Method for recycling blended textiles containing cellulose and synthetic plastics

Abstract

A method for recycling a blended fabric (110), the method comprising: i) providing (52) a blended fabric (110), the blended fabric (110) containing cellulose fibers and synthetic fibers, the synthetic fibers containing at least one synthetic plastic; ii) at least partially depleting (54) the synthetic plastic from the cellulose; and iii) further processing (58) the depleted blended fabric (60) after depletion. [Figure 1]

Description

[Technical Field]

[0001] The present invention relates to a method for recycling blended textiles and regenerated cellulose moldings produced from the blended textiles by further processing.

[0002] The present invention relates to the technical field of reuse, in particular the reuse of blended textiles containing cellulose and at least one synthetic plastic, and further to the reuse of blended textiles for the production of regenerated cellulose moldings, in particular regenerated cellulose moldings in which the cellulose of the moldings is substantially present in the form of lyocell and / or viscose fibers. [Background technology]

[0003] Chemical and regenerated fibers produced by the wet spinning process known as the viscose process are referred to as viscose fibers. The starting material for the viscose process is cellulose, which is derived from wood. From this starting material, very pure cellulose is obtained in the form of chemical pulp. In a subsequent process step, the pulp is first treated with caustic soda to form alkali cellulose. Subsequent conversion of the alkali cellulose with carbon disulfide forms cellulose xanthate. By adding additional caustic soda, a viscose spinning solution is produced from the cellulose xanthate, which is then pumped through the holes of a shower-like spinning nozzle into a spinning bath. In the spinning bath, one viscose filament is produced per spinning nozzle hole by coagulation. The viscose filaments thus produced are then chopped into viscose staple fibers.

[0004] Lyocell refers to a type of regenerated fiber containing cellulose and is produced according to the direct solvent method. The cellulose for the Lyocell process is extracted from wood as a raw material. The pulp thus obtained can then be dissolved in the solvent N-methylmorpholine-N-oxide (NMMO) by dehydration without chemical modification, filtered, and then forced through a spinning nozzle. The filaments thus formed, after passing through an air gap, are precipitated in a bath with an aqueous NMMO solution and then chopped into staple fibers.

[0005] When using recycled materials as raw materials for cellulose production, the purity of the starting materials often becomes an issue. They are often contaminated with materials that are not typical for wood. In particular, for example, currently used textiles and / or residues from clothing manufacturing are highly contaminated with plastics. On the one hand, this is because the residues from used textiles and / or clothing manufacturing consist of plastics. On the other hand, this is because many old textiles today, which are primarily made from natural fibers such as cellulose, are partially contaminated with plastics. These plastics are, for example, elastane in elastic bands or polyester in sewing threads. In this context, textiles containing both cellulose and synthetic plastics can be referred to as blended textiles.

[0006] Conventionally, when recycling starting materials such as old textiles, especially blended textiles, attempts are made to remove all possible additives and foreign substances through complex process steps in order to provide as pure cellulose as possible as a "new" raw material. These process steps include, for example, bleaching, chemical separation, and mechanical separation. These process steps are often costly and laborious. On the other hand, methods are known for recovering synthetic plastics, such as polyethylene terephthalate (PET), as raw materials. In this context, processes in which cellulose is depleted or destroyed are mainly used. For example, WO 2014045062 A1 describes a method for extracting polyester from objects using a solvent system.

[0007] For example, recycled materials (starting materials) can be used to produce cellulose for use in recycling processes using the lyocell or viscose processes. When processing these starting materials, such as blended textiles, closing the material cycle generates various undesirable foreign substances that must be removed in the production of recycled bodies, such as fibers. This is especially so that the chemical and physical properties of the recycled fibers are sufficiently similar to those of non-regenerated fibers. Summary of the Invention [Problem to be solved by the invention]

[0008] It is an object of the present invention to recycle blended textiles in a resource-saving and sustainable manner so that shaped bodies with specific properties can be produced.

[0009] This object is solved by the subject matter of the independent patent claims. Preferred embodiments arise from the dependent patent claims. [Means for solving the problem]

[0010] According to one aspect of the present invention, a method for recycling a blended textile is described, comprising: i) providing a blended textile, the blended textile containing cellulose fibers and synthetic fibers, the synthetic fibers containing at least one synthetic plastic, ii) at least partially depleting the synthetic plastic from the cellulose, and iii) further processing the depleted blended textile after depletion.

[0011] According to a further aspect of the present invention, a regenerated cellulose molding produced by the method described above is described. The molding is selected from the group consisting of filaments, fibers, foils, tissues, fleeces, (micro)spheres, beads, and sponges. Furthermore, the molding contains cellulose, in particular cellulose and synthetic plastics, which are derived from at least partially depleted blended textiles. Furthermore, the molding has at least one of the characteristics described below.

[0012] In the context of this application, the term "cellulose" may specifically refer to an organic compound that is a component of plant cell walls or that can be synthetically produced. Cellulose is a polysaccharide (i.e., multiple sugars). Cellulose is unbranched and typically contains hundreds up to tens of thousands of β-D-glucose molecules (β-1,4-glycosidic bonds) and cellobiose units, respectively. Cellulose fibers are made from plant-derived cellulose molecules in a controlled manner. Through technological processes, the cellulose molecules can be aggregated to form regenerated fibers, e.g., as fibers that are resistant to tearing.

[0013] In the context of this application, the term "molded body" may particularly refer to a two- or three-dimensional geometric object resulting from the respective processes for the production and recovery of cellulose. In particular, a shaped body refers to a two- or three-dimensional object containing or consisting of cellulose and produced from dissolved pulp. The shaped body may, in particular, be a lyocell shaped body, a viscose shaped body, or a modal shaped body. Typical shaped bodies are filaments, fibers, sponges, and / or membranes. Essentially, all types of cellulose shaped bodies are suitable for embodiments of the present invention. Both endless filaments and chopped staple fibers with conventional dimensions (e.g., 38 mm length) and short fibers are considered fibers. To produce fibers, both methods with a take-off device downstream of one or more extrusion nozzles and other methods, particularly meltblowing, are possible. As an alternative to fibers, cellulose-containing foils, i.e., planar and substantially uniform membranes containing or consisting of cellulose, can be produced as shaped bodies. Foils can be produced, in particular, by adjusting the process parameters of the Lyocell process so that solidification occurs at least partially only after the filaments impinge on the receiving surface. Planar cellulose moldings are considered foils, and the thickness of these foils is adjustable (e.g., by selecting several serially arranged nozzle beams). Other embodiments of moldings are tissues and fleeces composed of cellulose filaments and cellulose fibers, respectively, in particular spun fleeces composed of integrally bonded ("bonded") substantially continuous cellulose filaments ("meltblown"). Here, in particular, woven planar structures composed of at least two (preferably perpendicular or nearly perpendicular) intersecting thread (or fiber) systems can be considered tissues, with the longitudinal threads (or fibers) designated as warp threads and the transverse threads (or fibers) designated as weft threads. Fleeces or nonwovens can be described as irregular (e.g., randomly oriented) structures of filaments or fibers or cut yarns with limited length that are bonded and connected to one another (e.g., in a frictionally engaged manner) in a fibrous layer or fibrous web.The shaped body may be produced in the form of a sphere. Cellulose-containing particles, particularly beads (i.e., granules and globules, respectively) or flakes, which can be further processed into this form, may also be provided as a shaped body. Possible cellulose shaped bodies are thus also particle structures such as granules, spherical powders, or fibrids. The formation of the shaped body is preferably carried out by extrusion of a cellulose-containing spinning solution through an extrusion nozzle, since this method allows the production of large quantities of cellulose shaped bodies with a very uniform shape. Other possible cellulose shaped bodies are sponges, or more generally, porous shaped bodies. According to exemplary embodiments, the aforementioned shaped bodies can be used, for example, to produce yarns, fabrics, gels, or composite materials.

