Anchor coating agent and method for producing flexographic prints using the same

Abstract

To provide an anchor coat agent having appropriate viscosity, capable of suppressing a misting phenomenon, capable of transferring a necessary amount uniformly to a printing medium, and capable of obtaining a coating film excellent in coating film resistance.SOLUTION: An anchor coat agent containing an emulsion, cellulose ether and / or polyvinyl alcohol and an aqueous medium. Preferably, the cellulose ether is selected from hydroxypropylmethylcellulose and hydroxyethylmethylcellulose, and an acid value of the emulsion is smaller than 50 mgKOH / g.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to an anchor coating agent and a method for producing a flexographic print using the same. [Background technology]

[0002] In the field of packaging containers, flexographic printing is generally used. In recent years, there has been growing interest in inkjet printing methods that are capable of reproducing high-quality designs in the field of packaging containers as well, from the perspective of increasing added value.

[0003] When printing by the inkjet printing method, it is known to apply an anchor coating agent containing a water-soluble polyvalent metal salt to the printing medium as a pretreatment.

[0004] For example, Patent Document 1 discloses an anchor coating agent that is applied to liner paper or cardboard and used in flexographic printing, and that contains a dissociable polyvalent metal salt, an emulsion, and an aqueous medium.

[0005] The anchor coating agent disclosed in Patent Document 1 has a low viscosity, which can cause misting, where the agent is sprayed and scattered during printing. In addition, the misting phenomenon can cause problems such as the agent not being transferred uniformly in the required amount to the printing medium.

[0006] Furthermore, in the anchor coating agent disclosed in Patent Document 1, the viscosity can be increased by adding a thickener, but misting caused by the thickener can occur, leaving room for further improvement. [Prior art documents] [Patent documents]

[0007] [Patent Document 1] Japanese Patent Application Laid-Open No. 2015-134914 Summary of the Invention [Problem to be solved by the invention]

[0008] An object of the present invention is to provide an anchor coating agent that has an appropriate viscosity, can suppress misting, can be uniformly transferred in a required amount to a printing medium, and can provide a coating film with excellent coating film resistance. [Means for solving the problem]

[0009]

[0006] As a result of extensive research in light of the above-mentioned problems, the present inventors have found that by containing an emulsion, cellulose ether and / or polyvinyl alcohol, and an aqueous medium, it is possible to obtain an anchor coating agent that has an appropriate viscosity, is capable of suppressing the misting phenomenon, is capable of being uniformly transferred in the required amount to a printing medium, and is capable of forming a coating film with excellent coating film resistance, and have completed the present invention.

[0010] That is, the anchor coating agent of the present invention is characterized by containing an emulsion, cellulose ether and / or polyvinyl alcohol, and an aqueous medium.

[0011] In the anchor coating agent of the present invention, the cellulose ether is preferably at least one selected from hydroxypropyl methylcellulose and hydroxyethyl methylcellulose. The emulsion preferably has an acid value of less than 50 mgKOH / g. The content of the emulsion is preferably 5 to 65 mass % in terms of solid content, based on the mass of the anchor coating agent. The anchor coating agent of the present invention preferably further contains an ionic salt. The ionic salt is preferably a calcium salt. The content of the ionic salt is preferably 0.1 to 40% by mass based on the mass of the anchor coating agent. The anchor coat of the present invention is preferably used in flexographic printing. The method for producing a flexographic print of the present invention is a method for producing a flexographic print printed by a flexographic printing machine, and is characterized by comprising a step of applying the anchor coating agent of the present invention to a printing medium. In the method for producing a flexographic printed matter of the present invention, the amount of the anchor coating agent applied is 0.1 to 10 g / m 2 It is preferable that the density is 0.1 to 2 g / m 2 It is more preferable that: The anchor coating agent of the present invention and the method for producing a flexographic print using the same will be described in detail below.

[0012] <Anchor coating agent> The anchor coating agent of the present invention is characterized by containing an emulsion, cellulose ether and / or polyvinyl alcohol, and an aqueous medium.

[0013] (emulsion) The anchor coating agent of the present invention contains an emulsion.

