Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet, and bonded body

Abstract

To provide an adhesive layer having excellent adhesive strength (initial adhesive strength) when no electric voltage is applied, the adhesive layer sufficiently lowering an adhesive strength when electric voltage is applied.SOLUTION: An adhesive composition includes a polymer, an ionic liquid and an orientation material. An adhesive sheet includes an adhesive layer formed from the adhesive composition.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] The present invention relates to a pressure-sensitive adhesive composition, a pressure-sensitive adhesive sheet including a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition, and a bonded body of the pressure-sensitive adhesive sheet and an adherend. [Background technology]

[0002] In electronic component manufacturing processes, etc., there is an increasing demand for rework to improve yields and recycling by disassembling and recovering components after use. To meet such demands, double-sided pressure-sensitive adhesive sheets that have a certain level of adhesive strength and releasability are sometimes used to join components in electronic component manufacturing processes, etc. Furthermore, with the miniaturization of electronic devices, pressure-sensitive adhesive sheets that have a certain level of adhesive strength and releasability are sometimes used for transferring and fixing fine components.

[0003] Known double-sided pressure-sensitive adhesive sheets that achieve the above-mentioned adhesive strength and releasability include pressure-sensitive adhesive sheets (electrically peelable pressure-sensitive adhesive sheets) that use an ionic liquid consisting of cations and anions as a component that forms the pressure-sensitive adhesive composition and that can be peeled off by applying a voltage to the pressure-sensitive adhesive layer (Patent Documents 1 to 3). In the electrically peelable adhesive sheets of Patent Documents 1 to 3, application of voltage causes cations of the ionic liquid to migrate on the cathode side, resulting in reduction, and anions of the ionic liquid to migrate on the anode side, resulting in oxidation, which is thought to weaken the adhesive strength at the adhesive interface and make the sheet more susceptible to peeling. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] Japanese Patent Application Laid-Open No. 2010-037354 [Patent Document 2] Patent No. 6097112 [Patent Document 3] Patent No. 4139851 Summary of the Invention [Problem to be solved by the invention]

[0005] It is preferable that an electrically peelable pressure-sensitive adhesive sheet firmly bonds members when no voltage is applied and can be peeled off with little force when a voltage is applied. However, conventional electrically peelable pressure-sensitive adhesive sheets using ionic liquids have had the problem that if the adhesive strength after voltage application is reduced, the initial adhesive strength when no voltage is applied is not sufficient, and if the initial adhesive strength when no voltage is applied is increased, the adhesive strength after voltage application does not decrease sufficiently.

[0006] The present invention was completed in view of the above, and aims to provide a pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive layer that has excellent adhesive strength when no voltage is applied and whose adhesive strength is sufficiently reduced when a voltage is applied, and a pressure-sensitive adhesive sheet including a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition. [Means for solving the problem]

[0007] As a result of extensive research to achieve the above object, the present inventors have found that the above problems in the prior art can be solved by blending an alignment material into a pressure-sensitive adhesive composition, and have thus completed the present invention.

[0008] [1] A pressure-sensitive adhesive composition comprising a polymer, an ionic liquid, and an alignment material. [2] The pressure-sensitive adhesive composition according to [1], wherein a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition is attached to an adherend and cleaved and peeled from the adherend by applying a voltage of 10 V for 10 seconds. [3] The pressure-sensitive adhesive composition according to [2], wherein the cleavage peeling is natural peeling. [4] The pressure-sensitive adhesive composition according to any one of [1] to [3], comprising 4 parts by mass or more of the ionic liquid per 100 parts by mass of the polymer. [5] The pressure-sensitive adhesive composition according to any one of [1] to [4], wherein the polymer includes at least one selected from the group consisting of polyester-based polymers, urethane-based polymers, and acrylic-based polymers. [6] The pressure-sensitive adhesive composition according to [5], wherein the acrylic polymer contains a unit derived from a polar group-containing monomer having a carboxyl group, an alkoxy group, a hydroxyl group, and / or an amide bond. [7] The pressure-sensitive adhesive composition according to [6], wherein the polar group-containing monomer accounts for 0.1 to 35% by mass of all monomer components constituting the acrylic polymer. [8] The pressure-sensitive adhesive composition according to any one of [1] to [7], which is for electrical peeling. [9] A pressure-sensitive adhesive sheet comprising a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition according to any one of [1] to [8].

[10] A bonded body comprising an adherend having a metal adherend surface and the pressure-sensitive adhesive sheet according to [9], wherein the pressure-sensitive adhesive layer of the pressure-sensitive adhesive sheet is bonded to the metal adherend surface. [Effects of the Invention]

[0009] The pressure-sensitive adhesive composition of the present invention can form a pressure-sensitive adhesive layer that has excellent adhesive strength when no voltage is applied, and whose adhesive strength is sufficiently reduced by the application of a voltage. [Brief explanation of the drawings]

[0010] [Figure 1] 1 is a schematic cross-sectional view showing an example of the pressure-sensitive adhesive sheet of the present invention. [Figure 2] 1 is a schematic cross-sectional view showing an example of a laminate structure of the pressure-sensitive adhesive sheet of the present invention. [Figure 3] FIG. 2 is a schematic cross-sectional view showing another example of the laminate structure of the pressure-sensitive adhesive sheet of the present invention. [Figure 4] FIG. 2 is a cross-sectional view showing an outline of the method for the 180° peel test in the examples. [Figure 5]FIG. 2 is a schematic perspective view showing a test bonded body used in a cleavage peel test in the examples. DETAILED DESCRIPTION OF THE INVENTION

[0011] DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The following describes in detail the preferred embodiments of the present invention, but the present invention is not limited to the following preferred embodiments.

[0012] [Adhesive composition] The pressure-sensitive adhesive composition according to an embodiment of the present invention is a pressure-sensitive adhesive composition containing a polymer, an ionic liquid, and an alignment material. The pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition according to the embodiment of the present invention has excellent adhesive strength (initial adhesive strength) when no voltage is applied, and the adhesive strength is sufficiently reduced by the application of voltage, making it suitable for use in the manufacturing process of electronic devices, etc. Furthermore, since the adhesive strength is sufficiently reduced by the application of voltage, cleavage peeling is possible. Furthermore, the pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition is preferably attached to an adherend, and cleavage peeled from the adherend by applying a voltage of 10 V for 10 seconds.

[0013] Here, cleavage peeling refers to peeling along the interface between the pressure-sensitive adhesive layer and the adherend. Cleavage peeling allows the entire interface between the pressure-sensitive adhesive layer and the adherend to be easily peeled off, eliminating the need to apply a large stress to a portion of the interface between the pressure-sensitive adhesive layer and the adherend as in peel peeling or the like, and has the advantage of not deforming the adherend. In the embodiment of the present invention, the cleavage peeling may or may not be natural peeling, but is preferably natural peeling. Furthermore, natural peeling refers to peeling (cleavage) along the interface between the adherend and the pressure-sensitive adhesive layer, without applying stress to part of the interface between the pressure-sensitive adhesive layer and the adherend. Natural peeling also includes cases where peeling occurs when the adhesive layer is left standing, where peeling occurs naturally during transfer to the next process, and where peeling occurs between the adherend and the pressure-sensitive adhesive layer due to the weight of the adherend or the pressure-sensitive adhesive layer itself. Examples of cleavage peeling other than natural peeling include when a slight stress is applied to part of the interface between the adhesive layer and the adherend, causing the adhesive layer to peel off from one end of the adherend without deformation or destruction of the adhesive layer or the adherend.

[0014] The pressure-sensitive adhesive composition according to an embodiment of the present invention comprises a polymer, an ionic liquid, and an alignment material. By including the polymer, the ionic liquid, and the alignment material, the pressure-sensitive adhesive composition exhibits excellent adhesive strength when no voltage is applied, and the adhesive strength decreases sufficiently when a voltage is applied. This is thought to be because the mobility of the ionic liquid increases as the alignment material undergoes dielectric polarization upon application of a voltage.

[0015] The adhesive layer formed from the adhesive composition according to the embodiment of the present invention has excellent adhesive strength when no voltage is applied, and has the property that when a voltage is applied, the adhesive strength is sufficiently reduced to enable cleavage peeling, making the adhesive composition suitable as an electrically peelable adhesive composition. These pressure-sensitive adhesive compositions will be described below.

[0016] In this specification, the adhesive strength when no voltage is applied is sometimes referred to as "initial adhesive strength." Furthermore, the property of adhesive strength decreasing with the application of voltage is called "electrical releasability," and a large rate of decrease in adhesive strength with the application of voltage is sometimes referred to as "excellent electrical releasability."

[0017] <Components of Pressure-Sensitive Adhesive Composition> (polymer) The pressure-sensitive adhesive composition according to the embodiment of the present invention contains a polymer. In the present embodiment, the polymer is not particularly limited as long as it is a general organic polymer compound, and is, for example, a polymer or partial polymer of a monomer. The monomer may be one type of monomer or a mixture of two or more types of monomers. Note that the partial polymer refers to a polymer in which at least a part of the monomer or monomer mixture is partially polymerized.

[0018] The polymer in the embodiment of the present invention is not particularly limited as long as it is normally used as an adhesive and has adhesive properties, and examples thereof include acrylic polymers, rubber polymers, vinyl alkyl ether polymers, silicone polymers, polyester polymers, polyamide polymers, urethane polymers, fluorine-containing polymers, and epoxy polymers. The polymers can be used alone or in combination of two or more.

