Method for controlling weeds using pyridazine derivatives

Pyridazine derivatives, combined with various active ingredients, form a composition that addresses the inadequacies of existing weed control methods by offering a multifaceted approach to manage weeds effectively and specifically.

JP2026027456APending Publication Date: 2026-02-18SUMITOMO CHEM CO LTD
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Patent Information

Application Number
JP2025195052
Authority / Receiving Office
JP · JP
Patent Type
Applications
Current Assignee / Owner
Filing Date
2025-11-14
Publication Date
2026-02-18

AI Technical Summary

Technical Problem

Existing methods for weed control are inadequate in effectively managing weeds using pyridazine derivatives, particularly in terms of efficacy and specificity.

Method used

The use of pyridazine derivatives represented by formula (I) and their salts, combined with various active ingredients, to create a composition for weed control that includes arthropodicidal, nematicidal, fungicidal, plant growth regulating, phytotoxicity-reducing, synergistic, repellent, molluscicidal, herbicidal, and biological control components, applied to weeds or soil to achieve effective weed management.

Benefits of technology

The composition effectively controls weeds by leveraging the properties of pyridazine derivatives, providing a comprehensive approach to weed management that includes multiple modes of action, enhancing efficacy and specificity.

✦ Generated by Eureka AI based on patent content.

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Abstract

To provide a method for controlling weeds.SOLUTION: A method for controlling weeds, which comprises applying a compound represented by the formula (I) or its salt to weeds or soil where weeds grow.SELECTED DRAWING: None
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Description

[Technical Field]

[0001] The present invention relates to a method for controlling weeds using pyridazine derivatives. [Background technology]

[0002] Various compounds have been investigated and put to practical use for the purpose of weed control. In addition, it is known that certain compounds have the effect of inducing male sterility (see, for example, Patent Document 1). [Prior art documents] [Patent documents]

[0003] [Patent Document 1] U.S. Patent No. 4,345,934 Summary of the Invention [Problem to be solved by the invention]

[0004] An object of the present invention is to provide a method for controlling weeds. [Means for solving the problem]

[0005] The present invention is as follows. [1] Formula (I) TIFF2026027456000001.tif3970 [in the formula, R 1 is the group G 1 a phenyl group optionally substituted with one or more substituents selected from the group G 1 represents a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the following: R 2 is the group G 2 a C1-C8 chain hydrocarbon group optionally substituted with one or more substituents selected from group G 3 a C3-C8 alicyclic hydrocarbon group optionally substituted with one or more substituents selected from the group consisting of a halogen atom, a cyano group, OR10 , C(=Z 1 )R 11 , C(=Z 1 ) OR 12 , C(=Z 1 )NR 11 R 12 , mercapto group, S(O) p R 13 , or NR 11 R 14 represents p represents 0, 1, or 2; R 3 is the group G 4 a phenyl group optionally substituted with one or more substituents selected from the group G 4 a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the group G 4 a group represented by formula B1, or a group represented by formula B2 (● represents the bonding site to the nitrogen atom), which may be substituted by one or more substituents selected from the group consisting of: TIFF2026027456000002.tif4793G 7a , G 7b and G 7c The combination of G 7a is C=O or CR 30a R 31a and G 7b is C=O or CR 30b R 31b and G 7c is C=O or CR 30c R 31c The combination G 7a is C=O or CR 30a R 31a and G 7b is C=O or CR 30b R 31b and G 7c is NR 32c , an oxygen atom, a sulfur atom, S=O, or a combination of S=O2; G 7a is C=O or CR 30a R 31a and G 7b is NR 32b, an oxygen atom, a sulfur atom, S=O, or S=O2, and G 7c is C=O or CR 30c R 31c The combination G 7a is NR 32a , an oxygen atom, a sulfur atom, S=O, or S=O2, and G 7b is C=O or CR 30b R 31b and G 7c is C=O or CR 30c R 31c or G 7a is NR 32a , an oxygen atom, a sulfur atom, S=O, or S=O2, and G 7b is C=O or CR 30b R 31b and G 7c is NR 32c , an oxygen atom, a sulfur atom, S=O, or a combination of S=O2; G 7d , G 7e , G 7f and G 7g The combination of G 7d is C=O or CR 30d R 31d and G 7e is C=O or CR 30e R 31e and G 7f is C=O or CR 30f R 31f and G 7g is C=O or CR 30g R 31g The combination G 7d is C=O or CR 30d R 31d and G 7e is C=O or CR 30e R 31e and G 7f is C=O or CR 30f R 31f and G 7g is NR 32g , an oxygen atom, a sulfur atom, S=O, or a combination of S=O2; G 7d is C=O or CR 30d R 31d and G 7e is C=O or CR 30e R 31e and G 7f is NR 32f , an oxygen atom, a sulfur atom, S=O, or S=O2, and G 7g is C=O or CR 30g R 31g The combination G 7d is C=O or CR 30d R 31d and G 7e is NR 32e , an oxygen atom, a sulfur atom, S=O, or S=O2, and G 7f is C=O or CR 30f R 31f and G 7g is C=O or CR 30g R 31g The combination G 7d is C=O or CR 30d R 31d and G 7e is NR 32e , an oxygen atom, a sulfur atom, S=O, or S=O2, and G 7f is C=O or CR 30f R 31f and G 7g is NR 32g , an oxygen atom, a sulfur atom, S=O, or a combination of S=O2; G 7d is NR 32d , an oxygen atom, a sulfur atom, S=O, or S=O2, and G 7e is C=O or CR 30e R 31e and G 7f is C=O or CR 30f R 31f and G 7g is C=O or CR 30g R 31g The combination G 7d is NR 32d , an oxygen atom, a sulfur atom, S=O, or S=O2, and G7e is C=O or CR 30e R 31e and G 7f is C=O or CR 30f R 31f and G 7g is NR 32g , an oxygen atom, a sulfur atom, S=O, or a combination of S=O2, or G 7d is NR 32d , an oxygen atom, a sulfur atom, S=O, or S=O2, and G 7e is C=O or CR 30e R 31e and G 7f is NR 32f , an oxygen atom, a sulfur atom, S=O, or S=O2, and G 7g is C=O or CR 30g R 31g combinations where X 1 and X 2 are the same or different and represent an oxygen atom or a sulfur atom, Y 1 is OR 15 or SR 15 represents m and n are the same or different and represent 0, 1, or 2; A is a single bond, oxygen atom, sulfur atom, -S(O)-, -S(O)2-, -CR 4 R 5 -, -C(=Z 4 )- or -NR 6 - represents R 4 and R 5 are the same or different and represent a C1-C3 alkyl group optionally substituted with one or more halogen atoms, a C1-C3 alkoxy group optionally substituted with one or more halogen atoms, a hydroxy group, or a hydrogen atom, or R 4 and R 5 and together form a C2-C5 alkylene group, or -O(CH2) q represents O-, q represents 2, 3 or 4; Z 4represents an oxygen atom, a sulfur atom, or CH2, R 6 represents a C1-C3 alkyl group optionally substituted with one or more halogen atoms, C(=Z 5 )R 34 base, C(=Z 5 ) OR 34 represents a group or a hydrogen atom, Z 1 , Z 2 , Z 3 , and Z 5 are the same or different and represent an oxygen atom or a sulfur atom, R 10 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, or a group G 6 represents a phenyl group optionally substituted with one or more substituents selected from the group consisting of R 11 , R 21 , and R 26 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, a group G 6 represents a phenyl group optionally substituted by one or more substituents selected from the group consisting of: R 12 , R 20 , R 22 , R 25 , and R 27 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 13 , R 23 , and R 28 are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, or a group G 6 represents a phenyl group optionally substituted with one or more substituents selected from the group consisting of R 14 , R24 , R 29 , and R 34 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, R 35 and R 36 represent, together with the nitrogen atom to which they are bonded, a saturated or unsaturated 5- or 6-membered cyclic amino group {the cyclic amino group may be substituted with one or more substituents selected from the group consisting of a C1-C3 alkyl group optionally substituted with one or more halogen atoms, and a halogen atom}; R 15 is the group G 8 a C1-C10 chain hydrocarbon group optionally substituted with one or more substituents selected from the group consisting of a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, a benzyl group {the phenyl moiety in the benzyl group is selected from the group G 6 and the methylene portion is optionally substituted with one or two C1-C3 alkyl groups}, or a hydrogen atom; R 30a 、 R 30b 、 R 30c , R 30d 、 R 30e 、 R 30f 、 R 30g 、 R 31a , R 31b 、 R 31c , R 31d 、 R 31e 、 R 31f 、 and R 31g are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, R 32a 、 R 32b 、 R32c , R 32d 、 R 32e 、 R 32f 、 and R 32g are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a (C1-C3 alkyl)carbonyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 33a 、 R 33b 、 R 33c , R 33d 、 R 33e 、 and R 33f are the same or different and represent a C1-C3 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom. Group G 1 : C1-C3 alkyl group optionally substituted with one or more halogen atoms; Group G 1-1 a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of OR 20 base, C(=Z 2 )R 21 base, C(=Z 2 ) OR 22 base, C(=Z 2 )NR 21 R 22 group, mercapto group, S(O) n R 23 group, NR 20 R 24 The group consisting of a nitro group, a halogen atom, and a cyano group. Group G 1-1 : The group consisting of halogen atoms and cyano groups. Group G 2The group consisting of a C1-C3 alkoxy group optionally substituted with one or more halogen atoms, a C1-C3 alkylthio group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfonyl group optionally substituted with one or more halogen atoms, a halogen atom, a cyano group, a hydroxy group, and a mercapto group. Group G 3 The group consisting of a C1-C3 alkyl group optionally substituted with one or more halogen atoms, a C1-C3 alkoxy group optionally substituted with one or more halogen atoms, a C1-C3 alkylthio group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfonyl group optionally substituted with one or more halogen atoms, an oxo group, a thioxo group, a halogen atom, a cyano group, a hydroxy group, and a mercapto group. Group G 4 :G group 4-2 a C1-C6 alkyl group optionally substituted with one or more substituents selected from the group G 4-1 a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of OR 25 base, C(=Z 3 )R 26 base, C(=Z 3 ) OR 27 base, C(=Z 3 )NR 26 R 27 group, mercapto group, S(O) m R 28 group, NR 25 R 29 group, NR 35 R 36 The group consisting of a nitro group, a halogen atom, an SF5 group, a morpholino group, and a cyano group. Group G 6The group consisting of a C1-C3 alkoxy group optionally substituted with one or more halogen atoms, a C1-C3 alkylthio group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfonyl group optionally substituted with one or more halogen atoms, a halogen atom, a cyano group, a nitro group, a hydroxy group, and a mercapto group. Group G 4-1 C1-C6 chain hydrocarbon group, C1-C6 alkoxy group, C1-C6 alkylthio group, C1-C6 alkylamino group, C2-C8 dialkylamino group, (C1-C6 alkyl)carbonyl group, (C1-C6 alkoxy)carbonyl group, (C1-C6 alkylamino)carbonyl group, (C2-C8 dialkylamino)carbonyl group, C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group, (C1-C6 alkylamino)sulfonyl group, (C2-C8 dialkylamino)sulfonyl group {the C1-C6 chain hydrocarbon group The hydrogen hydride group, the C1-C6 alkoxy group, the C1-C6 alkylthio group, the C1-C6 alkylamino group, the C2-C8 dialkylamino group, the (C1-C6 alkyl)carbonyl group, the (C1-C6 alkoxy)carbonyl group, the (C1-C6 alkylamino)carbonyl group, the (C2-C8 dialkylamino)carbonyl group, the C1-C6 alkylsulfinyl group, the C1-C6 alkylsulfonyl group, the (C1-C6 alkylamino)sulfonyl group, and the (C2-C8 dialkylamino)sulfonyl group are each selected from the group G 4-1-1 the group consisting of a halogen atom, a cyano group, a nitro group, a hydroxy group, an amino group, a formyl group, an aminocarbonyl group, an aminosulfonyl group, and an SF5 group, each of which may be substituted with one or more substituents selected from the group consisting of a halogen atom, a cyano group, a nitro group, a hydroxy group, an amino group, a formyl group, an aminocarbonyl group, an aminosulfonyl group, and an SF5 group; Group G 4-1-1the group consisting of halogen atoms, cyano groups, nitro groups, hydroxy groups, amino groups, oxo groups, thioxo groups, aminocarbonyl groups, aminosulfonyl groups, C3-C6 cycloalkyl groups, C1-C3 alkoxy groups, C1-C3 alkylthio groups, (C1-C3 alkyl)carbonyl groups, (C1-C3 alkoxy)carbonyl groups, C1-C3 alkylsulfinyl groups, and C1-C3 alkylsulfonyl groups {the C3-C6 cycloalkyl groups, the C1-C3 alkoxy groups, the C1-C3 alkylthio groups, the (C1-C3 alkoxy)carbonyl groups, the C1-C3 alkylsulfinyl groups, and the C1-C3 alkylsulfonyl groups are optionally substituted with one or more halogen atoms}. Group G 4-2 C1-C6 alkoxy group, C1-C6 alkylthio group, C1-C6 alkylamino group, C2-C8 dialkylamino group, (C1-C6 alkyl)carbonyl group, (C1-C6 alkoxy)carbonyl group, (C1-C6 alkylamino)carbonyl group, (C2-C8 dialkylamino)carbonyl group, C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group, (C1-C6 alkylamino)sulfonyl group, (C2-C8 dialkylamino)sulfonyl group {the C1-C6 alkoxy group, The oxy group, the C1-C6 alkylthio group, the C1-C6 alkylamino group, the C2-C8 dialkylamino group, the (C1-C6 alkyl)carbonyl group, the (C1-C6 alkoxy)carbonyl group, the (C1-C6 alkylamino)carbonyl group, the (C2-C8 dialkylamino)carbonyl group, the C1-C6 alkylsulfinyl group, the C1-C6 alkylsulfonyl group, the (C1-C6 alkylamino)sulfonyl group, and the (C2-C8 dialkylamino)sulfonyl group are each selected from the group G 4-1-1 the group consisting of a halogen atom, a cyano group, a nitro group, a hydroxy group, an amino group, a formyl group, an aminocarbonyl group, an aminosulfonyl group, and an SF5 group, each of which may be substituted with one or more substituents selected from the group consisting of a halogen atom, a cyano group, a nitro group, a hydroxy group, an amino group, a formyl group, an aminocarbonyl group, an aminosulfonyl group, and an SF5 group; Group G 8The group consisting of a (C1-C6 alkyl)carbonyl group optionally substituted with one or more halogen atoms, a (C1-C6 alkoxy)carbonyl group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylthio group optionally substituted with one or more halogen atoms, a cyano group, and a halogen atom. or a salt thereof (hereinafter, the compound represented by formula (I) or a salt thereof will be referred to as "the compound") to weeds or soil in which weeds grow. [2] A composition containing the compound represented by formula (I) according to [1] or a salt thereof and one or more components selected from the group consisting of group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i), and group (j): Group (a): A group consisting of arthropodicidal active ingredients and nematicidal active ingredients; Group (b): Fungicidally active ingredients; Group (c): Plant growth regulating components; Group (d): phytotoxicity-reducing components; Group (e): synergists; Group (f): repellent components; Group (g): molluscicidal ingredients; Group (h): insect pheromones; Group (i): herbicidal active ingredients; Group (j): Biological control materials. [3] A method for controlling weeds, comprising the step of applying an effective amount of the composition according to [2] to weeds or soil in which weeds grow. [Effects of the Invention]

[0006] The present invention makes it possible to control weeds. DETAILED DESCRIPTION OF THE INVENTION

[0007] The substituents in the present invention will be explained. A halogen atom means a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom. When a substituent is substituted with two or more halogen atoms or substituents, the halogen atoms or substituents may be the same or different. In this specification, the expression "optionally substituted with one or more substituents selected from group X" means that when two or more substituents selected from group X are present, those substituents may be the same or different. In this specification, the notation "CX-CY" means that the number of carbon atoms is X to Y. For example, the notation "C1-C8" means that the number of carbon atoms is 1 to 8. The chain hydrocarbon group represents an alkyl group, an alkenyl group, or an alkynyl group. Examples of alkyl groups include methyl, ethyl, propyl, isopropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-ethylpropyl, butyl, sec-butyl, tert-butyl, pentyl, hexyl, and octyl groups. Examples of alkenyl groups include vinyl, 1-propenyl, 2-propenyl, 1-methyl-1-propenyl, 1-methyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1-ethyl-2-propenyl, 3-butenyl, 4-pentenyl, 5-hexenyl, and 7-octenyl groups. Examples of alkynyl groups include ethynyl, 1-propynyl, 2-propynyl, 1-methyl-2-propynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 2-butynyl, 4-pentynyl, 5-hexynyl, and 7-octynyl groups. Examples of alkoxy groups include methoxy, ethoxy, propoxy, isopropoxy, butoxy, tert-butoxy, pentyloxy, hexyloxy, and octyloxy groups. Haloalkoxy groups include, for example, trifluoromethoxy, difluoromethoxy, trifluoroethoxy, pentafluoroethoxy, and chlorodifluoromethoxy groups. Examples of the alkylsulfinyl group include a methylsulfinyl group, an ethylsulfinyl group, a propylsulfinyl group, and an isopropylsulfinyl group. Examples of the alkylsulfonyl group include a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, and an isopropylsulfonyl group.

[0008] Alicyclic hydrocarbon groups include, for example, cycloalkyl groups and cycloalkenyl groups. Examples of cycloalkyl groups include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, and cyclooctyl groups. Examples of cycloalkenyl groups include cyclopentenyl, cyclohexenyl, and cyclooctenyl groups.

[0009] Examples of the 5- to 6-membered aromatic heterocyclic group include a pyrrolyl group, a furyl group, a thienyl group, a pyrazolyl group, an imidazolyl group, a triazolyl group, a tetrazolyl group, an oxazolyl group, an isoxazolyl group, a thiazolyl group, an isothiazolyl group, an oxadiazolyl group, a thiadiazolyl group, a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, and a tetrazinyl group.

[0010] Examples of the 8- to 10-membered fused aromatic heterocyclic group include a quinolyl group, a benzoxazolyl group, a benzothiazolyl group, a benzimidazolyl group, an indazolyl group, a benzisothiazolyl group, and a benzothiophenyl group. Examples of the saturated or unsaturated 5- or 6-membered cyclic amino group include a pyrrolidinyl group, a piperidinyl group, and a pyrrolyl group.

[0011] The present compound may exist in one or more stereoisomers. Examples of stereoisomers include enantiomers, diastereomers, atropisomers, and geometric isomers. The present compound includes each stereoisomer and a mixture of stereoisomers in any ratio.

[0012] The present compound may form a base addition salt such as an isopropylamine salt, a dimethylamine salt, a sodium salt, or a potassium salt by mixing with a base such as isopropylamine, dimethylamine, sodium carbonate, or potassium carbonate. The present compound may form an acid addition salt such as a hydrochloride, sulfate, nitrate, phosphate, acetate, or benzoate when mixed with an acid such as hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, acetic acid, or benzoic acid.

[0013] The compounds may exist as zwitterions. In addition, in the present compound, at least one nitrogen atom contained in the compound represented by formula (I) may be oxidized to form a bond with an oxygen atom, thereby forming an N-oxide structure.

[0014] Next, the methods for producing the present compound and its intermediates will be explained.

[0015] Manufacturing method A The compound represented by formula (I-1) (hereinafter referred to as compound (I-1)) can be produced by reacting a compound represented by formula (A1) (hereinafter referred to as compound (A1)) with a compound represented by formula (M1) (hereinafter referred to as compound (M1)) in the presence of a catalyst and a base. TIFF2026027456000003.tif41150 [In the formula, W 1 represents a chlorine atom, a bromine atom, or an iodine atom; M 1 is an alkoxyboranyl group such as B(OH)2, 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl group, or a trifluoroborate salt (BF3 - K + ) and A a represents -CH2-, -C(=CH2)-, or a single bond, and R 15a represents a C1-C10 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, or a benzyl group {the phenyl moiety in the benzyl group is selected from the group G 6and the methylene portion may be substituted with one or two C1-C3 alkyl groups}, and the other symbols have the same meanings as above. The reaction is usually carried out in a single solvent or a mixed solvent. Examples of the solvent used in the reaction include hydrocarbons such as toluene, xylene, and hexane (hereinafter referred to as hydrocarbons); ethers such as methyl tert-butyl ether (hereinafter referred to as MTBE), tetrahydrofuran (hereinafter referred to as THF), and 1,4-dioxane (hereinafter referred to as ethers); halogenated hydrocarbons such as dichloromethane, chloroform, and chlorobenzene (hereinafter referred to as halogenated hydrocarbons); amides such as N,N-dimethylformamide (hereinafter referred to as DMF) (hereinafter referred to as amides); esters such as ethyl acetate (hereinafter referred to as esters); nitriles such as acetonitrile (hereinafter referred to as nitriles); water; and mixtures of two or more of these. Examples of the catalyst used in the reaction include palladium catalysts such as tetrakistriphenylphosphinepalladium(0), palladium(II) acetate, tris(dibenzylideneacetone)dipalladium, and [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride. Examples of the base used in the reaction include organic bases such as triethylamine, diisopropylethylamine, 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), pyridine, and 4-(dimethylamino)pyridine (hereinafter referred to as organic bases); alkali metal carbonates such as sodium carbonate and potassium carbonate (hereinafter referred to as alkali metal carbonates); alkali metal bicarbonates such as potassium bicarbonate (hereinafter referred to as alkali metal bicarbonates); alkaline earth metal carbonates such as magnesium carbonate and calcium carbonate (hereinafter referred to as alkaline earth metal carbonates); sodium fluoride and tripotassium phosphate. In the reaction, the compound (M1) is usually used in a ratio of 1 to 10 moles, the catalyst is usually used in a ratio of 0.01 to 1 mole, and the base is usually used in a ratio of 1 to 10 moles, relative to 1 mole of the compound (A1). The reaction temperature is usually within the range of 0 to 150° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is dried and concentrated, among other post-treatment procedures, to isolate compound (I-1). Compound (M1) is a commercially available compound, or can be prepared by the method described in Chemical Reviews, Vol. 95, pp. 2457-2483 (1995) or a method analogous thereto. Boronic acid derivatives can also be prepared by hydrolyzing, as necessary, boronate ester derivatives obtained by these methods or commercially available boronic acid ester derivatives. Furthermore, the boronate esters can be fluorinated to give trifluoroborate salts (BF3 - K + ) can also be obtained.

[0016] Manufacturing method B The compound represented by formula (I-2) (hereinafter referred to as compound (I-2)) can be produced by reacting compound (A1) with a compound represented by formula (M2) (hereinafter referred to as compound (M2)) in the presence of one or more catalysts and one or more bases. TIFF2026027456000004.tif45150 [In formula, A b is an oxygen atom, a sulfur atom, -NR 6 - group or a single bond, and other symbols have the same meanings as above.] The reaction is usually carried out in a single solvent or a mixed solvent, such as hydrocarbons, ethers, halogenated hydrocarbons, amides, esters, nitriles, water, or a mixture of two or more thereof. Examples of the catalyst used in the reaction include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), 1,1'-bis(diphenylphosphino)ferrocenepalladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(0), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and copper catalysts such as copper(I) iodide and copper(I) chloride. Examples of the base used in the reaction include organic bases; alkali metal carbonates; alkaline earth metal carbonates; alkali metal hydrogencarbonates; metal carboxylates such as sodium acetate, potassium acetate, calcium acetate, magnesium acetate, and the like (hereinafter referred to as metal carboxylates); metal alkoxides such as sodium methoxide, sodium ethoxide, sodium tert-butoxide, potassium methoxide, potassium tert-butoxide, and the like (hereinafter referred to as metal alkoxides); metal hydroxides such as sodium hydroxide, potassium hydroxide, calcium hydroxide, magnesium hydroxide, and the like (hereinafter referred to as metal hydroxides); and metal hydrides such as lithium hydride, sodium hydride, potassium hydride, calcium hydride, and the like (hereinafter referred to as metal hydrides). Ligands can also be used in the reaction, if necessary. Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, N,N'-dimethylethylenediamine, N,N,N'-trimethylethylenediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline. When a ligand is used in the reaction, the ligand is typically used in a ratio of 0.01 to 1 mole per mole of compound (A1). In the reaction, the compound (M2) is usually used in a ratio of 1 to 10 moles, the catalyst is usually used in a ratio of 0.01 to 1 mole, and the base is usually used in a ratio of 1 to 10 moles, relative to 1 mole of the compound (A1). The reaction temperature is usually within the range of −20 to 200° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is dried and concentrated, among other post-treatment procedures, to isolate compound (I-2). Compound (M2) is a commercially available compound, or can be prepared according to known methods.

[0017] Manufacturing method C-1 The compound represented by formula (I-3) (hereinafter referred to as compound (I-3)) can be produced by reacting a compound represented by formula (I-1-1) (hereinafter referred to as compound (I-1-1)) with a compound represented by formula (M3) (hereinafter referred to as compound (M3)) in the presence of a base. TIFF2026027456000005.tif42150 [in the formula, R 4a represents a C1-C3 alkyl group optionally substituted with one or more halogen atoms, L 1 represents a leaving group such as a halogen atom, a methanesulfonyloxy group, a trifluoromethylsulfonyloxy group, a 4-methylphenylsulfonyloxy group, or a phenylsulfonyloxy group, and other symbols have the same meanings as above. The reaction is usually carried out in a single solvent or a mixed solvent. Examples of the solvent used in the reaction include hydrocarbons, ethers, halogenated hydrocarbons, amides, esters, nitriles, alcohols such as methanol and ethanol (hereinafter referred to as alcohols), ketones such as acetone and methyl isobutyl ketone (hereinafter referred to as MIBK), water, and mixtures of two or more of these. Examples of the base used in the reaction include organic bases; alkali metal carbonates; alkaline earth metal carbonates; alkali metal hydrogencarbonates; metal carboxylates; metal hydroxides; and metal hydrides. In the reaction, the compound (M3) is usually used in a proportion of 1 to 10 moles and the base is usually used in a proportion of 1 to 10 moles per mole of the compound (I-1-1). The reaction temperature is usually within the range of −20 to 200° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is dried and concentrated, among other post-treatment procedures, to isolate compound (I-3). Compound (M3) is a commercially available compound, or can be prepared according to known methods.

[0018] Manufacturing method C-2 The compound represented by formula (I-4) (hereinafter referred to as compound (I-4)) can be produced by reacting compound (I-3) with a compound represented by formula (M4) (hereinafter referred to as compound (M4)) in the presence of a base. TIFF2026027456000006.tif43150 [in the formula, R 5a represents a C1-C3 alkyl group optionally substituted with one or more halogen atoms, and the other symbols have the same meanings as above. The reaction can be carried out according to Production Method C-1, using compound (I-3) instead of compound (I-1-1) and compound (M4) instead of compound (M3). Compound (M4) is a commercially available compound, or can be prepared according to known methods.

[0019] Manufacturing method C-3 The compound represented by formula (I-5) (hereinafter referred to as compound (I-5)) can be produced by reacting compound (I-1-1) with a compound represented by formula (M5) (hereinafter referred to as compound (M5)) in the presence of a base. TIFF2026027456000007.tif43150 [wherein r represents an integer of 1 to 4, L 2represents a leaving group such as a halogen atom, a methanesulfonyloxy group, a trifluoromethylsulfonyloxy group, a 4-methylphenylsulfonyloxy group, or a phenylsulfonyloxy group, and other symbols have the same meanings as above. The reaction can be carried out according to Production Method C-1, using compound (M5) instead of compound (M3). Compound (M5) is a commercially available compound, or can be prepared according to known methods.

[0020] Manufacturing method D The compound represented by formula (I-6) (hereinafter referred to as compound (I-6)) can be produced by reacting a compound represented by formula (I-1-2) (hereinafter referred to as compound (I-1-2)) with hydrogen in the presence of a hydrogenation catalyst. TIFF2026027456000008.tif45150 (wherein the symbols have the same meanings as above.) The reaction is usually carried out in a solvent under a hydrogen atmosphere at 1 to 100 atmospheres. Examples of the solvent used in the reaction include alcohols, esters, halogenated hydrocarbons, ethers, hydrocarbons, water, and mixtures of two or more of these. Examples of the hydrogenation catalyst used in the reaction include transition metal catalysts such as palladium on carbon (Pd / C), platinum on carbon (Pt / C), Raney nickel, and palladium hydroxide, and compounds thereof. The reaction can be carried out by adding an acid or a base, if necessary. Examples of acids include acetic acid and hydrochloric acid, and examples of bases include tertiary amines such as triethylamine and magnesium oxide. In the reaction, a hydrogenation catalyst is usually used in a proportion of 0.001 to 1 mole, and hydrogen is usually used in a proportion of 1 mole or more, relative to 1 mole of compound (I-1-2).When an acid or a base is used in the reaction, the acid is usually used in a proportion of 0.001 to 10 moles, and the base is usually used in a proportion of 1 to 10 moles. The reaction temperature is usually within the range of −20 to 150° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the catalyst is filtered off, and the filtrate is concentrated or other post-treatment procedures are carried out to isolate compound (I-6).

[0021] Manufacturing method E The compound represented by formula (I-8) (hereinafter referred to as compound (I-8)) can be produced by reacting the compound represented by formula (I-7) (hereinafter referred to as compound (I-7)) in the presence of a reducing agent. TIFF2026027456000009.tif42150 (wherein the symbols have the same meanings as above.) The reaction is usually carried out in a single solvent or a mixed solvent, such as hydrocarbons, ethers, halogenated hydrocarbons, amides, esters, nitriles, alcohols, water, or a mixture of two or more thereof. The reducing agent used in the reaction includes, for example, borohydride salts such as sodium borohydride and potassium borohydride. In the reaction, the reducing agent is usually used in a proportion of 0.3 to 1.5 moles per mole of compound (I-7). The reaction temperature is usually within the range of −20 to 200° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is dried and concentrated, allowing compound (I-8) to be isolated.

[0022] Manufacturing method E The compound represented by formula (I-9) (hereinafter referred to as compound (I-9)) can be produced by reacting compound (I-8) with compound (M3) in the presence of a base. TIFF2026027456000010.tif46150 (wherein the symbols have the same meanings as above.) The reaction can be carried out according to Production Method C-1, using Compound (I-8) instead of Compound (I-1-1).

[0023] Manufacturing method F Compound (I-7) can be produced by reacting a compound represented by formula (I-10) (hereinafter referred to as compound (I-10)) with a compound represented by formula (M6) (hereinafter referred to as compound (M6)) in the presence of a base. TIFF2026027456000011.tif41150 (wherein the symbols have the same meanings as above.) The reaction is usually carried out in a single solvent or a mixed solvent. Examples of the solvent used in the reaction include hydrocarbons, ethers, halogenated hydrocarbons, amides, imidazolinones such as 1,3-dimethyl-2-imidazolinone, sulfoxides (hereinafter referred to as sulfoxides) such as dimethyl sulfoxide (hereinafter referred to as DMSO), nitriles, water, and mixtures of two or more of these. Examples of the base used in the reaction include organic bases; alkali metal carbonates; alkaline earth metal carbonates; alkali metal hydrogencarbonates; metal carboxylates; metal alkoxides; metal hydroxides; and metal hydrides. In the reaction, compound (M6) is usually used in a proportion of 1 to 10 moles, and a base is usually used in a proportion of 1 to 10 moles, relative to 1 mole of compound (I-10). The reaction temperature is usually within the range of −20 to 200° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is dried and concentrated, among other post-treatment procedures, to isolate compound (I-7). Compound (M6) is a commercially available compound, or can be prepared according to known methods.

[0024] Manufacturing method G Compound (I-10) can be produced using a compound represented by formula (A2) (hereinafter referred to as compound (A2)) and a compound represented by formula (A3) (hereinafter referred to as compound (A3)) according to the following scheme. TIFF2026027456000012.tif65150 (wherein the symbols have the same meanings as above.) Each reaction in the above scheme can be carried out according to the method described in US Pat. No. 2,454,742. Compound (A2) is a commercially available compound, or can be prepared according to a known method. Compound (A3) is a commercially available compound, or can be prepared according to the method described in Journal of the Chemical Society 1963, 4483-4489.

[0025] Manufacturing method H-1 The compound represented by formula (I-12) (hereinafter referred to as compound (I-12)) can be produced by reacting the compound represented by formula (I-11) (hereinafter referred to as compound (I-11)) in the presence of a base. TIFF2026027456000013.tif42150 (wherein the symbols have the same meanings as above.) The reaction is usually carried out in a single solvent or a mixed solvent, such as ethers, alcohols, water, or a mixture of two or more thereof. Examples of the base used in the reaction include organic bases; alkali metal carbonates; alkaline earth metal carbonates; alkali metal hydrogencarbonates; metal carboxylates; and metal hydroxides. In the reaction, the base is usually used in a proportion of 1 to 10 moles per mole of compound (I-11). The reaction temperature is usually within the range of −20 to 200° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is dried and concentrated, allowing compound (I-12) to be isolated.

[0026] Manufacturing method H-2 Compound (I-12) can also be produced by reacting compound (I-11) in the presence of a lithium salt and an amine. TIFF2026027456000014.tif40150 (wherein the symbols have the same meanings as above.) The reaction can be carried out according to the method described in Tetrahedron Letters 2007, 48, 2497-2499.

[0027] Manufacturing method H-3 Compound (I-12) can also be produced by reacting compound (I-11) in the presence of an acid. TIFF2026027456000015.tif40150 (wherein the symbols have the same meanings as above.) The reaction is usually carried out in a single solvent or a mixed solvent, such as hydrocarbons, ethers, halogenated hydrocarbons, water, or a mixture of two or more thereof. Examples of the acid used in the reaction include sulfonic acids such as methanesulfonic acid and p-toluenesulfonic acid (hereinafter referred to as sulfonic acids); inorganic acids such as hydrochloric acid and sulfuric acid (hereinafter referred to as inorganic acids); and carboxylic acids such as acetic acid and trifluoroacetic acid (hereinafter referred to as carboxylic acids). In the reaction, the acid is usually used in a proportion of 0.001 to 10 moles per mole of compound (I-11). The reaction temperature is usually within the range of −20 to 150° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is dried and concentrated, allowing compound (I-12) to be isolated.

[0028] Manufacturing method I Compound (I-13) can be produced using a compound represented by formula (A2) (hereinafter referred to as compound (A2)) and a compound represented by formula (A10) (hereinafter referred to as compound (A10)) according to the following scheme. Each reaction in the above scheme can be carried out according to the method described in Production Method G. TIFF2026027456000016.tif74169 (wherein the symbols have the same meanings as above).

[0029] Manufacturing method J Compound (I-15) can be produced using a compound represented by formula (I-14) (hereinafter referred to as compound (I-14)) and a compound represented by formula (M7) (hereinafter referred to as compound (M7)) according to the following scheme. TIFF2026027456000017.tif44117 [in the formula, R 2a represents a hydrogen atom, a C1-C7 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C3 alkoxy group optionally substituted with one or more halogen atoms, a C1-C3 alkylthio group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfonyl group optionally substituted with one or more halogen atoms, or a cyano group; R 2b represents a C1-C7 chain hydrocarbon group which may be substituted with one or more halogen atoms, and the other symbols have the same meanings as above. The reaction is usually carried out in a single solvent or a mixed solvent, such as hydrocarbons, ethers, halogenated hydrocarbons, or a mixture of two or more thereof. Examples of the base used in the reaction include organic bases; alkali metal carbonates; alkaline earth metal carbonates; alkali metal hydrogencarbonates; metal alkoxides; metal hydroxides; and metal hydrides; metal amides, alkyllithiums, and Grignard reagents. In the reaction, compound (M7) is usually used in a proportion of 1 to 10 moles, and a base is usually used in a proportion of 1 to 10 moles, relative to 1 mole of compound (I-14). The reaction temperature is usually within the range of −80 to 200° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is neutralized with an acidic aqueous solution, extracted with an organic solvent, and the organic layer is dried and concentrated, allowing compound (I-15) to be isolated. Compound (M7) is a commercially available compound, or can be prepared according to known methods.

[0030] Manufacturing method L-1 The compound represented by formula (I-16) (hereinafter referred to as compound (I-16)) can be produced by a step (step M-1) of reacting compound (I-13) with a chlorinating agent to obtain a compound represented by formula (IM-17) (hereinafter referred to as compound (IM-17)), and a step (step M-2) of reacting compound (IM-17) obtained in step M-1 with a compound represented by formula (M8) (hereinafter referred to as compound (M8)) in the presence of a base to obtain compound (I-16). TIFF2026027456000018.tif32150 (wherein the symbols have the same meanings as above.)

[0031] First, step M-1 will be described. The reaction is usually carried out in a single solvent or a mixed solvent, such as hydrocarbons, ethers, halogenated hydrocarbons, esters, and mixtures of two or more thereof. Examples of the chlorinating agent used in the reaction include thionyl chloride, oxalyl chloride, phosphorus oxychloride, etc. The chlorinating agent is usually used in a proportion of 1 to 10 moles per mole of compound (I-13). The reaction may be carried out in the presence of a catalyst. An example of the catalyst is DMF. When the reaction is carried out in the presence of a catalyst, the catalyst is usually used in a proportion of 0.01 to 1 mole per mole of compound (I-13). The reaction temperature is usually within the range of −80 to 150° C. The reaction time is usually within the range of 0.1 to 120 hours. After completion of the reaction, compound (IM-17) can be isolated by carrying out post-treatment. After the reaction is complete, the reaction mixture may be directly subjected to step M-2, or the mixture obtained by concentrating the reaction mixture may be subjected to step M-2. Next, step M-2 will be described. The reaction is usually carried out in a single solvent or a mixed solvent, such as hydrocarbons, ethers, halogenated hydrocarbons, esters, and mixtures of two or more thereof. Examples of the base used in the reaction include organic bases; alkaline earth metal carbonates; alkali metal carbonates; alkali metal hydrogencarbonates; metal carboxylates; and metal hydroxides. In the reaction, the compound (M8) is usually used in a proportion of 1 to 10 moles, and the base is usually used in a proportion of 0 to 10 moles, relative to 1 mole of the compound (I-13) used in step M-1. The reaction temperature is usually within the range of −80 to 150° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is washed, dried, concentrated, and other post-treatment procedures to isolate compound (I-16). The reaction conditions (solvent, reaction temperature, reaction time, etc.) for step M-1 and step M-2 may be the same or different. Step M-1 and step M-2 may be carried out simultaneously by mixing compound (I-13), a chlorinating agent, a base, and compound (M8), or step M-2 may be carried out after step M-1. Step M-2 may also be started between the start and end of step M-1.

