Secondary battery manufacturing method

Abstract

To provide a technique that can increase a holding amount of an electrolytic solution inside a battery case and that can suppress a reduction in a manufacture efficiency.SOLUTION: A manufacturing method disclosed herein includes: a battery case assembling step at which an upper surface opening is sealed by a sealing plate under a state where an electrode body is arranged inside an outer case so as to assemble a battery case; a capacity increasing step at which an inside capacity of the battery case is increased by injecting a gas via an electrolytic solution liquid injection hole to an inside of the battery case having been assembled so as to deform the battery case; a liquid injecting step at which an electrolytic solution is injected via the electrolytic solution liquid injection hole to the inside of the battery case having been deformed; and a sealing step of sealing the electrolytic solution liquid injection hole of the battery case on which the liquid injection has been performed. By doing this, it is possible to induce a whole deformation due to an expansion from the inside onto the battery case, and thus it is possible to remarkably increase the inside capacity of the battery case. As this result, it is possible to reduce a number of performing the liquid injection of the electrolytic solution, and to suppress a reduction in a manufacture efficiency.SELECTED DRAWING: Figure 3

Description

[Technical field]

[0001] The technology disclosed herein relates to a method for manufacturing a secondary battery. [Background technology]

[0002] Secondary batteries such as lithium ion secondary batteries are widely used in various fields. For example, the secondary battery has a configuration in which an electrode body and an electrolyte are accommodated in a battery case. At this time, most of the electrolyte permeates the inside of the electrode body. In addition, the battery case of the secondary battery is provided with an electrolyte injection hole for injecting the electrolyte. This electrolyte injection hole is sealed with a sealing member after the electrolyte is injected.

[0003] Patent Document 1 (JP 2018-170210 A) discloses an example of a method for manufacturing a secondary battery having the above configuration. The manufacturing method described in Patent Document 1 includes a liquid injection step of injecting an electrolyte into a container housing an electrode body, an internal volume expansion step of expanding the volume of the container, and a depressurization step of depressurizing the container. This makes it possible to prevent the electrolyte from spraying out of the liquid injection port during the depressurization step after the liquid injection. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] JP 2018-170210 A Summary of the Invention [Problem to be solved by the invention]

[0005] Incidentally, the electrolyte injected into the battery case is once held in the surplus space between the battery case and the electrode body, and then permeates into the inside of the electrode body over a long period of time (e.g., several hours to several days). Meanwhile, in recent years, as the electrode body becomes larger, the surplus space that holds the electrolyte before permeation tends to become narrower. In this case, even if the surplus space is filled with the electrolyte, it is difficult to supply a sufficient amount of electrolyte to the entire electrode body. Therefore, in recent injection processes, it has become necessary to inject the electrolyte in multiple batches, which causes a decrease in manufacturing efficiency.

[0006] The technology disclosed herein has been made to solve the above-mentioned problems, and aims to provide a technology that can increase the amount of electrolyte held in a battery case and suppress a decrease in manufacturing efficiency. [Means for solving the problem]

[0007] In order to achieve the above object, the technology disclosed herein provides a method for manufacturing a secondary battery having the following configuration (hereinafter, also simply referred to as a "manufacturing method").

[0008] The manufacturing method disclosed herein manufactures a secondary battery including an electrode assembly including a positive electrode and a negative electrode, an electrolyte, and a battery case that accommodates the electrode assembly and the electrolyte. The battery case of this secondary battery includes an exterior body including a plate-shaped bottom, a side wall extending upward from the outer periphery of the bottom, and an upper opening surrounded by the upper end of the side wall, and a sealing plate that seals the upper opening and has an electrolyte injection hole. The manufacturing method disclosed herein includes the following steps: a battery case assembly step of assembling a battery case by sealing the upper opening with a sealing plate in a state in which the electrode assembly is placed inside the exterior body; a volume increasing step of increasing the internal volume of the battery case by injecting gas through the electrolyte injection hole into the interior of the assembled battery case to deform the battery case; an electrolyte injection step of injecting electrolyte through the electrolyte injection hole into the interior of the deformed battery case; and a sealing step of sealing the electrolyte injection hole of the battery case after electrolyte injection.