[0014] In the context of this application, the term "cellulose source" may particularly denote a medium (especially a solid medium) that provides the cellulose material used for this purpose as the main component for producing cellulose-containing shaped bodies during the corresponding production process. An example is wood and wood pulp, respectively.

[0015] In the context of this application, the term "Lyocell process" may specifically refer to a method for producing cellulose according to the direct solvent method. Cellulose for the Lyocell process can be obtained from a starting material containing said cellulose. In the Lyocell process, the starting material can be dissolved in a suitable solvent (especially containing tertiary amine oxides such as N-methylmorpholine-N-oxide (NMMO) and / or ionic liquids, i.e., low-melting-point salts composed of cations and anions). Dissolution can be carried out, in particular, by dehydration and / or without chemical modification. The resulting solution, also referred to as a dope or spinning solution, can then be forced through one or more spinning nozzles in the Lyocell process. The filaments formed thereby can be precipitated during and / or after free or controlled fall through an air gap in a water-containing bath (especially a bath using an aqueous NMMO solution) and / or in the air humidity present in the air gap.

[0016] In the context of this application, the term "viscose process" may specifically refer to a process for producing cellulose according to the wet spinning method. Cellulose for the viscose process can be obtained from a starting material containing said cellulose, in particular wood or wood pulp. In a subsequent process step in the viscose process, the starting material can first be treated with a base (e.g., caustic soda), thereby forming alkali cellulose. Subsequent conversion of said alkali cellulose with carbon disulfide forms cellulose xanthate. By further adding a base (e.g., caustic soda), a viscose spinning solution can be produced from the cellulose xanthate, which can be forced through one or more spinning nozzles. In the spinning bath, viscose filaments are produced by coagulation.

[0017] In the context of this application, the term "residue from garment manufacturing" may particularly refer to waste and / or offcuts of cellulose-containing or cellulose-based fabrics or yarns, where the residue is generated during the process of manufacturing clothing. In the manufacture of clothing, for example, cellulose-containing textiles are produced as starting material from which flat pieces (e.g., in the form of half T-shirts) are cut. According to an exemplary embodiment, the residue can be retained and re-fed to a process for manufacturing cellulose-containing molded bodies. Thereby, the residue from garment manufacturing may be a cellulose-containing or cellulose-based starting material and can be used to recover cellulose before the consumer uses the residue as clothing or in another way. In particular, the residue from garment manufacturing may consist of substantially pure cellulose, in particular without any separate and non-cellulose-containing foreign matter (e.g., as buttons, textile prints, or seams).

[0018] In the context of this application, the term "used clothing" may refer to clothing that contains cellulose and has already been used (especially worn) by a user when at least a portion of the cellulose is recovered. Used clothing may (but need not) contain a significant amount of foreign matter and may be a cellulose-containing starting material that can be used to recover cellulose after the user has used the used clothing as clothing or in any other way. In particular, used clothing may be composed of a mixture of cellulose and one or more foreign substances (e.g., synthetic plastics (e.g., polyester and / or elastane)) and / or discrete, non-cellulose-containing foreign substances (such as buttons, textile prints, or seams) (e.g., often used in clothing). Polyester may particularly refer to polymers with ester functionality in the main chain (R-[-CO-O-]-R). Polycarbonate and polyethylene terephthalate belong to the polyester family. Elastane may particularly refer to stretchable synthetic fibers with high elasticity. The block copolymer underlying elastane may contain 85% by weight of polyurethane.

[0019] In the context of the present invention, the term "blended textile" may particularly refer to textiles that contain more than one component and consist of at least two components. The textile may, for example, be leftovers from clothing production or used clothing (see below). The textile may consist of one component, for example, cotton or synthetic plastic. In contrast, a blended textile contains at least two different such components. The blended textile may, for example, contain cotton and synthetic plastic. Furthermore, the blended textile may contain cellulose, in particular cotton cellulose, and polyester, in particular polyethylene terephthalate (PET). The blended textile may also contain more than two components, for example, cellulose, polyester, and polyamide. According to a further embodiment, the blended textile may contain (cotton) cellulose, PET, and elastane. The components may also be described as fibers. Thereby, the blended textile may contain cellulose fibers and synthetic fibers. The synthetic fibers may contain at least one synthetic plastic.

[0020] In the context of this application, the term "synthetic plastic" specifically refers to materials composed of macromolecules and synthetically produced. Each macromolecule of a plastic is a polymer and, therefore, is composed of repeating basic units (repeating units). The size of the macromolecule of a polymer can vary from several thousand to over a million basic units. For example, the polymer polyethylene (PE) consists of multiple repeating ethylene units linked to each other. Here, the polymer can be unbranched, branched, or crosslinked. Regarding their physical properties, plastics can be divided into three basic groups: thermoplastics, duroplastics, and elastomers. Furthermore, these properties can be combined in subgroups, such as thermoplastic elastomers. Important characteristics of plastics are technical properties such as moldability, strength, elasticity, fracture toughness, temperature resistance, thermal dimensional stability, and chemical resistance, which can be varied within wide limits by the choice of polymer, the manufacturing method, and, typically, the addition of additives. Typical reactions for producing synthetic plastics from monomers or prepolymers are chain polymerization, polyaddition, or polycondensation. Examples of synthetic plastics that are also used in particular in textiles are, for example, polyurethanes (PUR), polyesters (PE, e.g. polyethylene terephthalate (PET)), polyamides (PA, e.g. nylon, Perlon), and polyethers, especially polyethylene glycol (PEG), especially as a component of elastane.

[0021] In the context of this application, the term "elastane" may specifically refer to a synthetic plastic with thermoplastic and elastic properties. Elastane may thereby be referred to as a thermoplastic elastomer (TPE). Elastane may exist as a block copolymer specifically characterized by both blocks: polyurethane (PUR) and polyethylene glycol ether (PEG). Here, the PUR segments may form stiff cross sections alternating with soft, elastic PEG cross sections. The PUR may form stiff, elongated cross sections that adhere to each other longitudinally and allow fiber adhesion, for example, through the formation of subvalent forces. In contrast, rubber-like PEG blocks (e.g., about 40 to 50 monomer units each) may exist in a highly entangled manner, but the PEG blocks may still be elongated. Here, elastane may exist as a spiral structure with very high elongation (multiples of 100%, e.g., 700%). The density may be, for example, 1.1 g / cm. 3 to 1.3 g / cm 3 and the strength may be, for example, 5 cN / tex to 12 cN / tex. The elasticity may be temperature dependent. Furthermore, the term "elastane" can refer to both elastane itself and related thermoplastic elastomers (e.g., ellastolan, desmopan, texin, utechlan).

[0022] In the context of this application, the term "depletion" may specifically refer to a process in which a component is at least partially removed from a mixture of at least two components. For example, a blended textile may contain the components cellulose and PET. If the portion of the component PET is reduced, this may be referred to as PET depletion. Numerous possibilities for carrying out such depletion are known. Depletion may be carried out mechanically, for example by density separation. Additionally, or alternatively, depletion may be carried out by chemical separation. An example of this is hydrolysis and derivatization of the depleted component. Furthermore, the depleted component may be removed by a solvent. During depletion, the depleted component may be degraded and destroyed, respectively. Furthermore, the depleted component may be present in its original form (i.e., non-degraded) after depletion.

