Composition for keratinous materials

Abstract

To provide compositions that can give a satisfactory texture for use in both hair and skin.SOLUTION: The present invention relates to a composition that contains: (a) at least one volatile non-silicone oil; (b) at least one non-volatile non-silicone oil; (c) at least one silicone; and (d) water, the amount of (c) the silicone being 1.0 mass% to 5.0 mass%, preferably 1.5 mass% to 4.0 mass%, and more preferably 2.0 mass% to 3.0 mass%, based on the total mass of the composition. The composition according to the invention can impart a satisfactory texture for use in both hair and skin. By using a cosmetic containing the composition according to the invention, the cosmetic treatment can be simplified.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a composition for treating keratinous materials, preferably skin or hair, more preferably both skin and hair. [Background technology]

[0002] In the field of cosmetic treatments, making cosmetic treatments convenient is an emerging consumer trend around the world. In line with this trend, "multi-use" cosmetic products that can be used for multiple parts of the human body, such as both hair and skin, are rapidly emerging in the cosmetic market.

[0003] However, conventional "multi-use" cosmetic preparations are not sufficient in terms of cosmetic texture. For example, even if such a "multi-use" cosmetic preparation can impart a texture that is satisfactory for hair use, the cosmetic preparation may tend to impart an unsatisfactory texture for skin use. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] U.S. Patent No. 6,491,927 [Patent Document 2] EP0216479 B2 [Patent Document 3] U.S. Patent No. 3,915,921 [Patent Document 4] U.S. Patent No. 4,509,949 [Patent Document 5] French Patent No. 2416723 [Patent Document 6] U.S. Patent No. 2,798,053 [Patent Document 7] U.S. Patent No. 2,923,692 [Non-patent literature]

[0005] [Non-Patent Document 1] Walter NOLL, Chemistry and Technology of Silicones (1968), Academic Press [Non-Patent Document 2] Cosmetics and Toiletries, Vol. 91, January 1976, pp. 27-32, Todd & Byers, Volatile Silicone Fluids for Cosmetics [Non-Patent Document 3] ASTM Standard 445 Appendix C [Non-Patent Document 4] ASTM Standard D-445 [Non-Patent Document 5] "Encyclopedia of Chemical Technology", Kirk-Othmer, 3rd ed., 1982, Vol. 3, pp. 896-900 and Vol. 15, pp. 439-458 [Non-Patent Document 6] EA MacGregor and CT Greenwood, Polymers in Nature, John Wiley & Sons, Chapter 6, pp. 240-328, 1980 [Non-Patent Document 7] "Industrial Gums-Polysaccharides and their Derivatives", edited by Roy L. Whistler, 2nd ed., published by Academic Press Inc. Summary of the Invention [Problem to be solved by the invention]

[0006] It is an object of the present invention to provide a composition that is capable of imparting a pleasing texture for both hair and skin use. [Means for solving the problem]

[0007] The above objectives are: (a) at least one volatile non-silicone oil; (b) at least one non-volatile non-silicone oil; (c) at least one silicone; (d) Water and A composition comprising: This can be achieved by a composition in which the amount of (c) silicone is 1.0 mass % to 5.0 mass %, preferably 1.5 mass % to 4.0 mass %, and more preferably 2.0 mass % to 3.0 mass %, relative to the total mass of the composition.

[0008] (a) The volatile non-silicone oil may be chosen from hydrocarbon oils.

[0009] The amount of (a) volatile non-silicone oil in the composition according to the present invention may be in the range of 0.1% by mass to 20% by mass, preferably 0.5% by mass to 15% by mass, and more preferably 1% by mass to 10% by mass, relative to the total mass of the composition.

[0010] (b) The non-volatile non-silicone oils may be selected from vegetable oils, synthetic triglycerides, and mixtures thereof.

[0011] The amount of (b) non-volatile non-silicone oil in the composition according to the present invention may be in the range of 0.005% by mass to 5% by mass, preferably 0.01% by mass to 1% by mass, and more preferably 0.05% by mass to 0.5% by mass, relative to the total mass of the composition.

[0012] (c) The silicone may be non-volatile.

[0013] (c) The silicone may be selected from polydimethylsiloxane, organically modified polydimethylsiloxane, and mixtures thereof. The organically modified polydimethylsiloxane may be selected from dimethiconol.

[0014] (c) The silicone may be a mixture of dimethylpolysiloxane and dimethiconol.

[0015] The mass ratio of the amount of (b) non-volatile non-silicone oil / the amount of (c) silicone may be 0.5 or less, more preferably 0.1 or less, more preferably 0.05 or less.

[0016] The amount of (d) water in the composition according to the present invention may be in the range of 50% by mass to 95% by mass, preferably 60% by mass to 90% by mass, and more preferably 70% by mass to 85% by mass, based on the total mass of the composition.

[0017] The composition according to the present invention may further comprise (e) at least one polyol.

[0018] The composition according to the present invention may further comprise (f) at least one thickening agent.

[0019] The present invention also relates to a cosmetic composition, preferably a cosmetic composition for keratin materials, more preferably a cosmetic composition for both the skin and the hair.

[0020] The present invention also relates to a cosmetic method for keratinous materials, preferably both skin and hair, comprising the step of applying a composition according to the invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0021] After extensive investigation, the inventors have discovered that it is possible to provide a composition that is capable of imparting a satisfactory texture for both hair and skin use.

[0022] The texture for hair use may include at least one selected from the group consisting of smooth, sticky and runnable.

[0023] The texture for skin use may include at least one selected from the group consisting of sticky and moist.

[0024] Therefore, the present invention provides (a) at least one volatile non-silicone oil; (b) at least one non-volatile non-silicone oil; (c) at least one silicone; (d) Water and A composition comprising: (c) It mainly relates to a composition, in which the amount of silicone is 1.0% by mass to 5.0% by mass, preferably 1.5% by mass to 4.0% by mass, and more preferably 2.0% by mass to 3.0% by mass, relative to the total mass of the composition.

[0025] The composition according to the present invention can impart a satisfactory texture for both hair and skin use, and therefore, by using a cosmetic preparation containing the composition according to the present invention, cosmetic treatment can be simplified.

[0026] The present invention will now be described in detail.

[0027] [Composition] One aspect of the present invention is (a) at least one volatile non-silicone oil; (b) at least one non-volatile non-silicone oil; (c) at least one silicone; (d) Water and A composition comprising: (c) The composition, wherein the amount of silicone is from 1.0% to 5.0% by mass, preferably from 1.5% to 4.0% by mass, and more preferably from 2.0% to 3.0% by mass, relative to the total mass of the composition.

[0028] (volatile non-silicone oils) The composition according to the present invention comprises (a) at least one volatile non-silicone oil. A single type of volatile non-silicone oil may be used, or two or more different types of volatile non-silicone oils may be used in combination.

[0029] As used herein, "oil" means a compound or substance that is in the form of a liquid or paste at atmospheric pressure (760 mmHg) and room temperature (25° C.).

[0030] It is preferred that the (a) volatile non-silicone oil is selected from hydrocarbon oils.

[0031] The term "hydrocarbon-based oil" (or "hydrocarbonized oil" or "hydrocarbon oil") means an oil essentially formed or even consisting of carbon and hydrogen atoms, and optionally oxygen and nitrogen atoms, and which does not contain any silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

[0032] According to one preferred embodiment, the volatile hydrocarbon oil has a flash point above 65°C, and better still above 80°C.

[0033] Volatile hydrocarbon oils are selected from hydrocarbon oils containing 8 to 16 carbon atoms, in particular branched C8-C 16 It may be selected from alkanes (also known as isoparaffins), such as isododecane (also called 2,2,4,4,6-pentamethylheptane), isodecane and isohexadecane, and mixtures thereof.

