Pesticidally active cyclic amine compounds

Abstract

Formula (I) [Formula 1] JPEG2025538608000047.jpg45150 (wherein the substituents are as defined in claim 1) The compounds of formula (I) and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of these compounds can be used as insecticides and acaricides.

Description

[Technical Field]

[0001] The present invention relates to pesticidally effective, in particular insecticidally effective, piperidinyl-pyridinylcarbonyl compounds, processes for their preparation, compositions containing these compounds and their use for controlling animal pests, including arthropods and in particular insects or representatives of the order Acarina. [Background technology]

[0002] WO 2017195703, WO 2019039429, WO 2019082808, JP 2019085371, WO 2021053161, WO 2021160680, WO 2021215393 and WO 2022219146 describe certain piperidinyl-pyridinyl carbonyl compounds for use in controlling plant-damaging pests. Summary of the Invention [Means for solving the problem]

[0003] It has now been found that novel pesticidal active piperidinyl-pyridinyl carbonyl compounds.

[0004] The present invention therefore provides in a first aspect a compound of formula (I) [ka] (In the formula, R 1 is CN or C(=S)NH2, R 2 is H or methyl, R 3 is C1-C2-alkyl, C1-C2-haloalkyl, C3-C6-cycloalkyl, C1-C2-alkoxy-C1-C2-alkyl, R 4 is halogen, C1-C2-haloalkyl, C1-C2-haloalkoxy, -OC 1-2haloalkanediyl-O-; q is 1, 2 or 3 or an agriculturally acceptable salt, enantiomer, tautomer and / or N-oxide of a compound of formula I. DETAILED DESCRIPTION OF THE INVENTION

[0005] The compounds of formula (I) having at least one basic center can form, for example, acid addition salts with strong inorganic acids, such as mineral acids such as perchloric acid, sulfuric acid, nitric acid, nitrous acid, phosphoric acid or hydrohalic acids; with strong organic carboxylic acids, such as unsubstituted or halogen-substituted C1-C4 alkanecarboxylic acids, for example acetic acid; with saturated or unsaturated dicarboxylic acids, for example oxalic acid, malonic acid, succinic acid, maleic acid, fumaric acid or phthalic acid; with hydroxycarboxylic acids, for example ascorbic acid, lactic acid, malic acid, tartaric acid or citric acid; or with benzoic acid; or with organic sulfonic acids, such as unsubstituted or halogen-substituted C1-C4 alkane or arylsulfonic acids, for example methane or p-toluenesulfonic acid. Compounds of formula (I) having at least one acidic group can, for example, form salts with bases, for example mineral salts, for example alkali metal or alkaline earth metal salts, for example sodium, potassium or magnesium salts, or salts with ammonia or organic amines, for example morpholine, piperidine, pyrrolidine, mono-, di- or tri-lower alkylamines, for example ethyl, diethyl, triethyl or dimethylpropylamine or mono-, di- or trihydroxy-lower alkylamines, for example mono-, di- or triethanolamine.

[0006] In each case, the compounds of formula (I) according to the invention are in free form, in oxidized form as N-oxides or in salt form, such as, for example, agriculturally usable salt form.

[0007] N-oxides are the oxidized forms of tertiary amines or nitrogen-containing heteroaromatic compounds, as described, for example, in the book "Heterocyclic N-oxides" by A. Albini and S. Pietra, CRC Press, Boca Raton 1991.

[0008] The compounds of formula (I) according to the invention also include the hydrates which may be formed during salt formation.

[0009] As used herein, "C1-C n The term "-alkyl" refers to any one of saturated alkyl groups, such as methyl and ethyl groups.

[0010] As used herein, "C3-C n The term "-cycloalkyl" refers to 3 to n-membered cycloalkyl groups such as cyclopropane and cyclobutane.

[0011] As used herein, "C1-C n The term "haloC1-C6" refers to a linear or branched saturated alkyl group having 1 to n carbon atoms (as defined above) attached through an oxygen atom, i.e., for example, any one of methoxy and ethoxy groups. n The term "-alkoxy" refers to a C1-C alkyl group in which one or more hydrogen atoms on the alkyl group have been replaced by the same or different halo atoms. n -refers to an alkoxy group, examples of which include trifluoromethoxy, difluoromethoxy, fluoromethoxy, or 2-fluoroethoxy. Two adjacent substituents on a phenyl ring may, together with the carbons of the phenyl ring, form a 5- or 6-membered ring. Examples include -OCF2O- and -OCF2CF2O-.

[0012] Halogen is generally fluorine, chlorine, bromine or iodine. This also applies correspondingly to halogen in combination with other meanings, such as haloalkyl.

[0013] As used herein, "C1-C n The term "-haloalkyl" refers to a straight-chain saturated alkyl group having 1 to n carbon atoms bonded via any of the carbon atoms (as defined above), in which some or all of the hydrogen atoms in these groups may be replaced by fluorine, chlorine, bromine and / or iodine, i.e., any one of, for example, chloromethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2-iodoethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl or pentafluoroethyl. Thus, the term "C1-C2 fluoroalkyl" refers to a C1-C2 alkyl group bearing 1, 2, 3, 4 or 5 fluorine atoms, such as any one of difluoromethyl, trifluoromethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 1,1,2,2-tetrafluoroethyl or pentafluoroethyl.

[0014] As used herein, "C1-C n -Alkoxy-C1~C n The term "-alkyl" refers to C1-C n -refers to an alkyl group substituted with an alkoxy group. Examples are methoxymethyl, methoxyethyl and ethoxymethyl.

[0015] As used herein, "-OC" 1-2 The term "haloalkanediyl-O-" means that adjacent positions on the phenyl ring are -OC 1-2 It means that the oxygen atom of the haloalkanediyl-O- group is connected to the oxygen atom by one to two carbon atoms substituted with one or more halogen atoms. Examples are -OCF2O- and -OCF2CF2O-.

[0016] As used herein, the term "control" refers to reducing the number of pests, eradicating pests and / or preventing further pest damage such that damage to plants or plant-derived products is reduced.

[0017] As used herein, the term "pest" refers to insects and mollusks found in agriculture, horticulture, forestry, storage of plant-derived products (such as fruit, grain, and lumber), and pests associated with damage to man-made structures. The term pest encompasses all stages in the life cycle of a pest.

[0018] As used herein, the term "effective amount" refers to the amount of a compound or salt thereof that produces a desired effect upon one or more applications.

[0019] Effective amounts are readily determined by those skilled in the art by the use of known techniques and by observing results obtained under analogous circumstances. Determining an effective amount takes into account several factors, including, but not limited to, the type of plant or derived product being applied, the pest being controlled and its life cycle, the particular compound being applied, the type of application, and other relevant circumstances.

[0020] Embodiments according to the present invention are provided as described below.

[0021] In an embodiment of each aspect of the invention, R 1 teeth, AC(=S)NH2, or B.CN.

[0022] In an embodiment of each aspect of the invention, R 2 teeth, A. hydrogen, or B. Methyl.

[0023] In an embodiment of each aspect of the invention, R 3 teeth, A. C1-C2-alkyl, C1-C2-haloalkyl, C3-C4-cycloalkyl or C1-C2-alkoxy-C1-C2-alkyl, or B. methyl, ethyl, cyclopropyl, monofluoromethyl, difluoromethyl, trifluoromethyl, methoxymethyl or ethoxymethyl; C. methyl, ethyl, cyclopropyl, monofluoromethyl, difluoromethyl, trifluoromethyl or methoxymethyl; or D. methyl, difluoromethyl, trifluoromethyl or methoxymethyl, or E. Methyl, trifluoromethyl or methoxymethyl.

[0024] In an embodiment of each aspect of the invention, R 4 are independently selected from: A. Fluorine, bromine, chlorine, iodine, trifluoroethyl, trifluoromethyl, difluoromethyl, trifluoromethoxy, difluoromethoxy, -OCF2O- and -OCF2CF2O-, or B. Fluorine, chlorine, bromine, trifluoromethyl, difluoromethyl, difluoromethoxy, trifluoromethoxy and -OCF2O-, or C. Fluorine, trifluoromethyl, trifluoromethoxy and -OCF2O-, or D. Trifluoromethyl and -OCF2O-.

[0025] In an embodiment of each aspect of the invention, q (with respect to halogen, C1-C2-haloalkyl and C1-C2-haloalkoxy) is A.1, 2 or 3, or B.1 and 2, or C.1.

[0026] The present invention therefore provides a compound comprising the substituent R 1 , R 2 , R 3 and R 4In one embodiment, R 1 is embodiment B (i.e., CN), and R 2 is embodiment A (i.e., R 2 is hydrogen), and R 3 is embodiment B (i.e., R 3 is methyl, ethyl, cyclopropyl, monofluoromethyl, difluoromethyl, trifluoromethyl, methoxymethyl or ethoxymethyl), and R 4 is embodiment B (i.e., selected from fluorine, chlorine, bromine, trifluoromethyl, difluoromethyl, difluoromethoxy, trifluoromethoxy, and —OCF2O—, and q is embodiment B (i.e., 1 or 2) with respect to fluorine, chlorine, bromine, trifluoromethyl, difluoromethyl, and trifluoromethoxy), thereby providing a compound of formula I.

[0027] In an embodiment of each aspect of the invention, the compound of formula I is R 1 is cyano or C(=S)NH2, and R 2 is hydrogen or methyl, and R 3 as C1-C2-alkyl, C1-C2-haloalkyl, C3-C4-cycloalkyl or C1-C2-alkoxy-C1-C2-alkyl, and R 4 as independently selected from halogen, C1-C2-haloalkyl and C1-C2-haloalkoxy or -OCF2O-.

[0028] In an embodiment of each aspect of the invention, the compound of formula I is R 1 is cyano or C(=S)NH2, and R 2 is hydrogen or methyl, and R 3 as methyl, ethyl, cyclopropyl, monofluoromethyl, difluoromethyl, trifluoromethyl or methoxymethyl, and R 4as independently selected from fluorine, bromine, chlorine, difluoromethyl, trifluoromethyl, difluoromethoxy and trifluoromethoxy, or —OCF 2 O—.

[0029] In an embodiment of each aspect of the invention, the compound of formula I is R 1 as cyano, R 2 is hydrogen or methyl, and R 3 is methyl, difluoromethyl, trifluoromethyl or methoxymethyl, R 4 as 4-trifluoromethyl or 3-OCF2O-4.

[0030] In an embodiment of each aspect of the invention, the compound of formula I is R 1 as cyano, R 2 is methyl, R 3 is methyl, trifluoromethyl or methoxymethyl, R 4 as 4-trifluoromethyl or 3-OCF2O-4.

[0031] In a second aspect, the present invention provides a composition comprising a compound of formula (I) as defined in the first aspect, one or more adjuvants and diluents, and optionally one or more other active ingredients.

[0032] In a third aspect, the present invention provides a method for combating and controlling insects, acaridae, nematodes or molluscs, which method comprises applying an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound as defined in the first aspect, or a composition as defined in the second aspect, to the pest, the habitat of the pest or plants susceptible to attack by the pest.

[0033] In a fourth aspect, the present invention provides a method of protecting plant propagation material from attack by insects, mites, nematodes or mollusks, which method comprises treating the propagation material or the locus in which the propagation material is planted with an effective amount of a compound of formula (I) as defined in the first aspect or a composition as defined in the second aspect.

[0034] In a fifth aspect, the present invention provides plant propagation material, such as a seed, comprising, treated with or having attached thereto a compound of formula (I) as defined in the first aspect or a composition as defined in the second aspect.

[0035] In a further aspect, the present invention provides a method of controlling parasites in or on an animal in need thereof, the method comprising administering an effective amount of a compound of formula I as defined in the first aspect. The present invention further provides a method of controlling ectoparasites on an animal in need thereof, the method comprising administering an effective amount of a compound of formula (I) as defined in the first aspect. The present invention further provides a method of preventing and / or treating diseases transmitted by ectoparasites, the method comprising administering to an animal in need thereof an effective amount of a compound of formula (I) as defined in the first aspect.

[0036] Compounds of formula (I) can be prepared by those skilled in the art according to known methods. More specifically, compounds of formula I and intermediates therefor can be prepared as described below in the schemes and examples.

[0037] The process according to the invention for preparing compounds of formula (I) is carried out by methods known to those skilled in the art.

[0038] A compound of formula (I) 1 , R 2 , R 3 , R 4 and q are novel) can be prepared according to Scheme 1 by the addition of an acid II (wherein R 1 , R 3 , R 4 and q are as defined above) with an amine III (wherein R 2(wherein is as defined above) or a salt thereof with a known amide coupling reagent, such as 1-[bis(dimethylamino)-methylene]-1H-1,2,3-triazolo[4,5-b]pyridinium 3-oxide hexafluorophosphate (HATU) and a base, such as Hunig's base, in a suitable solvent, such as dimethylformamide (DMF) or dimethylacetamide (DMA). Piperidine III is commercially available or can be prepared by one skilled in the art. Scheme 1: [ka]

[0039] Alternatively, compounds of formula (I) can be prepared according to Scheme 2 by cleaving an acid chloride IV (wherein R 1 , R 3 , R 4 and q are as defined above) with an amine III (wherein R 2 (wherein R is as defined above) or a salt thereof in the presence of a base such as triethylamine or pyridine and in the presence of a suitable solvent such as dichloromethane (DCM), tetrahydropyran (THF) or toluene. Scheme 2: [ka]

[0040] Acid chloride IV (wherein R 1 , R 3 , R 4 and q are as defined above) can be converted into the corresponding acid II (wherein R 1 , R 3 , R 4 and q are as defined above). Scheme 3: [ka]

[0041] Acid II (wherein, R 1 , R 3 , R 4 and q are as defined above) can be converted to the corresponding ester V (wherein R 1 , R 3 , R 4 and q are as defined above, and R x It can be prepared by hydrolysis of a hydroxybenzoate (wherein = C1-C6-alkyl). Scheme 4: [ka]

[0042] Ester V (wherein R 1 , R 3 , R 4 , R x and q are as defined above) to form compound VI, 1 , R 3 , R x is as defined above, and LG 1 is a leaving group such as bromine, chlorine or a sulfonate such as trifluoromethanesulfonate) with a boronic acid VII or a stannane reagent VIII (wherein R 4 and q are as defined above). Palladium-catalyzed cross-coupling reactions are known to those skilled in the art. These reactions can be carried out in a variety of organic or aqueous solvents compatible with these conditions, according to Scheme 5, at temperatures from below 0° C. to the boiling point of the solvent system, and with a variety of palladium catalysts, such as tetrakis(triphenylphosphine)palladium(0) or palladium(II) acetate and triphenylphosphine. Scheme 5: [ka]

[0043] Ester VI (wherein, for example, R 1 is a cyano group, and LG 1 is a bromo atom or a chloro atom, and R 3 and R x The esters IX (wherein R is as defined above) can be prepared by reacting the esters IX with a halogenating reagent, such as phosphorus oxychloride, oxalyl dichloride, or phosphorus oxybromide, respectively. The reaction can be carried out in dimethylformamide (DMF) or dichloromethane (DCM), toluene, or preferably without solvent at elevated temperatures, according to Scheme 6. The esters VI (wherein, for example, R 1 is a cyano group, and LG 1 is trifluoromethanesulfonate and R 3 and R x (wherein X is as defined above) can be prepared by reacting ester IX with trifluoromethanesulfonic anhydride. The reaction can be carried out in the presence of a base such as pyridine in dimethylformamide (DMF) or dichloromethane (DCM), toluene according to Scheme 6. Scheme 6: [ka]

[0044] An ester of formula IX, wherein R 1 is a cyano group, and R 3 and R x is as defined above) are known in the literature, for example Y. Xie et al., Pest Manag. Sci. 2017, 73, 945-952, or can be prepared by a person skilled in the art.

[0045] A compound of formula (Ib) 2 , R 3 , R4 and q are as defined above) can be converted according to Scheme 7 to a compound of formula (Ia), wherein R 2 , R 3 , R 4 and q are as defined above) with phosphorus sulfide in a suitable solvent, for example a mixture of methanol and water, or with phosphorus sulfide (P2S5) in ethanol. Scheme 7: [ka]

[0046] Compounds of formula (I) according to the following Tables 1 to 7 can be prepared according to the above methods. The following examples are intended to illustrate the invention and to show preferred compounds of formula (I). [ka]

[0047] Each of Tables 1 to 7 following Table M below lists 156 compounds of formula (I), where R 1 , R 2 and (R 4 ) q has the values ​​shown in each row of table M, and R 3 have the values ​​shown in the relevant Tables 1 to 7).

[0048] Therefore, compound 1.1 is a compound of formula (I) 1 , R 2 and (R 4 ) q is as defined in row 1 of table M, and R 3 is as defined in Table 1), and compound 5.14 corresponds to a compound of formula (I) 1 , R 2 and (R 4 ) q is as defined in row 14 of Table M, and R 3 is as defined in Table 5), etc.

[0049] [Table 1-1]

[0050] [Table 1-2]

[0051] [Table 1-3]

[0052] [Table 1-4]

[0053] [Table 1-5]

[0054] Table 1: This table lists 156 compounds of formula (I), 1.1 to 1.156, where R 3 is methyl and R 1 , R 2 and (R 4 ) q is as defined in Table M. For example, Compound No. 1.1 has the following structure: [ka] Table 2: This table lists 156 compounds of formula (I), 2.1 to 2.156, where R 3 is ethyl, and R 1 , R 2 and (R 4 ) q is as defined in Table M). Table 3: This table lists 156 compounds of formula (I), 3.1 to 3.156, where R 3 is cyclopropyl and R 1 , R 2 and (R 4) q is as defined in Table M). Table 4: This table lists 156 compounds of formula (I) 4.1 to 4.156 (wherein R 3 is methoxymethyl, and R 1 , R 2 and (R 4 ) q is as defined in Table M). Table 5: This table lists 156 compounds of formula (I), 5.1 to 5.156, where R 3 is fluoromethyl, and R 1 , R 2 and (R 4 ) q is as defined in Table M). Table 6: This table lists 156 compounds of formula (I), 6.1 to 6.156, where R 3 is difluoromethyl, and R 1 , R 2 and (R 4 ) q is as defined in Table M). Table 7: This table lists 156 compounds of formula (I), 6.1 to 6.156, where R 3 is trifluoromethyl and R 1 , R 2 and (R 4 ) q is as defined in Table M).

[0055] The compounds of formula (I) according to the present invention are valuable preventive and / or therapeutic active ingredients in the field of pest control, having a very favorable biocidal spectrum even at low application rates, and are well tolerated by warm-blooded species, fish, and plants. The active ingredients according to the present invention act not only against normally susceptible animal pests, such as insects or representatives of the order Acarina, but also against all or individual developmental stages of resistant animal pests. The insecticidal or acaricidal activity of the active ingredients according to the present invention can manifest itself directly, i.e., in the destruction of the pest, which occurs either immediately or only after a certain period of time, for example, during molting, or can manifest itself indirectly, for example, by a reduction in egg-laying and / or hatching rate.

[0056] Examples of the animal pests mentioned above are: Acarina, for example Acalitus spp., Aculus spp., Acaricalus spp., Aceria spp., Acarus siro, Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia spp., Calipitrimerus spp., Chorioptes spp., Dermanyssus gallinae, Dermatophagoides spp., Eotetranychus spp., Eriophyes spp., Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Olygonychus spp., Ornithodoros spp., Polyphagotarsone latus, Panonychus spp., Phyllocoptruta oleivora, Phytonemus spp., Polyphagotarsonemus spp., Psoroptes spp., Rhipicephalus spp.), Rhizoglyphus spp., Sarcoptes spp., Steneotarsonemus spp., Tarsonemus spp. and Tetranychus spp.; from the order Anoplura, for example Haematopinus spp., Linognathus spp., Pediculus spp., Pemphigus spp. and Phylloxera spp.; Coleoptera, e.g. Agriotes spp., Amphimallon majale, Anomala orientalis, Anthonomus spp., Aphodius spp., Astylus atromaculatus, Ataenius spp., Atomaria linearis, Chaetocnema tibialis, Cerotoma spp., Conoderus spp., Cosmopolites spp., Cotinis nitida, Curculio spp. spp.), Cyclocephala spp., Dermestes spp., Diabrotica spp., Diloboderus abderus, Epilachna spp., Eremnus spp., Heteronychus arator, Hypothenemus hampei, Lagria vilosa, Leptinotarsa ​​decemlineata, Lissorhoptrus spp., Liogenys spp., Maecolaspis spp., Maladera castanea, Megascelis spp., Melighetes aeneus, Melolontha spp., Myochrous armatus, Orycaephilus spp., Otiorhynchus spp., Phyllophaga spp., Phlyctinus spp.), Popillia spp., Psylliodes spp., Rhyssomatus aubtilis, Rhizopertha spp., Scarabaeidae, Sitophilus spp., Sitotroga spp., Somaticus spp., Sphenophorus spp., Sternechus subsignatus, Tenebrio spp., Tribolium spp. and Trogoderma spp.;. Diptera, e.g. Aedes spp., Anopheles spp., Antherigona soccata, Bactrocea oleae, Bibio hortulanus, Bradysia spp., Calliphora erythrocephala, Ceratitis spp., Chrysomyia spp., Culex spp., Cuterebra spp., Dacus spp., Delia spp., Drosophila melanogaster, Fannia spp. spp.), Gastrophilus spp., Geomyza tripunctata, Glossina spp., Hypoderma spp., Hyppobosca spp., Liriomyza spp., Lucilia spp., Melanagromyza spp., Musca spp., Oestrus spp., Orseolia spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp. spp.), Rhagoletis spp., Rivelia quadrifasciata, Scatella spp., Sciara spp., Stomoxys spp., Tabanus spp., Tannia spp. and Tipula spp.; Hemiptera, e.g. Acanthocoris scabrator, Acrosternum spp., Adelphocoris lineolatus, Aleurodes spp., Amblypelta nitida, Bathycoelia thalassina, Blissus spp., Cimex spp., Clavigrella tomentosicollis, Creontiades spp., Distantiella theobroma, Dichelops furcatus, Dysdercus spp.), Edessa spp., Euchistus spp., Eurydema pulchrum, Eurygaster spp., Halyomorpha halys, Horcias nobilellus, Leptocorisa spp., Lygus spp., Margarodes spp., Murgantia histrionic, Neomegalotomus spp., Nesidiocoris tenuis, Nezara spp., Nysius simulans simulans, Oebalus insularis, Piesma spp., Piezodorus spp., Rhodnius spp., Sahlbergella singularis, Scaptocoris castanea, Scotinophara spp.), Thyanta spp., Triatoma spp. and Vatiga illudens;. Acyrthosium pisum, Adalges spp., Agalliana ensigera, Agonoscena targionii, Aleurodicus spp., Aleurocanthus spp., Aleurolobus barodensis, Aleurothrixus floccosus, Aleyrodes brassicae, Amarasca biguttula, Amritodus atkinsoni, Aonidiella spp. spp.), Aphididae, Aphis spp., Aspidiotus spp., Aulacorthum solani, Bactericera cockerelli, Bemisia spp., Brachycaudus spp., Brevicoryne brassicae, Cacopsylla spp., Cavariella aegopodii Scop., Ceroplaster spp.), Chrysomphalus aonidium, Chrysomphalus dictyospermi, Cicadella spp., Cofana spectra, Cryptomyzus spp., Cicadulina spp., Coccus hesperidum, Dalbulus maidis, Dialeurodes spp., Diaphorina citri, Diuraphis noxia, Dysaphis spp., Empoasca spp., Eriosoma larigerum, Erythroneura spp., Gascardia spp., Glycaspis brimblecombei, Hyadaphis pseudobrassicae, Hyalopterus spp., Hyperomyzus pallidus, Idioscopus clypealis, Jacobiasca lybica, Laodelphax spp., Lecanium corni, Lepidosaphes spp., Lopaphis erysimi, Lyogenys maidis, Macrosiphum spp., Mahanarva spp., Metcalfa pruinosa, Metopolophium dirhodum, Myndus crudus, Myzus spp.), Neotoxoptera spp., Nephotettix spp., Nilaparvata spp., Nippolachnus piri Mats, Odonaspis ruthae, Oregma lanigera Zehnter, Bayberry whitefly (Parabemisia myricae), Paratrioza cockerelli, Parlatoria spp., Pemphigus spp., Corn planthopper (Peregrinus maidis), Perkinsiella spp., Hop wart aphid (Phorodon humuli, Phylloxera spp., Planococcus spp., Pseudaulacaspis spp., Pseudococcus spp., Pseudatomoscelis seriatus, Psylla spp., Pulvinaria aethiopica, Quadraspidiotus spp., Quesada gigas, Recilia dorsalis, Rhopalosiphum spp., Saissetia spp., Scaphoideus spp. spp.), Schizaphis spp., Sitobion spp.), Sogatella furcifera, Spisstilus festinus, Tarophagus Proserpina, Toxoptera spp., Trialeurodes spp., Tridiscus sporoboli, Trionymus spp., Trioza erytreae, Unaspis citri, Zygina flammigera, Zyginidia scutellaris; the order Hymenoptera, for example Acromyrmex, Arge spp., Atta spp., Cephus spp., Diprion spp., the family Diprionidae, Gilpinia polytoma, Hoplocampa spp., Lasius spp., Monomorium pharaonis, Neodiprion spp., Pogonomyrmex spp., Slenopsis invicta, Solenopsis spp. and Vespa spp.; Isoptera, for example, Coptotermes spp., Corniternes cumulans, Incisitermes spp., Macrotermes spp., Mastotermes spp., Microtermes spp., Reticulitermes spp.; Solenopsis geminate; Lepidoptera, e.g. Acleris spp., Adoxophyes spp., Aegeria spp., Agrotis spp., Alabama argillaceae, Amylois spp., Anticarsia gemmatalis, Archips spp., Argyresthia spp., Argyrotaenia spp., Autographa spp., Bucculatrix thurberiella, Busseola fusca, Cadra cautella, peach fruit moth (Carposina nipponensis), Chilo spp., Choristoneura spp., Chrysoteuchia topiaria, grapevine moth (Clysia ambiguella), Cnaphalocrocis spp., Cnephasia spp., Cochylis spp., Coleophora spp., Colias lesbia, cotton moth (Cosmophila flava), Crambus spp., woolly moth (Crocidolomia binotalis), Cryptophlebia leucotreta leucotreta, Cydalima perspectalis, Cydia spp., Diaphania perspectalis, Diatraea spp., Diparopsis castanea, Earias spp.), Elasmopalpus lignosellus, Eldana saccharina, Ephestia spp., Epinotia spp., Estigmene acrea, Etiella zinckinella, Eucosma spp., Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Feltia jaculiferia, Grapholita spp., Hedya nubiferana, Heliothis spp. spp.), Hellula undalis, Herpetogramma spp., Hyphantria cunea, Keiferia lycopersicella, Lasmopalpus lignosellus, Leucoptera scitella, Lithocollethis spp., Lobesia botrana, Loxostege bifidalis, Lymantria spp., Lyonetia spp., Malacosoma spp., Mamestra brassicae, Manduca sexta, Mythimna spp., Noctua spp., Operophtera spp., Orniodes indica, Ostrinia nubilalis, Pammene spp., Pandemis spp.), pine sawyer moth (Panolis flammea), Papaipema nebris, pink bollworm (Pectinophora gossypiela), coffee leafminer (Perileucoptera coffeella), Pseudaletia unipuncta, potato tuber moth (Phthorimaea operculella), cabbage white butterfly (Pieris rapae), Pieris spp., diamondback moth (Plutella xylostella), Prays spp., Pseudoplusia spp., Rachiplusia nu, Richia albicosta, Scirpophaga spp., Sesamia spp.), Sparganothis spp., Spodoptera spp., Sylepta derogate, Synanthedon spp., Thaumetopoea spp., Tortrix spp., Trichoplusia ni, Tuta absoluta and Yponomeuta spp.;. Mallophaga, e.g., Damalinea spp. and Trichodectes spp.; Orthoptera, for example Blatta spp., Blattella spp., Gryllotalpa spp., Leucophaea maderae, Locusta spp., Neocurtilla hexadactyla, Periplaneta spp., Scapteriscus spp. and Schistocerca spp.; Psocoptera, e.g., Liposcelis spp.; from the order Siphonaptera, for example Ceratophyllus spp., Ctenocephalides spp. and Xenopsylla cheopis; Thysanoptera, e.g., Calliothrips phaseoli, Frankliniella spp., Heliothrips spp., Hercinothrips spp., Parthenothrips spp., Scirtothrips aurantii, Sericothrips variabilis, Taeniothrips spp., Thrips spp.; Thysanura, for example, the silverfish (Lepisma saccharina).