[0009] The manufacturing method disclosed herein includes a volume increasing step of injecting gas into the assembled battery case through an electrolyte injection hole to deform the battery case. This causes the battery case to deform overall due to internal expansion, rather than local deformation due to external force. This allows the internal volume of the battery case to be significantly increased compared to conventional techniques. As a result, the number of electrolyte injections can be reduced, and a decrease in manufacturing efficiency can be suppressed. [Brief description of the drawings]

[0010] [Figure 1] 1 is a perspective view showing a schematic appearance of a secondary battery manufactured by a manufacturing method according to an embodiment of the present invention; [Diagram 2] 2 is a vertical sectional view showing a schematic internal structure of the secondary battery shown in FIG. [Diagram 3] 1 is a flowchart illustrating a manufacturing method according to an embodiment. [Figure 4] FIG. 11 is a perspective view illustrating the connection between the sealing plate and the electrode body in the battery case assembly process. [Diagram 5] 5 is a vertical cross-sectional view illustrating gas injection into the battery case in the volume increasing process. FIG. [Figure 6] FIG. 4 is a vertical cross-sectional view illustrating the injection of an electrolyte in a liquid injection step. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0011] Hereinafter, an embodiment of the technology disclosed herein will be described in detail with reference to the drawings. Note that matters other than those specifically mentioned in this specification and necessary for implementing the technology disclosed herein can be understood as design matters of a person skilled in the art based on the prior art in the relevant field. The technology disclosed herein can be implemented based on the contents disclosed in this specification and the technical common sense in the relevant field. In addition, in the following drawings, members and parts that perform the same function are described with the same reference numerals. Furthermore, the dimensional relationships (length, width, thickness, etc.) in each drawing do not reflect the actual dimensional relationships.

[0012] In this specification, the term "secondary battery" refers to a general electric storage device that can repeatedly be charged and discharged by the movement of charge carriers between a positive electrode and a negative electrode via an electrolyte. Such "secondary batteries" include so-called storage batteries such as lithium ion secondary batteries, nickel-metal hydride batteries, and nickel-cadmium batteries, as well as capacitors such as electric double layer capacitors. In other words, the manufacturing method disclosed herein is not limited to a method for manufacturing a specific type of battery, and can be widely applied to the manufacture of general electric storage devices in which an electrode body and an electrolyte are housed in a battery case.

[0013] 1. Structure of secondary batteries First, the structure of a secondary battery to be manufactured by the manufacturing method according to this embodiment will be described. FIG. 1 is a perspective view that typically shows the appearance of a secondary battery manufactured by the manufacturing method according to this embodiment. FIG. 2 is a vertical cross-sectional view that typically shows the internal structure of the secondary battery shown in FIG. 1. In addition, the symbol X in FIG. 1 and FIG. 2 indicates the width direction, the symbol Y indicates the depth direction, and the symbol Z indicates the height direction. Furthermore, the symbols L, R, F, Rr, U, and D indicate the left, right, front, rear, upper, and lower, respectively. However, these directions are determined for the convenience of explanation, and are not intended to limit the installation mode of the secondary battery during use or manufacture.

[0014] 1 and 2, the secondary battery 1 in this embodiment includes a battery case 10, an electrode assembly 20, and an electrolyte 30. Each member constituting the secondary battery 1 will be specifically described below.

[0015] (1) Battery case The battery case 10 in this embodiment is a box-shaped container having an internal space 10a. The internal space 10a of the battery case 10 accommodates an electrode assembly 20 and an electrolyte 30. As shown in Figs. 1 and 2, the battery case 10 in this embodiment is a flat rectangular parallelepiped container. The battery case 10 is preferably a metal member having a certain level of strength or higher. Examples of materials for the battery case 10 include aluminum and aluminum alloys. Although it is not intended to limit the technology disclosed herein, the internal volume of the battery case 10 may be 500 cm3 or more. 3 More than 1000cm is preferable. 3 The above is more preferable. Since such a large-capacity secondary battery 1 requires a large amount of electrolyte 30, the effects of the technology disclosed herein are more preferably exhibited. The upper limit of the internal volume of the battery case 10 is not particularly limited, and is not limited to 3000 cm. 3 Less than 1500cm is also acceptable. 3 The technology disclosed herein can be applied to a distance of 300 cm or less. 3 Less than (typically 150cm 3 This can also be applied to small batteries (see below).

[0016] The battery case 10 in this embodiment also includes an exterior body 14 and a sealing plate 12. Each of these components will be described below.

[0017] (a) Exterior body The exterior body 14 is a box-shaped body with an open top. Specifically, the exterior body 14 includes a plate-shaped bottom 14b, side walls 14c and 14d extending upward D from the outer periphery of the bottom 14b, and a top opening 14a surrounded by the upper ends of the side walls 14c and 14d. As described above, the battery case 10 shown in FIG. 1 and FIG. 2 is a flat rectangular parallelepiped case. In the case of the battery case 10 having such an outer shape, the bottom 14b of the exterior body 14 is a long rectangular plate-shaped member. The side walls 14c and 14d include a pair of first side walls 14c extending upward U from the long sides (sides along the width direction X) of the bottom 14b, and a pair of second side walls 14d extending upward U from the short sides (sides along the depth direction Y) of the bottom 14b. In other words, the first side walls 14c are side walls having a relatively large area. On the other hand, the second side wall 14d has a relatively small area. In such a flat rectangular parallelepiped battery case 10, the first side wall 14c tends to deform (expand) preferentially when the internal pressure increases. This makes it easier to control the position and amount of deformation in the volume increasing step S20 described below.