[0032] Manufacturing method L The compound represented by formula (I-18) (hereinafter referred to as compound (I-18)), the compound represented by formula (I-19) (hereinafter referred to as compound (I-19)), and the compound represented by formula (I-20) (hereinafter referred to as compound (I-20)) can be produced by reacting compound (I-11) with a sulfiding agent. TIFF2026027456000019.tif67146 (wherein the symbols have the same meanings as above.) The reaction is usually carried out in a single solvent or a mixed solvent, such as hydrocarbons, ethers, halogenated hydrocarbons, and mixtures of two or more thereof. Examples of the sulfurizing agent used in the reaction include diphosphorus pentasulfide and 2,4-bis(4-methoxyphenyl)-1,3-dithia-2,4-diphosphetane 2,4-disulfide (hereinafter referred to as Lawesson's reagent). The reaction may be carried out in the presence of a base. Examples of the base include organic bases, alkali metal carbonates, alkaline earth metal carbonates, alkali metal hydrogencarbonates, metal carboxylates, metal alkoxides, metal hydroxides, and metal hydrides. When the reaction is carried out in the presence of a base, the base is usually used in a proportion of 1 to 10 moles per mole of compound (I-16). In the reaction, the sulfurizing agent is usually used in a proportion of 1 to 10 moles per mole of compound (I-11). The reaction temperature is usually within the range of −20 to 150° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is dried and concentrated, among other post-treatment procedures, to isolate compound (I-18), compound (I-19), or compound (I-20). The proportions of compound (I-18), compound (I-19), and compound (I-20) produced can be increased or decreased by adjusting the type of solvent and sulfurizing agent, the equivalent amount of the sulfurizing agent, the reaction temperature, and the reaction time.

[0033] Manufacturing method M Compound (I-21) can be produced by a step (step M-3) of treating a compound represented by formula (I-22) (hereinafter referred to as compound (I-22)) with a halogenating agent or a sulfonylating agent to obtain a compound represented by formula (I-23) (hereinafter referred to as compound (I-23)), and a step (step M-4) of reacting compound (I-23) obtained in step M-3 with a compound represented by formula (M9) (hereinafter referred to as compound (M9)) in the presence of a base to obtain compound (I-21). TIFF2026027456000020.tif36155 [In the formula, L 3 represents a chlorine atom, a methanesulfonyloxy group, a trifluoromethylsulfonyloxy group, a 4-methylphenylsulfonyloxy group, or a phenylsulfonyloxy group; R 1a is a group represented by formula (C-2) TIFF2026027456000021.tif2921 (wherein ● represents a bonding site with a carbon atom or a hydrogen atom, and represents G 11a , G 11b , G 11c , G 11d are the same or different and are a nitrogen atom or G 1 represents a methine group which may be substituted with one or more substituents selected from represents.]

[0034] First, the step M-3 will be described. The reaction is usually carried out in a single solvent or a mixed solvent, such as hydrocarbons, halogenated hydrocarbons, ethers, nitriles, or a mixture of two or more thereof. Chlorinating agents used in the reaction include thionyl chloride and phosphorus trichloride. Examples of the sulfonylating agent used in the reaction include paratoluenesulfonyl chloride, methanesulfonyl chloride, paratoluenesulfonic anhydride, and methanesulfonic anhydride, and examples of the base include organic bases such as pyridine and triethylamine. In the reaction, the chlorinating agent or sulfonylating agent is usually used in a proportion of 1 to 10 moles, and the base is usually used in a proportion of 0 to 10 moles, relative to 1 mole of compound (I-22). The reaction temperature is usually within the range of 0 to 150° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water and then extracted with an organic solvent. The organic layer is then dried and concentrated, or the residue is subjected to column chromatography or other post-treatment procedures to isolate compound (I-23).

[0035] Next, step M-4 will be described. The reaction is usually carried out in a single solvent or a mixed solvent. Examples of the solvent used in the reaction include hydrocarbons, ethers, halogenated hydrocarbons, amides, esters, nitriles, imidazolinones, sulfoxides, and mixtures of two or more of these. Examples of the base used in the reaction include organic bases; alkali metal carbonates; alkaline earth metal carbonates; metal hydroxides; and metal hydrides. The base is usually used in an amount of 1 to 10 moles per mole of compound (I-23). The reaction may be carried out in the presence of a catalyst. Examples of the catalyst include alkali metal halides such as sodium iodide, sodium bromide, lithium iodide, and lithium bromide; and ammonium salts such as tetrabutylammonium iodide and tetrabutylammonium bromide. When the reaction is carried out in the presence of a catalyst, the catalyst is usually used in a proportion of 0.01 to 1 mole per mole of compound (I-23). The reaction temperature is usually within the range of −20 to 150° C. The reaction time is usually within the range of 0.1 to 120 hours. After completion of the reaction, compound (I-21) can be isolated by carrying out post-treatment.

[0036] Reference manufacturing method 1 Compound (A1) can be produced by reacting a compound represented by formula (A6) (hereinafter referred to as compound (A6)) in the presence of a halogenating agent. TIFF2026027456000022.tif41146 (wherein the symbols have the same meanings as above). The reaction is usually carried out in a single solvent or a mixed solvent, such as hydrocarbons, ethers, halogenated hydrocarbons, amides, esters, nitriles, imidazolinones, sulfoxides, or a mixture of two or more thereof. Examples of halogenating agents used in the reaction include chlorine, bromine, iodine, N-chlorosuccinimide, N-bromosuccinimide, N-iodosuccinimide, 1,3-dibromo-5,5-dimethylhydantoin, and dibromoisocyanuric acid. In the reaction, the halogenating agent is usually used in a proportion of 1 to 10 moles per mole of compound (A6). The reaction temperature is usually within the range of −100 to 200° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is dried and concentrated, among other post-treatment procedures, to isolate compound (A1).

[0037] Reference manufacturing method 2 Compound (A6) can be produced by reacting a compound represented by formula (A7) (hereinafter referred to as compound (A7)) with compound (M6) in the presence of a base. TIFF2026027456000023.tif41143 (wherein the symbols have the same meanings as above.) The reaction can be carried out according to Production Method F, using Compound (A7) instead of Compound (I-10).

[0038] Reference manufacturing method 3 Compound (A7) can be produced using compound (A2) and a compound represented by formula (A8) (hereinafter referred to as compound (A8)) according to the following scheme. TIFF2026027456000024.tif69156 (wherein the symbols have the same meanings as above.) Each reaction in the above scheme can be carried out according to Production Method G. Compound (A8) is a commercially available compound, or can be prepared according to known methods.

[0039] Reference manufacturing method 4 Compound (A10) can be produced from a compound represented by formula (A12) (hereinafter referred to as compound (A12)) according to the scheme described below. TIFF2026027456000025.tif54154 (wherein the symbols have the same meanings as above.) Each reaction in the above scheme can be carried out according to the method described in Organic Letters 2022, 24, 3440-3444. The compound (A12) can be produced in accordance with a known method. Compound (A12) and the compound represented by formula (A12-1) (hereinafter referred to as compound (A12-1)) may exist as keto-enol tautomers. Compound (A12) and compound (A12-1) include each keto-enol tautomer and a mixture of keto-enol tautomers in any ratio.

[0040] Reference manufacturing method 5 Compound (A-13) can be produced by reacting a compound represented by formula (A1) (hereinafter referred to as compound (A1)) with a compound represented by formula (M10) (hereinafter referred to as compound (M10)) in the presence of a base and a catalyst, according to the scheme described below. TIFF2026027456000026.tif38132 [in the formula, R 6a represents a C1-C6 alkyl group, a C1-C6 alkoxy group, or a phenyl group, and other symbols have the same meanings as above. The reaction is usually carried out in a single solvent or a mixture of solvents, such as hydrocarbons, ethers, halogenated hydrocarbons, amides, esters, nitriles, water, and mixtures of two or more thereof. Examples of the catalyst used in the reaction include palladium catalysts such as tetrakistriphenylphosphinepalladium(0), palladium(II) acetate, tris(dibenzylideneacetone)dipalladium, and [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride. Examples of the base used in the reaction include organic bases, alkali metal carbonates, alkali metal hydrogencarbonates, alkaline earth metal carbonates, sodium fluoride, and tripotassium phosphate. In the reaction, the compound (M10) is usually used in a proportion of 1 to 10 moles, the catalyst is usually used in a proportion of 0.01 to 1 mole, and the base is usually used in a proportion of 1 to 10 moles, relative to 1 mole of the compound (A1). The reaction temperature is usually within the range of 0 to 150° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water, extracted with an organic solvent, and the organic layer is dried and concentrated, among other post-treatment procedures, to isolate compound (A-13).

[0041] Compound (I-22) can be produced by reacting compound (A-13) with an oxidizing agent and then with a reducing agent according to the scheme shown below. TIFF2026027456000027.tif37152 (wherein the symbols have the same meanings as above.) The reaction is usually carried out in a single solvent or a mixed solvent, such as hydrocarbons, halogenated hydrocarbons, esters, alcohols, nitriles, water, or a mixture of two or more thereof. Examples of oxidizing agents used in the reaction include ozone, osmium tetroxide, sodium periodate, potassium periodate, ruthenium (IV) oxide, and ruthenium chloride. The reducing agent used in the reaction includes, for example, borohydride salts such as sodium borohydride and potassium borohydride. In the reaction, the oxidizing agent is usually used in an amount of 1 mole to an excess amount per mole of compound (A-13). When ozone is used as the oxidizing agent, the ozone is used in large excess per mole of compound (A-13). In the reaction, the reducing agent is usually used in a ratio of 0.3 to 1.5 per mole of compound (A-13). The reaction temperature is usually within the range of −80 to 200° C. The reaction time is usually within the range of 0.1 to 120 hours. After the reaction is complete, the reaction mixture is mixed with water and then extracted with an organic solvent. The organic layer is then dried and concentrated, or the residue is subjected to column chromatography or other post-treatment procedures to isolate compound (I-22).

[0042] This compound can be mixed or used in combination with one or more components (hereinafter referred to as this component) selected from the group consisting of the following groups (a), (b), (c), (d), (e), (f), (g), (h), (i), and (j): The term "mixed or combined use" means that the present compound and the present ingredient are used simultaneously, separately or with an interval of time. When the present compound and the present ingredient are used simultaneously, the present compound and the present ingredient may be contained in separate preparations or may be contained in a single preparation. One aspect of the present invention is a composition (hereinafter referred to as Composition A) containing one or more components selected from the group consisting of Group (a), Group (b), Group (c), Group (d), Group (e), Group (f), Group (g), Group (h), Group (i), and Group (j) (i.e., the present component), and the present compound.

[0043] Group (a) includes acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphate insecticides), GABAergic chloride ion channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamatergic chloride ion channel allosteric modulators (e.g., macrolide insecticides), juvenile hormone receptor modulators, multisite inhibitors, chordotonal organ TRPV channel modulators, mite growth inhibitors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, mitochondrial electron transport chain complex I, II, The group consisting of inhibitors of classes III and IV, voltage-dependent sodium channel blockers, acetyl-CoA carboxylase inhibitors, ryanodine receptor modulators (e.g., diamide insecticides), chordotonal organ nicotinamidase inhibitors, GABA-gated chloride ion channel allosteric modulators, calcium-activated potassium channel modulators, target suppressors via RNA interference, vesicular acetylcholine transporter inhibitors, and other arthropodicidal and nematicidal active ingredients, which are described in the mechanism-based classification of IRAC.

[0044] Group (b) consists of nucleic acid synthesis inhibitors (e.g., phenylamide fungicides, acylamino acid fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiratory inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid synthesis and protein synthesis inhibitors (e.g., anilinopyrimidine fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., DMI fungicides such as triazoles), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multisite contact-active fungicides, microbial fungicides, and other fungicidal active ingredients. These are described in the FRAC classification based on the mechanism of action.

[0045] Group (c) is a group of plant growth regulators.

[0046] Group (d) is a group of safeners.

[0047] Group (e) is a group of synergists.

[0048] Group (f) is a group of repellent components consisting of bird repellent components, insect repellent components and animal repellent components.

[0049] Group (g) is the group of molluscicidal ingredients.

[0050] Group (h) is a group of signaling substances consisting of pheromones and allelochemicals used by insects.

[0051] Group (i) consists of acetyl-CoA carboxylase (ACCase) inhibitors, acetolactate synthase (ALS) inhibitors, photosynthesis (photosystem II) inhibitors, photosystem I electron converters, protoporphyrinogen oxidase (PPO) inhibitors, phytoene desaturase system (PDS) inhibitors, 4-hydroxyphenylpyruvate dioxygenase (4-HPPD) inhibitors, carotenoid biosynthesis inhibitors, EPSP synthase inhibitors, glutamine synthase inhibitors, dihydropteroic acid (DHP) synthase inhibitors, microtubule polymerization inhibitors, mitosis / microtubule formation inhibitors, very long-chain fatty acid (VLCFA) inhibitors, cellulose synthesis inhibitors, uncoupling agents, lipid synthesis inhibitors, indoleacetic acid-like active agents, auxin transport inhibitors, and other herbicidal active ingredients. These are listed in the HRAC classification based on the mechanism of action.

[0052] Group (j) is a group of biological control agents consisting of bacteria, fungi, yeasts, protozoa, viruses, natural products, insects, mites, and mollusks that have pest control effects (e.g., insecticidal, acaricidal, nematicidal, fungicidal, and fungicidal activities), herbicidal activities, or plant growth-regulating effects such as rhizobia and mycorrhizal fungi. Specifically, group (j) is divided into subgroups (j-1): bacteria, (j-2): fungi and yeasts, (j-3): protozoa, (j-4): viruses, (j-5): nematodes, (j-6): natural products, (j-7): insects, (j-8): mites, and (j-9): mollusks.

[0053] Examples of combinations of the present ingredients and compounds are listed below: For example, alanycarb + SX means a combination of alanycarb and SX. The abbreviation SX means any one of the present compounds selected from the compound group SX1 to SX24 and the present compounds 1 to 236 described below. The present components described below are all known components and can be obtained from commercially available preparations or produced by known methods. When the present component is a microorganism, it can also be obtained from a bacterial depository. The number in parentheses indicates the CAS RN (registered trademark).

[0054] Combinations of the present components and the present compounds in group (a) above: Abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetic acid + SX, acetoprole + SX, acrinathrin + SX, acinonapyr + SX, afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha-endosulfan + SX, aluminum phosphide + SX, Amitraz + SX, azamethiphos + SX, azinphos-ethyl + SX, azinphos-methyl + SX, azocyclotin + SX, bendiocarb + SX, benfluthrin + SX, benfuracarb + SX, bensultap + SX, bentiofluorin + SX, benzoic acid + SX, benzoximate + SX, benzpyrimoxan + SX, beta-cyfluthrin + SX, beta-cypermethrin + SX, Bifenazate + SX, bifenthrin + SX, bilobalide + SX, bioallethrin + SX, bioresmethrin + SX,Bistrifluron + SX, bisulfurfen + SX, borax + SX, boric acid + SX, broflanilide + SX, bromopropylate + SX, buprofezin + SX, butyric acid + SX, butocarboxim + SX, butoxycarboxim + SX, cadusafos + SX, calcium phosphide + SX, carbaryl + SX, carbofuran + SX, carbosulfan + SX, cartap hydrochloride + SX, Cartap + SX, chinomethionate + SX, chlorantraniliprole + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr + SX, chlorfenvinphos + SX, chlorfluazuron + SX, chlormephos + SX, chloropicrin + SX, chlorpyrifos + SX, chlorpyrifos-methyl + SX, chromafenozide + SX, citric acid + SX, clofentezine + SX, Clothianidin + SX, coumaphos + SX, cryolite + SX, cyanophos + SX,Cyantraniliprole + SX, cybenzoxasulfyl + SX, cyclaniliprole + SX, cyclobutrifluram + SX, cycloprothrin + SX, cycloxaprid + SX, cyenopyrafen + SX, cyetpyrafen + SX, cyflumetofen + SX, cyfluthrin + SX, cyhalodiamide + SX, cyhalothrin + SX, cyhexatin + SX, cypermethrin + SX, cyphenothrin + SX, cyproflanilide + SX, cyromazine + SX, dazomet + SX, deltamethrin + SX, demeton-S-methyl + SX, diafenthiuron + SX, diatomaceous earth + SX, diazinon + SX, dichlorvos + SX, dichloromezotiaz + SX, dicofol + SX, dicrotophos + SX, diflovidazin + SX, diflubenzuron + SX, dimefluthrin + SX Dimethoate + SX, dimethylvinphos + SX, dimpropyridaz + SX, dinotefuran + SX, disodium octaborate + SX,Disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, doramectin + SX, emamectin benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethiofencarb + SX, ethion + SX, ethiprole + SX, ethoprophos + SX, Etofenprox + SX, etoxazole + SX, famphur + SX, fenamiphos + SX, fenargimine + SX, fenazaquin + SX, fenbutatin oxide + SX, fenitrothion + SX, fenmezoditiaz + SX, fenobucarb + SX, fenoxycarb + SX, fenpropathrin + SX, fenpyroximate + SX, fenthion + SX, fentiazoluron + SX Fenvalerate + SX, fipronil + SX, flometoquin + SX, flonicamid + SX,Fluacrypyrim + SX, fluazaindolizine + SX, fluazuron + SX, flubendiamide + SX, fluchlordiniliprole + SX, flucycloxuron + SX, flucythrinate + SX, fluensulfone + SX, flufenprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flupentiofenox + SX, flupimezotiaz + SX, Flupyradifurone + SX, flupyrimin + SX, flupyroxystrobin + SX, fluralaner + SX, fluvalinate + SX, fluxametamide + SX, formetanate + SX, fosthiazate + SX, fumaric acid + SX, furamethrin + SX, furathiocarb + SX, gamma-cyhalothrin + SX, halfenprox + SX, halofenozide + SX, heptafluthrin + SX, Heptenophos + SX, hexaflumuron + SX, hexythiazox + SX, potassium salt of hop beta acid + SX,Hydramethylnon + SX, imicyafos + SX, imidacloprid + SX, imidaclothiz + SX, imiprothrin + SX, indazapyroxamet + SX, indoxacarb + SX, isocycloseram + SX, isofenphos + SX, isoflualanam + SX, isoprocarb + SX, isopropyl-O-(methoxyaminothiophosphoryl) salicylate + SX, isoxathion + SX, kadethrin + SX SX, kappa-tefluthrin + SX, kappa-bifenthrin + SX, lactic acid + SX, lambda-cyhalothrin + SX, lavandulyl senecioate + SX, ledprona + SX, lenoremycin + SX, lepimectin + SX, lime sulfur + SX, lotilaner + SX, lufenuron + SX, machine oil + SX, malathion + SX, malic acid + SX, mecarbam + SX, Meperfluthrin + SX, metaflumizone + SX, metam + SX, methamidophos + SX, methidathion + SX,Methiocarb + SX, methomyl + SX, methoxychlor + SX, methoxyfenozide + SX, methyl bromide + SX, metofluthrin + SX, metolcarb + SX, metoxadiazone + SX, mevinphos + SX, milbemectin + SX, milbemycin oxime + SX, mivorilaner + SX, modoflaner + SX, momfluorothrin + SX, monocrotophos + SX, moxidectin + SX Naled + SX, nicofluprole + SX, nicotine + SX, nicotine sulfate + SX, nitenpyram + SX, novaluron + SX, noviflumuron + SX, omethoate + SX, organic acid + SX, oxalic acid + SX, oxamyl + SX, oxazosulfyl + SX, oxydemeton-methyl + SX, Parathion + SX, parathion-methyl + SX, permethrin + SX, phenothrin + SX, phenthoate + SX, phorate + SX, phosalone + SX, phosmet + SX, phosphamidon + SX, phosphine + SX, phoxim + SX, pioxaniliprole + SX, piperflanilide + SX, pirimicarb + SX, pirimiphos-methyl + SX, prallethrin + SX, profenofos + SX, profluthrin + SX, propionic acid + SX, propargite + SX, propetamphos + SX, propoxur + SX, propylene glycol alginate + SX, prothiofos + SX, pyflubumide + SX, pymetrozine + SX, pyraclofos + SX, pyrethrins + SX, pyridaben + SX, pyridalyl + SX, pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + SX, Pyriminostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinalphos + SX,Resmethrin + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, sodium metaborate + SX, spidoxamat + SX, spinetoram + SX, spirobudifen + SX, spirodiclofen + SX, spiromesifen + SX, spiropidione + SX, spirotetramat + SX, sulfiflumin + SX, Sulfindoflufen + SX, sulfluramid + SX, sulfotep + SX, sulfoxaflor + SX, sulfoxamyl + SX, sulfur + SX, sulfuryl fluoride + SX, tartar emetic + SX, tartaric acid + SX, tau-fluvalinate + SX, tebufenozide + SX, tebufenpyrad + SX, tebupirimfos + SX, teflubenzuron + SX, tefluthrin + SX, temephos + SX, terbufos + SX, tetrachlorantraniliprole + SX, tetrachlorvinphos + SX, tetradifon + SX,Tetramethrin + SX, tetramethylfluthrin + SX, tetraniliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam + SX, thiocyclam + SX, thiodicarb + SX, thiofanox + SX, thiometon + SX, thiosultap disodium + SX, thiosultap monosodium + SX, tigolaner + SX, thioantraniliprole + SX, tioxazafen + SX, tolfenpyrad + SX, tralomethrin + SX, transfluthrin + SX, triazamate + SX, triazophos + SX, trichlorfon + SX, trifluenfuronate + SX, triflumezopyrim + SX, triflumuron + SX, trimethacarb + SX, trioxyflanilide + SX, tyclopyrazoflor + SX, umifoxolaner + SX, vadescana + SX, vamidothion + SX, vinylfluthrin + SX, XMC (3,5-dimethylphenyl N-methylcarbamate) + SX,Xylylcarb + SX, zeta-cypermethrin + SX, zinc phosphide + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-N-ethyl-3-(3,3,3-trifluoropropanesulfinyl)propanamide (1477923-37-7) + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, 2-({2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}imino)-3-(2,2,2-trifluoroethyl)-1,3-thiazolidin-4-one (1445683-71-5) + SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methanesulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methanesulfonyl)propanamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methanesulfonyl)propanamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09-3) + SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylsulfanyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfinyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfonyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7) + SX, 4-[5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5R)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5R)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4S)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4S)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, (S)-2-chloro-N-(3-ethylpentan-2-yl)furan-3-carboxamide + SX。,

[0055] Combination of this component of group (b) and this compound: Acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, aminotipyr + SX, amisulbrom + SX, anilazine + SX, azaconazole + SX, azoxystrobin + SX, basic copper sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, Benthiavalicarb-isopropyl + SX, benzovindiflupyr + SX, bifemetstrobin + SX, binapacryl + SX, biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin S + SX, Bordeaux mixture + SX, boscalid + SX, bromothalonil + SX, bromuconazole + SX, bupirimate + SX, captafol + SX, captan + SX, Carbendazim + SX, carboxin + SX, carmeconazole + SX, carpropamid + SX, chinomethionate + SX,Chlorinconazide + SX, chloroneb + ​​SX, chlorothalonil + SX, chlozolinate + SX, copper(II) acetate + SX, copper(II) hydroxide + SX, copper oxychloride + SX, copper(II) sulfate + SX, coumoxystrobin + SX, cyazofamid + SX, cyclobunofen + SX, cyflufenamid + SX, cymoxanil + SX, cyproconazole + SX, cyprodinil + SX, dichlobentiazox + SX, dichlofluanid + SX, diclocymet + SX, diclomezine + SX, dicloran + SX, diethofencarb + SX, difenoconazole + SX, diflumetorim + SX, dimethachlone + SX, dimethirimol + SX, dimethomorph + SX, dimoxystrobin + SX, diniconazole + SX, diniconazole-M + SX, dinocap + SX, dipotassium hydrogenphosphite + SX, dipymetitrone + SX, dithianon + SX,Dodecylbenzenesulphonic acid bisethylenediamine copper(II) salt + SX, dodemorph + SX, dodine + SX, edifenphos + SX, enoxastrobin + SX, enprocymid + SX, epoxiconazole + SX, etaconazole + SX, ethaboxam + SX, ethirimol + SX, etridiazole + SX, famoxadone + SX, fenamidone + SX, fenaminstrobin + SX, Fenarimol + SX, fenbuconazole + SX, feneptamidoquin + SX, fenfuram + SX, fenhexamid + SX, fenopyramide + SX, fenoxanil + SX, fenpiclonil + SX, fenpicoxamid + SX, fenpropidin + SX, fenpropimorph + SX, fenpyrazamine + SX, fentin acetate + SX, fentin chloride + SX, triphenyltin hydroxide + SX SX, ferbam + SX, ferimzone + SX, florylpicoxamid + SX, fluazinam + SX,Flubeneteram + SX, fludioxonil + SX, flufenoxadiazam + SX, flufenoxystrobin + SX, fluindapyr + SX, flumethylsulfonim + SX, flumorph + SX, fluopicolide + SX, fluopyram + SX, fluopimomide + SX, fluoroimide + SX, fluoxapiprolin + SX, fluoxastrobin + SX, fluoxytioconazole + SX, Fluquinconazole + SX, fluquinometoate + SX, flusilazole + SX, flusulfamide + SX, flutianil + SX, flutolanil + SX, flutriafol + SX, fluxapyroxad + SX, folpet + SX, fosetyl + SX, fosetylaluminium + SX, fuberidazole + SX, furalaxyl + SX, furametpyr + SX, galquin + SX, guazatine + SX, Hexaconazole + SX, hymexazole + SX, imazalil + SX, imibenconazole + SX, iminoctadine + SX,Iminoctadine triacetate + SX, iminoctadine albesilate + SX, inpyrfluxam + SX, iodocarb + SX, ipconazole + SX, ipfentrifluconazole + SX, ipflufenoquin + SX, iprobenfos + SX, iprodione + SX, iprovalicarb + SX, isofetamide + SX, isofleucine + SX, isofleucine + SX, isoprothiolane + SX, isopyrazam + SX, Isotianil + SX, kresoxim-methyl + SX, mancozeb + SX, mandestrobin + SX, mandipropamid + SX, maneb + ​​SX, mefentrifluconazole + SX, mepanipyrim + SX, mepronil + SX, meptyldinocap + SX, metalaxyl + SX, metalaxyl-M + SX, metarylpicoxamid + SX, metconazole + SX, metocyclofenstrobin + SX SX, methasulfocarb + SX, metiram + SX, metominostrobin + SX, metrafenone + SX,Methyltetraprole + SX, mineral oils + SX, myclobutanil + SX, naftifine + SX, nuarimol + SX, octhilinone + SX, ofurace + SX, orysastrobin + SX, oxadixyl + SX, oxathiapiprolin + SX, oxine-copper + SX, oxolinic acid + SX, oxpoconazole + SX, oxpoconazole fumarate + SX, oxycarboxin + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, penflufen + SX, penthiopyrad + SX, phenamacril + SX, phosphorous acid + SX, phthalide + SX, picarbutrazox + SX, picoxystrobin + SX, piperalin + SX, potassium hydrogencarbonate + SX, potassium dihydrogenphosphite + SX, probenazole + SX, prochloraz + SX, procymidone + SX, Propamidine + SX, propamocarb + SX,Propiconazole + SX, propineb + ​​SX, proquinazid + SX, prothiocarb + SX, prothioconazole + SX, pydiflumetofen + SX, pyraclostrobin + SX, pyrametostrobin + SX, pyraoxystrobin + SX, pyrapropoyne + SX, pyraziflumid + SX, pyrazophos + SX, Pyribencarb + SX, pyributicarb + SX, pyridaclomethyl + SX, pyrifenox + SX, pyrimethanil + SX, pyrimorph + SX, pyriophenone + SX, pyrisoxazole + SX, pyroquilon + SX, quinconazole + SX, quinofumelin + SX, quinoxyfen + SX, quintozene + SX, saccharin + SX, saccharin sodium + SX, saccharin potassium + SX, Saccharin calcium + SX, saccharin ammonium + SX, saccharin salt + SX, seboctylamine + SX, sedaxane + SX, silthiofam + SX, simeconazole + SX, sodium carbonate peroxhydrate + SX, sodium hydrogencarbonate + SX, spiroxamine + SX, sulfur + SX, tebuconazole + SX, tebufloquin + SX, teclofthalam + SX, tecnazene + SX, terbinafine + SX Tetraconazole + SX, Thiabendazole + SX,Thifluzamide + SX, thiophanate + SX, thiophanate-methyl + SX, thiram + SX, tiadinil + SX, tolclofos-methyl + SX, tolfenpyrad + SX, tolprocarb + SX, tolylfluanid + SX, triadimefon + SX, triadimenol + SX, triazoxide + SX, triclopyricarb + SX, tricyclazole + SX, tridemorph + SX, trifloxystrobin + SX, triflumizole + SX, triforine + SX, triticonazole + SX, validamycin + SX, valifenalate + SX, vinclozolin + SX, zinc thiazole + SX, zineb + ​​SX, ziram + SX, zoxamide + SX, 3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1R)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-48-7) + SX, 3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1S)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-49-8) + SX, 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide (141573-94-6) + SX, 3-(difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide (1513466-73-3) + SX, N'-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, N'-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylmethanimidamide (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylmethanimidamide (1052688-31-9) + SX, N'-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055589-28-9) + SX,N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055756-21-1) + SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylmethanimidamide (2062599-39-5) + SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N-methylmethanimidamide (2101814-55-3) + SX, N'-[5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylmethanimidamide (1817828-69-5) + SX, [4-(difluoromethoxy)phenyl]methyl 4-[(N-ethyl-N-methylamino)methylidene]amino-2,5-dimethylbenzoate + SX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, α-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229605-96-2) + SX, (αS)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-46-5) + SX, (αR)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-02-3) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R, 2S, 5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2) + SX, (1S, 2R, 5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol ( 1801930-07-3) + SX, (1R,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-53-8) + SX, (1S,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-54-9) + SX, (1R,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-55-0) + SX, (1S,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-56-1) + SX, (1R,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-57-2) + SX, (1S,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-58-3) + SX, methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (1791398-02-1) + SX, methyl (1R,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-90-2) + SX, methyl (1S,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-91-3) + SX, methyl (1R,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-92-4) + SX,methyl (1S,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-93-5) + SX, methyl (1R,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-94-6) + SX, methyl (1S,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-95-7) + SX, methyl (1R,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2081061-22-3) + SX, methyl (1S,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2081061-23-4) + SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6) + SX, (1R,2S,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4) + SX, (1S,2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) + SX, (1R,2R,3R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-08-4) + SX, (1S,2S,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-10-8) + SX, (1R,2R,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-13-1) + SX, (1S,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-16-4) + SX, (1R,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-20-0) + SX, (1S,2R,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-24-4) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-86-0) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018316-13-5) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX, methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8) + SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-33-8) + SX, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952305-97-3) + SX, 2-(difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, 2-(difluoromethyl)-N-[(3R)-3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952306-00-1) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) + SX, (2E,3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-54-3) + SX, 5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9) + SX, N-[(1S)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide + SX, N-[(1R)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide (2132414-06-1) + SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N,2-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N'-ethyl-N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-acetyl-2-(ethanesulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-28-9) + SX,3-(4-bromo-7-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromoindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX,3,3,3-trifluoro-N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butanamide + SX, N-methoxy-N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N-diethyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one + SX, 3,3-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 5-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, ethyl 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylate + SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N,N-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine + SX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + SX, 1-(2,3-dimethylpyridin-5-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-[2-(difluoromethyl)-3-methylpyridin-5-yl]-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 2,2-difluoro-N-[6-({[1-(1-methyl-1H-tetrazol-5-yl)benzimidazol-2-yl]oxy}methyl)pyridin-2-yl]-2-phenoxyacetamide + SX, 1-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile + SX, ethyl 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, ethyl 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX,6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide + SX, 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methylpropanoyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX,2-{[(oxetan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxolan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxan-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine + SX, 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(Z)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(Z)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(Z)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(Z)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[(Z)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, methyl ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinolin-4(3H)-one + SX, rel-N-[(1R,2R)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[(1S,2S)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[(1R,2R)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[2-(pyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2S)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2R)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-(2-{6-[(1E)-(methoxyimino)ethyl]pyridin-2-yl}-2-(1-methylpyrazol-4-yl)propyl)-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(5-methylpyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-dichlorophenyl)isoxazole-3-carboxamide + SX, methyl 6-(2-{[5-(2,4-difluorophenyl)isoxazole-3-carbonyl]amino}-1-methyl-1-(1-methylpyrazol-4-yl)ethyl)pyridine-3-carboxylate + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-3-(2,4-difluorophenyl)-1,2,4-oxadiazole-5-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(5-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,6-difluoropyridin-3-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,6-difluoropyridin-3-yl)-1,3,4-thiadiazole-2-carboxamide + SX, ethyl 1-[(4-{5-[chloro(difluoro)methyl]-1,2,4-oxadiazol-3-yl}-2-fluorophenyl)methyl]pyrazole-4-carboxylate + SX, ethyl 1-[(5-{5-[chloro(difluoro)methyl]-1,2,4-oxadiazol-3-yl}thiophen-2-yl)methyl]pyrazole-4-carboxylate + SX, 1-[(4-{5-[chloro(difluoro)methyl]-1,2,4-oxadiazol-3-yl}phenyl)methyl]-1,3-dimethoxyurea + SX, N-[(4-{5-[chloro(difluoro)methyl]-1,2,4-oxadiazol-3-yl}phenyl)methyl]-N,2-dimethoxypropanamide + SX, 2-(4-fluorophenoxy)-1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}ethanone + SX, 2-[(6-fluoropyridin-3-yl)oxy]-1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}ethanone + SX, 2-(4-fluoroanilino)-1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}ethanone + SX, 1-(4-{4-[5-(2,6-dichlorophenyl)-4,5-dihydroisoxazol-3-yl]thiazol-2-yl}piperidin-1-yl)-2-[3-(trifluoromethyl)pyrazin-2-yl]oxyethanone + SX, 1-(4-{4-[5-(2-chloro-6-fluorophenyl)-4,5-dihydroisoxazol-3-yl]thiazol-2-yl}piperidin-1-yl)-2-[3-(trifluoromethyl)pyridin-2-yl]oxyethanone + SX, tert-butyl 4-{4-[5-(2-bromo-6-fluorophenyl)-4,5-dihydroisoxazol-3-yl]thiazol-2-yl}piperidine-1-carboxylate + SX。,

[0056] Combination of this component of group (c) and this compound:1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 1,3,5-triazinane-2,4,6-trithione + SX, 2,3,5-triiodobenzoic acid + SX, IAA ((1H-indol-3-yl)acetic acid) + SX, IBA (4-(1H-indol-3-yl)butyric acid) + SX, MCPA (2-(4-chloro-2-methylphenoxy)acetic acid) + SX, MCPB (4-(4-chloro-2-methylphenoxy)butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat chloride + SX, chlorpropham + SX, choline chloride + SX, cloprop + SX, cyanamide + SX, cyclanilide + SX, cyprosulfamide + SX, daminozide + SX, Decane-1-ol + SX,Dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat + SX, ethephon + SX, ethychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, formononetin + SX, gibberellin A + SX, gibberellin A3 + SX, inabenfide + SX, kinetin + SX, lipochitooligosaccharide MOR116 + SX, lipochitooligosaccharide SP104 + SX SX, maleic hydrazide + SX, mefluidide + SX, mepiquat chloride + SX, methyl-alpha-D-mannopyranoside + SX, oxidized glutathione + SX, paclobutrazol + SX, pendimethalin + SX, prohexadione calcium + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, pyroglutamic acid + SX, sintophen + SX, sodium 1-naphthaleneacetate 1-naphthaleneacetate + SX, sodium cyanate + SX, thidiazuron + SX, titanium apatite + SX,Triapenthenol + SX, tribufos + SX, trinexapac-ethyl + SX, uniconazole-P + SX, 2-(naphthalen-1-yl)acetamide + SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid + SX, methyl 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylate + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol + SX, strigolactone + SX, (1E)-1-[[1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-5-oxo-2H-pyrrol-2-yl]oxymethylene]-3,3a,4,8b-tetrahydroindeno[2,1-b]pyrrol-2-one + SX, as described in WO 2018 / 145979; (2R)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one + SX, as described in WO 2018 / 145979; (2S)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one + SX, as described in WO 2018 / 145979.

