Water-breaking makeup cosmetics

Abstract

This makeup cosmetic comprises: (A) a crosslinking polyether modified silicone in which silicone chains are crosslinked with polyether chains: 0.1-4 mass%; (B) a UV absorbing agent: 3.5-20 mass%; (C) one or more types selected from cyclic or straight-chain dimethyl polysiloxanes having a kinetic viscosity of 4-100 mm2 / s at 25°C: 1.9 mass% or less; (D) an aqueous component: 40-90 mass%; and (E) a powder: 1-25 mass%. The makeup cosmetic exhibits lightweight feel, good feeling in use, and excellent water-breaking sensation and coating properties.

Description

[Technical Field]

[0001] The present invention relates to a water-releasing makeup cosmetic. [Background technology]

[0002] In the case of makeup cosmetics, organic UV absorbers such as ethylhexyl methoxycinnamate are sometimes used to impart UV protection effects, but these have poor compatibility with silicones, making it difficult to stabilize silicone-based cosmetics that have a light feel.As a result, there has been a problem in that the feel of the cosmetics deteriorates when a high amount of organic UV absorbers is incorporated.

[0003] In recent years, oil-in-water sunscreen cosmetics have been developed that provide a refreshing feel and are easy to use continuously as sunscreen measures in daily life, and that do not have a poor feel due to the incorporation of organic UV absorbers (Patent Document 1: JP 2013-91625 A). However, oil-in-water cosmetics have the problem of low water resistance and being easily removed by exposure to sweat, water, etc.

[0004] On the other hand, it is known that in order to obtain a water-in-oil cosmetic with a fresh feel, a crosslinked polyether-modified silicone can be used to prepare a high-water content, large-particle emulsion, thereby obtaining a cosmetic with a fresh feel when used (Patent Document 2: JP 2001-2521 A). It is also known that by designing such large emulsion particle sizes, it is possible to prepare a water-release type cosmetic.

[0005] Furthermore, technologies for obtaining water-in-oil, water-breaking cosmetics containing UV absorbers are also known (Patent Document 3: JP 2011-219448 A, Patent Document 4: WO 2018 / 221174 A, Patent Document 5: WO 2016 / 204947 A). However, since no research has been conducted on the use of non-volatile dimethicone for stabilization, when crosslinked polyether-modified silicone is incorporated, components such as acrylic silicone are required for stabilization, making it difficult to incorporate high amounts of UV absorbers. Furthermore, when stabilization is performed using crosslinked polyether-modified silicone with alkyl branches instead of crosslinked polyether-modified silicone, there is a problem of a heavy feel to the touch. Furthermore, when a high amount of crosslinked polyether-modified silicone is incorporated for stabilization, the viscosity increases, resulting in a heavy feel to the touch, making it difficult to incorporate powders such as color pigments, which are essential components of makeup cosmetics. When a high amount of dimethicone is added as a compatibilizer to reduce the concentration of UV absorbers, the amount of oil phase increases, and when additional pigments, etc. are added, the amount of water phase decreases, which can make it difficult to design a water-breaking formulation.When UV absorbers are added, a refreshing feel is required, as mentioned above, so there is a need for research into refreshing, water-breaking makeup cosmetics that use cross-linked polyether-modified silicones, rather than stabilization using conventional technology. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] Japanese Patent Application Laid-Open No. 2013-91625 [Patent Document 2] Japanese Patent Application Laid-Open No. 2001-2521 [Patent Document 3] Japanese Patent Application Laid-Open No. 2011-219448 [Patent Document 4] International Publication No. 2018 / 221174 [Patent Document 5] International Publication No. 2016 / 204947 Summary of the Invention [Problem to be solved by the invention]

[0007] The present invention has been made in view of the above circumstances, and aims to provide a makeup cosmetic that has a light feel, a good sensation when used, a water-repellent feeling, and good application properties. Note that in the present invention, a composition for a cosmetic may be referred to as a cosmetic. [Means for solving the problem]

[0008] As a result of extensive research into achieving the above-mentioned object, the present inventors have discovered that a water-releasing makeup cosmetic containing (A) 0.1 to 4 mass% of a crosslinked polyether-modified silicone in which a silicone chain is crosslinked with a polyether chain, (B) 3.5 to 20 mass% of an ultraviolet absorber, (D) 40 to 90 mass% of an aqueous component, and (E) 1 to 25 mass% of a powder has a kinematic viscosity at 25°C of 4 to 100 mm 2 The present inventors have found that the above problems can be solved by limiting the content of one or more cyclic or linear dimethylpolysiloxanes selected from the group consisting of dimethylpolysiloxanes having a molecular weight of 1.9 mass % or less, and have thus completed the present invention.

[0009] Accordingly, the present invention provides the following water-releasing makeup cosmetic. 1. (A) Crosslinked polyether-modified silicone in which silicone chains are crosslinked with polyether chains: 0.1 to 4 mass %; (B) ultraviolet absorber: 3.5 to 20 mass % (C) Kinematic viscosity at 25°C is 4 to 100 mm 2 / s: 1.9 mass% or less of one or more selected from cyclic or linear dimethylpolysiloxanes, (D) aqueous component: 40 to 90% by mass, and (E) Powder: 1~25% by mass A water-releasing makeup cosmetic containing 2. The water-releasing makeup cosmetic according to 1, wherein the total amount of the components (B) and (E) is 4.5 to 45% by mass based on the total amount of the cosmetic. 3. The water-releasing makeup cosmetic according to 1 or 2, wherein the component (A) is a (dimethicone / (PEG-10 / 15)) crosspolymer. 4. A water-releasing makeup cosmetic according to any one of 1 to 3, wherein the component (D) is water, in an amount of 38 to 85% by mass based on the total mass of the cosmetic. 5. The water-releasing makeup cosmetic according to any one of 1 to 4, further comprising 0.1 to 20% by mass of (F) diphenylsiloxyphenyl trimethicone. 6. The water-releasing makeup cosmetic according to any one of items 1 to 5, further comprising (G) ethyl methicone: 0.1 to 20 mass %. 7. The water-releasing makeup cosmetic according to any one of 1 to 6, further comprising 0.1 to 1.0 mass % of (H) a non-crosslinked silicone surfactant. [Effects of the Invention]

[0010] According to the present invention, it is possible to provide a water-releasing makeup cosmetic that has a light feel and a good sensation when used, and has excellent water-releasing properties and spreadability (spreadability). DETAILED DESCRIPTION OF THE INVENTION

[0011] The present invention will be described in detail below. In the present invention, ingredient names may be written in cosmetic name or International Nomenclature of Cosmetic Ingredients (INCI). When the cosmetic name and INCI correspond, the English name may be omitted.

[0012] [Component (A)] The crosslinked polyether-modified silicone (A) of the present invention in which silicone chains are crosslinked with polyether chains (hereinafter sometimes abbreviated as crosslinked polyether-modified silicone) is a linear dimethylpolysiloxane crosslinked with polyether. Specific examples include (Dimethicone / (PEG-10 / 15)) Crosspolymer (INCI: Dimethicone PEG-10 / 15 Crosspolymer), which can be used alone or in combination of two or more. The above-mentioned component (A) is an essential component for achieving both stabilization of the cosmetic composition and a water-repellent feel in the cosmetic composition of the present invention.

[0013] The crosslinked polyether-modified silicone preferably swells with an oil that is liquid at 25°C, at a weight equal to or greater than its own weight. The oil that is liquid at 25°C is preferably an oil other than component (C), described below. Specific examples include phenyl silicones such as diphenylsiloxyphenyl trimethicone; silicones modified with alkyl groups having 2 to 18 carbon atoms, such as ethyl methicone and caprylyl methicone; hydrocarbon oils such as liquid paraffin, squalane, isododecane, and isohexadecane; glyceride oils such as triethylhexanoin; ester oils such as isotridecyl isononanoate, N-acyl glutamate, isodecyl neopentanoate, and lauroyl sarcosinate; and natural animal and vegetable oils such as macadamia nut oil. Among these, diphenylsiloxyphenyl trimethicone is preferred. A specific example of the crosslinked polyether-modified silicone is KSG-270 manufactured by Shin-Etsu Chemical Co., Ltd.

[0014] The blending amount of component (A) is 0.1 to 4 mass % of the total cosmetic, more preferably 0.2 to 3 mass %, even more preferably 0.6 to 2 mass %, and particularly preferably 0.8 to 1.5 mass %.

[0015] [(B) Component] The ultraviolet absorber (B) of the present invention is not particularly limited as long as it is a component normally used in cosmetics, and can be used alone or in combination of two or more. Examples of ultraviolet absorbers include homosalate (INCI), octocrylene (INCI), t-butyl methoxydibenzoylmethane (INCI), ethylhexyl salicylate (INCI), diethylamino hydroxybenzoyl hexyl benzoate (INCI), oxybenzone-6 (INCI: Benzophenone-6), oxybenzone-9 (INCI: Benzophenone-9), oxybenzone-1 (INCI: Benzophenone-1), polysilicone-15 (INCI), and dimethoxybenzylidene dioxoimidazolidine octyl propionate (INCI: Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate, Oxybenzone-2 (INCI: Benzophenone-2), Terephthalylidene Dicamphor Sulfonic Acid (INCI: Terephthalylidene Dicamphor Sulfonic Acid), Ethylhexyl Triazone (INCI), Bis(trimethylsiloxy)silylisopentyl Trimethoxycinnamate Trisiloxane (INCI: Isopentyl Trimethoxycinnamate Trisiloxane), Drometrizole Trisiloxane (INCI), Ethylhexyl Dimethyl PABA (INCI: Ethylhexyl Dimethyl PABA), Isopropyl Methoxycinnamate (INCI: Isopropyl Methoxycinnamate), Ethylhexyl Methoxycinnamate (INCI: Ethylhexyl Methoxycinnamate), Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (INCI: Bis-Ethylhexyloxyphenol MethoxyphenylTriazine), Oxybenzone-3 (INCI: Benzophenone-3), Oxybenzone-4 (INCI: Benzophenone-4), Oxybenzone-5 (INCI: Benzophenone-5), Phenylbenzimidazole Sulfonic Acid (INCI: Phenylbenzimidazole Sulfonic Acid), Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (INCI: Methylene Bis-Benzotriazolyl Tetramethylbutylphenol), Glyceryl Dimethoxycinnamate Ethylhexanoate (INCI: Glyceryl PABA), Diisopropyl Methyl Cinnamate (INCI: Methyl Cinnamate), Cinoxate (INCI), Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate) and others.

