Manufacturing method of electrode plate, manufacturing method of secondary battery, electrode plate and secondary battery

Abstract

To prevent a conductive foreign material from falling and peeling from an electrode board after a production, and contribute an improvement of a safety of a secondary battery.SOLUTION: A manufacturing method of an electrode plate, disclosed here, comprises: a precursor preparation step of preparing an electrode precursor 20A comprising: an active material application region A1 to which an electrode active material layer 24 is applied to a front surface of an electrode core body 22; and a core body exposure region A2 in which the electrode core body 22 is exposed without applying the electrode active material layer 24; an active material application region cutting step of cutting the active material application region A1 with a pulse laser; and a core body exposure region cutting step of cutting the core body exposure region A2 with the pulse layer. Then, when a pulse width (ns) of the pulse layer in the core body exposure region cutting step is X, and a lap rate (%) is Y, a condition indicated by a formulation of Y≥-3logX+106 is satisfied. According to the manufacturing method of the electrode plate, since a conductive foreign material can be prevented from being fallen and peeled from the electrode plate after the manufacturing, a safety of the secondary battery can be improved.SELECTED DRAWING: Figure 3

Description

[Technical field]

[0001] The present invention relates to a method for manufacturing an electrode plate, a method for manufacturing a secondary battery, an electrode plate, and a secondary battery. [Background technology]

[0002] A secondary battery such as a lithium ion secondary battery includes, for example, an electrode body in which a positive electrode plate and a negative electrode plate face each other via a separator. Hereinafter, these positive electrode plate and negative electrode plate are collectively referred to as "electrode plate". This electrode plate includes, for example, an electrode core body which is a foil-shaped metal member, and an electrode active material layer which is applied to the surface of the electrode core body and contains an electrode active material. In manufacturing an electrode plate having such a configuration, first, an electrode active material layer is applied to the surface of a large electrode core body. This produces a precursor of the electrode plate (hereinafter referred to as "electrode precursor"). Then, an electrode plate of a desired size is cut out from the electrode precursor using a laser or the like. An example of a technique related to cutting out such an electrode plate is disclosed in Patent Documents 1 and 2.

[0003] However, in the electrode precursor having the above configuration, the thickness of the electrode active material layer is likely to be non-uniform at the outer periphery of the region where the electrode active material layer is applied (active material applied region). For this reason, when cutting out an electrode plate from the electrode precursor, the outer periphery of the active material applied region is usually cut out with a laser. In addition, in a normal electrode plate, it is necessary to provide a portion where the electrode core (metal foil) is exposed in order to connect with a conductive member such as an electrode terminal. For this reason, when cutting out an electrode plate, a region where the electrode active material layer is not applied and where the electrode core substrate is exposed (core exposed region) is partially cut out to form an electrode tab. As described above, in the manufacture of an electrode plate, a process of cutting the active material applied region and a process of cutting the core exposed region are carried out (see, for example, Patent Document 1). [Prior art documents] [Patent documents]

[0004] [Patent Document 1] JP 2010-34009 A [Patent Document 2] JP 2016-33912 A Summary of the Invention [Problem to be solved by the invention]

[0005] However, the electrode plate manufactured by the above-mentioned manufacturing method has a characteristic that pieces of the electrode active material layer and fine metal pieces (spatter) are easily dropped or peeled off. If these conductive foreign objects drop or peel off inside the secondary battery, they can cause an internal short circuit.

[0006] The present invention has been made in consideration of the above-mentioned problems, and aims to provide a technology that can prevent conductive foreign matter from falling off or peeling off from electrode plates after manufacture, thereby contributing to improving the safety of secondary batteries. [Means for solving the problem]

[0007] The present inventors have conducted various investigations to solve the above-mentioned problems, and as a result have found the causes of the falling off and peeling off of the broken pieces of the electrode active material layer and the falling off and peeling off of the sputters.

[0008] First, the cause of the falling off and peeling off of the broken pieces of the electrode active material layer will be explained. As described above, in the manufacture of the electrode plate, the outer peripheral edge of the active material application area is cut off with a laser. At this time, the electrode core may melt due to the heat of the laser and mix with a part of the electrode active material layer. Then, the electrode active material layer mixed with this molten metal has a significantly reduced adhesiveness, so it easily falls off and peels off with a slight impact. The inventor of the present invention thought that in order to suppress the decrease in adhesiveness of the electrode active material layer due to the inclusion of this molten metal, it is sufficient to cut the active material application area using a pulsed laser. Such a pulsed laser can repeatedly irradiate spots in a very short time width and apply a large amount of energy to the cutting part in a concentrated manner, so that the electrode core can be quickly cut with a small amount of melting.

[0009] Next, the cause of the falling off and peeling off of fine metal pieces (spatter) will be explained. As described above, in the manufacture of an electrode plate, it is required to cut out a part of the core exposed region in order to form an electrode tab. However, when a high-energy laser is irradiated to a part where a metal member is exposed, such as the core exposed region, spatter may scatter from the irradiated part. When this spatter adheres to the electrode plate, it becomes fine metal pieces that easily fall off and peel off with a slight impact. The inventor of the present invention thought that in order to suppress the scattering of this spatter, it is sufficient to cut the core exposed region using a continuous wave laser (CW laser). This CW laser continuously irradiates a low-energy laser to melt and cut the electrode core, so that the electrode tab can be formed while suppressing the scattering of spatter.

[0010] As described above, according to the study by the present inventor, in order to prevent the falling off and peeling off of the fragments of the electrode active material layer, it is necessary to use a pulsed laser to cut the active material applied region, and in order to prevent the falling off and peeling off of the sputter, it is necessary to use a CW laser to cut the core exposed region. However, the method of cutting the active material applied region and the core exposed region separately by switching the laser to be used causes a significant decrease in manufacturing efficiency, so it is difficult to adopt it at an actual manufacturing site. In addition, when the active material applied region and the core exposed region are cut separately, it is required to connect the cutting lines formed in each region without misalignment, which may cause frequent cutting defects. In consideration of this point, the present inventor has studied a method that can continuously cut the active material applied region and the core exposed region while preventing the generation of each of the above two types of conductive foreign matter.

[0011] The manufacturing method of the electrode plate disclosed herein has been made based on the above findings, and manufactures an electrode plate including an electrode core that is a metal foil and an electrode active material layer that is applied to the surface of the electrode core and contains an electrode active material. The manufacturing method of the electrode plate includes a precursor preparation step of preparing an electrode precursor including an active material applied region where an electrode active material layer is applied to the surface of the electrode core and a core exposed region where the electrode core is exposed without the electrode active material layer applied, an active material applied region cutting step of cutting the active material applied region with a pulsed laser, and a core exposed region cutting step of cutting the core exposed region with a pulsed laser. The manufacturing method of the electrode plate disclosed herein is characterized in that, when the pulse width (ns) of the pulsed laser in the core exposed region cutting step is X and the overlap rate (%) is Y, the following formula (1) is satisfied: Y≧-3logX+106 (1)

[0012] In the manufacturing method of the electrode plate having the above configuration, a pulsed laser is used when cutting the active material imparted region. This makes it possible to prevent molten metal derived from the electrode core from being mixed into the electrode active material layer, and therefore prevents fragments of the electrode active material layer from falling off and peeling off from the manufactured electrode plate. On the other hand, in the manufacturing method disclosed herein, in order to prevent a significant decrease in manufacturing efficiency and the occurrence of cutting defects, a pulsed laser is also used to cut the core exposed region, and the active material imparted region and the core exposed region are continuously cut. However, in the manufacturing method disclosed herein, the state of the pulsed laser that cuts the core exposed region is made closer to that of a CW laser. Specifically, according to an experiment conducted by the present inventor, a pulsed laser that satisfies the above formula (1) increases the melting amount of the electrode core to the same level as a CW laser, melts and cuts the electrode core, and therefore can suppress the scattering of spatter. As described above, according to the manufacturing method of the electrode plate disclosed herein, it is possible to prevent conductive foreign matter from falling off and peeling off from the manufactured electrode plate, which can contribute to improving the safety of secondary batteries.

[0013] In a preferred embodiment of the electrode plate manufacturing method disclosed herein, the frequency of the pulsed laser in the active material applied region cutting step is lower than the frequency of the pulsed laser in the core exposed region cutting step, thereby more appropriately preventing the fragments and spatters of the electrode active material layer from falling off or peeling off.

[0014] In a preferred embodiment of the electrode plate manufacturing method disclosed herein, the frequency of the pulsed laser in the active material application region cutting step is 100 kHz to 2000 kHz, which can more appropriately prevent fragments of the electrode active material layer from falling off or peeling off.

[0015] In a preferred embodiment of the electrode plate manufacturing method disclosed herein, the pulse width X of the pulse laser in the core exposed region cutting step is 30 ns to 240 ns, which can more suitably prevent the spatter from falling off or peeling off.

[0016] In a preferred embodiment of the electrode plate manufacturing method disclosed herein, the overlap rate of the pulsed laser in the active material applied region cutting step is smaller than the overlap rate of the pulsed laser in the core exposed region cutting step, thereby more appropriately preventing the fragments and spatters of the electrode active material layer from falling off or peeling off.

[0017] In a preferred embodiment of the electrode plate manufacturing method disclosed herein, the overlap rate of the pulse laser in the core exposed region cutting step is 90% to 99%, which can more suitably prevent the spatter from falling off or peeling off.

[0018] In a preferred embodiment of the method for producing an electrode plate disclosed herein, the electrode plate is a negative electrode plate including a negative electrode core made of copper or a copper alloy and a negative electrode active material layer containing a carbon material as an electrode active material. A negative electrode plate having such a configuration is particularly susceptible to a decrease in the adhesiveness of the electrode active material layer due to the inclusion of molten metal. However, according to the method for producing an electrode plate disclosed herein, the decrease in the adhesiveness of the electrode active material layer can be appropriately suppressed even in the production of a negative electrode plate having such a configuration.

