Tobacco filter and cigarette containing the same

The cigarette filter integrates a moisturizer and granules with a paper filter and wrapping paper to improve flavor and nicotine transfer, addressing the limitations of existing filters in maintaining suction resistance and granule adhesion.

JP7667877B2Active Publication Date: 2025-04-23KT&G CO LTD
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Patent Information

Application Number
JP2023571388
Authority / Receiving Office
JP · JP
Patent Type
Patents
Current Assignee / Owner
Priority Date
2021-10-18
Filing Date
2022-10-18
Publication Date
2025-04-23
Estimated Expiration
2042-10-18

AI Technical Summary

Technical Problem

Existing cigarette filters do not effectively combine granules and a moisturizer to enhance flavor and nicotine transfer while maintaining adequate suction resistance.

Method used

A cigarette filter comprising a paper filter with a moisturizer applied to its surface, granules bound with the moisturizer, and a filter wrapping paper to surround the paper filter, ensuring the granules adhere properly and maintain flavor and nicotine transfer.

Benefits of technology

The solution provides a cigarette filter that enhances flavor and nicotine transfer by ensuring granules adhere well to the paper filter, while maintaining suitable suction resistance for a satisfying smoking experience.

✦ Generated by Eureka AI based on patent content.

Smart Images

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Patent Text Reader

Abstract

The present invention relates to a cigarette filter and a manufacturing method thereof, and can provide a cigarette paper filter using paper and a cigarette including the same. The cigarette filter according to one embodiment of the present invention can provide a high smoking satisfaction due to high granule adhesion and can eliminate a burnt taste. Various embodiments of the cigarette filter and the manufacturing method thereof are possible as follows.
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Description

[Technical field]

[0001] The present invention relates to a cigarette filter and a cigarette containing the same. [Background technology]

[0002] Generally, to manufacture cigarettes, various types of leaf tobacco are blended and processed to produce a desired aroma and flavor, the processed leaf tobacco is then cut to produce cut tobacco leaves, which are then wrapped in cigarette paper to produce cigarettes, and a filter can be attached to the cigarette if necessary.

[0003] Filters used in cigarettes can be broadly classified into acetate filters, paper filters, and charcoal filters. The commonly manufactured acetate filters contain cellulose acetate tow, and activated carbon and plasticizers are added to the cigarette filter.

[0004] The above-mentioned background art is owned or acquired by the inventors in the process of deriving the contents of the disclosure of this application, and is not necessarily publicly known art that was disclosed to the general public prior to the filing of this application. Summary of the Invention [Problem to be solved by the invention]

[0005] SUMMARY OF THE DISCLOSURE In order to solve the above-mentioned problems, the present invention seeks to provide a cigarette filter comprising paper.

[0006] According to one embodiment of the present invention, there is provided a granule-containing cigarette filter, which contains a large amount of granules and a moisturizing agent.

[0007] According to one embodiment of the present invention, there is provided a method for producing a cigarette filter containing granules.

[0008] However, the problems to be solved by the present invention are not limited to those mentioned above, and other problems not mentioned will be clearly understood by a person having ordinary skill in the relevant technical field from the following description. [Means for solving the problem]

[0009] A cigarette filter according to one embodiment of the present invention may include a paper filter formed by wrapping a base paper, a humectant applied to at least a portion of the surface of the paper filter, granules bound with the humectant, and a filter wrapper surrounding the paper filter.

[0010] A cigarette according to one embodiment of the present invention may include a cigarette column portion, a cigarette filter portion located on one side of the tobacco shredded portion and including one or more cigarette filters, and tip paper wrapping a portion of the tobacco shredded portion and the cigarette filter portion.

[0011] A method for manufacturing a cigarette filter according to one embodiment of the present invention may include the steps of crimping a base paper to produce a crimped paper, applying a humectant to the crimped paper through a plurality of nozzles, injecting granules onto the humectant-containing paper, and wrapping the paper with the granules attached thereto with a filter wrapper. Effect of the Invention

[0012] The present invention can provide a cigarette filter comprising paper.

[0013] According to one embodiment of the present invention, there is provided a granule-containing cigarette filter, which contains a large amount of granules and a moisturizing agent.

[0014] According to one embodiment of the present invention, there is provided a method for producing a cigarette filter containing granules. [Brief description of the drawings]

[0015] [Figure 1] 1 is a perspective view showing a cigarette according to an embodiment of the present invention; [Diagram 2] 1 is a cross-sectional view of a tobacco shredded portion according to one embodiment of the present invention. [Diagram 3] 2 is a flowchart showing a manufacturing process of a tobacco filter according to one embodiment of the present invention. [Figure 4] 1 is a schematic diagram of a tobacco filter manufacturing apparatus according to one embodiment of the present invention; [Diagram 5] 2 is a conceptual diagram showing a method of applying a moisturizer in a moisturizer application device according to an embodiment of the present invention; DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0016] Hereinafter, the embodiments will be described in detail with reference to the accompanying drawings. However, since various modifications can be made to the embodiments, the scope of the patent application is not limited or restricted by these embodiments. It should be understood that all modifications, equivalents, or alternatives to the embodiments are included in the scope of the patent.

[0017] The terms used in the examples are merely used for the purpose of explanation and should not be construed as limiting. A singular expression includes a plural expression unless the context clearly indicates otherwise. In this specification, the terms "include" or "have" and the like specify the presence of the features, numbers, steps, operations, components, parts, or combinations thereof described in the specification, and should be understood not to preclude the presence or additional possibility of one or more other features, numbers, steps, operations, components, parts, or combinations thereof.

[0018] Unless otherwise defined, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by a person of ordinary skill in the art to which the embodiments belong. Terms defined in commonly used dictionaries should be interpreted as meanings consistent with the meanings they have in the context of the relevant art, and unless expressly defined in this application, they should not be interpreted as ideal or overly formal meanings.

[0019] In the description with reference to the accompanying drawings, the same reference numerals are used for the same components regardless of the reference numerals, and the duplicated description thereof will be omitted. When it is determined that the detailed description of the related publicly known technology may unnecessarily obscure the gist of the embodiment, the detailed description thereof will be omitted.

[0020] Furthermore, in describing components of the embodiments, terms such as first, second, A, B, (a), (b), etc. may be used. These terms are used to distinguish the components from other components, and do not limit the nature, order, or sequence of the components. When a component is described as being "coupled," "coupled," or "connected" to another component, it should be understood that the component is directly coupled or connected to the other component, but that other components are "coupled," "coupled," or "connected" between each component.