[0023] According to an exemplary embodiment of the present invention, the drawback of depleting cellulose from blended textiles, in that the cellulose is somewhat highly degraded and therefore cannot be further reused for subsequent processes (e.g., Lyocell or Viscose processes), is overcome. Conventionally, various methods exist in which cellulose is depleted or degraded in order to separate synthetic plastics (e.g., polyester PET) from cellulose.

[0024] According to one embodiment of the present invention, it has now been found that by selectively dissolving and depleting the synthetic plastic (e.g., PET) from a blended fabric containing synthetic plastic and cellulose, both the synthetic plastic and the cellulose can be recovered in sufficient quality. This can be made economically possible by using a blended fabric with a low plastic (PET) fraction, in addition.

[0025] According to an exemplary embodiment of the present invention, it has surprisingly been found that by targeted control of the residual concentration in the context of the reuse of blended textiles (including the recycling process and the treatment of the starting material, respectively), new properties can be achieved in the (lyocell) moldings produced and in the subsequent production of the textile, respectively. The functionalization thus achieved of the residual concentration of blended textiles based on thermoplastics can provide a number of advantageous properties, such as strength or elasticity.

[0026] According to one exemplary embodiment of the present invention, the functionalization thus achieved of residual concentrations from blended textiles based on thermoplastic elastomers such as elastane can surprisingly allow for efficient compensation of (negative) property changes that may arise in particular from the portion of regenerated cellulose fibers in the (lyocell) molded body produced.

[0027] According to an exemplary embodiment of the present invention, synthetic plastics, which are used in large quantities in textiles, can be at least partially depleted in order to obtain cellulose as a raw material for the recycling process. However, it is not necessary to completely deplete the plastics, and a defined (at least partially depleted) portion of the synthetic plastics can remain in the blended textile. This can lead to particularly controllable desired properties in the produced cellulose-containing molded bodies.

[0028] While the problem has traditionally been recovering particularly large amounts of synthetic plastics from textiles with a very high plastic content (whereby cellulose is generated as waste), according to an exemplary embodiment of the present invention, a blended textile with a low plastic content is instead utilized as the starting material for the primary recovery of cellulose, rather than for the recovery of synthetic plastics. In this way, cellulose can be efficiently recovered.

[0029] According to an advantageous embodiment, the entire plastic does not have to be depleted, but a small portion can remain in the blended fabric for further processing. Surprisingly, a low residual portion of (certain) synthetic plastics in the produced and cellulose-containing moldings can not only be accepted without hindrance, but can even provide advantageous properties such as increased stability and / or improved elasticity.

[0030] In summary, according to one embodiment of the present invention, a situation is used in which blended textiles containing cellulose and synthetic plastics can be reused by depleting the plastic (e.g., by selectively dissolving and precipitating the polymer moiety in a solvent, particularly a solvent that does not degrade cellulose) as a resource-saving and sustainable cellulose starting material from which regenerated cellulose moldings can be produced, for example, by the lyocell or viscose process.

[0031] According to one embodiment, moldings produced from blended textiles as starting materials, for example by the Lyocell or viscose process, can have desired properties due to the residual portion of certain synthetic plastics.

[0032] Additional embodiments of the method and compact are described below.

[0033] According to one embodiment, the synthetic plastic is at least one of the group consisting of polyester, polyamide, polyurethane, polyether, and elastane. This has the advantage that industrial plastics that are used in large quantities in textiles can be at least partially depleted to obtain cellulose as a starting material for reuse. Additionally, the aforementioned plastics can lead to particularly controllable desired properties in the produced and cellulose-containing molded bodies.

[0034] Examples of synthetic plastics that are also particularly used in blended textiles are, for example, polyesters (PE, e.g., polyethylene terephthalate (PET)), polyamides (e.g., nylon, Perlon), polyurethanes (PUR), particularly as a component of elastane, and polyethers, particularly polyethylene glycol (PEG), as a component of elastane. According to one embodiment, PET, which may be present in large amounts in many blended textiles, is particularly depleted. In addition, a larger proportion of PET in the blended textile may result in undesirable properties for the recycling process and the resulting molded articles, respectively.

[0035] According to a further embodiment, the cellulose of the blended fabric is derived from cotton. This can have the advantage that industrially relevant materials that occur in very large quantities in blended fabrics can be directly used. Furthermore, since cotton production is very resource-intensive, environmental benefits are provided.

[0036] Many blended fabrics contain cellulose in the form of cotton (see description of Figure 5 below). This cotton cellulose differs phenotypically and in physical properties from lyocell and viscose cellulose. For example, cotton cellulose fibers do not require additional matting agents (e.g., titanium dioxide), while lyocell and viscose cellulose fibers can be transparent without such chemicals, especially in wet conditions.

[0037] According to a further embodiment, the starting material may comprise, in whole or in part, garment manufacturing residues and / or used clothing (e.g., blended textiles). That is, textiles, particularly garment manufacturing residues and / or used clothing, may be used as at least a portion of the starting material. The use of garment manufacturing residues is particularly preferred, since such offcuts and waste often have a very high cellulose content and thus a very high degree of purity, respectively. In particular, such pre-consumer textiles may be free of foreign matter such as buttons, seams, or textile prints. For example, garment manufacturing residues may substantially comprise knitted (and optionally dyed) cellulose, so that such residues can be directly transferred into a solution for cellulose recovery by the Lyocell process, if desired. In used clothing or post-consumer textiles, large foreign matter such as buttons, prints, and seams may already be separated during or after mechanical comminution. Residues or other foreign matter from used clothing, such as colorants and synthetic plastics (such as polyester and elastane), may be completely or partially removed before dissolving the corresponding starting materials to form the dope and spinning solution, respectively, or may remain completely or partially in the spinning solution.

[0038] According to a further embodiment, the method further comprises a step of washing the cellulose, which step occurs between the depleting step and the further processing step, which may have the advantage that a particularly high quality cellulose may be provided for the recycling method.

[0039] Such washing can, for example, remove at least a portion of the synthetic plastics, if desired. For example, in this way, the synthetic plastic portion of the molded body produced can be adjusted and affected, respectively. Washing does not represent actual depletion, but serves as an additional method step, for example, to remove (certain) synthetic plastics that are not firmly bonded and / or to wash away plastic residues. Furthermore, washing can include at least partial removal of colorants by bleaching. This makes it possible to completely or partially decolorize the blended fabric, for example, to produce white or gray molded bodies. Furthermore, the blended fabric can be at least partially freed from crosslinking agents that crosslink the fibers. In applications where such crosslinking agents are present between the fibers of the blended fabric, the fibers can be completely or partially freed from these crosslinking agents by alkaline or acidic pretreatment.

[0040] According to a further embodiment, the depletion step further comprises selectively depleting at least one synthetic plastic from the blended textile. The synthetic plastic may in particular be one of the group consisting of polyamide, polyester, polypropylene, polyurethane, and elastane. This may provide the advantage that the plastic portion of the blended textile further used in the recycling method can be specifically influenced and controlled, respectively, to obtain specific properties of the molded body to be produced.

[0041] Certain synthetic plastics can have properties that interfere with recycling processes, particularly the Lyocell process.

