Processing methods for textile products

Abstract

This invention provides a method for processing textile products that is highly effective in deodorizing odors caused by sebum stains on textile products after dehydration. [Solution] (a) A specific alkylbenzene sulfonic acid or a salt thereof, (b) General formula R 1 O-(EO) p -Specific compounds represented by SO3M, (c) General formula R 2 O-(A2O) n A method for treating textile products, comprising bringing a textile product to contact with a soiled textile product a treatment liquid containing a specific compound represented by -H, a fragrance composition containing a specific fragrance compound, and water, wherein the total content of component (a), component (b), and component (c) in the treatment liquid is 100 mg / kg or more and 800 mg / kg or less, the mass ratio of the content of component (b) to the content of component (a) [(b) / (a)] is 0.5 or more and 0.9 or less, and the mass ratio of the content of component (c) to the total content of component (a) and component (b) [(c) / {(a)+(b)}] is 0.2 or more and 0.7 or less.

Description

Technical Field

[0001] The present invention relates to a method for treating textile products.

Background Art

[0002] Liquid detergents for textile products are used for the purpose of washing various stains attached to textile products, such as stains derived from the body, food stains, or mud stains. As surfactants used in liquid detergents for textile products, anionic surfactants such as alkylbenzene sulfonates, polyoxyalkylene alkyl ether sulfates, and alkyl sulfates, and nonionic surfactants such as polyoxyalkylene alkyl ethers are used.

[0003] Patent Document 1 describes a method for reducing malodor on a fabric by washing the fabric with a cleaning liquid containing metal ions, preferably Cu2+ and a specific alkylated phenol antioxidant.

Prior Art Documents

Patent Documents

[0004]

Patent Document 1

Summary of the Invention

Problems to be Solved by the Invention

[0005] For example, in a treatment agent composition for textile products, a fragrance composition is often blended for the purpose of imparting a fragrance to the textile products. However, due to sebum stains attached to the textile products during wearing or use, an odor derived from the sebum stains may be felt from the textile products after dehydration. The present invention provides a method for treating textile products, which is excellent in deodorizing the odor caused by stains on the textile products after dehydration even when sebum stains are attached to the textile products.

Means for Solving the Problems

[0006] In one embodiment, the present invention provides a method for treating textile products, comprising bringing a treatment solution for textile products containing the following components (a), (b), (c), (d), and water into contact with a textile product to which dirt has adhered, In the aforementioned treatment liquid for textile products, the total content of component (a), component (b), and component (c) is 100 mg / kg or more and 800 mg / kg or less. The mass ratio of the content of component (b) to the content of component (a), [(b) / (a)], is 0.5 or more and 0.9 or less. The mass ratio of the content of component (c) to the total content of components (a) and (b), [(c) / {(a)+(b)}], is between 0.2 and 0.7. Regarding methods for processing textile products. (a) Components: Alkylbenzenesulfonic acid or salt thereof having an alkyl group with 10 to 18 carbon atoms. (b) Components: Compound represented by the following general formula (1) R 1 O-(EO) p -SO3M (1) [In the formula, R 1 represents an aliphatic alkyl group with 10 to 18 carbon atoms, EO represents an ethylene oxy group, p represents the average number of added moles, p represents a number between 1 and 4, and M represents a cation. (c) Components: Compound represented by the following general formula (2) R 2 O-(A 2 O) n -H (2) [In the formula, R 2 A is an aliphatic hydrocarbon group having 9 to 16 carbon atoms, 2 The O group is one or more groups selected from ethyleneoxy groups and propyleneoxy groups, and n is the average number of moles added, which is between 5 and 15. (d) Component: A fragrance composition containing one or more fragrance compounds selected from 2-methylundecanal, γ-undecalactone, ambroxide, benzyl salicylate, 3-ethoxy-4-hydroxybenzaldehyde, (12E)-1-oxacyclohexadeca-12-en-2-one, α-hexylcinnamaldehyde, 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphthalen-2-yl)ethanone, methyl dihydrojasmonate, (5E)-3-methylcyclopentadeca-5-en-1-one, and methyl 2-naphthyl ether

Advantages of the Invention

[0007] According to the present invention, even when sebum stains adhere to a textile product, the odor caused by the sebum stains can be deodorized. In the present invention, deodorization is not limited to the complete disappearance of the odor, and the effect of reducing the odor is also included in deodorization.

Modes for Carrying Out the Invention

[0008] 〔Treatment Liquid for Textile Products〕 First, the treatment liquid for textile products used in the method for treating textile products of the present invention will be described in detail. In the specification, the viewpoint of enhancing the deodorizing effect may sometimes be expressed as the viewpoint of the deodorizing effect.

[0009] In an exemplary embodiment of the present invention, the treatment liquid for textile products of the present invention (hereinafter also referred to as the treatment liquid of the present invention) contains the following component (a), the following component (b), the following component (c), the following component (d), and water. Each component will be described below. (a) Component: An alkylbenzene sulfonic acid having an alkyl group with 10 to 18 carbon atoms or a salt thereof (b) Component: A compound represented by the following general formula (1) R 1 O-(EO) p -SO3M (1) 〔In the formula, R 1represents an aliphatic alkyl group with 10 to 18 carbon atoms, EO represents an ethylene oxy group, p represents the average number of added moles, p represents a number between 1 and 4, and M represents a cation. (c) Components: Compound represented by the following general formula (2) R 2 O-(A 2 O) n -H (2) [In the formula, R 2 A is an aliphatic hydrocarbon group having 9 to 16 carbon atoms, 2 The O group is one or more groups selected from ethyleneoxy groups and propyleneoxy groups, and n is the average number of moles added, which is between 5 and 15. (d) Components: A fragrance composition containing one or more fragrance compounds selected from 2-methyl undecanal, γ-undecalactone, ambroxide, benzyl salicylate, 3-ethoxy-4-hydroxybenzaldehyde, (12E)-1-oxacyclohexadeca-12-en-2-one, α-hexyl cinnamaldehyde, 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphthalene-2-yl)ethanone, methyl dihydrojasmonate, (5E)-3-methylcyclopentadeca-5-en-1-one, and methyl 2-naphthyl ether.

[0010] <(a) Ingredients> (a) Component is alkylbenzene sulfonic acid or a salt thereof having an alkyl group with 10 to 18 carbon atoms. When used in combination with components (b) and (c) described later, component (a) can deodorize textile products after dehydration or impart a rich fragrance to textile products, even if dirt is attached to the textile products.

[0011] (a) The alkyl group of component (a) is an alkyl group having 10 or more carbon atoms, preferably 11 or more, more preferably 12 or more, and even more preferably 13 or more, and 18 or fewer carbon atoms, preferably 17 or fewer, and more preferably 16 or fewer, from the viewpoint of deodorizing effect, and preferably a linear alkyl group.

[0012] When preparing the treatment solution of the present invention, alkylbenzenesulfonic acid, which is an acidic compound, may be added to the water that will form the composition and neutralized with an alkali in the system to form an alkylbenzenesulfonate, or it may be neutralized beforehand and then added to the treatment solution. Strong bases such as sodium hydroxide, potassium hydroxide, lithium hydroxide, and ammonium hydroxide, or alkanolamines such as monoethanolamine, diethanolamine, and triethanolamine can be used to neutralize alkylbenzenesulfonic acid. In the present invention, the mass of component (a) is used as the value converted to the sodium salt.

[0013] <(b) Component> (b) The component is a compound represented by the following general formula (1). R 1 O-(EO) p -SO3M (1) [In the formula, R 1 represents an aliphatic alkyl group with 10 to 18 carbon atoms, EO represents an ethylene oxy group, p represents the average number of added moles, p represents a number between 1 and 4, and M represents a cation.

[0014] In general formula (1), R 1 R represents an aliphatic alkyl group having 10 to 18 carbon atoms, 1 From the viewpoint of deodorizing effect, preferably has 11 or more carbon atoms, more preferably 12 or more, and from the same viewpoint, preferably has 17 or fewer carbon atoms, more preferably 16 or fewer. In general formula (1), R 1 From the viewpoint of deodorizing effect, it is preferably a linear primary alkyl group. Here, "primary" in relation to an alkyl group means that among the carbon atoms of the alkyl group, the carbon atoms bonded to other groups are primary carbon atoms.

[0015] All (b) components R contained in the processing solution of the present invention 1 The base is R 1 When converted to OH, the total R 1 R during OH 1 R 1The compound content, converted to OH, is preferably 50% by mass or more, more preferably 60% by mass or more, even more preferably 70% by mass or more, and 100% by mass or less, and preferably 95% by mass or less, from the viewpoint of further enhancing the deodorizing effect. Setting a specific ratio is preferable in that it modifies sebum stains so that the deodorizing effect of component (d) is more easily enhanced, even if sebum-derived stains remain on the textile product. All R 1 R during OH 1 R is an aliphatic alkyl group having 12 to 14 carbon atoms. 1 The OH content is determined by the raw material alcohol R used when manufacturing component (b). 1 The OH content ratio may be used. Also, if multiple (b) components are used, R is calculated from the total mass of all (b) components contained in the treatment solution of the present invention. 1 The value may be calculated based on the content ratio converted to OH. 1 The OH content may be expressed as the area percentage of alcohols with each carbon number obtained by gas chromatography analysis of the raw material alcohol, expressed as mass %.

