Aqueous cosmetic
An aqueous cosmetic composition with Myrothamnaceae extract, water-soluble polymers, and lower alcohols addresses the balance of eyelash extension, drying speed, and firmness, offering improved application and reduced stinging.
Patent Information
- Application Number
- JP2024125230
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2024-07-31
- Publication Date
- 2026-02-13
AI Technical Summary
Conventional eyelash serums face challenges in achieving a balance between eyelash extension, drying speed, resistance to stinging, and firmness, often failing to provide satisfactory qualities when applied in appropriate amounts.
An aqueous cosmetic composition containing an extract of the Myrothamnaceae family, a water-soluble polymer, and a lower alcohol, with a viscosity of 30,000 to 100,000 mPa·s, which includes components like polyacrylic acid or its salts and lower alcohols such as ethanol, to promote eyelash growth and enhance drying speed, resistance to smudging, and firmness.
The composition allows for an appropriate application amount, rapid drying, and improved eyelash extension with reduced stinging, providing excellent properties in all respects.
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Abstract
Description
[Technical Field]
[0001] The present invention relates to an aqueous cosmetic preparation. [Background technology]
[0002] Aqueous cosmetics are often used in skin care products due to their fresh texture and good spreadability. Furthermore, many plant extracts used as cosmetic ingredients are water-soluble, and therefore are used in aqueous cosmetics (e.g., serums, etc.). With the recent increase in interest in eyelash care, eyelash serums have been attracting attention in the market, and the development of eyelash serums that can produce noticeable hair growth effects is eagerly awaited.
[0003] Technologies relating to eyelash serums and hair growth compositions have been developed to date. For example, a cosmetic product for the eyelashes and eyelash roots has been disclosed that contains a hair growth agent, a thickener, and a film-forming agent with a specific refractive index to promote eyelash growth and achieve long, beautiful eyelashes, and can be applied without stickiness, and has makeup effects such as giving the eyelashes a glossy finish and making them appear thicker (see, for example, Patent Document 1). [Prior art documents] [Patent documents]
[0004] [Patent Document 1] Japanese Patent Application Laid-Open No. 2006-306854 Summary of the Invention [Problem to be solved by the invention]
[0005]
[0003] Conventional techniques have been excellent in eyelash growth and luster, but have not provided satisfactory qualities in terms of eyelash sting resistance and firmness when the applied aqueous cosmetic composition drips onto the eyes, or drying speed, which is particularly important when used before applying makeup. Furthermore, reducing the amount applied to the eyelashes in order to increase the drying speed has resulted in failure to provide satisfactory qualities in eyelash extension, eyelash sting resistance, and firmness. On the other hand, increasing the amount applied to the eyelashes has resulted in achievement of eyelash extension and eyelash sting resistance, but has sometimes resulted in failure to provide satisfactory qualities in terms of drying speed. Therefore, an object of the present invention is to provide an aqueous cosmetic composition that can be applied in an appropriate amount to the eyelashes and is excellent in eyelash extension, drying speed, eyelash sting resistance, and firmness. [Means for solving the problem]
[0006] As a result of extensive research, the present inventors have discovered that by containing an extract of a plant of the Myrothamnaceae family, a water-soluble polymer, and a lower alcohol, and by adjusting the viscosity at 25°C to 30,000 to 100,000 mPa·s, it is possible to obtain an aqueous cosmetic composition that can be applied in an appropriate amount from the base to the tip of the eyelashes, promotes eyelash growth, and is excellent in all respects: drying speed, resistance to smudging, and firmness, and has thereby completed the present invention.