[0019] Another aspect of the technology disclosed herein provides a method for manufacturing a secondary battery. Specifically, the technology disclosed herein is a method for manufacturing a secondary battery including an electrode assembly in which a pair of electrode plates face each other via a separator, characterized in that at least one of the pair of electrode plates is manufactured using the electrode plate manufacturing method having the above-described configuration. According to this manufacturing method, it is possible to suppress conductive foreign matter (fragments and spatters of the electrode active material layer) from falling off or peeling off from the electrode plate inside the secondary battery, thereby making it possible to obtain a secondary battery with excellent safety.

[0020] In addition, an electrode plate is provided as another aspect of the technology disclosed herein. The electrode plate includes an electrode core, which is a foil-shaped metal member, and an electrode active material layer that is applied to the surface of the electrode core and contains an electrode active material. The electrode plate includes an electrode plate main body part in which an electrode active material layer is applied to the surface of the electrode core, and an electrode tab that protrudes outward from a part of the outer periphery of the electrode plate main body part in an area where the electrode active material layer is not applied and the electrode core is exposed. The electrode plate disclosed herein includes a first thick part that is thicker than the center part of the electrode tab formed on the outer periphery of the electrode tab, and an aspect ratio of the first thick part in a cross-sectional view along the thickness direction of the electrode tab is 0.85 or more. Furthermore, a second thick part that is thicker than the electrode core in the center part of the electrode plate main body part is formed on the end of the electrode core on at least one side of the outer periphery of the electrode plate main body part, and a coating layer containing an electrode active material is attached to the surface of the second thick part.

[0021] The electrode plate disclosed herein is manufactured by the manufacturing method of the electrode plate having the above configuration. Specifically, this electrode plate has a first thick portion formed on the outer periphery of the electrode tab. The first thick portion is a trace of laser cutting. In the manufacturing method of the electrode plate having the above configuration, when cutting out the electrode tab (cutting the core-exposed region), the pulse laser conditions are made closer to those of the CW laser. When melting and cutting with such a pulse laser, the amount of melting of the electrode core becomes the same as that of the CW laser, so that the cross-sectional shape of the cut mark (first thick portion) becomes approximately circular (aspect ratio of 0.85 or more). On the other hand, in the manufacturing method of the electrode plate having the above configuration, when cutting out the electrode plate main body (cutting the active material-applied region), a high-energy pulse laser is used to suppress a decrease in adhesion of the electrode active material layer due to the inclusion of molten metal. Therefore, a coating layer containing the electrode active material adheres to the laser cut mark (second thick portion) formed on the outer periphery of the electrode plate main body. Unlike an electrode active material layer containing molten metal, such a coating layer is not easily peeled off or detached from the electrode core.

[0022] In a preferred embodiment of the electrode plate disclosed herein, the second thick portion has a claw shape with a cap portion protruding from both sides or one side in the thickness direction and a recess formed between the cap portion and the electrode core. As described above, the second thick portion is a laser cut mark formed by a high-energy pulse laser. When a high-energy pulse laser is used, the amount of metal melted during cutting is very small, so that the above-mentioned claw-shaped cut mark (second thick portion) may be formed. This claw-shaped second thick portion exhibits an excellent anchor effect, and can further effectively prevent the electrode active material layer from falling off or peeling off.

[0023] In a preferred embodiment of the electrode plate disclosed herein, the coating layer attached to the surface of the second thick portion has a thickness of 1 μm to 20 μm. This allows the second thick portion to be appropriately coated with the coating layer of the electrode active material, and therefore makes it possible to preferably prevent other members (e.g., a separator of a secondary battery) from being damaged by the second thick portion.

[0024] In a preferred embodiment of the electrode plate disclosed herein, the center point of the first thick portion is located between a pair of extension lines extending from each surface of the central portion of the electrode tab. The electrode plate having such a configuration can contribute to improving the manufacturing efficiency of secondary batteries because the electrode tab can be easily bent. Such a first thick portion can be formed when cutting out the electrode tab with a pulse laser that satisfies the above formula (1).

[0025] In a preferred embodiment of the electrode plate disclosed herein, the first thick portion has a first region having a relatively large thickness and a second region having a relatively small thickness, and the first region and the second region are alternately formed along the outer peripheral edge of the electrode tab. In the manufacturing method of the electrode plate having the above configuration, the electrode core (negative electrode tab) is melted and cut with a pulsed laser having a high overlap ratio that satisfies formula (1). In this case, the molten electrode core is deformed into a substantially spherical shape by surface tension, so that the first region, which is a portion where the molten metal is concentrated, and the second region, which is a portion where the molten metal is sparse, are alternately formed.

[0026] Another aspect of the technology disclosed herein provides a secondary battery. Specifically, the technology disclosed herein is characterized in that in a secondary battery having an electrode body in which a pair of electrode plates face each other via a separator, the electrode plate having the above-mentioned configuration is used for at least one of the pair of electrode plates. This can prevent conductive foreign matter (fragments of the electrode active material layer, spatter) from being released from the electrode plate, thereby contributing to improving the safety of the secondary battery. [Brief description of the drawings]

[0027] [Figure 1] 4 is a flowchart illustrating a method for manufacturing an electrode plate according to an embodiment. [Diagram 2] FIG. 2 is a plan view showing a schematic diagram of a negative electrode plate produced by a method for producing an electrode plate according to an embodiment of the present invention. [Diagram 3] 4A to 4C are plan views illustrating a method for manufacturing an electrode plate according to an embodiment. [Figure 4] FIG. 2 is a diagram illustrating an overlap ratio of a pulse laser. [Diagram 5]3 is a cross-sectional view taken along the line VV in FIG. 2. [Figure 6] 6 is a cross-sectional view taken along the line VI-VI in FIG. 2. [Figure 7] FIG. 1 is a perspective view illustrating a secondary battery according to an embodiment. [Figure 8] 8 is a schematic vertical cross-sectional view taken along line VIII-VIII in FIG. 7. [Figure 9] FIG. 8 is a schematic longitudinal sectional view taken along line IX-IX in FIG. [Figure 10] FIG. 8 is a schematic cross-sectional view taken along line XX in FIG. [Figure 11] FIG. 2 is a perspective view showing a schematic view of an electrode body attached to a sealing plate. [Figure 12] 4 is a perspective view that shows a schematic diagram of an electrode assembly to which a positive electrode second current collecting portion and a negative electrode second current collecting portion are attached. FIG. [Figure 13] FIG. 2 is a perspective view illustrating an electrode assembly of the secondary battery according to one embodiment. [Figure 14] FIG. 2 is a front view of an electrode assembly of the secondary battery according to the embodiment. [Figure 15] 1 is a cross-sectional SEM photograph (1000x) of a negative electrode tab of a negative electrode plate of an example. [Figure 16] 1 is a cross-sectional SEM photograph (1000x) of a side edge portion of a main body of a negative electrode plate of an example. [Figure 17] 1 is a cross-sectional SEM photograph (1000x) of a negative electrode tab of a negative electrode plate of Comparative Example 1. [Figure 18] 1 is a cross-sectional SEM photograph (1000x) of a side edge portion of a main body of a negative electrode plate in Comparative Example 1. [Figure 19] 1 is a cross-sectional SEM photograph (1000x) of a negative electrode tab of a negative electrode plate of Comparative Example 2. [Figure 20] 1 is a cross-sectional SEM photograph (370x) of a side edge portion of a main body of a negative electrode plate in Comparative Example 2. [Figure 21] 13 is a graph showing the relationship between the overlap ratio and the pulse width of each sample measured in the second test. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0028] Hereinafter, an embodiment of the technology disclosed herein will be described with reference to the drawings. It should be noted that matters other than those specifically mentioned in this specification and necessary for implementing the technology disclosed herein (for example, the general configuration and manufacturing process of a battery) can be understood as design matters for a person skilled in the art based on the conventional technology in the field. The technology disclosed herein can be implemented based on the contents disclosed in this specification and the technical common sense in the field. In this specification, the expression "A to B" indicating a range includes the meaning of A or more and B or less, as well as "preferably greater than A" and "preferably smaller than B".

[0029] In this specification, the term "secondary battery" refers generally to an electricity storage device in which a charge / discharge reaction occurs by the movement of charge carriers between a pair of electrodes (positive and negative electrodes) via an electrolyte. Such secondary batteries include so-called storage batteries such as lithium ion secondary batteries, nickel hydrogen batteries, and nickel cadmium batteries, as well as capacitors such as electric double layer capacitors. In the following, an embodiment in which a lithium ion secondary battery is the subject of the above-mentioned secondary batteries will be described.

[0030] <Electrode plate manufacturing method> The method for manufacturing an electrode plate disclosed herein is a method for manufacturing an electrode plate including an electrode core body that is a metal foil and an electrode active material layer that is applied to the surface of the electrode core body and contains an electrode active material. Hereinafter, as one embodiment of the method for manufacturing an electrode plate disclosed herein, a method for manufacturing an electrode plate (negative electrode plate) on the negative electrode side of a secondary battery will be described. FIG. 1 is a flowchart showing a method for manufacturing an electrode plate according to this embodiment. FIG. 2 is a plan view that shows a schematic diagram of a negative electrode plate manufactured in the method for manufacturing an electrode plate according to this embodiment. FIG. 3 is a plan view that explains the method for manufacturing an electrode plate according to this embodiment. FIG. 4 is a diagram that explains the overlap ratio of a pulse laser. FIG. 5 is a cross-sectional view taken along the arrow VV in FIG. 2. FIG. 6 is a cross-sectional view taken along the arrow VI-VI in FIG. 2. In addition, the symbol L in FIGS. 2, 3, 5, and 6 indicates the "longitudinal direction" of the negative electrode plate 20 (or the negative electrode precursor 20A), the symbol S indicates the "short-side direction", and the symbol T indicates the "thickness direction".

[0031] As shown in Fig. 1, the method for manufacturing an electrode plate according to this embodiment includes a precursor preparation step S1, an active material application region cutting step S2, and a core exposed region cutting step S3. This produces a negative electrode plate 20 having a configuration as shown in Fig. 2. Below, an overview of the negative electrode plate 20 to be produced will be described, and then each step shown in Fig. 1 will be described.