[0021] Components included in any of the embodiments and components having common functions will be described using the same names in other embodiments. Unless otherwise specified, the description of any of the embodiments may be applied to the other embodiments, and detailed description will be omitted to the extent that they overlap.

[0022] FIG. 1 is a perspective view showing a cigarette according to one embodiment of the present invention.

[0023] According to one embodiment, the cigarette 1 may include a cigarette column portion 10, a cigarette filter portion 20 located on one side of the tobacco column portion 10, and tip paper 30 wrapping a portion of the tobacco column portion 10 and the cigarette filter portion 20.

[0024] According to one embodiment, the tobacco filter part 20 may include one or more tobacco filters. According to one embodiment, the tobacco filter part 20 may include a single tobacco filter, or may include two or more tobacco filters positioned consecutively in the longitudinal direction of the cigarette 1.

[0025] According to one embodiment, heating of the shredded tobacco portion 10 of the cigarette 1 generates mainstream smoke which can be inhaled longitudinally of the cigarette 1 from the shredded tobacco portion 10 through the cigarette filter portion 20 by the user.

[0026] According to one embodiment, the "longitudinal direction" may refer to the longitudinal direction of the tobacco 1, the tobacco shredded part 10 and / or the tobacco filter part 20, and more specifically, may refer to the direction aligned with the height of the cylindrical tobacco 1, the tobacco shredded part 10 and / or the tobacco filter part 20. The "longitudinal direction" may have the same meaning throughout this specification.

[0027] FIG. 2 is a cross-sectional view of a tobacco shredded portion according to one embodiment of the present invention.

[0028] According to one aspect of the present invention, the cigarette filter part 20 may include a cigarette filter 200 and a tipping paper 30 that wraps the cigarette filter 200. According to one embodiment, the cigarette filter 200 may include a paper filter 210 and a filter wrapper 220 that surrounds the paper filter 210. The paper filter 210 may be made by crimping a base paper. The base paper may be crimped to produce a crimped paper. Here, the crimping process refers to a process in which the base paper is compressed and crumpled, and the base paper may be processed by passing it between two or more rollers.

[0029] According to one embodiment, the cigarette filter 200 may include a humectant applied to at least a portion of the surface of the paper filter 210. The humectant may be sprayed onto all or a portion of the surface of the paper filter 210. The cigarette filter 200 may achieve a desired level of pressure drop (PD) by including the paper filter 210 containing a humectant. The pressure drop may refer to the air resistance felt by a user when inhaling air by biting a cigarette. Since the smoking satisfaction felt by a user may vary depending on the pressure drop, it is necessary to achieve a desired pressure drop.

[0030] According to one embodiment, the cigarette filter 200 includes granules, and the granules can be bound to a humectant. The humectant can be sprayed onto all or part of the surface of the paper filter 210, and the granules can be added to the paper filter 210 impregnated with the propellant to bind the humectant to the granules. The humectant can act as a binder that binds the granules to the paper, and can prevent the granules from falling off the paper filter 210. If the granules are added to an area of ​​the surface of the paper filter 210 where the humectant is not applied, they cannot be sufficiently bonded to the paper filter 210 and may fall off.

[0031] According to an embodiment, the granules may be present in an amount of 0.3% to 5% by mass based on the entire cigarette filter portion 20 .

[0032] According to one embodiment, the filter wrapper 220 may have a constant thickness d1, and the tipping paper 30 wrapping the cigarette filter 200 may have a constant thickness d2.

[0033] According to one embodiment, the filter wrapping paper 220 is cylindrical and can surround the paper filter 210. The thickness d1 of the filter wrapping paper 220 can be about 5 μm to about 30 μm. According to one embodiment, when the filter wrapping paper 220 has the thickness d1 in the above-mentioned range, heat can be appropriately transferred throughout the cigarette filter 200 as a whole, and leakage of liquid components (e.g., humectant) from the inside of the cigarette filter 200 to the outside can be prevented or reduced. According to one embodiment, when the filter wrapping paper 220 has the thickness d1 in the above-mentioned range, the tensile strength of the filter wrapping paper 220 can be improved.

[0034] According to one embodiment, the filter paper 220 may include at least one of aluminum (Al), copper (Cu), zinc (Zn), gold (Au) and iron (Fe). According to one embodiment, the filter paper 220 may be cylindrical and made of a thin metal film, for example, the filter paper 220 may be cylindrical and made of aluminum foil, copper foil or silver foil. According to one embodiment, the filter paper 220 may be cylindrical and made of a thin metal film, so that heat can be appropriately transferred throughout the cigarette filter 200, and leakage of liquid components (e.g., humectants) from the inside to the outside of the cigarette filter 200 can be prevented or reduced.

[0035] According to one embodiment, the thickness d2 of the tipping paper 30 may be about 5 μm to about 30 μm. According to one embodiment, the tipping paper 30 may wrap a part of the tobacco shredded grass portion 10 and the tobacco filter portion 20, and the filter wrapper paper 220 of the cigarette filter 200 may be surrounded by the tipping paper 30.

[0036] According to one embodiment, tipping paper 30 can include cellulose or dextrin. For example, tipping paper 30 can include cellulose.

[0037] According to one embodiment, the total thickness (d1+d2) of the filter wrapper 220 and the tipping paper 30 may be about 30 μm to 100 μm. According to one embodiment, by having the total thickness (d1+d2) of the filter wrapper 220 and the tipping paper 30 within the above-mentioned numerical range, it is possible to prevent or reduce leakage of liquid components (e.g., humectant) from inside the cigarette filter 200 to the outside.

[0038] According to one embodiment, the base paper is for manufacturing the paper filter 210 included in the cigarette filter 200. According to one embodiment, the performance (e.g., suction resistance) of the cigarette filter 200 can be determined according to the type of base paper (base paper 401 in FIG. 4) and physical and chemical properties such as surface characteristics (e.g., porosity, moisture permeability). According to one embodiment, the characteristics of the moisturizer applied to the surface of the base paper and its adhesive strength with the granules can be improved according to the type and surface characteristics of the base paper.