[0016] It is also possible to use a UVA absorber (e.g., diethylamino hydroxybenzoyl hexyl benzoate (INCI)) and a UVB absorber (e.g., ethylhexyl methoxycinnamate (INCI)) in combination, and they can also be combined in any desired manner.

[0017] Among these, from the viewpoint of usability, one or more organic ultraviolet absorbers selected from ethylhexyl methoxycinnamate, diethylaminohydroxybenzoylhexyl benzoate, ethylhexyl salicylate, polysilicone-15, t-butylmethoxydibenzoylmethane, oxybenzone, methylenebisbenzotriazolyltetramethylbutylphenol, bisethylhexyloxyphenol methoxyphenyl triazine, homomenthyl salicylate, and octocrylene are preferred.

[0018] The blending amount of component (B) is 3.5 to 20% by mass, more preferably 5 to 20% by mass, even more preferably 6 to 20% by mass, particularly preferably 7 to 12% by mass, and most preferably 7.5 to 12% by mass, based on the total amount of the cosmetic.

[0019] [(C) component] The component (C) of the present invention has a kinematic viscosity at 25°C of 4 to 100 mm 2 / s, preferably 4 to 20 mm 2 The component (C) is a cyclic or linear dimethylpolysiloxane having the formula R / s. Examples of cyclic dimethylpolysiloxanes include cyclopentasiloxane (INCI) and cyclohexasiloxane (INCI), and examples of linear dimethylpolysiloxanes include dimethicone (INCI). Note that component (C) is a cyclic or linear dimethylpolysiloxane having the formula R / s. 2 SiO 2 / 2 is 4 or more, and component (C) is (R 3 SiO 1 / 2 )2(R 2 SiO 2 / 2 )2, (R 3 SiO 1 / 2 )2(R 2 SiO 2 / 2 )3, kinematic viscosity at 25°C is 1.5 to 2 mm 2 / s dimethicone to a dynamic viscosity of 4mm 2 Even if the kinematic viscosity of a mixed oil is less than 1 / s, it is defined as the kinematic viscosity before mixing. In the present invention, the kinematic viscosity refers to a value measured using a Cannon-Fenske viscometer described in JIS Z 8803:2011.

[0020] The blending amount of component (C) is 1.9% by mass or less (0 to 1.9% by mass) of the total cosmetic, preferably 1.0% by mass or less, more preferably less than 1.0% by mass, even more preferably 0.5% by mass or less, and particularly preferably 0% by mass (i.e., no component is present). Component (C) of the present invention is not an essential component but an optional component. Component (C) has poor compatibility with component (B), which affects the stability of the cosmetic. By keeping the blending amount of component (C) less than 1.9% by mass, the cosmetic can be stably emulsified even when the blending amount of component (B) or component (E) described below in the cosmetic is increased. Furthermore, the resulting water-releasing makeup cosmetic has a light feel, a pleasant texture, a water-releasing feel, and excellent application (spreadability). When component (C) is present, the mass ratio of component (C) to component (B), expressed as (C) / (B), is preferably less than 0.5, more preferably less than 0.28, and even more preferably less than 0.15.

[0021] [(D) component] The component (D) of the present invention is an aqueous component having a solubility of 0.01 g / 100 g or more in purified water at 25° C. Specific examples include water, moisturizers, lower alcohols, water-soluble polymeric compounds, skin-beautifying ingredients, water-soluble inorganic salts (pH adjusters, etc.), water-soluble preservatives, etc. These can be used alone or in appropriate combinations of two or more.

[0022] Examples of water include purified water commonly used in cosmetics and distilled water from fruits and plants, as well as seawater (INCI: Sea Water), hot spring water (Onsen-Sui), peat water (INCI: Peat Water), etc., as defined by their labeling names.

[0023] Examples of moisturizing agents include sugar alcohols such as sorbitol (INCI), maltose (INCI), and xylitol (INCI); polyhydric alcohols such as BG (INCI: Butylene Glycol), PG (INCI: Propylene Glycol), pentylene glycol (INCI), 1,10-decanediol (INCI), octanediol (INCI), 1,2-hexanediol (INCI), erythritol (INCI), glycerin (INCI), diglycerin (INCI), and polyethylene glycol; glucose (INCI), glyceryl glucoside (INCI), betaine (INCI), sodium chondroitin sulfate (INCI: Sodium Chondroitin Sulfate), PCA-Na (INCI: Sodium PCA), methyl gluceth-10 (INCI), and methyl gluceth-20 (INCI). The blending amount of the moisturizing agent is preferably 2 to 52% by mass, more preferably 5 to 13% by mass, and even more preferably 7 to 10% by mass of the entire cosmetic. By blending the moisturizing agent, it is possible to improve the emulsion stability of the cosmetic and adjust the water-repellent feeling.

[0024] Examples of lower alcohols (having 5 or less carbon atoms) include ethanol (INCI) and isopropanol (INCI).

[0025] Examples of water-soluble polymer compounds include natural water-soluble polymer compounds such as carrageenan (INCI), sodium hyaluronate (INCI), and xanthan gum (INCI); semi-synthetic water-soluble polymer compounds such as hydroxyethyl cellulose (INCI), hydroxypropyl methyl cellulose (INCI), and carboxymethyl cellulose (INCI); synthetic water-soluble polymer compounds such as polyvinyl alcohol (INCI) and carbomer (INCI); and inorganic water-soluble polymer compounds such as bentonite (INCI) and laponite (INCI).

[0026] Examples of skin-beautifying ingredients include whitening agents such as arbutin (INCI), ascorbic acid and its derivatives; anti-inflammatory agents such as allantoin (INCI), glycyrrhizinate; and blood circulation promoters such as nicotinic acid benzyl ester.

[0027] Examples of water-soluble inorganic salts include sodium chloride (INCI), magnesium sulfate (INCI), sodium citrate (INCI), and other water-soluble inorganic salts, as well as pH adjusters.

[0028] Water-soluble preservatives include methylparaben (INCI), phenoxyethanol (INCI), imidazolidinyl urea (INCI), ethylhexylglycerin (INCI), glyceryl caprylate (INCI), caprylhydroxamic acid (INCI), polyaminopropyl biguanide (INCI), and the like.

[0029] The blending amount of component (D) is 40 to 90% by mass, preferably 50 to 85% by mass, more preferably 60 to 80% by mass, and even more preferably 60 to 70% by mass, of the total cosmetic. By setting the amount of component (D) to 40% by mass or more, the sensation of water-repellency can be enhanced, while setting it to 90% by mass or less further improves stability. The blending amount of water is preferably 38 to 85% by mass, more preferably 45 to 80% by mass, even more preferably 50 to 70% by mass, and particularly preferably 50 to 60% by mass, of the total cosmetic. By setting the amount of water to 38% by mass or more, the sticky feeling can be suppressed, while setting it to 85% by mass or less further improves stability.

[0030] [(E) Powder] Component (E) of the present invention is a powder. Examples of powders include fine particle metal oxide powders, hydrophobically treated color pigments, inorganic powders, metal powders, organic powders, and inorganic-organic composite powders. These can be used alone or in appropriate combinations of two or more. However, those corresponding to component (B) above are excluded.

[0031] ·Fine metal oxide powder The fine particle metal oxide used in the present invention is one or more selected from fine particle titanium oxide (display name (INCI: Titanium Dioxide)), iron-containing titanium oxide, zinc oxide (display name (INCI: Zinc Oxide)), cerium oxide (display name (INCI: Cerium Oxide)), and composites thereof. These metal oxides may be composite powders with other powders. The average primary particle size is preferably 200 nm or less, more preferably 120 nm or less. If the particle size is larger than this, the UV protection function may be reduced and white residue may occur. The average primary particle size can be measured using a transmission electron microscope photograph or the like.

[0032] The above-mentioned fine particle metal oxide may be untreated or may be surface-treated with a known method commonly used in cosmetics, without any particular limitation. For example, inorganic treatments include silica (display name (INCI: Silica)) coating, alumina (display name (INCI: Alumina)) coating, and aluminum hydroxide (display name (INCI: Aluminum Hydroxide)) coating. Organic treatments include silanes or silylating agents such as triethoxycaprylylsilane (display name (INCI: Triethoxycaprylylsilane)), silicone oils such as dimethicone (display name (INCI: Dimethicone)), hydrogen dimethicone (display name (INCI: Hydrogen Dimethicone)), and triethoxysilylethyl polydimethylsiloxyethyl hexyl dimethicone (display name (INCI: Triethoxysilylethyl Polydimethylsiloxyethyl Hexyl Dimethicone)), waxes, paraffins, organic fluorine compounds such as perfluoroalkyl phosphates, surfactants, amino acids such as N-acyl glutamic acid, aluminum stearate (display name (INCI: Aluminum Examples include metallic soaps such as magnesium myristate (labeled as "Magnesium Myristate") and triethoxysilylethyl polydimethylsiloxyethyl hexyl dimethicone (labeled as "Triethoxysilylethyl Polydimethylsiloxyethyl Hexyl Dimethicone"), which exhibits high dispersibility in both silicones and oils, and is therefore used in sunscreens and foundations. Triethoxycaprylylsilane (labeled as "Triethoxycaprylylsilane") and metallic soap treatments are preferred in terms of compatibility with component (B) and component (D), which will be described later. These surface treatments may be used alone or in combination of two or more depending on the purpose.