[0032] (Outline of negative plate) As shown in FIG. 2, the negative electrode plate 20 is a long strip-shaped member. The negative electrode plate 20 includes a negative electrode core 22, which is a foil-shaped metal member, and a negative electrode active material layer 24 provided on the surface of the negative electrode core 22. From the viewpoint of battery performance, the negative electrode active material layer 24 is preferably provided on both sides of the negative electrode core 22. In addition, the negative electrode plate 20 has two regions, a plate main body 20b and a negative electrode tab 22t, in a plan view. The plate main body 20b is a region where the negative electrode active material layer 24 is provided on the surface of the negative electrode core 22. On the other hand, the negative electrode tab 22t is a region where the negative electrode active material layer 24 is not provided and the negative electrode core 22 is exposed. In addition, the negative electrode tab 22t protrudes outward (upward in the short-side direction S in FIG. 2) from a part of the outer peripheral edge portion 20b1 of the plate main body 20b. 2 has a plurality of negative electrode tabs 22t. These multiple negative electrode tabs 22t are provided in the longitudinal direction L of the negative electrode plate 20 at predetermined intervals.

[0033] For each member constituting the negative electrode plate 20, materials that can be used in conventional general secondary batteries can be used without particular restrictions. For example, a metal material having a predetermined electrical conductivity can be preferably used for the negative electrode core 22. The negative electrode core 22 is preferably made of, for example, copper or a copper alloy. The thickness of the negative electrode core 22 is preferably 2 μm to 30 μm, more preferably 3 μm to 20 μm, and further preferably 5 μm to 15 μm.

[0034] The negative electrode active material layer 24 is a layer containing a negative electrode active material. A material capable of reversibly absorbing and releasing charge carriers in relation to the positive electrode active material is used for the negative electrode active material. Examples of such negative electrode active materials include carbon materials and silicon-based materials. Examples of carbon materials that can be used include graphite, hard carbon, soft carbon, and amorphous carbon. Also, amorphous carbon-coated graphite, in which the surface of graphite is coated with amorphous carbon, can also be used. On the other hand, examples of silicon-based materials include silicon and silicon oxide (silica). Also, the silicon-based material may contain other metal elements (e.g., alkaline earth metals) or their oxides. Also, the negative electrode active material layer 24 may contain additives other than the negative electrode active material. Examples of such additives include binders and thickeners. Specific examples of binders include rubber-based binders such as styrene butadiene rubber (SBR). Also, specific examples of thickeners include carboxymethyl cellulose (CMC). The content of the negative electrode active material is generally 30% by mass or more, typically 50% by mass or more, when the entire solid content of the negative electrode active material layer 24 is taken as 100% by mass. The negative electrode active material may account for 80% by mass or more, or may account for 90% by mass or more of the negative electrode active material layer 24. The thickness of the negative electrode active material layer 24 is preferably 10 μm to 500 μm, more preferably 30 μm to 400 μm, and further preferably 50 μm to 300 μm.

[0035] The negative electrode plate 20 having the above configuration is manufactured by carrying out a precursor preparation step S1, an active material applied region cutting step S2, and a substrate exposed region cutting step S3, as shown in Fig. 1. Each step will be described below.

[0036] (Precursor preparation step S1) In this step, an electrode precursor, which is a precursor of an electrode plate, is prepared. The electrode precursor shown in FIG. 3 is a precursor of a negative electrode plate (negative electrode precursor 20A). This negative electrode precursor 20A includes a negative electrode core 22 that is a strip-shaped metal foil. The area of ​​the negative electrode core 22 of this negative electrode precursor 20A is larger than the area of ​​the manufactured negative electrode plate 20 (see FIG. 2). A negative electrode active material layer 24 is applied to the surface of the negative electrode core 22. The negative electrode active material layer 24 is applied to the center of the negative electrode core 22 in the short side direction S so as to extend along the longitudinal direction L. In this specification, the region to which the negative electrode active material layer 24 is applied is referred to as a "negative electrode active material applied region A1". On the other hand, the negative electrode active material layer 24 is not applied to both side edge portions (regions outside the negative electrode active material layer 24 in the short side direction S) of the negative electrode precursor 20A, and the negative electrode core 22 is exposed. In this specification, the region where the negative electrode core 22 is exposed is referred to as the "negative electrode core exposed region A2". The means for preparing the negative electrode precursor 20A having the above configuration is not particularly limited, and various conventionally known methods can be adopted without particular limitation. For example, the negative electrode precursor 20A can be prepared by applying a raw material paste containing a negative electrode active material and the like to the surface of the negative electrode core 22 and then drying it. In addition, this process is not particularly limited as long as the negative electrode precursor 20A can be prepared. For example, the negative electrode precursor 20A prepared separately may be purchased and prepared. The negative electrode precursor is not limited to the structure shown in FIG. 2. For example, the negative electrode precursor may adopt a structure in which the negative electrode core exposed region is formed only on one side edge portion.

[0037] (Active material application area cutting step S2) In this step, negative electrode active material applied region A1 of negative electrode precursor 20A is cut by a pulse laser. N1 As shown in FIG. 1, the pulsed laser is scanned on the negative electrode active material applied region A1 along the side edge portion A1a of the negative electrode active material applied region A1. This allows the side edge portion A1a of the negative electrode active material applied region A1, where the thickness of the negative electrode active material layer 24 is not uniform, to be cut off, and the negative electrode plate 20 with the negative electrode active material layer 24 having a uniform thickness can be produced. N1As shown in FIG. 1, when the negative electrode active material applied region A1 is cut with a laser, a part of the negative electrode core 22 melted by the heat of the laser may be mixed into the negative electrode active material layer 24. When the molten metal solidifies in the negative electrode active material layer 24, the adhesion of the negative electrode active material layer 24 is significantly lost, and there is a risk that fragments of the negative electrode active material layer 24 may easily fall off or peel off with a slight impact. In the active material applied region cutting step S2 in this embodiment, a pulsed laser is used when cutting the negative electrode active material applied region A1 in order to prevent a decrease in adhesion due to the inclusion of the molten metal. Such a pulsed laser can apply a large amount of energy in a short time width in a concentrated manner (high peak output), so that the negative electrode core 22 can be quickly cut with a small amount of melting. This makes it possible to suppress a decrease in adhesion of the negative electrode active material layer 24 due to the inclusion of the molten metal, and therefore to prevent the fragments of the negative electrode active material layer 24 from falling off or peeling off.

[0038] The conditions of the pulse laser in the active material-applied region cutting step S2 are not particularly limited, and are preferably adjusted appropriately according to the structure of negative electrode precursor 20A (typically, the thickness and material of negative electrode active material layer 24 and negative electrode core 22). For example, the average output of the pulse laser in this step is preferably 70 W to 1000 W, more preferably 100 W to 900 W, and even more preferably 150 W to 800 W. This makes it possible to easily cut negative electrode precursor 20A while preventing negative electrode active material layer 24 from falling off or peeling off. Specifically, as the average output of the pulse laser increases, negative electrode precursor 20A tends to be cut more easily. On the other hand, as the average output of the pulse laser decreases, the impact during laser irradiation decreases, and therefore it is possible to prevent a part of negative electrode active material layer 24 from being blown away by the impact of the laser.

[0039] Moreover, the repetition frequency of the pulse laser in the active material applied region cutting step S2 is preferably 100KHz to 2000KHz, more preferably 150KHz to 1500KHz, and even more preferably 200KHz to 1000KHz. This makes it possible to easily cut the negative electrode precursor 20A while preventing the molten negative electrode core 22 from being mixed into the negative electrode active material layer 24. Specifically, when the frequency of the pulse laser is low, the peak output is high, making it easy to cut the negative electrode core 22. On the other hand, when the frequency of the pulse laser is high, the peak output is low, making it possible to prevent a part of the negative electrode active material layer 24 irradiated with the laser from being blown away. Moreover, the spot diameter of the pulse laser in the active material applied region cutting step S2 is preferably 10μm to 60μm, more preferably 20μm to 50μm, and even more preferably 25μm to 40μm. This makes it possible to easily cut out the negative electrode plate 20 from the negative electrode precursor 20A.

[0040] Furthermore, the overlap ratio of the pulsed laser in the active material applied region cutting step S2 is preferably smaller than the overlap ratio of the pulsed laser in the core exposed region cutting step S3 described later. As the overlap ratio of the pulsed laser is reduced, the negative electrode core 22 tends to be cut more easily with a smaller amount of melting. On the other hand, as the overlap ratio is increased, the state of the pulsed laser approaches that of a CW laser, and the occurrence of spattering described later tends to be more easily suppressed. For this reason, in the active material applied region cutting step S2, where the inclusion of the molten negative electrode core 22 is likely to be a problem, it is preferable to use a pulsed laser with a small overlap ratio. The specific overlap ratio of the pulsed laser in the active material applied region cutting step S2 is preferably 40% to 95%, more preferably 50% to 90%, and even more preferably 70% to 90%.

[0041] Next, the scanning speed of the pulse laser in the active material applied region cutting step S2 is preferably 5000 mm / sec or less, more preferably 3000 mm / sec or less. By slowing down the scanning speed in this way, it is possible to suppress poor cutting of the negative electrode core 22. On the other hand, the lower limit of the scanning speed of the pulse laser is not particularly limited and may be 20 mm / sec or more. From the viewpoint of improving manufacturing efficiency by shortening the cutting time, the lower limit of the scanning speed of the pulse laser is preferably 200 mm / sec or more, more preferably 500 mm / sec or more. Moreover, the pulse width of the pulse laser in the active material applied region cutting step S2 is preferably 30 ns to 240 ns, more preferably 60 ns to 120 ns. This makes it possible to more suitably prevent the melted negative electrode core 22 from being mixed into the negative electrode active material layer 24. Specifically, since the peak output tends to improve as the pulse width of the pulse laser becomes shorter, it is easier to reduce the amount of melting of the negative electrode core 22 during laser cutting. On the other hand, as the pulse width becomes longer, the impact on the negative electrode active material layer 24 becomes smaller, so that it is possible to prevent a part of the negative electrode active material layer 24 from being blown away during laser irradiation.

