Cosmetics

Abstract

To provide a cosmetic containing a branched organopolysiloxane, which has a light feel, spreads well, can provide a uniform cosmetic film with high water repellency, does not give a strong oily feeling, has a good feeling of use, and has excellent storage stability and makeup longevity even when containing oil-based ingredients such as silicone and organic UV absorbers.SOLUTION: Provided is a cosmetic containing one or more branched organopolysiloxanes represented by the following formula (1): (R13SiO1 / 2)a(R12SiO2 / 2)b(R1SiO3 / 2)c(SiO4 / 2)d (where, R1 is independently a hydrogen atom, a hydroxyl group, or a monovalent alkyl group having 1 to 3 carbon atoms, and two or more of R1 are monovalent alkyl groups having 2 or 3 carbon atoms) and having a boiling point of 87 to 119°C at 10 hPa.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] The present invention relates to a cosmetic composition containing a branched organopolysiloxane. [Background technology]

[0002] Silicones, typified by dimethylpolysiloxane, have been widely used in recent years as oils in cosmetics due to their characteristics such as light feel, good spreadability, excellent water repellency, and high safety.

[0003] For example, volatile cyclic siloxanes such as octamethyltetrasiloxane (D4), decamethylpentasiloxane (D5), and dodecamethylhexasiloxane (D6), kinematic viscosities at 25°C of 0.65 to 6 mm 2 Cosmetics containing linear siloxanes such as / s and volatile siloxanes with branched siloxane chains such as tristrimethylsiloxymethylsilane (M3T) have a light feel when applied to the skin, good spreadability, and excellent water repellency (Patent Document 1).

[0004] However, these silicone-based additives may have low affinity with oily ingredients, such as wax, that are incorporated into cosmetics for the purpose of solidifying them. This may prevent the oily ingredients from crystallizing, resulting in a uniform cosmetic preparation or in a failure to achieve the desired hardness. Furthermore, the silicone-based additives have poor compatibility with polar oils, making it impossible to achieve a transparent blend, and may impair the feel and stability of the cosmetic. This tendency is particularly pronounced when organic UV absorbers are used.

[0005] On the other hand, it is also known to use phenyl-modified silicones, esters, etc. as compatibilizers for the purpose of increasing compatibility with polar oils, waxes, etc. However, in these cases, the feeling when used becomes heavy, and the light feeling of silicone may be lost. Furthermore, since many of these oils are non-volatile or low-volatile, they may cause a strong oily feeling after application of the cosmetic to the skin.

[0006] Meanwhile, Patent Document 2 proposes a composition incorporating a powder with a high oil absorption capacity, etc., for the purpose of reducing the stickiness of sunscreen formulations containing an organic UV absorber and a volatile oil, etc. However, as a study to improve the compatibility of volatile silicone oil, only an example of the combined use of a hydrocarbon oil such as isododecane is published. When these low-viscosity hydrocarbon oils are incorporated at high levels, irritation to the skin may be felt. Furthermore, when a high level of powder is incorporated, it is difficult to achieve a uniform cosmetic film after application, and the cosmetic film may not last long enough. [Prior art documents] [Patent documents]

[0007] [Patent Document 1] International Publication No. 01 / 015658 [Patent Document 2] Japanese Patent Application Publication No. 2018-70556 Summary of the Invention [Problem to be solved by the invention]

[0008] The present invention has been made in view of the above circumstances, and has as its object to provide a cosmetic composition containing a branched organopolysiloxane that has a light feel, spreads well, forms a uniform and highly water-repellent cosmetic film, does not leave a strong oily feeling, provides a good feel when used, and has excellent storage stability and cosmetic durability (cosmetic wear) even when blended with oily components such as silicone and organic UV absorbers. [Means for solving the problem]

[0009] As a result of extensive research into achieving the above object, the present inventors discovered that the above problem can be solved by incorporating a branched organopolysiloxane with a specific structure and a boiling point within a specified range into a cosmetic, and thus completed the present invention.

[0010] Thus, the present invention provides a cosmetic preparation. 1. The following formula (1) (R 13SiO 1 / 2 ) a (R 1 2SiO 2 / 2 ) b (R 1 SiO 3 / 2 ) c (SiO 4 / 2 ) d (1) (In the formula, R 1 are independently a hydrogen atom, a hydroxyl group, or a monovalent alkyl group having 1 to 3 carbon atoms, a is an integer of 0 to 5, b is an integer of 0 to 3, c is an integer of 0 to 2, d is 0 or 1, c+d is 1 or 2, and a+b+c+d is an integer of 4 to 7, provided that R 1 At least two of the groups are monovalent alkyl groups having 2 or 3 carbon atoms. and a boiling point at 10 hPa of 87 to 119°C. 2. A cosmetic composition according to 1, wherein in the above formula (1), b=0, d=0, and c=1. 3. A cosmetic composition according to 1 or 2, wherein the branched organopolysiloxane is one or more selected from 1,5-diethyl-3-trimethylsiloxy-1,1,3,5,5-pentamethyltrisiloxane and 1,5-diethyl-3-ethyldimethylsiloxy-1,1,3,5,5-pentamethyltrisiloxane. 4. A cosmetic preparation according to any one of 1 to 3, further comprising an oily component that is solid at 25°C. 5. A cosmetic preparation according to 4, wherein the oily component that is solid at 25°C is one or more selected from polyethylene, ceresin, ozokerite, candelilla wax, beeswax, microcrystalline wax, stearyl alcohol, behenyl alcohol, and cetanol. 6. A cosmetic preparation according to any one of 1 to 5, further comprising an organic ultraviolet absorber. 7. The cosmetic preparation according to 6, wherein the organic ultraviolet absorber is one or more selected from ethylhexyl methoxycinnamate, diethylaminohydroxybenzoylhexylbenzoate, ethylhexyl salicylate, polysilicone-15, t-butylmethoxydibenzoylmethane, oxybenzone, methylenebisbenzotriazolyltetramethylbutylphenol, bisethylhexyloxyphenol methoxyphenyl triazine, and octocrylene. [Effects of the Invention]

[0011] According to the present invention, it is possible to provide a cosmetic containing a branched organopolysiloxane that has a light feel, spreads well, forms a uniform cosmetic film with high water repellency, does not give a strong oily feel, provides a good feel in use, and has excellent stability over time and cosmetic durability even when blended with oily components such as silicone and organic ultraviolet absorbers. [Brief explanation of the drawings]

[0012] [Figure 1] 1 is a chart of the 1H-NMR spectrum of the branched organopolysiloxane synthesized in Synthesis Example 1. [Figure 2] 1 is a chart of the 29Si-NMR spectrum of the branched organopolysiloxane synthesized in Synthesis Example 1. DETAILED DESCRIPTION OF THE INVENTION

[0013] The present invention is described in detail below. However, the present invention is not limited thereto. In the present invention, ingredient names may be written in cosmetic name or International Nomenclature of Cosmetic Ingredients (INCI). When the cosmetic name and INCI correspond, the English name may be omitted.

[0014] I. Branched Organopolysiloxane The organopolysiloxane of the present invention is represented by the following formula (1): (R 13SiO 1 / 2 ) a (R 1 2SiO 2 / 2 ) b (R 1 SiO 3 / 2 ) c (SiO 4 / 2 ) d (1) (In the formula, R 1 are independently a hydrogen atom, a hydroxyl group, or a monovalent alkyl group having 1 to 3 carbon atoms, a is an integer of 0 to 5, b is an integer of 0 to 3, c is an integer of 0 to 2, d is 0 or 1, c+d is 1 or 2, and a+b+c+d is an integer of 4 to 7, provided that R 1 At least two of the groups are monovalent alkyl groups having 2 or 3 carbon atoms. and has a boiling point at 10 hPa of 87 to 119°C, and can be used alone or in combination of two or more.

[0015] R 1 are independently a hydrogen atom, a hydroxyl group, or a monovalent alkyl group having 1 to 3 carbon atoms, and specific examples thereof include a methyl group, an ethyl group, and a propyl group. 1 At least two of R are monovalent alkyl groups having 2 to 3 carbon atoms, and specific examples thereof include an ethyl group and a propyl group. 1 are all methyl groups, or R 1 If only one of the groups is a monovalent alkyl group having 2 to 3 carbon atoms, the affinity for oily components or polar oils that are solid at 25°C is insufficient, making it difficult to obtain a cosmetic that has excellent stability over time and cosmetic durability.

[0016] a is an integer of 0 to 5, b is an integer of 0 to 3, c is an integer of 0 to 2, d is 0 or 1, c + d is 1 or 2, and a + b + c + d is an integer of 4 to 7. Of these, b = 0, d = 0, and c = 1 are preferred. When such a branched organopolysiloxane is incorporated into cosmetics, it does not impart a strong oily feel and provides a good feel during use. Furthermore, even when various oils, oily components that are solid at 25°C, or organic UV absorbers are incorporated, the resulting cosmetics have excellent stability over time and long-lasting cosmetic effect.

[0017] Examples of branched organopolysiloxanes include the following: [ka]

[0018] The boiling point of the branched organopolysiloxane of the present invention at 10 hPa is 87 to 119°C. When a cosmetic containing such an organopolysiloxane is applied to the skin, it does not impart a dry feeling, nor does it impart a strong oily feeling after application. If the boiling point is less than 87°C, the evaporation rate is rapid, which may impart a dry feeling and make it difficult to spread the cosmetic. If the boiling point is higher than 119°C, it will impart a strong oily feeling. Furthermore, since the branched organopolysiloxane of the present invention has a boiling point in the range of 87 to 119°C at 10 hPa and is highly volatile, it does not impart a strong oily feeling after application to the skin, resulting in a good usability. Furthermore, the present invention does not require strict control of the evaporation rate, such as by combining a highly volatile organopolysiloxane with a mildly volatile organopolysiloxane. In other words, the above-mentioned object can be achieved even by using the branched organopolysiloxane of the present invention alone. When two or more branched organopolysiloxanes are used in combination, the average boiling point of the branched organopolysiloxanes should be within the above range. Therefore, it is sufficient that the boiling point of at least one of the branched organopolysiloxanes is within the above range, and the boiling points of other branched organopolysiloxanes incorporated into the cosmetic may be outside the above range. In the present invention, the boiling point refers to the equilibrium reflux boiling point, measured by heating a sample at 10 hPa and recording the internal temperature while refluxing is repeated at a rate of several drops per second.

[0019] The branched organopolysiloxane is preferably one or more selected from 1,5-diethyl-3-trimethylsiloxy-1,1,3,5,5-pentamethyltrisiloxane and 1,5-diethyl-3-ethyldimethylsiloxy-1,1,3,5,5-pentamethyltrisiloxane. Such branched organopolysiloxanes more reliably provide cosmetics that do not give a strong oily feel and provide a good feel when used. They also more reliably provide cosmetics that have excellent stability over time and long-lasting cosmetic effect, even when blended with various oils, oily ingredients that are solid at 25°C, or organic UV absorbers.

[0020] II. Method for producing branched organopolysiloxane One example of a method for producing the branched organopolysiloxane of the present invention is to subject an organohydrogensiloxane to an addition reaction with ethylene or propylene.

[0021] Specific examples of the organohydrogensiloxane include the two types represented by the following general formulas (2) and (3), which may be used in combination. [ka] (In the formula, R 1 is as above.) [ka] (In the formula, R 1 is as above.)

[0022] The compounding ratio of the organohydrogenpolysiloxane represented by the above general formulas (2) and (3) to ethylene or propylene is preferably 1.0 to 2.0, more preferably 1.0 to 1.2, in terms of the molar ratio of ethylene or propylene to hydrosilyl groups.

[0023] The addition reaction is desirably carried out in the presence of a platinum catalyst or a rhodium catalyst, and specifically, chloroplatinic acid, alcohol-modified chloroplatinic acid, chloroplatinic acid-vinylsiloxane complex, etc. The amount of catalyst used may be a catalytic amount, and in particular, the amount of platinum or rhodium is preferably 50 ppm or less, more preferably 20 ppm or less.

[0024] The addition reaction may be carried out without a solvent, or may use an organic solvent as necessary. Examples of the organic solvent include aromatic hydrocarbons such as toluene and xylene, aliphatic or alicyclic hydrocarbons such as n-pentane, n-hexane and cyclohexane, halogenated hydrocarbons such as dichloromethane, chloroform and carbon tetrachloride, ether compounds such as tetrahydrofuran and dioxane, and ketones such as acetone and methyl ethyl ketone. It is preferable to carry out the addition reaction without a solvent, or to carry out the addition reaction using a hydrocarbon or ether compound as the organic solvent.