[0033] These surface-treated fine particle metal oxides are also commercially available. For example, fine particle titanium oxides are commercially available under the trade names STR-100C-LP, STR-100A-LP, STR-100W, STR-100W-LP, STR-100C-LF, and STR-40-LP (manufactured by Sakai Chemical Industry Co., Ltd.), MT-01, MT-05, MT-100Z, MT-100TV, MT-100AQ, MT-150EX, MT-500B, MT-505SAS, MT-700B, MT-014Z, and SMT-500SAS (manufactured by Teika Co., Ltd.), ST-455, ST-455WS, ST-457ECS, and ST-495M (manufactured by Titanium Industries Co., Ltd.). Zinc oxide fine particles are commercially available under the trade names FINEX-50S-LP2, FINEX-30S-LP2, FINEX-50W, FINEX-30W, FINEX-50W-LP2, FINEX-52W-LP2, FINEX-30W-LP2, FINEX-33W-LP2, FINEX-50-LPT, FINEX-25-LPT, FINEX-50S-LPT, FINEX-30S-LPT (manufactured by Sakai Chemical Industry Co., Ltd.), MZ-150, MZ-200, MZ-300, MZ-306X, MZ-500HP, MZ-505T, MZ-506X, MZY-203S, MZY-210M3S, TMZ-HA1, MZX-5080TS (manufactured by Teika Co., Ltd.), and the like.

[0034] Hydrophobic treated color pigments The hydrophobically treated color pigment is not particularly limited as long as it is a pigment that is normally used for coloring cosmetics, and examples thereof include red iron oxide (display name (INCI: Iron Oxides)), yellow iron oxide (display name (INCI: Iron Oxides)), white titanium oxide (display name (INCI: Titanium Dioxide)), black iron oxide (display name (INCI: Iron Oxides)), ultramarines (display name (INCI: Ultramarines)), ferric ferrocyanide (display name (INCI: Ferric Ferrocyanide, Ferric Ammonium Ferrocyanide)), manganese violet (display name (INCI: Manganese Violet)), cobalt titanate (display name (INCI: Cobalt Titanium Oxide)), chromium hydroxide (display name (INCI: Chromium Hydroxide Green)), chromium oxide (display name (INCI: Chromium Oxide)), and the like. Greens), Oxide (Al / Cobalt) (Display name (INCI: Cobalt Aluminum Oxide)), ( Titanium / Titanium Oxide) Calcined Product (Display Name (INCI: Titanium / Titanium Dioxide)), Titanium Oxide (Li / Cobalt) (Display Name (INCI: Lithium Cobalt Titanate)), ( Any of the following can be used: iron oxide / titanium oxide sinter (display name: IRON OXIDE / TITANIUM DIOXIDO SINTER), composites doped with different metals such as iron oxide-doped titanium oxide (display name: INCI: Iron Oxides, Titanium Dioxide), titanium nitride (display name: INCI: Titanium Nitride), ferrous hydroxide (display name: INCI: Iron Hydroxide), inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as ochre, and colored pigments such as lakes of tar-based pigments and lakes of natural pigments.

[0035] The shape of the hydrophobized color pigment may be spherical, approximately spherical, rod-shaped, spindle-shaped, petal-shaped, strip-shaped, irregular, or the like, and there are no particular limitations on its geometric form as long as it is capable of imparting color to cosmetics. From the viewpoint of hiding power, pigments with particle diameters, i.e., volume-average particle diameters (MV values), in the range of 150 to 600 nm are preferred. The volume-average particle diameter can be measured using a TEM or the like. If the particle diameter is less than 150 nm, the hiding power is low, which may result in a decrease in the coloring efficiency of the cosmetic, and if the particle diameter is greater than 600 nm, the feeling during use may be poor.

[0036] Furthermore, the pigment according to the present invention may be partially or completely surface-treated with an inorganic compound such as alumina (display name (INCI: Alumina)), aluminum hydroxide (display name (INCI: Aluminum Hydroxide)), silica (display name (INCI: Silica)), or hydrated silica (display name (INCI: Hydrated Silica)).

[0037] The hydrophobization of the hydrophobized color pigment refers to surface treatment of the color pigment with a hydrophobizing agent. The surface hydrophobizing agent for the color pigment according to the present invention is not particularly limited as long as it can impart hydrophobicity, and examples thereof include silicone treatment agents, waxes, paraffins, organic fluorine compounds such as perfluoroalkyl phosphates, surfactants, amino acids such as N-acyl glutamic acid, and metal soaps such as aluminum stearate (display name (INCI: Aluminum Stearate)) and magnesium myristate (display name (INCI: Magnesium Myristate)).

[0038] Among these, silicone treatment agents are preferably used, and examples thereof include silanes or silylating agents such as triethoxycaprylylsilane (display name (INCI: Triethoxycaprylylsilane)) and trimethoxysilyl dimethicone (display name (INCI: Trimethoxysilyl Dimethicone)), silicone oils such as dimethicone (display name (INCI: Dimethicone)), hydrogen dimethicone (display name (INCI: Hydrogen Dimethicone)), and triethoxysilylethyl polydimethylsiloxyethyl hexyl dimethicone (display name (INCI: Triethoxysilylethyl Polydimethylsiloxyethyl Hexyl Dimethicone)), and (acrylates / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate) copolymer (display name (INCI: Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / Dimethicone Methacrylate) copolymer. Examples of suitable silicone treatment agents include silicone compounds such as Acrylates / Dimethicone Copolymer and Acrylates / Dimethicone Copolymer (labeled as (INCI: Acrylates / Dimethicone Copolymer)). The silicone powder treatment agent described in Japanese Patent No. 3912961 is preferably used, and in particular, Triethoxysilylethyl Polydimethylsiloxyethyl Hexyl Dimethicone (labeled as (INCI: Triethoxysilylethyl Polydimethylsiloxyethyl Hexyl Dimethicone), which is a dimethylpolysiloxane having a triethoxysilyl group, a polydimethylsiloxyethyl group, and a hexyl group in its side chain, is effectively used because it exhibits high affinity even when the dispersion medium used to disperse the highly hydrophobic treated color pigment is a mixture of silicone and hydrocarbon. The above surface hydrophobic treatment agents can be used alone or in combination of two or more.

[0039] Commercially available examples of color pigments that have been subjected to hydrophobic surface treatment include the KTP-09 series, particularly KTP-09W, KTP-09R, KTP-09Y, KTP-09B, etc. (manufactured by Shin-Etsu Chemical Co., Ltd.).

[0040] ·Inorganic powder Inorganic powders include zirconium oxide (display name (INCI: Zirconium Dioxide)), zinc oxide (display name (INCI: Zinc Oxide)), cerium oxide (display name (INCI: Cerium Oxide)), magnesium oxide (display name (INCI: Magnesium Oxide)), barium sulfate (display name (INCI: Barium Sulfate)), calcium sulfate (display name (INCI: Calcium Sulfate)), Magnesium Sulfate (Indication Name (INCI: Magnesium Sulfate)), Calcium Carbonate (Indication Name (INCI: Calcium Carbonate)), Magnesium Carbonate (Indication Name (INCI: Magnesium Carbonate)), Talc (Indication Name (INCI: Talc)), Cleaved Talc (Indication Name (INCI: Talc)), Mica (Indication Name (INCI: Mica)), Kaolin (Indication Name (INCI: Kaolin)), Sericite (Indication Name (INCI: Mica)), Synthetic Fluorphlogopite (Indication Name (INCI: Synthetic Fluorphlogopite)), Biotite (Indication Name (INCI: Biotite)), Potassium Silicate (Indication Name (INCI: Potassium Silicate)), Silica (Indication Name (INCI: Silica)), Fumed Silica, Aluminum Silicate (Indication Name (INCI: Aluminum) Silicate), Magnesium silicate (Indication name (INCI: Magnesium Silicate)), Aluminum / Mg silicate (Indication name (INCI: Magnesium Aluminum Silicate)), Calcium silicate (Indication name (INCI: Calcium Silicate)), Aluminum / Ca / Na silicate (Indication name (INCI: Aluminum Calcium Sodium Silicate)), Lithium / Mg / Na silicate (Indication name (INCI: Lithium Magnesium Sodium Silicate)), Na / Mg silicate (Indication name (INCI: Sodium Magnesium Silicate)), Calcium / Al borosilicate (Indication name (INCI: Calcium Aluminum Borosilicate)), Ca / Na borosilicate (Indication name (INCI: Calcium SodiumExamples of such particles include fine particles made of titanium dioxide (INCI: Titanium Dioxide), ... Furthermore, examples of inorganic colored pearl pigments include pearl agents such as titanium oxide-coated mica, bismuth oxychloride (display name (INCI: Bismuth Oxychloride)), bismuth oxychloride coated with titanium oxide (display name (INCI: Titanium Dioxide)) (display name (INCI: Bismuth Oxychloride)), talc coated with titanium oxide (display name (INCI: Titanium Dioxide)) (display name (INCI: Talc)), fish scale foil, and colored mica coated with titanium oxide (display name (INCI: Titanium Dioxide)), and are not particularly limited.

[0041] ·Metal powder Examples of metal powder include fine metal particles made of aluminum (display name (INCI: Aluminum Powder)), copper (display name (INCI: Copper Powder)), silver (display name (INCI: Silver Powder)), and the like.