[0014] Examples of the emulsion include emulsions of acrylic resins, polyester resins, polyurethane resins, polyvinyl acetate resins, polyvinyl chloride resins, polystyrene resins, polybutadiene resins, and the like. Among these, acrylic resin emulsions are preferred from the viewpoint of providing excellent cohesiveness of the coating film of the anchor coating agent and favorably imparting coating film resistance. The above emulsions can be used alone or in combination of two or more.

[0015] The acid value of the emulsion is preferably less than 50 mgKOH / g. If the acid value of the emulsion is 50 mgKOH / g or more, when the anchor coating agent contains an ionic salt described below, interactions with the emulsion tend to occur, reducing the salting-out effect and decreasing inkjet printability.Furthermore, compatibility with the ionic salt described below decreases, making it impossible to impart sufficient storage stability. The acid value of the emulsion is more preferably 30 mgKOH / g or less, and from the viewpoint of imparting more favorable storage stability, is even more preferably 20 mgKOH / g or less.

[0016] The acid value of the emulsion can be measured using potentiometric titration. For example, it can be performed based on JIS K 0070:1992 "Testing methods for acid value, saponification value, ester value, iodine value, hydroxyl value and unsaponifiable matter of chemical products", etc. An example of such a potentiometric titrator is the automatic potentiometric titrator AT610 (manufactured by Kyoto Electronics Manufacturing Co., Ltd.).

[0017] The emulsion preferably has a glass transition temperature of 70°C or lower, more preferably 40°C or lower from the viewpoint of providing favorable storage stability, and even more preferably 20°C or lower from the viewpoint of providing more favorable coating film resistance. The lower limit of the glass transition temperature of the emulsion is preferably −10° C. or higher, and from the viewpoint of providing more suitable storage stability, it is more preferably 0° C. or higher.

[0018] The glass transition temperature of the emulsion can be measured by differential scanning calorimetry (DSC) in accordance with, for example, JIS K 7121:2012 "Method for measuring the glass transition temperature of plastics."

[0019] The content of the emulsion is preferably 5 to 65 mass % in terms of solid content, based on the mass of the anchor coating agent. If the content of the emulsion is less than 5% by mass in terms of solids, the cohesive strength of the coating film of the anchor coating agent may decrease, resulting in a decrease in coating film durability, whereas if the content of the emulsion is more than 65% by mass in terms of solids, there may be less room for blending other components, resulting in insufficient effects of the invention. From the viewpoint of providing favorable coating film resistance, the content of the emulsion is more preferably 6% by mass or more, and even more preferably 7% by mass or more, based on the mass of the anchor coating agent, in terms of solids. Also, from the viewpoint of providing favorable storage stability, the content of the emulsion is more preferably less than 30% by mass, even more preferably 15% by mass or less, particularly preferably 10% by mass or less, and most preferably 9% by mass or less, in terms of solids.

[0020] Examples of the emulsion include those obtained by emulsifying the above-mentioned resins in an aqueous medium described below using a low molecular weight emulsifier, those obtained by emulsifying the resins in an aqueous medium described below using a polymeric emulsifier, and those obtained by emulsifying the resins in an aqueous medium described below by self-emulsification.

[0021] Examples of the low molecular weight emulsifier include fatty acid esters of monosaccharides or polysaccharides, polyglycerol fatty acid esters, organic acid monoglycerides, propylene glycol fatty acid esters, polyglycerol condensed ricinoleate esters, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene alkyl ethers, alkylbenzene sulfonates, alkanesulfonates, α-olefin sulfonates, polyoxyethylene alkyl ether sulfates, alkyl sulfates, polyoxyethylene alkyl ether phosphates, alkyl phosphates, tetraalkylammonium salts, alkylbenzyldimethylammonium salts, fatty acid amidoamines, alkylpyridinium salts, alkylbetaines, and alkylamine oxides.

[0022] (Cellulose ether and / or polyvinyl alcohol) The anchor coating agent of the present invention contains cellulose ether and / or polyvinyl alcohol.