[0034] The volatile hydrocarbon-based oil may also be a linear volatile alkane containing from 7 to 17 carbon atoms, in particular from 9 to 15 carbon atoms, more particularly from 11 to 13 carbon atoms. Particular mention may be made of n-nonadecane, n-decane, n-undecane, n-dodecane, n-tridecane, n-tetradecane, n-pentadecane and n-hexadecane, and mixtures thereof.

[0035] The volatile hydrocarbon oil may preferably be selected from the group consisting of isododecane, isohexadecane, undecane, tridecane, and mixtures thereof.

[0036] The amount of (a) the volatile non-silicone oil in the composition according to the present invention may be 0.1% by weight or more, preferably 0.5% by weight or more, more preferably 1% by weight or more, relative to the total weight of the composition.

[0037] The amount of (a) volatile non-silicone oil in the composition according to the present invention may be up to 20% by weight, preferably up to 15% by weight, more preferably up to 10% by weight, relative to the total weight of the composition.

[0038] The amount of (a) volatile non-silicone oil in the composition according to the present invention may be in the range of 0.1% by mass to 20% by mass, preferably 0.5% by mass to 15% by mass, and more preferably 1% by mass to 10% by mass, relative to the total mass of the composition.

[0039] (Non-volatile non-silicone oil) The composition according to the present invention comprises (b) at least one non-volatile non-silicone oil. A single type of non-volatile non-silicone oil may be used, or two or more different types of non-volatile non-silicone oils may be used in combination.

[0040] As used herein, "oil" means a compound or substance that is in the form of a liquid or paste at atmospheric pressure (760 mmHg) and room temperature (25° C.).

[0041] The term "non-volatile oil" means an oil that remains on keratinous materials such as skin and hair at room temperature and pressure. More precisely, non-volatile oils have a concentration of exactly 0.01 mg / cm 2 It has an evaporation rate of less than 1 / min.

[0042] Non-volatile non-silicone oils may include: - Hydrocarbon oils of vegetable origin, such as phytostearyl esters, such as phytostearyl oleate, phytostearyl isostearate and lauroyl / octyldodecyl / phytostearyl glutamate; in particular those whose fatty acids are C 18 ~C 36triglycerides formed from fatty acid esters of glycerol which may have chain lengths in the range of 0.1 to 100%; these oils may be linear or branched, and saturated or unsaturated; these oils are in particular heptanoic or octanoic triglycerides, shea oil, alfalfa oil, poppy oil, pumpkin seed oil, millet oil, barley oil, quinoa oil, rye oil, candlenut oil, passion flower oil, shea butter oil, aloe oil, sweet almond oil, peach kernel oil, peanut oil, argan oil, avocado oil, baobab oil, borage oil, broccoli oil, calendula oil, cabbage oil, cucumber ... Melina oil, carrot oil, safflower oil, hemp oil, rapeseed oil, cottonseed oil, coconut oil, pith seed oil, wheat germ oil, jojoba oil, lily oil, macadamia oil, corn oil, meadowfoam oil, Hypericum perforatum oil, monoi oil, hazelnut oil, apricot kernel oil, walnut oil, olive oil, evening primrose oil, palm oil, black currant seed oil, kiwi seed oil, grape seed oil, pistachio oil, quinoa oil, musk rose oil, sesame oil, soybean oil, sunflower oil, castor oil and watermelon oil, and mixtures thereof, or caprylic / capric triglycerides, such as those sold by the company Stearineries Dubois or under the names Miglyol 810®, 812® and 818® by the company Dynamit Nobel, - synthetic ethers containing 10 to 40 carbon atoms, synthetic esters, such as oils having the formula R1COOR2, in which R1 represents at least one linear or branched fatty acid residue containing from 1 to 40 carbon atoms and R2 represents a hydrocarbon-based chain, in particular branched, containing from 1 to 40 carbon atoms, with the proviso that R1+R2≧10. The esters may in particular be chosen from fatty acid esters of alcohols, such as cetostearyl octanoate, isopropyl alcohol esters, such as isopropyl myristate, isopropyl palmitate, ethyl palmitate, 2-ethylhexyl palmitate, isopropyl stearate, isopropyl isostearate, isostearyl isostearate, octyl stearate, hydroxylated esters, such as isostearyl lactate, octyl hydroxystearate, diisopropyl adipate, heptanoic acid esters, in particular isostearyl heptanoate, octanoic, decanoic or ricinoleic acid alcohols or polyalcohols, such as propylene glycol dioctanoate, cetyl octanoate, tridecyl octanoate, 2-ethylhexyl 4-diheptanoate, 2-ethylhexyl palmitate, alkyl benzoates, in particular C 12 ~C 15 alkyl benzoates, polyethylene glycol diheptanoates, propylene glycol 2-diethylhexanoates, and mixtures thereof; may be selected from hexyl laurate, neopentanoic acid esters, such as isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyldodecyl neopentanoate; may be selected from isononanoic acid esters, such as isononyl isononanoate, isotridecyl isononanoate, octyl isononanoate; may be selected from hydroxylated esters, such as isostearyl lactate and diisostearyl maleate; - polyol esters and pentaerythritol esters, e.g. dipentaerythrityl tetrahydroxystearate / tetraisostearate; - esters of diol dimers and diacid dimers, - copolymers of diol dimers and diacid dimers and their esters, such as dilinoleyldiol dimer / dilinoleyl dimer copolymers and their esters; - copolymers of polyols and diacid dimers and their esters; fatty alcohols which are liquid at room temperature and have a branched and / or unsaturated carbon-based chain containing from 12 to 26 carbon atoms, such as 2-octyldodecanol, isostearyl alcohol, oleyl alcohol, 2-hexyldecanol, 2-butyloctanol and 2-undecylpentadecanol; - C 12 ~C 22 Higher fatty acids, such as oleic acid, linoleic acid and linolenic acid, and mixtures thereof; dialkyl carbonates, the two alkyl chains of which may be the same or different, such as dicaprylyl carbonate, oils with a molar mass ranging from about 400 g / mol to about 10,000 g / mol, in particular from about 650 g / mol to about 10,000 g / mol, in particular from about 750 g / mol to about 7500 g / mol and even more particularly from about 1000 g / mol to about 5000 g / mol; mention may be made, alone or in mixtures, of (i) lipophilic polymers, such as polybutylene, polyisobutylene, for example hydrogenated, polydecene and hydrogenated polydecene, vinylpyrrolidone copolymers, for example vinylpyrrolidone / 1-hexadecene copolymers, and polyvinylpyrrolidone (PVP) copolymers, for example C2-C 30 Alkenes, e.g. C3-C 22 (ii) linear fatty acid esters having a total carbon number ranging from 35 to 70, such as pentaerythrityl tetrapelargonate; (iii) hydroxylated esters, such as polyglyceryl 2-triisostearate; (iv) aromatic esters, such as tridecyl trimellitate; (v) fatty alcohol or branched C 24 ~C 28Esters of fatty acids, such as those described in U.S. Pat. No. 6,491,927 and pentaerythritol esters, and in particular triisoarachidyl citrate, pentaerythrityl tetraisononanoate, glyceryl triisostearate, glyceryl 2-tridecyltetradecanoate, pentaerythrityl tetraisostearate, poly(2-glyceryl) tetraisostearate or pentaerythrityl 2-tetradecyltetradecanoate; (vi) diol dimer esters and polyesters, such as esters of diol dimers with fatty acids and esters of diol dimers with diacids.

[0043] In one embodiment, the (b) non-volatile non-silicone oil is a polar oil, preferably an ester oil, more preferably an ester oil of the formula RCOOR′, where R is C 1~29 represents a fatty acid residue, and R' is C 2~30 The fatty ester may be selected from fatty esters represented by the formula (I) and (II), which represents a hydrocarbon group.

[0044] (b) It may be preferred that the non-volatile, non-silicone oil is selected from vegetable oils, synthetic triglycerides, and mixtures thereof.