[0057] In a further aspect, the present invention relates to plant parasitic nematodes (endoparasitic, semi-endoparasitic and ectoparasitic nematodes), in particular root-knot nematodes, Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica, Meloidogyne arenaria and other Meloidogyne species; cyst-forming nematodes, Globodera rostochiensis and other Globodera species; Heterodera avenae, Heterodera glycines, Heterodera schachtii, Heterodera trifolii and other Heterodera species; seed nematodes, Anguina species; stem and leaf nematodes, Aphelenchoides species; stinging nematodes, Belonolaimus longicaudatus and other Belonolaimus species; pine nematodes, Bursaphelenchus xylophilus and other Bursaphelenchus species; ring nematodes, Criconema species, Criconemella species, Criconemoides species, Mesocriconema species; stem and bulb nematodes, Ditylenchus destructor, Ditylenchus dipsacchii dipsaci and other Ditylenchus species; Awl nematodes, Dolichodorus species; Spiral nematodes, Heliocotylenchus multicinctus and other Helicotylenchus species;Sheath and sheath-like nematodes, Hemicycliophora spp. and Hemicriconemoides spp.; Hirshmanniella spp.; Lance nematodes, Hoploaimus spp.; Root-knot nematodes, Nacobbus spp.; Needle nematodes, Longidorus elongatus and other Longidorus spp.; Pin nematodes, Pratylenchus spp.; Lesion nematodes, Pratylenchus neglectus, Pratylenchus penetrans, Pratylenchus curbitatus curvitatus, Pratylenchus goodeyi and other Pratylenchus species; Burrowing nematode, Radopholus similis and other Radopholus species; Rotylenchus robustus, Rotylenchus reniformis and other Rotylenchus species; Scutellonema species; Stubby root nematode, Trichodurus primitivus and other Trichodurus species, Paratrichodorus species; Stunt nematode, Tylenchorhynchus claytoni, Tylenchorhynchus dubius and other Tylenchorhynchus species; Citrus nematodes, Tylenchulus species; Dagger nematodes, Xiphinema species;and other plant parasitic nematode species such as Subanguina, Hypsoperine, Macroposthonia, Melinius, Punctodera and Quinisulcius, and the like;

[0058] The compounds of the present invention may also have activity against mollusks, examples of which include, for example, Ampullariidae; Arion (A. ater, A. circumscriptus, A. hortensis, A. rufus); Bradybaenidae (Bradybaena furticum); fruticum); Cepaea (C. hortensis, C. nemoralis); Ochrogyna; Deroceras (D. agrestis, D. empiricorum, D. laeve, D. reticulatum); Discus (D. rotundatus); Euonphalia; Galba (G. trunculata); Heliceria (H. itala, H. obvia); Helicidae Helicigona albustrum arbustorum); Helicodiscus; Helix (H. aperta); Limax (L. cinereoniger, L. flavus, L. marginatus, L. maximus, L. tenellus); Lymnaea; Milax (M. gagates, M. marginatus, M. sowerbyi); Opeas; Pomacea (P. canaticulata); Vallonia and Zanitoides.

[0059] The active ingredients according to the invention can be used to control, i.e. contain or destroy, pests of the above-mentioned types that occur in particular on plants, in particular on useful and ornamental plants in agriculture, horticulture and forestry, or on organs of such plants, such as fruits, flowers, leaves, stems, tubers or roots, and in some cases on plant organs that are formed even later and remain protected against these pests.

[0060] Suitable target crops are, in particular, cereals such as wheat, barley, rye, oats, rice, maize or sorghum; beets, such as sugar or fodder beets; fruits, such as pome fruits, stone fruits or soft fruits, for example apples, pears, plums, peaches, almonds, cherries or berries, for example strawberries, raspberries or blackberries; legumes, for example beans, lentils, peas or soybeans; oil crops, for example rape, mustard, poppy, olives, sunflower, coconut, castor, cocoa or ground nuts; cucurbits, for example ... Plants, such as pumpkin, cucumber or melon; fiber plants, such as cotton, flax, hemp or jute; citrus fruits, such as orange, lemon, grapefruit or tangerine; vegetables, such as spinach, lettuce, asparagus, cabbage, carrot, onion, tomato, potato or bell pepper; Lauraceae, such as avocado, Cinnamonium or camphor; and also tobacco, nuts, coffee, eggplant, sugarcane, tea, pepper, grapevine, hops, Plantaginaceae and latex plants.

[0061] In particular embodiments, the compounds of formula (I) control mites, rust mites and spider mites on crops, trees and plants selected from vegetables (especially tomatoes and cucumbers), citrus fruits, pome fruits, stone fruits, nuts, cotton, tropical crops, avocados, ornamentals, beans, soybeans, strawberries and grapes.

[0062] The compositions and / or methods of the present invention may be used on any ornamental and / or vegetable crop, including flowers, shrubs, broadleaf trees and evergreen trees.

[0063] For example, the present invention can be used with any of the following ornamental species: Ageratum spp., Alonsoa spp., Anemone spp., Anisodontea capsenisis, Anthemis spp., Antirrhinum spp., Aster spp., Begonia (e.g., B. elatior, B. semperflorens, B. tubereux), Bougainvillea spp., Brachycome spp., Brassica spp. (ornamental), Calceolaria spp. spp.), Capsicum annuum, Catharanthus roseus, Canna spp., Centaurea spp., Chrysanthemum spp., Cineraria spp. (C. maritime), Coreopsis spp., Crassula coccinea, Cuphea ignea, Dahlia spp., Delphinium spp., Dicentra spectabilis, Dorotheantus spp., Eustoma grandiflorum grandiflorum, Forsythia spp., Fuchsia spp., Geranium gnaphalium, Gerbera spp., Gomphrena globosa, Heliotropium spp., Helianthus spp., Hibiscus spp.), Hortensia spp., Hydrangea spp., Hypoestes phyllostachya, Impatiens spp. (I. Walleriana), Iresines spp., Kalanchoe spp., Lantana camara, Lavatera trimestris, Leonotis leonurus, Lilium spp., Mesembryanthemum spp., Mimulus spp., Monarda spp., Nemesia spp. spp.), Tagetes spp., Dianthus spp. (carnations), Canna spp., Oxalis spp., Bellis spp., Pelargonium spp. (P. peltatum, P. zonale), Viola spp. (pansies), Petunia spp., Phlox spp., Plectranthus spp., Poinsettia spp., Parthenocissus spp. spp.) (P. quinquefolia, P. tricuspidata), Primula spp., Ranunculus spp., Rhododendron spp., Rosa spp. (roses), Rudbeckia spp., Saintpaulia spp., Salvia spp., Scaevola aemola, Schizanthus wisetonensis, Sedum spp.), Solanum spp., Surfinia spp., Tagetes spp., Nicotinia spp., Verbena spp., Zinnia spp. and other bedding plants.

[0064] For example, the present invention can be used with any of the following vegetable species: Allium spp. (garlic (A. sativum), onion (A. cepa), shallot (A. oschaninii), leek (A. porrum), scallion (A. ascalonicum), green onion (A. fistulosum)), chervil (Anthriscus cerefolium), celery (Apium graveolus), asparagus (Asparagus officinalis), beet (Beta vulgarus), Brassica spp. (B. oleracea, Chinese cabbage (B. pekinensis), turnip (B. rapa)), pepper (Capsicum annuum), chickpea (Cicer arietinum), endive (Cichorium endivia), Cichorum spp. spp.) (chicory (C. intybus), endive (C. endivia)), watermelon (Citrillus lanatus), Cucumis spp. (saffron (C. sativus), melon (C. melo)), Cucurbita spp. (Cucurbita pepo, Cucurbita maxima), Cyanara spp. (artichoke (C. scolymus), cardoon (C. cardunculus)), carrot (Daucus carota), fennel (Foeniculum vulgare), Hypericum spp., lettuce (Lactuca sativa), tomato (Lycopersicon spp.) (tomato (L. esculentum), tomato (L. lycopersicum)), mint (Mentha spp.), basil (Ocimum basilicum), parsley (Petroselinum crispum), Phaseolus spp. (Phaseolus vulgaris, runner bean (P.coccineus), pea (Pisum sativum), radish (Raphanus sativus), rhubarb (Rheum rhaponticum), rosemary (Rosemarinus spp.), salvia (Salvia spp.), yellow rosemary (Scorzonera hispanica), eggplant (Solanum melongena), spinach (Spinacea oleracea), Valerianella spp. (V. locusta, V. eriocarpa) and broad bean (Vicia faba).

[0065] Preferred ornamental plant species include African violet, begonia, dahlia, gerbera, hydrangea, verbena, rosa, kalanchoe, poinsettia, aster, centaurea, coreopsis, delphinium, monarda, and phlox. , Rudbeckia, Sedum, Petunia, Viola, Impatiens, Geranium, Chrysanthemum, Ranunculus, Fuchsia, Salvia, Hortensia, rosemary, sage, St. John's wort, mint, peppers, tomatoes, and cucumbers.

[0066] The active ingredients according to the invention are particularly suitable for controlling Aphis craccivora, Diabrotica balteata, Heliothis virescens, Myzus persicae, Plutella xylostella, and Spodoptera littoralis in cotton, vegetable, corn, rice, and soybean crops. They are even more particularly suitable for controlling Mamestra (preferably on vegetables), codling moth (Cydia pomonella) (preferably on apples), Empoasca (preferably on vegetables and vineyards), Leptinotarsa ​​(preferably on potatoes), and Chilo supressalis (preferably on rice).

[0067] The compounds of formula (I) are effective against mites, spider mites and rust mites, for example Acarapis spp; Acarapis woodi; Acarus siro; Acarus spp; Aceria sheldoni; Aculops pelekassi; Aculops spp; Aculus schlechtendali; Aculus spp; Amblyseius fallacis; Brevipalpus spp; Brevipalpus phoenicis; Bryobia praetiosa; Bryobia rubrioculus; Caloglyphus spp); Cheyletiella blakei; Cheyletiella spp; Cheyletiella yasguri; Chorioptes bovis; Chorioptes spp; Cytodites spp; Demodex bovis; Demodex caballi; Demodex canis; Demodex caprae; Demodex equi; Demodex ovis; Demodex spp; Demodex suis; Dermonychus gallinae; Dermonychus spp; Eotetranychus spp); Willamette spider mite (Eotetranychus willamettei); Pear rust mite (Epitrimerus pyri); Eriophyes ribis; Eriophyes spp; Grape leafminer mite (Eriophyes vitis);Eutetranychus spp; Halotydeus destructor; Hemitarsonemus spp; Knemidocoptes spp; Laminosioptes spp; Listrophorus spp; Myobia spp; Neoschongastia xerothermobia; Neotrombicula autumnalis; Neotrombicula desaleri; Notoedres cati; Notoedres spp; Oligonychus coffeae; Oligonychus ilicis; Oligonychus spp; Ornithocheyletia spp; Ornithonyssus bursa; Ornithonyssus spp; Ornithonyssus sylviarum; Otodectes cynotis; Otodectes spp; Panonychus citri; Panonychus spp; Panonychus ulmi; Phyllocoptruta oleivora; Phyllocoptruta spp.; Phytoseiulus spp.; Pneumonyssoides caninum; Polyphagotarsonemus latus); Polyphagotarsonemus spp; Psorergates ovis; Psorergates spp; Psoroptes cuniculi;Psoroptes equi, Psoroptes ovis, Psoroptes spp., Pterolichus spp., Raillietia spp., Rhizoglyphus spp., Sarcoptes bovis, Sarcoptes canis, Sarcoptes caprae, Sarcoptes equi, Sarcoptes ovis, Sarcoptes rupicaprae, Sarcoptes spp., Sarcoptes spp. suis; Steneotarsonemus spinki; Steneotarsonemus spp; Sternostoma spp; Tarsonemus spp; Tetranychus cinnabarinus; Tetranychus kanzawai; Tetranychus spp; Tetranychus urticae; Trombicula akamushi; Trombicula spp; Typhlodromus occidentalis; Tyrophagus spp; Varroa jacobsoni; Varroa spp spp); Vasates lycopersici; and Zetzellia mali.

[0068] In certain embodiments, the compounds of formula (I) are particularly suitable for controlling one or more of the following: Aceria sheldoni; Aculus lycopersici; Aculus pelekassi; Aculus schlechtendali; Brevipalpus phoenicis; Brevipalpus spp.; Bryobia rubrioculus; Eotetranychus carpini; Eotetranychus spp.; Epitrimerus pyri; Eriophyes piri; Eriophyes spp.; Eriophyes vitis; Eutetranychus africanus africanus); Oriental spider mite (Eutetranychus orientalis); Oligonychus pratensis; Panonychus citri; Panonychus ulmi; Phyllocoptes vitis; Phyllocoptruta oleivora; Polyphagotarsonemus latus; Tetranychus cinnabarinus; Tetranychus kanzawai; Tetranychus spp.; and Tetranychus urticae.

[0069] In a further embodiment, the compounds of formula (I) are more particularly suitable for controlling one or more of the following: Aceria sheldoni; Aculus pelekassi; Brevipalpus phoenicis; Brevipalpus spp.; Eriophyes piri; Eriophyes vitis; Eutetranychus africanus; Eutetranychus orientalis; Oligonychus pratensis; Panonychus ulmi; Phyllocoptes vitis; Phyllocoptruta oleivora; Polyphagotarsonemus latus); Tetranychus cinnabarinus; Tetranychus kanzawai; Tetranychus spp.; and Tetranychus urticae.

[0070] The term "crop plant" should also be understood to include crop plants that have been transformed using recombinant DNA techniques so as to be capable of synthesizing one or more selectively acting toxins, such as those known from toxin-producing bacteria, particularly those belonging to the genus Bacillus.

[0071] Toxins that can be expressed by transformed plants include, for example, insecticidal proteins, such as insecticidal proteins from Bacillus cereus or Bacillus popilliae; or insecticidal proteins from Bacillus thuringiensis, such as δ-endotoxins, such as Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, or vegetative insecticidal proteins (Vip), such as Vip1, Vip2, Vip3 or Vip3A; or insecticidal proteins from bacteria, such as Photorhabdus spp. or Xenorhabdus spp., such as Photorhabdus luminescens, Xenorhabdus nematophilus, insecticidal proteins of nematode-symbiotic bacteria such as Pseudomonas spp.; toxins produced by animals such as scorpion toxins, spider toxins, wasp toxins and other insect-specific neurotoxins; toxins produced by fungi such as Streptomycete toxins, plant lectins such as pea lectin, barley lectin or snowdrop lectin; agglutinins; proteinase inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, papain inhibitors; ricin, Ribosome-inactivating proteins (RIPs) such as maize RIP, abrin, ruffin, saporin or bryodin; steroid metabolic enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glycosyl-transferase, cholesterol oxidase, ecdysone inhibitors, HMG-COA-reductase, ion channel blockers such as sodium or calcium blockers, juvenile hormone esterase, diuretic hormone receptor, stilbene synthase, bibenzyl synthase, chitinase and glucanase.

[0072] In the context of the present invention, it should be understood that δ-endotoxins, such as Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1, or Cry9C, or trophic insecticidal proteins (Vip), such as Vip1, Vip2, Vip3, or Vip3A, are also particularly hybrid toxins, truncated toxins, and modified toxins. Hybrid toxins are produced recombinantly by combining different domains of these proteins (see, for example, WO 02 / 15701). For example, truncated toxins, such as truncated Cry1Ab, are known. In the case of modified toxins, one or more amino acids of the natural toxin are replaced. In such amino acid substitutions, a non-naturally occurring protease recognition sequence is preferably inserted into the toxin, for example, in the case of Cry3A055, a cathepsin-G recognition sequence is inserted into the Cry3A toxin (see WO 03 / 018810).

[0073] Examples of such toxins or transformed plants capable of synthesizing such toxins are disclosed, for example, in EP 0 374 753, WO 93 / 07278, WO 95 / 34656, EP 0 427 529, EP 451 878 and WO 03 / 052073.

[0074] Processes for the preparation of such transformed plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above. CryI-type deoxyribonucleic acids and their preparation are known, for example, from WO 95 / 34656, EP 0 367 474, EP 0 401 979 and WO 90 / 13651.

[0075] The toxins contained in the transformed plants confer resistance to harmful insects on the plants, which can be from any taxonomic group of insects, but are particularly commonly found among beetles (Coleoptera), two-winged insects (Diptera), and moths (Lepidoptera).

[0076] Transgenic plants containing one or more genes encoding insecticide resistance and expressing one or more toxins are known, and some are commercially available. Examples of such plants include YieldGard® (a corn variety expressing the Cry1Ab toxin); YieldGard Rootworm® (a corn variety expressing the Cry3Bb1 toxin); YieldGard Plus® (a corn variety expressing the Cry1Ab and Cry3Bb1 toxins); Starlink® (a corn variety expressing the Cry9C toxin); Herculex I® (a corn variety expressing the Cry1Fa2 toxin and the enzyme phosphinothricin N-acetyltransferase (PAT) for tolerance to the herbicide glufosinate ammonium); NuCOTN 33B® (a cotton variety expressing the Cry1Ac toxin); Bollgard I® (a cotton variety expressing the Cry1Ac toxin); Bollgard II® (a cotton variety expressing Cry1Ac and Cry2Ab toxins); VipCot® (a cotton variety expressing Vip3A and Cry1Ab toxins); NewLeaf® (a potato variety expressing Cry3A toxin); NatureGard®, Agrisure® GT Advantage (GA21 glyphosate tolerance trait), Agrisure® CB Advantage (Bt11 corn borer (CB) trait), and Protecta®.

[0077] Further examples of such transformed crops are as follows: 1. Bt11 maize, registration number C / FR / 96 / 05 / 10, manufactured by Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31 790 St. Sauveur, France. Genetically modified maize (Zea mays) rendered resistant to attack by the European pine moth (Ostonia nubilalis and Sesamia nonagrioides) through transgenic expression of a truncated Cry1Ab toxin. Bt11 maize also achieves tolerance to the herbicide glufosinate-ammonium through transgenic expression of the enzyme PAT. 2. Bt176 maize, registration number C / FR / 96 / 05 / 10, manufactured by Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31 790 St. Sauveur, France. Genetically modified maize (Zea mays) rendered resistant to attack by the European pine moth (Ostonia nubilalis and Sesamia nonagrioides) through transgenic expression of the Cry1Ab toxin. Bt176 maize also achieves tolerance to the herbicide glufosinate-ammonium through transgenic expression of the enzyme PAT. 3. MIR604 corn, registration number C / FR / 96 / 05 / 10, manufactured by Syngenta Seeds SAS, Chemin de l'Hobit 27, F-31 790 St. Sauveur, France. This corn is resistant to insects through transgenic expression of a modified Cry3A toxin. The toxin is Cry3A055 modified by the insertion of a cathepsin-G-proteinase recognition sequence. The preparation of such transformed corn plants is described in WO 03 / 018810. 4. MON 863 maize, registration number C / DE / 02 / 9, manufactured by Monsanto Europe SA270-272 Avenue de Tervuren, B-1150 Brussels, Belgium. MON 863 expresses the Cry3Bb1 toxin and confers resistance to certain Coleoptera insects. 5. Monsanto Europe SA270-272 Avenue de Tervuren, B-1150 Brussels, Belgium. IPC 531 cotton, registration number C / ES / 96 / 02. 6. 1507 corn, registration number C / NL / 00 / 10, manufactured by Pioneer Overseas Corporation, Avenue Tedesco, 7 B-1160 Brussels, Belgium. Maize genetically engineered for expression of the protein Cry1F to achieve resistance to certain lepidopteran insects and for expression of the PAT protein to achieve tolerance to the herbicide glufosinate ammonium. 7. NK603 x MON810 corn, registration number C / GB / 02 / M3 / 03, manufactured by Monsanto Europe SA270-272 Avenue de Tervuren, B-1150 Brussels, Belgium. This corn variety is a conventional hybrid corn variety resulting from a cross between the genetically modified varieties NK603 and MON 810. NK603 x MON810 corn transgenicly expresses the protein CP4 EPSPS from Agrobacterium sp. strain CP4, which confers resistance to the herbicide Roundup® (containing glyphosate), and also transgenicly expresses the Cry1Ab toxin from Bacillus thuringiensis subsp. kurstaki, which confers resistance to certain Lepidoptera, including the European corn borer.

[0078] Transformed insect-resistant plants are also described in the BATS (Zentrum fur Biosicherheit und Nachhaltigkeit, Zentrum BATS, Clarastrasse 13, 4058 Basel, Switzerland) Report 2003 (http: / / bats.ch).

[0079] The term "crop plant" should also be understood to include crop plants that have been transformed using DNA recombinant techniques so as to be able to synthesize antipathogenic substances with selective action, such as, for example, so-called "infection-specific proteins" (PRPs, see, for example, EP-A-0 392 225). Examples of such antipathogenic substances and transformed plants capable of synthesizing such antipathogenic substances are known, for example, from EP-A-0 392 225, WO 95 / 33818 and EP-A-0 353 191. Methods for producing such transformed plants are generally known to those skilled in the art and are described, for example, in the above-mentioned publications.

[0080] Crops can also be modified for enhanced resistance to fungal (e.g., Fusarium, Anthracnose, or Phytophthora), bacterial (e.g., Pseudomonas), or viral (e.g., potato leaf curl virus, tomato spotted wilt virus, cucumber mosaic virus) pathogens.

[0081] Crops also include those with enhanced resistance to nematodes, such as the soybean cyst nematode.

[0082] Crops that are tolerant to abiotic stress include, for example, those that have enhanced tolerance to drought, high salinity, high temperature, low temperature, frost, or light due to expression of NF-YB or other proteins known in the art.

[0083] Anti-pathogenic substances that can be expressed by such transformed plants include, for example, ion channel blockers, such as sodium and calcium channel blockers, for example viral KP1, KP4 or KP6 toxins, stilbene synthases, bibenzyl synthases, chitinases, glucanases, so-called "pathogenesis-related proteins" (PRPs, see, for example, EP 0 392 225), anti-pathogenic substances produced by microorganisms, such as peptide or heterocyclic antibiotics (see, for example, WO 95 / 33818), or proteins or polypeptide factors involved in plant pathogen defense (so-called "plant disease resistance genes", as described in WO 03 / 000906).

[0084] Further areas of use of the compositions according to the invention are the protection of stored goods and storage rooms against pests of the types mentioned and the protection of raw materials such as wood, textiles, floor coverings or buildings and also in the hygiene sector, in particular the protection of humans, livestock and productive livestock.

[0085] The present invention provides compounds of the first aspect for use in therapy. The present invention provides compounds of the first aspect for use in controlling parasites in or on animals. The present invention further provides compounds of the first aspect for use in controlling ectoparasites in animals. The present invention further provides compounds of the first aspect for use in the prevention and / or treatment of diseases transmitted by ectoparasites.

[0086] The present invention provides the use of a compound of the first aspect for the manufacture of a medicament for controlling parasites in or on an animal. The present invention further provides the use of a compound of the first aspect for the manufacture of a medicament for controlling ectoparasites on an animal. The present invention further provides the use of a compound of the first aspect for the manufacture of a medicament for preventing and / or treating diseases transmitted by ectoparasites.

[0087] The present invention provides the use of a compound of the first aspect in the control of parasites in or on an animal. The present invention further provides the use of a compound of the first aspect in the control of ectoparasites on an animal.

[0088] The term "control," when used in reference to parasites in or on animals, refers to reducing the number of pests or parasites, eliminating pests or parasites, and / or preventing further pest or parasite infestation.

[0089] The term "treating" when used in reference to a parasite in or on an animal refers to inhibiting, slowing, halting or reversing the progression or severity of an existing symptom or disease.

[0090] The term "prevention," when used in reference to a parasite in or on an animal, refers to the avoidance of symptoms or disease developing in the animal.

[0091] The term "animal," when used in reference to parasites in or on animals, can refer to mammals and non-mammals, such as birds or fish. In the case of mammals, it can be a human or non-human mammal. Non-human mammals include, but are not limited to, livestock animals and companion animals. Livestock animals include, but are not limited to, cows, camels, pigs, sheep, goats, and horses. Companion animals include, but are not limited to, dogs, cats, and rabbits.

[0092] A "parasite" is a pest that lives in or on a host animal and benefits by deriving nutrients at the host animal's expense. An "endoparasite" is a parasite that lives within a host animal. An "ectoparasite" is a parasite that lives on a host animal. Ectoparasites include, but are not limited to, mites, insects, and crustaceans (e.g., biting lice). The subclass Acari (or Acarina) includes ticks and mites. Ticks include, but are not limited to, members of the following genera: Rhipicaphalus, such as Rhipicaphalus (Boophilus) microplus and Rhipicephalus sanguineus; Amblyomma; Dermacentor; Haemaphysalis; Hyalomma; Ixodes; Rhipicentor; Margaropus; Argas; Otobius; and Ornithodoros. Mites include, but are not limited to, members of the following genera: Chorioptes, such as Chorioptes bovis; Psoroptes, such as Psoroptes ovis; Cheyletiella; Dermanyssus, such as Dermanyssus gallinae; Ortnithonyssus; Demodex, such as Demodex canis; Sarcoptes, such as Sarcoptes scabiei; and Psorergates.Insects include, but are not limited to, members of the following orders: Siphonaptera, Diptera, Phthiraptera, Lepidoptera, Coleoptera, and Homoptera. Members of the Siphonaptera include, but are not limited to, the cat flea (Ctenocephalides felis) and the dog flea (Ctenocephatides canis). Members of the Diptera order include, but are not limited to, Musca; bot flies, such as Gasterophilus intestinalis and Oestrus ovis; stable flies; bot flies, such as Haematopota and Tabunus; haematobia, such as Haematobia irritans; Stomoxys; Lucilia; midges; and mosquitoes. Members of the Phthiraptera class include, but are not limited to, sucking lice and chewing lice, such as Bovicola ovis and Bovicola bovis.

[0093] The term "effective amount," when used in reference to parasites in or on animals, refers to the amount or dosage of a compound of the present invention or its salt that provides the desired effect in or on the animal upon single or multiple administration to the animal. An effective amount can be readily determined by the attending diagnostician, as one skilled in the art, using known techniques and observing results obtained under analogous circumstances. In determining an effective amount, the attending diagnostician will take into account numerous factors, including, but not limited to, the species of mammal; its size, age, and general health; the parasite and level of infestation to be controlled; the particular disease or disorder involved; the degree of complication or severity of the disease or disorder; the individual's response; the particular compound administered; the mode of administration; the bioavailability characteristics of the administered preparation; the selected dosage regimen; the use of concomitant medications; and other relevant circumstances.

