Hair cavity repair agent and hair cavity repair method using the same

Abstract

To provide a hair cavity repairing agent that repairs cavities inside the hair and improves the gloss and elasticity of the hair and a hair cavity repairing method using the same.SOLUTION: A hair cavity repairing agent comprises (A) an organic acid and (B) a diester of a dicarboxylic acid represented by the general formula 1 with polyoxyethylene monoalkyl ether represented by the general formula 2. Here, the general formula 1 is HO-CO-R1-CO-OH (in the formula, R1 represents a straight chain, a branched chain, or a cyclic hydrocarbon group having 2 to 10 carbon atoms) and the general formula 2 is R2-(OCH2CH2)n-OH (in the formula, R2 is a straight chain, a branched chain, or a cyclic hydrocarbon group having 1 to 12 carbon atoms, and n represents an integer from 2 to 11).SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a hair cavity repair agent containing an organic acid and a diester of a dicarboxylic acid and a polyoxyethylene monoalkyl ether, and a hair cavity repair method using the same. [Background technology]

[0002] Hair is continually damaged on a daily basis by chemical treatments such as perms, bleaching, and hair coloring, ultraviolet rays from sunlight, washing, heat from hair dryers, brushing, and so on. Numerous studies on such damaged hair have been conducted since ancient times. For example, Non-Patent Document 1 reports a study focusing on the interior of hair (medulla). According to this document, when cavities form in the medulla, diffused reflection of light causes hair to appear dull and lose its transparency. It also reports that such cavities are caused by everyday processes such as heat from a hair dryer or brushing. Patent Document 1 describes that low-molecular-weight compounds such as organic acids are effective in repairing such medulla. Patent Documents 2 and 3 also disclose hair cosmetics containing a combination of organic acids and specific organic solvents to improve the cavities inside hair that occur during coloring or drying with a hair dryer. However, these hair cosmetics are not necessarily effective in improving the cavities inside hair. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Patent Publication No. 2000-109411 [Patent Document 2] Patent Publication No. 2002-047142 [Patent Document 3] JP 2004-256551 [Non-patent literature]

[0004] [Non-Patent Document 1] FRAGRANCE JOURNAL June 2000 issue (pages 11-15) Summary of the Invention [Problem to be solved by the invention]

[0005] To provide a hair cavity repairing agent that repairs cavities inside hair and improves hair gloss and firmness, and a hair cavity repairing method using the same. [Means for solving the problem]

[0006] As a result of intensive research conducted by the inventors to solve the above problems, they discovered that a hair cavity repair agent containing the following components (A) and (B) solves the above problems, and thus completed the present invention. (A)Organic acid (B) Diester of dicarboxylic acid represented by Chemical Formula 1 and polyoxyethylene monoalkyl ether represented by Chemical Formula 2 (Chemical Formula 1) HO-CO-R1-CO-OH (wherein R1 represents a linear, branched, or cyclic hydrocarbon group having 2 to 10 carbon atoms) (Chemical formula 2)R2-(OCH2CH2)n-OH (wherein R2 is a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms; n represents an integer between 2 and 11. [Effects of the Invention]

[0007] By using the hair cavity repair agent of the present invention, it is possible to repair the cavities inside the hair, thereby improving the shine and firmness of the hair. DETAILED DESCRIPTION OF THE INVENTION

[0008] The present invention is a hair cavity repair agent containing the following components (A) and (B) as essential components. (A)Organic acid (B) Diester of dicarboxylic acid represented by Chemical Formula 1 and polyoxyethylene monoalkyl ether represented by Chemical Formula 2 (Chemical Formula 1) HO-CO-R1-CO-OH (wherein R1 represents a linear, branched, or cyclic hydrocarbon group having 2 to 10 carbon atoms) (Chemical formula 2)R2-(OCH2CH2)n-OH (wherein R2 is a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms; n represents an integer between 2 and 11.

[0009] Examples of organic acids used as component (A) in the present invention include acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, benzoic acid, salicylic acid, gallic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, phthalic acid, glycolic acid, lactic acid, malic acid, tartaric acid, citric acid, gluconic acid, levulinic acid, and ketoglutaric acid. These may be used alone or in combination of two or more. Of these, malonic acid, succinic acid, maleic acid, lactic acid, and malic acid are preferred.

[0010] The amount of component (A) used in the present invention to be blended into the hair cavity repair agent is not particularly limited, but is 0.001 to 10% by weight, preferably 0.005 to 5% by weight.

[0011] The diester of component (B) used in the present invention is used for the purpose of promoting penetration of component (A) into the interior of the hair. The dicarboxylic acid represented by Chemical Formula 1 constituting the diester is a dicarboxylic acid in which R1 represents a straight-chain, branched-chain, or cyclic hydrocarbon group having 2 to 10 carbon atoms, and specific examples include saturated straight-chain dicarboxylic acids such as succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, and dodecanedioic acid; saturated branched-chain dicarboxylic acids such as 2,2,4-trimethyladipic acid and 2,4,4-trimethyladipic acid; and cyclic dicarboxylic acids such as 1,2-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, phthalic acid, isophthalic acid, and terephthalic acid. Among these, from the viewpoints of availability, economy, penetration-promoting effect, etc., preferred saturated linear dicarboxylic acids are succinic acid, adipic acid, azelaic acid, sebacic acid, and dodecanedioic acid, and preferred cyclic dicarboxylic acids are 1,4-cyclohexanedicarboxylic acid, phthalic acid, and terephthalic acid. Of these, succinic acid, adipic acid, and 1,4-cyclohexanedicarboxylic acid are more preferred, with 1,4-cyclohexanedicarboxylic acid being most preferred.

[0012] On the other hand, in the polyoxyethylene monoalkyl ether represented by Chemical Formula 2 constituting the diester, R2 is a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms, and n is an integer of 2 to 11. Examples of linear, branched, or cyclic hydrocarbon groups having 1 to 12 carbon atoms include methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, n-pentyl, n-hexyl, cyclohexyl, n-octyl, 2-ethylhexyl, n-decyl, and n-dodecyl groups. From the viewpoints of reactivity during esterification, performance of the diester, and economic efficiency, methyl and ethyl groups are preferred, and ethyl is particularly preferred. Furthermore, from the viewpoints of economic efficiency, reactivity, and the like, n is preferably 2 or 3. As the polyoxyethylene monoalkyl ether represented by Chemical Formula 2, diethylene glycol monoethyl ether and triethylene glycol monoethyl ether are preferred, and diethylene glycol monoethyl ether is most preferred.

[0013] A preferred compound as the diester of component (B) used in the present invention is a combination of the preferred dicarboxylic acid and the preferred polyoxyethylene monoalkyl ether described above. Specifically, 1,4-cyclohexanedicarboxylic acid bis(diethylene glycol monoethyl ether) ester, 1,4-cyclohexanedicarboxylic acid bis(triethylene glycol monoethyl ether) ester, and adipic acid bis(diethylene glycol monoethyl ether) ester are preferred, and 1,4-cyclohexanedicarboxylic acid bis(diethylene glycol monoethyl ether) ester is most preferred.

[0014] The amount of component (B) used in the present invention to be blended into the hair cavity repair agent is not particularly limited, but is 0.001 to 5% by weight, preferably 0.005 to 2% by weight.

[0015] The hair cavity repair agent of the present invention preferably has a pH of 2 to 7, particularly 2 to 5. To obtain a preferred pH, an acid or alkali can be added to adjust the pH as appropriate.

[0016] The method for repairing cavities occurring inside hair using the hair cavity repair agent of the present invention is achieved by applying a composition containing the above-mentioned components (A) and (B) to the hair. After application, the hair may be washed with water and dried, if necessary.

[0017] The hair cavity repair agent of the present invention may contain, as needed, water and additional ingredients typically incorporated into cosmetics, such as oily bases, surfactants, alcohols, moisturizers, polymers, thickeners, gelling agents, antioxidants, preservatives, bactericides, chelating agents, pH adjusters, acids, alkalis, UV absorbers, whitening agents, solvents, exfoliants and dissolving agents, antipruritics, anti-inflammatory agents, antiperspirants, cooling agents, antihistamines, astringents, stimulants, hair growth agents and blood circulation promoters, reducing agents, oxidizing agents, polymer powders, hydroxy acids, vitamins and derivatives thereof, sugars and derivatives thereof, organic acids, enzymes, nucleic acids, hormones, inorganic powders, fragrances, pigments, etc., to an extent that does not impair the effects of the present invention.

[0018] Examples of oily bases include higher alcohols such as cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, arachyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, selachyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, 2-octyldodecanol, and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, and behenyl alcohol. Higher fatty acids such as carboxylic acid, undecylenic acid, 12-hydroxystearic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long-chain branched fatty acids, dimer acids, hydrogenated dimer acids, and their aluminum salts, calcium salts, magnesium salts, zinc salts, potassium salts, sodium salts, and other metal soaps, as well as nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefins Hydrocarbons such as polyisobutene oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum, and solid paraffin; waxes such as candelilla wax, carnauba wax, rice wax, Japan wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, Fischer-Tropsch wax, polyethylene wax, and ethylene-propylene copolymer; coconut oil, palm oil, palm kernel oil, safflower oil, olive oil, and castor oil. Vegetable oils and fats such as shiitake oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cocoa butter, shea butter, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, and hydrogenated jojoba oil; animal oils and fats such as beef tallow, milk fat, horse fat, egg yolk oil, mink oil, and turtle oil; animal waxes such as whale wax, lanolin, and orange roughy oil;Lanolin derivatives such as liquid lanolin, reduced lanolin, adsorbed purified lanolin, acetated lanolin, acetated liquid lanolin, hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acids, hard lanolin fatty acids, lanolin alcohol, acetated lanolin alcohol, and cetyl lanolyl acetate esters; phospholipids such as lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids such as sphingomyelin, phosphatidic acid, cyclic lysophosphatidic acid or its salts, and lysolecithin; phospholipid derivatives such as hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, and partially hydrogenated egg yolk phospholipid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, N-laurate Acyl sarcosine alkyl esters such as N-lauroyl-L-glutamic acid di(cholesteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamic acid di(cholesteryl / octyldodecyl), N-lauroyl-L-glutamic acid di(phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamic acid di(phytosteryl / octyldodecyl), and N-lauroylsarcosine isopropyl; sterol esters such as 12-hydroxystearate, cholesteryl macadamiate, phytosteryl macadamiate, phytosteryl sunflower seed oil fatty acid, phytosteryl isostearate, cholesteryl soft lanolinate, cholesteryl hard lanolinate, cholesteryl long-chain branched fatty acids, and cholesteryl long-chain α-hydroxy fatty acids; lipid complexes such as phospholipid-cholesterol complex and phospholipid-phytosterol complex;Octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl palmitate, octyldodecyl palmitate, cetyl octanoate, hexyldecyl octanoate, isotridecyl isononanoate, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, octyldodecyl lanolinate, dicaprylyl carbonate, hexyldecyl dimethyloctanoate, octyldodecyl erucate, hydrogenated castor oil isostearate, ethylene oleate monoalcohol carboxylic acid esters such as ethyl acrylate, avocado oil fatty acid ethyl, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, isopropyl lanolinate, methylheptyl laurate, methylheptyl myristate, methylheptyl palmitate, methylheptyl isostearate, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl adipate, dioctyl succinate, and triethyl citrate; oxyacid esters such as cetyl lactate, diisostearyl malate, hydrogenated castor oil monoisostearate, and γ-erucalactone;Glyceryl Trioctanoate, Glyceryl Trioleate, Glyceryl Triisostearate, Glyceryl Diisostearate, Caprylic / Capric Triglyceride, Caprylic / Capric / Myristic / Stearic Triglyceride, Hydrogenated Rosin Triglyceride (Hydrogenated Ester Gum), Rosin Triglyceride (Ester Gum), Glyceryl Behenate Eicosandioate, Trimethylolpropane Trioctanoate, Trimethylolpropane Triisostearate, Neopentyl Glycol Dioctanoate, Dicaprylate Neopentyl glycol dioctanoate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, pentaerythrityl hydrogenated rosin, ditrimethylolpropane triethylhexanoate, ditrimethylolpropane isostearate / sebacic acid, pentaerythrityl triethylhexanoate, dipentaerythrityl hydroxystearate / stearic acid / rosin acid, diglyceryl diisostearate, polyglyceryl tetraisostearate Polyol fatty acid esters such as ethylene glycol distearate, 3-methyl-1,5-pentanediol dineopentanoate, 2,4-diethyl-1,5-pentanediol dineopentanoate, polyglyceryl-10 nonaisostearate, polyglyceryl-8 deca(erucate / isostearate / ricinoleate), diglyceryl oligoester of hexyldecanoate / sebacic acid, glycol distearate, alkyl ethers such as dicaprylyl ether, diisopropyl dimer dilinoleate, dimer Derivatives of dimer acid or dimer diol such as diisostearyl dimer dilinoleate, di(isostearyl / phytosteryl) dimer dilinoleate, phytosteryl / behenyl dimer dilinoleate, phytosteryl / isostearyl / cetyl / stearyl / behenyl dimer dilinoleate, dimer dilinoleyl dimer dilinoleate, dimer dilinoleyl diisostearate, dimer dilinoleyl hydrogenated rosin condensate, hydrogenated castor oil dimer dilinoleate, and hydroxyalkyl dimer dilinoleyl ether;Fatty acid alkanolamides such as coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (palmitamide MEA), palmitic acid diethanolamide (palmitamide DEA), coconut oil fatty acid methylethanolamide (cocamide methyl MEA); dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyl trimethicone, diphenyl dimethicone, phenyl dimethicone, (aminoethyl aminopropyl methicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone Preferred examples of the silicone include silicones such as cellulose gum, amino-modified silicones such as aminopropyl dimethicone and amodimethicone, cation-modified silicones, polyether-modified silicones such as dimethicone copolyol, polyglycerin-modified silicones, sugar-modified silicones, carboxylic acid-modified silicones, phosphate-modified silicones, sulfate-modified silicones, alkyl-modified silicones, fatty acid-modified silicones, alkyl ether-modified silicones, amino acid-modified silicones, peptide-modified silicones, fluorine-modified silicones, cation-modified and polyether-modified silicones, amino-modified and polyether-modified silicones, alkyl-modified and polyether-modified silicones, amidoalkyl-modified silicones, aminoglycol-modified silicones, aminophenyl-modified silicones, and polysiloxane-oxyalkylene copolymers; and fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyethers.