[0042] According to one exemplary embodiment, PET can be selectively depleted from a blended textile. In this way, the treated blended textile, present as a fragmented tissue / fiber mixture, can be treated under pressure with tetrahydrofuran (THF) at temperatures between 120°C and 190°C, where the PET is selectively dissolved. The polymer concentration in the solvent can be adjusted to a maximum of 10%, since otherwise the viscosity would be too high in the next step. At this point, filtration of the residue is hardly possible. Due to this variable, proper temperature control is particularly important to achieve the desired final PET fraction. In this way, the extent of degradation can be controlled, and a relatively precise final PET concentration can be adjusted.

[0043] According to a further exemplary embodiment, dissolving the PET can be achieved by a solvent, and the precipitation can be carried out at a temperature below the melting point of PET (approximately in the range between 180°C and 220°C). For example, a dicarboxylic acid dialkyl ester or a mixture of dicarboxylic acid dialkyl esters can be used as the solvent. Furthermore, for example, the dimethyl or diethyl esters of oxalic acid, malonic acid, succinic acid, glutaric acid, and / or adipic acid can be used as the solvent. For example, a non-polar substance such as an aliphatic hydrocarbon or a mixture of petroleum ether and benzenes can be used as the precipitation agent. In particular, n-alkanes and / or isoalkanes can be used as the precipitation agent.

[0044] According to a further exemplary embodiment, the cellulose (with any polyamide (PA) moieties) is filtered so that its fluidity is maintained, and the filtrate is concentrated by distillation. The concentrate is precipitated by introducing it into a liquid that is not a suitable solvent for PET but is miscible with THF (in particular, methanol, ethanol, hydrocarbons from C5 (pentane) to C10 (gasoline / diesel)). Since the described method does not cause degradation of the polyester, after filtration and drying, the PET can be used in the form of fine particles as a suitable raw material.

[0045] Polypropylene (PP) may also occur in blended textiles. PP originates, for example, from nonwoven fabrics such as fleece linings in clothing or similar materials. However, in the Lyocell process, for example, PP can cause significant process interference because it is insoluble in NMMO and can cause filter clogging in the subsequent production of Lyocell moldings.

[0046] According to one exemplary embodiment, the PP portion can be selectively depleted by mechanical flotation (PP density is approximately 0.75 kg / L to 0.9 kg / L, density of further plastics significantly above 1.0 kg / L).

[0047] According to a further exemplary embodiment, if this depletion is unsuccessful, the PP can be selectively pre-depleted (dissolved) from the mixture in a first step with an aromatic solvent (e.g., toluene, xylene, trimethylbenzene, ethylbenzene, cumene) at temperatures up to about 150°C. This pre-deposition variable of PP is of particular interest since cellulose, PET, PA, and PUR are insoluble in aromatic solvents. In a second step, the PET portion can then be reduced as described above, but the process can be interlocked without first completely removing the previous solvent, since the final resulting solvent mixture can be separated by fractional distillation in a safe and suitable manner.

[0048] In a further embodiment, in the recycling of old textiles, a primary reduction of the polymer component is desired. For example, PP can be separated (selectively depleted) to a high degree by flotation. Furthermore, polyamides (PA) and polyacrylonitrile (PAN) can be separated (selectively depleted) by hydrolysis in the pH range below 7. Finally, additional polyester fractions can then be selectively depleted by the dissolution described above. According to one embodiment of the present invention, an upstream selection mechanism allows for resource- and effort-saving recycling processes.

[0049] By treating a blended fabric according to one embodiment of the present invention, it can be ensured that residual (desirably depleted) plastics such as PUR, PA, PET, polyester, etc. remain in the proper concentration for further processing in a recycling process such as the Lyocell process. When this is achieved, the plastic portion present in the Lyocell process spinning solution can act similarly to a composite fiber thermoplast.

[0050] In a preferred embodiment, the desired proportion of, for example, PET and PUR in the blended fabric can be adjusted by selectively depleting the existing residual plastics. The recycled (lyocell) moldings produced after adding such a processed blended fabric have properties similar and almost identical to those of unregenerated lyocell moldings. In particular, by adding recycled lyocell fiber, these properties can become even closer to those of unregenerated lyocell fibers, so that the difference cannot be measured any more by measurement techniques.

[0051] In the described cases, the solvent can be substantially recovered by fractional distillation, making the described depletion process particularly advantageous, especially from the point of view of closed material cycles and resource use.

[0052] According to a further embodiment, the depleting step of the method further comprises a step of completely removing at least one synthetic plastic from the blended fabric. The synthetic plastic may in particular be polyester and / or elastane. This may have the advantage that the depleted blended fabric is particularly pure, whereby undesirable properties may be significantly reduced.

[0053] Some synthetic plastics, such as polyester (PET), elastane, or polypropylene, can have chemical / physical properties that can be particularly detrimental to recycling processes. For example, insolubility in the spinning solution can be considered a major problem. Depleted blended fabrics that do not transfer this negative property to further processing methods (e.g., the Lyocell process) can be correspondingly advantageous.

[0054] According to a further embodiment, the depletion step of the method further comprises at least partially retaining the synthetic plastic in the blended fabric. The synthetic plastic may be, in particular, one of the group consisting of polyamide, polyester, polyurethane, and elastane. This may have the advantage that the synthetic plastic does not need to be further depleted in a particularly suitable and pure manner, respectively. Depletion of small residual concentrations may therefore be technically difficult and resource-intensive.

[0055] Instead, synthetic plastics, such as polyurethanes, can remain in the blended fabric, thereby reducing and eliminating the need for laborious and expensive depletion processes, respectively. If at least a portion of the polyurethane is allocated to elastane, even further advantages can be achieved, such as improved strength and / or elasticity of the molded body produced.

[0056] To achieve adequate incorporation into cellulose, for example, a small portion (e.g., less than 2%) of polyamides and polyesters can be co-processed in the recycling process. This can be a significant advantage, since it can be disproportionately difficult to at least partially remove additional synthetic polymers, especially those with low concentrations, in the recycling process. The aforementioned additional synthetic plastics can very frequently and commonly be contained in starting materials such as textiles. This allows for a small residual amount, which greatly facilitates the recycling process.

[0057] According to a further embodiment, the blended fabric contains a first synthetic plastic, particularly polyamide and / or polyurethane. The blended fabric also contains a second synthetic plastic, particularly polyester, more particularly polyethylene terephthalate (PET) and / or polypropylene. Additionally, the depleting step further comprises: i) at least partially depleting the first synthetic plastic to a first concentration value; and ii) at least partially depleting the second synthetic plastic to a second concentration value. The first concentration value is different from, and particularly greater than, the second concentration value. This has the advantage that the technically laborious and expensive depletion of the additional plastic can be at least partially omitted. Alternatively, the presence of at least one additional synthetic plastic may even advantageously influence and control the properties of the resulting fiber.

[0058] For example, high concentrations of polyester, particularly PET and / or PP, may not be desirable for the recycling process of blended textiles. Furthermore, the use of PA and / or PUR, particularly elastane, as a component may not necessarily be desirable. As described herein, PA, PUR, and elastane may each provide advantageous properties, such as improved fiber strength. In this manner, the first concentration value may correspond to, for example, the concentration of polyester or PP, but be kept as low as possible. Furthermore, the second concentration value may correspond to, for example, the concentration of PA or PUR, but a specific range of concentrations may be advantageous. The polyester / PP concentration may thereby be adjusted to be as low as possible, while the PA / PUR concentration may be adjusted to be higher. However, this is merely one example, and many different combinations of plastics and concentrations are possible. In this manner, many specific concentrations may be adjusted based on the desired properties of the molded body to be produced.