[0094] The compounds of the present invention can be administered to animals by any route that has the desired effect, including, but not limited to, topical, oral, parenteral, and subcutaneous administration. Topical administration is preferred. Formulations suitable for topical administration include, for example, solutions, emulsions, and suspensions, and can be in the form of pour-ons, spots, spray-ons, spray-laces, or dips. Alternatively, the compounds of the present invention can be administered by ear tag or collar.

[0095] Salt forms of the compounds of the present invention include both pharmaceutically acceptable salts and veterinarily acceptable salts, which may differ from agrochemically acceptable salts. Pharmaceutically and veterinarily acceptable salts and the general methodology for preparing them are well known in the art. See, for example, Gould, PL, "Salt selection for basic drugs," International Journal of Pharmaceutics, 33:201-217 (1986); Bastin, RJ, et al., "Salt Selection and Optimization Procedures for Pharmaceutical New Chemical Entities," Organic Process Research and Development, 4:427-435 (2000); and Berge, SM, et al., "Pharmaceutical Salts," Journal of Pharmaceutical Sciences, 66:1-19, (1977). Those skilled in the synthetic arts will understand that the compounds of the present invention can be easily converted to salts, such as hydrochloride salts, and isolated as salts using techniques and conditions well known to those skilled in the art. Additionally, those skilled in the synthetic arts will recognize that compounds of the invention can be readily converted from a corresponding salt to the corresponding free base and isolated as such.

[0096] The present invention also provides methods for controlling pests (e.g., mosquitoes and other disease vectors; see also http: / / www.who.int / malaria / vector_control / irs / en / ). In one embodiment, the method for controlling pests comprises applying a composition of the present invention to target pests, their habitats, or surfaces or substrates by brushing, rolling, spraying, dusting, or dipping. By way of example, IRS (indoor residual spray) application of surfaces, such as wall, ceiling, or floor surfaces, is contemplated by the methods of the present invention. In another embodiment, it is contemplated to apply such compositions to substrates, such as nonwoven or woven materials, in the form of (or that can be used in the manufacture of) netting, clothing, bedding, curtains, and tents.

[0097] In one embodiment, a method for controlling such pests comprises applying a pesticidally effective amount of a composition of the present invention to target pests, their habitat, or a surface or substrate to achieve effective residual pesticidal activity on the surface or substrate. Such application may be by brushing, rolling, spraying, dusting, or dipping the pesticidal composition of the present invention. By way of example, IRS application of a surface, such as a wall, ceiling, or floor surface, is contemplated by the method of the present invention to achieve effective residual pesticidal activity on the surface. In another embodiment, application of such a composition for residual control of pests on substrates, such as fabric materials in the form of (or that can be used in the manufacture of) netting, clothing, bedding, curtains, and tents, is contemplated.

[0098] The substrates to be treated, including nonwovens, fabrics or netting, can be made of natural fibers such as cotton, raffia, jute, flax, sisal, burlap or wool, or synthetic fibers such as polyamide, polyester, polypropylene, polyacrylonitrile, etc. Polyesters are particularly suitable. Methods for treating textiles are known, for example WO 2008 / 151984, WO 2003 / 034823, U.S. Pat. No. 5,631,072, WO 2005 / 64072, WO 2006 / 128870, EP 1 724 392, WO 2005 113 886 or WO 2007 / 090739.

[0099] A further area of ​​use of the compositions according to the invention is in the field of trunk injection / trunk treatment for all ornamental trees and all fruit and nut trees.

[0100] In the field of trunk injection / trunk treatment, the compounds according to the invention are particularly suitable against wood-boring insects from the orders Lepidoptera and Coleoptera as mentioned above, in particular against the wood-boring organisms listed in Tables A and B below.

[0101] [Table 2]

[0102] [Table 3-1]

[0103] [Table 3-2]

[0104] [Table 3-3]

[0105] [Table 3-4]

[0106] The present invention may also be used to control any pest that may be present in turfgrass, including, for example, beetles, caterpillars, fire ants, ground pearls, millipedes, woodlice, mites, mole crickets, scale insects, mealybugs, mites, boxworms, long-legged bugs, and grubs. The present invention may be used to control pests at various stages of their life cycle, including eggs, larvae, nymphs, and adults.

[0107] In particular, the present invention may be used to control grubs (e.g., Cyclocephala spp. (e.g., masked scarabs, C. lurida), Rhizotrogus spp. (e.g., European scarabs, R. majalis), Cotinus spp. (e.g., blue cockroach beetles, C. nitida), Popillia spp. (e.g., Japanese beetles, P. japonica), Phyllophaga spp. (e.g., May / June beetles), Ataenius spp. spp.) (e.g., black turfgrass Attaenius, A. spretulus), Maladera spp. (e.g., red-velvet beetle, M. castanea) and Tomarus spp.), ground pearls (Margarodes spp.), mole crickets (tan, southern and short-winged; Scapteriscus spp., Gryllotalpa africana) and crane fly larvae (European crane fly, Tipula spp.).

[0108] The present invention may also be used to control straw-dwelling turfgrass pests, including cutworms (e.g., the armyworm Spodoptera frugiperda and the common cutworm Pseudaletia unipuncta), cutworms, weevils (Sphenophorus spp., e.g., S. venatus verstitus and S. parvulus), and sod webworms (e.g., Crambus spp. and the tropical sod webworm, Herpetogramma phaeopteralis).

[0109] The present invention may also be used to control turfgrass pests that live above ground and feed on turfgrass leaves, including stink bugs (e.g., the Japanese longhorn bug, Blissus insularis), horseradish mite (Eriophyes cynodoniensis), oak leafbug (Antonina graminis), two-lined foxtail bug (Propsapia bicincta), leafhoppers, cutworms (Noctuidae), and greenbugs.

[0110] The present invention may also be used to control other pests of turfgrass, such as the red fire ant (Solenopsis invicta), which causes ant mounds in turf.

[0111] In the hygiene sector, the compositions according to the invention are active against ectoparasites such as hard mites, scorpion mites, scabies mites, chiggers, flies (stable flies and dentaries), parasitic fly larvae, lice, head lice, biting lice and fleas.

[0112] Examples of such parasites are: In the order Anoplurida, the genera Haematopinus, Linognathus, Pediculus, Phtirus, and Solenopotes are included. From the order Mallophagida, the genera Trimenopon, Menopon, Trinoton, Bovicola, Werneckiella, Lepikentron, Damalina, Trichodectes and Felicola are included. From the order Diptera and the suborders Nematocerina and Brachycerina, for example, the genera Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp. spp.), Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp.), Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp. and Melophagus spp. In the order Siphonapterida, for example, the genus Pulex, the genus Ctenocephalides, the genus Xenopsylla, and the genus Ceratophyllus. In the order Heteropterida, for example, the genera Cimex, Triatoma, Rhodnius, and Panstrongylus. From the order Blattaria, for example, the Asian cockroach, the American cockroach, Blattela germanica and Supella spp. From the subclass Acaria (Acarida) and the orders Mesostigmata, for example, the genera Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp. spp.), Pneumonyssus spp., Sternostoma spp. and Varroa spp. From the suborder Actinedida (Prostigmata) and Acaridida (Astigmata), for example Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp. spp.), Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp. and Laminosioptes spp.

[0113] The compositions according to the invention are suitable for protecting materials such as wood, textiles, plastics, adhesives, glues, paints, paper and card, leather, floor coverings and also buildings against insect infestation.

[0114] The compositions according to the invention can be used, for example, against the following pests: beetles, such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinuspecticornis, Dendrobium pertinex, pine wood beetles, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicolis, planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthesrugicollis, Xyleborus spec., Tryptodendron spec., Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. and Dinoderus minutus, and also insects of the order Hymenoptera, for example Sirex juveniles. juvencus, Urocerus gigas, Urocerus gigas taignus and Urocerus augur and termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicolaindicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis and Coptotermes formosanus and silverfish such as Lepisma saccharina. The compounds of formula I and I'a or salts thereof are particularly suitable for controlling one or more pests selected from the following families: Noctuidae, Plutellidae, Chrysomelidae, Thripidae, Pentatomidae, Tortricidae, Delphacidae, Aphididae, Noctuidae, Crambidae, Meloidogynidae and Heteroderidae. In preferred embodiments of each aspect, compound TX (the abbreviation "TX" means "one compound selected from the compounds defined in Tables 1 to 7 and Table P") controls one or more pests selected from the following families: Noctuidae, Plutellidae, Chrysomelidae, Thripidae, Pentatomidae, Tortricidae, Delphacidae, Aphididae, Noctuidae, Crambidae, Meloidogynidae, and Heteroderidae.

[0115] The compounds of formula I and I'a or salts thereof are particularly suitable for controlling one or more pests selected from the following genera: Spodoptera spp., Plutella spp., Frankliniella spp., Thrips spp., Euschistus spp., Cydia spp., Nilaparvata spp., Myzus spp., Aphis spp., Diabrotica spp., Rhopalosiphum spp., Pseudoplusia spp. and Chilo spp. In a preferred embodiment of each aspect, the compound TX (the abbreviation "TX" means "one compound selected from the compounds defined in Tables 1 to 7 and Table P") controls one or more pests selected from the following genera: Spodoptera spp., Plutella spp., Frankliniella spp., Thrips spp., Euschistus spp., Cydia spp., Nilaparvata spp., Myzus spp., Aphis spp., Diabrotica spp., Rhopalosiphum spp., Pseudoplusia spp., and Chilo spp.

[0116] The compounds of formula I and I'a or salts thereof are particularly suitable for controlling one or more of Spodoptera littoralis, diamondback moth (Plutella xylostella), western flower thrips (Frankliniella occidentalis), onion thrips (Thrips tabaci), Euschistus heros, codling moth (Cydia pomonella), brown planthopper (Nilaparvata lugens), green peach aphid (Myzus persicae), Chrysodeixis includens, bean aphid (Aphis craccivora), Diabrotica balteata, Rhopalosiphum padi and rice stem borer (Chilo suppressalis).

[0117] In a preferred embodiment of each aspect, compound TX (wherein the abbreviation "TX" means "one compound selected from the compounds defined in Tables 1 to 7 and Table P") is effective against Spodoptera littoralis, diamondback moth (Plutella xylostella), western flower thrips (Frankliniella occidentalis), onion thrips (Thrips tabaci), Euschistus heros, codling moth (Cydia pomonella), brown planthopper (Nilaparvata lugens), green peach aphid (Myzus persicae), Chrysodeixis includens, bean aphid (Aphis craccivora), Diabrotica balteata, Rhopalosiphum padiata, Padia and the Egyptian armyworm (Spodoptera littoralis) + TX, diamondback moth (Plutella xylostella) + TX, and other rice stem borers (Chilo Suppressalis); western flower thrips (Frankliniella occidentalis) + TX, onion thrips (Thrips tabaci) + TX, Euschistus heros + TX, codling moth (Cydia pomonella) + TX, brown planthopper (Nilaparvata lugens) + TX, green peach aphid (Myzus persicae) + TX, Chrysodeixis includens + TX, bean aphid (Aphis craccivora) + TX, Diabrotica balteata + TX, Rhopalosiphum Padi) + TX and rice stem borer (Chilo suppressalis) + TX.

[0118] In an embodiment of each aspect, one compound in Tables 1-7 and Table P is effective against Spodoptera littoralis, Plutella xylostella, Frankliniella occidentalis, Thrips tabaci, Euschistus heros, Cydia pomonella, Nilaparvata lugens, Myzus persicae, Chrysodeixis includens, Aphis craccivora, Diabrotica balteata, Rhopalosiphum padiata, Rhopalosiphum nigricans ... It is suitable for controlling the rice stem borer (Chilo suppressalis) and the rice stem borer (Padia).

[0119] In one embodiment, one compound from Tables 1 to 7 and Table P is suitable for controlling Mamestra (preferably in vegetables), codling moth (Cydia pomonella) (preferably in apple), Empoasca (preferably in vegetables, vineyards), Leptinotarsa ​​(preferably in potato) and Chilo supressalis (preferably in rice).

[0120] Compounds according to the invention may have any number of benefits, including, inter alia, advantageous levels of biological activity for protecting plants from insects or superior properties for use as pesticide active ingredients (e.g., better biological activity, favorable spectrum of activity, increased safety profile (against above- and below-ground non-target organisms such as fish, birds and bees), improved physicochemical properties or increased biodegradability). In particular, it has surprisingly been found that certain compounds of formula (I) may exhibit advantageous safety profiles against non-target arthropods, particularly pollinators such as honeybees, solitary bees and bumblebees, most particularly the European honeybee (Apis mellifera).

[0121] Although the compounds according to the present invention can be used as pesticides in their native form, they are generally formulated into compositions using formulation aids such as carriers, solvents, and surfactants in various ways.The formulations can be in various physical forms, such as dusts, gels, wettable powders, water-dispersible granules, water-dispersible tablets, effervescent pellets, emulsifiable concentrates, microemulsifiable concentrates, oil-in-water emulsions, oil flowables, aqueous dispersions, oil dispersions, suspoemulsions, capsule suspensions, emulsifiable granules, soluble liquids, water-soluble concentrates (with water or water-miscible organic solvents as carriers), impregnated polymer films, or other forms known from, for example, the Manual on Development and Use of FAO and WHO Specifications for Pesticides, United Nations, First Edition, Second Revision (2010).Such formulations can be used directly or diluted before use.Dilution can be carried out, for example, with water, liquid fertilizer, trace elements, biological organisms, oil, or solvents.

[0122] The formulations can be prepared, for example, by mixing the active ingredient with formulation adjuvants to obtain a composition in the form of a finely divided solid, granules, solution, dispersion or emulsion. The active ingredient can also be formulated with other adjuvants, such as finely divided solids, mineral oil, oils of vegetable or animal origin, modified oils of vegetable or animal origin, organic solvents, water, surfactants or combinations thereof.

[0123] The active ingredient can also be contained in extremely small microcapsules. Microcapsules contain the active ingredient in a porous carrier, allowing the active ingredient to be released into the environment in controlled amounts (e.g., sustained release). Microcapsules typically have diameters of 0.1 to 500 microns. They contain the active ingredient in an amount of approximately 25 to 95% by weight of the capsule. The active ingredient can be in the form of a monolithic solid, fine particles in a solid or liquid dispersion, or a suitable solution. The encapsulating membrane can comprise, for example, natural or synthetic rubber, cellulose, styrene / butadiene copolymer, polyacrylonitrile, polyacrylate, polyester, polyamide, polyurea, polyurethane, or chemically modified polymers and starch xanthate, or other polymers known to those skilled in the art. Alternatively, fine microcapsules can be formed in which the active ingredient is contained in the form of finely divided particles in a solid matrix of a base material, but the microcapsules themselves are not encapsulated.

[0124] The formulation auxiliaries suitable for preparing the compositions according to the invention are known per se. Liquid carriers include water, toluene, xylene, petroleum ether, vegetable oils, acetone, methyl ethyl ketone, cyclohexanone, acid anhydrides, acetonitrile, acetophenone, amyl acetate, 2-butanone, butylene carbonate, chlorobenzene, cyclohexane, cyclohexanol, alkyl esters of acetic acid, diacetone alcohol, 1,2-dichloropropane, diethanolamine, p-diethylbenzene, diethylene glycol, diethylene glycol abietic acid, diethylene glycol butyl ether, diethylene glycol ethyl ether, diethylene glycol methyl ether, N,N-dimethylformamide, dimethyl sulfoxide, 1,4-dioxane, dipropylene glycol, dipropylene glycol methyl ether, dipropylene glycol dibenzoate, diproxitol, alkylpyrrolidone, ethyl acetate, 2-ethylhexanol, ethylene carbonate, 1,1,1-Trichloroethane, 2-heptanone, alpha-pinene, d-limonene, ethyl lactate, ethylene glycol, ethylene glycol butyl ether, ethylene glycol methyl ether, gamma-butyrolactone, glycerol, glycerol acetate, glycerol diacetate, glycerol triacetate, hexadecane, hexylene glycol, isoamyl acetate, isobornyl acetate, isooctane, isophorone, isopropyl benzene, isopropyl myristate, lactic acid, laurylamine, mesityl oxide, methoxypropanol, methyl isoamyl ketone, methyl isobutyl ketone, methyl laurate, methyl octanoate, methyl oleate, methylene chloride, m-xylene, n-hexane, n-octylamine, octadecanoic acid, octylamine acetate , oleic acid, oleylamine, o-xylene, phenol, polyethylene glycol, propionic acid, propyl lactate, propylene carbonate, propylene glycol, propylene glycol methyl ether, p-xylene, toluene, triethyl phosphate, triethylene glycol, xylene sulfonic acid, paraffin, mineral oil, trichloroethylene, perchloroethylene, ethyl acetate, amyl acetate, butyl acetate, propylene glycol methyl ether, diethylene glycol methyl ether, methanol, ethanol, isopropanol, and higher molecular weight alcohols such as amyl alcohol, tetrahydrofurfuryl alcohol, hexanol, octanol, ethylene glycol, propylene glycol, glycerol, N-methyl-2-pyrrolidone, and the like may be used.

[0125] Suitable solid carriers are, for example, talc, titanium dioxide, pyrophyllite clay, silica, attapulgite clay, diatomaceous earth, limestone, calcium carbonate, bentonite, calcium montmorillonite, cottonseed kernels, wheat flour, soybean flour, pumice, wood flour, ground walnut kernels, lignin and similar substances.

[0126] Many surface-active substances can be used advantageously in both solid and liquid formulations, especially those that can be diluted with a carrier before use. The surface-active substances can be anionic, cationic, nonionic, or polymeric, and can be used as emulsifying agents, wetting agents, or suspending agents, or for other purposes. Typical surface-active substances include, for example, salts of alkyl sulfates, such as diethanolammonium lauryl sulfate; salts of alkylarylsulfonates, such as calcium dodecylbenzenesulfonate; alkylphenol / alkylene oxide adducts, such as nonylphenol ethoxylate; alcohol / alkylene oxide adducts, such as tridecyl alcohol ethoxylate; soaps, such as sodium stearate; salts of alkylnaphthalenesulfonates, such as sodium dibutylnaphthalenesulfonate; dialkyl esters of sulfosuccinates, such as sodium di(2-ethylhexyl)sulfosuccinate; sorbitol esters, such as sorbitol oleate; quaternary amines, such as lauryltrimethylammonium chloride, polyethylene glycol esters of fatty acids, such as polyethylene glycol stearate; block copolymers of ethylene oxide and propylene oxide; and salts of mono- and dialkyl phosphate esters; and also further substances, such as those described in McCutcheon's Detergents and Emulsifiers Annual, MC Publishing Corp., Ridgewood, New Jersey (1981).

[0127] Further adjuvants that can be used in the pesticidal formulations include crystallization inhibitors, viscosity modifiers, suspending agents, dyes, antioxidants, foaming agents, light absorbers, mixing aids, antifoaming agents, complexing agents, neutralizing or pH adjusting substances and buffers, corrosion inhibitors, fragrances, wetting agents, absorption enhancers, micronutrients, plasticizers, glidants, lubricants, dispersants, thickeners, antifreeze agents, fungicides and liquid and solid fertilizers.

[0128] The composition according to the present invention may contain an additive comprising a vegetable oil or animal oil, a mineral oil, an alkyl ester of such oils, or a mixture of such oils and oil derivatives. The amount of oil additive in the composition according to the present invention is generally 0.01 to 10% based on the mixture to be applied. For example, the oil additive can be added to the spray tank at the desired concentration after preparing the spray mixture. Preferred oil additives include mineral oil or vegetable oils such as rapeseed oil, olive oil, or sunflower oil, emulsified vegetable oil, alkyl esters of vegetable oils, e.g., methyl derivatives, or animal oils such as fish oil or beef tallow. Preferred oil additives include C8 to C 22 Alkyl esters of fatty acids, especially C 12 ~C 18 Methyl derivatives of fatty acids, such as the methyl esters of lauric acid, palmitic acid, and oleic acid (methyl laurate, methyl palmitate, and methyl oleate, respectively), are included. Many oil derivatives are listed in the Compendium of Herbicide Adjuvants, 10 th Edition, Southern Illinois University, 2010.

[0129] The compositions of the present invention generally comprise 0.1 to 99% by weight, especially 0.1 to 95% by weight, of a compound of the present invention and 1 to 99.9% by weight of formulation adjuvants, preferably including 0 to 25% by weight of a surfactant. Commercial products are preferably formulated as concentrates, although end users will typically utilize diluted formulations.

[0130] The application rates vary within wide limits and depend on the nature of the soil, the method of application, the crop plant, the pests to be controlled, the prevailing weather conditions and other factors which depend on the method, time of application and target crop. As a general guideline, the compounds may be applied at a rate of 1 to 2000 l / ha, especially 10 to 1000 l / ha.

[0131] A preferred formulation may have the following composition (by weight): Emulsifiable concentrate: Active ingredient: 1-95%, preferably 60-90% Surfactant: 1 to 30%, preferably 5 to 20% Liquid carrier: 1 to 80%, preferably 1 to 35% Powder: Active ingredient: 0.1 to 10%, preferably 0.1 to 5% Solid carrier: 99.9 to 90%, preferably 99.9 to 99% Suspension concentrates: Active ingredient: 5-75%, preferably 10-50% Water: 94-24%, preferably 88-30% Surfactant: 1 to 40%, preferably 2 to 30% Wettable powder: Active ingredient: 0.5 to 90%, preferably 1 to 80% Surfactant: 0.5 to 20%, preferably 1 to 15% Solid carrier: 5 to 95%, preferably 15 to 90% Granules: Active ingredient: 0.1 to 30%, preferably 0.1 to 15% Solid carrier: 99.5 to 70%, preferably 97 to 85%

[0132] The following examples further illustrate, but do not limit, the present invention.

[0133] [Table 4]

[0134] This combination is thoroughly mixed with adjuvants and the mixture is thoroughly ground in a suitable mill to give a wettable powder which is diluted with water to give a suspension of the desired concentration.

[0135] [Table 5]

[0136] This combination is thoroughly mixed with an adjuvant and the mixture is thoroughly ground in a suitable mill to obtain a dust that can be used directly as a seed treatment.

[0137] [Table 6]

[0138] Emulsions of any desired dilution that can be used for plant protection are obtained from this concentrate by dilution with water.

[0139] [Table 7]

[0140] Ready-to-use dusts are obtained by combining and mixing with a carrier and grinding the mixture in a suitable mill. Such powders can also be used as dry fertilizers for seeds.

[0141] [Table 8]

[0142] This combination is mixed with an adjuvant, ground, and the mixture is wetted with water, extruded, and then dried in a stream of air.

[0143] [Table 9]

[0144] This micronized combination is applied uniformly in a mixer to kaolin wetted with polyethylene glycol, thus obtaining coated granules that do not generate dust.

[0145] [Table 10]

[0146] The finely ground combination is intimately mixed with adjuvants to form a suspension concentrate which can be diluted with water to obtain any desired dilution of suspension, and can be used to treat and protect living plants and plant propagation material against microbial infestation by spraying, pouring, or dipping.

[0147] [Table 11]

[0148] The finely ground combination is intimately mixed with adjuvants to form a suspension concentrate which can be diluted with water to obtain any desired dilution of suspension, and can be used to treat and protect living plants and plant propagation material against microbial infestation by spraying, pouring, or dipping.

[0149] extended-release capsule suspension 28 parts of the combination are mixed with 2 parts aromatic solvent and 7 parts toluene diisocyanate / polymethylene-polyphenylisocyanate (8:1) mixture. This mixture is emulsified in a mixture of 1.2 parts polyvinyl alcohol, 0.05 parts antifoaming agent, and 51.6 parts water until the desired particle size is achieved. To this emulsion, a mixture of 2.8 parts 1,6-diaminohexane in 5.3 parts water is added. The mixture is stirred until the polymerization reaction is complete. The resulting capsule suspension is stabilized by adding 0.25 parts thickener and 3 parts dispersant. This capsule suspension formulation contains 28% active ingredient. The average capsule diameter is 8 to 15 microns. The resulting formulation is applied to seeds as an aqueous suspension in equipment suitable for this purpose.

[0150] Formulation types include emulsion concentrates (EC), suspension concentrates (SC), suspoemulsions (SE), capsule suspensions (CS), water dispersible granules (WG), emulsifiable granules (EG), emulsions, water-in-oil (EO), emulsions, oil-in-water (EW), microemulsions (ME), oil dispersions (OD), oil-miscible flowables (OF), oil-miscible liquids (OL), soluble concentrates (SL), ultra-low volume suspensions (SU), ultra-low volume liquids (UL), technical concentrates (TK), dispersible concentrates (DC), wettable powders (WP), soluble granules (SG) or any technically desirable formulation in combination with agriculturally acceptable adjuvants. [Example]

[0151] Preparation Examples: LCMS method: Method 1: Spectra were recorded on a Waters Corporation mass spectrometer (SQD, SQDII, or QDA single quadrupole mass spectrometer) equipped with an electrospray source (polarity: positive and negative ions), capillary: 0.8-3.00 kV, cone: 5-30 V, source temperature: 120-150 °C, desolvation temperature: 350-600 °C, cone gas flow: 50-150 l / h, desolvation gas flow: 650-1000 l / h, mass range: 110-950 Da, and a Waters Corporation Acquity UPLC: binary pump, heated column compartment, diode array detector, and ELSD. Column: Waters UPLC HSS T3, 1.8 μm, 30 × 2.1 mm; Temperature: 60 °C; DAD wavelength range (nm): 210–400; Run time: 1.5 min; Solvent: A = water + 5% MeOH + 0.05% HCOOH, B = acetonitrile + 0.05% HCOOH; Flow rate (ml / min): 0.85; Gradient: 10% B isocratic for 0.2 min, then 10–100% B for 1.0 min, 100% B isocratic for 0.2 min, 100–10% B for 0.05 min, 10% B isocratic for 0.05 min.

[0152] The following abbreviations are used in the experimental description below: s = singlet, d = doublet, t = triplet, q = quartet, m = multiplet, RT = retention time, min = minutes.

[0153] Example P1: 1-[5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carbonyl]-N-ethyl-N-methyl-piperidine-4-sulfonamide (compound P.4): [ka] Step 1: Ethyl 5-cyano-6-hydroxy-2-(trifluoromethyl)pyridine-3-carboxylate [ka] A solution of sodium ethoxide (1.1 equiv.) in ethanol (20% w / w) was slowly added to a suspension of 2-cyanoacetamide (5.9 g, 70.2 mmol, 1 equiv.) at 4 °C, and the mixture was stirred for 15 min. Next, a solution of ethyl 2-(ethoxymethylene)-4,4,4-trifluoro-3-oxobutanoate (17 g, 70.1 mmol) in 34 ml of ethanol was added under ice cooling. The reaction mixture was stirred for 16 h and allowed to reach room temperature. The reaction mixture was then poured into an ice-cold solution of 1 N hydrochloric acid. The resulting mixture was diluted with ice-cold water and stirred for 20 min. The precipitate was filtered, washed twice with ice-cold water, and dried. 12.4 g of ethyl 5-cyano-6-hydroxy-2-(trifluoromethyl)pyridine-3-carboxylate was obtained with a purity greater than 95% as determined by quantitative NMR. 1 H-NMR[ppm] in CDCl3: 1.29(t,3H),4.29(q,2H),8.27(s,1H).

