「1-14+(J01)」、「1-14+(J02)」、「1-14+(J03)」、「1-14+(J04)」、「1-14+(J05)」、「1-14+(J06)」、「1-14+(J07)」、「1-14+(J08)」、「1-14+(J09)」、「1-14+(J10)」、「1-14+(J11)」、「1-14+(J12)」、「1-14+(J13)」、「1-14+(K01)」、「1-14+(K02)」、「1-14+(K03)」、「1-14+(K04)」、「1-14+(K05)」、「1-14+(K06)」、「1-14+(K07)」、「1-14+(K08)」、「1-14+(K09)」、「1-14+(K10)」、「1-14+(K11)」、「1-14+(K12)」、「1-14+(K13)」、「1-14+(K14)」、「1-14+(K15)」、「1-14+(L01)」、「1-14+(L02)」、「1-14+(M01)」、「1-14+(M02)」、「1-14+(M03)」、「1-14+(M04)」、「1-14+(M05)」、「1-14+(M06)」、「1-14+(M07)」、「1-14+(M08)」、「1-14+(N01)」、「1-14+(N02)」、「1-14+(N03)」、「1-14+(N04)」、「1-14+(N05)」、「1-14+(N06)」、「1-14+(O01)」、「1-14+(O02)」、「1-14+(O03)」、「1-14+(O04)」、「1-14+(O05)」、「1-14+(O06)」、「1-14+(O07)」、「1-14+(O08)」、「1-14+(O09)」、「1-14+(O10)」、「1-14+(O11)」、「1-14+(O12)」、「1-14+(O13)」、「1-14+(O14)」、「1-14+(O15)」、「1-14+(O16)」、「1-14+(O17)」、「1-15+(A01)」、「1-15+(A02)」、「1-15+(A03)」、「1-15+(A04)」、 「1-15+(A05)」、「1-15+(A06)」、「1-15+(A07)」、「1-15+(A08)」、「1-15+(A09)」、「1-15+(A10)」、「1-15+(A11)」、「1-15+(A12)」、「1-15+(A13)」、「1-15+(A14)」、「1-15+(A15)」、「1-15+(A16)」、「1-15+(A17)」、「1-15+(B01)」、「1-15+(B02)」、「1-15+(B03)」、「1-15+(B04)」、「1-15+(B05)」、「1-15+(B06)」、「1-15+(B07)」、「1-15+(B08)」、「1-15+(B09)」、「1-15+(C01)」、「1-15+(C02)」、「1-15+(C03)」、「1-15+(C04)」、「1-15+(C05)」、「1-15+(C06)」、「1-15+(C07)」、「1-15+(C08)」、「1-15+(C09)」、「1-15+(C10)」、「1-15+(C11)」、「1-15+(C12)」、「1-15+(D01)」、「1-15+(D02)」、「1-15+(D03)」、「1-15+(E01)」、「1-15+(E02)」、「1-15+(E03)」、「1-15+(E04)」、「1-15+(E05)」、「1-15+(E06)」、「1-15+(E07)」、「1-15+(E08)」、「1-15+(E09)」、「1-15+(E10)」、「1-15+(E11)」、「1-15+(E12)」、「1-15+(E13)」、「1-15+(F01)」、「1-15+(F02)」、「1-15+(G01)」、「1-15+(G02)」、「1-15+(G03)」、「1-15+(G04)」、「1-15+(G05)」、「1-15+(G06)」、「1-15+(G07)」、「1-15+(H01)」、「1-15+(H02)」、「1-15+(H03)」、「1-15+(H04)」、「1-15+(I01)」、「1-15+(I02)」、「1-15+(I03)」、「1-15+(I04)」、「1-15+(I05)」、「1-15+(I06)」、「1-15+(I07)」、「1-15+(I08)」、「1-15+(J01)」、「1-15+(J02)」、「1-15+(J03)」、「1-15+(J04)」、「1-15+(J05)」、「1-15+(J06)」、「1-15+(J07)」、「1-15+(J08)」、「1-15+(J09)」、「1-15+(J10)」、「1-15+(J11)」、「1-15+(J12)」、「1-15+(J13)」、「1-15+(K01)」、「1-15+(K02)」、「1-15+(K03)」、「1-15+(K04)」、「1-15+(K05)」、「1-15+(K06)」、「1-15+(K07)」、「1-15+(K08)」、「1-15+(K09)」、「1-15+(K10)」、「1-15+(K11)」、「1-15+(K12)」、「1-15+(K13)」、「1-15+(K14)」、「1-15+(K15)」、「1-15+(L01)」、「1-15+(L02)」、「1-15+(M01)」、「1-15+(M02)」、「1-15+(M03)」、「1-15+(M04)」、「1-15+(M05)」、「1-15+(M06)」、「1-15+(M07)」、「1-15+(M08)」、「1-15+(N01)」、「1-15+(N02)」、「1-15+(N03)」、「1-15+(N04)」、「1-15+(N05)」、「1-15+(N06)」、「1-15+(O01)」、「1-15+(O02)」、「1-15+(O03)」、「1-15+(O04)」、「1-15+(O05)」、「1-15+(O06)」、「1-15+(O07)」、「1-15+(O08)」、「1-15+(O09)」、「1-15+(O10)」、「1-15+(O11)」、「1-15+(O12)」、「1-15+(O13)」、「1-15+(O14)」、「1-15+(O15)」、「1-15+(O16)」、「1-15+(O17)」、「1-16+(A01)」、「1-16+(A02)」、「1-16+(A03)」、「1-16+(A04)」、「1-16+(A05)」、「1-16+(A06)」、「1-16+(A07)」、「1-16+(A08)」、「1-16+(A09)」、「1-16+(A10)」、「1-16+(A11)」、「1-16+(A12)」、「1-16+(A13)」、「1-16+(A14)」、「1-16+(A15)」、「1-16+(A16)」、「1-16+(A17)」、「1-16+(B01)」、「1-16+(B02)」、「1-16+(B03)」、「1-16+(B04)」、「1-16+(B05)」、「1-16+(B06)」、「1-16+(B07)」、「1-16+(B08)」、「1-16+(B09)」、「1-16+(C01)」、「1-16+(C02)」、「1-16+(C03)」、「1-16+(C04)」、「1-16+(C05)」、「1-16+(C06)」、「1-16+(C07)」、「1-16+(C08)」、「1-16+(C09)」、「1-16+(C10)」、「1-16+(C11)」、「1-16+(C12)」、「1-16+(D01)」、「1-16+(D02)」、「1-16+(D03)」、「1-16+(E01)」、「1-16+(E02)」、「1-16+(E03)」、「1-16+(E04)」、「1-16+(E05)」、「1-16+(E06)」、「1-16+(E07)」、「1-16+(E08)」、「1-16+(E09)」、「1-16+(E10)」、「1-16+(E11)」、「1-16+(E12)」、「1-16+(E13)」、「1-16+(F01)」、「1-16+(F02)」、「1-16+(G01)」、「1-16+(G02)」、「1-16+(G03)」、「1-16+(G04)」、「1-16+(G05)」、「1-16+(G06)」、「1-16+(G07)」、「1-16+(H01)」、「1-16+(H02)」、「1-16+(H03)」、「1-16+(H04)」、「1-16+(I01)」、「1-16+(I02)」、「1-16+(I03)」、「1-16+(I04)」、「1-16+(I05)」、「1-16+(I06)」、「1-16+(I07)」、「1-16+(I08)」、「1-16+(J01)」、「1-16+(J02)」、「1-16+(J03)」、「1-16+(J04)」、「1-16+(J05)」、「1-16+(J06)」、「1-16+(J07)」、「1-16+(J08)」、「1-16+(J09)」、「1-16+(J10)」、「1-16+(J11)」、「1-16+(J12)」、「1-16+(J13)」、「1-16+(K01)」、「1-16+(K02)」、「1-16+(K03)」、「1-16+(K04)」、「1-16+(K05)」、「1-16+(K06)」、「1-16+(K07)」、「1-16+(K08)」、「1-16+(K09)」、「1-16+(K10)」、「1-16+(K11)」、「1-16+(K12)」、「1-16+(K13)」、「1-16+(K14)」、「1-16+(K15)」、「1-16+(L01)」、「1-16+(L02)」、「1-16+(M01)」、「1-16+(M02)」、「1-16+(M03)」、「1-16+(M04)」、「1-16+(M05)」、「1-16+(M06)」、「1-16+(M07)」、「1-16+(M08)」、「1-16+(N01)」、「1-16+(N02)」、「1-16+(N03)」、「1-16+(N04)」、「1-16+(N05)」、「1-16+(N06)」、「1-16+(O01)」、「1-16+(O02)」、「1-16+(O03)」、「1-16+(O04)」、「1-16+(O05)」、「1-16+(O06)」、「1-16+(O07)」、「1-16+(O08)」、「1-16+(O09)」、「1-16+(O10)」、「1-16+(O11)」、「1-16+(O12)」、「1-16+(O13)」、「1-16+(O14)」、「1-16+(O15)」、「1-16+(O16)」、「1-16+(O17)」、「1-17+(A01)」、「1-17+(A02)」、「1-17+(A03)」、「1-17+(A04)」、「1-17+(A05)」、「1-17+(A06)」、「1-17+(A07)」、「1-17+(A08)」、「1-17+(A09)」、「1-17+(A10)」、「1-17+(A11)」、「1-17+(A12)」、「1-17+(A13)」、「1-17+(A14)」、「1-17+(A15)」、「1-17+(A16)」、「1-17+(A17)」、「1-17+(B01)」、「1-17+(B02)」、「1-17+(B03)」、「1-17+(B04)」、「1-17+(B05)」、「1-17+(B06)」、「1-17+(B07)」、「1-17+(B08)」、「1-17+(B09)」、「1-17+(C01)」、「1-17+(C02)」、「1-17+(C03)」、「1-17+(C04)」、「1-17+(C05)」、「1-17+(C06)」、「1-17+(C07)」、「1-17+(C08)」、「1-17+(C09)」、「1-17+(C10)」、「1-17+(C11)」、「1-17+(C12)」、「1-17+(D01)」、「1-17+(D02)」、「1-17+(D03)」、「1-17+(E01)」、「1-17+(E02)」、「1-17+(E03)」、「1-17+(E04)」、「1-17+(E05)」、「1-17+(E06)」、「1-17+(E07)」、「1-17+(E08)」、「1-17+(E09)」、「1-17+(E10)」、「1-17+(E11)」、「1-17+(E12)」、「1-17+(E13)」、「1-17+(F01)」、「1-17+(F02)」、「1-17+(G01)」、「1-17+(G02)」、「1-17+(G03)」、「1-17+(G04)」、「1-17+(G05)」、「1-17+(G06)」、「1-17+(G07)」、「1-17+(H01)」、「1-17+(H02)」、「1-17+(H03)」、「1-17+(H04)」、「1-17+(I01)」、「1-17+(I02)」、「1-17+(I03)」、「1-17+(I04)」、「1-17+(I05)」、「1-17+(I06)」、「1-17+(I07)」、「1-17+(I08)」、「1-17+(J01)」、「1-17+(J02)」、「1-17+(J03)」、「1-17+(J04)」、「1-17+(J05)」、「1-17+(J06)」、「1-17+(J07)」、「1-17+(J08)」、「1-17+(J09)」、「1-17+(J10)」、「1-17+(J11)」、「1-17+(J12)」、「1-17+(J13)」、「1-17+(K01)」、「1-17+(K02)」、「1-17+(K03)」、「1-17+(K04)」、「1-17+(K05)」、「1-17+(K06)」、「1-17+(K07)」、「1-17+(K08)」、「1-17+(K09)」、「1-17+(K10)」、「1-17+(K11)」、「1-17+(K12)」、「1-17+(K13)」、「1-17+(K14)」、「1-17+(K15)」、「1-17+(L01)」、「1-17+(L02)」、「1-17+(M01)」、「1-17+(M02)」、「1-17+(M03)」、「1-17+(M04)」、「1-17+(M05)」、「1-17+(M06)」、「1-17+(M07)」、「1-17+(M08)」、「1-17+(N01)」、「1-17+(N02)」、「1-17+(N03)」、「1-17+(N04)」、「1-17+(N05)」、「1-17+(N06)」、「1-17+(O01)」、「1-17+(O02)」、「1-17+(O03)」、「1-17+(O04)」、「1-17+(O05)」、「1-17+(O06)」、「1-17+(O07)」、「1-17+(O08)」、「1-17+(O09)」、「1-17+(O10)」、「1-17+(O11)」、「1-17+(O12)」、「1-17+(O13)」、「1-17+(O14)」、「1-17+(O15)」、「1-17+(O16)」、「1-17+(O17)」、「1-18+(A01)」、「1-18+(A02)」、「1-18+(A03)」、「1-18+(A04)」、「1-18+(A05)」、「1-18+(A06)」、「1-18+(A07)」、「1-18+(A08)」、「1-18+(A09)」、「1-18+(A10)」、「1-18+(A11)」、「1-18+(A12)」、「1-18+(A13)」、「1-18+(A14)」、「1-18+(A15)」、「1-18+(A16)」、「1-18+(A17)」、「1-18+(B01)」、「1-18+(B02)」、「1-18+(B03)」、「1-18+(B04)」、「1-18+(B05)」、「1-18+(B06)」、「1-18+(B07)」、「1-18+(B08)」、「1-18+(B09)」、「1-18+(C01)」、「1-18+(C02)」、「1-18+(C03)」、「1-18+(C04)」、「1-18+(C05)」、「1-18+(C06)」、「1-18+(C07)」、「1-18+(C08)」、「1-18+(C09)」、「1-18+(C10)」、「1-18+(C11)」、「1-18+(C12)」、「1-18+(D01)」、「1-18+(D02)」、「1-18+(D03)」、「1-18+(E01)」、「1-18+(E02)」、「1-18+(E03)」、「1-18+(E04)」、「1-18+(E05)」、「1-18+(E06)」、「1-18+(E07)」、「1-18+(E08)」、「1-18+(E09)」、「1-18+(E10)」、「1-18+(E11)」、「1-18+(E12)」、「1-18+(E13)」、「1-18+(F01)」、「1-18+(F02)」、「1-18+(G01)」、「1-18+(G02)」、「1-18+(G03)」、「1-18+(G04)」、「1-18+(G05)」、「1-18+(G06)」、「1-18+(G07)」、「1-18+(H01)」、「1-18+(H02)」、「1-18+(H03)」、「1-18+(H04)」、「1-18+(I01)」、「1-18+(I02)」、「1-18+(I03)」、「1-18+(I04)」、「1-18+(I05)」、「1-18+(I06)」、「1-18+(I07)」、「1-18+(I08)」、「1-18+(J01)」、「1-18+(J02)」、「1-18+(J03)」、「1-18+(J04)」、「1-18+(J05)」、「1-18+(J06)」、「1-18+(J07)」、「1-18+(J08)」、「1-18+(J09)」、「1-18+(J10)」、「1-18+(J11)」、「1-18+(J12)」、「1-18+(J13)」、「1-18+(K01)」、「1-18+(K02)」、「1-18+(K03)」、「1-18+(K04)」、「1-18+(K05)」、「1-18+(K06)」、「1-18+(K07)」、「1-18+(K08)」、「1-18+(K09)」、「1-18+(K10)」、「1-18+(K11)」、「1-18+(K12)」、「1-18+(K13)」、「1-18+(K14)」、「1-18+(K15)」、「1-18+(L01)」、「1-18+(L02)」、「1-18+(M01)」、「1-18+(M02)」、「1-18+(M03)」、「1-18+(M04)」、「1-18+(M05)」、「1-18+(M06)」、「1-18+(M07)」、「1-18+(M08)」、「1-18+(N01)」、「1-18+(N02)」、「1-18+(N03)」、「1-18+(N04)」、「1-18+(N05)」、「1-18+(N06)」、「1-18+(O01)」、「1-18+(O02)」、「1-18+(O03)」、「1-18+(O04)」、「1-18+(O05)」、「1-18+(O06)」、「1-18+(O07)」、「1-18+(O08)」、「1-18+(O09)」、「1-18+(O10)」、「1-18+(O11)」、「1-18+(O12)」、「1-18+(O13)」、「1-18+(O14)」、「1-18+(O15)」、「1-18+(O16)」、「1-18+(O17)」、「1-19+(A01)」、「1-19+(A02)」、「1-19+(A03)」、「1-19+(A04)」、「1-19+(A05)」、「1-19+(A06)」、「1-19+(A07)」、「1-19+(A08)」、「1-19+(A09)」、「1-19+(A10)」、「1-19+(A11)」、「1-19+(A12)」、「1-19+(A13)」、「1-19+(A14)」、「1-19+(A15)」、「1-19+(A16)」、「1-19+(A17)」、「1-19+(B01)」、「1-19+(B02)」、「1-19+(B03)」、「1-19+(B04)」、「1-19+(B05)」、「1-19+(B06)」、「1-19+(B07)」、「1-19+(B08)」、「1-19+(B09)」、「1-19+(C01)」、「1-19+(C02)」、「1-19+(C03)」、「1-19+(C04)」、「1-19+(C05)」、「1-19+(C06)」、「1-19+(C07)」、「1-19+(C08)」、「1-19+(C09)」、「1-19+(C10)」、「1-19+(C11)」、「1-19+(C12)」、「1-19+(D01)」、「1-19+(D02)」、「1-19+(D03)」、「1-19+(E01)」、「1-19+(E02)」、「1-19+(E03)」、「1-19+(E04)」、「1-19+(E05)」、「1-19+(E06)」、「1-19+(E07)」、「1-19+(E08)」、「1-19+(E09)」、「1-19+(E10)」、「1-19+(E11)」、「1-19+(E12)」、「1-19+(E13)」、「1-19+(F01)」、「1-19+(F02)」、「1-19+(G01)」、「1-19+(G02)」、「1-19+(G03)」、「1-19+(G04)」、「1-19+(G05)」、「1-19+(G06)」、「1-19+(G07)」、「1-19+(H01)」、「1-19+(H02)」、「1-19+(H03)」、「1-19+(H04)」、「1-19+(I01)」、「1-19+(I02)」、「1-19+(I03)」、「1-19+(I04)」、「1-19+(I05)」、「1-19+(I06)」、「1-19+(I07)」、「1-19+(I08)」、「1-19+(J01)」、「1-19+(J02)」、「1-19+(J03)」、「1-19+(J04)」、「1-19+(J05)」、「1-19+(J06)」、「1-19+(J07)」、「1-19+(J08)」、「1-19+(J09)」、「1-19+(J10)」、「1-19+(J11)」、「1-19+(J12)」、「1-19+(J13)」、「1-19+(K01)」、「1-19+(K02)」、「1-19+(K03)」、「1-19+(K04)」、「1-19+(K05)」、「1-19+(K06)」、「1-19+(K07)」、「1-19+(K08)」、「1-19+(K09)」、「1-19+(K10)」、「1-19+(K11)」、「1-19+(K12)」、 