Activated porous fibers and products containing same

Abstract

At least 5m 2 A composition comprising inorganic fibers having a surface area of ​​0.15 .mu.m / g and an activator incorporated into and / or applied to at least a portion of the inorganic fibers. Products comprising the composition can include fiber assemblies, composite materials, filter elements, catalytic elements, exhaust gas treatment devices and other exhaust system components, and paper. [Selection diagram] Figure 6

Description

[Technical Field]

[0001] This application claims priority to U.S. Provisional Patent Application No. 62 / 652,551, filed April 4, 2018, the contents of which are incorporated herein by reference in their entirety.

[0002] The present disclosure relates to activated fiber compositions comprising porous inorganic fibers and an active agent incorporated into and / or applied to at least a portion of the inorganic fibers, and product forms comprising the activated fiber compositions. [Background technology]

[0003] Many manufacturing, industrial, and other processes produce waste gases that must be treated to some extent before being released into the environment. For example, electricity generation may be produced by burning carbon-based fuels to generate heat, which can then be converted into electricity via a steam turbine. Similarly, concrete and glass manufacturing plants burn fuel to generate heat as part of the manufacturing process. Additionally, internal combustion engines, which may be used in many systems, generate electricity and / or power by burning fuels such as gasoline or diesel fuel. All of these processes can produce waste gases that must be treated to some extent before being released into the environment.

[0004] These exhaust gases may contain carbon monoxide, carbon dioxide, nitrogen oxides, sulfur oxides, hydrogen chloride, hydrogen fluoride, arsenic, boron, lead, mercury, and other harmful gases (e.g., unburned hydrocarbons (“HC”) and volatile organic compounds (“VOC”)) and / or particles. Some or all of these undesirable components of the exhaust gases can be removed by a variety of conventional techniques, many of which involve filters and / or catalytic supports that may physically remove and / or chemically alter the undesirable components before they are discharged into the environment.

[0005] Many of the conventional components for implementing these reduction processes have drawbacks. For example, in certain situations, ceramic honeycomb filter / catalyst supports are used to remove and / or chemically modify undesirable components found in exhaust gases. These supports can be undesirably heavy, have poor heat resistance, and / or be expensive to install and / or operate.

[0006] An example of an industrial process that produces waste gases that must be treated before being released into the environment is fluid catalytic cracking ("FCC"). FCC processes are used to convert high molecular weight hydrocarbons into more valuable short-chain hydrocarbon groups such as gasoline and olefins. FCC processes consume large amounts of energy to generate steam, heat the feedstock, and regenerate the catalyst. FCC processes would benefit from low-cost catalyst support materials that could reduce the amount of energy required to catalyze the feedstock and regenerate the catalyst support material, as well as materials that increase the efficiency of treating the waste gases produced by the FCC process.

[0007] Other industrial processes may also benefit from improved catalyst support materials, such as the synthesis of ethylene oxide using a silver catalyst on alumina; the desulfurization of petroleum using a molybdenum-cobalt catalyst on alumina; the hydrogenation of benzene to cyclohexane using a nickel / platinum catalyst; the production of synthetic gas ("syngas") using a nickel catalyst; the reforming of naphtha using a platinum and rhenium catalyst on alumina; the production of epoxyethane using a silver catalyst on alumina; or the production of sulfuric acid using a vanadium catalyst.

[0008] What is needed are compositions that can be used in many different product forms to produce lightweight, high-temperature resistant, low-cost, and / or energy-efficient components for waste gas treatment systems and other manufacturing / industrial processes. Such compositions and / or product forms may potentially allow existing ceramic substrates, such as spheres, powders, etc., to be replaced with such compositions / product forms. The prior art documents relevant to the invention of this application are as follows (including documents cited in the international phase after the international filing date and documents cited when the invention entered the national phase in other countries). (Prior art document) (Patent document) (Patent Document 1) U.S. Patent Application Publication No. 2015 / 251163 (Patent Document 2) U.S. Patent Application Publication No. 2012 / 0049114 (Patent Document 3) U.S. Patent Application Publication No. 2016 / 0244001 (Patent Document 4) U.S. Patent Application Publication No. 2003 / 106311 [Brief explanation of the drawings]

[0009] Embodiments of the subject matter are disclosed with reference to the accompanying drawings, which are for purposes of illustration only. The subject matter is not limited in its application to the details of construction or the arrangement of components shown in the drawings. Like reference numerals are used to refer to like components unless otherwise specified. [Figure 1A] FIG. 1A is an exemplary embodiment of a product form comprising the activated fiber composition described herein. [Figure 1B] FIG. 1B is an exemplary embodiment of a product form comprising the activated fiber composition described herein. [Figure 1C] FIG. 1C is an exemplary embodiment of a product form comprising the activated fiber composition described herein. [Figure 1D] FIG. 1D is an exemplary embodiment of a product form comprising the activated fiber composition described herein. [Figure 1E] FIG. 1E is an exemplary embodiment of a product form comprising the activated fiber composition described herein. [Figure 1F] FIG. 1F is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 1G] FIG. 1G is an exemplary embodiment of a product form comprising the activated fiber composition described herein. [Figure 1H] FIG. 1H is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 2] FIG. 2 is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 3] FIG. 3 is an exemplary embodiment of an exhaust system including the activated fiber compositions described herein. [Figure 4] FIG. 4 is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 5] FIG. 5 is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 6] FIG. 6 is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 7] FIG. 7 is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 8] FIG. 8 is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 9] FIG. 9 is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 10] FIG. 10 is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 11] FIG. 11 is an exemplary embodiment of a product form comprising the activated fiber compositions described herein. [Figure 12A] FIG. 12A is a photograph of a conventional ceramic honeycomb filter. [Figure 12B] FIG. 12B is a photograph of a conventional ceramic honeycomb filter. [Figure 13] FIG. 13 is a graph showing back pressure generation in the ceramic honeycomb filter shown in FIGS. 12A and 12B. [Figure 14A] FIG. 14A is a graph summarizing the results of Example 1. [Figure 14B] FIG. 14B is a graph summarizing the results of Example 1. [Figure 15A] FIG. 15A is a graph summarizing the results of Example 2. [Figure 15B] FIG. 15B is a graph summarizing the results of Example 2. [Figure 16A] FIG. 16A is a graph summarizing the results of Example 3. [Figure 16B]FIG. 16A is a graph summarizing the results of Example 3. Summary of the Invention

[0010] Activated fiber compositions are provided that include porous inorganic fibers and an activator incorporated into and / or applied to at least a portion of the inorganic fibers. In certain embodiments, the activated fiber compositions include: (a)(i) at least 5 m 2 / g, (ii) a porosity of at least 5% by volume, or (iii) a pore volume of at least 0.005 mL / g, and (b) an active agent incorporated into and / or applied to at least a portion of the inorganic fibers.

[0011] Various product forms are also provided that include the activated fiber compositions disclosed herein, including fiber assemblies, composite materials, filter elements, catalytic elements, exhaust system components, catalyst support materials, paper, blanket These may include, but are not limited to, mats, felts, fibers, films, and the like.

[0012] The activated fiber compositions and resulting product forms offer advantages over conventional product forms. For example, ceramic honeycomb filter / catalyst supports can be heavy, susceptible to damage during handling and installation, relatively poor temperature resistance, and relatively expensive. Filter / catalyst elements made from the activated fiber compositions disclosed herein can be lighter, less susceptible to damage, more temperature resistant, and / or less expensive than conventional ceramic honeycomb products. These advantages apply equally to the other product forms disclosed herein, as well as to the many product forms that can be made from the activated fiber compositions disclosed herein. DETAILED DESCRIPTION OF THE INVENTION

[0013] With respect to weight percent of the compositions disclosed herein, it will be understood that the total weight percent of the composition cannot exceed 100%. For example, a composition comprising 5%-94% by weight of component X, 0-55% or more by weight of component Y, and 0-85% or more by weight of component Z will not exceed 100% by weight, with the amount of each component being adjusted to include the desired amount of each component such that the total composition does not exceed 100% by weight.

[0014] When ranges of values ​​are set forth in this disclosure (such as, but not limited to, "X to Y," "at least X," or "up to Y"), all values ​​within the range, including the endpoints, are considered to be stated and disclosed as possible values ​​for the associated property, or as the minimum and / or maximum possible alternatives of a narrower range (of course, the minimum value does not exceed the maximum value of the particular range). For example, a range of "1 to 10" should be read as indicating all possible numbers along a continuum from 1 to 10. The inventors are considered to have designated each and every value within the range, and the inventors own the entire range and all values ​​within it. While alternative values ​​and / or narrower ranges may be expressly set forth herein, the present disclosure should not be construed as limited to only the specifically disclosed values ​​and / or ranges in accordance with the understanding set forth in this paragraph.

[0015] porous inorganic fiber The inorganic fibers may comprise one or more types of inorganic fibers, alone or in combination. Any inorganic fibers that can be made porous and contain an active agent while maintaining their physical properties may be used. In certain embodiments, the inorganic fibers may comprise at least one of inorganic oxide fibers, ceramic fibers, refractory ceramic fibers, polycrystalline wool fibers, alumina fibers, high alumina fibers, glass fibers, silica fibers, boehmite fibers, low biopersistence fibers, alkaline earth silicate fibers, calcia-alumina fibers, zirconia fibers, or titania fibers.