[0025] The addition reaction conditions are not particularly limited, but it is preferable to carry out the reaction at 40 to 100° C. for 1 to 10 hours while introducing gaseous ethylene or gaseous propylene into or out of the liquid in the reaction vessel.

[0026] III. Cosmetics The branched organopolysiloxane (A) of the present invention has good compatibility with polar oils and the like, making it suitable for use as various solvents and oils in cosmetics. The branched organopolysiloxane of the present invention can be combined with two or more types with different boiling points to adjust the feel during use and evaporation rate. To achieve a moderate evaporation rate, strict adjustment is not required, and the branched organopolysiloxane (A) of the present invention can be used alone in cosmetics. When the branched organopolysiloxane (A) of the present invention is blended in cosmetics and the like, its blending amount is not particularly limited, and it is appropriately blended in within the range of 0.01 to less than 100 mass%. The formulation, use, optional ingredient blending amount, and blending amount are not particularly limited, and known ingredients can be appropriately selected. The optional ingredients are listed below. Each can be used alone or in combination of two or more.

[0027] (B) Oily components that are solid at 25°C The branched organopolysiloxane (A) of the present invention has a high affinity with oily components, even when used in combination with the oily component that is solid at 25° C. This makes it easy to prepare stick-shaped preparations and the like without interfering with the solidification of the oily component, and the desired hardness can be achieved in the preparation.

[0028] The oily component that is solid at 25° C. preferably has a melting point of 40° C. or higher, more preferably 60 to 110° C. Examples include waxes, hydrocarbons, esters, higher alcohols, and higher fatty acids, and are not particularly limited as long as they are raw materials that can be typically incorporated into cosmetics.

[0029] Specific examples include vegetable waxes such as carnauba wax (display name (INCI: Copernicia Cerifera (Carnauba) Wax)), candelilla wax, rice wax, and Japan wax; animal waxes such as beeswax and spermaceti; hydrocarbon waxes such as solid paraffin, polyethylene, ceresin, ozokerite, and microcrystalline wax; higher alcohols such as stearyl alcohol, behenyl alcohol, and cetanol; fatty acids such as stearic acid and behenic acid; and silicone waxes such as (acrylates / stearyl acrylate / dimethicone methacrylate) copolymer (display name (INCI: Acrylates / Stearyl Acrylate / Dimethicone Methacrylate Copolymer), or derivatives thereof, and it is preferable to use one or more selected from these. An example of a commercially available silicone wax is KP-561P manufactured by Shin-Etsu Chemical Co., Ltd.

[0030] In particular, polyethylene (INCI), ceresin (INCI), ozokerite (INCI), candelilla wax (display name (INCI: Euphorbia Cerifera (Candelilla) Wax)), beeswax (display name (INCI: Beeswax)), microcrystalline wax (INCI), stearyl alcohol (INCI), behenyl alcohol (INCI), and cetanol (display name (INCI: Cetyl Alcohol)) have a high affinity with the branched organopolysiloxane of the present invention, and can easily prepare stick-shaped preparations and the like without interfering with the solidification of these oily components, thereby achieving the desired hardness of the preparation.

[0031] The amount of oily components that are solid at 25°C is preferably 0.5 to 50 mass% in the cosmetic, and more preferably 2 to 35 mass% in the cosmetic.

[0032] (C) UV absorber In the present invention, when an ultraviolet shielding effect is desired in the cosmetic, it is preferable to blend an ultraviolet absorber. Because the branched organopolysiloxane of the present invention has excellent compatibility with ultraviolet absorbers, cosmetics containing such ultraviolet absorbers are cosmetic that have a good feel in use, excellent stability over time, and cosmetic durability.

[0033] The ultraviolet absorber is not particularly limited as long as it is a raw material that can be normally incorporated into cosmetics. Specifically, these include oxybenzone-1 (label name (INCI: Benzophenone-1)), oxybenzone-2 (label name (INCI: Benzophenone-2)), oxybenzone-3 (label name (INCI: Benzophenone-3)), oxybenzone-4 (label name (INCI: Benzophenone-4)), oxybenzone-5 (label name (INCI: Benzophenone-5)), oxybenzone-6 (label name (INCI: Benzophenone-6)), oxybenzone-9 (label name (INCI: Benzophenone-9)), homosalate (INCI), octocrylene, t-butyl methoxydibenzoylmethane, ethylhexyl salicylate, diethylaminohydroxybenzoyl hexyl benzoate, polysilicone-15, dimethoxybenzylidene dioxoimidazolidine octyl propionate (label name (INCI: Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate), Terephthalylidene Dicamphor Sulfonic Acid (Indication Name: Terephthalylidene Dicamphor Sulfonic Acid), Ethylhexyl Triazone (Indication Name: Isopentyl Trimethoxycinnamate Trisiloxane), Drometrizole Trisiloxane (Indication Name: Ethylhexyl Dimethyl PABA), Isopropyl Paramethoxycinnamate (Indication Name: Isopropyl Methoxycinnamate), Ethylhexyl Methoxycinnamate, Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, Phenylbenzimidazole Sulfonic Acid (Indication Name: Phenylbenzimidazole Sulfonic Acid) Acid), Methylenebisbenzotriazolyltetramethylbutylphenol, Ethyl dimethoxycinnamate, Glyceryl hexanoate (Indication name (INCI: GlycerylEthylhexyl Dimethoxycinnamate (INCI), Glyceryl PABA (INCI), Methyl Diisopropyl Cinnamate (INCI: Diisopropyl Methyl Cinnamate), Cinoxate (INCI), Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate (INCI: Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate), etc. It is also possible to use a UVA absorber (e.g., diethylaminohydroxybenzoyl hexyl benzoate, etc.) in combination with a UVB absorber (e.g., ethylhexyl methoxycinnamate, etc.), and they can also be combined in any desired manner.

[0034] In this case, the UV absorber is preferably one or more organic UV absorbers selected from ethylhexyl methoxycinnamate (labeled as "Ethylhexyl Methoxycinnamate" in IncI), diethylamino hydroxybenzoyl hexyl benzoate (labeled as "Diethylamino Hydroxybenzoyl Hexyl Benzoate" in IncI), ethylhexyl salicylate (labeled as "Ethylhexyl Salicylate" in IncI), polysilicone-15 (Inci), t-butyl methoxydibenzoylmethane (labeled as "Butyl Methoxydibenzoylmethane" in IncI), oxybenzone (labeled as "Benzophenone" in IncI), methylene bisbenzotriazolyl tetramethylbutylphenol (Inci), bisethylhexyloxyphenol methoxyphenyl triazine (Inci), and octocrylene (Inci). Such organic UV absorbers are particularly preferred because they have enhanced UV absorption effects and excellent compatibility with the branched organopolysiloxane of the present invention.

[0035] The amount of the ultraviolet absorber in the cosmetic is preferably 1 to 50% by mass, more preferably 3 to 20% by mass.

[0036] <Other optional ingredients> Other optional components may include, for example, (1) an oil other than the above (B), (2) a compound having an alcoholic hydroxyl group, (3) a surfactant, (4) a powder, (5) a composition consisting of a crosslinked organopolysiloxane and an oil that is liquid at room temperature, (6) a film-forming agent, (7) an antiperspirant, (8) an antibacterial agent, and (9) other additives. These may be used alone or in appropriate combinations of two or more in appropriate amounts.

[0037] (1) Oils other than those listed above (B) The oil may be semi-solid or liquid, excluding the oily components that are solid at 25°C. For example, natural animal and vegetable oils and semi-synthetic oils and fats, hydrocarbon oils, higher fatty acids, higher alcohols, esters, silicone oils other than the branched organopolysiloxanes that are essential components for achieving the effects of the present invention, and fluorine-based oils can be used.

[0038] Natural animal and vegetable oils and semi-synthetic oils Natural animal and vegetable oils and semi-synthetic oils, アボカド oil (indicated name (INCI: Persea Gratissima (Avocado) Oil)), アマニ oil (indicated name (INCI: Linum Usitatissimum (Linseed) Seed Oil)), アーモンド oil (indicated name (INCI: Prunus Amygdalus Dulcis (Sweet Almond) Oil)), エゴマoil (indicated name), オリーブoil (indicated name (INCI: Olea Europaea (Olive) Fruit Oil)), アメリカガヤ oil (indicated name (INCI: Torreya Californica (California Nutmeg) Oil), Koushiga Oil (INCI: Cymbopogon Nardus (Citronella) Oil), Kaya Seed Oil (INCI: Torreya Nucifera Seed Oil), Kiownin Oil (INCI: Kyounin Yu), Komugi Germ Oil (INCI: Triticum Vulgare (Wheat) Germ Oil), Goma Oil (INCI: Sesamum Indicum (Sesame) Seed Oil), Komugi Germ Oil (INCI: Triticum Vulgare (Wheat) Germ Oil), Kome Germ Oil (INCI: Oryza Sativa (Rice) Germ Oil), Comed Oil (INCI: Oryza Sativa (Rice) Bran Oil), Sazan Oil (INCI: Camellia Kissi Seed Oil), Saffron Oil (INCI: Carthamus Tinctorius (Safflower) Seed Oil), Daizu Oil (INCI: Glycine Soja (Soybean) Oil), Chiya Oil (INCI: Camellia Sinensis Seed Oil), Tsubaki Oil (INCI: Camellia Japonica Seed Oil), Evening Primrose Oil (INCI: Oenothera Biennis (Evening Primrose)Oils such as rapeseed oil (designated name (INCI: RAPE SHUSHI YU)), corn germ oil (designated name (INCI: Zea Mays (Corn) Germ Oil)), wheat germ oil (designated name (INCI: Triticum Vulgare (Wheat) Germ Oil)), etc., persic oil (designated name), palm oil (designated name (INCI: Elaeis Guineensis (Palm) Oil)), palm kernel oil (designated name (INCI: Elaeis Guineensis (Palm) Kernel Oil)), castor oil (designated name (INCI: Ricinus Communis (Castor) Seed Oil)), sunflower oil (designated name (INCI: Helianthus Annuus (Sunflower) Seed Oil)), grape seed oil (designated name (INCI: Vitis Vinifera (Grape) Seed Oil)), jojoba seed oil (designated name (INCI: Simmondsia Chinensis (Jojoba) Seed Oil)), macadamia seed oil (designated name (INCI: Macadamia Ternifolia Seed Oil)), meadowfoam oil (designated name (INCI: Limnanthes Alba (Meadowfoam) Seed Oil)), cottonseed oil (designated name (INCI: Gossypium Herbaceum (Cotton) Seed Oil)), coconut oil (designated name (INCI: Cocos Nucifera (Coconut) Oil)), peanut oil (designated name (INCI: Arachis Hypogaea (Peanut) Oil)), etc. natural vegetable oils, shark liver oil (designated name (INCI: Shark Liver Oil)), cod liver oil (designated name (INCI: Cod Liver Oil)), fish liver oil (designated name (INCI: Fish Liver Oil)), turtle oil (designated name (INCI: Turtle Oil)), mink oil (designated name (INCI: Mink Oil)), egg oil (designated name (INCI: Egg Oil)), etc. natural animal oils, hydrogenated coconut oil (designated name (INCI: Hydrogenated Coconut Oil)), liquid lanolin (designated name (INCI: Lanolinand semi-synthetic oils and fats such as synthetic oils.

[0039] Hydrocarbon oil The hydrocarbon oil may be a linear or branched hydrocarbon oil, and may be either a volatile or non-volatile hydrocarbon oil. Specific examples include isoparaffins such as olefin oligomers (INCI) and (C13,14) isoparaffin (INCI), alkanes such as isododecane (INCI), undecane (INCI), dodecane (INCI), isohexadecane (INCI), hydrogenated polyisobutene (display name (INCI: Hydrogenated Polyisobutene)), squalane (INCI), mineral oil (INCI), palm alkanes (INCI), (C13-15) alkanes (INCI), and petrolatum (display name (INCI: Petrolatum)).

[0040] ·Higher fatty acids Examples of higher fatty acids include oleic acid (labeled as "Oleic Acid" in Inc.), linoleic acid (labeled as "Linoleic Acid" in Inc.), linolenic acid (labeled as "Linolenic Acid" in Inc.), arachidonic acid (labeled as "Arachidonic Acid" in Inc.), eicosapentaenoic acid (labeled as "Eicosapentaenoic Acid" in Inc.), docosahexaenoic acid (labeled as "Docosahexaenoic Acid" in Inc.), isostearic acid (labeled as "Isostearic Acid" in Inc.), and hydroxystearic acid (labeled as "Hydroxystearic Acid" in Inc.).