「1-19+(K13)」、「1-19+(K14)」、「1-19+(K15)」、「1-19+(L01)」、「1-19+(L02)」、「1-19+(M01)」、「1-19+(M02)」、「1-19+(M03)」、「1-19+(M04)」、「1-19+(M05)」、「1-19+(M06)」、「1-19+(M07)」、「1-19+(M08)」、「1-19+(N01)」、「1-19+(N02)」、「1-19+(N03)」、「1-19+(N04)」、「1-19+(N05)」、「1-19+(N06)」、「1-19+(O01)」、「1-19+(O02)」、「1-19+(O03)」、「1-19+(O04)」、「1-19+(O05)」、「1-19+(O06)」、「1-19+(O07)」、「1-19+(O08)」、「1-19+(O09)」、「1-19+(O10)」、「1-19+(O11)」、「1-19+(O12)」、「1-19+(O13)」、「1-19+(O14)」、「1-19+(O15)」、「1-19+(O16)」、「1-19+(O17)」、「1-20+(A01)」、「1-20+(A02)」、「1-20+(A03)」、「1-20+(A04)」、「1-20+(A05)」、「1-20+(A06)」、「1-20+(A07)」、「1-20+(A08)」、「1-20+(A09)」、「1-20+(A10)」、「1-20+(A11)」、「1-20+(A12)」、「1-20+(A13)」、「1-20+(A14)」、「1-20+(A15)」、「1-20+(A16)」、「1-20+(A17)」、「1-20+(B01)」、「1-20+(B02)」、「1-20+(B03)」、「1-20+(B04)」、「1-20+(B05)」、「1-20+(B06)」、「1-20+(B07)」、「1-20+(B08)」、「1-20+(B09)」、「1-20+(C01)」、「1-20+(C02)」、「1-20+(C03)」、「1-20+(C04)」、「1-20+(C05)」、「1-20+(C06)」、「1-20+(C07)」、「1-20+(C08)」、「1-20+(C09)」、「1-20+(C10)」、「1-20+(C11)」、「1-20+(C12)」、「1-20+(D01)」、「1-20+(D02)」、「1-20+(D03)」、「1-20+(E01)」、「1-20+(E02)」、「1-20+(E03)」、「1-20+(E04)」、「1-20+(E05)」、「1-20+(E06)」、「1-20+(E07)」、「1-20+(E08)」、「1-20+(E09)」、「1-20+(E10)」、「1-20+(E11)」、「1-20+(E12)」、「1-20+(E13)」、「1-20+(F01)」、「1-20+(F02)」、「1-20+(G01)」、「1-20+(G02)」、「1-20+(G03)」、「1-20+(G04)」、「1-20+(G05)」、「1-20+(G06)」、「1-20+(G07)」、「1-20+(H01)」、「1-20+(H02)」、「1-20+(H03)」、「1-20+(H04)」、「1-20+(I01)」、「1-20+(I02)」、「1-20+(I03)」、「1-20+(I04)」、「1-20+(I05)」、「1-20+(I06)」、「1-20+(I07)」、「1-20+(I08)」、「1-20+(J01)」、「1-20+(J02)」、「1-20+(J03)」、「1-20+(J04)」、「1-20+(J05)」、「1-20+(J06)」、「1-20+(J07)」、「1-20+(J08)」、「1-20+(J09)」、「1-20+(J10)」、「1-20+(J11)」、「1-20+(J12)」、「1-20+(J13)」、「1-20+(K01)」、「1-20+(K02)」、「1-20+(K03)」、「1-20+(K04)」、「1-20+(K05)」、「1-20+(K06)」、「1-20+(K07)」、「1-20+(K08)」、「1-20+(K09)」、「1-20+(K10)」、「1-20+(K11)」、「1-20+(K12)」、「1-20+(K13)」、「1-20+(K14)」、「1-20+(K15)」、「1-20+(L01)」、「1-20+(L02)」、「1-20+(M01)」、「1-20+(M02)」、「1-20+(M03)」、「1-20+(M04)」、「1-20+(M05)」、「1-20+(M06)」、「1-20+(M07)」、「1-20+(M08)」、「1-20+(N01)」、「1-20+(N02)」、「1-20+(N03)」、「1-20+(N04)」、「1-20+(N05)」、「1-20+(N06)」、「1-20+(O01)」、「1-20+(O02)」、「1-20+(O03)」、「1-20+(O04)」、「1-20+(O05)」、「1-20+(O06)」、「1-20+(O07)」、「1-20+(O08)」、「1-20+(O09)」、「1-20+(O10)」、「1-20+(O11)」、「1-20+(O12)」、「1-20+(O13)」、「1-20+(O14)」、「1-20+(O15)」、「1-20+(O16)」、「1-20+(O17)」、「1-21+(A01)」、「1-21+(A02)」、「1-21+(A03)」、「1-21+(A04)」、「1-21+(A05)」、「1-21+(A06)」、「1-21+(A07)」、「1-21+(A08)」、「1-21+(A09)」、「1-21+(A10)」、「1-21+(A11)」、「1-21+(A12)」、「1-21+(A13)」、「1-21+(A14)」、「1-21+(A15)」、「1-21+(A16)」、「1-21+(A17)」、「1-21+(B01)」、「1-21+(B02)」、「1-21+(B03)」、「1-21+(B04)」、「1-21+(B05)」、「1-21+(B06)」、「1-21+(B07)」、「1-21+(B08)」、「1-21+(B09)」、「1-21+(C01)」、「1-21+(C02)」、「1-21+(C03)」、「1-21+(C04)」、「1-21+(C05)」、「1-21+(C06)」、「1-21+(C07)」、「1-21+(C08)」、「1-21+(C09)」、「1-21+(C10)」、「1-21+(C11)」、「1-21+(C12)」、「1-21+(D01)」、「1-21+(D02)」、「1-21+(D03)」、「1-21+(E01)」、「1-21+(E02)」、「1-21+(E03)」、「1-21+(E04)」、「1-21+(E05)」、「1-21+(E06)」、「1-21+(E07)」、「1-21+(E08)」、「1-21+(E09)」、「1-21+(E10)」、「1-21+(E11)」、「1-21+(E12)」、「1-21+(E13)」、「1-21+(F01)」、「1-21+(F02)」、「1-21+(G01)」、「1-21+(G02)」、「1-21+(G03)」、「1-21+(G04)」、「1-21+(G05)」、「1-21+(G06)」、「1-21+(G07)」、「1-21+(H01)」、「1-21+(H02)」、「1-21+(H03)」、「1-21+(H04)」、「1-21+(I01)」、「1-21+(I02)」、「1-21+(I03)」、「1-21+(I04)」、「1-21+(I05)」、「1-21+(I06)」、「1-21+(I07)」、「1-21+(I08)」、「1-21+(J01)」、「1-21+(J02)」、「1-21+(J03)」、「1-21+(J04)」、「1-21+(J05)」、「1-21+(J06)」、「1-21+(J07)」、「1-21+(J08)」、「1-21+(J09)」、「1-21+(J10)」、「1-21+(J11)」、「1-21+(J12)」、「1-21+(J13)」、「1-21+(K01)」、「1-21+(K02)」、「1-21+(K03)」、「1-21+(K04)」、「1-21+(K05)」、「1-21+(K06)」、「1-21+(K07)」、「1-21+(K08)」、「1-21+(K09)」、「1-21+(K10)」、「1-21+(K11)」、「1-21+(K12)」、「1-21+(K13)」、「1-21+(K14)」、「1-21+(K15)」、「1-21+(L01)」、「1-21+(L02)」、「1-21+(M01)」、「1-21+(M02)」、「1-21+(M03)」、「1-21+(M04)」、「1-21+(M05)」、「1-21+(M06)」、「1-21+(M07)」、「1-21+(M08)」、「1-21+(N01)」、「1-21+(N02)」、「1-21+(N03)」、「1-21+(N04)」、「1-21+(N05)」、「1-21+(N06)」、「1-21+(O01)」、「1-21+(O02)」、「1-21+(O03)」、「1-21+(O04)」、「1-21+(O05)」、「1-21+(O06)」、「1-21+(O07)」、「1-21+(O08)」、「1-21+(O09)」、「1-21+(O10)」、「1-21+(O11)」、「1-21+(O12)」、「1-21+(O13)」、「1-21+(O14)」、「1-21+(O15)」、「1-21+(O16)」、「1-21+(O17)」、「1-22+(A01)」、「1-22+(A02)」、「1-22+(A03)」、「1-22+(A04)」、「1-22+(A05)」、「1-22+(A06)」、「1-22+(A07)」、「1-22+(A08)」、「1-22+(A09)」、「1-22+(A10)」、「1-22+(A11)」、「1-22+(A12)」、「1-22+(A13)」、「1-22+(A14)」、「1-22+(A15)」、「1-22+(A16)」、「1-22+(A17)」、「1-22+(B01)」、「1-22+(B02)」、「1-22+(B03)」、「1-22+(B04)」、「1-22+(B05)」、「1-22+(B06)」、「1-22+(B07)」、「1-22+(B08)」、「1-22+(B09)」、「1-22+(C01)」、「1-22+(C02)」、「1-22+(C03)」、「1-22+(C04)」、「1-22+(C05)」、「1-22+(C06)」、「1-22+(C07)」、「1-22+(C08)」、「1-22+(C09)」、「1-22+(C10)」、「1-22+(C11)」、「1-22+(C12)」、「1-22+(D01)」、「1-22+(D02)」、「1-22+(D03)」、「1-22+(E01)」、「1-22+(E02)」、「1-22+(E03)」、「1-22+(E04)」、「1-22+(E05)」、「1-22+(E06)」、「1-22+(E07)」、「1-22+(E08)」、「1-22+(E09)」、「1-22+(E10)」、「1-22+(E11)」、「1-22+(E12)」、「1-22+(E13)」、「1-22+(F01)」、「1-22+(F02)」、「1-22+(G01)」、「1-22+(G02)」、「1-22+(G03)」、「1-22+(G04)」、「1-22+(G05)」、「1-22+(G06)」、「1-22+(G07)」、「1-22+(H01)」、「1-22+(H02)」、「1-22+(H03)」、「1-22+(H04)」、「1-22+(I01)」、「1-22+(I02)」、「1-22+(I03)」、「1-22+(I04)」、「1-22+(I05)」、「1-22+(I06)」、「1-22+(I07)」、「1-22+(I08)」、「1-22+(J01)」、「1-22+(J02)」、「1-22+(J03)」、「1-22+(J04)」、「1-22+(J05)」、「1-22+(J06)」、「1-22+(J07)」、「1-22+(J08)」、「1-22+(J09)」、「1-22+(J10)」、「1-22+(J11)」、「1-22+(J12)」、「1-22+(J13)」、「1-22+(K01)」、「1-22+(K02)」、「1-22+(K03)」、「1-22+(K04)」、「1-22+(K05)」、「1-22+(K06)」、「1-22+(K07)」、「1-22+(K08)」、「1-22+(K09)」、「1-22+(K10)」、「1-22+(K11)」、「1-22+(K12)」、「1-22+(K13)」、「1-22+(K14)」、「1-22+(K15)」、「1-22+(L01)」、「1-22+(L02)」、「1-22+(M01)」、「1-22+(M02)」、「1-22+(M03)」、「1-22+(M04)」、「1-22+(M05)」、「1-22+(M06)」、「1-22+(M07)」、「1-22+(M08)」、「1-22+(N01)」、「1-22+(N02)」、「1-22+(N03)」、「1-22+(N04)」、「1-22+(N05)」、「1-22+(N06)」、「1-22+(O01)」、「1-22+(O02)」、「1-22+(O03)」、「1-22+(O04)」、「1-22+(O05)」、「1-22+(O06)」、「1-22+(O07)」、「1-22+(O08)」、「1-22+(O09)」、「1-22+(O10)」、「1-22+(O11)」、「1-22+(O12)」、「1-22+(O13)」、「1-22+(O14)」、「1-22+(O15)」、「1-22+(O16)」、「1-22+(O17)」、「1-23+(A01)」、「1-23+(A02)」、「1-23+(A03)」、「1-23+(A04)」、「1-23+(A05)」、「1-23+(A06)」、「1-23+(A07)」、「1-23+(A08)」、「1-23+(A09)」、「1-23+(A10)」、「1-23+(A11)」、「1-23+(A12)」、「1-23+(A13)」、「1-23+(A14)」、「1-23+(A15)」、「1-23+(A16)」、「1-23+(A17)」、「1-23+(B01)」、「1-23+(B02)」、「1-23+(B03)」、「1-23+(B04)」、「1-23+(B05)」、「1-23+(B06)」、「1-23+(B07)」、「1-23+(B08)」、「1-23+(B09)」、「1-23+(C01)」、「1-23+(C02)」、「1-23+(C03)」、「1-23+(C04)」、「1-23+(C05)」、「1-23+(C06)」、「1-23+(C07)」、「1-23+(C08)」、「1-23+(C09)」、「1-23+(C10)」、「1-23+(C11)」、「1-23+(C12)」、「1-23+(D01)」、「1-23+(D02)」、「1-23+(D03)」、「1-23+(E01)」、「1-23+(E02)」、「1-23+(E03)」、「1-23+(E04)」、「1-23+(E05)」、「1-23+(E06)」、「1-23+(E07)」、「1-23+(E08)」、「1-23+(E09)」、「1-23+(E10)」、「1-23+(E11)」、「1-23+(E12)」、「1-23+(E13)」、「1-23+(F01)」、「1-23+(F02)」、「1-23+(G01)」、「1-23+(G02)」、「1-23+(G03)」、「1-23+(G04)」、「1-23+(G05)」、「1-23+(G06)」、「1-23+(G07)」、「1-23+(H01)」、「1-23+(H02)」、「1-23+(H03)」、「1-23+(H04)」、「1-23+(I01)」、「1-23+(I02)」、「1-23+(I03)」、「1-23+(I04)」、「1-23+(I05)」、「1-23+(I06)」、「1-23+(I07)」、「1-23+(I08)」、「1-23+(J01)」、「1-23+(J02)」、「1-23+(J03)」、「1-23+(J04)」、「1-23+(J05)」、「1-23+(J06)」、「1-23+(J07)」、「1-23+(J08)」、「1-23+(J09)」、「1-23+(J10)」、「1-23+(J11)」、「1-23+(J12)」、「1-23+(J13)」、「1-23+(K01)」、「1-23+(K02)」、「1-23+(K03)」、「1-23+(K04)」、「1-23+(K05)」、「1-23+(K06)」、「1-23+(K07)」、「1-23+(K08)」、「1-23+(K09)」、「1-23+(K10)」、「1-23+(K11)」、「1-23+(K12)」、「1-23+(K13)」、「1-23+(K14)」、「1-23+(K15)」、「1-23+(L01)」、「1-23+(L02)」、「1-23+(M01)」、「1-23+(M02)」、「1-23+(M03)」、「1-23+(M04)」、「1-23+(M05)」、「1-23+(M06)」、「1-23+(M07)」、「1-23+(M08)」、「1-23+(N01)」、「1-23+(N02)」、「1-23+(N03)」、「1-23+(N04)」、「1-23+(N05)」、「1-23+(N06)」、「1-23+(O01)」、「1-23+(O02)」、「1-23+(O03)」、「1-23+(O04)」、「1-23+(O05)」、「1-23+(O06)」、「1-23+(O07)」、「1-23+(O08)」、「1-23+(O09)」、「1-23+(O10)」、「1-23+(O11)」、「1-23+(O12)」、「1-23+(O13)」、「1-23+(O14)」、「1-23+(O15)」、「1-23+(O16)」、「1-23+(O17)」、「1-24+(A01)」、「1-24+(A02)」、「1-24+(A03)」、「1-24+(A04)」、「1-24+(A05)」、「1-24+(A06)」、「1-24+(A07)」、「1-24+(A08)」、「1-24+(A09)」、「1-24+(A10)」、「1-24+(A11)」、「1-24+(A12)」、「1-24+(A13)」、「1-24+(A14)」、「1-24+(A15)」、「1-24+(A16)」、「1-24+(A17)」、「1-24+(B01)」、「1-24+(B02)」、「1-24+(B03)」、「1-24+(B04)」、「1-24+(B05)」、「1-24+(B06)」、「1-24+(B07)」、「1-24+(B08)」、「1-24+(B09)」、「1-24+(C01)」、「1-24+(C02)」、「1-24+(C03)」、「1-24+(C04)」、「1-24+(C05)」、「1-24+(C06)」、「1-24+(C07)」、「1-24+(C08)」、「1-24+(C09)」、「1-24+(C10)」、「1-24+(C11)」、「1-24+(C12)」、「1-24+(D01)」、「1-24+(D02)」、「1-24+(D03)」、「1-24+(E01)」、「1-24+(E02)」、「1-24+(E03)」、「1-24+(E04)」、「1-24+(E05)」、「1-24+(E06)」、「1-24+(E07)」、「1-24+(E08)」、「1-24+(E09)」、「1-24+(E10)」、「1-24+(E11)」、「1-24+(E12)」、「1-24+(E13)」、「1-24+(F01)」、「1-24+(F02)」、「1-24+(G01)」、「1-24+(G02)」、「1-24+(G03)」、「1-24+(G04)」、 「1-24+(G05)」、「1-24+(G06)」、「1-24+(G07)」、「1-24+(H01)」、「1-24+(H02)」、「1-24+(H03)」、「1-24+(H04)」、「1-24+(I01)」、「1-24+(I02)」、「1-24+(I03)」、「1-24+(I04)」、「1-24+(I05)」、「1-24+(I06)」、「1-24+(I07)」、「1-24+(I08)」、「1-24+(J01)」、「1-24+(J02)」、「1-24+(J03)」、「1-24+(J04)」、「1-24+(J05)」、「1-24+(J06)」、「1-24+(J07)」、「1-24+(J08)」、「1-24+(J09)」、「1-24+(J10)」、「1-24+(J11)」、「1-24+(J12)」、「1-24+(J13)」、「1-24+(K01)」、「1-24+(K02)」、「1-24+(K03)」、「1-24+(K04)」、「1-24+(K05)」、「1-24+(K06)」、「1-24+(K07)」、「1-24+(K08)」、「1-24+(K09)」、「1-24+(K10)」、「1-24+(K11)」、「1-24+(K12)」、「1-24+(K13)」、「1-24+(K14)」、「1-24+(K15)」、「1-24+(L01)」、「1-24+(L02)」、「1-24+(M01)」、「1-24+(M02)」、「1-24+(M03)」、「1-24+(M04)」、「1-24+(M05)」、「1-24+(M06)」、「1-24+(M07)」、「1-24+(M08)」、「1-24+(N01)」、「1-24+(N02)」、「1-24+(N03)」、「1-24+(N04)」、「1-24+(N05)」、「1-24+(N06)」、「1-24+(O01)」、「1-24+(O02)」、「1-24+(O03)」、「1-24+(O04)」、「1-24+(O05)」、「1-24+(O06)」、「1-24+(O07)」、「1-24+(O08)」、「1-24+(O09)」、「1-24+(O10)」、「1-24+(O11)」、「1-24+(O12)」、「1-24+(O13)」、「1-24+(O14)」、「1-24+(O15)」、「1-24+(O16)」、「1-24+(O17)」。