[0045] It may be more preferred that the vegetable oil is selected from the group consisting of soybean oil, coconut oil, and mixtures thereof.

[0046] It may be more preferred that the synthetic triglyceride is selected from the group consisting of caprylic / capric triglyceride, heptanoic or octanoic triglyceride, and mixtures thereof.

[0047] The amount of (b) non-volatile non-silicone oil in the composition according to the present invention may be 0.005% by weight or more, preferably 0.01% by weight or more, more preferably 0.05% by weight or more, relative to the total weight of the composition.

[0048] The amount of (b) non-volatile non-silicone oil in the composition according to the present invention may be 5% by weight or less, preferably 1% by weight or less, more preferably 0.5% by weight or less, relative to the total weight of the composition.

[0049] The amount of (b) non-volatile non-silicone oil in the composition according to the present invention may be in the range of 0.005% by mass to 5% by mass, preferably 0.01% by mass to 1% by mass, and more preferably 0.05% by mass to 0.5% by mass, relative to the total mass of the composition.

[0050] (silicone) The composition according to the present invention comprises at least one (c) silicone. A single type of silicone may be used, or two or more different types of silicone may be used in combination.

[0051] (c) The silicone is preferably in the form of an oil. As used herein, "oil" means a compound or substance that is in the form of a liquid or paste at atmospheric pressure (760 mmHg) and room temperature (25° C.).

[0052] Silicones or organopolysiloxanes are defined, for example, by Walter NOLL in "Chemistry and Technology of Silicones" (1968), Academic Press. They may be volatile or non-volatile.

[0053] Therefore, (c) silicone can be selected from volatile silicone, non-volatile silicone, and mixtures thereof.For example, (c) silicone can comprise at least one volatile silicone oil or at least one non-volatile silicone oil, or both at least one volatile silicone oil and at least one non-volatile silicone oil.Of course, (c) silicone can comprise two or more volatile silicone oils or two or more non-volatile silicone oils.

[0054] Volatile Silicone It is preferred that the volatile silicone is in the form of an oil.

[0055] The volatile silicone oils can be chosen from those having a boiling point between 60° C. and 260° C., and more particularly from: (i) Cyclic polydialkylsiloxanes containing 3 to 7, preferably 4 to 5, silicon atoms. These are, for example, in particular, octamethylcyclotetrasiloxane sold under the name Volatile Silicone® 7207 by Union Carbide or under the name Silbione® 70045 V2 by Rhodia, decamethylcyclopentasiloxane sold under the name Volatile Silicone® 7158 by Union Carbide and under the name Silbione® 70045 V5 by Rhodia, and dodecamethylcyclopentasiloxane sold under the name Silsoft 1217 by Momentive Performance Materials, and mixtures thereof. Formula:

[0056] [ka]

[0057] Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as Silicone Volatile® FZ 3109 sold by Union Carbide.

[0058] Mention may also be made of mixtures of cyclic polydialkylsiloxanes and organosilicon compounds, such as a 50 / 50 mixture of octamethylcyclotetrasiloxane and tetratrimethylsilylpentaerythritol, and a mixture of octamethylcyclotetrasiloxane and oxy-1,1'-bis(2,2,2',2',3,3'-hexatrimethylsilyloxy)neopentane. (ii) Contains 2 to 9 silicon atoms and has a density of 5 × 10 at 25 °C -6 m 2Linear volatile polydialkylsiloxanes with a viscosity of less than 100 / s. An example is decamethyltetrasiloxane, sold in particular under the name SH 200 by Toray Silicone. Silicones belonging to this class are also described in the article published in Cosmetics and Toiletries, Vol. 91, January 1976, pages 27-32, Todd & Byers, Volatile Silicone Fluids for Cosmetics. The viscosity of the silicones is measured at 25°C according to ASTM Standard 445 Appendix C.

[0059] The volatile silicone oil may be selected from cyclic silicones, preferably from the group consisting of cyclopentasiloxane, cyclohexasiloxane, and mixtures thereof.

[0060] Non-volatile silicone It is preferred that the non-volatile silicone be in the form of an oil.

[0061] The non-volatile silicone oils that may be used in the present invention have a viscosity of 8 centistokes (cSt) (8×10 -6 m 2 The viscosity of the silicone oil may be selected from silicone oils having a viscosity of at least 100 / s and less than 800,000 cSt, preferably between 10 cSt and 600,000 cSt, preferably between 100 cSt and 500,000 cSt. The viscosity of the silicone may be measured according to ASTM standard D-445.

[0062] Among these silicone oils, two types of oils can be distinguished, depending on whether they contain phenyl or not. Thus, the non-volatile silicone oils can be chosen from non-phenylated silicone oils and phenylated silicone oils.

[0063] Representative examples of these non-volatile, non-phenylated silicone oils that may be mentioned are polydimethylsiloxanes (dimethicones); alkyl dimethicones; vinyl methyl methicones; and also silicones modified with aliphatic groups, optionally fluorinated, or with functional groups such as hydroxyl groups, thiol groups and / or amine groups.

[0064] Thus, non-volatile non-phenylated silicone oils that may be mentioned include: - PDMS containing alkyl or alkoxy groups, each containing from 2 to 24 carbon atoms, pendant and / or at the ends of silicone chains; - PDMS containing aliphatic groups or functional groups such as hydroxyl groups, thiol groups and / or amine groups, - polyalkylmethylsiloxanes optionally substituted with fluorinated groups, such as polymethyltrifluoropropyldimethylsiloxane; - polyalkylmethylsiloxanes substituted with functional groups such as hydroxyl, thiol and / or amine groups, for example dihydroxydimethylsiloxane (dimethiconol); polysiloxanes which have been modified with fatty acids, fatty alcohols or polyoxyalkylenes, - A mixture of these.

[0065] According to one embodiment, the non-volatile silicone oil is chosen from linear, non-volatile, non-phenylated silicone oils.

[0066] The linear, non-volatile, non-phenylated silicone oils are in particular those of the formula:

[0067] [ka]

[0068] (In the formula, R1, R2, R5 and R6, together or separately, are an alkyl group containing 1 to 6 carbon atoms; R3 and R4, together or separately, are an alkyl group containing 1 to 6 carbon atoms, a vinyl group, an amine group, or a hydroxyl group; X is an alkyl group containing 1 to 6 carbon atoms, a hydroxyl group, or an amine group; n and p are integers selected to have a fluid composition. You can choose from the following silicones:

[0069] Among the non-volatile silicone oils that may be used according to the invention, mention may be made of: - those in which the R1 to R6 substituents and X represent methyl groups and p and n are numbers such that the viscosity is 500,000 cSt, such as, for example, the product sold under the name SE30 by General Electric, the product sold under the name AK 500000 by Wacker, the product sold under the name Mirasil DM 500 000 by Bluestar and the product sold under the name Dow Corning 200 Fluid 500 000 cSt by Dow Corning; - those in which the R1 to R6 substituents and X represent methyl groups and p and n are such that the viscosity is 300,000 cSt, for example the product sold under the name Wacker Belsil DM 300 000 by the company Wacker; - R1 to R6 substituents and X represent methyl groups and p and n are numbers such that the viscosity is 60,000 cSt, such as the product sold under the name Dow Corning 200 Fluid 60000 CS by Dow Corning and the product sold under the name Wacker Belsil DM 60 000 by Wacker; - R1 to R6 substituents and X represent methyl groups, p and n being numbers such that the viscosity is 350 cSt, for example the product sold under the name Dow Corning 200 Fluid 350 CS by the company Dow Corning, - R1 to R6 substituents and X represent a methyl group, the X group represents a hydroxyl group, n and p are such that the viscosity is 700 cSt, for example the product sold under the name Baysilone Fluid T0.7 by the company Momentive.