[0154] Step 2: Ethyl 6-chloro-5-cyano-2-(trifluoromethyl)pyridine-3-carboxylate [ka] Ethyl 5-cyano-6-hydroxy-2-(trifluoromethyl)pyridine-3-carboxylate (7.00 g, 26.9 mmol) was suspended in dichloromethane (100 mL) and DMF (1 mL), and the mixture was cooled to 0° C., followed by the addition of oxalyl chloride (6.83 mL, 80.7 mmol). The reaction mixture was refluxed for 6 hours, cooled to room temperature, diluted with saturated sodium carbonate solution, extracted with dichloromethane (3×250 mL), dried over NaSO, concentrated under reduced pressure, and purified by chromatography (hexane:ethyl acetate 5:1) to give 5.12 g of ethyl 6-chloro-5-cyano-2-(trifluoromethyl)pyridine-3-carboxylate as a white solid. 1 H-NMR[ppm] in CDCl3: 1.42(t,3H),4.46(q,2H),8.45(s,1H).

[0155] Step 3: Ethyl 5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carboxylate [ka] To a solution of ethyl 6-chloro-5-cyano-2-(trifluoromethyl)pyridine-3-carboxylate (4.00 g, 14.4 mmol) in toluene (28.7 mL) under argon was added potassium carbonate (1.98 g, 14.4 mmol), [4-(trifluoromethyl)phenyl]boronic acid (2.73 g, 14.4 mmol), and tetrakis(triphenylphosphine)palladium(0) (0.855 g, 0.718 mmol, 0.05 equiv.). The suspension was heated under reflux for 4 hours. The reaction mixture was diluted with water and saturated ammonium chloride solution and extracted three times with ethyl acetate. The combined organic layers were extracted with water and brine, dried over sodium sulfate, and concentrated. The residue was purified on a silica column to give 4.43 g of ethyl 5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carboxylate as a white solid. 1H-NMR[ppm] in CDCl3: 1.45(t,3H),4.52(q,2H),7.86(d,2H),8.22(d,2H),8.61(s,1H);LC-MS(method 1):RT=1.19min;[M+H] + =389.

[0156] Step 4: 5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carboxylic acid [ka] To a solution of ethyl 5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carboxylate (1.70 g, 4.4 mmol) in tetrahydrofuran (11 mL) and water (5.3 mL) was added lithium hydroxide monohydrate (0.75 g, 18 mmol, 4 equivalents). The reaction mixture was stirred for 2 hours at room temperature. The reaction mixture was then diluted with ethyl acetate and 2N hydrochloric acid and extracted three times with ethyl acetate. The combined organic layers were extracted with water and brine, dried over sodium sulfate, and concentrated under reduced pressure to give 1.47 g of 5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carboxylic acid. 1 H-NMR[ppm] in DMSO-d6: 8.02(d,2H),8.14(d,2H),8.99(s,1H),14.3(broad s,1H);LC-MS(method 1):RT=0.95min;[M+H] + =361.

[0157] Step 5: tert-Butyl 4-[ethyl(methyl)sulfamoyl]piperidine-1-carboxylate [ka] To a solution of commercially available tert-butyl 4-chlorosulfonylpiperidine-1-carboxylate (10.0 g, 33.5 mmol) in tetrahydrofuran (100 mL) was added N-ethyl-methylamine (8.9 mL, 100.4 mmol, 3 equiv.). The reaction was stirred at room temperature for 12 hours. The reaction mixture was poured into water and extracted with ethyl acetate. The combined organic layers were washed with water and brine, dried over sodium sulfate, and concentrated under reduced pressure. The residue was purified by combiflash (30-60% EtOAc / cyclohexane) to give 7.6 g of tert-butyl 4-[ethyl(methyl)sulfamoyl]-piperidine-1-carboxylate. 1 H-NMR [ppm] in CDCl3: 1.21 (t, 3H), 1.45 (s, 9H), 1.62-1.78 (m, 2H), 2.01 (broad d, 2H), 2.60-2.78 (m, 2H), 2.90 (s, 3H), 2.99-3.08 (m, 1H), 3.29 (q, 2H), 4.24 (broad s, 2H).

[0158] Step 6: N-ethyl-N-methyl-piperidin-1-ium-4-sulfonamide chloride [ka] tert-Butyl 4-[ethyl(methyl)sulfamoyl]piperidine-1-carboxylate (7.6 g, 24 mmol) was dissolved in methanol (76 mL) and a solution of hydrogen chloride (3 mol / L) in methanol (94 mmol, 4 equivalents) was added. The reaction mixture was stirred at room temperature for 12 hours, and then the solvent was evaporated. The crude product was triturated with tert-butyl methyl ether to give 5.7 g of N-ethyl-N-methyl-piperidin-1-ium-4-sulfonamide chloride. 1 H-NMR[ppm] in DMSO-d6: 1.22(t,3H),1.85-1.98(m,2H),2.24(broad d,2H),2.85(s,3H),2.94-3.05(m,2H),3.24(q,2H),3.46-3.63(m,3H).

[0159] Step 7: 1-[5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carbonyl]-N-ethyl-N-methyl-piperidine-4-sulfonamide (Compound P.4) [ka] To a solution of 5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carboxylic acid (200 mg, 0.555 mmol) in dimethylformamide (5 mL) was added N-ethyl-N-methyl-piperidin-1-ium-4-sulfonamide chloride (202 mg, 0.833 mmol, 1.50 equiv.), followed by the addition of HATU coupling reagent (239 mg, 0.611 mmol, 1.1 equiv.) and N,N-diisopropyl-ethylamine (0.34 mL, 2.00 mmol, 3.6 equiv.). The reaction mixture was stirred at room temperature for 3 hours. The reaction was quenched with NaHCO3 solution and extracted three times with ethyl acetate. The combined organic layers were dried over sodium sulfate and concentrated under reduced pressure. The residue was purified by Combiflash to give 150 mg of 1-[5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carbonyl]-N-ethyl-N-methyl-piperidine-4-sulfonamide as a white foam. 1 H-NMR[ppm], in CDCl3: 1.22-1.28(m,3H),1.71-2.03(m,2H),2.06-2.16(m,1H),2.18-2.37(m,1H),2.86-3.06(m,1H),2.94(s,3H),3.12-3 .24(m,2H),3.29-3.39(m,2H),3,56(t,1H),4.86(dd,1H),7.87(d,2H),8.19(d,2H),8.12 and 8.22(2s,1H).LC-MS(Method 1): RT=1.09min;[M+H] + =549.

[0160] Example P2: 1-[5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carbonyl]-N-ethyl-piperidine-4-sulfonamide (compound P.6): [ka] Step 1: tert-Butyl 4-(ethylsulfamoyl)piperidine-1-carboxylate [ka] To a solution of commercially available tert-butyl 4-chlorosulfonylpiperidine-1-carboxylate (1.5 g, 5.0 mmol) in tetrahydrofuran (15 mL) was added a solution of N-ethylamine in water (approximately 12 mol / L, 1.6 mL, 25 mmol, 5 equivalents). The reaction was stirred at room temperature for 2 hours. The reaction mixture was concentrated to dryness under reduced pressure. The residue was triturated with cold water to give 1.4 g of tert-butyl 4-(ethylsulfamoyl)piperidine-1-carboxylate. 1 H-NMR [ppm] in DMSO-d6: 1.07 (t, 3H), 1.40 (s, 9H), 1.36-1.45 (m, 2H), 1.94 (broad d, 2H), 2.62-2.9 (broad s, 2H), 2.91-3.01 (m, 2H), 3.10-3.24 (m, 1H), 3.95-4.08 (broad d, 2H), 7.09 (t, 1H).

[0161] Step 2: N-Ethyl-piperidin-1-ium-4-sulfonamide chloride [ka] tert-Butyl 4-(ethylsulfamoyl)piperidine-1-carboxylate (1.4 g, 4.5 mmol) was dissolved in methanol (14 mL) and a solution of hydrogen chloride (3 mol / L) in methanol (18 mmol, 4 equivalents) was added. The reaction mixture was stirred at room temperature for 12 hours, and then the solvent was evaporated. The crude product was triturated with acetonitrile to give 1.1 g of N-ethyl-piperidin-1-ium-4-sulfonamide chloride.1 H-NMR[ppm] in DMSO-d6: 1.06(t,3H),1.75-1.90(m,2H),2.24(broad d,2H),2.91-3.02(m,2H),3.03(q,2H),3.39-3.53(m,3H).

[0162] Step 3: 1-[5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carbonyl]-N-ethyl-piperidine-4-sulfonamide (Compound P.6) [ka] To a solution of 5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carboxylic acid (200 mg, 0.555 mmol) in dimethylformamide (5 mL) was added N-ethyl-piperidin-1-ium-4-sulfonamide chloride (191 mg, 0.833 mmol, 1.50 equiv.), followed by the addition of HATU coupling reagent (239 mg, 0.611 mmol, 1.1 equiv.) and N,N-diisopropyl-ethylamine (0.34 mL, 2.00 mmol, 3.6 equiv.). The reaction mixture was stirred at room temperature for 3 hours. The reaction was quenched with NaHCO3 solution and extracted three times with ethyl acetate. The combined organic layers were dried over sodium sulfate and concentrated under reduced pressure. The residue was purified by Combiflash to give 145 mg of 1-[5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carbonyl]-N-ethyl-piperidine-4-sulfonamide as a white foam. 1 H-NMR[ppm] in DMSO-d6: 1.04-1.13(m,3H),1.35-1.58(m,1H),1.62-1.81(m,1H),1.81-1.94(broad t,1H),2.06-2.18(m,1H),2.85-3.42( m,5H),3.52-3.68(m,1H),3,61(broad t,1H),7.14(t,1H),8.02(d,2H),8.14(d,2H),8.88 and 9.04(2s,1H).LC-MS(Method 1): RT=1.04min;[M+H]+ =535.

[0163] Table P: Compounds of formula (Ia) [ka] The compounds in Table P may be prepared as described in the Examples above or by similar methodologies. The following abbreviations are used in the tables below: Rt = retention time, min = minutes.

[0164] [Table 12]

[0165] The activity of the compositions according to the invention can be broadened considerably by adding other insecticidal, acaricidal and / or fungicidal active ingredients, and adapted to the prevailing conditions. Mixtures of compounds of formula (I) with other insecticidal, acaricidal and / or fungicidal active ingredients can also have unexpected advantages, which can be described as synergistic activity in a broader sense. For example, better plant resistance, reduced phytotoxicity, insects can be controlled during their production, for example, during grinding or mixing, during their storage or during their use, at different developmental stages, or better behavior.

[0166] Suitable additives to the active ingredients herein are, for example, exemplified by the following classes of active ingredients: organophosphorus compounds, nitrophenol derivatives, thioureas, juvenile hormones, formamidines, benzophenone derivatives, urea, pyrrole derivatives, carbamates, pyrethroids, chlorinated hydrocarbons, acylureas, pyridylmethyleneamino derivatives, macrolides, neonicotinoids and Bacillus thuringiensis preparations.

[0167] The following mixtures of compounds of formula (I) and active substances in a 1:1 weight ratio are preferred (the abbreviation "TX" means "one compound selected from the compounds defined in Tables 1 to 7 and Table P"): (7E,9Z)-dodeca-7,9-dien-1-yl acetate + TX, (9Z,11E)-tetradec-9,11-dien-1-yl acetate + TX, (9Z,12E)-tetradec-9,12-dien-1-yl acetate + TX, (E)-6-methylhept-2-en-4-ol + TX, (E)-dec-5-en-1-yl acetate and (E)-dec-5-en-1-ol + TX, (E)-tridec-4-en-1-yl acetate + TX, (E,Z)-tetradec-4,10-dien-1-yl acetate + TX, yl acetate + TX, (Z)-dodec-7-en-1-yl acetate + TX, (Z)-hexadec-11-en-1-yl acetate + TX, (Z)-hexadec-11-enal + TX, (Z)-hexadec-13-en-11-yn-1-yl acetate + TX, (Z)-icos-13-en-10-one + TX, (Z)-tetradec-7-en-1-al + TX, (Z)-tetradec-9-en-1-ol + TX, (Z)-tetradec-9-en-1-yl acetate + TX, 1,2-dibromobenzoate Bromo-3-chloropropane + TX, 1,2-dichloropropane + TX, 1,2-dichloropropane and 1,3-dichloropropene + TX, 1,3-dichloropropene + TX, 14-methyloctadec-1-ene + TX, 1-hydroxy-1H-pyridine-2-thione + TX, 2-(octylthio)ethanol + TX, 2-chlorophenyl N-methylcarbamate (CPMC) + TX, 3-(4-chlorophenyl)-5-methylrhodanine + TX, 3,4-dichlorotetrahydrothiophene 1,1-dioxide +TX, 4-(quinoxalin-2-ylamino)benzenesulfonamide +TX, 4-methylnonan-5-ol and 4-methylnonan-5-one +TX, 5-methyl-6-thioxo-1,3,5-thiadiazinan-3-ylacetic acid +TX, 6-isopentenylaminopurine +TX, 8-hydroxyquinoline sulfate +TX, abamectin +TX, acequinocyl +TX, acetamiprid +TX, acetoprole +TX, acrinathrin +TX, acinonapyr +TX, Adoxophyes orana GV +TX, aphidpiropen +TX, afoxolaner +TX, Agrobacterium radiobacter +TX,AKD-3088+TX, alanycarb+TX, aldicarb+TX, aldoxycarb+TX, allethrin+TX, alpha-cypermethrin+TX, alphamethrin+TX, alpha-multistriatin+TX, Amblyseius spp.+TX, amidoflumet+TX, amino acids+TX, aminocarbn+TX, Anagrapha falcifera NPV+TX, Anagrus atomus+TX, Aphelinus abdominalis+TX, Aphidius colemani+TX, Aphidoletes aphidimyza+TX, afolate+TX, Autographa californica NPV+TX, AZ 60541 + TX, azadirachtin + TX, azocyclotin + TX, Bacillus aizawai + TX, Bacillus chitinosporus AQ746 (NRRL accession number B-21618) + TX, Bacillus firmus + TX, Bacillus kurstaki + TX, Bacillus mycoides AQ726 (NRRL accession number B-21664) + TX, Bacillus pumilus (NRRL accession number B-30087) + TX, Bacillus pumilus AQ717 (NRRL accession number B-21662) + TX, Bacillus sp.) AQ175 (ATCC accession number 55608) + TX, Bacillus sp.) AQ177 (ATCC accession number 55609) + TX, Bacillus sp.) AQ178 (ATCC accession number 53522) + TX, Bacillus sphaericus Neide + TX, Bacillus subtilis AQ153 (ATCC accession number 55614) + TX,Bacillus subtilis AQ30002 (NRRL accession number B-50421) + TX, Bacillus subtilis AQ30004 (NRRL accession number B-50455) + TX, Bacillus subtilis AQ713 (NRRL accession number B-21661) + TX, Bacillus subtilis AQ743 (NRRL accession number B-21665) + TX, Bacillus subtilis non-specified species + TX, Bacillus thuringiensis AQ52 (NRRL accession number B-21619) + TX, Bacillus thuringiensis thuringiensis BD#32 (NRRL accession number B-21530) + TX, Bacillus thuringiensis Berliner + TX, Bacillus thuringiensis subsp. Aizawai + TX, Bacillus thuringiensis subsp. Israelensis + TX, Bacillus thuringiensis subsp. Japonensis + TX, Bacillus thuringiensis subsp. Kurstaki + TX, Bacillus thuringiensis subsp. Tenebrionis + TX, Bacillus thuringiensis thuringiensis subspecies kurstaki BMP 123+TX, Beauveria bassiana+TX, Beauveria brongniartii+TX, Benclotiaz+TX, Benomyl+TX, Bensultap+TX, Benzoximate+TX, Benzpyrimoxane+TX, Beta-cyfluthrin+TX, Beta-cypermethrin+TX, Bethoxazin+TX, Bifenazate+TX,Bifenthrin + TX, Binapacryl + TX, Bioallethrin + TX, Bioresmethrin + TX, Bis(tributyltin)oxide + TX, Visadyl + TX, Bistrifluron + TX, Brevicomin + TX, Brofuranilide + TX, Broflutrinate + TX, Bromoacetamide + TX, Bromophos-ethyl + TX, Bronopol + TX, Buprofezin + TX, Busulfan + TX, Butocarboxim + TX, Butopyronoxyl + TX, Butoxy(polypropylene glycol) + TX, Butylpyridaben + TX, Cadusafos + TX, Arsenic Acid Carboxylate Sodium + TX, Carbaryl + TX, Carbofuran + TX, Carbon disulfide + TX, Carbosulfan + TX, Cartap + TX, CAS Number: 1594624-87-9 + TX, CAS Number: 1922957-47-8 + TX, CAS Number: 1255091-74-7 + TX, CAS Number: 1365070-72-9 + TX, CAS Number: 1445683-71-5 + TX, CAS Number: 1445684-82-1 + TX, CAS Number: 1594626-19-3 + TX, CAS Number: 1594637-65-6 + TX, CAS Number: 1632218- 00-8+TX, CAS number:1808115-49-2+TX, CAS number:1922957-45-6+TX, CAS number:1922957-46-7+TX, CAS number:1922957-48-9+TX, CAS number:1956329-03-5+TX, CAS number :1990457-52-7+TX, CAS number:1990457-55-0+TX, CAS number:1990457-57-2+TX, CAS number:1990457-66-3+TX, CAS number:1990457-77-6+TX, CAS number:1990457-85-6 +TX, CAS number:2032403-97-5+TX, CAS number:2044701-44-0+TX, CAS number:2095470-94-1+TX, CAS number:2128706-05-6+TX, CAS number:2133042-31-4+TX, CAS number:213 3042-44-9+TX, CAS number: 2171099-09-3+TX, CAS number: 2220132-55-6+TX, CAS number: 2368920-61-8+TX, CAS number: 2377084-09-6+TX, CAS number: 2396747-83-2+TX,CAS No.: 2408220-91-5 + TX, CAS No.: 2408220-94-8 + TX, CAS No.: 2415706-16-8 + TX, CAS No.: 2615135-05-0 + TX, CAS No.: 2719848-60-7 + TX, CAS No.: RNA (Leptinotarsa ​​decemlineata-specific recombinant double-stranded interfering GS2) + TX, chlorantraniliprole + TX, chlordane + TX, chlorfenapyr + TX, chloropicrin + TX, chlorprallethrin + TX, chlorpyrifos + TX, chromafenozide + TX, Chrysoperla carnea carnea) + TX, clenpirin + TX, cloetocarb + TX, clothianidin + TX, codlerua + TX, codlemone + TX, copper acetoarsenite + TX, copper octanoate + TX, copper hydroxide + TX, copper sulfate + TX, cresol + TX, crufomate + TX, Cryptolaemus montrouzieri + TX, curua + TX, cyanofenphos + TX, cyantraniliprole + TX, sibutrin + TX, cyclaniliprole + TX, cyclobutrifluram + TX, cycloprothrin + TX, cycloxaprid + TX, codling moth (Cydia pomella) pomonella))GV+TX, cyenopyrafen+TX, cyetopyrafen+TX, cyflumetofen+TX, cyfluthrin+TX, cyhalodiamide+TX, cyhalothrin+TX, cypermethrin+TX, cyphenothrin+TX, cyprofanilide+TX, Cyromazine + TX, cytokinin + TX, leaf conch wasp (Dacnusa sibirica) + TX, dazomet + TX, DBCP + TX, DCIP + TX, deltamethrin + TX, diafenthiuron + TX, dialifos + TX, diamidaphos + TX, dibrom + TX, dibutyl adipate + TX, dibutyl phthalate + TX, dibutyl succinate + TX, diclofenthion + TX, dichloron + TX, dichlorophen + TX, dicrifos + TX, dichloromezothiaz + TX, diethyltoluamide + TX, diflubenzuron + TX, Diglyphus isaea (Diglyphus isaea)) + TX, Dimatif + TX, Dimethoate + TX, Dimethylcarbamate + TX, Dimethylphthalate + TX, Zinpropylidaz + TX, Dinactin + TX, Dinocap + TX, Dinotefuran + TX, Dioxabenzophos + TX, Zinc Pyrithione + TX, Disparlure + TX, D-Limonene + TX, Dodec-8-en-1-yl acetate + TX, Dodec-9-en-1-yl acetate + TX, Dodeca-8,10-dien-1-yl acetate + TX, Dodisin + TX, Dominicale + TX, Doramectin + TX, Emamectin + TX, Emamectin Benzoate + TX, Empenthrin + TX, Encarsia formosa (Encarsia formosa)) + TX, Endothal + TX, Endrin + TX, Eprinomectin + TX, Epsilon-monfluorotrin + TX, Epsilon-metofluthrin + TX, Desert Wasp (Eretmocerus eremicus eremicus)) +TX, Esfenvalerate +TX, Ethion +TX, Ethiprole +TX, Ethoprophos +TX, Ethyl 4-methyloctanoate +TX, Ethyl hexanediol +TX, Ethylene dibromide +TX, Etofenprox +TX, Etoxazole +TX, Ethopirafen +TX, Eugenol +TX, Melasse-derived seaweed extract and fermented product +TX, Melasse-derived seaweed extract and fermented product containing urea +TX, Seaweed extract and fermented plant product +TX, Seaweed extract and fermented plant product containing plant hormones +TX, Vitamins +TX, EDTA-chelated copper +TX, Zinc +TX and iron +TX, Famful +TX, Fenaminosulf +TX,Fenamiphos + TX, fenazaquin + TX, fenfluthrin + TX, fenitrothion + TX, phenmezodithiaz + TX, fenobucarb + TX, fenothiocarb + TX, fenoxycarb + TX, fenpropathrin + TX, fenpyrad + TX, fenpyroximate + TX, fensulfothion + TX, fenthion + TX, fentin + TX, fentin acetate + TX, fenvalerate + TX, ferric phosphate hydrate + TX, fen Ipronil + TX, flometoquin + TX, flonicamid + TX, fluacrypyrim + TX, fluazaindolizine + TX, fluazuron + TX, flubendiamide + TX, flubenzimine + TX, fluchlordiniliprole + TX, flucythrinate + TX, flucycloxuron + TX, flucythrinate + TX, fluensulfone + TX, fluensulfone [318290-98-1] + TX, flufenerim + TX, flufenprox + TX , Flufiprole +TX, Fluhexafon +TX, Flumethrin +TX, Fluopyram +TX, Flupentiofenox, Flupyradifurone +TX, Flupirimine +TX, Flupiroxystribine +TX, Fluralaner +TX, Fluvalinate +TX, Fluxamethamide +TX, Formaldehyde +TX, Fosthiazate +TX, Fostietan +TX, Frontalin +TX, Furfural +TX, Gamma-Cyhalothrin +TX, Gossyplu re® (a 1:1 mixture of the (Z,E) and (Z,Z) isomers of hexadeca-7,11-dien-1-yl acetate) + TX, Grand Lure + TX, Grand Lure I + TX, Grand Lure II + TX, Grand Lure III + TX, Grand Lure IV + TX, Granulovirus + TX, Guadipyr + TX, GY-81 + TX, Halfenprox + TX, Halofenozide + TX, Harpin + TX, Helicoverpa armigera nuclear polyhedrosis virus + TX, Helicoverpa zea NPV + TX, Helicoverpa zea nuclear polyhedrosis virus + TX, Heliothis punctigera nuclear polyhedrosis virus + TX,Heliothis virescens nuclear polyhedrosis virus + TX, Hemel + TX, Hempa + TX, Heptafluthrin + TX, Heterophos + TX, Heterorhabditis bacteriophora and H. megidis + TX, Hexalua + TX, Hexamido + TX, Hexythiazox + TX, Hippodamia convergens convergens)) + TX, hydramethylnon + TX, hydralgafen + TX, hydrated lime + TX, imicyaphos + TX, imidacloprid + TX, imiprothrin + TX, indazapiroxameth + TX, indoxacarb + TX, iodomethane + TX, iprodione + TX, ipsdienol + TX, ipsenol + TX, isamidophos + TX, isazophos + TX, isocycloceram + TX, isofluara Nam (CAS number: 2892524-05-7) + TX, Isothioate + TX, Ivermectin + TX, Japonirua + TX, Kappa-bifenthrin + TX, Kappa-tefluthrin + TX, Kasugamycin + TX, Kasugamycin hydrochloride hydrate + TX, Kinetin + TX, Lambda-cyhalothrin + TX, Redoprona + TX, Lepimectin + TX, Leptomastix dactylopii (Leptomastix dactylopii + TX, Lineatin + TX, Littlea + TX, Looplua + TX, Lotilaner + TX, Lufenuron + TX, Macrolophus caliginosus + TX, Armyworm moth (Mamestra brassicae) NPV + TX, Mecarfone + TX, Medlura + TX, Megatomoic acid + TX, Metaflumizone + TX, Metaldehyde + TX, Metam + TX, Metam-potassium + TX, Metam-sodium + TX, Metaphycus helvolus + TX, Metarhizium anisopliae var. acridum + TX, Metarhizium anisopliae var. anisopliae + TX,Metarhizium spp. + TX, Metepa + TX, Methiocarb + TX, Methiotepa + TX, Methomyl + TX, Methoquin-butyl + TX, Methoxyfenozide + TX, Methyl afolate + TX, Methyl bromide + TX, Methyl eugenol + TX, Methyl isothiocyanate + TX, Methyl neodecanamide + TX, Metofluthrin + TX, Metolcarb + TX, Mexacarbate + TX, Milbemectin + TX, Milbemycin oxime + TX, Momfluorotrin + TX, Morzide + TX, Moxidectin + TX, Muscalua + TX, Muscodor albus 620 (NRRL accession number 30547) + TX, Muscodor roseus roseus) A3-5 (NRRL accession number 30548) + TX, Mulberry dark spot fungus (Myrothecium verrucaria) composition + TX, Naabum + TX, NC-184 + TX, Neem wood-based product + TX, Pine sawfly (Neodiprion ertifer) sertifer NPV and N. lecontei NPV + TX, nickel bis(dimethyldithiocarbamate) + TX, niclosamide + TX, niclosamide-olamine + TX, nicofluprole + TX, nitenpyram + TX, nithiazine + TX, nitrapyrin + TX, octadeca-2,13-dien-1-yl acetate + TX, octadeca-3,13-dien-1-yl acetate + TX, octilinone + TX, omethoate + TX, orfurala + TX, Orius spp. + TX, orictalua + TX, ostramon + TX, oxamate + TX, oxamyl + TX, oxazosulfil + TX, oxolinic acid + TX, oxytetracycline + TX, Paecilomyces fumosoroseus fumosoroseus+TX, Paecilomyces lilacinus+TX, parathion-ethyl+TX, Pasteuria nishizawae+TX, Pasteuria penetrans+TX, Pasteuria ramosa+TX,Pasteuria thornei + TX, Pasteuria usgae + TX, P-cymene + TX, Penfluron + TX, Pentachlorophenol + TX, Permethrin + TX, Fenothrin + TX, Phorate + TX, Phosphamidon + TX, phosphocarb + TX, Phytoseiulus persimilis (Phytoseiulus persimilis) + TX, picaridin + TX, piperazine + TX, piperonyl butoxide + TX, pirimicarb + TX, pirimiphos-ethyl + TX, pirimiphos-methyl + TX, diamondback moth (Plutella xylostella) granulosis virus + TX, diamondback moth (Plutella xylostella nuclear polyhedrosis virus + TX, polyhedrosis virus + TX, potassium and molybdenum and manganese EDTA-chelate + TX, potassium ethylxanthate + TX, potassium hydroxyquinoline sulfate + TX, prallethrin + TX, probenazole + TX, profenofos + TX, profluthrin + TX, propargite + TX, propetamphos + TX, propoxur + TX, prothiofos + TX, protrifenbut + TX, piflubumid + TX, pymetrozine + TX, pyraclofos + TX, pyrafluprole + TX, pyrethrum + TX, pyridaben + TX, pyridalyl + TX, pyridin-4-amine + TX, pyrifluquinazon + TX, pyrimidifen + TX, pyriminostrobin + TX, pyriprole + TX, pyriprole [394730-71-3] + TX, pyriproxyfen + TX, QRD 420 (Terpenoid Blend) + TX, QRD 452 (Terpenoid Blend) + TX, QRD 460 (Terpenoid Blend) + TX, Quillaja saponaria + TX, Quinoclamine + TX, Quinonamide + TX, Resmethrin + TX, Rhodococcus globerrus globerulus) AQ719 (NRRL accession number B-21663) + TX, sarolaner + TX, S-bioallethrin + TX, cebufos + TX, selamectin + TX, cigla + TX, silafluofen + TX, simazine + TX, sodium pentachlorophenoxide + TX, soldidine + TX, spidoxamato + TX, spinetoram + TX, spinosad + TX, spirobudifen + TX, spirodiclofen + TX, spiromesifen + TX, spiropydione + TX, spirotetramat + TX, Spodoptera exigua (Spodopteraexigua multicapsid nuclear polyhedrosis virus + TX, Spodoptera frugiperda nuclear polyhedrosis virus + TX, Steinernema bibionis + TX, Steinernema carpocapsae + TX, Steinernema feltiae + TX, Steinernema glaseri + TX, Steinernema riobrave + TX, Steinernema riobravis + TX, Steinernema scapterisci + TX, Steinernema spp.) + TX, Streptomyces galvus (Streptomycesgalbus) (NRRL Accession No. 30232) + TX, Streptomyces (sp.) (NRRL Accession No. B-30145) + TX, Streptomycin + TX, Streptomycin sesquisulfate + TX, Strychnine + TX, Sulcatol + TX, Sulfoxaflor + TX, Thazimcarb + TX, Tebufenozide + TX, Tebufenpyrad + TX, Tebupirimfos + TX, Tecloftalam + TX, Tefluthrin + TX, Temephos + TX, Tepa + TX, Turbam + TX, Terbufos + TX, Terpenoid Blend + TX, Tetrachlorantraniliprole + TX, Tetrachlorothiophene + TX, Tetradec-11-en-1-yl acetate + TX, Tetradifon + TX, Tetramethrin + TX, Tetramethylfluthrin + TX, Tetranactin + TX, Tetrani Riprole +TX, Theta-cypermethrin +TX, Thiacloprid +TX, Thiafenox +TX, Thiamethoxam +TX, Thiocyclam +TX, Thiodicarb +TX, Thiofanox +TX, Thiohempa +TX, Thimerosal +TX, Thiometon +TX, Thionazine +TX, Thiophanate +TX, Thiosultap +TX, Thiotepa +TX, Tigoraner +TX, Chlorantraniliprole +TX, Thioxazaphen +TX, Tolfenpyrad +TX, Toxaphene +TX, Tralomethrin +TX, Transfluthrin +TX, Trethamin +TX, Triazamate +TX, Triazophos +TX, Triazuron +TX, Tributyltin Oxide +TX, Trichlorfon +TX, Trichloronaphthalene +TX, Trichlorfon +TX, Trichogramma spp.) + TX, Trifenmorph + TX, Trifluenfuronate + TX, Triflumezopyrim + TX, Trimedulla + TX, Trimedulla A + TX, Trimedulla B1 + TX, Trimedulla B2 + TX, Trimedulla C + TX, Trimethacarb + TX, Triphenyltin acetate + TX, Triphenyltin hydroxide + TX, Tranqu-Cole + TX, Cyclopyrazoflor + TX, Typhlodromus occidentalis + TX, Uredepa + TX, Verticillium lecanii + TX, Verticilliumspp.)+TX, xylenol+TX, YI-5302+TX, zeatin+TX, zeta-cypermethrin+TX; N-[(1R)-1-benzyl-3-chloro-1-methyl-but-3-enyl]-8-fluoro-quinoline-3-carboxamide + TX, N-[(1S)-1-benzyl-3-chloro-1-methyl-but-3-enyl]-8-fluoro-quinoline-3-carboxamide + TX, N-ethyl-N'-[5-methoxy-2-methyl-4-[(2-trifluoromethyl)tetrahydrofuran-2-yl]phenyl]-N-methyl-formamidine (these compounds (These compounds can be prepared from the methods described in WO 2019 / 110427) + TX, (3',4',5'-trifluoro-biphenyl-2-yl)-amide + TX, (3-methylisoxazol-5-yl)-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methanone (These compounds can be prepared from the methods described in WO 2017 / 220485) + TX, (4-phenoxyphenyl)methyl 2-Amino-6-methyl-pyridine-3-carboxylate (this compound can be prepared from the method described in WO 2014 / 006945) + TX, (5-methyl-2-pyridyl)-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methanone + TX, (7E,9Z)-dodeca-7,9-dien-1-yl acetate + TX, (9Z,11E)-tetradeca-9,11-dien-1-yl acetate + TX, (9Z,12E)-tetradec-9,12-dien-1-yl acetate + TX, (E)-6-methylhept-2-en-4-ol + TX, (E)-dec-5-en-1-yl acetate and (E)-dec-5-en-1-ol + TX, (E)-tridec-4-en-1-yl acetate + TX, (E,Z)-tetradec-4,10-dien-1-yl acetate + TX, + TX, (R)-3-(difluoromethyl)-1-methyl-N-[1,1,3-Trimethylindan-4-yl]pyrazole-4-carboxamide + TX, (Z)-dodec-7-en-1-yl acetate + TX, (Z)-hexadec-11-en-1-yl acetate + TX, (Z)-hexadec-11-enal + TX, (Z)-hexadec-13-en-11-yn-1-yl acetate + TX, (Z)-icos-13-en-10-one + TX, (Z)-tetradec-7-en-1-al + TX, (Z)-tetradec-9-en-1-ol + TX, (Z)-tetradec-9-en-1-yl acetate + TX, (Z ,2E)-5-[1-(2,4-dichlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide (this compound can be prepared by the method described in WO 2018 / 153707) + TX, (Z,2E)-5-[1-(4-chlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide + TX, + TX, [2-[3-[2-[1-[2-[3,5-bis(difluoromethyl)pyrazol-1-yl]acetyl]-4-piperidyl]thiazoline [4-yl]-4,5-dihydroisoxazol-5-yl]-3-chloro-phenyl]methanesulfonate + TX, 1-(4,5-dimethylbenzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-isoquinoline + TX, 1-(4,5-dimethylbenzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-isoquinoline + TX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4,5-trifluoro-3,3-dimethyl-isoquinoline + TX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4,5-trifluoro-3,3-dimethyl-isoquinoline + TX 1-(6-chloro-7-methyl-pyrazolo[1,5-a]pyridin-3-yl)-4,4,6-trifluoro-3,3-dimethyl-isoquinoline + TX, 1-(6-chloro-7-methyl-pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-isoquinoline (these compounds can be prepared by the method described in WO 2017 / 025510) + TX, 1,1-bis(4-chlorophenyl)-2-ethoxyethanol + TX, 1,1-dichloro-2,2-bis(4-ethylphenyl)ethane + TX, 1,2-dibromo-3-chloropropane + TX, 1,2-Dichloropropane and 1,3-dichloropropene + TX, 1,3-dichloropropene + TX, 1,3-dimethoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea + TX, 1-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]-3-methyl-phenyl]-4-methyl-tetrazol-5-one + TX, 10-dien-1-yl acetate +TX, 14-methyloctadec-1-ene +TX, 1-bromo-2-chloroethane +TX, 1-dichloro-1-nitroethane +TX, 1-hydroxy-1H-pyridine-2-thione +TX, 1-methoxy-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea +TX, 1-methyl-4-[3-methyl-2-[[2-methyl-4-(3,4,5-trimethylpyrazole) 2-(difluoromethyl)-N-((3R)-1+TX, 1+TX, 3-trimethylindan-4-yl)pyridine-3-carboxamide + TX, 2-(difluoromethyl)-N-((3R)-1+TX, 1+TX, 3-trimethylindan-4-yl)pyridine-3-carboxamide + TX, 2-(1,3-dithiolan-2-yl)phenyldimethylcarba Mate + TX, 2-(2-butoxyethoxy)ethyl piperonylate + TX, 2-(2-butoxyethoxy)ethyl thiocyanate + TX, 2-(4,5-dimethyl-1,3-dioxolan-2-yl)phenylmethylcarbamate + TX, 2-(4-chloro-3,5-xylyloxy)ethanol + TX, 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide + TX, 2-(Difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide + TX, 2-(Difluoromethyl)-N-[(3S)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide (this compound can be prepared from the method described in WO 2014 / 095675) + TX, 2-(Difluoromethyl)-N-[3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide + TX, 2-(Octylthio)ethanol + TX, 2,2,2-trichloro-1-(3,4-dichlorophenyl)ethyl acetate + TX, 2,2-dichlorovinyl 2-ethylsulfinylethyl methylphosphate + TX, 2,2-difluoro-N-methyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]acetamide + TX, 2,4-dichlorophenylbenzenesulfonate + TX, 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrole-1,3,5,7(2H,6H)-tetrone (this compound