[0016] In general formula (1), p represents the average number of moles of EO added and is a number between 1 and 4. In general formula (1), from the viewpoint of deodorizing effect, p is 1 or more, preferably 1.5 or more, more preferably 2 or more, and 4 or less, and from the same viewpoint, preferably 3.5 or less. In general formula (1), p is R, which is the raw material alcohol when producing component (b). 1 This is expressed as the number of moles of ethylene oxide added to the OH group.

[0017] In general formula (1), M represents a cation, and is preferably one or more selected from hydrogen ions, alkali metal ions, alkaline earth metal ions, ammonium ions, and alkanolammonium ions having 1 to 6 carbon atoms. Examples of alkali metal ions include sodium ions, potassium ions, and lithium ions; examples of alkaline earth metal ions include magnesium ions; and examples of alkanolammonium ions having 1 to 6 carbon atoms include monoethanolammonium ions and triethanolammonium ions.

[0018] In general formula (1), M is preferably one or more selected from alkali metal ions such as sodium ions and potassium ions, and alkanolammonium ions having 1 to 6 carbon atoms such as monoethanolammonium ions, from the viewpoint of deodorizing effect, more preferably one or more selected from sodium ions and monoethanolammonium ions. In the present invention, the mass of component (b) is the value converted to the sodium salt.

[0019] <(c) component> (c) Component is a compound represented by the following general formula (2). R 2 O-(A 2 O) n -H (2) [In the formula, R 2 A is an aliphatic hydrocarbon group having 9 to 16 carbon atoms, 2 The O group is one or more groups selected from ethyleneoxy groups and propyleneoxy groups, and n is the average number of moles added, which is between 5 and 15.

[0020] In general formula (2), R 2 This represents an aliphatic hydrocarbon group with 9 to 16 carbon atoms. In general formula (2), R 2 The carbon atoms have 9 or more carbon atoms, preferably 10 or more, more preferably 11 or more, and even more preferably 12 or more, and 16 or fewer carbon atoms, preferably 15 or fewer from the same viewpoint. In general formula (2), R 2R is one or more selected from aliphatic hydrocarbon groups, preferably aliphatic alkyl groups and aliphatic alkenyl groups. That is, in general formula (2), R 2 This is an aliphatic hydrocarbon group having 9 or more carbon atoms, preferably 10 or more, more preferably 11 or more, even more preferably 12 or more, and having 16 or fewer carbon atoms, preferably 15 or fewer from the same viewpoint, one or more groups selected from aliphatic alkyl groups and aliphatic alkenyl groups, more preferably an aliphatic alkyl group, and even more preferably a linear aliphatic alkyl group.

[0021] Furthermore, from the perspective of deodorizing effect, (c) component R 2 Preferably, component (c) is an aliphatic hydrocarbon group containing a branched alkyl group. That is, component (c) is R 2 However, it is preferable that component (c) contains a compound having a branched alkyl group. A branched alkyl group is a group selected from primary branched alkyl groups and linear secondary alkyl groups. Component (c) is preferable from the viewpoint of deodorizing effect, R 2 However, it is preferable to include one or more compounds selected from those having a primary branched alkyl group or a linear secondary alkyl group. In addition, R 2 However, if it contains a compound having a primary branched alkyl group, from the viewpoint of deodorizing effect, R 2 It is preferable that primary linear alkyl groups and primary branched alkyl groups are mixed. (c) The mass ratio of the content of a compound having a primary branched alkyl group to the content of a compound having a primary linear alkyl group in component [(content of a compound having a primary branched alkyl group) / (content of a compound having a primary linear alkyl group)] is, from the viewpoint of deodorizing effect, preferably greater than 0 / 100, more preferably 0.5 / 99.5 or more, even more preferably 1 / 99 or more, and even more preferably 2 / 98 or more, and from the same viewpoint, preferably 95 / 5 or less, more preferably 80 / 20 or less, even more preferably 50 / 50 or less, and even more preferably 30 / 70 or less.

[0022] R 2However, the method for producing component (c), which is selected from compounds having a primary branched alkyl group or a linear secondary alkyl group, is known. For example, it can be produced using alcohols synthesized with a Ziegler catalyst, alcohols produced by oxo synthesis, or alcohols obtained by oxidation using n-paraffin as a raw material.

[0023] Also, in general formula (2), R 2 From the viewpoint of deodorizing effect, it is preferable that multiple groups with different numbers of carbon atoms are present. That is, the compound represented by general formula (2) as component (c) is R 2 Nonionic surfactants containing multiple compounds with different numbers of carbon atoms are preferred.

[0024] In general formula (2), A 2 The O group represents one or more groups selected from ethyleneoxy and propyleneoxy groups. If ethyleneoxy and propyleneoxy groups are included, the ethyleneoxy and propyleneoxy groups may be in the form of block bonds or random bonds. In general formula (2), A 2 From the viewpoint of deodorizing effect, the O group is preferably a group containing an ethyleneoxy group, and more preferably a group containing both an ethyleneoxy group and a propyleneoxy group.

[0025] In general formula (2), n is A 2 This indicates the average number of added moles of O groups, and is a number between 5 and 15. In general formula (2), n is preferably 5.5 or more, more preferably 6 or more, and from the viewpoint of deodorizing effect, preferably 14 or less, more preferably 13 or less, and even more preferably 12 or less. In the present invention, n is R, which is a raw material when producing component (c). 2 A 2 This is expressed as the number of moles added by reacting with alkylene oxide, which is the raw material for the oxygen group.

[0026] In general formula (2), A 2 In the case where the O group is an ethylene oxy group, component (c) [hereinafter referred to as component (c1)] includes R 2The compound contains multiple compounds with different numbers of ethyleneoxy groups attached to the O group. When the number of ethyleneoxy groups with the highest content among the compounds contained in component (c1) is taken as n-max, the total content of n-max ± 2 is preferably 50% by mass or more, more preferably 55% by mass or more, and 100% by mass or less, from the viewpoint of deodorizing effect, preferably 95% by mass or less, and more preferably 90% by mass or less. In addition, the compound (c1) contains R 2 From the viewpoint of deodorizing effect, the OH content is preferably 8% by mass or less, more preferably 6% by mass or less, and even more preferably 4% by mass or less.

[0027] The proportion of compounds with different numbers of added ethyleneoxy groups in component (c1) can be determined by reacting component (c1) with trimethylsilane to trimethylsilylate the terminal OH of component (c1), and then performing gas chromatography analysis. In the chart output by gas chromatography, the proportion of each component with different numbers of ethyleneoxy groups can be calculated by taking the number of added ethyleneoxy groups of the compound with the largest peak area value as n-max, and then summing the area values ​​of the compounds with n-max ± 10 to 100. If there are two compounds with the same n-max, the sum of the area values ​​of the compounds with n-max ± 9 is set to 100. If there are three compounds with the same n-max, the middle compound is taken as n-max, and the sum of the area values ​​of the compounds with n-max ± 10 is set to 100. Furthermore, in the calculation of n-max ± 2 as described above, if there are two n-max values, the average of the area values ​​of the compounds at the upper limit + 2 and upper limit + 3 of n-max, and the average of the compounds at the lower limit - 2 and lower limit - 3 shall be used. For example, R 2 If the areas of compounds with 9 and 10 moles of ethyleneoxy groups added to the O group are the largest and the same, the calculation shall be based on the sum of the five areas: the average of the areas of 7 and 6, the area of ​​8, the area of ​​9, the area of ​​10, the area of ​​11, and the average of the areas of 12 and 13.

[0028] The analytical conditions for gas chromatography are as follows: Sample preparation: Dissolve 0.1 g of the sample in 10 mL of acetonitrile, then add 1 mL of trimethylsilane, react at 70°C for 1 hour, and cool to 30°C. Dilute the sample with acetonitrile as appropriate before use. Column: UA1(HT)-15M-0.25F (manufactured by Shimadzu Corporation) Inlet temperature: 250°C to 320°C (The condition that best separates the peaks is selected.) Detector: FID Heating conditions: 40℃ ⇒ 350℃ or 380℃ (20-30 minutes), 10℃ Injection method: Splitless 1 μL injection Carrier gas: Helium gas

[0029] <(d) component> (d) component is a fragrance composition containing one or more fragrance compounds selected from 2-methyl undecanal, γ-undecalactone, ambroxide, benzyl salicylate, 3-ethoxy-4-hydroxybenzaldehyde, (12E)-1-oxacyclohexadeca-12-en-2-one, α-hexyl cinnamaldehyde, 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphthalene-2-yl)ethanone, methyl dihydrojasmonate, (5E)-3-methylcyclopentadeca-5-en-1-one, and methyl 2-naphthyl ether [hereinafter referred to as component (d1)].