[0041] Higher alcohols Examples of higher alcohols include alcohols preferably having 6 or more carbon atoms. Specific examples of higher alcohols include lauryl alcohol (INCI), myristyl alcohol (INCI), palmityl alcohol (INCI), stearyl alcohol (INCI), behenyl alcohol (INCI), oleyl alcohol (INCI), isostearyl alcohol (INCI), octyldodecanol (INCI), cholesterol (INCI), phytosterols (INCI), and batyl alcohol (INCI).

[0042] Ester oil Examples of ester oils include n-alkyl glycol monoisostearates such as diisobutyl adipate (label name (INCI: Diisobutyl Adipate)), dihexyldecyl adipate (label name (INCI: Diheptylundecyl Adipate)), and isostearyl isostearate (label name (INCI: Isostearyl Isostearate)), isocetyl isostearate (label name (INCI: Isocetyl Isostearate)), trimethylolpropane triisostearate (label name (INCI: Trimethylolpropane Triisostearate)), glycol diethylhexanoate (label name (INCI: Glycol Diethylhexanoate)), cetyl ethylhexanoate (label name (INCI: Cetyl Ethylhexanoate)), and trimethylolpropane triethylhexanoate (label name (INCI: Trimethylolpropane Triethylhexanoate), pentaerythrityl tetraethylhexanoate (label name (INCI: Pentaerythrityl Tetraethylhexanoate)), cetyl octanoate (label name (INCI: Cetyl Ethylhexanoate)), octyldodecyl esters such as octyldodecyl stearoyloxystearate (label name (INCI: Octyldodecyl Stearoyl Stearate)), oleyl oleate (label name (INCI: Oleyl Oleate)), octyldodecyl oleate (label name (INCI: Octyldodecyl Oleate)), decyl oleate (label name (INCI: Decyl Oleate)), neopentyl glycol dioctanoate (label name (INCI: Neopentyl Glycol Diethylhexanoate)), neopentyl glycol dicaprate (label name (INCI: Neopentyl Glycol Dicaprate), Diisostearyl Malate (Indication Name (INCI: Diisostearyl Malate)), Triethyl Citrate (Indication Name (INCI: Triethyl Citrate)Citrate), Diethylhexyl succinate (Label Name (INCI: Diethylhexyl Succinate)), Amyl acetate (Label Name (INCI: Amyl Acetate)), Ethyl acetate (Label Name (INCI: Etyl Acetate)), Butyl acetate (Label Name (INCI: Butyl Aceetate)), Isocetyl stearate (Label Name (INCI: Isocetyl Stearate)), Butyl stearate (Label Name (INCI: Butyl Stearate)), Diisopropyl sebacate (Label Name (INCI: Diisopropyl Sebacate)), Diethylhexyl sebacate (Label Name (INCI: Diethylhexyl Sebacate)), Cetyl lactate (Label Name (INCI: Cetyl Lactate)), Myristyl lactate (Label Name (INCI: Myristyl Lactate)), Isononyl isononanoate (Label Name (INCI: Isononyl Palmitate esters such as isotridecyl isononanoate (label name (INCI: Isotridecyl Isononanoate)), isopropyl palmitate (label name (INCI: Isopropyl Palmitate)), ethylhexyl palmitate (label name (INCI: Ethylhexyl Isopalmitate)), and hexyldecyl palmitate (label name (INCI: Isocetyl Palmitate, Hexyldecyl Palmitate)), cholesteryl hydroxystearate (label name (INCI: Cholesteryl Hydroxystearate)), isopropyl myristate (label name (INCI: Isopropyl Myristate)), octyldodecyl myristate (label name (INCI: Octyldodecyl Myristate)), and myristyl myristate (label name (INCI: Myristyl Myristate), ethylhexyl laurate (labeled as (INCI: Ethylhexyl Laurate)), hexyl laurate (labeled as (INCI: Hexyl Laurate)), dioctyldodecyl lauroyl glutamate (labeled as (INCI: DioctyldodecylLauroyl Glutamate), lauroyl sarcosine isopropyl ester (labeled name (INCI: Isopropyl Lauroyl Sarcosinate)), etc. Furthermore, among ester oils, examples of glyceride oils include triethylhexanoin (INCI), tri(caprylic / capric)glyceryl (labeled as (INCI: Caprylic / Capric Triglyceride)), cocoglyceryl (INCI), (caprylic / capric / succinic) triglyceride (labeled as (INCI: Caprylic / Capric / Succinic Triglyceride)), and (caprylic / capric) glycerides (labeled as (INCI: Caprylic / Capric Glycerides)).

[0043] Silicone oil As the silicone oil, silicone oils other than the branched organopolysiloxane, which is an essential component for achieving the effects of the present invention, can be blended. For example, alkyl-modified silicones such as dimethicone (INCI), trisiloxane (INCI), methyl trimethicone (INCI), ethyl trisiloxane (INCI), ethyl methicone (INCI), and hexyl dimethicone (INCI), long-chain alkyl-modified silicones such as caprylyl methicone (INCI), low- to high-viscosity linear or branched organopolysiloxanes such as phenyl trimethicone (INCI), diphenyl dimethicone (INCI), diphenylsiloxyphenyl trimethicone (INCI), tetraphenyldimethyldisiloxane (INCI), and methylhydrogen polysiloxane, cyclotetrasiloxane (INCI), and cyclopentasiloxane (INCI). Examples of such silicone rubbers include cyclic organopolysiloxanes such as cyclohexasiloxane (INCI), amino-modified organopolysiloxanes such as amodimethicone (INCI) and aminopropyl dimethicone (INCI), pyrrolidone-modified organopolysiloxanes such as PCA dimethicone (INCI), pyrrolidone carboxylic acid-modified organopolysiloxanes, gummy dimethylpolysiloxanes with a high degree of polymerization, gummy amino-modified organopolysiloxanes, and silicone rubbers such as gummy dimethylsiloxane-methylphenylsiloxane copolymers, as well as low-viscosity organopolysiloxane solutions of silicone gums and rubbers, amino acid-modified silicones, fluorine-modified silicones, silicone resins, and silicone resin solutions.

[0044] Examples of commercially available silicone oils include KF-96L-1cs, KF-96L-1.5cs, KF-96L-2cs, KF-96A-6cs, KF-4422, KF-54, KF-54HV, KF-56A, and KF-995 manufactured by Shin-Etsu Chemical Co., Ltd.

[0045] Fluorine-based oils Examples of fluorine-based oils include perfluorodecalin (INCI), perfluorononyl dimethicone (INCI), and perfluoromethylcyclopentane (INCI).

[0046] (2) Compounds with an alcoholic hydroxyl group Examples of compounds having an alcoholic hydroxyl group include lower alcohols preferably having 2 to 5 carbon atoms, such as ethanol (display name (INCI: Alcohol)) and isopropanol (display name (INCI: Isopropyl Alcohol)), and sugar alcohols, such as sorbitol (INCI), maltose (INCI), and xylitol (INCI). Further examples include sterols, such as cholesterol (INCI), sitosterol (display name (INCI: Beta-Sitosterol)), phytosterols (INCI), and lanosterol (INCI).

[0047] (3) Surfactants Surfactants include nonionic, anionic, cationic, and amphoteric surfactants, but are not particularly limited thereto; any surfactant commonly used in cosmetics can be used. Among these surfactants, partially crosslinked polyether-modified silicones, partially crosslinked polyglycerin-modified silicones, linear or branched polyoxyethylene-modified organopolysiloxanes, linear or branched polyoxyethylene-polyoxypropylene-modified organopolysiloxanes, linear or branched polyoxyethylene-alkyl-co-modified organopolysiloxanes, linear or branched polyoxyethylene-polyoxypropylene-alkyl-co-modified organopolysiloxanes, linear or branched polyglycerin-modified organopolysiloxanes, and linear or branched polyglycerin-alkyl-co-modified organopolysiloxanes are preferred. In these surfactants, the content of hydrophilic polyoxyethylene groups, polyoxyethylene-polyoxypropylene groups, or polyglycerin residues preferably accounts for 10 to 70% by mass of the molecule.

[0048] Examples of partially crosslinked polyether-modified silicones and partially crosslinked polyglycerin-modified silicones include (dimethicone / (PEG-10 / 15)) crosspolymer (INCI), (PEG-15 / lauryl dimethicone) crosspolymer (INCI), (PEG-10 / lauryl dimethicone) crosspolymer (INCI), (PEG-15 / lauryl polydimethylsiloxyethyl dimethicone) crosspolymer (INCI), (dimethicone / polyglycerin-3) crosspolymer (INCI), (lauryl dimethicone / polyglycerin-3) crosspolymer (INCI), and (polyglycerin-3 / lauryl polydimethylsiloxyethyl dimethicone) crosspolymer (INCI). Furthermore, when a partially crosslinked polyether-modified silicone or a partially crosslinked polyglycerin-modified silicone is used, in a composition comprising the crosslinked organopolysiloxane and an oil that is liquid at room temperature, the crosslinked organopolysiloxane preferably swells in the liquid oil by absorbing an amount of the liquid oil that is equal to or greater than its own weight.

[0049] The liquid oil may be the branched organopolysiloxane of the present invention, or may be a liquid silicone oil, hydrocarbon oil, ester oil, natural animal or vegetable oil, semi-synthetic oil, or fluorine-based oil contained in the optional component (1) oil, and examples thereof include cyclopentasiloxane (INCI), dimethicone (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (display name (INCI: Isotridecyl Isononanoate)), squalane (INCI), and the like.

[0050] Examples of commercially available crosslinked organopolysiloxanes that swell when they contain a liquid oil include KSG-210, KSG-240, KSG-270, KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, KSG-350Z, KSG-710, KSG-810, KSG-820, KSG-830, KSG-840, KSG-820Z, and KSG-850Z manufactured by Shin-Etsu Chemical Co., Ltd. Examples of surfactants that are not crosslinked organopolysiloxanes include PEG-11 methyl ether dimethicone (INCI), PEG / PPG-20 / 22 butyl ether dimethicone (INCI), PEG-3 dimethicone (INCI), PEG-10 dimethicone (INCI), PEG-9 polydimethylsiloxyethyl dimethicone (INCI), lauryl PEG-9 polydimethylsiloxyethyl dimethicone (INCI), cetyl PEG / PPG-10 / 1 dimethicone (INCI), polyglyceryl-3 disiloxane dimethicone (INCI), polyglyceryl-3 polydimethylsiloxyethyl dimethicone (INCI), and lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (INCI).

[0051] Commercially available examples include KF-6011, KF-6011P, KF-6012, KF-6015, KF-6017, KF-6043, KF-6028, KF-6038, KF-6048, KF-6100, KF-6104, KF-6106, KF-6105, and KF-6115 manufactured by Shin-Etsu Chemical Co., Ltd.

[0052] In either case, the amount of surfactant blended is preferably 0.1 to 20% by mass of the total cosmetic. If it is 0.1% or more, the dispersing and emulsifying functions can be fully performed, and if it is 20% by mass or less, the cosmetic will not feel sticky after use, which is preferable. The HLB of the surfactant is not limited, but is preferably 2 to 14.5 for the purpose of maintaining the water resistance of the cosmetic.

[0053] (4) Powder Examples of powders include color pigments, inorganic powders, metal powders, organic powders, inorganic-organic composite powders, etc. Specific examples are as follows:

[0054] Color pigments The color pigment is not particularly limited as long as it is a pigment that is normally used for coloring cosmetics, and examples thereof include red iron oxide (display name (INCI: Iron Oxides)), yellow iron oxide (display name (INCI: Iron Oxides)), white titanium oxide (display name (INCI: Titanium Dioxide)), black iron oxide (display name (INCI: Iron Oxides)), ultramarines (display name (INCI: Ultramarines)), ferric ferrocyanide (display name (INCI: Ferric Ferrocyanide, Ferric Ammonium Ferrocyanide)), manganese violet (display name (INCI: Manganese Violet)), cobalt titanate (display name (INCI: Cobalt Titanium Oxide)), chromium hydroxide (display name (INCI: Chromium Hydroxide Green)), chromium oxide (display name (INCI: Chromium Oxide Greens)), aluminum / cobalt oxide (display name (INCI: Cobalt Aluminum Oxide)), and the like. Any of the following pigments can be used: inorganic brown pigments such as titanium nitride (label name (INCI: Titanium Oxide)), cobalt titanate (label name (INCI: Cobalt Titanium Oxide)), (titanium / titanium oxide) baked product (label name (INCI: Titanium / Titanium Dioxide)), titanate (Li / cobalt) (label name (INCI: Lithium Cobalt Titanate)), cobalt titanate (label name (INCI: Cobalt Titanium Oxide)), (iron oxide / titanium oxide) sintered product (label name), iron oxide-doped titanium oxide (label name (INCI: Iron Oxides, Titanium Dioxide)), inorganic brown pigments such as titanium nitride (label name (INCI: Titanium Nitride)), ferrous hydroxide (label name (INCI: Iron Hydroxide)), gamma-iron oxide, inorganic yellow pigments such as ochre, and colored pigments such as lakes of tar-based pigments and lakes of natural pigments. The shape of the pigment may be any shape, such as spherical, approximately spherical, rod-like, spindle-like, petal-like, strip-like, or irregular, and there are no particular limitations on the geometric form as long as it is possible to impart color to the cosmetic.