[0019] In order to obtain a pressure-sensitive adhesive layer that has excellent adhesive strength when no voltage is applied and whose adhesive strength is sufficiently reduced when a voltage is applied, it is preferable that the polymer have a large relative dielectric constant, and from this viewpoint, it is particularly preferable that the polymer in this embodiment includes at least one selected from the group consisting of polyester-based polymers, urethane-based polymers, and acrylic-based polymers. The acrylic polymer preferably contains a unit derived from a polar group-containing monomer having a carboxyl group, an alkoxy group, a hydroxyl group, and / or an amide bond. Since polyester polymers and urethane polymers have terminal hydroxyl groups that are easily polarized, and since acrylic polymers having a carboxyl group, an alkoxy group, a hydroxyl group, and / or an amide bond have carboxyl groups, alkoxy groups, hydroxyl groups, and / or amide bonds that are easily polarized, the use of these polymers makes it possible to obtain a polymer that can be used as a pressure-sensitive adhesive layer that has excellent adhesive strength when no voltage is applied and whose adhesive strength is sufficiently reduced when a voltage is applied.

[0020] The total content of the polyester-based polymer, urethane-based polymer, and acrylic-based polymer in the polymer of this embodiment is preferably 60% by mass or more, and more preferably 80% by mass or more. In particular, in order to improve costs, productivity, and initial adhesive strength, the polymer in this embodiment is preferably an acrylic polymer. That is, the pressure-sensitive adhesive composition according to the embodiment of the present invention is preferably an acrylic pressure-sensitive adhesive composition containing an acrylic polymer as the polymer.

[0021] The acrylic polymer preferably contains a monomer unit derived from a (meth)acrylic acid alkyl ester (the following formula (1)) having an alkyl group of 1 to 14 carbon atoms. Such a monomer unit is suitable for obtaining a large initial adhesive strength. Furthermore, in order to improve electrical peelability, the alkyl group R b The number of carbon atoms is preferably small, particularly preferably 8 or less, and more preferably 4 or less. CH2=C(R a )COOR b (1) [R in formula (1)] a is a hydrogen atom or a methyl group, and R b is an alkyl group having 1 to 14 carbon atoms.

[0022] Examples of (meth)acrylic acid alkyl esters having an alkyl group having 1 to 14 carbon atoms include methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, sec-butyl (meth)acrylate, 1,3-dimethylbutyl acrylate, pentyl (meth)acrylate, isopentyl (meth)acrylate, hexyl (meth)acrylate, and 2-ethylbutyl (meth)acrylate. Examples of suitable acrylates include n-butyl (meth)acrylate, heptyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, n-nonyl (meth)acrylate, isononyl (meth)acrylate, n-decyl (meth)acrylate, isodecyl (meth)acrylate, n-dodecyl (meth)acrylate, n-tridecyl (meth)acrylate, and n-tetradecyl (meth)acrylate. Among these, n-butyl acrylate, 2-ethylhexyl acrylate, and isononyl acrylate are preferred. The (meth)acrylic acid alkyl esters having an alkyl group having 1 to 14 carbon atoms can be used alone or in combination of two or more.

[0023] The proportion of the (meth)acrylic acid alkyl ester having an alkyl group of 1 to 14 carbon atoms relative to all monomer components (100% by mass) constituting the acrylic polymer is not particularly limited, but is preferably 70% by mass or more, more preferably 80% by mass or more, and even more preferably 85% by mass or more. When the proportion of the (meth)acrylic acid alkyl ester having an alkyl group of 1 to 14 carbon atoms is 70% by mass or more, a large initial adhesive strength is easily obtained.

[0024] The acrylic polymer preferably contains, in addition to a monomer unit derived from a (meth)acrylic acid alkyl ester having an alkyl group with 1 to 14 carbon atoms, a monomer unit derived from a polar group-containing monomer copolymerizable therewith, for the purpose of improving cohesive strength, heat resistance, crosslinkability, etc. The monomer unit can provide crosslinking points and is suitable for obtaining a large initial adhesive strength.

[0025] Examples of polar group-containing monomers include carboxyl group-containing monomers, alkoxy group-containing monomers, hydroxyl group-containing monomers, cyano group-containing monomers, vinyl group-containing monomers, aromatic vinyl monomers, amide group-containing monomers, imide group-containing monomers, amino group-containing monomers, epoxy group-containing monomers, vinyl ether monomers, N-acryloylmorpholine, sulfo group-containing monomers, phosphate group-containing monomers, and acid anhydride group-containing monomers. Among these, carboxyl group-containing monomers, alkoxy group-containing monomers, hydroxyl group-containing monomers, and amide group-containing monomers are preferred from the viewpoint of excellent cohesion, and carboxyl group-containing monomers are particularly preferred. Carboxyl group-containing monomers are particularly suitable for obtaining high initial adhesive strength. Polar group-containing monomers can be used alone or in combination of two or more.

[0026] Examples of carboxyl group-containing monomers include acrylic acid, methacrylic acid, carboxyethyl (meth)acrylate, carboxypentyl (meth)acrylate, itaconic acid, maleic acid, fumaric acid, crotonic acid, and isocrotonic acid. Acrylic acid is particularly preferred. The carboxyl group-containing monomers can be used alone or in combination of two or more.

[0027] Examples of the alkoxy group-containing monomer include a methoxy group-containing monomer and an ethoxy group-containing monomer, and an example of the methoxy group-containing monomer is 2-methoxyethyl acrylate.

[0028] Examples of hydroxyl group-containing monomers include 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 6-hydroxyhexyl (meth)acrylate, 8-hydroxyoctyl (meth)acrylate, 10-hydroxydecyl (meth)acrylate, 12-hydroxylauryl (meth)acrylate, (4-hydroxymethylcyclohexyl)methyl (meth)acrylate, N-methylol (meth)acrylamide, vinyl alcohol, allyl alcohol, 2-hydroxyethyl vinyl ether, 4-hydroxybutyl vinyl ether, and diethylene glycol monovinyl ether. 2-hydroxyethyl (meth)acrylate and 4-hydroxybutyl (meth)acrylate are particularly preferred. The hydroxyl group-containing monomers can be used alone or in combination.

[0029] Examples of amide group-containing monomers include acrylamide, methacrylamide, N-vinylpyrrolidone, N,N-dimethylacrylamide, N,N-dimethylmethacrylamide, N,N-diethylacrylamide, N,N-diethylmethacrylamide, N,N'-methylenebisacrylamide, N,N-dimethylaminopropylacrylamide, N,N-dimethylaminopropylmethacrylamide, and diacetoneacrylamide. The amide group-containing monomers can be used alone or in combination of two or more.

[0030] Examples of cyano group-containing monomers include acrylonitrile and methacrylonitrile.

[0031] Examples of vinyl group-containing monomers include vinyl esters such as vinyl acetate, vinyl propionate, and vinyl laurate, with vinyl acetate being particularly preferred.

[0032] Examples of aromatic vinyl monomers include styrene, chlorostyrene, chloromethylstyrene, α-methylstyrene, and other substituted styrenes.

[0033] Examples of imide group-containing monomers include cyclohexylmaleimide, isopropylmaleimide, N-cyclohexylmaleimide, and itaconimide.

[0034] Examples of amino group-containing monomers include aminoethyl (meth)acrylate, N,N-dimethylaminoethyl (meth)acrylate, and N,N-dimethylaminopropyl (meth)acrylate.

[0035] Examples of epoxy group-containing monomers include glycidyl (meth)acrylate, methyl glycidyl (meth)acrylate, and allyl glycidyl ether.

[0036] Examples of vinyl ether monomers include methyl vinyl ether, ethyl vinyl ether, and isobutyl vinyl ether.

[0037] The proportion of the polar group-containing monomer relative to all monomer components (100% by mass) constituting the acrylic polymer is preferably 0.1% by mass or more and 35% by mass or less. The upper limit of the polar group-containing monomer proportion is more preferably 25% by mass, even more preferably 20% by mass, and the lower limit is more preferably 0.5% by mass, even more preferably 1% by mass, and particularly preferably 2% by mass. When the proportion of the polar group-containing monomer is 0.1% by mass or more, cohesive strength is easily obtained, reducing the likelihood of adhesive residue remaining on the adherend surface after peeling the pressure-sensitive adhesive layer, and improving electrical releasability. Furthermore, when the proportion of the polar group-containing monomer is 35% by mass or less, excessive adhesion of the pressure-sensitive adhesive layer to the adherend, resulting in heavy peeling, is easily prevented. In particular, when the proportion is 2% by mass or more and 20% by mass or less, it is easy to achieve both releasability from the adherend and adhesion between the pressure-sensitive adhesive layer and other layers.

[0038] Furthermore, the monomer components constituting the acrylic polymer may contain a polyfunctional monomer in order to introduce a crosslinked structure into the acrylic polymer and make it easier to obtain the required cohesive strength.

[0039] Examples of polyfunctional monomers include ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, neopentyl glycol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, dipentaerythritol hexa(meth)acrylate, divinylbenzene, and N,N'-methylenebisacrylamide. The polyfunctional monomers can be used alone or in combination of two or more.

[0040] The content of the polyfunctional monomer relative to the total monomer components (100% by mass) constituting the acrylic polymer is preferably 0.1% by mass or more and 15% by mass or less. The upper limit of the polyfunctional monomer content is more preferably 10% by mass, and the lower limit is more preferably 3% by mass. When the content of the polyfunctional monomer is 0.1% by mass or more, the flexibility and adhesiveness of the pressure-sensitive adhesive layer are easily improved, which is preferable. When the content of the polyfunctional monomer is 15% by mass or less, the cohesive force is not too high, and appropriate adhesiveness is easily obtained.

[0041] Polyester-based polymers are typically polymers having a structure formed by condensation of a polycarboxylic acid such as a dicarboxylic acid or its derivative (hereinafter also referred to as a "polycarboxylic acid monomer") with a polyhydric alcohol such as a diol or its derivative (hereinafter referred to as a "polyhydric alcohol monomer").

