Active Compound Combination

Abstract

The present invention relates to active compound combinations, particularly in fungicidal compositions, comprising a compound of formula (I) as compound (A) and a further fungicidally active compound as specified below as compound (B). The present invention further relates to compositions comprising such compound combinations and to the use of the compound combinations and fungicidal compositions as biologically active agents, particularly for the control of phytopathogenic fungi in crop protection and in the protection of industrial materials, and as plant growth regulators.

Claims

1. (A) Formula (I) 【Chemical 1】 at least one compound of the formula A is O; m is 1; T is hydrogen; R ３ and R ４ is hydrogen; R ５ is hydrogen; L is methylene; R ６ is 2,4-dimethylphenyl, 2-methyl-4-bromophenyl, or 2-chloro-4-methylphenyl; R ７ is methyl; R ８ is hydrogen; Q is 2-fluoro-3-chlorophenyl, 2-fluoro-3-bromophenyl, or 2-fluoro-3-cyclopropylphenyl; (B) at least one further active compound, (1.002) Difenoconazole, (1.018) Prothioconazole, (1.020) Spiroxamine, (1.021) Tebuconazole, (1.055) Mefentrifluconazole, (1.062) Fluoxythioconazole, (1.067) N'-(2,5-dimethyl-4-{3-[(1,1,2,2-tetrafluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1.092) Methyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1,2,4-triazol-1-yl)propanoate, (2.001) Benzovindiflupyr, (2.002) Bixafen, (2.003) Boscalid, (2.005) Fluopyram, (2.007) Fluxapyroxad, (2.009) Isofetamide, (2.017) Penflufen, (2.019) Pydiflumetofen, (2.028) Inpirfluxam, (2.030) Fluindapyr, (2.038) Isoflucipram, (3.012) Fluoxastrobin, (3.020) Trifloxystrobin, (3.025) Fenpicoxamide, (3.030) Methyltetraprole, (3.031) Florylpicoxamide, (3.032) (2S,3S)-3-(o-Tolyl)butan-2-yl N-{[4-methoxy-3-(propanoyloxy)-2-pyridyl]carbonyl}-L-alaninate, (5.003) Captan, (5.010) Dithianon, (5.012) Folpet, (5.013) Mancozeb, (5.018) Propineb, (6.002) Isotianil, (7.005) Pyrimethanil, (12.004) Metalaxyl-M (mefenoxam), (13.001) Fludioxonil, (13.004) Proquinazid, (13.005) Quinoxyfen, (15.012) Fosetylaluminum, (15.016) Metrafenone, (15.041) ipflufenoquine, (15.043) fluoxapiprolin, and (15.064) (N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylimidoformamide), (17.001) Bacillus subtilis, strain QST713 / AQ713 (available from Bayer CropScience LP, USA, as SERENADE OPTI® or SERENADE ASO®, having NRRL accession number B21661 and described in U.S. Pat. No. 6,060,051), (17.012) a strain of Paenibacillus sp., having NRRL accession number B-50972 or NRRL accession number B-50973, B-67129 and those described in International Publication No. WO 2016 / 154297, and (18.001) a composition comprising one or more fatty acids selected from unsaturated and saturated C 12 -C 24 fatty acids, their salts, or mixtures of any of the foregoing, wherein at least 95% of the fatty acids are in the C 14 to C 20 range (available as FLiPPER from AlphaBio Pesticides or Bayer AG), and at least one further active compound selected from the group consisting of 10. An active compound combination comprising:

2. The compound of formula (I) is (I-052) rac-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine, (I-130) (5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2,4-dimethylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazine, (I-300) rac-5-[(4-bromo-2-methylphenyl)methyl]-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5,6-dihydro-4H-1,2,4-oxadiazine, (I-302) rac-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine, (I-337) (5S)-5-[(4-bromo-2-methylphenyl)methyl]-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5,6-dihydro-4H-1,2,4-oxadiazine, (I-338) 2. The active compound combination according to claim 1, wherein the active compound is selected from the group consisting of (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazine and (I-339) (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazine.