[0018] In addition, the specific dimensions of the exterior body 14 can be changed as appropriate as long as the effect of the technology disclosed herein is not significantly impaired. For example, the height (dimension in the height direction Z) of the first side wall 14c is preferably 5 cm or more, more preferably 8 cm or more. The width (dimension in the width direction X) of the first side wall 14c is preferably 20 cm or more, more preferably 25 cm or more. In this way, by forming the first side wall 14c having a certain height and width (i.e., area) or more, the first side wall 14c becomes easier to deform in the volume increasing step S20. On the other hand, the upper limit of the height and width of the first side wall 14c is not particularly limited. For example, the height of the first side wall 14c may be 12 cm or less, or 10 cm or less. The width of the first side wall 14c may be 35 cm or less, or 30 cm or less. The aspect ratio (ratio of height to width) of the first side wall 14c is preferably 2 or more, more preferably 3 or more. This makes it easier to deform the first side wall 14c. On the other hand, the upper limit of the aspect ratio of the first side wall 14c is not particularly limited, and may be 8 or less, or 5 or less.

[0019] Moreover, the width (dimension in the depth direction Y) of the second side wall 14d is preferably 5 cm or less, and more preferably 4 cm or less. In this way, by narrowing the width of the second side wall 14d, deformation of the second side wall 14d can be suitably suppressed. On the other hand, the lower limit of the width of the second side wall 14d is not particularly limited, and may be 1 cm or more, or 3 cm or more. The height (dimension in the height direction Z) of the second side wall 14d is set to the same height as the first side wall 14c.

[0020] Moreover, the thickness (dimension in the depth direction Y) of the first side wall 14c is preferably 3 mm or less, more preferably 2 mm or less, and even more preferably 1.5 mm or less. This makes it easier to deform the first side wall 14c. On the other hand, from the viewpoint of ensuring the strength of the battery case 10, the thickness of the first side wall 14c is preferably 0.15 mm or more, and more preferably 0.2 mm or more. On the other hand, the bottom 14b and the second side wall 14d are preferably thicker than the first side wall 14c. This makes it easier to deform the first side wall 14c. The specific thickness of the bottom 14b is preferably 0.5 mm or more, and more preferably 1 mm or more. This makes it possible to suitably suppress the deformation of the bottom 14b. On the other hand, in consideration of the weight and material cost of the secondary battery 1, the thickness of the bottom 14b is preferably 4 mm or less, more preferably 3 mm or less, and even more preferably 2.5 mm or less. The thickness (dimension in the width direction X) of the second side wall 14d is preferably 0.15 mm or more, and more preferably 0.2 mm or more. This can suppress deformation of the second side wall 14d. On the other hand, in consideration of the weight and material cost of the secondary battery 1, the thickness of the second side wall 14d is preferably 3 mm or less, more preferably 2 mm or less, and even more preferably 1.5 mm or less.

[0021] (b) Sealing plate The sealing plate 12 is a plate-like member that seals the upper opening 14a of the exterior body 14. The sealing plate 12 is provided with an electrolyte injection hole 12a for injecting the electrolyte 30 into the battery case 10. In the secondary battery 1 after manufacture, the electrolyte injection hole 12a is sealed with a sealing member 16. The sealing plate 12 is also preferably thicker than the first side wall 14c. This can suppress deformation of the sealing plate 12 in the volume increasing step S20. Specifically, the thickness of the sealing plate 12 is preferably 1 mm or more, and more preferably 1.5 mm or more. On the other hand, in consideration of the weight and material cost of the secondary battery 1, the thickness of the sealing plate 12 is preferably 5 mm or less, and more preferably 4 mm or less.

[0022] Further, the sealing plate 12 in this embodiment is formed with a gas release valve 12b. The gas release valve 12b is a thin-walled portion formed to be thinner than other portions of the sealing plate 12. This gas release valve 12b breaks open when the internal pressure of the battery case 10 rises suddenly due to the generation of decomposition gas or the like. This can prevent excessive deformation of the secondary battery 1 during charging and discharging. The thickness of the gas release valve 12b is preferably 0.5 mm or less, more preferably 0.3 mm or less. This allows the gas release valve 12b to operate appropriately when the internal pressure rises during charging and discharging. On the other hand, the lower limit of the thickness of the gas release valve 12b is preferably 0.05 mm or more, more preferably 0.1 mm or more. This can suppress malfunction of the gas release valve 12b in the volume increase step S20.

[0023] A pair of electrode terminals 40 are attached to the sealing plate 12. Each electrode terminal 40 is a structure combining a plurality of conductive members and extends along the height direction Z. A current collecting member 40a constituting the lower end of the electrode terminal 40 is connected to the electrode body 20 inside the battery case 10. As shown in FIG. 4, in this embodiment, each of the pair of electrode terminals 40 has a plurality of current collecting members 40a (three in FIG. 4). Meanwhile, an external terminal 40b constituting the upper end of the electrode terminal 40 is exposed to the outside of the battery case 10. The structure of the electrode terminal 40 can be a structure that can be adopted in a general secondary battery without any particular restrictions, and the technology disclosed herein is not limited thereto, so detailed description will be omitted.