[0057] Combinations of the present component and the present compound in group (d) above: Allidochlor + SX, benoxacor + SX, cloquintocet + SX, cloquintocet-mexyl + SX, cyometrinil + SX, cyprosulfamide + SX, dichlormid + SX, dicyclonone + SX, dimepiperate + SX, disulfoton + SX, dymron + SX, fenchlorazole + SX, fenchlorazole-ethyl + SX, fenclorim + SX, flurazole + SX, Furilazole + SX, fluxofenim + SX, hexim + SX, isoxadifen + SX, isoxadifen-ethyl + SX, Jiecaowan + SX, Jiecaoxi + SX, mecoprop + SX, mefenpyr + SX, mefenpyr-ethyl + SX, mefenpyr-diethyl + SX, mephenate + SX, metcamifen + SX, oxabetrinil + SX, 1,8-naphthalic anhydride + SX, Octane-1,8-diamine + SX, AD-67 (4-(dichloroacetyl)-1-oxa-4-azaspiro [4.5] decane) + SX, CL-304415 (4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) + SX, CSB (1-bromo-4-[(chloromethyl)sulfonyl]benzene) + SX, DKA-24 (2,2-dichloro-N-[2-oxo-2-(2-propenylamino)ethyl]-N-(2-propenyl)acetamide) + SX, MG191 (2-(dichloromethyl)-2-methyl-1,3-dioxolane) + SX, MG-838 (2-propenyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithioate) + SX, PPG-1292 (2,2-dichloro-N-(1,3-dioxan-2-ylmethyl)-N-(2-propenyl)acetamide) + SX, R-28725 (3-(dichloroacetyl)-2,2-dimethyl-1,3-oxazolidine) + SX, R-29148 (3-(dichloroacetyl)-2,2,5-trimethyl-1,3-oxazolidine) + SX, TI-35 (1-(dichloroacetyl)azepane) + SX。

[0058] Combination of this component of group (e) and this compound: 1-dodecyl-1H-imidazole + SX, N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide + SX, bucarpolate + SX, N,N-dibutyl-4-chlorobenzenesulfonamide + SX, dietholate + SX, diethylmaleate + SX, Jiajizengxiaolin + SX, octachlorodipropyl ether + SX, perbutin + SX, piperonyl butoxide butoxide + SX, piperonyl cyclonene + SX, piprotal + SX, propyl isome + SX, safroxan + SX, sesamex + SX, sesamolin + SX, sulfoxide + SX, verbutin + SX, DMC (1,1-bis(4-chloro) phenyl)ethanol) + SX, FDMC (1,1-bis(4-chlorophenyl)-2,2,2-trifluoroethanol) + SX, ETN (1,2-epoxy-1,2,3,4-tetrahydronaphthalene) + SX, ETP (1,1,1-trichloro-2,3-expoxypropane) + SX, PSCP (phenylsaligenin cyclic phosphate) + SX, TBPT (S,S,S-tributyl phosphorotrithioate) + SX, TPP (triphenyl phosphate) + SX.

[0059] Combinations of the present component and the present compound in group (f) above: Anthraquinone + SX, chloralose + SX, acrep + SX, butopyronoxyl + SX, camphor + SX, d-camphor + SX, carboxide + SX, dibutyl phthalate + SX, deet + SX, dimethyl carbate + SX, dimethyl phthalate + SX, dibutyl succinate + SX, dibutyl adipate + SX, ethohexadiol + SX, hexamide + SX, icaridin + SX, Methoquin-butyl + SX, methylneodecanamide + SX, 2-(octylthio)ethanol + SX, butoxypolypropylene glycol + SX, oxamate + SX, quwenzhi + SX, quyingding + SX, zengxiaon + SX, rebemide + SX, copper naphthenate + SX, zinc naphthenate + SX.

[0060] Combination of the present component and the present compound in group (g) above: Bis(tributyltin) oxide + SX, allicin + SX, bromoacetamide + SX, calcium arsenate + SX, cloethocarb + SX, copper sulfate + SX, fentin + SX, ferric phosphate + SX, metaldehyde + SX, niclosamide + SX, Paris green + SX, pentachlorophenol + SX, sodium ferric EDTA + SX, sodium pentachlorophenoxide + SX, tazimcarb + SX, Tralopyril + SX, tributyltin oxide + SX, trifenmorph + SX.

[0061] Combinations of the present component and the present compound in group (h) above: (4Z,7Z)-deca-4,7-dien-1-yl acetate + SX, (2E)-dec-2-en-1-ol + SX, (4Z)-dec-4-en-1-yl acetate + SX, (5Z)-dec-5-en-1-ol + SX, +-5Z a-ceta-1-dec (8Z)-dec-8-en-1-ol + SX, (7Z,13Z,16Z,19Z)-docosa-7,13,16,19-tetraen-1-ly isobutylate + SX, (7Z)-dodec-7-en-1-yl acetate + SX-,1-ol +8)-endo (8E)-dodec-8-en-1-yl acetate + SX, (8Z)-dodec-8-en-1-yl acetate + SX, (9E)-dodec-9-en-1-yl acetate + SX, (9Z)-dodec-9-en-1-yl acetate-Z3-Z-endo, (de (2E)-but-2-enoate + SX, (7E,9E)-dodeca-7,9-diene-1-yl acetate + SX, (7E,9Z)-dodeca-7,9-diene-1-yl acetate + SX, (7Z,9E)-dodeca-7,9-dien-te +1-yl (8E,10E)-dodeca-8,10-diene-1-ol + SX, (8E,10E)-dodeca-8,10-diene-1-yl acetate + SX, (6Z)-henicos-6-en-1-one + SX, (9Z)-hexadec-9-enal-9l- SX, + SX, (10Z)-hexadec-10-en-1-yl acetate + SX, (11Z)-hexadec-11-enal + SX, (11Z)-hexadec-11-en-1-ol + SX, (11Z)-hexadec-11-en-1-yl acetate (13Z)-hexadec-13-en-11-yn-1-yl acetate + SX, (7Z,11Z)-hexadeca-7,11-dienal + SX, (7E,11E)-hexadeca-7,11-dien-1-yl acetate + SX, (7E,11Z)-hexadeca-7,11-dien-1-yl acetate + SX, (7Z,11E)-hexadeca,ta-7,1-Xcel-dien (7Z,11Z)-hexadeca-7,11-dien-1-yl acetate + SX, (10E,12E)-hexadeca-10,12-dienal + SX, (11Z,13Z)-hexadeca-11,13-dienal + SX, (7Z,1caZ-37-Z + SX, (7Z,11Z,13E)-hexadeca-7,11,13-trienal + SX, (13Z)-icos-13-en-10-one + SX, (2E)-6-methylhept-2-en-4-ol + SX, (11Z)-ol-octadec,1-11 (11Z)-octadec-11-enal + SX, (13Z)-octadec-13-enal + SX, (2E,13Z)-octadeca-2,13-diene-1-ol + SX, (2E,13Z)-octadeca-2,13-dienete-1-1-yl acetate (2Z,13Z)-octadeca-2,13-diene-1-yl acetate + SX, (3E,13Z)-octadeca-3,13-diene-1-ol + SX, (3E,13Z)-octadeca-3,13-dien-1-yl acetate + SX, (3Z,13Z)-octadeca-3,13-dien-1-ol + SX, (3Z,13Z)-octadeca-3,13-diene-1-yl acetate + SX, (7Z)-tetradec-7-enal + SX, (7Z)-tetradec-1c-Z-7-en-X-en-9-ol + SX, (9Z)-tetradec-9-en-1-yl acetate + SX, (11Z)-tetradec-11-enal + SX,(11E)-tetradec-11-en-1-yl acetate + SX, (11Z)-tetradec-11-en-1-yl acetate + SX, (3E,8Z)-tetradeca-3,8-dien-1-yl acetate + SX, (4E,10Z)-tetradeca-4,10-dien-1-yl acetate + SX, (8E,10Z)-tetradeca-8,10-dienal + SX, (9E,11E)-tetradeca-9,11-dien-1-yl acetate + SX, (9Z,11E)-tetradeca-9,11-dien-1-yl acetate + SX, (9Z,12E)-tetradeca-9,12-dien-1-yl acetate + SX, (3E,8Z,11Z)-tetradeca-3,8,11-trien-1-yl acetate + SX, (9E)-tricos-9-ene + SX, (4E)-tridec-4-en-1-yl acetate + SX, (4Z)-tridec-4-en-1-yl acetate + SX, allyl isothiocyanate + SX, 4-allylanisole + SX, 3-carene + SX, (5R)-5-[(1Z)-dec-1-en-1-yl]dihydro-2(3H)-furanone + SX, (5R)-5-[(1Z)-dec-1-en-1-yl]dihydro-2(3H)-furanone + eugenol + 2-phenylethyl propionate + SX, (Z)-2-(3,3-dimethylcyclohexylidene)ethanol + SX, (4R,8R)-4,8-dimethyldecanal + SX, (4R,8S)-4,8-dimethyldecanal + SX, 2,4-dimethyl-5-ethyl-6,8-dioxabicyclo[3,2,1]octane + SX, 1,7-dioxaspiro[5,5]undecane + SX, dodecan-1-ol + SX, dodecyl acetate + SX, ethyl (2E,4Z)-deca-2,4-dienoate + SX, ethyl 4-methyloctanoate + SX, (2R,5R)-ethyl-1,6-dioxaspiro[4,4]nonane + SX, (2R,5S)-ethyl-1,6-dioxaspiro[4,4]nonane + SX, (E)-β-farnesene + SX, farnesyl alcohol + SX, ferrugineol + SX, geranyl hexanoate + SX, (E)-2-hexenyl butyrate + SX, (E)-2-hexenyl butyrate + hexyl butyrate + (E)-4-oxo-2-hexenal + SX, hexyl butyrate + SX, jasmone + SX, 3-ketopetromyzonol-24-sulfate ammonium salt + SX, methyl 2,6,10-trimethyldodecanoate + SX, methyl (2E,4E)-hepta-2,4-dienoate + SX, 2-methylbut-3-en-1-ol + SX, 2-(1-methyl-2-prop-1-en-2-ylcyclobutyl)ethanol + SX, 3-methylcyclohex-2-en-1-one + SX, (-)-4-methylheptan-3-ol + SX, 4-methylnonan-5-ol + SX, 4-methylnonan-5-one + SX, 14-methyloctadec-1-ene + SX, nepetalactone + SX, ocimene + SX, 1,2-octanediol + SX, oct-1-en-3-ol + SX, (R)-oct-1-en-3-ol + SX, olean + SX, 4-(3-oxobutyl)phenyl acetate + SX, (E)-4-oxo-2-hexenal + SX, pentacosane + SX, penta-termanone + SX, phenylacetaldehyde + SX, putrescine + SX, tetradecan-1-ol + SX,tetradecyl acetate + SX, tricosane + SX, tridecan-2-one + SX, 1,2,4-trimethoxybenzene + SX, trimethylamine + SX, trimethylamine hydrochloride + SX, 2-(undecyloxy)ethanol + SX, querciverol + SX, alpha-terpinene + SX, alpha-terpineol + SX, alpha-terpinoline + SX, animal tissue hydrolysate + SX, beet molasses-urea hydrolysate + SX, camphene + SX, capilure + SX, ceralure + SX, chalcogran + SX, codlerure + SX, codlemone + SX, copaene + SX, cosmolure + SX, cucujolide VIII + SX, cuelure + SX, cyclotene + SX, disparlure + SX, dominicalure + SX, endobrevicomin + SX, eugenol + SX, exitlure + SX, exobrevicomin + SX, farnesol + SX, ferrolure + SX, frontalin + SX, German cockroach pheromone + SX Gossyplure + SX, Gossyplure HF + SX,Grandlure + SX, Grandlure I + SX, Grandlure II + SX, Grandlure III + SX, Grandlure IV + SX, Hexalure + SX, Ipsdienol + SX, Ipsenol + SX, Japonilure + SX, Lavandin Oil + SX, Lineatin + SX, Litlue + SX, Looplure + SX, Medlure + SX, Megatomoic Acid + SX, Methyl Eugenol + SX Multistriatin + SX, Muscalure + SX, Nerolidol + SX, Orfralure + SX, Oryctalure + SX, Ostramone + SX, Peachflure + SX, Prodenialure B + SX, Rescalure + SX, Rhyncolure + SX, Siglure + SX, Sordidin + SX, Sulcatol + SX, Trimedlure + SX, Trimedlure A + SX, Trimedlure B1 + SX Trimedlure B2 + SX, trimedlure C + SX, trunc-call + SX, (E)-verbenol + SX, (Z)-verbenol + SX, trans-verbenol + SX,S-verbenone + SX.

[0062] Combinations of the present components of group (i) above with the present compounds: 2,3,6-TBA (2,3,6-trichlorobenzoic acid) + SX, 2,3,6-TBA-dimethylammonium + SX, 2,3,6-TBA-lithium + SX, 2,3,6-TBA-potassium + SX, 2,3,6-TBA-sodium + SX, 2,4-D + SX, 2,4-D choline salt + SX, 2,4-D-biproamine + SX, 2,4-D-doboxyl + SX, 2,4-D 2,4-D-2-ethylhexyl + SX, 2,4-D-3-butoxypropyl + SX, 2,4-D-ammonium + SX, 2,4-D-butotyl + SX, 2,4-D-butyl + SX, 2,4-D-diethylammonium + SX, 2,4-D-dimethylammonium + SX, 2,4-D-diolamine + SX, 2,4-D-dodecylammonium + SX, 2,4-D-ethyl + SX, 2,4-D-heptylammonium + SX, 2,4-D-isobutyl + SX, 2,4-D-isooctyl + SX, 2,4-D-isopropyl + SX, 2,4-D-isopropylammonium + SX, 2,4-D-lithium + SX, 2,4-D-meptyl + SX, 2,4-D-methyl4-D-methyl + SX, 2,4-D-octyl + SX, 2,4-D-pentyl + SX, 2,4-D-propyl + SX, 2,4-D-sodium + SX, 2,4-D-tefuryl + SX, 2,4-D-tetradecylammonium + SX, 2,4-D-triethylammonium + SX, 2,4-D-tris(2-hydroxypropyl)ammonium + SX, 2,4-D-trolamine + SX, 2,4-DB + SX, 2,4-DB choline salt + SX, 2,4-DB biproamine + SX, 2,4-DB butyl + SX, 2,4-DB dimethylammonium + SX, 2,4-DB isoctyl + SX, 2,4-DB potassium + SX, 2,4-DB sodium + SX, acetochlor + SX, acifluorfen + SX, acifluorfen sodium + SX, aclonifen + SX, ACN (2-amino-3-chloronaphthalene-1,4-dione) + SX, alachlor + SX, alloxydim + SX, ametryn + SX, amicarbazone + SX, amidosulfuron + SX, aminocyclopyrachlor + SX,Aminocyclopyrachlor-methyl + SX, aminocyclopyrachlor-potassium + SX, aminopyralid + SX, aminopyralid choline salt + SX, aminopyralid-potassium + SX, aminopyralid-tripromine + SX, amiprophos-methyl + SX, amitrole + SX, anilofos + SX, asulam + SX, atrazine + SX, azafenidin + SX, azimsulfuron + SX, beflubutamid + SX Benazolin-ethyl + SX, bencarbazone + SX, benfluralin + SX, benfuresate + SX, benquitrione + SX, bensulfuron + SX, bensulfuron-methyl + SX, bensulide + SX, bentazon + SX, benthiocarb + SX, benzfendizone + SX, benzobicyclon + SX, benzofenap + SX, benzthiazuron + SX, bialaphos + SX, Bicyclopyrone + SX, Bifenox + SX, Bipyrazone + SX, Bispyribac + SX,Bispyribac-sodium + SX, bixlozone + SX, bromacil + SX, bromobutide + SX, bromofenoxim + SX, bromoxynil + SX, bromoxynil octanoate + SX, butachlor + SX, butafenacil + SX, butamifos + SX, butroxydim + SX, butyrate + SX, cafenstrole + SX, carbetamide + SX, carfentrazone + SX, Carfentrazone-ethyl + SX, chlomethoxyfen + SX, chloramben + SX, chloridazon + SX, chlorimuron + SX, chlorimuron + SX, chlorimuron-ethyl + SX, chlorbromuron + SX, chlorotoluron + SX, chloroxuron + SX, chlorpropham + SX, chlorsulfuron + SX, chlorthal-dimethyl + SX, chlorthiamid + SX, cinflubrolin + SX, cinidon + SX, cinidon-ethyl + SX, Cinmethylin + SX, Cinosulfuron + SX, Clethodim + SX, Clodinafop + SX,Clodinafop-propargyl + SX, clomazone + SX, clomeprop + SX, clopyralid + SX, clopyralid choline salt + SX, clopyralid-methyl + SX, clopyralid-olamine + SX, clopyralid-potassium + SX, clopyralid-tris(2-hydroxypropyl)ammonium + SX, cloransulam + SX, cloransulam-methyl + SX, cumyluron + SX, cyanazine + SX, Cycloate + SX, cyclopyranil + SX, cyclopyrimorate + SX, cyclosulfamuron + SX, cycloxydim + SX, cyhalofop + SX, cyhalofop-butyl + SX, cypyrafluone + SX, dalapon + SX, dazomet + SX, desmedipham + SX, desmetryn + SX, di-allate + SX, dicamba + SX, dicamba choline salt + SX, dicamba-biproamine + SX, Dicambatrolamine + SX, Dicamba-diglycolamine + SX,Dicamba dimethylammonium + SX, dicamba diolamine + SX, dicamba isopropylammonium + SX, dicamba methyl + SX, dicamba olamine + SX, dicamba potassium + SX, dicamba sodium + SX, dichlobenil + SX, dichlorprop choline + SX, dichlorprop biproamine + SX, dichlorprop 2-ethylhexyl + SX, dichlorprop butotyl + SX, Dichlorprop-dimethylammonium + SX, dichlorprop-ethylammonium + SX, dichlorprop-isoctyl + SX, dichlorprop-methyl + SX, dichlorprop-P + SX, dichlorprop-P choline salt + SX, dichlorprop-P-biproamine + SX, dichlorprop-P-etexyl + SX, dichlorprop-P-dimethylammonium + SX, dichlorprop-potassium + SX, dichlorprop-sodium + SX, Diclofop + SX,Diclofop-methyl + SX, diclosulam + SX, difenoxuron + SX, difenzoquat + SX, difenzoquat methylsulfate + SX, Diflufenican + SX, diflufenzopyr + SX, diflufenzopyr sodium + SX, dimefuron + SX, dimepiperate + SX, dimepyrolimet + SX, dimesulfazet + SX, dimethachlor + SX, dimethametryn + SX, dimethenamid + SX, dimethenamid P + SX, dinitramine + SX, dinoseb + SX, dinoterb + SX Dioxopyritrione + SX, diphenamid + SX, diquat-dibromide + SX, disodium methylarsonate (DSMA) + SX, dithiopyr + SX, diuron + SX, 2-methyl-4,6-dinitrophenol (DNOC) + SX, epirifenacil + SX, esprocarb + SX, ethalfluralin + SX, ethametsulfuron + SX, ethametsulfuron-methyl + SX, ethidimuron + SX, ethofumesate + SX Ethoxyfen-ethyl + SX, ethoxysulfuron + SX, etobenzanid + SX, fendioxypyracil + SX, fenoxaprop + SX,Fenoxaprop-ethyl + SX, fenoxaprop-P + SX, fenoxaprop-P-ethyl + SX, fenoxasulfone + SX, fenpyrazone + SX, fenquinotrione + SX, fentrazamide + SX, fenuron + SX, feproxydim + SX, flamprop-M + SX, flazasulfuron + SX, florasulam + SX, florpyrauxifen + SX Florpyrauxifen-benzyl + SX, fluazifop + SX, fluazifop-butyl + SX, fluazifop-P + SX, fluazifop-P-butyl + SX, fluazolate + SX, flucarbazone + SX, flucarbazone-sodium + SX, flucetosulfuron + SX, fluchloraminopyr + SX, fluchloraminopyr-tefuryl + SX, flufenacet + SX, flufenauxirim + SX Flufenauxirim-metotyl + SX, Flufenazopyr + SX, Flufenoximacil + SX, Flufenpyr + SX, Flufenpyr-ethyl + SX,Flumetsulam + SX, Flumetsulam + SX, Flumiclorac + SX, Flumiclorac-pentyl + SX, Flumioxazin + SX, Fluometuron + SX, Fluoroglycofen-ethyl + SX, Flupoxam + SX, Flupropanate + SX, Flupyrsulfuron + SX, Flupyrsulfuron-methyl-sodium + SX, Flurenol + SX, Fluridone + SX, Flurochloridone + SX, Fluroxypyr + SX Fluroxypyr-butometyl + SX, Fluroxypyr-meptyl + SX, Flurtamone + SX, Flusulfinam + SX, Fluthiacet + SX, Fluthiacet-methyl + SX, Fomesafen + SX, Fomesafen sodium + SX, Foramsulfuron + SX, Fosamine + SX, Glufosinate + SX, Glufosinate-ammonium + SX, Glufosinate-P + SX Glufosinate-P-ammonium + SX, glufosinate-P-sodium + SX, glyphosate + SX,Glyphosate choline salt + SX, glyphosate-isopropylammonium + SX, glyphosate-biproamine + SX, glyphosate-ammonium salt + SX, glyphosate-diammonium salt + SX, glyphosate-potassium salt + SX, glyphosate-sodium salt + SX, glyphosate-trimesium + SX, halauxifen + SX, halauxifen-benzyl + SX, halauxifen-methyl + SX, halosafen + SX Halosulfuron + SX, halosulfuron-methyl + SX, haloxyfop + SX, haloxyfop-ethotyl + SX, haloxyfop-methyl + SX, haloxyfop-P + SX, haloxyfop-P-ethotyl + SX, haloxyfop-P-methyl + SX, hexazinone + SX, icafolin + SX, icafolin-methyl + SX, imazamethabenz + SX, imazamethabenz-methyl + SX, imazamox + SX, imazamox-ammonium + SX, imazamox-sodium + SX,Imazapic + SX, imazapic-ammonium + SX, imazapyr + SX, imazapyr-ammonium + SX, imazapyr-isopropylammonium + SX, imazaquin + SX, imazaquin-ammonium + SX, imazethapyr + SX, imazethapyr-ammonium + SX, imazosulfuron + SX, indanofan + SX, indaziflam + SX, indolauxipyr + SX, indolauxipyr-cyanomethyl + SX Iodosulfuron + SX, iodosulfuron-methyl-sodium + SX, iofensulfuron + SX, iofensulfuron-sodium + SX, ioxynil + SX, ioxynil-octanoate + SX, ipfencarbazone + SX, iptriazopyrid + SX, isoproturon + SX, isouron + SX, isoxaben + SX, isoxachlortole + SX, isoxafenacil + SX Isoxaflutole + SX, lactofen + SX, lenacil + SX, linuron + SX,Maleic hydrazide + SX, MCPA choline salt + SX, MCPA-biproamine + SX, MCPA-etexyl + SX, MCPA-butotyl + SX, MCPA-butyl + SX, MCPA-dimethylammonium + SX, MCPA-diolamine + SX, MCPA-ethyl + SX, MCPA-isobutyl + SX, MCPA-isoctyl + SX, MCPA-isopropyl + SX, MCPA-methyl + SX, MCPA-olamine + SX MCPA sodium salt (MCPA-sodium) + SX, MCPA trolamine salt (MCPA-trolamine) + SX, MCPB (4-(4-chloro-2-methylphenoxy)butanoic acid) + SX, MCPB choline salt + SX, MCPB-biproamine + SX, MCPB-ethyl + SX, MCPB-methyl + SX, MCPB sodium salt (MCPB-sodium) + SX, mecoprop choline salt + SX, mecoprop-biproamine + SX, mecoprop-2-ethylhexyl + SX, mecoprop-dimethylammonium + SX, mecoprop-diolamine + SX, mecoprop-ethadyl + SX,Mecoprop-isoctyl + SX, mecoprop-methyl + SX, mecoprop-potassium + SX, mecoprop-sodium + SX, mecoprop-trolamine + SX, mecoprop-P + SX, mecoprop-P choline + SX, mecoprop-P-2-ethylhexyl + SX, mecoprop-P-dimethylammonium + SX, mecoprop-P-isobutyl + SX, mecoprop-P-potassium + SX Mefenacet + SX, mesosulfuron + SX, mesosulfuron-methyl + SX, mesotrione + SX, metam + SX, metamifop + SX, metamitron + SX, metazachlor + SX, metazosulfuron + SX, methabenzthiazuron + SX, methiozolin + SX, methyldymron + SX, Metobromuron + SX, metolachlor + SX, metoxuron + SX, metosulam + SX, metproxybicyclone + SX, metribuzin + SX, metsulfuron + SX, metsulfuron-methyl + SX, molinate + SX, monolinuron + SX, naproanilide + SX, napropamide + SX, napropamide M + SX, naptalam + SX, neburon + SX Nicosulfuron + SX, norflurazon + SX, oleic acid + SX, orbencarb + SX, orthosulfamuron + SX, oryzalin + SX, oxadiargyl + SX, oxadiazon + SX, oxasulfuron + SX, oxaziclomefone + SX, oxyfluorfen + SX, paraquat + SX, paraquat-dichloride + SX, pebulate + SX, pelargonic acid + SX, pendimethalin + SX, penoxsulam + SX, pentanochlor + SX, pentoxazone + SX, pethoxamid + SX, phenisopham + SX,Phenmedipham + SX, picloram, picolinafen + SX, picolinafen + SX, pinoxaden + SX, piperophos + SX, pretilachlor + SX, primisulfuron + SX, primisulfuron-methyl + SX, prochlorosulfone + SX, prodiamine + SX, profluazol + SX, profoxydim + SX, prometon + SX, prometryn + SX, propachlor + SX, propanil + SX, Propaquizafop + SX, propazine + SX, propham + SX, propisochlor + SX, propoxycarbazone + SX, propoxycarbazone-sodium + SX, propyrisulfuron + SX, propyzamide + SX, prosulfocarb + SX, prosulfuron + SX, pyraclonil + SX, pyraquinate + SX, pyrasulfotole + SX, pyrazolynate + SX, pyrazosulfuron + SX, Pyrazosulfuron-ethyl + SX, pyrazoxyfen + SX, pyribenzoxim + SX,Pyributicarb + SX, pyridafol + SX, pyridate + SX, pyriflubenzoxim + SX, pyriftalid + SX, pyriminobac + SX, pyriminobac-methyl + SX, pyrimisulfan + SX, pyrithiobac + SX, pyrithiobac-sodium + SX, pyroxasulfone + SX, pyroxsulam + SX, quinclorac + SX, quinmerac + SX, quizalofop + SX, Quizalofop-ethyl + SX, quizalofop-tefuryl + SX, quizalofop-P + SX, quizalofop-P-ethyl + SX, quizalofop-P-tefuryl + SX, rimisoxafen + SX, rimsulfuron + SX, saflufenacil + SX, sethoxydim + SX, EPTC (S-ethyl N,N-dipropylcarbamothioate) + SX, siduron + SX, simazine + SX, simetryn + SX S-metolachlor + SX, MSMA (sodium hydrogen methylarsonate) + SX, sulcotrione + SX, sulfentrazone + SX, sulfometuron + SX,Sulfometuron methyl + SX, sulfosulfuron + SX, swep + SX, 2,2,2-trichloroacetic acid (TCA) + SX, ammonium TCA + SX, calcium TCA + SX, ethadyl TCA + SX, magnesium TCA + SX, sodium TCA + SX, tebutam + SX, tebuthiuron + SX, tefuryltrione + SX, tembotrione + SX, tepraloxydim + SX, terbacil + SX, terbumeton + SX SX, terbuthylazine + SX, terbutryn + SX, tetflupyrolimet + SX, thaxtomin A + SX, thenylchlor + SX, thiazopyr + SX, thidiazimine + SX, thiencarbazone + SX, thiencarbazone-methyl + SX, thifensulfuron + SX, thifensulfuron-methyl + SX, thifensulfuron + SX, thiafenacil + SX, tiocarbazil + SX, tolpyralate + SX, Topramezone + SX, toxapyzone + SX, tralkoxydim + SX, triafamone + SX, tri-allate + SX,Triasulfuron + SX, triaziflam + SX, tribenuron + SX, tribenuron-methyl + SX, triclopyr + SX, triclopyr-butotyl + SX, triclopyr-ethyl + SX, triclopyr-triethylammonium + SX, tridiphane + SX, trietazine + SX, trifloxysulfuron + SX, trifloxysulfuron-sodium + SX, trifludimoxazin + SX, trifluralin + SX, Triflusulfuron + SX, triflusulfuron-methyl + SX, tripyrasulfone + SX, tritosulfuron + SX, vernolate + SX, 4-(4-fluorophenyl)-6-[(2-hydroxy-6-oxo-1-cyclohexen-1-yl)carbonyl]-2-methyl-1,2,4-triazine-3,5(2H,4H)-dione + SX, 2-chloro-N-(1-methyl-1H-tetrazol-5-yl)-3-(methylthio)-4-(trifluoromethyl)benzamide + SX, 2-methyl-N-(5-methyl-1,3,4-oxadiazol-2-yl)-3-(methanesulfonyl)-4-(trifluoromethyl)benzamide + SX, 1-{2-chloro-6-[(5-chloropyrimidin-2-yl)oxy]phenyl}-4,4,4-trifluorobutan-1-one (2052297-97-7) + SX. ,

[0063] Combinations of the present component and the present compound in group (j) above:

[0064] Subgroup (j-1): Combination of the present bacterial component and the present compound: Acidovorax wautersii + SX, Agrobacterium radiobacter strain K1026 + SX, Agrobacterium radiobacter strain K84 + SX, Agrobacterium vitis strain VAR03-1 + SX, Arthrobacter globiformis + SX, Arthrobacter globiformis + Erwinia gerundensis + SX, Azorhizobium spp. + SX, Azorhizobium caulinodans strain ZB-SK-5 + SX, Azospirillum amazonense + SX, Azospirillum brasilense + SX, Azospirillum brasilense strain XOH + SX, Azospirillum brasilense strain Ab-V5 + SX, Azospirillum brasilense strain Ab-V6 + SX, Azospirillum caulinodans + SX, Azospirillum halopraeferens + SX Azospirillum irakense + SX, Azospirillum lipoferum + SX, Azotobacter + SX,Azotobacter chroococcum + SX, Azotobacter chroococcum strain H23 + SX, Azotobacter salinestris strain CECT9690 + SX, Azotobacter vinelandii strain ATCC12837 + SX, Bacillus acidocaldarius + SX, Bacillus acidoterrestris + SX, Bacillus agri + SX, Bacillus albolactis + SX Bacillus alcalophilus + SX, Bacillus alvei + SX, Bacillus aminoglucosidicus + SX, Bacillus aminovorans + SX, Bacillus amyloliquefaciens strain PTA-4838 (Aveo™ EZ nematicide) + SX, Bacillus amyloliquefaciens strain AH2 + SX, Bacillus amyloliquefaciens strain AT79 + SX, Bacillus amyloliquefaciens strain AT332 + SX, Bacillus amyloliquefaciens strain B3 + SX,Bacillus amyloliquefaciens strain BV03 + SX, Bacillus amyloliquefaciens strain CECT7657 + SX, Bacillus amyloliquefaciens strain D203 + SX, Bacillus amyloliquefaciens strain D747 + SX, Bacillus amyloliquefaciens strain DB101 + SX, Bacillus amyloliquefaciens strain DB102 + SX, Bacillus amyloliquefaciens strain ENV503 + SX, Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens strain FZB24 + SX, Bacillus amyloliquefaciens strain FZB42 + SX, Bacillus amyloliquefaciens strain GB03 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain IT-45 + SX, Bacillus amyloliquefaciens strain MBI600 + SX,Bacillus amyloliquefaciens strain R6-CDX + SX, Bacillus amyloliquefaciens isolate strain B246 + SX, Bacillus amyloliquefaciens subsp. Plantarum strain D747 + SX, Bacillus amylolyticus + SX, Bacillus aneurinolyticus + SX, Bacillus atrophaeus + SX, Bacillus atrophaeus strain Abi05 + SX, Bacillus azotoformans + SX, Bacillus badius + SX, Bacillus cereus strain Ar56 + SX, Bacillus cereus strain B4 + SX, Bacillus cereus strain BP01 + SX, Bacillus cereus strain bromelia + SX, Bacillus cereus strain CIL + SX, Bacillus cereus CNCM I-1562 + SX, Bacillus cereus strain DGA34 + SX cereus strain DGA34 + SX, Bacillus cereus strain N6 + SX, Bacillus cereus strain N7 + SX,Bacillus cereus strain peumo + SX, Bacillus cereus strain UW85 + SX, Bacillus chitinosporus strain AQ746 + SX, Bacillus chitinosporus strain CM-1 + SX, Bacillus circulans + SX, Bacillus coagulans strain TQ33 + SX, Bacillus fastidiosus + SX, Bacillus firmus strain GB-126 + SX, Bacillus firmus strain I-1582 + SX, Bacillus firmus strain NCIM2637 + SX, Bacillus lacticola + SX, Bacillus lactimorbus + SX, Bacillus lactis + SX, Bacillus lautus + SX, Bacillus lentimorbus + SX, Bacillus lentus + SX, Bacillus licheniformis strain copihue + SX, Bacillus licheniformis strain B000106 licheniformis strain B000106 + SX, Bacillus licheniformis strain DSM17236 + SX,Bacillus licheniformis strain FMCH001 + SX, Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 + SX, Bacillus maroccanus + SX, Bacillus medusa + SX, Bacillus megaterium strain ATCC10778 + SX, Bacillus megaterium strain NCIM2087 + SX, Bacillus megaterium strain YFM3.25 + SX megaterium strain YFM3.25 + SX, Bacillus methylotrophicus strain BAC-9912 + SX, Bacillus methylotrophicus strain C1 + SX, Bacillus methylotrophicus isolate UFPEDA20 + SX, Bacillus metiens + SX, Bacillus mojavensis strain R3 + SX, Bacillus mojavensis strain SR11 + SX, Bacillus mycoides strain AQ726 + SX, Bacillus mycoides isolate J + SX, Bacillus nematocida + SX, Bacillus nigrificans + SX,Bacillus nigrum + SX, Bacillus popilliae + SX, Bacillus psychrosaccharolyticus + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain CCTB05 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus strain QST2808 + SX, Bacillus safensis strain HCX-01 + SX, Bacillus siamensis strain KCTC 13613 + SX, Bacillus simplex strain CGF2856 + SX, Bacillus smithii + SX, Bacillus sp. strain AQ175 + SX, Bacillus sp. strain AQ177 + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b (Bacillus sphaericus strain AQ178) + SX, Bacillus sphaericus strain 2362 serotype H5a5b (Bacillus sphaericus strain AQ178) + SX, Bacillus sphaericus strain AQ175 + SX, Bacillus sp. strain AQ177 + SX, Bacillus sp. strain AQ178 ...7 + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b (Bacillus sphaericus strain AQ178) + SX, Bac 2362 serotype H5a5b) + SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus subtilis strain AFS032321 + SX, Bacillus subtilis strain antumavida + SX, Bacillus subtilis strain AP-01 + SX, Bacillus subtilis strain AQ153 + SX, Bacillus subtilis strain AQ743 + SX, Bacillus subtilis strain B246 + SX, Bacillus subtilis strain BU1814 + SX, Bacillus subtilis strain BV02 + SX, Bacillus subtilis strain BV09 + SX, Bacillus subtilis strain C-3102 + SX, Bacillus subtilis strain CCTB04 + SX, Bacillus subtilis strain CX-9060 + SX, Bacillus subtilis strain D747 + SX, Bacillus subtilis strain DB101 + SX, Bacillus subtilis strain DB102 + SX, Bacillus subtilis strain FMCH002 + SX,Bacillus subtilis strain FZB24 + SX, Bacillus subtilis strain GB03 + SX, Bacillus subtilis strain HAI0404 + SX, Bacillus subtilis strain IAB / BS03 + SX, Bacillus subtilis strain MBI600 + SX, Bacillus subtilis strain DSM17231 + SX, Bacillus subtilis strain N5 + SX, Bacillus subtilis strain NCIM2063 + SX, Bacillus subtilis strain NCIM8872 + SX, Bacillus subtilis strain NSRS89-24 + SX, Bacillus subtilis strain PAH17 + SX, Bacillus subtilis strain QST30002 / AQ30002 + SX, Bacillus subtilis strain QST30004 / AQ30004 + SX SX, Bacillus subtilis strain QST713 + SX, Bacillus subtilis strain QST714 + SX, Bacillus subtilis strain RTI477 + SX,Bacillus subtilis strain S1 + SX, Bacillus subtilis strain S2 + SX, Bacillus subtilis strain SEIBS23 + SX, Bacillus subtilis strain UFPEDA764 + SX, Bacillus subtilis strain Y1336 + SX, Bacillus subtilis strain YL13 + SX, Bacillus subtilis subsp. natto + SX, Bacillus subtilis var. Amyloliquefaciens strain FZB24 + SX, Bacillus tequilensis strain 10b + SX, Bacillus tequilensis strain NII-0943 + SX, Bacillus thuringiensis strain 4042 + SX, Bacillus thuringiensis strain anemophila + SX, Bacillus thuringiensis strain AQ52 + SX, Bacillus thuringiensis strain BD#32 + SX thuringiensis strain BD#32 + SX, Bacillus thuringiensis strain CR-371 + SX, Bacillus thuringiensis strain EX297512 + SX,Bacillus thuringiensis subsp. aizawai strain ABTS-1857 + SX, Bacillus thuringiensis subsp. aizawai strain GC-91 + SX, Bacillus thuringiensis subsp. aizawai strain NB200 + SX, Bacillus thuringiensis subsp. aizawai serotype H-7 + SX, Bacillus thuringiensis subsp. galleriae strain SDS-502 + SX, Bacillus thuringiensis subsp. israelensis strain AM65-52 + SX, Bacillus thuringiensis subsp. israelensis strain AM65-52 serotype H-14 + SX, Bacillus thuringiensis subsp. israelensis strain BMP144 + SX, Bacillus thuringiensis subsp. israelensis strain D142 + SX, Bacillus thuringiensis subsp. israelensis strain EG2215 + SX,Bacillus thuringiensis subsp. israelensis strain SA3A + SX, Bacillus thuringiensis subsp. israelensis strain SUM-6218 + SX, Bacillus thuringiensis subsp. israelensis strain VCRC B17 serotype 11-14 + SX, Bacillus thuringiensis subsp. japonensis + SX, Bacillus thuringiensis subsp. kurstaki CrylA delta endotoxins (Bacillus thuringiensis subsp. Kurstaki CrylA delta endotoxins + SX, Bacillus thuringiensis subsp. Kurstaki CrylC delta endotoxins + SX, Bacillus thuringiensis subsp. Kurstaki strain 3A3B + SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351 + SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123 + SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306 + SX thuringiensis subsp. Kurstaki strain CCT1306) + SX,Bacillus thuringiensis subsp. Kurstaki strain EG2348 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2371 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2424 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7673 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7826 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 + SX, Bacillus thuringiensis subsp. Kurstaki strain F810 + SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1 + SX, Bacillus thuringiensis subsp. Kurstaki strain M-200 + SX, Bacillus thuringiensis subsp. Kurstaki strain NCIM2514 + SX, Bacillus thuringiensis subsp. Kurstaki strain PB54 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12 + SX, Bacillus thuringiensis subsp. Kurstaki strain VBTS-2546 + SX, Bacillus thuringiensis subsp. Kurstaki strain Z-52, serotype H-3a, 3b + SX, Bacillus thuringiensis subsp. morrisoni + SX, Bacillus thuringiensis subsp. tenebriosis strain NB 176 + SX, Bacillus thuringiensis subsp. tenebriosis strain SA-10 + SX, Bacillus thuringiensis subsp. thuringiensis strain MPPL002 + SX MPPL002) + SX, Bacillus thuringiensis subsp. var. colmeri + SX,Bacillus thuringiensis subsp. var. darmstadiensis strain 24-91 + SX, Bacillus thuringiensis subsp. var. dendrolimus + SX, Bacillus thuringiensis subsp. var. galleriae + SX, Bacillus thuringiensis subsp. var. japonensis strain buibui + SX, Bacillus thuringiensis subsp. var. aegypti + SX, Bacillus thuringiensis var. 7216 + SX, Bacillus thuringiensis var. sandiego strain M-7 + SX, Bacillus thuringiensis var. T36 + SX, Bacillus velezensis + SX, Bacillus velezensis isolate CNPSo3602 + SX, Bacillus velezensis strain ABi19 + SX, Bacillus velezensis strain FZB42 + SX, Bacillus velezensis strain FZB45 + SX, Bacillus velezensis strain NRRL B-41580 + SX,Bacillus velezensis strain RTI301 + SX, Bradyrhizobium spp. + SX, Bradyrhizobium elkanii + SX, Bradyrhizobium elkanii strain SEMIA 587 + SX, Bradyrhizobium elkanii strain SEMIA 5019 + SX, Bradyrhizobium japonicum + SX, Bradyrhizobium japonicum strain TA-11 + SX SX, Bradyrhizobium japonicum strain USDA 110 + SX, Bradyrhizobium japonicum strain WB74 + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Bradyrhizobium lupini strain LL13 + SX, Bradyrhizobium spp. (Arachis) + SX, Bradyrhizobium spp. (Vigna) + SX, Brevibacillus brevis strain maguellines I + SX, Brevibacillus brevis strain 2904 + SX, Brevibacillus brevis strain SS86-3 + SX,Brevibacillus brevis strain SS86-4 + SX, Brevibacillus brevis strain SS86-5 + SX, Brevibacillus laterosporus strain ATCC64 + SX, Brevibacillus laterosporus strain BPM3 + SX, Brevibacillus laterosporus strain G4 + SX, Brevibacillus laterosporus strain NCIMB 41419 + SX, Brevibacillus laterosporus strain NRS1111 + SX, Brevibacillus laterosporus strain NRS1645 + SX, Brevibacillus laterosporus strain NRS1647 + SX, Burkholderia ambifaria strain AMMD + SX, Burkholderia cenocepacia strain A396 + SX, Burkholderia cenocepacia strain Ral-3 + SX, Burkholderia cepacia type Wisconsin strain J82 + SX, Burkholderia cepacia type Wisconsin strain M54 + SX,Burkholderia cepacia + SX, Burkholderia gladii strain BA-7 + SX, Burkholderia rinojensis strain A396 + SX, Chromobacterium subtsugae strain PRAA4-1T + SX, Corynebacterium flavescens strain B2575 + SX, Corynebacterium glutamicum + SX, Delftia acidovorans + SX, Delftia acidovorans strain RAY209 acidovorans strain RAY209 + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, Erwinia gerundensis + SX, Gluconacetobacter diazotrophicus strain IMI504853 + SX, Klebsiella variicola 137 + SX, Kosakonia cowanii strain SYM00028 + SX, Lactobacillus acidophilus + SX, Lactobacillus brevis + SX, Lactobacillus casei strain LPT-111 + SX, Lactobacillus plantarum + SX,Lactobacillus spp. + SX, Lysobacter antibioticus strain 13-1 + SX, Lysobacter enzymogenes strain B25 + SX, Lysobacter enzymogenes strain C3 + SX, Metylobacterium spp. + SX, Methylobacterium isolate ISO01 + SX, Methylobacterium isolate ISO02 + SX, Methylobacterium isolate ISO03 + SX, Methylobacterium isolate ISO04 + SX, Methylobacterium isolate ISO07 + SX, Methylobacterium isolate ISO09 + SX, Methylobacterium isolate ISO10 + SX, Methylobacterium isolate ISO11 + SX, Methylobacterium symbioticum + SX, Mesorhizobium spp. + SX, Mesorhizobium ciceri + SX, Mesorhizobium huakii + SX, Mesorhizobium loti + SX, Paenibacillus alvei strain 2771 + SX,Paenibacillus alvei strain 46C3 + SX, Paenibacillus alvei strain III2E + SX, Paenibacillus alvei strain III3DT-1A + SX, Paenibacillus alvei strain T36 + SX, Paenibacillus macerans + SX, Paenibacillus polymyxa strain AC-1 + SX, Paenibacillus polymyxa strain BS-0105 + SX, Paenibacillus polymyxa strain H-5 + SX, Paenibacillus popilliae + SX, Pantoea agglomerans strain E325 + SX, Pantoea vagans strain C9-1 + SX, Pasteuria nishizawae strain Pn1 + SX, Pasteuria penetrans + SX, Pasteuria ramose + SX, Pasteuria usgae + SX, Pectobacterium carotovorum + SX, Pasteuria thornei + SX, Pseudomonas aeruginosa strain PN1 + SX, Pseudomonas aeruginosa strain WS-1 + SX, Pseudomonas aureofaciens strain TX-1 TX-1 + SX, Pseudomonas alcaligenes + SX, Pseudomonas cepacia type Wisconsin strain J82 + SX,Pseudomonas cepacia type Wisconsin strain M54 + SX, Pseudomonas chlororaphis strain 63-28 + SX, Pseudomonas chlororaphis strain AFS009 + SX, Pseudomonas chlororaphis strain MA342 + SX, Pseudomonas entomophila strain 1257 + SX, Pseudomonas fluorescens isolate Pf-5 + SX, Pseudomonas fluorescens strain 1629RS + SX, Pseudomonas fluorescens strain A506 + SX, Pseudomonas fluorescens strain ACK55 + SX, Pseudomonas fluorescens strain CL145A + SX, Pseudomonas fluorescens strain D7 + SX, Pseudomonas fluorescens strain G7090 + SX, Pseudomonas fluorescens biover B XJ3 + SX Pseudomonas fluorescens biover B strain XJ3 + SX, Pseudomonas fluorescens biover B strain XS18 + SX,Pseudomonas fluorescens biover A strain LRS12 + SX, Pseudomonas proradix + SX, Pseudomonas putida strain CECT8538 + SX, Pseudomonas reactans + SX, Pseudomonas resinovorans + SX, Pseudomonas rhodesiae strain HAI-0804 + SX, Pseudomonas sp. strain CAB-02 + SX, Pseudomonas sp. DSMZ13134 + SX sp. strain DSMZ13134 + SX, Pseudomonas syringae strain 742RS + SX, Pseudomonas syringae strain ESC-10 + SX, Pseudomonas syringae strain ESC-11 + SX, Pseudomonas syringae strain MA-4 + SX, Pseudomonas trivialis + SX, Rhizobium etli + SX, Rhizobium galegae + SX, Rhizobium leguminosarum bv. Phaseoli (Rhizobium leguminosarum bv. Phaseoli) + SX, Rhizobium leguminosarum bv. Trifolii + SX,Rhizobium leguminosarum bv. Viciae + SX, Rhizobium trifolii + SX, Rhizobium tropici + SX, Rhodococcus globerulus strain AQ719 + SX, Saccharopolyspora spinosa + SX, Serratia entomophila strain 626 + SX, Serratia marcescens strain 35 + SX, Serratia marcescens strain SRM + SX, Serratia nematodiphila strain S-CSR-0024 + SX, Sphingobacterium nematocida strain ZY-71-1 + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti + SX, Streptomyces acidiscabies strain RL-110T + SX, Streptomyces candidus strain Y21007-2 + SX, Streptomyces colombiensis + SX, Streptomyces galbus strain QST6047 + SX, Streptomyces globosus strain LZH-48 + SX,Streptomyces goshikiensis + SX, Streptomyces griseofuscus strain 200101 + SX, Streptomyces griseoviridis strain K61 + SX, Streptomyces jalisciencis isolate CM-CNRG0001 + SX, Streptomyces jofer isolate CM-CNRG0002 + SX, Streptomyces lavendulae + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYEC108 + SX, Streptomyces microflavus strain AQ6121 + SX, Streptomyces prasinus + SX, Streptomyces rimosus + SX, Streptomyces saraceticus + SX, Streptomyces sp. strain NRRL No. B-30145 + SX, Streptomyces sp. strain WYE20 + SX, Streptomyces sp. strain WYE 324 + SX, Streptomyces venezuelae + SX,Thiobacillus spp. + SX, Variovorax paradoxus strain GF4526 + SX, Virgibacillus pantothenticus strain ATCC14576 + SX, Virgibacillus pantothenticus strain DSM491 + SX, Wolbachia pipientis + SX, Xanthomonas campestris pv poae + SX, Xanthomonas campestris + SX, Xenorhabdus luminescens + SX, Xenorhabdus nematophila + SX,

[0065] Subgroup (j-2): Combination of this compound with the component of fungi and yeast Acaulospora spp. + SX, Acaulospora longula + SX, Alternaria destruens + SX, Alternaria destruens strain 59 + SX, Ambispora spp. + SX, Ambispora leptoticha + SX, Ampelomyces quisqualis strain AQ10 + SX, Ampelomyces quisqualis strain RSAQ7690 + SX, Ampelomyces quisqualis strain M-10 + SX SX, Archaeospora spp. + SX, Arkansas Fungus 18 + SX, Arthrobotrys dactyloides + SX, Arthrobotrys superba + SX, Aschersonia aleyrodis + SX, Aspergillus flavus strain AF36 + SX, Aspergillus flavus strain MUCL54911 + SX, Aspergillus flavus strain NRRL21882 + SX, Aureobasidium pullulans strain DSM14940 + SX, Aureobasidium pullulans strain DSM14941 + SX,Aureobasidium pullulans strain YBCA5 + SX, Beauveria bassiana isolate B21 + SX, Beauveria bassiana isolate B33 + SX, Beauveria bassiana isolate CBMAI1306 + SX, Beauveria bassiana strain 147 + SX, Beauveria bassiana strain 203 + SX, Beauveria bassiana strain 447 + SX, Beauveria bassiana strain ANT-03 ANT-03 + SX, Beauveria bassiana strain ATCC74040 + SX, Beauveria bassiana strain ATP02 + SX, Beauveria bassiana strain CFL-A + SX, Beauveria bassiana strain CG716 + SX, Beauveria bassiana strain ESALQ PL63 + SX, Beauveria bassiana strain GHA + SX, Beauveria bassiana strain HF23 + SX, Beauveria bassiana strain IBCB66 + SX, Beauveria bassiana strain IMI389521 + SX,Beauveria bassiana strain J25 + SX, Beauveria bassiana strain NCIM1216 ATCC26851 + SX, Beauveria bassiana strain NPP111B005 + SX, Beauveria bassiana strain PL63 + SX, Beauveria bassiana strain PPRI 5339 + SX, Beauveria bassiana strain R444 + SX, Beauveria bassiana strain ZJU435 + SX ZJU435 + SX, Beauveria brongniartii + SX, Beauveria brongniartii isolate IMBST95.031 + SX, Beauveria brongniartii isolate IMBST95.041 + SX, Candida oleophila strain O + SX, Candida oleophila isolate I-182 + SX, Candida saitoana + SX, Candida spp. + SX, Cell walls of Saccharomyces cerevisiae strain LAS117 + SX, Chaetomium cupreum + SX, Chlorella + SX, Chondrostereum purpureum + SX,Cladosporium cladosporioides strain H39 + SX, Claroideoglomus spp. (formerly Glomus spp.) + SX, Claroideoglomus claroideum (formerly Glomus claroideum) + SX, Claroideoglomus etunicatum (formerly Glomus etunicatum) + SX, Claroideoglomus luteum + SX, Clonostachys rosea strain ACM941 + SX, Clonostachys rosea strain CR-7 CR-7 + SX, Clonostachys rosea strain IDAC 040913-01 + SX, Clonostachys rosea strain J1446 + SX, Colletotrichum gloeosporioides + SX, Conidiobolus obscurus + SX, Conidiobolus thromboide + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON / M / 91-08 CON / M / 91-08) + SX, Cryphonectria parasitica + SX, Cryptococcus albidus + SX,Cryptococcus flavescens + SX, Cylindrobasidium laeve + SX, Dactyllela ellipsospora + SX, Decylaria thaumasia + SX, Dilophosphora alopecuri + SX, Diversispora spp. + SX, Enterococcus faecium + SX, Entomophthora virulenta + SX, Entrophospora spp. + SX, Entyloma ageratinae ageratinae + SX, Epicoccum nigrum + SX, Funneliformis spp. (formerly Glomus spp.) + SX, Funneliformis mosseae (formerly Glomus mosseae) + SX, Fusarium oxysporum strain Fo47 + SX, Fusarium oxysporum strain RS-21 + SX, Fusarium oxysporum strain RS-25 + SX, Fusarium proliferatum strain NCIM1101 + SX, Geosiphon spp. + SX, Gigaspora spp. + SX, Gigaspora margarita + SX, Gigaspora rosea + SX,Gliocladium catenulatum strain J1446 + SX, Gliocladium roseum + SX, Gliocladium virens strain GL-21 + SX, Glomus spp. + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus etunicatum + SX, Glomus iranicum + SX, Glomus monosporum + SX, Hirsutella minnesotensis minnesotensis + SX, Hirsutella rhossiliensis + SX, Hirsutella thompsonii + SX, Isaria fumosorosea isolate B3 + SX, Isaria fumosorosea strain Isfm-CPF + SX, Isaria tenuipes + SX, Laccaria bicolor + SX, Laccaria laccata + SX, Lagenidium giganteum + SX, Lecanicillium lecanii KV01 + SX, Lecanicillium lecanii conidia of strain DAOM198499 + SX, Lecanicillium lecanii conidia of strain DAOM216596 + SX,Lecanicillium muscarium strain 1 / 1 (formerly Verticillium lecanii strain 1 / 1) + SX, Lecanicillium muscarium strain Ve6 (formerly Verticillium lecanii strain Ve6) + SX, Metarhizium anisopliae isolate D1 + SX, Metarhizium anisopliae isolate IBCB425 + SX, Metarhizium anisopliae strain CQMa421 + SX, Metarhizium anisopliae strain ESALQ E9 + SX, Metarhizium anisopliae strain ESF1 + SX, Metarhizium anisopliae strain F52 + SX, Metarhizium anisopliae strain FI-985 anisopliae strain FI-985 + SX, Metarhizium anisopliae strain FI-1045 + SX, Metarhizium anisopliae strain ICIPE30 + SX, Metarhizium anisopliae strain ICIPE62 + SX, Metarhizium anisopliae strain ICIPE69 + SX, Metarhizium anisopliae strain ICIPE78 + SX, Metarhizium anisopliae strain NCIM1311 NCIM1311) + SX, Metarhizium anisopliae var. acridum strain EVCH077) + SX,Metarhizium anisopliae var. acridum isolate IMI 330189 + SX, Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52 + SX, Metarhizium brunneum strain Cb15-III + SX, Metarhizium flavoviride strain F001 + SX, Metarhizium rileyi strain PHP1705 + SX, Metschnikowia fructicola strain NRRLY-27328 + SX, Metschnikowia fructicola strain NRRLY-30752 + SX, Microdochium dimerum strain L13 + SX, Microsphaeropsis ochracea + SX, Monacrosporium phymatopagum + SX, Mucor hiemalis + SX, Muscodor albus strain 620 + SX, Muscodor albus QST Muscodor albus strain QST 20799 + SX, Muscodor albus strain SA13 + SX, Muscodor roseus strain A3-5 + SX,Myrothecium verrucaria strain AARC-0255 + SX, Nomuraea rileyi strain CG128 + SX, Nomuraea rileyi strain GU87401 + SX, Nomuraea rileyi strain SA86101 + SX, Nomuraea rileyi strain SR86151 + SX, Nomuraea rileyi strain VA9101 + SX, Ophiostoma piliferum strain D97 + SX SX, Pacispora spp. + SX, Paecilomyces fumosoroseus Apopka strain 97 (now known as Isaria fumosorosea Apopka strain 97) + SX, Paecilomyces fumosoroseus strain FE9901 (now known as Isaria fumosorosea strain FE9901) + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain T1 T1) + SX, Paecilomyces variotii strain Q-09 + SX, Pandora delphacis + SX, Paraglomus spp. + SX,Paraglomus brasilianum (formerly Glomus brasilianum) + SX, Penicillium bilaiae strain ATCC22348 + SX, Penicillium citrinum strain VFI-51 + SX, Penicillium vermiculatum + SX, Phlebiopsis gigantea strain FOC PG410.3 + SX, Phlebiopsis gigantea strain VRA1835 + SX, Phlebiopsis gigantea strain VRA1984 + SX, Phlebiopsis gigantea strain VRA1985 + SX, Phlebiopsis gigantea strain VRA1986 + SX, Phlebiopsis gigantea strain VRA1992 + SX, Phlebiopsis spp. + SX, Phoma macrostroma strain 94-44B + SX, Phytophthora palmivora + SX, Pichia anomala strain WRL-076 + SX, Pichia guilliermondii strain Z1 + SX, Pichia guilliermondii strain Z8 + SX, Pisolithus tinctorius + SX,Pochonia chlamydosporia isolate strain PC10 + SX, Pochonia chlamydosporia + SX, Pseudozyma flocculosa strain ATTC64874 + SX, Pseudozyma flocculosa strain PF-A22UL + SX, Puccinia thlaspeos strain woad + SX, Purpureocillium lilacinum strain 251 + SX, Purpureocillium lilacinum strain PL11 + SX PL11) + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Racocetra spp. + SX, Rhizophagus spp. (formerly Glomus spp.) + SX, Rhizophagus clarus (formerly Glomus clarum) + SX, Rhizophagus intraradices (formerly Glomus intraradices) + SX, Rhizophagus intraradices strain RTI-801 + SX, Rhizophagus irregularis Rhizophagus irregularis (formerly Glomus intraradices) + SX, Rhizophagus irregularis strain DAOM 197198 + SX,Scutellospora spp. + SX, Rhizopogon amylopogon + SX, Rhizopogon fulvigleba + SX, Rhizopogon luteolus + SX, Rhizopogon villosullus + SX, Saccharomyces cerevisiae strain LAS02 + SX, Saccharomyces cerevisiae strain DDSF623 + SX, Saccharomyces cerevisiae strain SP.1026 + SX, Scleroderma cepa + SX, Scleroderma citrinum + SX, Sclerotinia minor strain IMI34414 + SX, Sporothrix insectorum + SX, Suillus granulatus + SX, Suillus punctatapies + SX, Talaromyces flavus strain SAY-Y-94-01 + SX, Talaromyces flavus strain V117b + SX, Trichoderma afroharzianum afroharzianum + SX, Trichoderma album + SX, Trichoderma asperelloides strain JM41R + SX,Trichoderma asperellum strain CBMAI840 + SX, Trichoderma asperellum strain CBMAI1622 + SX, Trichoderma asperellum strain BV09 + SX, Trichoderma asperellum strain BV10 + SX, Trichoderma asperellum strain ICC012 + SX, Trichoderma asperellum strain kd + SX, Trichoderma asperellum strain M103 + SX, Trichoderma asperellum strain RNCIM F-1323 + SX, Trichoderma asperellum strain T11 + SX, Trichoderma asperellum strain T25 + SX, Trichoderma asperellum strain T34 + SX, Trichoderma asperellum strain SKT-1 + SX, Trichoderma asperellum strain TV1 + SX, Trichoderma atroviride strain 77B + SX, Trichoderma atroviride strain CNCM 1-1237 + SX, Trichoderma atroviride strain I-1237 + SX, Trichoderma atroviride strain IMI 206040 + SX, Trichoderma atroviride strain K4 + SX, Trichoderma atroviride strain LC52 + SX, Trichoderma atroviride Trichoderma atroviride strain LU132 + SX, Trichoderma atroviride strain SC1 + SX, Trichoderma atroviride strain SKT-1 + SX, Trichoderma atroviride strain T11 + SX, Trichoderma atroviride strain TV1 + SX, Trichoderma atroviride strain WW10TC4 + SX, Trichoderma gamsii strain ICC080 + SX, Trichoderma harmatum strain 382 + SX, Trichoderma harmatum strain TH382 + SX, Trichoderma harzianum strain 21 + SX,Trichoderma harzianum strain AP-001 + SX, Trichoderma harzianum strain BK-Th001 + SX, Trichoderma harzianum strain CBS101525 + SX, Trichoderma harzianum strain DB 104 + SX, Trichoderma harzianum strain DSM 14944 + SX, Trichoderma harzianum strain ESALQ-1303 + SX, Trichoderma harzianum strain ESALQ-1306 + SX, Trichoderma harzianum strain F11Bab + SX, Trichoderma harzianum strain Gomorteka + SX, Trichoderma harzianum strain IB19 / 17 + SX, Trichoderma harzianum strain IBLF006 + SX, Trichoderma harzianum strain IIHR-Th-2 + SX Trichoderma harzianum strain ITEM908 + SX, Trichoderma harzianum strain K2 + SX, Trichoderma harzianum strain kd + SX,Trichoderma harzianum strain KRL-AG2 + SX, Trichoderma harzianum strain MO1 + SX, Trichoderma harzianum strain queule + SX, Trichoderma harzianum strain RR17Bc + SX, Trichoderma harzianum strain SF + SX, Trichoderma harzianum strain T5 + SX, Trichoderma harzianum strain T22 + SX, Trichoderma harzianum strain T24 + SX harzianum strain T24 + SX, Trichoderma harzianum strain T39 + SX, Trichoderma harzianum strain T78 + SX, Trichoderma harzianum strain TH35 + SX, Trichoderma harzianum strain TH315 + SX, Trichoderma harzianum rifai + SX, Trichoderma koningii + SX, Trichoderma lignorum strain TL-0601 + SX SX, Trichoderma lignorum + SX, Trichoderma longibrachiatum strain T-397 + SX,Trichoderma polysporum strain IMI206039 + SX, Trichoderma parceramosum + SX, Trichoderma reesei + SX, Trichoderma strain SKT-1 + SX, Trichoderma spp. + SX, Trichoderma saturnisporium strain PBP-TH-001 + SX, Trichoderma stromaticum + SX, Trichoderma virens strain chagual + SX, Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 (formy Gliocladium virens GL-21) + SX, Trichoderma virens strain nire + SX, Trichoderma virens strain sherwood + SX, Trichoderma viride strain (NRRL B-50520) + SX, Trichoderma viride strain K5 + SX, Trichoderma viride strain T111 + SX Tsukamurella paurometabola strain C-924 + SX, Tsukamurella paurometabola + SX,Typhula phacorrhiza strain 94671 + SX, Ulocladium oudemansii strain HRU3 + SX, Ulocladium oudemansii strain U3 + SX, Verticillium alboatrum strain WCS850 + SX, Verticillium chlamydosporium + SX, Verticillium dahliae + SX, Verticillium lecanii strain ID05-F0117 + SX, Verticillium lecanii strain NCIM1312 + SX, Verticillium lecanii strain SZWL7 + SX, Zoophtora radicans + SX.

[0066] Subgroup (j-3): Combination of the present component of protozoa with the present compound: Nosema locustae + SX, Thelohania solenopsis + SX, Vairimorpha spp. strain Q-09 + SX.

[0067] Subgroup (j-4): Combination of this component of the virus with this compound: Adoxophyes orana granulovirus BV-0001 (GV (granulovirus) strain BV-0001) + SX, Agrotis segetum nucleopolyhedrovirus NPV (nucleopolyhedrovirus) + SX, Anagraoha falcifera NPV (NPV) + SX, Anticarsia gemmatalis MNPV (multiple nucleocapsid nucleopolyhedrovirus) + SX, Autographa californica MNPV strain FV11 (MNPV) + SX, Autographa californica MNPV strain R3 (MNPV) + SX SX, Bacteriophage of Clavibacter michiganesis + SX, Bacteriophage active against Clavibacter michiganensis subsp. michiganensis + SX, Bacteriophage active against Erwinia amylovora + SX, Bacteriophage active against Pseudomonas syringae pv. tomato + SX, Bacteriophage active against Xanthomonas campestris pv. vesicatoria + SX, Bacteriophage active against Xanthomonas citri subsp. citri + SX, Bacteriophage against Xylella fastidiosa + SX, Biston suppressaria NPV + SX, Bombyx mori NPV + SX,Chrysodeixis includens nucleopolyhedrovirus isolate 460 + SX, Cryptophlebia leucotreta granulosis virus (GV) + SX, Cydia pomonella granulosis virus (GV) + SX, Cydia pomonella granulosis virus M (GV M) + SX, Cydia pomonella granulosis virus CP4 (GV strain CP4) + SX, Cydia pomonella granulosis virus R5 (GV strain R5) + SX, Cydia pomonella granulosis virus V15 (GV strain V15) + SX Cydia pomonella granulosis virus V22 + SX, Douglas fir tussock moth NPV + SX, Dendrolimus punctatus cypovirus + SX, Ectropis obliqua picorna-like virus + SX, Helicoverpa armigera NPV + SX, Helicoverpa armigera NPV strain BV-0003 + SX, Helicoverpa zea NPV + SX, Indian meal moth granulosis virus GV) + SX, Leucoma salicis NPV + SX, Lymantria dispar MNPV + SX, Mamestra brassicae NPV + SX,Mamestra configurata nucleopolyhedrosis virus (NPV) + SX, Neodiprion abietis nucleopolyhedrosis virus (NPV) + SX, Neodiprion lecontei nucleopolyhedrosis virus (NPV) + SX, Neodiprion sertifer nucleopolyhedrosis virus (NPV) + SX, Orgyia pseudotsugata nucleopolyhedrosis virus (NPV) + SX, pepino mosaic virus strain CH2 isolate 1906 + SX, pepino mosaic virus strain CH2 isolate Abp1 + SX Pepino mosaic virus strain CH2 isolate Abp2 + SX, Pepino mosaic virus isolate VC1 + SX, Pepino mosaic virus isolate VX1 + SX, Phthorimaea operculella GV isolate DSMZ GV-0019 + SX, Pieris rapae GV + SX, Plodia interpunctella GV + SX, Plutella xylostella GV + SX Spodoptera albula MNPV + SX, Spodoptera exempta MNPV + SX,Spodoptera exigua MNPV strain BV-0004 + SX, Spodoptera frugiperda MNPV + SX, Spodoptera littoralis MNPV isolate DSMZ BV-0005 + SX, Spodoptera litura NPV + SX, Tobacco mild tobamovirus strain U2 + SX, Zucchini Yellow Mosaic Virus weak strain + SX.

[0068] Subgroup (j-5): Combination of the present component of nematodes and the present compound: Abreviata caucasica + SX, Acuaria spp. + SX, Agamermis decaudata + SX, Allantonema spp. + SX, Amphimermis spp. + SX, Deladenus siricidicola + SX, Bovienema spp. + SX, Cameronia spp. + SX, Chitwoodiella ovofilamenta + SX, Contortylenchus spp. + SX, Culicimermis spp. + SX, Diplotriaena spp. + SX, Empidomermis spp. + SX, Filipjevimermis leipsandra + SX, Gastromermis spp. + SX, Gongylonema spp.) + SX, Gynopoecilia pseudovipara + SX, Heterorhabditis bacteriophora + SX, Heterorhabditis baujardi + SX, Heterorhabditis downesi + SX, Heterorhabditis heliothidis + SX, Heterorhabditis indica + SX, Heterorhabditis marelatus + SX, Heterorhabditis megidis + SX, Heterorhabditis zealandica zealandica + SX, Hexamermis spp. + SX, Hydromermis spp. + SX, Isomermis spp. + SX, Limnomermis spp. + SX, Maupasina weissi + SX, Mermis nigrescens + SX, Mesomermis spp. + SX, Neomesomermis spp. + SX, Neoparasitylenchus rugulosi + SX, Octomyomermis spp. spp.) + SX, Parasitaphelenchus spp.) + SX, Parasitorhabditis spp.) + SX, Parasitylenchus spp.) + SX, Perutilimermis culicis + SX, Phasmarhabditis hermaphrodita isolate DDT M1 + SX, Physaloptera spp. + SX, Protrellatus spp. + SX, Pterygodermatites spp. + SX, Romanomermis spp. + SX, Seuratum cadarachense + SX, Sphaerulariopsis spp. + SX, Spirura guianensis + SX, Steinernema bibionis + SX, Steinernema carpocapsae + SX, Steinernema feltiae isolate DDT D2 + SX, Steinernema glaseri + SX, Steinernema indica + SX, Steinernema kraussei + SX, Steinernema riobrave + SX, Steinernema scapterisci + SX, Steinernema scarabaei + SX, Steinernema siamkayai + SX, Steinernema thailandse + SX, Steinernema spp.) + SX, Strelkovimermis peterseni + SX, Subulura spp. + SX, Sulphuretylenchus elongatus + SX, Tetrameres spp. + SX.

[0069] Subgroup (j-6): Combination of the present component of natural products and the present compound: (2S,3R,4R,5S)-2,5-bis(hydroxymethyl)pyrrolidine-3,4-diol + SX, 1,4-dimethylnaphthalene + SX, 2-methyl-1-butanol + SX, 2-phenylethyl propionate + SX, 9,21-didehydroryanodine + SX, alizarin 2-glucoside + SX, dihydroazadirachtin + SX, ethyl 3-[acetyl(butyl)amino]propanoate + SX, glycerol monocaprate + SX, glycerol monocaprylate + SX, glycerol monolaurate + SX, heptyl butyrate + SX, methyl anthranilate + SX, methyl nonyl ketone + SX, methyl Salicylate + SX, N-(3-methyl-2-buten-1-yl)-9H-purin-6-amine + SX, N,N'-diformylurea + SX, octanal + SX, oxypurinol + SX, p-cymene + SX, p-menthane-3,8-diol + SX, phenazine-1-carboxylic acid + SX, propylene glycol monocaprylate + SX, propylene glycol monolaurate + SX, sorbitol octanoate + SX, sucrose octanoate + SX, terpinen-4-ol + SX, balsam of fir oil (Abies balsamea oil) + SX, α-ionone + SX, β-citronellol + SX, gamma-Terpinene + SX, ammonium bicarbonate + SX, anabasine + SX, anise oil + SX,Ascaridole + SX, azadirachtin + SX, Celastrus angulatus bark + SX, Brassica juncea (mustard) + SX, brassinolide + SX, Bacillus thuringiensis Cry1Ab protein + SX, Bacillus thuringiensis Cry1Ac protein + SX, Bacillus thuringiensis Cry1Fa protein + SX, Bacillus thuringiensis Cry1A.105 protein + SX, Bacillus Cry2Ab protein from Bacillus thuringiensis (Bacillus thuringiensis Cry2Ab protein) + SX, Vip3A protein from Bacillus thuringiensis (Bacillus thuringiensis Vip3A protein) + SX, mCry3A protein from Bacillus thuringiensis (Bacillus thuringiensis mCry3A protein) + SX, Cry3Ab protein from Bacillus thuringiensis (Bacillus thuringiensis Cry3Ab protein) + SX, Cry3Bb protein from Bacillus thuringiensis (Bacillus thuringiensis Cry3Bb protein) + SX,Bacillus thuringiensis Cry34Ab1 / Cry35Ab1 protein + SX, insecticidal protein Tma12 derived from the fern Tectaria macrodonta + SX, insecticidal protein IPD083 derived from the fern Adiantum spp. + SX, insecticidal protein IPD113 derived from the fern Pteris cretica cv. albolineata or Pteris umbrosa + SX, calcium acetate + SX, calcium lactate + SX, calcium polysulfide + SX, canola oil + SX, capsaicin + SX, capsicum oleoresin + SX, castor oil + SX, cedarwood oil + SX, cevadine + SX, chitin + SX, chitosan + SX, chlorophyllin + SX, chlortetracycline + SX, cinerin I + SX, cinerin II + SX, cinnamaldehyde + SX, cis-jasmone + SX, citral + SX, citric acid + SX,Citronella oil + SX, Citrus bergamia fruit oil + SX, clarified hydrophobic extract of neem oil + SX, clove oil + SX, collagen protein hydrolysate + SX, colletochlorin B + SX, concanamycin A + SX, cottonseed oil + SX, cytokinin + SX, cow's milk + SX, deguelin + SX, diallyl sulfide + SX, d-limonene + SX, dried leaves of Dryopteris filix-mas + SX, Ea peptide 91398 + SX, eucalyptol + SX, black wattle extract (extract of Acacia mearnsii) + SX, Achillea fragrantissima extract (extract of Achillea fragrantissima) + SX, onion extract (extract of Allium cepa) + SX, garlic extract (extract of Allium sativum) + SX, dill extract (extract of Anethum graveolens) + SX, sugar apple extract (extract of Annona squamosa) + SX, burdock extract (extract of Arctium lappa) + SX, wormwood extract (extract of Artemisia absinthium) + SX, jackfruit extract (extract of Artocarpus heterophyllus) + SX,Neem extract (extract of Azadirachta indica) + SX, Calendula extract (extract of Calendula officinalis) + SX, Tea plant extract (extract of Camelia sinensis) + SX, Capsicum annuum extract (extract of Capsicum annuum) + SX, Cassia nigricans extract (extract of Cassia nigricans) + SX, Chenopodium ambrosioides extract (extract of Chenopodium quinoa) + SX, Cinnamon extract (extract of Cinnamomum verum) + SX, Clitoria ternatea extract (extract of the cotyledons of lupine plantlets ("BLAD")) + SX, Daphne gnidium extract (extract of Daphne gnidium) + SX, extract of Equisetum arvense + SX, extract of Equisetum giganteum + SX, extract of Galenia africana + SX, extract of green tea + SX, extract of Liliaceae plant Liliaceae) + SX, extract of Macleaya + SX, extract of Matricaria chamomilla + SX, extract of Melaleuca alternifolia + SX, extract of Millettia pinnata + SX,Opuntia lindheimeri extract (extract of Opuntia lindheimeri) + SX, Oregano extract (extract of Origanum vulgare) + SX, Piper auritum extract (extract of Piper auritum) + SX, Pyrethrum extract (extract of Pyrethrum), Southern red oak extract (extract of Quercus falcata) + SX, Quillaja extract (extract of Quillaja saponaria) + SX, Giant knotweed extract (extract of Reynoutria sachalinensis) + SX, Siebold tree extract (extract of Rhamnus utilis) + SX, Sumac extract (extract of Rhus aromatica) + SX, Rheum officinale extract (extract of Rhizophora mangle) + SX, Rosemary extract (extract of Rosmarinus officinalis + SX, Ruta chalepensis extract + SX, Sabadilla seed extract + SX, Sweet lupin seed extract + SX, Swinglea glutinosa extract + SX, Comfrey extract + SX, Sweet lupinseed extract + SX, Tagetes erecta extract + SX, Tansy extract + SX, Thymus vulgaris extract + SX,Nasturtium extract (Tropaeolum majus extract) + SX, Stinging nettle extract (Urtica dioica extract) + SX, Mistletoe extract (Viscum album extract) + SX, Yucca schidigera extract (Yucca schidigera extract) + SX, Fenugreek seed powder + SX, Fish oil + SX, Formic acid + SX, Geraniol + SX, Ginkgolide A + SX, Ginkgolide B + SX, Ginkgolide C + SX, Ginkgolide J + SX, Ginkgolide M + SX, Gougerotin + SX GS-omega / kappa HXTX-Hv1a peptide + SX, Harpin protein + SX, hydrogenated castor oil + SX, hydroprene + SX, Illicium verum oil + SX, ivermectin + SX, jasmolin I + SX, jasmolin II + SX, jojoba oil + SX, karanjin + SX, kasugamycin + SX, kinoprene + SX, laminarin + SX, L-ascorbic acid + SX, Oak leaves and bark of Quercus + SX, Lemongrass oil + SX, L-glutamic acid + SX, Linalool + SX,Linseed oil + SX, alyssum (Lobularia maritima) + SX, lysophosphatidylethanolamine + SX, maltodextrin + SX, matrine + SX, matrine N-oxide + SX, menthol + SX, methoprene + SX, Milbemycin A4 + SX, Mildiomycin + SX, Natamycin + SX, Nemadectin + SX, Nepeta cataria oil + SX, Nootkatone + SX, Chenopodium anthelminticum seed oil + SX, Orange oil + SX, Pelargonium odoratissimum oil + SX, Pellitorine + SX, Piperine + SX, Piper nigrum seed oil + SX, Polyoxin B + SX, Polyoxorim + SX Potassium phosphonate + SX, potassium silicate + SX, precocene II + SX, putrescent whole egg solids + SX, pyrethrin I + SX, pyrethrin II + SX, quillaja extract + SX, quinaminoprole + SX, rotenone + SX, rapeseed oil + SX, rhamnolipid + SX, ryanodine + SX, rosemary oil + SX, sabadilla + SX, salicylic acid + SX Sanguinarine + SX, Saponins of Chenopodium quinoa + SX, Sesame oil + SX,Soy lecithin + SX, soybean oil + SX, spinosad + SX, squamocin + SX, streptomycin + SX, sunflower oil + SX, marigold oil + SX, terpene constituents of the extract of chenopodium ambrosioides near ambrosioides (Brand name: Terpenoid blend QRD 460) + SX, thyme oil + SX, thymol + SX, trypsin modulating oostatic factor + SX, veratrine + SX, veratridine + SX, Surinamese oak wood extract Extract of Quassia amara + SX, Xanthine + SX, Yellow mustard powder + SX.