[0055] ·Inorganic powder Inorganic powders include zirconium oxide (display name (INCI: Zirconium Dioxide)), zinc oxide (display name (INCI: Zinc Oxide)), cerium oxide (display name (INCI: Cerium Oxide)), magnesium oxide (display name (INCI: Magnesium Oxide)), barium sulfate (display name (INCI: Barium Sulfate)), calcium sulfate (display name (INCI: Calcium Sulfate)), Magnesium Sulfate (Indication Name (INCI: Magnesium Sulfate)), Calcium Carbonate (Indication Name (INCI: Calcium Carbonate)), Magnesium Carbonate (Indication Name (INCI: Magnesium Carbonate)), Talc (INCI), Mica (INCI), Kaolin (INCI), Synthetic Fluorphlogopite (Indication Name (INCI: Synthetic Fluorphlogopite)), Synthetic Iron Phlogopite (Indication Name), Biotite (Indication Name (INCI: Biotite)), Potassium Silicate (Indication Name (INCI: Potassium Silicate)), Silica (INCI), Aluminum Silicate (Indication Name (INCI: Aluminum Silicate)), Magnesium Silicate (Indication Name (INCI: Magnesium Silicate)), Aluminum / Magnesium Silicate (Indication Name (INCI: Magnesium Aluminum Silicate)), Calcium Silicate (Indication Name (INCI: Calcium Silicate), Al / Ca / Na silicate (Indication name (INCI: Aluminum Calcium Sodium Silicate)), Li / Mg / Na silicate (Indication name (INCI: Lithium Magnesium Sodium Silicate)), Na / Mg silicate (Indication name (INCI: Sodium Magnesium Silicate)), Calcium / Al borosilicate (Indication name (INCI: Calcium Aluminum Borosilicate)), Calcium / Na borosilicate (Indication name (INCI: Calcium Sodium Borosilicate)), Hydroxyapatite (INCI), Bentonite (INCI), Montmorillonite (INCI), Hectorite (INCI), Zeolite (INCI), Alumina (INCI), Aluminum hydroxide (Indication name (INCI: Aluminum Hydroxide)), Boron nitride (Indication name (INCI: Boron Examples of suitable fine particles include fine particles made of glass (labeled name (INCI: Glass)), etc. Examples of inorganic colored pearl pigments include pearl agents such as mica (INCI) coated with titanium oxide (display name (INCI: Titanium Dioxide)) and synthetic fluorophlogopite (display name (INCI: Synthetic Fluorphlogopite) coated with titanium oxide (display name (INCI: Titanium Dioxide)), as well as pearl pigments such as bismuth oxychloride (display name (INCI: Bismuth Oxychloride)), bismuth oxychloride (display name (INCI: Bismuth Oxychloride)) coated with titanium oxide (display name (INCI: Titanium Dioxide)), talc (INCI) coated with titanium oxide (display name (INCI: Titanium Dioxide)), fish scale foil (display name), and colored mica coated with titanium oxide (display name (INCI: Titanium Dioxide)), and are not particularly limited and may be untreated or may have been subjected to a known surface treatment commonly used in cosmetics.

[0056] ·Metal powder Examples of metal powders include fine metal particles made of Al (display name (INCI: Aluminum, Aluminum Powder)), copper (display name (INCI: Copper Powder)), silver (display name (INCI: Silver Powder)), gold (display name (INCI: Gold)), etc.

[0057] ·Organic powder Examples of organic powders include powders made from silicone, polyamide, polyacrylic acid / acrylic acid ester, polyester, polyethylene (INCI), polypropylene (INCI), polystyrene (INCI), styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, polyurethane, vinyl resin, urea resin, melamine resin, benzoguanamine, polymethylbenzoguanamine, tetrafluoroethylene, polymethyl methacrylate, cellulose (INCI), silk (INCI), nylon (display name), phenolic resin, epoxy resin, polycarbonate, etc.

[0058] In particular, examples of silicones include silicone resin particles; polymethylsilsesquioxane (INCI), silicone rubber powder, silicone resin-coated silicone rubber powder; (vinyl dimethicone / methicone silsesquioxane) crosspolymer (INCI), (diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) crosspolymer (INCI), polysilicone-1 crosspolymer (INCI), polysilicone-22 (INCI), and the like.

[0059] Examples of commercially available silicone powders include KMP-590, KMP-591, KMP-592, KMP-597, KMP-598, KSP-100, KSP-101, KSP-102, KSP-105, KSP-300, KSP-411, KSP-441, KM-9729, and KM-440 manufactured by Shin-Etsu Chemical Co., Ltd. Other examples include metal soaps, and specific examples include powders made of zinc stearate (display name (INCI: Zinc Stearate)), aluminum stearate (display name (INCI: Aluminum Stearate)), calcium stearate (display name (INCI: Calcium Stearate)), magnesium stearate (display name (INCI: Magnesium Stearate)), zinc myristate (display name (INCI: Zinc Myristate)), magnesium myristate (display name (INCI: Magnesium Myristate)), zinc / sodium cetyl phosphate (display name (INCI: Sodium Zinc Cetyl Phosphate)), potassium cetyl phosphate (display name (INCI: Potassium Cetyl Phosphate)), etc.

[0060] Further, organic dyes and the like can also be mentioned, and specific examples thereof include Red 3, Red 104(1) (display name (INCI: Red 28, Red 28 Lake)), Red 106, Red 201 (display name (INCI: Red 6)), Red 202 (display name (INCI: Red 7)), Red 204, Red 205, Red 220 (display name (INCI: Red 34)), Red 226 (display name (INCI: Red 30)), Red 227 (display name (INCI: Red 33, RED 33 Lake)), Red 228 (display name (INCI: Red 36)), Red 230(1) (display name (INCI: Red 22, Red 22 Lake)), Red 230(2) (display name), Red 401 (display name), Red 505 (display name), Yellow 4 (display name (INCI: Yellow 5)), Yellow 5 (Display name (INCI: Yellow 6, Yellow 6 Lake)), Yellow 202 (1) (Display name (INCI: Yellow 8)), Yellow 203 (Display name (INCI: Yellow 10, Yellow 10 Lake)), Yellow 204 (Display name (INCI: Yellow 11)), Yellow 401, Blue 1 (Display name (INCI: Blue) 1, Blue 1 Lake)), Blue 2, Blue 201, Blue 205 (Display name (INCI:Blue 4))Blue 404 (Display name), Green 3 (Display name (INCI:Green 3, Green 3 Lake))), Green 201 (Display name (INCI:Green 5))), Green 202 (Display name (INCI:Green 6)), Green 204 (Display name (INCI:Green) 8), Green 205 (label name), Orange 201 (label name (INCI: Orange 5)), Orange 203 (label name (INCI: Pigment Orange 5)), Orange 204 (label name), Orange 205 (label name (INCI: Orange 4, Orange 4 Lake)), Orange 206 (label name (INCI: Orange 10)), Orange 207 (label name (INCI: Orange 11)), and other tar dyes, cochineal (INCI), laccaic acid (label name (INCI: Laccaic Acid)), safflower red (label name (INCI: Carthamus Tinctorius (Safflower) Flower Extract)), purple root extract (label name (INCI: Lithospermum OfficinaleExamples of natural pigments include Gardenia Root Extract), Gardenia Yellow (display name), and Gardenia Blue (display name (INCI: Hydrolyzed Gardenia Florida Extract)).

[0061] ·Inorganic / organic composite powder The inorganic-organic composite powder may be, for example, a composite powder in which the surface of an inorganic powder is coated with an organic powder by a known or commonly used method.

[0062] The above-mentioned powders may also be surface-treated. The surface treatment agent is preferably one that can impart hydrophobicity from the viewpoint of water resistance of the cosmetic. Examples of the surface treatment agent that can impart hydrophobicity include, but are not limited to, silicone treatment agents, waxes, paraffins, organic fluorine compounds such as perfluoroalkyl phosphates, surfactants, amino acids such as N-acyl glutamic acid, and metal soaps such as aluminum stearate and magnesium myristate.

[0063] More preferred are silicone treatment agents, including silanes or silylating agents such as triethoxycaprylylsilane (INCI), dimethicone (INCI), methicone (INCI), hydrogen dimethicone (INCI), triethoxysilylethyl polydimethylsiloxyethyl dimethicone (INCI), triethoxysilylethyl polydimethylsiloxyethyl hexyl dimethicone (INCI), and (acrylates / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate) copolymer (display name (INCI: Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / Dimethicone Methacrylate Copolymer). Specific examples of these silicone treating agents include AES-3083, KF-99P, KF-9901, KF-9908, KF-9909, KP-574, KP-541, and the like, all manufactured by Shin-Etsu Chemical Co., Ltd.

[0064] The above surface hydrophobic treatment agents may be used alone or in combination of two or more. Specific examples of surface-treated color pigments include the KTP-09 series manufactured by Shin-Etsu Chemical Co., Ltd., particularly KTP-09W, 09R, 09Y, and 09B.

[0065] (5) A composition comprising a crosslinked organopolysiloxane and an oil that is liquid at room temperature In a composition comprising a crosslinked organopolysiloxane and an oil that is liquid at room temperature, the crosslinked organopolysiloxane preferably swells with the liquid oil in an amount equal to or greater than its own weight. The liquid oil may be the branched organopolysiloxane of the present invention, or may be a liquid silicone oil, hydrocarbon oil, ester oil, natural animal or vegetable oil, semi-synthetic oil, or fluorine-containing oil contained in the optional component (1) oil, such as cyclopentasiloxane (INCI), dimethicone (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (labeled name: Isotridecyl Isononanoate), or squalane (INCI). Unlike the aforementioned component (3), component (5) is a compound that does not have a polyether or polyglycerin structure in its molecular structure, and specific examples include (dimethicone / vinyl dimethicone) crosspolymer (INCI), (dimethicone / phenyl vinyl dimethicone) crosspolymer (INCI), (vinyl dimethicone / lauryl dimethicone) crosspolymer (INCI), (lauryl polydimethylsiloxyethyl dimethicone / bisvinyl dimethicone) crosspolymer (INCI), etc. Examples of commercially available compositions comprising a crosslinked organopolysiloxane and an oil that is liquid at room temperature include KSG-15, KSG-1510, KSG-16, KSG-1610, KSG-19, KSG-016F, KSG-18A, KSG-41A, KSG-42A, KSG-43, KSG-44, KSG-042Z, KSG-045Z, and KSG-048Z manufactured by Shin-Etsu Chemical Co., Ltd.

[0066] (6) Film-forming agent The film-forming agent is mainly blended for the purpose of further maintaining the durability of the cosmetic effect. Although there are no particular limitations, a silicone-based composition is preferable from the viewpoint of imparting water repellency. Specifically, trimethylsiloxysilicate, acrylic-silicone film-forming agent, silicone-modified norbornene, silicone-modified pullulan, etc. can be used.

[0067] Examples of film-forming agents for silicone-based compositions include trimethylsiloxysilicate (labeled as (INCI): Trimethylsiloxysilicate), (acrylates / dimethicone) copolymer (INCI), (norbornene / tris(trimethylsiloxy)silylnorbornene) copolymer (INCI), tri(trimethylsiloxy)silylpropylcarbamate pullulan (labeled as (INCI): Trimethylsiloxysilylcarbamoyl Pullulan), and the like.