[0016] In certain embodiments, the inorganic fibers can be produced by any known method for producing inorganic fibers. In certain embodiments, the inorganic fibers may be produced via a sol-gel process. Exemplary sol-gel fiber production processes include: - Optionally, forming a solution or sol containing the desired ratio of metal salts or compounds. • The inclusion of spinning aids such as organic polymers in the solution or sol to provide the necessary rheology for fiberization. ● Inclusion in the solution or sol of other materials deemed desirable in the final product (including, but not limited to, a phase change inhibitor or metal oxide powder for enhanced performance; at least one activator as described herein; and / or a dopant to improve adhesion of the activator to the inorganic fibers). ● These include, but are not limited to: o "Spinning" is a process in which a solution or sol is provided on a rotating disk which can be extruded into fibers by centrifugal force; providing the solution or sol to an extrusion nozzle (or assembly thereof) and extruding the solution or sol as continuous or discontinuous fibers with or without a damping airflow; and Electrospinning process fiberizing the material obtained from the solution or sol by an established fiberization method, comprising: • The resulting fibers are subjected to a drying and calcination process to remove water, residual organic components and volatile salt anions. • The fibre is further heat treated to develop a crystalline structure.

[0017] Any means can be used to rotate the liquid. For example, the spinning solution can be placed in a centrifugal discharge spinner in the form of a cylinder with multiple nozzle orifices on its periphery. As the spinner rotates at high speed, the spinning solution is expelled through the nozzle orifices into a dry atmosphere, converting the liquid into fibers. The resulting fiber material is then dried to remove water and calcined, i.e., heated at high temperatures, e.g., 700°C to 1500°C in the case of silica fibers, to produce polycrystalline fibers. The fibers can be 5 to 200 mm in length. 2 BET surface area on the order of 60 to 140 m / g, in certain embodiments 2 / g, and a porosity of 5% to 60%.

[0018] Alternatively, the liquid can be placed in a vessel with a nozzle orifice and allowed to fall onto a rapidly rotating disk located below the vessel. The falling spinning solution is then blown into a dry atmosphere, where it is converted into fibers or fibres. The resulting fibres are then dried and heated as described above. In another example, the liquid can be placed in a vessel with a nozzle orifice and allowed to fall while a high-velocity gas stream is applied transversely. The falling spinning solution is then blown into a dry atmosphere, where it is converted into fibres.

[0019] Before forcing the solution through the orifice, the solution can be heated to 30-40°C. Preheating allows for rapid evaporation of the solvent, thus allowing the oxide precursor to assume a fibrous form more quickly.

[0020] These sol-gel processes introduce controlled porosity by using aqueous sols containing non-ionic surfactants such as siloxanes, which introduce micelles into the green fibers and leave pores of controlled dimensions in the final sintered fiber structure.

[0021] In certain embodiments, the spinning temperature may be 25° C. and the surfactant may have a cloud point in the spinning solution of less than 45° C. As the spinning temperature increases, the acceptable cloud point of the surfactant increases. For example, if the spinning temperature is 50° C., the cloud point of the surfactant will be less than 70° C. In certain embodiments, the cloud point of the surfactant is at least 5° C. above the spinning temperature, but not more than 15° C. above the spinning temperature.

[0022] As used herein, the term "spinning temperature" refers to the maximum temperature reached by the spinning solution or sol during the extrusion and drawdown (stretching) stages of the fiber formation process. Thus, extrusion of the solution or sol into a heated environment results in an increase in the temperature of the solution or sol during drawdown (stretching) into green fiber. The spinning temperature in such a case is the maximum temperature reached by the solution or sol (green fiber) before the drawdown (stretching) is complete. The spinning temperature may be the wet-bulb temperature of the attenuated air.

[0023] The "cloud point of a surfactant" referred to herein is the temperature at which a spinning solution containing the surfactant becomes cloudy when heated. Aqueous solutions of nonionic surfactants become cloudy when heated. These cloud points are determined by immersing a boiling tube containing 10 ml of the solution in a cold stirred water bath and heating at a rate of 1°C per minute. The solution in the tube is not stirred or stirred very gently (to avoid air bubbles) with a spatula. The solution may become cloudy over a narrow temperature range of 1-2°C, and the cloudy temperature or cloud point may be recorded.

[0024] Several chemical types of surfactants can be used, and examples of such chemical types are alkyl ethoxylates, alkylphenyl-ethoxylates, polypropylene oxide-polyethylene oxide block copolymers, comb siloxane-polyethoxylate copolymers, and polyethoxylated amines. It will be understood that within each of these chemical classes of surfactants, some may have cloud points that are too high to be useful in the process, as well as some that are useful. However, it is a matter of simple routine experimentation to measure the cloud point of a surfactant to determine whether it is suitable for use in the process. Blends or mixtures of surfactants can be used to provide the appropriate cloud point.

[0025] The amount of surfactant used in the spinning solution can vary within a wide range, but is typically at least 1% by weight based on the spinning solution. The amount of surfactant can be from 1% to 15% by weight of the solution, and in certain embodiments, from 3% to 10% by weight of the solution.

[0026] In addition to surfactants, the spinning solution or sol may contain precursors of fiber stabilizing and / or sintering additives. In any embodiment, the surfactant itself may be a source of phase stabilizers or sintering agents in the resulting fibers. For example, if a siloxane copolymer is used as the surfactant, silica will form in the fibers when the latter is heated, decomposing the silicon oxide precursor into silica that will form the fibers. Therefore, a stabilizer precursor that can be incorporated into the spinning solution or sol is silica, such as a silica sol for silica fibers.

[0027] Calcination of the fiber precursor begins at a low temperature (e.g., 150°C) and increases to a final high-temperature condition (e.g., 700°C-1500°C) to ensure the fiber has heat resistance and / or sufficient mechanical strength. Different atmospheres in the heat treatment furnace can be used to support the heat treatment process, such as by adding steam to the furnace. Using different heating rates (sometimes called "ramp rates") or holding a constant temperature for a certain period of time can affect the calcination process, such as by altering the concentration or size of crystallites in the fiber. U.S. Patent No. 3,950,478 provides information in this regard, the entire disclosure of which is incorporated herein by reference.

[0028] The concentration and size of crystallites present in the finished inorganic fibers can also be controlled by adding crystal growth inhibitors and / or nucleation "seeds" with the desired crystallography. In certain embodiments, this may involve controlling the crystallographic composition to ensure low surface energy and maximize surface acidity while maintaining porosity. Crystal growth inhibitors may include particulates that prevent grain boundary movement and thus prevent the formation of large crystals (known as "Zener pinning"). In certain embodiments, silica, magnesia, zirconia, and / or yttria particles can be used as crystal growth inhibitors for alumina fibers. In certain embodiments, alumina, magnesia, and / or yttria particles can be used as crystal growth inhibitors for zirconia fibers. In certain embodiments, phosphates can be used as crystal growth inhibitors in titania fibers. Nucleation seeds with the desired crystallography can lower the activation energy of the target crystalline phase, thereby promoting its preferential growth in the fiber during calcination. In certain embodiments, low concentrations of iron, copper, and / or crystalline alumina can promote the crystallographic growth of alumina fibers. In certain embodiments, low concentrations of rutile titania and / or thorlite can promote the crystallographic growth of zirconia fibers. In these embodiments, "low concentration" can mean less than 1 weight percent, e.g., 0.1 weight percent or less.

[0029] In certain embodiments, the inorganic fibers may include ceramic fibers. Suitable ceramic fibers include, but are not limited to, alumina fibers, alumino-silicate fibers, alumina-boria-silicate fibers, alumina-zirconia-silicate fibers, zirconia-silicate fibers, zirconia fibers, and similar fibers. Suitable alumina-silicate ceramic fibers are commercially available from Unifrax ILL (Tonawanda, NY, USA) under the registered trademark FIBERFRAX. FIBERFRAX refractory ceramic fibers include a fiberized product of 45 to 75 weight percent alumina and 25 to 55 weight percent silica. FIBERFRAX fibers exhibit operating temperatures of up to 1540°C and melting points of up to 1870°C.

[0030] In certain embodiments, the alumino-silicate fibers can include 40 weight percent to 60 weight percent Al2O3 and 60 weight percent to 40 weight percent SiO2; 50 weight percent Al2O3 and 50 weight percent SiO2; 30 weight percent Al2O3 and 70 weight percent SiO2; 45 to 51 weight percent Al2O3 and 46 to 52 weight percent SiO2; or 30 to 70 weight percent Al2O3 and 30 to 70 weight percent SiO2.

[0031] In certain embodiments, the inorganic fibers can include alumino-silica-magnesia glass fibers that include 64 weight percent to 66 weight percent SiO 2 , 24 weight percent to 25 weight percent A 12 O 3 , and 9 weight percent to 10 weight percent MgO.

[0032] Suitable examples of low biopersistent fibers include, but are not limited to, the fibers disclosed in U.S. Patent Nos. 6,953,757, 6,030,910, 6,025,288, 5,874,375, 5,585,312, 5,332,699, 5,714,421, 7,259,118, 7,153,796, 6,861,381, 5,955,389, 5,928,975, 5,821,183, and 5,811,360, the disclosures of which are incorporated herein by reference.

[0033] Suitable low biopersistence fibers include, but are not limited to, alkaline earth silicate fibers such as calcia-magnesia-silicate fibers or magnesia-silicate fibers, calcia-aluminate fibers, potassium-calcia-aluminate fibers, potassium-alumina-silicate fibers, or sodium-alumina-silicate fibers.

[0034] In certain embodiments, alkaline earth silicate fibers may comprise a fiberization product of a mixture of magnesium and silica oxides. These fibers are commonly referred to as magnesium silicate fibers. The magnesium silicate fibers may comprise a fiberization product of 60-90 weight percent silica, 0-35 weight percent or more magnesia, and 5 weight percent or less impurities; 65-86 weight percent silica, 14-35 weight percent magnesia, and 5 weight percent or less impurities; or 70-86 weight percent silica, 14-30 weight percent magnesia, and 5 weight percent or less impurities. Suitable magnesium silicate fibers are commercially available from Unifrax I LLC (Tonawanda, NY) under the registered trademark ISOFRAX. Commercially available ISOFRAX fibers typically comprise a fiberization product of 70-80 weight percent silica, 18-27 weight percent magnesia, and 4 weight percent or less impurities. In certain embodiments, the fibers comprise a fiberization product of 85 weight percent silica and 15 weight percent magnesia.

