Method for manufacturing coagulated egg-like food and coagulated egg-like food

By controlling the reaction speed and viscosities of egg white and yolk components with calcium alginate and a sparingly soluble calcium agent, the method encapsulates the yolk within the white, addressing the appearance issues of plant-based egg substitutes and achieving a realistic egg-like product.

JP2026091525AActive Publication Date: 2026-06-04Q P CORP

Patent Information

Authority / Receiving Office
JP · JP
Patent Type
Applications
Current Assignee / Owner
Q P CORP
Filing Date
2024-11-25
Publication Date
2026-06-04

AI Technical Summary

Technical Problem

Existing plant-based egg substitutes, such as those described in Patent Document 2, often have an unnatural appearance with the yolk protruding from the egg white, and there is a need for a coagulated egg-like food that encapsulates the yolk within the white to mimic the appearance of a real egg.

Method used

The method involves gelling the egg white portion with calcium alginate by controlling the reaction speed between alginate and calcium salt, adjusting the viscosities of the egg yolk and egg white portions to ensure the egg yolk is fully enclosed by the egg white, using a sparingly soluble calcium agent like calcium carbonate or calcium sulfate, and optionally incorporating a chelating agent to control the reaction rate.

Benefits of technology

This approach allows for the production of a coagulated egg-like food that resembles a real egg in appearance, with the yolk fully enclosed by the white, using plant-based ingredients and avoiding animal-derived materials.

✦ Generated by Eureka AI based on patent content.

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Abstract

The present invention provides a coagulated egg-like food product that substantially does not contain egg yolk or egg white, in which the egg yolk portion is encapsulated within the egg white portion, and a method for producing the same. [Solution] A method for producing a coagulated egg-like food that substantially does not contain egg yolk and egg white, comprising: an egg yolk preparation step; a step of preparing an egg white slurry by dissolving a poorly soluble calcium agent in a raw material liquid; a first egg white filling step of filling a container with a portion of the egg white slurry; an egg yolk placement step; a second egg white filling step of filling a container with the remaining egg white slurry so as to cover the egg yolk; and a step of forming an egg white portion that encloses the egg yolk by gelling the egg white slurry, wherein the viscosity of the egg yolk portion at 25°C is 2000 mPa·s or more, and if the viscosity of the egg yolk portion at 25°C is less than 8000 mPa·s, the viscosity of the egg white slurry in the first egg white filling step at 25°C is 4000 mPa·s or more.
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Description

Technical Field

[0001] The present invention relates to a coagulated egg-like food having a yolk part and an egg white part and substantially free of yolk and egg white, and a method for producing the same.

Background Art

[0002] By heating and coagulating the cracked egg without stirring, egg cooked foods in which the yolk part and the egg white part such as tamagoyaki and boiled eggs exist independently can be prepared. Such egg cooked foods generally have a shape in which the egg white part encloses the yolk part, and are eaten as they are, and are also popular as ingredients or toppings for other cooked foods.

[0003] On the other hand, a tamagoyaki-like processed food having an appearance similar to that of a real tamagoyaki and a method for producing the same are known. For example, in Patent Document 1, a step of obtaining a first egg white part by disposing a first egg white part liquid in a heated first mold having a first recess, and a second recess and a third recess A step of obtaining a second egg white part having at least a fluid surface by disposing a second egg white part liquid in a heated second mold, and a third recess on the second egg white part liquid A method for producing a tamagoyaki-like processed food having a step of disposing a yolk part liquid having a large specific gravity to obtain a yolk part, and a step of binding the first egg white part, the second egg white part, and the yolk part is described.

[0004] In recent years, due to the increasing preference for plant-based foods and fluctuations in the supply of chicken eggs, the demand for alternatives to egg cooked foods that do not contain eggs has been increasing, and attempts have been made to produce alternatives such as tamagoyaki. For example, Patent Document 2 describes an example of producing a plant-based vegan tamagoyaki (Fried egg)-like food, in which a yolk part spheroidized by an alginate is added to a heated egg white part sample and heated.

Prior Art Documents

Patent Documents

[0005]

Patent Document 1

[0006] The fried egg-like food described in Patent Document 2 had a shape in which the yolk portion was not covered by the egg white portion, and the yolk portion protruded unnaturally from the egg white portion. Even in a coagulated egg substitute that substantially does not contain egg yolk or egg white, it is preferable that the yolk portion is enclosed within the egg white portion in order to make the appearance closer to that of a real cooked egg product and to prevent damage such as the egg yolk falling off.

[0007] In view of the above circumstances, the object of the present invention is to provide a coagulated egg-like food product that substantially does not contain egg yolk and egg white, and in which the egg yolk portion is encapsulated within the egg white portion, and a method for producing the same. [Means for solving the problem]

[0008] The inventors diligently conducted research on coagulated egg-like foods in order to achieve the above objective. The inventors conceived that by gelling the egg white portion with calcium alginate obtained by the reaction of alginate and calcium salt, it is possible to produce a coagulated egg-like food of the desired shape without the viscosity of the slurry before gelling becoming too high. Furthermore, the inventors found that conventional egg white portions that enclose the egg yolk portion could not be obtained due to the rapid reaction speed of alginate and calcium salt. They investigated conditions for controlling the reaction speed of alginate and calcium salt to form an egg white portion that encloses the egg yolk portion, and by adjusting the viscosity of the egg yolk portion and egg white portion to a predetermined range, the egg white portion can sufficiently enclose the egg yolk portion, thus completing the present invention.

[0009] This invention relates, for example, to the following inventions. (1) A method for producing a coagulated egg-like food having an egg yolk portion and an egg white portion, but substantially not containing egg yolk and egg white, An egg yolk preparation step for preparing the egg yolk portion containing a thickening agent, A slurry preparation step for the egg white portion, which involves preparing a fluid slurry for the egg white portion by dissolving the sparingly soluble calcium agent in a raw material solution containing a water-soluble alginate, water, and a sparingly soluble calcium agent, A first egg white portion filling step involves filling a portion of the egg white portion slurry, which is in a fluid state, into a container. A step of placing the egg yolk portion in the egg white portion slurry, A second egg white portion filling step involves filling the container with the remaining egg white portion slurry, which is in a fluid state, so as to cover the egg yolk portion. The process includes a gelling step, in which the slurry for the egg white portion filled in the container in the first egg white portion filling step and the second egg white portion filling step is gelled to form the egg white portion containing the egg yolk portion, The viscosity of the prepared egg yolk portion at 25°C is 2000 mPa·s or more. If the viscosity of the prepared egg yolk portion at 25°C is less than 8000 mPa·s, then the viscosity of the slurry for the egg white portion in the first egg white portion filling step at 25°C is 4000 mPa·s or more. A method for producing a coagulated egg-like food product. (2) The poorly soluble calcium agent comprises at least one selected from calcium carbonate, calcium sulfate, and calcium citrate. (1) A method for producing a coagulated egg-like food product as described in (1). (3) The process of dissolving the sparingly soluble calcium agent includes the process of mixing the sparingly soluble calcium agent with the raw material liquid. A method for producing a coagulated egg-like food product as described in (1) or (2). (4) The process of dissolving the poorly soluble calcium agent includes the process of adding a pH adjusting agent to the raw material solution to lower the pH. A method for producing a coagulated egg-like food according to any one of (1) to (3). (5) The slurry for the egg white portion further contains a chelating agent. A method for producing a coagulated egg-like food according to any one of (1) to (4). (6) The container is It has a recess including a bottom and a side wall, The bottom includes a substantially flat bottom surface that is substantially circular or substantially elliptical, The method for producing a coagulated egg-like food according to any one of (1) to (5). (7) When the viscosity of the prepared egg yolk portion at 25°C is 8000 mPa·s or more, the viscosity of the slurry for the egg white portion in the first egg white portion filling step at 25°C is 200 mPa·s or more. The method for producing a coagulated egg-like food according to any one of (1) to (6). (8) The thickener for the egg yolk portion includes a gum and / or starch. The method for producing a coagulated egg-like food according to any one of (1) to (7). (9) The entire egg yolk portion is not gelled by calcium alginate. The method for producing a coagulated egg-like food according to any one of (1) to (8). (10) A coagulated egg-like food having an egg yolk portion and an egg white portion, substantially free of egg yolk and egg white, The egg yolk portion contains a thickener, The viscosity of the egg yolk portion at 25°C is 2000 mPa·s or more, The egg white portion is entirely gelled by calcium alginate and encloses the egg yolk portion. Coagulated egg-like food.