[0007] That is, the present invention includes the following aspects. [1] The following components (A) to (C): (A) Extract of Myrothamnus family plants (B) Water-soluble polymer (C) Lower alcohol and having a viscosity of 30,000 to 100,000 mPa·s at 25°C. [2] The aqueous cosmetic preparation according to [1], wherein the component (B) comprises (B1) polyacrylic acid or a salt thereof. [3] The aqueous cosmetic preparation according to [1] or [2], which contains two or more water-soluble polymers as the component (B). [4] The aqueous cosmetic preparation according to [1] or [2], wherein the mass ratio (C) / (B) of the component (C) to the component (B) is 5 to 150. [5] The aqueous cosmetic preparation according to [1] or [2], wherein the content of the component (C) is 1 to 50% by mass. [6] The aqueous cosmetic preparation according to [1] or [2] further contains a component (D) (VP / VA) copolymer. [7] The aqueous cosmetic preparation according to [1] or [2], which is a hair cosmetic preparation. [8] [7] The aqueous cosmetic preparation according to [7], which is a beauty serum for eyelashes. [Effects of the Invention]
[0008] According to the present invention, it is possible to provide an aqueous cosmetic composition that is excellent in all respects: an appropriate amount to be applied to eyelashes, eyelash extension property, drying speed, resistance to stinging, and firmness. DETAILED DESCRIPTION OF THE INVENTION
[0009] Preferred embodiments of the present invention will be described in detail. However, the present invention is not limited to the following preferred embodiments and can be freely modified within the scope of the present invention. In this specification, the symbol "to" means a range including the numerical values before and after it. In addition, the "viscosity" in this specification is a value determined by measurement using a B-type viscometer (manufactured by Shibaura Systems Co., Ltd.) in an environment of 25°C. In addition, in this specification, ingredient names may be written as cosmetic names or International Nomenclature of Cosmetic Ingredients (INCI). When the cosmetic name and INCI correspond, the English description may be omitted. In this specification, when simply writing "%" it means % by mass. In addition, when writing the content of each ingredient hereinafter, if two or more types of that ingredient are present, the content refers to the total amount.
[0010] [Component (A)] Component (A) in the present invention is an extract of a plant of the Myrothamnaceae family, scientifically known as "Myrothamnaceae." Examples of plants belonging to the Myrothamnaceae family include the genus Myrothamnus, and examples of plants belonging to the genus Myrothamnus include Myrothamnus flabellifolius. The parts of the Myrothamnaceae plant extract used in the present invention are not particularly limited and include, for example, flowers, leaves, stems, and roots, with leaves and stems being particularly preferred. Component (A) is not particularly limited and may be extracted using, for example, the plant itself, or a frozen, dried, or lyophilized product of the plant. Furthermore, the method for producing the Myrothamnaceae plant extract is not particularly limited and can be produced according to conventional methods, such as extraction using an aqueous solvent such as water, ethanol, or 1,3-butylene glycol. Among these, water is preferred.
[0011] Examples of the extract of component (A) include Myrothamnus Flabellifolia Leaf / Stem Extract.
[0012] In the present invention, commercially available products of component (A) may be used, such as Resulook Advanced Botanical Ingredient (manufactured by Lubrizol Japan Co., Ltd.), which is a mixture of Myrothamnus flabellifolia leaf / stem extract, glycerin, and water.
[0013] The content of component (A) in the present invention is not particularly limited, and is, for example, preferably 0.0001% or more, more preferably 0.0005% or more, even more preferably 0.001% or more, in terms of eyelash elongation, based on the total amount of the aqueous cosmetic, in terms of the pure extract content of the extract, and preferably 0.5% or less, more preferably 0.1% or less, even more preferably 0.05% or less, in terms of drying speed. Also, the content is preferably 0.0001 to 0.5%, more preferably 0.0005 to 0.1%, even more preferably 0.001 to 0.05%.
[0014] [Component (B)] Component (B) in the present invention is a water-soluble polymer. There are no particular limitations on the water-soluble polymer, and any may be used as long as it is one that is normally used in cosmetics. Examples include acrylic acid polymers, polysaccharides, and hydrophobically modified polyether urethanes, and one or more of these may be used.
[0015] The acrylic acid-based polymer may be any polymer or copolymer formed by polymerizing or copolymerizing acrylic acid as a constituent unit, and examples thereof include carboxyvinyl polymers, alkyl-modified carboxyvinyl polymers, polyacrylic acid or its salts, acrylamide-based copolymers, etc. Examples of polyacrylic acid or its salts include polyacrylic acid, sodium polyacrylate, ammonium polyacrylate, etc. Examples of acrylamide copolymers include vinylpyrrolidone / 2-acrylamido-2-methylpropanesulfonic acid (salt) copolymer, dimethylacrylamide / 2-acrylamido-2-methylpropanesulfonic acid (salt) copolymer, acrylamide / acrylic acid / 2-acrylamido-2-methylpropanesulfonic acid (salt) copolymer, a mixture of polyacrylamide and polyacrylic acid (salt), sodium acrylate / 2-acrylamido-2-methylpropanesulfonic acid (salt) copolymer, acrylamide / 2-acrylamido-2-methylpropanesulfonic acid (salt) copolymer, polyacrylamide, acrylamide / acrylic acid (salt) copolymer, a homopolymer of 2-acrylamido-2-methylpropanesulfonic acid (salt), and acrylic acid / sodium acryloyldimethyltaurate copolymer.