[0019] Moisturizing agents and feel improvers include polyols and their polymers such as glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, and ethylene glycol-propylene glycol copolymer; glycol alkyl ethers such as diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, and diethylene glycol dibutyl ether; water-soluble esters such as polyglyceryl-10 (eicosane diacid / tetradecanedioic acid), polyglyceryl-10 tetradecanedioate, and bisethoxydiglycol cyclohexanedicarboxylate; and sugar alkyl esters such as sorbitol, xylitol, erythritol, mannitol, and maltitol. Alcohols; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylated and hydroxyalkylated), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabinogalactan, dextrin, dextran, glycol Sugars and their derivatives, such as cogen, ethyl glucoside, and glucosyl ethyl methacrylate polymers or copolymers; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate, caronin sulfate, keratosulfate, dermatan sulfate; Tremella fuciformis extract, Tremella fuciformis polysaccharide; fructans, such as inulin and levan; fucoidan; tuberose polysaccharide, naturally occurring polysaccharides; organic acids, such as citric acid, tartaric acid, and lactic acid, and their salts; urea; 2-pyrrolidone-5-carboxylic acid and its sodium salts, etc.Amino acids and their salts, such as betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, and taurine; collagen, fish collagen, atelocollagen, gelatin, elastin, collagen hydrolyzed peptides, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin hydrolyzed peptides, keratin hydrolyzed peptides, hydrolyzed keratin, conchiolin hydrolyzed peptides, hydrolyzed conchiolin, silk proteolytic peptides, hydrolyzed silk, sodium lauroyl hydrolyzed silk, soybean proteolytic peptides, wheat proteolytic peptides, hydrolyzed wheat protein, and ketamine. Preferred examples of such ingredients include protein peptides and derivatives thereof, such as isoproteolytic peptides and acylated peptides; acylated peptides, such as palmitoyl oligopeptide, palmitoyl pentapeptide, and palmitoyl tetrapeptide; silylated peptides; lactic acid bacteria culture medium, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesame lignan glycoside, glutathione, albumin, and whey; choline chloride, phosphorylcholine; animal and plant extracts, such as aloe extract, witch hazel water, loofah water, chamomile extract, licorice extract, comfrey extract, silk extract, rose rouge extract, yarrow extract, eucalyptus extract, and melilot extract; and ceramides, such as natural ceramides (types 1, 2, 3, 4, 5, and 6), hydroxyceramides, pseudoceramides, glycosphingolipids, ceramides, and glycoceramide-containing extracts.

[0020] Preferred surfactants include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, polymer surfactants, etc. The HLB of the surfactant is not particularly limited, and surfactants ranging from a low of about 1 to a high of about 20 can be used, and it is also preferable to combine surfactants with low and high HLB. Preferred examples of surfactants include anionic surfactants such as fatty acid salts (e.g., potassium laurate, potassium myristate, etc.); alkyl sulfate ester salts (e.g., sodium lauryl sulfate, triethanolamine lauryl sulfate, ammonium lauryl sulfate, etc.); polyoxyethylene alkyl sulfates (e.g., sodium laureth sulfate, triethanolamine laureth sulfate, etc.); acyl N-methylamino acid salts (e.g., sodium cocoyl methyl taurate, potassium cocoyl methyl taurate, sodium lauroyl methyl taurate, sodium myristoyl methyl taurate, sodium lauroyl methyl alanine, sodium lauroyl sarcosine, triethanolamine lauroyl sarcosine, sodium lauroyl methyl alanine glutamate); sodium cocoyl glutamate, triethanolamine cocoyl glutamate, sodium lauro ... Acyl amino acid salts such as sodium myristoyl glutamate, sodium stearoyl glutamate, palmitoyl aspartic acid ditriethanolamine, cocoyl alanine triethanolamine, and sodium dilauroyl glutamate lysine; polyoxyethylene alkyl ether acetates such as sodium laureth acetate; succinic acid ester salts such as sodium lauroyl monoethanolamide succinate; fatty acid alkanolamide ether carboxylates; acyl lactylate salts; polyoxyethylene fatty amine sulfates; fatty acid alkanolamide sulfates; fatty acid glyceride sulfates such as sodium hydrogenated coconut oil fatty acid glycerin sulfate; alkyl benzene polyoxyethylene sulfates; olefin sulfonates such as sodium α-olefin sulfonate; alkyl sulfosuccinates such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate;Alkyl ether sulfosuccinates such as disodium laureth sulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, and sodium lauryl polypropylene glycol sulfosuccinate; alkyl benzene sulfonates such as sodium tetradecylbenzene sulfonate and triethanolamine tetradecylbenzene sulfonate; alkyl naphthalene sulfonates; alkane sulfonates; α-sulfofatty acid methyl ester salts; acyl isethionates; alkyl glycidyl ether sulfonates; alkyl sulfoacetates; alkyl ether phosphate ester salts such as sodium laureth phosphate, sodium dilaureth phosphate, sodium trilaureth phosphate, and sodium monoolethphosphate; alkyl phosphate ester salts such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphates; fatty acid amide ether phosphates; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, and cyclic lysophosphatidic acid or their salts; silicones such as carboxylic acid-modified silicones, phosphate-modified silicones, and sulfate-modified silicones. glycerol-based anionic surfactants, etc.; nonionic surfactants include laureths (polyoxyethylene lauryl ethers), ceteths (polyoxyethylene cetyl ethers), steareths (polyoxyethylene stearyl ethers), beheneths (polyoxyethylene behenyl ethers), isosteareths (polyoxyethylene isostearyl ethers), and octyldodeceths (polyoxyethylene octyldodecyl ethers), as well as polyoxyethylene alkyl ethers with various polyoxyethylene addition numbers; polyoxyethylene alkylphenyl ethers; esters; castor oil and hydrogenated castor oil derivatives such as polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearate diester, and polyoxyethylene hydrogenated castor oil maleic acid; polyoxyethylene phytosterols; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin;Polyoxyethylene-polyoxypropylene alkyl ethers such as polyoxyethylene-polyoxypropylene cetyl ether, polyoxyethylene-polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene-polyoxypropylene monobutyl ether, polyoxyethylene-polyoxypropylene hydrogenated lanolin, and polyoxyethylene-polyoxypropylene glycerin ether; polyoxyethylene-polyoxypropylene glycol; polyoxyethylene-polyoxypropylene diglyceryl; ) Glycerin polyoxypropylene glycol; glycerin fatty acid partial esters such as glyceryl stearate, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, glyceryl coconut oil fatty acid, glycerin mono-cottonseed oil fatty acid, glycerin mono-erucate, glycerin sesquioleate, glycerin α,α'-oleic acid pyroglutamate, glycerin monostearate malate, etc.; polyglyceryl-2, 3, 4, 5, 6, and 8 stearate , 10, Polyglyceryl-6 distearate, 10, Polyglyceryl-2 tristearate, Polyglyceryl-10 decaisostearate, Polyglyceryl-2 isostearate, 3, 4, 5, 6, 8, 10, Polyglyceryl-2 diisostearate (diglyceryl diisostearate), 3, 10, Polyglyceryl-2 triisostearate, Polyglyceryl-2 tetraisostearate, Polyglyceryl-10 decaisostearate, Polyglyceryl-2 oleate, 3, Nos. 4, 5, 6, 8, and 10, polyglycerin fatty acid esters such as polyglyceryl-6 dioleate, polyglyceryl-2 trioleate, and polyglyceryl-10 decaoleate; ethylene glycol mono-fatty acid esters such as ethylene glycol monostearate; propylene glycol mono-fatty acid esters such as propylene glycol monostearate; pentaerythritol partial fatty acid esters; sorbitol partial fatty acid esters; maltitol partial fatty acid esters; maltitol ethers;Sorbitan fatty acid esters such as sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, and diglycerol sorbitan tetra-2-ethylhexylate; partial esters of sugar derivatives such as sucrose fatty acid esters, methyl glucoside fatty acid esters, and trehalose undecylenate; alkyl glucosides such as caprylyl glucoside; alkyl polyglycosides Glycolipids such as mannosylerythritol lipid; lanolin alcohol; reduced lanolin; polyoxyethylene fatty acid mono- and diesters such as polyoxyethylene distearate, polyethylene glycol diisostearate, polyoxyethylene monooleate, and polyoxyethylene dioleate; polyoxyethylene propylene glycol fatty acid esters; polyoxyethylene monooleates such as polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, and polyoxyethylene glycerin triisostearate Polyoxyethylene glycerin fatty acid esters such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, and polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol fatty acid esters such as polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, and polyoxyethylene sorbitol monostearate; polyoxyethylene methyl glucoside fatty acid esters; polyoxyethylene alkyl ether fatty acid esters; polyoxyethylene animal and vegetable oils and fats such as polyoxyethylene sorbitol beeswax; alkyl glyceryl ethers such as isostearyl glyceryl ether, chimyl alcohol, selachyl alcohol, and batyl alcohol; polyhydric alcohol alkyl ethers; polyoxyethylene alkylamines; tetrapolyoxyethylene-tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponin and sophorolipids;Polyoxyethylene fatty acid amides; fatty acid alkanolamides such as coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (palmitamide MEA), palmitic acid diethanolamide (palmitamide DEA), and coconut oil fatty acid methylethanolamide (cocamide methyl MEA). alkyl dimethylamine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, and behenamine oxide; alkyl ethoxydimethylamine oxide; polyoxyethylene alkyl mercaptan; silicone-based nonionic surfactants such as polyether-modified silicones such as dimethicone copolyol, polysiloxane-oxyalkylene copolymers, polyglycerin-modified silicones, and sugar-modified silicones; cationic surfactants such as behentrimonium chloride, steartrimonium chloride, and cetrimonium chloride. Alkyltrimethylammonium chlorides such as lauryltrimonium chloride; alkyltrimethylammonium bromides such as stearyltrimonium bromide; dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; fatty acid amidoamines and their salts such as stearamidopropyldimethylamine and stearamidoethyldiethylamine; alkyl ether amines and their salts or quaternary salts such as stearoxypropyldimethylamine; fatty acid amide quaternary ammonium salts such as ethyl sulfate of long-chain branched fatty acid (12-31) aminopropylethyldimethylammonium and ethyl sulfate of lanolin fatty acid aminopropylethyldimethylammonium; polyoxyethylene alkylamines and their salts or quaternary salts; alkylamine salts; fatty acid amide guanidinium salts; alkyl ether amine ammonium salts; alkyl trialkylene glycol ammonium salts; benzalkonium salts; benzethonium salts; pyridinium salts such as cetylpyridinium chloride; imidazolinium salts; alkylisoquinolinium salts; dialkylmorphonium salts; polyamine fatty acid derivatives;Silicone-based cationic surfactants such as amino-modified silicones such as aminopropyl dimethicone and amodimethicone, cation-modified silicones, cation-modified and polyether-modified silicones, and amino-modified and polyether-modified silicones; amphoteric surfactants include N-alkyl-N,N-dimethyl amino acid betaines such as lauryl betaine (lauryl dimethyl amino acetate betaine); fatty acid amidoalkyl-N,N-dimethyl amino acid betaines such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkyl sulfobetaines such as alkyl dimethyl taurine; sulfate-type betaines such as alkyl dimethyl amino ethanol sulfate esters; phosphate-type betaines such as alkyl dimethyl amino ethanol phosphate esters; tine; sphingophospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, and sphingomyelin, phospholipids such as lysolecithin, hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid, and hydroxylated lecithin; silicone-based amphoteric surfactants; and among polymer surfactants, preferred examples include polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum, and acrylic acid / alkyl methacrylate copolymers; and various silicone-based surfactants.