[0052] In the composition and method of the present invention, the suitable mixing ratio of active ingredient A selected from compound (1) and active ingredient B selected from known compounds is usually 0.001 to 1000 parts by weight, preferably 0.01 to 100 parts by weight, more preferably 0.1 to 10 parts by weight, of active ingredient B per 1 part by weight of active ingredient A.
[0053] The preferred application rates of the active ingredients in the composition and method of the present invention vary depending on the type of plant disease to be controlled, but are typically 0.1 to 1000 ga.i. / ha for active ingredient A and 0.1 to 3000 ga.i. / ha for active ingredient B, preferably 1 to 300 ga.i. / ha for active ingredient A and 1 to 2000 ga.i. / ha for active ingredient B.
[0054] In this specification, the term "plant" refers to vascular plants (Tracheophyta) such as grains, fruit trees, and vegetables cultivated for human food, feed crops for livestock and poultry, ornamental plants appreciated for their appearance and shape, and plants planted in parks and streets, etc. Specific examples of plants include, but are not limited to, the following plants:
[0055] Plants of the Pinales order, such as Japanese Red Pine (Pinus densiflora), Scots Pine (Pinus sylvestris), and Japanese Black Pine (Pinus thunbergii), belong to the Pinaceae family.
[0056] Pepper (Piper nigrum) and other members of the Piperaceae family, magnoliids (Lauraceae) such as avocado (Persea americana) and other members of the magnolia family, Araceae such as konjac (Amorphophallus konjac) and eddoe (Colocasia esculenta), Dioscoreaceae such as Chinese yam (Dioscorea batatas) and Japanese yam (Dioscorea japonica), leek (Allium ampeloprasum var. porrum), onion (Allium cepa), rakkyo (Allium chinense), Welsh onion (Allium fistulosum), and garlic (Allium Alliaceae (family of plants) such as Allium sativum, chives (Allium schoenoprasum), chives (Allium schoenoprasum var. foliosum), Chinese chives (Allium tuberosum), and scallions (Allium x wakegi); Asparagaceae (family of plants) such as asparagus (Asparagus officinalis); Arecaceae (family of palms) such as coconut palms (Cocos nucifera) and oil palms (Elaeis guineensis); Arecaceae (family of palms) such as date palms (Phoenix dactylifera); and Pineapple (family of palms) such as pineapples. Bromeliaceae (Bromeliaceae) such as Oryza comosus, Poaceae (Ehrhartoideae) such as rice (Oryza sativa), Bent grass (Agrostis spp.Poaceae (Poa family), Pooideae (Pooideae) such as bluegrass (Poa spp.), barley (Hordeum vulgare), wheat (Triticum aestivum, T. durum), and rye (Secale cereale); Poaceae (Chloridoideae) such as Bermuda grass (Cynodon dactylon) and Zoysia spp.; Poaceae (Poa family), Panicoideae (Panicoideae) such as sugarcane (Saccharum officinarum), sorghum (Sorghum bicolor), and corn (Zea mays); Musaceae (Musaceae) such as banana (Musa spp.); Monocots belonging to the Zingiberaceae family include Zingiber mioga and Zingiber officinale.
[0057] Nelumbonaceae (Lotus root, Nelumbo nucifera) and other plants; Fabaceae (Fabaceae) (Peanut, Arachis hypogaea), chickpea, Cicer arietinum, lentil, Pisum sativum, broad bean, Vicia faba, soybean, Glycine max, common bean, Phaseolus vulgaris, adzuki bean, Vigna angularis, and cowpea, Vigna unguiculata); Cannabaceae (Humulus lupulus) and other plants; Moraceae (Moraceae) (Fig tree, Ficus carica, mulberry, Morus spp.) and other plants; Rhamnaceae (family of trees) such as jujube (Ziziphus jujuba), strawberry (Fragaria), rose (Rosa spp.) and other species of the Rosaceae subfamily Rosoideae, Japanese loquat (Eriobotrya japonica), apple (Malus pumila), European pear (Pyrus communis), and pear (Pyrus pyrifolia var.Rosaceae (Rosaceae) subfamily Maloideae (Pear subfamily Maloideae) such as peach (Amygdalus persica), apricot (Prunus armeniaca), cherry (Prunus avium), prune (Prunus domestica), almond (Prunus dulcis), Japanese apricot (Prunus mume), Japanese plum (Prunus salicina), Oshima cherry (Cerasus speciosa), Somei-yoshino cherry (Cerasus x yedoensis 'Somei-yoshino') and other species from the Rosaceae subfamily Prunoideae (Prunus siceraria) such as winter melon (Benincasa hispida), watermelon (Citrullus lanatus), bottle gourd (Lagenaria siceraria var. Cucurbitaceae, such as cucumber (Cucumis hispida), loofah (Luffa cylindrica), pumpkin (Cucurbita spp.), zucchini (Cucurbita pepo), bitter melon (Momordica charantia var. pavel), muskmelon (Cucumis melo), Oriental pickling melon (Cucumis melo var. conomon), Oriental melon (Cucumis melo var. makuwa), and cucumber (Cucumis sativus); Fagaceae, such as Japanese chestnut (Castanea crenata); and walnut (Juglans spp.).), the Anacardiaceae family (Anacardiaceae) including cashew nuts (Anacardium occidentale), mango (Mangifera indica), and pistachios (Pistacia vera), the Rutaceae family (Rutoideae) including Japanese pepper (Zanthoxylum piperitum), bitter orange (Citrus aurantium), lime (Citrus aurantifolia), hassaku orange (Citrus hassaku), yuzu (Citrus junos), lemon (Citrus limon), Natsumikan (Citrus natsudaidai), grapefruit (Citrus x paradisi), orange (Citrus sinensis), and kabosu (Citrus sphaerocarpa), Sudachi (Citrus sudachi), Ponkan (Mandarin Orange) (Citrus tangerina), Satsuma (Citrus unshiu), Kumquat (Fortunella spp.), and other members of the Rutaceae (Aurantioideae) subfamily; Horseradish (Armoracia rusticana), Mustard (Brassica juncea), Takana (Brassica juncea var. integrifolia), Rapeseed (Brassica napus), Cauliflower (Brassica oleracea var. botrytis), Cabbage (Brassica oleracea var. capitata), and Brussels sprout (Brassica oleracea var. gemmifera), Broccoli (Brassica oleracea var.italica), Green pak choi(Brassica rapa var. chinensis), Nozawana(Brassica rapa var. hakabura), Napa cabbage(Brassica rapa var. nippo-oleifera), Mizuna Potherb Mustard(Brassica rapa var. nipposinica), Chinese cabbage Napa cabbage (Brassica rapa var. pekinensis), Turnip leaf (Brassica rapa var. perviridis), Turnip (Brassica rapa var. rapa), Garden rocket (Eruca vesicaria), Daikon (Raphanus sativus var. longipinnatus), Wasabi (Wasabia japonica) and other members of the Brassicaceae family; Caricaceae, such as papaya (Carica papaya); Malvaceae, such as okra (Abelmoschus esculentus), cotton plant (Gossypium spp.), and cacao (Theobroma cacao); Vitaceae, such as grape (Vitis spp.); sugar beet (Beta vulgaris ssp. vulgaris var. altissima), table beet (Beta vulgaris ssp. vulgaris var.vulgaris, Amaranthaceae such as spinach (Spinacia oleracea), Polygonaceae such as buckwheat (Fagopyrum esculentum), Ebenaceae such as persimmon (Diospyros kaki), Theaceae such as tea plant (Camellia sinensis), Actinidiaceae such as kiwifruit (Actinidia deliciosa, A. chinensis), Ericaceae such as blueberry (Vaccinium spp.) and cranberry (Vaccinium spp.), Rubiaceae such as coffee plants (Coffea spp.), and Lemon balm (Melissa officinalis), mint (Mentha spp.), basil (Ocimum basilicum), shiso (Perilla frutescens var. crispa), perilla (Perilla frutescens var. frutescens), common sage (Salvia officinalis), thyme (Thymus spp.), etc. from the Lamiaceae family; sesame (Sesamum indicum), etc. from the Pedaliaceae family; olive (Olea europaea), etc. from the Oleaceae family; sweet potato (Ipomoea batatas), etc. from the Convolvulaceae family; tomato (Solanum lycopersicum), eggplant (Solanum melongena), potato (Solanum tuberosum), Chili pepper (Capsicum annuum), Bell pepper (Capsicum annuum var.Solanaceae (Solanaceae) such as 'grossum', tobacco (Nicotiana tabacum), celery (Apium graveolens var. dulce), coriander (Coriandrum sativum), Japanese honeywort (Cryptotaenia Canadensis subsp. japonica), carrot (Daucus carota subsp. sativus), parsley (Petroselium crispum), Italian parsley (Petroselinum neapolitanum), Apiaceae (Apiaceae) such as Udo (Aralia cordata) and Aralia elata, and artichoke (Cynara Eudicots include the Carduoideae family of the Asteraceae family, such as Cichorium scolymus, the Dandelion subfamily of the Asteraceae family, such as Cichorium intybus and Lactuca sativa, and the Florists' daisy (Dendranthema grandiflorum), Crown daisy (Glebionis coronaria), Sunflower (Helianthus annuus), Butterbur (Petasites japonicus), and Burdock (Arctium lappa).