[0030] Furthermore, component (d) may be used in combination with component (d1) to include fragrance compounds other than component (d1). From the viewpoint of further enhancing the deodorizing effect of component (d1), component (d) may include ethoxymethylcyclododecyl ether, citronellol, cyclohexyl salicylate, damascenone (α-damascenone, β-damascenone, or mixtures thereof), ethyl 2-methylbutyrate, ethylene brassylate, diethyl-1,4-cyclohexanedicarboxylate, ionone (α-ionone, β-ionone, γ-ionone, or mixtures of two or more thereof), methylionone (α-methylionone, β-methylionone, γ-methylionone, or mixtures of two or more thereof). A fragrance composition containing one or more fragrance compounds selected from the above mixture, isobornyl acetate, limonene, linalool, linalyl acetate, 2,6-dimethyl-5-heptenal, 2-(tert-butyl)cyclohexyl acetate, 16-oxacyclohexadecan-1-one, 4-tert-butylcyclohexyl acetate, tetrahydrolinalool, 3,7-dimethylocta-1-en-2-ol, tricyclodecenyl acetate, and 2,4-dimethylcyclohexa-3-en-1-carbaldehyde (hereinafter referred to as (d2) component) is preferred. Table 1 lists examples of components (d1), (d2), and fragrance compounds other than components (d1) and (d2).

[0031] [Table 1]

[0032] The total content of component (d1) in component (d) is preferably 5% by mass or more, more preferably 10% by mass or more, even more preferably 15% by mass or more, even more preferably 20% by mass or more, even more preferably 25% by mass or more, even more preferably 30% by mass or more, even more preferably 35% by mass or more, even more preferably 40% by mass or more, even more preferably 45% by mass or more, and from the same viewpoint, preferably 100% by mass or less, more preferably 90% by mass or less, even more preferably 80% by mass or less, and even more preferably 70% by mass or less.

[0033] (d) component is a fragrance composition containing component (d1), and in order to more easily obtain the effect of enhancing the deodorizing effect of component (c), the types of components (d1) contained in component (d) are preferably two or more selected from component (d1), more preferably three or more, even more preferably four or more, even more preferably five or more, even more preferably six or more, even more preferably seven or more, even more preferably eight or more, even more preferably nine or more, and even more preferably ten or more.

[0034] If component (d) contains component (d2), the content of component (d2) in component (d) is preferably more than 0% by mass, more preferably 10% by mass or more, even more preferably 15% by mass or more, even more preferably 20% by mass or more, even more preferably 25% by mass or more, even more preferably 30% by mass or more, even more preferably 35% by mass or more, even more preferably 40% by mass or more, and from the same viewpoint, preferably 90% by mass or less, more preferably 80% by mass or less, and even more preferably 70% by mass or less.

[0035] (d) If component (d) is a fragrance composition containing component (d1) and component (d2), from the viewpoint of further enhancing the deodorizing effect of component (d1), the types of component (d2) contained in component (d) are preferably two or more selected from component (d2), more preferably three or more, even more preferably four or more, even more preferably five or more, even more preferably six or more, even more preferably seven or more, even more preferably eight or more, even more preferably nine or more, and even more preferably ten or more.

[0036] <(e) component> The treatment liquid for textile products of the present invention may optionally contain (e) alkoxylated polyethyleneimine [hereinafter referred to as component (e)] from the viewpoint of deodorizing effect. Component (e) is alkoxylated polyethyleneimine. Alkoxylation can refer to a compound in which one or more alkylene oxy groups having 2 or 3 carbon atoms are bonded to some or all of the nitrogen atoms of ethyleneimine in component (e).

[0037] (e) Examples of polyethyleneimines constituting component (e) include polymers composed of the constituent unit ethyleneimine-CH2CH2NH-. This polyethyleneimine chain may branch when the hydrogen on the nitrogen is substituted by another chain of the constituent unit ethyleneimine. That is, the polyethyleneimine does not have a completely linear structure, but may have a branched chain structure containing primary, secondary, and tertiary amino nitrogens. From the viewpoint of deodorizing effect, the number of ethyleneimines, which are the constituent units of component (e), is preferably 2 or more, more preferably 3 or more, and from the same viewpoint, preferably 15 or less, more preferably 13 or less, even more preferably 10 or less, and even more preferably 8 or less.

[0038] Furthermore, the alkoxylated polyethyleneimine of component (e) is not particularly limited, but from the viewpoint of deodorizing effect, it may be an alkoxylated polyethyleneimine in which the average number of alkoxy groups per ethyleneimine unit is preferably 1 or more, more preferably 5 or more, even more preferably 7 or more, even more preferably 10 or more, even more preferably 13 or more, even more preferably 16 or more, and from the same viewpoint, 40 or less, more preferably 35 or less, even more preferably 30 or less, and even more preferably 25 or less.

[0039] (e)Specific examples of the alkoxy group of component include, for example, the ethyleneoxy group and the propyleneoxy group. If the average number of alkoxy groups per ethyleneimine unit is 2 or more, the alkoxy group may be only the ethyleneoxy group, or it may be the propyleneoxy group, or it may be one or more groups selected from the ethyleneoxy group and the propyleneoxy group.

[0040] (e) If the alkoxy group of component contains an ethyleneoxy group and a propyleneoxy group, the average number of ethyleneoxy groups per ethyleneimine unit is preferably 3 or more, more preferably 5 or more, even more preferably 7 or more, and from the same viewpoint, 35 or less, more preferably 30 or less, even more preferably 20 or less, and even more preferably 15 or less. The average number of propyleneoxy groups is preferably 1 or more, more preferably 2 or more, even more preferably 3 or more, even more preferably 5 or more, and from the same viewpoint, 20 or less, more preferably 15 or less, and even more preferably 10 or less.

[0041] (e) The ratio of the average number of propyleneoxy groups (ax) to the average number of ethyleneoxy groups (ay) in the component, ax / ay, is preferably 0 or more, more preferably 0.1 or more, even more preferably 0.2 or more, even more preferably 0.3 or more, even more preferably 0.4 or more, even more preferably 0.5 or more, even more preferably 0.6 or more, and from the same viewpoint, preferably 10 or less, more preferably 5 or less, even more preferably 3 or less, even more preferably 1 or less, and even more preferably 0.9 or less.

[0042] (e) The weight-average molecular weight of component is preferably 500 or more, more preferably 1,000 or more, even more preferably 1,500 or more, and still more preferably 2,000 or more, and from the same viewpoint, preferably 20,000 or less, more preferably 15,000 or less, even more preferably 10,000 or less, still more preferably 8,000 or less, and still more preferably 7,000 or less. The weight-average molecular weight can be measured by gel permeation chromatography using polyethylene glycol as the standard substance.

[0043] Component (e) can be obtained by the addition reaction of alkylene oxide to polyethyleneimine, which can be carried out by conventional methods, such as adding alkylene oxide such as ethylene oxide to polyethyleneimine, the starting material, in the presence of a basic catalyst such as sodium hydroxide, potassium hydroxide, or sodium methylate, at 100°C to 180°C.

[0044] <Water> The treatment solution for textile products of the present invention contains water. The water can be deionized water (sometimes called ion-exchanged water) or water to which sodium hypochlorite has been added at a rate of 1 mg / kg to 5 mg / kg. Alternatively, tap water, river water, well water, industrial water, or any other water suitable for treating textile products can be used. The water is used as the remainder of the treatment solution for textile products, in an amount equal to 100% by mass of the treatment solution.

[0045] <Composition, etc.> The textile product treatment solution of the present invention contains component (a), component (b), component (c), component (d), and water, wherein the total content of component (a), component (b), and component (c) in the textile product treatment solution is 100 mg / kg or more and 800 mg / kg or less, the mass ratio of the content of component (b) to the content of component (a), [(b) / (a)], is 0.5 or more and 0.9 or less, and the mass ratio of the content of component (c) to the total content of components (a) and (b), [(c) / {(a)+(b)}], is 0.2 or more and 0.7 or less. The present inventors have found that by bringing a textile product with a treatment liquid for textile products containing a fragrance composition comprising components (a), (b), and (c) in predetermined proportions and amounts, and also containing a specific fragrance compound, it is possible to deodorize the odor derived from the dirt on the textile product after dewatering, and also to perceive a rich fragrance derived from the fragrance composition.

[0046] In the treatment liquid for textile products of the present invention, the content of component (a) is preferably 30 mg / kg or more, more preferably 50 mg / kg or more, from the viewpoint of deodorizing effect, and preferably 400 mg / kg or less, more preferably 300 mg / kg or less, and even more preferably 250 mg / kg or less.

[0047] In the treatment liquid for textile products of the present invention, the content of component (b) is preferably 10 mg / kg or more, more preferably 30 mg / kg or more, from the viewpoint of deodorizing effect, and preferably 200 mg / kg or less, more preferably 180 mg / kg or less, and even more preferably 160 mg / kg or less.