[0059] According to a further embodiment, the depleting step of the method comprises at least one of the separation methods described below.

[0060] Mechanical separation, especially due to differences in density of materials.

[0061] Chemical separation includes at least one of the following: hydrolysis, derivatization, and the use of a solvent. According to a preferred embodiment, a solvent that does not decompose cellulose is used. For example, alkaline boiling with caustic soda (NaOH) can be performed to degrade the residual polyester and adjust the chain length of the cellulose molecules.

[0062] According to a further embodiment, the method further comprises the step of providing at least one further blended fabric containing cellulose and at least one synthetic plastic, the proportions of the synthetic plastic in the blended fabric and the further blended fabric being different so that the resulting plastic composition has at least one predetermined property, which has the advantage that the desired proportions of the synthetic plastic can be adjusted and influenced accordingly, respectively, substantially without the additional use of chemical methods.

[0063] In a preferred embodiment, the residual synthetic plastic content of the starting material is adjusted to a specific amount. The cellulose-containing molded body produced after adding the specific starting materials can then have the desired plastic concentration and composition, as well as the corresponding specific chemical and physical properties, which can correspond to the properties of non-regenerated lyocell fibers.

[0064] In particular, by mixing different compositions of starting materials such as blended textiles and / or used clothing and / or residues from clothing production, specific properties, such as the concentration of synthetic plastics (e.g. elastane) and optionally at least one further synthetic plastic, can be adjusted and subsequent use and / or functionalization can be specifically controlled.

[0065] In a further preferred embodiment, different starting materials with different compositions are mixed so that the desired proportions of different plastics are prepared. In this embodiment, the desired mixture is achieved solely by selecting the starting materials. As a result, additional plastics that would otherwise have to be chemically pretreated separately do not need to be added. Therefore, this reduced / no chemical embodiment (achieved solely by mixing the starting materials) can be considered particularly advantageous in terms of resource consumption and environmental protection.

[0066] The step of providing the additional blended fabric may be performed during the step of providing the blended fabric. Furthermore, the additional blended fabric and the depleted (treated) blended fabric, respectively, may be provided at a later time, for example, during the lyocell process.

[0067] According to a further embodiment, the further processing step comprises the lyocell or viscose process to produce regenerated cellulose moulded bodies, which has the advantage that proven and robust methods can be directly applied. The lyocell process is described in detail herein.

[0068] According to a further embodiment, the regenerated cellulose molding has at least one of the characteristics described below.

[0069] The regenerated cellulose molding may contain less than 0.5% polyethylene terephthalate (PET) and / or more than 1% polyurethane (PUR) and / or polyamide (PA). At least 2% of the blended textile portion in the regenerated cellulose molding may be synthetic plastic.

[0070] The regenerated cellulose molding has the strength values ​​of conventional lyocell fibers. Average fiber data for conventional lyocell fibers (e.g., Tencel®) can be as follows: maximum positive tension (FFk): 40.2 cN / dtex, maximum wet tension (FFn): 37.5 cN / dtex, maximum positive tension elongation (FDk): 13.0%, maximum wet tension elongation (FDn): 18.4% (see Lenzinger Berichte 87 (2009) 98-105, Table 1). Thus, the maximum tension (FFk) can be in the range of 35 cN / dtex to 45 cN / dtex, in particular 38 cN / dtex to 42 cN / dtex, and the maximum wet tension (FFn) can be in the range of 32 cN / dtex to 42 cN / dtex, in particular 35 cN / dtex to 40 cN / dtex. The maximum tensile extension (FDk) may range from 10% to 15% and the maximum wet tension (FDn) may range from 16% to 20%.

[0071] According to one embodiment, the synthetic plastic (elastane, optionally with additional portions of, for example, PET, PUR, and PA) fraction can be present in a specific concentration. This can lead to a particularly uniform distribution in the spinning solution, such that during the spinning process, the plastic is incorporated in a uniform and finely distributed manner into the (lyocell) moldings produced. In this way, specific fiber properties can be controlled and influenced accordingly.

[0072] The regenerated cellulose moldings also have a reduced tendency to fibrillate compared to conventional lyocell fibers. The surprisingly low fibrillation tendency achieved in this way can be explained by the fact that the incorporated residual plastics, such as polyester oligomers, support the stirring of single crystalline cellulose strands in the sense of separating the (at least partially amorphous) sliding layers and also control the adhesion between the cellulose strands in the transverse direction. This can result in a corresponding suppression of the delamination typical of fibrillation. In other words, the polyester oligomers and the additional synthetic plastics each act as a hot-melt adhesive within the fiber. Fibrillation can particularly refer to the local separation of cellulose elements longitudinal to the fiber axis, especially when mechanical and moisture forces act simultaneously on the fiber.

[0073] According to a preferred embodiment, the synthetic plastic in the molded body is derived mainly, particularly exclusively, from the blended textile. This has the advantage that the molded body can be produced in a particularly resource-saving manner. The synthetic plastic in the molded body can be derived entirely or at least partially from the starting material. Therefore, essentially no additional plastic needs to be added. Furthermore, the step of painstakingly removing the plastic from the starting material can be at least partially omitted.

[0074] According to a preferred embodiment, the concentration of synthetic plastic, in particular polyester, in the regenerated cellulose molding may be in the range of 0.1 to 60 percent by weight, in particular 0.1 to 15 percent by weight, relative to the cellulose.

[0075] According to a further embodiment, the plastic concentration of the finished (lyocell) moulded body can be detected to within an accuracy of + / - 0.2%.

[0076] According to one embodiment, the method may include a post-treatment of the precipitated cellulose to obtain a molded body from the molded body preform. Such optional post-treatment may include, for example, drying, impregnation, and / or reforming of the obtained cellulose filaments. By corresponding post-treatment, it is possible to complete the production of the molded body at the end of the Lyocell process in an application-specific manner.

[0077] According to one embodiment, the fibers of the starting material and / or the fibers of the shaped body may have a smooth, rounded outer surface. As illustrated in Figure 3, the cellulose fibers extracted by the Lyocell process are characterized by such a shape and therefore differ from the shapes of other fibers that occur in natural cotton or are obtained by the viscose process.

[0078] Molded articles produced according to the present invention can be used as packaging materials, textile materials, woven composites, fiber composites, fiber fleeces, needle felts, quilting batting, thin woven fabrics, knitted fabrics, household textiles such as bedding, clothing, hospital textiles such as fillers, flocking materials, underlays, diapers, or mattresses, heating blankets, shoe insoles, and fabrics for wound dressings. Embodiments of the present invention may be applicable in various technical fields, both in medicine and in cosmetics and health. In medicine, for example, materials for wound treatment and wound healing may consist of a carrier that determines mechanical properties and a biocompatible covering material that specifically matches the surface of the skin and wounds. Many other applications are possible. [Brief explanation of the drawings]

[0079] In the following, exemplary embodiments of the present invention will be described in detail with reference to the following figures:

[0080] [Figure 1] 1 shows a flow diagram of a method for recycling a blended textile fabric, in which a regenerated cellulose molding is produced according to an exemplary embodiment of the present invention.