[0021] Polymers, thickeners, and gelling agents include guar gum, locust bean gum, queen seed, carrageenan, galactan, gum arabic, tara gum, tamarind, furcellaran, karaya gum, aoi, caragam, tragacanth gum, pectin, pectinic acid and its salts such as sodium salt, alginic acid and its salts such as sodium salt, mannan; starch from rice, corn, potato, wheat, etc.; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salts, xanthan gum, pullulan, gellan gum, chitin, chitosan, Agar, cassou extract, chondroitin sulfate, casein, collagen, gelatin, albumin; cellulose and its derivatives such as methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and its sodium salts, methylhydroxypropyl cellulose, sodium cellulose sulfate, dialkyldimethylammonium cellulose sulfate, crystalline cellulose, cellulose powder; starch such as soluble starch, carboxymethyl starch, methylhydroxypropyl starch, methyl starch, etc. Starch derivatives such as polyvinylpyrrolidone (PVP), polyvinyl alcohol (PVA), vinylpyrrolidone-vinyl alcohol copolymer, polyvinyl methyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene-polyoxypropylene copolymer; amphoteric methacrylate copolymers such as (methacryloyloxyethyl carboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine oxide methacrylate) copolymer; (dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer; partially saponified polyvinyl acetate, maleic acid copolymer; vinylpyrrolidone-dialkylaminoalkyl methacrylate copolymer; acrylic resins with alkanolamine; polyesters, water-dispersible polyesters;Polyacrylamide; polyacrylic acid ester copolymers such as polyethyl acrylate, carboxyvinyl polymers, polyacrylic acid and its salts such as sodium salt, acrylic acid-methacrylic acid ester copolymers; acrylic acid-alkyl methacrylate copolymers; cationized cellulose such as Polyquaternium-10, diallyldimethylammonium chloride-acrylamide copolymers such as Polyquaternium-7, acrylic acid-diallyldimethylammonium chloride copolymers such as Polyquaternium-22, acrylic acid-diallyldimethylammonium chloride-acrylamide copolymers such as Polyquaternium-39, acrylic acid-cationized methacrylic acid ester copolymers, acrylic acid-cationized methacrylic acid amide copolymers, acrylic acid-methyl acrylate-methacrylamidopropyltrimethylammonium chloride copolymers such as Polyquaternium-47, methacrylic acid choline ester chloride polymers; cationized oligosaccharides, cationized dextran, cationized guar hydroxypropyltrimonium chloride, etc. Preferred examples of the polymer include polysaccharides, polyethyleneimine, cationic polymers, 2-methacryloyloxyethyl phosphorylcholine polymers such as polyquaternium-51 and copolymers with butyl methacrylate copolymers, polymer emulsions such as acrylic resin emulsions, polyethyl acrylate emulsions, polyacrylic alkyl ester emulsions, polyvinyl acetate resin emulsions, natural rubber latex, and synthetic latex; nitrocellulose; polyurethanes and various copolymers; various silicones; various silicone copolymers such as acrylic-silicone graft copolymers; various fluorine-containing polymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride, fumed silica (ultrafine silicic anhydride particles), aluminum magnesium silicate, sodium magnesium silicate, metal soaps, dialkyl phosphate metal salts, bentonite, hectorite, organically modified clay minerals, sucrose fatty acid esters, and fructooligosaccharide fatty acid esters.

[0022] Solvents and propellants include lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol, and isobutyl alcohol; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, and isopentyl diol; diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, and diethylene glycol diethyl ether. Preferred examples of the propellant include glycol ethers such as propylene glycol monoethyl ether; glycol ether esters such as ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, and propylene glycol monoethyl ether acetate; glycol esters such as diethoxyethyl succinate and ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbons, next-generation chlorofluorocarbons; LPG, dimethyl ether, and carbon dioxide gas.

[0023] Preferred antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or its derivatives; erythorbic acid and its derivatives; sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, and cysteine ​​hydrochloride. Preferred reducing agents include thioglycolic acid, cysteine, and cysteamine. Preferred oxidizing agents include hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

[0024] Examples of antibacterial agents or preservatives include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, and butylparaben; phenoxyethanol; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, and 1,2-octanediol; alkyl glyceryl ethers such as 2-ethylhexylglyceryl ether (ethylhexylglycerin); glycerin fatty acid esters such as glyceryl caprylate, glyceryl caprate, and glyceryl (caprylic / capric acid); salicylic acid; sodium benzoate; isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; imidazolinium urea; dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, and quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzalkonium chloride, and benzyl chloride. Preferred examples of the antibacterial agent include zethonium, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, and hinokitiol; other phenols such as phenol, isopropylphenol, cresol, thymol, parachlorophenol, phenylphenol, and sodium phenylphenol; phenylethyl alcohol, photosensitizers, antibacterial zeolites, and silver ions. However, when used as an antibacterial agent or preservative for preservative purposes, from the viewpoint of safety of the cosmetic or topical skin preparation, it is more preferred to use phenoxyethanol; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, and 1,2-octanediol; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether; and glycerin fatty acid esters such as glyceryl caprylate, glyceryl caprate, and glyceryl (caprylic / capric acid).

[0025] Preferred examples of the chelating agent include edetates (ethylenediaminetetraacetates) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetates such as HEDTA3Na; pentetates (diethylenetriaminepentaacetate); phytic acid; phosphonic acids such as etidronic acid and salts thereof such as sodium salts; sodium oxalate; polyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine, gluconic acid, ascorbic acid, succinic acid, and tartaric acid. Preferred examples of the pH adjuster, acid, or alkali include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, sodium hydroxide, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate.

[0026] Powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, lepidolite, biotite, vermiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, metal soaps (e.g., zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, Prussian blue, carbon black, titanium oxide, fine and ultrafine titanium oxide particles, zinc oxide, fine and ultrafine zinc oxide particles, alumina, silica, fumed silica (ultrafine silicic anhydride particles), titanium mica Preferred examples include inorganic powders of various sizes and shapes, such as fish scale foil, boron nitride, photochromic pigments, synthetic fluorine-containing phlogopite, fine particle composite powders, gold, and aluminum, and inorganic powders obtained by treating these with silicones such as hydrogen silicone and cyclic hydrogen silicone, or other silanes, or various surface treatment agents such as titanium coupling agents to make them hydrophobic or hydrophilic; organic powders of various sizes and shapes, such as starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene-acrylic acid copolymer resin powder, polyester powder, benzoguanamine resin powder, polyethylene terephthalate-polymethyl methacrylate laminate powder, polyethylene terephthalate-aluminum-epoxy laminate powder, urethane powder, silicone powder, and Teflon (registered trademark) powder, as well as surface-treated powders and organic-inorganic composite powders.Preferred examples of inorganic salts include sodium chloride-containing salts such as table salt, regular salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, and ammonium chloride; sodium sulfate, aluminum sulfate, aluminum-potassium sulfate (alum), aluminum-ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, and copper sulfate; and sodium phosphates such as mono-, di-, and tri-Na phosphate, potassium phosphates, calcium phosphates, and magnesium phosphates.

[0027] Examples of ultraviolet absorbers include benzoic acid-based ultraviolet absorbers such as para-aminobenzoic acid, para-aminobenzoic acid monoglycerin ester, N,N-dipropoxypara-aminobenzoic acid ethyl ester, N,N-diethoxypara-aminobenzoic acid ethyl ester, N,N-dimethylpara-aminobenzoic acid ethyl ester, N,N-dimethylpara-aminobenzoic acid butyl ester, and N,N-dimethylpara-aminobenzoic acid ethyl ester; anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; salicylic acid-based ultraviolet absorbers such as salicylic acid and its sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, and p-isopropanol phenyl salicylate; octyl cinnamate, Cinnamic acid-based UV absorbers such as ethyl 4-isopropyl cinnamate, methyl 2,5-diisopropyl cinnamate, ethyl 2,4-diisopropyl cinnamate, methyl 2,4-diisopropyl cinnamate, propyl p-methoxycinnamate, isopropyl p-methoxycinnamate, isoamyl p-methoxycinnamate, 2-ethylhexyl p-methoxycinnamate (octyl p-methoxycinnamate), 2-ethoxyethyl p-methoxycinnamate (cinoxate), cyclohexyl p-methoxycinnamate, ethyl α-cyano-β-phenylcinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate (octocurine), glyceryl mono-2-ethylhexanoyl di-paramethoxycinnamate, ferulic acid and its derivatives;Benzophenone-based UV absorbers such as 2,4-dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2',4,4'-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, and 4-hydroxy-3-carboxybenzophenone; 3-(4'-methylbenzylidene)-d,l-camphor, 3-benzylidene-d,l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-methylphenylbenzotriazole; 2-(2'-hydroxy 2-(2'-hydroxy-5'-methylphenylbenzotriazole; Dibenzalazine; Dianisoylmethane; 5-(3,3-dimethyl-2-norbornylidene)-3-pentan-2-one; Dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; Octyltriazone; Urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2-(2'-hydroxy-5'-methylphenyl)benzotriazole Preferred examples thereof include hydantoin derivatives such as 1-(3,4-dimethoxyphenyl)-4,4-dimethyl-1,3-pentanedione, 2-ethylhexyl dimethoxybenzylidene dioxoimidazolidinepropionate, phenylbenzimidazolazole sulfonic acid, terephthalylidene dicamphor sulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, and oryzanol and its derivatives;

[0028] Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, and retinol palmitate; vitamin B such as thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, flavin adenine dinucleotide, cyanocobalamin, folic acids, nicotinic acids such as nicotinamide and benzyl nicotinate, and choline; vitamin C such as ascorbic acid and its sodium salts; vitamin D; vitamin E such as α-, β-, γ-, and δ-tocopherol; other vitamins such as pantothenic acid and biotin; and vitamin B such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt. Preferred examples include ascorbic acid phosphate salts, ascorbic acid fatty acid esters such as ascorbic acid tetraisopalmitate, ascorbyl stearate, ascorbyl palmitate, and ascorbyl dipalmitate, ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucoside and its fatty acid esters such as ascorbic acid-2-glucoside, and ascorbic acid derivatives such as tocopheryl ascorbyl phosphate; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, tocopherol ferulate, and tocopherol phosphate; tocotrienols; and various other vitamin derivatives.