[0016] Examples of polysaccharides include agar, carrageenan, pectin, gellan gum, locust bean gum, tamarind gum, guar gum, xanthan gum, cellulose or its derivatives, mucopolysaccharides, Tremella fuciformis polysaccharide, sodium chondroitin sulfate, and proteoglycans. Examples of cellulose include cellulose nanofibers. Examples of cellulose derivatives include carboxymethylcellulose, sodium carboxymethylcellulose, methylcellulose, ethylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, and hydroxypropylmethylcellulose. Examples of mucopolysaccharides include hyaluronic acid or its salts, and chondroitin sulfate or its salts. Examples of hydrophobically modified polyether urethanes include PEG-240 / decyltetradeceth-20 / hexamethylene diisocyanate copolymers.
[0017] Among these, one or more selected from the group consisting of acrylic acid polymers and polysaccharides are preferred, with acrylic acid polymers being more preferred, and alkyl-modified carboxyvinyl polymers and polyacrylic acid or its salts being even more preferred. In particular, from the viewpoints of stain-resistant properties and firmness, it is preferred that component (B) contains at least (B1) polyacrylic acid or its salt. While component (B) may be used alone, using two or more in combination is more preferred, as it provides superior stain-resistant properties and allows for an appropriate application amount to the eyelashes. When two or more are combined, the type is not particularly limited, and examples include polyacrylic acid or its salt and alkyl-modified carboxyvinyl polymer, polyacrylic acid or its salt and acrylic acid polymer, and polyacrylic acid or its salt and polysaccharide. In the present invention, from the viewpoints of stain-resistant properties and allows for an appropriate application amount to the eyelashes, it is preferred to use a combination of two or more including polyacrylic acid or its salt and alkyl-modified carboxyvinyl polymer.
[0018] Component (B) may be a commercially available product, such as CARBOPOL 1382 (manufactured by LUBRIZOL ADVANCED METERIALS A) as an alkyl-modified carboxyvinyl polymer, NATROSOL 250 HHR (manufactured by ASHLAND SPECIALTY INGREDIENTS) as a hydroxyethyl cellulose, or ARONBIS SX (manufactured by TOAGOSEI CO., LTD.) as a polyacrylate.
[0019] The content of component (B) in the present invention is not particularly limited, and is, for example, preferably 0.0001% or more, more preferably 0.0005% or more, and even more preferably 0.001% or more, based on the total amount of the aqueous cosmetic. It is also preferably 5% or less, more preferably 3% or less, and even more preferably 1% or less. It is also preferably 0.0001 to 5%, more preferably 0.0005 to 3%, and even more preferably 0.001 to 1%. This range is more preferable because it provides excellent resistance to stinging, drying speed, and an appropriate amount to be applied to the eyelashes. The content of component (B1) is also not particularly limited, and is, for example, preferably 0.0001% or more, more preferably 0.0005% or more, and even more preferably 0.001% or more, based on the total amount of the aqueous cosmetic. It is also preferably 3% or less, more preferably 1% or less, and even more preferably 0.5% or less. The content is preferably 0.0001 to 3%, more preferably 0.0005 to 1%, and even more preferably 0.001 to 0.5%. This range is more preferable because it provides a faster drying rate, an appropriate amount to be applied to the eyelashes, and a firmer feeling.
[0020] [Component (C)] Component (C) in the present invention is a lower alcohol. In the present invention, the lower alcohol is a monohydric alcohol having 1 to 5 carbon atoms. The lower alcohol in the present invention is volatile under normal temperature and pressure conditions (25°C, 1 atmosphere). Examples include linear alcohols such as ethanol, propanol, and butanol, and branched alcohols such as isopropanol, and one or more of these can be used. In the present invention, ethanol is preferred from the viewpoints of resistance to staining and drying speed.
[0021] An example of a commercially available product of component (C) is Synthetic Alcohol 95% (manufactured by Nippon Alcohol Co., Ltd.).
[0022] The content of component (C) in the present invention is not particularly limited, and for example, from the viewpoint of drying speed, it is preferably 1% or more, more preferably 3% or more, even more preferably 4% or more, and most preferably 5% or more, based on the total amount of the aqueous cosmetic, and from the viewpoint of resistance to stinging and an appropriate amount to be applied to the eyelashes, it is preferably 50% or less, more preferably 40% or less, and even more preferably 30% or less. Also, it is preferably 1 to 50%, more preferably 3 to 40%, even more preferably 4 to 30%, and most preferably 5 to 30%.