[0058] Furthermore, the term "plant" as used herein also includes plants that have been conferred tolerance to HPPD inhibitors such as isoxaflutole, ALS inhibitors such as imazethapyr and thifensulfuron-methyl, EPSP synthase inhibitors such as glyphosate, glutamine synthase inhibitors such as glufosinate, acetyl-CoA carboxylase inhibitors such as sethoxydim, PPO inhibitors such as flumioxazin, and herbicides such as bromoxynil, dicamba, and 2,4-D by classical breeding methods and by genetic engineering techniques.
[0059] Examples of "horticultural plants" that have been made resistant through classical breeding methods include rapeseed, wheat, sunflower, rice, and corn that are resistant to imidazolinone ALS-inhibiting herbicides such as imazethapyr, and these are already sold under the trade name Clearfield®.
[0060] Similarly, soybeans that have been bred tolerant to sulfonylurea ALS-inhibiting herbicides such as thifensulfuron-methyl through classical breeding techniques are already available on the market under the trade name STS soybean. Similarly, examples of horticultural plants that have been bred to be tolerant to acetyl-CoA carboxylase inhibitors, such as trione oxime and aryloxyphenoxypropionic acid herbicides, include SR corn. Agricultural plants bred to be tolerant to acetyl-CoA carboxylase inhibitors are described in, for example, Proceedings of the National Academy of Sciences of the United States of America (Proc. Natl. Acad. Sci. USA) Vol. 87, pp. 7175–7179 (1990). Mutant acetyl-CoA carboxylases resistant to acetyl-CoA carboxylase inhibitors have been reported in Weed Science, Vol. 53, pp. 728-746 (2005), among others. Plants resistant to acetyl-CoA carboxylase inhibitors can be produced by introducing such mutant acetyl-CoA carboxylase genes into plants using genetic engineering or by introducing resistance-conferring mutations into crop acetyl-CoA carboxylase. Furthermore, plants resistant to acetyl-CoA carboxylase inhibitors / herbicides can be produced by introducing nucleic acids with base substitution mutations, such as those typified by chimeraplasty technology (Gura T. 1999. Repairing the Genome's Spelling Mistakes. Science 285: 316-318), into plant cells to induce site-specific amino acid substitutions in the crop (acetyl-CoA carboxylase / herbicide target) gene.
[0061] Examples of agricultural and horticultural plants that have been made resistant through genetic engineering include glyphosate-resistant corn, soybean, cotton, rapeseed, and sugar beet varieties, which are already sold under trade names such as Roundup Ready® and AgrisureGT®. Similarly, glufosinate-resistant corn, soybean, cotton, and rapeseed varieties, which have been made resistant through genetic engineering, are already sold under trade names such as LibertyLink®. Similarly, bromoxynil-resistant cotton, which has been made resistant through genetic engineering, is already sold under the trade name BXN.
[0062] The above-mentioned "agricultural and horticultural plants" also include plants that have been made capable of synthesizing selective toxins known in the genus Bacillus through the use of genetic engineering techniques.
[0063] Examples of insecticidal toxins that can be expressed in such genetically modified plants include insecticidal proteins derived from Bacillus cereus or Bacillus popilliae; δ-endotoxins such as Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1, or Cry9C derived from Bacillus thuringiensis, insecticidal proteins such as VIP1, VIP2, VIP3, or VIP3A; insecticidal proteins derived from nematodes; toxins produced by animals such as scorpion toxins, spider toxins, bee toxins, or insect-specific neurotoxins; toxins from filamentous fungi; plant lectins; agglutinins; protease inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, and papain inhibitors; ricin Ribosome-inactivating proteins (RIPs) such as maize-RIP, abrin, saporin, and bryodin; steroid metabolic enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, and cholesterol oxidase; ecdysone inhibitors; HMG-CoA reductase; ion channel inhibitors such as sodium channel inhibitors and calcium channel inhibitors; juvenile hormone esterase; diuretic hormone receptor; stilbene synthase; bibenzyl synthase; chitinase; and glucanase.
[0064] Toxins expressed in such genetically modified plants also include hybrid toxins, truncated toxins, and modified toxins made from δ-endotoxin proteins such as Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1, or Cry9C, and insecticidal proteins such as VIP1, VIP2, VIP3, or VIP3A. Hybrid toxins are produced using recombinant technology by combining different domains of these proteins in new ways. A known example of a truncated toxin is Cry1Ab, which lacks a portion of its amino acid sequence. Modified toxins have one or more amino acids substituted in the native toxin.
[0065] Examples of these toxins and recombinant plants capable of synthesizing them are described in patent documents such as EP-A-0374753, WO93 / 07278, WO95 / 34656, EP-A-0427529, EP-A-451878, WO03 / 052073, etc. The toxins contained in these recombinant plants confer resistance to plants, inter alia, to coleopteran, dipteran and lepidopteran pests.
[0066] Additionally, transgenic plants containing one or more insecticidal pest resistance genes and expressing one or more toxins are already known, and some are commercially available. Examples of these genetically modified plants include YieldGard® (a corn variety expressing the Cry1Ab toxin), YieldGard Rootworm® (a corn variety expressing the Cry3Bb1 toxin), YieldGard Plus® (a corn variety expressing the Cry1Ab and Cry3Bb1 toxins), Herculex I® (a corn variety expressing the Cry1Fa2 toxin and phosphinothricin N-acetyltransferase (PAT) to confer resistance to glufosinate), NuCOTN33B® (a cotton variety expressing the Cry1Ac toxin), Bollgard I® (a cotton variety expressing the Cry1Ac toxin), and Bollgard II® (a cotton variety expressing the Cry1Ac toxin). II)™ (a cotton variety expressing Cry1Ac and Cry2Ab toxins), Bollgard III™ (a cotton variety expressing Cry1Ac, Cry2Ab, and VIP3A toxins), VIPCOT™ (a cotton variety expressing VIP toxins), WideStrike™ (a cotton variety expressing Cry1Ac and Cry1F toxins), NewLeaf™ (a potato variety expressing Cry3A toxin), NatureGard Agrisure™ GT Advantage (GA21 glyphosate tolerance trait), Agrisure™ CB Advantage (Bt11 corn borer (CB) trait), Protecta™, and the like. This includes soybeans that have been given resistance to aphids by introducing the Rag1 (Resistance Aphid Gene 1) gene. RNAi is a genetic engineering technique that confers nematode resistance.
[0067] The above plants also include those that have been given the ability to produce anti-pathogenic substances with selective action using genetic engineering techniques.
[0068] Antipathogenic substances include, for example, PR proteins (PRPs, as described in EP-A-0392225); ion channel inhibitors such as sodium channel inhibitors and calcium channel inhibitors (such as viral toxins KP1, KP4, and KP6); stilbene synthase, bibenzyl synthase, chitinase, glucanase; peptide antibiotics, heterocyclic antibiotics, and protein factors involved in plant disease resistance (called plant disease resistance genes, as described in WO 03 / 000906), among others. Such antipathogenic substances and genetically modified plants that produce them are described in EP-A-0392225, WO 95 / 33818, EP-A-0353191, and others.
[0069] The above plants also include crops that have been genetically modified to improve oil composition or enhance amino acid content, etc. Examples include VISTIVE® (low-linolenic soybeans) and high-lysine (high foil) corn (corn with increased lysine or oil content).
[0070] Furthermore, it also includes stacked varieties that combine multiple useful traits such as the classic herbicide traits mentioned above, herbicide tolerance genes, insecticide resistance genes, antipathogenic substance production genes, oilseed component modification traits, and amino acid content enhancement traits, as well as plants into which RNAi technology has been introduced.
[0071] In this specification, the term "pest control agent" refers to a pest control agent that targets harmful arthropods in the fields of agriculture and horticulture, livestock farming, and hygiene (internal and external parasites of mammals or birds as livestock or pets, and sanitary pests and nuisance pests for household and commercial use).
[0072] In addition, the term "pesticides" as used herein refers to insecticides, miticides, nematicides, herbicides, fungicides, and the like used in the agricultural and horticultural fields.
[0073] As used herein, "sanitary pests" refers to harmful invertebrates that bite target animals, causing allergic symptoms such as severe pain, swelling, and itching, and in some cases, fatal anaphylactic shock, or that transmit serious diseases through blood-sucking, sometimes even leading to death; invertebrates that sometimes contaminate food with pathogens such as viruses, bacteria, and parasites through contact with food; invertebrates whose living organisms, carcasses, molted skin, and feces act as allergens, causing allergic diseases such as bronchial asthma, rhinitis, conjunctivitis, and atopic dermatitis; invertebrates that cause economic damage by feeding on food, clothing, and housing; and invertebrates that cause discomfort by invading and infesting human living environments without causing direct harm. More specifically, these include ants that bite with their mandibles, hornets that sting with their poisonous stingers, mosquitoes and assassin bugs that suck blood through the skin, and termites that are omnivorous and damage buildings such as houses.
[0074] In this specification, the term "nuisance pests" refers to pests that do not directly harm humans in their living environment, but that cause discomfort and psychological harm due to their appearance or shape.
[0075] Specific examples of insects, mites, crustaceans, mollusks, nematodes, ectoparasites, and endoparasites that can be controlled using the composition and method of the present invention include, but are not limited to, the following organisms:
[0076] Pests include the following insects from the order Lepidoptera: Allium leafminer (Acrolepiopsis sapporensis), Yam leafminer (Acrolepiopsis suzukiella), Smaller tea tortrix (Adoxophyes honmai), Summer fruit tortrix (Adoxophyes orana fasciata), Fruit-piercing moth (Adris tyrannus), Sweet potato leafworm (Aedia leucomelas), Black cutworm (Agrotis ipsilon), Turnip moth (Agrotis segetum), Cotton leafworm (Alabama argillacea), and Asiatic leafroller (ArCHIps breviplicanus), Apple tortrix (ArCHips fuscocupreanus), Oriental tussock moth (Artaxa subflava), Bamboo zygaenid (Artona martini), Japanese giant looper (Ascotis selenaria), Asiatic common looper (Autographa nigrisigna), Pear leaf miner (Bucculatrix pyrivorella), Tea leafroller (Caloptilia theivora), Peach fruit moth (PeaCH), Rice stem borer (Cilo suppressalis), Rice leafroller (Cnaphalocrocis medinalis), Yellow peaCH moth (Conogethespunctiferalis), Carpenter moth (Cossus insularis), Threespotted plusia moth (Ctenoplusia agnata), Codling moth (Cydia pomonella), Pine moth (Dendrolimus spectabilis), Jananese hemlock caterpillar (Dendrolimus superans), Cucumber moth (Diaphania indica), Sugarcane borer (Diatraea sacCHARALIS), Sorghum moth (Eilema fuscodorsalis), Sorghum moth (Eilema laevis), Lesser corn stalk moth borer (Elasmopalpus lignosellus), grape berry moth (Endopiza viteana), Limabean pod borer (Etiella zinckenella), Japanese tussock moth (Euproctis piperita), Tea tussock moth (Euproctis pseudoconspersa), Japanese bamboo lappet moth (Euthrix albomaculata), Reed moth (Euthrix potatoria), Oriental lappet moth (Gastropa orientalis), Mulberry pyralid (Glyphodes pyloalis), Plum fruit moth (Grapholita dimorpha), Oriental fruit moth (Grapholita molesta), Sweetpotato leaffolder(Helcystogramma triannullella), CottonBollworm (Helicoverpa armigera), Oriental tobacco budworm (Helicoverpa assulta), Corn earworm (Helicoverpa zea), Tobacco budworm (Heliothis virescens), Cabbage webworm (Hellula undalis), Oriental tea tortrix (Homona magnanima), Fall webworm moth (Hyphantria cunea), Pearl leaf worm (Illiberis pruni), Prunus bud moth (Illiberis rotundata), Oak moth (Quercus lasiocampid) (Kunugia undans), Mountain moth (Quercus lasiocampid) (Kunugia yamadai), Soybean pod borer (Leguminivora glycinivorella), Mulberry tiger moth (Lemyra imparilis), Gypsy moth (Lymantria dispar), Peach leafminer (Lyonetia clerkella), Silver leafminer (Lyonetia prunifoliella malinella), Cabbage armyworm (Mamestra brassicae), Tomato hornworm (Manduca quinquemaculata), Tobacco hornworm (Manduca sexta), Soybean podworm (Matsumuraeses phaseoli), Oriental moth (Monema flavescens), Rice green caterpillar (Narangaaenescens), White-spotted tussock moth (Orgyia thyellina), Asian corn borer (Ostrinia furnacalis), European corn borer (Ostrinia nubilalis), Adzuki bean borer (Ostrinia scapulalis), Dark fruit-tree tortrix (Pandemis heparana), Bluegrass webworm (Parapediasia teterrella), Green cochlid moth (Parasa consocia), Broad-headed corn borer (Parasa lepida), Chinese cochlid moth (Parasa sinica), Straight swift skipper (Parnara guttata), Pink bollworm (Pectinophora gossypiella), Citrus leafminer (Phyllocnistis citrella), Apple leafminer (Phyllonorycter ringoniella), Large white (Pieris brassicae), Cabbage white butterfly (Pieris rapae crucivora), Diamondback moth (Plutella xylostella), Oriental armyworm (Pseudaletia separata), Soybean looper (Pseudoplusia includens), Swan moth (Sphrageidus similis), Lawn grass cutworm (Spodoptera depravata), Southern armyworm (Spodoptera eridania), Beet armyworm (Spodopteraexigua), Fall armyworm (Spodoptera frugiperda), Cotton leafworm (Spodoptera littoralis), Common cutworm (Spodoptera litura), Persimmon fruit moth (Stathmopoda masinissa), Peach tree borer (Synanthedon exitiosa), Cherry tree borer (Synanthedon hector), Red-collared clearwing moth (Toleria romanovi), Cabbage looper (TriCHoplusia ni), etc. Coleoptera: Common bean weevil (Acanthoscelides obtectus), Cupreous chafer (Anomala cuprea), Soybean beetle (Anomala rufocuprea), Asian long-horn beetle (Anoplophora