[0029] Preferred examples of the anti-inflammatory agent include glycyrrhizinic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; and plant extracts such as peach leaf extract and mugwort leaf extract. Preferred examples of hair growth agents, blood circulation promoters, and stimulants include plant extracts and tinctures such as Swertia japonica extract, capsicum tincture, ginger tincture, ginger extract, and cantharis tincture; capsaicin, nonylic acid valenylamide, zingerone, ichthammol, tannic acid, borneol, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, γ-oryzanol, cepharanthine, vitamin E, and derivatives thereof such as tocopherol nicotinate and tocopherol acetate, γ-oryzanol, nicotinic acid, and derivatives thereof such as nicotinamide, nicotinic acid benzyl ester, inositol hexanicotinate, and nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, flavanonol derivatives, stigmasterol or stigmastanol and their glycosides, and minoxidil. Preferred examples of hormones include estradiol, estrone, ethinylestradiol, cortisone, hydrocortisone, and prednisone.Other medicinal agents such as anti-wrinkle agents, anti-aging agents, firming agents, cooling agents, warming agents, wound healing promoters, irritation soothing agents, analgesics, and cell activators include retinols, retinoic acids, and tocopheryl retinoate; lactic acid, glycolic acid, gluconic acid, fruit acids, salicylic acid and their glycoside and ester derivatives; α- or β-hydroxy acids and their derivatives, such as hydroxycapric acid, long-chain α-hydroxy fatty acids, and long-chain α-hydroxy fatty acid cholesteryl; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosine; creatine; ceramides; sphingosines; caffeine, xanthine, and their derivatives; coenzyme Q10, carotene, lycopene, astaxanthin, lutein, α-lipoic acid, and platinum nanoparticles. Preferred examples include antioxidants and active oxygen scavengers such as rhodopsin, rhodopsin-3, rhodopsin-4, rhodopsin-5, rhodopsin-6, rhodopsin-7, rhodopsin-8, rhodopsin-9, rhodopsin-10, rhodopsin-11, rhodopsin-12, rhodopsin-13, rhodopsin-14, rhodopsin-15, rhodopsin-16, rhodopsin-17, rhodopsin-18, rhodopsin-19, rhodopsin-20, rhodopsin-21, rhodopsin-22, rhodopsin-23, rhodopsin-24, rhodopsin-25, rhodopsin-30, rhodopsin-40, rhodopsin-50, rhodopsin-60, rhodopsin-70, rhodopsin-80, rhodopsin-90, rhodopsin-100, rhodopsin-110, rhodopsin-120, rhodopsin-130, rhodopsin-140, rhodopsin-150, rhodopsin-160, rhodopsin-170, rhodopsin-180, rhodopsin-190, rhodopsin-210, rhodopsin-220, rhodopsin-230, rhodopsin-240, rhodopsin-250, rhodopsin-260, rhodopsin-270, rhodopsin-280, rhodopsin-290, rhodopsin-300, rhodopsin-310, rhodopsin-320, rhodopsin-33

[0030] Plant, animal and microbial extracts include iris extract, angelica extract, asparagus extract, avocado extract, hydrangea extract, almond extract, althaea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo extract, chinko extract, fennel extract, turmeric extract, oolong tea extract, uva-ursi extract, angelica tree extract, echinacea leaf extract, emmeiso extract, scutellaria root extract, phellodendron bark extract, coptis japonica extract, barley extract, ginseng extract, St. John's wort extract, and oak leaf extract. Kosou extract, Ononis extract, Netherlands mustard extract, orange extract, dried seawater, seaweed extract, oyster leaf extract, kakyoku extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk, pueraria root extract, chamomilla extract, oil-soluble chamomilla extract, carrot extract, artemisia capillaris extract, oat extract, kalk extract, licorice extract, oil-soluble licorice extract, kiwi extract, ash extract, wood ear extract, cinchona extract, cucumber extract, paulownia leaf extract, guanosine, guava extract, kudzu root extract, gardenia extract, kumazasa extract , Sophora flavescens extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, mulberry extract, gentian extract, geranium extract, black tea extract, yeast extract, magnolia bark extract, coffee extract, burdock extract, rice extract, fermented rice extract, fermented rice bran extract, rice germ oil, comfrey extract, collagen, cowberry extract, Chinese radish extract, Bupleurum Root extract, umbilical cord extract, saffron extract, salvia extract, soapwort extract, bamboo grass extract, hawthorn extract, Chinese radish extract , Zanthoxylum extract, Shiitake mushroom extract, Rehmannia root extract, Lithospermum root extract, Perilla extract, Tilia extract, Meadowsweet extract, Jatoba extract, Peony extract, Angelica root extract, Calamus root extract, Birch extract, White wood ear extract, Horsetail extract, Stevia extract, Stevia fermented product, Nishikawa willow extract, Ivy extract, Hawthorn extract, Elderberry extract, Yarrow extract, Peppermint extract, Sage extract, Mallow extract, Cnidium extract, Swertia japonica extract, Sophora japonica extract, Rhubarb extract,Soybean extract, Chinese laurel extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, Imperata cylindrica extract, tangerine extract, tea tree oil, sweet tea extract, chili pepper extract, angelica extract, calendula extract, peach kernel extract, spruce extract, Houttuynia cordata extract, tomato extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, burdock extract, lotus extract, parsley extract, birch extract, honey, witch hazel extract, parietaria extract, jasmine extract, bisabolol, cypress extract, bifidobacteria extract, loquat extract, coltsfoot extract, butterbur extract, poria cocos extract, butcher's broom extract, grape extract, grape seed extract Preferred examples of extracts include kiss, propolis, loofah extract, safflower extract, peppermint extract, linden extract, peony extract, hop extract, squid extract, pine extract, horse chestnut extract, skunk cabbage extract, soapberry extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, saxifrage extract, yuzu extract, lily extract, coix seed extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, lychee extract, lettuce extract, lemon extract, forsythia extract, astragalus extract, rose extract, rosemary extract, Roman chamomile extract, royal jelly extract, and burnet extract.

[0031] Examples of antipruritic agents include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance P inhibitors, etc. Examples of keratin exfoliating / dissolving agents include salicylic acid, sulfur, resorcinol, selenium sulfide, pyridoxine, etc. Examples of antiperspirants include aluminum chlorohydrate, aluminum chloride, zinc oxide, zinc paraphenolsulfonate, etc. Examples of cooling agents include menthol and methyl salicylate, etc. Examples of astringents include citric acid, tartaric acid, lactic acid, aluminum potassium sulfate, tannic acid, etc. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, etc. Examples of nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and adenosine triphosphate disodium, etc.

[0032] Fragrance: acetyl cedrene, amyl cinnamaldehyde, allyl amyl glycolate, β-ionone, isoe super, isobutylquinoline, iris oil, iron, indole, ylang-ylang oil, undecanal, undecenal, γ-undecalactone, estragole, eugenol, oakmoss, opoponax resinoid, orange oil, eugenol, aurantiol, galacsolids, carvacrol, L-carvone, camphor, cannon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile, isobornyl acetate, geranyl acetate, dimethylbenzylcarbinyl acetate, styraryl acetate, cedryl acetate, terpineol acetate, pt-butylcyclohexyl acetate Al, vetiveryl acetate, benzyl acetate, linalyl acetate, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamen aldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromyrcenol, jasmine absolute, jasmine lactone, cis-jasmone, citral, citronenol, citronellal, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, styrax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascone, damascenone, thymol, tuberose absolute, decanal, decalactone, terpineol, gamma-terpinene, tripluran, nerol, nonanal, 2,6-Nonadienol, Nonalactone, Patchouli Alcohol, Vanilla Absolute, Vanillin, Basil Oil, Patchouli Oil, Hydroxycitronellal, Alpha-Pinene, Piperitone, Phenethyl Alcohol, Phenylacetaldehyde, Petitgrain Oil, Hexyl Cinnamaldehyde, cis-3-Hexenol, Balsam of Peru, Vetiver Oil, Vetiverol, Peppermint Oil, Pepper Oil, Heliotropin, Bergamot Oil, Benzyl Benzene Preferred examples of the fragrance include synthetic and natural fragrances such as maltodextrin, borneol, myrrhizoid, musk ketone, methylnonylacetaldehyde, γ-methylionone, menthol, L-menthol, L-menthone, eucalyptus oil, β-ionone, lime oil, lavender oil, D-limonene, linalool, lyral, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, and various essential oils, as well as various blended fragrances.

[0033] Colorants, dyes, and pigments include Brown No. 201, Black No. 401, Purple No. 201, Purple No. 401, Blue No. 1, Blue No. 2, Blue 201, Blue No. 202, Blue No. 203, Blue No. 204, Blue No. 205, Blue No. 403, Blue No. 404, Green No. 3, Green 201, Green 202, Green 204, Green No. 205, Green No. 3, Green 401, and Green 402 No., Red No. 102, Red No. 104-1, Red No. 105-1, Red No. 106, Red No. 2, Red No. 3, Red No. 201, Red No. 202, Red No. 203, Red No. 204, Red No. 205, Red No. 206, Red No. 207, Red No. 208, Red No. 213, Red No. 214, Red No. 215, Red No. 218, Red No. 219, Red No. 220, Red No. 221, Red No. 223 , Red No. 225, Red No. 226, Red No. 227, Red No. 228, Red No. 230-1, Red No. 230-2, Red No. 231, Red No. 232, Red No. 3, Red No. 401, Red No. 40 No. 4, Red No. 405, Red No. 501, Red No. 502, Red No. 503, Red No. 504, Red No. 505, Red No. 506, Orange No. 201, Orange No. 203, Orange No. 204, Orange 20 Legal dyes such as No. 5, Orange 206, Orange 207, Orange 401, Orange 402, Orange 403, Yellow 201, Yellow 202-1, Yellow 202-2, Yellow 203, Yellow 204, Yellow 205, Yellow 4, Yellow 401, Yellow 402, Yellow 403-1, Yellow 404, Yellow 405, Yellow 406, Yellow 407, and Yellow 5; Acid Other acid dyes such as Red 14; basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, and Arianor Straw Yellow; nitro dyes such as HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydroxypropylamino-3-nitrophenol, N,N'-bis(2-hydroxyethyl)-2-nitro-p-phenylenediamine, HC Blue 2, and Basic Blue 26; disperse dyes; inorganic white pigments such as titanium dioxide and zinc oxide; inorganic red pigments such as iron oxide (red iron oxide) and iron titanate; inorganic brown pigments such as gamma-iron oxide; inorganic yellow pigments such as yellow iron oxide and ochre; inorganic black pigments such as black iron oxide and low-order titanium oxide;Inorganic purple pigments such as mango violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide, and cobalt titanate; inorganic blue pigments such as ultramarine and Prussian blue; pearl pigments such as titanium dioxide-coated mica, titanium dioxide-coated bismuth oxychloride, titanium dioxide-coated talc, colored titanium dioxide-coated mica, bismuth oxychloride, and fish scale foil; metal powder pigments such as aluminum powder, copper powder, and gold; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsanthin, chalcone, carthamine, and quercetin. Preferred examples include natural pigments and dyes such as naphthoquinones (e.g., cinnamon, crocin, chlorophyll, curcumin, cochineal, and shikonin), bixin, flavones, betacyanidin, henna, hemoglobin, lycopene, riboflavin, and rutin; oxidation dye intermediates and couplers (e.g., p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcinol, 1-naphthol, 2,6-diaminopyridine, and salts thereof); autoxidation dyes (e.g., indoline); and dihydroxyacetone.