[0042] (Core exposed area cutting step S3) In this step, negative electrode core exposed region A2 of negative electrode precursor 20A is cut with a pulse laser. Specifically, in core exposed region cutting step S3, first, a pulse laser is used to cut the negative electrode core exposed region A2 along dotted line L in FIG. N2 As shown in FIG. 3, a pulsed laser is scanned along the short side direction S of the negative electrode precursor 20A from the negative electrode active material applied region A1 toward the negative electrode core exposed region A2. Thereafter, the pulsed laser is scanned a certain distance along the longitudinal direction L of the negative electrode precursor 20A, and then the pulsed laser is scanned again along the short side direction S toward the negative electrode active material applied region A1. As a result, a part of the negative electrode core exposed region A2 is cut out in a convex shape to form the negative electrode tab 22t (see FIG. 2). Then, in this embodiment, an active material applied region cutting step S2 (along the dotted line L in FIG. 3) is performed. N1 ), and a core-exposed region cutting process S3 (dotted line L in FIG. 3 ). N2) is repeated at regular intervals. This makes it possible to cut out the side edge portion A1a of the negative electrode active material-applied region A1 and to cut out a plurality of negative electrode tabs 22t.

[0043] In the electrode plate manufacturing method according to this embodiment, the pulsed laser irradiated to the negative electrode substrate exposed region A2 in the substrate exposed region cutting step S3 is controlled so as to satisfy the following formula (1): "X" in the following formula (1) is the pulse width (ns) of the pulsed laser, and "Y" is the overlap rate (%) of the pulsed laser. Y≧-3logX+106 (1)

[0044] In the manufacturing method according to the present embodiment, the negative electrode core exposed region A2 is cut using a pulsed laser that satisfies the above formula (1). As a result, even though a pulsed laser is used, the negative electrode core exposed region A2 can be melted and cut like a CW laser, so that scattering of spatter can be suppressed. Specifically, as the wrap rate of the pulsed laser increases, the laser irradiation approaches continuous irradiation, so that spatter tends to be less likely to occur. On the other hand, the degree of spatter generation when a metal member is irradiated with a pulsed laser is affected not only by the wrap rate but also by the length of the pulse width. Specifically, as the pulse width of the pulsed laser increases, the heat-affected time applied to the metal member increases, and the molten part spreads, so that spatter tends to be less likely to occur. That is, when cutting the negative electrode core exposed region A2 using a pulsed laser, it is preferable to increase the wrap rate and increase the pulse width. As a result, the state of the pulsed laser can be brought closer to that of a CW laser, so that spatter generation can be suppressed. The above formula (1) represents the pulse laser irradiation conditions (relationship between overlap rate and pulse width) that can sufficiently suppress the occurrence of sputtering, which the inventor discovered as a result of repeated experiments based on this knowledge (see Figure 21).

[0045] As shown in FIG. 4, in laser cutting using a pulsed laser, multiple spots R1 and R2 are irradiated while being shifted little by little toward a predetermined scanning direction D. This results in an overlapping irradiation area A3 where adjacent spots R1 and R2 are irradiated while overlapping, and a single irradiation area A4 where single spots R1 and R2 are irradiated. The "wrap ratio" in this specification is a value indicating the degree to which adjacent spots R1 and R2 overlap in the irradiation of the pulsed laser. The wrap ratio Y can be calculated based on the following formula (2) when the spot diameter is W1 and the irradiation interval between adjacent spots is W2. The spot diameter W1 and the irradiation interval W2 are both lengths in the direction along the scanning direction D of the pulsed laser. That is, when elliptical spots R1 and R2 as shown in FIG. 4 are irradiated, the spot diameter W1 refers to the diameter of the spots R1 and R2 along the scanning direction D. When elliptical spots are irradiated, each spot may be inclined with respect to the scanning direction D. Even in this case, the length along the scanning direction D is measured as the spot diameter W1 and irradiation interval W2 of each spot. Note that the specific spot diameter W1 of the pulsed laser in the core exposed region cutting step S3 is preferably 10 μm to 60 μm, more preferably 20 μm to 50 μm, and further preferably 25 μm to 40 μm. Wrap ratio Y(%)=(W1-W2) / W1×100 (2)

[0046] As described above, in the manufacturing method according to the present embodiment, various conditions are adjusted so that the overlap ratio Y of the pulsed laser in the core exposed region cutting step S3 satisfies the condition of -3logX+106 or more. This can suppress the scattering of spatter when cutting the negative electrode core exposed region A2. At this time, if the overlap ratio Y is large, the scattering of spatter can be further preferably suppressed. From this viewpoint, it is more preferable that the overlap ratio Y of the pulsed laser in the core exposed region cutting step S3 is controlled to be -3logX+107 or more. On the other hand, the upper limit of the overlap ratio Y of the pulsed laser in the core exposed region cutting step S3 is not particularly limited and may be 99% or less. However, as the overlap ratio Y decreases, the scanning speed of the pulsed laser tends to be increased, and therefore the manufacturing efficiency tends to improve. From this viewpoint, it is preferable that the overlap ratio Y of the pulsed laser in the core exposed region cutting step S3 is controlled to be -3logX+109 or less (more preferably -3logX+108 or less).

[0047] The pulsed laser in the core exposed region cutting step S3 only needs to satisfy the above formula (1), and other conditions are not particularly limited. For example, it is preferable to appropriately adjust other conditions of the pulsed laser in the core exposed region cutting step S3 according to the structure of the negative electrode core exposed region A2 (typically, the thickness and material of the negative electrode core 22). For example, the pulse width X constituting the above formula (1) may be 10 ns to 300 ns, 30 ns to 240 ns, or 120 ns to 240 ns. As shown in formula (1) and FIG. 21, in the core exposed region cutting step S3, it is required to increase the overlap ratio Y as the pulse width X is reduced.

[0048] The average output of the pulsed laser in the core exposed region cutting step S3 may be 70 W to 2000 W, 100 W to 1800 W, or 200 W to 1500 W. As the average output of the pulsed laser increases, the cutting of the negative electrode core exposed region A2 tends to become easier. On the other hand, as the average output of the pulsed laser decreases, the impact during laser irradiation decreases, so that scattering of spatters tends to occur less easily.

[0049] Furthermore, the repetition frequency of the pulsed laser in the core exposed region cutting step S3 may be 400KHz to 4000KHz, 1000KHz to 3500KHz, or 2000KHz to 3000KHz. As the frequency of the pulsed laser decreases, the peak output increases, which tends to facilitate cutting of the negative electrode core 22. On the other hand, as the frequency of the pulsed laser increases, scattering of sputters tends to be less likely to occur.

[0050] Next, the scanning speed of the pulsed laser in the core exposed region cutting step S3 is preferably 5000 mm / sec or less, more preferably 3000 mm / sec or less. As the scanning speed is slowed, there is a tendency that poor cutting of the negative electrode core 22 is less likely to occur. On the other hand, the lower limit of the scanning speed of the pulsed laser is not particularly limited, and may be 20 mm / sec or more. From the viewpoint of improving manufacturing efficiency by shortening the cutting time, the lower limit of the scanning speed of the pulsed laser is preferably 200 mm / sec or more, more preferably 500 mm / sec or more. The scanning speed of the pulsed laser may be approximately the same in the active material applied region cutting step S2 and the core exposed region cutting step S3.

[0051] (Other processes) As described above, in the manufacturing method according to the present embodiment, the active material application region cutting step S2 (dotted line L in FIG. 3) N1 ), and a core-exposed region cutting process S3 (dotted line L in FIG. 3 ). N2 3 ) is repeated at regular intervals to cut off the side edge portion A1a of the negative electrode active material application region A1, where the thickness of the negative electrode active material layer 24 is likely to become non-uniform, and to form a plurality of negative electrode tabs 22t. N3 As shown in FIG. 2, the center of the negative electrode precursor 20A in the short-side direction S is cut along the long-side direction L. This makes it possible to produce a negative electrode plate 20 in which a negative electrode tab 22t is formed only on one side of the outer peripheral edge portion 20b1 of the electrode plate main body portion 20b, as shown in FIG. 2. N4As shown in FIG. 1, negative electrode precursor 20A is cut in short direction S at a predetermined interval in length direction L. This allows negative electrode plate 20 of a desired length to be manufactured. N3 , L N4 The cutting of negative electrode precursor 20A along the two-dot chain line L may not necessarily involve laser cutting, and may involve the use of a cutting blade, a mold, a cutter, or the like. N3 , L N4 When laser cutting is used for cutting along the dotted line L, N1 It is preferable to use a pulse laser having the same conditions as those of the two-dot chain line L. This makes it possible to more suitably prevent the fragments of the negative electrode active material layer 24 from peeling off or falling off. N3 , L N4 The cutting along the line may be appropriately performed according to the shape of the negative electrode plate after production, and is not limited to the technology disclosed herein.

[0052] As described above, in the method for producing an electrode plate according to this embodiment, when cutting the negative electrode active material application region A1 (dotted line L N1A pulsed laser is used for cutting the negative electrode active material layer 24 (see FIG. 1). This can prevent the molten metal from mixing with the negative electrode active material layer 24 and reducing the adhesion of the negative electrode active material layer 24, and therefore can prevent fragments of the negative electrode active material layer 24 from falling off and peeling off from the negative electrode plate 20 after production. On the other hand, in the production method according to the present embodiment, a pulsed laser is also used when cutting the negative electrode core exposed region A2, and the negative electrode active material applied region A1 and the negative electrode core exposed region A2 are cut continuously. This can prevent a significant decrease in production efficiency and cutting defects caused by switching the type of laser. In this embodiment, the pulsed laser when cutting the negative electrode core exposed region A2 is controlled to satisfy the conditions specified in the above formula (1). This can increase the melting amount of the electrode core when cutting the negative electrode core exposed region A2 with a pulsed laser to the same level as that of a CW laser, and therefore can prevent the scattering of spatter. As a result, it is possible to prevent fine metal pieces from falling off and peeling off from the negative electrode plate 20 after production. As described above, according to this embodiment, it is possible to prevent conductive foreign matter from falling off or peeling off from the negative electrode plate 20 after manufacture, which can contribute to improving the safety of secondary batteries.