glabripennis), White-spotted longicorn beetle (Anoplophora malasiaca), Boll weevil (Anthonomus grandis), Cucurbit leaf beetle (Aulacophora femoralis), Adzuki bean beetle (Callosobruchus chinensis), Flea beetle (Chaetocnema concinna), sweet potato weevil (Cylas formicarius), leaf beetle (Demotina fasciculata), northern corn rootworm (Diabrotica barberi), southern corn rootworm (Diabrotica undecimpunctata), western corn rootworm (Diabrotica virgifera), rice plant weevil (ECHinocnemus squameus), Mexican bee beetle (EpilaCHna varivestis), large 28-spotted ladybird (EpilaCHna vigintioctomaculata), 28-spotted ladybird (EpilaCHna vigintioctopunctata), Epuraeadomina (Epuraea domina), West Indian sweet potato weevil (Euscepes postfasciatus), Citrus flower chafer (Gametis jucunda), White-fringed beetle (Graphognatus leucoloma), Yellowish elongate chafer (Heptophylla picea), Alfalfa weevil (Hypera postica), Tobacco beetle (Lasioderma serricorne), Colorado potato beetle (Leptinotarsa decemlineata), Rice water weevil (Lissohoptrus oryzophilus), Sweet potato wireworm (Melanotus fortnumi), Sugarcane wireworm (Melanotus tamsuyensis), Pollen beetle (Meligethes aeneus), Japanese pine sawyer (Monochamus alternatus), Black vine weevil (Otiorhynchus sulcatus), Rice leaf beetle (Oulema oryzae), Rove beetle (Paederus fuscipes), Mustard leaf beetle (Phaedon cochleariae), Striped flea beetle (Phyllotreta striolata), Japanese beetle (Popillia japonica), Yellow-spotted longhorn beetle longicorn beetle (Psacothea hilaris), Solanum fleaBeetle (Psylliodes angusticollis), peach curculio (RhynCHites heros), Granary weevil (Sitophilus granarius), Maize weevil (Sitophilus zeamais), Hunting billbug (Sphenophorus venatus vestitus), Yellow mealworm (Tenebrio molitor), Red flour beetle (Tribolium castaneum), Grape borer (XylotreCHus pyrrhoderus), etc. Hymenoptera: Chestnut sawfly (Apethymus kuri), Large rose sawfly (Arge pagana), Cabbage sawfly (Athalia infumata), Turnip sawfly (Athalia rosae), Japanese carpenter ant (Camponotus japonicus), Chestnut gall wasp (Dryocosmus kuriphilus), Army ant (Eciton burCHellii, E. sCHmitti), Argentine ant (Linepithema humile), Pharaoh ant (Monomorium pharaonis), Bulldog ant (Myrmecia spp.), European pine sawfly Sawfly (Neodiprion sertifer), Fire ants (Solenopsis spp.), Asian giant hornet (Vespa mandarinia), Japanese yellow hornet (Vespa simillima), etc. Diptera: Yellow fever mosquito (Aedes aegypti), Asian tiger mosquito (Aedes albopictus), Aedes spp., Aedes taeniorhynchus, Rice leaf miner (Agromyza oryzae), Mexican fruit fly (Anastrepha ludens), African malaria mosquito (Anopheles gambiae), African malaria mosquito (Anopheles hyrcanus sinensis), Anopheles koreicus, Anopheles lesteri lesteri, Anopheles maculipennis, Anopheles spp., Soybean pod gall midge (Asphondylia yushimai), Atylotus spp., Melon fly (Bactrocera cucurbitae), Oriental fruit fly (Bactrocera dorsalis), Queensland fruit fly (Bactrocera tryoni), Japanese orange fly (Bactrocera tsuneonis), Boophthora erythrocephala, Braula coeca, Braula spp., Calliphora erythrocephala erythrocephala), the blowfly Calliphora lata, and Calliphora spp.), Bottle fly (Calliphora vicina), Mediterranean fruit fly (Ceratitis capitata), Pea leaf miner (CHromatomyia horticola), Old World screwworm fly (CHrysomya bezziana), Blow fly (CHrysomya CHloropyga), Oriental latrine fly (CHrysomya megacephala), Chrysomya spp., Splayed deerfly (CHrysops caecutiens), Chrysops relictus, Chrysops spp., Deer fly (CHrysops suavis, Chrysozona pluvialis, New World screwworm fly (CCHliomyia hominivorax), House mosquito (Culex pipiens molestus), House mosquito (Culex pipiens pallens), Culex quinquefasciatus, Culex tarsalis, Culex tritaeniorhynCHus, Culex spp., Biting midge (Culicoides arakawae), Culicoides spp., Bot flies (Cuterebra spp.), Onion fly (Delia antiqua), Seed corn maggot (Delia platura), Human botfly (Dermatobia hominis), Japanese fruit fly (Drosophila suzukii), Eusimulium spp., Lesser house fly (Fannia canicularis), Fannia spp., Horse nose bot fly (Gasterophilus haemorrhoidalis), Gasterophilus inermis, Horse bot fly (Gasterophilus intestinalis), Throat bot fly (Gasterophilus nasalis), Gasterophilus nigricornis nigricornis, Gasterophilus pecorum, Gasterophilus spp., Tsetse fly (Glossina morsitans, G. palpalis), Glossina spp., Horn fly (Haematobia irritans), Haematobia irritans exigua, Haematobia spp., Haematobia stimulans, Haematopota italic, Common horse fly (Haematopota pluvialis), Haematopota spp., Forest fly (Hippobosca equina), Hippobosca spp.), Hippobosca variegate, Hybomitra ciurea, Hybomitra spp., Smaller rice leaf miner (Hydrellia griseola), Hydrotaea albipuncta, Sheep headfly (Hydrotaea irritans), Hydrotaea spp., Warble fly (Hypoderma bovis), Common cattle grub (Hypoderma lineatum), Hypoderma spp., Black gnat (Leptoconops nipponensis), Lipoptena capreoli, Lipoptena cervi, Lipoptena spp., Cabbage leafminer (Liriomyza brassicae), Tomato leafminer (Liriomyza bryoniae), Stone leek leafminer (Liriomyza chinensis), Pea leafminer (Liriomyza huidobrensis), Tomato leafminer (Liriomyza sativae), Serpentine leafminer (Liriomyza trifolii), Australian sheep blowfly (Lucilia cuprina), Green bottle fly (Lucilia illustris), Common green bottle fly (Lucilia sericata), Lucilia spp., Lutzomyia spp.), Hessian fly (Mayetiola destructor), Sheep ked (Melophagus ovinus), Melophagus spp., Sweat fly (Morellia simplex), Morellia spp., Face fly (Musca autumnalis), Housefly (Musca domestica), Musca spp., Australian bush fly (Musca vetustissima), Odagmia ornate, Odagmia spp., Sheep nasal bot fly (Oestrus ovis), Oestrus spp., Beet leaf miner miner (Pegomya cunicularia), Philipomyia spp., Phlebotomus longipalpis, Phlebotomus papatasi, Sandfly (Phlebotomus spp.), Black blow fly (Phormia regina), Yellow-legged fly (Prosimulium yezoensis), Northern blowfly (Protophormia terraenovae), Przhevalskiana silenus, Apple maggot (Rhagoletis pomonella), Rhinoestrus spp., Flesh fly (Sarcophaga carnaria), Flesh fly (Sarcophaga peregrina), Sarcophaga spp., Black fly (Simulium oCHraceum), Simulium reptans, Black fly (Simulium spp.), Orange wheat blossom midge (Sitodiplosis mosellana), Stable fly (Stomoxys calcitrans), Stomoxys spp., Tabanus atratus, Tabanus bromius, Greenhead horse fly (Tabanus nigrovittatus), Tabanus spodopterus, Tabanus spp., Tabanus sudeticus, Horse fly (Tabanus trigonus), Moth fly (Telmatoscopus albipunctatus), Tipula paludosa, Tipula spp. spp.), Wilhelmia equine, Wilhelmia spp., Wohlfahrtia spp., etc. Hemiptera: Green stink bug (Acrosternum hilare), Pea aphid (Acyrthosiphon pisum), Camellia spiny whitefly (Aleurocanthus camelliae), Orange spiny whitefly (Aleurocanthus spiniferus), Indian cotton leafhopper (Amrasca devastans), California red scale (Aonidiella aurantii), Cowpea aphid (Aphis craccivora), Black bean aphid (Aphis fabae), Soybean aphid (Aphis glycines), Cotton aphid (Aphis gossypii) gossypii), Green apple aphid (Aphis pomi), Spiraea aphid (Aphis spiraecola), Pale greenplant bug (Apolygus spinolae), Grape leafhopper (Arboridia apicalis), Foxglove aphid (Aulacorthum solani), Beardsley leafhopper (Balclutha saltuella), Silverleaf whitefly (Bemisia argentifolii), Sweetpotato whitefly (Bemisia tabaci), True CHinCH bug (Blissus leucopterus), Leafcurl plum aphid Aphid (BraCHycaudus heliCHrysi), Radish aphid CabbageAphid (Brevicoryne brassicae), Oriental CHinCH bug (Cavelerius sacCHarivorus), Indian wax scale bug (Ceroplastes ceriferus), Red wax scale bug (Ceroplastes rubens), Walnut aphid (CHromaphis juglandicola), Bed bug (Cimex lectularius), Rice stink bug (Cletus punctiger), Citricola scale bug (Coccus pseudomagnoliarum), San jose scale bug (Comstockaspis perniciosa), Citrus whitefly (Dialeurodes citri), Asian citrus psyllid (Diaphorina citri), stinkbag (DiCHelops furcatus), Russian wheat aphid (Diuraphis noxia), spotted stink bug (Dolycoris baccarum), giant margarodid scale (DrosiCHa corpulenta), rosy apple aphid (Dysaphis plantaginea), red cotton bug (Dysdercus cingulatus), potato leafhopper (Empoasca fabae), persimmon leafhopper (Empoasca nipponica), tea green leafhopper (Empoasca onukii), bean's smaller leafhopper Green leafhopper (Empoasca sakaii), GrapeLeafhopper (Epiacanthus stramineus), Wooly apple aphid (Eriosoma lanigerum), Cabbage bug (Eurydema rugosa), Brown stink bug (EusCistus servus), White-spotted spined bug (Eysarcoris aeneus), Large-spotted spiny stink bug (Eysarcoris lewisi), White-spotted stink bug (Eysarcoris ventralis), Tea scale (Fiorinia theae), Shield bug (Glaucias subpunctatus), Island fleahopper (Halticus insularis), Brown marmorated stink bug (Halyomorpha halys), Mealy plum aphid (Hyalopterus pruni), Cottony cushion scale (Icerya purCHasi), Small brown planthopper (Laodelphax striatellus), Rice bug (Leptocorisa CHinensis), Turnip aphid (Lipaphis erysimi), Western tarnished plant bug (Lygus hesperus), Tarnished plant bug (Lygus lineolaris), Potato aphid (Macrosiphum euphorbiae), Aster Grape leafhopper (Macrosteles fascifrons), Grape leafhopper (Macrostelesstriifrons), Sugarcane spittlebug (Mahanarva fimbriolata), Blackmargined aphid (Monellia caryella), Green pea aphid (Myzus persicae), Lettuce aphid (Nasonovia ribisnigri), Onion aphid (Neotoxoptera formosana), Green rice leafhopper (Nephotettix cincticeps), Eastern green stink bug (Nezara antennata), Southern green stink bug (Nezara viridula), Brown rice planthopper (Nilaparvata lugens), Squash bug (Paradasynus spinosus), Cotton mealy bug (Phenacoccus solani), Redbanded stink bug (Piezodorus guildinii), Redbanded shield bug (Piezodorus hybneri), Citrus mealy bug (Planococcus citri), Japanese mealy bug (Planococcus kraunhiae), Brown-winged green bug (Plautia crossota), Peony scale (Pseudaonidia paeoniae), Cotton fleahopper (Pseudatomoscelis seriatus), Mulberry scale (Pseudaulacaspis pentagona), plum scale White peaCHScale (Pseudaulacaspis prunicola), Comstock mealybug (Pseudococcus comstocki), Grape mealybug (Pseudococcus maritimus), Pear sucker (Psylla pyrisuga), Blood-sucking bug (Rhodnius prolixus), Bird cherry-oat aphid (Rhopalosiphum padi), Rice root aphid (Rhopalosiphum rufiabdominalis), Rhopalid bug (Rhopalus maculatus), Bean bug (Riptortus clavatus), Greenbug (SCHizaphis graminum), Japanese rice black stink bug Black rice bug (Scotinophora lurida), Corn leaf aphid (Sitobion akebiae), English grain aphid (Sitobion avenae), White-backed rice planthopper (Sogatella furcifera), Rice stink bug (Stenodema sibiricum), Sorghum plant bug (Stenotus rubrovittatus), Azalea lace bug (Stephanitis pyrioides), Seed bug (Togo hemipterus), Black citrus aphid (Toxoptera aurantii), Brown citrus aphid (Toxoptera citricida), Greenhouse whitefly whitefly(Trialeurodesvaporariorum), Mexican kissing bug (Triatoma dimidiata), Brazilian kissing bug (Triatoma infestans), rice leaf bug (Trigonotylus caelestialium), false yanon scale (Citrus snow scale) (Unaspis citri), Euonymus scale (Unaspis euonymi), Yanon scale (Unaspis yanonensis), grape aphid (Grape phylloxera) (Viteus vitifolii), etc. Thysanoptera: Flower thrips (Frankliniella intonsa), Western flower thrips (Frankliniella occidentalis), Greenhouse thrips (Heliothrips haemorrhoidalis), Japanese gall-forming thrips (Ponticulothrips diospyrosi), Yellow tea thrips (Scirtothrips dorsalis), Melon thrips (Thrips palmi), Onion thrips (Thrips tabaci), etc. Orthoptera: Australian plague locust (CHortoicetes terminifera), Oriental mole cricket (Gryllotalpa orientalis), Migratory locust (Locusta migratoria), Lesser paddy grasshopper (Oxya japonica), Rice grasshopper (Oxya yezoensis), Desert locust (SCHistocerca gregaria), Emma field cricket (Teleogryllus emma), etc. Order Blattola (Dictyoptera): German cockroach (Blattella germanica), Formosan subterranean termite (Coptotermes formosanus), Daikoku dry-wood termite (Cryptotermes domesticus), Western dry-wood termite (Incisitermes minor), Black-winged subterranean termite (Odontotermes formosanus), American cockroach (Periplaneta americana), Smoky-brown cockroach (Periplaneta fuliginosa), Japanese cockroach (Periplaneta japonica), Japanese subterranean termite (Reticulitermes speratus), etc. Isoptera: Coptotermes formosanus (Coptotermes formosanus), Reticulitermes speratus (Reticulitermes speratus), Odontotermes formosanus (Odontotermes formosanus), etc. Acari: Cyclamen mite (Phytonemus pallidus), Broad mite (Polyphagotarsonemus latus), Tarsonemus bilobatus (Tarsonemus bilobatus), Chinese cabbage mite (Penthaleus erythrocephalus), Winter grain mite (Penthaleus major), Rice spider mite (OligonyCHus shinkajii), Citrus red mite (PanonyCHus citri), Mulberry red mite (PanonyCHus mori), European red mite (PanonyCHus ulmi), Kanzawa spider mite (TetranyCHus kanzawai), Two-spotted spider mite (Tetranychus urticae), Tea long-spotted rust mite (Acaphylla theavagrans), Tulip rust mite (Aceria tulipae), Tomato erineum mite (Aculops lycopersici), Pink citrus rust mite (Aculops pelekassi), Apple rust mite (Aculus sCHleCHtendali), Pear rust mite (Eriophyes CHibaensis), Citrus rust mite (Phyllocoptruta oleivora), Robin bulb mite (Rhizoglyphus robini), Mold mite (Tyrophagus putrescentiae), spinach mite Tyrophagus similis (Tyrophagussimilis, Acarapis spp., Honey bee tick (Acarapis woodi), Acarus spp., Lone star tick (Amblyomma americanum), Cayenne tick (Amblyomma cajennense), South African bont tick (Amblyomma hebraeum), Gulf coast tick (Amblyomma maculatum), Amblyomma spp., Tropical bont tick (Amblyomma variegatum), Fowl tick (Argas persicus), Pigeon tick (Argas reflexus), Argas spp., Blue cattle tick (Boophilus annulatus, Boophilus calceratus, African blue tick (Boophilus decoloratus), Tropical cattle tick (Boophilus microplus), Boophilus spp., Caloglyphus spp., Chelacaropsis moorei, Cat tick (CHeyletiella blakei), Rabbit fur mite (CHeyletiella parasitovorax), Cheyletiella spp., Dog tick (CHeyletiella yasguri), Cheyletus eruditus, Stag tick (CHeyletus malaccensis), and Cattle mite (CHorioptic mange) Mite (CHorioptes bovis), Chorioptes species (CHorioptesspp.), Cytodites spp., Cattle follicle mite (Demodex bovis), Demodex caballi, Dog follicle mite (Demodex canis), Demodex caprae, Cat follicle mite (Demodex cati), Demodex equi, Face mite (Demodex folliculorum), Demodex