[0034] Preferred examples of water include tap water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionized water, and cluster water.

[0035] In addition to these, it is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc. in known combinations, ratios, and amounts, such as ingredients listed in the Cosmetic Ingredient Standards, Cosmetic Type Ingredient Standards, Japan Cosmetic Industry Association Ingredient Labeling List, INCI Dictionary (The International Cosmetic Ingredient Dictionary and Handbook), Quasi-drug Ingredient Standards, Japanese Pharmacopoeia, Pharmaceutical Additives Standards, Food Additives Official Standards, and ingredients listed in Japanese and foreign patent gazettes and patent publications (including published gazettes and republications) that fall into the International Patent Classification IPC classifications A61K7 and A61K8.

[0036] The hair cavity repair agent of the present invention can also be incorporated into common hair cosmetics. More specifically, preferred types of hair cosmetics include shampoos such as oil shampoo, cream shampoo, conditioning shampoo, anti-dandruff shampoo, hair color shampoo, and rinse-in-one shampoo; rinse, treatment, hair pack, hair foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, setting lotion, color lotion, hair tonic, hair liquid, pomade, hair balm, hair cream, hair blow dryer, split end coat, hair oil, permanent wave agent, straight perm agent, oxidation hair dye, hair bleach, hair color pre-treatment, hair color after-treatment, perm pre-treatment, perm after-treatment, hair manicure, and hair growth agent.

[0037] Preferred formulations of hair cosmetics include emulsion-type cosmetics such as oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, and O / W / O type, oil-based cosmetics, solid cosmetics, aqueous liquid cosmetics, paste cosmetics, stick-type cosmetics, volatile oil-type cosmetics, powder cosmetics, jelly-type cosmetics, gel-type cosmetics, paste-type cosmetics, emulsified polymer-type cosmetics, sheet-type cosmetics, mist-type cosmetics, and spray-type cosmetics. [Example]

[0038] The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples in any way.

[0039] Hair cavity repair agents containing components (A) and (B) of the present invention were prepared according to the compositions shown in Table 1 (Examples 1 to 5). For comparison, agents not containing component (B) were prepared (Comparative Examples 1 to 5). The hair cavity repair effect of the resulting agents was evaluated using the following method. In addition, the effect of improving hair firmness and luster was evaluated using the following method. The results are also shown in the columns below the table. <Hair cavity repair effect> Healthy black human hair was bleached once with a commercially available two-component bleach to create damaged hair. The damaged hair tips were then cut to a length of approximately 5 cm, and both ends were fixed to a glass slide with adhesive. The fixed hair was observed using a microscope (Keyence VHX-1000, 175x magnification) to determine whether or not the hair had cavities. Since hair with cavities is characterized by the porous portion of the medulla appearing as a white streak in the center of the hair (Non-Patent Document 1), the white streak was identified as the cavities, and its length was measured. The hair was then immersed in 10 g of each agent at room temperature for 6 hours, rinsed with tap water at approximately 20°C, and dried with cold air from a hair dryer for 3 minutes. The resulting treated hair was again observed under the microscope at the same location as before treatment, and the length of the cavities was measured. The cavity repair rate was calculated using the total length of the cavity area before treatment (L1) and the total length of the cavity area after treatment (L2) according to the following formula, which was used as an index of hair cavity repair, and the hair cavity repair effect was evaluated according to the following criteria. Observations were made at 14 locations per hair, with three hairs per sample. An example of microscope observation is shown in Figure 1. Cavity repair rate (%)=(L1-L2) / L1×100 ◎ Cavity repair rate is over 60% ○ Cavity repair rate is between 40% and 60% △: Cavity repair rate is between 20% and 40% ×...Cavity repair rate is less than 20% <Improves hair firmness and shine> Healthy black human hair was bleached once with a commercially available two-component bleach to create damaged hair. Next, 3g of the damaged hair strands were immersed in 30g of hair cavity repair agent at room temperature for 3 hours, then rinsed with tap water and dried with hot air from a hair dryer for 3 minutes. Five panelists evaluated the resulting hair strands for their bounce and shine improvement effects based on their sensory assessment using the following criteria: ◎ Significant improvement compared to the hair bundle before treatment (damaged hair) ○ Improved compared to the hair bundle before treatment (damaged hair) △: Slight improvement compared to the hair bundle before treatment (damaged hair) × No change compared to the hair bundle before treatment (damaged hair)

[0040] [Table 1]

[0041] The results in Table 1 show that the hair cavity repair agent of the present invention has a higher hair cavity repair rate and an excellent hair cavity repair effect than the agent not containing component (B). It was also found to be excellent in improving the firmness and shine of hair.

[0042] A hair cosmetic containing the hair cavity repair agent of the present invention described below was prepared. The obtained hair cosmetic improved the firmness and strength of hair and enhanced its shine.

[0043] Example 6 Hair Lotion Component Amount (% by weight) -------------------------------------- Neosolue-Aqulio (Nippon Fine Chemical) 0.5 Glycerin 5.0 BG 3.0 Succinic acid 1.0 Hydroxyethyl cellulose 0.2 Phenoxyethanol 0.4 Purified water (amount to make a total of 100) -------------------------------------- (Preparation method) All ingredients were mixed uniformly and the pH was adjusted to 6.0 with sodium hydroxide.

[0044] Example 7 Hair Lotion Component Amount (% by weight) -------------------------------------- Neosolue-Aqulio (Nippon Fine Chemical) 1.0 Neosolue-AquaS (Nippon Fine Chemical) 0.2 BG 3.0 Propanediol 2.0 Malonic acid 2.0 Lactic Acid 2.0 Tremoist-SL (Nippon Fine Chemical) 1.0 Xanthan gum 0.5 Methylparaben 0.2 Purified water (amount to make a total of 100) -------------------------------------- (Preparation method) All ingredients were heated to about 80°C and mixed uniformly with stirring. The pH was 2.2.

[0045] Example 8 Hair Lotion Component Amount (% by weight) -------------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 0.5 Neosolue-DiSM (Nippon Fine Chemical) 0.1 PEG-40 Hydrogenated Castor Oil 0.2 Part B Glycerin 2.0 Propylene Glycol 3.0 Inulin-SC (Nippon Fine Chemical) 1.0 Malic acid 0.05 Lactic acid 0.02 (Acrylates / C10-30 alkyl acrylate) crosspolymer 0.05 Purified water (amount to make a total of 100) C part Phenoxyethanol 0.4 Ethanol 5.0 -------------------------------------- (Preparation method) Parts A and B were heated to 80°C, and then Part B was added to Part A and mixed uniformly. After cooling to around 50°C, Part C was added to make a homogeneous solution. The pH was adjusted to 6.0 with sodium hydroxide.

[0046] Example 9 Treatment Hair Mist Component Amount (% by weight) -------------------------------------- Part A Phytopresome MEL (Nippon Fine Chemical) 2.0 Glycerin 5.0 BG 3.0 Steartrimonium chloride 0.2 Part B Purified water 40.0 C part NanoRepair-CMC 10.0 Tremoist-SL (Nippon Fine Chemical) 1.0 Neosolue-Aqulio (Nippon Fine Chemical) 1.0 Succinic acid 2.0 Glutamic acid 0.1 Phenylalanine 0.05 Cysteine ​​0.2 Glycine 0.3 Hydroxyethyl cellulose 0.05 Phenoxyethanol 0.4 Ethanol 5.0 Purified water (amount to make a total of 100) -------------------------------------- (Preparation method) Parts A and B were heated to 60°C, and Part A was added to Part B to prepare an aqueous dispersion. Part C was then added with stirring to make a homogeneous solution. The pH was adjusted to 4.0 with arginine.

[0047] Example 10: Silicone-free shampoo Component Amount (% by weight) --------------------------------- Neosolue-Aqulio 1.0 Plandool-LG2 (Nippon Fine Chemical) 0.03 Neosolue-AquaS (Nippon Fine Chemical) 0.1 Tremoist-SL (Nippon Fine Chemical) 0.5 Sodium Laureth-4 Carboxylate (28%) 10.0 Laureth-6 Carboxylic Acid 4.0 Cocamidopropyl Betaine (30%) 10.0 Sodium Lauroyl Methylalanine (30%) 5.0 Cocamidomethyl MEA 3.0 PEG-7 Glyceryl Cocoate 5.0 Polyquaternium-10 0.8 Glycol distearate 0.5 Polyquaternium-7 0.5 EDTA-2Na 0.05 Succinic acid 0.1 Malic acid 0.1 Methylparaben 0.2 Phenoxyethanol 0.4 Purified water (amount to make a total of 100) --------------------------------- (Preparation method) All ingredients were heated to approximately 80°C and mixed uniformly with stirring. The pH was adjusted to 6.0 with sodium hydroxide.

[0048] Example 11: Leave-in hair treatment Component Amount (% by weight) ------------------------------------- Part A Polyquaternium-37 2.0 Squalane 2.0 PPG-3 Caprylyl Ether 2.0 Microcrystalline wax 0.1 Lanolin alcohol 0.2 Montan wax 0.1 Polyethylene wax 0.1 Beeswax 0.1 Rowlet 0.2 Ceresin 0.1 PG Dicaprate 1.0 Almond oil 0.5 Ethylhexyl ethylhexanoate 1.0 Candelilla wax extract 0.1 Octyldodecyl erucate 4.5 Tocopheryl acetate 0.02 Erucalactone MCT (Nippon Fine Chemical) 2.0 Dipentaerythrityl Tri-Polyhydroxystearate 1.5 PPG-5 Phytosteryl 0.5 Glycerin 4.0 Sorbitol 2.0 Phenoxyethanol 0.5 Neosolue-Aqulio (Nippon Fine Chemical) 0.5 Part B Hydrolyzed conchiolin 0.1 Panthenol 0.1 Hyaluronic acid hydroxypropyltrimonium 0.01 Polyquaternium-11 0.2 Glycosyltrehalose 0.1 Glyceryl glucoside 0.3 C part Purified water (amount to make a total of 100) Hydroxypropyl Starch Phosphate 1.0 Malonic acid 0.1 -------------------------------------- (Preparation method) Part C was dispersed uniformly and heated to approximately 80°C. Next, part A was heated to approximately 80°C and dissolved. Part A was added to part C while stirring, and after uniform mixing, the mixture was cooled to approximately 40°C. Next, part B was added and mixed uniformly. The pH was adjusted to 6.0 with arginine.