[0042] ·Organic powder Examples of organic powders include powders made of silicone, polyamide, polyacrylic acid / acrylic acid ester, polyester, polyethylene, polypropylene, polystyrene, styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, polyurethane, vinyl resin, urea resin, melamine resin, benzoguanamine, polymethylbenzoguanamine, tetrafluoroethylene, polymethyl methacrylate (e.g., polymethyl methacrylate), cellulose, silk, nylon, phenolic resin, epoxy resin, polycarbonate, etc. In particular, examples of silicones include silicone resin particles (specific examples include polymethylsilsesquioxane (labeled as "INCI: Polymethylsilsesquioxane"), commercially available products of which include Shin-Etsu Chemical Co., Ltd.: KMP-590, KMP-591, KMP-592, etc.); silicone rubber powder (specific examples include Shin-Etsu Chemical Co., Ltd.: KMP-597, KMP-598, etc.); silicone resin-coated silicone rubber powder (specific examples include (vinyl dimethicone / methicone silsesquioxane) crosspolymer (labeled as "INCI: Vinyl Dimethicone / Methicone Silsesquioxane Crosspolymer"), commercially available products of which include Shin-Etsu Chemical Co., Ltd.: KSP-100, KSP-101, KSP-102, KSP-105); and (diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) crosspolymer (labeled as "INCI: Diphenyl Dimethicone / Vinyl Diphenyl Dimethicone / Silsesquioxane) crosspolymer (labeled as "INCI: Diphenyl Dimethicone / Vinyl Diphenyl Dimethicone / Silsesquioxane"). Dimethicone / Silsesquioxane Crosspolymer), commercially available products include Shin-Etsu Chemical Co., Ltd.'s KSP-300; Polysilicone-1 Crosspolymer (labeled name (INCI: Polysilicone-1Examples of commercially available products include Polysilicone-22 (labeled as (INCI: Polysilicone-22), a commercially available product is KSP-441 manufactured by Shin-Etsu Chemical Co., Ltd.). The polysilicone may be dispersed in water or oil in advance (specific examples include KM-9729, KM-440, KSG-016F, etc., manufactured by Shin-Etsu Chemical Co., Ltd.). Other examples include metal soaps, and specific examples include powders made of zinc stearate (display name (INCI: Zinc Stearate)), aluminum stearate (display name (INCI: Aluminum Stearate)), calcium stearate (display name (INCI: Calcium Stearate)), magnesium stearate (display name (INCI: Magnesium Stearate)), zinc myristate (display name (INCI: Zinc Myristate)), magnesium myristate (display name (INCI: Magnesium Myristate)), zinc / sodium cetyl phosphate (display name (INCI: Sodium Zinc Cetyl Phosphate)), potassium cetyl phosphate (display name (INCI: Potassium Cetyl Phosphate)), etc. Further, organic dyes and the like can also be mentioned, and specific examples thereof include Red 3, Red 104(1) (display name (INCI: Red 28, Red 28 Lake)), Red 106, Red 201 (display name (INCI: Red 6)), Red 202 (display name (INCI: Red 7)), Red 204, Red 205, Red 220 (display name (INCI: Red 34)), Red 226 (display name (INCI: Red 30)), Red 227 (display name (INCI: Red 33, RED 33 Lake)), Red 228 (display name (INCI: Red 36)), Red 230(1) (display name (INCI: Red 22, Red 22 Lake)), Red 230(2), Red 401, Red 505, Yellow 4 (display name (INCI: Yellow 5)), Yellow 5 (display name (INCI: Yellow 6, Yellow 6 Lake)), Yellow 202(1)(Display name(INCI:Yellow 8)), Yellow 203(Display name(INCI:Yellow 10, Yellow 10 Lake)), Yellow 204(Display name(INCI:Yellow11), Yellow 401 (Indication name (INCI:)), Blue 1 (Indication name (INCI:Blue 1, Blue 1 Lake)), Blue 2, Blue 201, Blue 205 (Indication name (INCI:Blue 4)), Blue 404, Green 3 (Indication name (INCI:Green 3, Green 3 Lake)), Green 201 (Indication name (INCI:Green 5)), Green 202 (Indication name (INCI:Green 6)), Green 204 (Indication name (INCI:Green 8)), Green 205, Orange 201 (Indication name (INCI:Orange 5)), Orange 203 (Indication name (INCI:Pigment Orange 5)), Orange 204, Orange 205 (Indication name (INCI:Orange 4, Orange 4 Lake)), Orange 206 (Indication name (INCI:Orange 10)), Orange 207 (Indication name (INCI:Orange 11), cochineal (labeled name (INCI: Cochineal)), laccaic acid (labeled name (INCI: Laccaic Acid)), safflower red (labeled name (INCI: Carthamus Tinctorius (Safflower) Flower Extract)), purple root extract (labeled name (INCI: Lithospermum Officinale Root Extract)), gardenia yellow, and gardenia blue (labeled name (INCI: Hydrolyzed Gardenia Florida Extract)).

[0043] ·Inorganic / organic composite powder The inorganic-organic composite powder may be, for example, a composite powder in which the surface of an inorganic powder is coated with an organic powder by a known or commonly used method.

[0044] Among these, fine particle metal oxide powders and hydrophobically treated color pigments are particularly preferred. The blending amount of the fine particle metal oxide powder is preferably 1 to 25% by mass, more preferably 3 to 15% by mass, and even more preferably 6 to 10% by mass, based on the total cosmetic. If the blending amount is less than 1% by mass, a sufficient ultraviolet blocking effect may not be obtained. The blending amount of the water-repellent treated color pigment is preferably 1 to 25% by mass, more preferably 3 to 15% by mass, and even more preferably 6 to 10% by mass, based on the total cosmetic. If the blending amount is less than 1% by mass, a sufficient hiding effect or coloring effect may not be obtained.

[0045] When component (E) is blended, the blending amount is 1 to 25% by mass, more preferably 3.0 to 20% by mass, even more preferably 6.0 to 20% by mass, and particularly preferably 12 to 20% by mass, based on the total cosmetic preparation. If the blending amount exceeds 25% by mass, it may be difficult to stabilize the formulation.

[0046] The combined use of component (B) and component (E) makes it possible to achieve both UV protection and concealing effects. Furthermore, when the total amount of component (B) and component (E) is high, a higher UV protection effect is obtained, but formulation design becomes difficult. According to the present invention, even when the blending amount of component (B) and component (E) is higher, a water-releasing cosmetic product with a pleasant feel can be obtained. The total amount of component (B) and component (E) is preferably 4.5 to 45% by mass, more preferably 6.0 to 30% by mass, even more preferably 12 to 30% by mass, and particularly preferably 19 to 30% by mass, based on the total cosmetic product.

[0047] [Component (F)] The component (F) of the present invention is diphenylsiloxy phenyl trimethicone (INCI). A commercially available example is KF-56A manufactured by Shin-Etsu Chemical Co., Ltd.

[0048] When component (F) is blended, the blending amount is preferably 0.1 to 20 mass% of the total cosmetic, more preferably 2.0 to 15 mass%, even more preferably 3 to 12 mass%, and particularly preferably 4 to 10 mass%. Component (F) is preferred because it has excellent compatibility with component (B) and has a light feel.

[0049] [(G) component] The component (G) of the present invention is ethyl methicone (INCI). A commercially available example is KF-4422 manufactured by Shin-Etsu Chemical Co., Ltd.

[0050] The blending amount of component (G) is preferably 0.1 to 20 mass% of the total cosmetic, more preferably 2.0 to 15 mass%, even more preferably 3.0 to 12 mass%, and particularly preferably 4.0 to 10 mass%. Component (G) is preferred because it has good compatibility with component (B) and has an extremely light feel.

[0051] [(H) component] Component (H) of the present invention is a non-crosslinked silicone surfactant in which some of the methyl groups in a linear or branched silicone backbone are substituted with hydrophilic groups such as polyethylene glycol or polyglycerin. Unlike component (A), this silicone surfactant does not crosslink the backbone with hydrophilic groups. Specifically, linear or branched polyoxyethylene-modified organopolysiloxanes, linear or branched polyoxyethylene-polyoxypropylene-modified organopolysiloxanes, linear or branched polyoxyethylene-alkyl-co-modified organopolysiloxanes, linear or branched polyoxyethylene-polyoxypropylene-alkyl-co-modified organopolysiloxanes, linear or branched polyglycerin-modified organopolysiloxanes, linear or branched polyglycerin-alkyl-co-modified organopolysiloxanes, and linear or branched pyrrolidone-modified organopolysiloxanes are preferred. In these surfactants, the content of hydrophilic polyoxyethylene groups, polyoxyethylene polyoxypropylene groups, or polyglycerin residues preferably accounts for 10 to 70% by mass of the molecule. Commercially available surfactants include KF-6011, KF-6013, KF-6043, KF-6017, KF-6028, KF-6038, KF-6048, KF-6100, KF-6104, KF-6105, KF-6106, and KF-6115 manufactured by Shin-Etsu Chemical Co., Ltd. These surfactants can be used alone or in appropriate combinations of two or more.

[0052] For example, the combination of a linear or branched polyoxyethylene-modified organopolysiloxane with a linear or branched polyglycerin-modified organopolysiloxane can further adjust the water-removal feel and stability of the cosmetic. When a linear or branched polyoxyethylene-modified organopolysiloxane is incorporated, the amount is preferably 0.05 to 0.5% by mass, more preferably 0.2 to 0.3% by mass, based on the total cosmetic. If the amount of polyoxyethylene-modified organopolysiloxane exceeds 0.5% by mass, the water-removal feel may be affected, while if it is less than 0.05% by mass, the cosmetic may become unstable. When a linear or branched polyglycerin-modified organopolysiloxane is incorporated, the amount is preferably 0.05 to 1.0% by mass, more preferably 0.1 to 0.6% by mass, based on the total cosmetic.

[0053] More specifically, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (INCI) and Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone (INCI) are preferred in terms of compatibility with component (B), and Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone (INCI) is particularly preferred in terms of its water-removing feel.

[0054] When component (H) is blended, the blending amount is preferably 0.1 to 1.0 mass % of the total cosmetic, more preferably 0.1 to 0.8 mass %, even more preferably 0.2 to 0.8 mass %, and particularly preferably 0.5 to 0.8 mass %.

[0055] The cosmetic composition of the present invention can contain an appropriate amount of optional ingredients other than those described above, provided that the effects of the present invention are not impaired. Examples of such optional ingredients include (1) oily ingredients other than the ingredients (B), (F), and (G), (2) film-forming agents, (3) surfactants other than the ingredient (H), (4) compositions comprising crosslinked organopolysiloxanes other than the ingredient (A) and oils that are liquid at 25°C, and (5) other additives. These can be used alone or in combination of two or more.

[0056] (1) Oily components other than components (B), (F), and (G) Examples of oily components other than components (B), (F), and (G) include silicone oils, hydrocarbon oils, fluorine-based oils, ester oils, natural animal and vegetable oils, and semi-synthetic oils.