[0070] According to another embodiment, the non-volatile silicone oil is chosen from non-volatile phenylated silicone oils.

[0071] Representative examples of these non-volatile phenylated silicone oils that may be mentioned are: - phenyl silicone oils corresponding to the formula:

[0072] [ka]

[0073] [In formula (I), the R groups are, independently of one another, methyl or phenyl, with the proviso that at least one R group is phenyl]. Preferably, in this formula, the phenyl silicone oil comprises at least three phenyl groups, for example at least four, at least five or at least six phenyl groups. - phenyl silicone oils corresponding to the formula:

[0074] [ka]

[0075] [In formula (II), the R groups are, independently of one another, methyl or phenyl, with the proviso that at least one R group is phenyl.] Preferably, in this formula, said organopolysiloxane comprises at least three phenyl groups, for example at least four or at least five phenyl groups. Mixtures of the previously described phenylorganopolysiloxanes can be used. Examples that may be mentioned are mixtures of triphenyl, tetraphenyl or pentaphenylorganopolysiloxanes. - phenyl silicone oils corresponding to the formula:

[0076] [ka]

[0077] [In formula (III), Me stands for methyl and Ph stands for phenyl]. Such phenyl silicones are in particular manufactured by the company Dow Corning under the reference PH-1555HRI or Dow Corning 555 Cosmetic Fluid (chemical name: 1,3,5-trimethyl-1,1,3,5,5-pentaphenyltrisiloxane, INCI name: trimethylpentaphenyltrisiloxane). Reference Dow Corning 554 Cosmetic Fluid can also be used. - phenyl silicone oils corresponding to the formula:

[0078] [ka]

[0079] [In the formula (IV), Me represents methyl, y is between 1 and 1000, and X represents -CH2-CH(CH3)(Ph)], - a phenyl silicone oil corresponding to the following formula (V):

[0080] [ka]

[0081] [In formula (V), Me is methyl, Ph is phenyl, OR' represents the -OSiMe3 group, y is 0 or ranges between 1 and 1000, and z ranges between 1 and 1000, so that compound (V) is a non-volatile oil]. According to a first embodiment, y ranges between 1 and 1000. Use can be made, for example, of trimethylsiloxyphenyl dimethicone, sold in particular under the reference Belsil PDM 1000 by the company Wacker. According to a second embodiment, y is equal to 0. Use can be made, for example, of phenyltrimethylsiloxytrisiloxane, sold in particular under the reference Dow Corning 556 Cosmetic Grade Fluid. phenylsilicone oils corresponding to the following formula (VI), and mixtures thereof:

[0082] [ka]

[0083] [In formula (VI), - R1~R 10 are each independently a saturated or unsaturated, linear, cyclic or branched C1-C 30 is a hydrocarbon group, m, n, p and q are, independently of one another, integers between 0 and 900, with the proviso that the sum m+n+q is other than 0, preferably the sum m+n+q is between 1 and 100. Preferably, the sum m+n+p+q is between 1 and 900, and even better still between 1 and 800. Preferably, q is equal to 0. phenylsilicone oils corresponding to the following formula (VII), and mixtures thereof:

[0084] [ka]

[0085] [In formula (VII), R1 to R6 are each independently a saturated or unsaturated, linear, cyclic or branched C1-C30 is a hydrocarbon group, m, n and p are, independently of one another, integers between 0 and 100, with the proviso that the sum n+m is between 1 and 100, and preferably R1 to R6 are, independently of one another, saturated, linear or branched C1 to C 30 , especially C1~C 12 represents a hydrocarbon-based group, in particular a methyl, ethyl, propyl or butyl group, R1 to R6 may in particular be identical and may additionally be a methyl group, preferably in formula (VII) m=1 or 2 or 3, and / or n=0 and / or p=0 or 1, phenylsilicone oils corresponding to formula (VIII), and mixtures thereof:

[0086] [ka]

[0087] [In formula (VIII), - R is C1~C 30 is an alkyl group, an aryl group, or an aralkyl group, - n is an integer ranging from 0 to 100; - m is an integer ranging from 0 to 100, with the proviso that the sum n+m ranges from 1 to 100. In particular, the R groups of formula (VIII) and the R1 to R2 groups defined above 10 are each a linear or branched, saturated or unsaturated alkyl group, particularly C2-C 20 Alkyl groups, specifically C3-C 16 Alkyl groups, more specifically C4-C 10 may represent an alkyl group, or a monocyclic or polycyclic C6-C 14 and especially C. 10 ~C 13 It may represent an aryl group or an aralkyl group, the aryl and alkyl residues of which are as previously defined. Preferably, R and R to R of formula (VIII) 10may each represent a methyl, ethyl, propyl, isopropyl, decyl, dodecyl or octadecyl group, or a phenyl, tolyl, benzyl or phenethyl group. 2 / s to 1500mm 2 / s (i.e., 5 to 1500 cSt), preferably with a viscosity of 5 mm 2 / s to 1000mm 2 Phenyl silicone oils of formula (VIII) can be used, which have a viscosity between 0.1 and 0.25 g / s (i.e. 5 to 1000 cSt). As phenyl silicone oils of formula (VIII), it is particularly possible to use phenyl trimethicones, such as DC556 (22.5 cSt) from Dow Corning, oil Silbione 70663V30 (28 cSt) from Rhone-Poulenc, or diphenyl dimethicones, such as Belsil oils from Wacker, in particular Belsil PDM 1000 (1000 cSt), Belsil PDM 200 (200 cSt) and Belsil PDM 20 (20 cSt). The values ​​in brackets represent the viscosity at 25°C. - phenyl silicone oils corresponding to the following formula, and mixtures thereof:

[0088] [ka]

[0089] [In formula (IX), R1, R2, R5 and R6, together or separately, are an alkyl group containing 1 to 6 carbon atoms; R3 and R4, together or separately, are an alkyl group containing 1 to 6 carbon atoms or an aryl group; X is an alkyl group containing 1 to 6 carbon atoms, a hydroxyl group, or a vinyl group; n and p are selected to give the oil a weight average molecular weight of less than 200,000 g / mol, preferably less than 150,000 g / mol, more preferably less than 100,000 g / mol.

[0090] Phenylsilicones most particularly suitable for use in the present invention may be those corresponding to formula (II) herein above, and in particular to formulae (III), (V) and (VIII).

[0091] More particularly, the phenyl silicones may be chosen from phenyl trimethicone, phenyl dimethicone, phenyl-trimethylsiloxydiphenyl siloxane, diphenyl dimethicone, diphenyl methyl diphenyl trisiloxane and 2-phenylethyl trimethyl siloxy silicate, and mixtures thereof.

[0092] Preferably, the weight average molecular weight of the non-volatile phenylsilicone oils used according to the present invention may be in the range of 500 to 10,000 g / mol.

[0093] (c) The silicone may be selected from polydimethylsiloxane, organomodified polydimethylsiloxane, and mixtures thereof.

[0094] By organically modified polydimethylsiloxane is meant a PDMS comprising at least one aliphatic group or at least one functional group such as a hydroxyl group, a thiol group and / or an amine group, preferably a PDMS comprising at least one functional group, more preferably a PDMS comprising at least one hydroxyl group.

[0095] In particular, the organomodified polydimethylsiloxane may be selected from dimethiconols.

[0096] In one particular embodiment of the present invention, the (c) silicone may be a mixture of dimethylsiloxane and dimethiconol.

[0097] The amount of (c) silicone in the composition according to the present invention is in the range of 1.0 mass % to 5.0 mass %, preferably 1.5 mass % to 4.0 mass %, and more preferably 2.0 mass % to 3.0 mass %, relative to the total mass of the composition.

[0098] It may be preferred that the mass ratio of the amount of (b) non-volatile non-silicone oil / the amount of (c) silicone is no greater than 0.5, more preferably no greater than 0.1, more preferably no greater than 0.05.

