Cleansing composition containing polyglycerin
Incorporating polyglycerin with an average degree of polymerization of 3 to 20 in detergent compositions with surfactants enhances foam generation and persistence, addressing the limitations of glycerin and diglycerin.
Patent Information
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- SAKAMOTO YAKUHIN KOGYO CO LTD
- Filing Date
- 2024-11-13
- Publication Date
- 2026-05-25
AI Technical Summary
Existing detergent compositions fail to adequately increase the amount of foam generated and maintain foam persistence when incorporating glycerin and diglycerin.
Incorporating polyglycerin with an average degree of polymerization of 3 to 20, along with a surfactant, in a detergent composition to enhance foam generation and persistence.
The composition significantly increases the amount of foam immediately after foaming and improves foam persistence.
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Abstract
Description
Technical Field
[0001] The present invention relates to a detergent composition containing polyglycerin with an average degree of polymerization of 3 or more and improving the foam quality as an improver.
Background Art
[0002] The performances required for detergents include good foaming, foam persistence, and stability. These are directly related to the feeling of use of detergents, and in body and household detergents, they are one of the essential factors that affect consumer satisfaction. In addition, since the persistence of foam leads to an improvement in detergency, it is also highly regarded not only in body and household detergents but also in industrial detergents.
[0003] Conventionally, detergent compositions with good foaming properties during washing are known. For example, in Patent Document 1, a detergent composition containing a surfactant and glycerin as a polyhydric alcohol is disclosed, and it is also suggested that diglycerin can be blended as a polyhydric alcohol. Further, in Patent Document 2, a detergent composition containing a surfactant and glycerin as a polyhydric hydroxyl group-containing compound is disclosed, and it is also suggested that diglycerin can be blended as a polyhydric hydroxyl group-containing compound.
Prior Art Documents
Patent Documents
[0004]
Patent Document 1
Patent Document 2
Summary of the Invention
Problems to be Solved by the Invention
[0005] However, the detergent composition in Patent Document 1 describes that by incorporating polyhydric alcohols such as glycerin and diglycerin, the conditioning effect after washing is good and the storage stability of the detergent composition is good. In contrast, the detergent composition in Patent Document 2 does not clearly explain the technical significance of incorporating glycerin and diglycerin, and there were problems with the amount of foam generated and the persistence of the foam when glycerin and diglycerin were incorporated.
[0006] Therefore, the present invention aims to provide a cleaning composition that, when combined with a surfactant, can increase the amount of foam immediately after foaming and improve the persistence of the foam. [Means for solving the problem]
[0007] [1] That is, the present invention is a detergent composition characterized by containing polyglycerin having an average degree of polymerization of 3 to 20, a surfactant, and water.
[0008] [2] The cleaning composition according to claim 1, characterized in that when 500 mL of the cleaning composition according to claim 1 is dropped from a height of 450 mm at 25°C into a graduated cylinder containing 50 mL of the cleaning composition according to claim 1, the volume of foam generated is 270 to 350 ml.
[0009] [3] The detergent composition according to [1] or [2] above, characterized in that the blending ratio of the surfactant to the polyglycerin having an average degree of polymerization of 3 to 20 is the surfactant / polyglycerin having an average degree of polymerization of 3 to 20 = 10 / 1 to 1 / 1.
[0010] [4] The detergent composition according to [1] or [2], characterized in that the average degree of polymerization of the polyglycerin is 3 to 10.
[0011] [5] The detergent composition according to [1] or [2], characterized in that the surfactant is an anionic surfactant having 10 to 22 carbon atoms. [Effects of the Invention]
[0012] The present invention provides a cleaning composition that, when combined with a surfactant, can increase the amount of foam immediately after foaming and improve the persistence of the foam. [Modes for carrying out the invention]
[0013] The embodiments for carrying out the present invention will be described in more detail below, but the scope of the present invention is not limited to these embodiments, and embodiments that have been modified or otherwise altered without impairing the spirit of the present invention also belong to the present invention. The notation "~" indicating the range includes both an upper and lower limit.