[0048] In the treatment liquid for textile products of the present invention, the content of component (c) is preferably 10 mg / kg or more, more preferably 30 mg / kg or more, from the viewpoint of deodorizing effect, and preferably 250 mg / kg or less, more preferably 200 mg / kg or less, and even more preferably 160 mg / kg or less.

[0049] In the treatment liquid for textile products of the present invention, the total content of component (a), component (b), and component (c) is 100 mg / kg or more, preferably 120 mg / kg or more, more preferably 150 mg / kg or more, and 800 mg / kg or less, preferably 700 mg / kg or less, more preferably 600 mg / kg or less, even more preferably 500 mg / kg or less, even more preferably 400 mg / kg or less, even more preferably 350 mg / kg or less, and even more preferably 300 mg / kg or less.

[0050] The treatment liquid for textile products of the present invention has a mass ratio of the content of component (b) to the content of component (a), [(b) / (a)], which is 0.5 or more, preferably 0.55 or more, more preferably 0.6 or more, even more preferably 0.65 or more, and 0.9 or less, preferably 0.85 or less, even more preferably 0.8 or less, from the viewpoint of deodorizing effect.

[0051] The treatment liquid for textile products of the present invention has a mass ratio [(c) / {(a)+(b)}] of the content of component (c) to the total content of components (a) and (b) which is 0.2 or more, preferably 0.25 or more, more preferably 0.3 or more, even more preferably 0.35 or more, and 0.7 or less, preferably 0.65 or less, more preferably 0.6 or less, even more preferably 0.55 or less, and even more preferably 0.5 or less, from the viewpoint of deodorizing effect.

[0052] From the viewpoint of deodorizing effect, the content of the fragrance composition, which is component (d) in the treatment liquid for textile products of the present invention, is preferably 0.5 mg / kg or more, more preferably 1 mg / kg or more, even more preferably 1.5 mg / kg or more, and even more preferably 2 mg / kg or more. From the same viewpoint, it is preferably 10 mg / kg or less, more preferably 8 mg / kg or less, even more preferably 6 mg / kg or less, and even more preferably 5 mg / kg or less.

[0053] If the treatment solution for textile products of the present invention contains component (e), the content of alkoxylated polyethyleneimine, which is component (e), in the treatment solution for textile products of the present invention is preferably 0.5 mg / kg or more, more preferably 1 mg / kg or more, even more preferably 1.5 mg / kg or more, even more preferably 2 mg / kg or more, and from the same viewpoint, preferably 30 mg / kg or less, more preferably 20 mg / kg or less, even more preferably 15 mg / kg or less, even more preferably 10 mg / kg or less, even more preferably 8 mg / kg or less, even more preferably 6 mg / kg or less, and even more preferably 5 mg / kg or less.

[0054] <Optional ingredients> <(f) component> From the viewpoint of deodorizing effect, the treatment liquid for textile products of the present invention preferably further contains an alkanolamine having 2 to 6 carbon atoms as component (f). (f) Component may include, for example, monoethanolamine, triethanolamine, etc., preferably one or more selected from monoethanolamine and triethanolamine, and more preferably monoethanolamine.

[0055] When the textile product treatment solution of the present invention contains component (f), from the viewpoint of deodorizing effect, component (f) is preferably contained in the textile product treatment solution at a concentration of 0.05 mg / kg or more, more preferably 0.1 mg / kg or more, and from the same viewpoint, preferably 20 mg / kg or less, and even more preferably 15 mg / kg or less. Furthermore, in the treatment solution for textile products of the present invention, alkanolamine salts released from components (a), (b), etc., shall be included in the content of component (f).

[0056] The textile product treatment solution of the present invention may optionally contain surfactants other than components (a), (b), and (c), for example, anionic surfactants such as fatty acids or salts thereof. In this case, the textile product treatment solution may contain surfactants other than components (a), (b), and (c) in an amount of preferably 5 mg / kg or more, more preferably 10 mg / kg or more, and preferably 90 mg / kg or less, and more preferably 80 mg / kg or less.

[0057] <(g) component> The treatment solution for textile products of the present invention may optionally contain an organic solvent having a hydroxyl group as component (g). Regarding component (g), the inventors have found that by using component (g) in combination with component (d) in a processing solution for textile products containing components (a), (b), and (c) in a total amount of 100 mg / kg to 800 mg / kg and water, the effect of the fragrance composition, which is component (d), being more uniformly attached to the textile product is enhanced.

[0058] Component (g) is preferably an organic solvent having a CLogP of -1.5 or more and 2 or less. The ClogP value of component (g) is preferably 1.5 or less, more preferably 1 or less, even more preferably 0.7 or less, and preferably -1.5 or more. Here, the ClogP value is the ClogP value calculated using ChemProperty of Perkin Elmer's ChemBioDraw Ultra ver.14.0.

[0059] Component (g) is preferably one or more compounds (g1) selected from the group consisting of the following components (g1-1), (g1-2), and (g1-3) [hereinafter also referred to as component (g1)]. (g1-1) component: Divalent to hexavalent alcohol with 2 to 6 carbon atoms [excluding (g1-2) component] (g1-2) Components: Polyalkylene glycol containing alkylene glycol units with 2 to 4 carbon atoms. (g1-3) Components: Monoalkyl ethers of (mono or poly)alkylene glycols having alkylene glycol units with 2 to 4 carbon atoms and alkyl groups with 1 to 4 carbon atoms.

[0060] Furthermore, in the above (g1-3) components, the term "(mono or poly)alkylene glycol" means monoalkylene glycol or polyalkylene glycol. Also, "polyalkylene glycol" means that the alkylene glycol units are contained in an amount of 9 or less per molecule.Specific examples of components (g1-1) to (g1-3) are shown below.The numbers in parentheses are the calculated values ​​(CLogP) of each component calculated using ChemProperty in Perkin Elmer's ChemBioDraw Ultra ver.14.0.

[0061] (g1-1) Component may be a divalent or trivalent alcohol selected from, for example, ethylene glycol (-1.4), propylene glycol (-1.1), butylene glycol (-0.73), hexylene glycol (-0.02), and glycerin (-1.5).

[0062] (g1-2) Component(s) include, for example, polyalkylene glycols selected from diethylene glycol (-1.3), triethylene glycol (-1.5), tetraethylene glycol (-1.66), dipropylene glycol (-0.69), and tripropylene glycol (-0.55).

[0063] The components (g1-3) include monoalkyl ethers of (mono or poly)alkylene glycols selected from, for example, diethylene glycol monomethyl ether (-0.78), triethylene glycol monomethyl ether (-0.96), diethylene glycol monoethyl ether (-0.39), dipropylene glycol monomethyl ether (-0.16), dipropylene glycol monoethyl ether (0.23), tripropylene glycol monomethyl ether (-0.03), diethylene glycol monobutyl ether (0.67), 1-methoxy-2-propanol (-0.30), and 1-ethoxy-2-propanol (0.09).

[0064] Component (g1) is preferably one or more selected from components (g1-1) and (g1-3), and more preferably one or more selected from propylene glycol (-1.1), glycerin (-1.5), and diethylene glycol monobutyl ether (0.67), from the viewpoint of enhancing the effect of uniformly adhering the fragrance composition, which is component (d), to the textile product. That is, component (g) is preferably one or more selected from propylene glycol, glycerin, and diethylene glycol monobutyl ether, from the viewpoint of enhancing the effect of uniformly adhering the fragrance composition to the textile product.

[0065] When the treatment solution for textile products of the present invention contains component (g), the content of component (g) in the treatment solution for textile products of the present invention is preferably 10 mg / kg or more, more preferably 50 mg / kg or more, even more preferably 80 mg / kg or more, and from the viewpoint of enhancing the effect of the fragrance composition adhering more uniformly to the textile product, preferably 300 mg / kg or less, more preferably 200 mg / kg or less.