[0068] The film-forming agent may be dissolved in a liquid oil at room temperature before blending into the cosmetic. The liquid oil may be the branched organopolysiloxane of the present invention, or may be a liquid silicone oil, hydrocarbon oil, ester oil, natural animal or vegetable oil, semi-synthetic oil, or fluorine-based oil contained in the optional component (1) oil, such as cyclopentasiloxane (INCI), dimethicone (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (labeled name: Isotridecyl Isononanoate), squalane (INCI), or butyl acetate (labeled name: Butyl Acetate). Specific examples of commercially available silicone film-forming agents include KF-7312J, KP-545, KP-549, KP-543, NBN-30-ID, TSPL-30-ID, and TSPL-30-D5 manufactured by Shin-Etsu Chemical Co., Ltd.

[0069] (7) Antiperspirant When the cosmetic composition of the present invention is a deodorant, it can optionally contain an antiperspirant. The antiperspirant is not particularly limited, and a wide variety of commonly used ingredients can be used, as long as it is a component that suppresses sweating by astringing the skin. Examples include aluminum hydroxyhalides such as aluminum chlorohydrate and aluminum allantoin chlorohydrate, aluminum halides such as aluminum chloride, aluminum allantoin salts, tannic acid, persimmon tannin, potassium aluminum sulfate, zinc oxide, zinc paraphenolsulfonate, burnt alum, tetrachloro(Al / zirconium) hydrate, and trichlorohydrex glycine (Al / zirconium). In particular, components that exhibit high effectiveness are preferably antiperspirant active ingredients selected from the group consisting of aluminum halides, aluminum hydroxyhalides, and complexes or mixtures of aluminum halides with zirconyl oxyhalides and zirconyl hydroxyhalides. These antiperspirants can be dissolved in water and used, or the powder can be directly incorporated into the formulation. Commercially available antiperspirants can also be used. The commercially available antiperspirants used may be in the form of a mixed raw material with other ingredients. The content of the antiperspirant is not particularly limited and can be appropriately changed depending on the amount of other ingredients. For the purpose of obtaining a deodorant with excellent antiperspirant effect and a deodorant with reduced skin irritation, the content is preferably in the range of 0.001 to 30% by mass, more preferably 0.01 to 20% by mass, based on the total deodorant.

[0070] (8) Antibacterial agents The antibacterial agent is not particularly limited as long as it is a component that can obtain a deodorizing effect by inhibiting the proliferation of normal bacteria on the skin that produce substances that cause body odor.For example, antibacterial agents such as triclosan, benzalkonium chloride, benzothonium chloride, chlorhexidine hydrochloride, chlorhexidine gluconate, halocarban, and isomethylphenol are commonly used.In addition, essential oils and extracts derived from herbal medicines, such as dry distillation extract of green tea, which have antibacterial properties, may also be added. Examples of antibacterial agents with deodorizing effects, such as essential oils and extracts derived from herbal medicines, include green tea extract, lavender extract, Scutellaria root extract, Coptis chinensis extract, Bark extract, Artemisia capillaris extract, Aloe arborescens extract, Sophora flavescens root extract, Sasa kumamoto leaf extract, garlic extract, Hamamelis virginiana extract, black tea extract, sage leaf extract, Zanthoxylum piperitum extract, ginger root extract, Calamus calamus root extract, Hedera helix extract, Houttuynia cordata extract, peach fruit extract, peach leaf extract, peppermint leaf extract, Cnidium rhizome extract, eucalyptus leaf extract, peanut seed coat extract, Ganoderma lucidum extract, Sanguisorba officinalis extract, etc. One or more plant extracts may be used, or two or more may be mixed.

[0071] (9) Other additives Other additives include oil-soluble gelling agents, UV absorbing / scattering agents, moisturizers, preservatives, fragrances, salts, antioxidants, pH adjusters, chelating agents, cooling agents, anti-inflammatory agents, skin-beautifying ingredients (whitening agents, cell activators, skin roughness improving agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, and inclusion compounds.

[0072] Oil-soluble gelling agent Examples of oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate, and zinc myristate; amino acid derivatives such as lauroyl glutamic acid (labeled as "Lauroyl Glutamic Acid" in Inc.) and α,γ-di-n-butylamine; dextrin palmitate (labeled as "Dextrin Palmitate" in Inc.), dextrin isostearate (labeled as "Dextrin Isostearate" in Inc.), dextrin myristate (labeled as "Dextrin Myristate" in Inc.), inulin stearate (labeled as "Stearoyl Inulin" in Inc.), and dextrin (palmitate / ethylhexanoate) (labeled as "Dextrin" in Inc.). dextrin fatty acid esters such as dextrin palmitate / ethylhexanoate); sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate and fructooligosaccharide 2-ethylhexanoate; benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol; disteardimonium hectorite (INCI), stearalkonium hectorite (INCI), organically modified clay minerals of hectorite; stearalkonium bentonite (INCI), etc.

[0073] UV absorbing and scattering agent Examples of ultraviolet absorbing / scattering agents include particles that absorb and scatter ultraviolet light, such as titanium dioxide microparticles, iron-containing titanium dioxide microparticles, zinc oxide microparticles, cerium oxide microparticles, and composites thereof. Dispersions of these ultraviolet absorbing / scattering particles dispersed in an oil agent can also be used. The oil agent can be the branched organopolysiloxane of the present invention, or a liquid silicone oil, hydrocarbon oil, ester oil, natural animal or vegetable oil, semi-synthetic oil, or fluorine-based oil contained in the optional component (1) oil agent, such as cyclopentasiloxane (INCI), dimethicone (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (display name: Isotridecyl Isononanoate), and squalane (INCI).

[0074] Specific examples of dispersions in which particles that absorb and scatter ultraviolet light are dispersed in an oil agent in advance include the SPD series (trade name) manufactured by Shin-Etsu Chemical Co., Ltd., particularly SPD-T5, Z5, T6, Z6, T7, etc.

[0075] Moisturizer Moisturizing agents include polyhydric alcohols such as BG (display name (INCI: Butylene Glycol)), PG (display name (INCI: Propylene Glycol)), DPG (display name (INCI: Dipropylene Glycol)), pentylene glycol (INCI), 1,10-decanediol (INCI), octanediol (INCI), 1,2-hexanediol (INCI), erythritol (INCI), glycerin (INCI), diglycerin (INCI), and polyethylene glycol; glucose (INCI), glyceryl glucoside (INCI), betaine (INCI), sodium chondroitin sulfate (display name (INCI: Sodium Chondroitin Sulfate)), and PCA-Na (display name (INCI: Sodium PCA), methyl gluceth-10 (INCI), methyl gluceth-20 (INCI), hyaluronic acid, egg yolk lecithin, soybean lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids, etc.

[0076] Preservatives Examples of preservatives include alkyl parahydroxybenzoates, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, and phenoxyethanol. Examples of antibacterial agents include benzoic acid, salicylic acid, carbolic acid, sorbic acid, alkyl parahydroxybenzoates, parachlorometacresol, hexachlorophene, trichlorocarbanilide, photosensitizers, and phenoxyethanol.

[0077] ·Fragrance Fragrances include natural and synthetic fragrances. Natural fragrances include plant-based fragrances isolated from flowers, leaves, wood, and peels; and animal-based fragrances such as musk and civet. Synthetic fragrances include hydrocarbons such as monoterpenes; alcohols such as aliphatic alcohols and aromatic alcohols; aldehydes such as terpene aldehydes and aromatic aldehydes; ketones such as alicyclic ketones; esters such as terpene esters; lactones; phenols; oxides; nitrogen-containing compounds; and acetals.

[0078] ·salts Examples of salts include inorganic salts, organic acid salts, amine salts, and amino acid salts. Examples of inorganic salts include sodium salts, potassium salts, magnesium salts, calcium salts, aluminum salts, zirconium salts, and zinc salts of inorganic acids such as hydrochloric acid, sulfuric acid, carbonic acid, and nitric acid; examples of organic acid salts include salts of organic acids such as acetic acid, dehydroacetic acid, citric acid, malic acid, succinic acid, ascorbic acid, and stearic acid; examples of amine salts and amino acid salts include salts of amines such as triethanolamine, and salts of amino acids such as glutamic acid. In addition, salts of hyaluronic acid, chondroitin sulfate, aluminum zirconium glycine complex, and even acid-alkali neutral salts used in cosmetic formulations can also be used.

[0079] Antioxidants The antioxidant is not particularly limited, but examples thereof include carotenoids, ascorbic acid and its salts, ascorbyl stearate, tocopherol, tocopherol acetate, tocopherol, pt-butylphenol, butylhydroxyanisole, dibutylhydroxytoluene, phytic acid, ferulic acid, thiotaurine, hypotaurine, sulfites, erythorbic acid and its salts, chlorogenic acid, epicatechin, epigallocatechin, epigallocatechin gallate, apigenin, campherol, myricetin, quercetin, etc. One type of antioxidant may be used alone, or two or more types may be used in combination.

[0080] pH adjuster Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium bicarbonate, and ammonium bicarbonate.

[0081] Chelating agents Examples of the chelating agent include alanine, edetate sodium salt, sodium polyphosphate, sodium metaphosphate, phosphoric acid, and the like.

[0082] · Cooling agent Examples of cooling agents include L-menthol and camphor.

[0083] Anti-inflammatory Anti-inflammatory agents include allantoin, glycyrrhizinic acid and its salts, glycyrrhetinic acid and stearyl glycyrrhetinate, tranexamic acid, azulene, and the like.

[0084] ·Skin-beautifying ingredients Skin-beautifying ingredients include whitening agents such as placenta extract, arbutin, glutathione, and saxifrage extract; cell activators such as royal jelly, photosensitizers, cholesterol derivatives, and calf blood extract; rough skin improving agents; blood circulation promoters such as nonylic acid valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantharides tincture, ichthammol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, and γ-oryzanol; skin astringents such as zinc oxide and tannic acid; and antiseborrheic agents such as sulfur and thianthrol.

[0085] Vitamins Vitamins include vitamin A oil, retinol, retinol acetate, retinol palmitate, and other vitamin A derivatives; riboflavin, riboflavin butyrate, flavin adenine nucleotide, and other vitamin B2 derivatives; pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine tripalmitate, and other vitamin B6 derivatives; and vitamin B 12and its derivatives, vitamin B 15 and derivatives thereof; vitamin C such as L-ascorbic acid, L-ascorbic acid dipalmitate, sodium L-ascorbic acid-2-sulfate, and dipotassium L-ascorbic acid phosphate diester; vitamin D such as ergocalciferol and cholecalciferol; vitamin E such as α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol nicotinate, and dl-α-tocopherol succinate; nicotinic acids such as nicotinic acid, benzyl nicotinate, and nicotinamide; vitamin H; vitamin P; pantothenic acids such as calcium pantothenate, D-pantothenyl alcohol, pantothenyl ethyl ether, and acetylpantothenyl ethyl ether; and biotin.

[0086] Amino acids Examples of amino acids include glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, and tryptophan.

[0087] ·Nucleic acid Examples of nucleic acids include deoxyribonucleic acid.

[0088] ·hormone Examples of hormones include estradiol and ethenylestradiol.

[0089] ·Inclusion compounds Examples of the inclusion compound include cyclodextrin.

[0090] In the present invention, the formulation or form of the cosmetic is not particularly limited, and examples include powder, liquid, solid, etc. Any of aqueous, oily, water-in-oil emulsion, oil-in-water emulsion, non-aqueous emulsion, and multiple emulsions such as W / O / W and O / W / O may be used. Major formulation forms of the cosmetic according to the present invention include liquid, cream, aerosol, ointment, emulsified solid, stick, emulsified stick, etc.

[0091] The uses of cosmetics are not particularly limited, and examples thereof include skin care cosmetics, hair cosmetics, makeup cosmetics, UV protection cosmetics, antiperspirants, etc. Skin care cosmetics include lotions, emulsions, creams, cleansers, packs, oil liquids, massage products, beauty serums, beauty oils, hand creams, lip balms, and wrinkle-concealing skin care cosmetics. Hair cosmetics include shampoos, rinses, treatments, hair creams, cuticle coats, and setting agents. Makeup cosmetics include makeup bases, concealers, face powders, powder foundations, liquid foundations, cream foundations, oil-based foundations, blushers, eye shadows, mascaras, eyeliners, eyebrow pencils, lipsticks, and nail products. UV protection cosmetics include sunscreen oils, sunscreen emulsions, sunscreen creams, and sunscreen lotions. [Example]

[0092] The present invention will be specifically described below with reference to examples and comparative examples, but the present invention is not limited to the following examples. 1 H-NMR was performed using a Brucker Avance III 400. 29 Si-NMR was measured using an ECX-500 manufactured by JEOL. Purity is the area % of the chromatogram measured by gas chromatography. The kinematic viscosity is the value measured at 25°C using a Cannon-Fenske viscometer according to JIS Z8803:2011. The blending amount listed with the product name is the blending amount of the blended product.