Advantages of the Invention

[0010] According to the present invention, it is possible to provide a coagulated egg-like food substantially free of egg yolk and egg white, in which the egg yolk portion is enclosed by the egg white portion, and a method for producing the same.

Brief Description of the Drawings

[0011] <了 [Figure 1] It is a perspective view of a coagulated egg-like food according to an embodiment of the present invention. [Figure 2] It is a cross-sectional view of the above coagulated egg-like food as seen from the II-II direction. [Figure 3] It is a flowchart showing the manufacturing process of the above coagulated egg-like food. [Figure 4] It is a diagram showing a container used in the manufacturing process of the above-mentioned coagulated egg-like food. (A) is a plan view (top view), and (B) is a cross-sectional view seen from the IV-IV direction of (A). [Figure 5] (A) to (D) are all diagrams schematically showing the manufacturing process of the above-mentioned coagulated egg-like food.

Embodiments for Carrying out the Invention

[0012] Hereinafter, the present invention will be described in detail. In the present invention, the expression "content of B in A" refers to the proportion of the mass of B in A when the mass of A is 100%, and it may be a theoretical value or an analytical value. Also, in this specification, a product temperature of 25°C allows a range of 25°C ± 2°C.

[0013] <Coagulated Egg-like Food> The coagulated egg-like food of the present invention is a food mimicking a coagulated egg having a yolk part and an egg white part, and is characterized by substantially not containing egg yolk and egg white. In the present invention, "substantially not containing egg yolk and egg white" means that the total content of the components of egg white and egg yolk of avian eggs generally used for food in the coagulated egg-like food is 0.1% by mass or less. The coagulated egg-like food of the present invention preferably contains no egg white and egg yolk at all. The egg white referred to here includes, in addition to the liquid egg white obtained by cracking an egg such as a chicken egg and separating the egg yolk, those obtained by subjecting it to freeze-thaw treatment, heat sterilization treatment, de-sugaring treatment, drying treatment, lysozyme removal treatment, concentration treatment, etc. Similarly, the egg yolk includes, in addition to the liquid egg yolk obtained by cracking an egg such as a chicken egg, those obtained by subjecting it to freezing and thawing treatment, heat sterilization treatment, de-sugaring treatment, concentration treatment, etc. Also, the coagulated egg-like food of the present invention preferably has a low content of animal-derived raw materials or does not contain animal-derived raw materials. For example, the content of animal-derived raw materials in the coagulated egg-like food is preferably 5% by mass or less, more preferably 1% by mass or less, still more preferably 0.5% by mass or less, and even more preferably 0% by mass. The coagulated egg-like food of the present invention may be, for example, a refrigerated product stored and distributed at 0°C or higher and 10°C or lower, or a frozen product stored and distributed at -15°C or lower.

[0014] <Coagulated egg containing egg yolk and egg white> In this invention, "coagulated egg having an egg yolk portion and an egg white portion" refers to an egg dish in which the egg white portion and the egg yolk portion are present together, with the egg white portion enclosing the egg yolk portion, and which has been coagulated by heating. The coagulated egg of this invention does not include egg dishes such as omelets or scrambled eggs in which the egg white and yolk are intentionally mixed after cracking the egg. Specific examples of coagulated eggs having an egg yolk portion and an egg white portion include fried eggs and boiled eggs. Note that a "coagulated egg" only needs to have at least the outer egg white portion coagulated, and the egg yolk portion may be semi-cooked.

[0015] <Shape of solidified egg-like food> In the present invention, the shape of the coagulated egg-like food is not particularly limited as long as the egg white portion encloses the egg yolk portion. Specific examples of the shape of the coagulated egg-like food include, for example, a roughly disc shape, an egg shape like a boiled egg, a rod shape (roughly cylindrical, etc.), a roughly triangular prism shape, a spherical shape (ball shape), etc. In this specification, a roughly disc shape refers to a shape having a roughly circular or roughly elliptical upper surface and a roughly circular or roughly elliptical lower surface facing the upper surface, and having a relatively thin thickness (for example, a thickness of 1 / 2 or less of the maximum dimension of the upper surface), or a shape like a so-called fried egg, having a roughly circular or roughly elliptical lower surface and a vertex where the thickness is greatest, and having a relatively thin thickness (for example, a thickness of 1 / 2 or less of the maximum dimension of the lower surface).

[0016] Referring to the perspective view in Figure 1 and the cross-sectional view in Figure 2, a coagulated egg-like food product 10 according to one embodiment of the present invention will be described. In the illustrated example, the coagulated egg-like food product 10 has an egg yolk portion 11 and an egg white portion 12 enclosing the egg yolk portion 11, and is configured in a substantially disc shape. The egg white portion 12 constitutes the outer shape of the coagulated egg-like food product 10 and includes an upper surface 12a, a lower surface 12b, and a circumferential surface 12e connecting the upper surface 12a and the lower surface 12b. In the illustrated example, the lower surface 12b is formed substantially flat. In this specification, "substantially flat" means a shape without clear irregularities, and includes configurations with microscopic irregularities. In the illustrated example, the upper surface 12a is also formed substantially flat, but is not limited to this, and may have irregularities. Furthermore, the roughly disc-shaped egg white portion 12 in the illustrated example, when formed from a single mold (recess) as described later, may have no visible seams (linear irregularities, etc.) on its periphery (circumferential surface 12e in the illustrated example). Also, in the illustrated example, the egg yolk portion 11 is positioned approximately in the center of the coagulated egg-like food 10 (egg white portion 12) in a plan view from the thickness direction T, but it may be off-center. Moreover, the coagulated egg-like food 10 may have multiple (for example, two) egg yolk portions 11, and may mimic a coagulated egg containing multiple egg yolks.

[0017] <Egg yolk portion> In the present invention, the egg yolk portion is a part that mimics the egg yolk portion of a coagulated egg in a coagulated egg-like food product, as illustrated by the egg yolk portion 11 in Figures 1 and 2. The egg yolk portion may be semi-cooked and fluid, or it may be solid and coagulated throughout. The egg yolk portion contains a thickening agent to satisfy the viscosity requirements described later. Furthermore, the egg yolk portion may contain a coloring agent to achieve the color of an egg yolk. In addition, the egg yolk portion can contain a variety of raw materials as long as they do not impair the effects of the present invention. Examples include one or more selected from edible oils and fats (preferably vegetable oils and fats), sugars other than thickeners (monosaccharides, disaccharides, oligosaccharides, sugar alcohols, fructose-glucose liquid sugar, dextrin, etc.), dietary fiber, seasonings (soy sauce, salt, pepper, amino acids, etc.), emulsifiers, legumes (soybeans, peas, kidney beans, mung beans, adzuki beans, etc.) and their processed products, nuts and seeds (almonds, coconuts, etc.) and their processed products, grains (wheat, barley, rice, corn, etc.) and their processed products. In particular, the egg yolk portion preferably contains plant-based milk made from legumes, nuts and seeds, and / or grains, from the viewpoint of supplying protein and lipids to reproduce the richness of real egg yolk. Such plant-based milks are not particularly limited, but examples include soy milk, almond milk, oat milk, rice milk, etc. Furthermore, from the viewpoint of being able to adjust the desired viscosity, it is preferable that the egg yolk portion is not entirely gelled by calcium alginate. In other words, it is preferable that the egg yolk portion is not a gelled substance that does not have fluidity overall, but rather that at least a part of it has fluidity, and it is preferable that it is not a gelled substance made by calcium alginate, for example.