[0035] In certain embodiments, alkaline earth silicate fibers may comprise the fiberization product of a mixture of calcium, magnesium, and silica oxides. These fibers are commonly referred to as calcia-magnesia-silicate fibers. In certain embodiments, the calcia-magnesia-silicate fibers comprise 45 to 90 weight percent silica, 0 to greater than 45 weight percent calcia, 0 to greater than 35 weight percent magnesia, and 10 weight percent or less impurities; or 71.25 to 85 weight percent silica, 0 to 20 weight percent magnesia, 5 to 28.75 weight percent calcia, and 0 to 5 weight percent zirconia.

[0036] Suitable calcia-magnesia-silicate fibers include those commercially available from Unifrax I LLC (Tonawanda, NY) under the registered trademark INSULFRAX. In certain embodiments, the calcia-magnesia-silicate fibers comprise a fiberized product of 61-67 weight percent silica, 27-33 weight percent calcia, and 2-7 weight percent magnesia. In certain embodiments, the calcia-magnesia-silicate fibers comprise 79 weight percent silica, 18 weight percent calcia, and 3 weight percent magnesia. Other suitable calcia-magnesia-silicate fibers include those commercially available from Thermal Ceramics (Augusta, GA) under the trade names SUPERWOOL 607, SUPERWOOL 607 MAX, and SUPERWOOL HT. SUPERWOOL 607 fiber contains 60-70 weight percent silica, 25-35 weight percent calcia, 4-7 weight percent magnesia, and trace amounts of alumina. SUPERWOOL 607 MAX fiber contains 60-70 weight percent silica, 16-22 weight percent calcia, 12-19 weight percent magnesia, and trace amounts of alumina. SUPERWOOL HT fiber contains 74 weight percent silica, 24 weight percent calcia, and trace amounts of magnesia, alumina, and iron oxide.

[0037] In certain embodiments, alkaline earth silicate fibers may comprise a fiberization product of a mixture of calcium and aluminum oxides. In certain embodiments, at least 90 weight percent of the calcia-aluminate fibers comprise a fiberization product of 50 to 80 weight percent calcia, 20 to less than 50 weight percent alumina, and 10 weight percent or less impurities; or 50 to 80 weight percent alumina, 20 to less than 50 weight percent calcia, and 10 weight percent or less impurities. In certain embodiments, alkaline earth silicate fibers may comprise a fiberization product of a mixture of potassium, calcium, and aluminum oxides ("potassium-calcium-aluminate fibers"). In certain embodiments, the potassium-calcium-aluminate fibers comprise a fiberization product of 10 to 50 weight percent calcia, 50 to 90 weight percent alumina, 0 to more than 10 weight percent potassium, and 10 weight percent or less impurities.

[0038] In certain embodiments, the alkaline earth silicate fibers may comprise the fiberization product of a mixture of magnesium, silica, lithium, and strontium oxides. In certain embodiments, the alkaline earth silicate fibers may comprise 65 to 86 weight percent silica, 14 to 35 weight percent magnesia, lithium oxide, and strontium oxide; or 65 to 86 weight percent silica, 14 to 35 weight percent magnesia, greater than 0 to 1 weight percent lithium oxide, and greater than 0 to 5 weight percent strontium oxide.

[0039] In certain embodiments, the alkaline earth silicate fibers may comprise the fiberization product of a mixture of magnesium, silica, lithium, and strontium oxides. In certain embodiments, the alkaline earth silicate fibers comprise 65 to 86 weight percent silica, 14 to 35 weight percent magnesia, lithium oxide, and strontium oxide; 65 to 86 weight percent silica, 14 to 35 weight percent magnesia, 0 to more than 1 weight percent lithium oxide, and 0 to more than 5 weight percent strontium oxide; 14 to 35 weight percent magnesia, and 0 to more than 0.45 weight percent lithium oxide; 14 to 35 weight percent magnesia, and 0 to more than 5 weight percent strontium oxide; or 70 weight percent or more silica, magnesia, and 0 to more than 10 weight percent iron oxide.

[0040] Suitable silica fibers include leached glass fibers available from BELChem Fiber Materials GmbH, Germany under the trademark BELCOTEX, from Hitco Carbon Composites, Inc., Gardena, California under the registered trademark REFRASIL, and from Polotsk-Steklovolokno, Republic of Belarus under the designation PS-23®.

[0041] BELCOTEX fiber is a standard type of staple fiber ply yarn. These fibers have an average fineness of 550 tex and are typically made from silicic acid modified with alumina. BELCOTEX fiber is amorphous and typically contains 94.5% silica, 4.5% alumina, less than 0.5% sodium oxide, and less than 0.5% other components. These fibers have an average fiber diameter of 9 microns and a melting point in the range of 1500°C to 1550°C. These fibers are heat resistant to temperatures up to 1100°C and are typically shot-free and binder-free.

[0042] Like BELCOTEX fibers, REFRASIL fibers are amorphous leached glass fibers with a high silica content, providing thermal insulation for applications in the temperature range of 1000°C to 1100°C. These fibers are 6 to 13 microns in diameter and have a melting point of 1700°C. After leaching, the fibers typically have a silica content of 95 percent by weight. Alumina may be present in amounts of 4 percent by weight, and other components may be present in amounts of 1 percent or less.

[0043] Polotsk-Steklovolokno's PS-23® fibers are amorphous glass fibers with a high silica content, suitable for thermal insulation in applications requiring resistance to at least 1000°C. These fibers have fiber lengths ranging from 5 to 20 mm and fiber diameters of 9 microns. These fibers, like REFRASIL fibers, have a melting point of 1700°C.

[0044] In certain embodiments, the glass fibers may comprise a fiberization product of 63 to 67 weight percent SiO2, 3 to 5 weight percent Al2O3, 4 to 7 weight percent CaO, 2 to 4 weight percent MgO, 4 to 7 weight percent B2O3, 14 to 17 weight percent Na2O, greater than 0 to 2 weight percent K2O, greater than 0 to 1 weight percent ZnO, greater than 0 to 1 weight percent Fe2O3, greater than 0 to 1 weight percent BaO, and greater than 0 to 1 weight percent F2.

[0045] In certain embodiments, the glass fibers may include E-glass fibers, which may include 52 weight percent to 56 weight percent SiO2, 16 weight percent to 25 weight percent CaO, 12 weight percent to 16 weight percent Al2O3, 5 weight percent to 10 weight percent B2O3, up to 5 weight percent MgO, up to 2 weight percent sodium oxide, potassium oxide, and trace amounts of iron oxide and fluoride, such as 55 weight percent SiO2, 15 weight percent Al2O3, 7 weight percent B2O3, 3 weight percent MgO, 19 weight percent CaO, and trace amounts of the above materials.

[0046] Suitable glass fibers with physical properties such as high specific surface area, high tensile strength, and consistent glass chemistry and purity are available from Unifrax Specialty Fibers (Tonawanda, NY). These fibers are produced by a rotary and flame-attenuated manufacturing process. Average fiber diameters range from very fine, 0.25 μm to 5.0 μm. Examples of glass fiber compositions are listed in Table 1 below. [Table 1]

[0047] Glass fibers can be converted to high-silica fibers by extracting monovalent, divalent, and trivalent glass-forming metal oxide components, leaving fibers essentially composed of silica, with such metal oxides contained in proportions of no more than 10 parts, or even no more than 1 or 2 parts, per 90 parts of SiO₂, with the remaining oxide portion being SiO₂. This is accomplished by leaching the fibers, either in loose mass or in processed form, with an acid other than phosphoric or phosphoric acid that attacks SiO₂ for a time and temperature sufficient to extract substantially all of the oxides other than silica. The treated fibers are then washed until substantially acid-free and, if necessary, heated at elevated temperatures to dehydrate and shrink the fibers. The above process shrinks the fibers both in diameter and lengthwise.

[0048] Suitable leaching acids include, for example, HCl, H2SO4, HNO3, acetic acid, chloroacetic acid, and chlorinated low molecular weight fatty acids, such as trichloroacetic acid. Acid strength can vary over a wide range, for example, from 0.1 N to over 5 N. The leaching process can be carried out at elevated temperatures ranging from 100°F up to the boiling point of the acid, or above the boiling point by conducting the leaching in an autoclave under superatmospheric pressure.

[0049] It may be desirable to shrink the fibers by dehydration at high temperatures for a time sufficient to remove the water of hydration and adsorbed water without materially shrinking the fibers, e.g., by heating to a temperature of 400°F to 500°F for a time sufficient to remove substantially all the water of hydration and all the adsorbed water.

[0050] Borosilicate glass fibers can be readily leached with acid to remove metal oxides other than silica and can be dehydrated by heating to temperatures above 1000°F, preferably in the range of 1400°F to 1600°F. By properly controlling the acid extraction process, the resulting fibers after calcination contain a high silica content and can be 90% or 99.9% silica as determined by hydrofluoric acid extraction.

[0051] Methods for preparing silica fibers are disclosed in U.S. Pat. Nos. 2,215,039, 2,221,709, 2,461,841, 2,491,761, 2,500,092, 2,624,658, 2,635,390, 2,686,954, 2,718,461, and 2,730,475, the entire disclosures of which are incorporated herein by reference.

[0052] In certain embodiments, the inorganic fibers may comprise refractory ceramic fibers comprising a fiberization product of 45 to 75 weight percent alumina and 25 to 55 weight percent silica.

[0053] In certain embodiments, the inorganic fibers may include alkaline earth silicate fibers containing 60 to 90 weight percent silica, 0 to greater than 35 weight percent magnesia, and 5 weight percent or less of impurity fiberization products.