ovis, Demodex spp., Sarcoptes suis mite (Demodex suis), Winter tick (Dermacentor albipictus), Rocky Mountain wood tick (Dermacentor andersoni), Ornate sheep tick tick (Dermacentor marginatus), meadow tick (Dermacentor pictus), ornate dog tick (Dermacentor reticulatus), Dermacentor spp., American dog tick (Dermacentor variabilis), poultry red mite (Dermanyssus gallinae), Dermacentor spp., American house dust mite (Dermatophagoides farina), house dust mite (Dermatophagoides pteronyssinus), Asian chigger (Eutrombicula wiCHmanni), storage mite (Glycyphagus destructor), house itCH mite (Glycyphagusdomesticus, Haemaphysalis cinnabarina, Common rodent tick (Haemaphysalis concinna), Yellow dog tick (Haemaphysalis leaCHi), Bush tick (Haemaphysalis longicornis), Haemaphysalis otophila, Red sheep tick (Haemaphysalis punctate), Haemophysalis spp., House mite (HaploCHthonius simplex), Trombiculid mite (Helenicula miyagawai), Tortoise tick (Hyalomma aegyptium), Hyalomma anatolicum anatolicum, Bont-legged tick (Hyalomma marginatum), Hyalomma mauritanicus, Hyalomma spp., Small smooth bont-legged tick (Hyalomma transiens), Hypodectes spp., Dog tick (Ixodes canisuga), Hedgehog tick (Ixodes hexagonus), Australian paralysis tick (Ixodes holocyclus), Western black-legged tick (Ixodes pilosus), Castor bean tick (Ixodes ricinus), Karoo paralysis tick (Ixodes rubicundus, Deer tick (Ixodes scapularis), Ixodes speciesspp.), Knemidocoptes spp., Laminosioptes spp., Leptotrombidium akamushi, Leptotrombidium pallida, Tsutsugamushi mite (Leptotrombidium scutellare), Listrophorus spp., Feather mite (Megninia cubitalis), Myobia spp., NeosCHoengastia xerothermobia, Harvest mite (Neotrombicula autumnalis), Neotrombicula desaleri, Cat mange Mite (Notoedres cati), Notoedres spp., OrnithoCHeyletia spp., Soft tick (Ornithodorus moubata), Ornithodorus spp., Tropical fowl mite (Ornithonyssus bursa), Ornithonyssus spp., Northern fowl mite (Ornithonyssus sylviarum), Spinose ear tick (Otobius megnini), Otobius spp., Dog ear mite (Otodectes cynotis), Otodectes spp., Canine nasal mite mite (Pneumonyssoides caninum), Pneumonyssoides mange, Pneumonyssus spp., Pneumonyssus spp., Psorergatesspp.), Psoroptic mite (Psoroptes communis), Rabbit ear mite (Psoroptes cuniculi), Psoroptes equi, Sheep scab mite (Psoroptes ovis), Psoroptes ovis, Psoroptes spp., Feather mite (PteroliCHus obtusus), PteroliCHus spp., Raillietia spp., Brown ear tick (Rhipicephalus appendiculatus), Brown ear tick (Rhipicephalus bursa, Rhipicephalus capensis, Asian blue tick (Rhipicephalus evertsi), Kennel tick (Rhipicephalus sanguineus), Rhipicephalus spp., Rhipicephalus turanicus, Rhipicephalus zambeziensis, Sarcoptes bovis, Sarcoptes equi, Sarcoptes ovis, Sarcoptes rupicaprae (=S. caprae), ItCH mite (Sarcoptes scabiei, Sarcoptes spp., Sarcoptes suis, ItCH mite (Sarcoptis canis), Sternostoma spp., Trombicula akamushi, Trombicula spp.spp.), Cheese mite (Tyrophagus putrescentiae), Tyrophagus species (Tyrophagus spp.), Varroa mite (Varroa jacobsoni), Varroa species (Varroa spp.), etc. Order Anoplurida: Short-nosed cattle louse (Haematopinus eurysternus), Tail switch louse (Haematopinus quadripertusus), Pig louse (Haematopinus spp.), Large pig louse (Haematopinus suis), Buffalo louse (Haematopinus tuberculatus), Rabbit louse (Haemodipsus ventricosus), Dog sucking louse (Linognathus setosus), Linognathus spp., Long-nosed cattle louse (Linognathus vituri), Head louse (Pediculus humanus), Pediculus spp., Mouse louse (Polyplax serratus), Crab louse (Pthirus pubis), Pthirus spp., Little blue cattle louse (Solenopotes capillatus), Solenopotes spp., etc. Mallophaga: Goat biting louse (Bovicola caprae), Bovicola limbata, Sheep body louse (Bovicola ovis), Bovicola spp., Chicken head louse (Cuclotogaster heterographa), Cattle chewing louse (Damalinia bovis), Felicola spp., Cat louse (Felicola subrostrata), Brown chicken louse (Goniodes dissmilis), Fluff louse (Goniodes gallinae), Large hen louse (Goniodes gigas), Lepikentron ovis, Lepikentron spp., Chicken Wing louse (Lipeurus caponis), Chicken Body louse (Menacanthus cornutus), Chicken Small body louse (Menacanthus pallidulus), Menacanthus spp., Chicken body louse (Menacanthus stramineus), Chicken shaft louse (Menopon gallinae), Menopon spp., Dog biting louse (TriCHodectes canis), Chicken flea louse (TriCHodectes spp.), Werneckiella equi, Werneckiella spp., etc. Siphonaptera: Chicken flea (Ceratophyllus gallinae), Dog flea (Ctenocephalides canis), Cat flea (Ctenocephalides felis), Sticktight flea (ECHidnophaga gallinacean), Human flea (Pulex irritans), CHigoe flea (Tunga penetrans), Oriental rat flea (Xenopsylla CHeopis), etc. Other parasites include Monogenea; Benedenia epinepheli, Benedenia hoshinai, Benedenia sekii, Benedenia seriolae, Bivagina tai, sea louse (Caligus curtus), Caligus elongates, Caligus labaracis, Caligus longipedis, Caligus orientalis, Caligus teres, Dactylogyrus spp., Gyrodactylus spp. spp.), Heteraxine heterocerca, Heterobothrium okamotoi, Lamellodiscus spp., copepod (Lepeophtheirus cuneifer), Lepeophtheirus hippoglossi, Lepeophtheirus pectoralis, salmon louse (Lepeophtheirus salmonis), Microcotyle sebastis, Microcotyle sebastisci, Neobenedenia, Neobenedenia congeri, Neobenedenia girellae, Neoheterobothrium hirame, Polystoma spp., Pseudocaligus fugu, Zeuxapta japonica, etc. Tapeworms (Cestoda): Andyra spp., Anoplocephala spp., Avitellina spp., Bertiella spp., Bothridium spp., Cittotaenia spp., Davainea spp., DiorCHis spp., Manson's tapeworm (Diphyllobothrium erinacei), fish tapeworm (Diphyllobothrium latum), Diphyllobothrium spp., Diphyllogonoporus spp., Diplopylidium spp., dog tapeworm Tapeworm (Dipylidium caninum), Dipylidium spp., dog tapeworm (ECHinococcus granulosus), fox tapeworm (ECHinococcus multilocularis), Echinococcus spp., Echinococcus spp., Echinoctyle spp., Echinolepsis spp., Hydatigera spp., Hymenolepis diminuta, Hymenolepis spp., Joyeuxiella spp., Ligura spp., Mesocestoides spp., Moniezia benedeni, Moniezia spp., Paranoplocephala spp., Raillietina spp., SCHistocephalus spp., Spirometra spp., Stilesia spp.), including the beef tapeworm (Taenia saginata), the pork tapeworm (Taenia solium), the cat tapeworm (Taenia taeniaeformis), the thysaniezia spp., and the thysanosomsa spp., etc. Trematoda: Austrobilharzia spp., BraCHylaema spp., Calicophoron spp., Catatropis spp., Chinese river fluke (ClonorCHis sinensis), ClonorCHis spp., Collyriclum spp., Cotylophoron spp., Cyclocoelum spp., Dicrocoelium spp., Diplostomum spp., ECHinoCHasmus spp., ECHinoparyphium spp. spp.), ECHinostoma spp., Eurytrema coelomaticum, Eurytrema pancreaticum, Eurytrema spp., Fasciola gigantica, Fasciola hepatica, Fasciola spp., Fasciolides spp., Fasciolopsis bruski, Fasciolopsis spp., FisCHoederius spp., Gastrothylacus spp. spp.), Gigantobilharzia spp., Gigantocotyle spp., Heterophyes spp., Hypoderaeum spp., LeucoCHloridium spp., Metagonimus spp., MetorCHis spp.), Nanophyetus spp., Notocotylus spp., Opisthorchis spp., Ornithobilharzia spp., Paragonimus spp., Oriental lung fluke (Paragonimus westermani), Paramphistomum spp., Plagiorchis spp., Posthodiplostomum spp., Prosthogonimus spp., Schistosoma haematobium, Schistosoma japonicum, Schistosoma mansoni mansoni, Schistosoma spp., TriCHobilharzia spp., Troglotrema spp., Typhlocoelum spp., etc., Nematoda; Aelurostrongylus spp., Amidostomum spp., Ancylostoma spp., Angiostrongylus spp., Anisakis spp., Ascaridia galli, Ascaridia spp., Ascaris spp., Ascaris suum, Aspiculuris spp. spp.), Brugia spp., Bunostomum spp., Capillaria spp., Chabertia spp., Cooperia oncophora intestinal worm, Cooperia spp., Crenosoma spp., Cyathostoma spp.), Cyclococcus spp., Cylicostephanus spp., Cylindropharynx spp., Cystocaulus spp., Dictyocaulus spp., Dirofilaria immitis, Dirofilaria spp., Dracunculus spp., DrasCHia spp., Elaphostrongylus spp., Enoplida spp., Enterobius spp., Filaroides spp., Filicollis spp. spp.), Globocephalus spp., Gnathostoma spp., Gongylonema spp., Gyalocephalus spp., Habronema spp., Barber's pole worm (HaemonCHus contortus), HaemonCHus spp., Heterakis spp., Hyostrongylus spp., Litomosoides spp., Loa spp., Macracanthorhynx spp., Marshallagia spp., Metastrongylus spp. spp.), Micronema spp., Moniliformis spp., Muellerius spp., Nematodirus spp., Neostrongylus spp., Obeliscoides spp.), pig stomatal nodule worm (Oeophagostomum dentatum), Oesophagodontus spp., cattle stomatal nodule worm (Oesophagostomum radiatum), stomatal nodule worm spp., Ollulanus spp., Gibson's heartworm (OnCHocerca gibsoni), Onchocerca spp., Brown stomatal worm (Ostertagia ostertagi), Ostertagia spp., Oxyuris spp., Parabronema spp., Paraacrenosoma spp., Parafilaria spp. spp.), Parafilaroides spp., Parascaris spp., Parelaphostrongylus spp., Passalurus spp., Physaloptera spp., Pneumostrongylus spp., Poteriostomum spp., ProstenorCHis spp., Protostrongylus spp., Setaria spp., Spicocaulus spp., Stephanofilaria spp., Stephanurus spp. spp.), Strongyloides spp., Strongylus spp., Syngamus spp., Syphacia spp., Thelazia spp., Toxascaris spp., Toxocara spp., TriCHinella spp., TriCHomosoides spp.), TriCHonema spp., ruminant nematode TriCHostrongylus colubriformis, TriCHostrongylus spp., Enoplus spp., Triodontophorus spp., Uncinaria spp., WuCHereria spp., etc. Protozoa: Babesia spp., Eimeria acervulina, Eimeria bovis, Eimeria brunette, Eimeria maxima, Eimeria necatrix, Eimeria ovinoidalis, Eimeria spp., Eimeria tenella, Entamoeba histolytica, Giardia spp., Histomanas spp., Plasmodium spp., Theileria spp. spp.), Toxoplasma spp., TriCHomonadidae spp., Trypanosomsa cruzi, etc.
[0077] Furthermore, the composition and method of the present invention are also effective against pests that have developed resistance to existing insecticides such as organophosphorus compounds, carbamate compounds, and pyrethroid compounds.
[0078] That is, the composition and method of the present invention can effectively control pests belonging to the orders of Collembola, Dictyoptera (Bockroaches), Orthoptera (Orthoptera), Termitida, Thysanoptera (Thysanoptera), Hemiptera (Hemiptera and Cicadellida), Lepidoptera (Lepidoptera), Coleoptera (Coleoptera), Hymenoptera (Hymenoptera), Diptera (Flea Bugs), Isoptera (Flea Pits), and Phthiraptera, as well as crustaceans such as Lepidoptera, Cyprinodontida, and Cyclopida, as well as mites, gastropods, cestodes, trematodes, nematodes, and protozoa, even at low concentrations.
[0079] On the other hand, the composition and method of the present invention have the extremely useful feature of having almost no adverse effect on mammals, fish, crustaceans, and beneficial insects (useful insects such as honeybees and bumblebees, and natural enemies such as aster wasps, oil wasps, parasitic flies, orthoptera, and phytoseiid mites).
[0080] The composition of the present invention can be used as a mixture of active ingredient A, which is a first active ingredient, and active ingredient B, which is a second active ingredient, as is. However, it is usually mixed with an appropriate solid or liquid carrier, and, if desired, surfactants, penetrants, spreaders, thickeners, antifreeze agents, binders, anticaking agents, disintegrants, antifoaming agents, preservatives, antidegradants, and the like may be added to form the composition into any dosage form, such as a soluble concentrate, emulsifiable concentrate, wettable powder, water-soluble powder, water-dispersible granules, water-soluble granules, suspension concentrate, concentrated emulsion, suspoemulsion, microemulsion, dustable powder, granule tablet, or emulsifiable gel. Furthermore, from the viewpoint of labor saving and improved safety, the above-mentioned formulations in any dosage form can be provided by being enclosed in a water-soluble package such as a water-soluble capsule or a bag made of a water-soluble film.
[0081] Examples of solid carriers include natural minerals such as quartz, calcite, sepiolite, dolomite, chalk, kaolinite, pyrophyllite, sericite, halloysite, metahaloysite, kibushi clay, gairome clay, pottery stone, ziglite, allophane, shirasu, kira, talc, bentonite, activated clay, acid clay, pumice, attapulgite, zeolite, and diatomaceous earth; calcined products of natural minerals such as calcined clay, perlite, shirasu balloon, vermiculite, attapulgus clay, and calcined diatomaceous earth; magnesium carbonate, calcium carbonate, sodium carbonate, Examples of suitable inorganic salts include sodium bicarbonate, ammonium sulfate, sodium sulfate, magnesium sulfate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, and potassium chloride; sugars such as glucose, fructose, sucrose, and lactose; polysaccharides such as starch, powdered cellulose, and dextrin; organic substances such as urea, urea derivatives, benzoic acid, and salts of benzoic acid; plants such as wood flour, cork powder, corn cobs, walnut shells, and tobacco stalks; fly ash, white carbon (e.g., hydrated synthetic silica, anhydrous synthetic silica, hydrated synthetic silicate, etc.), and fertilizers.
[0082] Examples of liquid carriers include xylene, alkyl (C9 or C 10Aromatic hydrocarbons such as benzene, phenylxylylethane, alkyl (C1 or C3, etc.) naphthalene; aliphatic hydrocarbons such as machine oil, normal paraffin, isoparaffin, naphthene; mixtures of aromatic and aliphatic hydrocarbons such as kerosene; alcohols such as ethanol, isopropyl alcohol, cyclohexanol, phenoxyethanol, benzyl alcohol; polyhydric alcohols such as ethylene glycol, propylene glycol, diethylene glycol, hexylene glycol, polyethylene glycol, and polypropylene glycol; ethers such as propyl cellosolve, butyl cellosolve, phenyl cellosolve, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, and propylene glycol monophenyl ether; ketones such as acetophenone, cyclohexanone, and γ-butyrolactone; esters such as fatty acid methyl esters, dialkyl succinate esters, dialkyl glutamate esters, dialkyl adipate esters, and dialkyl phthalate esters; N-alkyl (C1, C8, or C 12 acid amides such as pyrrolidone; oils and fats such as soybean oil, linseed oil, rapeseed oil, palm oil, cottonseed oil, castor oil; dimethyl sulfoxide, water; and the like.
[0083] These solid carriers and liquid carriers may be used alone or in combination of two or more.