[0066] The textile product treatment solution of the present invention may optionally contain the following components as other components in the textile product treatment solution, in an amount that does not impair the effects of the present invention. (i) Anti-redeposition agents and dispersants such as polyacrylic acid, polymaleic acid, carboxymethylcellulose, polyethylene glycol with a weight-average molecular weight of 5,000 or more, maleic anhydride-diisobutylene copolymer, maleic anhydride-methyl vinyl ether copolymer, maleic anhydride-vinyl acetate copolymer, naphthalene sulfonate formalin condensate, and polymers as described in claims 1 to 21 (page 1, column 3, line 5 to page 3, column 4, line 14) of Japanese Patent Publication No. 59-62614, preferably polyacrylic acid, polymaleic acid or salts thereof, more preferably polyacrylic acid or salts thereof, in the treatment liquid at a concentration of preferably 0.1 mg / kg to 10 mg / kg or less (ii) Color transfer inhibitors such as polyvinylpyrrolidone (iii) Bleaching agents such as hydrogen peroxide, sodium percarbonate, and sodium perborate (iv) Bleaching activators such as tetraacetylethylenediamine and bleaching activators represented by general formulas (I-2) to (I-7) of Japanese Patent Publication No. 6-316700. (v) Enzymes such as cellulase, amylase, pectinase, protease, and lipase (vi) Enzyme stabilizers such as boron compounds, calcium ion sources (calcium ion supply compounds), bihydroxy compounds, and formic acid. (vii) Fluorescent dyes, such as those commercially available as Chinopearl CBS (trade name, manufactured by Ciba Specialty Chemicals Co., Ltd.) or Whitex SA (trade name, manufactured by Sumitomo Chemical Co., Ltd.) (viii) Antioxidants such as butylhydroxytoluene, distyrenated cresol, sodium sulfite, and sodium bisulfite (ix) Solubilizing agents such as p-toluenesulfonic acid, metaxylenesulfonic acid, and benzoates (which also have preservative effects). (x) Water-immiscible organic solvents such as paraffins such as octane, decane, dodecane, tridecane, etc., olefins such as decene, dodecene, etc., alkyl halides such as methylene chloride, 1,1,1-trichloroethane, etc., and terpenes such as D-limonene (xi) Metal ion exchangers such as zeolites and crystalline layered silicates (xii) Other defoaming agents such as pigments and silicones (xiii) A polyvalent carboxylic acid having 2 to 6 carbon atoms and 2 to 4 valences, such as citric acid, is preferably 0.1 mg / kg or more and 100 mg / kg or less in the treatment liquid

[0067] From the viewpoint of the deodorizing effect, the pH of the treatment liquid for textile products of the present invention is preferably 5 or more, more preferably 6 or more, and preferably 9.0 or less, more preferably 8.5 or less, still more preferably 8.0 or less at 25°C. In the present invention, the pH at 25°C is the value measured at 25°C using a glass electrode. Specifically, it is measured by the following method.

[0068] <pH Measurement Method> Calibrate the pH electrode (type 6367) in advance with a phthalic acid buffer solution (pH 4.01), a phosphate standard solution (pH 6.84), and a borate standard solution (pH 9.18) for the pH meter D-52 manufactured by Horiba, Ltd., and rinse thoroughly with ion-exchanged water. Put the pH electrode calibrated and washed as described above into the treatment liquid for textile products whose temperature has been adjusted to 25°C, and measure using the AUTO HOLD mode of the pH meter until the measured value becomes constant.

[0069] Textile products include clothing and products other than clothing. Specifically, textile products such as denim pants and jackets, batik, undershirts, T-shirts, Y-shirts, blouses, slacks, hats, handkerchiefs, towels, knits, socks, underwear, tights, etc. are included, and it is particularly useful in an embodiment where textile products that are likely to be attached with sebum stains are the treatment target. The fibers that make up the textile product may be either hydrophobic or hydrophilic. Examples of hydrophobic fibers include protein-based fibers (milk protein casein fiber, Promix, etc.), polyamide-based fibers (nylon, etc.), polyester-based fibers (polyester, etc.), polyacrylonitrile-based fibers (acrylic, etc.), polyvinyl alcohol-based fibers (vinylon, etc.), polyvinyl chloride-based fibers (polyvinyl chloride, etc.), polyvinylidene chloride-based fibers (vinylidene, etc.), polyolefin-based fibers (polyethylene, polypropylene, etc.), polyurethane-based fibers (polyurethane, etc.), and polyvinyl chloride / polyvinyl alcohol copolymer-based fibers (Polycloral, etc.). Examples of hydrophilic fibers include seed hair fibers (cotton, kapok, etc.), bast fibers (hemp, flax, ramie, cannabis, jute, etc.), leaf vein fibers (Manila hemp, sisal, etc.), coconut fibers, rush, straw, animal hair fibers (wool, mohair, cashmere, camel hair, alpaca, vicuña, angora, etc.), silk fibers (domestic silk, wild silk), feathers, and cellulose fibers (rayon, polynosic, cupro, acetate, etc.).

[0070] <Method for manufacturing treatment solution for textile products> In exemplary embodiments, the present invention provides a method for producing a treatment liquid for textile products by mixing component (a), component (b), component (c), component (d) and water, which can be produced by the following production method (1) or production method (2). In the method for producing the textile treatment solution of the present invention, the matters described in the description of the textile treatment solution of the present invention may be applied as appropriate. Each component used in the method for producing the textile treatment solution of the present invention is the same as those described in the description of the textile treatment solution of the present invention. In the method for producing the textile treatment solution of the present invention, the "content" in the textile treatment solution of the present invention is read as "mixing amount," and the matters described in the description of the textile treatment solution of the present invention are applied as appropriate.

[0071] [Manufacturing method 1] The present invention provides a method for producing a treatment liquid for textile products, which involves mixing the aforementioned raw materials for mixing, namely component (a), component (b), component (c), component (d), optional component as needed, and water, so that the total amount of component (a), component (b), and component (c) is between 100 mg / kg and 800 mg / kg, the mass ratio of the content of component (b) to the content of component (a), [(b) / (a)], is between 0.5 and 0.9, and the mass ratio of the content of component (c) to the total content of components (a) and (b), [(c) / {(a)+(b)}], is between 0.2 and 0.7.

[0072] [Manufacturing method 2] The present invention provides a method for producing a treatment liquid for textile products, which involves mixing a liquid treatment agent composition for textile products, which is the raw material to be mixed, containing component (a), component (b), component (c), component (d), an optional component as needed, and water, wherein the total amount of component (a), component (b), and component (c) is 30% by mass or more and 70% by mass or less, the mass ratio of the content of component (b) to the content of component (a), [(b) / (a)], is 0.5 or more and 0.9 or less, and the mass ratio of the content of component (c) to the total content of components (a) and (b), [(c) / {(a)+(b)}], is in the range of 0.2 or more and 0.7 or less, with water used for treating the fibers. The liquid treatment agent composition for textile products is described below.

[0073] [Liquid treatment agent composition for textile products] In exemplary embodiments, a liquid treatment agent composition for textile products that can be used in the method for producing the treatment solution for textile products 2 of the present invention may be a liquid treatment agent composition for textile products that contains component (a), component (b), component (c), component (d), an optional component if necessary, and water, wherein the total amount of component (a), component (b), and component (c) is 30% by mass or more and 70% by mass or less, the mass ratio of the content of component (b) to the content of component (a), [(b) / (a)] is 0.5 or more and 0.9 or less, and the mass ratio of the content of component (c) to the total content of components (a) and (b), [(c) / {(a)+(b)}] is in the range of 0.2 or more and 0.7 or less. In the liquid treatment agent composition for textile products of the present invention, the matters described in the treatment solution for textile products of the present invention may be applied as appropriate. Each component used in the liquid treatment agent composition for textile products of the present invention is the same as those described in the treatment solution for textile products of the present invention.

[0074] The present inventors have found that by mixing a liquid treatment agent composition for textile products containing components (a), (b), and (c) in predetermined proportions and amounts, and (d) a specific fragrance compound, with water, a treatment solution obtained by contacting a soiled textile product with this solution can deodorize the odor derived from the dirt on the textile product after dewatering, and also allow the user to experience a rich fragrance derived from the fragrance composition.

[0075] In the liquid treatment agent composition for textile products of the present invention, the content of component (a) is preferably 10% by mass or more, more preferably 15% by mass or more, from the viewpoint of deodorizing effect, and preferably 30% by mass or less, more preferably 28% by mass or less, and even more preferably 25% by mass or less.

[0076] In the liquid treatment agent composition for textile products of the present invention, the content of component (b) is preferably 8% by mass or more, more preferably 10% by mass or more, from the viewpoint of deodorizing effect, and preferably 30% by mass or less, more preferably 25% by mass or less, and even more preferably 20% by mass or less.

[0077] In the liquid treatment agent composition for textile products of the present invention, the content of component (c) is preferably 8% by mass or more, more preferably 10% by mass or more, from the viewpoint of deodorizing effect, and preferably 30% by mass or less, more preferably 25% by mass or less, and even more preferably 20% by mass or less.

[0078] In the liquid treatment agent composition for textile products of the present invention, the total content of component (a), component (b), and component (c) is 30% by mass or more, preferably 35% by mass or more, more preferably 40% by mass or more, and 70% by mass or less, preferably 65% ​​by mass or less, and more preferably 60% by mass or less, from the viewpoint of deodorizing effect.

[0079] The liquid treatment agent composition for textile products of the present invention has a mass ratio of the content of component (b) to the content of component (a), [(b) / (a)], which is 0.5 or more, preferably 0.55 or more, more preferably 0.6 or more, even more preferably 0.65 or more, and 0.9 or less, preferably 0.85 or less, even more preferably 0.8 or less, from the viewpoint of deodorizing effect.

[0080] The liquid treatment agent composition for textile products of the present invention has a mass ratio [(c) / {(a)+(b)}] of the content of component (c) to the total content of components (a) and (b), which is 0.2 or more, preferably 0.25 or more, more preferably 0.3 or more, even more preferably 0.35 or more, and 0.7 or less, preferably 0.65 or less, more preferably 0.6 or less, even more preferably 0.55 or less, and even more preferably 0.5 or less, from the viewpoint of deodorizing effect.