[0018] <Thickening agent> The egg yolk portion of the present invention contains one or more thickening agents. Examples of thickening agents include modified starch, gums, pectin, curdlan, pullulan, mannan, cellulose derivatives, and unprocessed starch. Examples of modified starch include hydroxypropyl starch, acetylated oxidized starch, sodium octenyl succinate starch, acetic acid starch, oxidized starch, hydroxypropylated phosphate crosslinked starch, and phosphorylated starch. Examples of gums include xanthan gum, native gellan gum, deacyl gellan gum, carrageenan, locust bean gum, tara gum, guar gum, gum arabic, tamarind gum, and psyllium seed gum. Examples of cellulose derivatives include methylcellulose, hydroxypropyl methylcellulose, and carboxymethylcellulose. Examples of unprocessed starch include rice starch, corn starch, tapioca starch, potato starch, and wheat starch. Of these, the thickening agent for the egg yolk portion of the present invention preferably contains a gum and / or starch, and more preferably contains both a gum and starch, from the viewpoint of satisfying the viscosity conditions described later. Examples of gums include xanthan gum, but the invention is not limited to this. The starch includes at least one selected from modified starch and unprocessed starch, and it is particularly preferable to include modified starch, which has high thickening properties and stability.

[0019] <Content of thickener in the egg yolk portion> The lower limit of the thickening agent content in the egg yolk portion of the present invention is not particularly limited as long as a viscosity within the range described later can be achieved, but is preferably 0.5% by mass or more, more preferably 1.0% by mass or more. The upper limit of the thickening agent content in the egg yolk portion is not particularly limited, but from the viewpoint of improving the flexibility of the egg yolk portion, is preferably 20% by mass or less, more preferably 15% by mass or less. If the egg yolk portion contains multiple types of thickening agents, the thickening agent content in the egg yolk portion shall be the total content of these multiple types of thickening agents. If the thickening agent contains modified starch, the modified starch content in the egg yolk portion is, for example, 0.5% by mass or more and 15% by mass or less. If the thickening agent contains gum, the gum content in the egg yolk portion is, for example, 0.01% by mass or more and 1.0% by mass or less.

[0020] <Viscosity of the egg yolk> In this invention, the viscosity of the egg yolk portion at 25°C is 2000 mPa·s or higher. This suppresses excessive flow of the egg yolk portion and enables encapsulation by the egg white portion. Furthermore, from the viewpoint of more reliably obtaining the above effects, the lower limit of the viscosity is preferably 8000 mPa·s or higher, more preferably 10000 mPa·s or higher. The upper limit of the viscosity is not particularly limited, and it may be in a state without fluidity, but from the viewpoint of obtaining a soft texture, it is preferably 500000 mPa·s or lower, more preferably 400000 mPa·s or lower. The viscosity of the egg yolk portion can be measured using, for example, a digital viscometer (e.g., RVDV-1 Prime (Brookfield Corporation)). When using the above digital viscometer, for example, measurement can be performed using spindle RV-6 under conditions of product temperature 25°C and speed 4 rpm, and if the viscosity exceeds 240000 mPa·s, measurement can then be performed using spindle RV-7. Furthermore, if the torque percentage displayed on the screen falls below 10% when measuring with spindle RV-6, the measurement should then be performed using spindle RV-2. Viscosity values ​​should be read when the viscometer reading is stable.

[0021] <Egg white portion> As illustrated by the egg white portion 12 in Figures 1 and 2, the egg white portion of the present invention is entirely gelled by calcium alginate and encloses the entire egg yolk portion. In other words, the egg white portion of the present invention is a gelled product containing a gel network mainly composed of calcium alginate. Furthermore, the egg white portion of the present invention is not formed by binding together multiple gelled products, but rather as a continuous and integrated gelled product. Such an egg white portion that encloses the entire egg yolk portion can be realized, as will be described later, by controlling the reaction speed between the alginate and calcium salt contained in the egg white portion slurry, placing the fluid egg white portion slurry above and below the egg yolk portion, and then forming a calcium alginate gel.

[0022] <Ingredients for the egg white portion> In the present invention, the egg white portion preferably contains a chelating agent and / or a pH adjuster in addition to calcium alginate, from the viewpoint of controlling the reaction speed between alginate and calcium salt. Details of these will be described later. The egg white portion can also contain a variety of other ingredients as long as they do not impair the effects of the present invention. Examples include one or more selected from edible oils and fats (preferably vegetable oils and fats), thickeners, sugars other than thickeners (monosaccharides, disaccharides, oligosaccharides, sugar alcohols, fructose-glucose liquid sugar, dextrin, etc.), dietary fiber, seasonings (soy sauce, salt, pepper, amino acids, etc.), emulsifiers, legumes (soybeans, peas, kidney beans, mung beans, adzuki beans, etc.) and their processed products, nuts and seeds (almonds, coconuts, etc.) and their processed products, grains (wheat, barley, rice, corn, etc.) and their processed products. In particular, the egg white portion preferably contains plant-based milk made from legumes, nuts, and / or grains, in order to reproduce the white color while supplying protein and lipids to make it nutritionally closer to a real egg. Such plant-based milks are not particularly limited, but examples include soy milk, almond milk, oat milk, and rice milk. Although some of the listed ingredients, such as soy milk, contain calcium, the amount of calcium salts derived from these ingredients is so small that the contribution of calcium alginate to gelation can be ignored.

[0023] <Percentage and content of egg yolk and egg white> In the coagulated egg-like food of the present invention, the ratio and content of the egg yolk and egg white can be appropriately set from the viewpoint of making the appearance closer to that of a real coagulated egg, such as a fried egg or a boiled egg. For example, the amount of egg white relative to 1 part by mass of egg yolk is preferably 1 part by mass or more and 15 parts by mass or less, more preferably 1.5 parts by mass or more and 10 parts by mass or less. Also, the amount of egg yolk contained in one coagulated egg-like food is preferably 2 g or more and 30 g or less. The amount of egg white contained in one coagulated egg-like food is preferably 2 g or more and 60 g or less.

[0024] <Method for producing coagulated egg-like food> The method for producing a coagulated egg-like food according to the present invention includes, as shown in the flowchart of Figure 3, an egg yolk preparation step S01, an egg white slurry preparation step S02, a first egg white filling step S03, an egg yolk placement step S04, a second egg white filling step S05, and an egg white slurry gelation step S06. The order of the above steps is not limited to the example in Figure 3 and can be changed as much as possible. For example, the egg yolk preparation step S01 may be performed at any timing before the egg yolk placement step S04. Each step will be described below.

[0025] <Egg yolk preparation process S01> In this step, the egg yolk portion containing a thickening agent is prepared. In this step, for example, the egg yolk portion can be prepared by mixing all the raw materials for the egg yolk portion using a stirrer or the like.

[0026] <Viscosity of the egg yolk after preparation> In the present invention, the viscosity of the prepared egg yolk portion at 25°C is 2000 mPa·s or higher, from the viewpoint of forming an egg yolk portion that is enclosed within the egg white portion. Furthermore, the lower limit of the viscosity is preferably 8000 mPa·s or higher, more preferably 10000 mPa·s or higher, from the viewpoint of more reliably obtaining the above effects. If the viscosity of the egg yolk portion is 2000 mPa·s or higher but less than 8000 mPa·s, it is necessary to adjust the viscosity of the slurry for the egg white portion, described later, to a predetermined viscosity or higher. The upper limit of the viscosity is not particularly limited, and it may be in a state that has almost no fluidity, but from the viewpoint of obtaining a soft texture and improving handling during manufacturing, it is preferably 500000 mPa·s or lower, more preferably 400000 mPa·s or lower. The viscosity of the prepared egg yolk portion is also measured in the same way as the viscosity of the egg yolk portion of the coagulated egg-like food described above. Furthermore, if the viscosity of the egg yolk portion is not considered to change substantially in each step after the egg yolk portion preparation step S01, the "viscosity of the prepared egg yolk portion" may be considered the same as the "viscosity of the egg yolk portion of the coagulated egg-like food product."