[0084] Examples of surfactants include nonionic surfactants such as polyoxyethylene alkyl ethers, polyoxyethylene alkyl (mono- or di-)phenyl ethers, polyoxyethylene (mono-, di-, or tri-)styrylphenyl ethers, polyoxyethylene polyoxypropylene block copolymers, polyoxyethylene fatty acid (mono- or di-)esters, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, castor oil ethylene oxide adducts, acetylene glycol, acetylene alcohol, ethylene oxide adducts of acetylene glycol, ethylene oxide adducts of acetylene alcohol, and alkyl glycosides; alkyl sulfate ester salts, alkylbenzene sulfonates, lignin sulfonates, alkyl sulfosuccinates, and naphthalene anionic surfactants such as alkyl phenyl ether sulfonates, alkyl naphthalene sulfonates, salts of formalin condensates of naphthalene sulfonic acid, salts of formalin condensates of alkyl naphthalene sulfonic acid, polyoxyethylene alkyl ether sulfates or phosphate ester salts, polyoxyethylene (mono- or di-) alkyl phenyl ether sulfates or phosphate ester salts, polyoxyethylene (mono-, di-, or tri-) styryl phenyl ether sulfates or phosphate ester salts, polycarboxylates (for example, polyacrylates, polymaleates, copolymers of maleic acid and olefins, etc.), and polystyrene sulfonates; cationic surfactants such as alkylamine salts and alkyl quaternary ammonium salts; amphoteric surfactants such as amino acid types and betaine types; silicone-based surfactants; and fluorine-based surfactants.
[0085] The content of these surfactants is not particularly limited, but is generally in the range of 0.05 to 20 parts by mass per 100 parts by mass of the formulation of the present invention. These surfactants may be used alone or in combination of two or more. The application amounts of the composition and method of the present invention will vary depending on the type of target pest to be controlled, the application site, application time, application method, cultivated crop, etc., but typically, the appropriate amount is approximately 0.005 to 50 kg per hectare (ha) of active ingredient A and approximately 0.005 to 50 kg per hectare (ha) of active ingredient B.
[0086] Next, examples of formulations using the composition of the present invention are shown. However, the formulation examples of formulations containing the composition of the present invention are not limited to these. In the following formulation examples, "parts" means parts by mass. "Active ingredient" is a collective term for active ingredient A, which is the first active ingredient of the composition of the present invention, and active ingredient B, which is the second active ingredient.
[0087] [Wettable powder] Active ingredient 0.1~80 parts Solid carrier 5 to 98.9 parts Surfactant 1 to 10 parts Others 0-5 Other examples include anti-caking agents, anti-decomposition agents, etc.
[0088] 〔emulsion〕 Active ingredient 0.1~30 parts 45-95 parts liquid carrier Surfactant 4.9 to 15 parts Others 0-10 Other examples include spreading agents, anti-decomposition agents, etc.
[0089] [Suspension agent] Active ingredient 0.1~70 parts 15 to 98.89 parts liquid carrier Surfactant 1 to 12 parts Other 0.01 to 30 copies Other examples include antifreeze agents, thickeners, etc.
[0090] [Water dispersible granules] Active ingredient 0.1~90 parts Solid carrier 0 to 98.9 parts Surfactant 1 to 20 parts Others 0-10 Other examples include binders, anti-decomposition agents, etc.
[0091] [Liquid] Active ingredient 0.01~70 parts 20 to 99.99 parts liquid carrier Others 0-10 Other examples include antifreeze agents, spreading agents, etc.
[0092] [Granules] Active ingredient 0.01~80 parts Solid carrier 10 to 99.99 parts Others 0-10 Other examples include binders, anti-decomposition agents, etc.
[0093] [Powder] Active ingredient 0.01~30 parts Solid carrier 65 to 99.99 parts Others 0-5 Other examples include drift inhibitors and anti-decomposition agents.
[0094] Next, specific formulation examples of preparations containing the composition of the present invention as an active ingredient are shown, but the present invention is not limited to these. Note that the composition of the present invention No. 1-01 shown below refers to N-(4-fluorophenyl)-6-[3-(6-fluoropyridin-3-yl)-4-(trifluoromethyl)phenyl]-4-hydroxy-2-oxo-1,2,5,6-tetrahydropyridine-3-carboxamide described in Synthesis Example 1 below.
[0095] [Mixing Example 1] Wettable powder Compound No.1-01 10 parts Compound No.A01 10 parts 74 parts of pyrophyllite Solpol 5039 4 parts (Product name of Toho Chemical Industry Co., Ltd., a mixture of nonionic surfactants and anionic surfactants) Carplex #80D Part 2 (Shionogi & Co., Ltd. product name, synthetic hydrous silica) The above ingredients are uniformly mixed and pulverized to prepare a wettable powder.
[0096] [Formulation Example 2] Emulsion Compound No.1-01 6 parts Compound No.A01 4 parts 70 parts xylene N-methylpyrrolidone 15 parts 5 parts of Solpol 2680 (Product name of Toho Chemical Industry Co., Ltd., a mixture of nonionic surfactants and anionic surfactants) The above ingredients are mixed uniformly to form an emulsion.
[0097] [Formulation Example 3] Suspension agent Compound No.1-01 15 parts Compound No.A01 10 parts Agrisol S-710 10 parts (Kao Corporation product name, non-ionic surfactant) Lunox 1000C 0.5 parts (Product name of Toho Chemical Industry Co., Ltd., anionic surfactant) Xanthan gum 0.2 parts Water 64.3 parts After the above ingredients are mixed uniformly, they are wet-pulverized to form a suspension.
[0098] [Mixing Example 4] Granular water dispersible agent Compound No.1-01 40 parts Compound No.A01 35 parts High Tenor NE-15 5 parts (Dai-ichi Kogyo Seiyaku Co., Ltd. product name, anionic surfactant) Vanilex N 10 parts (Nippon Paper Industries product name, anionic surfactant) Carplex #80D 10 copies (Shionogi & Co., Ltd. product name, synthetic hydrous silica) After the above ingredients are uniformly mixed and pulverized, a small amount of water is added and the mixture is stirred and mixed, granulated in an extrusion granulator, and dried to give water dispersible granules.
[0099] [Formulation example 5] Granules Compound No.1-01 3 parts Compound No.A01 2 parts 50 parts bentonite Talc 45 parts After the above ingredients are uniformly mixed and pulverized, a small amount of water is added and the mixture is stirred and mixed, granulated in an extrusion granulator, and dried to give granules.
[0100] [Mixing Example 6] Powder Compound No.1-01 2 parts Compound No.A01 1 part Carplex #80D 0.5 parts (Shionogi & Co., Ltd. product name, synthetic hydrous silica) 95 parts kaolinite Diisopropyl phosphate 1.5 parts The above ingredients are mixed and pulverized uniformly to obtain a powder.
[0101] When used, the above formulation is diluted 1 to 10,000 times with water, or sprayed directly without dilution.
[0102] [Formulation Example 7] Wettable powder preparation Compound No.1-01 15 parts Compound No.A01 10 parts Sodium diisobutylnaphthalene sulfonate 1 part Calcium n-dodecylbenzenesulfonate 10 parts Alkylaryl polyglycol ether 12 parts Sodium salt of naphthalenesulfonic acid formalin condensate 3 parts 1 part emulsion silicone Silicon dioxide 3 parts 45 parts kaolin [Formulation Example 8] Water-soluble thickener preparation Compound No.1-01 10 parts Compound No.A01 10 parts Polyoxyethylene lauryl ether 3 parts Dioctyl sodium sulfosuccinate 3.5 parts Dimethyl sulfoxide 37 parts 2-propanol 36.5 parts [Formulation Example 9] Spray liquid Compound No.1-01 1 part Compound No.A01 1 part Dimethyl sulfoxide 10 parts 2-propanol 35 parts 53 parts acetone [Formulation Example 10] Liquid for transdermal administration Compound No.1-01 3 parts Compound No.A01 2 parts Hexylene glycol 50 parts 2-propanol 45 parts [Formulation Example 11] Liquid for transdermal administration Compound No.1-01 3 parts Compound No.A01 2 parts Propylene glycol monomethyl ether 50 parts Dipropylene glycol 45 parts [Formulation Example 12] Liquid for transdermal administration (drops) Compound No.1-01 1 part Compound No.A01 1 part Light liquid paraffin 98 parts [Formulation Example 13] Liquid for transdermal administration (drops) Compound No.1-01 1 part Compound No.A01 1 part Light liquid paraffin 58 parts 30 parts olive oil ODO 9th Division (Nisshin Oillio Group product name, medium-chain fatty acid oil) Shin-Etsu Silicone Division 1 In the present invention, the composition of the present invention containing the first active ingredient, Active Component A, and the second active ingredient, Active Component B, can be formulated and used as described above, but it is also possible to obtain an excellent synergistic control effect by separately preparing agents containing Active Component A and Active Component B as active ingredients and treating or applying these agents simultaneously or closely in time. When applying agents closely in time, it is desirable to wait until the first application has sufficiently dried before applying the next, although this depends on the control means and the target disease to be controlled, etc.
[0103] The composition of the present invention has excellent insecticidal and acaricidal activity against many agricultural pests, spider mites, and internal or external parasites of mammals or birds, and is also effective in controlling pests that have acquired resistance to existing insecticides. Furthermore, it has almost no adverse effects on mammals, fish, and beneficial insects, and is low-residual and has a low environmental impact. Therefore, the present invention can provide a useful novel pest control agent.
[0104] [Example] [Example] Next, in order to clarify the usefulness of the present invention, the following efficacy test examples will be specifically explained, but the present invention is not limited to these examples.
[0105] [Test Example 1] Efficacy test against common cutworm Active ingredient A listed in Tables 1 to 3 and active ingredient B listed in Tables 4 to 18 were each prepared into 10% by weight emulsions according to the above formulation examples. These formulations were diluted with water to the concentrations listed in Tables 19 to 42 to obtain test solutions. Cabbage leaves were immersed in the solutions for 10 seconds. The treated cabbage leaves were then transferred, one per dish, to 7 cm petri dishes lined with filter paper and air-dried. After air-drying, seven third-instar larvae of the common cutworm (Spodoptera litura) were released into each dish. After release, the dishes were placed in a thermostatic chamber at 25°C. Six days after treatment, the number of dead larvae was counted, and the mortality rate was calculated using the following formula. The test was conducted in duplicate.
[0106] Mortality rate (%) = Number of dead insects / Number of tested insects × 100 The results regarding the mortality rate of each chemical solution are shown in Tables 19 to 42 below. [Table 19] TIFF2025174863000011.tif90110
[0107] [Table 20] TIFF2025174863000012.tif90110
[0108] [Table 21] TIFF2025174863000013.tif90110
[0109] [Table 22] TIFF2025174863000014.tif90110
[0110] [Table 23] TIFF2025174863000015.tif90110
[0111] [Table 24] TIFF2025174863000016.tif90110
[0112] [Table 25] TIFF2025174863000017.tif90110
[0113] [Table 26] TIFF2025174863000018.tif90110
[0114] [Table 27] TIFF2025174863000019.tif90110
[0115] [Table 28] TIFF2025174863000020.tif90110
[0116] [Table 29] TIFF2025174863000021.tif90110
[0117] [Table 30] TIFF2025174863000022.tif90110
[0118] [Table 31] TIFF2025174863000023.tif82100
[0119] [Table 32] TIFF2025174863000024.tif82100
[0120] [Table 33] TIFF2025174863000025.tif80100
[0121] [Table 34] TIFF2025174863000026.tif82100
[0122] [Table 35] TIFF2025174863000027.tif82100
[0123] [Table 36] TIFF2025174863000028.tif80100
[0124] [Table 37] TIFF2025174863000029.tif82100
[0125] [Table 38] TIFF2025174863000030.tif82100
[0126] [Table 39] TIFF2025174863000031.tif80100
[0127] [Table 40] TIFF2025174863000032.tif82100
[0128] [Table 41] TIFF2025174863000033.tif82100
[0129] [Table 42] TIFF2025174863000034.tif80100
[0130] [Test Example 2] Efficacy test against green peach aphid larvae Active ingredient A listed in Tables 1 to 3 and active ingredient B listed in Tables 4 to 18 were each prepared into a 10% by mass emulsion in accordance with the above formulation examples. This formulation was diluted with water to the concentrations listed in Tables 43 to 66 to obtain test solutions. A damp filter paper was placed in a glass petri dish with an inner diameter of 3 cm, and cabbage leaves of the same diameter were placed on top of it. Five wingless female adult green peach aphids were released and left overnight to allow green peach aphid larvae to hatch. Immediately before spraying, the female adult green peach aphids were removed, and the solution was uniformly sprayed (2.5 mg / cm) using a spraying device. 2 Six days after the treatment, the number of dead larvae was counted, and the mortality rate was calculated using the formula described in Test Example 1. The test was carried out in duplicate.
[0131] The results regarding the mortality rate of each chemical solution are shown in Tables 43 to 66 below. [Table 43] TIFF2025174863000035.tif107100
[0132] [Table 44] TIFF2025174863000036.tif107100
[0133] [Table 45] TIFF2025174863000037.tif107100
[0134] [Table 46] TIFF2025174863000038.tif107100
[0135] [Table 47] TIFF2025174863000039.tif107100
[0136] [Table 48] TIFF2025174863000040.tif107100
[0137] [Table 49] TIFF2025174863000041.tif107100
[0138] [Table 50] TIFF2025174863000042.tif107100
[0139] [Table 51] TIFF2025174863000043.tif107100
[0140] [Table 52] TIFF2025174863000044.tif107100
[0141] [Table 53] TIFF2025174863000045.tif107100
[0142] [Table 54] TIFF2025174863000046.tif107100
[0143] [Table 55] TIFF2025174863000047.tif107100
[0144] [Table 56] TIFF2025174863000048.tif107100
[0145] [Table 57] TIFF2025174863000049.tif107100
[0146] [Table 58] TIFF2025174863000050.tif107100
[0147] [Table 59] TIFF2025174863000051.tif107100
[0148] [Table 60] TIFF2025174863000052.tif107100
[0149] [Table 61] TIFF2025174863000053.tif107100
[0150] [Table 62] TIFF2025174863000054.tif107100
[0151] [Table 63] TIFF2025174863000055.tif107100
[0152] [Table 64] TIFF2025174863000056.tif107100
[0153] [Table 65] TIFF2025174863000057.tif107100
[0154] [Table 66] TIFF2025174863000058.tif107100
[0155] [Test Example 3] Efficacy test against two-spotted spider mite larvae Five adult female twospotted spider mites were released onto leaf disks (1 cm diameter) prepared in advance from kidney bean leaves and allowed to lay eggs overnight in a thermostatic chamber at 25°C. The following day, the adult female twospotted spider mites were removed from the leaf disks, and the leaf disks were then maintained for five days to allow the eggs to hatch. The day before the chemical treatment, a polystyrene cup (lid diameter 7.5 cm x height 4 cm) was filled with tap water, and a lid with a hole in the center was placed on top of the lid. Filter paper was placed on top of the lid to absorb the tap water. A leaf disk (3 cm diameter) prepared from kidney bean leaves was placed on this filter paper, and the leaf disk with twospotted spider mite larvae prepared as described above was left on top of this filter paper overnight to release the twospotted spider mite larvae. This cup was used as a test container for the following tests.
[0156] Active ingredient A listed in Tables 1 to 3 and active ingredient B listed in Tables 4 to 18 were each prepared into a 10% by mass emulsion in accordance with the above formulation examples. This formulation was diluted with water to the concentrations listed in Tables 67 to 90 to obtain test solutions. Using a spraying device, the spray solution was uniformly sprayed into each test container (2.5 ml / cup). The investigation was carried out 6 days after spraying, and the mortality rate was calculated using the formula described in Test Example 1. The test was conducted in two plots.