[0014] The polyglycerin having an average degree of polymerization of 3 to 20 in the present invention is a compound obtained by dehydrating and condensing an average of 3 to 20 glycerin molecules, or an equivalent compound. By incorporating polyglycerin with an average degree of polymerization of 3 to 20, the amount of foam immediately after foaming can be increased, and the persistence of the foam can be improved. The average degree of polymerization is the repeating unit of the glycerin skeleton; therefore, an average degree of polymerization of 3 indicates triglycerin, an average degree of polymerization of 4 indicates tetraglycerin, an average degree of polymerization of 6 indicates hexaglycerin, and an average degree of polymerization of 10 indicates decaglycerin. Here, the average degree of polymerization is calculated from the hydroxyl value by terminal analysis using the following formulas (1) and (2). In formula (2), the hydroxyl value is a numerical indicator of the number of hydroxyl groups contained in polyglycerin, and refers to the number of milligrams of potassium hydroxide required to neutralize the acetic acid necessary to acetylate the free hydroxyl groups contained in 1 g of polyglycerin. The number of milligrams of potassium hydroxide is calculated in accordance with the "Standard Test Methods for Analysis of Fats and Oils, 2013 Edition," edited by the Japan Oil Chemists' Society. Molecular weight = 74 x average degree of polymerization + 18 (1) Hydroxyl value = 56110 (average degree of polymerization + 2) / molecular weight ... (2) In the present invention, the average degree of polymerization of polyglycerin is preferably 3 to 20, more preferably 3 to 10, and most preferably 3 to 4. If the average degree of polymerization of polyglycerin is within this range, the amount of foam immediately after foaming can be increased, and the persistence of the foam can be improved.
[0015] The polyglycerins with an average degree of polymerization of 3 to 20 used in this invention include, specifically, PGL-S (triglycerin), polyglycerin #310 (tetraglycerin), polyglycerin #500 (hexaglycerin), and polyglycerin #750 (decaglycerin) manufactured by Sakamoto Pharmaceutical Co., Ltd., and one or more of these can be used in combination.
[0016] Furthermore, the proportion of polyglycerin with an average degree of polymerization of 3 to 20 in the detergent composition of the present invention is preferably 0.1 to 10% by weight, more preferably 0.3 to 5% by weight, and most preferably 0.5 to 3% by weight.
[0017] The surfactants used in this invention are components for emulsifying and dispersing oils and other contaminants in water, and are organic compounds having lipophilic and hydrophilic groups. These surfactants can be used to create oil-in-water emulsions (W / O emulsions), etc. Examples of surfactants include anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, and polymeric surfactants.
[0018] Specifically, surfactants include anionic surfactants such as alkyl fatty acid salts, alkyl sulfate salts, alkylbenzene sulfonates, polyoxyethylene alkyl sulfates, polyoxyethylene fatty amine sulfates, acyl N-methyl taurate salts, alkyl phosphate salts, alkyl ether phosphate salts, and N-acyl amino acid salts; nonionic surfactants such as polyoxyethylene alkyl ethers, polyoxyethylene alkylphenyl ethers, polyoxyethylene alkyl ether sorbitan fatty acid partial esters, polyoxyethylene hydrogenated castor oil, polyhydric alcohol fatty acid partial esters, polyglycerin fatty acid esters, polyoxyethylene fatty acid esters, alkyldimethylamine oxides, alkyl polyglycosides, and alkyl glucosides; and alkyltrimethyl Cationic surfactants such as ammonium chloride, alkyltrimethylammonium bromide, dialkyldimethylammonium chloride, long-chain branched fatty acid (12-31) aminopropylethyldimethylammonium ethyl sulfate, lanolin fatty acid aminopropylethyldimethylammonium ethyl sulfate, short-chain polyoxyethylene alkylamines and their salts or quaternary salts, and benzalkonium chloride; fatty acid amidoamines and their salts; amphoteric surfactants such as alkyldimethylaminoacetic acid betaine, alkylamidedimethylaminoacetic acid betaine, and 2-alkyl-N-carboxy-N-hydroxyimidazolinium betaine; and polymeric surfactants such as polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum, and acrylic acid / alkyl methacrylate copolymers are preferred.