[0081] [Figure 2] 1 shows an apparatus for producing regenerated cellulose moldings by the Lyocell process according to an exemplary embodiment of the present invention.

[0082] [Figure 3] 1 shows cellulose fibers produced by the Lyocell process.

[0083] [Figure 4] 1 shows cellulose fibers produced by the viscose process.

[0084] [Figure 5] Shows the natural cellulose fibers of the cotton plant.

[0085] Components that are the same or similar in different figures are provided with the same reference numbers. DETAILED DESCRIPTION OF THE INVENTION

[0086] Before an exemplary embodiment is described with reference to the figures, some basic considerations are summarized based on which the exemplary embodiment of the present invention is derived.

[0087] According to an exemplary embodiment of the present invention, selective depletion of thermoplastic additives in the blended fabric is carried out so that they can be recycled for the production of (lyocell) molded articles. The PET portion is greatly reduced, and the PUR portion is slightly reduced. In the context of the Lyocell process, the situation is used in which residual components of PUR can act as positive property changers.

[0088] According to a further exemplary embodiment of the present invention, recycling of cellulose from mixed fabrics (blended textiles) having polymer moieties is carried out by selectively dissolving and precipitating the polymer moieties in a solvent that does not attack the cellulose.

[0089] According to a further exemplary embodiment of the present invention, the recovery of cellulose suggests a new solution concept, which is based on the typically low (<50%) polymer fraction in the starting material (woven fabric blend). The implementation of the present invention is optimal when it is important to reduce the polymer fraction, for example, from less than 30% to values ​​in the single-digit percentage range (up to the per mil range). This is particularly advantageous because, in contrast to known methods, the focus is not on recycling plastics but on recycling non-polymerized residual components, particularly cellulose. Instead, previously known methods are based on the fact that the recycled material contains a high to very high plastic fraction. From an exemplary high plastic fraction of 80% to 90%, a significant portion of the polymer can be recovered. In the residual material that is typically further thermally processed, a residual polymer fraction of up to 50% will still be present.

[0090] According to a further exemplary embodiment of the present invention, residual polymers from the starting material are used as adhesion promoters between cellulose fibers or as thermoplastic property promoters within the lyocell molded body. They remain substantially inert until the completion of a specific stage in the production process. In particular, post-thermal reinforcement of the fabric (similar to melting adhesives) can be achieved thereby (e.g., no-ironing shirts, pleating, etc.). To produce fabrics with high dimensional stability (e.g., no-ironing) typically requires laborious methods. For example, this may involve a combination of very laborious chemical methods. This allows the shirt to look new for a long time. So-called "wet cross-linking" is also possible, in which elastic cross-links are formed between the molecules of cotton cellulose. These cross-links allow the fabric to return to its correct shape after washing.

[0091] According to one embodiment, a specific thermoplasticity in the lyocell fiber can be obtained by targeted control of the portion of residual polymer (e.g. polyurethane from elastane from blended fabric), which according to one embodiment of the present invention is resupplied via the lyocell process by returning a corresponding portion of the residual polymer from the starting material to the lyocell molding via a depletion step.

[0092] According to a further exemplary embodiment of the present invention, the appropriate incorporation behavior of a particular synthetic plastic can be explained by the compatibility between cellulose and other synthetic plastics, such as elastane, polyamide, or polyester. Due to its typical ether structure, the polyethylene glycol (PEG) moiety in elastane can contribute to its appropriate compatibility with the ether bonds of the cellulose glycans. Therefore, appropriate homogenization / mixing between the substances occurs. According to one embodiment, the corresponding incorporation process may also be highly dependent on the temperature of the respective process.

[0093] FIG. 1 shows a flow diagram 50 of a method for producing a regenerated cellulose molded body 102 (compare FIG. 2) from a blended textile 110 according to one exemplary embodiment of the present invention.

[0094] Below, first, a depletion method for the blended fabric 110 is described by blocks 52, 54, 56, and 58. The respective depleted and treated blended fabric 60 can then be fed to a lyocell process 78. Further, next, a lyocell process is described by blocks 62, 64, 66, 70, 72, and 74 for producing a regenerated cellulose molding 102 from the respective depleted and treated blended fabric 60 as starting material 110. According to a preferred embodiment, the depleted blended fabric 60 contains substantially only cellulose. According to a further embodiment, the depleted blended fabric 60 contains cellulose and synthetic plastic.

[0095] The blended fabric 110 contains cellulosic fibers and at least one synthetic plastic fiber and exists in the form of used clothing and / or residue from clothing manufacturing.

[0096] The blended fabric 110 may be used by a consumer, for example, as a garment, if used, as shown by block 48. When the consumer discards the garment, the garment is treated as post-consumer and may then be used as starting material for a subsequent lyocell or viscose process, the latter of which is described in more detail below.

[0097] Alternatively, or additionally, it is also possible to use pre-consumer blended textiles, such as scrap offcuts from garment manufacturing.

[0098] According to block 52, the blended fabric 110 is first fed to a depletion process. A depletion step 54 of the blended fabric then occurs, in which at least one synthetic plastic is at least partially depleted. This may include a hydrolysis step or a derivatization step. Particularly preferably, a solvent that does not degrade cellulose is used. In this way, polyesters, such as PET, can be depleted from the cellulose. Between the depletion step 54 and a subsequent further processing step 58 of the blended fabric 110, a washing step 56 can occur, whereby the cellulose can be cleaned of excess plastic or other foreign matter. The further processing step 58 particularly includes feeding the depleted blended fabric 60 as starting material 110 to a lyocell process.

[0099] In the following, it is explained how, according to one embodiment of the present invention, a shaped body 102 made of cellulose can be produced on the basis of a depleted blended fabric 60. For this purpose, the depleted blended fabric 60 is fed to an apparatus 100 (see FIG. 2) for carrying out the Lyocell process. Compare reference number 78. In the following, the depleted blended fabric 60 is shown as starting material 110 for the Lyocell process (compare FIG. 2).

[0100] There, first, mechanical comminution 62 of the starting material 110 is carried out by cutting, whereby mainly large non-cellulose impurities, such as buttons, seams, and prints from old clothes that were at least partly used to produce the starting material 110, can be removed from the starting material 110. By mechanical comminution 62, the starting material 110 can be separated into, for example, single fibers. It should be noted that the described mechanical comminution 62 according to a further embodiment can also be carried out during the attrition process, in particular before attrition stage 54.

[0101] It is also possible to use the cellulose-containing starting material 110 together with other cellulose-containing materials for the subsequent lyocell process (see block 64). The starting material 110 can then be mixed with a further starting material containing cellulose and at least one synthetic plastic (see block 64). This further starting material contains a synthetic plastic fraction, but this synthetic plastic fraction is different from the synthetic plastic fraction in the starting material 110. Producing a regenerated cellulose molded body can then be performed based on the starting material 110 and the further starting material, such that the regenerated cellulose molded body 102 contains a predetermined proportion of synthetic plastic. Alternatively or additionally, the further starting material can include residues from garment manufacturing. Preferably, the further starting material is also a blended textile. According to a further exemplary embodiment, the further blended textile can also be provided during the attrition process, in particular substantially simultaneously with step 52 of providing the blended textile 110.