[0054] In certain embodiments, the inorganic fibers may include alkaline earth silicate fibers containing 45 to 90 weight percent silica, 0 to greater than 45 weight percent calcia, 0 to greater than 35 weight percent magnesia, and 10 weight percent or less of impurity fiberization products.

[0055] In certain embodiments, the inorganic fibers may include alkaline earth silicate fibers, including fiberization products of calcia and silica.

[0056] In certain embodiments, the inorganic fibers can include calcia-alumina fibers comprising 20 to 80 weight percent calcia and 20 to 80 weight percent alumina.

[0057] In certain embodiments, the inorganic fibers may include silica fibers containing 90 weight percent or more of silica.

[0058] In certain embodiments, the inorganic fibers may include alumina fibers containing 90 weight percent or more of alumina.

[0059] In certain embodiments, the inorganic fibers may include polycrystalline wool fibers containing a fiberization product of 95-97 weight percent alumina and 3 to 5 weight percent silica.

[0060] In certain embodiments, the inorganic fibers may be present in the activated fiber composition in an amount of 20 to 100 weight percent, based on the total weight of the activated fiber composition. In embodiments in which the inorganic fibers include an activator incorporated therein, such inorganic fibers may comprise up to 100 weight percent of the activated fiber composition, based on the total weight of the activated fiber composition. In certain embodiments, the inorganic fibers may be present in the activated fiber composition in an amount such that the amount of inorganic fibers present in the activated fiber composition and the amount of activator present in the activated fiber composition together equal the total weight of the activated fiber composition. In certain embodiments, the inorganic fibers may be present in the activated fiber composition in an amount such that the amount of inorganic fibers present in the activated fiber composition, the amount of activator present in the activated fiber composition, and the amount of any other components described herein present in the composition together equal the total weight of the activated fiber composition.

[0061] In certain embodiments, the inorganic fibers may be present in the activated fiber composition in an amount of 20 to 99 weight percent, 20 to 98 weight percent, 20 to 97 weight percent, 20 to 96 weight percent, 20 to 95 weight percent, 20 to 94 weight percent, 20 to 93 weight percent, 20 to 92 weight percent, 20 to 91 weight percent, 20 to 90 weight percent, 20 to 85 weight percent, 20 to 80 weight percent, 20 to 75 weight percent, 20 to 70 weight percent, 20 to 65 weight percent, 20 to 60 weight percent, 20 to 55 weight percent, or 20 to 50 weight percent, based on the total weight of the activated fiber composition.

[0062] In certain embodiments, the inorganic fibers may be present in the activated fiber composition in an amount of 25 to 99 weight percent, 25 to 98 weight percent, 25 to 97 weight percent, 25 to 96 weight percent, 25 to 95 weight percent, 25 to 94 weight percent, 25 to 93 weight percent, 25 to 92 weight percent, 25 to 91 weight percent, 25 to 90 weight percent, 25 to 85 weight percent, 25 to 80 weight percent, 25 to 75 weight percent, 25 to 70 weight percent, 25 to 65 weight percent, 25 to 60 weight percent, 25 to 55 weight percent, or 25 to 50 weight percent, based on the total weight of the activated fiber composition.

[0063] In certain embodiments, the inorganic fibers may be present in the activated fiber composition in an amount of 30 to 99 weight percent, 30 to 98 weight percent, 30 to 97 weight percent, 30 to 96 weight percent, 30 to 95 weight percent, 30 to 94 weight percent, 30 to 93 weight percent, 30 to 92 weight percent, 30 to 91 weight percent, 30 to 90 weight percent, 30 to 85 weight percent, 30 to 80 weight percent, 30 to 75 weight percent, 30 to 70 weight percent, 30 to 65 weight percent, 30 to 60 weight percent, 30 to 55 weight percent, or 30 to 50 weight percent, based on the total weight of the activated fiber composition.

[0064] In certain embodiments, the inorganic fibers may be present in the activated fiber composition in an amount of 35 to 99 weight percent, 35 to 98 weight percent, 35 to 97 weight percent, 35 to 96 weight percent, 35 to 95 weight percent, 35 to 94 weight percent, 35 to 93 weight percent, 35 to 92 weight percent, 35 to 91 weight percent, 35 to 90 weight percent, 35 to 85 weight percent, 35 to 80 weight percent, 35 to 75 weight percent, 35 to 70 weight percent, 35 to 65 weight percent, 35 to 60 weight percent, 35 to 55 weight percent, or 35 to 50 weight percent, based on the total weight of the activated fiber composition.

[0065] In certain embodiments, the inorganic fibers may be present in the activated fiber composition in an amount of 40 to 99 weight percent, 40 to 98 weight percent, 40 to 97 weight percent, 40 to 96 weight percent, 40 to 95 weight percent, 40 to 94 weight percent, 40 to 93 weight percent, 40 to 92 weight percent, 40 to 91 weight percent, 40 to 90 weight percent, 40 to 85 weight percent, 40 to 80 weight percent, 40 to 75 weight percent, 40 to 70 weight percent, 40 to 65 weight percent, 40 to 60 weight percent, 40 to 55 weight percent, or 40 to 50 weight percent, based on the total weight of the activated fiber composition.

[0066] In certain embodiments, the inorganic fibers may be present in the activated fiber composition in an amount of 45 to 99 weight percent, 45 to 98 weight percent, 45 to 97 weight percent, 45 to 96 weight percent, 45 to 95 weight percent, 45 to 94 weight percent, 45 to 93 weight percent, 45 to 92 weight percent, 45 to 91 weight percent, 45 to 90 weight percent, 45 to 85 weight percent, 45 to 80 weight percent, 45 to 75 weight percent, 45 to 70 weight percent, 45 to 65 weight percent, 45 to 60 weight percent, 45 to 55 weight percent, or 45 to 50 weight percent, based on the total weight of the activated fiber composition.

[0067] In certain embodiments, the inorganic fibers may be present in the activated fiber composition in an amount of 50 to 99 weight percent, 50 to 98 weight percent, 50 to 97 weight percent, 50 to 96 weight percent, 50 to 95 weight percent, 50 to 94 weight percent, 50 to 93 weight percent, 50 to 92 weight percent, 50 to 91 weight percent, 50 to 90 weight percent, 50 to 85 weight percent, 50 to 80 weight percent, 50 to 75 weight percent, 50 to 70 weight percent, 50 to 65 weight percent, 50 to 60 weight percent, or 50 to 55 weight percent, based on the total weight of the activated fiber composition.

[0068] In certain embodiments, the inorganic fibers may include first inorganic fibers and second inorganic fibers. The first inorganic fibers may have a porosity that is different from the porosity of the second inorganic fibers. The first inorganic fibers may have an average fiber diameter that is different from the average fiber diameter of the second inorganic fibers. The first inorganic fibers may have an average fiber length that is different from the average fiber length of the second inorganic fibers. The first inorganic fibers may have a composition that is different from the composition of the second inorganic fibers.

[0069] In certain embodiments, the inorganic fibers have a median fiber diameter of 0.25 to 20 μm, 0.25 to 18 μm, 0.25 to 16 μm, 0.25 to 14 μm, 0.25 to 12 μm, 0.25 to 10 μm, 0.25 to 9 μm, 0.25 to 8 μm, 0.25 to 7 μm, 0.25 to 6 μm, or 0.25 to 5 μm.

[0070] In certain embodiments, the inorganic fibers have a median fiber diameter of 0.5 to 20 μm, 0.5 to 18 μm, 0.5 to 16 μm, 0.5 to 14 μm, 0.5 to 12 μm, 0.5 to 10 μm, 0.5 to 9 μm, 0.5 to 8 μm, 0.5 to 7 μm, 0.5 to 6 μm, or 0.5 to 5 μm.

[0071] In certain embodiments, the inorganic fibers have a median fiber diameter of 1 to 20 μm, 1 to 18 μm, 1 to 16 μm, 1 to 14 μm, 1 to 12 μm, 1 to 10 μm, 1 to 9 μm, 1 to 8 μm, 1 to 7 μm, 1 to 6 μm, or 1 to 5 μm.

[0072] In certain embodiments, the inorganic fibers have a median fiber diameter of 1.5 to 20 μm, 1.5 to 18 μm, 1.5 to 16 μm, 1.5 to 14 μm, 1.5 to 12 μm, 1.5 to 10 μm, 1.5 to 9 μm, 1.5 to 8 μm, 1.5 to 7 μm, 1.5 to 6 μm, or 1.5 to 5 μm.

[0073] In certain embodiments, the inorganic fibers have a median fiber diameter of 2 to 20 μm, 2 to 18 μm, 2 to 16 μm, 2 to 14 μm, 2 to 12 μm, 2 to 10 μm, 2 to 9 μm, 2 to 8 μm, 2 to 7 μm, 2 to 6 μm, or 2 to 5 μm.

[0074] In certain embodiments, the inorganic fibers have a median fiber diameter of 2.5 to 20 μm, 2.5 to 18 μm, 2.5 to 16 μm, 2.5 to 14 μm, 2.5 to 12 μm, 2.5 to 10 μm, 2.5 to 9 μm, 2.5 to 8 μm, 2.5 to 7 μm, 2.5 to 6 μm, or 2.5 to 5 μm.

[0075] In certain embodiments, the inorganic fibers have a median fiber diameter of 3 to 20 μm, 3 to 18 μm, 3 to 16 μm, 3 to 14 μm, 3 to 12 μm, 3 to 10 μm, 3 to 9 μm, 3 to 8 μm, 3 to 7 μm, 3 to 6 μm, or 3 to 5 μm.

[0076] The standard deviation of the median fiber diameter can be 2 μm or less, 1.8 μm or less, 1.6 μm or less, 1.4 μm or less, 1.2 μm or less, 1 μm or less, 0.9 μm or less, 0.8 μm or less, 0.7 μm or less, 0.6 μm or less, or 0.5 μm or less.