[0057] The silicone oil refers to dimethylpolysiloxane and modified silicone oil other than component (C), specifically, silicone oils having a kinematic viscosity of 1.5 to 2 mm at 25°C. 2 Examples of suitable organopolysiloxanes include alkyl-modified silicones such as dimethicone (INCI), trisiloxane (INCI), methyl trimethicone (INCI), ethyl trisiloxane (INCI), and hexyl dimethicone (INCI), long-chain alkyl-modified silicones such as caprylyl methicone (INCI), linear or branched organopolysiloxanes such as phenyl trimethicone (INCI), diphenyl dimethicone (INCI), and tetraphenyl dimethyl disiloxane (INCI), aromatic group-modified silicones such as cyclic organopolysiloxanes such as tetramethyl tetraphenyl cyclotetrasiloxane, amino-modified organopolysiloxanes such as amodimethicone (INCI) and aminopropyl dimethicone (INCI), pyrrolidone-modified organopolysiloxanes such as PCA dimethicone (INCI), pyrrolidone carboxylic acid-modified organopolysiloxanes, amino acid-modified silicones, and fluorine-modified silicones.

[0058] Examples of the hydrocarbon oil include linear and cyclic hydrocarbon oils, etc. Specific examples include isoparaffins such as olefin oligomers (INCI), (C13,14) isoparaffin (INCI), isododecane (INCI), undecane (INCI), dodecane (INCI), isohexadecane (INCI), hydrogenated polyisobutene (INCI), squalane (INCI), mineral oil (INCI), palm alkanes (INCI), and (C13-15) alkanes (INCI).

[0059] Examples of the fluorine-based oil include perfluoropolyether, perfluorodecalin, and perfluorooctane.

[0060] Examples of the ester oil include n-alkyl glycol monoisostearates such as diisobutyl adipate (INCI: Diisobutyl Adipate), dihexyldecyl adipate (display name), diheptylundecyl adipate (INCI: Diheptylundecyl Adipate), and isostearyl isostearate (INCI: Isostearyl Isostearate), isocetyl isostearate (INCI: Isocetyl Isostearate), trimethylolpropane triisostearate (INCI: Trimethylolpropane Triisostearate), glycol diethylhexanoate (INCI: Glycol Diethylhexanoate), cetyl ethylhexanoate (INCI: Cetyl Ethylhexanoate), trimethylolpropane triethylhexanoate (INCI: Trimethylolpropane Triethylhexanoate), and pentaerythrityl tetraethylhexanoate (INCI: Pentaerythrityl Tetraethylhexanoate). Octyldodecyl esters such as Cetyl Ethylhexanoate, Octyldodecyl Stearoyl Stearate (INCI: Octyldodecyl Stearoyl Stearate), Oleyl Oleate (INCI: Oleyl Oleate), Octyldodecyl Oleate (INCI: Octyldodecyl Oleate), Decyl Oleate (INCI: Decyl Oleate), Neopentyl Glycol Dioctanoate (INCI: Neopentyl Glycol Dicaprate), Diisostearyl Malate (INCI: Diisostearyl Malate), Triethyl Citrate (INCI: Triethyl Citrate), Diethylhexyl Succinate (INCI: Diethylhexyl Succinate), Amyl Acetate (INCI: Amyl Acetate), ethyl acetate (INCI: Etyl Acetate), butyl acetate (INCI: ButylAceetate, Isocetyl Stearate (INCI: Isocetyl Stearate), Butyl Stearate (INCI: Butyl Stearate), Diisopropyl Sebacate (INCI: Diisopropyl Sebacate), Diethylhexyl Sebacate (INCI: Diethylhexyl Sebacate), Cetyl Lactate (INCI: Cetyl Lactate), Myristyl Lactate (INCI: Myristyl Lactate), Isononyl Isononanoate (INCI: Isononyl Isononanoate), Isotridecyl Isononanoate (INCI: Isotridecyl Isononanoate), Isopropyl Palmitate (INCI: Isopropyl Palmitate), Ethylhexyl Palmitate (INCI: Ethylhexyl Isopalmitate), Hexyldecyl Palmitate (INCI: Isocetyl Palmitate, Hexyldecyl palmitate, myristates such as cholesteryl hydroxystearate (INCI: Cholesteryl Hydroxystearate), isopropyl myristate (INCI: Isopropyl Myristate), octyldodecyl myristate (INCI: Octyldodecyl Myristate), and myristyl myristate (INCI: Myristyl Myristate), ethylhexyl laurate (INCI: Ethylhexyl Laurate), hexyl laurate (INCI: Hexyl Laurate), dioctyldodecyl lauroyl glutamate (INCI: Dioctyldodecyl Lauroyl Glutamate), and isopropyl lauroyl sarcosinate (INCI: Isopropyl Lauroyl Sarcosinate).

[0061] Among ester oils, glyceride oils include triethylhexanoin (INCI), tri(caprylic / capric)glyceryl (INCI: Caprylic / Capric Triglyceride), cocoglyceryl (INCI), (caprylic / capric / succinic) triglyceride (INCI: Caprylic / Capric / Succinic Triglyceride), (caprylic / capric) glycerides (INCI), etc.

[0062] Examples of the natural animal and vegetable oils and semi-synthetic oils include avocado oil (INCI: Persea Gratissima (Avocado) Oil), linseed oil (INCI: Linum Usitatissimum (Linseed) Seed Oil), almond oil (INCI: Prunus Amygdalus Dulcis (Sweet Almond) Oil), perilla oil (labeled name), olive oil (INCI: Olea Europaea (Olive) Fruit Oil), American nutmeg oil (INCI: Torreya California (California Nutmeg) Oil), Japanese cypress oil (INCI: Cymbopogon Nardus (Citronella) Oil), torreya seed oil (INCI: Torreya Nucifera Seed Oil), apricot kernel oil (INCI: Kyonin Yu), and wheat germ oil (INCI: Triticum Vulgare (Wheat) Germ Oil). Oil), Sesame oil (INCI: Sesamum Indicum (Sesame) Seed Oil), コRice germ oil (INCI: Oryza Sativa (Rice) Germ Oil), Rice bran oil (INCI: Oryza Sativa (Rice) Bran Oil), Camellia sasanqua oil (INCI: Camellia Kissi Seed Oil), Safflower oil (INCI: Carthamus Tinctorius (Safflower) Seed Oil), Soybean oil (INCI: Glycine Soja (Soybean) Oil), Tea seed oil (INCI: Camellia Sinensis Seed Oil), Camellia oil (INCI: Camellia Japonica Seed Oil), Evening primrose oil (INCI: Oenothera Biennis (Evening Primrose) Oil), Rapeseed oil (INCI: Rape Shushi Yu), Corn germ oil (INCI: Zea Mays (Corn) Germ Oil) )waitGerm oil, persic oil (label name), palm oil (INCI: Elaeis Guineensis (Palm) Oil), palm kernel oil (INCI: Elaeis Guineensis (Palm) Kernel Oil), castor oil (INCI: Ricinus Communis (Castor) Seed Oil), sunflower oil (INCI: Helianthus Annuus (Sunflower) Seed Oil), grape seed oil (INCI: Vitis) Vinifera (Grape) Seed Oil), Jojoba Seed Oil (INCI), Macadamia Ternifolia Seed Oil (INCI), Meadowfoam Seed Oil (INCI), Gossypium Herbaceum (Cotton) Seed natural vegetable oils such as coconut oil (INCI: Cocos Nucifera (Coconut) Oil), and peanut oil; natural animal oils such as shark liver oil (INCI: Shark Liver Oil), cod liver oil (INCI: Cod Liver Oil), fish liver oil (INCI: Fish Liver Oil), turtle oil (INCI: Turtle Oil), mink oil (INCI: Mink Oil), and egg yolk oil (INCI: Egg Oil); and semi-synthetic oils and fats such as hydrogenated coconut oil (INCI: Hydrogenated Coconut Oil) and liquid lanolin (INCI).

[0063] Among the above-mentioned components (1), silicone oil, hydrocarbon oil, and ester oil are preferred. As the silicone oil, among these, those having a kinematic viscosity of 1.5 to 2 mm are particularly preferred. 2Dimethicone (INCI), trisiloxane (INCI), and methyl trimethicone (INCI) are preferred because they provide a very light feel when used, and when used, they are preferably added in an amount of 0.1 to 10% by mass, more preferably 1 to 8% by mass, and even more preferably 2 to 8% by mass, based on the total amount of the cosmetic. Commercially available examples include KF-96A-1cs, KF-96L-1.5cs, KF-96L-2cs, and TMF-1.5, manufactured by Shin-Etsu Chemical Co., Ltd.

[0064] As the hydrocarbon oil, isododecane (INCI), undecane (INCI), dodecane (INCI), isohexadecane (INCI), and (C13-15) alkanes (INCI) are particularly preferred.

[0065] Particularly preferred ester oils are triethylhexanone (INCI), isononyl isononanoate (INCI: Isononyl Isononanoate), isotridecyl isononanoate (INCI: Isotridecyl Isononanoate), cetyl ethylhexanoate (INCI: Cetyl Ethylhexanoate), caprylic / capric triglyceride (INCI: Caprylic / Capric Triglyceride), ethylhexyl palmitate (INCI: Ethylhexyl Isopalmitate), and hexyl laurate (INCI: Hexyl Laurate).

[0066] (2) Film-forming agent The film-forming agent is not particularly limited as long as it is a raw material that can normally be incorporated into cosmetics, but specific examples include latexes such as polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl acetate, and alkyl polyacrylates, dextrin, cellulose derivatives such as alkyl cellulose and nitrocellulose, siliconized polysaccharide compounds such as tri(trimethylsiloxy)silylpropylcarbamate pullulan, acrylic-silicone graft copolymers such as (alkyl acrylate / dimethicone) copolymers, silicone resins such as trimethylsiloxysilicate (INCI), silicone-based resins such as silicone-modified polynorbornene and fluorine-modified silicone resins, fluororesins, aromatic hydrocarbon resins, polymer emulsion resins, terpene resins, polybutene, polyisoprene, alkyd resins, polyvinylpyrrolidone-modified polymers, rosin-modified resins, and polyurethanes.