[0157] The results regarding the mortality rate of each chemical solution are shown in Tables 67 to 90 below. [Table 67] TIFF2025174863000059.tif71100
[0158] [Table 68] TIFF2025174863000060.tif71100
[0159] [Table 69] TIFF2025174863000061.tif71100
[0160] [Table 70] TIFF2025174863000062.tif71100
[0161] [Table 71] TIFF2025174863000063.tif71100
[0162] [Table 72] TIFF2025174863000064.tif71100
[0163] [Table 73] TIFF2025174863000065.tif71100
[0164] [Table 74] TIFF2025174863000066.tif71100
[0165] [Table 75] TIFF2025174863000067.tif71100
[0166] [Table 76] TIFF2025174863000068.tif71100
[0167] [Table 77] TIFF2025174863000069.tif71100
[0168] [Table 78] TIFF2025174863000070.tif71100
[0169] [Table 79] TIFF2025174863000071.tif71100
[0170] [Table 80] TIFF2025174863000072.tif71100
[0171] [Table 81] TIFF2025174863000073.tif71100
[0172] [Table 82] TIFF2025174863000074.tif71100
[0173] [Table 83] TIFF2025174863000075.tif71100
[0174] [Table 84] TIFF2025174863000076.tif71100
[0175] [Table 85] TIFF2025174863000077.tif71100
[0176] [Table 86] TIFF2025174863000078.tif71100
[0177] [Table 87] TIFF2025174863000079.tif71100
[0178] [Table 88] TIFF2025174863000080.tif71100
[0179] [Table 89] TIFF2025174863000081.tif71100
[0180] [Table 90] TIFF2025174863000082.tif71100
[0181] [Test Example 4] Efficacy test against diamondback moth Active ingredient A listed in Tables 1 to 3 and active ingredient B listed in Tables 4 to 18 were each prepared into 10% by weight emulsions according to the above formulation examples. These formulations were diluted with water to the concentrations listed in Tables 91 to 114 to obtain test solutions. Cabbage leaves were immersed in the solutions for 10 seconds. The treated cabbage leaves were then transferred, one per dish, to 7 cm petri dishes lined with filter paper and air-dried. After air-drying, seven third-instar diamondback moth larvae were released per dish. After release, the dishes were placed in a thermostatic chamber at 25°C. Six days after treatment, the number of dead larvae was counted, and the mortality rate was calculated using the formula described in Test Example 1. The test was conducted in duplicate.
[0182] The results regarding the mortality rate of each chemical solution are shown in Tables 91 to 114 below.
[0183] [Table 91] TIFF2025174863000083.tif46100
[0184] [Table 92] TIFF2025174863000084.tif46100
[0185] [Table 93] TIFF2025174863000085.tif46100
[0186] [Table 94] TIFF2025174863000086.tif46100
[0187] [Table 95] TIFF2025174863000087.tif46100
[0188] [Table 96] TIFF2025174863000088.tif46100
[0189] [Table 97] TIFF2025174863000089.tif46100
[0190] [Table 98] TIFF2025174863000090.tif46100
[0191] [Table 99] TIFF2025174863000091.tif46100
[0192] [Table 100] TIFF2025174863000092.tif46100
[0193] [Table 101] TIFF2025174863000093.tif46100
[0194] [Table 102] TIFF2025174863000094.tif46100
[0195] [Table 103] TIFF2025174863000095.tif45100
[0196] [Table 104] TIFF2025174863000096.tif45100
[0197] [Table 105] TIFF2025174863000097.tif45100
[0198] [Table 106] TIFF2025174863000098.tif45100
[0199] [Table 107] TIFF2025174863000099.tif45100
[0200] [Table 108] TIFF2025174863000100.tif45100
[0201] [Table 109] TIFF2025174863000101.tif45100
[0202] [Table 110] TIFF2025174863000102.tif45100
[0203] [Table 111] TIFF2025174863000103.tif45100
[0204] [Table 112] TIFF2025174863000104.tif45100
[0205] [Table 113] TIFF2025174863000105.tif45100
[0206] [Table 114] TIFF2025174863000106.tif46100
[0207] [Test Example 5] Efficacy test against brown planthoppers Active ingredient A listed in Tables 1 to 3 and active ingredient B listed in Tables 4 to 18 were each prepared into 10% by mass emulsions according to the above formulation examples. These formulations were diluted with water to the concentrations listed in Tables 115 to 138 to obtain test solutions. Rice leaf sheaths were immersed in the solutions for 10 seconds. After air drying, the treated rice leaf sheaths were transferred to one test tube per tube. Seven third-instar brown planthopper larvae were released into each tube, and the tubes were covered with sponge lids. After release, the test tubes were placed in a thermostatic chamber at 25°C. Six days after treatment, the number of dead larvae was counted, and the mortality rate was calculated using the formula described in Test Example 1. The test was conducted in duplicate.
[0208] The results regarding the mortality rate of each chemical solution are shown in Tables 115 to 138 below. [Table 115] TIFF2025174863000107.tif51100
[0209] [Table 116] TIFF2025174863000108.tif51100
[0210] [Table 117] TIFF2025174863000109.tif51100
[0211] [Table 118] TIFF2025174863000110.tif51100
[0212] [Table 119] TIFF2025174863000111.tif51100
[0213] [Table 120] TIFF2025174863000112.tif51100
[0214] [Table 121] TIFF2025174863000113.tif51100
[0215] [Table 122] TIFF2025174863000114.tif51100
[0216] [Table 123] TIFF2025174863000115.tif51100
[0217] [Table 124] TIFF2025174863000116.tif51100
[0218] [Table 125] TIFF2025174863000117.tif51100
[0219] [Table 126] TIFF2025174863000118.tif51100
[0220] [Table 127] TIFF2025174863000119.tif50100
[0221] [Table 128] TIFF2025174863000120.tif50100
[0222] [Table 129] TIFF2025174863000121.tif50100
[0223] [Table 130] TIFF2025174863000122.tif50100
[0224] [Table 131] TIFF2025174863000123.tif50100
[0225] [Table 132] TIFF2025174863000124.tif50100
[0226] [Table 133] TIFF2025174863000125.tif50100
[0227] [Table 134] TIFF2025174863000126.tif50100
[0228] [Table 135] TIFF2025174863000127.tif50100
[0229] [Table 136] TIFF2025174863000128.tif50100
[0230] [Table 137] TIFF2025174863000129.tif50100
[0231] [Table 138] TIFF2025174863000130.tif50100 [Industrial Applicability]
[0232] The composition and method of the present invention can be used to control various pests.
Claims
1. A pesticide composition comprising a compound selected from the following active ingredient A and a compound selected from the following active ingredient B. 1) Active ingredient A: an aryltetrahydropyridine compound of the following formula (1) or a salt thereof. Formula (1): 【Chemistry 1】 [In the formula, Q represents Q-1, Q-2, Q-3, Q-4 or Q-12, 【Chemistry 2】 Z 1 represents a halogen atom, Z 3 is C 1 ~C 6 represents alkyl, J represents J-1 or J-2; 【Transformation 3】 A 1 represents a nitrogen atom, G represents G-1 or G-3; 【Chemistry 4】 Z 2 is a halogen atom or halo(C 1 ~C 6 ) alkyl, R 1 is a halogen atom or halo(C 1 ~C 6 ) alkyl, R 2 represents a hydrogen atom, R 3 represents a hydrogen atom, X represents an oxygen atom; Y represents an oxygen atom; t3 represents an integer of 0, 1, 2 or 3; t4 represents an integer of 0, 1, 2, 3, or 4; and t5 represents an integer of 0, 1, 2, 3, 4 or 5.] or a salt thereof. 2) Active ingredient B: A compound selected from the following active ingredients: Abamectin, acephate, acequinocyl, acetamiprid, acrinathrin, acinonapyr, afidopyropen, afoxolaner, alanycarb, aldicarb, allethrin, alpha-cypermethrin, alpha-endosulfan, amidoflumet, amitraz, azamethiphos, azinphos-ethyl, azinphos-methyl, azocyclotin, Bacillus thuringiensis thuringiensis), bendiocarb, benfluthrin, benfuracarb, bensultap, benzoximate, benzpyrimoxan, beta-cyfluthrin, beta-cypermethrin, bifenazate, bifenthrin, bioallethrin, bioresmethrin smethrin), bistrifluron, bisulflufen, broflanilide, bromopropylate, buprofezin, butocarboxim, carbaryl, carbofuran, carbosulfan, cartap, chinomethionate, chlorantraniliprole,Chlorethoxyfos (chlorethxyfos), chlorfenapyr (chlorfenapyr), chlorfenvinphos (chlorfenvinphos), chlorfluazuron (chlorfluazuron), chlormephos (chlormephos), chlorobenzilate (chlorobezilate), chloroprallethrin (chloroprallethrin), chlorpyrifos (chlorpyrifos), chlorpyrifos-methyl (chlorpyrifos-methyl), chromafenozide (chromafenozide), clofentezine (clofentezine), clothianidin (clothianidin), cyanophos (cyanophos), cyantraniliprole (cyantraniliprole), cybenzoxasulfyl (cybenzoxasulfyl), cyclaniliprole (cyclaniliprole), cycloprothrin (cycloprothrin), cyenopyrafen (cyenopyrafen), cyetpyrafen (cyetpyrafen), cyflumetofen (cyflumet ofen), cyfluthrin, cyhalodiamide, cyhalothrin, cyhexatine, cypermethrin, cyphenothrin, cyproflanilide, cyromazine, deltamethrin, diaclor, diafenthiuron, diazinon diazinon), dichlorvos (dichlorvos), dichloromezotiaz (dicloromezotiaz), dicofol (dicofol), dienochlor (dienochlor), diflovidadin (diflovidazin), diflubenzuron (diflubenzuron), dimefluthrin (dimefluthrin), dimethoate (dimethoate), dimethylvinphos (dimethylvinphos), dipropylidaz (dimpropyridaz), dinotefuran (dinotefuran),Diofenolan, disulfoton, DNOC, d-T-80-phthalthrin, emamectin benzoate, empenthrin, endosulfan, EPN, epsilon-metofluthrin, epsilon-momfluorothrin, esfenvalerate, ethifencarb, ethiprole, etofenprox, etoxazole, etrimfos, Febantel, fenazaquin, fenbutatin oxide oxide), fenitrothion, fenmezoditiaz, fenobucarb, fenothiocarb, fenoxycarb, fenpropathrin, fenpyroximate, fenthion, fenvalerate, fipronil, flometoquin, flonicamid, fluacrylamide, Pyrim (fluacrypyrim), fluazuron (fluazuron), flubendiamide (flubendiamide), fluchlordiniliprole (fluchlorodiniliprole), flucycloxuron (flucycloxuron), flucythrinate (flucythrinate), flufenerim (flufenerim), flufenoxuron (flufenoxuron), flufenprox (flufenprox), flufiprole (flufiprole), fluhexafon (fluhexafon), flumethrin (flumethrin),Flupentiofenox, flupyradifurone, flupyrimin, flupyroxystrobin, fluralaner, fluvalinate, fluxametamide, fonophos, formetanate, formothion, furathiocarb b), gamma-cyhalothrin, halfenprox, halofenozide, heptafluthrin, hexaflumuron, hexythiazox, hydramethylnon, imidacloprid, imiprothrin, indazapyroxamet, indoxa indoxacarb, indoxacarb-MP, isocycloseram, isofenphos, isoflualanam, isoprocarb, isoxathion, kappa-bifenthrin, kappa-tefluthrin, lambda-cyhalothrin, ledpr ona (ledprona), lepimectin (lepimectin), lufenuron (lufenuron), malathion (malathion), meperfluthrin (meperfluthrin), metaflumizone (metaflumizone), metalcarb (metalcarb), metaldehyde (metaldehyde), methacrifos (methacrifos), methamidophos (methamidophos), methidathion (methidathion), methomyl (methomyl), methoprene (methoprene),Methoxychlor, methoxyfenozide, methyl bromide bromide), metofluthrin, milbemectin, momfluorothrin, monocrotophos, muscalure, nicofluprole, nitenpyram, novaluron, noviflumuron, omethoate, oxazosulfyl, oxydemeton-methyl, oxydeprofos, parathion, parathion-methyl, pentachlorophenol, permethrin, phenothrin, phenthoate, phorate, phosalone, phosmet To (phosmet), phosphamidon (phosphamidon), phoxim (phoxim), pioxaniliprole (pioxaniliprole), piperflanilide (piperflanilide), pirimicarb (pirimicarb), pirimiphos - methyl (pirimiphos-methyl), praziquantel (Praziquantel), profenofos (profenofos), profluthrin (profluthrin), propaphos (propaphos), propargite (propargite), prothiofos (prothiofos), protrifenbut (protrifenbute), piflubumide (pyflubumide), pymetrozine (pymetrozine), pyraclofos (pyraclofos), pyrafluprole (pyrafluprole), pyrethrins (pyrethrins), pyridaben (pyridaben), pyridalyl (pyridalyl), pyrifluquinazon (pyrifluquinazon),Pyrimidifen, pyriprole, pyriproxyfen, resmethrin, rotenone, silafluofen, spidoxamat, spinetoram, spinosad, spirobudifen, spirodiclofen, spiromesifen, Spiropidione (spiropidion), spirotetramat (spirotetramat), spiromesifen (spyromesifen), sulfiflumin (sulfiflumin), sulfotep (sulfotep), sulfoxaflor (sulfoxaflor), sulprofos (sulprofos), tau-fluvalinate (tau-fluvalinate), tebufenozide (tebfenozide), tebufenpyrad (tebufenpyrad), teflubenzuron (teflubenzuron), tef Lutrin (tefluthorin), terbufos (terbufos), tetrachlorantraniliprole (tetrachlorantraniliprole), tetrachlorvinphos (tetrachlorvinphos), tetramethrin (tetramethrin), tetramethylfluthrin (tetramethylfluthrin), tetraniliprole (tetraniliprole), thiacloprid (thiacloprid), thiamethoxam (thiamethoxam), thiocyclam (thiocyclam), thiodicarb (thiodicarb), thiofanox (thiofanox), thiometon (thiometon), thioantraniliprole (tiorantraniliprole), tolfenpyrad (tolfenpyrad), tralomethrin (tralomethrin), transfluthrin (transfluthrin), triazamate (triazamate), triazuron (triazuron), trichlorfon (trichlorfon), triflumezopyrim (triflumezopyrim),Triflumuron, tyclopyrazoflor, vamidothion, zeta-cypermethrin.
2. The active ingredient B is selected from the group consisting of chlorpyrifos, phenthoate, bifenthrin, cypermethrin, etofenprox, lambda-cyhalothrin, acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, and the like. yram, Thiacloprid, Thiamethoxam, Sulfoxaflor, Flupyradifurone, Triflumezopyrim, Fenmezoditiaz, Spinetoram, Spinosad, Ethiprole, Fipronil, Broflanilide, Fluxamic acid Fluxametamide, Isocycloseram, Abamectin, Emamectin-Benzoate, Chlorantraniliprole, Cyantraniliprole, Flubendiamide, Cyclaniliprole, Tetraniliprole, Pyridaben ben), Cyenopyrafen, Methoxyfenozide, Lufenuron, Buprofezin, Etoxazole, Benzpyrimoxan, Pymetrozine, Flonicamid, Dimpropyridaz, Spiromesifen, Spirotetramat,2. The pesticide composition according to claim 1, wherein the pesticide is selected from the group consisting of indoxacarb, pyridalyl, amitraz, bifenazate, and flupentiofenox.
3. A method for controlling pests by treating an insecticide with the active ingredient A according to claim 1 and the active ingredient B according to claim 1 or claim 2 simultaneously or in close temporal proximity.
4. 4. The method for controlling pests according to claim 3, which comprises treating seeds with the active ingredient A according to claim 1 and the active ingredient B according to claim 1 or claim 2 simultaneously or in close temporal proximity.
Citation Information
Patent Citations
Aryl tetrahydropyridine derivative or salt thereof, insecticide containing same, and method for use thereof
WO2021261562A1
Aryl tetrahydropyridine derivative or salt thereof, pest control agent containing same, and method for use thereof
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Aryltetrahydropyridine compound and pest control agent
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