[0024] (2) Electrode body As described above, the electrode body 20 is housed inside the battery case 10. As shown in Fig. 4, in this embodiment, a plurality of electrode bodies 20 (three in Fig. 4) are housed inside the battery case 10. However, the number of electrode bodies 20 is not particularly limited and may be one. Although not shown in the figure, an insulating sheet is disposed between the electrode body 20 and the exterior body 14. This can prevent electrical conduction between the electrode body 20 and the battery case 10.

[0025] The electrode body 20 includes a positive electrode and a negative electrode. The electrode body 20 in this embodiment is a flat wound electrode body. Specifically, the electrode body 20 is formed by winding a laminate formed by stacking long sheet-like positive electrodes and negative electrodes with a separator interposed therebetween. Note that the materials of each member (positive electrode, negative electrode, separator, etc.) constituting the electrode body 20 can be materials that can be used in general secondary batteries without particular restrictions, and detailed explanations are omitted since they do not limit the technology disclosed herein. In addition, the electrode body 20 is housed in the battery case 10 so that its winding axis is along the long side of the bottom 14b of the exterior body 14. Therefore, in the secondary battery 1 in this embodiment, the flat surface of the electrode body 20 and the first side wall 14c of the exterior body 14 face each other.

[0026] The dimensions of the electrode body 20 are not particularly limited, and are appropriately adjusted in consideration of the relationship between battery performance and production efficiency. Specifically, when the electrode body 20 is made smaller, the surplus space in the battery case 10 (internal volume of the battery case - volume of the electrode body) increases, and the amount of liquid injected in the liquid injection step S30 described below can be increased. This contributes to improving production efficiency. From this perspective, the dimensions of the electrode body 20 are set to a value that satisfies the requirement that the surplus space in the battery case 10 is 50 cm 3 or more (more preferably 100 cm 3 More preferably, 150 cm 3 On the other hand, if the electrode body 20 is made larger, the battery performance such as the battery capacity can be improved. From this viewpoint, the dimensions of the electrode body 20 are set so that the surplus space in the battery case 10 is 250 cm or more. 3 Less than or equal to 200 cm 3 Less than 170cm, more preferably 3 In the manufacturing method disclosed herein, since the internal capacity of the battery case 10 can be increased in the volume increasing step S20, it is preferable that the surplus space in the battery case 10 immediately after the battery case assembling step S10 is set to 170 cm 3 Even in the following cases, a decrease in production efficiency can be suitably prevented.

[0027] (3) Electrolyte The electrolyte 30 is accommodated in the battery case 10 together with the electrode assembly 20. Specifically, the electrolyte 30 permeates the inside of the electrode assembly 20 (between the positive and negative electrodes). A part of the electrolyte 30 may be present outside the electrode assembly 20 (between the electrode assembly 20 and the battery case 10) as excess electrolyte 32. This allows the excess electrolyte 32 to be supplied to the inside of the electrode assembly 20 when the electrolyte 30 is decomposed inside the electrode assembly 20. Note that the components of the electrolyte 30 can be any components that can be used in general secondary batteries without any particular restrictions, and detailed description thereof will be omitted since they do not limit the technology disclosed herein.

[0028] 2. Manufacturing method of secondary batteries Next, an embodiment of a method for manufacturing a secondary battery disclosed herein will be described. Fig. 3 is a flow chart for explaining the manufacturing method according to this embodiment. Fig. 4 is a perspective view for explaining the connection between the sealing plate and the electrode body in the battery case assembly process. Fig. 5 is a perspective view for explaining the injection of gas into the battery case in the volume increasing process. Fig. 6 is a perspective view for explaining the injection of electrolyte in the electrolyte injection process.

[0029] 3, the manufacturing method according to this embodiment includes at least a battery case assembly step S10, a volume increasing step S20, a liquid injection step S30, and a sealing step S40. Each step will be described below.

[0030] (1) Battery case assembly process S10 In this step, the upper opening 14a is sealed with the sealing plate 12 while the electrode body 20 is disposed inside the exterior body 14, and the battery case 10 is assembled. An example of a specific procedure of this step is as follows. First, as shown in FIG. 4, the current collecting member 40a of the electrode terminal 40 is connected to each of the multiple electrode bodies 20. This allows the sealing plate 12 and the electrode body 20 to be integrated. In this state, the electrode body 20 is inserted into the interior of the exterior body 14 from the upper opening 14a. Then, the electrode body 20 and the sealing plate 12 are further lowered, so that the upper opening 14a of the exterior body 14 is closed with the sealing plate 12. Next, the upper ends of the side walls 14c and 14d of the exterior body 14 are joined to the outer periphery of the sealing plate 12. This results in the construction of a battery case 10 in which the electrode body 20 is accommodated in the internal space 10a. Note that, for joining the sealing plate 12 to the exterior body 14, a conventionally known joining means can be used without any particular restrictions. A suitable example of such a joining means is laser welding.