[0023] In the present invention, the mass ratio (C) / (B) of the component (C) to the component (B) is not particularly limited, and is, for example, preferably 5 or more, more preferably 7 or more, even more preferably 10 or more, and preferably 150 or less, more preferably 140 or less, and even more preferably 130 or less. Also, it is preferably 5 to 150, more preferably 7 to 140, and even more preferably 10 to 130. This range is more preferable because it provides excellent drying speed, resistance to stinging, and an appropriate amount to be applied to the eyelashes.
[0024] [Component (D)] The present invention can further contain component (D) (VP / VA) copolymer. The inclusion of component (D) in the present invention is preferred because it further improves firmness. Component (D) in the present invention is a copolymer of vinylpyrrolidone monomer and vinyl acetate monomer, and is not particularly limited as long as it is typically used in cosmetics, and any can be used. Examples of commercially available products of component (D) include Acorn KS (manufactured by Osaka Organic Chemical Industry Ltd.).
[0025] The content of component (D) in the present invention is not particularly limited, and is, for example, preferably 0.05% or more, more preferably 0.1% or more, even more preferably 0.5% or more, and preferably 10% or less, more preferably 5% or less, and even more preferably 3% or less, based on the total amount of the aqueous cosmetic. Also, 0.05 to 10% is preferred, more preferably 0.1 to 5%, and even more preferably 0.5 to 3% is preferred. This range is more preferred because it provides a more excellent firmness.
[0026] In addition to the above-mentioned components, the aqueous cosmetic preparation of the present invention may contain other components commonly used in cosmetics, as needed, provided that the effects of the present invention are not impaired. For example, it may contain powders, oils, alcohols other than component (C), surfactants, film-forming agents, UV absorbers, antioxidants, anti-fading agents, antifoaming agents, pH adjusters, chelating agents, cosmetic ingredients other than component (A), preservatives, fragrances, and refreshing agents.
[0027] In the present invention, the water may contain, in addition to water, a water-soluble component, such as glycols (e.g., propylene glycol, 1,3-butylene glycol, dipropylene glycol, polyethylene glycol), glycerols (e.g., glycerin, diglycerin, polyglycerin), and plant extracts (e.g., aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, rose), etc., and one or more of these may be used.
[0028] The water content in the present invention is not particularly limited, and is, for example, preferably 50% or more, more preferably 55% or more, even more preferably 60% or more, particularly preferably 65% or more, preferably 99% or less, more preferably 98% or less, even more preferably 95% or less, based on the total amount of the aqueous cosmetic preparation. Also, the water content is preferably 50 to 99%, more preferably 55 to 98%, even more preferably 60 to 95%, and particularly preferably 65 to 95%.
[0029] The content of the aqueous phase in the present invention is not particularly limited, and is, for example, preferably 60% or more, more preferably 65% or more, even more preferably 70% or more, particularly preferably 75% or more, and preferably 100% or less, based on the total amount of the aqueous cosmetic. Also, it is preferably 60 to 100%, more preferably 65 to 100%, even more preferably 70 to 100%, and particularly preferably 75 to 100%.
[0030] The oil agent is not particularly limited as long as it is one that is normally used in cosmetics, and any oil can be used regardless of its origin (e.g., animal oil, vegetable oil, synthetic oil) and its type (e.g., solid oil, semi-solid oil, liquid oil, non-volatile oil, volatile oil, etc.) Examples include hydrocarbon oils, ester oils, fatty acids, higher alcohols, silicone oils, lanolin derivatives, etc.
[0031] More specifically, hydrocarbon oils such as paraffin wax, ceresin wax, microcrystalline wax, polyethylene wax, ethylene-propylene copolymer, montan wax, Fischer-Tropsch wax, petrolatum, liquid paraffin, isododecane, isohexadecene, hydrogenated polyisobutene, squalane, and polybutene, hydrogenated jojoba oil, beeswax, carnauba wax, candelilla wax, rice wax, rhododendron bark, Japan wax, glyceryl tribehenate, N-lauroyl-L-glutamic acid di(phytosteryl / octyldodecyl), N-lauroyl-L-glutamic acid di(cholesteryl / behenyl / octyldodecyl), olive oil, castor oil, jojoba oil, mink oil, macadamia nut oil, cetyl isooctanoate, isopropyl myristate, and isopropyl palmitate. ester oils such as glyceryl trioctanoate, polyglyceryl-2 isostearate, polyglyceryl-2 diisostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, and neopentyl glycol dioctanoate; fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, oleic acid, palmitic acid, and isostearic acid; higher alcohols such as stearyl alcohol, isostearyl alcohol, oleyl alcohol, octyldodecanol, behenyl alcohol, and decyltetradecanol; silicone oils such as dimethylpolysiloxane, methylphenylpolysiloxane, and dimethiconol; and lanolin derivatives such as lanolin, lanolin acetate, lanolin fatty acid isopropyl, and lanolin alcohol.