[0049] Example 12: Leave-in hair treatment Component Amount (% by weight) -------------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 1.0 FineNeo-EHS (Nippon Fine Chemical) 1.0 Cetrimonium chloride (25%) 2.8 Ecolano LH (Nippon Fine Chemical) 1.0 Plandool-SUN (Nippon Fine Chemical) 0.2 PPG-3 Caprylyl Ether 1.0 Methylheptyl myristate 0.5 Cetyl ethylhexanoate 0.3 Isononyl isononanoate 0.3 Tridecyl neopentanoate 0.5 Myristyl isooctanoate 0.3 Neopentyl glycol diethylhexanoate 0.3 Isobutyl isostearate 0.3 Glyceryl triisostearate 0.3 Trimethylolpropane triisostearate 0.3 Broccoli seed oil 0.3 Sphinganine 0.01 Glycerin 1.0 Part B Methylparaben 0.1 Purified water (amount to make a total of 100) Phenoxyethanol 0.5 C part NanoRepair-CMC5 (Nippon Fine Chemical) 5.0 NanoRepair-EL (Nippon Fine Chemical) 1.0 Polyquaternium-6 0.6 Polyquaternium-7 0.4 Polyquaternium-39 0.5 D part Carrageenan 0.1 Hydroxypropyl chitosan 0.05 Hydroxypropyl methylcellulose 0.1 Tuberose polysaccharide 0.1 Cationic guar gum 0.05 Succinic acid 1.3 Maleic acid 0.5 Purified water 20.0 -------------------------------------- (Preparation method) Part B was heated to about 80°C and dissolved. Next, part A was heated to about 80°C and dissolved. Part D was dispersed to form a viscous liquid. Part A was added to part B while stirring, and after uniform mixing, the mixture was cooled to about 40°C. Next, parts C and D were added and mixed uniformly. The pH was 2.4.

[0050] Example 13: Leave-in scalp / hair treatment Component Amount (% by weight) -------------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 1.0 Ethanol 40.0 Glycyrrhetinic acid 0.02 PPG-3 Caprylyl Ether 0.3 Erucalactone DES (Nippon Fine Chemical) 1.5 PEG / PPG-20 / 20 Dimethicone 0.2 PEG-12 Dimethicone 0.4 Hydrogenated Retinol 0.1 Pyridoxine trishexyldecanoate 0.05 Bisglyceryl ascorbate 0.3 Hexyl 3-glyceryl ascorbate 0.3 Part B Purified water (amount to make a total of 100) (Acrylates / C10-30 alkyl acrylate) crosspolymer 0.4 Carbomer 0.05 Tremoist-SL (Nippon Fine Chemical) 1.0 (Acryloyldimethyltaurate ammonium / VP) copolymer 0.05 (Ammonium acryloyldimethyltaurate / methacrylic acid Beheneth-25 Crosspolymer 0.1 Hydroxypropyl chitosan 0.1 Methylparaben 0.1 Phenoxyethanol 0.2 C part Malic acid 0.5 3-O-Ethyl ascorbic acid (Nippon Fine Chemical) 0.05 Nicotinamide 0.3 Pyridoxine hydrochloride 0.1 Caffeine 0.1 Glucosyltrehalose 0.1 Purified water 10.0 ---------------------------------------- (Preparation method) Part A was heated to approximately 50°C and dissolved. Next, part B was uniformly dispersed to form a viscous liquid. Part A was added to part B while stirring and mixed uniformly. Next, part C was added and mixed uniformly. The pH was adjusted to 4.0 with triethanolamine.

[0051] Example 14 Hair Treatment Component Amount (% by weight) ------------------------------------ Part A LUSPLAN DD-DHR (Nippon Fine Chemicals) 0.5 Dodecane 1.5 Neosolue-Aqulio (Nippon Fine Chemical) 0.2 Candelilla Wax 0.2 Cetyl Esters 0.3 Stearyl ethylhexanoate 1.0 Cetearyl Alcohol 3.5 PEG-200 0.5 Hydroxyethyl cellulose 0.4 Cetrimonium chloride (30%) 1.0 Behentrimonium chloride (80%) 1.0 Trideceth-6 0.3 BHT 0.03 Part B Methylparaben 0.2 Malic acid 0.1 Lactic acid 0.05 Purified water (amount to make a total of 100) C part PPG-3 Myristyl 0.5 Neosolue-MP (Nippon Fine Chemical) 1.0 ------------------------------------- (Preparation method) Part B was heated to about 80°C and dissolved. Part A was added to a separate container, heated, and dissolved. Part B was gradually added to part A and mixed uniformly. Part C was added at about 50°C with stirring and made uniform. The pH was 3.5.

[0052] Example 15: Non-silicone hair treatment Component Amount (% by weight) -------------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 0.5 Plandool-LG2 (Nippon Fine Chemical) 0.5 LUSPLAN DD-DA5 (Nippon Fine Chemical) 0.05 Propanediol 3.0 Behenamidopropyl dimethylamine 1.5 Cetyl alcohol 2.2 Stearyl alcohol 0.8 Hydrogenated rapeseed oil alcohol 0.5 Neopentyl glycol diethylhexanoate 0.8 Jojoba Seed Oil 1.0 Glyceryl stearate 0.4 Propylparaben 0.1 Cocamide MEA 0.8 Caesalpinia spinosa Hydroxypropyltrimonium chloride 0.1 Rice bran wax 0.5 Glycerin 1.0 Part B Methylparaben 0.1 Tremoist-TP (Nippon Fine Chemical) 0.5 Lactic acid 0.4 Succinic acid 0.1 Purified water (amount to make a total of 100) C part Methylheptyl caprylate 1.0 Polyquaternium-7 0.15 Myristic acid PPG-3 benzyl ether 0.5 -------------------------------------- (Preparation method) Part A was mixed uniformly at about 80°C. Part B, which had been set aside, was heated to about 60°C and homogenized. Part B was gradually added to part A while stirring, and after mixing uniformly, the mixture was cooled to about 50°C. Part C was then added and mixed uniformly. The pH was 3.1.

[0053] Example 16: Non-silicone hair treatment Component Amount (% by weight) ----------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 1.0 FineNeo-MCT (Nippon Fine Chemical) 0.6 Stearyl Alcohol 2.0 Cetyl alcohol 1.2 Steartrimonium chloride 1.0 PEG-45M 0.8 Plandool-LG1 (Nippon Fine Chemical) 0.3 Camellia reticulata seed oil 0.4 Hydroxyethyl urea 0.5 Dicaprylyl Carbonate 2.0 PPG-1 / PEG-1 stearamine 1.0 Squalane 0.1 Isoceteth-10 0.5 Sunflower Wax 0.8 Cocoyl Arginate Ethyl PCA 0.2 Phenoxyethanol 0.2 Tocopherol 0.05 Part B DPG 2.2 Glycerin 1.3 Sorbitol 3.5 BG 1.0 Hydroxycellulose 0.07 Phenoxyethanol 0.2 Malonic acid 0.3 Malic acid 0.2 EDTA-2Na 0.01 Purified water (amount to make a total of 100) C part Tremoist-SL (Nippon Fine Chemical) 1.0 Polyquaternium-61 0.3 ----------------------------------- (Preparation method) Part A was mixed uniformly at about 80°C. Part B, which had been set aside, was heated to about 60°C and homogenized. Part B was gradually added to part A while stirring, and after mixing uniformly, the mixture was cooled to about 50°C. Part C was then added and mixed uniformly. The pH was 3.3.

[0054] Example 17: Non-silicone hair treatment Component Amount (% by weight) ----------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 2.0 LUSPLAN DD-DA7 (Nippon Fine Chemical) 0.1 Cetearyl Alcohol 3.0 PPG-1 / PEG-1 stearamine 0.8 Behenamidopropyl dimethylamine 1.0 Ethylhexyl palmitate 1.0 Dextrin palmitate 0.5 Inulin stearate 0.5 Neosolue-DE (Nippon Fine Chemical) 1.0 Hybrid Sunflower Oil 1.0 DPG 1.8 Glycerin 4.0 Mineral oil 0.5 Plandool-DP (Nippon Fine Chemical) 1.0 PEG-160M ​​0.5 Rice Bran Wax 1.0 Part B Hydroxylated lecithin 0.2 Succinic acid 0.2 Lactic acid 0.2 Maleic acid 0.1 Hydrolyzed starch 0.4 Sodium Hyaluronate 0.05 Inulin-SC (Nippon Fine Chemical) 1.0 Hydroxypropyl methylcellulose 0.1 Purified water (amount to make a total of 100) C part Polyquaternium-107 0.5 Neopentyl glycol diheptanoate 2.0 Ethylhexyl isononanoate 1.0 ----------------------------------- (Preparation method) Part B was heated to approximately 80°C and dissolved uniformly. Part A was added to a separate container, heated, and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. At around 50°C, part C was added and mixed uniformly. The pH was adjusted to 5.0 with sodium hydroxide.

[0055] Example 18: Non-silicone treatment Component Amount (% by weight) ---------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 0.3 Neosolue-Aqua (Nippon Fine Chemical) 0.2 Stearyl Alcohol 3.0 Behentrimonium chloride 1.0 Steartrimonium chloride 0.5 Stearamidopropyl dimethylamine 0.1 Hydrogenated polyisobutene 1.0 Hydrogenated polydecene 0.6 Camellia seed oil 0.5 Dicaprylyl Ether 3.0 Sodium Dilauramidolysine 0.1 Ascorbyl dipalmitate 0.1 BG 3.0 Tocopherol 0.1 Phenoxyethanol 0.4 Part B Sodium bicarbonate 0.4 Malic acid 1.0 Purified water (amount to make a total of 100) Locust Bean Hydroxypropyltrimonium Chloride 0.1 Tremoist-SL (Nippon Fine Chemical) 1.0 ---------------------------------- (Preparation method) Part B was heated to about 80°C and dissolved uniformly. Part A was added to a separate container, heated, and dissolved. Part B was gradually added to part A, mixed uniformly, emulsified, and then cooled to about 40°C. The pH was 3.6.

[0056] Example 19: Non-silicone treatment Component Amount (% by weight) ----------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 1.0 Plandool-S (Nippon Fine Chemical) 0.5 Plandool-MAS (Nippon Fine Chemicals) 0.3 Behentrimonium methosulfate 1.3 Cetrimonium chloride 0.3 Paraffin 1.0 Hyaluronic acid hydroxypropyltrimonium 0.2 Hydrogenated castor oil isostearate 1.0 Squalane 2.0 Tocopheryl acetate 0.05 Diethyl sebacate 2.0 Candelilla Wax 0.3 Rice bran wax 0.2 Apricot kernel oil 1.0 DPG 2.0 Propanediol 1.0 Benzyl alcohol 0.5 Glycerin 1.0 PEG-7 Propylheptyl Ether 0.8 PEG-180M 0.3 Part B Methylisothiazolinone 0.005 EDTA-2Na 0.03 Succinic acid 0.6 Zinc chloride 0.1 Purified water (amount to make a total of 100) Polyquaternium-10 0.2 C part LUSPLAN SR-DM4 (Nippon Fine Chemicals) 0.05 Neosolue-MP (Nippon Fine Chemicals) 0.5 FineNeo-EHS (Nippon Fine Chemical) 0.7 ----------------------------------- (Preparation method) Part B was heated to about 80°C and dissolved uniformly. Part A was added to a separate container, heated, and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 50°C and mixed uniformly. The pH was 4.1.

[0057] Example 20 Dandruff shampoo Component Amount (% by weight) ------------------------------------ Part A Neosolue-Aqulio (Nippon Fine Chemical) 0.05 Sodium Lauroyl Methylalanine (30%) 13.0 Cocamidopropyl Betaine (30%) 20.0 TEA-Cocoyl Glutamate (30%) 5.0 Cocamide DEA 1.0 Glycerin 1.0 Glyceryl Caprylate 0.4 Glyceryl Undecylenate 0.1 Neosolue-Aqua (Nippon Fine Chemical) 1.0 Sorbitol 1.6 Miconazole nitrate 0.75 Glycol distearate 1.5 Polyquaternium-7 0.3 Part B Malonic acid 2.0 Sodium benzoate 0.4 Sodium chloride 0.2 Purified water (amount to make a total of 100) C part Swertia japonica extract 3.0 Polyquaternium-10 0.2 Guar Hydroxypropyltrimonium Chloride 0.1 Polyquaternium-47 0.1 Piroctone Olamine 0.1 Purified water 9.7 ------------------------------------ (Preparation method) Part B was heated to approximately 80°C and dissolved uniformly. Part A was placed in a separate container and heated to dissolve. Part B was gradually added to part A and mixed uniformly, and then part C was added at approximately 60°C. The pH was adjusted to 5.0 with sodium hydroxide.