[0039] The compound can be prepared from the method described in WO 2011 / 138281) + TX, 2-[2-fluoro-6-[(8-fluoro-2-methyl-3-quinolyl)oxy]phenyl]propan-2-ol + TX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol (this compound can be prepared from the method described in WO 2017 / 029179) + TX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)- 3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol (this compound can be prepared from the method described in WO 2017 / 029179) + TX, 2-chlorovinyldiethyl phosphate + TX, 2-fluoro-N-methyl-N-1-naphthylacetamide + TX, 2-imidazolidone + TX, 2-isovalerylindan-1,3-dione + TX, 2-methyl(prop-2-ynyl)aminophenylmethylcarbamate + TX, 2-oxo-N-propyl-2-[4-[5-(trifluoromethyl)-1,2,4-Oxadiazol-3-yl]phenyl]acetamide (this compound can be prepared by the method described in WO 2018 / 065414) + TX, 2-thiocyanatoethyl laurate + TX, 3-(4,4-difluoro-3,3-dimethyl-1-isoquinolyl)-7,8-dihydro-6H-cyclopenta[e]benzimidazole (these compounds can be prepared by the method described in WO 2016 / 156085) + TX, 3-(4,4-difluoro-3,4-dihydro-3,3-dimethylisoquinolin-1-yl)quinolone +TX, 3-(4-chlorophenyl)-5-methylrhodanine +TX, 3-(difluoromethyl)-1-methyl-N-[1,1,3-trimethylindan-4-yl]pyrazole-4-carboxamide +TX, 3,4-dichlorotetrahydrothiophene 1,1-dioxide +TX, 3-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]imidazole-4-carbonitrile (this compound can be prepared from the method described in WO 2016 / 156290) +TX, 3-[2-(1- chlorocyclopropyl)-3-(3-chloro-2-fluoro-phenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile (this compound can be prepared from the method described in WO 2016 / 156290) + TX, 3-bromo-1-chloroprop-1-ene + TX, 3-chloro-6-methyl-5-phenyl-4-(2,4,6-trifluorophenyl)pyridazine + TX, 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid + TX, 3-ethyl-1-methoxy-1-[[4-[5-(trifluoromethyl)-4-methyl-2H-pyrazole-4-carboxylic acid + TX, (2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1H-pyrazol-5-amine + TX, 4-(2,6-difluorophenyl)-6-methyl-5-phenyl-pyridazine-3-carbonitrile + TX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-2H-pyrazol-5-amine + TX, 4-(2,6-difluorophenyl)-6-methyl-5-phenyl-pyridazine-3-carbonitrile + TX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-2H-pyrazol-5-amine + TX,5-Dimethyl-pyrazol-3-amine + TX, 4-(quinoxalin-2-ylamino)benzenesulfonamide + TX, 4,4-difluoro-1-(5-fluoro-4-methyl-benzimidazol-1-yl)-3,3-dimethyl-isoquinoline + TX, 4,4-difluoro-3,3-dimethyl-1-(6-methylpyrazolo[1,5-a]pyridin-3-yl)isoquinoline + TX, 4,4-difluoro-3,3-dimethyl-1-(7-methylpyrazolo[1,5-a]pyridin-3-yl)isoquinoline + TX, 4,4-dimethyl-2-[ [4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one + TX, 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile + TX, 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile + TX [6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-thioxo-4H-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile + TX, 4-chloro-2-(2-chloro-2-methyl-propyl)-5-[(6-iodo-3-pyridyl)methoxy]pyridazin-3-one + TX, 4-chlorophenyl phenyl sulfone + TX, 4-methyl(prop-2-ynyl)amino-3,5-xylylmethylcarbamate + TX, 4-methyl Nonan-5-ol and 4-methylnonan-5-one + TX, 5-(1,3-benzodioxol-5-yl)-3-hexylcyclohex-2-enone + TX, 5,5-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one + TX, 5,5-dimethyl-3-oxocyclohex-1-enyl dimethylcarbamate + TX, 5-amino-1,3,4-thiadiazole-2-thiol zinc salt (2:1) + TX, 5-methyl-6-thioxo-1,3,5-Thiadiazinan-3-ylacetic acid + TX, 6-chloro-3-(3-cyclopropyl-2-fluoro-phenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoro-ethyl]-5-methyl-pyridazine-4-carboxamide (preparable from the method described in WO 2020 / 109391) + TX, 6-chloro-3-(3-cyclopropyl-2-fluoro-phenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoro-ethyl]-5-methyl-pyridazine-4-carboxamide (preparable from the method described in WO 2020 / 109391) + TX, 6-chloro-4,4-difluoro-3,3-dimethyl-1-(4-methylbenzimidazol-1-yl)i isoquinoline + TX, 6-chloro-N-[2-(2-chloro-4-methyl-phenyl)-2,2-difluoro-ethyl]-3-(3-cyclopropyl-2-fluoro-phenoxy)-5-methyl-pyridazine-4-carboxamide (preparable from the method described in WO 2020 / 109391) + TX, 6-ethyl-5,7-dioxo-pyrrolo[4,5][1,4]dithiino[1,2-c]isothiazole-3-carbonitrile + TX, 6-isopentenylaminopurine + TX, 8-fluoro-N-[(1R)-1-[(3-fluorophenyl)methyl]-1,3-dimethyl-butyl]quinoline-3-carboxamide + TX, 8-fluoro-N-[(1S)-1-[(3-fluorophenyl)methyl]-1,3-dimethyl-butyl]quinoline-3-carboxamide + TX[3-dimethyl-butyl]quinoline-3-carboxamide + TX, 8-hydroxyquinoline sulfate + TX, acetione + TX, acetoprole + TX, acibenzolar + TX, acibenzolar-S-methyl + TX, acrylonitrile + TX, smaller tea tortrix (Adoxophyes orana) GV + TX, Agrobacterium radiobacter + TX, aldoxycarb + TX, aldrin + TX, allosamidin + TX, alixycarb + TX, alpha-chlorohydrin + TX, alpha-ecdysone + TX, alpha-multistriatin + TX, aluminum phosphide + TX, Amblyseius spp.) +TX, Amethoctotractin +TX, Ametoctrazine +TX, Amidithione +TX, Amidothioate +TX, Aminocarb +TX, Aminopyrifen +TX, Amisulbrom +TX, Amiton +TX, Amiton Hydrogen Oxalate +TX, Amitraz +TX, Anabasine +TX, Anagrapha falcifera NPV +TX, Anagrus atomus + TX, Ancymidol + TX, Anilazine + TX, Anicifluprine + TX, Anthraquinone + TX, Antu + TX, Aphelinus abdominalis + TX, Aphidius colemani + TX, Aphidoletes aphidimyza + TX, Aphorate + TX, Aramite + TX, Arsenic trioxide + TX, Atidathion + TX, Autographa californica NPV + TX, Azaconazole + TX, Azamethiphos + TX, Azobenzene + TX, Azothoate + TX, Azoxystrobin + TX, Bacillus sphaericus Neide) + TX, Bacillus thuringiensis delta endotoxin + TX, Barium carbonate + TX, Barium hexafluorosilicate + TX, Barium polysulfide + TX, Bartholin's + TX, Bayer 22 / 190 + TX, Bayer 22408 + TX, Beauveria bronniartii brongniartii) + TX, Benalaxyl + TX, Benclotiaz + TX, Benomyl + TX, Benoxafos + TX, Benthiavalicarb + TX, Benzothiostrobin + TX, Benzovindiflupyr + TX, Benzyl Benzoate + TX, Beta-Cyfluthrin + TX, Beta-Cypermethrin + TX, Bethoxadin + TX, Bioethanometrin + TX, Biopermethrin + TX, Bis(2-chloroethyl) ether + TX, Bis(tributyltin) oxide + TX, Bisadil + TX, Bisthiosemi TX, Bitertanol + TX, Bixafen + TX, Blasticidin-S + TX, Borax + TX, Bordeaux mixture + TX, Boscalid + TX, Brevicomin + TX, Brodifacoum + TX, Brofenvalerate + TX, bromadiolone + TX, Bromethalin + TX, Bromfenvinphos + TX, Bromoacetamide + TX, Bromocyclen + TX, Bromo-DDT + TX, Bromophos + TX, Bromopropylate + TX, Bromuconazole + TX, Bronopol + TX, Bufencarb + TX,Bupirimate + TX, Buprofezin + TX, Busulfan + TX, But-3-ynyl N-[6-[[(Z)-[(1-methyltetrazol-5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate + TX, Butacarb + TX, Butathiophos + TX, Butocarboxim + TX, Butonate + TX, Butopyronoxyl + TX, Butoxy(polypropylene glycol) + TX, Butoxycarboxim + TX, Butylpyridaben + TX, Calcium arsenate + TX, Calcium cyanide + TX, Calcium polysulfide + TX, Camphechlor + TX, Captafol + TX, Captan + TX, Carbanolate + TX, Carbendazim + TX, Carbon disulfide + TX, Carbon tetrachloride + TX, Carbophenothion + TX, Carboxin + TX, Cartap Hydrochloride +TX, Cevadine +TX, Chinomethionate +TX, Chloralose +TX, Chlorbeside +TX, Chlorbicyclen +TX, Chlordane +TX, Chlordecone +TX, Chlordimeform +TX, Chlordimeform Hydrochloride +TX, Chlorphenetole +TX, Chlorfenson +TX, Chlorphenesulfide +TX, Chlorbenzilate +TX, Chloroform +TX, Chlorinconazide +TX, Chlormebform +TX, Chlormethiron +TX, Chloroneb +TX, Chlorophacinone +TX, Chloropicrin +TX, Chloropropylate +TX, Chlorothalonil +TX, Chlorphoxim +TX, Chlorprazofos +TX, Chlorthiophos +TX, Chlozolinate +TX, Cholecalciferol +TX, Chrysoperla carnea carnea) + TX, cinerin I + TX, cinerin II + TX, cinerin + TX, cismethrin + TX, cis-resmethrin + TX, clocitrin + TX, closantel + TX, codrelua + TX, codremon + TX, copper acetarsenite + TX, copper arsenate + TX, copper dioctanoate + TX, copper hydroxide + TX, copper naphthenate + TX, copper oleate + TX, copper oxide + TX, copper oxychloride + TX, copper sulfate + TX, coumachlor + TX, coumafuryl + TX, coumaphos + TX, coumatetralyl + TX, chlomethoxystrobin (jiaxiangjunzhi) + TX, coumitoate + TX, coumoxystrobin + TX, cresol + TX, crimidine + TX, crotamiton + TX,Crotoxyphos + TX, crufomate + TX, cryolite + TX, red ladybird (Cryptolaemus montrouzieri) + TX, CS 708 + TX, cuulua + TX, khuraneb + ​​TX, cyanofenphos + TX, cyanophos + TX, cyanthoate + TX, cyazofamid + TX, sibutrin + TX, ciclethrin + TX, cyclobutrifluram + TX, codling moth (Cydia pomonella) GV + TX, cyflufenamid + TX, cimiazole + TX, cymoxanil + TX, cyproconazole + TX, cyprodinil + TX, cythioate + TX, cytokinin + TX, leaf conch (Dacnusa sibirica) sibirica))+TX, DAEP+TX, Dazomet+TX, DCIP+TX, DCPM+TX, DDT+TX, Debacarb+TX, Decarbofuran+TX, Demefion+TX, Demefion-O+TX, Demefion-S+TX, Demeton-methyl+TX, Demeton-O+TX, Demeton-O-methyl+TX, Demeton-S+TX, Demeton-S-methyl+TX, Demeton-S-methylsulfone+TX, Diamidaphos+TX, Dibutyl adipate+TX, Dibutyl phthalate+TX, Dibutyl succinate+TX, Dikapton+TX, Diclobenthiazox+TX, Diclofenthion+TX, Diclofenthion Lofluanid + TX, Dichloron + TX, Dichlorophen + TX, Dichlorvos + TX, Dichlozolin + TX, Dicrifos + TX, Diclocymet + TX, Diclomedine + TX, Dicloran + TX, Dicresyl + TX, Dicyclanil + TX, Dicyclopentadiene + TX, Dieldrin + TX, Dienochlor + TX, Diethofencarb + TX, Diethyl 5-methylpyrazol-3-yl phosphate + TX, Diethyltoluamide + TX, Difenacoum + TX, Difenoconazole + TX, Difethialone + TX, Diflobidazin + TX, Diglyphus isaea (Diglyphus isaea) isaea)) + TX, Dirol + TX, Dimatif + TX, Dimefluthrin + TX, Dimefox + TX, Dimethane + TX, Dimethirimol + TX, Dimethomorph + TX, Dimethrine + TX, Dimethylcarbate + TX, Dimethylphthalate + TX,Dimethylvinphos + TX, Dimethilan + TX, Dimoxystrobin + TX, Zinex + TX, Zinex-Diclexin + TX, Diniconazole + TX, Dinocap-4 + TX, Dinocap-6 + TX, Dinocton + TX, Dinopenton + TX, Dinoprop + TX, Dinosam + TX, Dinoseb + TX, Dinosulfone + TX, Dinotervone + TX, Diofenolan + TX, Dioxabenzophos + TX, Dioxathion + TX, Diphacinone + TX, Diphenylsulfone + TX, Dipimethicone Thoron + TX, Dipyrithione + TX, Disparlure + TX, Disulfiram + TX, Dithianon + TX, Dicyclophos + TX, DNOC + TX, Dodec-8-en-1-yl acetate + TX, Dodec-9-en-1-yl acetate + TX, Dodeca-8 + TX, Dodemorph + TX, Dodicin + TX, Dodine + TX, Dofenapine + TX, Dominicalure + TX, Doramectin + TX, DSP + TX, d-Tetramethrin + TX, Ecdysterone + TX, Edifenphos + TX, EI 1642 + TX, EMPC + TX, Greenhouse Wasp (Encarsia formosa) + TX, Endothal + TX, Endothion + TX, Enestrobulin + TX, Enoxastrobin + TX, EPBP + TX, Epoxiconazole + TX, Eprinomectin + TX, Desert fire wasp (Eretmocerus eremicus) + TX, ergocalciferol + TX, etaphos + TX, ethaboxam + TX, ethiofencarb + TX, ethirimol + TX, ethoate-methyl + TX, ethyl 1-[[4-[(Z)-2-ethoxy-3,3,3-trifluoro-prop-1-enoxy]phenyl]methyl]pyrazole-3-carboxylate (preparable from the method described in WO 2020 / 056090) + TX, ethyl 1-[[4-[[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy]phenyl ]methyl]pyrazole-3-carboxylate (which can be prepared from the method described in WO 2020 / 056090) + TX, ethyl 1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrazole-4-carboxylate + TX, ethyl 1-[[5-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]-2-thienyl]methyl]pyrazole-4-carboxylate (this compound can be prepared from the method described in WO 2018 / 158365) ) + TX, ethyl 4-methyloctanoate + TX, ethyl formate + TX, ethyl hexanediol + TX, ethylene dibromide + TX, ethylene dichloride + TX, ethylene oxide + TX, etridiazole + TX, etrimphos + TX, eugenol + TX, EXD + TX, famoxadone + TX, farnesol + TX, farnesol and nerolidol + TX, fenamidone + TX, fenaminosulf + TX, phenaminestrobin + TX, fenarimol + TX, fenazaflor + TX, fenbuconazole + TX, fenbutadiene oxide Tin + TX, fenchlorphos + TX, fenetacarb + TX, fenfuram + TX, fenhexamid + TX, fenitrothion + TX, fenothiocarb + TX, fenoxacrim + TX, fenoxanil + TX, fenpiclonil + TX, fenpicoxamid + TX, fenpyrithrin + TX, fenpropidin + TX, fenpropimorph + TX, fenpyrad + TX, fenpyrazamine + TX, fenpyroximate + TX, fenthone + TX, fensulfothion + TX, fenthion + TX, fenthion-ethyl + TX,Fentin +TX, Fentrifanil +TX, Ferbam +TX, Ferimzone +TX, Ferric phosphate +TX, Flocoumafen +TX, Florylpicoxamide +TX, Fluazinam +TX, Flubeneteram +TX, Flubenzimine +TX, Flucofuron +TX, Flucycloxuron +TX, Fludioxonil +TX, Fluenethyl +TX, Flufenoxadiazam +TX, Flufenoxystrobin +TX, Fluindapyr +TX, Flumethylsulfolim +TX, Flumorph +TX, Fluo Picolide + TX, fluopimomide + TX, fluopyram + TX, fluorbenside + TX, fluoroacetamide + TX, fluoroimide + TX, fluoxapiprolin + TX, fluoxastrobin + TX, fluoxytioconazole + TX, flupropaline + TX, flupropaline hydrochloride + TX, fluquinconazole + TX, flusilazole + TX, flusulfamide + TX, flutianil + TX, flutolanil + TX, flutriafol + TX, fluxapyroxad + TX, FMC 1137+TX, Folpet+TX, Formaldehyde+TX, Formetanate+TX, Formetanate Hydrochloride+TX, Formoparanate+TX, Fosetyl-aluminum+TX, Fosmetilan+TX, Fospirate+TX, Fostietan+TX, Frontalin+TX, Fuberidazole+TX, Furalaxyl+TX, Furamethopyr+TX, Furathiocarb+TX, Frethrin+TX, Furfural+TX, Gamma-HCH+TX, Gliodin+TX, Grandolure+TX, Grandolure I+TX, Grandolure II+TX, Grandolure III+TX, Grandolure IV+TX, Guazatine+TX, Guazatine Acetate+TX, Halfenprox+TX, HCH+TX, Hemel+TX, Hempa+TX, HEOD+TX, Heptachlor+TX, Heterofos+TX, Heterorhabditis bacteriophora bacteriophora) and H. megidis (H. megidis) + TX, hexaconazole + TX, hexadecylcyclopropanecarboxylate + TX, hexalure + TX, hexamide + TX, HHDN + TX, ladybug (Hippodamia convergens) + TX, hydralgafen + TX, hydrated lime + TX,Hydrogen cyanide +TX, Hymexazole +TX, Hikincarb +TX, Imanin +TX, Imazalil +TX, Imibenconazole +TX, Iminoctadine +TX, Impilfluxam +TX, Ipconazole +TX, Ipfentrifluconazole +TX, Ipflufenoquin +TX, Iprobenfos +TX, Iprodione +TX, Iprovalicarb +TX, Ipsdienol +TX, Ipsenol +TX, IPSP +TX, Isamidophos +TX, Isazophos +TX, Isobenzane +TX, Isocarbophos +TX, Isodrin +TX, Isofenphos +TX, Isofetamide + TX, Isoflucipram + TX, Isolane + TX, Isoprothiolane + TX, Isopyrazam + TX, Isotianil + TX, Isoxathion + TX, Japonirua + TX, Jasmolin I + TX, Jasmolin II + TX, Jodofenphos + TX, Juvenile Hormone I + TX, Juvenile Hormone II + TX, Juvenile Hormone III + TX, Kadetrin + TX, Kasugamycin + TX, Kasugamycin Hydrochloride Hydrate + TX, Keleban + TX, Kinetin + TX, Kinoprene + TX, Kresoxim-methyl + TX, Lead Arsenate + TX, Leptomastix dactylopii dactylopii + TX, leptophos + TX, lindane + TX, lineatin + TX, lilimphos + TX, litrea + TX, lupurua + TX, lvbenmixianan + TX, ritidathion + TX, Macrolophus caliginosus + TX, magnesium phosphide + TX, malonoven + TX, armyworm (Mamestra brassicae) brassicae))NPV+TX, Mancopar+TX, Mancozeb+TX, Mandestrobin+TX, Mandipropamid+TX, Maneb+TX, Magidox+TX, m-cumenylmethylcarbamate+TX, Mecarbam+TX, Mecarfone+TX, Medlua+TX, Mefentrifluconazole+TX, Megatomoic acid+TX, Menasone+TX, Mepanipyrim+TX, Meperfluthrin+TX, Mefosfolan+TX, Mepronil+TX, Mercuric oxide+TX, Mercurous chloride+TX, Mesulfen+TX, Mesulfenphos+TX, Metalaxyl+TX, Metam+TX, Metam-potassium+TX, Metam-sodium+TX,Metaphycus helvolus + TX, Metarhizium anisopliae var. acridum + TX, Metarhizium anisopliae var. anisopliae + TX, methallylpicoxamide + TX, metconazole + TX, metepa + TX, methacrifos + TX, methanesulfonyl fluoride + TX, methasulfocarb + TX, methiotepa + TX, metocrotophos + TX, methoprene + TX, methoquin-butyl + TX, methotrin + TX, methoxychlor + TX, methyl (Z)-2-(5-cyclohexyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoate + TX, methyl ( Z)-2-(5-cyclopentyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoate (these compounds can be prepared from the method described in WO 2020 / 193387) + TX, methyl (Z)-2-[5-(3-isopropylpyrazol-1-yl)-2-methyl-phenoxy]-3-methoxy-prop-2-enoate + TX, methyl (Z)-3-methoxy-2-[2-methyl-5-(3-propylpyrazol-1-yl)phenoxy]prop prop-2-enoate + TX, methyl (Z)-3-methoxy-2-[2-methyl-5-(4-propyltriazol-2-yl)phenoxy]prop-2-enoate + TX, methyl (Z)-3-methoxy-2-[2-methyl-5-[3-(trifluoromethyl)pyrazol-1-yl]phenoxy]prop-2-enoate (these compounds can be prepared from the method described in WO 2020 / 079111) + TX, methyl (Z)-3-methoxy-2-[2-methyl-5-[3-(trifluoromethyl)pyrazol-1-yl]phenoxy]prop-2-enoate Methyl-5-[4-(trifluoromethyl)triazol-2-yl]phenoxy]prop-2-enoate + TX, methyl afolate + TX, methyl bromide + TX, methyl eugenol + TX, methyl isothiocyanate + TX, methyl N-[[4-[1-(2,6-difluoro-4-isopropyl-phenyl)pyrazol-4-yl]-2-methyl-phenyl]methyl]carbamate (preparable from the method described in WO 2020 / 097012) + TX,Methyl N-[[4-[1-(4-cyclopropyl-2,6-difluoro-phenyl)pyrazol-4-yl]-2-methyl-phenyl]methyl]carbamate (preparable from the method described in WO 2020 / 097012) + TX, methyl N-[[5-[4-(2,4-dimethylphenyl)triazol-2-yl]-2-methyl-phenyl]methyl]carbamate + TX, methyl chloroform + TX, methylene chloride + TX, methyl neodecanamide + TX, metiram + TX, metolcarb + TX, metominostrobin + TX, methoxadiazone + TX, metrafenone + TX, methyltetraprole + TX, MGK 264 + TX, milbemycin oxime + TX, mipafox + TX, mirex + TX, monocrotophos + TX, morphothion + TX, morzide + TX, moxidectin + TX, muscalure + TX, myclobutanil + TX, mycozolin + TX, mulberry dark spot fungus (Myrothecium verrucaria) composition + TX, N-((1R)-1-benzyl-3-chloro-1-methyl-but-3-enyl)-8-fluoro-quinoline-3-carboxamide (these compounds can be prepared by the method described in WO 2017 / 153380) + TX, N-((1S)-1-benzyl-3-chloro-1-methyl-but-3-enyl)-8-fluoro-quinoline-3-carboxamide (these compounds can be prepared by the method described in WO 2017 / 153380) / 153380) + TX, N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine + TX, N'-(2-chloro-5-methyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine + TX, N,2-dimethoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide + TX, N,N-dimethyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-1,2,4-triazol-3-amine (these compounds can be prepared from the methods described in WO 2017 / 055473 + TX, WO 2017 / 055469 + TX, WO 2017 / 093348 and WO 2017 / 118689) + TX, N-[(1R)-1-benzyl-1,3-dimethyl-butyl]-7,8-difluoro-quinoline-3-carboxamide + TX, N-[(1R)-1-benzyl-1,3-dimethyl-butyl]-8-fluoro-quinoline-3-carboxamide + TX, N-[(1R)-1-benzyl-3,3,3-trifluoro-1-methyl-propyl]-8-fluoro-quinoline-3-carboxamide + TX, N-[(1S)-1-benzyl-1,3-dimethyl-butyl]-7,8-difluoro-quinoline-3-carboxamide + TX, N-[(1S)-1-benzyl-1,3-dimethyl-butyl]-8-fluoro-quinoline-3-carboxamide + TX, N-[(1S)-1-benzyl N-[(E)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + TX, N-[(Z)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + TX, N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide + T X, N-[2-[2,4-dichloro-phenoxy]phenyl]-3-(difluoromethyl)-1-methyl-pyrazole-4-carboxamide + TX, N-[2-[2-chloro-4-(trifluoromethyl)phenoxy]phenyl]-3-(difluoromethyl)-1-methyl-pyrazole-4-carboxamide + TX, N'-[2-chloro-4-(2-fluorophenoxy)-5-methyl-phenyl]-N-ethyl-N-methyl-formamidine (this compound can be prepared from the method described in WO 2016 / 202742) + TX,N'-[4-(4,5-dichlorothiazol-2-yl)oxy-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine + TX, N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine + TX, N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-isopropyl-N-methyl-formamidine (these compounds are described in WO 201 No. 5 / 155075) + TX, N'-[5-bromo-2-methyl-6-(2-propoxypropoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine (this compound can be prepared by the method described in IPCOM000249876D) + TX, N'-[5-bromo-2-methyl-6-[(1R)-1-methyl-2-propoxy-ethoxy]-3-pyridyl]-N-ethyl-N-methyl-formamidine + TX, N'-[5-bromo-2-methyl-6-[ (1S)-1-methyl-2-propoxy-ethoxy]-3-pyridyl]-N-ethyl-N-methyl-formamidine + TX, N'-[5-chloro-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine + TX, N-[N-methoxy-C-methyl-carbonimidoyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide (these compounds are described in WO 2018 / 202428). N'-[4-(1-cyclopropyl-2,2,2-trifluoro-1-hydroxy-ethyl)-5-methoxy-2-methyl-phenyl]-N-isopropyl-N-methyl-formamidine (these compounds can be prepared from the method described in WO 2018 / 228896) + TX, Nabam + TX, Naphthalophos + TX, Naled + TX, Naphthalene + TX, NC-170 + TX, pine sawfly (Neodiprion sertifer) NPV and N. lecontei NPV + TX, nerolidol + TX,N-Ethyl-2-methyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide + TX, N-Ethyl-N'-[5-methoxy-2-methyl-4-[(2-trifluoromethyl)oxetan-2-yl]phenyl]-N-methyl-formamidine + TX, Nickel bis(dimethyldithiocarbamate) + TX, Niclosamide-olamine + TX, Nicotine + TX, Nicotine sulfate + TX, Nifluridide + TX, Nikkomycin + TX, N-Isopropyl-N'-[5-methoxy-2-methyl-4-(2,2,2-trifluoro-1-hydroxy-1-phenyl-ethyl)phenyl]-N-methyl-formamidine + TX, Nithiazine + TX, Nitrapyrin + TX, Nitrilacarb + TX, Nitrilacarb 1:1 zinc chloride complex + TX, Nitrota N-isopropyl ether + TX, N-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]cyclopropanecarboxamide + TX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + TX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + TX ]Benzenecarbothioamide + TX, Norbormide + TX, Nuarimol + TX, O,O,O',O'-Tetrapropyldithiopyrophosphate + TX, Octadeca-2,13-dien-1-yl acetate + TX, Octadeca-3,13-dien-1-yl acetate + TX, Octilinone + TX, Ofurace + TX, Oleic acid + TX, Omethoate + TX, Olfural + TX, Orius sp. spp.) +TX, Orictalua +TX, Orysastrobin +TX, Ostramon +TX, Oxadixyl +TX, Oxamate +TX, Oxathiapiprolin +TX, Oxine-copper +TX, Oxolinic acid +TX, Oxocarboxin +TX, Oxideprophos +TX, Oxydisulfoton +TX, Oxytetracycline +TX, Paclobutrazol +TX, Paecilomyces fumosoroseus +TX, Para-dichlorobenzene +TX, Parathion +TX, Parathion-methyl +TX, Pefurazoate +TX, Penconazole +TX,Pencycuron +TX, Penflufen +TX, Penfluron +TX, Pentachlorophenol +TX, Pentachlorophenyl laurate +TX, Penthiopyrad +TX, Permethrin +TX, PH 60-38 +TX, Fenamacryl +TX, Fenkapton +TX, Fosacetim +TX, Phosalone +TX, Phosdifen +TX, Phosphorane +TX, Phosglycine +TX, Fosniclor +TX, Phosphamidon +TX, Phosphine +TX, Phosphorus +TX, Phoxim-methyl +TX, Phthalide +TX, Phytoseiulus persimilis (Phytoseiulus persimilis) persimilis)) + TX, picarbutrazox + TX, picaridin + TX, picoxystrobin + TX, pindone + TX, piperazine + TX, piperonyl butoxide + TX, piprotal + TX, pyrimetaphos + TX, polychlorodicyclopentadiene isomers + TX, polychloroterpenes + TX, polynactin + TX, polyoxins + TX, potassium arsenite + TX, potassium ethylxanthate + TX, potassium hydroxyquinoline sulfate + TX, potassium thiocyanate + TX, pp'-DDT + TX, precocene I + TX, precocene II + TX, precocene III + TX, primidophos + TX, probenazole + TX, prococene Loraz + TX, Proclonol + TX, Procymidone + TX, Profluthrin + TX, Promacyl + TX, Promecarb + TX, Propamocarb + TX, Propiconazole + TX, Propineb + ​​TX, Propoxur + TX, Propyl isomer + TX, Proquinazid + TX, Protidathion + TX, Prothioconazole + TX, Prothiofos + TX, Prothoate + TX, Pydiflumetofen + TX, Pyraclostrobin + TX, Pyramethorbin + TX, Pyraoxystrobin + TX, Pyrapropoin + TX, Pyraziflumid + TX, Pyrazophos + TX, Pyresmethrin + TX, Pyrethrin I + TX, Pyrethrin II + TX, Pyrethrin + TX, Pyribencarb + TX, pyridaclomethyl + TX, pyridaphenthion + TX, pyridin-4-amine + TX, pyrifenox + TX, pyrimethanil + TX, pirimitate + TX, pyrimorph + TX, pyrinuron + TX, pyriophenone + TX, pyrizoxazole + TX, pyroquilon + TX, quassia + TX, quinalphos + TX, quinalphos-methyl + TX, quinoclamine + TX, quinofumelin + TX, quinonamide + TX, quinothione + TX, quinoxyfen + TX, quinthiofos + TX, quintozene + TX, R-1492 + TX, rafoxanide + TX, resmethrin + TX, Japanese knotweed (Reynoutria sacharinensis (Reynoutria sachalinensis) extract +TX, ribavirin +TX, R-metalaxyl +TX, rotenone +TX, ryania +TX, ryanodine +TX, S421 +TX, sabadila +TX, shradan +TX, sciliroside +TX, seboxylamine +TX, cebufos +TX, sedaxane +TX, selamectin +TX, sesamex +TX, sesamolin +TX, SI-0009 +TX, siglua +TX, simazine +TX, simeconazole +TX, Sodium arsenate + TX, sodium cyanide + TX, sodium fluoride + TX, sodium fluoroacetate + TX, sodium hexafluorosilicate + TX, sodium pentachlorophenoxide + TX, sodium selenate + TX, sodium tetrathiocarbonate + TX, sodium thiocyanate + TX, sofamide + TX, sordisin + TX, spiroxamine + TX, SSI-121 + TX, Steinernema bibionis (Steinernema bibionis + TX, Steinernema carpocapsae + TX, Steinernema feltiae + TX, Steinernema glaseri + TX, Steinernema riobrave + TX, Steinernema riobravis + TX, Steinernema scapterisci + TX, Steinernema spp.) + TX, Streptomycin + TX, Streptomycin Sesquisulfate + TX, Strychnine + TX, Sulcatol + TX, Sulcofuron + TX, Sulcofuron-Sodium + TX, Sulphiram + TX, Sulphuramide + TX, Sulphotep + TX, Sulphoxide + TX, Sulphuryl Fluoride + TX, Sulprofos + TX, Tar Oil + TX, Tau-Fluvalinate + TX, Thazimcarb + TX, TDE + TX, Tebuconazole + TX, Tebufloquine + TX, Tebupirimfos + TX, Tecloftalam + TX, Temephos + TX, Tepa + TX, TEPP + TX, Teralethrin + TX, Therbam + TX, tert-butyl N-[6-[[[(1-methyltetrazol-5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate + TX, tetrachloroethane + TX, tetrachlorothiophene + TX, tetraconazole + TX, tetradec-11-en-1-yl acetate + TX, tetradifon + TX, tetramethylfluthrin + TX, tetrasulfur + TX, thallium sulfate + TX, thiabendazo ol + TX, thiafenox + TX, tiapronil + TX, cyclophos + TX, thifluzamide + TX, thiocarboxim + TX, thiocyclam + TX, thiocyclam hydrogen oxalate + TX, thiodiazole copper + TX, thiofanox + TX, thiohenpa + TX, thimerosal + TX, thiometon + TX, thionazine + TX, thiophanate + TX, thiophanate-methyl + TX, thioquinox + TX, thiosultap + TX, thiosultap-sodium + TX, thiotepa + TX, thiram + TX, thuringia Insin + TX, tiadinil + TX, tolclofos-methyl + TX, tolprocarb + TX, tolylfluanid + TX, tralomethrin + TX, transpermethrin + TX, toretamine + TX, triadimefon + TX, triadimenol + TX, triamiphos + TX, trilatene + TX, triazamate + TX, triazophos + TX, triazoxide + TX, triazuron + TX, tributyltin oxide + TX, trichlormethaphos-3 + TX, trichloronaphthalene + TX, Trichogramma spp.)+TX, Triclopyricarb+TX, Tricyclazole+TX, Tridemorph+TX, Trifenmorph+TX, Tripenofos+TX, Trifloxystrobin+TX, Triflumizole+TX, Triforine+TX, Trimedlure+TX, Trimedlure A+TX, Trimedlure B1+TX, Trimedlure B2+TX, Trimedlure C+TX, Trimethacarb+TX, Trinactin+TX, Trinexapac+TX, Triphenyltin Acetate+TX, Triphenyltin Hydroxide+TX, Triplen+TX, Triticonazole+TX, Tranqu-Cole+TX, Typhlodromus occidentalis (Typhlodromus occidentalis + TX, Uredep + TX, Validamycin + TX, Valifenalate + TX, Vamidothion + TX, Vaniliprole + TX, Veratridine + TX, Veratrine + TX, Verbutin + TX, Verticillium lecanii + TX, Vinclozolin + TX, Warfarin + TX, XMC + TX, Xylenol + TX, Zeatin + TX, Zetametrine + TX, Zhongshengmycin + TX, Zinc naphthenate + TX, Zinc phosphide + TX, Zinc thiazole + TX, Zineb + ​​TX, Ziram + TX, Zolaprofos + TX, Zoxamide + TX, α-(1-dimethylethyl)-α-[4'-(trifluoromethoxy)[1-biphenyl]-4-yl]-5-pyrimidinemethanol + TX; Typhula phacorrhiza strain 94670 + TX, Acinetobacter lwoffii + TX, Acremonium alternatum + TX, Acremonium cephalosporium + TX, Acremonium diospyri + TX, Acremonium obclavatum + TX, Adoxophyes orana granulovirus (AdoxGV) (Capex®) + TX, Agrobacterium radiobacter strain K84 (Galltrol-A®) + TX, Alternaria alternatum alternate) + TX, Alternaria cassia + TX, Alternaria destruens (Smolder®) + TX, Ampelomyces quisqualis (AQ10®) + TX, Aspergillus flavus AF36 (AF36®) + TX, Aspergillus flavus NRRL 21882 (Aflaguard®) + TX, Aspergillus spp.) + TX, Aureobasidium pullulans + TX, Azospirillum (MicroAZ® + TX, + TX, TAZO B®) + TX, Azotobacter + TX, Azotobacter chroocuccum (Azotomeal®) + TX, Azotobacter cysts (Bionatural Blooming Blossoms®) + TX, Bacillus amyloliquefaciens + TX, Bacillus cereus + TX, Bacillus chitinosporus strain AQ746 + TX, Bacillus chitinosporus strain CM-1 + TX, Bacillus circulans + TX, Bacillus firmus (BioSafe® + TX, BioNem-WP®), in particular strain CNMC1-1582 (e.g. VOTIVO® from BASF SE) + TX, Bacillus licheniformis strain 3086 (EcoGuard® + TX, Green Releaf®) + TX, Bacillus licheniformis strain HB-2 (Biostart®, formerly Rhizoboost®) + TX, Bacillus macerans + TX, Bacillus marismortii marismortui + TX, Bacillus megaterium + TX, Bacillus mycoides strain AQ726 + TX, Bacillus papillae (Milky Spore Powder®) + TX, Bacillus pumilus spp.) +TX, Bacillus pumilus strain AQ717 +TX, Bacillus pumilus strain GB34 (Yield Shield®) +TX, Bacillus pumilus strain QST2808 (Sonata® +TX, Ballad Plus®) +TX, Bacillus sphaericus (VectoLex®) +TX, Bacillus spp. +TX, Bacillus spp. strain AQ175 +TX, Bacillus spp. strain AQ177 +TX, Bacillus spp. strain AQ178 +TX, Bacillus subtilis subtilis strain AQ153+TX, Bacillus subtilis strain AQ743+TX, Bacillus subtilis strain QST713 (CEASE®+TX, Serenade®+TX, Rhapsody®)+TX, Bacillus subtilis strain QST714 (JAZZ®)+TX, Bacillus subtilis strain QST3002+TX, Bacillus subtilis strain QST3004+TX, Bacillus subtilis var. amyloliquefaciens (Bacillus subtilis var.amyloliquefaciens strain FZB24 (Taegro® +TX, Rhizopro®) +TX, Bacillus thuringiensis aizawai GC91 (Agree®) +TX, Bacillus thuringiensis Cry 2Ae +TX, Bacillus thuringiensis Cry1Ab +TX, Bacillus thuringiensis israelensis (BMP123® +TX, Aquabac® +TX, VectoBac®) +TX, Bacillus thuringiensis kurstaki kurstaki (Javelin® + TX, Deliver® + TX, CryMax® + TX, Bondide® + TX, Scutella WP® + TX, Turilav WP® + TX, Astuto® + TX, Dipel WP® + TX, Biobit® + TX, Foray®) + TX, Bacillus thuringiensis kurstaki BMP123 (Baritone®) + TX, Bacillus thuringiensis kurstaki HD-1 (Bioprotec-CAF / 3P®) + TX, Bacillus thuringiensis strain AQ52 + TX, Bacillus thuringiensis thuringiensis strain BD#32+TX, Bacillus thuringiensis tenebrionis (Novodor®+TX, BtBooster)+TX, Bacillus thuringiensis var. Aizawai (Bacillus thuringiensis var.aizawai (XenTari® +TX, DiPel®) +TX, bacteria spp. (GROWMEND® +TX, GROWSWEET® +TX, Shootup®) +TX, Clavipacter michiganensis bacteriophage (AgriPhage®) +TX, Bakflor® +TX, Beauveria bassiana (Beaugenic® +TX, Brocaril WP®) +TX, Beauveria bassiana GHA (Mycotrol ES® +TX, Mycotrol O® +TX, BotaniGuard®) +TX, Beauveria bronniartii (Beauveria brongniartii) (Engerlingspilz® + TX, Schweizer Beauveria® + TX, Melocont®) + TX, Beauveria spp. + TX, Botrytis cineria + TX, Bradyrhizobium japonicum (TerraMax®) + TX, Brevibacillus brevis + TX, Burkholderia cepacia (Deny® + TX, Intercept® + TX, Blue Circle®) + TX, Burkholderia gladii + TX, Burkholderia gladioli + TX, Burkholderia spp. + TX, Canadian thistle fungus (CBH Canadian Bioherbicide®) + TX, Candida butyri + TX, Candida famata + TX, Candida fructus + TX, Candida glabrata glabrata + TX, Candida guilliermondii + TX, Candida melibiosica + TX, Candida oleophila strain O + TX, Candida parapsilosis + TX, Candida pelliculosa + TX, Candida pulcherrima + TX, Candida reukaufii + TX, Candida saitoana (Bio-Coat® + TX, Biocure®) + TX, Candida sake + TX, Candida spp.) + TX, Candida tenius + TX, Cedecea davisae + TX, Cellulomonas flavigena + TX, Chaetomium cochliodes (Nova-Cide®) + TX, Chaetomium globosum (Nova-Cide®) + TX, Chromobacterium subtsugae strain PRAA4-1T (Grandevo®) + TX, Cladosporium chlorocephalum + TX, Cladosporium cladosporioides + TX, Cladosporium oxysporum oxysporum + TX, Cladosporium spp. + TX, Cladosporium tenuissimum + TX, Clonostachys rosea (EndoFine®) + TX, Colletotrichum acutatum + TX, Coniothyrium minitans (Cotans WG®) + TX, Coniothyrium spp.) + TX, Cryptococcus albidus (YIELDPLUS®) + TX, Cryptococcus humicola + TX, Cryptococcus infirmo-miniatus + TX, Cryptococcus laurentii + TX, Cryptophlebia leucotreta granulovirus (Cryptex®) + TX, Cupriavidus campinensis + TX, Cydia pomonella granulovirus (CYD-X® + TX, Madex® + TX, Madex®) Plus® +TX, Madex Max +TX, Carpovirusine® +TX, Cylindrobasidium laeve (Stumpout®) +TX, Cylindrocladium +TX, Debaryomyces hansenii +TX, Drechslera hawaiinensis +TX, Enterobacter cloacae +TX, Enterobacteriaceae +TX, Entomophtora virulenta (Vektor®) +TX, Epicoccum nigrum +TX, Epicoccum purpurascens purpurascens) + TX, Epicoccum spp.) + TX, Filobasidium floriforme + TX, Fusarium acuminatum + TX, Fusarium chlamydosporum + TX, Fusarium oxysporum (Fusaclean® + TX, Biofox C®) + TX, Fusarium proliferatum + TX, Fusarium spp. + TX, Galactomyces geotrichum + TX, Gliocladium catenulatum (Primastop® + TX, Prestop®) + TX, Gliocladium roseum roseum + TX, Gliocladium spp. (SoilGard®) + TX, Gliocladium virens (Soilgard®) + TX, Granulovirus (Granupom®) + TX, Halobacillus halophilus + TX, Halobacillus litoralis + TX, Halobacillus trueperi + TX, Halomonas spp. + TX, Halomonas subglaciescola + TX, Halovibrio variabilis + TX. Hanseniaspora uvarum + TX, Helicoverpa armigera nucleopolyhedrovirus (Helicovex®) + TX, Helicoverpa zea nuclear polyhedrosis virus (Gemstar®) + TX, Isaria fumosorosea (formerly known as Paecilomyces fumosoroseus strain + TX, PFR-97® + TX, PreFeRal®) + TX, isoflavone-formononetin (Myconate®) + TX, Kloeckera apiculata + TX, Kloeckera spp.) + TX, Lagenidium giganteum (Laginex®) + TX, conidia of Lecanicillium lecanii (formerly known as Verticillium lecanii) (Mycotal®) strain KV01 (e.g., Vertalec® by Koppert / Arysta) + TX, conidia of Lecanicillium longisporum (Vertiblast®) strain KV01 (e.g., Vertalec® by Koppert / Arysta) + TX, Lecanicillium muscarium (Vertikil®) + TX, gypsy moth nucleopolyhedrosis virus (Lymantria dispar nucleopolyhedrosis virus) virus) (Disparvirus®) + TX, Marinococcus halophilus + TX, Meira geulakonigii + TX, Metarhizium anisopliae (DestruxinWP®) + TX, Metarhizium anisopliae (Met52®) + TX, Metschnikowia fruticola (Shemer®) + TX, Metschnikowia pulcherrima + TX, Microdochium dimerum (Antibot®) + TX, Micromonospora coerulea + TX, Microsphaeropsis ochracea + TX, Muscodor albus 620 (Muscudor®) + TX, Muscodor roseus, particularly strain A3-5 (accession number NRRL 30548) + TX, Mycorrhizae spp. (AMykor® + TX, Root Maximizer®) + TX, Myrothecium verrucaria strain AARC-0255 (DiTera®) + TX, BROS PLUS® + TX, Ophiostoma piliferum strain D97 (Sylvanex®) + TX, Paecilomyces farinosus + TX, Paecilomyces lilacinus strain 251 (MeloCon WG®) + TX, Paecilomyces linacinus (Biostat®) + TX, WP®) + TX, Paenibacillus polymyxa + TX, Pantoea agglomerans (BlightBan C9-1®) + TX, Pantoea spp. + TX, Pasteuria nishizawaenishizawae, especially Pn1 (CLARIVA from Syngenta / ChemChina) + TX; + TX, Pasteuria spp. (Econem®) + TX, Penicillium aurantiogriseum + TX, Penicillium billai (Jumpstart® + TX, TagTeam®) + TX, Penicillium brevicompactum + TX, Penicillium frequentans + TX, Penicillium griseofulvum + TX, Penicillium purpurogenum + TX, Penicillium spp. spp.) + TX, Penicillium viridicatum + TX, Phlebiopsis gigantean (Rotstop®) + TX, Phosphhomeal® + TX, Phytophthora cryptogea + TX, Phytophthora palmivora (Devine®) + TX, Pichia anomala + TX, Pichia guilermondii + TX, Pichia membranaefaciens + TX, Pichia onychis + TX, Pichia stypithis stipites) + TX, Pseudomonas aeruginosa) + TX, Pseudomonas aureofaciens (Spot-Less Biofungicide®) + TX, Pseudomonas cepaciacepacia + TX, Pseudomonas chlororaphis (AtEze®) + TX, Pseudomonas corrugate + TX, Pseudomonas fluorescens strain A506 (BlightBan A506®) + TX, Pseudomonas putida + TX, Pseudomonas reactans + TX, Pseudomonas spp. + TX, Pseudomonas syringae (Bio-Save®) + TX, Pseudomonas viridiflava + TX, Pseudomonas fluorescens fluorescens (Zequanox®) + TX, Pseudozyma flocculosa strain PF-A22UL (Sporodex L®) + TX, Puccinia canaliculata + TX, Puccinia thlaspeos (Wood Warrior®) + TX, Pythium paroecandrum + TX, Pythium oligandrum (Polygandron® + TX, Polyversum®) + TX, Rhanella aquatilis + TX, Rhanella sp. spp.) + TX, Rhizobia (Dormal® + TX, Vault®) + TX, Rhizoctonia + TX, Rhodococcus globerulus strain AQ719 + TX, Rhodosporidium diobovatum + TX, Rhodosporidium toruloidestoruloides) + TX, Rhodotorula glutinis + TX, Rhodotorula graminis + TX, Rhodotorula mucilagnosa + TX, Rhodotorula rubra + TX, Rhodotorula spp. + TX, Saccharomyces cerevisiae + TX, Salinococcus roseus + TX, Sclerotinia minor + TX, Sclerotinia minor (SARRITOR®) + TX, Scytalidium spp. + TX, Scytalidium uredinicola + TX, Serratia marcescens + TX, Serratia plymuthica + TX, Serratia spp.) + TX, Sordaria fimicola + TX, Spodoptera exigua nuclear polyhedrosis virus (Spod-X® + TX, Spexit®) + TX, Spodoptera littoralis nucleopolyhedrovirus (Littovir®) + TX, Sporobolomyces roseus + TX, Stenotrophomonas maltophilia + TX, Streptomyces hygroscopicus + TX, Streptomyces albaduncus + TX, Streptomyces exfoliate exfoliates + TX, Streptomyces galbus + TX, Streptomyces griseoplanus + TX, Streptomyces griseoviridis (Mycostop®) + TX, Streptomyces lydicus (Actinovate®) + TX, Streptomyces lydicus WYEC-108 (ActinoGrow®) + TX, Streptomyces violaceus + TX, Tilletiopsis minor + TX, Tilletiopsis spp.) + TX, Trichoderma asperellum (T34 Biocontrol®) + TX, Trichoderma atroviride (Plantmate®) + TX, Trichoderma gamsii (Tenet®) + TX, Trichoderma hamatum TH382 + TX, Trichoderma harzianum rifai (Mycostar®) + TX, Trichoderma harzianum T-22 (Trianum-P® + TX, PlantShield HC® + TX, RootShield® + TX, Trianum-G®) + TX, Trichoderma harzianum harzianum) T-39 (Trichodex®) + TX, Trichoderma inhamatum + TX, Trichoderma koningii + TX, Trichoderma lignorum + TX, Trichoderma longibrachiatum + TX, Trichoderma polysporum (Binab T®) + TX, Trichoderma spp.) LC52 (Sentinel®) + TX, Trichoderma taxi + TX, Trichoderma virens + TX, Trichoderma virens (formerly Gliocladium virens GL-21) (SoilGuard®) + TX, Trichoderma viride + TX, Trichoderma viride strain ICC 080 (Remedier®) + TX, Trichosporon pullulans + TX, Trichosporon spp. + TX, Trichothecium roseum + TX, Trichothecium spp.) + TX, Typhula phacorrhiza strain 94671 + TX, Ulocladium atrum + TX, Ulocladium oudemansii (Botry-Zen®) + TX, Ustilago maydis + TX, various bacteria and supplemental trace elements (Natural II®) + TX, various fungi (Millennium Microbes®) + TX, Verticillium chlamydosporium + TX, Vip3Aa20 (VIPtera®) + TX, Virgibacillus marismortii marismortui + TX, Xanthomonas campestris pv. Poae (Camperico®) + TX, Xenorhabdfus bovienii + TX, Xenorhabdus nematophilus + TX;. Azadirachtin (Plasma Neem Oil® +TX, AzaGuard® +TX, MeemAzal® +TX, Molt-X® +TX, e.g., AZATIN XL from Certis+US), +TX, Botanical IGR (Neemazad® +TX, Neemix®) +TX, canola oil (Lilly Miller Vegol®) +TX, antler (Chenopodium ambrosioides near ambrosioides) (Requiem®) +TX, chrysanthemum (Chrysanthemum) extract (Crisant®) +TX, neem oil extract (Trilogy®) +TX, extracts of clove, rosemary, peppermint, and thyme oils (Garden insect killer®) + TX, garlic + TX, glycine betaine (Greenstim®) + TX, kaolin (Screen®) + TX, lemongrass oil (GreenMatch®) + TX, tea tree extract (Melaleuca alternifolia extract) (also known as tea tree oil) (Timorex Gold®) + TX, clove, peppermint, garlic oil and mint mixture (Soil Shot®) + TX, clove, rosemary and peppermint extract mixture (EF400®) + TX, rosemary, sesame, peppermint, thyme and cinnamon extract mixture (EF300®) + TX, neem oil + TX, catnip (Nepeta cataria) (catnip oil) + TX, catnip (Nepeta cataria) +TX, Nicotine +TX, Oregano Oil (MossBuster®) +TX, Sesame (Pedaliaceae) Oil (Nematon®) +TX, Pine Oil (Retenol®) +TX, Pyrethrum +TX, Quillaja saponaria (NemaQ®) +TX, Giant Knotweed (Reynoutriasachalinensis) (Regalia® +TX, Sakalia®) +TX, rotenone (Eco Roten®) +TX, tangerine (Rutaceae) plant extract (Soleo®) +TX, soybean oil (Ortho ecosense®) +TX, brown algae storage glucan (Laminarin®) +TX, thyme oil (AGNIQUE® MMF +TX, BugOil®) +TX; (E,Z)-7,9-dodecadien-1-yl acetate + TX, (E,Z,Z)-3,8,11 tetradecatrienyl acetate + TX, (Z,Z,E)-7,11,13-hexadecatrienal + TX, 2-methyl-1-butanol + TX, Biolure® + TX, blackheaded fireworm pheromone (3M Sprayable Blackheaded Fireworm Pheromone®) + TX, calcium acetate + TX, Check-Mate® + TX, codling moth pheromone (Paramount dispenser-(CM) / Isomate C-Plus®) + TX, Entostat powder (palm tree extract) (Exosex CM®) + TX, grape berry moth pheromone (3M MEC-GBM Sprayable Pheromone®) + TX, Lavandulyl Senecioate + TX, Leafroller Pheromone (3M MEC-LR Sprayable Pheromone®) + TX, Muscamone (Snip7 Fly Bait®) + TX, Oriental Fruit Moth Pheromone (3M oriental fruit moth sprayable pheromone®) + TX, Peachtree Borer Pheromone (Isomate-P®) + TX, Scenturion® + TX, Starbar Premium Fly Bait®) + TX, Tomato Pinworm Pheromone (3M Sprayable pheromone®) + TX; Fopius arisanus + TX, Acerophagus papaya + TX, Adalia bipunctata (Adalia-System®) + TX, Adalia bipunctata (Adaline®) + TX, Adalia bipunctata (Aphidalia®) + TX, Ageniaspis citricola + TX, Ageniaspis fuscicollis + TX, Amblyseius andersoni (Anderline® + TX, Andersoni-System®) + TX, Amblyseius californicus californicus (Amblyline® + TX, Spical®) + TX, Amblyseius cucumeris (Thripex® + TX, Bugline cucumeris®) + TX, Amblyseius fallacis (Fallacis®) + TX, Amblyseius swirskii (Bugline swirskii® + TX, Swirskii-Mite®) + TX, Amblyseius womersleyi (WomerMite®) + TX, Amitus hesperidum + TX, Anagrus atomus + TX, Anagyrus fusciventris fusciventris + TX, Anagyrus kamali + TX, Anagyrus loecki + TX, Anagyrus pseudococci (Citripar®) + TX, Anicetus veneficesbenefices + TX, Anisopteromalus calandrae + TX, Anthocoris nemoralis (Anthocoris-System®) + TX, Aphelinus abdominalis (Apheline® + TX, Aphiline®) + TX, + TX, Aphelinus asychis + TX, Aphidius colemani (Aphipar®) + TX, Aphidius ervi (Aphelinus-System® + TX, Aphidius ervi (Ervipar®) + TX, Aphidius gifuensis + TX, Aphidius matricariae matricariae (Aphipar-M®) + TX, Aphidoletes aphidimyza (Aphidend® + TX, Aphidoline®) + TX, Aphytis lingnanensis + TX, Aphytis melinus + TX, Aprostocetus hagenowii + TX, Atheta coriaria (Staphyline®) + TX, Bombus spp. + TX, Bombus terrestris (Beeline® + TX, Tripol®) + TX, Bombus terrestris (Natupol®) + TX, Beehive® + TX, Cephalonomia stephanoderis + TX, Chilocorus nigritus + TX, Chrysoperlacarnea (Chrysoline®) + TX, Chrysopa® + TX, Chrysoperla rufilabris + TX, Cirrospilus ingenuus + TX, Cirrospilus quadristriatus + TX, Citrostichus phyllocnistoides + TX, Closterocerus chamaeleon + TX, Closterocerus spp. + TX, Coccidoxenoides perminutus (Planopar®) + TX, Coccophagus cowperi + TX, Coccophagus lyssimnia lycimnia + TX, Cotesia flavipes + TX, Cotesia plutellae + TX, Cryptolaemus montrouzieri (Cryptobug® + TX, Cryptoline®) + TX, Cybocephalus nipponicus (Cybocephalus nipponicus) + TX, Dacnusa sibirica (Minusa® + TX, DacDigline® + TX, Minex®) + TX, Delphastus catalinae (Delphastus®) + TX, Delphastus pusillus + TX, Diachasmimorpha clausii krausii + TX, Diachasmimorpha longicaudata + TX, Diaparsis jucunda + TX, Diaphorencyrtusaligarhensis + TX, Diglyphus isaea (Diminex® + TX, Miglyphus® + TX, Digline®) + TX, Diversinervus spp. + TX, Encarsia citrina + TX, Encarsia formosa (Encarsia max® + TX, Encarline® + TX, En-Strip®) + TX, Encarsia guadeloupae + TX, Encarsia haitiensis + TX, Episyrphus balteatus (Syrphidend®) + TX, Eretmoceris sihonini siphonini + TX, Eretmocerus californicus + TX, Eretmocerus eremicus (Enermix® + TX, Ercal® + TX, Eretline e® + TX, Bemimix®) + TX, Eretmocerus hayati + TX, Eretmocerus mundus (Bemipar® + TX, Eretlinem®) + TX, Eretmocerus siphonini + TX, Exochomus quadripustulatus + TX, Feltiella acarisuga (Feltiline®) + TX, Feltiella acarisuga (Spidend®) + TX, Fopius ceratitivorus (Fopius ceratitivorus) + TX, Formononetin (Wirless Beehome®) + TX, Franklinothripsvespiformis (Vespop®) + TX, Galendromus occidentalis + TX, Goniozus legneri + TX, Habrobracon hebetor + TX, Harmonia axyridis (HarmoBeetle®) + TX, Heterorhabditis bacteriophora (NemaShield HB® + TX, Nemaseek® + TX, Terranem-Nam® + TX, Terranem® + TX, Larvanem® + TX, B-Green® + TX, NemAttack® + TX, Nematop® + TX, Heterorhabditis megidis (Nemasys H® + TX, BioNem H® + TX, Exhibitlinehm® + TX, Larvanem-M®) + TX, Heterorhabditis spp. (Lawn Patrol®) + TX, Hippodamia convergens + TX, Hypoaspis aculeifer (Aculeifer-System® + TX, Entomite-A®) + TX, Hypoaspis myres miles) (Hypolinem® + TX, Entomite-M®) + TX, Lbalia leucospoides + TX, Lecanoideus floccissimus + TX, Lemophagus errabundus + TX, Leptomastidea abnormis + TX, Leptomastix dactylopii (Leptopar®) + TX, Leptomastix epona + TX, Lindorus lophanthae + TX, Lipolexis oregmae + TX, Lucilia caesar (Natufly®) + TX, Lysiphlebus testaceipes + TX, Macrolophus caliginosus (Mirical-N® + TX, Macrolinec® + TX, Mirical®) + TX, Mesoseiulus longipeslongipes + TX, Metaphycus flavus + TX, Metaphycus lounsburyi + TX, Micromus angulatus (Milacewing®) + TX, Microterys flavus + TX, Muscidifurax raptorellus and Spalangia cameroni (Biopar®) + TX, Neodryinus typhlocybae + TX, Neoseiulus californicus + TX, Neoseiulus cucumeris (THRYPEX®) + TX, Neoseiulus fallasis fallacis + TX, Nesideocoris tenuis (NesidioBug® + TX, Nesibug®) + TX, Ophyra aenescens (Biofly®) + TX, Orius insidiosus (Thripor-I® + TX, Oriline i®) + TX, Orius laevigatus (Thripor-L® + TX, Oriline l®) + TX, Orius majusculus (Orilinem®) + TX, Orius strigicollis (Thripor-S®) + TX, Pauesia juniperorum juniperorum + TX, Pediobius foveolatus + TX, Phasmarhabditis hermaphrodita (Nemaslug®) + TX, Phymastichuscoffea + TX, Phytoseiulus macropilus + TX, Phytoseiulus persimilis (Spidex® + TX, Phytoline p®) + TX, Podisus maculiventris (Podisus®) + TX, Pseudacteon curvatus + TX, Pseudacteon obtusus + TX, Pseudacteon tricuspis + TX, Pseudaphycus maculipennis + TX, Pseudleptomastix mexicana + TX, Psyllaephagus pilosus pilosus + TX, Psyttalia concolor (complex) + TX, Quadrastichus spp. + TX, Rhyzobius lophanthae + TX, Rodolia cardinalis + TX, Rumina decollate + TX, Semielacher petiolatus + TX, Sitobion avenae (Ervibank®) + TX, Steinernema carpocapsae (Nematac C® + TX, Millennium® + TX, BioNem C®+TX, NemAttack®+TX, Nemastar®+TX, Capsanem®+TX, Steinernema feltiae (NemaShield®+TX, Nemasys F®+TX, BioNemF® + TX, Steinernema-System® + TX, NemAttack® + TX, Nemaplus® + TX, Exhibitline sf® + TX, Scia-rid® + TX, Entonem® + TX, Steinernema kraussei (Nemasys L® + TX, BioNem L® + TX, Exhibitline srb®) + TX, Steinernema riobrave (BioVector® + TX, BioVektor®) + TX, Steinernema scapterisci (Nematac S®) + TX, Steinernema spp. + TX, Steinernema spp. (Guardian Nematodes®) + TX, Stethorus punctillum (Stethorus®) + TX, Tamarixia radiate + TX, Tetrastichus setifer + TX, Thripobius semiluteus + TX, Torymus sinensis + TX, Trichogramma brassicae (Tricholine b®) + TX, Trichogramma brassicae (Tricho-Strip®) + TX, Trichogramma evanescens + TX, Trichogramma minutum + TX, Trichogramma ostriniae ostriniae) + TX, Trichogramma platneri + TX, Trichogramma pretiosumpretiosum) + TX, Yellow-legged flathead wasp (Xanthopimpla stemmator) + TX; Abscisic acid + TX, Aminomité® + TX, BioGain® + TX, bioSea® + TX, Chondrostereum purpureum (Chontrol Paste®) + TX, Colletotrichum gloeosporioides (Collego®) + TX, Copper octanoate (Cueva®) + TX, Delta Trap (Trapline d®) + TX, Erwinia amylovora (Harpin) (ProAct® + TX, Ni-HIBIT Gold CST®) + TX, Fatty acids derived from natural by-products of extra virgin olive oil (FLIPPER®) + TX, Ferri-phosphate (Ferramol®) + TX, Funnel Trap (Trapline y®) + TX, Gallex® + TX, Grower's Secret® + TX, Homo-brassonolide + TX, Iron phosphate (Lilly Miller Worry Free Ferramol Slug & Snail Bait®) + TX, MCP hail trap (Trapline f®) + TX, Microctonus hyperodae + TX, Mycoleptodiscus terrestris (Des-X®) + TX, Nosema locustae (Semaspore Organic Grasshopper Control®) + TX, pheromone trap (Thripline ams®) + TX, potassium bicarbonate (MilStop®) + TX, potassium iodide + potassium thiocyanate (Enzicur®) + TX, potassium salts of fatty acids (Sanova®) + TX, potassium silicate solution (Sil-Matrix®) + TX, spider venom + TX, sticky traps (Trapline YF® + TX, RebellAmarillo®) + TX, SuffOil-X® + TX, trap (Takitrapline y+b®) + TX, Zenox® + TX; Bacillus mojavensis strain R3B (accession number NCAIM(P)B001389) from Certis USA LLC (WO 2013 / 034938), Bacillus pumilus +TX, in particular strain BU F-33 +TX having NRRL accession number 50185 (CARTISSA® +TX from BASF, EPA registration number 71840-19) +TX, Bacillus subtilis CX-9060 from Certis USA LLC, Bacillus sp. +TX, in particular strain D747 having accession number FERM BP-8234 (DOUBLE BLUE BLUE BLUE from Kumiai Chemical Industry Co. +TX, Ltd.), NICKEL®) +TX, U.S. Pat. No. 7,094,592 +TX, Bacillus subtilis strain BU1814 +TX, (VELONDIS® PLUS +TX, VELONDIS® FLEX and VELONDIS® EXTRA from BASF SE) +TX, Bacillus subtilis var. amyloliquefaciens strain FZB24 with accession number DSM 10271 (available as TAEGRO® or TAEGRO® ECO from Novozymes (EPA registration number 70127-5)) +TX, Bacillus subtilis +TX, in particular strain QST713 / AQ713 (with NRRL accession number B-21661 and described in U.S. Pat. No. 6,060,051 +TX, Bayer CropScience LP+TX, available as SERENADE® OPTI or SERENADE® ASO from US)+TX, Paenibacillus polymyxa+TX, in particular strain AC-1 (e.g., TOPSEED® from Green Biotech Company Ltd.)+TX, Paenibacillus sp. having accession number NRRL B-50972 or accession number NRRL B-67129.) strain +TX, WO 2016 / 154297 +TX, Pantoea agglomerans +TX, in particular strain E325 (accession number NRRL B-21856) (available from Northwest Agri Products as BLOOMTIME BIOLOGICAL™ FD BIOPESTICIDE) +TX, Pseudomonas proradix (e.g., PRORADIX® from Sourcon Padena) +TX; Aureobasidium pullulans + TX, in particular blastospores of the strain DSM 14940 + TX, blastospores of the strain DSM 14941 or a mixture of blastospores of the strains DSM 14940 and DSM 14941 (e.g. BOTECTOR® and BLOSSOM PROTECT® + TX from bio-ferm, CH) + TX; Pseudozyma aphidis (as disclosed in WO 2011 / 151819 by Yissum Research Development Company of the Hebrew University of Jerusalem) + TX; Saccharomyces cerevisiae from Lesaffre et Compagnie. cerevisiae) + TX, in particular strain CNCM No. 1-3936 + TX, CNCM No. 1-3937 + TX, CNCM No. 1-3938 or CNCM No. 1-3939 (WO 2010 / 086790) + TX; Bacteria including Agrobacterium radiobacter strain K84 (e.g., GALLTROL-A® from AgBioChem, CA) +TX, Bacillus amyloliquefaciens isolate B246 (e.g., AVOGREEN® from University of Pretoria) +TM, Bacillus amyloliquefaciens strain F727 (also known as strain MBI110) (NRRL accession number B-50768 +TX, WO 2014 / 028521) (STARGUS® from Marrone Bio Innovations) +TX, Bacillus amyloliquefaciens strain FZB42 +TX, accession number DSM 23117 (available as RHIZOVITAL® from ABiTEP®, DE)®, Bacillus amyloliquefaciens®, particularly strain D747 (available as Double Nickel® from Kumiai Chemical Industry Co., Ltd., having accession number FERM BP-8234®, U.S. Pat. No. 7,094,592) TX, Bacillus licheniformis FMCH001 and Bacillus subtilis FMCH002 (QUARTZO® (WG) and PRESENCE® (WG) from FMC Corporation) + TX, Bacillus licheniformis + TX, in particular strain SB3086 having accession number ATCC 55406 + TX, WO 2003 / 000051 (available from Novozymes as ECOGUARD® biological control agent and GREEN RELEAF™) + TX, Bacillus methylotrophicus strain BAC-9912 (from the Chinese Academy of Sciences' Institute of Applied Ecology) + TX, Bacillus mycoides mycoides +TX, isolate +TX, having accession number B-30890 (available from Certis USA LLC as BMJ TGAI® or WG and LifeGard®) +TX, Bacillus pumilus +TX, in particular strain GB34 (available from Bayer AG +TX, DE as Yield Shield®) +TX, Bacillus pumilus +TX, in particular strain QST2808 (having accession number NRRL B-30087 and described in U.S. Pat. No. 6,245,551, Bayer CropScience LP +TX,US) + TX, Bacillus subtilis CX-9060 from Certis USA LLC, Bacillus subtilis IAB / BS03 (AVIV™ + TX from STK Bio-Ag Technologies, PORTENTO™ from Idai Nature) + TX, Bacillus subtilis strain KTSB (FOLIACTIVE™ from Donaghys) + TX, Bacillus subtilis strain BU1814 + TX (VELONDIS™ PLUS + TX, VELONDIS™ FLEX, and VELONDIS™ EXTRA from BASF SE) + TX, Bacillus subtilis strain GB03 (available as Kodiak™ from Bayer AG + TX, DE) + TX, Bacillus subtilis strain MBI 600 (BASF Bacillus subtilis strain Y1336 (available from Bion-Tech, Taiwan as BIOBAC® WP) +TX, registered in Taiwan as a biological fungicide under registration numbers 4764, 5454, 5096, and 5277 +TX), Bacillus subtilis var. amyloliquefaciens strain FZB24 (available from Novozymes as TAEGRO® or ECO® (EPA registration number 70127-5)) +TX, Bacillus subtilis var. amyloliquefaciens strain FZB24 (available from Novozymes as TAEGRO® or ECO® (EPA registration number 70127-5)) +TX, Bacillus subtilis) Y1336 (Bion-Tech+TX, registered as a biological fungicide in Taiwan under registration numbers 4764+TX, 5454+TX, 5096, and 5277,available as BIOBAC® WP from Taiwan +TX), Paenibacillus epiphyticus from BASF SE (WO 2016 / 020371) +TX, Paenibacillus polymyxa ssp. plantarum from BASF SE (WO 2016 / 020371) +TX, Paenibacillus sp. strains having accession number NRRL B-50972 or NRRL B-67129 +TX, WO 2016 / 154297 +TX, Pseudomonas chlororaphis strain AFS009 +TX, accession number NRRL B-50897+TX, International Publication No. 2017 / 019448 (e.g., +TX, AgBiome Innovations+TX,HOWLER™ and ZIO® from the US) + TX, Pseudomonas chlororaphis + TX, in particular strain MA342 (e.g. CEDOMON® + TX, CERALL® + TX and CEDRESS® from Bioagri and Koppert) + TX, Pseudomonas fluorescens strain A506 (e.g. BLIGHTBAN® A506 from NuFarm) + TX, Pseudomonas proradix (e.g. PRORADIX® from Sourcon Padena) + TX, Streptomyces griseoviridis strain K61 (also known as Streptomyces galbus strain K61) (accession number DSM 7206) (MYCOSTOP® +TX from Verdera, PREFENCE® +TX from BioWorks, ref: Crop Protection 2006+TX, 25+TX, 468-475) +TX, Streptomyces lydicus strain WYEC108 (also known as Streptomyces lydicus strain WYCD108US) (® and ACTINOVATE® from Novozymes) +TX; Trichoderma atroviride strain T11 (IMI352941 / CECT20498)+TX, having the accession number CNCM 1-807, Ampelomyces quisqualis strain AQ10+TX (e.g., +TX, AQ 10® by IntrachemBio Italia)+TX, Ampelomyces quisqualis+TX, especially strain AQ 10 (e.g., AQ 10® by IntrachemBio Italia)+TX, Aspergillus flavus strain NRRL 21882 (product known as AFLA-GUARD® manufactured by Syngenta / ChemChina) + TX, Aureobasidium pullulans + TX, in particular blastospores of the strain DSM 14941 + TX, Aureobasidium pullulans + TX, in particular blastospores of the strain DSM 14940 + TX, Aureobasidium pullulans + TX, in particular a mixture of blastospores of the strains DSM 14940 and DSM 14941 (e.g. bio-ferm + TX,Botector® by CH) + TX, Chaetomium cupreum (accession number CABI 353812) (e.g., BIOKUPRUM® by AgriLife) + TX, Chaetomium globosum (available as RIVADIOM® by Rivale) + TX, Cladosporium cladosporioides + TX, strain H39 + TX, having accession number CBS122244 + TX, US Patent Application Publication No. 2010 / 0291039 (according to Stichting Dienst Landbouwkundig Onderzoek) + TX, Coniothyrium minitans + TX, in particular strain CON / M / 91-8 (accession number DSM9660 + TX, e.g., Bayer Contans® from CropScience Biologics GmbH) + TX, Cryptococcus flavescens + TX, strain 3C (NRRL Y-50378) + TX, + TX, Dactylaria candida + TX, Dilophosphora alopecuri (available as TWIST FUNGUS®) + TX, Fusarium oxysporum + TX, strain Fo47 (available as FUSACLEAN® by Natural Plant Protection) + TX, Gliocladium catenulatum (synonym: Clonostachys rosea f. catenulatum), strain J1446 (e.g., Prestop® by Lallemand) + TX, Gliocladium roseum (also known as Clonostachys rosea f. rosea) strain IK726 (Jensen DF + TX, et al., Development of a biocontrol agent for plant disease control with special emphasis on the near commercial fungal antagonist Clonostachys rosea strain 'IK726', Australasian Plant Pathol. 2007, 36(2):95-101) + TX, Gliocladium roseum (also known as Clonostachys rosea f. rosea) + TX, strain 321U + TX, especially from Adjuvants Plus, Xue AG (Efficacy of Clonostachys rosea strain strain ACM941+TX as disclosed in "ACM941 and fungicide seed treatments for controlling the root tot complex of field pea+TX, Can Jour Plant Sci 2003+TX, 83(3):519-524," Metschnikowia fructicola+TX, in particular the strain NRRL Y-30752+TX, Microsphaeropsis ochracea+TX, Penicillium steckii from BASF SE (DSM 27859+TX, WO 2015 / 067800)+TX, Trichoderma asperellum strain ICC having the accession number CABI CC IMI 392716. 012 (Trichoderma harzianum)harzianum ICC012 +TX) with accession number IMI 392151 (formerly T. viride strain ICC 080 +TX (e.g., +TX, BIO-TAM™ from Isagro USA +TX, Inc. or BIODERMA® from Agrobiosol de Mexico +TX, SA de CV) +TX, Penicillium vermiculatum +TX, Phlebiopsis gigantea strain VRA 1992 (ROTSTOP® from Danstar Ferment) +TX, Pseudozyma flocculosa strain PF-A22 UL (Plant Products Saccharomyces cerevisiae strain LAS117 cell walls (CEREVISANE® from Lesaffre, ROMEO® from BASF SE) + TX, Saccharomyces cerevisiae strains CNCM No. 1-3936 + TX, CNCM No. 1-3937 + TX, CNCM No. 1-3938 + TX, CNCM No. 1-3939 (WO 2010 / 086790) + TX from Lesaffre et Compagnie + TX, FR, Saccharomyces cerevisiae + TX, in particular the strain LASO2 (Agro-Levures et Derives) +TX, Simplicillium lanosoniveum +TX, strain T34 (e.g., T34 Biocontrol by Biocontrol Technologies SL +TX, ES) or strain ICC 012 +TX from Isagro, strain WRL-076 (NRRLY-30842) + TX, U.S. Pat. No. 7,579,183 + TX, Talaromyces flavus + TX, strain V117b + TX, Trichoderma asperelloides JM41R (accession number NRRL B-50759) (TRICHO PLUS® from BASF SE) + TX, Trichoderma asperellum + TX, in particular the strain SKT-1 + TX having the accession number FERM P-16510 (e.g. ECO-HOPE® from Kumiai Chemical Industry) + TX, Trichoderma asperellum + TX, in particular + TX, strain kd (e.g. T-Gro from Andermatt Biocontrol) + TX, Trichoderma atroviride Trichoderma atroviride strain 77B (T77 from Andermatt Biocontrol) +TX, Trichoderma atroviride strain ATCC 20476 (IMI 206040) +TX, Trichoderma atroviride strain LC52 (e.g., Tenet from Agrimm Technologies Limited) +TX, Trichoderma atroviride strain LU132 (e.g., Sentinel from Agrimm Technologies Limited) +TX, TX, Trichoderma atroviride strain NMI number V08 / 002388 +TX, Trichoderma atroviride strain NMI number V08 / 002389 +TX, Trichoderma atroviride atroviride strain NMI number V08 / 002390+TX, Trichoderma atroviride strain number V08 / 002387+TX, Trichoderma atroviride strain SKT-1 (FERMP-16510) + TX, JP 11-253151 A + TX, Trichoderma atroviride strain SKT-2 (FERM P-16511) + TX, JP 11-253151 A + TX, Trichoderma atroviride strain SKT-3 (FERM P-17021) + TX, JP 11-253151 A + TX, Trichoderma atroviride strain + TX, in particular strain SC1 (accession number CBS 122089 + TX, WO 2009 / 116106 and U.S. Pat. No. 8,431,120 (manufactured by Bi-PA)) + TX, Trichoderma atroviride atroviride strain CNCM 1-1237 (e.g., Agrauxine + TX, Esquive® WP from FR) + TX, Trichoderma fertile (e.g., the product TrichoPlus from BASF) + TX, Trichoderma gamsii (formerly T. viride) + TX, Trichoderma gamsii (formerly T. viride) strain ICC 080 (IMI CC 392151 CABI) (available as BIODERMA® by AGROBIOSOL DE MEXICO + TX, SADE CV) + TX, Trichoderma gamsii strain ICC080 (IMI CC 392151 CABI) + TX, e.g., AGROBIOSOL DE MEXICO+TX, BioDerma by SADE CV+TX, +TX, Trichoderma harmatum+TX, Trichoderma harzianum+TX, Trichoderma harzianum riffai (Trichoderma harzianum riffai) with accession number ATCC 28012rifai) T39 (e.g., Trichodex® from Makhteshim + TX, US) + TX, Trichoderma harzianum strain Cepa SimbT5 (manufactured by Simbiose Agro) + TX, + TX, Trichoderma harzianum strain DB 103 (T-GRO® from Dagutat Biolab) 7456) +TX, Trichoderma harzianum strain ITEM 908 (e.g., Trianum-P from Koppert) +TX, Trichoderma harzianum strain T-22 (e.g., Trianum-P from Andermatt Biocontrol or Koppert) +TX, Trichoderma harzianum strain TH35 (e.g., Root-Pro from Mycontrol) +TX, Trichoderma polysporum strain IMI 206039 (e.g., Binab TF WP from BINAB Bio-Innovation AB +TX, Sweden) +TX, Trichoderma stromaticum with accession number Ts3550 stromaticum (e.g., Tricovab by CEPLAC +TX, Brazil) +TX, Trichoderma virens (also known as Gliocladium virens), in particular the strain GL-21 (e.g., SoilGard by Certis +TX, US), Trichoderma virens strain G-41 +TX (accession number ATCC 20906), formerly known as Gliocladium virens (e.g., ROOTSHIELD® and TURFSHIELD® PLUS WP from BioWorks +TX, US) +TX, Trichoderma viride, in particular the strain B35 (Pietr et al. +TX, 1993 +TX, Zesz. Nauk.AR w Szczecinie 161:125-137)+TX, Trichoderma viride strain TV1 (e.g., Trianum-P by Koppert)+TX, Ulocladium oudemansii strain U3+TX having accession number NM 99 / 06216 (e.g., BOTRY-ZEN® by Botry-Zen Ltd+TX, New Zealand and BOTRYSTOP® from BioWorks+TX, Inc.)+TX, Verticillium albo-atrum (formerly V. dahliae) strain WCS850+TX having accession number WCS850 deposited at the Central Bureau for Fungi Cultures (e.g., DUTCH by Tree Care Innovations)+TX, TRIG® + TX, Verticillium chlamydosporium + TX; Bacteria including a mixture of Azotobacter vinelandii and Clostridium pasteurianum (available from Agrinos as INVIGORATE®) TX, a mixture of Bacillus licheniformis FMCH001 and Bacillus subtilis FMCH002 (available from FMC Corporation as QUARTZO® (WG) + TX, PRESENCE® (WG)) + TX, Azorhizobium caulinodans + TX, particularly strain ZB-SK-5 + TX, Azospirillum brasilense (e.g., + TX, VIGOR® from KALO+TX, Inc.) + TX, Azospirillum lipoferrum lipoferum (e.g., +TX, VERTEX-IF™ from TerraMax+TX, Inc.) +TX, Azotobacter chroococcum +TX, in particular the strain H23 +TX, Azotobacter vinelandii +TX, in particular the strain ATCC 12837 +TX, Bacillus amyloliquefaciens BS27 (accession number NRRL B-5015) +TX, Bacillus amyloliquefaciens, in particular the strain FZB42 (e.g., ABiTEP+TX, RHIZOVITAL™ from DE) +TX, Bacillus amyloliquefaciens amyloliquefaciens, in particular the strain IN937a+TX, Bacillus amyloliquefaciens pm414 (LOLI-PEPTA® from Biofilm Crop Protection)+TX, Bacillus amyloliquefaciens SB3281 (ATCC#PTA-7542 +TX, WO 2017 / 205258 +TX, Bacillus amyloliquefaciens TJ1000 (available as QUIKROOTS® from Novozymes) +TX, Bacillus cereus family member EE128 (NRRL No. B-50917) +TX, Bacillus cereus family member EE349 (NRRL No. B-50928) +TX, Bacillus cereus, particularly strain BP01 (ATCC 55675 +TX, e.g., MEPICHLOR® from Arysta Lifescience, TX, US) +TX, Bacillus mycoides mycoides BT155 (NRRL No. B-50921) +TX, Bacillus mycoides BT46-3 (NRRL No. B-50922) +TX, Bacillus mycoides EE118 (NRRL No. B-50918) +TX, Bacillus mycoides EE141 (NRRL No. B-50916) +TX, Bacillus pumilus, particularly strain GB34 (e.g., YIELD SHIELD® from Bayer Crop Science, TX, DE) +TX, Bacillus pumilus, particularly strain QST2808 (Accession No. NRRL No. B-30087) +TX, Bacillus siamensis siamensis, particularly strain KCTC 13613T+TX, Bacillus subtilis, particularly strain AQ30002 (described in Accession No. NRRL No. B-50421 and U.S. Patent Application Publication No. 13 / 330,576)+TX, Bacillus subtilis, particularly strain AQ30004 (described in NRRL No. B-50455 and U.S. Patent Application Publication No. 13 / 330,576)+TX, Bacillus subtilis, particularly strain MBI 600 (e.g., BASFSUBTILEX® from BASF SE) +TX, Bacillus subtilis rm303 (RHIZOMAX® from Biofilm Crop Protection) +TX, Bacillus subtilis strain BU1814 (available as TEQUALIS® from BASF SE) +TX, Bacillus tequilensis, particularly strain NII-0943 +TX, Bacillus thuringiensis BT013A (NRRL number B-50924) (also known as Bacillus thuringiensis 4Q7) +TX, Bradyrhizobium japonicum (e.g., OPTIMIZE® from Novozymes) +TX, Delftia acidovorans acidovorans, in particular the strain RAY209 (e.g. BIOBOOST® from Brett Young Seeds) +TX, Lactobacillus sp. (e.g. LACTOPLANT® from LactoPAFI) +TX, Mesorhizobium cicer (e.g. +TX, NODULATOR from BASF SE) +TX, Paenibacillus polymyxa, in particular the strain AC-1 (e.g. TOPSEED® from Green Biotech Company Ltd.) +TX, Pseudomonas aeruginosa, in particular PN1 +TX, Pseudomonas proradix (e.g. Sourcon PRORADIX® +TX from Padena, Rhizobium leguminosarium biovar viciae (e.g., +TX, NODULATOR® +TX from BASF SE), Rhizobiumleguminosarum, in particular bv.viceae strain Z25 (accession number CECT 4585) + TX, Serratia marcescens, in particular strain (accession number MTCC 8708) + TX, + TX, Sinorhizobium meliloti strain NRG-185-1 (NITRAGIN® GOLD from Bayer CropScience) + TX, Thiobacillus sp. (e.g. CROPAID® from Cropaid Ltd UK) + TX; Myrothecium verrucaria strain AARC-0255 (e.g., DiTera™ from Valent Biosciences) +TX, Penicillium bilaii strain ATCC 22348 (e.g., JumpStart® from Acceleron BioAg) +TX, Penicillium bilaii strain ATCC ATCC20851 +TX, Purpureocillium lilacinum (formerly known as Paecilomyces lilacinus) strain 251 (AGAL 89 / 030550 +TX, e.g., BioAct from Bayer CropScience Biologics GmbH) +TX, Pythium oligandrum oligandrum strain DV74+TX, Pythium oligandrum strain M1 (ATCC 38472, e.g., Polyversum from Bioprepraty+TX, CZ)+TX, Rhizopogon amylopogon (Myco-Sol from Agri-Enterprise, LLC, formerly Helena Chemical Company)+TX, Rhizopogon fulvigleba (e.g., Myco-Sol from Agri-Enterprise, LLC, formerly Helena Chemical Company)+TX, Talaromyces flavus strain V117b+TX, Trichoderma asperellum strain (Eco-T from Plant Health Products, ZA)+TX; Mercuric oxide + TX, octhilinone + TX, thiophanate-methyl + TX; MGK 264 + TX, 2-(2-butoxyethoxy)ethyl piperonylate + TX, 2-isovalerylindan-1,3-dione + TX, 4-(quinoxalin-2-ylamino)benzenesulfonamide + TX, 5-(1,3-benzodioxol-5-yl)-3-hexylcyclohex-2-enone + TX, acibenzolar + TX, acibenzolar-S-methyl + TX, alpha-bromadiolone + TX, alpha-chlorohydrin + TX, aluminum phosphide + TX, anthraquinone + TX, anthraquinone + TX, arsenic acid + TX, barium carbonate + TX, beno Xacol +TX, Bisthiosemi +TX, Brodifacoum +TX, Bromadiolone +TX, Bromethalin +TX, Calcium cyanide +TX, Chloralose +TX, Chlorophacinone +TX, Cholecalciferol +TX, Cloquintocet (including Cloquintocet-methyl) +TX, Copper naphthenate +TX, Copper oxychloride +TX, Coumachlor +TX, Coumafuryl +TX, Coumatetralyl +TX, Crimidine +TX, Cyprosulfamide +TX, Diazinon +TX, Dichlormid +TX, Dicyclopentadiene +TX, Difenacoum +TX, Di Fethialone +TX, Diphacinone +TX, Ergocalciferol +TX, Farnesol +TX, Farnesol and Nerolidol +TX, Fenchlorazole (including Fenchlorazole-ethyl) +TX, Fenclorim +TX, Flocoumafen +TX, Fluoroacetamide +TX, Flupropaline +TX, Flupropaline Hydrochloride +TX, Fluxofenim +TX, Furilazole +TX, Gamma-HCH +TX, Guazatine +TX, Guazatine Acetate +TX, HCH +TX, Hydrogen Cyanide +TX, Imanine +TX, Iodomethane +TX, Iso Xadifen (including isoxadifen-ethyl) + TX, lindane + TX, magnesium phosphide + TX, MB-599 + TX, mefenpyr (mefenpyr-diethyl) + TX, metcamifen + TX, methiocarb + TX, methyl bromide + TX, nerolidol + TX, norbormide + TX, petroleum + TX, fosacetim + TX, phosphine + TX, phosphorus + TX, pindone + TX, piperonyl butoxide + TX, piprotal + TX, potassium arsenite + TX, probenazole + TX, propyl isomer + TX, pyridin-4-amine + TX, pyrinuron + TX,Giant knotweed (Reynoutria sachalinensis) extract +TX, ribavirin +TX, S421 +TX, sciliroside +TX, sesamex +TX, sesamolin +TX, sodium arsenite +TX, sodium cyanide +TX, sodium fluoroacetate +TX, strychnine +TX, sulfoxide +TX, thallium sulfate +TX, thiram +TX, trimethacarb +TX, warfarin +TX, zinc naphthenate +TX, zinc phosphide +TX, ziram +TX.