[0027] <Step S02: Preparation of Slurry for Egg White> In this process, a slurry for the egg white portion with good fluidity is prepared by dissolving the sparingly soluble calcium agent in a raw material solution containing water-soluble alginate, water, and sparingly soluble calcium agent (hereinafter also referred to as the "dissolution process").

[0028] <Raw material liquid> The raw material liquid in this process is a liquid containing the raw materials for the egg white slurry before dissolution treatment. It is preferable that the reaction between alginate and calcium salt is suppressed in the raw material liquid. "Moisture" refers to the total moisture content of the water added as a raw material and the moisture contained in each raw material. The raw material liquid may contain water-soluble alginate, moisture, and sparingly soluble calcium, as well as the raw materials for the egg white as appropriate.

[0029] <Water-soluble alginate> In the present invention, a water-soluble alginate refers to a salt in which the hydrogen atoms of the carboxyl groups in alginic acid are replaced by ions, and which is water-soluble and used in food applications. Examples of water-soluble alginates include at least one selected from sodium alginate, potassium alginate, and ammonium alginate. Of these, the water-soluble alginate preferably contains at least one selected from sodium alginate, which is easily soluble in water and easy to handle, and potassium alginate, which has similar physical properties, and it is particularly preferable that it contains sodium alginate.

[0030] <Poorly soluble calcium preparation> In the present invention, the sparingly soluble calcium agent is a calcium agent used in food applications and generally known to be sparingly soluble in water. Specifically, the sparingly soluble calcium agent of the present invention preferably contains at least one selected from calcium carbonate, calcium sulfate, and calcium citrate, and more preferably contains these as main components. In addition to these, examples of sparingly soluble calcium agents include those that have been processed or treated to become sparingly soluble in calcium salts, for example, those whose main component is an oil-coated calcium salt. The main component of the sparingly soluble calcium agent as used herein refers to a calcium compound whose content in the sparingly soluble calcium agent is 80% by mass or more, preferably 90% by mass or more, and more preferably 100% by mass. For example, if the sparingly soluble calcium agent contains multiple types of calcium carbonate, calcium sulfate, and calcium citrate, and the total content of these in the sparingly soluble calcium agent is 80% by mass or more, then these multiple types of calcium compounds are considered to be the main components of the sparingly soluble calcium agent.

[0031] Of these, calcium carbonate is known to be very poorly soluble in water. Calcium sulfate and calcium citrate are also known to be poorly soluble in water, though not as poorly soluble as calcium carbonate. Because sparingly soluble calcium salts like these are included in sparingly soluble calcium preparations, their slow dissolution rate in water can slow down the reaction speed with alginates. Furthermore, if the dissolution rate in water is too low, such as when using a sparingly soluble calcium preparation with calcium carbonate as the main component, dissolution in water and the ionization of the calcium salt can be promoted using pH adjusters, as described later.

[0032] <Slurry for egg white portion> The "slurry for egg white part" in this project contains calcium salts with a part of the poorly soluble calcium agent dissolved, but it is not in a completely gelled state as a whole, but a composition with fluidity. The slurry for egg white part is obtained by performing the dissolution treatment described below on the above-mentioned raw material liquid, and contains other raw materials of the egg white part in addition to the water-soluble alginate and the poorly soluble calcium agent. Hereinafter, specific examples of the dissolution treatment will be described.

[0033] <Example of dissolution treatment including mixing treatment> For example, the dissolution treatment in this process preferably includes a process of mixing a poorly soluble calcium agent into the raw material liquid. The mixing treatment is performed, for example, by a stirrer or the like. In this example, the poorly soluble calcium agent preferably contains a calcium compound with higher water solubility compared to calcium carbonate, for example, preferably contains calcium sulfate and / or calcium citrate, and more preferably contains these as the main components. By using a poorly soluble calcium agent that is slightly soluble in water, the poorly soluble calcium agent gradually dissolves by the mixing treatment, the ionization of calcium salts is promoted, and the reaction between the water-soluble alginate and the calcium salt is initiated. In addition, the timing of adding the poorly soluble calcium agent to the raw material liquid in this example may be approximately the same as that of other raw materials, or may be after mixing other raw materials. Also, the poorly soluble calcium agent may be added as a calcium agent-containing liquid mixed with water.

[0034] <Example of dissolution treatment including the process of adding a pH adjuster> Alternatively, the dissolution process in this step may include adding a pH adjusting agent to the raw material solution to lower the pH. In this example, the sparingly soluble calcium agent preferably contains calcium carbonate, which has particularly low solubility, and preferably contains calcium carbonate as its main component. By adding the pH adjusting agent to the raw material solution, the pH of the raw material solution is lowered, promoting the ionization of the calcium salt of the sparingly soluble calcium agent and initiating dissolution. This initiates the reaction between the water-soluble alginate and the calcium salt. Furthermore, after adding the pH adjusting agent to the raw material solution, it is preferable to mix them with a stirrer or the like to further promote the reaction. The pH adjusting agent may also be added as a pH adjusting agent-containing solution mixed with water.

[0035] <Content of poorly soluble calcium agent in egg white slurry when the poorly soluble calcium agent contains calcium carbonate as its main component> When the poorly soluble calcium agent contains calcium carbonate as its main component, the content of the poorly soluble calcium agent in the egg white slurry is not particularly limited as long as a gelled egg white portion can be formed, but is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, even more preferably 0.3% by mass or more, preferably 2.0% by mass or less, more preferably 1.5% by mass or less, and even more preferably 1.0% by mass or less.

[0036] <Content of poorly soluble calcium agent in egg white slurry when the poorly soluble calcium agent contains at least one of calcium sulfate and calcium citrate as the main component> When the poorly soluble calcium agent mainly contains at least one of calcium sulfate and calcium citrate, the content of the poorly soluble calcium agent in the egg white slurry is not particularly limited as long as a gelled egg white portion can be formed, but is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, even more preferably 0.5% by mass or more, preferably 2.0% by mass or less, more preferably 1.5% by mass or less, and even more preferably 1.3% by mass or less.

[0037] <Content of water-soluble alginate in the egg white slurry> During preparation, that is, during dissolution treatment, the content of water-soluble alginate in the egg white slurry is not particularly limited as long as it can form a gelled egg white part in cooperation with the calcium salt, but is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, preferably 10% by mass or less, and more preferably 5% by mass or less.

[0038] <pH adjuster> As described above, the egg white slurry of the present invention preferably contains a pH adjuster having an action of lowering the pH. The pH adjuster that lowers the pH can promote the ionization of the calcium salt of the poorly soluble calcium agent and promote the reaction between the alginate and the calcium salt. As described above, when the poorly soluble calcium agent contains calcium carbonate or an equivalent poorly soluble calcium compound as the main component, the solubility of the poorly soluble calcium agent is extremely low, so it is particularly preferable that the egg white slurry contains a pH adjuster. Also, when the poorly soluble calcium agent contains calcium sulfate and / or calcium citrate as the main component, it is preferable that the egg white slurry contains a pH adjuster from the viewpoint of promoting the dissolution of the poorly soluble calcium agent. Examples of the pH adjuster that lowers the pH include glucono delta lactone, gluconic acid, adipic acid, citric acid, succinic acid, DL-tartaric acid, L-tartaric acid, lactic acid, glacial acetic acid, fumaric acid, DL-malic acid, sodium DL-malic acid, and the like. Among these, the pH adjuster used in the present invention preferably contains glucono delta lactone. Glucono delta lactone has an action of gently lowering the pH, so it can gently dissolve the poorly soluble calcium agent and moderate the reaction speed between the alginate and the calcium salt.