[0058] Example 21 Shampoo Component Amount (% by weight) ---------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 0.2 Neosolue-DiSM (Nippon Fine Chemical) 0.5 PPG-3 Caprylyl Ether 0.2 Ammonium Laureth Sulfate 5.0 Sodium laureth sulfate (25%) 10.0 Lauryl Hydroxysultaine (30%) 10.0 Potassium laurate 1.0 Glycol distearate 0.5 Toluenesulfonic acid 0.3 Stearoxypropyldimethylamine 0.5 PPG-17 0.3 Dimethicone (6cs) 0.1 PEG-9 Dimethicone 0.1 Amodimethicone 0.1 FineNeo-EHS (Nippon Fine Chemical) 1.0 Neopentyl glycol diethylhexanoate 0.4 Lanolin Fatty Acids 0.3 Isodecyl glyceryl ether 0.4 Cocamide MEA 1.0 Laureth-4 0.3 Laureth-16 0.2 Steareth-6 0.2 Phenoxyethanol 0.3 Part B Malonic acid 0.1 Methylparaben 0.2 Sodium benzoate 0.3 Purified water (amount to make a total of 100) C part NanoRepair-CMC (Nippon Fine Chemical) 5.0 Polyquaternium-10 0.2 Guar Hydroxypropyltrimonium Chloride 0.1 Tremoist-SL (Nippon Fine Chemical) 3.0 Purified water 6.7 ---------------------------------- (Preparation method) Part A was mixed uniformly at about 80°C. Part B, which had been set aside, was heated to about 60°C and homogenized. Part B was gradually added to part A while stirring, and after mixing uniformly, the mixture was cooled to about 50°C. Part C was then added and mixed uniformly. The pH was 5.6.

[0059] Example 22 Non-silicone hair treatment Component Amount (% by weight) -------------------------------- Part A Plandool-LG3 1.0 Neosolue-Aqulio (Nippon Fine Chemical) 0.5 Glyceryl stearate (SE) 4.5 Steareth-10 4.0 Cetyl alcohol 4.0 Steartrimonium chloride (63%) 1.8 Behentrimonium chloride (80%) 1.0 Part B Methylparaben 0.2 Glycerin 3.0 Maleic acid 0.2 Purified water (amount to make a total of 100) --------------------------------- (Preparation method) Part B was heated to about 80°C and dissolved. Part A was added to a separate container, heated, and dissolved. Part B was gradually added to part A and mixed uniformly. The pH was 3.2.

[0060] Example 23 Hair Treatment Component Amount (% by weight) --------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 1.0 Plandool-G (Nippon Fine Chemical) 1.0 Behentrimonium chloride (80%) 2.4 Cetyl alcohol 5.2 Glyceryl stearate 1.2 FineNeo-EHS (Nippon Fine Chemical) 0.4 Cyclopentasiloxane 0.8 Dimethiconol 0.1 Part B Methylparaben 0.1 Propylparaben 0.1 Malic acid 0.1 Citric acid 0.1 Purified water (amount to make a total of 100) C part Aminoethylaminopropylsiloxane Dimethylsiloxane copolymer emulsion 2.0 --------------------------------- (Preparation method) Parts A and B were taken separately, heated to approximately 80°C, and mixed uniformly. Part B was gradually added to part A while stirring, mixed uniformly, and then cooled (part D). Part C was added to part D and mixed uniformly. The pH was adjusted to 6.0 with arginine.

[0061] Example 24 Hair Treatment Component Amount (% by weight) ------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 2.0 Plandool-SUN (Nippon Fine Chemical) 1.0 Cetyl alcohol 6.0 Dimethicone (1000cs) 2.0 Aminopropyl Dimethicone 0.4 Behentrimonium chloride (80%) 2.4 Distearyldimonium chloride (75%) 0.8 Glyceryl stearate 0.8 Part B Succinic acid 2.0 Phenoxyethanol 0.5 Purified water (amount to make a total of 100) C part Hydrolyzed Keratin (20%) 1.5 ------------------------------- (Preparation method) Part B was heated to about 80°C and dissolved uniformly. Part A was added to a separate container, heated, and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 40°C and mixed uniformly. The pH was 3.1.

[0062] Example 25 Hair Treatment Component Amount (% by weight) --------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 0.2 Plandool-LG4 (Nippon Fine Chemical) 2.0 Dodecane 3.0 Behenyl Alcohol 4.0 Cetyl alcohol 2.0 Behentrimonium Chloride 2.0 Stearamidopropyl dimethylamine 1.0 Glyceryl stearate 0.4 PPG-9 Diglyceryl 0.2 Polyglyceryl-2 Diisostearate 0.1 Hydrogenated lecithin 0.1 Adsorbed purified lanolin 0.2 Neopentyl glycol dioctanoate 0.5 FineNeo-EHS (Nippon Fine Chemical) 0.5 Tocopherol 0.05 Part B Glycerin 0.2 DPG 0.2 Hydrolyzed Collagen 0.1 Panthenol 0.1 Hydroxycellulose 0.02 Polyquaternium-10 0.05 Phenoxyethanol 0.2 Maleic acid 0.1 Citric acid 0.4 Disodium edetate 0.01 Pentetic acid 0.02 Purified water (amount to make a total of 100) --------------------------------- (Preparation method) Part A was heated to approximately 80°C and dissolved uniformly. Part B was placed in a separate container and heated to approximately 80°C and dissolved uniformly. Part B was gradually added to Part A, mixed uniformly, and cooled. The pH was adjusted to 5.0 with arginine.

[0063] Example 26 Hair growth agent Component Amount (% by weight) ------------------------------------- Part A Phytopresome Cera-23 (Nippon Fine Chemical) 0.05 BG 5.0 Glycerin 3.0 1,2-Pentanediol 5.0 Phytopresome MEL (Nippon Fine Chemical) 1.0 Polysorbate-20 0.1 LP70H (Nippon Fine Chemical) 0.02 Part B Neosolue-Aqulio (Nippon Fine Chemical) 0.5 DPG 2.0 Lactic acid 0.3 Tremoist-TP (Nippon Fine Chemical) 0.01 Purified water 50.0 C part Ethanol 10.0 Menthol 0.1 Menthyl glyceryl ether 0.15 Panthenyl ethyl ether 0.2 Camphor 0.1 Cordyceps extract 1.0 Swertia japonica extract 1.0 Loquat Leaf Extract 1.0 Hydrolyzed hyaluronic acid 0.02 Sodium cyclic lysophosphatidic acid 0.001 Capsicum extract 0.01 Betaine 0.3 Trehalose 0.2 Cymen-5-ol 0.1 Tocopheryl acetate 0.05 β-Glycyrrhetinic acid 0.05 Purified water (amount to make a total of 100) ------------------------------------- (Preparation method) Parts A and B were heated to 70°C, and part A was added to part B while stirring with a propeller (500 rpm) to prepare a nanovesicle solution. After cooling, premixed part C was added to make a homogeneous solution. The pH was adjusted to 5.1 with arginine.

[0064] Example 27 Leave-on Treatment Component Amount (% by weight) ------------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 1.50 Erucalactone DES (Nippon Fine Chemical) 2.50 Plandool-LG3 (Nippon Fine Chemical) 2.00 Myristyl alcohol 5.00 Behenyl Alcohol 1.00 Oleyl alcohol 1.00 Stearic acid dimethylpropylamide 2.00 Sodium Cocoamphoacetate (30%) 2.00 Glyceryl stearate 0.40 Myristic acid 0.60 Phenoxyethanol 0.40 Part B Lactic acid 1.00 Malonic acid 0.50 Purified water (amount to make a total of 100) ------------------------------------- (Preparation method) Part A was heated to about 80°C and dissolved uniformly. Part B was heated to about 80°C and dissolved. Part B was gradually added to Part A and mixed uniformly. The pH was adjusted to 4.5 with sodium hydroxide.

[0065] Example 28 Leave-on Hair Treatment Component Amount (% by weight) ---------------------------------- Part A PrimeLipid PI (Nippon Fine Chemical) 0.2 Phytopresome MEL (Nippon Fine Chemical) 1.5 Polysorbate 80 0.1 Neosolue-Aqulio (Nippon Fine Chemical) 2.0 Cetrimonium chloride (25%) 3.8 Isostearic acid 0.02 Erucalactone DES (Nippon Fine Chemical) 1.0 Caprylyl glucoside (50%) 0.8 Glycerin 4.0 1,2-Hexanediol 2.0 Phenoxyethanol 0.5 Part B Ethanol 5.0 C part Succinic acid 1.0 Hydrolyzed Keratin 0.2 Hydrolyzed silk 0.1 Hydrolyzed conchiolin 0.1 Polyquaternium-6 0.6 Polyquaternium-7 0.4 Polyquaternium-39 0.5 Purified water (amount to make a total of 100) ---------------------------------- (Preparation method) Part C was heated to about 80°C and dissolved. Next, part A was heated to about 80°C and dissolved. Part A was added to part C while stirring, and after uniformly mixing, the mixture was cooled to about 40°C. Next, part B was added and mixed uniformly. The pH was 3.4.

[0066] Example 29: Non-silicone leave-in hair treatment Component Amount (% by weight) ---------------------------------- Part A Erucalactone MCT (Nippon Fine Chemical) 1.20 LUSPLAN SR-DM4 (Nippon Fine Chemicals) 0.05 FineNeo-EHSU (Nippon Fine Chemicals) 0.396 LUSPAN PI-DA (Nippon Fine Chemical) 0.004 Cetearyl Alcohol 2.00 Seteth -20 0.40 Glyceryl stearate 0.20 Stearamidopropyl dimethylamine 0.20 Isostearyl alcohol 0.10 PG 3.00 Part B Purified water (amount to make a total of 100) Lactic acid 0.05 C part Neosolue-Aqulio (Nippon Fine Chemical) 0.50 Hydroxyethyl cellulose 0.20 Ethanol 10.00 Phenoxyethanol 0.5 ---------------------------------- (Preparation method) Parts A and B were heated to approximately 80°C, and part B was added to part A while stirring to emulsify. After cooling to approximately 50°C, part C was added and mixed uniformly. The pH was 6.1.

[0067] Example 30 Hair wax Component Amount (% by weight) ---------------------------------- Part A Microcrystalline Wax 10.0 Ecolano LH (Nippon Fine Chemical) 4.0 Candelilla Wax 2.0 Beeswax 2.0 Stearic Acid 4.0 Cetearyl Alcohol 4.0 Polyglyceryl-10 Stearate 2.0 FineNeo-IOP (Nippon Fine Chemical) 2.0 Glyceryl stearate 0.6 Tocopherol 0.05 Part B Purified water (amount to make a total of 100) Phenoxyethanol 0.4 Methylparaben 0.1 C part Neosolue-Aqulio (Nippon Fine Chemical) 0.2 Inulin-SC (Nippon Fine Chemical) 1.0 Succinic acid 0.3 Purified water 20.0 ---------------------------------- (Preparation method) Parts A and B were heated to approximately 80°C, and Part B was added to Part A while stirring to emulsify. After cooling to approximately 50°C, Part C was added and mixed uniformly. The pH was adjusted to 7.0 with sodium hydroxide.