[0093] [Synthesis Example 1] 1,5-diethyl-3-ethyldimethylsiloxy-1,1,3,5,5-pentamethyltrisiloxane In a 1 L four-neck flask, add the following formula (4) [ka] 580 g of an organohydrogenpolysiloxane (100% purity) represented by the formula (I) was added to 0.6 g of a toluene solution containing 0.5% by mass of chloroplatinic acid-vinylsiloxane complex. While stirring at 40-50°C, ethylene gas was blown into the liquid, and the hydrosilylation reaction was carried out while maintaining the temperature at 60-70°C. The reaction was monitored by gas chromatography, and was terminated when it was confirmed that the product ratio had reached 95% or more. Vacuum distillation (oil bath temperature 90-130°C, 1-30 hPa) was carried out, yielding 630 g of a colorless, transparent liquid fraction. The obtained fraction 1 H-NMR and 29 By Si-NMR spectrum analysis, the target compound represented by the following formula (5) was obtained. [ka] It was confirmed that an organopolysiloxane (1,5-diethyl-3-ethyldimethylsiloxy-1,1,3,5,5-pentamethyltrisiloxane) having the structure shown in the formula below was obtained with a purity of 100% and a yield of 83%. The kinematic viscosity was 2.5 mm 2 / s and the boiling point was 113°C / 10 hPa. 1 The H-NMR spectrum chart is shown in Figure 1. 29 The Si-NMR spectrum chart is shown in Figure 2.

[0094] [Synthesis Example 2] 1,5-diethyl-3-trimethylsiloxy-1,1,3,5,5-pentamethyltrisiloxane In a 1 L four-neck flask, add the following formula (6) [ka] 490 g of an organohydrogenpolysiloxane (72% purity) represented by the formula (I) was added to 0.5 g of a toluene solution containing 0.5% by mass of chloroplatinic acid-vinylsiloxane complex. While stirring at 40-50°C, ethylene gas was blown into the liquid, and the hydrosilylation reaction was carried out while maintaining the temperature at 60-70°C. The reaction was monitored by gas chromatography, and was terminated when it was confirmed that the product ratio had reached 95% or more. Distillation under reduced pressure (oil bath temperature 90-130°C, 1-30 hPa) was carried out, yielding 153 g of a colorless, transparent liquid fraction. The resulting fraction 1 H-NMR and 29 By Si-NMR spectrum analysis, the target compound represented by the following formula (7) was obtained. [ka] Organopolysiloxane (1,5-diethyl-3-trimethylsilyl) having the structure shown in Shiro It was confirmed that the resulting product (1,1,3,5,5-pentamethyltrisiloxane) was obtained with a purity of 100% and a yield of 36%. The kinematic viscosity was 2.2 mm. 2 / s and the boiling point was 97°C / 10 hPa.

[0095] [Compatibility and crystallization test with solid oily ingredients at 25℃] The branched organopolysiloxane obtained in Synthesis Example 2 and other organopolysiloxanes were evaluated for compatibility with oily components that are solid at 25°C and for their effect on crystallization using the methods described below. The evaluation results are shown in Table 1.

[0096] (Evaluation method) Each oil component that was solid at 25°C was mixed with the branched organopolysiloxane obtained in Synthesis Example 2 and another organopolysiloxane in a mass ratio of 1:9, heated at 90°C for 20 minutes, and the state of dissolution was visually observed. Evaluation was based on the following criteria. Uniform dissolution:◎ Uniform dispersion:〇 Separation:×

[0097] Each heated mixture was then placed in a jar and left to solidify at 25°C for two days, after which the rheometer hardness of the solid was measured. Measurements were performed using a rheometer RT2002D·D (manufactured by Rheotec Corporation) under the following conditions: Range: 200 g, Adapter: φ3 mm (rod type), Sample stage speed: 5 cm / min, Penetration width: 1 cm. Three measurements were taken each time. The average of the three measurements was calculated. A higher value indicates a harder sample (unit: g).

[0098] [Table 1] KF-96L-1.5cs: Decamethyltetrasiloxane (Shin-Etsu Chemical Co., Ltd.) KF-96L-2cs: Do Decamethylpentasiloxane (Shin-Etsu Chemical Co., Ltd.) K F-995: Decamethylpentasiloxane (Shin-Etsu Chemical Co., Ltd.) KF-4422: Diethyloctamethyltetrasiloxane (Shin-Etsu Chemical Co., Ltd.)

[0099] As shown in Table 1, the branched organopolysiloxane of the present invention was well dissolved or uniformly dispersed in all solid oil components. In particular, when candelilla wax was used, all other silicon compounds separated, whereas the branched organopolysiloxane of the present invention was found to be uniformly dispersed. Furthermore, when polyethylene was used, it was found to have better compatibility than linear dimethylpolysiloxane. Furthermore, it was found that the hybrid composition could be solidified by cooling the heated composition.

[0100] It is generally known that when a hybrid composition is prepared using an oil agent that is highly compatible with solid oil components such as wax, the hardness of the composition that is cooled and solidified after heating and dissolution is reduced, and even if the composition is uniformly dissolved or dispersed during heating, it may be difficult to obtain a sufficient hardness after cooling to obtain a cosmetic composition that has excellent stability over time. It has been revealed that when the branched organopolysiloxane of the present invention is used, it dissolves or disperses well in any solid oil component and has a higher hardness after cooling than other silicon compounds.

[0101] [Compatibility test with ethylhexyl methoxycinnamate] The compatibility of the branched organopolysiloxanes obtained in Synthesis Examples 1 and 2 and other organopolysiloxanes with organic UV absorbers was evaluated by the method described below. The evaluation results are shown in Table 2.

[0102] (Evaluation method) Ethylhexyl methoxycinnamate (sometimes referred to as OMC) and each organopolysiloxane (sometimes referred to as Sx) were collected in the mass ratios shown in Table 2, mixed by shaking at room temperature, and the state of dissolution was observed the next day. The state of dissolution is indicated by ○: dissolved, ×: separated.

[0103] [Table 2] KF-96L-1.5cs: Decamethyltetrasiloxane (Shin-Etsu Chemical Co., Ltd.) KF-96L-2cs: Do Decamethylpentasiloxane (Shin-Etsu Chemical Co., Ltd.) TMF-1.5: Tristrimethylsiloxymethylsilane (Shin-Etsu Chemical Co., Ltd.) KF-995: Decamethylcyclopentasiloxane (Shin-Etsu Chemical Co., Ltd.) D6: Dodecamethylhexasiloxane

[0104] As shown in Table 2, it was revealed that the branched organopolysiloxanes obtained in Synthesis Examples 1 and 2 of the present invention have higher compatibility with ethylhexyl methoxycinnamate than other silicon compounds.

[0105] The present invention will be specifically explained below with reference to formulation examples of cosmetic compositions and comparative examples, but the present invention is not limited to these examples. The blending amounts are shown in % (mass %) unless otherwise specified.

[0106] [Examples 1 and 2, Comparative Examples 1 to 3] W / O type sunscreen W / O type sunscreens were prepared according to the following manufacturing method using the branched organopolysiloxanes obtained in Synthesis Examples 1 and 2 for Examples 1 and 2, but not using them for Comparative Examples 1 to 3. The compositions of Examples 1 and 2 and Comparative Examples 1 to 3 are shown in Table 3.

[0107] [Table 3] (Note 1) Decamethylcyclopentasiloxane (Shin-Etsu Chemical Co., Ltd.) (Note 2) Tristrimethylsiloxymethylsilane (INCI: Methyltrimethicone) (Shin-Etsu Chemical Co., Ltd.) (Note 3) Diphenylsiloxyphenyl trimethicone (Shin-Etsu Chemical Co., Ltd.) (Note 4) A mixture of 70-80% dimethicone and 20-30% (dimethicone / (PEG-10 / 15)) crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 5) A mixture of 80-85% diphenylsiloxyphenyl trimethicone and 15-20% crosslinked phenyl-modified dimethylpolysiloxane (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 6) Cetyl PEG / PPG-10 / 1 Dimethicone (Shin-Etsu Chemical Co., Ltd.)

[0108] [Manufacturing method] Components 1 to 12 were stirred and mixed uniformly. Separately, components 13 to 16 were uniformly dissolved in component 17, and this was gently added to the mixture of components 1 to 12 and stirred to form an emulsion. This was filled into a specified container to obtain a W / O type sunscreen.

[0109] The obtained W / O sunscreens were subjected to a usability test by a panel of 10 women experts, who evaluated (1) texture (lightness), (2) spreadability, (3) film uniformity, and (4) cosmetic film durability based on the following criteria. The results are shown below based on the average scores obtained. In addition, (5) the condition of the cosmetic preparations after leaving them standing at 40°C for one month and (6) the condition of the cosmetic preparations after leaving them standing at 5°C for one month were also observed. The evaluation results are shown in Table 4.

[0110] (Score) 5 points: very good 4 points: Good 3 points: normal 2 points: slightly poor 1 point: Defective (Evaluation criteria) ◎: Average score is 4.5 points or more ○: Average score is 3.5 points or more and less than 4.5 points △: Average score is between 2.5 and 3.5 points ×: Average score is 1.5 points or more but less than 2.5 points ××: Average score is less than 1.5 points

[0111] [Table 4]

[0112] As is clear from Table 4, the sunscreens of Examples 1 and 2 have a lighter feel than Comparative Examples 1 to 3, do not feel oily, spread well, and form a uniform film with high water repellency, demonstrating that they are sunscreens that form a uniform, long-lasting cosmetic film. It was also revealed that these sunscreens have excellent storage stability.

[0113] [Examples 3 and 4, Comparative Examples 4 and 5] Lipstick Stick lipsticks were produced according to the following production method using the branched organopolysiloxanes obtained in Synthesis Examples 1 and 2 for Examples 3 and 4, but not using them for Comparative Examples 4 and 5. The compositions of Examples 3 and 4 and Comparative Examples 4 and 5 are shown in Table 5.

[0114] [Table 5] (Note 1) Decamethylcyclopentasiloxane (Shin-Etsu Chemical Co., Ltd.) (Note 2) Dimethicone (2cs) (Shin-Etsu Chemical Co., Ltd.) (Note 3) 50% trimethylsiloxysilicate dissolved in cyclopentasiloxane (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 4) A mixture of 65-75% triethylhexanoin and 25-35% alkyl-branched, cross-linked dimethylpolysiloxane (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 5) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd.)

[0115] [Manufacturing method] A: Component 13 was mixed with a portion of component 5 and dispersed using a roll mill. The resulting dispersion was then heated and mixed with components 1 to 4, the remainder of component 5, and components 6 to 14 to obtain a composition. B: The mixture obtained in A was poured into a mold and allowed to cool and solidify, yielding a stick-shaped lipstick.

[0116] The resulting lipsticks were subjected to a usability test by a panel of eight female experts based on the following criteria: (1) ease of spreading, (2) film uniformity, and (3) longevity. The results are shown below based on the average scores obtained and the evaluation criteria below. Additionally, (4) the condition of the cosmetics after leaving them at 40°C for one month was also observed. The evaluation results are shown in Table 6.

[0117] (Score) 5 points: very good 4 points: Good 3 points: normal 2 points: slightly poor 1 point: Defective (Evaluation criteria) ◎: The average score obtained is 4.5 points or more ○: The average score obtained is between 3.5 and 4.5 points. △: The average score obtained is between 2.5 and 3.5 points ×: The average score obtained is 1.5 points or more and less than 2.5 points ××: The average score obtained is less than 1.5 points

[0118] [Table 6]

[0119] As is clear from Table 6, the lipsticks of Examples 3 and 4 spread well, formed a uniform film, and had high water repellency, demonstrating that they were lipsticks with long-lasting makeup. They were also found to have excellent storage stability.