[0077] In some embodiments, the activated fiber composition may be formed from low-respirability fibers, i.e., the activated fiber composition may include less than 0.1 weight percent of fibers having a diameter of less than 3 μm. In some embodiments, the inorganic fibers have a median fiber diameter of 3-5 μm, and less than 0.1 weight percent of the inorganic fibers have a diameter of less than 3 μm.

[0078] In certain embodiments, the inorganic fibers can have a melting point of 500° C. or higher, 600° C. or higher, 700° C. or higher, 800° C. or higher, 900° C. or higher, 1000° C. or higher, 1100° C. or higher, 1200° C. or higher, 1300° C. or higher, 1400° C. or higher, 1500° C. or higher, 1600° C. or higher, 1700° C. or higher, 1800° C. or higher, 1900° C. or higher, or 2000° C. In certain embodiments, the inorganic fibers are stable at temperatures of 500° C. or higher, 600° C. or higher, 700° C. or higher, 800° C. or higher, 900° C. or higher, 1000° C. or higher, 1100° C. or higher, 1200° C. or higher, or 1300° C. or higher. For an inorganic fiber to be "stable" at a particular temperature means that after heating to that temperature for 30 minutes, the pore size and surface area are within 5% of the pre-heat measurements.

[0079] In the process for producing suitable inorganic fibers, porosity can be introduced into the fiber structure by including a nonionic surfactant in the solution phase containing the precursor metal salt, as described in more detail below and disclosed in European Patent Application No. 0318203 and U.S. Patent No. 5,176,857, the entire disclosures of which are incorporated herein by reference. Examples of surfactants include alkyl ethoxylates, alkylphenyl ethoxylates, polypropylene oxide-polyethylene oxide block copolymers, comb-type siloxane-polyethoxylate copolymers, and polyethoxylated amines. By controlling the addition of surfactants and the resulting micelle size in the solution or sol, the volume and size of the pores in the fibrous product can be directly controlled. Pore diameters can be controlled down to the tens of angstroms level. The presence of porosity drives the surface area-to-volume ratio to values ​​higher than that of the fiber alone.

[0080] In certain embodiments, the inorganic fibers are (i) at least 15 m 2 / g, (ii) a porosity of at least 10% by volume, or (iii) a pore volume of at least 0.01 mL / g.

[0081] In certain embodiments, the inorganic fibers are (i) at least 30 m2 / g, (ii) a porosity of at least 15% by volume, or (iii) a pore volume of at least 0.03 mL / g.

[0082] In certain embodiments, the inorganic fibers are (i) at least 45 m 2 / g, (ii) a porosity of at least 20% by volume, or (iii) a pore volume of at least 0.05 mL / g.

[0083] In certain embodiments, the inorganic fibers are (i) at least 60 m 2 / g, (ii) a porosity of at least 25% by volume, or (iii) a pore volume of at least 0.07 mL / g.

[0084] In certain embodiments, the inorganic fibers are (i) at least 75 m 2 / g, (ii) a porosity of at least 30% by volume, or (iii) a pore volume of at least 0.09 mL / g.

[0085] In certain embodiments, the inorganic fibers are (i) at least 90 mm 2 / g, (ii) a porosity of at least 35% by volume, or (iii) a pore volume of at least 0.1 mL / g.

[0086] In certain embodiments, the inorganic fibers are (i) 5 to 220 m 2 / g, (ii) a porosity of 5 to 60 volume %, or (iii) a pore volume of 0.005 to 0.25 mL / g.

[0087] In certain embodiments, the inorganic fibers are (i) 90 to 220 mm 2 / g, (ii) a porosity of 35 to 60 volume %, or (iii) a pore volume of 0.1 to 0.25 mL / g.

[0088] In certain embodiments, the inorganic fibers are at least 5 m 2 / g, at least 15m 2 / g, at least 30m 2 / g, at least 45m 2 / g, at least 60m 2 / g, at least 75m 2 / g, or at least 90m 2 / g of surface area.

[0089] In certain embodiments, the inorganic fibers are up to 220 mm 2 / g, up to 200m 2 / g, up to 180m 2 / g, up to 160m 2 / g, up to 140m 2 / g, up to 120m 2 / g, or up to 100m 2 / g of surface area.

[0090] In certain embodiments, the inorganic fibers have a thickness of 5 to 220 mm. 2 / g, 5-200m 2 / g, 5-180m 2 / g, 5-160m 2 / g, 5-140m 2 / g, 5-120m 2 / g, or 5 to 100m 2 / g of surface area.

[0091] In certain embodiments, the inorganic fibers have a thickness of 15 to 220 mm. 2 / g, 15-200m 2 / g, 15-180m 2 / g, 15-160m 2 / g, 15-140m 2 / g, 15-120m 2 / g, or 15 to 100 m 2 / g of surface area.

[0092] In certain embodiments, the inorganic fibers have a thickness of 30 to 220 mm. 2 / g, 30-200m 2 / g, 30-180m 2 / g, 30-160m 2 / g, 30-140m 2 / g, 30-120m 2 / g, or 30-100m 2 / g of surface area.

[0093] In certain embodiments, the inorganic fibers have a thickness of 45 to 220 mm. 2 / g, 45-200m 2 / g, 45-180m 2 / g, 45-160m 2 / g, 45-140m 2 / g, 45-120m 2 / g, or 45-100m 2 / g of surface area.

[0094] In certain embodiments, the inorganic fibers have a thickness of 60 to 220 mm. 2 / g, 60-200m 2 / g, 60-180m 2 / g, 60-160m 2 / g, 60-140m 2 / g, 60-120m 2 / g, or 60-100m 2 / g of surface area.

[0095] In certain embodiments, the inorganic fibers have a thickness of 75 to 220 mm. 2 / g, 75-200m 2 / g, 75-180m 2 / g, 75-160m 2 / g, 75-140m 2 / g, 75-120m 2 / g, or 75-100m 2 / g of surface area.

[0096] In certain embodiments, the inorganic fibers have a thickness of 90 to 220 mm. 2 / g, 90-200m 2 / g, 90-180m 2 / g, 90-160m 2 / g, 90-140m 2 / g, 90-120m 2 / g, or 90-100m2 / g of surface area.

[0097] In certain embodiments, the inorganic fibers can have a porosity of at least 5%, at least 10%, at least 15%, at least 20%, at least 30%, or at least 35% by volume.

[0098] In certain embodiments, the inorganic fibers can have a porosity of at most 60%, at most 55%, at most 50%, at most 45%, or at most 40% by volume.

[0099] In certain embodiments, the inorganic fibers may have a porosity of 5% to 60%, 5% to 55%, 5% to 50%, 5% to 45%, or 5% to 40%.

[0100] In certain embodiments, the inorganic fibers can have a porosity of 10% to 60%, 10% to 55%, 10% to 50%, 10% to 45%, or 10% to 40%.

[0101] In certain embodiments, the inorganic fibers can have a porosity of 15% to 60%, 15% to 55%, 15% to 50%, 15% to 45%, or 15% to 40%.

[0102] In certain embodiments, the inorganic fibers can have a porosity of 20% to 60%, 20% to 55%, 20% to 50%, 20% to 45%, or 20% to 40%.

[0103] In certain embodiments, the inorganic fibers can have a porosity of 25% to 60%, 25% to 55%, 25% to 50%, 25% to 45%, or 25% to 40%.

[0104] In certain embodiments, the inorganic fibers can have a porosity of 30% to 60%, 30% to 55%, 30% to 50%, 30% to 45%, or 30% to 40%.

[0105] In certain embodiments, the inorganic fibers can have a porosity of 35% to 60%, 35% to 55%, 35% to 50%, 35% to 45%, or 35% to 40%.

[0106] In certain embodiments, the inorganic fibers can have a pore volume of at least 0.005 mL / g, at least 0.01 mL / g, at least 0.03 mL / g, at least 0.05 mL / g, at least 0.07 mL / g, at least 0.09 mL / g, or at least 0.1 mL / g.

[0107] In certain embodiments, the inorganic fibers can have a pore volume of at most 0.25 mL / g, at most 0.2 mL / g, at most 0.18 mL / g, at most 0.16 mL / g, at most 0.14 mL / g, or at most 0.12 mL / g.

[0108] In certain embodiments, the inorganic fibers can have a pore volume of 0.005 mL / g to 0.25 mL / g, 0.005 mL / g to 0.2 mL / g, 0.005 mL / g to 0.18 mL / g, 0.005 mL / g to 0.16 mL / g, 0.005 mL / g to 0.14 mL / g, or 0.005 mL / g to 0.12 mL / g.

[0109] In certain embodiments, the inorganic fibers can have a pore volume of 0.01 mL / g to 0.25 mL / g, 0.01 mL / g to 0.2 mL / g, 0.01 mL / g to 0.18 mL / g, 0.01 mL / g to 0.16 mL / g, 0.01 mL / g to 0.14 mL / g, or 0.01 mL / g to 0.12 mL / g.

[0110] In certain embodiments, the inorganic fibers can have a pore volume of 0.03 mL / g to 0.25 mL / g, 0.03 mL / g to 0.2 mL / g, 0.03 mL / g to 0.18 mL / g, 0.03 mL / g to 0.16 mL / g, 0.03 mL / g to 0.14 mL / g, or 0.03 mL / g to 0.12 mL / g.

[0111] In certain embodiments, the inorganic fibers can have a pore volume of 0.05 mL / g to 0.25 mL / g, 0.05 mL / g to 0.2 mL / g, 0.05 mL / g to 0.18 mL / g, 0.05 mL / g to 0.16 mL / g, 0.05 mL / g to 0.14 mL / g, or 0.05 mL / g to 0.12 mL / g.