[0070] Subgroup (j-7): Combination of the present component of insects with the present compound: Adalia bipunctata + SX, Amitus hesperidum + SX, Amitus spiniferus + SX, Anagrus atomus + SX, Anagrus epos + SX, Anagyrus fusciventris + SX, Anagyrus fusciventris + SX, Anagyrus pseudococci + SX, Anaphes flavipes + SX, Anaphes iole + SX, Anaphes nitens + SX, Anastatus tenuipes + SX, Anthocoris nemoralis + SX, Aphelinus abdominalis + SX, Aphelinus asychis + SX, Aphelinus mali + SX, Aphelinus semiflavus + SX, Aphidius colemani + SX, Aphidius ervi + SX, Aphidius gifuensis + SX, Aphidius matricariae + SX, Aphidius smithi + SX, Aphidius aphidimyza + SX, Aphytis holoxanthus + SX, Aphytis lepidosaphes + SX, Aphytis lignanensis + SX, Aphytis melinus + SX, Aphytis mytilaspidis + SX, Apion fuscirostre + SX, Apion ulicis + SX, Aprostocetus hagenowii + SX, Avetianella longoi + SX, Bangasternus orientalis + SX, Bathyplectes anurus + SX, Bathyplectes curculionis + SX, Bracon cushmani + SX,Bracon gelechiae + SX, Bracon hebetor + SX, Cales noacki + SX, Calosoma sycophanta + SX, Carcinops pumillio + SX, Catolaccus grandis + SX, Cephalonomia tarsalis + SX, Chilocorus baileyi + SX, Chilocorus bipustulatus + SX, Chilocorus circumdatus + SX, Chilocorus kuwanae + SX, Chilocorus nigritus + SX, Chilocorus stigma + SX, Chrysoperla carnea + SX, Chrysoperla rufilabris + SX, Clitostethus arcuatus + SX, Coccidoxenoides perminutus + SX, Coccophagus cowperi + SX, Coccophagus lycimnia + SX, Coenosia attenuata + SX, Coleomegilla maculata + SX, Comperia merceti + SX, Comperiella bifascita + SX, Copidosoma floridanum + SX, Copidosoma truncatellum + SX, Cotesia flavipes + SX, Cotesia glomerata + SX, Cotesia marginiventris + SX, Cotesia medicaginis + SX, Cotesia melanoscela + SX, Cotesia plutellae + SX, Cotesia ruficrus + SX, Cryptolaemus montrouzieri + SX, Cybocephalus nipponicus + SX,Dacnusa sibirica + SX, Dalotia coriaria + SX, Delphastus catalinae + SX, Delphastus pusillus + SX, Dendrolimus punctatus + SX, Deraeocoris brevis + SX, Diaeretiella rapae + SX, Dicyphus hesperus + SX, Diglyphus isaea + SX, Encarsia aurantii + SX, Encarsia formosa + SX, Encarsia inaron + SX, Encarsia opulenta + SX, Encarsia perplexa + SX, Ephedrus cerasicola + SX, Episyrphus balteatus + SX, Eretmocerus eremicus + SX SX, Eretmocerus mundus + SX, Feltiella acarisuga + SX, Franklinothrips megalops + SX, Franklinothrips orizabensis + SX, Franklinothrips vespiformis + SX, Geocoris punctipes + SX, Glyptapanteles liparidis + SX, Goniozus legneri + SX, Harmonia axyridis + SX, Hippodamia convergens + SX, Hyposoter exiguae + SX, Hyposoter fugitivus + SX, Lariophagus distinguendus + SX, Leptomastidea abnormis + SX, Leptomastix algirica + SX, Leptomastix dactylopii + SX,Leptomastix epona + SX, Lydella thompsoni + SX, Lysiphlebus testaceipes + SX, Macrocentrus ancylivorus + SX, Macrocentrus iridescens + SX, Macrolophus pygmaeus + SX, Mallada signata + SX, Metaphycus bartletti + SX, Metaphycus californicus + SX, Metaphycus flavus + SX, Metaphycus funicularis + SX, Metaphycus helvolus + SX, Metaphycus luteolus + SX, Metaphycus stanleyi + SX, Meteorus autographae + SX, Meteorus laphygmae + SX, Meteorus pulchricornis + SX, Meteorus trachynotus + SX, Metoecus paradoxus + SX, Microctonus aethiopoides + SX, Red-bellied toad (Micromus angulatus) + SX, Micromus tasmaniae + SX, Micromus variegatus + SX, Microplitis brassicae + SX, Microplitis plutellae + SX, Microterys flavus + SX, Muscidifurax raptor + SX, Muscidifurax raptorellus + SX, Nabis kinbergii + SX, Necremnus artynes ​​+ SX, Neochrysocharis formosa + SX, Neodryinus typhlocybae + SX, Nesidiocoris tenuis + SX, Orius albidipennis + SX, Orius armatus + SX, Orius insidiosus + SX, Orius laevigatus + SX,Orius majusculus + SX, Orius niger + SX, Orius strigicollis + SX, Orygia pseudotsugata + SX, Pediobius foveolatus + SX, Pentalitomastix plethorica + SX, Pnigalio flavipes + SX, Podisus maculiventris + SX, Praon volucre + SX, Pseudaphycus maculipennis + SX, Psyllaephagus pilosus + SX, Rhapalosiphum padi + SX, Rhizophagus grandis + SX, Rhyzobius forestieri + SX, Rhyzobius lophantae + SX, Bedariia tentacles (Rodolia cardinalis) + SX, Scolothrips sexmaculatus + SX, Serangium parcesetosum + SX, Spalangia cameroni + SX, Spalangia endius + SX, Stethorus punctillum + SX, Sympiesis stigmata + SX, Telenomus podisi + SX, Tenodera sinensis + SX, Tetrastichus brevistigma + SX, Tetrastichus gallerucae + SX, Tetrastichus howardi + SX, Tetrastichus setifer + SX, Thripobius semiluteus + SX, Torymus sinensis + SX, Trichogramma achaeae + SX, Trichogramma brassicae + SX, Trichogramma evanescens + SX, Trichogramma minutum + SX, Trichogramma ostriniae + SX, Trichogramma platneri + SX,Trichogramma pretiosum + SX, Trichogramma semifumatum + SX, Trichogrammatoidea bactrae + SX, Trichopoda pennipes + SX, Trioxys complanatus + SX, Trioxys curvicaudus + SX, Trioxys pallidus + SX, Trioxys tenuicaudus + SX, Trissolcus bathos + SX, Vairimorpha necatrix + SX, Volucella inanis + SX, Voria ruralis + SX, Squid (Xylocoris flavipes) + SX, Zelus renardii + SX.

[0071] Material (j-8): Details and designs of the fish: Amblydromalus limonicus + SX, Amblyseius andersoni + SX, Amblyseius barkeri + SX, Amblyseius californicus + SX, Amblyseius cucumeris + SX, Amblyseius degenerans + SX, Amblyseius montdorensis + SX, Amblyseius swirskii + SX, Amblyseius womersleyi + SX, Anystis agilis + SX, Cheyletus eruditus + SX, Euseius gallicus + SX, Euseius stipulatus + SX, Euseius tularensis + SX, Gaeolaelaps gillespiei + SX, Galendromus annectens + SX, Galendromus helveolus + SX, Galendromus occidentalis + SX, Hypoaspis aculeifer + SX, Hypoaspis miles + SX, Macrocheles robustulus + SX, Mesoseiulus longipes + SX, Neoseiulus fallacis + SX, Phytoseiulus macropilis + SX, Phytoseiulus persimilis + SX, Thyreophagus entomophagus + SX, Typhlodromus pyri + SX。

[0072] Subgroup (j-9): Combination of the main component of mollusks and this compound: Rumina decollata + SX。

[0073] The component selected from group (j) is usually prepared by a method known in the art. For example, in the case of (j-1) bacteria or (j-2) fungi and yeast, it is prepared using a medium and a fermentation method known in the art. When the component is (j-1) bacteria or (j-2) fungi and yeast, the preparation is prepared at a concentration of 10×10 per 1 g. 4 ~1×10 13 CFU (colony forming units), preferably 1 x 10 8 ~1×10 12 If the component is a (j-4) virus, the preparation contains 1 x 10 CFU per gram. 4 ~1×10 13 Occlurion bodies (sometimes referred to as Obs), preferably 1 × 10 8 ~1×10 12 The ingredient contains occlurion bodies (sometimes referred to as Obs). If the ingredient is (j-5) nematodes, the preparation contains 1 x 10 4 ~1×10 13 Individual, preferably 1 x 10 8 ~1×10 12 Contains solid components.

[0074] This compound can be mixed with or used in combination with chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.).

[0075] The weight ratio of the application amount of the present compound to the application amount of the present component in Composition A is not particularly limited, and can be appropriately adjusted to an optimal weight ratio depending on the type of plant to be protected, the type and frequency of occurrence of harmful arthropods, harmful nematodes, harmful mollusks, plant pathogenic microorganisms or weeds to be controlled, the formulation form, application time, application method, application location, weather conditions, etc. For example, in the agricultural field, when applied to plants (particularly, stems and leaves, seeds, and vegetative reproductive organs) or to a cultivation carrier for cultivating plants (particularly, soil), the following weight ratios can be mentioned. The weight of the present component selected from group (j) refers to the weight of the preparation. For example, a weight ratio of 1:500 means that the application amount of the preparation of one or more components selected from group (j) is 500 parts by weight per 1 part by weight of the present compound.

[0076] Weight ratio [(this compound):(this component)] = 1:10^15 to 10^15:1, specifically, for example, approximately 1:10^15, 1:10^14, 1:10^13, 1:10^12, 1:10^11, 1:10^10, 1:10^9, 1:10^8, 1:10^7, 1:10^6, 1:10^5, 1:10000, 1:9000, 1:8000, 1:7000, 1:6000, 1:5000, 1:4000, 1:3000, 1:2000, 1:1000, 1:900, 1:800, 1:700, 1:600, 1:500 , 1:400, 1:350, 1:300, 1:250, 1:200, 1:150, 1:100, 1:90, 1:80, 1:70, 1:60, 1:50, 1:40, 1:30, 1:20, 1:19, 1:18, 1:17, 1:16, 1:15, 1:14, 1:13, 1:12, 1:11, 1:10, 1:9, 1:8, 1:7, 1:6, 1:5, 2:9, 1:4, 2:7, 3:10, 1:3, 3:8, 2:5, 3:7, 4:9, 1:2, 5:9, 4:7, 3:5, 5:8, 2:3, 7:10, 5:7, 3:4, 7:9, 4:5, 5:6, 6:7, 7:8, 8:9, 9:10, 1:1, 10:9, 9:8, 8:7, 7:6, 6:5, 5:4, 9:7, 4:3, 7:5, 10:7, 3:2, 8:5, 5:3, 7:4, 9:5, 2:1, 9:4, 7:3, 5:2, 8:3, 3:1, 10:3, 7:2, 4:1, 9:2, 5:1, 6:1, 7:1, 8:1, 9:1, 10:1, 11:1, 12:1, 13:1, 14:1, 15:1, 16:1, 17:1, 18:1, 19:1, 20:1, 30:1, 40:1, 50:1, 60:1, 70:1 , 80:1, 90:1, 100:1, 150:1, 200:1, 250:1, 300:1, 400:1, 500:1, 600:1, 700:1, 800:1, 900:1, 1000:1, 2000:1, 3000:1, 4000:1, 5000:1, 6000:1, 7000:1, 8000:1, 9000:1, 10000:1, 10^5:1, 10^6:1, 10^7:1, 10^8:1, 10^9:1, 10^10:1, 10^11:1, 10^12:1, 10^13:1, 10^14:1, 10^15:1. Here, the caret symbol "^" is an operator that indicates exponentiation. For example, "10^5" means "10 5" (i.e., 10 to the power of 5). In the preceding paragraph, "approximately" includes a range of ratios that are 10% higher or lower by weight from the specified ratio. For example, approximately 1:2 includes a range of 1:1.8 to 1:2.2.

[0077] The present compound or composition A is usually used as a composition further containing an inert carrier (hereinafter referred to as composition B). Composition B is usually prepared by mixing the present compound or composition A with a solid carrier, a liquid carrier, a surfactant, etc., and adding formulation adjuvants such as binders, dispersants, stabilizers, and gases as necessary to prepare aqueous suspensions, oily suspensions, emulsifiable concentrates, emulsions, microemulsions, microcapsules, wettable powders, water dispersible granules, dusts, granules, tablets, aerosols, resin formulations, etc. The present compound or composition A is usually used as a composition further containing an inert carrier, such as a solid carrier, a liquid carrier, a surfactant, etc. Composition B is usually prepared by mixing the present compound or composition A with a solid carrier, a liquid carrier, a surfactant, etc., and adding formulation adjuvants such as binders, dispersants, stabilizers, and gases as needed to prepare aqueous suspensions, oily suspensions, emulsifiable concentrates, emulsions, microemulsions, microcapsules, wettable powders, water dispersible granules, dusts, granules, tablets, aerosols, resin formulations, etc. The present compound or composition B can be formulated into the dosage forms described in the Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers-271 to 276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2016, ISSN: 0259-2517. Composition B may also be processed into, for example, sprays (aerosols, pump sprays, ultrasonic vibration preparations, electrostatic spray preparations, etc.), poison baits, combustibles (incense sticks, etc.), heat-transmitting agents (electric mosquito mats, liquid mosquito preparations, etc.), air-blowing transmitting agents (fan-type mosquito preparations, etc.), fumigants (self-combustion fumigants, chemical reaction fumigants, porous ceramic plate fumigants, etc.), fumigants, aerosols, ULV agents, mists, foams, paste-like preparations, paints, wood protective coatings, sealants, carbon dioxide preparations, sheet preparations, tape preparations, paper preparations, nonwoven fabric preparations, animal collars, animal ear tags, shampoos, spot-on preparations, pour-on preparations, suppositories, injections, oral treatments (capsules, tablets, chewable preparations, feed, etc.), sublimable tablets, mosquito nets, attractants, gardening poles, and screen doors, and then used. These preparations contain the present compound in an amount of usually 0.0001 to 99%, preferably 0.1 to 99%, and more preferably 0.2 to 90% by weight.

[0078] When the present compound or Composition A is formulated into an aqueous suspension, oil suspension, wettable powder, or water dispersible granule, the particle size of the present compound or Composition A is usually in the range of 0.1 to 20 μm, preferably 0.2 to 15 μm. When the present compound or Composition A is formulated into a granule, the particle size of the present compound or Composition A is usually in the range of 0.1 to 200 μm, preferably 0.5 to 100 μm. The particle size of the present compound or Composition A refers to the particle size (volume median diameter) that corresponds to 50% cumulative frequency in the volume-based frequency distribution, and can be determined by wet measurement using a laser diffraction particle size analyzer. An example of a laser diffraction particle size analyzer is the Mastersizer 3000 manufactured by Malvern Instruments. The cumulative frequency in the volume-based frequency distribution can be expressed based on any percentage other than the median (50%), and a preferred range can be expressed as "40% volume diameter of 2.5 μm to 60% volume diameter of 2.5 μm", etc. Furthermore, instead of the volume median diameter, it can also be expressed by the weight median diameter, which can then be expressed by any percentage.

[0079] Examples of solid supports include the following: Inorganic substances: minerals (natural silicates, marble, pumice, limestone, rare earth minerals, cryolite, activated clay, lime, activated carbon, talc, attapulgite, sodium montmorillonite, calcium montmorillonite, kaolinite, calcite, dolomite, diatomite, bentonite, zeolite, sepiolite, pyrophyllite, vermiculite, crystalline silica, amorphous silica, etc.), silicon dioxide, calcium sulfate, magnesium sulfate, barium sulfate, magnesium oxide, aluminum oxide, ammonium sulfate, ammonium phosphate, ammonium nitrate, calcium phosphate, sulfur, calcium carbonate, sodium bicarbonate, sodium carbonate, synthetic silicates, and their crushed products; Organic matter: Grain powders (rice bran, rice flour, corn flour, wheat flour, etc.), sugars (cellulose, starch, lactose, glucose, fructose, sucrose, etc.), plant-derived powders (ground nut shells (ground nut shells of coconut, walnut, peanut, etc.)), tree-derived powders (bark powder and sawdust, etc.), other plant powders (tobacco stalks, soybeans, cottonseed husks, etc.)), lignin, wax, shells, urea, polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinylpyrrolidone-methacrylic acid copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenolic resin, melamine resin, epoxy resin. The above solid carrier can also be used as an adsorption carrier.

[0080] Examples of liquid carriers include water, aliphatic hydrocarbons (hexane, 1-hexene, cyclohexane, octane, isooctane, 1-heptene, d-limonene, pinene, hexadecane, etc.), aromatic hydrocarbons (alkylbenzenes (toluene, xylene, isopropylbenzene, p-diethylbenzene, etc.), alkylbenzene derivatives, alkylnaphthalenes, alkylnaphthalene derivatives, tetrahydronaphthalene, etc.), chlorinated hydrocarbons (monochloroethylene, dichloroethylene, trichloroethylene, tetrachloroethylene, etc.), and the like. , dichloromethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane, 1,2-dichloropropane, etc.), ketones (cyclohexanone, acetone, 2-heptanone, isophorone, mesityl oxide, methyl isoamyl ketone, methyl ethyl ketone, methyl isobutyl ketone, acetophenone, diacetone alcohol, methylcyclohexanone, etc.), esters (fatty acid esters (ethyl acetate, butyl acetate, amyl acetate, isoamyl acetate, isobornyl acetate, hexyl acetate, heptyl acetate, octyl acetate) , isopropyl myristate, methyl octanoate, methyl oleate, methyl laurate, dibutyl adipate, tributyl citrate, dibutyl phthalate, etc.), lactate esters (ethyl lactate, propyl lactate, etc.), carbonate esters (ethylene carbonate, propylene carbonate, butylene carbonate, diethyl carbonate, dibutyl carbonate, etc.), esterified polyols (glycerol acetate, glycol acetate, glycerin monoacetate, glycerin diacetate, glycerin triacetate, diethylene glycol abietate, dipropyl propylene glycol dibenzoate, dipropylene glycol monomethyl ester, etc.), lactones (γ-butyl lactone, etc.), ethers (1,4-dioxane, tetrahydrofuran, dipropylene glycol methyl ether, ethylene glycol methyl ether, propylene glycol methyl ether, etc.), amides (N-octyl-caprolactam, N-dodecyl-caprolactam, N,N-dimethylformamide, fatty acid dimethylamides (N,N-dimethylacetamide, N,N-dimethyldecanamide, N,N-dimethyloctanamide, etc.), alkylpyrrolidones (N-methylpyrrolidone, N-octylpyrrolidone, N-dodecylpyrrolidone, etc.), lactams (α-lactam, β-lactam, γ-lactam, δ-lactam, etc.), amines (octylamine, octylamine acetate, oleylamine, diethanolamine, laurylamine, etc.), alcohols (methanol, ethanol, butanol, propanol, isopropanol, butanol, amyl alcohol, hexanol, heptanol, octanol, 2-ethylhexanol, etc.), hexylene glycol, cyclohexanol, phenol, benzyl alcohol, methoxypropanol (1-methoxy-2-propanol), tetrahydrofurfuryl alcohol, furfuryl alcohol, polyethylene glycol, ethylene glycol, diethylene glycol, hexylene glycol, ethylene glycol methyl ether, diethylene glycol Examples of suitable oils include glycol methyl ether, diethylene glycol butyl ether, triethylene glycol, propylene glycol methyl ether, dipropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol ether, dipropylene glycol monomethyl ether, glycerin, etc.), mineral oils (naphtha, petroleum ether, kerosene, diesel oil, paraffin, olefin, etc.), oils derived from animals and plants, oils derived from plants (palm oil, rapeseed oil, castor oil, coconut oil, soybean oil and derivatives thereof, etc.), oils derived from animals (sardine oil, saury oil, whale oil and derivatives thereof, etc.), dimethyl sulfoxide, silicone oil, acetonitrile, propanenitrile, acid anhydrides (such as acetic anhydride), triethyl phosphate, oleic acid, propionic acid, lactic acid, and xylene sulfonic acid.

[0081] Examples of gaseous carriers include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide gas.

[0082] Examples of anionic surfactants include carboxylic acids, sulfonic acids, sulfates, and phosphates, and specific examples thereof include the following: Carboxylic acids: fatty acid salts (octanoate, decanoate, laurate, myristate, palmitate, stearate, behenate, oleate, polyoxyethylene alkyl ether carboxylate, laureth-3-carboxylate, α-(carboxymethyl)-ω-(dodecyloxy)poly(oxyethylene) salt, etc.), N-acyl sarcosine salts (N-lauroyl sarcosine salt, etc.), N-acyl glutamate salts (N-lauroyl glutamate, etc.), polycarboxylates (polyacrylates, polyvinyl acetates, polyacid salt comb polymers, and their derivatives, etc.); Sulfonic acids: alkylsulfonic acid and its salts (dodecylsulfonate, etc.), alpha-olefin sulfonates (alkene (C14-18) hydroxysulfonate, alkapolyene (C12-20) hydroxysulfonate, alkene (C14-18) hydroxysulfonate, alkene (C12-20) hydroxysulfonate, tetradecene-1-sulfonate, α-olefin (C14-16) sulfonate, etc.), alkylbenzenesulfonates (decylbenzenesulfonate, dodecylbenzenesulfonate, tridecylbenzenesulfonate, diphenylsulfonate, etc.), alkylnaphthalenesulfonates (naphthalenesulfonate, 6-methylsulfonate, ... methyl-2-naphthalenesulfonate, dibutylnaphthalenesulfonate, 2,2'-dinaphthylmethane-6,6'-disulfonate, diisopropylnaphthalenesulfonate, triisopropylnaphthalenesulfonate, 1-isopropyl-2-naphthalenesulfonate, etc.), sulfosuccinic acid, monoalkyl sulfosuccinates, dialkyl sulfosuccinates (di(2-ethylhexyl)sulfosuccinate, etc.), N-methyl-N-acyltaurates (oleoyl methyl taurate, etc.), ligninsulfonates, alkylphenolsulfonates, naphthalenesulfonate-formaldehyde condensates, benzimidazole sulfonates and their derivatives; Sulfate esters: alkyl sulfates (hexyl sulfate, heptyl sulfate, octyl sulfate, lauryl sulfate, lauryl diethanol sulfate, hexadecyl sulfate, octadecyl sulfate, etc.), polyoxyethylene alkyl ether sulfate and its salts (laureth-3-sulfate, polyoxyethylene monotridecyl ether sulfate, α-sulfo-ω-hydroxyalkyl(C6-10)ether poly(oxyethylene) salts, etc.), polyoxyethylene alkyl phenyl ether sulfates (poly(oxyethylene) 2-decylphenyl ether sulfate, poly(oxyethylene) 3-decylphenyl ether sulfate, α-sulfo-ω-[2,4-bis(1,1,3,3-tetramethylbutyl)phenoxy]poly(oxyethylene) salts, etc.), polyoxypropylene alkyl ether sulfates, lignosulfite waste liquor, and derivatives thereof; Phosphate esters: alkyl phosphates (propyl phosphate, hexadecyl phosphate, lauryl phosphate, dioctyl phosphate, etc.), polyoxyethylene alkyl ether phosphates (polyoxyethylene decyl phosphate, α-phosphono-ω-butoxypoly(oxyethylene), etc.), polyoxyethylene alkyl phenyl ether phosphates (α-(dinonylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, α-(dodecylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, α-(nonylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, etc.), polyoxypropylene alkyl ether phosphates, and derivatives thereof.

[0083] Examples of cationic surfactants include amine salts and quaternary ammonium salts, and specific examples include the following: Amine salts: alkylamine salts (monomethylamine salts, dimethylamine salts, trimethylamine salts, etc.), fatty acid amidoamine salts (stearamidopropyldimethylamine, behenamidopropyldimethylamine, etc.), polyamine salts (polyvinylamine, polyethyleneimine, etc.), and derivatives thereof; Quaternary ammonium salts: lauryltrimethylammonium salt, cetyltrimethylammonium salt, dodecyltrimethylammonium salt, stearyltrimethylammonium salt, benzalkonium chloride, benzethonium chloride, benzylbis(2-chloroethyl)ethylammonium bromide salt.

[0084] Examples of zwitterionic surfactants include betaine, alkyl betaine, alkyl dimethyl betaine, imidazoline, taurine, alkyl taurine, dodecyl dimethyl ammonio acetate, 4-carboxy-N,N,N-trimethyl-1-butanaminium, 1-carboxy-N,N,N-2-tetramethyl-1-propanaminium, N-alkyl (or alkenyl) (C12-18) glycine and salts thereof, N-dodecyl glycine and salts thereof, and derivatives thereof.

[0085] Examples of nonionic surfactants include alcohols, amides, amines, esters, ethers, ether esters, and carboxylic acids, and specific examples thereof include the following: Alcohols: aromatic alcohols (alkylphenols (allylphenol, octylphenol, nonylphenol, octylcresol, etc.), acylphenols, etc.), aliphatic alcohols (isotridecyl alcohol, oleyl alcohol, cetyl alcohol, etc.), polyhydric alcohols (polysaccharides, starch, starch derivatives, sucrose, alkyl polyglucosides, sorbitan, ethoxylated sorbitan, cellulose derivatives, gum arabic, etc.), synthetic polymers (polyvinyl alcohol, polyethylene glycol, etc.); Amides: alkanolamides (fatty acid alkanolamides (lauric acid diethanolamide, etc.)), fatty acid glucamides (alkoxylated propylene oxide fatty acid glucamides, etc.), alkoxylated amides (polyoxyethylene oleic acid amide, polyoxyethylene stearic acid amide, etc.), synthetic polymers (polyvinylpyrrolidone, etc.); Amines: alkoxylated amines (polyoxyethylene oleylamine, α,α'-[(9-octadecenylimino)diethylene]bis(ω-hydroxy)polyoxyethylene, etc.); Esters: fatty acid esters (fatty acid esters of polyols, monoglycerides, phospholipids, etc.), sugar-derived esters (sucrose fatty acid esters (sucrose stearate diester, etc.), sorbitan fatty acid esters (sorbitan oleate monoester, etc.), glucose esters, cellulose esters, etc.), synthetic polymers (vinyl acetate copolymers, polymethacrylic acid, copolymers of methacrylic acid and methacrylic acid esters, etc.); Ethers: alcohol ethoxylates (fatty alcohol ethoxylates (tridecyl alcohol ethoxylate, isooctyl alcohol ethoxylate, lauryl alcohol ethoxylate, hexadecyl alcohol ethoxylate, stearyl alcohol ethoxylate, etc.)), alkylphenol ethoxylates (nonylphenol ethoxylate, tristyrylphenol ethoxylate, tributylphenol ethoxylate, octylphenol ethoxylate, etc.), arylalkylphenol ethoxylates, arylphenol ethoxylates (monobenzyl biphenol alcohol ethoxylate, etc.), alcohol propoxylates (fatty alcohol propoxylates, alkylphenol propoxylates, arylalkylphenol propoxylates, etc.), block polymers (block polymers of polyethylene oxide and polypropylene oxide, polyethylene oxide block polymers, polypropylene oxide block polymers, block polymers of alkanol, polyethylene oxide and polypropylene oxide, etc.); Ether esters: polyoxyethylene fatty acid esters (polyoxyethylene castor oil esters, polyoxyethylene stearic acid esters, polyoxyethylene beef tallow fatty acid esters, etc.), polyoxyethylene sorbitan fatty acid esters (polyoxyethylene sorbitan monooleate esters, polyoxyethylene sorbitan trioleate esters, polyoxyethylene sorbitan monolaurate esters, polyoxyethylene sorbitan stearate esters, etc.), polyoxyethylene fatty acid amine esters, polyoxyethylene rosin esters, polyoxypropylene fatty acid esters (polyoxypropylene castor oil esters, etc.), polyoxypropylene fatty acid amine esters; Carboxylic acids: undecafluorohexanoic acid.

[0086] Other formulation adjuvants include, for example, thickeners, antifreeze agents / humectants, antifoaming agents, antioxidants, pH adjusters, colorants, preservatives / disinfectants, binders, adhesives / spreaders, lubricants / lubricants, anti-caking agents, light stabilizers, fragrances, propellants, fertilizers, film-forming agents, deodorizers, plasticizers, desiccants / moisture-proofing agents, fumigation aids, attractants, inclusion agents, and efficacy enhancers.Specific examples include the following. Thickeners: polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose and its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, carrageenan, etc.), clays (organic clays, organically modified clays, inorganic clays, inorganically modified clays, etc.), minerals (bentonite, attapulgite, silica, silicates, etc.), synthetic polymers (polycarboxylates, polyacrylic acid derivatives, polyvinylpyrrolidone, polyvinyl alcohol, etc.); Antifreeze agents and humectants: alcohols (ethylene glycol, propylene glycol, dipropylene glycol, triethylene glycol, ethylene glycol methyl ether, propylene glycol methyl ether, dipropylene glycol methyl ether, ethylene glycol butyl ether, glycerin, polyethylene glycol, etc.), esters (dipropylene glycol dibenzoate, glycerol acetate, glycerol diacetate, glycerol triacetate, gamma-butyrolactone, etc.), ethers (1,4-dioxane, etc.), urea; Antifoaming agents: silicones (polysiloxane, diblock ethoxyl siloxane, triblock ethoxyl siloxane, etc.), alkyl sulfosuccinates, higher alcohols, higher alcohol derivatives, salts of fatty acids, fatty acid derivatives; Antioxidants: phenols (2,6-di-t-butyl-p-cresol, 2,2'-methylenebis(4-methyl-6-t-butylphenol), etc.), amines (p,p'-dioctyldiphenylamine, N,N'-diphenyl-p-phenylenediamine, etc.), dibutylhydroxytoluene, butylhydroxyanisole, sodium erythorbate, sodium sulfite, potassium sulfite, potassium pyrosulfite, catechin, propyl gallate, sulfur compounds (didodecyl thiodipropionate, etc.), phosphoric acids (trisnonylphenyl phosphite, etc.), vitamins (alpha tocopherol, L-ascorbic acid, sodium ascorbate, ascorbyl palmitate, etc.); pH adjusters: sulfuric acid, nitric acid, hydrochloric acid, acetic acid, carbonic acid, oxalic acid, lactic acid, succinic acid, gluconic acid, citric acid, phosphoric acid, sorbic acid, and their salts, sodium bicarbonate, sodium hydroxide, potassium hydroxide, calcium hydroxide, aluminum hydroxide, copper hydroxide, magnesium hydroxide; Colorants: Monoazo (Pigment Red 48:1, Pigment Red 48:2, Pigment Red 53:1, Pigment Red 57:1, Pigment Red 112, Pigment Brown 25, Cl Solvent Red 1, Pigment Yellow 1, Pigment Orange 5, Acid Red 14, Acid Yellow 23, etc.), disazos (Pigment Yellow 13, Pigment Orange 34, etc.), phthalocyanines (Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3, Pigment Blue 15:4, Pigment Green 7, Pigment Green 36, etc.), anthraquinones (Pigment Red 83, etc.), dioxazines (Pigment Blue 80, etc.), xanthenes (Basic Violet 10 (Rhodamine B), Acid Red 51, Acid Red 52, etc.), triarylmethanes (Acid Blue 9, etc.), Pigment Orange 43, iron oxide, titanium dioxide, titanium oxide, zinc oxide, zinc sulfide, iron hexacyanoate, chrome vermilion, yellow lead, calcium carbonate, baryte powder, aluminum powder; Preservatives and disinfectants: phenols (orthophenylphenol, thymol, 3,5-dimethyl-4-chlorophenol, etc.), isothiazolinone derivatives (methylisothiazolinone (2-methyl-4-isothiazolin-3-one), chloromethylisothiazolinone (5-chloro-2-methyl-4-isothiazolin-3-one), octylisothiazolinone (2-n-octyl-4-isothiazolin-3-one), dichlorooctylisothiazolinone (4,5-dichloro-2-octyl-4-isothiazolin-3-one), benzisothiazolinone (1,2-benzisothiazolin-3-one), etc.), bronopol Derivatives (bronopol (2-bromo-2-nitropropane-1,3-diol), etc.), benzyl alcohol hemiformal, isopropylmethylphenol, parabens (methylparaben, ethylparaben, propylparaben, isopropylparaben, butylparaben, isobutylparaben, heptylparaben, benzylparaben), imidazoles (thiabendazole), benzalkonium chloride, glyceryl caprylate, glyceryl caprate, glycerin fatty acid esters, sodium dehydroacetate, hinokitiol, acids (citric acid, phosphoric acid, sorbic acid, salicylic acid, benzoic acid, and their salts, etc.); Binders: polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clays, organically modified clays, inorganic clays, inorganically modified clays), minerals (bentonite), synthetic polymers (polycarboxylic acids or their salts, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or its salts), waxes (vegetable oils and fats, animal oils and fats, and their derivatives, paraffin, olefin, etc.); Fixing agents and spreading agents: the above-mentioned surfactants and liquid carriers (esters (alkyl fatty acid esters, sorbitan fatty acid esters, ethoxylated fatty acid esters, ethoxysorbitan fatty acids, etc.), alcohols (ethoxylated fatty alcohols, ethoxysorbitan fatty alcohols, etc.), waxes (vegetable oils and fats, animal oils and fats, and their derivatives, paraffin, olefin, etc.), vegetable oils (alkylated vegetable oils, etc.), mineral oils (mineral oil, etc.), silicone emulsions, synthetic polymers (styrene-butadiene copolymers, methyl methacrylate-butadiene copolymers, polyacrylic acid or its salts, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, polypropylene glycol, etc.), natural polymers (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose or its salts), dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, etc.); Lubricants and lubricants: Alcohols, fatty acid esters, sucrose fatty acid esters, glycerin fatty acid esters, hydrocarbons, paraffin, ethylene wax, aliphatic amides, erucic acid amide, stearic acid amide, oleic acid amide, methylene bisstearic acid amide, ethylene bisstearic acid amide, metal soaps, lead stearate, zinc stearate, calcium stearate, magnesium stearate, mineral oil, vegetable oil, kerosene, diesel oil, as listed above as liquid carriers and surfactants; Anti-caking agents: solid and liquid carriers as mentioned above, calcium phosphate, sodium phosphate, sodium carbonate, sodium silicate, calcium silicate, magnesium silicate, potassium aluminum silicate, silicon dioxide, talc, sodium aluminosilicate, calcium aluminosilicate, bentonite, stearic acid, dimethylpolysiloxane, powdered cellulose; Light stabilizers: titanium dioxide, zinc oxide, activated carbon, carbon black, ethylhexyl methoxycinnamate, tert-butyl methoxydibenzoylmethane, hindered amines, ferulic acid, phenyl hydroxybenzoate, ethyl para-aminobenzoate, octyl salicylate, t-butylphenyl salicylate, 4-tert-octylphenyl salicylate, 2-cyano-3,3-diphenylprop-2-enoic acid-2-ethylhexyl ester (octocrylene), drometrizole trisiloxane, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine (octyltriazone, TEAT), 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol] (MBP), 2-ethylhexyl paradimethylaminobenzoate (EDB), homomenthyl salicylate (HS), phenylbenzimidazole sulfonic acid (PBS), hydroxymethoxybenzophenone sulfonic acid (oxybenzone 4, OXB4), sodium hydroxymethoxybenzophenone sulfonate (oxybenzone 5, OXB5), sodium dihydroxydimethoxybenzophenone disulfonate (oxybenzone 9, OXB9), tetrahydroxybenzophenone, dihydroxybenzophenone, dihydroxydimethoxybenzophenone, 2-hydroxy-4-methoxybenzophenone, dimethoxybenzylidene dioxoimidazolidine-2-ethylhexyl propionate, 2,4-dihydroxybenzophenone, bis(2-methoxy-4-hydroxy-5-benzoylphenyl)methane; Fragrance: Hydrocarbons, α-limonene, β-caryophyllene, alcohols, cis-3-hexenol, linalool, farnesol, β-phenylethyl alcohol, aldehydes, 2,6-nonadenal, citral, α-hexyl cinnamic aldehyde, ketones, β-ionone, L-carvone, cyclopentadecanone, esters, linalyl acetate, benzyl benzoate, lactones, γ-undecalactone, phenols, eugenol, oxides, rose oxide, acetals, phenylacetaldehyde dimethyl acetal, α-pinene, β-pinene; Propellant: liquefied petroleum gas, aliphatic hydrocarbons having 3 to 5 carbon atoms such as propane, normal butane, isobutane, normal pentane, isopentane, etc., hydrofluoroolefins such as trans-1,3,3,3-tetrafluoroprop-1-ene, trans-2,3,3,3-tetrafluoroprop-1-ene, etc., dimethyl ether, nitrogen gas, carbon dioxide gas, nitrous oxide gas, compressed air, and mixtures thereof; Fertilizer: Nitrogenous fertilizer components (urea, ammonium nitrate, magnesium ammonium nitrate, ammonium chloride, ammonium sulfate, ammonium phosphate, sodium nitrate, calcium nitrate, potassium nitrate, lime nitrogen, formaldehyde-modified urea (UF), acetaldehyde-modified urea (CDU), isobutyraldehyde-modified urea (IBDU), guanylated urea (GU)), phosphate fertilizer components (superphosphate, triple superphosphate, fused phosphorus, humic acid phosphorus, calcined phosphorus, double calcined phosphorus, magnesium superphosphate, ammonium polyphosphate, potassium metaphosphate, calcium metaphosphate, magnesium phosphate, sulfur Ammonium phosphate, potassium ammonium phosphate nitrate, ammonium chloride, etc.), potassium fertilizer ingredients (potassium chloride, potassium sulfate, potassium soda sulfate, magnesium sulfate, potassium bicarbonate, potassium phosphate, etc.), silicate fertilizer ingredients (calcium silicate, etc.), magnesium fertilizer ingredients (magnesium sulfate, magnesium chloride, etc.), calcium fertilizer ingredients (quicklime, slaked lime, calcium carbonate, etc.), manganese fertilizer ingredients (manganese sulfate, manganese sulfate, manganese slag, etc.), boron fertilizer ingredients (boric acid, borates, etc.), iron-containing fertilizer ingredients (steel slag, etc.), other fertilizer ingredients (copper, cobalt, zinc, etc.); Film-forming agents: natural rubber, synthetic rubber, resins (styrene butadiene copolymer, polyacrylonitrile, polyester, polyamide, polyurethane, polyurea, polyether, rosin, melamine, etc.), waxes (vegetable oils and fats, animal oils and fats, and their derivatives, paraffin, olefin, etc.), polysaccharides (xanthan gum, cellulose ester, cellulose ether, carboxymethyl cellulose or its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, starch xanthate, carrageenan, etc.), proteins (gelatin, etc.); Deodorants: organic clay, organic modified clay, unmodified clay, zinc silicate, silica gel; Plasticizers: triethyl phosphate, citrate esters, phthalates, adipates, sebacates, phosphate esters; Desiccants and moisture-proofing agents: silica gel, calcium chloride, quicklime, aluminum oxide, zeolite, allophane; Fumigant additives: nitrocellulose, potassium chlorate, calcium oxide, melamine, potassium nitrate, azodicarbonamide; Attractants: starch, cellulose, dextrin, vinegar, alcohol, yeast extract; Inclusion agents: cyclodextrins, α-cyclodextrin, β-cyclodextrin, γ-cyclodextrin; Efficacy enhancers: Liquid carriers and surfactants as described above.