[0120] [Example 5] Sunscreen emulsion (shaking) Composition % 1.KF-995 (Note 1) 22.5 2. Siloxane 9 of Synthesis Example 2 3.KSG-18A (Note 2) 3 4.KF-6038 (Note 3) 2 5. Ethylhexyl methoxycinnamate 7.5 6. Diethylaminohydroxybenzoylhexyl benzoate 1 7. Octocrylene 2.5 8. Disteardimonium Hectorite 1 9.KP-545(Note 4) 2 10.KSP-105 (Note 5) 0.5 11.SPD-T5 (Note 6) 5 12.SPD-Z5 (Note 7) 10 13.BG 3 14. Sodium citrate 0.2 15. Sodium chloride 0.5 16. Ethanol 5 17.Wednesday 25.3 Total 100.0

[0121] (Note 1) Cyclopentasiloxane (Shin-Etsu Chemical Co., Ltd.) (Note 2) A mixture of 80-90% diphenylsiloxyphenyl trimethicone and 10-20% (dimethicone / phenylvinyldimethicone) crosspolymer (Shin-Etsu Chemical Co., Ltd.) (Note 3) Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (Shin-Etsu Chemical Co., Ltd.) (Note 4) Dissolved product of 70% cyclopentasiloxane and 30% acrylates / dimethicone copolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 5) (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (Shin-Etsu Chemical Co., Ltd.) (Note 6) Fine particle titanium dioxide 40% cyclopentasiloxane dispersion (Shin-Etsu Chemical Co., Ltd.) (Note 7) Cyclopentasiloxane dispersion of 60% zinc oxide particles (manufactured by Shin-Etsu Chemical Co., Ltd.)

[0122] [Manufacturing method] A: Components 1 to 9 were mixed uniformly. B: Component 10 was added to the mixture obtained in A and dispersed uniformly. C: Components 13 to 16 were added to component 17 and dissolved. D: The mixture obtained in C was gradually added to the mixture obtained in B and emulsified, after which ingredients 11 and 12 were added to obtain a sunscreen emulsion.

[0123] The sunscreen emulsion obtained in this manner spread easily, was light and non-sticky, and showed no change with temperature or time, demonstrating excellent usability and stability.

[0124] [Example 6] Sunscreen cream Composition % 1. Siloxane 30 of Synthesis Example 1 2. Squalane 3 3.KF-6105 (Note 1) 4 4. Ethylhexyl methoxycinnamate 7.5 5. t-Butyl methoxydibenzoylmethane 3 6. Polysilicone-15 1 7. Distearyldimonium Chloride 1 8. Tocopherol acetate 0.1 9. Ethanol 1 10. Sodium citrate 0.5 11. Magnesium sulfate 0.5 12. Preservatives 0.3 13.Wednesday 48.1 Total 100.0 (Note 1) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd.)

[0125] [Manufacturing method] A: Components 1 to 8 were mixed uniformly. B: Components 9 to 12 were dissolved uniformly in component 13. C: With stirring, the mixture obtained in B was gradually added to the mixture obtained in A and emulsified to obtain a sunscreen cream.

[0126] The sunscreen cream obtained in this manner was found to have a fine texture, spread easily, be moist and fresh, and be non-sticky, so it did not attract sand at all and was found to be very easy to use.It was also found to have excellent stability, with no change due to temperature or time.

[0127] [Example 7] Sunscreen cream Composition % 1. Siloxane 16 of Synthesis Example 2 2.KSG-310 (Note 1) 3.5 3.KSG-18A (Note 2) 3 4.KF-6048 (Note 3) 1.5 5.KF-7312J (Note 4) 3 6. Ethylhexyl methoxycinnamate 7.5 7. t-Butyl methoxydibenzoylmethane 3 8. Ethylhexyl Salicylate 3 9.BG 5 10. Sodium citrate 0.5 11. Sodium Chloride 1 12. Preservatives 0.3 13.Wednesday 52.7 Total 100.0

[0128] (Note 1) A mixture of 65-75% mineral oil and 25-35% (PEG-15 / lauryl dimethicone) crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 2) A mixture of 80-90% diphenylsiloxyphenyl trimethicone and 10-20% (dimethicone / phenylvinyldimethicone) crosspolymer (Shin-Etsu Chemical Co., Ltd.) (Note 3) Cetyl PEG / PPG-10 / 1 Dimethicone (Shin-Etsu Chemical Co., Ltd.) (Note 4) 50% trimethylsiloxysilicate dissolved in cyclopentasiloxane (manufactured by Shin-Etsu Chemical Co., Ltd.)

[0129] [Manufacturing method] A: Components 1 to 8 were mixed uniformly. B: Components 9 to 12 were dissolved uniformly in component 13. C: With stirring, the mixture obtained in B was gradually added to the mixture obtained in A and emulsified to obtain a sunscreen cream.

[0130] The sunscreen cream obtained in this way spreads easily, is fresh and not sticky, and has a uniform film with high water repellency, so the makeup lasts well and the UV protection effect lasts. It also shows no change with temperature or time, and is very easy to use and stable.

[0131] [Example 8] Non-aqueous mousse foundation Composition % 1.KSG-240 (Note 1) 18 2.KF-96A-6CS (Note 2) 1 3. Siloxane 11 of Synthesis Example 2 4. Ethylhexyl methoxycinnamate 5 5. Jojoba Oil 1 6. Silylated anhydrous silica (Note 3) 0.75 7.KTP-09R (Note 4) 0.2 8.KTP-09Y (Note 4) 1 9.KTP-09B (Note 4) 0.02 10.KTP-09W (Note 4) 5 11. KF-9909 (Note 5) treated talc 11.55 12.KF-7312J (Note 6) 4 13.KF-995 (Note 7) 25.28 14.KSP-411 (Note 8) 6 15.KМP-590 (Note 9) 3 16. Spherical poly(alkyl methacrylate) 7 17. Antioxidant 0.2 Total 100.0

[0132] (Note 1) A mixture of 75-85% cyclopentasiloxane and 15-25% dimethicone / PEG-10 / 15 crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 2) Dimethicone (6cs) (Shin-Etsu Chemical Co., Ltd.) (Note 3) Surface-hydrophobized fumed silica: Aerosil R-972 (manufactured by Nippon Aerosil Co., Ltd.) (Note 4) KF-9909 treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black (Shin-Etsu Chemical Co., Ltd.) (Note 5) Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone (Shin-Etsu Chemical Co., Ltd.) (Note 6) 50% trimethylsiloxysilicate dissolved in cyclopentasiloxane (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 7) Cyclopentasiloxane (Shin-Etsu Chemical Co., Ltd.) (Note 8) Polysilicone-1 crosspolymer (Shin-Etsu Chemical Co., Ltd.) (Note 9) Polymethylsilsesquioxane (Shin-Etsu Chemical Co., Ltd.)

[0133] [Manufacturing method] Components 1 to 10 were mixed uniformly using a roller. Components 11 to 17 were added to this mixture and mixed until uniform, yielding a non-aqueous mousse-like foundation.

[0134] The foundation obtained in this manner solidified firmly into a mousse-like appearance, spread lightly, and had an excellent feel without stickiness or oiliness, and it was confirmed that the makeup lasted very long. Furthermore, there was no oil seepage due to temperature or time, and the foundation was also excellent in stability.

[0135] [Example 9] Non-aqueous eye wrinkle cream Composition % 1.KSG-210 (Note 1) 5 2.KSG-41A (Note 2) 7 3.KSG-15 (Note 3) 55 4.KF-4422 (Note 4) 8 5. Siloxane 6 of Synthesis Example 1 6. Jojoba Oil 2 7.KSP-101 (Note 5) 12 8.KF-9028 (Note 6) 5 Total 100.0

[0136] (Note 1) A mixture of 70-80% dimethicone and 20-30% (dimethicone / (PEG-10 / 15)) crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 2) A mixture of 70-80% mineral oil and 20-30% vinyl dimethicone / lauryl dimethicone crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 3) A mixture of 90-96% cyclopentasiloxane and 4-10% dimethicone / vinyl dimethicone crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 4) Ethyl methicone (Shin-Etsu Chemical Co., Ltd.) (Note 5) (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (Shin-Etsu Chemical Co., Ltd.) (Note 6) Dimethicone (highly polymerized) 20% dissolved in cyclopentasiloxane (manufactured by Shin-Etsu Chemical Co., Ltd.)

[0137] [Manufacturing method] A: Ingredients 1 to 8 were mixed uniformly to obtain an eye wrinkle cream. The eye wrinkle cream obtained in this manner spreads lightly, is not sticky or oily, gives a moist feel that blends well with the skin, and is also found to have excellent stability, with no change due to temperature or the passage of time.

[0138] [Example 10] Wash-off pack cosmetic Composition % 1.KF-96A-6CS (Note 1) 3 2. Siloxane 3 of Synthesis Example 1 3.KF-6100 (Note 2) 2 4. Kaolin 30 5. Carbomer 0.4 6.BG 10 7. Glycerin 20 8. Preservatives 0.1 9.Fragrance 0.1 10.Wednesday 31.4 Total 100.0

[0139] (Note 1) Dimethicone (6cs) (Shin-Etsu Chemical Co., Ltd.) (Note 2) Polyglyceryl-3 Disiloxane Dimethicone (Shin-Etsu Chemical Co., Ltd.)

[0140] [Manufacturing method] A: Components 1 to 3 and 8 were mixed. B: Components 5 to 7 and 10 were mixed uniformly, and then components 4 and 9 were added and stirred. C: The mixture obtained in A was added to the mixture obtained in B and emulsified to obtain a paste-like wash-off type pack cosmetic.

[0141] The wash-off type pack cosmetic obtained in the above manner spreads easily during application, has excellent cleansing effect, and after rinsing, leaves the skin feeling moist, non-sticky, and smooth, providing an excellent feeling when used, and it was also found to have excellent stability.

[0142] [Example 11] Eye color Composition % 1.TMF-1.5 (Note 1) 25.5 2.KP-550(Note 2) 20 3.KP-561P (Note 3) 2 4.KSP-441 (Note 4) 6 5. Isododecane 3 6. Siloxane 5 of Synthesis Example 2 7. Vaseline 5 8.KSG-320 (Note 5) 5 9. Amorphous anhydrous silica (Note 6) 1 10. Barium sulfate 5 11. Organic pigment 0.2 12.KTP-09Y (Note 7) 1 13.KTP-09W (Note 7) 1 14. KF-9909 (Note 8) Treated Mica Titanium 20 15. Tocopherol 0.2 16.Fragrance 0.1 Total 100.0

[0143] (Note 1) Methyl trimethicone (Shin-Etsu Chemical Co., Ltd.) (Note 2) A solution of 60% isododecane and 40% acrylates / dimethicone copolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 3) (Acrylates / Stearyl Acrylate / Dimethicone Methacrylate) Copolymer (Shin-Etsu Chemical Co., Ltd.) (Note 4) Polysilicone-22 (Shin-Etsu Chemical Co., Ltd.) (Note 5) A mixture of 70-80% isododecane and 20-30% (PEG-15 / lauryl dimethicone) crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 6) Surface-hydrophobized fumed silica: Aerosil R-972 (manufactured by Nippon Aerosil Co., Ltd.) (Note 7) KF-9909 treated colored inorganic pigment, W: white, Y: yellow (Shin-Etsu Chemical Co., Ltd.) (Note 8) Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone (Shin-Etsu Chemical Co., Ltd.)

[0144] [Manufacturing method] A: Components 1 to 9 were mixed and dispersed uniformly. B: Components 10 to 16 were added to the mixture obtained in A and dispersed uniformly to obtain an eye color.

[0145] The eye colors obtained in this manner were easy to remove, spread lightly, and had a texture that was neither oily nor powdery. Furthermore, they were confirmed to have good water resistance, water repellency, and sweat resistance, long-lasting properties, and were resistant to makeup smearing. Furthermore, they were also confirmed to have excellent stability, with no change over time or with temperature changes.

[0146] [Example 12] Eyeliner Composition % 1. Siloxane 22 of Synthesis Example 2 2.KF-96A-6CS (Note 1) 5 3.KSG-42A (Note 2) 5 4. Jojoba Oil 2 5.KF-6038 (Note 3) 3 6. KF-9901 (Note 4) treated black iron oxide 20 7. Ethanol 5 8. Preservatives 0.1 9.Wednesday 37.9 Total 100.0

[0147] (Note 1) Dimethicone (6cs) (Shin-Etsu Chemical Co., Ltd.) (Note 2) A mixture of 75-85% isododecane and 15-25% (vinyl dimethicone / lauryl dimethicone) crosspolymer (Shin-Etsu Chemical Co., Ltd.) (Note 3) Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (Shin-Etsu Chemical Co., Ltd.) (Note 4) Hydrogen Dimethicone (Shin-Etsu Chemical Co., Ltd.)

[0148] [Manufacturing method] A: Components 1 to 5 were mixed under warming, and component 6 was added and dispersed uniformly. B: Components 7 to 9 were dissolved by heating. C: With stirring, the mixture obtained in B was gradually added to the mixture obtained in A and emulsified to obtain an eyeliner.