[0042] The polycarboxylic acid monomer is not particularly limited, but examples thereof include adipic acid, azelaic acid, dimer acid, sebacic acid, 1,4-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,2-cyclohexanedicarboxylic acid, 4-methyl-1,2-cyclohexanedicarboxylic acid, dodecenylsuccinic anhydride, fumaric acid, succinic acid, dodecanedioic acid, hexahydrophthalic anhydride, tetrahydrophthalic anhydride, maleic acid, maleic anhydride, itaconic acid, citraconic acid, and derivatives thereof. The polycarboxylic acid monomers can be used alone or in combination of two or more kinds.

[0043] The polyhydric alcohol monomer is not particularly limited, but examples thereof include ethylene glycol, 1,2-propylene glycol, 1,3-propanediol, 2-methyl-1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 3-methyl-1,5-pentanediol, neopentyl glycol, diethylene glycol, dipropylene glycol, 2,2,4-trimethyl-1,5-pentanediol, 2-ethyl-2-butylpropanediol, 1,9-nonanediol, 2-methyloctanediol, 1,10-decanediol, and derivatives thereof. The polyhydric alcohol monomers can be used alone or in combination of two or more.

[0044] The polymer of this embodiment may also contain an ionic polymer. The ionic polymer is a polymer having an ionic functional group. When the polymer contains an ionic polymer, the electro-separation property is improved. When the polymer contains an ionic polymer, the content of the ionic polymer is preferably 0.05 parts by mass or more and 2 parts by mass or less per 100 parts by mass of the polymer.

[0045] In this embodiment, the polymer can be obtained by (co)polymerizing monomer components. The polymerization method is not particularly limited, but examples thereof include solution polymerization, emulsion polymerization, bulk polymerization, suspension polymerization, and photopolymerization (active energy ray polymerization). In particular, from the viewpoints of cost and productivity, solution polymerization is preferred. When copolymerized, the polymer may be any of a random copolymer, a block copolymer, an alternating copolymer, a graft copolymer, and the like.

[0046] The solution polymerization method is not particularly limited, but examples thereof include a method in which a monomer component, a polymerization initiator, etc. are dissolved in a solvent and heated to polymerize, thereby obtaining a polymer solution containing a polymer.

[0047] As the solvent used in the solution polymerization method, various common solvents can be used. Examples of such solvents (polymerization solvents) include organic solvents such as aromatic hydrocarbons such as toluene, benzene, and xylene; esters such as ethyl acetate and n-butyl acetate; aliphatic hydrocarbons such as n-hexane and n-heptane; alicyclic hydrocarbons such as cyclohexane and methylcyclohexane; and ketones such as methyl ethyl ketone and methyl isobutyl ketone. The solvents can be used alone or in combination of two or more.

[0048] The amount of the solvent used is not particularly limited, but is preferably 10 parts by mass or more and 1,000 parts by mass or less relative to the total monomer components (100 parts by mass) constituting the polymer. The upper limit of the amount of the solvent used is more preferably 500 parts by mass, and the lower limit is more preferably 50 parts by mass.

[0049] The polymerization initiator used in the solution polymerization method is not particularly limited, but examples thereof include peroxide-based polymerization initiators and azo-based polymerization initiators.

[0050] The peroxide polymerization initiator is not particularly limited, but examples thereof include peroxycarbonate, ketone peroxide, peroxyketal, hydroperoxide, dialkyl peroxide, diacyl peroxide, and peroxyester. More specific examples thereof include benzoyl peroxide, t-butyl hydroperoxide, di-t-butyl peroxide, t-butyl peroxybenzoate, dicumyl peroxide, 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, and 1,1-bis(t-butylperoxy)cyclododecane.

[0051] The azo polymerization initiator is not particularly limited, but examples thereof include 2,2'-azobisisobutyronitrile, 2,2'-azobis-2-methylbutyronitrile, 2,2'-azobis(2,4-dimethylvaleronitrile), 2,2'-azobis(2-methylpropionate)dimethyl, 2,2'-azobis(4-methoxy-2,4-dimethylvaleronitrile), 1,1'-azobis(cyclohexane-1-carbonitrile), 2,2'-azobis(2,4,4-trimethylpentane), 4,4'-azobis Examples of suitable polymerization initiators include 4-cyanovaleric acid, 2,2'-azobis(2-amidinopropane) dihydrochloride, 2,2'-azobis[2-(5-methyl-2-imidazolin-2-yl)propane] dihydrochloride, 2,2'-azobis(2-methylpropionamidine) disulfate, 2,2'-azobis(N,N'-dimethyleneisobutylamidine) hydrochloride, and 2,2'-azobis[N-(2-carboxyethyl)-2-methylpropionamidine] hydrate. The polymerization initiators can be used alone or in combination of two or more.

[0052] The amount of the polymerization initiator used is not particularly limited, but is preferably 0.01 to 5 parts by mass relative to the total monomer components (100 parts by mass) constituting the polymer. The upper limit of the amount of the polymerization initiator used is more preferably 3 parts by mass, and the lower limit is more preferably 0.05 parts by mass.

[0053] In the solution polymerization method, the heating temperature when polymerizing by heating is not particularly limited, but is, for example, 50° C. to 80° C. The heating time is not particularly limited, but is, for example, 1 hour to 24 hours.

[0054] The weight-average molecular weight of the polymer is not particularly limited, but is preferably 100,000 or more and 5,000,000 or less. The upper limit of the weight-average molecular weight is more preferably 4,000,000, and even more preferably 3,000,000, and the lower limit is more preferably 200,000, and even more preferably 300,000. If the weight-average molecular weight is 100,000 to 5,000,000 or less, sufficient adhesive strength can be obtained.

[0055] The weight-average molecular weight is obtained by measurement using a gel permeation chromatography (GPC) method. More specifically, for example, it can be measured using a GPC measurement device (trade name "HLC-8220GPC" manufactured by Tosoh Corporation) under the following conditions, and calculated as a value converted into standard polystyrene.

[0056] (Weight average molecular weight measurement conditions) Sample concentration: 0.2% by mass (tetrahydrofuran solution) Sample injection volume: 10 μL Sample column: TSKguardcolumn SuperHZ-H (1 column) + TSKgel SuperHZM-H (2 columns) Reference column: TSKgel SuperH-RC (1 column) Eluent: tetrahydrofuran (THF) ·Flow rate: 0.6mL / min Detector: Differential refractometer (RI) Column temperature (measurement temperature): 40℃

[0057] The glass transition temperature (Tg) of the polymer is not particularly limited, but is preferably 0° C. or lower because this can prevent a decrease in the initial adhesive strength, more preferably −10° C. or lower, and even more preferably −20° C. or lower. Furthermore, a temperature of −40° C. or lower is particularly preferred because the rate of decrease in adhesive strength due to voltage application is particularly large, and is most preferably −50° C. or lower.

[0058] The glass transition temperature (Tg) can be calculated, for example, based on the following formula (Y) (Fox formula). 1 / Tg=W1 / Tg1+W2 / Tg2+···+Wn / Tgn (Y) [In formula (Y), Tg is the glass transition temperature of the polymer (unit: K), Tgi (i = 1, 2, . . . n) is the glass transition temperature (unit: K) when monomer i forms a homopolymer, and Wi (i = 1, 2, . . . n) is the mass fraction of monomer i in all monomer components.] The above formula (Y) is a calculation formula when the polymer is composed of n types of monomer components: Monomer 1, Monomer 2, . . . , Monomer n.

[0059] The glass transition temperature of a homopolymer refers to the glass transition temperature of a homopolymer of the monomer, and refers to the glass transition temperature (Tg) of a polymer formed using only a certain monomer (sometimes referred to as "monomer X") as the monomer component. Specific values ​​are listed in "Polymer Handbook" (3rd ed., John Wiley & Sons, Inc., 1989). The glass transition temperature (Tg) of a homopolymer not listed in this document refers to a value obtained, for example, by the following measurement method. Specifically, 100 parts by mass of monomer X, 0.2 parts by mass of 2,2'-azobisisobutyronitrile, and 200 parts by mass of ethyl acetate as a polymerization solvent are placed in a reactor equipped with a thermometer, a stirrer, a nitrogen inlet tube, and a reflux condenser, and the mixture is stirred for 1 hour while introducing nitrogen gas. After removing oxygen from the polymerization system in this way, the temperature is raised to 63°C and the reaction is continued for 10 hours. The mixture is then cooled to room temperature to obtain a homopolymer solution with a solids concentration of 33% by mass. The homopolymer solution was then cast onto a release liner and dried to prepare a test sample (homopolymer sheet) approximately 2 mm thick. Approximately 1-2 mg of this test sample was then weighed into an aluminum open cell, and the reversing heat flow (specific heat component) behavior of the homopolymer was measured using a temperature-modulated DSC (product name "Q-2000" manufactured by TA Instruments) at a heating rate of 5°C / min under a nitrogen atmosphere at 50 mL / min. Referring to JIS-K-7121, the glass transition temperature (Tg) of the homopolymer was determined by the temperature at the point where the line equidistant along the vertical axis from the line extending the low-temperature and high-temperature baselines of the reversing heat flow intersects with the curve representing the stepwise change in the glass transition.

[0060] The polymer content in the pressure-sensitive adhesive composition of the present embodiment is preferably 50% by mass or more and 99.9% by mass or less, relative to the total amount of the pressure-sensitive adhesive composition (100% by mass), with the upper limit being more preferably 99.5% by mass, and even more preferably 99% by mass, and the lower limit being more preferably 60% by mass, and even more preferably 70% by mass.