[0032] In the present invention, the aqueous cosmetic is a formulation in which an aqueous phase is the continuous phase. As long as the aqueous phase is the continuous phase, the aqueous cosmetic can also be in a formulation such as a solubilized formulation containing an oil, an oil-in-water formulation, or the like. The content of the oil in the present invention is not particularly limited and can be adjusted according to the formulation to be applied. In the case of a solubilized formulation, for example, the content is preferably 0.01% or more, more preferably 0.05% or more, even more preferably 0.1% or more, preferably 5% or less, more preferably 3% or less, and even more preferably 1% or less, relative to the total amount of the aqueous cosmetic. Also, 0.01 to 5% is preferred, more preferably 0.05 to 3%, and even more preferably 0.1 to 1%. In the case of an oil-in-water formulation, for example, the content is preferably 1% or more, more preferably 3% or more, even more preferably 5% or more, preferably 30% or less, more preferably 25% or less, and even more preferably 20% or less, relative to the total amount of the aqueous cosmetic. Moreover, it is preferably 1 to 30%, more preferably 3 to 25%, and even more preferably 5 to 20%.
[0033] In the present invention, the viscosity of the aqueous cosmetic preparation at 25°C is 30,000 to 100,000 mPa·s. Furthermore, the viscosity at 25°C is preferably 40,000 mPa·s or higher, more preferably 50,000 mPa·s or higher, even more preferably 60,000 mPa·s or higher, and preferably 95,000 mPa·s or lower, more preferably 90,000 mPa·s or lower, and even more preferably 85,000 mPa·s or lower. Furthermore, the viscosity is preferably 40,000 to 95,000 mPa·s, more preferably 50,000 to 90,000 mPa·s, and even more preferably 60,000 to 85,000 mPa·s. This range is preferred because it allows for an appropriate amount of application to the eyelashes, provides rapid drying, and is less likely to smear.
[0034] The method for producing the aqueous cosmetic composition of the present invention is not particularly limited, and it can be produced by a commonly known method. Examples of production methods are shown below, but the present invention is not limited to these. Specific examples include a method in which components (A) to (C), and optionally component (D) and other components, are mixed together, and then poured into a container to fill the mixture.
[0035] The aqueous cosmetic composition of the present invention can be used as a cosmetic composition for various purposes. In particular, it is preferable for it to be used as a hair cosmetic composition such as an eyelash beauty serum, an eyebrow beauty serum, a hair growth agent, mascara, or an eyebrow cream, and from the viewpoint of eyelash lengthening, an eyelash beauty serum is particularly preferable.
[0036] The present invention can also have the following configuration. [1] The following components (A) to (C): (A) Extract of Myrothamnus family plants (B) Water-soluble polymer (C) Lower alcohol and having a viscosity of 30,000 to 100,000 mPa·s at 25°C. [2] The aqueous cosmetic preparation according to [1], wherein the component (B) comprises (B1) polyacrylic acid or a salt thereof. [3] The aqueous cosmetic preparation according to [1] or [2], which contains two or more water-soluble polymers as the component (B). [4] The aqueous cosmetic preparation according to any one of [1] to [3], wherein the mass ratio (C) / (B) of the component (C) to the component (B) is 5 to 150. [5] The aqueous cosmetic preparation according to any one of [1] to [4], wherein the content of the component (C) is 1 to 50% by mass. [6] The aqueous cosmetic preparation according to any one of [1] to [5], further comprising a component (D) (VP / VA) copolymer. [7] The aqueous cosmetic preparation according to any one of [1] to [6], which is a hair cosmetic preparation. [8] [7] The aqueous cosmetic preparation according to [7], which is a beauty serum for eyelashes. [Example]
[0037] The present invention will be described in more detail below with reference to examples and comparative examples, but the present invention is not limited to the following examples.
[0038] Examples 1 to 13 and Comparative Examples 1 to 4: Water-based eyelash serum Aqueous eyelash serums having the compositions shown in Tables 1 and 2 were prepared by the manufacturing method described below, and evaluated and judged for (i) eyelash extension, (ii) resistance to stinging, (iii) drying speed, (iv) appropriate amount applied to eyelashes, and (vulnerability) using the evaluation methods and criteria described below, with the results also shown in Tables 1 and 2. The content of plant extracts in the examples represents the value of the pure extract content.