[0023] The anchor coating agent of the present invention preferably contains a cellulose ether from the viewpoint of imparting favorable storage stability. It is believed that the anchor coating agent of the present invention contains cellulose ether, which causes the numerous cyclic structures and numerous hydroxyl groups in the molecule to assume a specific orientation at the gas-liquid interface, thereby reducing the electrostatic charge of the mist that occurs when the anchor coating agent is used for flexographic printing, thereby reducing the misting phenomenon, and further improving the flow properties of the anchor coating agent and improving transferability. However, the present invention need not be interpreted as being limited to this mechanism of action.

[0024] Examples of the cellulose ether include alkyl celluloses such as methyl cellulose, ethyl cellulose, and propyl cellulose; hydroxyalkyl celluloses such as hydroxyethyl cellulose and hydroxypropyl cellulose; hydroxyalkyl alkyl celluloses such as hydroxypropyl methyl cellulose and hydroxyethyl methyl cellulose; aralkyl celluloses such as benzyl cellulose and trityl cellulose; cyanoalkyl celluloses such as cyanoethyl cellulose; carboxyalkyl celluloses such as carboxymethyl cellulose and carboxyethyl cellulose; carboxyalkyl alkyl celluloses such as carboxymethyl methyl cellulose and carboxymethyl ethyl cellulose; and aminoalkyl celluloses such as aminoethyl cellulose. The above cellulose ethers can be used alone or in combination of two or more kinds.

[0025] The cellulose ether is preferably at least one selected from hydroxypropyl methylcellulose and hydroxyethyl methylcellulose, and more preferably hydroxypropyl methylcellulose. When the cellulose ether is at least one selected from hydroxypropyl methylcellulose and hydroxyethyl methylcellulose, the solubility in an aqueous medium described below can be suitably imparted, and storage stability can be more suitably imparted. Furthermore, the use of hydroxyethyl methylcellulose can suitably impart the solubility in an aqueous medium described below and storage stability.

[0026] The content of the cellulose ether and / or polyvinyl alcohol is preferably 0.1 to 10 mass %, more preferably 0.2 to 5 mass %, and even more preferably 1 to 3 mass %, based on the mass of the anchor coating agent, from the viewpoints of imparting an appropriate viscosity, suppressing misting, and suitably imparting transferability that allows the required amount to be uniformly transferred to the printing medium.

[0027] The anchor coating agent of the present invention may contain a thickener other than the above-mentioned cellulose ether and / or polyvinyl alcohol, as long as the effect of the present invention is not impaired. Examples of thickeners other than the above-mentioned cellulose ether and / or polyvinyl alcohol include polyacrylic acid, (partially) neutralized polyacrylic acid, polyethylene glycol (and copolymers with other alkylene oxides), polyacrylamide (having a substituent on the nitrogen atom), polyethyleneimine, dextrin, sodium alginate, polyvinylpyrrolidone, polyethylene oxide (and copolymers with other alkylene oxides), various sugars such as cellulose and glucose, ethylene-vinyl alcohol copolymer, ethylene-acrylic acid copolymer (and neutralized products thereof), and the like.

[0028] From the viewpoint of imparting an appropriate viscosity and suppressing misting, the content of the cellulose ether and / or polyvinyl alcohol is preferably 80% by mass or more, more preferably 90% by mass or more, even more preferably 95% by mass or more, and most preferably 100% by mass, relative to the total mass of the thickener (the cellulose ether and / or polyvinyl alcohol and a thickener other than the cellulose ether and / or polyvinyl alcohol). The "appropriate viscosity" in the present invention refers to a viscosity that gives a viscosity of 8 to 35 seconds when measured at a liquid temperature of 23°C using a Zahn cup (manufactured by Rigaud, number 4).

[0029] (aqueous medium) The aqueous medium may be water or a mixture of water and a water-miscible solvent. Examples of the water-miscible solvent include lower alcohols, polyhydric alcohols, and alkyl ethers or alkyl esters thereof, specifically lower alcohols such as methanol, ethanol, normal propanol, isopropanol, butanol, isobutanol, and secondary butanol, polyhydric alcohols such as ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, and glycerin, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monoacetate, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monoacetate, diethylene glycol monomethyl ether, and dipropylene glycol monomethyl ether. The above aqueous media can be used alone or in combination of two or more kinds.