[0039] According to one embodiment, the base paper has low porosity. According to one embodiment, if the base paper has many pores, the humectant may be easily absorbed into the pores and may not remain well on the surface of the base paper. According to one embodiment, the porosity of the base paper can be calculated by measuring the Gurley porosity using TAPPI T460, and the porosity of the base paper is 10s / 100cc. 3 According to one embodiment, the porosity of the base paper can be 9s / 100cc. 3 Below, 8s / 100cc 3 Below, 7s / 100cc 3 Below, 6s / 100cc 3 Below, 5s / 100cc 3 Below, 4s / 100cc 3 Below, 3s / 100cc 3 Below, 2s / 100cc 3Less than or equal to 1s / 100cc 3 It can be the following:

[0040] According to one embodiment, the porosity of the base paper is 10s / 100cc. 3 In the following cases, the moisturizer can easily remain on the surface of the base paper and the adhesive strength with the added granules can be improved. According to one embodiment, the porosity of the base paper is 10s / 100cc. 3 The stability and dispersibility of the granules can be increased in the following cases:

[0041] According to one embodiment, the lower the basis weight and thickness of the base paper, the wider the base paper of the paper filter 210 applied to the cigarette filter 200 can be, and the adhesive strength with the granules and the stability of the granules can be improved. 2 ~30g / m 2 According to one embodiment, the base paper has a basis weight of 15 g / m 2 More than 16g / m 2 More than 17g / m 2 More than 18g / m 2 More than 19g / m 2 More than 20g / m 2 More than 21g / m 2 More than 22g / m 2 More than 23g / m 2 More than 24g / m 2 More than 25g / m 2 More than 26g / m 2 More than 27g / m 2 More than 28g / m 2 or more than 29g / m 2 or more than 29 g / m 2 Below 28g / m 2 Below 27g / m 2 Below, 26g / m 2 Below 25g / m 2 Below 24g / m 2 Below 23g / m 2 Below, 22g / m 2 Below, 21g / m 2 Below 20g / m 2 Below, 19g / m 2Below 18g / m 2 Below, 17g / m 2 Less than or equal to 16g / m 2 It may be less than or equal to 16 g / m2 or may be included in a range between any two selected from the above values. According to one embodiment, the basis weight of the base paper is preferably 16 g / m2 or less. 2 ~26.5g / m 2 It can be.

[0042] According to one embodiment, the base paper may have a width between 200mm and 300mm. According to one embodiment, the width of the base paper is a factor that determines the circumference of the paper filter 210 of the cigarette filter 200, and the paper filter 210 is crimped by crimping the base paper, and may be formed by rolling the base paper in a direction perpendicular to the longitudinal direction of the cigarette 1. According to one embodiment, the width of the base paper may determine the circumference of the cylindrical paper filter 210 included in the cigarette filter 200. According to one embodiment, the width of the base paper may be measured as the length perpendicular to the longitudinal direction of the cigarette 1 when the rolled paper filter 210 is spread out on a flat surface.

[0043] According to one embodiment, the width of the base paper may be 200mm or more, 210mm or more, 220mm or more, 230mm or more, 240mm or more, 250mm or more, 260mm or more, 270mm or more, 280mm or more, or 290mm or more, or 290mm or less, 280mm or less, 270mm or less, 260mm or less, 250mm or less, 240mm or less, 230mm or less, 220mm or less, or 210mm or less, or may be included in a range between two selected from the above values.

[0044] According to one embodiment, if the width of the base paper is outside the above numerical range, the circumference of the cylindrical paper filter 210 formed by rolling the base paper may be excessively small or large, and when manufacturing a cylindrical paper filter 210 having the same circumference as the tobacco shredded part 10, the space inside the cigarette filter 200 may be excessively remaining or narrow, which may reduce the ability to remove harmful components from mainstream smoke and / or the ability to pass mainstream smoke.

[0045] According to one embodiment, the product of the width and basis weight of the base paper may be 5.2 g / m to 5.6 g / m. According to one embodiment, when the product of the width and basis weight of the base paper is within the above numerical range, it may be easy to manufacture the filter smoothly and achieve suction resistance (e.g., about 80 mmWG). Also, according to one embodiment, when the product of the width and basis weight of the base paper is within the above numerical range, it may exhibit characteristics that granules put into the paper filter 210 are easily settled without falling off, and the uniformity of the smoking taste felt by the user of the cigarette 1 may be improved.

[0046] According to one embodiment, the paper filter 210 is cylindrical and has a circumference of 20 mm to 25 mm. According to one embodiment, the paper filter 210 is formed by winding a base paper in a cylindrical shape. According to one example, the paper filter 210 may be cylindrical, preferably having a circumference of 20 mm to 24 mm, more preferably having a circumference of 21 mm to 23 mm. According to one embodiment, the paper filter 210 is formed by winding a paper crimped by crimping the base paper, and is manufactured by winding the base paper so that it has a cylindrical shape when wound. At this time, the circumference of the paper filter 210 is measured by measuring the circumference of the bottom surface after winding in a cylindrical shape, and since the thickness of the filter wrapping paper 220 is thinner than that of the paper filter, it is replaced by measuring the circumference of the cigarette filter 200.

[0047] According to an embodiment, a moisturizer may be applied to at least a portion of the surface of the paper filter 210, thereby allowing the moisturizer to remain on the surface of the paper filter 210. According to an embodiment, the moisturizer may include at least one of glycerin, guar gum, starch, methylcellulose, ethylene vinyl acetate (EVA), gum arabic, and propylene glycol.

[0048] According to one embodiment, if too much moisturizer is applied to the surface of the paper filter 210, the adhesion of the granules may decrease, and if too little moisturizer is applied to the surface of the paper filter 210, the granules may easily fall off. According to one embodiment, the amount of moisturizer applied to the surface of the paper filter 210 based on the longitudinal direction of the cigarette 1 and / or the paper filter 210 may be 0.5 mg / mm to 5 mg / mm. According to one embodiment, the amount of moisturizer applied to the surface of the paper filter 210 may be 4 mg / mm or less, 3 mg / mm or less, 2 mg / mm or less, or 1 mg / mm or less, and preferably 0.5 mg / mm to 4 mg / mm, 0.5 mg / mm to 3 mg / mm, or 0.5 mg / mm to 2 mg / mm.

[0049] According to an embodiment, the cigarette filter 200 may include granules. According to an embodiment, the granules may be introduced and seated on the paper filter 210, and at this time, the humectant may improve the bonding strength with the paper filter 210. According to an embodiment, the granules may have a coating layer formed on the surface. According to an embodiment, the coating layer formed on the surface of the granules may prevent the granules from cracking or breaking. The granules may be broken by the humectant, may be broken by external impact, or may naturally crack or break over time. According to an embodiment, the coating layer formed on the surface of the granules may protect the granules from external impact.