[0039] [Table 1]
[0040] [Table 2]
[0041] *1:Resulook Advanced Botanical Ingredient (manufactured by Lubrizol Japan) *2: Taiso Extract BG (Maruzen Pharmaceuticals) *3: CARBOPOL 1382 (LUBRIZOL ADVANCED MATERIALS, manufactured by Company A) *4: Aronvis SX (manufactured by Toagosei) *5: Acorn KS (Osaka Organic Chemical Industry Co., Ltd.)
[0042] (Manufacturing method) A. Mix ingredients (1) to (11) uniformly at 25°C. B. A was filled into a container using a mascara filling machine to obtain an aqueous eyelash serum.
[0043] [Evaluation method 1] (Evaluation item: eyelash lengthening) A panel of 10 cosmetic product evaluators applied each sample to their eyelashes and lash line once morning and night for one month. Images of each panel's eyelashes were taken from the front before and after one month of use, and a 1cm square was cropped from the image near the center of the eye. The image was binarized so that the eyelashes appeared black and the rest of the eye was white, and the area of the black area corresponding to the eyelashes was measured. The average eyelash areas of the 10 panelists before and after use of the water-based eyelash serum were compared, and Y / X was calculated, where X was the average eyelash area of the 10 panelists before use and Y was the average eyelash area of the 10 panelists after one month of use. [Judgment criteria] (Judgment): (Y / X value) ◎: 1.10 or higher ○: 1.06 or more and less than 1.10 △: 1.02 or more and less than 1.06 ×: Less than 1.02
[0044] [Evaluation method 2] (Evaluation item: drying speed) Immediately after preparation, 1 g of each sample was taken, and its weight (a) on the artificial leather was measured in advance. Immediately after application, the surface was smoothed with a 100 μm doctor blade to form a uniform 100 μm coating film. The weight (b) was measured, and the sample was then left at 25°C for 10 minutes. After 10 minutes, the weight (c) of the coated artificial leather was measured. The weight of the sample before the 10-minute stand [(b) - (c)] was multiplied by the proportion of liquid components contained in the sample before the 10-minute stand [M], and the weight of the sample after the 10-minute stand [(b) - (a)] was defined as N, and the proportion of volatilized liquid components was calculated. The amount of change expressed by the following formula (1) was taken as the proportion of volatilized liquid components. The degree of volatilization was evaluated according to the following criteria. The proportions were converted to percentages for evaluation. [Proportion of volatilized liquid components] Ratio of evaporated liquid component = 1-(N / M) (1) [Judgment criteria] (Judgment) :(Drying speed) ◎: 90% or more of the liquid components have evaporated 〇: Volatilized liquid component is 70% or more but less than 90% △: Volatilized liquid component is 50% or more but less than 70% ×: Less than 50% of the liquid component has evaporated
[0045] [Evaluation method 3] (Evaluation criteria: non-stinging, appropriate amount applied to eyelashes, firmness) For each sample, 20 members of a panel of cosmetic product experts individually rated each sample on a 5-point scale for the categories of "non-staining," "appropriate amount applied to eyelashes," and "firmness," according to the absolute evaluation criteria below, and then used the average of the scores of all panelists to judge the results according to the following criteria: "non-staining," "appropriate amount applied to eyelashes," and "firmness" were evaluated by each panelist immediately after applying each sample to the eyelashes and lash line.
[0046] (Absolute evaluation criteria for stain resistance) (Score) :(Evaluation) 4 points: Very good (no stinging at all) 3 points: Good (slight stinging) 2 points: Normal (a little stinging but no pain) 1 point: Poor (stings and feels a little pain) 0 points: Very bad (stings strongly and causes pain) (Absolute evaluation standard for the appropriate amount of application to eyelashes) (Score) :(Evaluation) 4 points: Very good (just the right amount of application) 3 points: Good (slightly more or less) 2 points: Normal (too much or too little, but still acceptable) 1 point: Poor (too much or too little) 0 points: Very poor (very much or very little) (Absolute evaluation standard for firmness) (Score) :(Evaluation) 4 points: Very good (very firm) 3 points: Good (strong firmness) 2 points: Normal (firm) 1 point: Poor (weak firmness) 0 points: Very poor (no firmness at all)
[0047] (Judgment criteria) (Judgment): (Average score) ◎: 3.5 or above ○: 2.5 or more and less than 3.5 △: 1.5 or more and less than 2.5 ×: Less than 1.5
[0048] As is clear from the results in Tables 1 and 2, the aqueous eyelash serums of the Examples were excellent in all categories: "eyelash lengthening," "non-staining," "drying speed," "appropriate application amount to eyelashes," and "firmness." On the other hand, Comparative Example 1, which contained jujube fruit extract instead of component (A), did not achieve satisfactory quality in terms of eyelash lengthening. Furthermore, Comparative Example 2, which had a viscosity of more than 100,000 mPa·s, did not achieve satisfactory quality in terms of drying speed, appropriate application amount to eyelashes, or firmness. Comparative Example 3, which had a viscosity of less than 30,000 mPa·s, did not achieve satisfactory quality in terms of non-staining, appropriate application amount to eyelashes, or firmness. Furthermore, Comparative Example 4, which contained 1,3-butylene glycol instead of component (C), did not achieve satisfactory quality in terms of drying speed or firmness.