[0031] (2) Volume increasing step S20 In this step, gas is injected into the assembled battery case 10 through the electrolyte injection hole 12a to deform the battery case 10, thereby increasing the internal volume of the battery case 10. As an example, in this step, a gas supply means G as shown in FIG. 5 is used. The gas supply means G includes a supply port G1 and a gas generation source G2. The supply port G1 is configured so as to be able to seal the inside of the battery case 10 when attached to the electrolyte injection hole 12a. Meanwhile, various devices (such as a compressor or a gas cylinder) that generate high-pressure gas are used for the gas generation source G2. Then, in this step, the supply port G1 is attached to the electrolyte injection hole 12a, and the gas generation source G2 is operated. This increases the internal pressure of the case, and the side walls 14c and 14d (for example, the first side wall 14c) are generally deformed (expanded). As a result, the internal volume of the battery case 10 increases significantly.

[0032] In addition, the gas supply conditions (gas pressure, supply time, etc.) in this step are preferably adjusted so that the battery case 10 expands to a certain extent or more. This causes the battery case 10 to undergo plastic deformation, so that the internal volume increased in the volume increase step S20 is likely to be maintained until the liquid injection step S30 is started. For example, when the increase in the internal volume of the battery case 10 in the volume increase step S20 is set to 100%, it is preferable to set the gas supply conditions so that the increase in the internal volume of the battery case 10 at the start of the liquid injection step S30 is maintained at 10% or more (more preferably 30% or more, and even more preferably 50% or more). This makes it possible to suitably increase the amount of electrolyte that can be injected in the liquid injection step S30. Note that the upper limit of the increase in the internal volume at the start of the liquid injection step S30 is not particularly limited, and may be 100% or less (no contraction after the volume increase step S20) or 75% or less.

[0033] The increase in the internal volume in the volume increasing step S20 is 40 cm 3 More than 70cm is preferable. 3 More than 100cm is preferable. 3The above is even more preferable. This allows the battery case 10 to appropriately undergo plastic deformation, making it easier to maintain the increase in the internal volume until the liquid injection step S30 is started. On the other hand, it is preferable that the increase in the internal volume is set within a range that can prevent damage to the battery case 10 (the gas release valve 12b, the joint between the sealing plate 12 and the exterior body 14, etc.). Specifically, the upper limit of the increase in the internal volume is set to 200 cm 3 Less than 150cm is preferable. 3 Less than 120cm is preferable. 3 The following are particularly preferred:

[0034] The pressure of the gas supplied to the battery case 10 is preferably 0.03 MPa or more, more preferably 0.05 MPa or more, and particularly preferably 0.10 MPa or more. This allows the battery case 10 to be appropriately plastically deformed. On the other hand, the upper limit of the gas pressure is preferably 0.20 MPa or less, more preferably 0.15 MPa or less, and particularly preferably 0.12 MPa or less. This allows the battery case 10 to be prevented from being damaged. In addition, the gas supply time is preferably 5 seconds or more, more preferably 10 seconds or more, and even more preferably 12 seconds or more. This allows the battery case 10 to be appropriately plastically deformed. On the other hand, from the viewpoint of shortening the manufacturing time, the gas supply time is preferably 30 seconds or less, and more preferably 20 seconds or less. In addition, the gas used in this process is not particularly limited as long as it does not significantly impair the performance of the secondary battery 1 after manufacture. Examples of such gases include air, helium gas, nitrogen gas, and argon gas. In order to prevent deterioration in performance due to the inclusion of moisture, it is preferable to perform a drying process on the gas before it is supplied to the battery case 10.

[0035] As described above, when a flat battery case 10 is used, the first side wall 14c having a relatively large area expands preferentially, which makes it easier to manage the deformation position and deformation amount in this process. According to an experiment conducted by the present inventor, it has been confirmed that the first side wall 14c after deformation expands most at a portion slightly above the center portion in the height direction Z. Specifically, when the height dimension of the first side wall 14c is 100%, the first side wall 14c expands so that a peak occurs within a range of 50.5% to 52.5% (for example, at a position of about 51%) from the bottom end. It has also been confirmed that when the flat battery case 10 is expanded, the second side wall 14d having a relatively small area is slightly recessed toward the inside of the battery case 10.