[0081] In the liquid treatment agent composition for textile products of the present invention, the content of the fragrance composition, which is component (d), is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, even more preferably 0.5% by mass or more, and even more preferably 0.7% by mass or more, and from the same viewpoint, preferably 3% by mass or less, more preferably 2% by mass or less, even more preferably 1.5% by mass or less, and even more preferably 1% by mass or less.

[0082] The liquid treatment agent composition for textile products of the present invention may optionally contain alkoxylated polyethyleneimine as component (e). If the composition contains component (e), the content of component (e) in the composition is preferably 0.5% by mass or more, more preferably 1% by mass or more, even more preferably 1.5% by mass or more, even more preferably 2% by mass or more, and from the same viewpoint, preferably 5% by mass or less, more preferably 4.5% by mass or less, even more preferably 4% by mass or less, and even more preferably 3.5% by mass or less.

[0083] The liquid treatment agent composition for textile products of the present invention may optionally contain component (f). When the composition contains component (f), from the viewpoint of deodorizing effect, component (f) is preferably contained in the composition at a concentration of 0.2% by mass or more, more preferably 0.5% by mass or more, and from the same viewpoint, preferably 12% by mass or less, and even more preferably 10% by mass or less. In addition, alkanolamine salts released from components (a), (b), etc., in the treatment liquid for textile products of the present invention are included in the content of component (f).

[0084] The liquid treatment agent composition for textile products of the present invention may optionally contain component (g), and if the composition contains component (g), from the viewpoint of deodorizing effect, component (g) is preferably contained in the composition at a concentration of 10% by mass or more, more preferably 15% by mass or more, and from the same viewpoint, preferably 28% by mass or less, and even more preferably 26% by mass or less.

[0085] The liquid treatment agent composition for textile products of the present invention contains (xiii) a divalent to tetravalent polycarboxylic acid having 2 to 6 carbon atoms, such as citric acid, preferably containing (xiii) a divalent to tetravalent polycarboxylic acid having 2 to 6 carbon atoms, such as citric acid, in an amount of 0.1% by mass or more, more preferably 0.3% by mass or more, and from the same viewpoint, preferably 3% by mass or less, and even more preferably 1.5% by mass or less.

[0086] The liquid treatment agent composition for textile products of the present invention may contain water. The water content in the liquid treatment agent composition for textile products of the present invention is preferably 5% by mass or more, more preferably 10% by mass or more, preferably 65% ​​by mass or less, more preferably 50% by mass or less, and even more preferably 30% by mass or less.

[0087] <Processing methods for textile products> In exemplary embodiments, the present invention provides a method for treating textile products, comprising contacting a textile product with a treatment solution for textile products containing component (a), component (b), component (c), component (d), and water, wherein the total content of component (a), component (b), and component (c) in the treatment solution for textile products is 100 mg / kg or more and 800 mg / kg or less, the mass ratio of the content of component (b) to the content of component (a) [(b) / (a)] is 0.5 or more and 0.9 or less, and the mass ratio of the content of component (c) to the total content of components (a) and (b) [(c) / {(a)+(b)}] is 0.2 or more and 0.7 or less. Furthermore, the method for treating textile products according to the present invention may also be a method for deodorizing textile products.

[0088] In the method for treating textile products of the present invention, the matters described above for the treatment liquid or liquid treatment agent composition for textile products of the present invention may be applied as appropriate. The components, content ratios, and proportions of the treatment liquid or liquid treatment agent composition for textile products used in the method for treating textile products of the present invention are the same as those described above for the treatment liquid or liquid treatment agent composition for textile products of the present invention. It is preferable to use the liquid treatment agent composition for textile products of the present invention described above in the treatment method.

[0089] The aforementioned treatment liquid may be prepared by diluting the liquid treatment agent composition for textile products of the present invention with water used to treat the textile products. Specifically, from the viewpoint of imparting a desirable texture to the textile products, the amount of the liquid treatment agent composition for textile products of the present invention used per 30 liters of water is preferably 7.5 g or more, more preferably 10 g or more, from the viewpoint of deodorizing effect, and preferably 30 g or less, more preferably 20 g or less, from the same viewpoint.

[0090] In the method for treating textile products of the present invention, the textile products may be treated with a treatment solution for textile products prepared by diluting the liquid treatment agent composition for textile products of the present invention with water. Specifically, from the viewpoint of deodorizing effect, the amount of the liquid treatment agent composition for textile products of the present invention used per 1 kg of textile product is preferably 5 g or more, more preferably 7 g or more, and from the same viewpoint, preferably 30 g or less, more preferably 20 g or less.

[0091] The water used in the textile product processing method of the present invention is preferably hard water. The hardness of the water is preferably 1°dH or more, more preferably 2°dH or more, even more preferably 3.5°dH or more, and preferably 20°dH or less, more preferably 18°dH or less, and even more preferably 15°dH or less, in German hardness units. Herein, German hardness (°dH) as used herein refers to the concentration of calcium and magnesium in water expressed as a CaCO3 equivalent concentration of 1 mg / L (ppm) = approximately 0.056°dH (1°dH = 17.8 ppm).

[0092] The calcium and magnesium concentrations required for this German hardness are determined by chelation titration using ethylenediaminetetraacetate disodium salt. The specific method for measuring the German hardness of water as used herein is described below.

[0093] <Method for measuring water hardness in Germany> 〔reagent〕 • 0.01 mol / l EDTA-2Na solution: A 0.01 mol / l aqueous solution of disodium ethylenediaminetetraacetate (titration solution, 0.01 M EDTA-Na2, manufactured by Sigma-Aldrich). ·Universal BT indicator (product name: Universal BT, manufactured by Dojindo Kagaku Kenkyusho Co., Ltd.) • Ammonia buffer solution for hardness measurement (a solution made by dissolving 67.5g of ammonium chloride in 570ml of 28w / v% ammonia water and diluting the total volume to 1000ml with deionized water). [Measuring hardness] (1) Take 20 ml of water to be used as a sample into a conical beaker using a volumetric pipette. (2) Add 2 ml of ammonia buffer solution for hardness measurement. (3) Add 0.5 ml of Universal BT indicator. Confirm that the solution is reddish-purple after adding the indicator. (4) While shaking the conical beaker well, add the 0.01 mol / l EDTA·2Na solution dropwise from the burette, and the titration endpoint is reached when the sample water turns blue. (5) The total hardness is calculated using the following formula. Hardness (°dH)=T×0.01×F×56.0774×100 / A T:0.01mol / l Titration amount of EDTA・2Na solution (mL) A: Sample volume (20 mL, volume of water used as the sample) F: Factor of 0.01 mol / l EDTA-2Na solution

[0094] In the method for processing textile products of the present invention, the value of the bath ratio, which is expressed as the ratio of the mass of the textile product (kg) to the amount of processing liquid (liters), that is, the value of the amount of processing liquid (liters) / mass of the textile product (kg) (hereinafter, this ratio may also be referred to as the bath ratio), is preferably 2 or more, more preferably 3 or more, even more preferably 4 or more, even more preferably 5 or more, and preferably 50 or less, more preferably 40 or less, and even more preferably 30 or less.

[0095] In the method for processing textile products of the present invention, the processing time for the textile products is preferably 1 minute or more, more preferably 2 minutes or more, even more preferably 3 minutes or more, and preferably 1 hour or less, more preferably 30 minutes or less, even more preferably 20 minutes or less, and even more preferably 15 minutes or less, from the viewpoint of deodorizing effect.

[0096] In the textile product processing method of the present invention, after processing the textile product, it is optional to rinse the textile product with water, and rinsing with water is preferred. The water used for rinsing may also be water with the aforementioned hardness. In rinsing, the rinsing water can be used on the textile product in the same ratio as the bath ratio of the processing solution. The rinsing time can also be within the same range as the washing time.

[0097] In the textile product processing method of the present invention, it is preferable to dewater the textile product after processing or rinsing.

[0098] The method for processing textile products of the present invention is also suitable for rotary processing methods. A rotary processing method refers to a processing method in which textile products that are not fixed to a rotating machine are rotated around a rotating shaft together with the processing liquid. The rotary processing method can be carried out using a rotary washing machine. Specifically, rotary washing machines include drum-type washing machines, pulsator-type washing machines, and agitator-type washing machines. Commercially available rotary washing machines for household use can be used. Drum-type washing machines have become rapidly popular in recent years because they can reduce the amount of water used in one wash cycle. Drum-type washing machines, in particular, can reduce the amount of water used during washing. [Examples]

[0099] <Examples 1-14, Comparative Examples 1-2> Liquid treatment agent compositions for textile products shown in Table 3 were prepared using the following components. The pH was adjusted to pH 7.8 (25°C) using a 10% hydrochloric acid aqueous solution or a 10% sodium hydroxide aqueous solution. The pH of the composition was calculated by the method described later. The treatment solutions for textile products obtained by diluting the liquid treatment agent compositions for textile products obtained in Composition Examples 1-14 and Composition Examples 1-2 with water, respectively, were evaluated for deodorizing effect and fragrance release using the method described later. The results are shown in Table 4.