[0061] (ionic liquid) The ionic liquid in this embodiment is not particularly limited as long as it is a molten salt (room-temperature molten salt) composed of a pair of anion and cation and is liquid at 25° C. Examples of anions and cations are given below, but among the ionic substances obtained by combining these, those that are liquid at 25° C. are ionic liquids, and those that are solid at 25° C. are not ionic liquids but ionic solids, which will be described later.

[0062] The anion of the ionic liquid is, for example, (FSO2)2N - , (CF3SO2)2N - , (CF3CF2SO2)2N - , (CF3SO2)3C - , Br - , AlCl4 - , Al2Cl7 - , NO3 - , BF4 - , PF6 - , CH3COO - , CF3COO - , CF3CF2CF2COO - , CF3SO3 - , CF3(CF2)3SO3 - , AsF6 - , SbF6 - , and F(HF) n - Among them, the anion is (FSO2)2N - [bis(fluorosulfonyl)imide anion], and (CF3SO2)2N - Anions of sulfonylimide compounds such as [bis(trifluoromethanesulfonyl)imide anion] are preferred because they are chemically stable and suitable for improving electrical peeling properties.

[0063] As the cation in the ionic liquid, nitrogen-containing onium, sulfur-containing onium, and phosphorus-containing onium cations are preferred because they are chemically stable and suitable for improving electrical peeling properties, and imidazolium-based, ammonium-based, pyrrolidinium-based, and pyridinium-based cations are more preferred.

[0064] Examples of imidazolium cations include 1-methylimidazolium cation, 1-ethyl-3-methylimidazolium cation, 1-propyl-3-methylimidazolium cation, 1-butyl-3-methylimidazolium cation, 1-pentyl-3-methylimidazolium cation, 1-hexyl-3-methylimidazolium cation, 1-heptyl-3-methylimidazolium cation, 1-octyl-3-methylimidazolium cation, 1-nonyl-3-methylimidazolium cation, 1-undecyl-3-methylimidazolium cation, and 1-dodecyl-3-methylimidazolium cation. imidazolium cation, 1-tridecyl-3-methylimidazolium cation, 1-tetradecyl-3-methylimidazolium cation, 1-pentadecyl-3-methylimidazolium cation, 1-hexadecyl-3-methylimidazolium cation, 1-heptadecyl-3-methylimidazolium cation, 1-octadecyl-3-methylimidazolium cation, 1-undecyl-3-methylimidazolium cation, 1-benzyl-3-methylimidazolium cation, 1-butyl-2,3-dimethylimidazolium cation, and 1,3-bis(dodecyl)imidazolium cation.

[0065] Examples of pyridinium-based cations include 1-butylpyridinium cation, 1-hexylpyridinium cation, 1-butyl-3-methylpyridinium cation, 1-butyl-4-methylpyridinium cation, and 1-octyl-4-methylpyridinium cation.

[0066] Examples of pyrrolidinium cations include 1-ethyl-1-methylpyrrolidinium cation and 1-butyl-1-methylpyrrolidinium cation.

[0067] Examples of ammonium cations include tetraethylammonium cation, tetrabutylammonium cation, methyltrioctylammonium cation, tetradecylammonium cation, and tetradecylammonium cation. L Examples include trihexylammonium cation, glycidyltrimethylammonium cation, and trimethylaminoethyl acrylate cation.

[0068] From the viewpoint of increasing the rate of decrease in adhesive strength when a voltage is applied, it is preferable to select a cation having a molecular weight of 160 or less as the constituent cation of the ionic liquid. - [Bis(fluorosulfonyl)imide anion] or (CF3SO2)2N - Particularly preferred is an ionic liquid containing a [bis(trifluoromethanesulfonyl)imide anion] and a cation having a molecular weight of 160 or less. Examples of the cation having a molecular weight of 160 or less include a 1-methylimidazolium cation, a 1-ethyl-3-methylimidazolium cation, a 1-propyl-3-methylimidazolium cation, a 1-butyl-3-methylimidazolium cation, a 1-pentyl-3-methylimidazolium cation, a 1-butylpyridinium cation, a 1-hexylpyridinium cation, a 1-butyl-3-methylpyridinium cation, a 1-butyl-4-methylpyridinium cation, a 1-ethyl-1-methylpyrrolidinium cation, a 1-butyl-1-methylpyrrolidinium cation, a tetraethylammonium cation, a glycidyltrimethylammonium cation, and a trimethylaminoethyl acrylate cation.

[0069] Furthermore, as the cation of the ionic liquid, cations represented by the following formulas (2-A) to (2-D) are also preferred.

[0070] [ka]

[0071] R in formula (2-A) 1 represents a hydrocarbon group having 4 to 10 carbon atoms (preferably a hydrocarbon group having 4 to 8 carbon atoms, more preferably a hydrocarbon group having 4 to 6 carbon atoms), which may contain a heteroatom; R 2 and R 3 are the same or different and represent a hydrogen atom or a hydrocarbon group having 1 to 12 carbon atoms (preferably a hydrocarbon group having 1 to 8 carbon atoms, more preferably a hydrocarbon group having 2 to 6 carbon atoms, and even more preferably a hydrocarbon group having 2 to 4 carbon atoms), and may contain a heteroatom. However, when a nitrogen atom forms a double bond with an adjacent carbon atom, R 3 does not exist.

[0072] R in formula (2-B) 4 represents a hydrocarbon group having 2 to 10 carbon atoms (preferably a hydrocarbon group having 2 to 8 carbon atoms, more preferably a hydrocarbon group having 2 to 6 carbon atoms), which may contain a heteroatom; R 5 , R 6 , and R 7 are the same or different and represent a hydrogen atom or a hydrocarbon group having 1 to 12 carbon atoms (preferably a hydrocarbon group having 1 to 8 carbon atoms, more preferably a hydrocarbon group having 2 to 6 carbon atoms, and even more preferably a hydrocarbon group having 2 to 4 carbon atoms), and may contain a heteroatom.

[0073] R in formula (2-C) 8 represents a hydrocarbon group having 2 to 10 carbon atoms (preferably a hydrocarbon group having 2 to 8 carbon atoms, more preferably a hydrocarbon group having 2 to 6 carbon atoms), which may contain a heteroatom; R 9 , R 10 , and R 11 are the same or different and represent a hydrogen atom or a hydrocarbon group having 1 to 16 carbon atoms (preferably a hydrocarbon group having 1 to 10 carbon atoms, more preferably a hydrocarbon group having 1 to 8 carbon atoms), which may contain a heteroatom.

[0074] In formula (2-D), X represents a nitrogen, sulfur, or phosphorus atom, and R 12 , R 13 , R14 , and R 15 are the same or different and represent a hydrocarbon group having 1 to 16 carbon atoms (preferably a hydrocarbon group having 1 to 14 carbon atoms, more preferably a hydrocarbon group having 1 to 10 carbon atoms, even more preferably a hydrocarbon group having 1 to 8 carbon atoms, and particularly preferably a hydrocarbon group having 1 to 6 carbon atoms), which may contain a heteroatom. However, when X is a sulfur atom, R 12 does not exist.

[0075] The molecular weight of the cation in the ionic liquid is, for example, 500 or less, preferably 400 or less, more preferably 300 or less, even more preferably 250 or less, particularly preferably 200 or less, and most preferably 160 or less. It is usually 50 or more. It is believed that the cation in the ionic liquid has the property of migrating to the cathode side in the pressure-sensitive adhesive layer when a voltage is applied, and becoming concentrated near the interface between the pressure-sensitive adhesive layer and the adherend. For this reason, in the present invention, the adhesive strength during voltage application decreases relative to the initial adhesive strength, resulting in electro-separability. Cations with a small molecular weight, such as a molecular weight of 500 or less, are suitable for facilitating the migration of the cation to the cathode side in the pressure-sensitive adhesive layer and increasing the rate of decrease in adhesive strength when a voltage is applied.

[0076] Examples of commercially available ionic liquids include "ELEXCEL AS-210," "ELEXCEL AS-110," "ELEXCEL MP-442," "ELEXCEL IL-210," "ELEXCEL MP-471," "ELEXCEL MP-456," and "ELEXCEL AS-804" manufactured by Daiichi Kogyo Seiyaku Co., Ltd.; "HMI-FSI" manufactured by Mitsubishi Materials Corporation; and "CIL-312" and "CIL-313" manufactured by Nippon Carlit Co., Ltd.

[0077] The ionic conductivity of the ionic liquid is preferably 0.1 mS / cm or more and 10 mS / cm or less. The upper limit of the ionic conductivity is more preferably 5 mS / cm, even more preferably 3 mS / cm, and the lower limit is more preferably 0.3 mS / cm, even more preferably 0.5 mS / cm. By having an ionic conductivity within this range, the adhesive strength is sufficiently reduced even at low voltages. The ionic conductivity can be measured by the AC impedance method, for example, using a Solartron 1260 frequency response analyzer.

[0078] The content (blending amount) of ionic liquid in the pressure-sensitive adhesive composition of this embodiment is preferably 4 parts by mass or more relative to 100 parts by mass of polymer from the viewpoint of reducing adhesive strength during voltage application, and preferably 50 parts by mass or less from the viewpoint of increasing initial adhesive strength. From the same viewpoint, it is more preferably 40 parts by mass or less, even more preferably 30 parts by mass or less, particularly preferably 25 parts by mass or less, and most preferably 20 parts by mass or less. Furthermore, it is more preferably 8 parts by mass or more, even more preferably 10 parts by mass or more, particularly preferably 12 parts by mass or more, and most preferably 15 parts by mass or more.