[0112] In certain embodiments, the inorganic fibers can have a pore volume of 0.07 mL / g to 0.25 mL / g, 0.07 mL / g to 0.2 mL / g, 0.07 mL / g to 0.18 mL / g, 0.07 mL / g to 0.16 mL / g, 0.07 mL / g to 0.14 mL / g, or 0.07 mL / g to 0.12 mL / g.

[0113] In certain embodiments, the inorganic fibers can have a pore volume of 0.09 mL / g to 0.25 mL / g, 0.09 mL / g to 0.2 mL / g, 0.09 mL / g to 0.18 mL / g, 0.09 mL / g to 0.16 mL / g, 0.09 mL / g to 0.14 mL / g, or 0.09 mL / g to 0.12 mL / g.

[0114] In certain embodiments, the inorganic fibers can have a pore volume of 0.1 mL / g to 0.25 mL / g, 0.1 mL / g to 0.2 mL / g, 0.1 mL / g to 0.18 mL / g, 0.1 mL / g to 0.16 mL / g, 0.1 mL / g to 0.14 mL / g, or 0.1 mL / g to 0.12 mL / g.

[0115] In certain embodiments, the inorganic fibers can have an average pore radius of 20-300 Å, 50-300 Å, 50-250 Å, 50-200 Å, 50-150 Å, 100-200 Å, 100-150 Å, or 150-200 Å.

[0116] In certain embodiments, the inorganic fibers can have a pore size distribution of 10-200 Å, 50-200 Å, 100-200 Å, 150-200 Å, 10-150 Å, 50-150 Å, 10-100 Å, 10-50 Å, 50-100 Å, or 100-150 Å.

[0117] It has been found that the "skeletal" structure of a porous system (e.g., pore size, pore length, pore depth, and / or surface area) can affect the effectiveness of catalytic processes. The pores must be wide enough to thinly coat the active material and allow target reactants to freely enter and exit the structure. Pores that are too long or deep can trap reactants and reduce effectiveness. Therefore, it may be particularly desirable to provide porosity preferentially located at the surface of the inorganic fibers, limit the pore length and / or depth, and / or adjust the pore diameter.

[0118] Porosity control can be achieved using several different process variables. Combining different surfactants in solution, such as siloxane components with different micelle sizes or different functional groups, can provide pore size / distribution control. Altering the temperature and / or humidity during fiberization and / or drying can affect porosity, as can increasing or decreasing the concentration of solvent in the precursor fiber before heat treatment. As noted above, altering calcination conditions can also affect porosity.

[0119] Surface area can be maximized by reducing the median diameter of the inorganic fibers. The fiber manufacturing process described above can be tailored to provide inorganic fibers with median diameters ranging from 0.25 μm to 20 μm, with a standard deviation of less than 2 μm or even less than 1 μm. Non-limiting examples of methods for controlling the median fiber diameter include the following: Using different doping aids, such as polyvinyl alcohol, polyacrylamide (e.g., partially hydrolyzed polyacrylamide), polyacrylic acid, polyethylene oxide, carboxyalkyl cellulose, hydroxyalkyl cellulose, alkyl cellulose, hydrolyzed starch, dextrans, guar gum, polyvinylpyrrolidone, polyethylene glycol, alginic acid, polyisobutylene derivatives, copolymers of polysiloxane, polyethylene oxide, polyurethanes, or esters, and mixtures of each of these species, including at least one containing different molecular weights and concentrations, can increase or decrease the median fiber diameter depending on the doping aid. Decreasing the viscosity of the fiberizing solution can result in fibers with a decreased median fiber diameter, as can decreasing the opening size of the fiberizing nozzle in the fiberizing spinner, decreasing the flow rate through the nozzle, increasing the rotation speed of the fiberizing spinner in the fiberizing extrusion process, or increasing the air pressure.

[0120] In certain embodiments, at least 25% of the total porosity of the fiber, and in further embodiments, much more than 25%, is provided by axially aligned pores. As used herein, the term "axially aligned pores" is not limited to pores oriented exactly parallel to the fiber axis, but includes some pores oriented at an angle relative to the axis of up to 30 degrees. In certain embodiments, the majority of axially aligned pores may be essentially parallel to the axis, and in particular may deviate from the axis by up to 10 degrees. It will also be understood that pores having both axially aligned and non-axially aligned portions, such as radially aligned portions (e.g., labyrinth pores including axial pores communicating with radial pores), are considered axially aligned pores with respect to their axially aligned portions. Thus, axially aligned pores may be closed or open relative to the fiber surface.

[0121] The aligned pore structure of the fibers can be created by proper structuring within the gel fiber—i.e., in the case of silica fibers, green fibers formed prior to heat treatment to convert the silica precursor to inorganic silica for the fibers. Specific spinning conditions are required to generate the desired structure in gel fibers. The staple spinning process rapidly draws the fibers to a fine diameter, resulting in a rapid and uniform increase in the viscosity of the spinning solution or sol across the entire fiber cross-section while the gel fiber is stretched and subjected to extensional stress. The combination of rapidly increasing viscosity and a high spin / draw ratio provides flow forces strong enough and lasting to create the desired gel fiber structure. Blow spinning, operated under appropriate conditions, provides an overall spin / draw ratio of 500 to 2,500. Here, the overall spin / draw ratio is the ratio between the velocity of the gel fiber and the velocity of the spinning solution or sol within the spinneret holes.

[0122] activator As used herein, the term "active agent" refers to any composition or material that chemically alters undesirable components in a fluid and / or adsorbs undesirable components from a fluid, and that can be incorporated into and / or applied to inorganic fibers.

[0123] By "incorporated" into the inorganic fibers, it is meant that the active agent is added to the inorganic fibers during their manufacture, such as by adding the active agent to the sol-gel material used to produce the fibers. Thus, the active agent forms an integral component of the inorganic fibers. Thus, the active agent may be uniformly present throughout the individual fibers, or, through certain processing techniques, may be present in higher concentrations in certain portions of each inorganic fiber, such as near the surface of each inorganic fiber.

[0124] By "applying" to the inorganic fibers is meant applying the activator to the inorganic fibers at some point after the green inorganic fibers are formed. For example, but not limited to, the activator can be added to the inorganic fibers immediately after the green inorganic fibers are formed, such as immediately after the spinning step of a sol-gel process. This can be achieved by spraying the activator in liquid form onto the fibers at this stage. Additionally or alternatively, non-limiting examples include coating the activator onto the inorganic fibers after the inorganic fiber manufacturing process is complete, for example, by spraying the activator in liquid form onto the inorganic fibers or coating the activator in another manner. Additionally or alternatively, the activator can be applied before, during, or after any suitable step of the inorganic fiber manufacturing process.

[0125] In certain embodiments, the activator may include at least one of a catalytic activator or a gas scavenger.

[0126] In certain embodiments, the catalytic activator may include at least one of platinum, rubidium, antimony, copper, silver, palladium, ruthenium, bismuth, zinc, nickel, cobalt, chromium, cerium, titanium, iron, vanadium, gold, or manganese in elemental and / or compound form. In certain embodiments, when the catalytic activator is in compound form, the compound may include one or more of these elements.

[0127] In certain embodiments, the gas trapping agent may include at least one of a nitrogen oxide (NOx) trapping agent or a trace metal (e.g., lead or cadmium) adsorbent. The carbon dioxide trapping agent may include calcium oxide. The nitrogen oxide (NOx) trapping agent may include at least one barium-containing compound, such as barium oxide, barium hydroxide, barium carbonate, or a mixture thereof. In certain embodiments, the barium-containing compound may be supported on a ceramic material, such as gamma alumina. The trace metal adsorbent may include an aluminosilicate compound. In this context, aluminosilicate compounds refer to compounds ranging from pure alumina to pure silica. In certain embodiments, the aluminosilicate composition may include silica, kaolin, bauxite, diatomaceous earth, magnesium hydroxide silicate, alumina, or a mixture thereof.

[0128] In certain embodiments, the active agent may be present in the activated fiber composition in an amount of 0 to greater than 50 weight percent, based on the total weight of the activated fiber composition. In certain embodiments, the active agent may be present in the activated fiber composition in an amount such that the amount of active agent present in the activated fiber composition plus the amount of inorganic fiber present in the activated fiber composition together equals the total weight of the activated fiber composition. In certain embodiments, the active agent may be present in the activated fiber composition in an amount such that the amount of active agent present in the activated fiber composition plus the amount of inorganic fiber present in the activated fiber composition plus the amount of any other components described herein present in the activated fiber composition together equals the total weight of the activated fiber composition.

[0129] In certain embodiments, the active agent may be present in the activated fiber composition in an amount of 0.01 to 50 weight percent, 0.05 to 50 weight percent, 0.1 to 50 weight percent, 0.5 to 50 weight percent, 1 to 50 weight percent, 2 to 50 weight percent, 3 to 50 weight percent, 4 to 50 weight percent, 5 to 50 weight percent, 6 to 50 weight percent, 7 to 50 weight percent, 8 to 50 weight percent, 9 to 50 weight percent, or 10 to 50 weight percent, based on the total weight of the activated fiber composition.

[0130] In certain embodiments, the active agent may be present in the activated fiber composition in an amount of 0.01 to 45 weight percent, 0.05 to 45 weight percent, 0.1 to 45 weight percent, 0.5 to 45 weight percent, 1 to 45 weight percent, 2 to 45 weight percent, 3 to 45 weight percent, 4 to 45 weight percent, 5 to 45 weight percent, 6 to 45 weight percent, 7 to 45 weight percent, 8 to 45 weight percent, 9 to 45 weight percent, or 10 to 45 weight percent, based on the total weight of the activated fiber composition.