[0100] <Method for preparing a liquid treatment agent composition for textile products> A liquid treatment agent composition for textile products was prepared by blending the following components to obtain a final mass of 100g. A 200mL beaker was filled with water equivalent to 90% of the final mass and heated to 40°C. A rod-shaped Teflon® stirrer piece, 8cm long and 1cm wide, was added and stirred at 100 r / min. Next, components (a), (b), (c), and optional components (e), (f), (g), and citric acid were added sequentially and stirred for 20 minutes. Then, component (d) was added and stirred for another 5 minutes. The mixture was cooled in a 5°C water bath while stirring until the contents reached 25°C. The pH was adjusted to 7.8 with a 10% sodium hydroxide or 10% hydrochloric acid aqueous solution. Finally, water was added to obtain a final mass of 100g. The pH of the final product was 7.8 in all cases. The composition of the liquid treatment agent composition for textile products is shown in Table 3.

[0101] <Method for preparing treatment solution for textile products> A Teflon® stirrer piece (8 cm long x 1 cm wide, rod-shaped) was placed in a 1-liter glass beaker. 0.28 g of the textile product liquid treatment agent composition described in Table 3 and 700 g (700 mL) of water (Wakayama water, 25°C, 3° hard water) were added, and the mixture was stirred with a magnetic stirrer at 100 r / min for 5 minutes to prepare the textile product treatment solution. The composition of the textile product treatment solution is shown in Table 4.

[0102] <Ingredients used> <(a) Ingredients> • (a-1): Sodium alkylbenzenesulfonate (alkyl group is a linear alkyl group with 10 to 14 carbon atoms) <(b) Component> (b-1): Sodium polyoxyethylene alkyl ether sulfate (in general formula (1), R 1 R is a linear primary alkyl group having 10 to 18 carbon atoms, and the starting alcohol is R. 1 As OH, R 1 The mass percentages (mass%) of alcohols with 10 / 12 / 14 / 16 / 18 carbon atoms are 1 / 70 / 22.5 / 6 / 0.5, respectively, p is 2, and M is sodium ion. (b-2): Sodium polyoxyethylene alkyl ether sulfate (in general formula (1), R 1 R is a linear primary alkyl group having 10 to 18 carbon atoms, and the starting alcohol is R. 1 As OH, R 1 The mass percentages (mass%) of alcohols with 10 / 12 / 14 / 16 / 18 carbon atoms are 0.1 / 10 / 20 / 64.9 / 5, respectively, p is 2, and M is sodium ion.

[0103] <(c) component> • (c-1): Polyoxyethylene alkyl ether (in general formula (2), R 2 is a linear primary alkyl group having 10 to 16 carbon atoms, n is 10, A 2 (The O group is an ethylene oxy group, and the total content of n-max±2 in the compound is 47% by mass.) • (c-2): Polyoxyethylene alkyl ether (in general formula (2), R 2 is a linear secondary alkyl group having 12 to 14 carbon atoms, n is 9, A 2 (The O group is an ethylene oxy group; the total content of n-max±2 in the compound is 48% by mass.) • (c-3): Polyoxyethylene alkyl ether (in general formula (2), R 2 is a linear secondary alkyl group having 12 to 14 carbon atoms, n is 7, A 2 The O group is an ethylene oxy group, and the total content of n-max±2 in the compound is 52% by mass (component c1). • (c-4): Polyoxyethylene alkyl ether (in general formula (2), R 2 is a linear secondary alkyl group having 12 to 14 carbon atoms, n is 7, A 2 The O group is an ethylene oxy group, and the total content of n-max±2 in the compound is 57% by mass (component c1). • (c-5): Polyoxyalkylene alkyl ether (in general formula (2), R 2(The compound is a primary alkyl group having 12 to 13 carbon atoms, with a ratio of 95 / 5 (by mass) of linear primary alkyl groups to branched primary alkyl groups, an average number of moles of oxyethylene groups added being 7, and an average number of moles of propyleneoxy groups added being 4.) • (c-6): Polyoxyalkylene alkyl ether (in general formula (2), R 2 (The compound is a primary alkyl group having 14 to 15 carbon atoms, with a ratio of 95 / 5 (by mass) of linear primary alkyl groups to branched primary alkyl groups, an average number of moles of oxyethylene groups added being 8, and an average number of moles of propyleneoxy groups added being 3.)

[0104] <(d) component> (d-1): Fragrance compositions listed in Table 2

[0105] [Table 2]

[0106] <(e) component> • (e-1): Alkoxylated polyethyleneimine (average constituent units of ethyleneimine are 7, average number of ethyleneoxy groups per ethyleneimine skeleton (ay) is 25, average number of propyleneoxy groups per ethyleneimine skeleton (ax) is 0, ax / ay = 0, weight-average molecular weight: 3500) • (e-2): Alkoxylated polyethyleneimine (average constituent units of ethyleneimine are 4, average number of ethyleneoxy groups per ethyleneimine skeleton (ay) is 11, average number of propyleneoxy groups per ethyleneimine skeleton (ax) is 8, ax / ay = 0.73, weight-average molecular weight: 6600)

[0107] <Water> • Water containing 3 mg / kg of sodium hypochlorite in ion-exchanged water.

[0108] <Optional ingredients> <(f) component> • (f-1): Monoethanolamine <(g) component> ·(g-1): Propylene glycol <Others> · Citric acid

[0109] <Method for measuring pH> A combined electrode for pH measurement ((Glass folding sleeve type, manufactured by Horiba, Ltd.)) was connected to a pH meter (pH / Ion meter F-23, manufactured by Horiba, Ltd.), and the power was turned on. As the internal solution of the pH electrode, a saturated potassium chloride aqueous solution (3.33 mol / L) was used. Next, 100 mL beakers were filled with a pH 4.01 standard solution (phthalate standard solution), a pH 6.86 (neutral phosphate standard solution), and a pH 9.18 standard solution (borate standard solution), respectively, and immersed in a constant temperature bath at 25 °C for 30 minutes. The pH measurement electrode was immersed in the temperature-adjusted standard solution for 3 minutes, and calibration operations were performed in the order of pH 6.86 → pH 9.18 → pH 4.01. The sample to be measured was adjusted to 25 °C, the electrode of the above pH meter was immersed in the sample, and the pH after 1 minute was measured.

[0110] <Preparation of fiber products for evaluation> 1. Preparation of model sebum stains A model sebum stain having the following composition was prepared. * Composition of the model sebum artificial contamination solution: Lauric acid 0.4% by mass, Myristic acid 3.1% by mass, Pentadecanoic acid 2.3% by mass, Palmitic acid 6.2% by mass, Heptadecanoic acid 0.4% by mass, Stearic acid 1.6% by mass, Oleic acid 7.8% by mass, Triolein 13.0% by mass, Palmitic acid n-hexadecyl 2.2% by mass, Squalene 6.5% by mass, Egg white lecithin liquid crystal 1.9% by mass, Kanuma red clay 8.1% by mass, Carbon black 0.01% by mass, Balance water (total 100% by mass)

[0111] 2. Preparation of fiber products for evaluation 50 μl of the aforementioned model sebum stain was applied to each sheet of polyester faille (100% polyester, manufactured by Dyeing Test Materials Co., Ltd., cut into 6cm x 6cm squares). The sebum components were then spread onto the textile product in a constant temperature bath (60°C, 1 HR), and after standing overnight in a room at 20°C / 65%RH, the samples were used for the treatment test. A total of 8 sheets were used per bath during the treatment test.

[0112] 3. Preparation of textile products for bath ratio adjustment Two types of textile products (cotton knit fabric (unspun cotton, 100% cotton, Tanigashira Shoten) and polyester jersey (Tanigashira Shoten), each cut into 6cm x 6cm squares) were processed using a bath ratio of 20, with 23 pieces of cotton knit fabric and 10 pieces of polyester jersey fabric being used.

[0113] <Processing methods for textile products> <Processing conditions> The fibers were treated using a terg-O-tometer. 600 mL of the aforementioned textile treatment solution was placed in a 1-liter stainless steel cylindrical container (for Terg-O-Tometer), and eight evaluation textile products, eight polyester faille fabrics free of model sebum stains (criterion 3 for odor evaluation), and 33 textile products with the aforementioned bath ratio adjustment were placed inside. Each treatment was then carried out under the following conditions. • Processing: Textile products were processed under the following conditions: rotation speed of 100 r / m, 10 min, and bath ratio of 20. • Dehydration: All textile products processed under the above conditions were removed from the beaker and placed in the spin-drying tub of a twin-tub washing machine (Hitachi, Ltd., PS-H45L) and dehydrated for 1 minute. • Rinsing: Fresh water (Wakayama City water, 20°C) was added to the aforementioned stainless steel beaker, and the textile products were rinsed under the conditions of a rotation speed of 100 r / m, 10 min, and a bath ratio of 20. • Dehydration: All the textile products rinsed in the above rinse were removed from the beaker and placed in the spin-drying tub of a twin-tub washing machine (Hitachi, Ltd., PS-H45L) and dehydrated for 1 minute. Eight textile products were removed immediately after spin-drying, stacked, and placed in a disposable petri dish with a lid. The odor of each product was then evaluated immediately after washing. Furthermore, visual inspection of the evaluation textile products after dehydration revealed that while the cleaning was successful, some dirt remained.