[0036] (3) Liquid injection process S30 In this step, the electrolyte 30 is injected through the electrolyte injection hole 12a into the battery case 10 after deformation. As an example, in this step, the electrolyte 30 is injected according to the following procedure. First, as shown in FIG. 6, an injection nozzle P is inserted into the electrolyte injection hole 12a. Then, the electrolyte 30 is injected into the battery case 10 from the injection nozzle P. At this time, the electrolyte 30 is injected in a plurality of times while permeating the inside of the electrode body 20 so that the electrolyte 30 does not spray out from the electrolyte injection hole 12a. At this time, in this embodiment, since the battery case 10 is expanded by the volume increase step S20, the amount of electrolyte that can be supplied by one injection is increased. Therefore, the number of injections of the electrolyte 30 in this step can be reduced, and the manufacturing efficiency can be significantly improved.

[0037] In addition, in the liquid injection step S30 in this embodiment, a decompression process is performed to reduce the pressure inside the battery case 10. Specifically, the liquid injection step S30 in this embodiment is performed in a state in which the battery case 10 is accommodated in a decompression chamber D. As a result, the inside of the electrode body 20 (between the positive and negative electrodes) becomes negative pressure. When the electrolyte solution 30 is injected in this state, the electrolyte solution 30 is sucked into the inside of the electrode body 20, which has become negative pressure. This shortens the time required for the electrolyte solution 30 to permeate. In addition, as shown in FIG. 6, when the decompression process is performed in the decompression chamber D, it is possible to prevent the inside of the battery case 10 from becoming more negative than the outside. As a result, it is possible to suppress a decrease in the internal volume due to the contraction of the battery case 10.

[0038] The internal pressure of the battery case 10 during the decompression treatment is preferably -50 kPa or less, more preferably -80 kPa or less. This allows the permeation time of the electrolyte solution 30 to be suitably shortened. On the other hand, when the inside of the decompression chamber D is decompressed, the lower limit of the pressure during the decompression treatment is not particularly limited as long as the decompression chamber D is not damaged. For example, the lower limit of the pressure inside the decompression chamber D may be -100 kPa or more. The decompression treatment is not an essential treatment in the liquid injection step S30. For example, when an electrode body (such as a laminated electrode body) into which the electrolyte solution easily permeates is used, the electrolyte solution may be injected without carrying out the decompression treatment.

[0039] As described above, in the manufacturing method according to the present embodiment, it is preferable that the internal volume of the battery case 10 increased in the volume increasing step S20 is appropriately maintained until the electrolyte injection step S30 is started. As an example, the increase in the internal volume of the battery case 10 at the start of the electrolyte injection step S30 is 10 cm 3 More than 20cm is preferable. 3 More than 30cm is preferable. 3The above is more preferable. This increases the amount of electrolyte that can be supplied in one injection, improving manufacturing efficiency. The means for maintaining the internal volume of the battery case 10 is not particularly limited. For example, as described above, the contraction of the battery case 10 can be suppressed by causing plastic deformation in the battery case 10. In addition, the contraction of the battery case 10 may be mechanically suppressed by using a jig that maintains the shape of the battery case 10.

[0040] (4) Sealing process S40 In this step, the electrolyte injection hole 12a of the battery case 10 after injection is sealed. This results in the secondary battery 1 (see FIG. 1) in which the electrode body 20 and electrolyte 30 are accommodated in the sealed battery case 10. The sealing member 16 for sealing the electrolyte injection hole 12a is not limited to the technology disclosed herein, and any conventionally known member can be used without particular restriction. An example of the sealing member 16 is a blind rivet. In addition, after sealing the electrolyte injection hole 12a with the sealing member 16, the sealing member 16 may be welded to the battery case 10 (sealing plate 12). This allows the sealing member 16 to be fixed more firmly.

[0041] (5) Summary As described above, in the manufacturing method according to the present embodiment, a volume increasing step S20 is performed in which a gas is injected into the assembled battery case 10 to deform the battery case 10. This allows the battery case 10 to be deformed overall by expansion from the inside, rather than locally by an external force. As a result, it has been confirmed by experiments that the internal volume of the battery case 10 increases significantly. Specifically, it has been confirmed that the increase in the internal volume of the battery case by the volume increasing step S20 is 10 times or more larger than that in the case where the side of the battery case is mechanically pulled as in Patent Document 1. Therefore, according to the manufacturing method according to the present embodiment, the amount of electrolyte that can be supplied by one injection is significantly increased, and therefore manufacturing efficiency can be significantly improved.

[0042] 3. Other embodiments An embodiment of the manufacturing method disclosed herein has been described above. Note that the manufacturing method disclosed herein is not limited to the above embodiment, and various aspects can be modified as appropriate. An example of an aspect that can be modified from the above embodiment will be described below.

[0043] (1) Secondary batteries to be manufactured The manufacturing method disclosed herein is not limited to the secondary battery 1 having the above configuration, and can be widely applied to the manufacture of secondary batteries having various structures. For example, the secondary battery 1 in the above embodiment uses a flat rectangular parallelepiped battery case 10. However, the shape of the battery case does not limit the technology disclosed herein. For example, the shape of the battery case may be cubic or cylindrical. The shape of the electrode body also does not limit the technology disclosed herein. For example, in the above embodiment, a wound electrode body is used as the electrode body 20. However, the electrode body may be a laminated electrode body in which a plurality of rectangular electrode sheets are laminated with a separator interposed therebetween.