[0102] Direct dissolution 68 of the starting material 110 (respectively pure and mixed) in a further solvent 116 (e.g., a tertiary amine oxide such as N-methylmorpholine-N-oxide (NMMO)) immediately after mechanical comminution 62 and immediately after mixing 64, respectively, can be carried out in an advantageous manner without chemical pretreatment. More specifically, the mechanically comminuted (and optionally mixed) starting material 110 can be directly transferred into the solution, in particular without chemical washing and viscosity adjustment. In this way, the production method and the recycling method, respectively, can be carried out in an exceptionally simple, rapid, and environmentally friendly manner. Surprisingly, it has been found that certain synthetic plastics (e.g., elastane, polyamide) remaining as foreign matter in the starting material 110 after mechanical comminution 62 do not interfere with the lyocell process and do not negatively affect the quality of the recovered lyocell cellulose. In contrast, certain amounts of certain synthetic plastics remain in the produced cellulose fibers without impairing the properties of the cellulose fibers and may even improve them. A certain amount of residual polyester does not interfere with the resulting product and may even enhance the mechanical integrity of the molded body 102 produced.

[0103] Alternatively, the method may include an optional chemical washing 66 of the starting material 110 after mechanical comminution 62 (or after mixing 64) and before dissolving 68. Such optional washing 66 may include at least partial removal of colorants, for example, by bleaching. Thus, it is possible to fully or partially bleach the starting material 110 before the subsequent dissolving step 68 of the starting material 110 in a solvent 116, for example, to produce a white or gray molded body 102. Alternatively, or additionally, in the context of the optional chemical washing 66, the starting material 110 (before or after the dissolving step 68 of the starting material 110) may also be at least partially freed of crosslinking agents crosslinking the fibers of the starting material 110. In applications where such crosslinking agents are present between the fibers of the starting material 110, the starting material 110 may be fully or partially freed of these crosslinking agents, for example, by alkaline or acidic pretreatment. This additionally improves the solubility of the starting material 110. If desired, at least a portion of the synthetic plastic can be optionally removed by washing 66. For example, in this manner, the portion of the synthetic plastic in the produced molded body 102 can be adjusted and affected, respectively. According to a further exemplary embodiment, washing step 56 between the depletion steps can be performed as well. Furthermore, if washing step 56 has already been performed during the depletion step, washing step 66 may be unnecessary.

[0104] After step 68 of dissolving the starting material 110 in a solvent (preferably NMMO), the resulting lyocell spinning solution 104 may be forced through one or more spinning nozzles, thereby producing threads and filaments, respectively, having a honey-like viscosity (see block 70 for this spinning).

[0105] During and / or after the dropping of these yarns and filaments, respectively, they are operatively connected to an aqueous environment and thus diluted. The concentration of the solvent 116 in the yarns and filaments, respectively, is thereby reduced in the aqueous fog and aqueous bath, respectively, to the extent that the lyocell spinning solution transitions to a solid phase composed of cellulose filaments. That is, precipitation, deposition, or solidification of the cellulose filaments occurs. See reference numeral 72. Thus, a preform of the compact 102 is obtained.

[0106] The step 80 of producing the regenerated cellulose molded body 102 by the Lyocell process, in particular the dissolving step 68, the spinning step 70 and then the precipitation step 72, is carried out based on the depleted blended fabric 60 as starting material 110, which itself contains cellulose and optionally synthetic plastics.

[0107] Furthermore, the method may include post-treatment 74 of the precipitated lyocell cellulose to obtain the shaped body 102 from the preform of the shaped body 102. Such post-treatment may include, for example, drying, impregnation, and / or reforming of the obtained filaments towards the final shaped body 102. For example, the shaped body 102 may be processed into fibers, foils, tissues, fleeces, spheres, porous sponges, or beads by the described manufacturing methods, which may then be supplied for further use (see reference numeral 76).

[0108] Advantageously, after using the molded body 102, its cellulose (and optionally its synthetic plastics) can be recovered again (see block 80) by carrying out further processes corresponding to the process steps between reference numbers 48 and 74 and 78 and 74. Alternatively, the cellulose and any further synthetic plastics of the molded body 102 can be recovered in further processes (see also block 80), for example in a viscose process. This multiple repeatability of reuse by repeated process steps is made possible by the knowledge that cellulose from blended textiles can be used particularly efficiently in reuse processes by at least partial, selective depletion of the plastic portion.

[0109] FIG. 2 shows an apparatus 100 for producing a regenerated cellulose molding 102 by the Lyocell method based on starting materials 110, which are the depleted and treated blended fabrics 60, respectively, according to an exemplary embodiment of the present invention described with reference to FIG.

[0110] 2 shows an apparatus 100 according to an exemplary embodiment of the present invention for producing cellulose-containing shaped bodies 102, which can be produced, for example, in the form of fibers, foils, spheres, textiles, fleeces (nonwoven fabrics) such as sponges, or in the form of beads or flakes. According to FIG. 2, the shaped bodies 102 are produced directly from a spinning solution 104. The spinning solution 104 is converted into cellulose fibers 108 as the shaped bodies 102 by a coagulation fluid 106 (particularly composed of air moisture) and / or a coagulation bath 191 (e.g., a water bath optionally containing a tertiary amine oxide such as N-methylmorpholine-N-oxide (NMMO)). The apparatus 100 can be used to carry out the Lyocell process. In this way, for example, substantially endless filaments or fibers 108, or a mixture 108 of substantially endless filaments and fibers with individual lengths, can be produced as the shaped bodies 102. A plurality of nozzles, each having one or more openings 126 (sometimes referred to as spin holes), are provided for discharging the lyocell spinning solution 104 .

[0111] As can be seen from FIG. 2, the cellulose-based starting material 110 can be fed into a storage tank 114 via a dosing device 113 .

[0112] According to one embodiment, the ingress of water into the cellulose-based starting material 110 may be carried out by a solvent 116 (in particular NMMO), which will be described in more detail below. The cellulose-based starting material 110 may itself contain a certain residual moisture (e.g., dry pulp often has a residual moisture of 5 to 8 percent by weight). In particular, according to the described embodiment, the starting material 110 may be directly fed into the mixture of water and solvent 116 without pre-wetting. The optional water container 112 shown in FIG. 2 may then be omitted.

[0113] According to an alternative embodiment, the cellulose-containing starting material 110 may additionally be moistened, thus providing moist cellulose. To this end, water from an optional water container 112 may be supplied to the storage tank 114 via a dosing device 113. The dosing device 113, controlled by the control device 140, may thus supply adjustable relative amounts of water and starting material 110 to the storage tank 114.

[0114] A suitable solvent 116, preferably a tertiary amine oxide such as N-methylmorpholine-N-oxide (NMMO), and an aqueous mixture of the solvent 116, e.g., a 76% aqueous solution of NMMO, are contained in the solvent containers. The concentration of the solvent 116 can be adjusted in a concentrator 118 by adding either pure solvent or water. The solvent 116 is then mixed with a definable relative amount of the starting material 110 in a mixing section 119, which can also be controlled by a controller 140. The cellulose-containing starting material 110 is thereby dissolved in an adjustable relative amount of the concentrated solvent 116 in a dissolving section 120, thereby obtaining a lyocell spinning solution 104. The relative concentration ranges (also referred to as spinning windows) of the starting material 110, water, and solvent 116, which are components in the spinning solution 104 for producing regenerated cellulose bodies according to the lyocell process, can be appropriately adjusted, as known to those skilled in the art.

[0115] The lyocell spinning solution 104 is fed into a fiber-producing device 124, which may consist of several spinning beams or jets 122.