[0079] (oriented material) The pressure-sensitive adhesive composition according to the embodiment of the present invention contains an alignment material in addition to a polymer and an ionic liquid. An orientation material is a material that is dielectrically polarized by an electric field and easily oriented in a specific direction. Examples of the alignment material used in the embodiment of the present invention include liquid crystalline monomers and liquid crystalline polymers, with liquid crystalline monomers being preferred.

[0080] As the liquid crystalline monomer, either lyotropic or thermotropic monomers can be used, but thermotropic monomers are preferred from the viewpoint of workability. Examples of such monomers include those having a basic skeleton of a biphenyl derivative, a phenylbenzoate derivative, a stilbene derivative, a bicyclohexyl derivative, or the like, into which a functional group such as an acryloyl group, a vinyl group, or an epoxy group has been introduced. Such liquid crystalline monomers are preferably aligned using an appropriate known method, such as a method using heat or light, or a method using an alignment aid, and then, while maintaining this alignment, are crosslinked and polymerized using light, heat, an electron beam, or the like to fix the alignment.

[0081] The liquid crystalline monomer has the property of exhibiting ionic conductivity and may be non-polymerizable, in other words, may not have a polymerizable functional group, or may be a liquid crystalline molecule without a polymerizable functional group. The liquid crystalline molecule is a low molecular weight liquid crystalline compound having a molecular weight of less than 10,000, preferably 1,000 or less.

[0082] The liquid crystalline monomer is not limited to those that exhibit liquid crystallinity at room temperature (25° C.), and molecules that exhibit liquid crystallinity at higher temperatures can also be used. Even if a molecule does not exhibit liquid crystallinity at temperatures above 40°C by itself, when mixed with other liquid crystal molecules, the lower limit of the temperature at which it exhibits liquid crystallinity may be lowered to 40°C or lower.

[0083] Examples of liquid crystal monomers that exhibit liquid crystallinity at 40°C or below include, but are not limited to, cyanobiphenyl liquid crystals such as 4'-pentylbiphenyl-4-carbonitrile, 4'-hexylbiphenyl-4-carbonitrile, and 4'-heptylbiphenyl-4-carbonitrile; cyanophenylbenzoate liquid crystals such as 4-cyanophenyl 4-butylbenzoate; pyrimidine liquid crystals such as 5-n-heptyl-2-[4-(n-hexyloxy)phenyl]pyrimidine and 5-n-octyl-2-[4-(n-octyloxy)phenyl]pyrimidine; and tolane liquid crystals such as 1-(4-ethylphenyl)-2-(4-methoxyphenyl)acetylene and 1-(4-n-butylphenyl)-2-(4-methoxyphenyl)acetylene. All of the liquid crystal molecules exemplified above are non-polymerizable liquid crystal molecules. The liquid crystal molecules are not limited to two types, and three or more types may be blended.

[0084] Examples of liquid crystalline polymers include various main-chain and side-chain polymers in which a conjugated linear atomic group (mesogen) that imparts liquid crystal alignment properties is introduced into the main chain or side chain of the polymer. Specific examples of main-chain liquid crystalline polymers include nematically aligned polyester-based liquid crystalline polymers, discotic polymers, and cholesteric polymers, each of which has a structure in which mesogen groups are linked via a spacer moiety that imparts flexibility. Specific examples of side-chain liquid crystalline polymers include those having a main chain skeleton of polysiloxane, polyacrylate, polymethacrylate, or polymalonate, and having a mesogen moiety consisting of a para-substituted cyclic compound unit that imparts nematic alignment as a side chain, via a spacer moiety consisting of a conjugated atomic group.

[0085] The content (blending amount) of the alignment material in the pressure-sensitive adhesive composition of this embodiment is preferably 0.05 parts by mass or more relative to 100 parts by mass of the polymer from the viewpoint of reducing adhesive strength during voltage application, and preferably 30 parts by mass or less from the viewpoint of increasing initial adhesive strength. From the same viewpoint, it is more preferably 20 parts by mass or less, even more preferably 10 parts by mass or less, particularly preferably 8 parts by mass or less, and most preferably 5 parts by mass or less. Furthermore, it is more preferably 0.1 parts by mass or more, even more preferably 0.5 parts by mass or more, particularly preferably 1 part by mass or more, and most preferably 1.5 parts by mass or more.

[0086] (Other ingredients) The pressure-sensitive adhesive composition of the present embodiment may contain one or more components other than the polymer, ionic liquid, and alignment material (hereinafter, sometimes referred to as "other components"), as needed, within a range that does not impair the effects of the present invention. Hereinafter, other components that may be contained in the pressure-sensitive adhesive composition of the present embodiment will be described.

[0087] The pressure-sensitive adhesive composition of the present embodiment may contain an ionic additive for the purpose of imparting excellent adhesive strength (initial adhesive strength) when no voltage is applied and sufficiently reducing the adhesive strength upon application of voltage. As the ionic additive, for example, an ionic solid can be used.

[0088] The ionic solid is an ionic substance that is solid at 25°C. There are no particular limitations on the ionic solid, but for example, a solid ionic substance obtained by combining an anion and a cation as exemplified in the section describing the ionic liquid above can be used. When the pressure-sensitive adhesive composition contains an ionic solid, the content of the ionic solid is preferably 0.5 parts by mass or more, more preferably 1 part by mass or more, and preferably 10 parts by mass or less, more preferably 5 parts by mass or less, and even more preferably 2.5 parts by mass or less, relative to 100 parts by mass of the polymer.

[0089] The pressure-sensitive adhesive composition of the present embodiment may contain a crosslinking agent, if necessary, to improve creep and shear properties by crosslinking the polymer. Examples of crosslinking agents include isocyanate-based crosslinking agents, carbodiimide-based crosslinking agents, epoxy-based crosslinking agents, melamine-based crosslinking agents, peroxide-based crosslinking agents, urea-based crosslinking agents, metal alkoxide-based crosslinking agents, metal chelate-based crosslinking agents, metal salt-based crosslinking agents, oxazoline-based crosslinking agents, aziridine-based crosslinking agents, and amine-based crosslinking agents. Examples of isocyanate-based crosslinking agents include toluene diisocyanate and methylene bisphenyl isocyanate. Examples of epoxy-based crosslinking agents include N,N,N',N'-tetraglycidyl-m-xylylenediamine, diglycidylaniline, 1,3-bis(N,N-diglycidylaminomethyl)cyclohexane, and 1,6-hexanediol diglycidyl ether. When a crosslinking agent is contained, the content thereof is preferably 0.1 parts by mass or more, more preferably 0.7 parts by mass or more, and is preferably 50 parts by mass or less, more preferably 10 parts by mass or less, and even more preferably 3 parts by mass or less, relative to 100 parts by mass of the polymer. The crosslinking agent may be used alone or in combination of two or more kinds.

[0090] The pressure-sensitive adhesive composition of the present embodiment may contain polyethylene glycol or tetraethylene glycol dimethyl ether, if necessary, to aid in the movement of the ionic liquid when a voltage is applied. The polyethylene glycol or tetraethylene glycol dimethyl ether may have a number-average molecular weight of 100 to 6000. When these components are contained, the content is preferably 0.1 parts by mass or more, more preferably 0.5 parts by mass or more, and even more preferably 1 part by mass or more, and preferably 30 parts by mass or less, more preferably 20 parts by mass or less, and even more preferably 15 parts by mass or less, per 100 parts by mass of the polymer.

[0091] The pressure-sensitive adhesive composition of the present embodiment may contain a conductive filler, if necessary, for the purpose of imparting conductivity to the pressure-sensitive adhesive composition. The conductive filler is not particularly limited, and a commonly known or commonly used conductive filler can be used, such as graphite, carbon black, carbon fiber, or metal powder such as silver or copper. When a conductive filler is contained, the content thereof is preferably 0.1 parts by mass or more and 200 parts by mass or less relative to 100 parts by mass of the polymer.

[0092] The pressure-sensitive adhesive composition of the present embodiment may contain a corrosion inhibitor, if necessary, for the purpose of inhibiting corrosion of the metal adherend. The corrosion inhibitor is not particularly limited, and a commonly known or commonly used corrosion inhibitor can be used, such as a carbodiimide compound, an adsorptive inhibitor, or a chelating metal deactivator. Examples of carbodiimide compounds include 1-[3-(dimethylamino)propyl]-3-ethylcarbodiimide, 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide, N,N'-dicyclohexylcarbodiimide, N,N'-diisopropylcarbodiimide, 1-ethyl-3-tert-butylcarbodiimide, N-cyclohexyl-N'-(2-morpholinoethyl)carbodiimide, N,N'-di-tert-butylcarbodiimide, 1,3-bis(p-tolyl)carbodiimide, and polycarbodiimide resins containing these as monomers. These carbodiimide compounds can be used alone or in combination of two or more. When a carbodiimide compound is contained in the pressure-sensitive adhesive composition of the present embodiment, the content is preferably 0.01 to 10 parts by mass per 100 parts by mass of the polymer.

[0093] Examples of the adsorptive inhibitor include alkylamines, carboxylates, carboxylic acid derivatives, and alkyl phosphates. The adsorptive inhibitors can be used alone or in combination of two or more. When the adhesive composition of the present embodiment contains an alkylamine as the adsorptive inhibitor, the content is preferably 0.01 to 20 parts by mass per 100 parts by mass of the polymer. When the adhesive composition of the present embodiment contains a carboxylate as the adsorptive inhibitor, the content is preferably 0.01 to 10 parts by mass per 100 parts by mass of the polymer. When the adhesive composition of the present embodiment contains a carboxylic acid derivative as the adsorptive inhibitor, the content is preferably 0.01 to 10 parts by mass per 100 parts by mass of the polymer. When the adhesive composition of the present embodiment contains an alkyl phosphate as the adsorptive inhibitor, the content is preferably 0.01 to 10 parts by mass per 100 parts by mass of the polymer.