[0114] <Method for evaluating deodorizing effect> The odor level derived from model sebum stains emanating from textile products treated with the textile treatment solution of Example 1 was assigned an evaluation score of 2 (criterion 1), the odor level derived from model sebum stains emanating from textile products treated with the textile treatment solution of Comparative Example 1 was assigned an evaluation score of 1 (criterion 2), and the odor level derived from model sebum stains emanating from textile products without model sebum stains emanating was assigned an evaluation score of 6 (criterion 3). The relative odor level to each criterion was evaluated in increments of 0.5 points. The odor evaluation was performed by three evaluators skilled in sensory evaluation of odors, and the average score was calculated. The results are shown in Table 4. A higher evaluation score indicates superior deodorizing effect.

[0115] [Table 3]

[0116] [Table 4]

[0117] <Preparation Methods for Examples 15-20 of Liquid Treatment Agent Compositions for Textile Products> Using the same method as described above for preparing the liquid treatment agent compositions for textile products, the liquid treatment agent compositions for textile products 15 to 20 were prepared by mixing the amounts of each component to achieve the compositions shown in Table 5. The pH of all the final compositions was 7.8.

[0118] <Method for preparing a textile product treatment solution> • Preparation methods for example 1-6 of treatment solutions for textile products Using the liquid treatment agent composition for textile products shown in Composition Example 1 of Table 3, the treatment solution for textile products Example 1 was prepared according to the method for preparing the treatment solution for textile products described above, except that the amount of the composition used per 700 g (700 mL) of water was changed. Similarly, the treatment solutions for textile products Examples 2 to 4 were prepared using the liquid treatment agent composition for textile products shown in Composition Example 4 of Table 3, the treatment solution for textile products Example 5 was prepared using the liquid treatment agent composition for textile products, and the treatment solution for textile products Example 6 was prepared using the liquid treatment agent composition for textile products shown in Composition Example 12. The compositions of the treatment solutions for textile products Examples 1 to 6 are shown in Table 6.

[0119] • Preparation methods for treatment solutions for textile products (Examples 7-12) Except for using the liquid treatment agent compositions for textile products shown in Composition Examples 15-20 in Table 5, the treatment solutions for textile products shown in Treatment Examples 7-12 were prepared according to the method for preparing treatment solutions for textile products described above. The compositions of the treatment solutions for textile products shown in Treatment Examples 7-12 are shown in Table 6.

[0120] • Method for preparing example 13 of treatment solutions for textile products A textile processing solution for example 13 was prepared by blending the following components to achieve a final mass of 2 kg. Water (Wakayama water, 25°C, 3°dH hard water) equivalent to 90% of the final mass was placed in a 2 L beaker and heated to 40°C. A rod-shaped Teflon® stirrer piece, 8 cm long and 1 cm wide, was added and stirred at 200 r / min. Next, components (a), (b), (c), and optional components (e), (f), (g), and citric acid were added sequentially and stirred for 20 minutes, then component (d) was added and stirred for another 5 minutes. The contents were cooled to 25°C while stirring in a 5°C water bath. The pH was adjusted to 7.8 with a 10% sodium hydroxide or 10% hydrochloric acid aqueous solution. Water was added to achieve a final mass of 2 kg. The pH after preparation was 7.8 in all cases. Table 6 shows the composition of the textile product treatment solution for example 13.

[0121] [Table 5]

[0122] [Table 6]

[0123] When evaluating the deodorizing effect using the textile product treatment solutions of Examples 1 to 13, according to the textile product treatment method and deodorizing effect evaluation method in the above-mentioned examples, the following can be considered. Since the amount of composition example 1 used to prepare treatment solution example 1 is greater than that used to prepare example 1, treatment solution example 1 is considered to have a superior deodorizing effect than example 1. Also, when preparing treatment solutions examples 2 to 4, the amount of composition example 4 used is greater for treatment solution example 3 than for treatment solution example 2, and then for treatment solution example 4, so the deodorizing effect of treatment solutions examples 2 to 4 is considered to be better for treatment solution example 3 than for treatment solution example 2, and then for treatment solution example 4. Also, since the amount of composition example 4 used to prepare treatment solution example 2 is less than the amount used to prepare example 4, treatment solution example 2 is considered to have a slightly inferior deodorizing effect than example 4, but the deodorizing effect is still satisfactory. Also, since the amount of composition example 4 used to prepare treatment solutions examples 3 and 4 is greater than the amount used to prepare example 4, treatment solutions examples 3 and 4 are considered to have a superior deodorizing effect than example 4. Furthermore, since the amount of composition example 5 used to prepare treatment solution example 5 is greater than the amount used to prepare example 5, treatment solution example 5 is considered to have a superior deodorizing effect compared to example 5. Also, since the amount of composition example 12 used to prepare treatment solution example 6 is greater than the amount used to prepare example 12, treatment solution example 6 is considered to have a superior deodorizing effect compared to example 12. Furthermore, since treatment solution example 7 contains component (e) in addition to example 4, treatment solution example 7 is considered to have a superior deodorizing effect compared to example 4. Treatment solution example 8 has a slightly inferior deodorizing effect compared to example 4, but the deodorizing effect is considered satisfactory. Furthermore, since the (b) / (a) ratio of treatment solutions examples 9 and 10 falls outside the most preferable range, the deodorizing effect is slightly inferior to example 4, but the deodorizing effect is considered satisfactory. Furthermore, since the (c) / {(a)+(b)} ratio of treatment solution example 11 falls outside the most preferable range, the deodorizing effect is inferior to example 1, but a sufficient deodorizing effect is considered to be obtained. In example 12 of the treatment solution, the (b) / (a) ratio and (c) / {(a)+(b)} ratio fall outside the most preferable range, resulting in a slightly inferior deodorizing effect compared to Example 4 and Examples 10 and 11, although the deodorizing effect is considered satisfactory. In example 13 of the treatment solution, the deodorizing effect is considered to be equivalent to that of Example 4.

Claims

1. A method for treating textile products, comprising bringing a treatment solution for textile products containing the following components (a), (b), (c), (d), and water into contact with a textile product to which dirt has adhered, In the aforementioned treatment liquid for textile products, the total content of component (a), component (b), and component (c) is 100 mg / kg or more and 800 mg / kg or less. The mass ratio of the content of component (b) to the content of component (a), [(b) / (a)], is 0.5 or more and 0.9 or less. The mass ratio of the content of component (c) to the total content of components (a) and (b), [(c) / {(a)+(b)}], is 0.2 or more and 0.7 or less. Methods for processing textile products. (a) Component: Alkylbenzenesulfonic acid or salt thereof having an alkyl group with 10 to 18 carbon atoms. (b) Component: Compound represented by the following general formula (1) 2 １ 9-(59) ｐ -39 ３ 7(1) [In the formula, R １ represents an aliphatic alkyl group having 10 to 18 carbon atoms, EO represents an ethyleneoxy group, p represents the average number of added moles, p represents a number between 1 and 4, and M represents a cation. (c) Component: Compound represented by the following general formula (2) R ２ O-(A ２ O) ｎ -H (2) [In the formula, R ２ is an aliphatic hydrocarbon group having 9 to 16 carbon atoms, A ２ O group is one or more groups selected from an ethyleneoxy group and a propyleneoxy group, and n is the average number of added moles and is a number of 5 or more and 15 or less.] (d) A fragrance composition containing one or more fragrance compounds selected from the following: 2-methyl undecanal, γ-undecalactone, ambroxide, benzyl salicylate, 3-ethoxy-4-hydroxybenzaldehyde, (12E)-1-oxacyclohexadeca-12-en-2-one, α-hexyl cinnamaldehyde, 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7-hexahydronaphthalene-2-yl)ethanone, methyl dihydrojasmonate, (5E)-3-methylcyclopentadeca-5-en-1-one, and methyl 2-naphthyl ether.

2. The R of component (c) ２ The method for treating a textile product according to claim 1, wherein is an aliphatic hydrocarbon group containing a branched alkyl group.

3. The above (c) component is A ２ A method for treating a textile product according to claim 1 or 2, wherein O is a compound [component (c1)] in which O is an ethylene oxy group, and when the number of moles of the ethylene oxy group with the highest content among the compounds contained in component (c1) is taken as n-max, the total content of n-max ± 2 in component (c1) is 50% by mass or more and 100% by mass or less.

4. The method for treating a textile product according to claim 1 or 2, wherein the component (c) is a compound having an ethyleneoxy group and a propyleneoxy group.

5. The method for treating a textile product according to claim 1 or 2, further comprising (e) alkoxylated polyethyleneimine as component (e).

6. The method for treating a textile product according to claim 1 or 2, wherein the method for treating the textile product is a method for deodorizing the textile product.

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