[0019] Furthermore, the proportion of surfactant in the detergent composition of the present invention is preferably 0.1 to 20% by weight, more preferably 0.3 to 15% by weight, and most preferably 1 to 10% by weight.
[0020] The blending ratio of the surfactant and the polyglycerin with an average degree of polymerization of 3 to 20 is preferably surfactant / polyglycerin with an average degree of polymerization of 3 to 20 = 10 / 1 to 1 / 1, and more preferably 7 / 1 to 3 / 1. With these blending ratios, the amount of foam immediately after foaming can be increased and the foam persistence can be improved.
[0021] The water used in the present invention is a solvent that dissolves polyglycerin with an average degree of polymerization of 3 to 20 and a surfactant. As the water, water complying with the Japanese Pharmacopoeia standard is preferred. Specifically, tap water, well water and other ordinary water, and purified water obtained by treating ordinary water by any one of distillation, ion exchange treatment using an ion exchange membrane, ultrafiltration treatment using an ultrafiltration membrane, or a combination thereof, and sterilized purified water obtained by sterilizing purified water by heating or the like are preferred. Also, when the above-mentioned surfactant is an aqueous solution, the water contained therein may be used.
[0022] Also, the content ratio of the water is preferably in the range of 70 to 99% by weight, more preferably in the range of 80 to 98% by weight, and most preferably in the range of 87 to 97% by weight.
[0023] If necessary, an oily base material, alcohols, a humectant, a polymer / thickening / gelling agent, an antioxidant, a preservative, a bactericide, a chelating agent, a pH adjuster / acid / alkali, an ultraviolet absorber, a whitening agent, a solvent, a keratolytic / dissolving agent, an antipruritic agent, an anti-inflammatory agent, an antiperspirant, a cooling agent, a reducing agent / oxidizing agent, a polymer powder, vitamins and their derivatives, saccharides and their derivatives, organic acids, inorganic powders, fragrances, etc. can be blended in the skin cleansing composition of the present invention.
[0024] Examples of oily bases include higher alcohols such as cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, arachidodecanol, behenyl alcohol, jojoba alcohol, chimyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, 2-octyldodecanol, and dimergol. Other examples include coconut oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadowfoam oil, peach kernel oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cocoa butter, shea butter, hydrogenated coconut oil, and hydrogenated hyaluronic acid. Vegetable oils such as basil oil, jojoba oil, and hydrogenated jojoba oil; animal oils such as beef tallow, milk fat, horse fat, egg yolk oil, mink oil, and turtle oil; phospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, sphingomyelin, phosphatidic acid, and lysolecithin; phospholipid derivatives such as hydrogenated soybean phospholipid and hydrogenated egg yolk phospholipid; cholesterol, dihydrocholesterol, lanosterol, dihydro Sterols such as lanosterol and phytosterol; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, N-lauroyl-L-glutamic acid di(cholesteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamic acid di(cholesteryl / octyldodecyl), N-lauroyl-L-glutamic acid di(phytosteryl / behenyl / octyl Sterol esters such as dodecyl, N-lauroyl-L-glutamic acid di(phytosteryl / octyldodecyl), 12-hydroxystearate cholesteryl, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, isostearate phytosteryl, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long-chain branched fatty acid cholesteryl, long-chain α-hydroxy fatty acid cholesteryl;Lower alcohol