[0094] As the chelating metal deactivator, for example, a triazole group-containing compound or a benzotriazole group-containing compound can be used. These are preferred because they have a high effect of deactivating the surface of metals such as aluminum and are less likely to affect adhesiveness when contained in the adhesive component. The chelating metal deactivator can be used alone or in combination of two or more types. When a chelating metal deactivator is contained in the adhesive composition of this embodiment, the content is preferably 0.01 parts by mass or more and 20 parts by mass or less per 100 parts by mass of the polymer. The total content (blended amount) of the corrosion inhibitor is preferably 0.01 parts by mass or more and 30 parts by mass or less per 100 parts by mass of the polymer.

[0095] The pressure-sensitive adhesive composition of the present embodiment may also contain various additives such as fillers, plasticizers, antioxidants, antioxidants, pigments (dyes), flame retardants, solvents, surfactants (leveling agents), rust inhibitors, adhesion-imparting resins, and antistatic agents. The total content of these components is not particularly limited as long as the effects of the present invention are achieved, but is preferably 0.01 parts by mass or more and 20 parts by mass or less, more preferably 10 parts by mass or less, and even more preferably 5 parts by mass or less, per 100 parts by mass of the polymer.

[0096] Examples of fillers include silica, iron oxide, zinc oxide, aluminum oxide, titanium oxide, barium oxide, magnesium oxide, calcium carbonate, magnesium carbonate, zinc carbonate, pyrophyllite clay, kaolin clay, and calcined clay. The plasticizer can be a known, commonly used plasticizer used in general resin compositions, etc., and examples thereof include oils such as paraffin oil and process oil; liquid rubbers such as liquid polyisoprene, liquid polybutadiene, and liquid ethylene-propylene rubber; tetrahydrophthalic acid, azelaic acid, benzoic acid, phthalic acid, trimellitic acid, pyromellitic acid, adipic acid, sebacic acid, fumaric acid, maleic acid, itaconic acid, citric acid, and derivatives thereof; dioctyl phthalate (DOP), dibutyl phthalate (DBP), dioctyl adipate, diisononyl adipate (DINA), and isodecyl succinate.

[0097] Examples of antioxidants include hindered phenol compounds, and aliphatic and aromatic hindered amine compounds. Examples of antioxidants include butylhydroxytoluene (BHT) and butylhydroxyanisole (BHA). Examples of pigments include inorganic pigments such as titanium dioxide, zinc oxide, ultramarine, red iron oxide, lithopone, lead, cadmium, iron, cobalt, aluminum, hydrochlorides, and sulfates, azo pigments, and organic pigments such as copper phthalocyanine pigments. Examples of the rust inhibitor include zinc phosphate, tannic acid derivatives, phosphoric acid esters, basic sulfonates, and various rust-preventive pigments.

[0098] Examples of adhesion promoters include titanium coupling agents and zirconium coupling agents. Examples of antistatic agents generally include quaternary ammonium salts, or hydrophilic compounds such as polyglycolic acid and ethylene oxide derivatives. Examples of tackifying resins include rosin-based tackifying resins, terpene-based tackifying resins, phenol-based tackifying resins, hydrocarbon-based tackifying resins, ketone-based tackifying resins, as well as polyamide-based tackifying resins, epoxy-based tackifying resins, and elastomer-based tackifying resins. These tackifying resins can be used alone or in combination of two or more.

[0099] <Method of manufacturing pressure-sensitive adhesive composition> The pressure-sensitive adhesive composition of the present invention is not particularly limited, but can be produced by appropriately stirring and mixing a polymer, an ionic liquid, an alignment material, and, if necessary, an additive, a crosslinking agent, polyethylene glycol, a conductive filler, etc.

[0100] [Adhesive sheet] (Adhesive sheet configuration) The pressure-sensitive adhesive sheet of this embodiment is not particularly limited as long as it has at least one pressure-sensitive adhesive layer (hereinafter also referred to as "electrically peelable pressure-sensitive adhesive layer") formed from the pressure-sensitive adhesive composition of this embodiment described above. The pressure-sensitive adhesive sheet of this embodiment may have a pressure-sensitive adhesive layer other than the electrically peelable pressure-sensitive adhesive layer that does not contain an ionic liquid (hereinafter sometimes referred to as "another pressure-sensitive adhesive layer"). The pressure-sensitive adhesive sheet of this embodiment may also have a substrate, a conductive layer, a conductive substrate, an intermediate layer, an undercoat layer, etc. in addition to the above. The pressure-sensitive adhesive sheet of this embodiment may be in the form of, for example, a roll or a sheet. It should be noted that the term "pressure-sensitive adhesive sheet" also encompasses the meaning of "pressure-sensitive adhesive tape." That is, the pressure-sensitive adhesive sheet of this embodiment may be a pressure-sensitive adhesive tape in the form of a tape.

[0101] The pressure-sensitive adhesive sheet of this embodiment may be a double-sided pressure-sensitive adhesive sheet that does not have a substrate and is composed only of an electrically releasing pressure-sensitive adhesive layer, i.e., a substrate-less double-sided pressure-sensitive adhesive sheet that does not include a substrate layer. The pressure-sensitive adhesive sheet of this embodiment may be a double-sided pressure-sensitive adhesive sheet that has a substrate, and both sides of the substrate are pressure-sensitive adhesive layers (electrically releasing pressure-sensitive adhesive layers or other pressure-sensitive adhesive layers). Alternatively, the pressure-sensitive adhesive sheet of this embodiment may be a single-sided pressure-sensitive adhesive sheet that has a substrate, and only one side of the substrate is a pressure-sensitive adhesive layer (electrically releasing pressure-sensitive adhesive layer or other pressure-sensitive adhesive layer). The pressure-sensitive adhesive sheet of this embodiment may have a separator (release liner) for the purpose of protecting the surface of the pressure-sensitive adhesive layer, but this separator is not included in the pressure-sensitive adhesive sheet of this embodiment.

[0102] The structure of the pressure-sensitive adhesive sheet of this embodiment is not particularly limited, but preferred examples include pressure-sensitive adhesive sheet X1 shown in FIG. 1, pressure-sensitive adhesive sheet X2 whose laminate structure is shown in FIG. 2, and pressure-sensitive adhesive sheet X3 whose laminate structure is shown in FIG. 3. Pressure-sensitive adhesive sheet X1 is a substrate-less double-sided pressure-sensitive adhesive sheet consisting only of an electrically releasing pressure-sensitive adhesive layer 1. Pressure-sensitive adhesive sheet X2 is a substrate-attached double-sided pressure-sensitive adhesive sheet having a layer structure of an adhesive layer 2, an electrically conducting substrate 5 (substrate 3 and conductive layer 4), and an electrically releasing pressure-sensitive adhesive layer 1. Pressure-sensitive adhesive sheet X3 is a substrate-attached double-sided pressure-sensitive adhesive sheet having a layer structure of an adhesive layer 2, an electrically conducting substrate 5 (substrate 3 and conductive layer 4), an electrically releasing pressure-sensitive adhesive layer 1, an electrically conducting substrate 5 (substrate 3 and conductive layer 4), and an adhesive layer 2. In the electrically conducting substrate 5 of pressure-sensitive adhesive sheets X2 and X3 shown in FIGS. 2 and 3, the substrate 3 is not essential, and only the conductive layer 4 may be present. Furthermore, pressure-sensitive adhesive sheet X2 in FIG. 2 may be a single-sided pressure-sensitive adhesive sheet without the adhesive layer 2.

[0103] The substrate 3 is not particularly limited, but examples thereof include paper-based substrates such as paper, fiber-based substrates such as cloth and nonwoven fabric, plastic-based substrates such as films and sheets made of various plastics (polyolefin-based resins such as polyethylene and polypropylene, polyester-based resins such as polyethylene terephthalate, acrylic resins such as polymethyl methacrylate, etc.), and laminates thereof. The substrate may have a single layer structure or a multi-layer structure. The substrate may be subjected to various treatments such as back surface treatment, antistatic treatment, and primer treatment as necessary.

[0104] The conductive layer 4 is not particularly limited as long as it is a layer having conductivity, but may be a metal substrate such as a metal (e.g., aluminum, magnesium, copper, iron, tin, gold, etc.) foil, a metal plate (e.g., aluminum, magnesium, copper, iron, tin, silver, etc.), a conductive polymer, or the like, or may be a metal vapor deposition film provided on the substrate 3.

[0105] The conductive substrate 5 is not particularly limited as long as it is a substrate having a conductive layer (conductive), but examples thereof include a substrate having a metal layer formed on the surface thereof, such as a substrate having a metal layer formed on the surface thereof by plating, chemical vapor deposition, sputtering, etc. Examples of the metal layer include the metals, metal plates, conductive polymers, etc. exemplified above.

[0106] In the pressure-sensitive adhesive sheet X1, the adherends on both sides preferably have metal adherend surfaces. In the pressure-sensitive adhesive sheet X2, the adherend on the electrically peelable pressure-sensitive adhesive layer 1 side preferably has a metal adherend surface.

[0107] Examples of metal-coated surfaces include conductive surfaces made of metals whose main components are aluminum, copper, iron, magnesium, tin, gold, silver, and lead, with aluminum being preferred. Examples of adherends having a metal-coated surface include sheets, parts, and plates made of metals whose main components are aluminum, copper, iron, magnesium, tin, gold, silver, and lead. Adherends other than those having a metal-coated surface include, but are not limited to, fiber sheets such as paper, cloth, and nonwoven fabric, and various plastic films and sheets.