[0131] In certain embodiments, the active agent may be present in the activated fiber composition in an amount of 0.01 to 40 weight percent, 0.05 to 40 weight percent, 0.1 to 40 weight percent, 0.5 to 40 weight percent, 1 to 40 weight percent, 2 to 40 weight percent, 3 to 40 weight percent, 4 to 40 weight percent, 5 to 40 weight percent, 6 to 40 weight percent, 7 to 40 weight percent, 8 to 40 weight percent, 9 to 40 weight percent, or 10 to 40 weight percent, based on the total weight of the activated fiber composition.

[0132] In certain embodiments, the active agent may be present in the activated fiber composition in an amount of 0.01 to 35 weight percent, 0.05 to 35 weight percent, 0.1 to 35 weight percent, 0.5 to 35 weight percent, 1 to 35 weight percent, 2 to 35 weight percent, 3 to 35 weight percent, 4 to 35 weight percent, 5 to 35 weight percent, 6 to 35 weight percent, 7 to 35 weight percent, 8 to 35 weight percent, 9 to 35 weight percent, or 10 to 35 weight percent, based on the total weight of the activated fiber composition.

[0133] In certain embodiments, the active agent may be present in the activated fiber composition in an amount of 0.01 to 30 weight percent, 0.05 to 30 weight percent, 0.1 to 30 weight percent, 0.5 to 30 weight percent, 1 to 30 weight percent, 2 to 30 weight percent, 3 to 30 weight percent, 4 to 30 weight percent, 5 to 30 weight percent, 6 to 30 weight percent, 7 to 30 weight percent, 8 to 30 weight percent, 9 to 30 weight percent, or 10 to 30 weight percent, based on the total weight of the activated fiber composition.

[0134] In certain embodiments, the active agent may be present in the activated fiber composition in an amount of 0.01 to 25 weight percent, 0.05 to 25 weight percent, 0.1 to 25 weight percent, 0.5 to 25 weight percent, 1 to 25 weight percent, 2 to 25 weight percent, 3 to 25 weight percent, 4 to 25 weight percent, 5 to 25 weight percent, 6 to 25 weight percent, 7 to 25 weight percent, 8 to 25 weight percent, 9 to 25 weight percent, or 10 to 25 weight percent, based on the total weight of the activated fiber composition.

[0135] In certain embodiments, the active agent may be present in the activated fiber composition in an amount of 0.01 to 20 weight percent, 0.05 to 20 weight percent, 0.1 to 20 weight percent, 0.5 to 20 weight percent, 1 to 20 weight percent, 2 to 20 weight percent, 3 to 20 weight percent, 4 to 20 weight percent, 5 to 20 weight percent, 6 to 20 weight percent, 7 to 20 weight percent, 8 to 20 weight percent, 9 to 20 weight percent, or 10 to 20 weight percent, based on the total weight of the activated fiber composition.

[0136] In certain embodiments, the active agent may be present in the activated fiber composition in an amount of 0.01 to 15 weight percent, 0.05 to 15 weight percent, 0.1 to 15 weight percent, 0.5 to 15 weight percent, 1 to 15 weight percent, 2 to 15 weight percent, 3 to 15 weight percent, 4 to 15 weight percent, 5 to 15 weight percent, 6 to 15 weight percent, 7 to 15 weight percent, 8 to 15 weight percent, 9 to 15 weight percent, or 10 to 15 weight percent, based on the total weight of the activated fiber composition.

[0137] In certain embodiments, the active agent may be present in the activated fiber composition in an amount of 0.01 to 10 weight percent, 0.05 to 10 weight percent, 0.1 to 10 weight percent, 0.5 to 10 weight percent, 1 to 10 weight percent, 2 to 10 weight percent, 3 to 10 weight percent, 4 to 10 weight percent, 5 to 10 weight percent, 6 to 10 weight percent, 7 to 10 weight percent, 8 to 10 weight percent, or 9 to 10 weight percent, based on the total weight of the activated fiber composition.

[0138] In embodiments in which an active agent is incorporated into the inorganic fibers, the active agent may be greater than 0 to 10 weight percent, 0.0001 to 10 weight percent, 0.0002 to 10 weight percent, 0.0003 to 10 weight percent, 0.0004 to 10 weight percent, 0.0005 to 10 weight percent, 0.0006 to 10 weight percent, 0.0007 to 10 weight percent, 0.0008 to 10 weight percent, 0.0009 to 10 weight percent, 0.001 to 10 weight percent, 0.002 to 10 weight percent, 0.003 to 10 weight percent, 0.004 to 10 weight percent, 0.005 to 10 weight percent, 0.006 to 10 weight percent, or 0.007 to 10 weight percent based on the total weight of the activated fiber composition. %, 0.008-10 weight percent, 0.009-10 weight percent, 0.01-10 weight percent, 0.02-10 weight percent, 0.03-10 weight percent, 0.04-10 weight percent, 0.05-10 weight percent, 0.06-10 weight percent, 0.07-10 weight percent, 0.08-10 weight percent, 0.09-10 weight percent, 0.1-10 weight percent, 0.2-10 weight percent, 0.3-10 weight percent, 0.4-10 weight percent, 0.5-10 weight percent, 0.6-10 weight percent, 0.7-10 weight percent, 0.8-10 weight percent, 0.9-10 weight percent, or 1-10 weight percent.

[0139] In embodiments in which an active agent is incorporated into the inorganic fibers, the active agent may be present in an amount greater than 0 to 8 weight percent, 0.0001 to 8 weight percent, 0.0002 to 8 weight percent, 0.0003 to 8 weight percent, 0.0004 to 8 weight percent, 0.0005 to 8 weight percent, 0.0006 to 8 weight percent, 0.0007 to 8 weight percent, 0.0008 to 8 weight percent, 0.0009 to 8 weight percent, 0.001 to 8 weight percent, 0.002 to 8 weight percent, 0.003 to 8 weight percent, 0.004 to 8 weight percent, 0.005 to 8 weight percent, 0.006 to 8 weight percent, 0.007 to 8 weight percent, weight percent, 0.008-8 weight percent, 0.009-8 weight percent, 0.01-8 weight percent, 0.02-8 weight percent, 0.03-8 weight percent, 0.04-8 weight percent, 0.05-8 weight percent, 0.06-8 weight percent, 0.07-8 weight percent, 0.08-8 weight percent, 0.09-8 weight percent, 0.1-8 weight percent, 0.2-8 weight percent, 0.3-8 weight percent, 0.4-8 weight percent, 0.5-8 weight percent, 0.6-8 weight percent, 0.7-8 weight percent, 0.8-8 weight percent, 0.9-8 weight percent, or 1-8 weight percent.

[0140] In embodiments in which an active agent is incorporated into the inorganic fibers, the active agent may be present in an amount greater than 0 to 6 weight percent, 0.0001 to 6 weight percent, 0.0002 to 6 weight percent, 0.0003 to 6 weight percent, 0.0004 to 6 weight percent, 0.0005 to 6 weight percent, 0.0006 to 6 weight percent, 0.0007 to 6 weight percent, 0.0008 to 6 weight percent, 0.0009 to 6 weight percent, 0.001 to 6 weight percent, 0.002 to 6 weight percent, 0.003 to 6 weight percent, 0.004 to 6 weight percent, 0.005 to 6 weight percent, 0.006 to 6 weight percent, 0.007 to 6 weight percent, weight percent, 0.008-6 weight percent, 0.009-6 weight percent, 0.01-6 weight percent, 0.02-6 weight percent, 0.03-6 weight percent, 0.04-6 weight percent, 0.05-6 weight percent, 0.06-6 weight percent, 0.07-6 weight percent, 0.08-6 weight percent, 0.09-6 weight percent, 0.1-6 weight percent, 0.2-6 weight percent, 0.3-6 weight percent, 0.4-6 weight percent, 0.5-6 weight percent, 0.6-6 weight percent, 0.7-6 weight percent, 0.8-6 weight percent, 0.9-6 weight percent, or 1-6 weight percent.

[0141] In embodiments in which an active agent is incorporated into the inorganic fibers, the active agent may be present in an amount greater than 0 to 4 weight percent, 0.0001 to 4 weight percent, 0.0002 to 4 weight percent, 0.0003 to 4 weight percent, 0.0004 to 4 weight percent, 0.0005 to 4 weight percent, 0.0006 to 4 weight percent, 0.0007 to 4 weight percent, 0.0008 to 4 weight percent, 0.0009 to 4 weight percent, 0.001 to 4 weight percent, 0.002 to 4 weight percent, 0.003 to 4 weight percent, 0.004 to 4 weight percent, 0.005 to 4 weight percent, 0.006 to 4 weight percent, 0.007 to 4 weight percent, percent by weight, 0.008 to 4 weight percent, 0.009 to 4 weight percent, 0.01 to 4 weight percent, 0.02 to 4 weight percent, 0.03 to 4 weight percent, 0.04 to 4 weight percent, 0.05 to 4 weight percent, 0.06 to 4 weight percent, 0.07 to 4 weight percent, 0.08 to 4 weight percent, 0.09 to 4 weight percent, 0.1 to 4 weight percent, 0.2 to 4 weight percent, 0.3 to 4 weight percent, 0.4 to 4 weight percent, 0.5 to 4 weight percent, 0.6 to 4 weight percent, 0.7 to 4 weight percent, 0.8 to 4 weight percent, 0.9 to 4 weight percent, or 1 to 4 weight percent.