[0067] Among these, silicone-based coating agents are particularly preferred, and among these, tri(trimethylsiloxy)silylpropylcarbamate pullulan (commercially available products dissolved in solvents include TSPL-30-D5 and ID manufactured by Shin-Etsu Chemical Co., Ltd.), (alkyl acrylate / dimethicone) copolymers (commercially available products dissolved in solvents include KP-543, KP-545, KP-549, KP-550, KP-545L, etc. manufactured by Shin-Etsu Chemical Co., Ltd.), and trimethylsiloxysilanes are particularly preferred. Examples of suitable film-forming agents include, but are not limited to, trimethylsiloxysilicate (INCI) (commercially available products dissolved in solvent include KF-7312J and X-21-5250 manufactured by Shin-Etsu Chemical Co., Ltd.), silicone-modified polynorbornene (commercially available products dissolved in solvent include NBN-30-ID manufactured by Shin-Etsu Chemical Co., Ltd.), and organosiloxane graft polyvinyl alcohol polymers. One or more film-forming agents may be used. The amount of this component, if present, is preferably 0.1 to 20% by mass of the total cosmetic composition.

[0068] (3) Surfactants other than component (H) The surfactant may be a nonionic, anionic, cationic, or amphoteric surfactant, but is not particularly limited thereto, and any surfactant used in ordinary cosmetics may be used. Furthermore, when a crosslinked organopolysiloxane such as a partially crosslinked polyether-modified silicone or a partially crosslinked polyglycerin-modified silicone is used, in a composition comprising the crosslinked organopolysiloxane and an oil that is liquid at room temperature, it is preferable that the crosslinked organopolysiloxane swells with the liquid oil in an amount equal to or greater than its own weight.

[0069] Specific examples of crosslinked organopolysiloxanes that have swelled with a liquid oil include KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, KSG-350Z, KSG-710, KSG-810, KSG-820, KSG-830, KSG-840, KSG-820Z, and KSG-850Z, all manufactured by Shin-Etsu Chemical Co., Ltd.

[0070] (4) A composition comprising a crosslinked organopolysiloxane other than component (A) and an oil that is liquid at 25°C In the present invention, a crosslinked organopolysiloxane may be blended. Such crosslinked organopolysiloxanes are not particularly limited as long as they are those typically used in cosmetics, and they can be used alone or in appropriate combinations of two or more. Unlike the powders described above, this crosslinked organopolysiloxane does not have a spherical shape. Furthermore, unlike the surfactants described above, it is a compound that does not have a polyether or polyglycerin structure in its molecular structure. It is an elastomer that exhibits structural viscosity when swollen with the above component (1).

[0071] Specific examples include (dimethicone / vinyl dimethicone crosspolymer) (INCI: Dimethicone / Vinyl Dimethicone Crosspolymer), (dimethicone / phenyl vinyl dimethicone) crosspolymer (INCI: Dimethicone / Phenyl Vinyl Dimethicone Crosspolymer), (vinyl dimethicone / lauryl dimethicone) crosspolymer (INCI: Vinyl Dimethicone / Lauryl Dimethicone Crosspolymer), (lauryl polydimethylsiloxyethyl dimethicone / bis-vinyl dimethicone) crosspolymer (INCI: Lauryl Polydimethylsiloxyethyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer), and the like. These are commercially available as swelling products containing oils that are liquid at room temperature. Specific examples include KSG-15, KSG-1510, KSG-16, KSG-1610, KSG-18A, KSG-19, KSG-41A, KSG-42A, KSG-43, KSG-44, KSG-042Z, KSG-045Z, and KSG-048Z, all manufactured by Shin-Etsu Chemical Co., Ltd. Among these, KSG-18A, which is swollen with diphenylsiloxyphenyl trimethicone, the aforementioned component (F), is particularly preferred. When this component is incorporated, its amount is preferably 0.01 to 30% by mass (solid content) of the entire cosmetic.

[0072] (5) Other additives Other additives include oil-soluble gelling agents, water-soluble thickeners, antiperspirants, preservatives / bactericides, fragrances, antioxidants, chelating agents, cooling agents, anti-inflammatory agents, skin-beautifying ingredients (whitening agents, cell activators, skin roughness improving agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, etc. Note that even if listed below, ingredients that fall under (D) and (E) are excluded.

[0073] Oil-soluble gelling agent Examples of oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate, and zinc myristate; amino acid derivatives such as N-lauroyl-L-glutamic acid and α,γ-di-n-butylamine; dextrin fatty acid esters such as dextrin palmitate, dextrin stearate, and dextrin 2-ethylhexanoate palmitate; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate and fructooligosaccharide 2-ethylhexanoate; benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol; organically modified clay minerals such as disteardimonium hectorite, stearalkonium hectorite, and hectorite; esters that are pastes at 25°C, petrolatum, lanolin, solid waxes, and silicone waxes. The blending amount of the oily gelling agent is preferably 0 to 12% by mass, and more preferably 0 to 8% by mass. Since a stable emulsion can be prepared for the water-releasing cosmetic of the present invention without blending an oil-soluble gelling agent, it is more preferable not to blend an oil-soluble gelling agent.

[0074] Antiperspirant Antiperspirants include aluminum hydroxyhalides such as aluminum chlorohydrate and aluminum allantoin chlorohydrate, aluminum halides such as aluminum chloride, aluminum allantoin salt, tannic acid, persimmon tannin, aluminum potassium sulfate, zinc oxide, zinc paraphenolsulfonate, burnt alum, tetrachloro(Al / zirconium) hydrate, trichlorohydrex glycine(Al / zirconium), etc. Particularly preferred components that exhibit high effectiveness are aluminum hydroxyhalides, aluminum halides, and complexes or mixtures thereof with zirconyl oxyhalides and zirconyl hydroxyhalides (for example, tetrachloro(Al / zirconium) hydrate, trichlorohydrex glycine(Al / zirconium)).

[0075] · Preservatives · Disinfectants Preservatives and disinfectants include benzoic acid, sorbic acid, salicylic acid, isopropylmethylphenol, carbolic acid, parachlormetacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, iodopropynyl butylcarbamate, polylysine, photosensitizers, silver, and plant extracts.

[0076] ·Fragrance Fragrances include natural fragrances and synthetic fragrances. Natural fragrances include plant-based fragrances isolated from flowers, leaves, wood, peels, etc., and animal-based fragrances such as musk and civet. Synthetic fragrances include hydrocarbons such as monoterpenes, alcohols such as aliphatic alcohols and aromatic alcohols, aldehydes such as terpene aldehydes and aromatic aldehydes, ketones such as alicyclic ketones, esters such as terpene esters, lactones, phenols, oxides, nitrogen-containing compounds, acetals, etc.

[0077] Antioxidants Examples of antioxidants include, but are not limited to, carotenoids, ascorbyl stearate, tocopherol, tocopherol acetate, tocopherol, pt-butylphenol, butylhydroxyanisole, dibutylhydroxytoluene, phytic acid, ferulic acid, thiotaurine, hypotaurine, sulfites, erythorbic acid and its salts, chlorogenic acid, epicatechin, epigallocatechin, epigallocatechin gallate, apigenin, campherol, myricetin, and quercetin.

[0078] Chelating agents Examples of the chelating agent include alanine, edetate sodium salt, sodium polyphosphate, sodium metaphosphate, phosphoric acid, and the like.

[0079] · Cooling agent Cooling agents include L-menthol, camphor, menthyl lactate, and the like.

[0080] Vitamins Examples of vitamins include vitamin A oil, vitamin A compounds such as retinol, retinol acetate, and retinol palmitate, vitamin D compounds such as ergocalciferol and cholecalciferol, vitamin E compounds such as α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol nicotinate, and dl-α-tocopherol succinate, vitamin H, and vitamin P.

[0081] Amino acids Examples of amino acids include glycine, valine, leucine, isoleucine, methionine, and tryptophan.

[0082] ·Nucleic acid Examples of nucleic acids include deoxyribonucleic acid.

[0083] ·hormone Examples of hormones include estradiol and ethenylestradiol.

[0084] ·Inclusion compounds Examples of the inclusion compound include cyclodextrin.

[0085] <Cosmetics> The emulsion form of the cosmetic preparation of the present invention may be either a W / O emulsion or an O / W / O emulsion. Water-breaking cosmetics provide a sensation of the internal aqueous phase bursting out when applied to the skin. Water-breaking refers to the phenomenon in which a water-in-oil emulsion is broken by shear force during application, causing the internal aqueous phase to burst out as droplets. Specifically, this sensation can be achieved by stabilizing cosmetics whose emulsion particle diameters, as observed under a microscope, are large or non-uniform. The emulsion particle diameter is preferably 1 to 30 μm, with 1 to 20 μm being the most commonly observed diameter.

[0086] The cosmetic preparation of the present invention can be prepared by various methods. For example, powder may be mixed with the oil phase before emulsification, the emulsion after emulsification, or both. It is preferable to disperse the powder in the oil agent beforehand. Preparation may be performed at room temperature or by heating. There are no particular limitations on the mixing method, and a pulsator, propeller mixer, paddle mixer, disperser, homomixer, roll, Henschel mixer, atomizer, pin mill, or rotation-revolution mixer may be used.

[0087] The cosmetic of the present invention is not limited to any particular makeup cosmetic, and can be applied to a variety of products, such as foundation, makeup base, concealer, blush, lipstick, gloss, mascara, eye shadow, eyeliner, body makeup, and nail cosmetics. Among these, makeup cosmetics containing a high content of coloring pigments, such as foundation and concealer, and makeup cosmetics with sunscreen properties are particularly preferred. The cosmetic of the present invention can be in a variety of forms, such as cream, solid, paste, gel, mousse, and stick. [Example]

[0088] The present invention will be explained in more detail below with reference to examples and comparative examples, but the present invention is not limited to the following examples. Unless otherwise specified, the percentages in the compositions are "mass %" and the ratios are mass ratios. The blend amounts in the tables are the blend amounts of the blended products described.

[0089] [Examples 1 to 4, Comparative Examples 1 to 3] A W / O type makeup base was prepared according to the formulation shown in Table 1.