[0030] From the viewpoint of imparting suitable fluidity and suitable abrasion resistance to the coating film of the anchor coating agent, the aqueous medium is preferably contained in an amount of 10 to 50 mass %, and more preferably 20 to 40 mass %, based on the mass of the anchor coating agent. The content of the aqueous medium is the total value of the content of the aqueous medium contained in the emulsion and the content of the aqueous medium other than the aqueous medium contained in the emulsion.

[0031] (ionic salt) The anchor coating agent of the present invention preferably further contains an ionic salt. By further comprising an ionic salt, the anchor coating agent of the present invention contains the ionic salt in the coating film formed using the anchor coating agent, thereby favorably functioning as a salting-out effect, and even when inkjet printing is performed, components such as the pigment and binder resin contained in the ink are less likely to penetrate into the base paper, resulting in excellent suitability for inkjet printing.

[0032] The ionic salts include organic ionic salts and inorganic ionic salts.

[0033] Examples of the organic ion salts include organic ion salts such as aliphatic sulfonates, higher alcohol sulfates, higher alcohol phosphates, higher alcohol ethylene oxide adduct sulfates, higher alcohol ethylene oxide adduct phosphates, quaternary ammonium salts, and betaine.

[0034] Examples of the inorganic ion salt include alkali metal salts and alkaline earth metal salts, and among these, dissociable polyvalent metal salts are preferred from the viewpoint of providing suitable inkjet printability. Examples of the dissociable polyvalent metal salt include inorganic salts such as chlorides, sulfates and nitrates of calcium, magnesium and the like, and organic acid salts such as acetates and formates. Specific examples include calcium acetate, calcium chloride, calcium formate, calcium nitrate, calcium sulfate, magnesium acetate, magnesium chloride, magnesium formate, magnesium nitrate, and magnesium sulfate. The above ionic salts can be used alone or in combination of two or more kinds.

[0035] The ionic salts are preferably calcium salts. When the ionic salt is a calcium salt, it is possible to provide the compound with favorable solubility in an aqueous medium, which will be described later. The ionic salt is more preferably calcium chloride or calcium nitrate, and is even more preferably calcium chloride from the viewpoint of favorable salting-out action and more favorable inkjet printability.

[0036] From the viewpoint of providing suitable inkjet printability, the content of the ionic salt is preferably 0.1 to 40 mass %, more preferably 2 to 20 mass %, and even more preferably 5 to 15 mass %, based on the mass of the anchor coating agent.

[0037] (others) The anchor coating agent of the present invention preferably contains a polyolefin wax from the viewpoint of suitably imparting coating film resistance. Examples of the polyolefin wax include waxes produced from olefins such as ethylene, propylene, and butylene, or derivatives thereof, and copolymers thereof, and specific examples include polyethylene-based waxes, polypropylene-based waxes, and polybutylene-based waxes. Among these, polyethylene waxes are preferred from the viewpoint of more suitably imparting coating film resistance to the coating film of the anchor coating agent. As the polyolefin wax, commercially available products can be used, such as Nopcoat PEM17 (manufactured by San Nopco), Chemipearl W400, Chemipearl W4005 (manufactured by Mitsui Chemicals), AQUACER 515, AQUACER 593 (manufactured by BYK Japan), etc.

[0038] The polyolefin wax contained in the anchor coating agent of the present invention is preferably 0.1 to 10 mass %, more preferably 0.2 to 5 mass %, based on the total mass of the anchor coating agent.

[0039] In addition to the components listed above, the anchor coating agent of the present invention may contain, as needed, known additives such as dispersants, dispersing aids, wetting agents, viscosity adjusters, pH adjusters, antifoaming agents, antifungal agents, rust inhibitors, and leveling agents, which may be appropriately selected and used.

[0040] (Method of manufacturing anchor coating agent) There are no particular limitations on the method for producing the anchor coating agent of the present invention. For example, the agent can be produced by adding additives and the like to the above-mentioned components as needed and kneading them.