[0050] According to one embodiment, the coating layer may be selected from the group consisting of microcrystalline cellulose, anhydrous lactose, Cellactose 80 (co-processed 75% microcrystalline cellulose and 25% lactose), isomalt, dibasic dihydrate calcium phosphate, calcium carbonate, calcium lactate, dibasic anhydrous calcium phosphate, tribasic calcium phosphate, calcium silicate, calcium sulfate, carbomer, calcium carboxymethylcellulose, sodium carboxymethylcellulose, cellulose, silicified microcrystalline cellulose, cellulose acetate, ceratonia, chitosan, copovidone, corn starch, pregelatinized starch, and the like. starch, dextrate, dextrin, dextrose, erythritol, ethyl cellulose, fructose, fumaric acid, glyceryl monooleate, glyceryl monostearate, glyceryl palmitostearate, hydroxyethyl cellulose, hydroxyethyl methylcellulose, hydroxypropyl betadex, hydroxypropyl cellulose, hydroxypropyl starch, hypromellose, hypromellose acetate succinate, kaolin, lactitol, anhydrous lactose, lactose monohydratemonohydrate), magnesium carbonate, magnesium oxide, maltitol, maltodextrin, maltose, mannitol, methylcellulose, pectin, polaxamer, polycarbophil, polydextrose, poly(DL-lactic acid), polyethylene glycol, polyethylene oxide, polymethacrylate, polyoxyglyceride, polyvinyl alcohol, povidone, shellac, simethicone, sodium alginate, sodium chloride, sorbitol, starch, pregelatinized starch, sucrose, sugar spheres, sulfobutyl ether B-cyclodextrin, titanium dioxide, trehalose, microcrystalline wax, white wax, yellow wax, xanthan gum gum, xylitol, beeswax, candelilla, carnauba, caraway, sugarcane wax, myrtle wax, gum arabic, locust bean wax, guar gum, alginates, carrageenan, and pectin.

[0051] According to one embodiment, the coating layer may be selected from the group consisting of microcrystalline cellulose, anhydrous lactose, Cellactose 80 (co-processed 75% microcrystalline cellulose and 25% lactose), isomalt, dibasic dihydrate calcium phosphate, calcium carbonate, calcium lactate, dibasic anhydrous calcium phosphate, tribasic calcium phosphate, calcium silicate, calcium sulfate, carbomer, calcium carboxymethylcellulose, sodium carboxymethylcellulose, cellulose, silicified microcrystalline cellulose, cellulose acetate, ceratonia, chitosan, copovidone, corn starch, pregelatinized starch, and the like. starch, dextrate, dextrin, dextrose, erythritol, ethyl cellulose, fructose, fumaric acid, glyceryl monooleate, glyceryl monostearate, glyceryl palmitostearate, hydroxyethyl cellulose, hydroxyethyl methylcellulose, hydroxypropyl betadex, hydroxypropyl cellulose, hydroxypropyl starch, hypromellose, hypromellose acetate succinate, kaolin, lactitol, anhydrous lactose, lactose monohydratemonohydrate), magnesium carbonate, magnesium oxide, maltitol, maltodextrin, maltose, mannitol, methylcellulose, pectin, polaxamer, polycarbophil, polydextrose, poly(DL-lactic acid), polyethylene glycol, polyethylene oxide, polymethacrylate, polyoxyglyceride, polyvinyl alcohol, povidone, shellac, simethicone, sodium alginate, sodium chloride, sorbitol, starch, pregelatinized starch, sucrose, sugar spheres, sulfobutyl ether B-cyclodextrin, titanium dioxide, trehalose, microcrystalline wax, white wax, yellow wax, xanthan gum By including at least one of gum, xylitol, beeswax, candelilla, carnauba, caraway, sugarcane wax, myrtle wax, gum arabic, locust bean wax, guar gum, alginate, carrageenin, and pectin, it is possible to prevent the breakage of the granules due to the moisturizing agent.

[0052] According to one embodiment, the granules may have a packing density of 0.65 g / cc to 0.80 g / cc based on the entire cigarette filter 200. According to one embodiment, the packing density of the granules may be determined by the amount of the granules added, and by adding the granules so that the packing density of the granules is within the above numerical range, breakage of the granules may be prevented.

[0053] According to one embodiment, the packing density of the granules may be 0.65 g / cc or more, 0.70 g / cc or more, or 0.75 g / cc or more, or 0.80 g / cc or less, 0.75 g / cc or less, or 0.70 g / cc or less, or may be included in a range between any two selected of the above values.

[0054] According to an embodiment, the granules may include at least one of activated carbon, chopped herb granules, and red ginseng powder granules. For example, the granules may be activated carbon.

[0055] According to one embodiment, the granules are added to the paper filter 210 and can be settled on its surface, and can be added at 3 mg / mm to 5 mg / mm based on the longitudinal direction of the paper filter 210. According to one embodiment, the amount of granules added can be 3 mg / mm or more or 4 mg / mm or more, 5 mg / mm or less or 4 mg / mm or less, or can be included in a range between two selected from the above values.

[0056] According to one embodiment, when the amount of granules added is 3 mg / mm to 5 mg / mm, a cigarette filter can be manufactured that has an excellent smoking taste and good transfer rates of nicotine components and moisture in mainstream smoke.

[0057] According to one embodiment, the average diameter of the granules may be 0.45 mm to 0.60 mm. According to one embodiment, the average diameter of the granules may be 0.45 mm or more, 0.50 mm or more, or 0.55 mm or more, or 0.60 mm or less, 0.55 mm or less, or 0.50 mm or less, or may be included in a range between two selected from the above values.

[0058] According to one embodiment, the total sugar content of the granules may be 35% or more. According to one embodiment, the higher the sugar content of the granules, the more fragrant the tobacco taste may be. According to one embodiment, the total sugar content of the granules may be preferably 40% or more.

[0059] According to one embodiment, the paper filter 210 may have a water resistance of 5% or more. According to one embodiment, the paper filter 210 has a high water resistance so that the moisturizer can easily remain on the surface. According to one embodiment, the water resistance of the paper filter 210 may preferably be 10% or more.