[0168] A reference in parentheses (if present) following an active ingredient, such as [3878-19-1], refers to the Chemical Abstracts Registry number. The aforementioned mixing partners are publicly known. When active ingredients are included in "The Pesticide Manual" [The Pesticide Manual - A World Compendium; Thirteenth Edition; Editor: CDS TomLin; The British Crop Protection Council], they are listed therein under the entry number indicated in parentheses above for the particular compound; for example, the compound "abamectin" is listed under entry number (1). When a particular compound is marked with "[CCN]," the compound in question is included in the "Compendium of Pesticide Common Names," accessible via the Internet at [A. Wood; Compendium of Pesticide Common Names, Copyright 1995-2004]; for example, the compound "acetoprole" is listed at the Internet address http: / / www.alanwood.net / pesticides / acetoprole.html.

[0169] Most of the active ingredients listed above are referred to above by so-called "common names", where in each case the relevant "ISO common name" or another "common name" is used. If the name is not a "common name", the nature of the name used instead is given for the particular compound in parentheses. In that case, the IUPAC name, IUPAC / Chemical Abstracts name, "chemical name", "customary name", "compound name" or "development code" is used, or if none of these names and no "common name" is used, an "alternative name" is utilized. "CAS Registry Number" means the Chemical Abstracts Registry Number.