[0039] <Content of pH adjuster in the egg white slurry> The lower limit of the pH adjusting agent content in the egg white slurry is not particularly limited as long as it promotes the dissolution of the poorly soluble calcium agent, but is preferably 0.05% by mass or more, more preferably 0.1% by mass or more. The upper limit of the pH adjusting agent content is not particularly limited as long as it suppresses a rapid increase in calcium salts, but is preferably 5% by mass or less, more preferably 2% by mass or less.

[0040] <Chelating agent> The egg white slurry of the present invention preferably contains a chelating agent, regardless of the main component of the poorly soluble calcium agent. This allows for the chelating of a portion of the released calcium salt by the chelating agent, thereby slowing down the reaction rate between the alginate and the calcium salt. Therefore, it is possible to suppress the gelation of the entire egg white slurry by the second egg white filling step S05 described later. Examples of chelating agents include condensed phosphates, which are also used in food applications. Specific examples include at least one selected from sodium metaphosphate, sodium pyrophosphate, sodium dihydrogen pyrophosphate, sodium polyphosphate (sodium tripolyphosphate, sodium tetrapolyphosphate, etc.), with sodium polyphosphate being particularly preferred. The chelating agent may be added to the raw material solution or added during the dissolution process.

[0041] <Chelating agent content in egg white slurry> The content of the chelating agent in the egg white slurry is not particularly limited as long as it provides an effect of slowing the reaction rate between the alginate and the calcium salt, but is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, preferably 1.0% by mass or less, and more preferably 0.5% by mass or less.

[0042] <Content of thickener in egg white slurry> The egg white slurry of the present invention may contain a thickening agent from the viewpoint of adjusting viscosity. The lower limit of the thickening agent content in the egg white slurry is not particularly limited as long as a viscosity within the range described later can be achieved, but is preferably 0.5% by mass or more, more preferably 1.0% by mass or more. The upper limit of the thickening agent content in the egg white slurry is not particularly limited, but from the viewpoint of improving the flexibility of the egg white slurry, is preferably 10% by mass or less, more preferably 5% by mass or less. When the egg white slurry contains multiple types of thickening agents, the thickening agent content in the egg white slurry shall be the total content of these multiple types of thickening agents. Furthermore, when the thickening agent contains modified starch, the modified starch content in the egg white slurry is, for example, 0.5% by mass or more and 10% by mass or less.

[0043] <First egg white filling process S03> In this step, as illustrated in Figure 5(A), a portion 31 of the egg white slurry in a fluid state is filled into the container 20. "Egg white slurry in a fluid state" means that the entire egg white slurry is not gelled, and at least the surface maintains a fluid state. "A portion of the egg white slurry" means a portion of the egg white slurry used in the production of one coagulated egg-like food product. The amount of egg white slurry filled in this step is not particularly limited as long as it is enough to form an egg white portion, including the bottom surface, below the thickness direction of the egg yolk portion that will be placed later. For example, the amount of egg white slurry filled in this step is preferably 0.5 parts by mass or more and 5 parts by mass or less per 1 part by mass of egg yolk portion. In this step, the egg white slurry can be filled using a known filling machine for food manufacturing.

[0044] <Container> The container used in this process may have a recess. The shape of the recess may be such that it corresponds to the shape of the egg white portion. For example, the container may have one recess or may have multiple recesses. If the container has one recess, the egg white slurry from the first egg white portion filling step S03, the egg yolk portion, and the egg white slurry from the second egg white portion filling step S05 are sequentially filled into the one recess. A container with one recess is suitable, for example, for the production of a disc-shaped coagulated egg-like food. If the container has multiple recesses, two recesses may constitute a first mold that forms the lower part of the coagulated egg-like food and a second mold that forms the upper part. In this case, the egg white slurry from the first egg white portion filling step S03 and the egg yolk portion are filled into the first mold, and the egg white slurry from the second egg white portion filling step S05 is filled into the second mold. The egg white portion can then be formed by inverting the second mold and pressing it against the first mold. Such a container with multiple recesses can be used to manufacture coagulated egg-like foods in a variety of shapes other than disc-shaped.

[0045] Figures 4(A) and (B) show examples of containers having one recess. In the container 20 illustrated in Figures 4(A) and (B), the recess 21 includes, for example, a bottom 22 and a side wall 23. The bottom 22 preferably includes a substantially flat, approximately circular or approximately elliptical bottom surface 24. The side wall 23 is connected to the periphery of the bottom 22 and forms the side surface of the recess 21. By placing the egg white slurry in such a recess 21, a coagulated egg-like food product that is approximately circular or approximately elliptical with a substantially flat bottom surface can be prepared. The container 20 may have one recess 21 or may have multiple recesses 21. Furthermore, the container used in this process is not limited to the examples in Figures 4(A) and (B) as described above.

[0046] <Viscosity of the egg white slurry> In the present invention, if the viscosity of the prepared egg yolk portion at 25°C is less than 8000 mPa·s, the viscosity of the slurry for the egg white portion in the first egg white portion filling step S03 at 25°C is 4000 mPa·s or more. By setting the viscosity of the slurry for the egg white portion to 4000 mPa·s or more when the viscosity of the egg yolk portion at 25°C is low (less than 8000 mPa·s), problems such as turbidity between the egg yolk portion and the slurry for the egg white portion, and leakage of the egg yolk portion from the bottom surface of the egg white portion can be suppressed. Furthermore, if the viscosity of the egg yolk portion at 25°C is 8000 mPa·s or more, the viscosity of the slurry for the egg white portion is not particularly limited, but for example, setting it to 200 mPa·s or more allows for more reliable containment of the egg yolk portion. The upper limit of the viscosity of the egg white slurry at 25°C in the first egg white filling step S03 is not particularly limited, but it is preferably 100,000 mPa·s or less from the viewpoint of allowing sufficient diffusion and encapsulation of the egg yolk before gelation begins. The viscosity of the egg white slurry can be measured, in the same way as the viscosity of the egg yolk, using, for example, a digital viscometer (e.g., RVDV-1 Prime (Brookfield Corporation)). When using the above digital viscometer, for example, measurement should be performed using spindle RV-6 under conditions of product temperature 25°C and speed 4 rpm, and if the viscosity exceeds 240,000 mPa·s, measurement should then be performed using spindle RV-7. Also, if the torque % value displayed on the screen when measuring with spindle RV-6 is less than 10%, measurement should then be performed using spindle RV-2. The viscosity value should be read when the viscometer reading is stable.

[0047] <Egg yolk placement process S04> In this step, as illustrated in Figure 5(B), the egg yolk portion 11 is placed in the egg white slurry 31 filled in a container 20, for example. In this step, the egg yolk portion 11 may be placed on top of the egg white slurry 31, or a portion of it may sink into the egg white slurry 31. In this step, it is preferable that the egg yolk portion 11 is placed in the center of the egg white slurry 31. As described above, the egg yolk portion 11 in this step has an appropriate viscosity and can maintain a cohesive shape without becoming cloudy with the egg white slurry 31. Therefore, a coagulated egg-like food product 10 in which the egg yolk portion 11 is enclosed by the egg white portion 12 can be prepared. In this step, the egg yolk portion may be placed using a known filling machine for food manufacturing.