[0060] According to one embodiment, the paper filter 210 may further include a flavoring agent. According to one embodiment, the flavoring agent may include a herbal flavoring. According to one embodiment, the flavoring agent may be dispersed on at least a portion of the surface of the paper filter 210.

[0061] According to an embodiment, the filter paper 220 may include a material that is heated by an induced magnetic field. According to an embodiment, the filter paper 220 may include at least one of aluminum (Al), copper (Cu), zinc (Zn), gold (Au), and iron (Fe). According to an embodiment, the filter paper 220 may be cylindrical and made of aluminum foil, copper foil, or silver foil. According to an embodiment, the material that is heated by an induced magnetic field may include at least one of aluminum foil, copper foil, and silver foil.

[0062] According to one embodiment of the present invention, a cigarette filter may include a paper filter formed by wrapping a base paper, a humectant applied to at least a portion of the surface of the paper filter, granules bound with the humectant, and a filter wrapper surrounding the paper filter.

[0063] According to one embodiment, the width of the base paper may be 200mm to 250mm.

[0064] According to one embodiment, the base paper is 15 g / m 2 ~30g / m 2 The sheet may have a basis weight of 100 g.

[0065] According to one embodiment, the product of the width and basis weight of the base paper may be 5.2 g / m to 5.6 g / m.

[0066] According to one embodiment, the paper filter may be cylindrical with a circumference of 20 mm to 25 mm.

[0067] According to an embodiment, the humectant may include at least one of glycerin, guar gum, starch, methylcellulose, ethylene vinyl acetate (EVA), gum arabic, and propylene glycol.

[0068] According to one embodiment, the amount of the moisturizer applied may be 1 mg / mm to 5 mg / mm based on the longitudinal direction of the paper filter.

[0069] According to one embodiment, the paper filter can have a water resistance of 5% or more.

[0070] According to one embodiment, the granules may be included at 3 mg / mm to 6 mg / mm based on the length of the paper filter.

[0071] According to an embodiment, the granules may have a coating layer formed on the surface.

[0072] According to one embodiment, the coating layer may be selected from the group consisting of microcrystalline cellulose, anhydrous lactose, Cellactose 80 (co-processed 75% microcrystalline cellulose and 25% lactose), isomalt, dibasic dihydrate calcium phosphate, calcium carbonate, calcium lactate, dibasic anhydrous calcium phosphate, tribasic calcium phosphate, calcium silicate, calcium sulfate, carbomer, calcium carboxymethylcellulose, sodium carboxymethylcellulose, cellulose, silicified microcrystalline cellulose, cellulose acetate, ceratonia, chitosan, copovidone, corn starch, pregelatinized starch, and the like. starch, dextrate, dextrin, dextrose, erythritol, ethyl cellulose, fructose, fumaric acid, glyceryl monooleate, glyceryl monostearate, glyceryl palmitostearate, hydroxyethyl cellulose, hydroxyethyl methylcellulose, hydroxypropyl betadex, hydroxypropyl cellulose, hydroxypropyl starch, hypromellose, hypromellose acetate succinate, kaolin, lactitol, anhydrous lactose, lactose monohydratemonohydrate), magnesium carbonate, magnesium oxide, maltitol, maltodextrin, maltose, mannitol, methylcellulose, pectin, polaxamer, polycarbophil, polydextrose, poly(DL-lactic acid), polyethylene glycol, polyethylene oxide, polymethacrylate, polyoxyglyceride, polyvinyl alcohol, povidone, shellac, simethicone, sodium alginate, sodium chloride, sorbitol, starch, pregelatinized starch, sucrose, sugar spheres, sulfobutyl ether B-cyclodextrin, titanium dioxide, trehalose, microcrystalline wax, white wax, yellow wax, xanthan gum gum, xylitol, beeswax, candelilla, carnauba, caraway, sugarcane wax, myrtle wax, gum arabic, locust bean wax, guar gum, alginates, carrageenan, and pectin.

[0073] According to one embodiment, the granules may have a packing density of 0.65 g / cc to 0.80 g / cc based on the entire cigarette filter.

[0074] According to an embodiment, the granules may include at least one of activated carbon, chopped herb granules, and red ginseng cake granules.

[0075] According to one embodiment, the loading amount of the granules may be 3 mg / mm to 5 mg / mm based on the longitudinal direction of the paper filter.

[0076] According to one embodiment, the average diameter of the granules may be between 0.45 mm and 0.60 mm.

[0077] According to one embodiment, the total sugar content of the granules may be greater than or equal to 35%.

[0078] According to one embodiment, the paper filter may further include a flavoring agent.

[0079] According to one embodiment of the present invention, a cigarette may include a cigarette column portion, a cigarette filter portion located on one side of the tobacco column portion and including one or more cigarette filters, and tip paper encasing a portion of the tobacco column portion and the cigarette filter portion.

[0080] According to one embodiment, the granules may be present in an amount of 0.3% to 5% by mass based on the entire cigarette filter portion.

[0081] According to one embodiment, the tipping paper may include at least one of aluminum (Al), copper (Cu), zinc (Zn), gold (Au), and iron (Fe).

[0082] FIG. 3 is a flowchart showing a manufacturing process for a tobacco filter according to one embodiment of the present invention.

[0083] A method for manufacturing a cigarette filter according to another aspect of the present invention may include step 310 of crimping a base paper to produce a crimped paper, step 320 of applying a humectant to the crimped paper through a plurality of nozzles, step 330 of injecting granules onto the humectant-containing paper, and step 340 of wrapping the paper with the granules attached thereto in a filter wrapper.

[0084] FIG. 4 is a schematic diagram of a tobacco filter manufacturing apparatus according to one embodiment of the present invention.

[0085] Referring to FIG. 4, a manufacturing apparatus for manufacturing the tobacco filter (the tobacco filter 20 of FIG. 1) can be seen.

[0086] According to an embodiment, step 310 of crimping the base paper to generate a crimped paper may be performed by a first roller 411 and a second roller 412, and the base paper 401 may be crimped to generate a crimped paper. According to an embodiment, the base paper 401 may be inserted into a gap between the first roller 411 and the second roller 412, and at this time, the base paper 401 may be transported by various transport means. According to an embodiment, the transport means for the base paper 401 may be composed of rollers, a conveyor belt, or both. Depending on the number and / or arrangement of the rollers and / or conveyor belts, various transport paths for the base paper 401 may be set.