[0044] (2) Drying process The manufacturing method disclosed herein may include steps other than the four steps S10 to S40 shown in FIG. 3. For example, a drying step for drying the electrode body in the battery case may be performed after the battery case assembly step S10 is performed and before the electrolyte injection step S30 is started. This can prevent performance degradation (capacity reduction, output reduction, etc.) caused by moisture entering the electrode body. In the drying step, it is preferable to perform heating while reducing the pressure inside the battery case. This can efficiently remove moisture inside the electrode body. For example, the heating temperature in the drying step is preferably 80° C. or higher, more preferably 90° C. or higher, and particularly preferably 100° C. or higher. This can suitably remove moisture inside the electrode body. In addition, the heating temperature is preferably 200° C. or lower, more preferably 150° C. or lower, and particularly preferably 120° C. or lower. This can suppress deterioration of resin members (separator, insulating film, etc.). In addition, the pressure inside the battery case during the drying step is preferably reduced to -6 Pa to -10 Pa. This allows the evaporated water to be easily removed.

[0045] As described above, the drying step can be performed without any particular limitation as long as it is performed after the battery case assembling step S10 and before the electrolyte injection step S30 is started. However, in consideration of drying efficiency, it is preferable to perform the drying step after the volume increasing step S20. Specifically, the battery case after expanding in the volume increasing step S20 has improved ventilation in the internal space. Therefore, by performing the drying step after the volume increasing step S20, it becomes easier to discharge moisture evaporated by heating to the outside of the battery case.

[0046] (3) Initial charging process In the manufacturing method disclosed herein, an initial charging step may be performed between the injection step S30 and the sealing step S40. In this initial charging step, an external charging device is connected to the electrode terminal 40 with the electrolyte injection hole 12a open, and charging is performed up to a predetermined voltage at room temperature (for example, about 20°C to 30°C). As a result, a part of the electrolyte 30 decomposes and a large amount of decomposition gas is generated. By performing this initial charging before the sealing step S40, it is possible to prevent the gas exhaust valve from operating during the initial charging. The charging conditions in the initial charging step are not particularly limited, and can be appropriately changed according to the specifications of the object to be manufactured (secondary battery). In addition, when the initial charging step is performed, it is preferable to perform a pressure reduction treatment before performing the sealing step S40. This allows the decomposition gas generated in the initial charging step to be more appropriately exhausted.

[0047] (4)Leak inspection process In the manufacturing method disclosed herein, it is preferable to perform a leak inspection process after the volume increasing process S20 is performed and before the sealing process S40 is started (preferably immediately after the volume increasing process S20). This makes it possible to detect damage to the battery case (such as a gas exhaust valve and a joint between the sealing plate and the exterior body) caused by the volume increasing process S20. An example of a specific procedure for the leak inspection process is as follows. In the leak inspection process, first, a test gas for leak inspection (e.g., helium gas) is filled into the battery case. Then, an inspection device that detects the test gas is used to inspect for leakage of the test gas from inside the battery case. This makes it possible to inspect the presence or absence of damage to the battery case and the location of the damage. Note that the leak inspection process can also be included in the volume increasing process S20 described above. Specifically, in the volume increasing process S20, the test gas may be used as the gas to be injected into the battery case, and the battery case may be deformed while inspecting for leakage of the test gas with the inspection device. This makes it possible to expand the battery case while checking for the presence or absence of damage.

[0048] The embodiments of the technology disclosed herein have been described above. However, the above description is merely an example and does not limit the scope of the claims. The technology described in the claims includes various modifications and changes to the specific examples exemplified in the above description.

[0049] That is, the technology disclosed herein encompasses the technologies described in the following [Item 1] to [Item 8].

[0050] [Item 1] A method for manufacturing a secondary battery including an electrode assembly including a positive electrode and a negative electrode, an electrolyte, and a battery case that accommodates the electrode assembly and the electrolyte, comprising: The battery case is an exterior body including a plate-shaped bottom portion, a side wall extending upward from an outer periphery of the bottom portion, and an upper surface opening surrounded by an upper end of the side wall; a sealing plate that seals the upper opening and has an electrolyte injection hole; Including, Here, the steps are as follows: a battery case assembling step of assembling the battery case by sealing the top opening with the sealing plate in a state where the electrode body is disposed inside the exterior body; a volume increasing step of injecting a gas into the assembled battery case through the electrolyte injection hole to deform the battery case, thereby increasing an internal volume of the battery case; a liquid injection step of injecting the electrolyte into the deformed interior of the battery case through the electrolyte injection hole; a sealing step of sealing the electrolyte injection hole of the battery case after the electrolyte injection; The method for producing a secondary battery includes the steps of:

[0051] [Item 2] 2. The manufacturing method according to item 1, wherein, when an increase in an internal volume of the battery case in the volume increasing step is taken as 100%, an increase in an internal volume of the battery case at the start of the liquid injection step is maintained at 10% or more.