[0048] <Second egg white filling process S05> In this step, as illustrated in Figure 5(C), the remaining fluid egg white slurry 32 is filled into the container 20 so as to cover the egg yolk portion 11. When using a container 20 having one recess 21 as illustrated in Figure 5(C), the egg white slurry 32 is filled on top of the egg white slurry 31 and egg yolk portion 11 that are filled in the recess 21. Alternatively, when using a container having the two recesses described above (a first mold and a second mold), the egg white slurry for this step is filled into the second mold, and the second mold is inverted and placed over the first mold, which is already filled with the egg white slurry and egg yolk portion. This fills the egg white slurry for this step so as to cover the egg yolk portion. In addition, from the viewpoint of suppressing the outflow of the egg white slurry during inversion, a film may be placed over the opening of the second mold before inversion, and the film may be removed after inversion. The amount of slurry for the egg white portion filled in this step is not particularly limited as long as it covers the entire egg yolk portion, but for example, it is 1 to 10 parts by mass per 1 part by mass of egg yolk portion. This step may also be performed in parallel with all or part of the egg yolk portion placement step S04, and in this case, this step may be performed continuously from the first egg white portion filling step S03. Furthermore, the time from the start of the dissolution treatment in the egg white portion slurry preparation step S02 to the end of the second egg white portion filling step S05 is preferably 60 minutes or less, more preferably 30 minutes or less, from the viewpoint of maintaining the fluidity of the egg white portion slurry.

[0049] <Percentage change in viscosity of the egg white slurry> Furthermore, in the present invention, when the viscosity of the egg white slurry at 25°C immediately after the dissolution treatment is X (mPa·s) and the viscosity of the egg white slurry at 25°C 10 minutes after the dissolution treatment is Y (mPa·s), the viscosity change rate expressed as (YX) / X × 100 is preferably 0% to 20%, more preferably 0% to 15%. In other words, it is preferable that the viscosity increase of the egg white slurry is small throughout the egg white filling steps S03 and S05. This suppresses the viscosity increase and gelation of the egg white slurry in the egg white filling steps S03 and S05, making it possible to form an egg white portion of the desired shape that encloses the egg yolk portion.

[0050] <Gelation process S06> In this process, as illustrated in Figure 5(D), the egg white slurries 31 and 32 filled in the first egg white portion filling step S03 and the second egg white portion filling step S05 are gelled to form an egg white portion 12 containing the egg yolk portion 11. This produces a coagulated egg-like food product 10. In this process, the egg white slurries 31 and 32 containing the egg yolk portion 11 are left to stand and held in the container 20. The holding temperature should be such that the reaction between the alginate and calcium salt is promoted, for example, between 5°C and 40°C. Furthermore, the time from the start of the dissolution process in the egg white portion slurry preparation step S02 to the end of the gelling step S06 is preferably 60 minutes or more, more preferably 90 minutes or more, from the viewpoint of preparing the gelled egg white portion, while preferably 10 hours or less, more preferably 4 hours or less, from the viewpoint of preventing a decrease in manufacturing efficiency.

[0051] <Other processes> The method for producing a coagulated egg-like food according to the present invention may, in addition to the above steps, optionally include a heat sterilization step (e.g., 70-100°C), a freezing step, etc. The heat sterilization step may be carried out under heating conditions that provide a sterilizing effect without changing the physical properties of the egg yolk and egg white portions.

[0052] <Summary of Embodiments of the Invention> As described above, in the method for producing the coagulated egg-like food of the present invention, a slurry for the egg white portion is prepared by dissolving a poorly soluble calcium agent in the raw material liquid, and then the slurry for the egg white portion, which is in a fluid state, is filled into a container so as to sandwich the egg yolk portion. In the present invention, by deliberately using a poorly soluble calcium agent to suppress the reaction speed between alginate and calcium salt, it is possible to prevent the formation of calcium alginate gel during the preparation and filling of the slurry for the egg white portion. Therefore, the egg yolk portion can be enclosed by the slurry for the egg white portion, which is in a fluid state, and then the entire mixture is gelled to prepare the egg white portion that encloses the egg yolk portion. Furthermore, because the egg white portion encloses the egg yolk portion, the detachment of the egg yolk portion during distribution and cooking is suppressed, and the desirable appearance of the coagulated egg-like food can be maintained. In addition, by maintaining a fluid state of the slurry for the egg white portion in the egg white portion filling steps S03 and S05, efficient processing using general filling techniques in food manufacturing becomes possible. In particular, when manufacturing a coagulated egg-like food product using a container having a single recess, the first egg white portion filling step S03, the egg yolk portion placement step S04, and the second egg white portion filling step S05 can be performed in a short time, thereby increasing manufacturing efficiency.

[0053] Furthermore, by setting the viscosity of the egg yolk portion at 25°C to 2000 mPa·s or higher, and, if the viscosity of the egg yolk portion at 25°C is less than 8000 mPa·s, setting the viscosity of the slurry for the egg white portion in the first egg white portion filling step at 25°C to 4000 mPa·s or higher, it is possible to suppress exposure of the egg yolk portion caused by turbidity of the egg yolk portion and egg white portion, crushing of the egg yolk portion, leakage of the egg yolk portion, etc., and to produce a coagulated egg-like food in which the egg yolk portion is sufficiently enclosed by the egg white portion.

[0054] Furthermore, by using alginate as the main component of the gelling agent in the egg white slurry, it is possible to obtain a coagulated egg-like food product that contains the egg yolk more effectively compared to other gelling agents such as gum or curdlan. If the egg white is gelled using other gelling agents such as gum or curdlan, it is necessary to increase the amount of gelling agent to obtain an egg white-like texture and sufficient gelling properties, which can increase the viscosity of the slurry before gelling. In this case, the fluidity of the egg white decreases, making it difficult to contain the egg yolk. In contrast, in this invention, by using alginate and a poorly soluble calcium agent, the viscosity of the egg white slurry can be suppressed and sufficient fluidity can be provided. As a result, an egg white portion with a shape that contains the egg yolk can be formed. In addition, because the egg white slurry has sufficient fluidity, the slurry spreads to adhere closely to the egg yolk, and an egg white portion with a high degree of unity with the egg yolk can be formed.

[0055] Furthermore, the egg white slurry may contain a pH adjuster and / or chelating agent to lower the pH and control the rate of calcium salt release and gelation by calcium alginate. By including a pH adjuster in addition to the sparingly soluble calcium agent in the egg white slurry, the ionization of calcium salt from the sparingly soluble calcium agent can be promoted. In particular, when using a sparingly soluble calcium agent mainly composed of calcium carbonate, which has very low solubility in water, the addition of a pH adjuster enables the ionization of calcium salt and initiates the reaction between alginate and calcium salt. On the other hand, by including a chelating agent in the egg white slurry, excess calcium salt can be chelated, and the reaction rate between calcium salt and alginate can be slowed. This makes it possible to maintain the fluidity of the egg white slurry until the second egg white filling step S05. Furthermore, by using a pH adjuster and a chelating agent in combination, the reaction speed between alginate and calcium salt can be effectively controlled in the egg white slurry by ionizing the calcium salt from the poorly soluble calcium agent while simultaneously chelating excess calcium salt that would otherwise lead to premature gelation. Therefore, by including a pH adjuster and / or chelating agent in the egg white slurry, the speed of gelation by calcium alginate can be controlled, and the egg white portion containing the egg yolk can be produced more stably.

[0056] <Additional Note> Although embodiments of the present invention have been described above, the present invention is not limited to the embodiments described above, and various modifications can be made without departing from the spirit of the present invention.

[0057] For example, if the sparingly soluble calcium agent mainly contains calcium carbonate, calcium sulfate, and / or calcium citrate, the slurry preparation step S02 for the egg white portion can be performed in a dissolution treatment according to these formulations. Examples of such dissolution treatments include adding a pH adjuster and calcium sulfate and / or calcium citrate to a raw material solution containing calcium carbonate and mixing them, or adding the sparingly soluble calcium agent to a raw material solution containing a pH adjuster. Alternatively, in the dissolution treatment, the sparingly soluble calcium agent may be added to a raw material solution that contains a pH adjuster but does not contain the sparingly soluble calcium agent. [Examples]

[0058] The following describes some embodiments of the present invention, but the present invention is not limited to these.