[0087] When the present compound or Composition A is formulated into an aqueous suspension or an oily suspension, an antifreeze agent and / or a preservative is usually added.Preferably, the antifreeze agent includes ethylene glycol, propylene glycol, and glycerin.Preferably, the preservative includes an isothiazolinone derivative (e.g., 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-n-octyl-4-isothiazolin-3-one) and Proxel (1,2-benzisothiazolin-3-one). Ethylene glycol (EG), propylene glycol (PG), glycerin (GL), 2-methyl-4-isothiazolin-3-one (MIT), 5-chloro-2-methyl-4-isothiazolin-3-one (CMIT), 2-n-octyl-4-isothiazolin-3-one (OIT), 4,5-dichloro-2-octyl-4-isothiazolin-3-one (DCOIT), 1,2-benzisothiazolin-3-one (BIT), and 2-bromo-2-nitropropane-1,3-diol (BNPD), which are used as antifreezes and preservatives, are commercially available.

[0088] Examples of combinations of the present compound or composition A with the above antifreeze agents or preservatives are given below. SX + EG, SX + PG, SX + GL, SX + MIT, SX + CMIT, SX + OIT, SX + DCOIT, SX + BIT, SX + BNPD, Composition A + EG, Composition A + PG, Composition A + GL, Composition A + MIT, Composition A + CMIT, Composition A + OIT, Composition A + DCOIT, Composition A + BIT, composition A+ BNPD.

[0089] The weight ratio of the present compound or composition A to the antifreeze agent or preservative is in the range of 1:0.0001 to 1:100, for example, 1:0.0001 to 1:1, 1:0.005 to 1:0.01, 1:0.15 to 1:0.35, or 1:0.125 to 1:0.25. Specific weight ratios are 1:0.0001, 1:0.0002, 1:0.0003, 1:0.0004, 1:0.0005, 1:0.0006, 1:0.0007, 1:0.0008, 1:0.0009, 1:0.001, 1:0.002, 1:0.003, 1:0.004, 1:0.005, 1:0.006, 1:0.007, 1:0.008, 1:0.009, 1:0.01, 1:0.02, 1:0.03, 1:0.04, 1:0.05, 1:0.06 Examples of suitable ratios include 1:0.06, 1:0.07, 1:0.08, 1:0.09, 1:0.1, 1:0.125, 1:0.15, 1:0.2, 1:0.25, 1:0.3, 1:0.4, 1:0.5, 1:0.6, 1:0.7, 1:0.8, 1:0.9, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:30, 1:40, 1:50, 1:60, 1:70, 1:80, 1:90, and 1:100. These weight ratios can also be expressed as "approximate." Approximately means plus or minus 10%. For example, "approximately 1:2" means 1:1.8 to 1:2.2.

[0090] Examples of combinations of the present compound or composition A with the above antifreeze agents and preservatives are given below. SX + EG + MIT, SX + EG + CMIT, SX + EG + OIT, SX + EG + DCOIT, SX + EG + BIT, SX + EG + BNPD, SX + PG + MIT, SX + PG + CMIT, SX + PG + OIT, SX + PG + DCOIT, SX + PG + BIT, SX + PG + BNPD, SX + GL + MIT, SX + GL + CMIT, SX + GL + OIT, SX + GL + DCOIT, SX + GL + BIT, SX + GL + BNPD, Composition A + EG + MIT, Composition A + EG + CMIT, Composition A + EG + OIT, Composition A + EG + DCOIT, Composition A + EG + BIT, Composition A + EG + BNPD, composition A + PG + MIT, composition A + PG + CMIT, Composition A + PG + OIT, Composition A + PG + DCOIT, Composition A + PG + BIT, Composition A + PG + BNPD, Composition A + GL + MIT, Composition A + GL + CMIT, Composition A + GL + OIT, Composition A + GL + DCOIT, Composition A + GL + BIT, Composition A + GL + BNPD. When combining this compound or composition A with the above-mentioned antifreeze and preservative, the mixing ratio of this compound or composition A to the antifreeze, and this compound or composition A to the preservative can be used within the same range as the above ratio.

[0091] In the case of granules or microgranules, a coloring agent may be added to make it easier to identify the granules or microgranules during or after application. Also, when applying Composition B to plant seeds or vegetative reproductive organs, a coloring agent may be added to make it easier to identify that the composition has been applied.

[0092] Examples of substrates for resin formulations include polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinylpyrrolidone-methacrylic acid copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenolic resins, melamine resins, and epoxy resins. These substrates may contain, as needed, plasticizers such as phthalates (dimethyl phthalate, dioctyl phthalate, etc.), adipic acid esters, and stearic acid. The resin formulations can be molded into various forms, such as plates, films, tapes, threads, nets, cloths, strings, and blocks, as needed. Specifically, they can be used in the form of animal collars, animal ear tags, clothing, protective hats, arm / leg covers, attractants, gardening poles, screen doors, mosquito nets, and the like. The resins can also be obtained by molding and processing the resins and then post-treating them with Composition B. Examples of base materials for poison bait include grain flour, vegetable oil, sugar, and crystalline cellulose, and, if necessary, may also contain antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, preservatives such as dehydroacetic acid, agents to prevent accidental ingestion by children and pets such as chili pepper powder, and pest-attracting flavors such as cheese flavoring, onion flavoring, and peanut oil.

[0093] Weeds can be controlled by applying an effective amount of the present compound, Composition A, or Composition B directly to the weeds or to the place where the weeds grow. The place where the weeds grow includes not only the place where the weeds grow but also the place where the weeds are expected to grow.

[0094] In the present invention, weeds include whole weeds and specific parts of weeds, such as roots, shoots, stems and leaves, flowers, spikes, fruits, branches, crowns, seeds, and vegetative reproductive organs.

[0095] Vegetative reproductive organs refer to plant roots, stems, leaves, and other parts that can grow when separated from the plant body and placed in soil. Examples of vegetative reproductive organs include tuberous roots, creeping roots, bulbs, corms (or solid bulbs), tubers, rhizomes, stolons, rhizophores, cane cuttings, propagules, and vine cuttings. Stolons are sometimes called runners, and propagules are also called bulbils and are divided into broad buds and bulbils. Bulbs, corms, tubers, rhizomes, stem cuttings, rhizophores, and tuberous roots are collectively called bulbils.

[0096] Places where weeds grow or are expected to grow include, for example, agricultural land such as fields, rice paddies, orchards, and non-agricultural land such as lawns, forests, etc. Application to a place includes application to the soil of these places.

[0097] When Composition B is used for weed control in agricultural fields, the application rate can vary over a wide range depending on the type of plant to which it is applied, the type and frequency of weeds to be controlled, the formulation, application time, application method, application location, weather conditions, etc. Typically, the application rate of the present compound or one of the present components is 1 to 10,000 g per hectare, preferably 5 to 5,000 g, and more preferably 50 to 2,000 g (specifically, for example, 100 g, 200 g, 300 g, or 500 g). When Composition B is formulated as an emulsifiable concentrate, wettable powder, flowable powder, or the like, it is typically diluted with water to a concentration of the present compound or one of the present components of 0.01 to 10,000 ppm, preferably 0.1 to 5,000 ppm, and more preferably 1 to 1,000 ppm (specifically, for example, 10 ppm, 100 ppm, or 500 ppm) before application. When composition B is formulated as granules, dust or the like, it is usually applied as is.

[0098] Examples of methods for applying Composition B include spraying Composition B on soil (soil treatment) and spraying Composition B on emerged weeds (foliage treatment). Soil treatment and foliage treatment are usually carried out by mixing Composition B with water to obtain a spray solution, and then spraying the solution on the soil or weeds using a sprayer. Composition B may be applied to the cultivation area of ​​the plants before sowing the seeds of the plants, or may be applied simultaneously with or after sowing the seeds of the plants. That is, examples of the number of times composition B may be applied include once before, simultaneously with, or after sowing the seeds of the plants, twice excluding before sowing, twice excluding simultaneously with sowing, or twice excluding after sowing, or three times applied at any timing before, simultaneously with, or after sowing the seeds of the plants. Weeds may already have appeared in the plants or the cultivation area of ​​the plants, or they may not have appeared yet. When applying composition B before sowing plant seeds, composition B is applied 50 days to immediately before sowing, preferably 30 days to immediately before sowing, more preferably 20 days to immediately before sowing, and even more preferably 10 days to immediately before sowing. When applying composition B after sowing plant seeds, the application is usually carried out between immediately after sowing and before flowering. More preferably, the application is carried out between immediately after sowing and before emergence, and during the 1- to 6-leaf stage of the plant. The case where Composition B is applied simultaneously with the sowing of plant seeds refers to the case where the sowing machine and the sprayer are integrated. As described above, methods for applying Composition B include soil treatment, in which Composition B is applied to soil where weeds emerge, and foliar treatment, in which Composition B is applied to weeds that have emerged and are growing. When Composition B is applied to growing weeds, the treatment can be both foliar and soil treatment. The timing of treatment can be determined independently of the above-mentioned plant growth stage. For example, foliar treatment can be performed on growing weeds before sowing the plants, or soil treatment can be performed while the plants are growing. These treatments can be uniform, area-wide treatments on the cultivation area, or spot treatments. The timing of application of Composition B before weed emergence includes the seed stage and cotyledon stage, and after weed emergence, includes the cotyledon stage, 2-leaf stage, 4-leaf stage, 6-leaf stage, and 8-leaf stage, but is not limited to these. Soil treatments include, for example, soil spraying, soil incorporation, and soil drenching. Examples of locations for soil treatment include planting holes, rows, areas near the planting holes, areas near the rows, the entire cultivated area, the plant's soil edge, between plants, under the tree trunk, and the main ridge. Treatment times include, for example, before sowing, at the time of sowing, after sowing, and during the growth period after emergence. In the above-mentioned soil treatments, a paste fertilizer, liquid fertilizer, solid fertilizer, etc. containing Composition B may be applied to the soil. It may also be mixed with irrigation liquid, for example, by injection into irrigation equipment (irrigation tubes, irrigation pipes, sprinklers, etc.), by mixing with inter-row flooding liquid, or by mixing with hydroponic solution. Alternatively, the active ingredient may be mixed with the irrigation liquid in advance, and then treated using the above-mentioned irrigation methods or other appropriate irrigation methods, such as sprinkling or flooding. An example of a water surface treatment is a method in which a liquid drug containing Composition B or a solid formulation containing Composition B is sprayed onto a flooded paddy field. When applying Composition B to plants or plant cultivation areas, Composition B is usually mixed with a carrier such as a solid carrier or a liquid carrier, and further, if necessary, formulation adjuvants such as surfactants are added, and the composition is used in the form of a formulation or a diluted solution. When formulating the present compound, preferred formulation forms are aqueous liquid suspension concentrates (SC), wettable powders (WP), water dispersible granules (WG), granules (GR), aqueous emulsion concentrates (EW), oil emulsion concentrates (EO), suspoemulsions (SE), and emulsifiable concentrates (EC). In one embodiment, when formulating the present compound, aqueous liquid suspension concentrates (SC) and emulsifiable concentrates (EC) are preferred. Furthermore, a formulation containing Composition B and another herbicide as an active ingredient may be used, or a formulation containing the present compound and another herbicide as an active ingredient may be mixed (tank-mixed) and used. The present compound and the present ingredient may be applied separately at the same time to plants or the soil in which plants are grown, or to the location where weeds occur, or the present compound and the present ingredient may be applied separately to weeds or to the location where weeds occur at different times.

[0099] Examples of seed treatment agents that are applied to soybeans in advance include the following. STANDAK-TOP 500FS (Fipronil / Pyraclostrobin / Thiophanate-m), DERMACOR 625FS (Chlorantraniliprole), CRUISER 350FS (Thiamethoxam), CROPSTAR 600FS (Imidacloprid / Thiodicarb), FORTENZA 600FS (Cyantraniliprole), S-UNSPEC-INS-WHEAT, NEMAT 300WP (Verticillium), FIPRONIL-ALTA 250FS (Fipronil), MAXIM-ADVANCED 195FS (Fludioxonil / Metalaxyl-M / Thiabendazole), SHELTER 250SC (Fipronil), MAXIM-XL 035FS (Fludioxonil / Metalaxyl-M), DEROSAL Plus(Carbendazim / Thirum), Vitavax - THIRAM (Carboxin / Thiram).

[0100] Examples of seed treatment agents that are applied to corn in advance include the following. PONCHO-VOTIVO 601EC (Bacillus-firmus / Clothianidin), ACCELERON-IC-609 600EC (Clothianidin), CRUISER 600FS (Thiamethoxam), ACCELERON-D-342 480FS (Prothioconazole), PONCHO 600FS (Clothianidin), MAXIM-QUATTRO 382.5FS (Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole), AVICTA-COMPLETE-CORN-250 280FS, Abamectin / Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole / Thiamethoxam), AVICTA-COMPLETE-CORN-500 423FS, (Abamectin / Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole / Thiamethoxam), LUMIVIA 625FS (Chlorantraniliprole), ACCELERON-D-281 480FS (Fluoxastrobin), ACCELERON-DC-309 312FS (Metalaxyl).

[0101] Examples of seed potato treatment agents that are used to treat potatoes in advance include the following: Maxim 4FS (fludioxonil), Maxim MZ (fludioxonil + mancozeb), Cruiser MAXX Vibrance Potato (fludioxonil + difenoconazole + sedaxane + thiamethoxam), Emesto Silver (penflufen + prothioconazole), MonCoatMZ (flutolanil + mancozeb), Moncut (flutolanil), Elatus (azoxystrobin + benzovindiflupyr), Quadris (azoxystrobin), Serenade ASO (Bacillus subtillis), DoubleNickel LC (Bacillus amyloliquefaciens), Atackin (streptomycin, thiophanate M), Furonside (fluazinam), Basidac (mepronil), Moncut (flutolanil), Lovral (iprodione), Moncut (flutolanil), Benlate (benomyl).

[0102] Composition B can be applied using a spraying device. Examples of devices used for application include hand-cranked sprayers, power sprayers, punkul sprayers, manned aircraft (such as manned helicopters), unmanned aircraft (such as radio-controlled helicopters and drones), tractors, planters, etc. The sprayer may be a hooded sprayer certified by the U.S. Environmental Protection Agency (EPA) for drift reduction technology (DRT). Examples of DRT-certified hooded sprayers include REDBALL 642, REDBALL 642E, REDBALL SPK645, REDBALL 645, REDBALL 645T, REDBALL SP645, and REDBALL ATV642, all manufactured by Willmar Fabrication LLC. Alternatively, the composition may be applied by hand without using a spraying device. When applying Composition B using a sprayer, the spray pressure is not particularly limited, but is usually 30 to 120 PSI, preferably 40 to 80 PSI. The spray pressure here is the setting before introduction into the nozzle. When applying Composition B using a sprayer, the spray nozzle is not particularly limited, but examples include flat spray nozzles, conical nozzles, rotary nozzles, hollow cone nozzles, deflector nozzles, linear nozzles, and drift-reducing nozzles. Examples of flat fan nozzles include Teejet's Teejet 110 series and XR Teejet 110 series. When these nozzles are used at normal spray pressures, typically in the range of 30 to 120 PSI, the volume median diameter of droplets discharged from the nozzle is typically less than 430 microns. A drift-reducing nozzle is a nozzle that reduces drift of the spray liquid compared to a flat fan nozzle, and is also known as an air induction nozzle or pre-orifice nozzle. The volume median diameter of droplets discharged from a drift-reducing nozzle is typically 430 microns or greater. An air induction nozzle has an air introduction section between the nozzle inlet (chemical solution introduction section) and outlet (chemical solution discharge section), and forms droplets filled with air by mixing air into the chemical solution. Examples of air induction nozzles include Green Leaf Technology's TDXL11003-D, TDXL11004-D1, TDXL11005-D1, and TDXL11006-D; Teejet's TTI110025, TTI11003, TTI11004, TTI11005, TTI11006, and TTI11008; and Pentair's ULD120-041, ULD120-051, and ULD120-061. A particularly preferred nozzle is the TTI11004. A pre-orifice nozzle has a metering orifice at the nozzle inlet (chemical introduction point), which restricts the flow rate into the nozzle and reduces the pressure inside the nozzle, forming larger droplets. When using this nozzle, the pressure is roughly halved during discharge compared to before introduction. Examples of pre-orifice nozzles include Wilger's DR110-10, UR110-05, UR110-06, UR110-08, and UR110-10, and Teejet's 1 / 4TTJ08 Turf Jet and 1 / 4TTJ04 Turf Jet.

[0103] When Composition B is applied in the form of a solution, the pH and hardness of the solution are not particularly limited, but the pH is usually in the range of 5 to 9, and the hardness is usually in the range of 0 to 500 on the American Hardness Scale. The time of day when Composition B is applied is not particularly limited, but is generally between 5:00 AM and 9:00 PM. In addition, the photon flux at the canopy level in the area where Composition B is applied is usually 10 to 2500 micromoles / m 2 The weather conditions when applying Composition B are not particularly limited, but the air temperature is usually 0 to 30°C, preferably 10 to 20°C, the soil temperature is usually 0 to 30°C, preferably 10 to 20°C, the relative humidity is 50 to 90%, preferably 40 to 80%, and the wind speed is 0 to 3 MPH. Composition B is usually sprayed by mixing it with water to obtain a spray solution, which can be prepared by directly diluting it with the amount of water needed to spray it, or by mixing Composition B with a small amount of water, homogenizing it, and then adding water to adjust the amount to the specified volume. The amount of spray solution is not particularly limited, but is usually in the range of 5 to 5,000 L / ha, preferably 20 to 1,000 L / ha, and more preferably 140 to 300 L / ha. Specific spraying liquid volume is 10L / ha, 30L / ha, 50L / ha, 70L / ha, 90L / ha, 100L / ha, 120L / ha, 150L / ha, 180L / ha, 20 Examples include 0L / ha, 250L / ha, 300L / ha, 400L / ha, 500L / ha, 700L / ha, 900L / ha, 2000L / ha, and 4000L / ha. When Composition B is sprayed using a manned or unmanned aircraft, the spray height is not particularly limited, but is usually 0.5 to 30 m, preferably 1 to 10 m.

[0104] When carrying out foliar treatment and soil treatment with Composition B, Composition B may be mixed with an adjuvant. The adjuvants may be mixed in advance when formulating the composition (premix) or immediately before use (tank mix). The type of adjuvant is not particularly limited, but examples include mineral oil-derived COC (crop oil concentrate), vegetable oil-derived MSO (methylated seed oil), alcohol-based solvents, nonionic surfactants, anionic surfactants, cationic surfactants, silicone-based surfactants, nitrogen fertilizers, and mixtures thereof. Specifically, AgriDex (registered trademark), Induce (registered trademark), Gramin S (registered trademark), Genamin T 200BM (registered trademark), Silwet L77 (registered trademark), Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol Gold (registered trademark), BreakThru (registered trademark), Sundance II (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), BANOLE (registered trademark), Ochima (registered trademark), Agris (registered trademark), AMS (Ammonium Sulfate), UAN (Urea Ammonium Sulfate), Examples of adjuvants include AdGreen (registered trademark), Mees (trademark), Rumba (registered trademark), Strides (registered trademark), Partner, Orix (registered trademark), and Penetrator. Furthermore, adjuvants that reduce drift, such as Intact (polyethylene glycol) and Intact Maxx (a mixture of potassium acetate, guar, etc.), and adjuvants that act as liquid fertilizers, such as AMS (ammonium sulfate) and UAN (urea ammonium nitrate), may also be used in combination.The weight ratio of composition B to the adjuvant or drift-reducing agent is not particularly limited, but may be, for example, in the range of 1:100 to 100:1.

[0105] Composition B can be applied by spot treatment. Spot treatment is a concept that is opposite to uniform application of Composition B, and refers to a treatment in which Composition B is selectively sprayed on locations where weeds have occurred or where weeds are likely to occur. "Applying to a location" means applying to plants or soil where weeds have occurred or are likely to occur, preferably when applying to plants. When applying to plants, this includes applying only to individuals in a plant population where weeds have occurred or are likely to occur, and also includes applying to parts of individual plants where weeds have occurred or are likely to occur. Even when Composition B is applied in small amounts to areas where weeds have not occurred or are not likely to occur due to scattering, transpiration, etc., it is included in spot treatment as long as it is not a uniform area treatment. Furthermore, spot treatment is not limited to cases where all areas where weeds have occurred or are likely to occur in a continuous cultivation area are selectively treated. In other words, even if only part of the cultivation area is treated area-wide, or even if some areas where weeds have occurred or are likely to occur are not treated with Composition B, it is included in spot treatment as long as there are areas in the continuous cultivation area that have been spot-treated. Spot treatment may be carried out while avoiding plants, or may be carried out based only on the location of weeds, regardless of the location of plants. Specific examples of spot treatment methods are given below. Spot treatment may be performed in a plant cultivation area by an applicator visually spraying composition B using a handheld nozzle or robotic arm nozzle while walking or aboard a ground-based or flying device. Furthermore, spot treatment may be performed by mapping areas where weeds have occurred or are likely to occur in advance and spraying composition B based on the map information. In spraying based on map information, in addition to the above-mentioned methods, spot treatment may be performed by automatically or manually opening and closing a boom nozzle or robotic arm nozzle while the sprayer is traveling or flying, based on the sprayer's position information (obtained by GPS, etc.) and the map information. The map information may be created based on image information captured by a manned or unmanned flying object, or may be created visually by an observer walking on the ground, riding on a ground-based or flying device, or by an observer aboard a flying device. Furthermore, a mobile or flying sprayer may be equipped with the function of detecting areas where weeds have occurred or are likely to occur, and spot treatment may be carried out using the boom or robotic arm while performing real-time mapping.

[0106] In addition to visual recognition by applicators or observers, weed infestation locations can be identified through image analysis using visible light, but they can also be recognized through image analysis using specific wavelengths of hyperspectral images. Image analysis can be performed by visually recognizing weed infestation on a screen, or image recognition using artificial intelligence can also be used (for example, OPTiM Corporation press release dated December 26, 2017). These images can be captured by manned or unmanned aircraft, or by a photographer walking on the ground, a photographer riding on a ground-based vehicle, or a photographer aboard a flying device. Locations at risk of weed infestation can be estimated based on the patchy occurrence of the pest weed in question during previous crop cultivation seasons, or from the distribution of weeds in the soil. The distribution of weeds in the soil can be investigated by soil sampling or estimated using remote sensing. Image analysis can also be used to detect and estimate the presence of weeds hiding in plants. Such technologies are described in patent literature (e.g., WO2018001893, WO2018036909) and non-patent literature (e.g., Crop Protection 26, 270-277, Weed Technology 17, 711-717, Applied Engineering in Agriculture 30, 143-152). These technologies are known as a form of emerging agriculture, also known as precision agriculture, smart agriculture, or digital agriculture. The uneven spraying pattern caused by spot treatment is sometimes referred to as VRA (Variable Rate Application) in the emerging agriculture terminology. Furthermore, technologies in which a traveling sprayer performs spot treatment in real time while detecting growing weeds are known as "See & Spray" or "OSST (Optical Spot Spray Technology)." Furthermore, sprayers equipped with See & Spray, such as the John Deere 400 series, have been put into practical use.

[0107] Methods for spot treatment with Composition B include spraying the soil where weeds are present or where weeds are likely to be present (soil treatment), and spraying Composition B on weeds (foliage treatment). Spraying is typically carried out using a spray solution prepared by mixing Composition B with water. The amount of spray solution is not particularly limited, but is typically 50 to 1,000 L / ha, preferably 100 to 500 L / ha, and more preferably 140 to 300 L / ha within the area to be spot treated. The proportion of the area in the plant cultivation area to be spot treated (the proportion of the area to which Composition B is sprayed relative to the area of ​​the entire continuous cultivation area) is typically 1 to 99%, preferably 10 to 80%. Specific examples include 20%, 30%, 40%, 50%, 60%, and 70%. The amount of Composition B to be applied in spot treatment is 5 to 2000 g per hectare, preferably 50 to 1500 g per hectare, more preferably 200 to 1000 g per hectare, and even more preferably 400 to 700 g per hectare, as the amount of one active ingredient to be applied within the area to be spot treated. When carrying out spot treatment, an adjuvant or a drift-reducing agent may be used in combination. The types of adjuvant and drift-reducing agent are not particularly limited, but examples thereof include those mentioned above. The pH and hardness of the spray solution are not particularly limited, but the pH is usually in the range of 5 to 9, and the hardness is usually in the range of 0 to 500 on the American hardness scale. The time period for spot treatment is not particularly limited, but is usually between 5:00 AM and 9:00 PM, and the photon flux at the canopy level in the area where spot treatment is performed is usually 10 to 2500 μmol / m 2 On the other hand, spot treatment can also be carried out at night using the map information and location information. The spray pressure when carrying out spot treatment is not particularly limited, but is usually 30 to 120 PSI, preferably 40 to 80 PSI. The spray pressure here is the setting before introduction into the nozzle. The weather conditions for carrying out spot treatment are not particularly limited, but the air temperature is usually 0 to 30°C, preferably 10 to 20°C, the soil temperature is usually 0 to 30°C, preferably 10 to 20°C, the relative humidity is 50 to 90%, preferably 40 to 80%, and the wind speed is 0 to 3 MPH.

[0108] Application of the present compound or Composition A may reduce the mycotoxin content in harvested materials and in foods and feeds prepared therefrom. The mechanism of the mycotoxin-reducing effect is not limited, but may be exerted, for example, by a direct or indirect action on mycotoxin-producing bacteria. Examples of direct effects include a bactericidal effect on mycotoxin-producing bacteria and an inhibitory effect on mycotoxin biosynthesis. Examples of indirect effects include effects on the microbiome, such as the ratio of mycotoxin-producing to non-producing bacteria, and a reduction in fungal infections by suppressing feeding damage by harmful arthropods. Examples of mycotoxins include, but are not limited to, the following: Deoxynivalenol (DON), nivalenol, fusarenon X, 15-Ac-DON, 3-Ac-DON, T2- and HT2-toxins, neosolaniol, fumonisins, zearalenone, moniliformin, fusarin, diacetoxyscirpenol (DAS), beauvericin, enniatins, fusaroproliferin, fusarenol, ochratoxin, patulin, sterigmatocystin, maltodine, citrinin, rugulosine, rubratoxin, citreoviridin, cyclochlorotine, luteoskairin, lolitrem B, suraflamin, sporidesmin, ergot alkaloids (e.g., lysergic acid, ergotamine, ergometrine), aflatoxins, and cyclopiazonic acid. These mycotoxins can be produced, for example, by the following fungi: Fusarium species such as F. acuminatum, F. asiaticum, F. avenaceum, F. crookwellense, F. culmorum, F. graminearum (Gibberella zeae), zeae), F. equiseti, F. fujikoroi, F. moniliforme, F. musarum, F. oxysporum, F. proliferatum, F. poae, F. pseudograminearum, F. sam-bucinum, F. sam-bucinum, F. scirpi, F. semitectum, F. solani, F. sporotrichoides, F. langsethiae, F. subglutinans, F. tricinctum, F. verticillioides, etc.; Aspergillus species, such as A. flavus, A. parasiticus, A. nomius. , A. ochraceus, A. carbonarius, A. clavatus, A. terreus, A. versicolor; Penicillium species such as P. verrucosum, P. viridicatum, P. citrinum, P. expansum, P. claviforme, P. roqueforti, Claviceps species such as C. purpurea.Stachybotrys species; Slafractonia species, such as S. leguminicola; Neotyphodium species, such as N. lolii; Pithomyces species, such as P. chartarum.

[0109] Application of the present compound or composition A can improve the seedling establishment rate of plants, improve plant growth, and improve resistance to abiotic stress (for example, improved resistance or tolerance to high or low temperatures, improved resistance to drought, excessive moisture, or salt contained in water or soil, improved resistance to osmotic stress, improved resistance to dryness stress, improved resistance to ozone exposure, improved resistance to ultraviolet stress, improved resistance to wind stress, and improved resistance to sunshine stress), depending on the plant species or plant variety, their growing location, and growing conditions (soil, climate, growing season, nutrients). In some cases, the benefits of using an improved plant include increased fertility, improved flowering ability, improved ease of harvesting, accelerated maturation, increased yield, increased number, size or weight of seeds or fruits, improved green leaf color, longer leaf green color, increased number of healthy leaves, retarded senescence, reduced plant lodging, earlier flowering, increased number of flowers or fruits, increased fruit set, improved quality and / or increased nutritional value of the harvested product (e.g., increased sugar content in the fruit, improved gluten strength, optimized protein content, optimized oil content, improved nutritional value), improved storage stability and / or improved processability of the harvested product. More specifically, examples of improvements in plant growth include promoting stem elongation, promoting stem thickening, promoting an increase in the number or total area of ​​leaves, increasing the number of healthy leaves, and promoting stem branching (e.g., promoting an increase in the number of stem branches), promoting lateral root formation (e.g., increasing the number of lateral roots), increasing the number of auxin-producing sites in the roots (tap root or lateral roots), promoting root elongation, improving root extension, and promoting root thickening. It may also be possible to improve tolerance to nutritional stress caused by a deficiency of any of the 17 essential nutrients (essential elements) for plant growth.

[0110] When Composition B is used to control weeds in non-agricultural land, the application amount can be varied over a wide range depending on the type and frequency of weeds to be controlled, the formulation, application time, application method, application location, weather conditions, etc. Specific application methods include, for example, when applied to non-agricultural land with soil, treatment of weeds or areas where weeds grow, such as railways, factory sites, company sites, school sites, residential sites, rivers, ponds, under pipelines, roadsides, parks, and embankments. For example, when applied to non-agricultural land without soil, treatment of building walls and rooftops, and treatment of pools and water systems of water and sewage facilities can be included. When applied to building materials, methods such as mixing or coating the building materials can be used. When Composition B is used for weed control in non-agricultural land, the application rate for surface application is 1 m2. 2 The amount of one active ingredient per square meter is usually 0.01 to 1000 mg, preferably 10 to 500 mg, more preferably 20 to 400 mg (specifically, for example, 25 mg, 50 mg, or 400 mg). When treating in a space, the application amount is 1 m2 of the treatment space. 3 The application amount when treating in water is usually 0.001 to 1000 mg, more preferably 0.01 to 100 mg, of one active ingredient per 1 L of water volume.

[0111] Examples of plants for which Composition B can be used include: Crops: Corn (horse-tooth, hard-grain, soft-grain, explosive, glutinous, sweet, field corn), rice (long-grain, short-grain, medium-grain, japonica, tropical japonica, indica, javanica, paddy rice, upland rice, floating rice, direct-seeded rice, transplanted rice, glutinous rice), wheat (bread wheat (hard, soft, medium, red wheat, white wheat), durum wheat, spelt wheat) , club wheat, each winter wheat type, spring wheat type), barley (two-row barley (= malting barley), six-row barley, naked barley, waxy barley, each winter barley type, spring barley type), rye (winter rye type, spring rye type), triticale (winter triticale type, spring triticale type), oats (winter oat type, spring oat type), sorghum, cotton (upland type, pima type), soybean (fully harvested seed varieties, edamame varieties, green-harvested varieties, each indeterminate type, determinate type, semi-determinate type), groundnut (peanut), Japanese bean (kidney bean), lima bean, adzuki bean, cowpea, mung bean, urad bean, scarlet runner bean, bamboo bean, moss bean, tepary bean, faba bean, Grains, chickpeas, lentils, lupins, pigeon peas, alfalfa, potatoes (tetraploid, diploid, true seed varieties), buckwheat, sugar beets (for sugar production, animal feed, root vegetables, leafy vegetables, fuel), rapeseed (winter rapeseed type, spring rapeseed type), canola (winter canola type, spring canola type), sunflowers (for oil extraction, food, ornamental), sugarcane, tobacco, tea plants, mulberry, etc. Vegetables: Solanaceae vegetables (eggplant, tomato, bell pepper, chili pepper, bell pepper, etc.), Cucurbitaceae vegetables (cucumber, pumpkin, zucchini, watermelon, melon, squash, etc.), Cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, mustard greens, broccoli, cauliflower, etc.), Asteraceae vegetables (burdock, chrysanthemum, artichoke, lettuce, etc.), Liliaceae vegetables (leeks, onions, garlic, asparagus, etc.), Umbelliferae vegetables (carrots, parsley, celery, parsley, etc.), Chenopodiaceae vegetables (spinach, Swiss chard, etc.), Lamiaceae vegetables (perilla, mint, basil, lavender, etc.), strawberries, sweet potatoes, yams, taro, etc. Fruit trees: pome fruits (apples, European pears, Japanese pears, Chinese pears, quince, quince, etc.), stone fruits (peaches, plums, nectarines, plums, cherries, apricots, prunes, etc.), citrus fruits (Satsuma mandarins, oranges, lemons, limes, grapefruit, etc.), nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashews, macadamia nuts, etc.), berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, persimmons, figs, olives, loquats, bananas, coffee, dates, coconuts, etc. Ornamental plants; flowering trees, street trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar, redbud, liquidamum, sycamore, zelkova, arborvitae, fir, hemlock, juniper, pine, spruce, yew), flowers, ornamental plants, lawn grasses.

[0112] The above-mentioned plants are not limited as long as they are varieties that are commonly cultivated.