[0149] The eyeliner obtained in this manner spreads easily, is not oily or powdery, and gives a fresh, light feel when used. It was also found to have good water resistance, water repellency, and sweat resistance, lasts well, is resistant to makeup smudging, and exhibits excellent stability, remaining unchanged over time and with varying temperatures.

[0150] [Example 13] W / O cleansing cream Composition % 1.KF-96A-6CS (Note 1) 10 2.KF-54 (Note 2) 15 3. Mineral oil 8 4. Isostearic acid 1 5. Siloxane 11 of Synthesis Example 1 6. Dextrin fatty acid ester 0.8 7.KF-6017 (Note 3) 4 8. Glycerin 10 9. Sodium citrate 0.2 10. Sodium Chloride 1 11. Preservatives 0.1 12.Fragrance 0.1 13.Purified water 38.8 Total 100.0

[0151] (Note 1) Dimethicone (6cs) manufactured by Shin-Etsu Chemical Co., Ltd. (Note 2) Diphenyl dimethicone, manufactured by Shin-Etsu Chemical Co., Ltd. (Note 3) PEG-10 Dimethicone, manufactured by Shin-Etsu Chemical Co., Ltd.

[0152] A: Components 1 to 7 were mixed under heating. B: Components 8 to 11 and 13 were heated and dissolved. C: With stirring, the mixture obtained in B was gradually added to the mixture obtained in A and emulsified, and after cooling, component 12 was added to obtain a cleansing cream.

[0153] The cleansing cream obtained in this manner had a fine texture, spread easily without stickiness or oiliness, and was moist, fresh, and gave a refreshing feeling when used. It also had a high cleansing effect and was stable, with no change due to temperature or the passage of time.

[0154] [Example 14] Cream lipstick Composition % 1. (Palmitic acid / ethylhexanoic acid) dextrin (Note 1) 9 2. Siloxane 7 of Synthesis Example 2 3.KP-545(Note 2) 5 4.KSG-43 (Note 3) 8 5.KF-6105 (Note 4) 2 6.KF-995 (Note 5) 46 7. 1,3-Butylene Glycol 5 8.Purified water 10.8 9. Colorant 1.2 10. Titanium dioxide coated mica 6 Total 100.0

[0155] (Note 1) Leopearl TT (manufactured by Chiba Flour Mills Co., Ltd.) (Note 2) Dissolved product of 70% cyclopentasiloxane and 30% acrylates / dimethicone copolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 3) A mixture of 65-75% triethylhexanoin and 25-35% (vinyl dimethicone / lauryl dimethicone) crosspolymer (Shin-Etsu Chemical Co., Ltd.) (Note 4) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd.) (Note 5) Cyclopentasiloxane (Shin-Etsu Chemical Co., Ltd.)

[0156] [Manufacturing method] A: Component 9 was mixed with a portion of Component 2 and dispersed using a roller mill, and the resulting dispersion was then heated and mixed with Component 1, the remainder of Component 2, and Components 3 to 6. B: Ingredients 7 and 8 were heated and added to the mixture obtained in A, emulsified, and then cooled. C: Component 10 was added to the emulsion obtained in B to obtain a cream lipstick.

[0157] The resulting creamy lipstick spread easily, was not sticky or oily, and formed a long-lasting film on the lips.

[0158] [Example 15] Mascara Composition % 1.KF-6028 (Note 1) 1 2. Disteardimonium Hectorite 4 3. Isododecane 39.5 4.KP-550(Note 2) 20 5. Palmitic acid / ethylhexanoic acid dextrin (Note 3) 3 6. Ceresin 2.5 7.KP-562P (Note 4) 2 8. Beeswax 2.5 9. Siloxane 5 of Synthesis Example 2 10. Hydrogenated lecithin 0.5 11. Silica 3 12. Talc 12 13.KTP-09B (Note 5) 5 Total 100.0

[0159] (Note 1) Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (Shin-Etsu Chemical Co., Ltd.) (Note 2) A solution of 60% isododecane and 40% acrylates / dimethicone copolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 3) Leopearl TT (manufactured by Chiba Flour Mills Co., Ltd.) (Note 4) (Acrylates / Behenyl Acrylate / Dimethicone Methacrylate) Copolymer (Shin-Etsu Chemical Co., Ltd.) (Note 5) KF-9909 treated colored inorganic pigment, B: Black (Shin-Etsu Chemical Co., Ltd.)

[0160] [Manufacturing method] A: Components 1 to 3 were mixed uniformly. B: Components 4 to 10 were dissolved by heating and stirring, and the mixture obtained in A and pulverized components 11, 12, and 13 were added, mixed uniformly, and then cooled.

[0161] The mascara obtained in this manner was not sticky, spread easily on the eyelashes, and had excellent makeup durability.

[0162] [Example 16] Oil cleansing Composition % 1. Mineral oil 30 2. Isopropyl myristate 2 3. Siloxane of Synthesis Example 1 54.9 4. PEG-6 Diisostearate 1 5. Tocopheryl acetate 0.1 6. PEG-20 Glyceryl Triisostearate 10 7. Glycerin 1 8.Water 1 Total 100.0

[0163] [Manufacturing method] A: Components 1 to 6 were mixed uniformly. B: Ingredients 7 and 8 were stirred to dissolve, and added to the mixture obtained in A and mixed until uniform to obtain an oil cleanser.

[0164] The oil cleanser obtained in this manner was not sticky, formed a uniform oil film that spread easily, and had a very high cleansing effect.

[0165] [Example 17] Deodorant stick Composition % 1. Chlorohydroxy Al 23 2. Siloxane of Synthesis Example 2 36.5 3. Stearyl alcohol 8 4. Talc 14.88 5.Fragrance 0.1 6. BHT 0.02 7. Paraffin (solid) 2 8. Mineral oil 14.5 9.KF-6048 (Note 1) 1 Total 100.0

[0166] (Note 1) Cetyl PEG / PPG-10 / 1 Dimethicone (Shin-Etsu Chemical Co., Ltd.)

[0167] [Manufacturing method] A: Components 2, 3, and 6 to 9 were heated, dissolved, and mixed. B: Components 1 and 4 were mixed uniformly with the mixture obtained in A, and the mixture was dispersed and mixed uniformly using a mixer. C: Component 5 was added to the mixture obtained in B and mixed uniformly. D: The mixture obtained in C was poured into a mold and allowed to cool and solidify.

[0168] The deodorant stick obtained in this manner was free from excessive dryness or stickiness and had excellent durability of deodorizing effect.

[0169] [Example 18] Deodorant spray Composition % 1. Chlorohydroxy Al 30 2. Silica 15 3. Siloxane 10 of Synthesis Example 1 4. KF-9909 (Note 1) Treated Talc 14.88 5.Fragrance 0.1 6. BHT 0.02 7. Zinc Oxide 5 8. Triclosan 0.1 9. Isopropyl myristate 21.9 10.KF-6105 (Note 2) 3 Total 100.0

[0170] (Note 1) Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone (Shin-Etsu Chemical Co., Ltd.) (Note 2) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd.)

[0171] [Manufacturing method] A: Components 2 to 4 and 6 to 10 were mixed uniformly. B: Component 1 was mixed uniformly with the mixture obtained in A, and the mixture was dispersed and mixed uniformly using a mixer. C: Component 5 was added to the mixture obtained in B and mixed uniformly. D: 10 parts by mass of the mixture obtained in C (stock solution component) and 90 parts by mass of LPG were filled into a spray container.

[0172] The deodorant spray obtained in this manner was not excessively dry or sticky and had excellent durability of deodorizing effect.

[0173] [Example 19] Non-aqueous deodorant cream Composition % 1. Trichlorohydrex glycine (Al / Zirconium) 19 2. Siloxane 30 of Synthesis Example 2 3.KSG-15 (Note 1) 21.5 4.KSP-100 (Note 2) 10 5. Neopentyl glycol dioctanoate 9.68 6.Fragrance 0.1 7. BHT 0.02 8. Citric acid 0.1 9. Benzyl alcohol 0.1 10. Silica dimethyl silylate 0.5 11. Polyethylene 3 12. Ceresin 6 Total 100.0

[0174] (Note 1) A mixture of 90-96% cyclopentasiloxane and 4-10% (dimethicone / vinyl dimethicone) crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 2) (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (Shin-Etsu Chemical Co., Ltd.)

[0175] [Manufacturing method] A: Ingredients 2, 3, 5, 7, 9, 11, and 12 were heated and mixed uniformly. B: Component 10 was mixed uniformly with the mixture obtained in A, and the mixture was dispersed and mixed uniformly using a mixer. C: To the mixture obtained in B, ingredients 1, 4, and 8 were added and mixed uniformly. D: Component 6 was added to the mixture obtained in C, and after uniform mixing, the mixture was filled into a container.

[0176] The deodorant cream obtained in this manner was a non-aqueous deodorant cream that spread very smoothly and had good spreadability, was not excessively dry or sticky, and had excellent durability of deodorizing effect.

[0177] [Example 20] W / O deodorant cream Composition % 1.KSG-210 (Note 1) 3 2.KSG-15 (Note 2) 2 3.KF-6028 (Note 3)) 2 4. Ethylhexyl Palmitate 5 5. Isopropylmethylphenol 0.1 6. Chlorohydroxyaluminum 5 7. Benzalkonium chloride 0.1 8. Siloxane 15 of Synthesis Example 1 9. Glycerin 5 10.BG 5 11. Ethanol 5 12. Phenoxyethanol 0.3 13.Wednesday 52.5 Total 100.0

[0178] (Note 1) A mixture of 70-80% dimethicone and 20-30% (dimethicone / (PEG-10 / 15)) crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 2) A mixture of 90-96% cyclopentasiloxane and 4-10% (dimethicone / vinyl dimethicone) crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 3) Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (Shin-Etsu Chemical Co., Ltd.)

[0179] [Manufacturing method] A: Components 1 to 4 and 8 were mixed uniformly. B: Components 5 to 7 were mixed uniformly with the mixture obtained in A, and the mixture was dispersed and mixed uniformly using a mixer. C: Components 9 to 13 were dissolved. D: The mixture obtained in C was added to the mixture obtained in B, emulsified, and then filled into a container.

[0180] The deodorant cream obtained in this manner was a W / O deodorant cream that had a refreshing feel when used, spread very smoothly and had good spreadability, was not excessively dry or sticky upon use, and had excellent durability of deodorizing effect.

[0181] [Example 21] Hair oil Composition % 1. Siloxane 68 of Synthesis Example 2 2. Hydrogenated polyisobutene 10.3 3.KF-7312J (Note 1) 3 4. Dimethiconol 7 5. Diethylhexyl succinate 10 6.KF-9030 (Note 2) 1.5 7. Tocopherol 0.1 8.Fragrance 0.1 Total 100.0

[0182] (Note 1) 50% trimethylsiloxysilicate dissolved in cyclopentasiloxane (manufactured by Shin-Etsu Chemical Co., Ltd.) (Note 2) Dimethicone (gum dissolved product) (Shin-Etsu Chemical Co., Ltd.)

[0183] [Manufacturing method] A: Components 1 to 8 were mixed uniformly to obtain a hair oil. The hair oil obtained in this manner spread easily and gave gloss and smoothness to hair.

[0184] The present invention is not limited to the above-described embodiments, which are merely examples, and anything that has substantially the same configuration as the technical idea described in the claims of the present invention and that provides similar effects is included within the technical scope of the present invention.

Claims

1. A cosmetic comprising one or more branched organopolysiloxanes selected from 1,5-diethyl-3-trimethylsiloxy-1,1,3,5,5-pentamethyltrisiloxane and 1,5-diethyl-3-ethyldimethylsiloxy-1,1,3,5,5-pentamethyltrisiloxane.

2. The cosmetic preparation according to claim 1, further comprising an oily component that is solid at 25°C.

3. 3. The cosmetic according to claim 2, wherein the oily component that is solid at 25°C is one or more selected from polyethylene, ceresin, ozokerite, candelilla wax, beeswax, microcrystalline wax, stearyl alcohol, behenyl alcohol, and cetanol.

4. The cosmetic according to any one of claims 1 to 3, further comprising an organic ultraviolet absorber.

5. The cosmetic according to claim 4, wherein the organic ultraviolet absorber is at least one selected from the group consisting of ethylhexyl methoxycinnamate, diethylaminohydroxybenzoylhexyl benzoate, ethylhexyl salicylate, polysilicone-15, t-butylmethoxydibenzoylmethane, oxybenzone, methylenebisbenzotriazolyltetramethylbutylphenol, bisethylhexyloxyphenol methoxyphenyl triazine, and octocrylene.

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