[0053] <Negative electrode plate> Next, a detailed structure of the electrode plate (negative electrode plate 20) manufactured by the electrode plate manufacturing method according to this embodiment will be described.

[0054] (Outline of negative plate) 2, the negative electrode plate 20 according to this embodiment includes a negative electrode core 22 and a negative electrode active material layer 24. The negative electrode plate 20 also includes an electrode plate main body 20b, which is a region where the negative electrode active material layer 24 is applied to the surface of the negative electrode core 22, and a negative electrode tab 22t, which is a region where the negative electrode active material layer 24 is not applied and where the negative electrode core 22 is exposed. These have already been described, so duplicated description will be omitted.

[0055] (1st thick part) As shown in FIG. 5, the negative electrode plate 20 according to this embodiment has a first thick portion 23 formed on the outer peripheral edge portion 22t1 of the negative electrode tab 22t, the first thick portion 23 being thicker than the central portion 22t2 of the negative electrode tab 22t. The first thick portion 23 is a mark of laser cutting in the above-mentioned core exposed region cutting step S3. Specifically, in the manufacturing method of the electrode plate according to this embodiment, as described above, in order to suppress scattering of spatter, the state of the pulsed laser when cutting the negative electrode core exposed region A2 (see FIG. 3) is made to be similar to that of a CW laser. In the outer peripheral edge portion 22t1 of the negative electrode tab 22t cut by such a pulsed laser, a first thick portion 23 is formed that is a mark of melting and cutting the metal foil, and has a cross section that is close to a circular shape, as in the case of cutting by a CW laser. Note that the "circular cross section" here means that the aspect ratio of the first thick portion 23 in the cross section along the thickness direction T of the negative electrode tab 22t as shown in FIG. 5 is 0.85 or more. The aspect ratio of the first thick portion 23 is calculated based on a cross-sectional photograph (see FIG. 15) of the electrode tab obtained using a scanning electron microscope (SEM). A specific calculation method for the aspect ratio of the first thick portion 23 is as follows. First, a cross-sectional photograph of the negative electrode tab as shown in FIG. 15 is obtained. Next, in this cross-sectional photograph, the first thick portion is surrounded by a rectangle having two sides along the surface of the negative electrode core body. Then, the long side and the short side of the rectangle surrounding the first thick portion are measured, and the value obtained by dividing the long side by the short side (short side / long side) is taken as the aspect ratio. Note that the "aspect ratio" in this specification is the average value of the aspect ratios of the first thick portion confirmed in multiple visual fields (typically one or more visual fields). Note that the cross-sectional shape of the first thick portion is not limited to a circle or an ellipse, and may be partially chipped or distorted. Even in the case of a first thick portion having such chips or distortions, the aspect ratio can be calculated according to the above-mentioned procedure.

[0056] In addition, when the cross-sectional shape of the first thick portion 23 approaches a circle, when the outer peripheral edge portion 22t1 of the negative electrode tab 22t contacts another member (for example, the separator 30 shown in FIG. 13), the other member can be prevented from being damaged. For this reason, the aspect ratio of the first thick portion 23 is preferably 0.88 or more, more preferably 0.90 or more. On the other hand, the upper limit of the aspect ratio of the first thick portion 23 is not particularly limited, and may be 1.00 or less. In addition, the first thick portion 23 may be thicker than the central portion 22t2 of the negative electrode tab 22t, and the specific thickness of the first thick portion 23 is not particularly limited. For example, the ratio (t1 / t2) of the thickness t1 of the first thick portion 23 to the thickness t2 of the central portion 22t2 may be 1.1 or more, 1.2 or more, 1.4 or more, or 1.5 or more. On the other hand, the upper limit of the above t1 / t2 may be 7 or less, 6 or less, 5 or less, or 3 or less.

[0057] In the manufacturing method of the electrode plate according to the present embodiment, as described above, the pulse laser conditions when cutting the negative electrode core exposed region A2 (see FIG. 3) are controlled to satisfy the above formula (1). When the negative electrode core exposed region A2 is melted and cut with such a pulse laser with a high overlap ratio, the molten electrode core is deformed into a substantially spherical shape due to surface tension, and therefore, areas where the molten metal is concentrated and areas where the molten metal is sparse are formed alternately. For this reason, a first region having a relatively large thickness and a second region having a relatively small thickness may be formed alternately in the outer peripheral edge portion 22t1 of the negative electrode tab 22t of the negative electrode plate 20 according to the present embodiment.

[0058] In addition, when the negative electrode core exposed region A2 is cut using a pulsed laser, the negative electrode tab 22t and the negative electrode core exposed region A2 can be separated at the time of laser irradiation, so there is no need to perform a process of peeling off the negative electrode tab 22t from the negative electrode core exposed region A2 as in the case of using a CW laser. As a result, in the manufactured negative electrode plate 20, unlike the cut marks (see FIG. 19) formed by the CW laser, the center point C of the first thick portion 23 is likely to be located between a pair of extension lines E1 and E2 extending from each surface (upper surface and lower surface) of the central portion 22t2 of the negative electrode tab 22t. When the center point C of the first thick portion 23 is located near the center in the thickness direction of the negative electrode tab 22t in this way, the bending process of the negative electrode tab 22t is facilitated, which can contribute to improving the manufacturing efficiency of the secondary battery.

[0059] (2nd thick part) On the other hand, as shown in FIG. 6, in this embodiment, a second thick portion 25 thicker than the negative electrode core 22 in the central portion 20b2 of the electrode plate main body portion 20b is formed at the end of the negative electrode core 22 in the outer peripheral edge portion 20b1 of the electrode plate main body portion 20b. The second thick portion 25 is a trace of the negative electrode active material applied region A1 of the negative electrode precursor 20A being irradiated with a pulse laser in the active material applied region cutting step S2. The second thick portion 25 is formed by cutting the negative electrode core 22 with a high-energy pulse laser. In addition, a coating layer 25b is attached to the surface of the second thick portion 25. The coating layer 25b is the negative electrode active material layer 24 after being irradiated with the pulse laser, and contains the negative electrode active material. The negative electrode active material layer 24 may also contain a sintered product such as the negative electrode active material. Then, as shown in FIG. 6, the thickness of the coating layer 25b is thinner than the thickness of the negative electrode active material layer 24. The coating layer 25b has superior adhesion to the surface of the negative electrode core 22 (second thick portion 25) compared to the negative electrode active material layer containing molten metal, and therefore can suitably prevent the peeling and falling off of conductive foreign matter. The second thick portion 25 and coating layer 25b described above may be formed on at least one side of the outer circumferential edge portion (see FIG. 2) of the electrode plate main body portion 20b. Specifically, in this embodiment, the outer circumferential edge portion 20b1 of the electrode plate main body portion 20b located between the negative electrode tabs 22t is cut by a pulse laser, and therefore the second thick portion 25 and coating layer 25b are formed in the region between the negative electrode tabs 22t.

[0060] The second thick portion 25 has a claw shape including a cap portion 25a1 protruding on both sides or one side of the thickness direction T of the negative electrode core 22 and a recessed portion 25a2 formed between the cap portion 25a1 and the negative electrode core 22. Unlike the first thick portion 23 described above, the second thick portion 25 is formed by a pulse laser with a high output, so that the amount of melting of the negative electrode core 22 is small, and the claw shape described above may be formed. The coating layer 25b enters the inside of the recessed portion 25a2 of the claw-shaped second thick portion 25. This provides an excellent anchor effect, so that the coating layer 25b is held more firmly, and the falling off and peeling of the fragments of the negative electrode active material layer 24 can be more suitably prevented. If such a claw-shaped second thick portion 25 is formed, it may cause damage to other members (for example, a separator of a secondary battery). However, in this embodiment, since the second thick portion 25 is covered with the covering layer 25b, it is possible to suitably prevent other members from being damaged by the claw-shaped second thick portion 25. From the viewpoint of more suitably preventing damage to other members by the second thick portion 25, the thickness of the covering layer 25b attached to the surface of the second thick portion 25 is preferably 1 μm or more, more preferably 2.5 μm or more, and even more preferably 5 μm or more. On the other hand, the upper limit of the thickness of the covering layer 25b is not particularly limited, and may be 20 μm or less, 17.5 μm or less, or 15 μm or less.

[0061] The thickness of the cap portion 25a1 of the second thick portion 25 is preferably 1 μm or more, more preferably 2.5 μm or more, and even more preferably 4 μm or more. This allows a more suitable anchoring effect to be exhibited. The "cap thickness" refers to the thickness of one side of the cap portion 25a1 based on the surface of the core body. From the viewpoint of more reliably preventing damage to other members, the upper limit of the thickness of the cap portion 25a1 is preferably 30 μm or less, more preferably 25 μm or less, and even more preferably 20 μm or less. On the other hand, the width of the cap portion 25a1 (the dimension in the short-side direction S of the negative electrode plate) is not particularly limited. For example, the width of the cap portion 25a1 may be 1 μm to 30 μm, 5 μm to 25 μm, or 10 μm to 20 μm. Furthermore, the height (dimension in the thickness direction T) of the inlet of the recess 25a2 of the second thick portion 25 is preferably 1 μm to 10 μm, more preferably 2.5 μm to 7.5 μm. Meanwhile, the depth (dimension in the short-side direction S of the negative electrode plate) of the recess 25a2 of the second thick portion 25 is preferably 0.1 to 10 μm, more preferably 2.5 μm to 7.5 μm. This allows an appropriate amount of the coating layer 25b to be held inside the recess 25a2, and a more suitable anchor effect can be exhibited. Furthermore, the angle at which the cap portion 25a1 rises from the surface of the negative electrode core 22 is preferably more than 0° and not more than 90°.