[0108] From the viewpoint of initial adhesive strength, the thickness of the electrically releasing pressure-sensitive adhesive layer 1 is preferably 1 μm or more and 1000 μm or less. The upper limit of the thickness of the electrically releasing pressure-sensitive adhesive layer 1 is more preferably 500 μm, even more preferably 100 μm, and particularly preferably 30 μm, and the lower limit is more preferably 3 μm, even more preferably 5 μm, and particularly preferably 8 μm. When the pressure-sensitive adhesive sheet is a substrate-less double-sided pressure-sensitive adhesive sheet consisting of only one electrically releasing pressure-sensitive adhesive layer (pressure-sensitive adhesive sheet X1 shown in FIG. 1), the thickness of the electrically releasing pressure-sensitive adhesive layer is the thickness of the pressure-sensitive adhesive sheet.

[0109] From the viewpoint of adhesive strength, the thickness of the pressure-sensitive adhesive layer 2 is preferably 1 μm or more and 2000 μm or less. The upper limit of the thickness of the pressure-sensitive adhesive layer 2 is more preferably 1000 μm, even more preferably 500 μm, and particularly preferably 100 μm, and the lower limit is more preferably 3 μm, even more preferably 5 μm, and particularly preferably 8 μm.

[0110] The thickness of the substrate 3 is preferably 10 μm or more and 1000 μm or less. The upper limit of the thickness is more preferably 500 μm, even more preferably 300 μm, and particularly preferably 100 μm, and the lower limit is more preferably 12 μm, and even more preferably 25 μm.

[0111] The thickness of the conductive layer 4 is preferably 0.001 μm or more and 1000 μm or less. The upper limit of the thickness is more preferably 500 μm, even more preferably 300 μm, even more preferably 50 μm, and even more preferably 10 μm, and the lower limit is more preferably 0.01 μm, more preferably 0.03 μm, and even more preferably 0.05 μm.

[0112] The thickness of the conductive substrate 5 is preferably 10 μm or more and 1000 μm or less. The upper limit of the thickness is more preferably 500 μm, even more preferably 300 μm, and particularly preferably 100 μm, and the lower limit is more preferably 12 μm, and even more preferably 25 μm.

[0113] The surfaces of the electrically releasable adhesive layer and other adhesive layers of the adhesive sheet of this embodiment may be protected by a separator (release liner). Examples of the separator include, but are not limited to, a release liner in which the surface of a substrate (liner substrate) such as paper or plastic film is treated with silicone, and a release liner in which the surface of a substrate (liner substrate) such as paper or plastic film is laminated with a polyolefin resin. The thickness of the separator is not particularly limited, but is preferably 10 μm or more and 100 μm or less.

[0114] The thickness of the pressure-sensitive adhesive sheet of this embodiment is preferably 20 μm or more and 3000 μm or less. The upper limit of the thickness is more preferably 1000 μm, even more preferably 300 μm, and particularly preferably 200 μm, and the lower limit is more preferably 30 μm, and even more preferably 50 μm.

[0115] In particular, in the case of the pressure-sensitive adhesive sheet X2 shown in Fig. 2, the thickness of the pressure-sensitive adhesive sheet is preferably 50 µm or more and 2000 µm or less. The upper limit of the thickness is more preferably 1000 µm, and even more preferably 200 µm, and the lower limit is more preferably 80 µm, and even more preferably 100 µm.

[0116] In particular, in the case of the adhesive sheet X3 shown in Fig. 3, the thickness of the adhesive sheet is preferably 100 µm or more and 3000 µm or less. The upper limit of the thickness is more preferably 1000 µm, and even more preferably 300 µm, and the lower limit is more preferably 150 µm, and even more preferably 200 µm.

[0117] (Method of manufacturing pressure-sensitive adhesive sheet) The pressure-sensitive adhesive sheet of this embodiment can be produced by a known or commonly used production method. For the electrically peelable pressure-sensitive adhesive layer in the pressure-sensitive adhesive sheet of this embodiment, a method can be used in which a solution of the pressure-sensitive adhesive composition of this embodiment dissolved in a solvent as needed is applied to a separator, followed by drying and / or curing. For the other pressure-sensitive adhesive layers, a method can be used in which a solution of a pressure-sensitive adhesive composition that does not contain an ionic liquid, an alignment material, or an additive dissolved in a solvent as needed is applied to a separator, followed by drying and / or curing. The solvents and separators listed above can be used.

[0118] For application, a conventional coater (for example, a gravure roll coater, a reverse roll coater, a kiss roll coater, a dip roll coater, a bar coater, a knife coater, a spray roll coater, etc.) can be used.

[0119] The above-mentioned method can produce an electrically releasing pressure-sensitive adhesive layer and other pressure-sensitive adhesive layers, and the pressure-sensitive adhesive sheet of the present embodiment can be produced by laminating the electrically releasing pressure-sensitive adhesive layer and other pressure-sensitive adhesive layers appropriately on a substrate, a conductive layer, and a conductive substrate. Note that the pressure-sensitive adhesive sheet may also be produced by using a substrate, a conductive layer, and a conductive substrate instead of a separator and applying the pressure-sensitive adhesive composition thereto.

[0120] (Method for electrically peeling adhesive sheets) The pressure-sensitive adhesive sheet of this embodiment can be peeled from an adherend by applying a voltage to the electrically-release-type pressure-sensitive adhesive layer, thereby generating a potential difference in the thickness direction of the electrically-release-type pressure-sensitive adhesive layer. For example, in the case of pressure-sensitive adhesive sheet X1, if the adherend has metal surfaces on both sides, peeling can be achieved by passing electricity through the metal surfaces on both sides and applying a voltage to the electrically-release-type pressure-sensitive adhesive layer. In the case of pressure-sensitive adhesive sheet X2, if the adherend has a metal surface on the electrically-release-type pressure-sensitive adhesive layer side, peeling can be achieved by passing electricity through the conductive adherend and the conductive layer 4 and applying a voltage to the electrically-release-type pressure-sensitive adhesive layer. In the case of pressure-sensitive adhesive sheet X3, peeling can be achieved by passing electricity through the conductive layer 4 on both sides and applying a voltage to the electrically-release-type pressure-sensitive adhesive layer. Electrical application is preferably carried out by connecting terminals to one end and the other end of the pressure-sensitive adhesive sheet so that a voltage is applied to the entire electrically-release-type pressure-sensitive adhesive layer. Note that, if the adherend has a metal surface, the one end and the other end may be part of the adherend having a metal surface. When peeling, water may be added to the interface between the metal adherend surface and the electrically peelable pressure-sensitive adhesive layer before applying voltage.

[0121] The voltage and time for which the voltage is applied during electrical peeling are not particularly limited as long as the pressure-sensitive adhesive layer or pressure-sensitive adhesive sheet can be peeled from the adherend. Preferred ranges for these are shown below. The applied voltage is preferably 1 V or more, more preferably 3 V or more, and even more preferably 6 V or more, and is preferably 100 V or less, more preferably 50 V or less, even more preferably 30 V or less, and particularly preferably 15 V or less. The voltage application time is preferably 60 seconds or less, more preferably 40 seconds or less, even more preferably 20 seconds or less, and particularly preferably 10 seconds or less. In such cases, workability is excellent. The shorter the application time, the better, but it is usually 1 second or more.

[0122] (Applications of adhesive sheets) Conventional removable technologies include adhesive layers that are hardened and released by ultraviolet (UV) irradiation, and adhesive layers that are released by heat. Adhesive sheets using such adhesive layers cannot be used in cases where ultraviolet (UV) irradiation is difficult or where heat damages the adherend. The adhesive sheet of the present embodiment, which includes the electrically peelable adhesive layer, does not use ultraviolet light or heat, and therefore can be easily cleaved and peeled by applying a voltage without damaging the adherend. Therefore, the adhesive sheet of the present embodiment is suitable for use in fixing secondary batteries (e.g., lithium-ion battery packs) used in mobile devices such as smartphones, mobile phones, laptops, video cameras, and digital cameras to the housings.

[0123] In addition, examples of rigid members that can be bonded with the pressure-sensitive adhesive sheet of this embodiment include silicon substrates for semiconductor wafers, sapphire substrates for LEDs, SiC substrates and metal-based substrates, TFT substrates and color filter substrates for displays, and base substrates for organic EL panels. Examples of fragile members that can be bonded with the double-sided pressure-sensitive adhesive sheet include semiconductor substrates such as compound semiconductor substrates, silicon substrates for MEMS devices, passive matrix substrates, surface cover glass for smartphones, OGS (One Glass Solution) substrates in which a touch panel sensor is attached to the cover glass, organic substrates and organic-inorganic hybrid substrates mainly composed of silsesquioxane, flexible glass substrates for flexible displays, and graphene sheets.

[0124] [zygote] The bonded structure of this embodiment has a laminated structure including an adherend having a metal adhesion surface and a pressure-sensitive adhesive sheet having an electrically peelable pressure-sensitive adhesive layer bonded to the metal adhesion surface. Examples of adherends having a metal adhesion surface include those made of metals primarily composed of aluminum, copper, iron, magnesium, tin, gold, silver, lead, etc., and among these, metals containing aluminum are preferred.

[0125] Examples of the bonded body of this embodiment include a bonded pressure-sensitive adhesive sheet X1 having an adherend with a metal coating surface on both sides of the electrically peeling pressure-sensitive adhesive layer 1, a bonded pressure-sensitive adhesive sheet X2 having an adherend with a metal coating surface on the electrically peeling pressure-sensitive adhesive layer 1 side and an adherend on the pressure-sensitive adhesive layer 2 side, and a bonded pressure-sensitive adhesive sheet X3 having adherends on both sides of the pressure-sensitive adhesive layer 2. [Example]

[0126] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples. The weight-average molecular weights shown below were measured by gel permeation chromatography (GPC) using the method described above.