[0116] As the lyocell spinning solution 104 is directed through the opening 126 of the jet 122, it separates into multiple parallel threads composed of the lyocell spinning solution 104. The described process flow converts the lyocell spinning solution 104 into increasingly longer and thinner threads whose properties can be adjusted by corresponding adjustments of the process conditions controlled by the controller 140. Optionally, a gas flow can accelerate the lyocell spinning solution 104 on its way from the opening 126 to the fiber receiver 132.

[0117] After the lyocell spinning solution 104 travels further downward through the jet 122 , the long, thin strands of the lyocell spinning solution 104 interact with the coagulating fluid 106 .

[0118] Upon interaction with the coagulating fluid 106 (e.g., water), the solvent concentration of the lyocell spinning solution 104 is reduced, resulting in the cellulose of the starting material 110 at least partially coagulating and precipitating, respectively, as long and thin cellulose fibers 108 (which may still contain solvent and water residues).

[0119] During or after the initial formation of individual cellulose fibers 108 from the extruded lyocell spinning solution 104, the cellulose fibers 108 are received in a fiber receiver 132. The cellulose fibers 108 may be immersed in a coagulation bath 191 (e.g., a water bath optionally containing a solvent such as NMMO) as shown in FIG. 2 and may complete precipitation upon interaction with the liquid of the coagulation bath 191. Depending on the coagulation process settings, the cellulose may form cellulose fibers 108 (as shown, where the cellulose fibers 108 are each composed of a single substance and may be integrally bonded to each other (“bonded”) or may exist as separate cellulose fibers 108), or a foil and membrane composed of cellulose may form in the fiber receiver 132, respectively (not shown in FIG. 2).

[0120] The cellulose fibers 108 are thereby extruded from the spinning nozzles of the jet 122 and guided through a spinning bath and a coagulation bath 191 (e.g., containing water and a low concentration of NMMO for precipitation / coagulation), respectively, where the cellulose fibers 108 are guided around respective deflection rolls 193 in the coagulation bath 191 and fed to a draw-off godet 195 outside the coagulation bath 191. The draw-off godet 195 serves for further transport and post-stretching of the cellulose fibers 108 to achieve the desired titer. Downstream of the draw-off godet 195, the fiber bundles composed of the cellulose fibers 108 are washed in a washing section 180, optionally wound up, and then cut (not shown).

[0121] Although not shown in FIG. 2, the solvent 116 of the lyocell spinning solution 104 that is removed from the cellulose fibers 108 during coagulation and subsequent washing in the washing section 180 may be at least partially recovered and reused, respectively, and returned to the storage tank 114 in the next cycle.

[0122] During transport along the fiber receiver 132, the formed bodies 102 (here in the form of cellulose fibers 108) may be washed by the washing section 180 as the washing section 180 provides a washing liquid to remove solvent residues. Thereafter, the formed bodies 102 may be dried.

[0123] Additionally, the compact 102 may be subjected to post-treatments, see the schematic illustration of post-treatment section 134. For example, such post-treatments may include hydroentangling, post-treating, needle treatment, impregnation, steam treatment using steam supplied under pressure, and / or calendering.

[0124] The fiber receiver 132 can feed the compact 102 to a winding device 136, where the compact 102 can be wound. The compact 102 can then be supplied as a rolled shipment to an entity that manufactures products such as wipes or fabrics based on the compact 102.

[0125] Figure 3 shows a cross-section of a cellulose fiber 200 produced by the Lyocell process. The Lyocell-produced cellulose fiber 200 has a smooth, rounded outer surface 202, is uniform, has no visible holes, and is filled with cellulose material. Therefore, those skilled in the art can clearly distinguish the cellulose fiber 200 from cellulose fibers produced by the viscose process (see reference numeral 204 in Figure 4) and cotton cellulose fibers (see reference numeral 206 in Figure 5).

[0126] 4 shows in cross section a cellulose fiber 204 produced by the viscose process. The cellulose fiber 204 is cloud-shaped and has a number of arc-like structures 208 along its periphery.

[0127] 5 shows a cross section of a natural cotton plant cellulose fiber 206. The cellulose fiber 206 is kidney-shaped and has a completely enclosed hollow lumen 210 inside that is free of material.

[0128] Due to the significant geometric and structural differences of the fibers according to Figures 3 to 5, it is possible for a person skilled in the art to clearly determine, for example by microscopy, whether the cellulose fibers are formed by the lyocell process, by the viscose process or naturally in cotton plants.

[0129] Additionally, it should be noted that "comprising" does not exclude other elements or steps, and that the indefinite article "a" or "an" does not exclude a plurality. Furthermore, it should be noted that features or steps described with reference to one of the above embodiments may also be used in combination with other features or steps of other embodiments described above. Reference signs in the claims are not to be construed as limiting.

Claims

1. 1. A method for recycling a blended textile fabric, the method comprising: providing the blended fabric, the blended fabric comprising cellulosic fibers and synthetic fibers, the synthetic fibers comprising at least one synthetic plastic; selectively depleting the synthetic plastic from the cellulosic fibers, thereby partially retaining the synthetic plastic in the blended fabric; after the attenuating step, further processing the attenuated blended fabric containing the partially retained synthetic plastic; Equipped with The further processing step includes producing a regenerated cellulose molded body using a lyocell or viscose process. method.

2. The method of claim 1 , wherein the synthetic plastic is at least one of the group consisting of polyester, polyamide, polyurethane, polyether, and elastane.

3. 3. The method of claim 1 or 2, wherein the blended fabric comprises or consists of cellulose in the form of cotton.

4. 4. The method according to any one of claims 1 to 3, wherein the blended fabric comprises completely or partly residues from clothing manufacturing and / or old clothes.

5. 5. The method of claim 1, further comprising washing the cellulose fibers between the depleting and further processing steps.

6. The depleting step comprises: further comprising the step of completely removing at least one other synthetic plastic from the blended fabric.

6. The method according to any one of claims 1 to 5.

7. The other synthetic plastics include polyester and / or elastane. The method of claim 6.

8. the at least one synthetic plastic comprises a first synthetic plastic; the at least one synthetic plastic comprises a second synthetic plastic; and The depleting step comprises: depleting the first synthetic plastic to a first concentration value; and depleting the second synthetic plastic to a second concentration value; the first density value is different from the second density value; 6. The method according to any one of claims 1 to 5.

9. The depleting step comprises: Mechanical separation; and / or further comprising a chemical separation comprising at least one of the group consisting of hydrolysis, derivatization, and the use of a solvent; 9. The method according to any one of claims 1 to 8.

10. The supplying step includes: providing at least one additional blended fabric containing additional cellulose and at least one additional synthetic plastic, wherein the concentration of the synthetic plastic in the blended fabric and the concentration of the additional synthetic plastic in the additional blended fabric are different such that the resulting plastic composition has at least one predetermined characteristic.

10. The method according to any one of claims 1 to 9.

11. 10. A method for producing a regenerated cellulose molded body according to claim 1, comprising: the regenerated cellulose shaped body is selected from the group comprising filaments, fibers, foils, spheres, or beads; The regenerated cellulose molding contains the cellulose in the depleted blended fabric and the synthetic plastic partially retained; and The regenerated cellulose molding has the following characteristics: The regenerated cellulose molding contains less than 0.5% polyethylene terephthalate (PET) and / or more than 1% polyurethane (PUR) and / or polyamide (PA); At least 2% of the blended textile portion in the regenerated cellulose molding is synthetic plastic; having at least one of Method for producing regenerated cellulose moldings.

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