[0062] The aspect ratio of the second thick portion 25 may be smaller than that of the first thick portion 23. As described above, the second thick portion 25 is a cut mark formed by a high-energy pulse laser, and therefore, unlike the first thick portion 23, the cross-sectional shape is unlikely to be substantially circular. Specifically, the upper limit of the aspect ratio of the second thick portion 25 may be 0.85 or less (typically 0.82 or less, for example 0.80 or less). On the other hand, the lower limit of the aspect ratio of the second thick portion 25 may be 0.40 or more (typically 0.45 or more, for example 0.50 or more). The aspect ratio of the second thick portion can be measured according to the same procedure as that of the aspect ratio of the first thick portion described above.

[0063] <Secondary battery> Next, a secondary battery produced using the negative electrode plate 20 according to this embodiment will be described. FIG. 7 is a perspective view showing the secondary battery according to this embodiment. FIG. 8 is a schematic longitudinal sectional view taken along line VIII-VIII in FIG. 7. FIG. 9 is a schematic longitudinal sectional view taken along line IX-IX in FIG. 7. FIG. 10 is a schematic transverse sectional view taken along line XX in FIG. 7. FIG. 11 is a perspective view showing the electrode body attached to the sealing plate. FIG. 12 is a perspective view showing the electrode body to which the positive electrode second current collector and the negative electrode second current collector are attached. FIG. 13 is a perspective view showing the electrode body of the secondary battery according to this embodiment. FIG. 14 is a front view of the electrode body of the secondary battery according to this embodiment. In addition, the symbol X in FIGS. 7 to 14 indicates the "thickness direction" of the secondary battery 100, the symbol Y indicates the "width direction", and the symbol Z indicates the "up-down direction". In addition, F in the thickness direction X indicates the "front", and Rr indicates the "rear". In the width direction Y, L indicates "left" and R indicates "right." In the vertical direction Z, U indicates "up" and "D" indicates "down." However, these directions are defined for the convenience of explanation and are not intended to limit the installation form of the secondary battery 100.

[0064] As shown in Figs. 7 to 10, the secondary battery 100 includes a wound electrode assembly 40, a battery case 50, a positive electrode terminal 60, a negative electrode terminal 65, a positive electrode current collector 70, and a negative electrode current collector 75. Although not shown, the battery case 50 of the secondary battery 100 also contains a non-aqueous electrolyte in addition to the wound electrode assembly 40. The non-aqueous electrolyte is prepared by dissolving a supporting salt in a non-aqueous solvent. Examples of the non-aqueous solvent include carbonate-based solvents such as ethylene carbonate, dimethyl carbonate, and ethyl methyl carbonate. Examples of the supporting salt include fluorine-containing lithium salts such as LiPF6.

[0065] (Battery case) The battery case 50 is a housing that houses the wound electrode body 40. Here, the battery case 50 has a flat, bottomed rectangular parallelepiped (rectangular) outer shape. The material of the battery case 50 may be the same as that conventionally used, and is not particularly limited. The battery case 50 is preferably made of metal, and more preferably made of, for example, aluminum, an aluminum alloy, iron, an iron alloy, or the like. The battery case 50 includes an exterior body 52 and a sealing plate 54.

[0066] The exterior body 52 is a flat, bottomed, rectangular container having an opening 52h on the upper surface. As shown in FIG. 7, the exterior body 52 includes a bottom wall 52a having a substantially rectangular shape in plan view, a pair of long side walls 52b extending in the vertical direction Z from the long side of the bottom wall 52a, and a pair of short side walls 52c extending in the vertical direction Z from the short side of the bottom wall 52a. On the other hand, the sealing plate 54 is a substantially rectangular plate-like member in plan view that closes the opening 52h of the exterior body 52. ​​The outer peripheral edge of the sealing plate 54 is joined (for example, welded) to the outer peripheral edge of the opening 52h of the exterior body 52. ​​This produces a battery case 50 whose inside is hermetically sealed (closed). The sealing plate 54 is also provided with a liquid injection hole 55 and a gas exhaust valve 57. The liquid injection hole 55 is provided for injecting a nonaqueous electrolyte into the battery case 50 after the exterior body 52 and the sealing plate 54 are joined together. After the nonaqueous electrolyte is injected, the liquid injection hole 55 is sealed with a sealing member 56. The gas exhaust valve 57 is a thin-walled portion designed to break (open) at a predetermined pressure to exhaust the gas inside the battery case 50 when a large amount of gas is generated inside the battery case 50.

[0067] (electrode terminal) A positive electrode terminal 60 is attached to one end (left side in Fig. 7 and Fig. 8) of the sealing plate 54 in the long side direction Y of the secondary battery 100. The positive electrode terminal 60 is connected to a plate-shaped positive electrode external conductive member 62 on the outside of the battery case 50. Meanwhile, a negative electrode terminal 65 is attached to the other end (right side in Fig. 7 and Fig. 8) of the sealing plate 54 in the long side direction Y of the secondary battery 100. A plate-shaped negative electrode external conductive member 67 is also attached to the negative electrode terminal 65. These external conductive members (positive electrode external conductive member 62 and negative electrode external conductive member 67) are connected to other secondary batteries and external devices via external connection members (bus bars, etc.). The external conductive members are preferably made of a metal with excellent conductivity (aluminum, aluminum alloy, copper, copper alloy, etc.).

[0068] (Electrode current collector) In the secondary battery 100, a plurality of (three in the figure) wound electrode bodies 40 are housed inside the battery case 50. The positive electrode terminal 60 is connected to each of the plurality of wound electrode bodies 40 via a positive electrode current collector 70 housed in the battery case 50. Specifically, the positive electrode current collector 70 that connects the positive electrode terminal 60 and the wound electrode body 40 is housed inside the battery case 50. As shown in FIGS. 8 and 11, the positive electrode current collector 70 includes a positive electrode first current collector 71 that is a plate-shaped conductive member extending along the inner side surface of the sealing plate 54, and a plurality of positive electrode second current collectors 72 that are plate-shaped conductive members extending along the up-down direction Z. The lower end 60c of the positive electrode terminal 60 extends toward the inside of the battery case 50 through the terminal insertion hole 58 of the sealing plate 54 and is connected to the positive electrode first current collector 71 (see FIG. 8). 11 and 12, the positive electrode second current collecting portion 72 is connected to each positive electrode tab group 42 of the multiple wound electrode bodies 40. Then, as shown in Fig. 10, the positive electrode tab group 42 of the wound electrode body 40 is bent so that the positive electrode second current collecting portion 72 and one side surface 40a of the wound electrode body 40 face each other. This electrically connects the upper end portion of the positive electrode second current collecting portion 72 and the positive electrode first current collecting portion 71.

[0069] On the other hand, the negative electrode terminal 65 is connected to each of the plurality of wound electrode bodies 40 via a negative electrode current collector 75 housed in the battery case 50. The connection structure on the negative electrode side is substantially the same as the connection structure on the positive electrode side described above. Specifically, the negative electrode current collector 75 includes a negative electrode first current collector 76 which is a plate-shaped conductive member extending along the inner side surface of the sealing plate 54, and a plurality of negative electrode second current collectors 77 which are plate-shaped conductive members extending along the up-down direction Z. The lower end 65c of the negative electrode terminal 65 extends into the battery case 50 through the terminal insertion hole 59 and is connected to the negative electrode first current collector 76 (see FIG. 8). The negative electrode second current collector 77 is connected to each of the negative electrode tab groups 44 of the plurality of wound electrode bodies 40 (see FIGS. 11 and 12). The negative electrode tab group 44 is bent so that the negative electrode second current collecting portion 77 faces the other side surface 40b of the wound electrode body 40 (see FIG. 10). This electrically connects the upper end portion of the negative electrode second current collecting portion 77 to the negative electrode first current collecting portion 76.

[0070] (Insulating material) In addition, in the secondary battery 100 according to this embodiment, various insulating members are attached to prevent electrical conduction between the wound electrode body 40 and the battery case 50. Specifically, an external insulating member 92 is interposed between the positive electrode external conductive member 62 (negative electrode external conductive member 67) and the outer surface of the sealing plate 54 (see FIG. 7). This can prevent the positive electrode external conductive member 62 and the negative electrode external conductive member 67 from being electrically connected to the sealing plate 54. Also, a gasket 90 is attached to each of the terminal insertion holes 58, 59 of the sealing plate 54 (see FIG. 8). This can prevent the positive electrode terminal 60 (or the negative electrode terminal 65) inserted into the terminal insertion holes 58, 59 from being electrically connected to the sealing plate 54. Also, an internal insulating member 94 is disposed between the positive electrode first current collecting portion 71 (or the negative electrode first current collecting portion 76) and the inner surface of the sealing plate 54. The internal insulating member 94 includes a plate-shaped base portion 94a interposed between the positive electrode first current collecting portion 71 (or the negative electrode first current collecting portion 76) and the inner surface of the sealing plate 54. This can prevent the positive electrode first current collecting portion 71 and the negative electrode first current collecting portion 76 from being electrically connected to the sealing plate 54. Furthermore, the internal insulating member 94 includes a protruding portion 94b protruding from the inner surface of the sealing plate 54 toward the wound electrode body 40. This can restrict the movement of the wound electrode body 40 in the vertical direction Z, and can prevent the wound electrode body 40 and the sealing plate 54 from coming into direct contact with each other. In addition, the wound electrode body 40 is accommodated inside the battery case 50 while being covered with an electrode body holder 98 (see FIG. 9) made of an insulating resin sheet. This can prevent the wound electrode body 40 and the exterior body 52 from coming into direct contact with each other. The material of each of the insulating members described above is not particularly limited as long as it has a predetermined insulating property. For example, synthetic resin materials such as polyolefin resin (e.g., polypropylene (PP), polyethylene (PE)), fluorine resin (e.g., perfluoroalkoxyalkane (PFA), polytetrafluoroethylene (PTFE)) can be used.

[0071] (Wound electrode body) Next, an electrode body used in the secondary battery 100 according to this embodiment will be described. In this embodiment, a wound electrode body 40 having a configuration shown in FIG. 13 is used as the electrode body. The wound electrode body 40 is wound in a state in which a pair of electrode plates (positive electrode plate 10, negative electrode plate 20) face each other via a separator 30. When producing this wound electrode body 40, first, a laminate is formed by laminating a long strip-shaped positive electrode plate 10 and a long strip-shaped negative electrode plate 20 with a long strip-shaped separator 30 interposed therebetween. Then, after this laminate is wound in the longitudinal direction, a stop tape 38 (see FIG. 14) is attached to the end portion 30a of the separator 30 arranged on the outermost periphery. This allows the wound electrode body 40 to be produced. In this embodiment, the negative electrode plate 20 having the above structure is used in producing this wound electrode body 40. Hereinafter, the wound electrode body 40 in this embodiment will be described.