[0041] <Manufacturing method for flexographic prints> The method for producing a flexographic print of the present invention is a method for producing a flexographic print printed by a flexographic printing machine, and is characterized by comprising a step of applying the anchor coating agent of the present invention to a print medium.

[0042] The printing medium is not particularly limited, and examples thereof include liner base paper obtained by mixing two or more types of chemical pulp, mechanical pulp, recycled paper pulp, etc. Furthermore, base paper having a multi-layer structure obtained by combining two or more pulp layers can also be used.

[0043] The anchor coating agent of the present invention can be printed using known printing methods, but is preferably used in flexographic printing. The anchor coating agent of the present invention can effectively suppress the misting phenomenon that is particularly likely to occur during flexographic printing. As the flexographic printing method, a known method can be appropriately selected and used.

[0044] The amount of the anchor coating agent applied is 0.1 to 20 g / m2 in solid content. 2 From the viewpoint of providing favorable coating film resistance, the solid content is preferably 0.1 to 15 g / m 2 It is more preferable to set the following. The coating amount of the anchor coating agent of the present invention is 0.1 g / m 2If the coating amount of the anchor coating agent is less than 20 g / m, the effect of the present invention may not be fully obtained. 2 If the temperature exceeds this range, backtrapping is likely to occur, and sufficient coating resistance may not be imparted.

[0045] The surface coated with the anchor coating agent can be dried using a common dryer used in this field, such as a hot air dryer. The surface coated with the anchor coating agent may be in a completely dried state or a semi-dried state.

[0046] The flexographic print formed by applying the anchor coating agent can have a printed layer formed by printing using a known ink by a known printing method.

[0047] Examples of the known printing method include gravure printing, offset printing, flexographic printing, screen printing, and inkjet printing, but inkjet printing is preferred because it is capable of reproducing high-quality designs.

[0048] The flexographic print produced by the method for producing a flexographic print of the present invention is formed using the anchor coating agent of the present invention, and therefore has excellent coating film resistance. [Effects of the Invention]

[0049] The present invention can provide an anchor coating agent that has an appropriate viscosity, can suppress the misting phenomenon, can be uniformly transferred in the required amount to a printing medium, and the coating film formed using the anchor coating agent has excellent coating film resistance. DETAILED DESCRIPTION OF THE INVENTION

[0050] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples. Unless otherwise specified, "%" means "% by mass" and "parts" means "parts by mass."

[0051] The materials used in the examples and comparative examples are as follows.

[0052] <Ionic salt> Calcium chloride dihydrate Calcium nitrate tetrahydrate <Emulsion> (Acrylic resin emulsion-1) (Nippon Carbide Corporation, FX2043, acid value 10 mg KOH / g, glass transition temperature 10°C, solid content 50% by mass, aqueous medium is water) Other acrylic resin emulsions were synthesized according to the following procedure. (Acrylic Resin Emulsion-2) A monomer mixture consisting of 1.5 parts by weight of acrylic acid, 89.5 parts by weight of methyl methacrylate, and 9 parts by weight of butyl acrylate was mixed with 3 parts by weight of Aqualon HS-10 (Dai-ichi Kogyo Seiyaku Co., Ltd.) as a surfactant. An aqueous solution of 0.3 parts by weight of potassium persulfate in 46 parts by weight of distilled water was then added and pre-emulsified using a stirrer. 20 parts by weight of distilled water was placed in a polymerization vessel equipped with a stirrer, condenser, thermometer, and nitrogen inlet tube. The atmosphere was purged with nitrogen and heated to 80°C. The monomer emulsion was then added dropwise over 3 hours and allowed to react for another 2 hours to complete the polymerization. A small amount of potassium persulfate was added toward the end of the polymerization to consume any remaining monomer. The pH of the resulting emulsion was adjusted to 7 with sodium hydroxide, and distilled water was added to adjust the solids concentration to 50% by weight to obtain acrylic resin emulsion-2 (acid value 10 mgKOH / g, glass transition temperature 70°C, solids content 50% by weight, aqueous medium: water). (Acrylic Resin Emulsion-3) In the synthesis of the above acrylic resin emulsion-2, the amounts of acrylic acid, methyl methacrylate, and butyl acrylate were changed to 19.3 parts by mass, 34.5 parts by mass, and 46.2 parts by mass, respectively, to obtain acrylic resin emulsion-3 (acid value 150 mgKOH / g, glass transition temperature 10°C, solid content 50% by mass, and aqueous medium water). <Cellulose ether> Cellulose ether A (hydroxypropyl methylcellulose, manufactured by Shin-Etsu Chemical Co., Ltd., Metolose 90SH-100) Cellulose ether B (hydroxypropyl methylcellulose, manufactured by Shin-Etsu Chemical Co., Ltd., Metolose 60SH-400) Cellulose ether C (carboxymethyl cellulose, Daicel Corporation, CMC1140) Cellulose ether D (hydroxyethyl methylcellulose, manufactured by Shin-Etsu Chemical Co., Ltd., Metolose 60SEB) <Polyvinyl alcohol> Polyvinyl alcohol (PVA224, manufactured by Kuraray Co., Ltd.) <Other thickeners> Polyethylene oxide (Meisei Chemical Co., Ltd., Alcox R-400) <Aqueous medium> purified water <Other> Polyethylene wax (Mitsui Chemicals, Chemipearl W-400) Leveling agent (Nissin Chemical Industry Co., Ltd., Surfynol 104) Antifoaming agent (Dow Toray, Antifoam 013A)