[0090] [Table 1] (Note 1) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (INCI) 80% + (Dimethicone / (PEG-10 / 15)) Crosspolymer (INCI) 20% mixture (Note 2) Shin-Etsu Chemical Co., Ltd.: Dimethicone (INCI) 75% + Dimethicone / (PEG-10 / 15)) Crosspolymer (INCI) 25% Mixture (Note 3) Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (INCI) (Note 4) Shin-Etsu Chemical Co., Ltd.: Kinematic viscosity at 25°C is 6mm 2 / s Dimethicone (INCI) (Note 5) Shin-Etsu Chemical Co., Ltd.: Kinematic viscosity at 25°C is 2 mm 2 / s Dimethicone (INCI) (Note 6) Shin-Etsu Chemical Co., Ltd.: Hydrophobic treated titanium dioxide (display name)

[0091] (Manufacturing method) Preparation of oil phase: Component 7 was dispersed in component 6, and then components 1 to 5 were mixed uniformly. Preparation of aqueous phase: Ingredients 8 to 10 were mixed uniformly. The water phase was gently added to the oil phase to effect phase transition and emulsification to obtain a makeup base.

[0092] The obtained W / O type makeup bases were evaluated according to the following criteria for (1) emulsification, (2) feel (non-stickiness), (3) water-repellent properties, and (4) application properties (ease of spreading the cosmetic and its staying power). The evaluation results are shown in Table 2.

[0093] [Emulsification possible] The state during transfer of the aqueous phase to the oil phase and the state during emulsification were observed and evaluated according to the following criteria. ◎: Phase transfer and emulsification are possible (standard). ○: Both phase transfer and emulsification are possible, but phase transfer takes 10 to 20% more time than standard. △: Both phase transfer and emulsification are possible, but the phase transfer takes 10 to 20% more time than the standard, and a small amount of water droplets remain on the surface of the emulsion (water droplet amount is less than 0.1% by mass). ×: Phase transfer is possible, but 0.1% by mass or more but less than 2% by mass of the aqueous phase is discharged during emulsification. XX: The water phase does not enter the oil phase, or 2% by mass or more of the water phase is discharged during emulsification. A grade of "△" or higher was considered a pass.

[0094] [Characteristics evaluation] The obtained cosmetics were evaluated by 10 expert panelists in terms of usability (non-stickiness), water-repellent feel, and application ease according to the evaluation criteria shown below. The results were judged based on the average of the 10 panelists' ratings and in accordance with the following criteria. However, cosmetics that could not be phase-transferred or emulsified were marked with a "-" because they could not be evaluated.

[0095] [Evaluation criteria] 5 points: very good 4 points: Good 3 points: Average 2 points: slightly poor 1 point: Defective The average score obtained was evaluated according to the following criteria. [Average score criteria] Average score obtained is 4.5 points or higher ◎ The average score obtained is between 3.5 and 4.5 points. The average score obtained is between 2.5 and 3.5 points. The average score obtained is between 1.5 and 2.5 points × The average score obtained is less than 1.5 points ×× A score of "○" or above was considered a pass.

[0096] [Table 2]

[0097] As is clear from Table 2, it was confirmed that the W / O type makeup bases of Examples 1 to 4 had good usability, water-repellent feel, and application properties. て Furthermore, it was confirmed that the blending amount of component (C) is important for emulsion stabilization of the cosmetic preparation of the present invention.

[0098] [Example 5, Comparative Examples 4 and 5]

[0099] [Table 3] (Note 1) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (INCI) 80% + Dimethicone / (PEG-10 / 15) Crosspolymer (INCI) 20% mixture (Note 2) Shin-Etsu Chemical Co., Ltd.: Kinematic viscosity at 25°C is 6mm 2 / s Dimethicone (INCI) 75% + (Dimethicone / (PEG-10 / 15)) Crosspolymer (INCI) 25% Mixture (Note 3) Shin-Etsu Chemical Co., Ltd.: A mixture of 85% diphenylsiloxyphenyl trimethicone (INCI) and 15% dimethicone / phenylvinyldimethicone crosspolymer (INCI). (Note 4) Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (INCI) (Note 5) Shin-Etsu Chemical Co., Ltd.: Kinematic viscosity at 25°C is 2 mm 2 / s Dimethicone (INCI) (Note 6) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (INCI) (Note 7) Shin-Etsu Chemical Co., Ltd.: Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone (INCI) (Note 8) Shin-Etsu Chemical Co., Ltd.: Hydrophobic treated titanium dioxide (display name) (Note 9) Shin-Etsu Chemical Co., Ltd.: Hydrophobic treated iron oxide (display name) (Note 10) Shin-Etsu Chemical Co., Ltd.: AES-3083 treatment (Manufacturing method) Preparation of oil phase: Components 1 to 6 were mixed uniformly. Preparation of aqueous phase: Ingredients 14 to 17 were mixed uniformly. Preparation of paste phase: Components 9 to 13 were mixed in Components 7 and 8, and the mixture was dispersed using a three-roll mill. The water phase was gently added to the oil phase to transfer the phases, and after emulsification, the paste was mixed to obtain a foundation. The obtained foundation was evaluated in the same manner as above. The results are also shown in the table.

[0100] [Table 4]

[0101] As is clear from Table 4, it was confirmed that the W / O type foundation of Example 5 had a good feel in use, water-repellent feel, and easy application. In addition, it was difficult to prepare the foundations of Comparative Examples 4 and 5 as cosmetics.

[0102] [Example 6] W / O type concealer <Preparation of cosmetics> A: Components 8 to 13 were dispersed in a three-roll mill. B: Components 1 to 7 were mixed uniformly. C: Ingredients 16 to 21 were mixed uniformly. D: C was added to B and emulsified, and then A and components 14 and 15 were added and mixed to obtain a W / O type concealer. Component Mass (%) 1.KSG-270 (Note 1) 5 2.KSG-18A (Note 2) 1 3.KF-6038 (Note 3) 0.5 4. Homosalate 3.5 5. (C13-15) Alkanes 6.5 6. Cetyl ethylhexanoate 3 7. Caprylic / Capric Triglyceride 2 8. Isotridecyl isononanoate 3 9.KP-578(Note 4) 0.5 10.KTP-09W (Note 5) 13 11.KTP-09R (Note 5) 0.7 12.KTP-09Y (Note 5) 1.2 13.KTP-09B (Note 5) 0.1 14.KSP-300 (Note 6) 6 15.KMP-590 (Note 7) 4 16. Sorbitol 3 17. Pentylene Glycol 2 18.BG 5 19. Sodium citrate 0.2 20.Mg sulfate 1 21. Water Remnants Total 100 (C) Ingredient amount: 0 (%) (Note 1) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (INCI) 80% + (Dimethicone / (PEG-10 / 15)) Crosspolymer (INCI) 20% mixture (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 85% diphenylsiloxyphenyl trimethicone (INCI) and 15% dimethicone / phenylvinyldimethicone crosspolymer (INCI). (Note 3) Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (INCI) (Note 4) Shin-Etsu Chemical Co., Ltd.: (Acrylates / Ethylhexyl Acrylate / Dimethicone Methacrylate Copolymer) (INCI: Acrylates / Ethylhexyl Acrylate / Dimethicone Methacrylate Copolymer) (Note 5) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black (Note 6) Shin-Etsu Chemical Co., Ltd.: (Diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) crosspolymer (INCI) (Note 7) Polymethylsilsesquioxane (INCI) manufactured by Shin-Etsu Chemical Co., Ltd. The obtained W / O type concealer had a good feel when used, a water-repellent feel, and good application properties.

[0103] [Example 7] W / O type cheek <Preparation of cosmetics> A: Components 7 to 14 were dispersed in a three-roll mill. B: Components 1 to 6 were mixed uniformly. C: Ingredients 16 to 21 were mixed uniformly. D: C was added to B and emulsified, and then A and component 15 were added to obtain a W / O type blush. Component Mass (%) 1.KSG-270 (Note 1) 5 2.KSG-18A (Note 2) 2 3.KF-6038 (Note 3) 0.1 4. Ethylhexyl methoxycinnamate 5 5.KF-4422 (Note 4) 2 6.KF-96L-2cs (Note 5) 8 7. Mica 0.3 8. Red 202 0.1 9. Yellow 4 0.3 10. KP-574 treated titanium dioxide (Note 6) 0.8 11. KP-574 treated black iron oxide (Note 6) 0.06 12. Red 201 0.04 13. KP-574 treated red iron oxide (Note 6) 0.2 14. Polyglyceryl-2 Triisostearate 1.2 15.KSP-441 (Note 7) 1.5 16. Glycerin 3 17. 1,2-Hexanediol 2 18.DPG 8 19. Sodium citrate 0.2 20. Sodium Chloride 1 21. Water Remnants Total 100 (C) Ingredient amount: 0 (%) (Note 1) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (INCI) 80% + (Dimethicone / (PEG-10 / 15)) Crosspolymer (INCI) 20% mixture (Note 2) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (INCI) 85% + Dimethicone / Phenylvinyldimethicone Crosspolymer (INCI) 15% mixture (Note 3) Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (INCI) (Note 4) Shin-Etsu Chemical Co., Ltd.: Ethyl methicone (INCI) (Note 5) Shin-Etsu Chemical Co., Ltd.: Kinematic viscosity at 25°C is 2 mm 2 / s Dimethicone (INCI) (Note 6) Shin-Etsu Chemical Co., Ltd.: (Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / Dimethicone Methacrylate) Copolymer (INCI: Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / Dimethicone Methacrylate Copolymer) (Note 7) Shin-Etsu Chemical Co., Ltd.: (Vinyl Dimethicone / Methicone Silsesquioxane) Crosspolymer (INCI) The obtained W / O type blush had a good feel when used, a water-repellent feel, and good application properties.