[0127] [Examples 1 to 4 and Comparative Examples 1 to 3] <Preparation of polymer solution> (Preparation of acrylic polymer 1 solution) Monomer components, 95 parts by mass of n-butyl acrylate (BA), 5 parts by mass of acrylic acid (AA), and 250 parts by mass of ethyl acetate as a polymerization solvent were placed in a separable flask and stirred for 1 hour while introducing nitrogen gas. After removing oxygen from the polymerization system in this way, 0.2 parts by mass of 2,2'-azobisisobutyronitrile (AIBN) was added as a polymerization initiator, and the mixture was heated to 63°C and reacted for 6 hours. Ethyl acetate was then added to obtain an acrylic polymer 1 solution (BA / AA (95 / 5)) with a solids concentration of 28.6% by mass.

[0128] <Preparation of Pressure-Sensitive Adhesive Composition> The acrylic polymer 1 solution obtained above, an ionic liquid, an alignment material, and a crosslinking agent shown below were added and stirred and mixed to obtain pressure-sensitive adhesive compositions of Examples 1 to 4 and Comparative Examples 1 to 3. Table 1 shows the amount (parts by mass) of each component. The values ​​of each component in Table 1 are in parts by mass. The abbreviations for the polymer, ionic liquid, alignment material, and crosslinking agent in Table 1 are as follows:

[0129] (ionic liquid) AS110: Cation: 1-ethyl-3-methylimidazolium cation, Anion: bis(fluorosulfonyl)imide anion, trade name "Elexcel AS-110", manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.

[0130] (oriented material) 4-Butylbenzoic acid-4-cyanophenyl: Wako Pure Chemical Industries, Ltd. trans,trans 4-butyl-4'-vinylbicyclohexyl: Tokyo Chemical Industry Co., Ltd. 4-Cyano-4'-heptylbiphenyl: Tokyo Chemical Industry Co., Ltd.

[0131] (Crosslinking agent) V-05: Polycarbodiimide resin, product name "Carbodilite V-05", manufactured by Nisshinbo Chemical Inc.

[0132] <Evaluation> (Initial adhesive strength) The pressure-sensitive adhesive composition of each example was applied to a uniform thickness using an applicator onto the release-treated surface of a polyethylene terephthalate separator (product name "MRF38", manufactured by Mitsubishi Plastics, Inc.) The coating was then dried by heating at 130°C for 3 minutes to obtain an electrically peelable pressure-sensitive adhesive layer (adhesive sheet) with a thickness of 30 μm. The resulting electrically peelable pressure-sensitive adhesive layer (adhesive sheet) was then cut into a sheet measuring 10 mm × 80 mm, and the metal layer side of a metal-layered film (product name "BR1075," manufactured by Toray Advanced Film Co., Ltd., 25 μm thick, 10 mm × 100 mm) was laminated to the side without the separator to produce a substrate-attached single-sided pressure-sensitive adhesive sheet. The separator was peeled off from the substrate-attached single-sided pressure-sensitive adhesive sheet, and a stainless steel plate (SUS304BA, Φ120 mm, thickness 1.5 mm) was attached to the peeled surface as an adherend so that one edge of the pressure-sensitive adhesive sheet protruded approximately 2 mm from the adherend. The sheet was pressed back and forth once with a 2 kg roller and left to stand for 30 minutes at 23°C to obtain an assembly consisting of stainless steel plate 6 / electrically peelable pressure-sensitive adhesive layer (adhesive sheet) 1 / metal-layered film (conductive substrate) 5. An overview of this assembly is shown in FIG. 4. Then, using a peel tester (product name "Variable Angle Peel Tester YSP", manufactured by Asahi Seiko Co., Ltd.), the peel strength was measured in the direction of the arrow in Figure 4. Direction The adhesive strength was measured in a 180° peel test (pulling speed: 300 mm / min, peel temperature: 23° C.). The measurement results are shown in Table 1.

[0133] (Adhesion strength after voltage application) The adhesive strength during voltage application was measured in the same manner as in the above initial adhesive strength measurement, except that after pressing back and forth with a 2 kg roller once, the bonded body was left to stand for 3 days in an environment of 22°C and 20% RH, and before peeling, the negative and positive electrodes of a DC current machine were attached to the α and β positions of the bonded body in Figure 4, respectively, and a voltage of 10 V was applied for 10 seconds before peeling. The measurement results are shown in Table 1.

[0134] (cleavage peel force) The pressure-sensitive adhesive composition of each example was applied to a uniform thickness using an applicator onto the release-treated surface of a polyethylene terephthalate separator (product name "MRF38", manufactured by Mitsubishi Plastics, Inc.) The coating was then dried by heating at 130°C for 3 minutes to obtain an electrically peelable pressure-sensitive adhesive layer (adhesive sheet) with a thickness of 30 μm. The resulting electrically peelable pressure-sensitive adhesive layer (adhesive sheet) was then cut into a sheet measuring 25 mm × 30 mm, and a stainless steel plate (SUS304BA, 50 mm × 60 mm) was attached to the side without the separator. The separator was peeled off from the pressure-sensitive adhesive sheet, and a round bar (SUS304, Φ12.7 mm × 38 mm) used in the round bar tensile peel strength test method described in JIS K6849 was attached to the peeled surface, pressed under 5 kg for 10 seconds, and left to stand in an environment of 23°C for 30 minutes to obtain a cleavage peel test assembly consisting of SUS304BA plate 10 / electrically peelable pressure-sensitive adhesive layer (adhesive sheet) 1 / round bar 15, as shown in Figure 5. Then, using a peel tester (product name "Small Tabletop Tester EZ-SX", manufactured by Shimadzu Corporation), the round bar was pulled while holding down the SUS304BA plate, and the adhesive strength in a cleavage peel test (pulling speed: 10 mm / min, peel temperature: 23°C) was measured as the cleavage peel force. The measurement results are shown in Table 1.

[0135] (Cleavage Electrical Peeling Force) The cleavage electrical peel force was measured in the same manner as the cleavage peel force measurement described above, except that after 10 seconds of pressure bonding at 5 kg, the specimen was left in an environment of 23°C and 50% RH for 48 hours, and before peeling, a positive electrode was attached to the SUS304BA plate of the bonded specimen, and a negative electrode was attached to the round bar. A voltage of 10 V was applied for 10 seconds, and then measurements were taken with the voltage still applied. If peeling is possible with a force of 25 N / 12.7 mmΦ or less, cleavage peeling is possible with the application of voltage. The measurement results are shown in Table 1.

[0136] [Table 1]

[0137] As shown in Table 1, the pressure-sensitive adhesive layers formed from the pressure-sensitive adhesive compositions of Examples 1 to 4 had excellent adhesive strength (initial adhesive strength) before voltage application, and the adhesive strength was sufficiently reduced by the application of voltage. Furthermore, because the adhesive strength was sufficiently reduced by the application of voltage, cleavage peeling was possible. On the other hand, in Comparative Examples 1 to 3, which did not contain an alignment material, the initial adhesive strength was lower than that of the Examples, and the decrease in adhesive strength was insufficient even when a voltage was applied. [Explanation of symbols]

[0138] X1, X2, X3 adhesive sheets 1 Electrically peelable adhesive layer 2. Adhesive layer 3 Base material 4 Conductive layer 5 Base material for current carrying 6 Stainless steel plate 10 SUS304BA plate 15 Round bar

Claims

1. A pressure-sensitive adhesive composition comprising a polymer, an ionic liquid, and an alignment material, the content of the polymer is 50% by mass or more and 94.8% by mass or less with respect to the total amount (100% by mass) of the pressure-sensitive adhesive composition, The ionic liquid is contained in an amount of 3 parts by mass or more and 50 parts by mass or less relative to 100 parts by mass of the polymer, The pressure-sensitive adhesive composition comprises the alignment material in an amount of 0.05 parts by mass or more and 30 parts by mass or less relative to 100 parts by mass of the polymer.

2. The pressure-sensitive adhesive composition according to claim 1 , wherein a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition is cleaved and peeled from the adherend by applying a voltage of 10 V for 10 seconds to the pressure-sensitive adhesive layer.

3. The pressure-sensitive adhesive composition according to claim 2 , wherein the cleavage peeling is natural peeling.

4. The pressure-sensitive adhesive composition according to any one of claims 1 to 3, comprising 4 parts by mass or more and 50 parts by mass or less of the ionic liquid relative to 100 parts by mass of the polymer.

5. The pressure-sensitive adhesive composition according to any one of claims 1 to 4, wherein the polymer comprises at least one selected from the group consisting of polyester-based polymers, urethane-based polymers, and acrylic-based polymers.

6. The pressure-sensitive adhesive composition according to claim 5 , wherein the acrylic polymer contains a unit derived from a polar group-containing monomer having a carboxyl group, an alkoxy group, a hydroxyl group, and / or an amide bond.

7. The pressure-sensitive adhesive composition according to claim 6, wherein the proportion of the polar group-containing monomer relative to all monomer components constituting the acrylic polymer is 0.1 to 35% by mass.

8. The pressure-sensitive adhesive composition according to any one of claims 1 to 7, which is for electrical peeling.

9. A pressure-sensitive adhesive sheet comprising a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition according to any one of claims 1 to 8.

10. A joined body comprising an adherend having a metal adherend surface and the pressure-sensitive adhesive sheet according to claim 9, wherein the pressure-sensitive adhesive layer of the pressure-sensitive adhesive sheet is joined to the metal adherend surface.

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