[0052] [Item 3] The increase in the internal volume of the battery case in the volume increasing step is 40 cm 3 The method for producing the present invention according to item 1 or 2,

[0053] [Item 4] The increase in the internal volume of the battery case when the liquid injection step is started is 10 cm 3 The above-mentioned production method according to any one of items 1 to 3.

[0054] [Item 5] The bottom portion is a long rectangular plate-like member, The manufacturing method according to any one of items 1 to 4, wherein the side walls include a pair of first side walls extending upward from a long side of the bottom portion and a pair of second side walls extending upward from a short side of the bottom portion.

[0055] [Item 6] 6. The method according to item 5, wherein the first side wall has a height of 5 cm or more and a width of 20 cm or more.

[0056] [Item 7] 7. The manufacturing method according to any one of items 1 to 6, further comprising a drying step of drying the electrode body in the battery case after the battery case assembling step is performed and before the liquid pouring step is started.

[0057] [Item 8] 8. The manufacturing method according to any one of items 1 to 7, wherein in the liquid injection step, a decompression treatment is carried out to reduce the pressure inside the battery case to −50 kPa or less. [Explanation of symbols]

[0058] 1 Secondary battery 10 Battery case 10a Internal space 12 Sealing plate 12a Electrolyte injection hole 12b Gas exhaust valve 14 Exterior body 14a Top opening 14b bottom 14c Side wall (1st side wall) 14d Side wall (2nd side wall) 16 Sealing member 20 Electrode body 30 Electrolyte 32 Excess electrolyte 40 electrode terminal 40a Current collecting member 40b External terminal

Claims

1. A method for manufacturing a secondary battery including an electrode assembly including a positive electrode and a negative electrode, an electrolyte, and a battery case that accommodates the electrode assembly and the electrolyte, comprising: The battery case is an exterior body including a plate-shaped bottom portion, a side wall extending upward from an outer periphery of the bottom portion, and an upper surface opening surrounded by an upper end of the side wall; a sealing plate that seals the upper opening and has an electrolyte injection hole; Including, Here, the steps are as follows: a battery case assembling step of assembling the battery case by sealing the top opening with the sealing plate in a state where the electrode body is disposed inside the exterior body; a volume increasing step of increasing an internal volume of the battery case by injecting a gas into the assembled battery case through the electrolyte injection hole to plastically deform the battery case; an injection step of injecting the electrolyte through the electrolyte injection hole into the inside of the battery case whose internal volume has been increased by the volume increasing step; a sealing step of sealing the electrolyte injection hole of the battery case after the electrolyte injection; The method for producing a secondary battery includes the steps of:

2. 2. The manufacturing method according to claim 1, wherein when an increase in an internal volume of the battery case in the volume increasing step is taken as 100%, an increase in an internal volume of the battery case at the start of the electrolyte injection step is maintained at 10% or more.

3. The increase in the internal volume of the battery case in the volume increasing step is 40 cm ３ The method for producing a composition according to claim 1 or 2, wherein the composition is a polyolefin.

4. The increase in the internal volume of the battery case when starting the electrolyte injection step is 10 cm ３ The method for producing a semiconductor device according to claim 3, wherein the above-mentioned step is carried out.

5. The bottom portion is a long rectangular plate-like member, The manufacturing method according to claim 1 or 2, wherein the side walls include a pair of first side walls extending upward from a long side of the bottom portion and a pair of second side walls extending upward from a short side of the bottom portion.

6. The method of claim 5 , wherein the first side wall has a height of at least 5 cm and a width of at least 20 cm.

7. The manufacturing method according to claim 1 , further comprising a drying step of drying the electrode body in the battery case after the battery case assembling step is performed and before the electrolyte injection step is started.

8. 3. The method according to claim 1, wherein a pressure reduction treatment is carried out in the liquid injection step to reduce the pressure inside the battery case to −50 kPa or less.

9. A manufacturing method as described in claim 1 or 2, wherein after the volume increasing step, the liquid injection step is performed without maintaining the deformed state of the battery case with a jig.

10. A manufacturing method as described in claim 1 or 2, wherein when the increase in the internal volume of the battery case in the volume increasing process is 100%, the increase in the internal volume of the battery case when the liquid injection process is started is 75% or less.

11. A manufacturing method as described in claim 1 or 2, further comprising carrying out a drying step for drying the electrode body in the battery case after the volume increasing step and before the liquid injecting step.

12. A manufacturing method as described in claim 1 or 2, wherein in the volume increasing process, a leak inspection of the battery case is performed by injecting gas through the electrolyte injection hole.

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