[0072] First, the separator 30 is a sheet-like member having a function of preventing contact between the positive electrode plate 10 and the negative electrode plate 20 and allowing charge carriers to pass through. An example of such a separator 30 is a resin sheet having a plurality of fine holes formed therein through which charge carriers can pass. Such a resin sheet preferably includes a resin layer made of a polyolefin resin (e.g., polyethylene (PE), polypropylene (PP)). In addition, a heat-resistant layer containing an inorganic filler such as alumina, boehmite, aluminum hydroxide, or titania may be formed on the surface of the resin sheet.

[0073] The positive electrode plate 10 includes a positive electrode core 12, which is a foil-shaped metal member, a positive electrode active material layer 14 provided on the surface of the positive electrode core 12, and a protective layer 16 provided on the surface of the positive electrode core 12 so as to be adjacent to the side edge portion 10a of the positive electrode plate 10. Furthermore, on the side edge portion 10a of the positive electrode plate 10, a plurality of positive electrode tabs 12t protruding toward the outside in the short direction S (the left side in FIG. 13) are provided at predetermined intervals in the longitudinal direction L of the positive electrode plate 10. The positive electrode tabs 12t are not provided with the positive electrode active material layer 14 or the protective layer 16, and are an area where the positive electrode core 12 is exposed. From the viewpoint of battery performance, it is preferable that the positive electrode active material layer 14 and the protective layer 16 are provided on both sides of the positive electrode core 12. In addition, the protective layer 16 may be provided so that a part of it covers the side edge portion of the positive electrode active material layer 14. The materials for each component (positive electrode core 12, positive electrode active material layer 14, protective layer 16) constituting the positive electrode plate 10 can be any conventionally known material that can be used in general secondary batteries (e.g., lithium ion secondary batteries) without any particular restrictions, and detailed explanations are omitted as they do not limit the technology disclosed herein.

[0074] Meanwhile, the configuration of the negative electrode plate 20 used in the secondary battery 100 according to this embodiment is as described above. In the negative electrode plate 20, a pulse laser is used when cutting out the plate body portion 20b from the negative electrode active material application region A1 (see FIG. 3) of the negative electrode precursor 20A. Therefore, in the negative electrode plate 20 according to this embodiment, the adhesion of the negative electrode active material layer 24 is suppressed due to the inclusion of molten metal. As a result, after the secondary battery 100 is constructed, it is possible to prevent the fragments of the negative electrode active material layer 24 from falling off and peeling off, which may cause an internal short circuit. Furthermore, in the negative electrode plate 20, a pulse laser similar to a CW laser is used when cutting out the negative electrode tab 22t from the negative electrode core exposed region A2 (see FIG. 3) of the negative electrode precursor 20A. Therefore, in the negative electrode plate 20 according to this embodiment, the adhesion of fine metal pieces (spatter) is suppressed. As a result, it is possible to prevent the spatter from falling off and peeling off, which may cause an internal short circuit, after the secondary battery 100 is constructed. That is, in the secondary battery 100 according to this embodiment, various conductive foreign objects are prevented from falling off or peeling off from the negative electrode plate 20, and therefore, the secondary battery 100 has a high level of safety.

[0075] <Other embodiments> An embodiment of the technology disclosed herein has been described above. Note that the above embodiment shows an example to which the technology disclosed herein is applied, and does not limit the technology disclosed herein.

[0076] For example, in the above-mentioned embodiment, the manufacturing target of the electrode plate manufacturing method disclosed herein is a negative electrode plate. However, the manufacturing target of the electrode plate manufacturing method disclosed herein is not limited to a negative electrode plate, and may be a positive electrode plate. Even when the manufacturing target is such a positive electrode plate, it is possible to prevent conductive foreign matter (fragments or spatters of the positive electrode active material layer) from falling off or peeling off from the manufactured electrode plate (positive electrode plate). In addition, the negative electrode plate manufactured in the above-mentioned embodiment is more likely to have a decrease in adhesion of the electrode active material layer due to the inclusion of molten metal than the positive electrode plate. In contrast, according to the electrode plate manufacturing method disclosed herein, the inclusion of such molten metal can be appropriately suppressed. For this reason, the electrode plate manufacturing method disclosed herein can be particularly suitably applied to the manufacture of a negative electrode plate.

[0077] In the above-mentioned embodiment, a wound electrode body is used as the electrode body. However, the electrode body is not limited to a wound electrode body as long as the positive electrode plate and the negative electrode plate face each other via a separator. Another example of the electrode body structure is a laminated electrode body in which multiple positive electrode plates and negative electrode plates are sequentially laminated with a separator interposed therebetween. To manufacture a negative electrode plate for this type of laminated electrode body, a two-dot chain line L in FIG. N4 It is advisable to perform cutting along the short direction S as shown in for each negative electrode tab 22t. Although detailed explanation is omitted, the positive electrode plate is produced in the same manner. Then, multiple positive electrode plates and multiple negative electrode plates are laminated with separators interposed therebetween so that the positive electrode tabs are laminated in the same position and the negative electrode tabs of the negative electrode plates are laminated in the same position. In this way, a laminated electrode body can be produced.

[0078] Moreover, the above-described embodiment is directed to a high-capacity secondary battery 100 in which three wound electrode bodies 40 are housed inside a battery case 50. However, the number of electrode bodies housed in one battery case is not particularly limited, and may be two or more (plural), or may be one. Furthermore, the secondary battery 100 according to the above-described embodiment is a lithium-ion secondary battery in which lithium ions are charge carriers. However, the secondary battery disclosed herein is not limited to a lithium-ion secondary battery. In the manufacturing process of other secondary batteries (such as nickel-metal hydride batteries), a process of cutting the active material-imparted region and the core-exposed region of the electrode precursor with a laser is also present, and therefore the technology disclosed herein can be applied without particular limitations.

[0079] Moreover, the secondary battery 100 according to the above embodiment is a non-aqueous electrolyte secondary battery using a non-aqueous electrolyte as an electrolyte. However, the technology disclosed herein can also be applied to batteries other than non-aqueous electrolyte secondary batteries. Another example of the structure of a secondary battery is an all-solid-state battery. In this all-solid-state battery, a solid electrolyte layer formed from a solid electrolyte in a sheet shape is used as a separator interposed between a positive electrode plate and a negative electrode plate. In this all-solid-state battery, the separator and the electrolyte are integrated and contained inside the electrode body, so that leakage of the electrolyte can be prevented. In the manufacturing process of this type of all-solid-state battery, a process of cutting the active material-imparted region and the core-exposed region of the electrode precursor with a laser exists, so that the technology disclosed herein can be applied without any particular restrictions.

[0080] [Test example] Test examples relating to the present invention will be described below. Note that the contents of the test examples described below are not intended to limit the present invention.

[0081] <First test> (1) Preparation of samples Example 1 In Example 1, a negative electrode for a lithium ion secondary battery was manufactured by using a pulse laser with different conditions in the negative electrode active material application region and the core exposed region of the negative electrode precursor. First, a negative electrode precursor was prepared in which a negative electrode active material layer with a thickness of 80 μm was applied to both sides of a negative electrode core (copper foil) with a thickness of 8 μm. The negative electrode active material layer of this negative electrode precursor contains a negative electrode active material, a thickener, and a binder in a ratio of 98.3:0.7:1.0. Note that graphite was used as the negative electrode active material, carboxymethyl cellulose (CMC) was used as the thickener, and styrene butadiene rubber (SBR) was used as the binder. Next, the negative electrode precursor was cut into a predetermined shape to cut out a negative electrode plate. Specifically, a pulse laser with a pulse width of 240 ns and an overlap rate of 89% was used when cutting the negative electrode active material application region. On the other hand, when cutting the core exposed region, a pulsed laser with a pulse width of 240 ns and an overlap rate of 90% was used. The frequency of the pulsed laser for cutting the negative electrode active material applied region was 300 kHz, and the frequency of the pulsed laser for cutting the core exposed region was 450 kHz. The spot diameter of the pulsed laser was set to 30 μm in both the negative electrode active material applied region and the core exposed region.

[0082] Comparative Example 1 In Comparative Example 1, a pulsed laser with the same conditions was used for the negative electrode active material applied region and the core exposed region of the negative electrode precursor to manufacture a negative electrode for a lithium ion secondary battery. First, the negative electrode precursor prepared in Comparative Example 1 was the same as the negative electrode precursor prepared in Example 1. Then, in Comparative Example 1, both the negative electrode active material applied region and the core exposed region were cut with a pulsed laser with a pulse width of 240 ns and an overlap rate of 89%. The frequency of the pulsed laser used in Comparative Example 1 was 400 kHz, and the spot diameter was 30 μm.

[0083] Comparative Example 2 In Comparative Example 2, a CW laser with the same conditions was used in the negative electrode active material application region and the core exposed region of the negative electrode precursor to manufacture a negative electrode for a lithium ion secondary battery. First, the negative electrode precursor prepared in Comparative Example 2 was the same as the negative electrode precursor prepared in Example 1 and Comparative Example 1. Then, in Comparative Example 2, a CW laser with an output of 1000 W and a scanning speed of 6000 mm / sec was used. The spot diameter of the CW laser used in Comparative Example 2 was 20 μm.