[0170] The active ingredient mixture of a compound of formula (I) selected from the compounds defined in Tables 1 to 7 and Table P with the above-mentioned active ingredient comprises a compound selected from one of the compounds defined in Tables 1 to 7 and Table P and the above-mentioned active ingredient in a mixing ratio of 100:1 to 1:6000, in particular 50:1 to 1:50, more in particular 20:1 to 1:20, even more in particular 10:1 to 1:10, very in particular 5:1 and 1:5, particularly preferably a ratio of 2:1 to 1:2, equally preferred is a ratio of 4:1 to 2:1, in particular 1:1, or 5:1, or 5:2, or 5:3, or 5:4, or is in a ratio of 4:1, or 4:2, or 4:3, or 3:1, or 3:2, or 2:1, or 1:5, or 2:5, or 3:5, or 4:5, or 1:4, or 2:4, or 3:4, or 1:3, or 2:3, or 1:2, or 1:600, or 1:300, or 1:150, or 1:35, or 2:35, or 4:35, or 1:75, or 2:75, or 4:75, or 1:6000, or 1:3000, or 1:1500, or 1:350, or 2:350, or 4:350, or 1:750, or 2:750, or 4:750. These mixing ratios are by weight.

[0171] The mixture may be used in a method for controlling pests, the method comprising the step of applying a composition comprising the mixture to the pest or its environment, excluding methods of treatment of the human or animal body by surgery or therapy and diagnostic methods performed on the human or animal body.

[0172] Mixtures comprising a compound of formula (I) selected from the compounds defined in Tables 1-7 and Table P and one or more of the active ingredients described above may be applied in combination with the single active ingredients, for example in a single "ready mix" form, as a combined spray mixture made up of separate formulations of the single active ingredients, such as a "tank mix," and when applied sequentially, i.e., one after the other over a fairly short period of time, such as a few hours or days. The order in which the compound of formula (I) and the active ingredients described above are applied is not critical to the practice of the invention.

[0173] The compositions according to the invention may also comprise further solid or liquid auxiliaries, such as stabilizers, for example non-epoxidized or epoxidized vegetable oils (for example epoxidized palm oil, rapeseed oil or soybean oil), antifoaming agents, for example silicone oils, preservatives, viscosity regulators, binders and / or tackifiers, fertilizers or other active ingredients for achieving specific effects, for example bactericides, fungicides, nematicides, plant activators, molluscicides or herbicides.

[0174] The compositions according to the invention are prepared in a manner known per se in the absence of auxiliaries, for example by grinding, sieving and / or compressing the solid active ingredient, and in the presence of at least one auxiliaries, for example by intimately mixing the active ingredient with one or more auxiliaries and / or grinding.These preparation processes of the compositions and the use of compound I for preparing these compositions are also the subject of the present invention.

[0175] The present invention also provides methods for controlling the above-mentioned types of pests, such as application methods for the compositions, i.e., spraying, atomizing, dusting, brushing, dusting, spreading, or pouring (which should be selected according to the intended purpose in the prevailing situation), and the use of the compositions for controlling the above-mentioned types of pests. Typical concentration rates are 0.1 to 1000 ppm, preferably 0.1 to 500 ppm, of active ingredient. The application rate per hectare is generally 1 to 2000 g of active ingredient per hectare, in particular 10 to 1000 g / ha, preferably 10 to 600 g / ha.

[0176] The preferred application method in the field of crop protection is application to the foliage of plants (foliar spray), which allows the application frequency and application rate to be selected to suit the threat of infestation by the targeted pest. Alternatively, the active ingredient can reach the plant via the root system (systemic action), by drenching the plant habitat with a liquid composition, or by uptake of the active ingredient in solid form, for example in granular form, into the plant habitat, e.g., the soil (soil application). In the case of rice crops, such granules can be metered into flooded rice fields.

[0177] The compounds of formula (I) of the present invention and compositions thereof are also suitable for protecting plant propagation material, such as seeds, e.g., fruits, tubers, or grains or seedlings, against the above-mentioned types of pests. The propagation material can be treated with the compounds before planting, e.g., seeds can be treated before sowing. Alternatively, the compounds can be applied to the seed kernels (coating) by immersing the kernels in a liquid composition or by applying a layer of a solid composition. It is also possible to apply the composition when the propagation material is planted at the site of application, e.g., in the seed furrow during drilling. These treatment methods for plant propagation material and the plant propagation material thus treated are further subjects of the present invention. Typical treatment rates depend on the plant and pest / fungus to be controlled and are generally 1 to 200 grams per 100 kg of seed, preferably 5 to 150 grams per 100 kg of seed, e.g., 10 to 100 grams per 100 kg of seed.

[0178] The term seed encompasses all types of seeds and plant propagules, including but not limited to true seeds, seed fragments, underground stolons, grains, bulbs, fruits, tubers, flour, rhizomes, cuttings, cuttings, etc., and in a preferred embodiment refers to true seeds.

[0179] The present invention also includes seeds coated or treated with or containing a compound of formula I. The terms "coated or treated and / or containing" generally indicate that the active ingredient is mostly on the surface of the seed at the time of application, although depending on the method of application, a greater or lesser portion of the ingredient may penetrate into the seed material. When the seed product is (re)planted, the seed product may absorb the active ingredient. In one embodiment, the present invention provides a plant propagation material having a compound of formula I attached thereto. Further, it thereby provides a composition comprising plant propagation material treated with a compound of formula I.

[0180] Seed treatment includes all suitable seed treatment techniques known in the art, such as seed dressing, seed coating, seed dusting, seed soaking, and seed pelleting. The seed treatment application of the compound of formula (I) can be carried out by any known method, such as spraying or dusting the seeds, before sowing or during sowing / planting of the seeds.

[0181] The compounds of the invention may optionally be applied at lower concentrations, for example 10 ppm, 5 ppm, 2 ppm, 1 ppm or 0.2 ppm, or at lower application rates, for example 300, 200 or 100 mg / m 2 These compounds can be verified by those skilled in the art using experimental procedures using the AIs described above and can be distinguished from other similar compounds by lower application rates and / or greater efficacy at different pest control. Greater efficacy can be observed by an increased safety profile (improved physicochemical properties or increased biodegradability against above- and below-ground non-target organisms (e.g., fish, birds, and bees)).

[0182] In various aspects and embodiments of the present invention, "consisting essentially of" and its conjugations are preferred embodiments of "comprise" and its conjugations, and "consisting of" and its conjugations are preferred embodiments of "consisting essentially of" and its conjugations.

[0183] The disclosure in this application provides any and all combinations of the embodiments disclosed herein.

[0184] Biological Examples: The following examples illustrate the present invention. Certain compounds of the present invention can be distinguished from known compounds by their higher efficacy at low dosages, which can be verified by those skilled in the art using the experimental procedures outlined in the examples and using lower dosages, such as 50 ppm, 24 ppm, 12.5 ppm, 3 ppm, 0.8 ppm, 0.2 ppm, etc., as needed.

[0185] Example B1: Tetranychus urticae (Tetranychus urticae): Feeding / contact activity Phaseolus vulgaris leaf discs on agar in 24-well microtiter plates were sprayed with test solutions prepared from a 10,000 ppm DMSO stock solution. After drying, the discs were infested with mite individuals of various ages. Eight days after infestation, samples were assessed for mortality against the mixed population (active phase).

[0186] The following compounds caused at least 80% mortality at application doses of 12.5 ppm or even lower: P.1, P.2, P.3, P.4, P.5, P.6, P.7.

[0187] Comparison: Compound A is a dimethylsulfonamide known from Nippon Soda International Publication No. 2019039429. Compound B is a methylsulfonamide analog of Compound A.

[0188] Compound P.4 is the ethyl (methyl) sulfonamide analog of Compound A. Compound P.4 is the ethyl sulfonamide analog of Compound A. The ethyl containing sulfonamides P.4 and P.6 exhibited better acaricidal activity than Compounds A and B in the assay described in Example B1 above.

[0189] [Table 13]

Claims

1. Formula (I) 【Chemistry 1】 (In the formula, R 1 is CN or C(=S)NH 2 and R 2 is H or methyl, R 3 is C 1 ~C 2 -Alkyl, C 1 ~C 2 -haloalkyl, C 3 ~C 6 -cycloalkyl, C 1 ~C 2 -alkoxy-C 1 ~C 2 - alkyl, R 4 is a halogen, C 1 ~C 2 -haloalkyl, C 1 ~C 2 -haloalkoxy, -O-C 1-2 haloalkanediyl-O—; q is 1, 2 or 3. or an agriculturally acceptable salt, enantiomer, tautomer and / or N-oxide of a compound of formula I.

2. R 1 The compound of claim 1 , wherein is cyano.

3. R 3 is C 1 ~C 2 -Alkyl, C 1 ~C 2 -haloalkyl, C 3 ~C 4 -cycloalkyl or C 1 ~C 2 -alkoxy-C 1 ~C 2 3. The compound according to claim 1, wherein: - alkyl.

4. R 4 is a halogen, C 1 ~C 2 -haloalkyl and C 1 ~C 2 one or two substituents from -haloalkoxy (i.e., q is 1 or 2) or -OCF 2 The compound of any one of claims 1 to 3, independently selected from O-.

5. R 4 is one or two substituents selected from fluorine, chlorine, bromine, trifluoromethyl, difluoromethyl, difluoromethoxy and trifluoromethoxy (i.e., q is 1 or 2), or -OCF 2 The compound of any one of claims 1 to 4, independently selected from O-.

6. 1-[5-cyano-6-(2,2-difluoro-1,3-benzodioxol-5-yl)-2-(methoxymethyl)pyridine-3-carbonyl]-N-ethyl-N-methyl-piperidine-4-sulfonamide (compound P.1), 1-[5-cyano-6-(2,2-difluoro-1,3-benzodioxol-5-yl)-2-methyl-pyridine-3-carbonyl]-N-ethyl-N-methyl-piperidine-4-sulfonamide (compound P.2), 1-[5-cyano-6-(2,2-difluoro-1,3-benzodioxol-5-yl)-2-(difluoromethyl)pyridine-3-carbonyl]-N-ethyl-N-methyl-piperidine-4-sulfonamide (compound P.3), 1-[5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carbonyl]-N-ethyl-N-methyl-piperidine-4-sulfonamide (compound P.4), 1-[5-cyano-6-(2,2-difluoro-1,3-benzodioxol-5-yl)-2-(difluoromethyl)pyridine-3-carbonyl]-N-ethyl-piperidine-4-sulfonamide (compound P.5), 1-[5-cyano-2-(trifluoromethyl)-6-[4-(trifluoromethyl)phenyl]pyridine-3-carbonyl]-N-ethyl-piperidine-4-sulfonamide (compound P.6), and 1-[5-cyano-6-(2,2-difluoro-1,3-benzodioxol-5-yl)-2-(methoxymethyl)pyridine-3-carbonyl]-N-ethyl-piperidine-4-sulfonamide (Compound P.7) 2. The compound of formula I according to claim 1, selected from the group consisting of:

7. A composition comprising a compound of formula I according to any one of claims 1 to 6, one or more adjuvants and diluents, and optionally one or more other active ingredients.

8. 10. A method for combating and controlling insects, acaridae, nematodes or molluscs which comprises applying an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula I as defined in any one of claims 1 to 6 or a composition as defined in claim 7 to the pest, the habitat of the pest or plants susceptible to attack by the pest.

9. A method for protecting plant propagation material from attack by insects, mites, nematodes or mollusks, which method comprises treating the propagation material or the locus in which the propagation material is planted with an effective amount of a compound of formula I as defined in any one of claims 1 to 6 or a composition as defined in claim 7.

10. Plant propagation material, such as seeds, comprising or treated with or having attached thereto a compound of formula I as defined in any one of claims 1 to 6 or a composition as defined in claim 7.

11. Compounds of formula I according to any one of claims 1 to 6 are reacted with compounds of formula II, 1 , R 3 , R 4 and q are as defined for formula I) with an acid of formula III, 2 is hydrogen or methyl) with an amine or its salt. 【Chemistry 2】

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