fatty acid esters such as ethyl oleate, ethyl avocado oil fatty acid, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, isopropyl lanolinate, diethyl sebatate, diisopropyl sebatate, dioctyl sebatate, diisopropyl adipate, dioctyl succinate; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, octyldodecyl palmitate Cetyl octanoate, hexyldecyl octanoate, isotridecyl isononanoate, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, octyldodecyl lanolinate, hexyldecyl dimethyloctanoate, octyldodecyl erucate, isoste Higher alcohol fatty acid esters such as hydrogenated castor oil phosphate; oxy acid esters such as cetyl lactate, diisostearyl malate, hydrogenated castor oil monoisostearate; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, caprylic / capric triglyceride, caprylic / capric / myristic / stearic triglyceride, hydrogenated rosin glyceryl (hydrogenated ester gum), neopentyl glycol dioctanoate, dioctane Polyhydric alcohol fatty acid esters such as 2-butyl-2-ethyl-1,3-propanediol acid, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl, (hydroxystearate / stearate / rosinate) dipentaerythrityl, diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl-10 nonaisostearate, and polyglyceryl-8 deca(erucic acid / isostearate / ricinoleic acid);Dimer acids or dimer ol derivatives such as diisopropyl dimer dilinoleate, diisostearyl dimer dilinoleate, di(isostearyl / phytosteryl) dimer dilinoleate, (phytosteryl / behenyl) dimer dilinoleate, (phytosteryl / isostearyl / cetyl / stearyl / behenyl) dimer dilinoleate, dimer dilinoleyl diisostearate, hydrogenated rosin condensate of dimer dilinoleate, hydrogenated castor oil dimer dilinoleate, and hydroxyalkyl dimer dilinoleyl ether; coconut oil fatty acid monoethanolamide, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, lauric acid diethanolamide, and palmitate monoethanol This product can contain amides, fatty acid alkanolamides such as palmitic acid diethanolamide, low-viscosity dimethylpolysiloxane, high-viscosity dimethylpolysiloxane, cyclic dimethylsiloxane (decamethylcyclopentasiloxane), methylphenylpolysiloxane, diphenylpolysiloxane, silicone resins, silicone rubber, amino-modified polysiloxanes such as aminopropyl dimethicone and amodimethicone, cation-modified polysiloxane, polyether-modified polysiloxane, polyglycerin-modified polysiloxane, sugar-modified polysiloxane, alkyl-modified polysiloxane, fatty acid-modified polysiloxane, fluorine-modified polysiloxane, and other silicones; and fluorine-based oils such as perfluoroodecane, perfluorooctane, and perfluoropolyether.
[0025] As humectants, propylene glycol, glycerin, diglycerin, polyglycerin, DPG, polyhydric alcohols such as 1,2-alkanediol, 1,3-butanediol, and 3-methyl-1,3-butanediol, sodium hyaluronate, citrate, urea, lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesamin glycosides, betaine, chondroitin sulfate, glutathione, polyethylene glycol, sorbitol, carbitol, sodium lactate, sodium 2-pyrrolidone-5-carboxylate, albumin, trimethylglycine; collagen, gelatin, elastin, collagen-degraded peptides, elastin-degraded peptides This product can contain protein peptides and their derivatives, such as keratin-degraded peptides, conchiolin-degraded peptides, silk-degraded peptides, soy-degraded peptides, wheat-degraded peptides, casein-degraded peptides, and acylated peptides; amino acids such as arginine, serine, glycine, threonine, glutamic acid, cysteine, methionine, leucine, and tryptophan; animal and plant extracts such as placenta extract, aerlastin, collagen, aloe extract, witch hazel water, loofah water, chamomile extract, licorice extract, and comfrey extract; and ceramides such as natural ceramides (types 1, 2, 3, 4, 5, and 6), hydroxyceramides, pseudoceramides, and sphingoglycolipids.