[0087] According to an embodiment, the transport path of the raw paper 401 may be set in various ways, and according to one example, it may be set to a straight path, a curved path, or a U-shaped path. However, the transport path of the raw paper 401 may be determined by various factors such as the arrangement of the processing device, and is not limited to the above-mentioned types of paths.

[0088] According to one embodiment, the first roller 411 and the second roller 412 may compress and crumple the base paper 401 to perform crimping. According to one embodiment, the first roller 411 and the second roller 412 may rotate in opposite directions to each other to transport the base paper 401 that has undergone the crimping process to the next processing device. The base paper 401 may be subjected to the crimping process to generate crimped paper 402, and sufficient tensile force may be applied to the crimped paper 402. According to one embodiment, the crimped paper 402 may pass through the moisturizer injection device 420 while suspended in the air.

[0089] According to an embodiment, the first roller 411 and the second roller 412 may each include projections and recesses in order to effectively compress and crumple the base paper 401. According to an embodiment, the crimping process may be smoothly performed by the rotational force of the first roller 411 and the second roller 412, and the base paper 401 may be appropriately compressed and crumpled to be suitable for application of a moisturizing agent, thereby producing the crimped paper 402.

[0090] According to one embodiment, the paper 402 that has been crimped by applying a moisturizer 320 can be coated with a moisturizer through a plurality of nozzles to produce moisturizer-containing paper 403. According to one embodiment, the step 320 of applying a moisturizer can be performed through a moisturizer applicator 420.

[0091] According to one embodiment, the step 320 of applying the moisturizer may be performed by spraying 0.5 mg / mm to 5 mg / mm of moisturizer based on the longitudinal direction of the crimped paper 403. According to one embodiment, the amount of moisturizer applied may be 4 mg / mm or less, 3 mg / mm or less, 2 mg / mm or less, or 1 mg / mm or less, and preferably 0.5 mg / mm to 4 mg / mm, 0.5 mg / mm to 3 mg / mm, or 0.5 mg / mm to 2 mg / mm.

[0092] FIG. 5 is a conceptual diagram showing a method for applying a moisturizer in a moisturizer application device according to one embodiment of the present invention.

[0093] 5(a), the moisturizer application device 420 may include a plurality of nozzles 501. According to one embodiment, the crimped paper 402 may be transported at a certain distance from the nozzles 501, and the moisturizer sprayed from the nozzles 501 may be applied to the surface of the crimped paper 402. According to one embodiment, in the step 330 of producing paper containing moisturizer, the moisturizer may be sprayed from the nozzles 501 positioned at a distance from the crimped paper 402. According to one embodiment, the nozzles 501 may be positioned at a distance from the crimped paper 402.

[0094] According to one embodiment, the nozzle 501 may be positioned at a distance upward from the transport path of the crimped paper 402. When the nozzle 501 sprays the moisturizer in a fixed direction, the moisturizer may be applied to the crimped paper 402 as it moves along the transport path. According to one embodiment, if the transport path of the crimped paper 402 is linear, the traces 504 of the moisturizer sprayed on the crimped paper 402 may be formed in a linear row.

[0095] According to one embodiment, a plurality of nozzles 501 may be used to uniformly apply moisturizer onto the crimped paper 402. For example, 2 to 10 nozzles 501 may be used, and the plurality of nozzles 501 may be arranged in a line perpendicular to the transport path of the crimped paper 402. According to one embodiment, the number of nozzles 501 is preferably two or three.

[0096] According to one embodiment, the plurality of nozzles 501 each spray humectant in a certain direction, so that the humectant is sprayed on the crimped paper 402 to form a plurality of parallel marks 504. The humectant can be sprayed at the same time by the number of nozzles 501, so that the humectant content of the crimped paper 402 can be improved. According to one embodiment, the humectant content of the crimped paper 402 can be improved, so that the conditioning period can be shortened and it can be easy to achieve a desired suction resistance.

[0097] Here, the conditioning period may refer to the period during which the humectant is absorbed and spread evenly on the paper filter of the cigarette filter. In order to shorten the conditioning period, it may be necessary to apply the humectant as evenly as possible to the paper in the step 320 of applying the humectant so that the humectant spreads quickly throughout the paper.

[0098] 5(b) and 5(c) are conceptual diagrams of the nozzle 501 ejecting from the perspective of the transport path of the crimped paper 402. Referring to FIG. 5(b) and FIG. 5(c), the multiple nozzles 501 may include a first nozzle 502 and a second nozzle 503, and the axes of the first nozzle 502 and the second nozzle 503 may form a certain angle with the vertical direction of the crimped paper 402. According to one embodiment, the multiple nozzles 501 may be disposed to be spaced apart from each other. For example, the axis of the first nozzle 502 may form a first angle (θ1) with the vertical direction of the crimped paper 402, and the axis of the second nozzle 503 may form a second angle (θ2) with the vertical direction of the crimped paper 402.

[0099] According to an embodiment of Fig. 5(b), the first angle (θ1) and the second angle (θ2) can each be 0 degrees. According to an embodiment of Fig. 5(c), the first angle (θ1) and the second angle (θ2) can each be 15 degrees to 45 degrees.

[0100] According to one embodiment, the plurality of nozzles includes a first nozzle 502 and a second nozzle 503, each of which is twisted toward each other with respect to a vertical direction of the crimped paper 402. According to one embodiment, the axes of the first nozzle 502 and the second nozzle 503 may form a first angle (θ1) and a second angle (θ2) with the vertical direction of the crimped paper 402, respectively, and the vertical line of the crimped paper 402, the axis of the first nozzle 502, and the axis of the second nozzle 503 may be located on a single plane.

[0101] According to an embodiment, the axis of the first nozzle 502 is angled from 15 degrees to 45 degrees toward the second nozzle 503 with respect to the vertical direction of the crimped paper 402, and the axis of the second nozzle 503 is angled from 15 degrees to 45 degrees toward the first nozzle 502 with respect to the vertical direction of the crimped paper 402. According to an embodiment, a first angle (θ1) formed by the axis of the first nozzle 502 and the vertical direction of the crimped paper 402 may be formed toward the second nozzle, and the first angle (θ1) may be 15 degrees to 45 degrees. According to an embodiment, a second angle (θ2) formed by the axis of the second nozzle 503 and the vertical direction of the crimped paper 402 may be formed toward the first nozzle, and the second angle (θ2) may be 15 degrees to 45 degrees.