[0068] Example 31 Styling Milk Component Amount (% by weight) --------------------------------- Part A LUSPLAN SR-DP4 (Nippon Fine Chemical) 1.0 Stearyl alcohol 1.7 Neosolue-IPP (Nippon Fine Chemical) 1.2 Stearamidopropyl dimethylamine 1.0 Plandool-H (Nippon Fine Chemical) 0.2 Plandool-ISS (Nippon Fine Chemical) 0.2 Seteth -20 0.3 Part B Phenoxyethanol 0.4 Lactic acid 0.5 Purified water (amount to make a total of 100) C part Neosolue-Aqulio (Nippon Fine Chemical) 0.5 Hydroxyethyl cellulose 0.4 BG 2.0 Purified water 30.0 --------------------------------- (Preparation method) Part A and Part B were mixed at approximately 80°C. Part B was added to Part A and emulsified, and after cooling to approximately 60°C, Part C was added. The mixture was cooled to approximately 40°C and mixed with Part D to make a homogenous mixture. The pH was 4.2.

[0069] Example 32 Styling Gel Component Amount (% by weight) --------------------------------- Part A Phytopresome MEL (Nippon Fine Chemical) 1.5 Neosolue-Aqulio (Nippon Fine Chemical) 2.0 Neosolue-AquaS (Nippon Fine Chemical) 0.5 Glycerin 3.0 PG 2.0 BG 5.0 Part B Lactic acid 0.3 Phenoxyethanol 0.5 Hydroxyethyl cellulose 0.4 (Acrylates / C10-30 alkyl acrylate) crosspolymer 0.5 (Acryloyldimethyltaurate ammonium / VP) copolymer 0.05 Carbomer 0.2 Purified water (amount to make a total of 100) --------------------------------- (Preparation method) Part A and Part B were mixed at approximately 60°C. Part A was added to Part B while stirring with a propeller, and mixed uniformly. The pH was adjusted to 6.0 with sodium hydroxide.

[0070] Example 33 Mousse Component Amount (% by weight) --------------------------------- Neosolue-Aqulio (Nippon Fine Chemical) 0.2 Ethanol 5.0 Polyethylene glycol oleyl ether (20) 1.0 Acrylic Resin Alkanolamine Liquid 3.0 Stearic acid diethylaminopropylamide 0.5 Pyrrolidone carboxylic acid 0.2 Malic acid 0.1 Preservatives, fragrances 1.0 Purified water (amount to make a total of 100) --------------------------------- (Preparation method) The above ingredients were mixed, and the resulting base was mixed with LPG in a ratio of base:LPG=92:8 to give a spray-type mousse. The pH was 5.1.

[0071] Example 34 Hair Cream Component Amount (% by weight) --------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 0.5 Stearic Acid 2.0 Lanolin 3.0 Paraffin Wax 2.0 Liquid paraffin 38.0 Glyceryl monostearate (SE) 1.0 Sorbitan Monostearate 1.0 Polyoxyethylene Cetyl Ether 1.5 Preservatives (appropriate amount) Part B 1,3-butylene glycol 3.0 Succinic acid 0.5 Fragrance (appropriate amount) Purified water (amount to make a total of 100) --------------------------------- (Preparation method) Part A was mixed at 80°C. Part B, excluding the fragrance, was mixed, heated to 80°C, and mixed with Part A until homogenous. After cooling to 50°C, the fragrance was added. The pH was adjusted to 5.5 with triethanolamine.

[0072] Example 35 Styling Milk Component Amount (% by weight) --------------------------------- Part A Phytocompo-C (Nippon Fine Chemical) 1.0 Glycerin 5.0 BG 8.0 Part B Erucalactone MCT (Nippon Fine Chemical) 1.0 LUSPLAN DD-IS (Nippon Fine Chemical) 1.0 Cetearyl Alcohol 1.0 FineNeo-IPP (Nippon Fine Chemical) 2.0 LUSPLAN SR-DM4 1.0 Seteth -20 0.3 C part Methylparaben 0.1 Purified water (amount to make a total of 100) D part Neosolue-Aqulio (Nippon Fine Chemical) 0.5 Carbomer (2%) 5.0 Xanthan gum 0.5 Malonic acid 0.2 Phenoxyethanol 0.4 Purified water 30.0 --------------------------------- pH 6.0 (Preparation method) Disperse part A uniformly. Heat and dissolve parts B and C separately at approximately 70°C. Add part B gradually to part A, then add part C gradually and emulsify. Cool with stirring, add part D at 45°C and stir. Adjust the pH to 6.5 with sodium hydroxide.

[0073] Example 36 Hair Color Treatment Component Amount (% by weight) -------------------------------------- Part A Neosolue-Aqulio (Nippon Fine Chemical) 1.0 Steartrimonium chloride (70%) 2.5 Ecolano CA-NH (Nippon Fine Chemical) 0.3 Cocamide DEA 1.0 Inulin stearate 0.5 Lanolin alcohol 0.2 Montan wax 0.1 Polyethylene wax 0.1 Beeswax 0.1 Dextrin palmitate 0.3 Ceresin 0.1 Capric Acid PPG-3 1.0 PG Dicaprate 1.0 Ethylhexyl ethylhexanoate 1.0 Dicaprylyl Carbonate 1.5 Glycerin 4.0 Seteth-7 1.0 Isostearyl alcohol 0.3 Rice bran oil 0.5 Glyceryl stearate 0.5 Erucalactone DES (Nippon Fine Chemical) 1.5 Hydrogenated polydecene 0.1 Macadamia nut fatty acid ethyl ester 1.0 Sodium Dilauramidoglutamide Lysine 0.1 Behendimonium ethyl stearyl phosphate 0.1 Tocopherol 0.05 Phenoxyethanol 0.3 C part Purified water 10.0 BG 2.0 Acylated Hydrolyzed Collagen 0.1 Panthenol 0.1 Hydroxyethyl cellulose 0.1 Polyquaternium-64 0.1 Polyquaternium-51 0.01 Polyquaternium-49 0.2 Phenoxyethanol 0.4 PCA-Na 0.1 Malic acid 0.1 D part Purified water (amount to make a total of 100) Basic Blue 99 0.1 Basic Tea 16 0.13 HC blue 2 0.05 HC yellow 2 0.03 HC red 3 0.1 Hydroxyethyl urea 0.5 Ammonium bicarbonate 1.0 -------------------------------------- (Preparation method) Part A, which had been mixed uniformly in advance, was added to part B and heated to approximately 80°C to dissolve (part E). In a separate container, part D was heated to approximately 80°C to dissolve. Part D was gradually added to part E while stirring, mixed uniformly, and then rapidly cooled (part F). Part C was added to part F, which had reached approximately 40°C, and the mixture was homogenized. The pH was adjusted to 5.0 with arginine.

[0074] Example 37 Hair Manicure Component Amount (% by weight) -------------------------------------- Part A Ethanol 10.0 Carnauba wax 0.01 Seteth-10 1.0 Erucalactone DES (Nippon Fine Chemical) 2.5 PPG-3 Caprylyl Ether 1.0 Neosolue-MP (Nippon Fine Chemical) 1.0 Capric Acid PPG-3 0.5 PG Dicaprate 0.5 Dicaprylyl Carbonate 0.5 Part B Purple 401 0.2 Black 401 0.1 Orange 205 0.1 Red 102 0.1 Benzyl alcohol 8.0 Ethanol 10.0 C part Purified water (amount to make a total of 100) (Acryloyldimethyltaurate ammonium / VP) copolymer 3.0 Glycolic Acid 2.0 Succinic acid 2.0 Neosolue-Aqulio (Nippon Fine Chemical) 2.0 Hydroxypropyl xanthan gum 0.2 -------------------------------------- (Preparation method) Part A and Part C were mixed together and homogenized. Part B was added to Part C while stirring and mixed homogenously. After that, Part A was added at about 60°C and mixed homogenously. The pH was 2.6.

[0075] In the above prescription, details of the ingredients listed by product name are as follows: LUSPLAN DD-IS: Dimer dilinoleyl diisostearate LUSPLAN PI-DA: Diisostearyl / Phytosteryl Dimer Dilinoleate LUSPLAN DD-DHR: Dimer dilinoleyl hydrogenated rosin condensate LUSPLAN DD-DA5: Dimer dilinoleyl dimer dilinoleate LUSPLAN DD-DA7: Dimer dilinoleyl dimer dilinoleate LUSPLAN SR-DM4: Dimer dilinoleyl dimer dilinoleate, caprylic / capric triglyceride LUSPLAN SR-DP4: Dimer dilinoleyl dimer dilinoleate, pentaerythrityl tetraisostearate Inulin-SC: Inulin NanoRepair-EL: Composition containing gamma-docosalactone and soybean sterols NanoRepair-CMC: Composition containing quaternium-18, quaternium-33, cholesterol, ceramide 2, ceramide 3, ceramide 6, and PG NanoRepair-CMC5: Composition containing ceramide 1, ceramide 2, ceramide 3, ceramide 5, ceramide 6, cholesterol, and quaternium-33 Neosolue-Aqulio: bisethoxydiglycol cyclohexanedicarboxylic acid Neosolue-Aqua: Polyglyceryl-10 (eicosanedioate / tetradecanedioate), glycerin Neosolue-AquaS: Polyglyceryl-10 (eicosanedioate / tetradecanedioate), glycerin Neosolue-DiSM: Diisostearyl malate Neosolue-MP: Methylpentanediol dineopentanoate Neosolue-DE: Diethyl pentanediol dineopentanoate FineNeo-EHS: Diethylhexyl sebacate FineNeo-EHSU: Diethylhexyl succinate FineNeo-MCT: ​​Caprylic / capric triglyceride FineNeo-IPP: Isopropyl palmitate FineNeo-IOP: Ethylhexyl palmitate Plandool-H: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) Plandool-S: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) Plandool-G: Dimer dilinoleyl bis(behenyl / isostearyl / phytosteryl) dimer dilinoleate Plandool-DP: Bis-diglyceryl polyacyladipate-2 Plandool-ISS: Phytosteryl isostearate Plandool-SUN: Sunflower seed oil fatty acid phytosteryl Plandool-MAS: Macadamia nut oil fatty acid phytosteryl Plandool-LG1: Phytosteryl / Octyldodecyl / Behenyl Lauroyl Glutamate Plandool-LG2: Phytosteryl / Octyldodecyl Lauroyl Glutamate Plandool-LG3: Phytosteryl / Octyldodecyl / Behenyl Lauroyl Glutamate Plandool-LG4: Phytosteryl / Octyldodecyl / Behenyl Lauroyl Glutamate Phytocompo-C: Hydrogenated lecithin, phytosterols, ceramide 2, ceramide 3, ceramide 6II Phytopresome Cera23: Hydrogenated lecithin, phytosterols, ceramide 2, ceramide 3 Phytopresome MEL: glycolipids, hydrogenated lecithin, BG, purified water PrimeLipid PI: Hydrogenated lecithin, lecithin, phytosterols, tocopherol Tremoist-TP: Tremella fuciformis polysaccharide Tremoist-SL: Tremella fuciformis polysaccharide aqueous solution (1%) LP70H: Hydrogenated lysolecithin Erucalactone MCT: γ-docosalactone, caprylic / capric triglyceride Erucalactone DES: γ-docosalactone, diethyl sebacate Ecolano LH: Lanolin wax Ecolano CA-NH: Quaternium-33, BG [Brief explanation of the drawings]

[0076] [Figure 1] 1 shows microscope images of hair before and after treatment with the hair cavity repair agent of Example 4.

Claims

1. A hair cavity repair agent containing the following components (A) and (B). (A) one or more selected from succinic acid, malonic acid, maleic acid, and malic acid (B) Diester of cyclohexanedicarboxylic acid and diethylene glycol monoethyl ether

2. A method for repairing cavities that occur inside hair using the hair cavity repair agent according to claim 1.

3. A hair cosmetic containing the hair cavity repair agent according to claim 1, the hair cosmetic being selected from shampoo, rinse, treatment, hair pack, hair foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, setting lotion, color lotion, hair cream, hair blow dryer, split end coat, hair oil, hair color pre-treatment, hair color after-treatment, perm pre-treatment, perm after-treatment and hair manicure.

Images