[0113] Examples of corn varieties include: P30F53, P30F53RR, P30F53YHV, DKB390, DKB390IPRO3, DKC62-08, DKC35-88RIB RR2 BT, P7958AM RR2 LL BT, NK1120-3122 RR+GLU+ECB+CRW, P9608AM LL RR2 CRW ECB, Golden Bantam

[0114] Examples of wheat varieties include: PAKITO; KWS Zyatt; Skyfall; Crusoe; RGT Illustrious; KWS Extrase; KWS Extase; KWS Siskin; LG Detroit; KWS Lili; KWS Firefly; KWS Barrel; Elicit; KWS Basset; Zulu; Viscount; Revelation; SY Insight; KWS Kinetic; Gleam; RGT Gravity; KWS Kerrin; Shabras; Graham; KWS Crispin; Theodore; Dunston; Costello

[0115] Examples of barley varieties include: Electrum; Craft; SY Venture; KWS Hawking; LG Mountain; KWS Gimlet; Jordan; LG Flynn; KWS Orwell; Valerie; Surge; KWS Creswell; KWS Tower; KWS Glacier; California; KWS Cassia; Belmont; SY Kingsbarn; SY Baracooda; Cosmopolitan; SY Tungsten; LG Diablo; Laureate; RGT Planet; RGT Asteroid; Iconic; KWS Sassy; Sienna; Propino; Fairing; Concerto; Fairway; Prospect

[0116] Examples of soybean varieties include: 5G8015 RR IPRO; ANTA 82 PR; AS 3797 IPRO; BMX POTENCIA RR; BRS 8170IPRO; BRS 8280 RR; DM 6583 IPRO; M 5947 IPRO; M 6410 IPRO; M 8644 IPRO; M8372 IPRO; M9114PR; MONSOY 5947 IPRO; MONSOY 7730 IPRO; MSOY 8372 IPRO; NA 5909 RG; NS 5445 IPRO; NS 5909 PR; NS 5969 IPRO; NS 6700 IPRO; ST 797; TMG 1180 RR; TMG 1188 RR NS 4823 RR; NS 5445 IPRO; NA 5909 RR; NS 6209 RR; NS 6601 IPRO; NS 6823 RR; NS 6906 IPRO; NS 7000 IPRO; NS 7200 RR; NS 7227 RR; NS 7300 IPRO; NS 7474 IPRO; NS 7505 IPRO; NS 7709 IPRO; NS 8270 IPRO; NS 8393 IPRO RR; NS 5106 IPRO; NS 5727 IPRO; NS 5959 IPRO; NS 6390; NS 6700 IPRO; NS 6828; NS 6909 IPRO - Centro; NS 7000 IPRO -SUL; NS 7202 IPRO; NS 7237 IPRO; NA 7337 RR; NS 7490 RR; NS 7667 IPRO; NS 7901; NS 8338 IPRO; NS 8490 IPRO; NS 5160 IPRO; NA 5909- RG IPRO; NS 6006 IPRO; NS 6535 IPRO; NS 6767 RR; NS 6906 IPRO - Centro; NS 6909 IPRO - Sul; NS 7070 IPRO; NS 7209 IPRO; NS 7300 IPRO - Centro; NS 7338 IPRO; NS 7497 RR; NS 7670 RR ; NS 8094 RR; NS 8383 RR; Syn 15600 IPRO;Syn 16861 IPRO; Syn 1059 RR; Syn 1163 RR; Syn 1258 RR; Syn 1281 RR; Syn 1683 IPRO; Syn 1785 IPRO; Syn 1687 IPRO; Syn 13610 IPRO; Syn 15640 IPRO; Syn 15630 IPRO; Syn 1562 IPRO; Syn 1561 IPRO; Syn 1366 IPRO; CZ 15B64 IPRO; CZ15B70 IPRO; CZ 15B92 IPRO; CZ 26B05 IPRO; CZ 26B10 IPRO; CZ 26B77 IPRO; CZ 7022 IPRO; CZ 26B42 IPRO; CZ 26B36 IPRO; CZ 26B42 IPRO; CZ 26B77 IPRO; TEC 7022 IPRO; CZ 37B22 IPRO; CZ 37B43 IPRO; CZ 47B90 IPRO; CZ 58B28 IPRO; CZ 48B32 IPRO; CZ 58B61 IPRO; W 791 RR; W 842 RR; CZ 58B61 IPRO; BS 1511 IPRO; BS 1543 IPRO; ST 575 IPRO; BS 1580 IPRO; ST 592 IPRO; BS 2590 IPRO; BS 2606 IPRO- SUL; ST 644 IPRO; BSIRGA 1642 IPRO; TEC 6702 IPRO; BS 1691 IPRO; TEC 7849 IPRO; TECIRGA 6070 RR; BS 1519 LL; BS 2606 IPRO -CERRADO; TEC 6702 IPRO -CERRADO; TEC 7849 IPRO-CERRADO; ST 721 IPRO; TEC 7578 IPRO; ST 777 IPRO; ST 797 IPRO; ST 804 IPRO; ST 830 IPRO; ST 845 IPRO; W 787 IPRO; W 799 RR; ST 815 RR; ST 820 RR; ST 860 RR; ST 920 RR; W 870; BRASMAX COMPACTA IPRO; BRASMAX FIBRA IPRO BRASMAX ZEUS IPRO; BRASMAX DELTA IPRO; BRASMAX RAIO IPRO; BRASMAX ICONE IPRO; BRASMAX LANCA IPRO; BRASMAX GARRA IPRO; BRASMAX PONTA IPRO BRASMAX VALENTE RR; BRASMAX POTENCIA RR; BRASMAX TORNADO RR; BRASMAX ALVO RR; BRASMAX ATIVA RR; BRASMAX VELOZ RR; BRASMAX VELOZ RR; BRASMAX VORAZ IPRO; BRASMAX EXTREMA IPRO; BRASMAX UNICA IPRO; BRASMAX DOMINIO IPRO; BRASMAX FOCO IPRO; BRASMAX EXTREMA IPRO; BRASMAX EXTRA IPRO; BRASMAX CERTA IPRO; BRASMAX POWER IPRO; BRASMAX ULTRA IPRO; BRASMAX FLX IPRO; BRASMAX BONUS; BRASMAX PONTA IPRO; BRASMAX OPUS IPRO; BRASMAX DESAFIO RR; M5705IPRO; MS5838IPRO; M5892IPRO; M8644IPRO; M5917IPRO; M5947IPRO; M6210IPRO; M7739IPRO; M8349IPRO; M8372IPRO; M6410IPRO; M7110IPRO; M7198IPRO; M8210IPRO; M8808IPRO; 95R51; 95Y52; 97R22IPRO; 99R03; P98Y70; 95R90IPRO; 95Y72; 98Y21IPRO; 99R09; 95R95IPRO; 96Y90; 98Y30; P98C81; BG4290; BG4786; CD2720 IPRO; CD2728 IPRO; CD2820 IPRO; CD2851 IPRO; CD2857 RR; DS5916 IPRO; 5D6215 IPRO; 5D634 RR; 5G8015 IPRO; DS6017 IPRO; DS7417 IRPO; B5860 IPRO; BG4781 IPRO; DS6217 IPRO; TMG2375 IPRO; TMG2379 IPRO; TMG7058 IPRO; TMG2165 IPRO; TMG2165 IPRO; TMG4377 IPRO; TMG1180 RR;TMG7063IPRO; TMG7062 IPRO; TMG7067 IPRO; TMG4182; TMG4182; TMG7262 RR; TMG2185 IPRO; TMG7061 IPRO; TMG2381 IPRO; TMG2383 IPRO; TMG1288 RR; TMG2181 IPRO; TMG1188 RR; TMG2378 IPRO; TMG2173 IPRO; TMG4185; TMG 7363 RR: TMG7260 IPRO; TMG133 RR; TMG132 RR; ANTA82; TMG1182 RR; TMG2182 IPRO; TMG7161 RR; TMG2183 IPRO; TMG2286 IPRO; K8620 IPRO; RK5519 RR; M6210 IPRO; RK6719 IPRO; RK6316 IPRO; RK7518 IPRO; RK8115 IPRO; RK8317 IPRO; RK5813 RR; RK6813 RR; BRS 1001IPRO; BRS 1074IPRO; BRS 6970IPRO; BRS 7570IPRO; BRS 9383IPRO; BRS 1003IPRO; BRS 706IPRO; BRS 7170IPRO; BRS 7780IPRO; BRS 1007IPRO; BRS 713IPRO; BRS 7270IPRO; BRS 7180IPRO; BRS1010IPRO; BRS 729IPRO; 413RR; BRS 8890RR; BRSGO 8151RR; BRSMG 850GRR; BRS 378RR; BRSMG 760SRR; BRS 9090RR; BRS 740SRR; 750SRR; BRS Sambaiba RR; BRS 359RR; BRS 399RR; BRS 8160RR; BRS 7460RR; BRSMG 811CRR; BRS VALIOSA RR; BRS 232; BRS 283; BRS 257;BRS 284; BRSGO LUZIANIA; BRS Petala; BRSMG 790A; BRSMG 7525; MG / BR 46 (Conquista); BRS 8381; BRS 217 (Flora); BRS 252 (Serena); BRSMG 810C; BRSMG 68 (Vencedora); BRSGO Chapadoes; BRS Raimunda; BRS313 (TIETA); BRS Corisco; BRS Barreiras; BRS 314 (Gabriela); BRS Tracaja; BRS Perola

[0117] The variety of the plant is not particularly limited as long as it is a commonly cultivated variety.

[0118] The above-mentioned plants may be plants that can be produced by natural crossbreeding, plants that can be generated by mutation, F1 hybrid plants, or transgenic plants (also called genetically modified plants). These plants generally have characteristics such as herbicide resistance, accumulation of substances toxic to pests (also called pest resistance), suppression of susceptibility to diseases (also called disease resistance), increased yield potential, improved resistance to biotic and abiotic stress factors, altered product quality (e.g., increased or decreased content of specific components, changed composition, improved storability or processability), altered harvest time (e.g., very early, early, mid-season, late, very late), etc.

[0119] An F1 hybrid plant is a first generation hybrid obtained by crossing two varieties of different lineages, and generally has hybrid vigor characteristics with superior traits to either parent. A transgenic plant is a plant that has been endowed with characteristics that cannot be easily obtained by cross-breeding, mutagenesis, or natural recombination in a natural environment by introducing foreign genes from other organisms such as microorganisms.

[0120] Technologies for producing the above-mentioned plants include, for example, conventional breeding techniques, genetic engineering techniques, genomic breeding techniques, new breeding techniques, and genome editing techniques. Conventional breeding techniques involve obtaining plants with desirable traits through mutation or crossbreeding. Genetic engineering techniques involve extracting a gene (DNA) of interest from one organism (e.g., a microorganism) and introducing it into the genome of another target organism to confer new traits to that organism. Alternatively, antisense or RNA interference techniques can be used to silence other genes present in the plant to confer new or improved characteristics. Genomic breeding techniques use genomic information to improve the efficiency of breeding and include DNA marker (also called genome marker or gene marker) breeding and genomic selection. For example, DNA marker breeding is a method of selecting progeny carrying a desired gene for a useful trait from multiple crossbreeding progeny using DNA markers, which are DNA sequences that mark the location of specific useful trait genes on the genome. This method has the advantage of being able to effectively shorten the time required for breeding by analyzing the progeny of the cross using DNA markers when they are still young plants. Genomic selection is a method of creating a prediction formula based on previously obtained phenotype and genomic information, and predicting characteristics from the formula and genomic information without evaluating the phenotype. This technology can contribute to the efficiency of breeding. New breeding techniques are a general term for plant improvement (breeding) techniques that combine molecular biological methods. Examples include cisgenesis / intragenesis, oligonucleotide-directed mutagenesis, RNA-dependent DNA methylation, genome editing, grafting onto GM rootstocks or scions, reverse breeding, agroinfiltration, and seed production technology (SPT). Genome editing technology is a technique for sequence-specifically converting genetic information, allowing for deletion of base sequences, substitution of amino acid sequences, and introduction of foreign genes. These tools include zinc finger nucleases (ZFNs), TALENs, CRISPR / Cas9, CRISPR / Cpf1, and meganucleases, which are capable of sequence-specific DNA cleavage. Furthermore, there are sequence-specific genome modification technologies, such as CAS9 nickase and Target-AID, which are derived from the aforementioned tools.

[0121] Examples of the above-mentioned plants include those listed in the GM Approval Database on the electronic information site of the International Service for the Acquisition of Agri-Biotech Applications (ISAAA) (http: / / www.isaaa.org / ). More specifically, these include herbicide-resistant plants, pest-resistant plants, disease-resistant plants, plants with modified product quality (e.g., increased or decreased content of ingredients, changes in composition, improved storability or processability), plants with modified fertility traits, abiotic stress-tolerant plants, and plants with modified traits related to growth or yield.

[0122] Examples of plants that have been made tolerant to herbicides include: Herbicide resistance mechanisms include, for example, reduced affinity between the herbicide and its target; rapid metabolism (degradation, modification, etc.) of the herbicide due to the expression of enzymes that inactivate the herbicide; inhibition of herbicide uptake into the plant; and inhibition of herbicide translocation within the plant.

[0123] Plants that have been made tolerant to herbicides using genetic engineering technology include, for example, plants that have been made tolerant to protoporphyrinogen oxidase (hereinafter abbreviated as PPO) herbicides such as flumioxazin; 4-hydroxyphenylpyruvate dioxygenase (hereinafter abbreviated as HPPD) inhibitors such as isoxaflutole and mesotrione; acetolactate synthase (hereinafter abbreviated as ALS) inhibitors such as imidazolinone herbicides such as imazethapyr and sulfonylurea herbicides such as thifensulfuron methyl; 5-enolpyruvylshikimate-3-phosphate synthase (hereinafter abbreviated as EPSPS) inhibitors such as glyphosate; glutamine synthase inhibitors such as glufosinate; auxin herbicides such as 2,4-D and dicamba; and oxynil herbicides such as bromoxynil. Preferred herbicide-tolerant transgenic plants are cereals such as wheat, barley, rye, and oats, canola, sorghum, soybean, corn, cotton, rice, rapeseed, sugar beet, sugarcane, grapes, lentils, sunflower, alfalfa, pome fruits, stone fruits, coffee, tea, strawberry, turfgrass, tomato, potato, cucumber, and lettuce, and other vegetables, more preferably cereals such as wheat, barley, rye, and oats, soybean, corn, rice, grapes, tomato, potato, and pome fruits. Specific herbicide-tolerant plants are shown below. Glyphosate herbicide-resistant plants: These plants can be obtained by introducing one or more of the following genes: a glyphosate-resistant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4; a glyphosate N-acetyltransferase gene (gat4601 or gat4621) modified from the glyphosate N-acetyltransferase gene derived from Bacillus licheniformis; a glyphosate oxidase gene (goxv247) derived from Ochrobacterum anthropi strain LBAA; or a glyphosate-resistant EPSPS gene (mepsps or 2mepsps) derived from corn (Zea mays). Major plants include, for example, alfalfa (Medicago sativa), Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.), creeping bentgrass (Agrostis stolonifera), corn (Zea mays L.), Polish canola (Brassica rapa), potato (Solanum tuberosum L.), soybean (Glycine max L.), sugar beet (Beta vulgaris), and wheat (Triticum aestivum). Some glyphosate-tolerant plants are commercially available. For example, genetically modified plants into which CP4 epsps has been introduced are sold under trade names including "Roundup Ready (registered trademark)," genetically modified plants into which gat4601 or gat4621 has been introduced are sold under trade names such as "Optimum GAT (trademark)" and "Optimum (registered trademark) Gly canola," and genetically modified plants into which mepsps or 2mepsps has been introduced are sold under the trade name "GlyTol (trademark)."More specific glyphosate-tolerant plants include, for example, corn varieties such as "Roundup Ready™ Maize," "Roundup Ready™ 2 Maize," "Agrisure™ GT," "Agrisure™ GT / CB / LL," "Agrisure™ GT / RW," "Agrisure™ 3000GT," "YieldGard™ VT™ Rootworm™ RR2," and "YieldGard™ VT Triple"; soybeans varieties such as "Roundup Ready™ Soybean" and "Optimum GAT™"; cotton varieties such as "Roundup Ready™ Cotton," "Roundup Ready™ Flex Cotton," and "GlyTol™"; canola varieties such as "Roundup Ready™ Canola" and "Optimum® Gly canola"; alfalfa varieties such as "Roundup Ready™ Alfalfa"; rice varieties such as "Roundup Ready™ Canola" and "Optimum® Gly canola"; sugarcane is sold under the trade names "Roundup Ready™ Rice"; sugarcane is sold under the trade names "Roundup Ready™ sugarbeet" and "InVigor™ sugarbeet"; and wheat (Triticum aestivum) is sold under the trade names "Roundup Ready™ wheat." Glyphosinate herbicide-tolerant plants: These can be obtained by introducing one or more of the following genes: the phosphinothricin N-acetyltransferase (PAT) gene (bar) from Streptomyces hygroscopicus, the PAT gene (pat) from Streptomyces viridochromogenes, or the synthetic PAT gene (pat syn) from Streptomyces viridochromogenes strain Tu494. Major plants include, for example, Argentine canola (Brassica napus), chicory (Cichorium intybus), cotton (Gossypium hirsutum L.), corn (Zea mays L.), Polish canola (Brassica rapa), rice (Oryza sativa L.), soybean (Glycine max L.), and sugar beet (Beta vulgaris). Some glufosinate-tolerant plants are commercially available. For example, transgenic plants incorporating bar or pat are sold under the trade names "LibertyLink™," "InVigor™," or "WideStrike™." More specific glyphosinate-tolerant plants are sold under the trade names, for example, "Roundup Ready™ 2," "Liberty Link™," "Herculex™ I," "Herculex RW," "Herculex XTRA™," "Agrisure™ GT / CB / LL," "Agrisure™ CB / LL / RW," and "Bt10" for corn; "FiberMax™ Liberty Link™" for cotton; "Liberty Link™ Rice" for rice; "inVigor™ Canola" for canola; "Liberty Link™ Soybean" for soybeans; and "Liberty Link™ sugarbeet" for sugarcane. Oxynil-herbicide (e.g., bromoxynil)-resistant plants can be obtained by introducing the nitrilase gene (bxn) derived from Klebsiella pneumoniae subsp. Ozaenae. Major plants include Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.), and tobacco (Nicotiana tabacum L.). Several oxynil-herbicide-resistant plants are commercially available. For example, they are sold under trade names including "Navigator™" or "BXN™." More specific examples of oxynil-herbicide-resistant plants include cotton sold under the trade names "BXN™ Cotton" and Argentine canola sold under the trade names "Navigator™ Cotton." ALS herbicide-resistant plants: Carnations (Dianthus caryophyllus) into which the ALS gene (surB) derived from tobacco (Nicotiana tabacum) conferring resistance to ALS herbicides has been introduced as a selection marker are commercially available under the trade names, for example, "Moondust™," "Moonshadow™," "Moonshade™," "Moonlite™," "Moonaqua™," "Moonvista™," "Moonique™," "Moonpearl™," "Moonberry™," and "Moonvelvet™." Flax (Linum usitatissumum L.) into which the ALS gene (als) derived from Arabidopsis thaliana conferring resistance to ALS herbicides has been introduced is commercially available under the trade name, for example, "CDC Triffid Flax." Corn (Zea mays L.) with resistance to sulfonylurea and imidazolinone herbicides, which has been introduced with the corn-derived ALS gene (zm-hra) conferring resistance to ALS herbicides, is commercially available under the trade name "Optimum GAT™." Soybeans with resistance to imidazolinone herbicides, which have been introduced with the Arabidopsis-derived ALS gene (csr1-2), are commercially available under the trade name "Cultivance." Soybeans with the soybean (Glycine max)-derived ALS gene (gm-hra) conferring resistance to ALS herbicides, are commercially available under the trade names "Treus™," "Plenish™," and "Optimum GAT™." Cotton is also available with the tobacco (Nicotiana tabacum cv. Xanthi)-derived ALS gene (S4-HrA) conferring resistance to ALS herbicides. HPPD herbicide-tolerant plants: These plants are obtained by introducing the HPPD gene (avhppd-03) derived from oat (Avena sativa). For example, soybeans that have been introduced with the PAT gene (pat) derived from Streptomyces viridochromogenes at the same time as the HPPD gene are sold under the trade name "Herbicide-tolerant Soybean line" as soybeans that are tolerant to mesotrione and glufosinate. 2,4-D-resistant plants or ACCase herbicide-resistant plants: Corn that is resistant to 2,4-D or ACCase herbicides, into which the aryloxyalkanoate dioxygenase gene (aad-1) derived from Sphingobium herbicidovorans has been introduced, is sold under the trade name "Enlist™ Maize," for example. Soybeans and cotton that are resistant to 2,4-D or ACCase herbicides, into which the aryloxyalkanoate dioxygenase gene (aad-12) derived from Delftia acidovorans has been introduced, are known, and are sold under the trade name "Enlist™ Soybean," for example. Dicamba herbicide-tolerant plants can be obtained by introducing the dicamba monooxygenase gene (dmo) from Stenotrophomonas maltophilia strain DI-6. Soybeans and cotton plants carrying this gene are known. Soybeans (Glycine max L.) carrying the glyphosate-tolerant EPSPS gene (CP4 epsps) from Agrobacterium tumefaciens strain CP4, along with the dicamba monooxygenase gene (dmo), are commercially available under the trade name "Genuity® Roundup Ready™ 2 Xtend™." Further plants with engineered herbicide tolerance are widely known, for example, alfalfa, apple, barley, eucalyptus, flax, grape, lentil, rapeseed, pea, potato, rice, sugar beet, sunflower, tobacco, tomato, turfgrass, and wheat that are tolerant to glyphosate (see, e.g., US5188642, US4940835, US5633435, US5804425, US5627061); bean, cotton, soybean, pea, potato, sunflower, tomato that are tolerant to dicamba. , tobacco, corn, sorghum and sugarcane (see, for example, WO2008 / 051633, US7105724 and US5670454); soybean, sugar beet, potato, tomato and tobacco that are resistant to glufosinate (see, for example, US6376754, US5646024, US5561236); cotton, peppers, apple, tomato, sunflower, tobacco, potato, corn, cucumber, wheat, soybean, sorghum and millet that are resistant to 2,4-D (see, for example, US6153401, canola, corn, millet, barley, cotton, mustard, lettuce, lentil, melon, foxtail millet, oat, natto, potato, rice, rye, sorghum, soybean, sugar beet, sunflower, tobacco, tomato, and wheat (see, e.g., US 6,100,446, WO 2005 / 107437, US 5,608,147, and US 5,670,454) that are resistant to ALS-inhibiting herbicides (e.g., sulfonylurea herbicides or imidazolinone herbicides); Rice plants that are resistant to herbicides, particularly imidazolinone herbicides, are known, including rice plants with specific mutations in the acetohydroxyacid synthase gene (e.g., S653N, S654K, A122T, S653(At)N, S654(At)K, A122(At)T (see, e.g., US2003 / 0217381, WO2005 / 020673); HPPD inhibitor herbicides (e.g., isoxazole herbicides such as isoxaflutole);Barley, sugarcane, rice, corn, tobacco, soybean, cotton, rapeseed, sugar beet, wheat and potato that are resistant to triketone herbicides such as sulcotrione and mesotrione; and pyrazole herbicides such as pyrazolinates) or diketonitrile degradation products of isoxaflutole (see, for example, WO2004 / 055191, WO1996 / 38567, WO1997 / 049816 and US6791014); and wheat, soybean, cotton, sugar beet, rapeseed, rice, corn, sorghum, sugarcane and sugar beet that are resistant to PPO-inhibiting herbicides (see, for example, US2002 / 0073443, US2008 / 0052798, Pest Management Science, 61, 2005, 277-285).

[0124] Examples of plants that have been conferred herbicide tolerance by conventional breeding techniques or genomic breeding techniques include rice "Clearfield® Rice," wheat "Clearfield® Wheat," sunflower "Clearfield® Sunflower," lentils "Clearfield® lentils," and canola "Clearfield® canola" (BASF products) that are resistant to imidazolinone ALS-inhibiting herbicides such as imazethapyr and imazamox; soybean "STS soybean" that is resistant to sulfonylurea ALS-inhibiting herbicides such as thifensulfuron methyl; and corn "SR corn" ("Poast Protected®") that is resistant to acetyl-CoA carboxylase inhibitors such as trione oxime herbicides and aryloxyphenoxypropionic acid herbicides. corn"); ExpressSun® sunflower tolerant to sulfonylurea herbicides such as tribenuron; Provisia™ Rice tolerant to acetyl-CoA carboxylase inhibitors such as quizalofop; and Triazine Tolerant Canola canola tolerant to photosystem II inhibitors; and Igrowth™ sorghum tolerant to imidazolinone herbicides.

[0125] Examples of plants conferred herbicide tolerance through genome editing include "SU Canola®," a canola strain with sulfonylurea herbicide tolerance developed using the Rapid Trait Development System (RTDS®). RTDS® is a genome editing technology called oligonucleotide-directed mutagenesis, which uses gene repair oligonucleotides (GRONs), i.e., chimeric DNA-RNA oligonucleotides, to introduce mutations without cleaving the plant's DNA. Other examples include maize, which has been conferred herbicide tolerance and reduced phytic acid content by deleting the endogenous IPK1 gene using zinc finger nucleases (see, for example, Nature 459, 437-441, 2009); and rice, which has been conferred herbicide tolerance using CRISPR-Cas9 (see, for example, Rice 7, 5, 2014).

[0126] An example of a plant that has been conferred herbicide tolerance through new breeding techniques is soybean, whose scion has been conferred the properties of a GM rootstock through grafting. Specifically, a soybean scion that has been conferred glyphosate tolerance using Roundup Ready® soybean, which has glyphosate tolerance, as a rootstock, has been conferred glyphosate tolerance (see Weed Technology 2013, 27, 412).

[0127] Examples of plants that have been given pest resistance include:

[0128] Examples of plants that have been conferred resistance to lepidopteran pests through genetic engineering include corn (Zea mays L.), soybean (Glycine max L.), cotton (Gossypium hirsutum L.), rice (Oryza sativa L.), poplar (Populus sp.), tomato (Lycopersicon esculentum), eggplant (Solanum melongena), and sugarcane (Saccharum sp.) into which a gene encoding delta-endotoxin, an insecticidal protein derived from the soil bacterium Bacillus thuringiensis (hereafter abbreviated as Bt), has been introduced. Delta-endotoxins that confer resistance to lepidopteran pests include, for example, Cry1A, Cry1Ab, modified Cry1Ab (Cry1Ab with a deleted portion), Cry1Ac, Cry1Ab-Ac (a hybrid protein in which Cry1Ab and Cry1Ac are fused), Cry1C, Cry1F, Cry1Fa2 (modified Cry1F), moCry1F (modified Cry1F), Cry1A.105 (a hybrid protein in which Cry1Ab, Cry1Ac, and Cry1F are fused), Cry2Ab2, Cry2Ae, Cry9C, Vip3A, and Vip3Aa20. Examples of plants that have been conferred resistance to coleopteran pests through genetic engineering include corn and potato plants into which a gene encoding delta-endotoxin, an insecticidal protein derived from the soil bacterium Bt, has been introduced. Examples of delta-endotoxins that confer resistance to coleopteran pests include Cry3A, mCry3A (modified Cry3A), Cry3Bb1, Cry34Ab1, Cry35Ab1, Cry6A, Cry6Aa, and mCry6Aa (modified Cry6Aa). Examples of plants that have been conferred resistance to dipteran pests through genetic engineering include corn (Zea mays L.) transfected with a synthetic gene encoding the hybrid protein eCry3.1Ab, which combines Cry3A and Cry1Ab derived from the soil bacterium Bt, and cotton (Gossypium hirsutum L.) transfected with a gene encoding the trypsin inhibitor CpTI derived from cowpea (Vigna unguiculata).Furthermore, there are poplars transfected with a gene encoding API, a protease inhibitor protein A derived from arrowhead (Sagittaria sagittifolia), which exhibit resistance to a wide range of pests. An example of a plant that has been conferred resistance to nematodes by genetic engineering is soybean (Glycine max L.) into which a gene encoding Cry14Ab-1.b derived from the soil bacterium Bt has been introduced. Insecticidal proteins that confer pest resistance to plants also include hybrid proteins, partially deleted proteins, and modified proteins of the above insecticidal proteins. Hybrid proteins are produced by combining different domains of multiple insecticidal proteins using genetic engineering techniques, and known proteins include Cry1Ab-Ac and Cry1A.105. Examples of partially deleted proteins include Cry1Ab, which lacks a portion of its amino acid sequence. Examples of modified proteins include proteins in which one or more amino acids of a natural delta-endotoxin have been replaced, such as Cry1Fa2, moCry1F, and mCry3A. Modified proteins also include proteins in which a non-naturally occurring protease recognition sequence has been inserted into the toxin, such as Cry3A055, in which a cathepsin G recognition sequence has been inserted into the Cry3A toxin (see WO 2003 / 018810). Monsanto has developed cotton (event MON88702) that incorporates a modified BT protein, Cry51Aa2 (Cry51Aa2.834_16), using genetic engineering technology. This cotton exhibits resistance to lygus species such as Lygus lineolaris, Hemiptera such as aphids, and thrips such as Frankliniella species. Other insecticidal proteins that confer pest resistance to plants using genetic engineering techniques include insecticidal proteins derived from Bacillus cereus or Bacillus popilliae; plant insecticidal proteins Vip1, Vip2, Vip3 (subclasses Vip3Aa to Vip3Aj, Vip3Ba, Vip3B, and Vip3Ca are known, and specific examples include Vip3Aa20 and Vip3Aa61) and Vip4; insecticidal proteins derived from nematode-symbiotic bacteria (which form colonies with nematodes) such as Photorhabdus spp., such as Photorhabdus luminescens, or Xenorhabdus spp., such as Xenorhabdus nematophilus; and insecticidal proteins from the fern Tectaria insecticidal protein Tma12 derived from Tactaria macrodonata; insecticidal protein IPD083 derived from Adiantum spp.; insecticidal protein IPD113 derived from Pteris cretica cv. albolineata or Pteris umbrosa;albolineata or Pteris umbrosa); toxins produced by animals, including insect-specific neurotoxins such as scorpion toxins, spider toxins, and wasp toxins; toxins produced by filamentous fungi, such as Streptomycetes venom; plant lectins, such as pea lectin, barley lectin, and snowdrop lectin; agglutinins; protease inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, and papain inhibitors; ribosome-inactivating proteins (RIPs), such as ricin, corn-RIP, abrin, rufin, saporin, and bryodin; steroid metabolic enzymes, such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, and cholesterol oxidase; ecdysone inhibitors; HMG-CoA-reductase; ion channel inhibitors, such as sodium channel inhibitors and calcium channel inhibitors; juvenile hormone esterase; diuretic hormone receptors; stilbene synthase; bibenzyl synthase; chitinase; and glucanases.

[0129] Furthermore, plants that have been conferred pest resistance by introducing one or more insecticidal protein genes are already known, and some of these plants are commercially available. Examples of cotton that has been given pest resistance include "Bollgard™ cotton," "BXN™ Plus Bollgard™ Cotton," "BXN™ Plus Bollgard™ Cotton," "JK 1," "Roundup Ready™ Bollgard™ Cotton," and "Ingard™," which express the insecticidal protein Cry1Ac derived from Bt bacteria; "Herculex™ I" and "Herculex™ CB," which express the insecticidal protein modified Cry1F (Cry1Fa2) derived from Bt bacteria; "VIPCOT™ Cotton," which expresses the insecticidal protein Vip3A derived from Bt bacteria; "Bollgard II™ cotton," "Roundup Ready™ Bollgard II™ Cotton," and "Roundup Ready™ Flex™ Bollgard II™," which express the insecticidal proteins Cry1Ac and Cry2Ab derived from Bt bacteria. Cotton" and "Fivermax™ Liberty Link™ Bollgard II™" expressing the insecticidal proteins Cry1Ac, Cry2Ab, and Vip3A derived from Bt bacteria; "Bollgard III™" and "Bollgard™ III x Roundup Ready™ Flex™" expressing the insecticidal proteins Vip3A and Cry1Ab derived from Bt bacteria; "VIPCOT™ Roundup Ready Flex™ Cotton" expressing the insecticidal proteins Vip3A and Cry1Ac derived from Bt bacteria; "VIPCOT™ Cotton" expressing the insecticidal proteins Vip3A and Cry1Ac derived from Bt bacteria; "WideStrike™ Cotton", "WideStrike™ Roundup Ready™ Cotton" and "Widestrike™ Roundup Ready Flex™" expressing the insecticidal proteins Cry1Ac and Cry1F derived from Bt bacteria. Cotton"; "TwinLink™ Cotton" and "Glytol™ x Twinlink™" expressing the insecticidal proteins Cry1Ab and Cry2Ae derived from Bt bacteria;Examples of commercially available cotton include "Widestrike® 3" and "Widestrike™ x Roundup Ready Flex™ x VIPCOT™ Cotton," which express the insecticidal proteins Cry1Ac, Cry1F, and Vip3A derived from Bt bacteria; "Glytol™ x Twinlink™ x VIPCOT™ Cotton," which expresses the insecticidal proteins Cry1Ab, Cry2Ae, and Vip3A derived from Bt bacteria; and "Bollgard™ III ThryvOn™ Cotton," which expresses the insecticidal proteins Cry1Ac, Cry2Ab, Vip3A, and Cry51Aa2 derived from Bt bacteria. Examples of maize that have been conferred pest resistance include "YieldGard® Rootworm RW," "YieldGard® RW + RR," "YieldGard® VT® Rootworm® RR2," and "MaxGard®," which express the insecticidal protein Cry3Bb1 derived from Bt bacteria; "YieldGard® VT Triple" and "YieldGard® Plus with RR," which express the insecticidal proteins Cry3Bb1 and Cry1Ab derived from Bt bacteria; "Bt Xtra® Maize," which expresses the insecticidal protein Cry1Ac derived from Bt bacteria; "YieldGard Plus®," which expresses the insecticidal proteins Cry1Ab and Cry3Bb1 derived from Bt bacteria; "Bt10" and "Liberty Link® Yieldgard®," which express the insecticidal protein Cry1Ab derived from Bt bacteria. Maize," "Agrisure™ GT / CB / LL," and "YieldGard™ CB + RR"; containing the insecticidal protein Cry1A derived from Bt bacteria.YieldGard™ VT Pro™ and Genuity™ VT Double Pro™ expressing 105 and Cry2Ab2; Agrisure™ RW and Agrisure™ GT / RW expressing the insecticidal protein mCry3A derived from Bt bacteria; Starlink™ Maize expressing the insecticidal protein Cry9C derived from Bt bacteria; YieldGard™, MaizeGard™, NaturGard KnockOut™, Maximizer™, Roundup Ready™ YieldGard™ maize, Agrisure™ CB / LL, and Mavera™ YieldGard™ expressing the insecticidal protein Cry1Ab derived from Bt bacteria. Maize; Agrisure® 3122 expressing the insecticidal proteins Cry1Ab, Cry1F, modified Cry3A, Cyr34Ab1, and Cyr35Ab1 derived from Bt bacteria; Agrisure® Viptera expressing the insecticidal protein Vip3Aa20 derived from Bt bacteria; Agrisure® Viptera™ 2100 and Agrisure® Viptera™ 3110 expressing the insecticidal proteins Vip3Aa20 and Cry1Ab derived from Bt bacteria; and Agrisure® Viptera™ 3100, Agrisure® Viptera™ 3111, and Agrisure® Viptera™ expressing the insecticidal proteins Vip3Aa20, Cry1Ab, and modified Cry3A derived from Bt bacteria. 4"; "Agrisure® Viptera® 3220" expressing the insecticidal proteins Vip3Aa20, Cry1Ab, and modified Cry1F derived from Bt bacteria; "Agrisure® Duracade®" expressing the insecticidal protein eCry3.1Ab (a chimeric protein of Cry3A-Cry1Ab) derived from Bt bacteria; and "Agrisure® Duracade®" expressing the insecticidal protein eCry3.1Ab derived from Bt bacteria.Agrisure® Duracade™ 5122 expresses the insecticidal proteins eCry3.1Ab (a chimeric protein of Cry3A-Cry1Ab), modified Cry3A, Cry1Ab, and modified Cry1F; Agrisure® Duracade™ 5222 expresses the insecticidal protein eCry3.1Ab (a chimeric protein of Cry3A-Cry1Ab), modified Cry3A, modified Cry1Ab, and a Vip3A mutant derived from Bt bacteria; Herculex™ RW expresses the insecticidal proteins Cyr34Ab1 and Cyr35Ab1 derived from Bt bacteria; and Herculex™ RW expresses the insecticidal proteins Cyr34Ab1, Cyr35Ab1, and Cry1F derived from Bt bacteria. "Genuity® VT Triple Pro™" expressing the insecticidal proteins Cry1A.105, Cry2Ab2, and Cry3Bb1 derived from Bt bacteria; "Genuity® SmartStax™" expressing the insecticidal proteins Cry1F, Cry2Ab, Cyr34Ab1, Cyr35Ab1, Cry3Bb1, and Cry1A.105 derived from Bt bacteria; "Power Core™" expressing the insecticidal proteins modified Cry1F, Cry2Ab, and Cry1A.105 derived from Bt bacteria; and "Herculex XTRA™" expressing the insecticidal proteins modified Cry1F, Cyr34Ab1, and Cyr35Ab1 derived from Bt bacteria. These include "Optimum® Intrasect Xtreme" which expresses the insecticidal proteins modified Cry1F, Cyr34Ab1, Cyr35Ab1, Cry1Ab, and modified Cry3A derived from Bt bacteria; "Optimum® Intrasect XTRA" which expresses the insecticidal proteins modified Cry1F, Cyr34Ab1, Cyr35Ab1, and Cry1Ab derived from Bt bacteria; and "Optimum® TRIsect" which expresses the insecticidal proteins modified Cry1F and modified Cyr3A derived from Bt bacteria. Other commercially available examples of plants that have been conferred pest resistance include the potato varieties "Atlantic NewLeaf™ potato," "NewLeaf™ Russet Burbank potato," "Lugovskoi plus," "Elizaveta plus," "Hi-Lite NewLeaf™ Y potato," "Superior NewLeaf™ potato," and "Shepody NewLeaf™ Y potato," which express the insecticidal protein Cry3A derived from Bt bacteria; the rice varieties "hanyou 63" and "Huahui-1," which express the insecticidal proteins Cry1Ab and Cry1Ac derived from Bt bacteria; the soybean "Intacta™ Roundup Ready™ 2 Pro," which expresses the insecticidal protein Cry1Ac derived from Bt bacteria; and the eggplant varieties "BARI Bt Begun-1, -2, -3, and -4," which express the insecticidal protein Cry1Ac derived from Bt bacteria. Also available are corn rootworm-resistant corn varieties "YieldGard corn rootworm," "YieldGard VT," "Herculex RW," "Herculex Rootworm," and "Agrisure CRW"; corn borer-resistant corn varieties "YieldGard corn borer," "YieldGard plus," "YieldGard VT Pro," "Agrisure CB / LL," "Agrisure 3000GT," "Hercules I," "Hercules II," "KnockOut," "NatureGard," and "StarLink"; western bean cutworm-resistant corn varieties "Herculex I," "Herculex Xtra," "NewLeaf," "NewLeaf Y," and "NewLeaf Plus"; corn borer-resistant corn varieties "YieldGard Plus"; and cotton varieties "Bollgard I" and "Bollgard" resistant to tobacco budworm. Known varieties include "Bollgard II", "WideStrike™" and "VipCot" cotton varieties which are resistant to tobacco budworm, cotton bollworm, fall armyworm, beet armyworm, cabbage looper, soybean looper and pink bollworm; "NewLeaf", "NewLeaf Y" and "NewLeaf Plus" potato varieties which are resistant to tobacco hornworm; and "Bt brinjal", "Dumaguete Long Purple" and "Mara" eggplant varieties which are resistant to eggplant borer, fruit borer and cotton bollworm (see, e.g., US Pat. No. 5,128,130). Further pest-resistant plants are generally known, such as rice borer-resistant rice (see, for example, Molecular Breeding, Vol. 18 (2006), No. 1), lepidoptera-resistant lettuce (see, for example, US5349124), and rice resistant to lepidoptera (e.g., rice stem borer, skipper butterfly, rice armyworm, rice leaf borer, rice caseworm, and rice armyworm) (see, for example, WO2001 / 021821). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above publications.