[0099] (water) The composition according to the present invention comprises (d) water.

[0100] The amount of (d) water in the composition according to the present invention may be 50% by mass or more, preferably 60% by mass or more, and more preferably 70% by mass or more, based on the total mass of the composition.

[0101] The amount of (d) water in the composition according to the present invention may be 95% by mass or less, preferably 90% by mass or less, and more preferably 85% by mass or less, based on the total mass of the composition.

[0102] Therefore, the amount of (d) water in the composition according to the present invention may be in the range of 50% by mass to 95% by mass, preferably 60% by mass to 90% by mass, and more preferably 70% by mass to 85% by mass, relative to the total mass of the composition.

[0103] (Polyol) The composition according to the present invention may comprise (e) at least one polyol. A single type of polyol may be used, but two or more different types of polyols may also be used in combination.

[0104] The term "polyol" as used herein means an alcohol having two or more hydroxyl groups, and does not include sugars or their derivatives. Derivatives of sugars include sugar alcohols obtained by reducing one or more carbonyl groups of a sugar, and sugars or sugar alcohols in which one or more hydrogen atoms in one or more hydroxyl groups are replaced with at least one substituent, such as an alkyl group, a hydroxyalkyl group, an alkoxy group, an acyl group, or a carbonyl group.

[0105] (e) The polyol is a C2~12 Polyol, preferably C 2~9 It may be a polyol.

[0106] (e) The polyol may be a natural or synthetic polyol. (e) The polyol may have a linear, branched or cyclic molecular structure.

[0107] (e) The polyol may be selected from glycerin and its derivatives, and glycols and its derivatives. The polyol may be selected from the group consisting of glycerin, diglycerin, polyglycerin, ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, butylene glycol, pentylene glycol, hexylene glycol, 1,2-propanediol, 1,3-propanediol, and 1,5-pentanediol.

[0108] It may be preferred that the (e) polyol has 3 or more carbon atoms and is selected from the group consisting of glycerin, diglycerin, ethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, butylene glycol, pentylene glycol, hexylene glycol, and mixtures thereof.

[0109] The amount of (e) polyol in the composition according to the present invention may be 1% by mass or less, preferably 5% by mass or less, and more preferably 10% by mass or less, based on the total mass of the composition.

[0110] On the other hand, the amount of the (e) polyol in the composition according to the present invention is 20% by mass or more, preferably 15% by mass or more, and more preferably 10% by mass or more, based on the total mass of the composition.

[0111] Therefore, the amount of (c) polyol in the composition according to the present invention may be in the range of 10% by mass to 20% by mass, preferably 5% by mass to 15% by mass, and more preferably 1% by mass to 10% by mass, relative to the total mass of the composition.

[0112] (Thickener) The composition according to the present invention may comprise (f) at least one thickening agent. A single type of thickening agent may be used, but two or more different types of thickening agents may also be used in combination.

[0113] (f) The thickening agent or thickening agent may be selected from organic thickeners and inorganic thickeners.

[0114] The organic thickener may be selected from at least one of the following: (i) associative thickeners, (ii) crosslinked acrylic acid homopolymers, (iii) crosslinked copolymers of (meth)acrylic acid and (C1-C6) alkyl acrylates; (iv) nonionic homopolymers and copolymers comprising at least one of ethylenically unsaturated ester monomers and ethylenically unsaturated amide monomers; (v) Homopolymers of ammonium acrylate and copolymers of ammonium acrylate and acrylamide; (vi) polysaccharides, and (vii) C 12 ~C 30 Fatty alcohols.

[0115] (i) As used herein, the expression “associative thickener” refers to a thickener that contains both hydrophilic and hydrophobic units, e.g., at least one C 30 By amphiphilic thickeners is meant those which contain a fatty chain and at least one hydrophilic unit.

[0116] Representative associative thickeners that may be used are: (aa) a non-ionic amphiphilic polymer comprising at least one fatty chain and at least one hydrophilic unit; (bb) an anionic amphiphilic polymer comprising at least one hydrophilic unit and at least one fatty chain unit; (cc) a cationic amphiphilic polymer comprising at least one hydrophilic unit and at least one fatty chain unit, and (dd) an amphiphilic polymer comprising at least one hydrophilic unit and at least one fatty chain unit; Associative polymers selected from the group consisting of: It is.

[0117] (aa) The non-ionic amphiphilic polymer comprising at least one fatty chain and at least one hydrophilic unit can be chosen, for example, from: (1) Cellulose modified with a group containing at least one fatty chain; examples that may be mentioned include: - hydroxyethylcellulose modified with at least one fatty chain-containing group selected from alkyl groups, arylalkyl groups and alkylaryl groups; where the alkyl group is, for example, a C8-C 22 For example, the product Natrosol Plus Grade 330 CS (C 1~6 alkyl), and the product Bermocoll EHM 100 sold by Berol Nobel, and - cellulose modified with polyalkylene glycol alkylphenyl ether groups, such as the product Amercell Polymer HM-1500 sold by the company Amerchol [polyethylene glycol (15) nonylphenyl ether]; (2) Hydroxypropyl guar modified with a group containing at least one fatty chain, such as the product Esaflor HM 22 (C 22 alkyl chain), and the product Miracare XC95-3 (C 14 alkyl chain) and RE205-1(C 20 alkyl chain), (3) at least one fatty acid chain, e.g., C 10 ~C 30polyetherurethanes containing alkyl or alkenyl groups, such as the products Elfacos T 210 and Elfacos T 212 sold by the company Akzo or the products Aculyn 44 and Aculyn 46 sold by the company Rohm & Haas; (4) Copolymers of vinylpyrrolidone and of hydrophobic fatty chain monomers; examples that may be mentioned are: - the products Antaron V216 and Ganex V216 (vinylpyrrolidone / hexadecene copolymers) sold by the company ISP, and - the products Antaron V220 and Ganex V220 (vinylpyrrolidone / eicosene copolymers) sold by the company ISP, (5) Copolymers of C1-C6 alkyl acrylates or C1-C6 alkyl methacrylates with amphiphilic monomers containing at least one fatty chain, such as the oxyethylenated methyl methacrylate / stearyl acrylate copolymer sold under the name Antil 208 by the company Goldschmidt; (6) Copolymers of hydrophilic acrylates or methacrylates with hydrophobic monomers containing at least one fatty chain, such as polyethylene glycol methacrylate / lauryl methacrylate copolymer.

[0118] (bb) Anionic amphiphilic polymers comprising at least one hydrophilic unit and at least one fatty chain unit can be chosen, for example, from those comprising at least one fatty chain allyl ether unit and at least one hydrophilic unit comprising an ethylenically unsaturated anionic monomer unit, for example a vinyl carboxylic acid unit, and further, for example, from units derived from acrylic acid, methacrylic acid, and mixtures thereof, in which the fatty chain allyl ether unit is represented by the formula (I): CH2=C(R1)CH2OB n R (I) wherein R1 is selected from H and CH3, B is an ethyleneoxy group, n is selected from zero and an integer ranging from 1 to 100, and R is selected from a hydrocarbon group selected from an alkyl group, an arylalkyl group, an aryl group, an alkylaryl group, and a cycloalkyl group, containing 10 to 30 carbon atoms, further for example 10 to 24 carbon atoms, and even further for example 12 to 18 carbon atoms. This corresponds to the monomer.

[0119] In one embodiment, the units of formula (I) can be, for example, where R1 can be H, n can be equal to 10, and R can be stearyl (C 18 ) group.

[0120] Anionic amphiphilic polymers of this type are described in EP 0216479 B2 and are prepared according to the emulsion polymerization method.