[0104] [Example 8] W / O type pourable foundation <Preparation of cosmetics> A: Components 11 to 16 were dispersed in a three-roll mill. B: Components 1 to 10 were mixed uniformly at 90°C. C: Ingredients 17 to 22 were mixed uniformly at 90°C. D: C was added to B and emulsified, and the mixture was filled into a specified container to obtain a W / O type pourable foundation. Component Mass (%) 1.KSG-270 (Note 1) 3 2.KSG-042Z (Note 2) 1 3.KF-6048 (Note 3) 0.3 4. Ethylhexyl methoxycinnamate 7 5. Octocrylene 5 6. Diethylaminohydroxybenzoylhexyl benzoate 3 7. Ethylhexyl Salicylate 5 8.KF-4422 (Note 4) 3 9. Hexyl Laurate 8 10. Ceresin 5 11. Ethylhexyl Palmitate 2 12. Alkylsilane-treated titanium dioxide (Note 5) 5 13. Alkylsilane-treated red iron oxide (Note 5) 0.2 14. Alkylsilane-treated yellow iron oxide (Note 5) 0.7 15. Alkylsilane-treated black iron oxide (Note 5) 0.1 16.KF-6115 (Note 6) 0.2 17. Diglycerin 1 18. Ethylhexylglycerin 0.1 19.BG 8 20. Sodium citrate 0.2 21. Sodium Chloride 1 22. Water Remnants Total 100 (C) Ingredient amount: 0 (%) (Note 1) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (INCI) 80% + (Dimethicone / (PEG-10 / 15)) Crosspolymer (INCI) 20% mixture (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 20% lauryl polydimethylsiloxyethyl dimethicone / bisvinyl dimethicone crosspolymer and 80% isododecane (INCI). (Note 3) Shin-Etsu Chemical Co., Ltd.: Cetyl PEG / PPG-10 / 1 Dimethicone (INCI) (Note 4) Shin-Etsu Chemical Co., Ltd.: Ethyl methicone (INCI) (Note 5) Shin-Etsu Chemical Co., Ltd.: AES-3083 treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black (Note 6) Shin-Etsu Chemical Co., Ltd.: Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone (INCI) The obtained W / O type pour foundation had a good feel when used, a water-repellent feel, and good application properties.

[0105] [Example 9] W / O type stick foundation <Preparation of cosmetics> A: Components 11 to 16 were dispersed in a three-roll mill. B: Components 1 to 10 were mixed uniformly at 90°C. C: Ingredients 17 to 22 were mixed uniformly at 90°C. D: C was added to B and emulsified, and the emulsified mixture was filled into a specified container to obtain a W / O type stick foundation. Component Mass (%) 1.KSG-270 (Note 1) 3 2.KSG-18A (Note 2) 1 3.KF-6048 (Note 3) 0.5 4. Ethylhexyl Salicylate 3 5. Bis-ethylhexyloxyphenol methoxyphenyl triazine 2 6. Caprylic / Capric Triglyceride 5 7.KF-4422 (Note 4) 2 8.KF-96L-1.5cs 5 9. Synthetic Wax 6 10. Microcrystalline wax 2 11. Cetyl ethylhexanoate 5 12.KTP-09W (Note 5) 13 13.KTP-09R (Note 5) 0.7 14.KTP-09Y (Note 5) 1.2 15.KTP-09B (Note 5) 0.1 16.KF-6115 (Note 6) 0.5 17. Betaine 1 18. Methylparaben 0.1 19.BG 8 20. Sodium citrate 0.2 21. Sodium Chloride 1 22. Water Remnants Total 100 (C) Ingredient amount: 0 (%) (Note 1) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (INCI) 80% + (Dimethicone / (PEG-10 / 15)) Crosspolymer (INCI) 20% mixture (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 85% diphenylsiloxyphenyl trimethicone (INCI) and 15% dimethicone / phenylvinyldimethicone crosspolymer (INCI). (Note 3) Shin-Etsu Chemical Co., Ltd.: Cetyl PEG / PPG-10 / 1 Dimethicone (INCI) (Note 4) Shin-Etsu Chemical Co., Ltd.: Ethyl methicone (INCI) (Note 5) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black (Note 6) Shin-Etsu Chemical Co., Ltd.: Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone (INCI) The obtained W / O type stick foundation had a good feel when used, a water-repellent feel, and good application properties.

[0106] [Example 10] W / O type foundation <Preparation of cosmetics> A: Components 7 to 12 were dispersed in a three-roll mill. B: Components 1 to 6 were mixed uniformly. C: Components 14 to 19 were mixed uniformly. D: C was added to B and emulsified, and then A and ingredient 13 were added to obtain a W / O type foundation. Component Mass (%) 1.KSG-270 (Note 1) 5 2.KSG-18A (Note 2) 2 3.KF-6038 (Note 3) 0.3 4. Ethylhexyl methoxycinnamate 5 5. Diethylaminohydroxybenzoylhexyl benzoate 2.5 6.TMF-1.5 (Note 4) 9 7. Isononyl isononanoate 2 8. KF-9901 treated titanium dioxide (Note 5) 8.5 9. KF-9901 treated red iron oxide (Note 5) 0.4 10. KF-9901 treated yellow iron oxide (Note 5) 1 11. KF-9901 treated black iron oxide (Note 5) 0.1 12.KP-578(Note 6) 0.3 13.KSP-105 (Note 7) 2 14. Glycerin 3 15. Phenoxyethanol 0.3 16.BG 5 17. Sodium citrate 0.2 18. Sodium Chloride 1 19. Water Remnants Total 100 (C) Ingredient amount: 0 (%) (Note 1) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (INCI) 80% + (Dimethicone / (PEG-10 / 15)) Crosspolymer (INCI) 20% mixture (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 85% diphenylsiloxyphenyl trimethicone (INCI) and 15% dimethicone / phenylvinyldimethicone crosspolymer (INCI). (Note 3) Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (INCI) (Note 4) Shin-Etsu Chemical Co., Ltd.: Methyl trimethicone (INCI) (Note 5) Shin-Etsu Chemical Co., Ltd.: Hydrogen Dimethicone (INCI) (Note 6) Shin-Etsu Chemical Co., Ltd.: (Acrylates / Ethylhexyl Acrylate / Dimethicone Methacrylate) Copolymer (INCI) (Note 7) Shin-Etsu Chemical Co., Ltd.: (Vinyl Dimethicone / Methicone Silsesquioxane) Crosspolymer (INCI) The obtained W / O type foundation had a good feel when used, a water-repellent feel, and good application properties.

[0107] [Example 11] W / O type foundation <Preparation of cosmetics> A: Components 8 to 15 were dispersed in a three-roll mill. B: Components 1 to 7 were mixed uniformly. C: Ingredients 16 to 21 were mixed uniformly. D: C was added to B and emulsified to obtain a W / O type foundation. Component Mass (%) 1.KSG-270 (Note 1) 5 2.KSG-42A (Note 2) 1 3.KF-6048 (Note 3) 0.3 4. Octocrylene 5 5. Diethylaminohydroxybenzoylhexyl benzoate 2 6. Ethylhexyl salicylate 5 7.KF-4422 (Note 4) 8 8. Ethylhexyl Palmitate 5 9.KTP-09W(Note 5 5 10.KTP-09R (Note 5) 0.2 11.KTP-09Y (Note 5) 0.7 12.KTP-09B (Note 5) 0.1 13.KF-6115 (Note 6) 0.5 14. Metal soap treated titanium dioxide particles 2 15. Silicone-treated zinc oxide particles 4 16. Glycerin 2 17. Ethanol 5 18.BG 5 19. Sodium citrate 0.2 20.Mg sulfate 1 21. Water Remnants Total 100 (C) Ingredient amount: 0 (%) (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 80% diphenylsiloxyphenyl trimethicone (INCI) and 20% dimethicone / PEG-10 / 15 crosspolymer (INCI). (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 20% vinyl dimethicone / lauryl dimethicone crosspolymer (INCI) and 80% isododecane (INCI). (Note 3) Shin-Etsu Chemical Co., Ltd.: Cetyl PEG / PPG-10 / 1 Dimethicone (INCI) (Note 4) Shin-Etsu Chemical Co., Ltd.: Ethyl methicone (INCI) (Note 5) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black (Note 6) Shin-Etsu Chemical Co., Ltd.: Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone (INCI) The obtained W / O type foundation had a good feel when used, a water-repellent feel, and good application properties.

Claims

1. (A) (Dimethicone / (PEG-10 / 15)) crosspolymer: 0.1 to 4% by mass, (B) ultraviolet absorber: 3.5 to 20 mass %, (C) A kinematic viscosity at 25°C of 4 to 100 mm 2 / s: 1.9 mass% or less of one or more selected from cyclic or linear dimethylpolysiloxanes, (D) aqueous component: 40 to 90% by mass, and (E) Powder: 1 to 25% by mass A water-releasing makeup cosmetic containing the above as an essential ingredient.

2. (A) (Dimethicone / (PEG-10 / 15)) crosspolymer: 0.1 to 4% by mass, (B) ultraviolet absorber: 3.5 to 20 mass %, (D) aqueous component: 40 to 90% by mass, and (E) Powder: 1 to 25% by mass and does not contain (C) one or more cyclic or linear dimethylpolysiloxanes having a kinematic viscosity at 25° C. of 4 to 100 mm 2 / s.

3. 3. The water-releasing makeup cosmetic according to claim 1, wherein the total amount of the components (B) and (E) is 4.5 to 45% by mass based on the total amount of the cosmetic.

4. 4. The water-releasing cosmetic makeup according to claim 1, further comprising a component (C), wherein the mass ratio of component (C) to component (B), represented by (C) / (B), is less than 0.

5.

5. 5. The water-releasing makeup cosmetic according to claim 1, wherein the component (D) is water in an amount of 38 to 85% by mass based on the total mass of the cosmetic.

6. The water-releasing cosmetic makeup according to any one of claims 1 to 5, further comprising 0.1 to 20% by mass of (F) diphenylsiloxyphenyl trimethicone.

7. 7. The water-releasing cosmetic makeup according to claim 1, further comprising 0.1 to 20% by mass of (G) ethyl methicone.

8. 8. The water-releasing cosmetic makeup according to claim 1, further comprising: (H) a non-crosslinked silicone surfactant: 0.1 to 1.0% by mass.

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