3. The compound of formula (I) is (I-302) rac-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine, (I-338) (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazine, and (I-339) 3. The active compound combination according to claim 1, which is selected from the group consisting of (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazine.

4. An active compound combination according to any one of claims 1 to 3, wherein the compound of formula (I) is (I-339) (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazine.

5. The further active compound (B) is (1.002) difenoconazole, (1.018) prothioconazole, (1.020) spiroxamine, (1.021) tebuconazole, (1.055) mefentrifluconazole, (1.062) fluoxythioconazole, (1.092) methyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1,2,4-triazol-1-yl)propanoate, (2.001) benzovindiflupyr, (2.002) bixafen, (2.003) boscalid, (2.005) fluopyram, (2.007) fluxapyroxad, (2.009) isofetamide, (2.017) Penflufen, (2.019) Pydiflumetofen, (2.028) Inpirfluxam, (2.030) Fluindapyr, (2.038) Isoflucipram, (3.012) Fluoxastrobin, (3.020) Trifloxystrobin, (3.025) Fenpicoxamide, (3.030) Methyltetraprole, (3.031) Florylpicoxamide, (3.032) (2S,3S)-3-(o-tolyl)butan-2-yl N-{[4-methoxy-3-(propanoyloxy)-2-pyridyl]carbonyl}-L-alaninate, (5.018) Propineb, (7.005) Pyrimethanil, (12.004) 5. The active compound combination according to any one of claims 1 to 4, selected from the group consisting of metalaxyl-M (mefenoxam), (13.001) fludioxonil, (13.004) proquinazid, (15.012) fosetylaluminum, (15.016) metrafenone, and (15.043) fluoxapiproline.

6. The further active ingredient (B) is (1.002) difenoconazole, (1.018) prothioconazole, (1.020) spiroxamine, (1.021) tebuconazole, (1.055) mefentrifluconazole, (1.062) fluoxythioconazole, (1.092) methyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1,2,4-triazol-1-yl)propanoate, (2.002) bixafen, (2.005) fluopyram, (2.007) fluxapyroxad, (2.009) isofetamide, (2.019) pydiflumetofen, (2.028) inpirfluxam, (2.038) 6. The active compound combination according to any one of claims 1 to 5, selected from the group consisting of isoflucipram, (3.020) trifloxystrobin, (3.025) fenpicoxamide, (3.030) methyltetraprole, (3.031) flurylpicoxamide, and (3.032) (2S,3S)-3-(o-tolyl)butan-2-yl N-{[4-methoxy-3-(propanoyloxy)-2-pyridyl]carbonyl}-L-alaninate.

7. A composition for controlling phytopathogenic harmful fungi in crop protection and material protection, characterized by the inclusion of an active compound combination as defined in any one of claims 1 to 6 in addition to one or more fillers and / or surfactants.

8. 10. A method for controlling phytopathogenic harmful fungi in crop protection and material protection, characterized in that an active compound combination according to at least one of claims 1 to 6 or a composition according to claim 7 is applied to the phytopathogenic harmful fungi and / or their habitat.

9. 10. Use of an active compound combination according to at least one of claims 1 to 6 or a composition according to claim 7 for controlling phytopathogenic harmful fungi in crop protection and material protection.

10. 8. Use of an active compound combination according to at least one of claims 1 to 6 or a composition according to claim 7 for treating transgenic plants.

11. 8. Use of an active compound combination according to at least one of claims 1 to 6 or a composition according to claim 7 for treating seeds.

12. Use of an active compound combination according to at least one of claims 1 to 6 or a composition according to claim 7 for treating seeds of transgenic plants.

13. Seeds coated with an active compound combination according to at least one of claims 1 to 6 or with a composition according to claim 7.

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