[0084] (2) Evaluation test In this test, first, the laser cut portion of the negative electrode plate manufactured in each example was observed with a scanning electron microscope (SEM). In this test, two SEM observations were performed on the negative electrode plate of each example, the side edge of the negative electrode tab and the side edge of the electrode plate body. FIG. 15 is a cross-sectional SEM photograph (1000 times) of the negative electrode tab of Example 1. FIG. 16 is a cross-sectional SEM photograph (1000 times) of the electrode plate body part of Example 1. FIG. 17 is a cross-sectional SEM photograph (1000 times) of the negative electrode tab of Comparative Example 1. FIG. 18 is a cross-sectional SEM photograph (1000 times) of the electrode plate body part of Comparative Example 1. FIG. 19 is a cross-sectional SEM photograph (1000 times) of the negative electrode tab of Comparative Example 2. And FIG. 20 is a cross-sectional SEM photograph (370 times) of the electrode plate body part of Comparative Example 2. The following points were confirmed from the SEM photographs shown in these FIGS. 15 to 20.

[0085] First, the state near the outer peripheral edge of the negative electrode tab in each example (i.e., near the laser-cut core exposed region) is compared and examined. As shown in FIG. 15, in Example 1, no metal pieces (spatter) were observed to adhere near the outer peripheral edge of the negative electrode tab. In addition, a first thick portion having a thickness greater than that of the central portion of the negative electrode tab was formed in the outer peripheral edge of this negative electrode tab. This first thick portion is presumed to be formed by solidification of the molten negative electrode core. The first thick portion formed in the negative electrode tab in Example 1 had an aspect ratio of 0.95. On the other hand, as shown in FIG. 17, in Comparative Example 2, it was confirmed that a large amount of spatter adhered near the outer peripheral edge of the negative electrode tab. In addition, the first thick portion formed in the negative electrode tab in Comparative Example 1 had an aspect ratio of 0.82. In Comparative Example 2, as shown in FIG. 19, no spatter adhesion was confirmed near the outer peripheral edge of the negative electrode tab. In addition, the first thick portion formed on the negative electrode tab of Comparative Example 2 had an aspect ratio of 0.96. From the above, it was found that in Example 1, in which a pulsed laser with conditions similar to those of a CW laser was used, and Comparative Example 2, in which a CW laser was used, the occurrence of sputtering during cutting of the core exposed region was suppressed, and a first thick portion having a substantially circular cross-sectional shape was formed on the outer peripheral edge of the negative electrode tab. In Comparative Example 2, the center of the first thick portion having a substantially circular cross-sectional shape was shifted downward from the center in the thickness direction of the negative electrode core. This is presumably because, in Comparative Example 2, in which a CW laser was used, the negative electrode tab was not completely separated from the core exposed region immediately after laser irradiation, and it was necessary to peel the negative electrode tab from the core exposed region, and the laser cutting mark (first thick portion) was pulled by peeling off the negative electrode tab.

[0086] Next, the state near the side edge of the plate main body in each example (i.e., near the laser-cut active material layer application region) is compared and examined. First, as shown in FIG. 16, in Example 1, a second thick part having a thickness greater than that of the negative electrode core in the center of the plate main body was formed at the end of the negative electrode core at the side edge of the negative electrode plate main body. In addition, a coating layer containing a negative electrode active material was attached to the surface of this second thick part. Also, as shown in FIG. 18, in Comparative Example 1, a second thick part was formed at the end of the negative electrode core at the side edge of the negative electrode plate main body, and a coating layer containing a negative electrode active material was attached to the surface of the second thick part. On the other hand, as shown in FIG. 20, in Comparative Example 2, a thick part was not formed at the end of the negative electrode core. And, a negative electrode active material mixed with molten metal was attached to the side edge of the plate main body in Comparative Example 2. And, it was found that the negative electrode active material attached to the side edge of this plate main body was easily detached and peeled off by a small impact.

[0087] From the above test results, it was found that in order to prevent conductive foreign matter (fragments or spatter of the negative electrode active material layer) from detaching and peeling off from the manufactured negative electrode plate, it is sufficient to use a pulsed laser with different conditions for the negative electrode active material applied area and the substrate exposed area when cutting the negative electrode plate from the negative electrode precursor.

[0088] <Second test> In this test, eight types of test examples were prepared using pulse lasers with different conditions for the negative electrode active material application region and the core exposed region, as in Example 1 of the first test. Then, the negative electrode plates prepared in each test example were observed, and the pulse laser conditions that can suppress the generation of spatters during laser cutting of the core exposed region were investigated. The specific conditions are described below.

[0089] (1) Preparation of samples (Test Examples 1 to 8) As described above, in this test, eight types of test examples (Test Examples 1 to 8) were prepared using pulsed lasers with different conditions for the negative electrode active material-applied region and the core-exposed region of the negative electrode precursor. The negative electrode precursor prepared in this test was the same as the negative electrode precursor prepared in the first test described above. In this test, the pulse width and overlap rate of the pulsed laser for cutting the core-exposed region were made different for each test example. The pulsed laser conditions in each test example are shown in Table 1 below.

[0090] (2) Evaluation test As in the first test, cross-sectional SEM was performed on the manufactured negative electrode plate, and the state near the outer periphery of the negative electrode tab was compared. The results are shown in FIG. 21 and Table 1. In FIG. 21 and Table 1, "○" means that no spatter adhesion was confirmed in the SEM observation and the aspect ratio of the first thick portion was 0.85 or more. On the other hand, "×" means that one or more spatter adhesions were confirmed and the aspect ratio of the first thick portion was less than 0.85.

[0091] [Table 1]

[0092] As shown in Table 1 and FIG. 21, in Test Examples 1, 3, 5, and 7, the occurrence of sputtering was suppressed, and a first thick-walled portion having a substantially circular cross section was formed at the end of the cut negative electrode core. As shown in FIG. 21, it was found that the occurrence of sputtering tends to be suppressed more easily as the overlap rate of the pulse laser increases. On the other hand, the results of this test also confirmed the tendency that the occurrence of sputtering tends to be suppressed more easily as the pulse width of the pulse laser increases. It was found that there is a threshold value of the pulse laser conditions that can suppress the occurrence of sputtering between Test Examples 1, 3, 5, and 7, in which the occurrence of sputtering was suppressed, and Test Examples 2, 4, 6, and 8, in which the occurrence of sputtering was not suppressed. From the results of this test, it is understood that the threshold value that enables the suppression of this sputtering is expressed by the following formula (1). Y≧-3logX+106 (1)

[0093] Although the present invention has been described in detail above, the above description is merely illustrative, and the technology disclosed herein includes various modifications and variations of the above-described specific examples. [Explanation of symbols]

[0094] 10 Positive electrode plate 12 Positive electrode core 12t Positive tab 14 Cathode active material layer 16 Protective layer 20 Negative plate 20A negative electrode precursor 20b Plate main body 22 Negative electrode core 22t negative electrode tab 23 1st thick part 24 Negative electrode active material layer 25 2nd thick part 25b Covering layer 30 Separator 38 Winding tape 40 Wound electrode body 42 Positive electrode tab group 44 Negative electrode tab group 50 Battery case 60 Positive terminal 65 Negative terminal 70 Positive electrode current collector 75 Negative electrode current collector 100 Secondary battery A1 Negative electrode active material application area A2 Negative electrode core exposed area A3 Overlapping irradiation area A4 Single irradiation area S1 Precursor preparation process S2 Active material application area cutting process S3 Core exposed area cutting process

Claims

1. A method for producing an electrode plate including an electrode core which is a metal foil and an electrode active material layer which is provided on a surface of the electrode core and contains an electrode active material, comprising: a precursor preparation step of preparing an electrode precursor including an active material applied region in which the electrode active material layer is applied to a surface of the electrode core, and a core exposed region in which the electrode active material layer is not applied and the electrode core is exposed; an active material-applied region cutting step of cutting the active material-applied region with a pulse laser; a core exposed region cutting step of cutting the core exposed region with a pulse laser; Equipped with When the pulse width (ns) of the pulse laser in the core exposed region cutting step is X and the overlap rate (%) is Y, the following formula (1) is satisfied: The frequency of the pulsed laser in the active material application region cutting step is lower than the frequency of the pulsed laser in the core exposed region cutting step, and The method for manufacturing an electrode plate, wherein the electrode plate is a negative electrode plate including a negative electrode core body made of copper or a copper alloy, and a negative electrode active material layer containing a carbon material as the electrode active material. Y≧-3logX+106 (1)

2. A method for producing an electrode plate including an electrode core which is a metal foil and an electrode active material layer which is provided on a surface of the electrode core and contains an electrode active material, comprising: a precursor preparation step of preparing an electrode precursor including an active material applied region in which the electrode active material layer is applied to a surface of the electrode core, and a core exposed region in which the electrode active material layer is not applied and the electrode core is exposed; an active material-applied region cutting step of cutting the active material-applied region with a pulse laser; a core exposed region cutting step of cutting the core exposed region with a pulse laser; Equipped with When the pulse width (ns) of the pulse laser in the core exposed region cutting step is X and the overlap rate (%) is Y, the following formula (1) is satisfied: The overlap rate of the pulsed laser in the active material application region cutting step is smaller than the overlap rate of the pulsed laser in the core exposed region cutting step, and The method for manufacturing an electrode plate, wherein the electrode plate is a negative electrode plate including a negative electrode core body made of copper or a copper alloy, and a negative electrode active material layer containing a carbon material as the electrode active material. Y≧-3logX+106 (1)

3. The method for manufacturing an electrode plate according to claim 2 , wherein a frequency of the pulsed laser in the active material application region cutting step is lower than a frequency of the pulsed laser in the core exposed region cutting step.

4. The method for manufacturing an electrode plate according to any one of claims 1 to 3, wherein a frequency of the pulsed laser in the active material application region cutting step is 100 kHz to 2000 kHz.

5. The method for manufacturing an electrode plate according to any one of claims 1 to 4, wherein a pulse width X of the pulse laser in the core exposed region cutting step is 30 ns to 240 ns.

6. The method for manufacturing an electrode plate according to any one of claims 1 to 5, wherein an overlap ratio of the pulse laser in the core exposed region cutting step is 90% to 99%.

7. A method for manufacturing a secondary battery having an electrode assembly in which a pair of electrode plates face each other via a separator, comprising the steps of: A method for producing a secondary battery, comprising the steps of: producing at least one of the pair of electrode plates by using the method for producing an electrode plate according to any one of claims 1 to 6.

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