[0121] In one embodiment, the anionic amphiphilic polymer is, for example, a polymer formed from 20% to 60% by weight of acrylic acid and / or methacrylic acid, 5% to 60% by weight of lower alkyl (meth)acrylate, 2% to 50% by weight of the fatty chain allyl ether of formula (I), and 0% to 1% by weight of a crosslinking agent which is a well-known copolymerizable unsaturated polyethylene-based monomer, for example, diallyl phthalate, allyl (meth)acrylate, divinylbenzene, (poly)ethylene glycol dimethacrylate, and methylene bisacrylamide.

[0122] An example of such a polymer is a crosslinked terpolymer of methacrylic acid, ethyl acrylate and polyethylene glycol (10 EO) stearyl ether (steareth-10), such as that sold by Ciba under the names Salcare SC 80 and Salcare SC 90, which are 30% aqueous emulsions of crosslinked terpolymers of methacrylic acid, ethyl acrylate and steareth-10 allyl ether (40 / 50 / 10).

[0123] The anionic amphiphilic polymer may further comprise at least one hydrophilic unit of, for example, an unsaturated olefinic carboxylic acid type and an unsaturated carboxylic acid type (C 10 ~C 30 ) alkyl ester, etc. The hydrophilic unit of the unsaturated olefinic carboxylic acid type can be selected from those containing at least one hydrophobic unit of the type represented by the formula (II):

[0124] [ka]

[0125] (In the formula, R 1 is selected from H, CH3 and C2H5, i.e., acrylic acid, methacrylic acid and ethacrylic acid units. It corresponds to the monomer of unsaturated carboxylic acid (C 10 ~C 30 Hydrophobic units of the type such as alkyl esters are, for example, represented by the formula (III):

[0126] [ka]

[0127] [In the formula, R 1 is selected from H, CH3 and C2H5 (i.e., acrylate, methacrylate and ethacrylate units), for example, H (acrylate unit) and CH3 (methacrylate unit); R 2 is C 10 ~C 30 Alkyl groups, such as C 12 ~C 22 alkyl groups] This corresponds to the monomer.

[0128] Unsaturated carboxylic acid (C 10~ C 30) Examples of alkyl esters include lauryl acrylate, stearyl acrylate, decyl acrylate, isodecyl acrylate, and dodecyl acrylate, and the corresponding methacrylic acid esters lauryl methacrylate, stearyl methacrylate, decyl methacrylate, isodecyl methacrylate, and dodecyl methacrylate.

[0129] According to one preferred embodiment, these thickening polymers are crosslinked.

[0130] Anionic amphiphilic polymers of this type are disclosed, for example, in US Pat. Nos. 3,915,921 and 4,509,949 and may be prepared in accordance therewith.

[0131] Representative anionic amphiphilic polymers that may be used may further be selected from polymers formed from mixtures of monomers including: (i) acrylic acid, (ii) The above formula (III) (wherein R2 represents H or CH3, and R 3 represents an alkyl group having 12 to 22 carbon atoms), as well as esters of (iii) Crosslinking agents which are well known copolymerizable polyethylenically unsaturated monomers, such as diallyl phthalate, allyl (meth)acrylate, allyl ethers of sucrose, allyl ethers of pentaerythritol, divinylbenzene, (poly)ethylene glycol dimethacrylate, and methylene bisacrylamide.

[0132] More specifically, among this type of copolymer, there are copolymers such as those mentioned above, which contain 95 to 60% by weight of acrylic acid (hydrophilic units), 4 to 40% by weight of C 10 ~C 30 A copolymer consisting of alkyl acrylate (hydrophobic unit) and 0 to 6% by mass of a cross-linkable monomer, or a copolymer consisting of 98 to 96% by mass of acrylic acid (hydrophilic unit), 1 to 4% by mass of C 10 ~C 30 A composition consisting of alkyl acrylate (hydrophobic unit) and 0.1 to 0.6% by mass of a cross-linking polymerizable monomer will be used.

[0133] Very particularly, according to the invention, among the above mentioned polymers, acrylate / C 10 ~C 30 Alkyl acrylate copolymer (INCI name: Acrylates / C 10 ~C 30 Preference is given to alkyl acrylate crosspolymers, such as the products sold under the names Pemulen® TR1, Pemulen® TR2, Carbopol® Ultrez 20 Polymer, Carbopol® 1382 and Carbopol® EDT 2020 by the company Lubrizol.

[0134] Among the anionic amphiphilic fatty chain polymers, mention may also be made of the ethoxylated copolymer of methacrylic acid / methyl acrylate / alkyldimethyl-meta-isopropenylbenzyl isocyanate, sold, for example, under the name Viscophobe DB 1000 by the company Amerchol.

[0135] The cationic amphiphilic polymers used (cc) are chosen, for example, from quaternized cellulose derivatives and polyacrylates containing amino side groups.

[0136] The quaternized cellulose derivatives are, for example, selected from: Quaternized cellulose modified with groups containing at least one fatty chain, such as alkyl, arylalkyl and alkylaryl groups, containing at least 8 carbon atoms, and mixtures thereof; Quaternized hydroxyethyl cellulose modified with at least one fatty chain, such as groups including alkyl groups, arylalkyl groups, and alkylaryl groups containing at least 8 carbon atoms, and mixtures thereof.

[0137] Quaternized and non-quaternized polyacrylates containing amino side groups have hydrophobic groups, such as steareth-20 [polyoxyethylenated (20) stearyl alcohol] and (C 10 ~C30 ) alkyl PEG-20 itaconate.

[0138] The alkyl groups carried by the above quaternized cellulose and hydroxyethyl cellulose contain, for example, 8 to 30 carbon atoms.

[0139] The aryl group is, for example, selected from a phenyl group, a benzyl group, a naphthyl group and an anthryl group.

[0140] C8~C 30 Examples of quaternized alkylhydroxyethylcelluloses containing fatty chains are the products Quatrisoft LM 200, Quatrisoft LM-X 529-18-A, Quatrisoft LM-X 529-18B (C 12 alkyl) and Quatrisoft LM-X 529-8(C 18 Alkyl), and Crodacel QM, Crodacel QL (C 12 Alkyl) and Crodacel QS(C 18 alkyl).

[0141] Examples of polyacrylates containing amino side chains are polymers 8781-124B or 9492-103 and Structure Plus from National Starch.

[0142] (dd) amphiphilic polymers containing at least one hydrophilic unit and at least one fatty chain unit, such as methacrylamide propyl trimethyl ammonium chloride / acrylic acid / C 10 ~C 30 Mention may be made of copolymers of alkyl methacrylates, where the alkyl group is, for example, a stearyl group.

[0143] The associative thickener in the composition may, for example, be in solution or in dispersion with a viscosity of 200 s measured at 25° C. using a Rheomat RM 180 rheometer. -1At a shear rate of 100 rpm and a concentration of 1% active material in water, the viscosity may be greater than 0.1 ps, such as greater than 0.2 cp.

[0144] Among the (ii) crosslinked acrylic acid homopolymers that may be mentioned are those crosslinked with allyl alcohol ethers of the sugar series, such as the products sold under the names Carbopol 980, 981, 954, 2984 and 5984 by the company Goodrich, or those sold under the names Synthalen M and Synthalen K by the company 3 VSA.

[0145] (iii) Crosslinked copolymers of (meth)acrylic acid and C1-C6 alkyl acrylates may be chosen, for example, from the crosslinked copolymer of methacrylic acid and ethyl acrylate sold by Coatex under the name Viscoatex 538C as an aqueous dispersion with 38% active material, and the crosslinked copolymer of acrylic acid and ethyl acrylate sold by Rohm & Haas under the name Aculyn 33 as an aqueous dispersion with 28% active material. Crosslinked copolymers of methacrylic acid and ethyl acrylate include the aqueous dispersion sold by NOVEON under the name CARBOPOL AQUA SF-1 with 30% active material.