[0059] <Test Example 1: Examination of Calcium Supplements in Egg White> [Preparation of egg white slurry 1] Using the formulations shown in Table 1, the raw materials other than the 10% glucono delta-lactone solution were uniformly mixed with a stirrer to prepare the raw material solution. Subsequently, the 10% glucono delta-lactone solution was added to the prepared raw material solution (corresponding to the "dissolution treatment") and uniformly mixed with a stirrer. This prepared slurry 1 for the egg white portion. In this example, the 10% glucono delta-lactone solution was an aqueous solution containing 10% by mass of glucono delta-lactone. In the following examples, hydroxypropylated phosphate crosslinked starch was used as the modified starch.

[0060] [Preparation of egg white slurry 2-5] The raw materials, excluding the calcium agents (calcium sulfate, calcium citrate, calcium chloride, and calcium lactate), were uniformly mixed according to the formulations shown in Table 1. Then, the calcium agents shown in Table 1 were added in the amounts indicated for each (corresponding to the "raw material liquid"), and the mixture was uniformly mixed using a stirrer (corresponding to the "dissolution process"). This prepared slurries 2 to 5 for the egg white portion.

[0061] [Table 1]

[0062] [First evaluation] The physical properties of egg white slurries 1-5 were evaluated by a trained panel with more than 6 years of experience in egg processing product development, approximately 20 minutes after the start of the dissolution process, based on the following scoring criteria. "Start of dissolution process" was defined as the addition of a 10% glucono delta-lactone solution to the raw material liquid for egg white slurry 1, and the start of mixing of the calcium agent for egg white slurries 2-5. (Evaluation Criteria) A: At least a portion of it was not gelled and retained its fluidity. B: The entire thing had turned into a gel.

[0063] As shown in Table 1, egg white slurries 1-3, containing calcium carbonate, calcium sulfate, and calcium citrate respectively, were not completely gelled at the time of the first evaluation and retained fluidity, receiving an A rating. In contrast, egg white slurries 4 and 5, containing calcium chloride and calcium lactate respectively, underwent gelation from the very beginning of the dissolution process and were completely gelled at the time of the first evaluation, receiving a B rating.

[0064] [Preparation of the egg white portion] Egg white slurry samples 1-3, which received an A rating in the evaluation of the egg white slurry, were allowed to stand and gel. Approximately 2 hours and 30 minutes after the start of the dissolution process, they were subjected to heat sterilization, followed by freezing to prepare egg white samples 1-3. In this example, the sample number for the egg white sample is the same as the sample number for the corresponding egg white slurry.

[0065] [Second evaluation] The frozen egg white portions 1-3 were thawed and subjected to a second evaluation. Three trained panel members with more than six years of experience in egg product development evaluated the egg whites based on the following scoring criteria. Next, the average score of all panel members was rounded to determine the second evaluation of the physical properties of each egg white portion based on the following overall evaluation criteria. (Scoring criteria) Points 2: Overall, it was a resilient gel with a cohesive feel. 1. The gel was formed in small, partial layers, or it was not an elastic gel. (Overall evaluation criteria) A: The average score of all panel members, rounded to 2 points (between 1.5 and 2 points). B: The average score of all panel members, rounded to 1 point (1 point or more, less than 1.5 points).

[0066] As shown in Table 1, egg white portions 1-3, which contain calcium carbonate, calcium sulfate, and calcium citrate respectively, formed a cohesive, elastic gel and received an A rating.

[0067] These results show that in egg white slurry containing calcium carbonate, calcium sulfate, or calcium citrate, the gelation speed is suppressed, and a resilient, cohesive gel can be formed after a predetermined period of time. Therefore, it was found that at least one of the calcium salts used in Test Example 1, selected from calcium carbonate, calcium sulfate, and calcium citrate, is suitable as the main component of the poorly soluble calcium agent in the egg white slurry.

[0068] <Test Example 2: Examination of the egg yolk> [Preparation of the egg yolk] The raw materials were uniformly mixed using a stirrer according to the formulations shown in Table 2 to prepare egg yolk portions 1-9.

[0069] [Table 2]

[0070] [Viscosity measurement] The viscosity was measured using a digital viscometer (RVDV-1 Prime (Brookfield)) based on the viscosity measurement method described above. As shown in Table 2, the viscosity of egg yolk portion 1 was less than 2000 mPa·s, while the viscosities of egg yolk portions 2-9 were 2000 mPa·s or higher. The viscosity of egg yolk portion 1 was below the lower limit of measurement, which is 100.

[0071] [Evaluation of the shape of the egg yolk] Each syringe was filled with egg yolk, and the tip of the syringe was fixed at a constant height (approximately 1 cm) above the surface. The maximum dimension of the egg yolk on the surface was measured after dispensing approximately 10 g. The time taken from dispensing to height measurement was approximately 5 minutes or less for each sample.

[0072] As a result, as shown in Table 2, egg yolk portion 1 flowed out onto a flat surface and did not form a shape, making it impossible to measure its maximum dimensions. Furthermore, it was found that egg yolk portions 2-9 tended to decrease in maximum dimensions as viscosity increased.

[0073] <Test Example 3: Examination of the egg white and egg yolk ratio in coagulated egg-like foods> [Preparation of the egg white slurry] Egg white slurries 6-8 were prepared using the formulations listed in Table 3, in the same manner as egg white slurry 1.

[0074] [Table 3]

[0075] [Measuring the viscosity of the egg white slurry] The viscosity of the prepared egg white slurries 6-8 and egg white slurry 1 prepared in Test Example 1 was measured at 25°C. The viscosity was measured at the time of the first egg white filling step, as described later. Viscosity was measured using a digital viscometer (RVDV-1 Prime (Brookfield)) based on the viscosity measurement method described above.

[0076] As shown in Table 3, the viscosities of egg white slurries 1, 6, 7, and 8 in the first egg white placement step were 14,000 mPa·s, 250 mPa·s, 6,000 mPa·s, and 73,000 mPa·s, respectively. Furthermore, the viscosity change rates were also measured and, as shown in Table 3, were all 20% or less. In other words, the egg white slurry remained fluid even 10 minutes after the dissolution process.

[0077] [Preparation of coagulated egg-like food products] As shown in Tables 4-6, the egg yolk portions 1-9 prepared in Test Example 2 were combined with egg white portion 1, and the egg yolk portions 1, 2, 3, 4, and 6 prepared in Test Example 2 were combined with egg white portions 6-8 to prepare roughly disc-shaped coagulated egg-like food samples for Examples 1-19 and Comparative Examples 1-5 as follows.

[0078] A container with a roughly circular shape (approximately 7 cm in diameter) and a recess including the bottom and side walls (see Figure 4) was prepared. A portion (10 g) of the prepared egg white slurry was filled into the container using a syringe to perform the first egg white filling step. 10 g of egg yolk was then filled into the egg white slurry in the container using a syringe. Immediately thereafter, 20 g of the remaining egg white slurry was filled to cover the egg yolk to perform the second egg white filling step. The mixture was left to stand for approximately 2.5 hours from the start of the dissolution process to gel, and then heat sterilization (approximately 70°C) and freezing were performed to produce each coagulated egg-like food sample.

[0079] [Table 4]

[0080] [Table 5]

[0081] [Table 6]

[0082] [Appearance Evaluation] Three trained panel members with over six years of experience in egg product development evaluated the appearance of each thawed coagulated egg-like food sample based on the scoring criteria outlined below. Next, the average score of all panel members was rounded to determine the final appearance evaluation of each coagulated egg-like food sample based on the overall evaluation criteria outlined below. (Scoring criteria) Points 2: The yolk portion maintains a structure in which it is surrounded by the egg white portion, giving it the appearance of a solidified egg. 1. The slurry for the egg yolk and egg white became cloudy before gelling, exposing most of the egg yolk. Alternatively, the viscosity of the egg yolk was too low, preventing it from maintaining its shape, and the egg white did not properly enclose the yolk. (Overall evaluation criteria) A: The average score of all panel members, rounded to 2 points (between 1.5 and 2 points). B: The average score of all panel members, rounded to 1 point (1 point or more, less than 1.5 points).