[0102] According to one embodiment, the axes of the first nozzle 502 and the second nozzle form a certain angle with the vertical direction of the crimped paper 402, so that the moisturizer can be sprayed evenly onto the crimped paper 402, and the moisturizer can be applied evenly to the sides of the crimped paper 402 without being biased toward the center of the crimped paper 402.

[0103] According to an embodiment, the step of applying the moisturizer 320 may be performed by heating the moisturizer to 80° C. to 120° C. According to an embodiment, the step of applying the moisturizer 320 may be performed by heating the moisturizer to 80° C. to 120° C. 2 ~0.08Ns / m 2 According to one embodiment, the viscosity of the moisturizer can be measured at a temperature range of 60° C. to 120° C. According to one embodiment, the moisturizer preferably has a viscosity of 0.014 Ns / m 2 ~0.03Ns / m 2 According to one embodiment, the viscosity of the moisturizer may decrease as the temperature at which it is measured increases, and the moisturizer according to one embodiment has a viscosity of 0.008 Ns / m measured at 100° C. 2 ~0.03Ns / m 2 It can be.

[0104] According to an embodiment, the humectant may include at least one of glycerin, guar gum, starch, methylcellulose, ethylene vinyl acetate (EVA), gum arabic, and propylene glycol.

[0105] According to one embodiment, the moisturizer may be added with tobacco extract. According to one embodiment, in the case of a cigarette filter including a moisturizer to which tobacco extract is added (e.g., the cigarette filter 200 of FIG. 2), aerosol and nicotine can be generated simultaneously when heated.

[0106] According to one embodiment, the tobacco extract may contain at least one of nicotine salt, nicotine, nicotine base, free nicotine, and nicotine derivatives. For example, nicotine salt is a substance naturally formed in tobacco leaves, and may be produced by reacting nicotine with an acid substance. The acid substance may include lactic acid or pyruvic acid, and it will be readily understood by those of ordinary skill in the art that it may further include organic acids that may react with nicotine to form nicotine salts.

[0107] According to one embodiment, the moisturizing agent-containing paper 403 produced in the moisturizing agent application step 320 can be used to produce the paper 404 with granules attached thereto in the granule addition step 330. According to one embodiment, the granule addition step 330 is performed by randomly adding granules onto the moisturizing agent-containing paper 403 in a granule addition device 430, specifically, the granules are attached onto the moisturizing agent.

[0108] According to one embodiment, the paper 404 on which the granules are placed, which is produced in the step 330 of feeding the granules, may be wrapped in filter paper in the step 340. According to one embodiment, the paper 404 on which the granules are placed may be transported and collected in one place through the discharge port 440. According to one embodiment, the discharge port 440 has a wide entrance and a narrow exit, so that the paper 404 on which the granules are placed may be collected in a narrow cylindrical space.

[0109] According to one embodiment, the paper 404 on which the granules are seated is collected in a form suitable for being wrapped in filter paper as it passes through the outlet 440. According to one embodiment, the outlet 440 may have a shape with a wide entrance, gradually narrowing to a circular exit having a diameter similar to that of a cigarette (e.g., cigarette 1 in FIG. 1). According to one embodiment, as the paper 404 on which the granules are seated passes through the outlet 440, it is wound to a diameter similar to that of a cigarette, and the paper filter thus formed (e.g., paper filter 210 in FIG. 2) can be discharged through the outlet of the outlet 440.

[0110] According to one embodiment, the paper 404 on which the granules are seated and discharged through the outlet 440 can be wrapped with filter paper (e.g., filter paper 220 in FIG. 2). According to one embodiment, the paper 404 on which the granules are seated can be wrapped with filter paper to manufacture a cigarette filter 405. According to one embodiment, the paper 404 on which the granules are seated and discharged through the outlet 440 can be wrapped and fixed with filter paper to prevent loosening due to a restoring force.

[0111] According to one embodiment, the steps of producing crimped paper 310, applying moisturizer 320, dosing granules 330 and wrapping with filter paper 340 can each be carried out along a pre-established path.

[0112] According to one embodiment of the present invention, a method for manufacturing a cigarette filter includes the steps of crimping a base paper to produce a crimped paper, applying a humectant to the crimped paper through a plurality of nozzles, injecting granules onto the humectant-containing paper, and wrapping the paper with the granules attached thereto with a filter wrapper.

[0113] According to an embodiment, the step of applying the moisturizer may be performed by spraying the moisturizer at 0.5 mg / mm to 5 mg / mm in the longitudinal direction of the crimped paper.

[0114] According to one embodiment, the plurality of nozzles can be two or three.

[0115] According to one embodiment, the step of producing paper containing a moisturizing agent may include spraying the moisturizing agent from a plurality of nozzles positioned to be spaced apart from the crimped paper.

[0116] According to one embodiment, multiple nozzles can be spaced apart relative to the crimped paper.

[0117] According to one embodiment, the nozzles are spaced apart from one another, and the axes of the nozzles are at an angle of 15 degrees to 45 degrees with respect to the perpendicular direction of the crimped paper.

[0118] According to one embodiment, the plurality of nozzles includes a first nozzle and a second nozzle, the axis of the first nozzle being angled from 15 degrees to 45 degrees toward the second nozzle relative to the vertical direction of the crimped paper, and the axis of the second nozzle being angled from 15 degrees to 45 degrees toward the first nozzle relative to the vertical direction of the crimped paper.

[0119] According to one embodiment, the step of producing paper containing a humectant comprises applying the humectant by heating it to 80°C to 120°C.

[0120] According to one embodiment, the humectant has a viscosity of 0.008 Ns / m 2 ~0.08Ns / m 2 It can be.

[0121] According to an embodiment, the humectant may include at least one of glycerin, guar gum, starch, methylcellulose, ethylene vinyl acetate (EVA), gum arabic, and propylene glycol.

[0122] According to one embodiment, the humectant may be tobacco extract.

[0123] According to one embodiment, the tobacco extract may include at least one of nicotine salts, nicotine, nicotine base, free nicotine, and nicotine derivatives.

[0124] According to one embodiment, the filter paper may include a material that is heated by an induced magnetic field.

[0125] According to one embodiment, the material heated by the induction magnetic field may include at least one of aluminum foil, copper foil, and silver foil.