[0026] Polymers, thickeners, and gelling agents include guar gum, locust bean gum, quince seed, carrageenan, galactan, gum arabic, tara gum, tamarind, fercerelan, karaya gum, okra gum, caramel gum, tragacanth gum, pectin, alginic acid and its salts, mannan, starch, xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salts, xanthan gum, pullulan, gellan gum, chitin, chitosan, agar, chondroitin sulfate, casein, gelatin, albumin, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose and its salts, methylhydroxypropylcellulose, cationized cellulose, soluble starch, carboxymethyl starch, methyl starch, propylene glycol alginate, polyvinyl alcohol, polyvinylpyrrolidone, polio Xyethylene-polyoxypropylene copolymer, partially saponified polyvinyl acetate, maleic acid copolymer, polyacrylic acid ester copolymer, carboxyvinyl polymer, polyacrylic acid and its salts, acrylic acid / methacrylic acid ester copolymer, amphoteric methacrylic acid ester copolymer, acrylic acid / alkyl methacrylate copolymer, diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / cationized methacrylic acid ester copolymer, acrylic acid / cationized methacrylamide copolymer, choline chloride methacrylate ester polymer, cationized guar gum, nitrocellulose; 12-hydroxystearic acid and its salts, dextrin fatty acid ester, anhydrous silicic acid, metal soap, organically modified clay mineral, sucrose fatty acid ester, fructooligosaccharide fatty acid ester, etc. can be incorporated.
[0027] Examples of antioxidants include BHT, BHA, propyl gallate, vitamin E (tocopherol) and / or its derivatives, vitamin C (ascorbic acid) and / or its derivatives, sulfites, bisulfites, etc. Examples of preservatives include phenols, phenoxyethanol, hydroxybenzoic acid and its salts, 1,2-pentanediol, 1,2-hexanediol, halogenated bisphenols, acid amides, quaternary ammonium salts, etc. Examples of disinfectants include trichlorocarbanides, zinc pyrithione, benzalkonium chloride, benzethonium chloride, chlorhexidine, halocarban, hinokitiol, phenols, isopropylphenol, photosensitizers, etc. Examples of chelating agents include edetates, phytic acid, phosphonic acids, sodium oxalate, polyamino acids, etc. As pH adjusters, acids, and alkalis, citric acid, lactic acid, glycolic acid, succinic acid, acetic acid, hydrochloric acid, monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, arginine, sodium hydroxide, potassium hydroxide, ammonia water, guanidine carbonate, etc. can be included.
[0028] As solvents, lower alcohols such as ethanol and 2-propanol; acetone, ethyl acetate, ethylene glycol monoethyl ether, toluene, etc. can be included.
[0029] Examples of exfoliating and dissolving agents include salicylic acid, sulfur, resorcinol, selenium sulfide, and pyridoxine. Examples of antipruritic agents include diphenhydramine hydrochloride, chlorpheniramine maleate, and camphor. Examples of anti-inflammatory agents include glycyrrhizic acid and its derivatives, guaiazulene, hydrocortisone acetate, and prednisone. Examples of antiperspirants include aluminum chlorohydrate, aluminum chloride, zinc oxide, and zinc paraphenolsulfonate. Examples of cooling agents include menthol and methyl salicylate. Examples of antihistamines include diphedramine hydrochloride, chlorpheniramine maleate, and glycyrrhetinic acid derivatives. Examples of astringent agents include citric acid, tartaric acid, lactic acid, potassium aluminum sulfate, and tannic acid. Examples of stimulants include cantharis tincture, ginger tincture, capsicum tincture, and benzyl nicotinate. Examples of hair growth agents and blood circulation promoters include plant extracts and tinctures such as Swertia japonica extract, capsicum tincture, ginger tincture, and cantharis tincture; cepharanthine, vitamin E and its derivatives, γ-oryzanol, nicotinic acid and derivatives such as benzyl nicotinate ester, allantoin, photosensitizer 301, photosensitizer 401, pentadecanoic acid monoglyceride, flavanonol derivatives, and minoxidil.
[0030] Examples of reducing agents include thioglycolic acid, cysteine, and cysteamine. Examples of oxidizing agents include hydrogen peroxide, ammonium persulfate, and sodium bromate.
[0031] Examples of polymer powders that can be used include starch, nylon powder, polyethylene powder, polymethyl methacrylate, polyethylene terephthalate / polymethyl methacrylate laminated powder, polyethylene terephthalate / aluminum / epoxy laminated powder, and surface-treated powders thereof.
[0032] Examples of α-hydroxy acids and their derivatives include lactic acid, glycolic acid, fruit acid, hydroxycapric acid, long-chain α-hydroxy fatty acids, and long-chain α-hydroxy fatty acid cholesteryl.