[0130] As a plant that has been given pest resistance using RNA interference technology, corn that is resistant to Coleoptera pests (corn rootworms) is commercially available under the trade names "SmartStax(R) Pro" or "Vorceed Enlist(R)."

[0131] Examples of plants that have been conferred pest resistance by conventional breeding techniques or genomic breeding techniques include soybeans that are resistant to the soybean aphid (Aphis glycines) and have the aphid resistance genes "Rag1 (Resistance to Aphis glycines 1)" or "Rag2 (Resistance to Aphis glycines 2)" (see J. Econ. Entomol., 2015, 108, 326); soybeans that are resistant to the soybean cyst nematode (Heterodera glycines) (see Phytopathology, 2016, 106, 1444); and cotton that is resistant to the root-knot nematode (Meloidogyne incognita) (see J. Nematol., 2009, 41, 2016). 140); rice "Kanto BPH1" that is resistant to the brown planthopper; and soybean "Fukuminori" that is resistant to the common cutworm.

[0132] These plants to which pest resistance has been imparted have been imparted resistance to any harmful insects (particularly lepidopteran insects, coleopteran insects, diptera insects, and beetle insects), harmful spiders, and harmful nematodes. The plants to which pest resistance has been imparted are preferably selected from wheat (e.g., wheat, barley, rye, and oats), corn, canola, sorghum, soybeans, rice, rapeseed, sugar beet, sugarcane, grapes, lentil, sunflower, alfalfa, pome fruits, stone fruits, peanuts, coffee, tea, strawberries, turf, and vegetables (e.g., tomatoes, potatoes, cucurbits, and lettuce), more preferably selected from soybeans, corn, tomatoes, rice, and wheat (e.g., wheat, barley, rye, and oats), and most preferably selected from soybeans, rice, corn, and wheat (e.g., wheat, barley, rye, and oats).

[0133] Examples of plants that have been given disease resistance include:

[0134] Plants that have been made disease-resistant by genetic engineering are, for example, plants that express so-called "pathogenesis-related proteins" (PRPs, see, for example, EP 0 392 225) or so-called "antifungal proteins" (AFPs, see, for example, US 6,864,068). Various antifungal proteins active against plant pathogenic fungi have been isolated from specific plant species and are common knowledge. Examples of such antipathogenic substances and plants capable of synthesizing such antipathogenic substances are known, for example, from EP 0 392 225, WO 1993 / 05153, WO 1995 / 33818, and EP 0 353 191. Plants that are resistant to fungicidal, viral, and bacterial pathogens can be produced by introducing disease resistance genes. Numerous resistance genes have been identified, isolated, and used to improve disease resistance, including the N gene, which was introduced into tobacco lines susceptible to tobacco mosaic virus (TMV) to create TMV-resistant plants (see, e.g., U.S. Pat. No. 5,571,706), the Prf gene, which was introduced into plants to confer enhanced pathogen resistance (see, e.g., WO 1998 / 02545), and the Rps2 gene from Arabidopsis thaliana, which was used to engineer resistance to bacterial pathogens such as Pseudomonas syringae (see, e.g., WO 1995 / 028423). Plants exhibiting systemic acquired resistance responses have been obtained by introducing nucleic acid molecules encoding the TIR domain of the N gene (see, e.g., U.S. Pat. No. 6,630,618).Further examples of known resistance genes include the Xa21 gene, which has been introduced into numerous rice varieties (see, for example, US Pat. No. 5,952,485, US Pat. No. 5,977,434, WO 1999 / 009151, WO 1996 / 022375), the Rcg1 gene for resistance to Colletotrichum (see, for example, US Pat. No. 2006 / 225152), the prp1 gene (see, for example, US Pat. No. 5,859,332, WO 2008 / 017706), the ppv-cp gene, which confers resistance to plum pox virus (see, for example, US Pat. No. 5,859,332, WO 2008 / 017706), the P1 gene (see, for example, US Pat. No. 5,968,828), and the P2 gene, which confers resistance to Phytophthora infestans in potato. Examples of genes that can be used include genes such as Blb1, Blb2, Blb3, RB2, and Rpi-vnt1 for conferring resistance to P. infestans (see, for example, US7,148,397), the LRPKml gene (see, for example, WO1999 / 064600), the P1 gene for potato virus Y resistance (see, for example, US5,968,828), the HA5-1 gene (see, for example, US5,877,403 and US6,046,384), the PIP gene for conferring broad-spectrum resistance to viruses such as potato virus X (PVX), potato virus Y (PVY), and potato leaf curl virus (PLRV) (see, for example, EP0707069), and genes such as the NI16 gene, ScaM4 gene, and ScaM5 gene of Arabidopsis for conferring fungal resistance (see, for example, US6,706,952 and EP1018553). Furthermore, common beans resistant to Bean golden mosaic virus (hereinafter referred to as BGMV) are plants that have been conferred resistance using RNA interference technology. The double-stranded RNA genes for replication proteins (sense and antisense ac1 genes) are introduced into the plants, inhibiting synthesis of BGMV replication proteins, thereby conferring resistance to BGMV. Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above. Antipathogenic substances that can be expressed by such plants include, for example, ion channel blockers (sodium channel blockers, calcium channel blockers, etc.); viral KP1, KP4 and KP6 toxins; stilbene synthases; bibenzyl synthases; chitinases; glucanases; so-called "pathogenesis-related proteins" (PRPs; see, for example, EP 0 392 225); antipathogenic substances produced by microorganisms, such as peptide antibiotics, heterocyclic antibiotics (see, for example, WO 1995 / 033818) and protein or polypeptide factors involved in plant pathogen defense (the so-called "plant disease resistance genes" described in WO 2003 / 000906). Antipathogenic substances produced by plants can protect plants from various pathogenic microorganisms such as fungi, viruses, and bacteria. Useful plants that are of increasing interest in the present invention are wheat (e.g., wheat, barley, rye, and oats), soybean, corn, rice, rapeseed, pome fruits, stone fruits, peanuts, coffee, tea, strawberry, grass, vines and vegetables (e.g., tomato, potato), cucurbits, papaya, melon, lens plants, and lettuce, more preferably selected from soybean, tomato, rice, and wheat (e.g., wheat, barley, rye, and oats), and most preferably selected from soybean, rice, and wheat (e.g., wheat, barley, rye, and oats). Plants resistant to fungal pathogens include, for example, soybeans resistant to soybean rust (Phakopsora pachyrhizi and Phakopsora meibomiae) (see, for example, WO2008 / 017706); solanaceous plants such as cotton, tomato, and potato resistant to potato late blight (Phytophthora infestans) (see, for example, US5859332, US7148397, EP1334979); corn resistant to Colletotrichum such as Colletotrichum graminicola (see, for example, US2006 / 225152); apples resistant to apple scab (venturia inaequalis) (see, for example, WO1999 / 064600); and Fusarium species (see, for example, Fusarium graminearum, fusarium sporotrichioides, fusarium lateritium, fusarium pseudograminearum, fusarium sambucinum, fusarium culmorum, fusarium poae, fusarium acuminatum, fusarium Examples of such fungicide-resistant plants include plants (e.g., rice, wheat, barley, rye, corn, oats, potato, melon, soybean, and sorghum) that are resistant to Pseudomonas equiseti (see, for example, US6646184, EP1477557); and plants such as corn, soybean, wheat (especially wheat, barley, rye, and oats), rice, tobacco, sorghum, sugarcane, and potato that are broadly resistant to fungicides (see, for example, US5859332, US5689046, US6706952, EP1018553, and US6020129). Examples of plants resistant to bacterial pathogens include rice resistant to Xylella fastidiosa (see, e.g., US6232528); plants such as rice, cotton, soybean, potato, sorghum, corn, wheat, barley, sugarcane, tomato, and pepper resistant to bacterial blight (see, e.g., WO2006 / 42145, US5952485, US5977434, WO1999 / 09151, WO1996 / 22375); and tomatoes resistant to Pseudomonas syringae (see, e.g., Can. J. Plant Path., 1983, 5:251-255). Plants resistant to viral pathogens include, for example, stone fruits (e.g., plums, almonds, apricots, cherries, peaches, and nectarines) resistant to plum pox virus (see, for example, US Patent No. 15154Ps and EP0626449); potatoes resistant to potato virus Y (see, for example, US Patent No. 5968828); plants such as potatoes, tomatoes, cucumbers, and legumes resistant to tomato spotted wilt virus (see, for example, EP0626449 and US Patent No. 5973135); maize resistant to maize streak virus (see, for example, US Patent No. 6040496); and papaya ring spot virus. papaya resistant to cucumber mosaic virus (see, for example, US Pat. No. 6,046,384); cucurbits (e.g., cucumber, melon, watermelon, and pumpkin) and solanaceous plants (e.g., potato, tobacco, tomato, eggplant, paprika, chili pepper, and pepper) resistant to cucumber mosaic virus (see, for example, US Pat. No. 6,849,780); cucurbits (e.g., cucumber, melon, watermelon, and pumpkin) resistant to watermelon mosaic virus 2 and zucchini yellow mosaic virus (see, for example, US Pat. No. 6,015,942); potatoes resistant to potato leafroll virus (see, for example, US Pat. No. 5,576,202); potato virus X, potato virus Y Y), potatoes with broad resistance to viruses such as potato leafroll virus (see, for example, EP 0707069);Examples include common beans that are resistant to Bean golden mosaic virus (see, for example, Mol Plant Microbe Interact. 2007 Jun;20(6):717-26). Some plants are resistant to antibiotics (e.g., kanamycin, neomycin, and ampicillin). The naturally occurring bacterial nptII gene expresses an enzyme that blocks the action of the antibiotics kanamycin and neomycin. The ampicillin resistance gene, ampR (also known as blaTEM1), originates from the bacterium Salmonella paratyphi and is used as a marker gene in the transformation of microorganisms and plants. ampR is involved in the synthesis of beta-lactamase, an enzyme that neutralizes the penicillin group of antibiotics, including ampicillin. Plants having resistance to antibiotics include, for example, potato, tomato, flax, canola, rapeseed, rapeseed, and corn (see, for example, Plant Cell Reports, 20, 2001, pp. 610-615; Trends in Plant Science, 11, 2006, pp. 317-319; Plant Molecular Biology, 37, 1998, pp. 287-296; Mol Gen Genet., 257, 1998, pp. 606-13; Plant Cell Reports, 6, 1987, pp. 333-336; Federal Register (USA), Vol. 60, No. 113, 1995, pp. 31139; Federal Register (USA), Vol. 67, No. 226, 2002, pp. 70392; Federal Register (USA), Vol. 67, No. 226, 2002, pp. 70392). (USA), Vol. 63, No. 88, 1998, p. 25194; Federal Register (USA), Vol. 60, No. 141, 1995, p. 37870; Canadian Food Inspection Agency, FD / OFB-095-264-A, October 1999; FD / OFB-099-127-A, October 1999). Preferably, the plant is selected from soybeans, tomatoes, and wheat (e.g., wheat, barley, rye, and oats), and most preferably from soybeans and wheat (e.g., wheat, barley, rye, and oats). Available plants that have been made resistant to plant viruses include, for example, the papaya varieties 'Rainbow', 'SunUp', and 'Huanong No. 1', which have been made resistant to Papaya ringspot virus; the potatoes 'Innate® Hibernate', 'Innate® Glaciate', and 'Innate® Acclimate', which are resistant to Phytophthora infestans; and the potato variety 'Newleaf™', which is resistant to Potato Virus Y and / or Potato Leaf Curl Virus (PLRV).

[0135] Plants that have been conferred disease resistance by conventional breeding techniques or genomic breeding techniques include rice conferred resistance to blast; rice conferred resistance to sheath blight; wheat conferred resistance to leaf rust; wheat conferred resistance to stripe rust; wheat conferred resistance to stem rust; wheat conferred resistance to powdery mildew; wheat conferred resistance to leaf blotch; wheat conferred resistance to glume blotch; wheat conferred resistance to tan spot; barley conferred resistance to powdery mildew; barley conferred resistance to dwarf leaf rust; and net blotch. Barley with resistance to blotch; barley with resistance to scald; barley with resistance to Ramularia disease; corn with resistance to anthracnose; corn with resistance to gray leaf spot; corn with resistance to Goss's wilt; corn with resistance to Fusarium stalk rot; soybean with resistance to Asian soybean rust; soybean with resistance to Phytophthora stem and root rot; soybean with resistance to sudden death syndrome; pepper with resistance to Phytophthora rot; powdery mildew lettuce resistant to mildew; tomatoes resistant to bacterial wilt; tomatoes resistant to Gemini virus;Examples of such resistant plants include lettuce that has been made resistant to downy mildew; cruciferous plants such as rapeseed, cabbage, Brussels sprouts, cauliflower, collard greens (Borekale), and broccoli that have been made resistant to clubroot; cruciferous plants such as rapeseed, cabbage, Brussels sprouts, cauliflower, collard greens (Borekale), and broccoli that have been made resistant to black leg; and melons that have been made resistant to melon wilt caused by Fusarium oxysporum f.sp. melonis (see, for example, WO2009 / 000736).

[0136] Examples of plants that have been conferred disease resistance using genome editing technology include bread wheat, which is resistant to powdery mildew by deleting the powdery mildew resistance locus O (MLO) gene using talen and CRISPR-Cas9 (see, for example, Nat. Biotech., 32, 947-951, 2014); slmlo1 tomato (Tomelo), which is resistant to powdery mildew by deleting the SlMLO1 gene, one of the MLOs, using CRISPR-Cas9 (see, for example, Scientific Reports 7, Article number: 482, 2017); and Xanthomonas oryzae pv., which causes bacterial leaf blight, by editing the OsSWEET14 gene in rice using talen. oryzae) (see Nat. Biotechnol. 30, 390-392, 2012); rice resistant to Magnaporthe oryzae, which causes rice blast disease, by modifying the OsERF922 gene in rice using CRISPR-Cas9 (see PLoS ONE 11:e0154027. doi: 10.1371 / journal.pone.0154027, 2016); cucumber resistant to cucumber vein yellow ing virus (CVYV), zucchini yellow mosaic virus (ZYMV), and papaya ringspot virus-type W (PRSV-W) by disrupting the recessive eIF4E (eukaryotic translation initiation factor 4E) gene using CRISPR-Cas9 (see Mol. Plant Pathol.17, 7 1140-1153 (2016); soybean that is resistant to phytophthora stem and root rot caused by Phytophthora sojae by disrupting the RXLR effector genes (Avr4 / 6) using CRISPR-Cas9 (Mol Plant Pathol 17(1)127-139 (2016)).

[0137] Examples of plants that have been made disease-resistant through new breeding techniques include apples that are resistant to apple scab caused by Venturia inaequalis, which have been resistant to the disease by introducing the Rvi6 (formerly known as HcrVf2) gene through cisgenesis (see, for example, Plant Biotech. J., 12, 2-9, 2014). Another example is a sweet cherry tree in which the properties of a GM rootstock, a grafting-based breeding technique, have been transferred to a non-transgenic scion, imparting resistance to Prunus necrotic ringspot virus from a transgenic rootstock (see, for example, Plant Biotech. J., 12, 1319-1328, 2014).

[0138] Examples of plants with altered product qualities include: Altered product quality refers to the synthesis of an altered component or an increase or decrease in the amount of a component synthesized compared to the corresponding wild-type plant. Examples of plants with altered product quality include modified plants with increased or decreased vitamin, amino acid, protein, starch, various oil contents, and modified plants with reduced nicotine content.

[0139] Plants whose product quality has been modified using genetic engineering include, for example, alfalfa, which has a reduced lignin content through RNA interference by introducing a gene that produces double-stranded RNA of the S-adenosyl-L-methionine:trans-caffeoyl CoA 3-O-methyltransferase (ccomt) gene derived from alfalfa, which is involved in lignin production; Laurical™ Canola, a canola with an increased content of triacylglycerols containing lauric acid, which has been introduced with the 12:0 ACP thioesterase gene derived from bay leaf (Umbellularia californica), which is involved in fatty acid synthesis; Plenish™ and Treus™ soybeans, which have an increased oleic acid content through the introduction of a partial gene (gm-fad2-1) for ω-6 desaturase, a fatty acid desaturase enzyme, which has been suppressed by introducing the gene; and soybean acyl-acyl "Vistive Gold™" soybean has a reduced saturated fatty acid content due to the introduction of a double-stranded RNA-producing gene for carrier protein thioesterase (fatb1-A) and a double-stranded RNA-producing gene for soybean-derived delta-12 desaturase (fad2-1A); genetically modified soybean that produces stearidonic acid, an omega-3 fatty acid, due to the introduction of a delta-6 desaturase gene (Pj.D6D) from primrose and a delta-12 desaturase gene (Nc.Fad3) from Neurospora crassa; "Enogen™" corn, which enhances bioethanol production due to the introduction of a thermostable alpha-amylase gene (amy797E) from Thermococcus sp. involved in starch degradation; and "Enogen™" corn, which enhances bioethanol production due to the introduction of a thermostable alpha-amylase gene (amy797E) from Corynebacterium sp. involved in the production of the amino acid lysine. "Mavera™ Maize" and "Mavera™ YieldGard™ Maize" maize, which have increased lysine production due to the introduction of the dihydrodipicolinate synthase gene (cordapA) derived from C. glutamicum;"Amflora™" and "Starch Potato" are potatoes in which the amylose content in starch granules has been reduced and the amylopectin content increased by introducing the antisense gene gbss of the potato-derived starch synthase (granule-bound starch synthase enzyme, GBSS); "Innate® Cultivate," "Innate® Generate," "Innate® Accelerate," "Innate® Invigorate," and "Innate® Cultivate" are potatoes in which the formation of black spots has been suppressed by introducing the gene pPhL and pR1, which generate double-stranded RNA of the potato-derived transcription factor genes PhL and R1, which promote starch degradation; "Innate® Cultivate," "Innate® Generate," "Innate® Accelerate," "Innate® Invigorate," and "Innate® Cultivate" are potatoes in which the formation of black spots has been suppressed by introducing the gene ppo5, which generates double-stranded RNA of the potato-derived polyphenol oxidase gene Ppo5, which suppresses starch degradation; ... These include the "Innate® Glaciate," "Innate® Acclimate," and "Innate® Hibernate" varieties; tobacco with reduced nicotine content, obtained by introducing an antisense gene (NtQPT1) of the quinolinate phosphoribosyltransferase gene QpTase from tobacco (Nicotiana tabacum); and "Golden Rice," a rice variety that produces vitamin A-rich rice by introducing and expressing the phytoene synthase gene (psy) from daffodil (Narcissus pseudonarcissus) and the carotene desaturase gene (crt1) from the carotenoid-synthesizing soil bacterium (Erwinia uredovora) specifically in the endosperm. Other examples include potatoes and corn with altered amylopectin content (see, e.g., US6784338, US2007 / 0261136, WO1997 / 04471);Oil content modified canola, corn, cotton, grape, cattail, cowpea, rice, soybean, rapeseed, wheat, sunflower, bitter melon, safflower, and plants of the genus Vernonia (e.g., US 7294759, US 7157621, US 5850026, US 6441278, US 5723761, US 6380462, US 6365802, US 6974898, WO2001 / 079 499, US 2006 / 0075515 and US 7294759); sunflower with increased fatty acid content (see, e.g., US 6084164); soybean with reduced allergen content (see, e.g., US 6864362); tobacco with reduced nicotine content (see, e.g., US 2006 / 0185684, WO 2005 / 000352 and WO 2007 / 064636); canola and soybean with increased lysine content (see, e.g., Bio / Technology 13, 1995, 577-582); maize and soybean with modified methionine, leucine, isoleucine, and / or valine compositions (see, e.g., US6946589, US6905877); soybean with increased sulfur amino acid content (see, e.g., EP0929685, WO1997 / 041239); maize with increased methionine content by leaf-specific expression of 3'-phosphoadenosine-5'-phosphosulfate reductase from Escherichia coli (PNAS, 2017, 114(43), 11386); tomatoes with an increased content of free amino acids (e.g., asparagine, aspartic acid, serine, threonine, alanine, histidine, and glutamic acid) (see, e.g., US Pat. No. 6,727,411); corn with an increased content of amino acids (see, e.g., WO 05 / 077117); potatoes, corn, and rice with modified starch content (see, e.g., WO 1997 / 044471 and US Pat. No. 7,317,146); tomatoes, corn, grapes, alfalfa, apples, beans, and peas with modified flavonoid content (see, e.g., WO 00 / 04175);These include maize, rice, sorghum, cotton, and soybeans with modified phenolic compound content (see, for example, US2008 / 0235829); tomatoes and canola with increased vitamin A content (see, for example, US6797498, US7348167); tomatoes, canola, soybeans, wheat, sunflower, rice, maize, barley, and rye with increased vitamin E content (see, for example, US7348167, WO2004 / 058934); and alfalfa, apples, beans, maize, grapes, tomatoes, and peas with modified flavonoid content (see, for example, WO00 / 04175). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the above-mentioned publications. Preferably, the plant is selected from soybean, canola, tomatoes, rice, and wheat (e.g., wheat, barley, rye, and oats), and most preferably, is selected from soybean, canola, rice, wheat, and barley;

[0140] Plants whose product quality has been modified using conventional breeding techniques or genomic breeding techniques include the rapeseed "Nexera® Canola," which produces unsaturated omega-9 fatty acids; the soybean "Yumeminori," which has reduced allergen content; and rice varieties designed for improved eating quality, such as the rice "Yumepirika," which has reduced amylose content. Additionally, citrus fruits with modified fruit characteristics (e.g., fruit weight, aroma, juiciness, and sugar content) through genomic selection are known (see Scientific Reports 7, 4721, 2017).

[0141] Plants with modified nutrient utilization include, for example, plants with enhanced assimilation or metabolism of nitrogen or phosphorus. Examples of plants with enhanced nitrogen assimilation and nitrogen utilization capabilities through genetic engineering include canola, corn, wheat, sunflower, rice, tobacco, soybean, cotton, alfalfa, tomato, wheat, potato, sugar beet, sugarcane, and rapeseed (see, for example, WO1995 / 009911, WO1997 / 030163, US6084153, US5955651, and US6864405). Plants whose phosphorus uptake has been improved through genetic engineering include, for example, alfalfa, barley, canola, corn, cotton, tomato, rapeseed, rice, soybean, sugar beet, sugarcane, sunflower, wheat, and potato (see, for example, US7417181, US2005 / 0137386). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above. Preferably, the plant is selected from soybean, tomato, and cereals (e.g., wheat, barley, rye, and oats), and most preferably, from soybean, rice, corn, and wheat.

[0142] Plants whose fertility traits have been modified by genetic engineering include plants that have been given male sterility and fertility restoration traits. For example, Bacillus Examples of such plants include maize and chicory that have been conferred male sterility by expressing the ribonuclease gene (barnase) derived from Bacillus amyloliquefaciens; maize that has been conferred male sterility by introducing the DNA adenine methyltransferase gene (dam) derived from Escherichia coli; maize that has been fertility-controlled by introducing the alpha-amylase gene (zm-aa1) derived from maize, which confers male sterility, and the ms45 protein gene (ms45) derived from maize, which confers fertility-restoring properties; canola that has been conferred fertility-restoring properties by expressing the ribonuclease inhibitor protein gene (barstar) derived from Bacillus in the tapetum cells of the anthers; and canola that has been fertility-controlled by expressing the ribonuclease gene (barnase) derived from Bacillus, which confers male sterility, and the ribonuclease inhibitor protein gene (barstar) derived from Bacillus, which confers fertility-restoring properties. Other plants that have been conferred fertility traits through genetic engineering include tomato, rice, mustard, wheat, soybean, and sunflower (see, e.g., US6720481, US6281348, US5659124, US6399856, US7345222, US7230168, US6072102, EP1135982, WO2001 / 092544, and WO1996 / 040949). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above. Preferably, the plant is selected from corn, canola, soybe...

Claims

1. Formula (I) [During the ceremony, R 1 is the group G 1 a phenyl group optionally substituted with one or more substituents selected from the group G 1 represents a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from the following: R 2 is the group G 2 a C1-C8 chain hydrocarbon group optionally substituted with one or more substituents selected from the group G 3 a C3-C8 alicyclic hydrocarbon group optionally substituted with one or more substituents selected from the group consisting of a halogen atom, a cyano group, OR 10 , C (= Z 1 ) R 11 , C (= Z 1 ) OR 12 , C (= Z 1 ) NR 11 R 12 , mercapto group, S(O) p R 13 , or NR 11 R 14 represents p represents 0, 1, or 2; R 3 is the group G 4 a phenyl group optionally substituted with one or more substituents selected from the group G 4 a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the group G 4 a group represented by formula B1, or a group represented by formula B2 (● represents a bonding site to a nitrogen atom), which may be substituted by one or more substituents selected from the group consisting of: G 7a , G 7b and G 7c The combination of G 7a is C=O or CR 30a R 31a and G 7b is C=O or CR 30b R 31b and G 7c is C=O or CR 30c R 31c The combination G 7a is C=O or CR 30a R 31a and G 7b is C=O or CR 30b R 31b and G 7c is NR 32c , an oxygen atom, a sulfur atom, S═O, or S═O 2 The combination G 7a is C=O or CR 30a R 31a and G 7b is NR 32b , an oxygen atom, a sulfur atom, S═O, or S═O 2 and G 7c is C=O or CR 30c R 31c The combination G 7a is NR 32a , an oxygen atom, a sulfur atom, S═O, or S═O 2 and G 7b is C=O or CR 30b R 31b and G 7c is C=O or CR 30c R 31c or G 7a is NR 32a , an oxygen atom, a sulfur atom, S═O, or S═O 2 and G 7b is C=O or CR 30b R 31b and G 7c is NR 32c , an oxygen atom, a sulfur atom, S═O, or S═O 2 combinations where G 7d , G 7e , G 7f and G 7g The combination of G 7d is C=O or CR 30d R 31d and G 7e is C=O or CR 30e R 31e and G 7f is C=O or CR 30f R 31f and G 7g is C=O or CR 30g R 31g The combination G 7d is C=O or CR 30d R 31d and G 7e is C=O or CR 30e R 31e and G 7f is C=O or CR 30f R 31f and G 7g is NR 32g , an oxygen atom, a sulfur atom, S═O, or S═O 2 The combination G 7d is C=O or CR 30d R 31d and G 7e is C=O or CR 30e R 31e and G 7f is NR 32f , an oxygen atom, a sulfur atom, S═O, or S═O 2 and G 7g is C=O or CR 30g R 31g The combination G 7d is C=O or CR 30d R 31d and G 7e is NR 32e , an oxygen atom, a sulfur atom, S═O, or S═O 2 and G 7f is C=O or CR 30f R 31f and G 7g is C=O or CR 30g R 31g The combination G 7d is C=O or CR 30d R 31d and G 7e is NR 32e , an oxygen atom, a sulfur atom, S═O, or S═O 2 and G 7f is C=O or CR 30f R 31f and G 7g is NR 32g , an oxygen atom, a sulfur atom, S═O, or S═O 2 The combination G 7d is NR 32d , an oxygen atom, a sulfur atom, S═O, or S═O 2 and G 7e is C=O or CR 30e R 31e and G 7f is C=O or CR 30f R 31f and G 7g is C=O or CR 30g R 31g The combination G 7d is NR 32d , an oxygen atom, a sulfur atom, S═O, or S═O 2 and G 7e is C=O or CR 30e R 31e and G 7f is C=O or CR 30f R 31f and G 7g is NR 32g , an oxygen atom, a sulfur atom, S═O, or S═O 2 or G 7d is NR 32d , an oxygen atom, a sulfur atom, S═O, or S═O 2 and G 7e is C=O or CR 30e R 31e and G 7f is NR 32f , an oxygen atom, a sulfur atom, S═O, or S═O 2 and G 7g is C=O or CR 30g R 31g combinations where X 1 and X 2 are the same or different and represent an oxygen atom or a sulfur atom, Y 1 is OR 15 or SR 15 represents m and n are the same or different and represent 0, 1, or 2; A is a single bond, an oxygen atom, a sulfur atom, -S(O)-, -S(O) 2 -, -CR 4 R 5 -, -C (=Z 4 ) - or -NR 6 represents -, R 4 and R 5 are the same or different and represent a C1-C3 alkyl group optionally substituted with one or more halogen atoms, a C1-C3 alkoxy group optionally substituted with one or more halogen atoms, a hydroxy group, or a hydrogen atom, or R 4 and R 5 and together form a C2-C5 alkylene group, or —O(CH 2 ) q represents O-, q represents 2, 3 or 4; Z 4 is an oxygen atom, a sulfur atom, or CH 2 represents R 6 represents a C1-C3 alkyl group optionally substituted with one or more halogen atoms, C(=Z 5 ) R 34 Group, C (=Z 5 ) OR 34 represents a group or a hydrogen atom, Z 1 , Z 2 , Z 3 , and Z 5 are the same or different and represent an oxygen atom or a sulfur atom, R 10 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, or a group G 6 represents a phenyl group optionally substituted with one or more substituents selected from the group consisting of R 11 , R 21 , and R 26 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, a group G 6 represents a phenyl group optionally substituted with one or more substituents selected from the group consisting of: R 12 , R 20 , R 22 , R 25 , and R 27 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 13 , R 23 , and R 28 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, or a group G 6 represents a phenyl group optionally substituted with one or more substituents selected from the group consisting of R 14 , R 24 , R 29 , and R 34 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, R 35 and R 36 represent, together with the nitrogen atom to which they are bonded, a saturated or unsaturated 5- or 6-membered cyclic amino group (the cyclic amino group may be substituted with one or more substituents selected from the group consisting of a C1-C3 alkyl group optionally substituted with one or more halogen atoms, and a halogen atom); R 15 is the group G 8 a C1-C10 chain hydrocarbon group optionally substituted with one or more substituents selected from the group consisting of a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more halogen atoms, a benzyl group {the phenyl moiety in the benzyl group is selected from the group G 6 and the methylene portion may be substituted with one or two C1-C3 alkyl groups}, or a hydrogen atom; R 30a 、 R 30b 、 R 30c , R 30d 、 R 30e 、 R 30f 、 R 30g 、 R 31a , R 31b 、 R 31c , R 31d 、 R 31e 、 R 31f 、 and R 31g are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, R 32a 、 R 32b 、 R 32c , R 32d 、 R 32e 、 R 32f 、 and R 32g are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a (C1-C3 alkyl)carbonyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 33a 、 R 33b 、 R 33c , R 33d 、 R 33e 、 and R 33f are the same or different and represent a C1-C3 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom. Group G 1 : a C1-C3 alkyl group optionally substituted with one or more halogen atoms, group G 1-1 a C3-C6 cycloalkyl group optionally substituted by one or more substituents selected from the group consisting of: OR 20 Group, C (=Z 2 ) R 21 Group, C (=Z 2 ) OR 22 Group, C (=Z 2 ) NR 21 R 22 group, mercapto group, S(O) n R 23 group, NR 20 R 24 The group consisting of a nitro group, a halogen atom, and a cyano group. Group G 1-1 : A group consisting of halogen atoms and cyano groups. Group G 2 The group consisting of a C1-C3 alkoxy group optionally substituted with one or more halogen atoms, a C1-C3 alkylthio group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfonyl group optionally substituted with one or more halogen atoms, a halogen atom, a cyano group, a hydroxy group, and a mercapto group. Group G 3 The group consisting of a C1-C3 alkyl group optionally substituted with one or more halogen atoms, a C1-C3 alkoxy group optionally substituted with one or more halogen atoms, a C1-C3 alkylthio group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfonyl group optionally substituted with one or more halogen atoms, an oxo group, a thioxo group, a halogen atom, a cyano group, a hydroxy group, and a mercapto group. Group G 4 :Group G 4-2 a C1-C6 alkyl group optionally substituted with one or more substituents selected from the group G 4-1 a C3-C6 cycloalkyl group optionally substituted by one or more substituents selected from the group consisting of: OR 25 Group, C (=Z 3 ) R 26 Group, C (=Z 3 ) OR 27 Group, C (=Z 3 ) NR 26 R 27 group, mercapto group, S(O) m R 28 group, NR 25 R 29 group, NR 35 R 36 group, nitro group, halogen atom, SF 5 The group consisting of the methyl group, the morpholino group, and the cyano group. Group G 6 The group consisting of a C1-C3 alkoxy group optionally substituted with one or more halogen atoms, a C1-C3 alkylthio group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C3 alkylsulfonyl group optionally substituted with one or more halogen atoms, a halogen atom, a cyano group, a nitro group, a hydroxy group, and a mercapto group. Group G 4-1 C1-C6 chain hydrocarbon group, C1-C6 alkoxy group, C1-C6 alkylthio group, C1-C6 alkylamino group, C2-C8 dialkylamino group, (C1-C6 alkyl)carbonyl group, (C1-C6 alkoxy)carbonyl group, (C1-C6 alkylamino)carbonyl group, (C2-C8 dialkylamino)carbonyl group, C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group, (C1-C6 alkylamino)sulfonyl group, (C2-C8 dialkylamino)sulfonyl group {the C1-C6 chain hydrocarbon group The hydrogen hydride group, the C1-C6 alkoxy group, the C1-C6 alkylthio group, the C1-C6 alkylamino group, the C2-C8 dialkylamino group, the (C1-C6 alkyl)carbonyl group, the (C1-C6 alkoxy)carbonyl group, the (C1-C6 alkylamino)carbonyl group, the (C2-C8 dialkylamino)carbonyl group, the C1-C6 alkylsulfinyl group, the C1-C6 alkylsulfonyl group, the (C1-C6 alkylamino)sulfonyl group, and the (C2-C8 dialkylamino)sulfonyl group are each selected from the group G 4-1-1 and optionally substituted with one or more substituents selected from the group consisting of a halogen atom, a cyano group, a nitro group, a hydroxy group, an amino group, a formyl group, an aminocarbonyl group, an aminosulfonyl group, and SF 5 A group consisting of groups. Group G 4-1-1 the group consisting of halogen atoms, cyano groups, nitro groups, hydroxy groups, amino groups, oxo groups, thioxo groups, aminocarbonyl groups, aminosulfonyl groups, C3-C6 cycloalkyl groups, C1-C3 alkoxy groups, C1-C3 alkylthio groups, (C1-C3 alkyl)carbonyl groups, (C1-C3 alkoxy)carbonyl groups, C1-C3 alkylsulfinyl groups, and C1-C3 alkylsulfonyl groups {the C3-C6 cycloalkyl groups, the C1-C3 alkoxy groups, the C1-C3 alkylthio groups, the (C1-C3 alkoxy)carbonyl groups, the C1-C3 alkylsulfinyl groups, and the C1-C3 alkylsulfonyl groups are optionally substituted with one or more halogen atoms}. Group G 4-2 a C1-C6 alkoxy group, a C1-C6 alkylthio group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group, a (C1-C6 alkyl)carbonyl group, a (C1-C6 alkoxy)carbonyl group, a (C1-C6 alkylamino)carbonyl group, a (C2-C8 dialkylamino)carbonyl group, a C1-C6 alkylsulfinyl group, a C1-C6 alkylsulfonyl group, a (C1-C6 alkylamino)sulfonyl group, a (C2-C8 dialkylamino)sulfonyl group {said C1-C6 alkoxy group, a C1-C6 alkylthio group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group, a (C1-C6 alkyl)carbonyl group, a (C1-C6 alkoxy)carbonyl group, a (C1-C6 alkylamino)carbonyl group, a (C2-C8 dialkylamino)carbonyl group {said C1-C6 alkoxy group, a C1-C6 alkylthio group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group, a (C1-C6 alkyl)carbonyl group, a (C1-C6 alkylamino)sulfonyl group, a (C2-C8 dialkylamino)sulfonyl group {said C1-C6 alkoxy group, a C1-C6 alkylthio ... The alkoxy group, the C1-C6 alkylthio group, the C1-C6 alkylamino group, the C2-C8 dialkylamino group, the (C1-C6 alkyl)carbonyl group, the (C1-C6 alkoxy)carbonyl group, the (C1-C6 alkylamino)carbonyl group, the (C2-C8 dialkylamino)carbonyl group, the C1-C6 alkylsulfinyl group, the C1-C6 alkylsulfonyl group, the (C1-C6 alkylamino)sulfonyl group, and the (C2-C8 dialkylamino)sulfonyl group are each selected from the group G 4-1-1 and optionally substituted with one or more substituents selected from the group consisting of a halogen atom, a cyano group, a nitro group, a hydroxy group, an amino group, a formyl group, an aminocarbonyl group, an aminosulfonyl group, and SF 5 A group consisting of groups. Group G 8 The group consisting of a (C1-C6 alkyl)carbonyl group optionally substituted with one or more halogen atoms, a (C1-C6 alkoxy)carbonyl group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylthio group optionally substituted with one or more halogen atoms, a cyano group, and a halogen atom. or a salt thereof to weeds or soil in which weeds grow.

2. A composition comprising the compound represented by formula (I) according to claim 1 or a salt thereof and one or more components selected from the group consisting of group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i), and group (j): Group (a): a group consisting of arthropodicidal active ingredients and nematicidal active ingredients; Group (b): bactericidal active ingredient; Group (c): plant growth regulating ingredients; Group (d): phytotoxicity safeners; Group (e): synergists; Group (f): repellent components; Group (g): molluscicidal components; Group (h): insect pheromones; Group (i): herbicidal active ingredients; Group (j): biological control materials.

3. A method for controlling weeds, comprising the step of applying an effective amount of the composition of claim 2 to weeds or soil in which weeds grow.

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Patent Citations

  • Method of producing hybrid cereal grain seeds by application of 1-aryl-1,4-dihydro-4-oxo(thio)-pyridazines

    US4345934A