[0146] (iv) Among the nonionic homo- or copolymers containing ethylenically unsaturated monomers of the ester and / or amide type, mention may be made of the products sold under the following names: Cynamer P250 (polyacrylamide) by Cytec, PMMA MBX-8C (methyl methacrylate / ethylene glycol dimethacrylate copolymer) by US Cosmetics, Acryloid B66 (butyl methacrylate / methyl methacrylate copolymer) by Rohm & Haas, and BPA 500 (polymethyl methacrylate) by Kobo.

[0147] Mention may also be made, by way of example, of at least one water-soluble or water-dispersible, crosslinked or non-crosslinked polymer comprising at least acrylamido-2-methylpropanesulfonic acid (AMPS) monomer.

[0148] The AMPS (co)polymers may preferably be fully neutralized or substantially fully neutralized, ie, at least 90% neutralized.

[0149] The AMPS (co)polymers may be crosslinked or non-crosslinked.

[0150] Examples of AMPS (co)polymers that may be mentioned include: Acrylamide / sodium acrylamide-2-methylpropanesulfonate crosslinked copolymers, such as the commercial product Sepigel 305 (INCI name: Polyacrylamide / C 13 ~C 14 copolymer of isoparaffin / laureth-7, or the commercial product sold by the company SEPPIC under the trade name Simulgel 600 (INCI name: Acrylamide / Sodium Acryloyldimethyltaurate / Isohexadecane / Polysorbate-80); Copolymers of AMPS with vinylpyrrolidone or with vinylformamide, such as the commercial product sold under the name Aristoflex AVC by Clariant (INCI name: Ammonium acryloyldimethyltaurate / VP copolymer), but neutralized with sodium hydroxide or potassium hydroxide; Copolymers of AMPS and sodium acrylate, such as AMPS / sodium acrylate copolymer, for example the commercial product sold under the name Simulgel EG by the company SEPPIC (INCI name: Sodium acrylate / sodium acryloyldimethyltaurate copolymer (and) isohexadecane (and) polysorbate-80), and Copolymers of AMPS and hydroxyethyl acrylate, such as AMPS / hydroxyethyl acrylate copolymer, for example the commercial product sold under the name Simulgel NS by the company SEPPIC (INCI name: Hydroxyethyl acrylate / Sodium acryloyldimethyltaurate copolymer (and) Squalane (and) Polysorbate-60).

[0151] It may be more preferred that the AMPS (co)polymer is a hydroxyethyl acrylate / sodium acryloyldimethyltaurate copolymer.

[0152] Among the (v) ammonium acrylate homopolymers that may be mentioned are the products sold under the name Microsap PAS 5193 by the company Hoechst.

[0153] Copolymers of ammonium acrylate and acrylamide include the product sold by the company Hoechst under the name Bozepol C Nouveau or the product PAS 5193 (described and prepared in the literature, in French Patent No. 2416723, in U.S. Pat. No. 2798053 and in U.S. Pat. No. 2923692).

[0154] (vi) Polysaccharides include, for example, glucans, modified or unmodified starches (e.g., those derived from cereals, such as wheat, corn or rice, those derived from vegetables, such as yellow pea, and those derived from tubers, such as potato or cassava), amylose, amylopectin, glycogen, dextran, cellulose and derivatives thereof (e.g., methylcellulose, hydroxyalkylcellulose, ethylhydroxyethylcellulose and carboxymethylcellulose), mannans, xylans, lignins, and the like. The gums are selected from gum arabic, galactan, galacturonan, chitin, chitosan, glucuronoxylan, arabinoxylan, xyloglucan, glucomannan, pectinic acid and pectins, alginic acid and alginates, arabinogalactan, carrageenan, agar, glycosaminoglucan, gum arabic, gum tragacanth, gum ghatti, gum karaya, carob gum, galactomannans such as guar gum and non-ionic derivatives thereof (e.g. hydroxypropyl guar), and xanthan gum, and mixtures thereof.

[0155] For example, polysaccharides that may be used are selected from those described, for example, in "Encyclopedia of Chemical Technology", Kirk-Othmer, 3rd Edition, 1982, Vol. 3, pp. 896-900 and Vol. 15, pp. 439-458, in "Polymers in Nature" by EA MacGregor and CT Greenwood, published by John Wiley & Sons, Chapter 6, pp. 240-328, 1980, and in "Industrial Gums - Polysaccharides and their Derivatives", edited by Roy L. Whistler, 2nd Edition, published by Academic Press Inc., the contents of which three publications are incorporated herein by reference in their entirety.

[0156] For example, starch, guar gum, cellulose, and derivatives thereof can be used.

[0157] Among the starches that may be used, mention may be made, for example, of macromolecules in the form of polymers containing base units that are anhydroglucose units. The number of these units and their assembly make it possible to distinguish between amylose (a linear polymer) and amylopectin (a branched polymer). The relative proportions of amylose and amylopectin, as well as their degree of polymerization, may vary depending on the plant origin of the starch.

[0158] The starch molecules used may have cereal or tuber origins, and thus may be chosen, for example, from corn, rice, cassava, tapioca, barley, potato, wheat, sorghum and pea starches.

[0159] Starch generally exists in the form of a white powder that is insoluble in cold water and whose primary particle size ranges from 3 to 100 microns.

[0160] The starch may optionally be C1-C6 hydroxyalkylated or C1-C6 acylated (eg acetylated). The starch may also be subjected to a heat treatment.

[0161] Distarch phosphate or compounds rich in distarch phosphate can also be used, such as the products offered by the company AVEBE under the references PREJEL VA-70-T AGGL (gelatinized hydroxypropylated cassava distarch phosphate), or PREJEL TK1 (gelatinized cassava distarch phosphate), or PREJEL 200 (gelatinized acetylated cassava distarch phosphate).

[0162] The guar gum may be modified or unmodified.

[0163] Unmodified guar gums are, for example, the products sold under the names Vidogum GH 175 by the company Unipectine and Meypro-Guar 50 and Jaguar C by the company Meyhall.

[0164] The modified nonionic guar gum is, for example, modified with C1-C6 hydroxyalkyl groups.

[0165] Among the hydroxyalkyl groups that may be mentioned are, for example, the hydroxymethyl group, the hydroxyethyl group, the hydroxypropyl group and the hydroxybutyl group.

[0166] These guar gums are well known in the art and can be prepared, for example, by reacting guar gum with the corresponding alkene oxide, such as propylene oxide, to obtain guar gum modified with hydroxypropyl groups.

[0167] The degree of hydroxyalkylation corresponds to the number of alkylene oxide molecules consumed by the number of free hydroxyl functional groups present on the guar gum and can range, for example, from 0.4 to 1.2.

[0168] Such non-ionic guar gums, optionally modified with hydroxyalkyl groups, are sold, for example, by the company Rhodia Chimie (Meyhall) under the trade names Jaguar HP8, Jaguar HP60, Jaguar HP120, Jaguar DC 293 and Jaguar HP 105 or by the company Aqualon under the name Galactasol 4H 4FD2 It is sold at.

[0169] Among the celluloses and cellulose derivatives that can be used, such as celluloses modified with hydroxyl alkyl groups, there are, for example, hydroxypropyl methylcellulose, hydroxyethyl cellulose and hydroxypropyl cellulose, as well as hydrophobized hydroxypropyl methylcellulose. Mention may be made of the products sold by the company Aqualon under the names Klucel EF, Klucel H, Klucel LHF, Klucel MF and Klucel G.

[0170] (vii) The fatty alcohols used as thickening agents do not contain polyoxyalkylenated groups and are selected, for example, from myristyl alcohol, cetyl alcohol, stearyl alcohol and behenyl alcohol.

[0171] (f) The thickener may be selected from polymeric thickeners, preferably associative polymeric thickeners, more preferably anionic associative polymeric thickeners.

[0172] (f) The thickening agent may be hydroxyethyl acrylate / sodium acryloyldimethyl tartrate copolymer, xanthan gum, and mixtures thereof.