[0033] Vitamins and their derivatives may include vitamins such as vitamin A, B vitamins, vitamin D, vitamin E, pantothenic acid, and biotin; and vitamin derivatives such as ascorbyl stearate, ascorbyl palmitate, ascorbyl dipalmitate, magnesium ascorbyl phosphate, sodium ascorbate, tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, and tocopherol ferulate.
[0034] Examples of sugars and their derivatives include cyclodextrin, β-glucan, chitin, chitosan, glucose, trehalose, pectin, arabinogalactan, dextrin, dextran, and glycosylethyl methacrylate polymers or copolymers. Examples of organic acids that can be included include acetic acid, propionic acid, citric acid, abietic acid, and tartaric acid.
[0035] Examples of enzymes include lysozyme chloride, papain, pancreatin, and proteases. Examples of nucleic acids include adenosine triphosphate disodium. Examples of hormones that can be included include estradiol, estrone, ethinylestradiol, cortisone, hydrocortisone, and prednisone.
[0036] Inorganic powders that can be incorporated include mica, talc, kaolin, montmorillonite, sericite, kaolinite, calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, Prussian blue, carbon black, titanium dioxide, zinc oxide, alumina, silica, fuzzy silica (ultrafine anhydrous silicic acid), titanium mica, fish scale foil, boron nitride, photochromic pigments, synthetic fluorphlogopite, fine particle composite powders, gold, aluminum, and other inorganic powders, as well as powders of these materials that have been hydrophobized by surface treatment.
[0037] Other known ingredients used in cosmetics, pharmaceuticals, food products, etc., may be appropriately incorporated as long as they do not impair the effects of the present invention. [Examples]
[0038] Specific examples are shown below, but the present invention is not limited to these examples. In addition, unless otherwise specified, the units of the amounts of each component in the tables in the examples are "weight percent".
[0039] The cleaning compositions of Examples 1-3 and Comparative Examples 1-4 were prepared by conventional methods, and the amount of foam immediately after foaming was measured using the Rossmiles method. For some of the Examples and Comparative Examples, the volume of foam after a predetermined time was measured as the persistence of the foam, and the retention rate was calculated as the ratio to the volume of foam immediately after foaming. The Rossmiles method was performed in accordance with the method specified in ISP696 of the International Organization for Standardization. Specifically, 50 mL of the cleaning composition was placed in a graduated cylinder (inner diameter approximately 65 mm), and the volume of foam immediately after pouring 500 mL of the same test solution from a height of 450 mm was measured. The results regarding the amount of foam immediately after foaming are shown in Tables 1-2, and the foam retention rate after a predetermined time is shown in Table 3.
[0040] [Table 1]
[0041] [Table 2]
[0042] [Table 3]
[0043] Based on the results above, and by comparing each example with each comparative example, it was found that by incorporating polyglycerin with an average degree of polymerization of 3 to 20, the amount of foam immediately after foaming can be increased and the foam's persistence can be improved compared to when glycerin or diglycerin is incorporated.
Claims
1. A detergent composition characterized by containing polyglycerin with an average degree of polymerization of 3 to 20, a surfactant, and water.
2. A cleaning composition characterized in that when 500 mL of the cleaning composition according to claim 1 is dropped from a height of 450 mm at 25°C into a graduated cylinder containing 50 mL of the cleaning composition according to claim 1, the volume of foam generated is 270 to 350 ml.
3. The detergent composition according to claim 1 or 2, characterized in that the blending ratio of the surfactant to the polyglycerin having an average degree of polymerization of 3 to 20 is the surfactant / polyglycerin having an average degree of polymerization of 3 to 20 = 10 / 1 to 1 / 1.
4. The detergent composition according to claim 1 or 2, characterized in that the average degree of polymerization of the polyglycerin is 3 to 10.
5. The detergent composition according to claim 1 or 2, characterized in that the surfactant is an anionic surfactant having 10 to 22 carbon atoms.