[0126] According to one embodiment, the steps of producing the crimped paper, applying the moisturizer, dosing the granules and wrapping with the filter paper can each be transported and performed along a pre-established path.

[0127] The present invention will now be described in more detail with reference to examples and comparative examples.

[0128] However, the following examples are for illustrative purposes only and are not intended to limit the scope of the present invention.

[0129] [Experimental Example 1] In order to confirm the granule adhesion depending on the type and physical properties of the base paper, cigarette filters were manufactured using various base papers. The cigarette filters were manufactured by the steps of crimping the base paper to produce crimped paper, applying a humectant to the crimped paper through multiple nozzles, pouring granules onto the paper containing the humectant, and wrapping the paper with the granules attached with a filter wrapper. As shown in Table 1 below, various types of base papers were used, glycerin was applied as a humectant at 1 mg / mm, and shellac-coated activated carbon was added as granules at 5 mg / mm. The granule adhesion of cigarette filters according to various embodiments using different types of base paper according to Experimental Example 1 is shown in Table 1 below.

[0130] [Table 1]

[0131] Referring to Table 1 above, the more non-porous the base paper is, the better the granule adhesion is. 2 ~30g / m 2 It can be confirmed that the stability of the granules is good when the product of the width and basis weight of the base paper is 5.2 g / m to 5.6 g / m.

[0132] [Experimental Example 2] In order to evaluate the tobacco taste depending on the amount of granules added to a cigarette filter, cigarette filters were manufactured with various amounts of granules added. The cigarette filters were manufactured by the steps of crimping a base paper to produce crimped paper, applying a humectant to the crimped paper through a number of nozzles, adding granules onto the paper containing the humectant, and wrapping the paper with the granules attached in a filter wrapper. As shown in Table 2 below, evaluations were carried out with different amounts of granules added, and the base paper had a basis weight of 24 g / m. 2The non-porous paper was used, glycerin was applied as a moisturizing agent at 1 mg / mm, and shellac-coated activated carbon was used as granules. The shellac-coated activated carbon had an average diameter of 0.45 mm to 0.60 mm, and the total sugar content was 0.35%. The results of the evaluation of the taste of cigarette filters and cigarettes containing the same with different granule loading amounts in Experimental Example 2 are shown in Table 2 below.

[0133] [Table 2]

[0134] Referring to Table 2 above, it can be seen that when the amount of granules added is 3 mg / mm to 5 mg / mm, the amount of nicotine and moisture transfer is good, and cigarettes using such cigarette filters have a good smoking taste.

[0135] [Experimental Example 3] In order to evaluate the granule adhesion of different humectants in cigarette filters, cigarette filters were manufactured using various humectants. The cigarette filters were manufactured by the steps of crimping a base paper to produce crimped paper, applying a humectant to the crimped paper through multiple nozzles, injecting granules onto the humectant-containing paper, and wrapping the paper with the granules attached in a filter wrapper. As shown in Table 3 below, evaluations were carried out for different humectants, and the base paper was 24 g / m2 in basis weight. 2 The non-porous paper was used, and the moisturizer was applied at 1 mg / mm, and shellac-coated activated carbon was used as the granules. The granule adhesion according to the different types of moisturizers in Experimental Example 3 is shown in Table 3 below.

[0136] [Table 3]

[0137] Referring to Table 3 above, it can be seen that all of the moisturizing agents, EVA, guar gum, glycerin, and methylcellulose, can be used to improve the stability of the granules, and only slight differences can be seen in terms of the generation of unpleasant odors.

[0138] As described above, although the embodiments have been described with reference to limited drawings, those having ordinary skill in the art may apply various technical modifications and variations based on the above. For example, the described techniques may be performed in a different order than described, and / or the components of the described systems, structures, devices, circuits, etc. may be combined or combined in a different manner than described, or may be replaced or substituted by other components or equivalents, and still achieve appropriate results.

[0139] Therefore, other embodiments, other examples, and equivalents to the claims are within the scope of the following claims. [Explanation of symbols]

[0140] 1: Cigarettes 10: Tobacco shredded section 20: Cigarette filter section 30: Tip paper 200: Cigarette filters 210: Paper filter 220: Filter paper 401: Original paper 402: Crimped paper 403: Paper containing moisturizing agent 404: Paper with granules attached 405: Cigarette filters 411: First Roller 412: The second roller 420: Moisturizer dispenser 430: Granule feeding device 440: Outlet 501: Nozzle 502: First nozzle 503: Second nozzle 504: Trace

Claims

1. a paper filter formed by rolling up a base paper; A moisturizing agent is applied to at least a portion of the surface of the paper filter; Granules bound with the moisturizing agent; and a filter wrapper surrounding the paper filter. The width of the base paper is 200 mm to 250 mm, The base paper has a basis weight of 15 g / m 2 to 30 g / m 2 , The product of the width and basis weight of the base paper is 5.2 g / m to 5.6 g / m; Tobacco filters.

2. The paper filter is cylindrical with a circumference of 20 mm to 25 mm.

2. The cigarette filter according to claim 1.

3. The moisturizing agent includes at least one of glycerin, guar gum, starch, methylcellulose, ethylene vinyl acetate (EVA), gum arabic, and propylene glycol; 2. The cigarette filter according to claim 1.

4. The amount of the moisturizing agent applied is 1 mg / mm to 5 mg / mm based on the longitudinal direction of the paper filter.

2. The cigarette filter according to claim 1.

5. The paper filter further comprises a flavoring agent.

2. The cigarette filter according to claim 1.

6. Tobacco shredded section, a tobacco filter section located on one side of the tobacco shred section and including one or more tobacco filters; a tipping paper wrapping a portion of the tobacco shredded portion and the tobacco filter portion; At least one of the one or more tobacco filters comprises: a paper filter formed by rolling up a base paper; A moisturizing agent is applied to at least a portion of the surface of the paper filter; Granules bound with the moisturizing agent; and a filter wrapper surrounding the paper filter. The width of the base paper is 200 mm to 250 mm, The base paper has a basis weight of 15 g / m 2 to 30 g / m 2 , The product of the width and basis weight of the base paper is 5.2 g / m to 5.6 g / m; tobacco.

7. The granules are present in an amount of 0.3% by mass to 5% by mass based on the entire tobacco filter part.

7. The cigarette of claim 6.

8. The tip paper is made of aluminum (Al), copper (Cu), zinc (Zn), gold (Au ) and iron (Fe), 7. The cigarette of claim 6.

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