[0049] Example 14: Water-based eyebrow serum (Component) (%) 1. Myrothamnus flabellifolia leaf / stem extract (Component (A)) *1 0.012 2. Carboxyvinyl polymer (component (B)) *6 0.5 3. Ethanol (component (C)) 20 4. Triethanolamine 0.8 5. Glycerin 5 6. Water remaining *6: CARBOPOL 980 (LUBRIZOL ADVANCED MATERIALS, manufactured by Company A)
[0050] (Manufacturing method) A: Components 1 to 6 were mixed uniformly at 25°C. B: A was filled into a container using a mascara filling machine to obtain an aqueous eyebrow serum.
[0051] The obtained aqueous eyebrow serum had a viscosity of 38,000 mPa·s and was excellent in terms of eyebrow extension, resistance to stinging, drying speed, appropriate amount of application to eyebrows, and firmness.
[0052] Example 15: Oil-in-water emulsion mascara (Component) (%) 1. Polyethylene wax *7 4 2. Decyltetradecanol *8 4 3. Stearic acid *9 2 4. Myrothamnus flabellifolia Leaf / Stem Extract (Component (A)) *1 0.012 5. Sodium polyacrylate (ingredient (B)) *4 0.01 6. Ethanol (component (C)) 10 7. (VP / VA) copolymer (component (D)) *5 0.5 8. Glycerin 5 9. Remaining purified water *7: PERFORMA SW-87 (manufactured by Nippon Surfactant Industries Co., Ltd.) *8: Lisonol 24SP (Kyukyu Alcohol Kogyo Co., Ltd.) *9: Stearic acid 65 (manufactured by Miyoshi Oil Co., Ltd.)
[0053] (Manufacturing method) A: Heat ingredients 1 to 3 to 90°C until uniform. B: Mix ingredients 4 to 9 uniformly at 25°C and heat to 80°C. C: Pour B into A and emulsify at 80°C. D: After cooling C to 25°C, it was filled into containers using a mascara filling machine to obtain an oil-in-water mascara.
[0054] The obtained oil-in-water mascara had a viscosity of 30,000 mPa·s and was excellent in eyelash extension, resistance to smudging, drying speed, appropriate application amount to eyelashes, and firmness.
[0055] Example 16: Oil-in-water emulsion mascara base (Component) (%) 1. Stearic acid *9 2 2. Cetostearyl alcohol 0.3 3. Behenyl alcohol 0.2 4. Polyethylene wax (melting point 93°C) 1 5. Carnauba wax (melting point 85°C) 2 6. Candelilla wax (melting point 75°C) 3 7. Vaseline (melting point 58°C) 1 8. Fumed silica 0.5 9. Trimethylsiloxysilicate 0.8 10. Acrylates copolymer *10 0.8 11. Myrothamnus flabellifolia Leaf / Stem Extract (Component (A)) *1 0.005 12. Sodium polyacrylate (ingredient (B)) *4 0.06 13. Ethanol (component (C)) 15 14.Fragrance 0.01 15. Polyvinyl acetate*11 10 16. (Acrylates / Ethylhexyl Acrylate) Copolymer *12 10 17. Jujube Fruit Extract 0.001 18. Glycerin 5 19.Blue No. 1 0.001 20. Remaining purified water 21. 1,3-Butylene Glycol 3 *10: ACULYN 33A (manufactured by Rohm and Haas) *11: Vinyblan GV-5651 (manufactured by Nissin Chemical Industry Co., Ltd.) *12: Daitosol 5000SJ (manufactured by Daito Kasei Kogyo Co., Ltd.)
[0056] (Manufacturing method) A: Heat ingredients 1 to 7 and 9 to 100°C until uniform. B: Add ingredient 8 to A and mix uniformly at 80°C. C: Mix ingredients 10 to 21 uniformly and heat to 80°C. D: Add C to B and emulsify at 80°C. E:D was cooled to 25°C and then filled into containers using a mascara filling machine to obtain an oil-in-water emulsion mascara base.