[0083] As shown in Tables 4-6, Examples 2-8 and 11-19, where the viscosity of the egg yolk portion at 25°C was 8000 mPa·s or higher, and Examples 1, 9, and 10, where the viscosity of the egg yolk portion was 2000 mPa·s or higher but less than 8000 mPa·s and the viscosity of the egg white slurry in the first egg white portion filling step at 25°C was 4000 mPa·s or higher, all maintained a structure in which the egg yolk portion was enclosed by the egg white portion and received an A rating. On the other hand, in Comparative Examples 1-4, where the viscosity of the egg yolk portion at 25°C was less than 2000 mPa·s, the viscosity of the egg yolk portion was too low to maintain its shape, and part of the egg yolk portion was exposed from the egg white portion, all received a B rating. In particular, in Comparative Example 2, where the viscosity of both the egg yolk portion and the egg white slurry was low, the egg yolk portion and the egg white slurry became cloudy, and the egg yolk portion was exposed over a wide area of ​​the egg white portion. Furthermore, in Comparative Example 5, where the viscosity of the egg yolk portion was 2000 mPa·s or more and less than 8000 mPa·s, and the viscosity of the slurry for the egg white portion was less than 4000 mPa·s, the egg yolk portion leaked out from the low-viscosity slurry for the egg white portion that was filled during the first egg white portion filling step, causing the egg yolk portion to be exposed from the bottom surface of the egg white portion, resulting in a rating of B.

[0084] <Test Example 4: Examination of the ratio of egg white to egg yolk in coagulated egg-like foods> [Preparation of coagulated egg-like food products] Samples of roughly disc-shaped coagulated egg-like food (Examples 20-22) were prepared in the same manner as in Test Example 3, except that the amounts of egg white slurry 1 and egg yolk 6 placed in the first egg white filling step, and the amounts of egg white slurry placed in the second egg white filling step were changed to the amounts shown in Table 7.

[0085] [Table 7]

[0086] [Appearance Evaluation] Three trained panel members with over six years of experience in egg product development evaluated the appearance of each thawed coagulated egg-like food sample based on the same scoring criteria as in Test Example 3. They also determined the overall appearance evaluation of each coagulated egg-like food sample based on the same evaluation criteria as in Test Example 3.

[0087] As shown in Table 7, in Examples 20-22, in which the amount of egg white slurry and egg yolk placed in the first egg white filling step, and the amount of egg white slurry placed in the second egg white filling step were changed, the structure in which the egg yolk was enclosed in the egg white was maintained, and all received an A rating.

[0088] <Test Example 5: Production of a boiled egg-like solidified egg food product> Using the egg white slurry 1 and egg yolk 6 used in the above-described test example, a coagulated egg-like food in the shape of a boiled egg was manufactured. A commercially available boiled egg-shaped mold was used as the container. This container has a first mold for the blunt end of the boiled egg and a second mold for the sharp end, and the boiled egg shape can be formed by overlapping the openings of the first and second molds.

[0089] First, the egg white slurry was filled into the first mold using a syringe up to a position 5 mm below the opening of the mold. Then, the egg yolk was filled into the first mold using a syringe from above the center of the filled egg white slurry. The second mold was filled to the brim with egg white slurry using a syringe. After that, a thin film was placed on top of the opening of the second mold. The second mold, inverted upside down, was quickly placed on top of the first mold, the film was removed, and the mixture was left to stand for approximately 2 hours and 30 minutes. After standing, the gelled coagulated egg-like food was removed from both the first and second molds. This coagulated egg-like food had the shape of a boiled egg, with the egg white completely enclosing the egg yolk. This demonstrated that by changing the shape of the mold, coagulated egg-like food of various shapes can be produced.

[0090] <Summary of Examples> From the above, it was found that, in addition to being manufactured through the above processes, if the viscosity of the prepared egg yolk portion at 25°C is set to 2000 mPa·s or higher, and if the viscosity of the egg yolk portion is less than 8000 mPa·s, if the viscosity of the slurry for the egg white portion in the first egg white portion filling step is set to 4000 mPa·s or higher at 25°C, a coagulated egg-like food can be obtained in which the entire egg yolk portion is enclosed by the egg white portion, even if it does not substantially contain egg yolk or egg white. [Explanation of symbols]

[0091] 10. Coagulated egg-like foods 11. Egg yolk 12 Egg white portion 20 containers 21 Recess 22 Bottom 23 Side wall 24 Bottom

Claims

1. A method for producing a coagulated egg-like food having an egg yolk portion and an egg white portion, but substantially not containing egg yolk and egg white, An egg yolk preparation step for preparing the egg yolk portion containing a thickening agent, A slurry preparation step for the egg white portion, which involves preparing a fluid slurry for the egg white portion by dissolving the sparingly soluble calcium agent in a raw material solution containing a water-soluble alginate, water, and a sparingly soluble calcium agent, A first egg white portion filling step involves filling a portion of the egg white portion slurry, which is in a fluid state, into a container. A step of placing the egg yolk portion in the egg white portion slurry, A second egg white portion filling step involves filling the container with the remaining egg white portion slurry, which is in a fluid state, so as to cover the egg yolk portion. The process includes a gelling step, in which the slurry for the egg white portion filled in the container in the first egg white portion filling step and the second egg white portion filling step is gelled to form the egg white portion containing the egg yolk portion, The viscosity of the prepared egg yolk portion at 25°C is 2000 mPa·s or more. If the viscosity of the prepared egg yolk portion at 25°C is less than 8000 mPa·s, then the viscosity of the slurry for the egg white portion in the first egg white portion filling step at 25°C is 4000 mPa·s or more. A method for producing a coagulated egg-like food product.

2. The poorly soluble calcium agent comprises at least one selected from calcium carbonate, calcium sulfate, and calcium citrate. A method for producing a coagulated egg-like food according to claim 1.

3. The process of dissolving the poorly soluble calcium agent includes the process of mixing the poorly soluble calcium agent with the raw material liquid. A method for producing a coagulated egg-like food according to claim 1 or 2.

4. The process of dissolving the poorly soluble calcium agent includes adding a pH adjusting agent to the raw material solution to lower the pH. A method for producing a coagulated egg-like food according to claim 1 or 2.

5. The aforementioned slurry for the egg white portion further contains a chelating agent. A method for producing a coagulated egg-like food according to claim 1 or 2.

6. The aforementioned container is It has a bottom, a side wall, and a recess, The bottom portion includes a substantially flat base surface that is roughly circular or roughly elliptical. A method for producing a coagulated egg-like food according to claim 1 or 2.

7. If the viscosity of the prepared egg yolk portion at 25°C is 8000 mPa·s or more, then the viscosity of the slurry for the egg white portion in the first egg white portion filling step at 25°C is 200 mPa·s or more. A method for producing a coagulated egg-like food according to claim 1 or 2.

8. The thickening agent in the egg yolk portion comprises gum and / or starch. A method for producing a coagulated egg-like food according to claim 1 or 2.

9. The egg yolk portion is not entirely gelled by calcium alginate. A method for producing a coagulated egg-like food according to claim 1 or 2.

10. A coagulated egg-like food having an egg yolk portion and an egg white portion, but substantially free of egg yolk and egg white, The egg yolk portion contains a thickening agent. The viscosity of the egg yolk portion at 25°C is 2000 mPa·s or more. The egg white portion is entirely gelled by calcium alginate and contains the egg yolk portion. Coagulated egg-like food.