[0053] (Examples 1 to 15, Comparative Examples 1 to 3) Various materials were mixed in the compounding ratios shown in Table 1 to prepare anchor coating agents.

[0054] <Viscosity measurement> The viscosity was measured using a Zahn cup (manufactured by Rigaud, number 4) at a liquid temperature of 23° C. The results are shown in Table 1.

[0055] <Metastatic> The anchor coating agents prepared in the examples and comparative examples were applied to a film of 0.5 g / m2 solid content using a hand proofer (360 lines). 2 Coated cardboard (manufactured by Rengo Co., Ltd., basis weight 230 g / m 2 ) and the coated surface was dried with a dryer. The coated surface was visually inspected and the state of transfer of the anchor coating agent was evaluated according to the following criteria. The results are shown in Table 1. ○: Transferred evenly and does not affect inkjet printing △: There are some areas where the transfer is uneven, but this does not affect the printing of the inkjet ink. ×: Transfer is uneven or not the required amount, causing problems with inkjet ink printing

[0056] <Misting> The anchor coating agents prepared in the examples and comparative examples were printed on coated cardboard (manufactured by Rengo Co., Ltd., basis weight 230 g / m) using a stack-type flexographic printing machine (manufactured by Orient Co., Ltd.) at a printing speed of 150 m / min. 2 ) printed on The degree of scattering of the anchor coating agent during the flexographic printing was evaluated visually, and the results are shown in Table 1. 〇: No scattering at all △: Although some scattering occurred, the appearance was not damaged and there was no concern about the impact on the equipment, so the printing press did not need to be stopped. ×: Spatter occurs, damaging the appearance, or there is concern about the impact on equipment, so the printing machine must be stopped and cleaned.

[0057] <Coating film resistance> The anchor coating agents prepared in the examples and comparative examples were applied to a film of 0.5 g / m2 solid content using a hand proofer (360 lines). 2 Coated cardboard (manufactured by Rengo Co., Ltd., basis weight 230 g / m 2 ) and the coated surface was dried with a dryer. The coating resistance was evaluated under the following conditions using a Gakushin-type rub fastness tester (manufactured by Toyo Seiki Seisakusho Co., Ltd. The results are shown in Table 1. Evaluation conditions: 200g x 2 times, paper: 5 drops of water on Kanakin cloth 〇: No paint film removal △: A small amount of anchor coating agent adheres to the paper. ×: Anchor coating agent adheres to the entire surface of the paper

[0058] <Suitable for inkjet printing> The anchor coating agents prepared in the examples and comparative examples were applied to a film of 0.5 g / m2 solid content using a hand proofer (360 lines). 2 Coated cardboard (manufactured by Rengo Co., Ltd., basis weight 230 g / m2 ) and the coated surface was dried with a dryer. On the resulting coated surface, a thin line of 0.3 mm was printed using an inkjet printer (Epson, PX105) and inkjet ink (Epson, IC4CL69). The printed surface was visually observed and evaluated for inkjet printability according to the following criteria. The results are shown in Table 1. 〇: The print is clear and there is no bleeding at all. △: There is a slight blur in the print, but the design is reproduced ×: The print is blurred and the design is difficult to see.