[0057] The obtained oil-in-water emulsion mascara base had a viscosity of 98,000 mPa·s and was excellent in eyelash extension, resistance to smearing, drying speed, appropriate application amount to eyelashes, and firmness.
[0058] Example 17: Water-based eyeliner (Component) (%) 1. Myrothamnus flabellifolia leaf / stem extract (Component (A)) *1 0.001 2. Carboxyvinyl polymer (component (B)) *6 0.5 3. (PEG-240 / Decyltetradeceth-20 / HDI) copolymer (component (B)) *13 0.2 4. Ethanol (component (C)) 20 5. Triethanolamine 0.8 6. Remaining purified water 7. Sodium polyacrylate (ingredient (B)) *4 0.02 8. Glycerin 3 9. 1,3-Butylene Glycol 10 10. Carbon Black 3 11. Stearoyl glutamic acid disodium (1%) treated black iron oxide 0.8 12. Hydrolyzed Collagen 0.001 13. Mallow extract 0.001 14.Fragrance 0.01 15. Caprylyl Glycol 2 16. (VP / VA) copolymer (component (D)) *5 0.5 17. Dipropylene Glycol 5 18. Polyvinyl alcohol 0.4 *13: ADEKA NOL GT-700 (ADEKA Corporation)
[0059] (Manufacturing method) A: Heat ingredients 1 to 8 to 60°C and mix evenly. B: Mix ingredients 9 to 11 uniformly at 25°C. C: Add B and ingredients 12 to 18 to A and mix uniformly at 25°C. D: C was filled into a container using a mascara filling machine to obtain a water-based eyeliner.
[0060] The resulting water-based eyeliner had a viscosity of 68,000 mPa·s and was excellent in eyelash extension, resistance to smearing, drying speed, application amount to the eyelashes, and firmness.
[0061] Example 18: Oil-in-water emulsified hair wax (Component) (%) 1. Beeswax *14 10 2. Vaseline 5 3. Glyceryl stearate *15 3 4. Myrothamnus flabellifolia Leaf / Stem Extract (Component (A)) *1 0.03 5. Xanthan gum (ingredient (B)) *16 0.1 6. Ethanol (component (C)) 10 7. (VP / VA) copolymer (component (D)) *5 0.5 8. Glycerin 5 9. Sodium polyacrylate (ingredient (B)) *4 0.005 10. Remaining purified water *14: WHITE BEEDS WAX (Miki Chemical Co., Ltd.) *15: Nikkor MGS-ASEV (manufactured by Nippon Surfactant Industries Co., Ltd.) *16: Nomcoat ZZ (manufactured by Nisshin Oillio Group)
[0062] (Manufacturing method) A: Heat ingredients 1 to 3 to 90°C until uniform. B: Mix ingredients 4 to 10 uniformly at 25°C and heat to 80°C. C: Pour B into A and emulsify at 80°C. D: After cooling C to 25°C, it was poured into a jar to obtain an oil-in-water emulsified hair wax.
[0063] The obtained oil-in-water emulsified hair wax had a viscosity of 80,000 mPa·s and was excellent in hair extensibility, resistance to stinging, drying speed, appropriate amount of application to hair, and firmness.
Claims
1. The following components (A) to (C): (A) Extract of a plant from the Myrothamniaceae family (B) Water-soluble polymer (C) Lower alcohol and having a viscosity at 25°C of 30,000 to 100,000 mPa·s.
2. 2. The aqueous cosmetic preparation according to claim 1, comprising (B1) polyacrylic acid or a salt thereof as the component (B).
3. 3. The aqueous cosmetic preparation according to claim 1, comprising two or more water-soluble polymers as component (B).
4. 3. The aqueous cosmetic preparation according to claim 1, wherein the mass ratio (C) / (B) of the component (C) to the component (B) is 5 to 150.
5. 3. The aqueous cosmetic preparation according to claim 1, wherein the content of the component (C) is 1 to 50% by mass.
6. The aqueous cosmetic preparation according to claim 1 or 2, further comprising a component (D) (VP / VA) copolymer.
7. 3. The aqueous cosmetic preparation according to claim 1, which is a hair cosmetic preparation.
8. 8. The aqueous cosmetic preparation according to claim 7, which is a beauty serum for eyelashes.
Citation Information
Patent Citations
Cosmetic for eyelashes and hairline of eyelashes, and method for using the same
JP2006306854A