[0173] The amount of the (f) thickener in the composition according to the present invention may be 0.01% by mass or more, preferably 0.05% by mass or more, and more preferably 0.1% by mass or more, based on the total mass of the composition.

[0174] The amount of (f) thickener in the composition according to the present invention may be 3% by mass or less, preferably 2% by mass or less, and more preferably 1% by mass or less, based on the total mass of the composition.

[0175] The amount of the (f) thickener in the composition according to the present invention may be 0.01 to 3% by mass, preferably 0.05 to 2% by mass, and more preferably 0.1 to 1% by mass, relative to the total mass of the composition.

[0176] (Other ingredients) The compositions according to the present invention may also include at least one optional or additional ingredient.

[0177] Optional or additional ingredients may be selected from the group consisting of anionic, nonionic or amphoteric polymers, anionic, nonionic or amphoteric surfactants, organic or inorganic UV filters, ceramides or pseudoceramides, peptides and their derivatives, protein hydrolysates, swelling and penetrating agents, agents effective for hair removal, antidandruff agents, suspending agents, sequestrants, dyes, vitamins or provitamins, fragrances, preservatives, co-preservatives, stabilizers, and mixtures thereof.

[0178] The amount of optional or additional components is not limited, but may be from 0.01% to 30% by weight, preferably from 0.1% to 20% by weight, more preferably from 1% to 10% by weight, relative to the total weight of the composition according to the present invention.

[0179] [Preparation] The composition according to the present invention can be prepared by mixing the essential components described above and the optional components (if required) described above.

[0180] The method and means for mixing the above essential components and optional components are not limited. Any conventional method and means can be used to mix the above essential components and optional components to prepare the composition according to the present invention.

[0181] [form] The composition according to the present invention may be of the O / W type or the W / O type, and is preferably of the O / W type.

[0182] [Use and Method] The composition according to the present invention can be used as a cosmetic composition. The cosmetic composition can be used to treat keratinous materials. Keratinous materials include skin, lips, hair, eyebrows, eyelashes, etc. In particular, the composition according to the present invention can be used to treat skin or hair, preferably both skin and hair, more preferably both skin care and hair care.

[0183] The composition according to the present invention may be used as a leave-on type cosmetic composition or a leave-off type cosmetic composition.

[0184] The present invention also relates to a method for keratinous materials, preferably both skin and hair, comprising the step of applying a composition according to the invention to keratinous materials.

[0185] The composition according to the present invention can provide a satisfactory texture even when it is used for both hair and skin.For example, when the composition according to the present invention is used for hair, the composition according to the present invention can provide good smoothness, less stickiness, and good finger-combing.On the other hand, when the composition according to the present invention is used for skin, the composition according to the present invention can provide less stickiness and moisturizing feeling.

[0186] Therefore, the cosmetic containing the composition according to the present invention can be used not only for the skin but also for the hair. Therefore, by using the cosmetic containing the composition according to the present invention, the cosmetic treatment can be simplified.

[0187] Therefore, the present invention also provides a method for producing a method for the preparation of a pharmaceutical composition comprising the steps of: (a) at least one volatile non-silicone oil; (b) at least one non-volatile non-silicone oil; (c) at least one silicone; (d) Water and A process or method for making a cosmetic composition suitable for both skin and hair use, comprising: (c) The present invention also relates to a process or method, characterized in that the amount of silicone is adjusted to within the range of 1.0% by mass to 5.0% by mass, preferably within the range of 1.5% by mass to 4.0% by mass, and more preferably within the range of 2.0% by mass to 3.0% by mass, relative to the total mass of the composition.

[0188] In addition, the present invention also provides a method for producing a composition suitable for both skin and hair use, comprising: (a) at least one volatile non-silicone oil; (b) at least one non-volatile non-silicone oil; (d) Water and (c) use of at least one silicone in a cosmetic composition comprising It may also concern the use of at least one silicone (c), wherein the amount of silicone (c) is in the range of 1.0% to 5.0% by weight, preferably 1.5% to 4.0% by weight, more preferably 2.0% to 3.0% by weight, relative to the total weight of the composition. EXAMPLES

[0189] The present invention will now be described in more detail with reference to examples, which should not be construed as limiting the scope of the present invention.

[0190] (Example 1 and Comparative Example 1) [Preparation] Each of the hair compositions according to Example 1 and Comparative Example 1 was prepared by mixing the components shown in Table 1. The numerical values ​​of the amounts of the components are all based on "mass %" of the active ingredients.

[0191] [Table 1]

[0192] [evaluation] (Sensory evaluation of hair) 0.1 g of the composition according to Example 1 was applied (1 g, 27 cm) onto a semi-wet hair swatch, after which the hair swatch was allowed to dry completely.

[0193] 0.1 g of the composition according to Comparative Example 1 was applied (1 g, 27 cm) onto another half-wet hair swatch, after which the hair swatch was allowed to dry completely.

[0194] Five panelists evaluated the items of smoothness, stickiness and smoothness according to the following criteria: 5: Very good 4: Good 3: Normal 2: Bad 1: Very poor

[0195] The average scores are shown in Table 2 in the rows for "smoothness," "stickiness," and "feel for running fingers through."

[0196] (Sensory evaluation of skin) 0.1 g of each of the compositions according to Example 1 and Comparative Example 1 was applied onto the lower forearms of five panelists, and the stickiness and moisturizing sensation were evaluated according to the following evaluation criteria: 5: Very good 4: Good 3: Normal 2: Bad 1: Very poor

[0197] The average scores are shown in Table 2 in the rows for "stickiness" and "moist feeling."

[0198] [Table 2]

[0199] It is clear that the composition according to Example 1 can provide sufficient texture for both hair use and skin use due to the adjustment of the total amount of silicone, while Comparative Example 1 cannot provide sufficient texture for both hair use and skin use.

Claims

1. (a) at least one volatile non-silicone oil; (b) at least one non-volatile non-silicone oil; (c) a mixture of dimethylpolysiloxane and dimethiconol; (d) Water and A cosmetic composition for both skin and hair comprising the amount of the (a) volatile non-silicone oil is in the range of 0.1% by mass to 20% by mass, based on the total mass of the composition; the amount of the (b) non-volatile non-silicone oil is in the range of 0.005% by mass to 5% by mass, based on the total mass of the composition; The composition, wherein the amount of the mixture of (c) dimethylpolysiloxane and dimethiconol is 1.0% by mass to 5.0% by mass, based on the total mass of the composition.

2. The composition of claim 1, wherein the (a) volatile non-silicone oil is selected from hydrocarbon oils.

3. The composition according to claim 1 or 2, wherein the amount of the (a) volatile non-silicone oil in the composition is in the range of 0.5% by weight to 15% by weight, based on the total weight of the composition.

4. 4. The composition according to claim 1, wherein the (b) non-volatile non-silicone oil is selected from vegetable oils, synthetic triglycerides, and mixtures thereof.

5. The composition according to any one of claims 1 to 4, wherein the amount of the (b) non-volatile non-silicone oil in the composition is in the range of 0.01% by weight to 1% by weight, based on the total weight of the composition.

6. 6. The composition according to claim 1, wherein the mass ratio of the amount of the (b) nonvolatile non-silicone oil to the amount of the (c) mixture of dimethylpolysiloxane and dimethiconol is 0.5 or less.

7. The composition according to any one of claims 1 to 6, wherein the amount of (d) water in the composition is in the range of 50% by weight to 95% by weight, based on the total weight of the composition.

8. The composition of claim 1 , further comprising: (e) at least one polyol.

9. 9. The composition of claim 1, further comprising: (f) at least one thickening agent.

10. A cosmetic method for both skin and hair, comprising the step of applying a composition described in any one of claims 1 to 9 to both skin and hair.

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