[0059] <Solubility> In order to achieve a viscosity of 10 seconds or more at a liquid temperature of 23°C, measured using a Zahn cup (Rigau, No. 4), various materials were added in the mass ratios shown in Table 1, and the solubility was evaluated according to the following criteria. The results are shown in Table 1. 〇: All materials are dissolved and no residue remains △: Some undissolved material remains, but can be removed with a filter (100 mesh) ×: The solubility of the material is poor, and the viscosity cannot be increased to 10 seconds or more, or a large amount of residue is generated and cannot be removed with a filter (100 mesh).

[0060] <Storage stability> The anchor coating agents prepared in the examples and comparative examples were stored in a sealed container at 40°C for 7 days, and the presence or absence of thickening, separation, and sedimentation was checked and evaluated according to the following criteria. The results are shown in Table 1. 〇: No thickening, separation or sedimentation observed △: Viscosity increase, separation or sedimentation is observed, but complete recovery is achieved by stirring ×: Viscosity increase, separation or sedimentation is observed, and the solution does not recover completely even after stirring.

[0061] [Table 1]

[0062] It was confirmed that the anchor coating agents according to the examples have an appropriate viscosity, can suppress the misting phenomenon, can be transferred uniformly in the required amount to the printing medium, and can produce a coating film with excellent coating film resistance. A comparison between Example 1 and Example 11 confirmed that the inclusion of an ionic salt can improve the inkjet printability. Furthermore, a comparison of Example 1 with Examples 12 and 14 confirmed that the use of hydroxypropyl methylcellulose can provide more suitable solubility and storage stability. Furthermore, a comparison between Example 1 and Example 13 confirmed that by setting the acid value of the emulsion within a predetermined range, it is possible to impart more suitable solubility and storage stability. Furthermore, it was confirmed from Example 15 that the use of hydroxyethyl methylcellulose provides an appropriate viscosity, has excellent transferability, suppresses misting, and provides a coating film with excellent coating film resistance and inkjet printability. On the other hand, Comparative Example 1, which did not contain a thickener, had insufficient viscosity and poor transferability. Comparative Example 2, which did not contain an emulsion, had poor coating film durability. Comparative Example 3, which used polyethylene oxide as a thickener, was unable to suppress misting. [Industrial Applicability]

[0063] The anchor coating agent has an appropriate viscosity, can suppress misting, can be uniformly transferred in the required amount to the printing medium, and provides a coating film formed using the anchor coating agent with excellent coating film resistance.

Claims

1. An anchor coating agent containing an emulsion, a cellulose ether, and an aqueous medium, the emulsion is an emulsion of an acrylic resin, has an acid value of less than 50 mgKOH / g, and has a glass transition temperature of 70°C or less; the content of the emulsion is 5 to 65 mass % in terms of solid content based on the mass of the anchor coating agent, The cellulose ether is at least one selected from hydroxypropyl methylcellulose and hydroxyethyl methylcellulose, An anchor coating agent used in flexographic printing.

2. The anchor coating agent according to claim 1, further comprising an ionic salt.

3. 3. The anchor coating agent according to claim 2, wherein the ionic salt is a calcium salt.

4. 4. The anchor coating agent according to claim 2, wherein the content of the ionic salt is 0.1 to 40% by mass based on the mass of the anchor coating agent.

5. A method for producing a flexographic print that is printed by a flexographic printing machine, comprising a step of applying the anchor coating agent according to any one of claims 1 to 4 to a print medium.

6. The amount of the anchor coating agent applied is 0.1 to 10 g / m in terms of solid content. ２ The method for producing a flexographic print according to claim 5, wherein

7. The amount of the anchor coating agent applied is 0.1 to 2 g / m in terms of solid content. ２ The method for producing a flexographic print according to claim 6, wherein

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