[0142] In embodiments in which an active agent is incorporated into the inorganic fibers, the active agent may be present in an amount greater than 0 to 2 weight percent, 0.0001 to 2 weight percent, 0.0002 to 2 weight percent, 0.0003 to 2 weight percent, 0.0004 to 2 weight percent, 0.0005 to 2 weight percent, 0.0006 to 2 weight percent, 0.0007 to 2 weight percent, 0.0008 to 2 weight percent, 0.0009 to 2 weight percent, 0.001 to 2 weight percent, 0.002 to 2 weight percent, 0.003 to 2 weight percent, 0.004 to 2 weight percent, 0.005 to 2 weight percent, 0.006 to 2 weight percent, 0.007 to 2 weight percent, from 0.008 to 2 weight percent, from 0.009 to 2 weight percent, from 0.01 to 2 weight percent, from 0.02 to 2 weight percent, from 0.03 to 2 weight percent, from 0.04 to 2 weight percent, from 0.05 to 2 weight percent, from 0.06 to 2 weight percent, from 0.07 to 2 weight percent, from 0.08 to 2 weight percent, from 0.09 to 2 weight percent, from 0.1 to 2 weight percent, from 0.2 to 2 weight percent, from 0.3 to 2 weight percent, from 0.4 to 2 weight percent, from 0.5 to 2 weight percent, from 0.6 to 2 weight percent, from 0.7 to 2 weight percent, from 0.8 to 2 weight percent, from 0.9 to 2 weight percent, or from 1 to 2 weight percent.

[0143] In embodiments in which an active agent is incorporated into the inorganic fibers, the active agent may be present in an amount greater than 0 to 1 weight percent, 0.0001 to 1 weight percent, 0.0002 to 1 weight percent, 0.0003 to 1 weight percent, 0.0004 to 1 weight percent, 0.0005 to 1 weight percent, 0.0006 to 1 weight percent, 0.0007 to 1 weight percent, 0.0008 to 1 weight percent, 0.0009 to 1 weight percent, 0.001 to 1 weight percent, 0.002 to 1 weight percent, 0.003 to 1 weight percent, 0.004 to 1 weight percent, 0.005 to 1 weight percent, 0.006 to 1 weight percent, 0. ...8 to 1 weight percent, 0.009 to 1 weight percent, 0.001 to 1 weight percent, 0.002 to 1 weight percent, 0.003 to 1 weight percent, 0.004 to 1 weight percent, 0.005 to 1 weight percent, 0.006 to 1 weight percent, 0.007 to 1 weight percent, 0.007 to 1 weight percent, 0.007 to 1 weight percent, 0.007 to 1 weight percent, 0.007 to 1 weight percent, 0.007 to 1 weight percent and 0.07 to 1 weight percent, 0.008 to 1 weight percent, 0.009 to 1 weight percent, 0.01 to 1 weight percent, 0.02 to 1 weight percent, 0.03 to 1 weight percent, 0.04 to 1 weight percent, 0.05 to 2 weight percent, 0.06 to 1 weight percent, 0.07 to 1 weight percent, 0.08 to 1 weight percent, 0.09 to 1 weight percent, 0.1 to 1 weight percent, 0.2 to 1 weight percent, 0.3 to 1 weight percent, 0.4 to 1 weight percent, 0.5 to 1 weight percent, 0.6 to 1 weight percent, 0.7 to 1 weight percent, 0.8 to 1 weight percent, or 0.9 to 1 weight percent.

[0144] Other Components of the Activated Fiber Composition In certain embodiments, the activated fiber composition of any of the above embodiments may further comprise a blend of different inorganic fiber compositions. In certain embodiments, the activated fiber composition of any of the above embodiments may further comprise secondary inorganic fibers. Note that the "secondary inorganic fibers" are different from the "second inorganic fibers" described above. The secondary inorganic fibers may differ from the inorganic fibers described above in any one or more of the characteristics of the inorganic fibers described above. Specifically, in the various embodiments described above, the inorganic fibers may be characterized in any number of ways. When secondary inorganic fibers are included in any of the above embodiments, it should be understood that in certain embodiments where secondary inorganic fibers may be included, they may differ from the inorganic fibers in that they have one or more characteristics that are mutually exclusive with the characteristics of the inorganic fibers. For example, the secondary inorganic fibers may be (i) 4m 2 / g, (ii) a porosity of less than 4 volume percent, or (iii) a pore volume of less than 0.004 mL / g.

[0145] In certain embodiments, the secondary inorganic fibers may be present in the activated fiber composition in an amount of up to 80 weight percent, 1 to 80 weight percent, 5 to 80 weight percent, 10 to 80 weight percent, 15 to 80 weight percent, 20 to 80 weight percent, 25 to 80 weight percent, 30 to 80 weight percent, 35 to 80 weight percent, 40 to 80 weight percent, 45 to 80 weight percent, or 50 to 80 weight percent, based on the total weight of the activated fiber composition.

[0146] In certain embodiments, the secondary inorganic fibers may be present in the activated fiber composition in an amount of up to 70 weight percent, 1 to 70 weight percent, 5 to 70 weight percent, 10 to 70 weight percent, 15 to 70 weight percent, 20 to 70 weight percent, 25 to 70 weight percent, 30 to 70 weight percent, 35 to 70 weight percent, 40 to 70 weight percent, 45 to 70 weight percent, or 50 to 70 weight percent, based on the total weight of the activated fiber composition.

[0147] In certain embodiments, the secondary inorganic fibers may be present in the activated fiber composition in an amount of up to 60 weight percent, 1-60 weight percent, 5-60 weight percent, 10-60 weight percent, 15-60 weight percent, 20-60 weight percent, 25-60 weight percent, 30-60 weight percent, 35-60 weight percent, 40-60 weight percent, 45-60 weight percent, or 50-60 weight percent, based on the total weight of the activated fiber composition.

[0148] In certain embodiments, the secondary inorganic fibers may be present in the activated fiber composition in an amount of up to 50 weight percent, 1-50 weight percent, 5-50 weight percent, 10-50 weight percent, 15-50 weight percent, 20-50 weight percent, 25-50 weight percent, 30-50 weight percent, 35-50 weight percent, 40-50 weight percent, or 45-50 weight percent, based on the total weight of the activated fiber composition.

[0149] In certain embodiments, the secondary inorganic fibers may be present in the activated fiber composition in an amount of up to 40 weight percent, 1 to 40 weight percent, 5 to 40 weight percent, 10 to 40 weight percent, 15 to 40 weight percent, 20 to 40 weight percent, 25 to 40 weight percent, 30 to 40 weight percent, or 35 to 40 weight percent, based on the total weight of the activated fiber composition.

[0150] In certain embodiments, the secondary inorganic fibers may be present in the activated fiber composition in an amount of up to 30 weight percent, 1 to 30 weight percent, 5 to 30 weight percent, 10 to 30 weight percent, 15 to 30 weight percent, 20 to 30 weight percent, or 25 to 30 weight percent, based on the total weight of the activated fiber composition.

[0151] In certain embodiments, the activated fiber composition of any of the above embodiments may further comprise organic fibers, metal fibers, carbon fibers, or combinations thereof.

[0152] In certain embodiments, the activated fiber composition of any of the above embodiments may further include a binder. The binder may include an organic binder and / or an inorganic binder. The organic binder may include a polymer emulsion, a solvent-based polymer, a solvent-free polymer, a starch, an organic binder fiber, or a mixture thereof. The polymer emulsion may include latex, natural rubber latex, styrene-butadiene latex, butadiene-acrylonitrile latex, a latex of an acrylate / methacrylate polymer / copolymer, or a mixture thereof. The solvent-based polymer may include an acrylic, polyurethane, vinyl acetate, cellulose, or rubber-based organic polymer, or a mixture thereof. The solvent-free polymer may include natural rubber, styrene-butadiene rubber, an elastomer, or a combination thereof. The starch may include potato starch, corn starch, or a mixture thereof. The organic binder fiber may include polyvinyl alcohol ("PVA") fiber, microfibrillated cellulose fiber, or a combination thereof.

[0153] The inorganic binder may include colloidal inorganic oxide dispersions including silica, alumina, titania, zinc, magnesia, zirconia, or mixtures thereof.

[0154] In certain embodiments, the binder can be present in the activated fiber composition in an amount of up to 50 weight percent, e.g., 0.1 to 50 weight percent, 0.5 to 50 weight percent, 1 to 50 weight percent, 2 to 50 weight percent, 3 to 50 weight percent, 4 to 50 weight percent, 5 to 50 weight percent, 6 to 50 weight percent, 7 to 50 weight percent, 8 to 50 weight percent, 9 to 50 weight percent, or 10 to 50 weight percent, based on the total weight of the activated fiber composition.

[0155] In certain embodiments, the binder can be present in the activated fiber composition in an amount of up to 45 weight percent, e.g., 0.1 to 45 weight percent, 0.5 to 45 weight percent, 1 to 45 weight percent, 2 to 45 weight percent, 3 to 45 weight percent, 4 to 45 weight percent, 5 to 45 weight percent, 6 to 45 weight percent, 7 to 45 weight percent, 8 to 45 weight percent, 9 to 45 weight percent, or 10 to 45 weight percent, based on the total weight of the activated fiber composition.

[0156] In certain embodiments, the binder can be present in the activated fiber composition in an amount of up to 40 weight percent, e.g., 0.1 to 40 weight percent, 0.5 to 40 weight percent, 1 to 40 weight percent, 2 to 40 weight percent, 3 to 40 weight percent, 4 to 40 weight percent, 5 to 40 weight percent, 6 to 40 weight percent, 7 to 40 weight percent, 8 to 40 weight percent, 9 to 40 weight percent, or 10 to 40 weight percent, based on the total weight of the activated fiber composition.

[0157] In certain embodiments, the binder can be present in the activated fiber composition in an amount of up to 35 weight percent, e.g., 0.1 to 35 weight percent, 0.5 to 35 weight percent, 1 to 35 weight percent, 2 to 35 weight percent, 3 to 35 weight percent, 4 to 35 weight percent, 5 to 35 weight percent, 6 to 35 weight percent, 7 to 35 weight percent, 8 to 35 weight percent, 9 to 35 weight percent, or 10 to 35 weight percent, based on the total weight of the activated fiber composition.

[0158] In certain embodiments, the binder can be present in the activated fiber composition in an amount of up to 30 weight percent, e.g., 0.1 to 30 weight percent, 0.5 to 30 weight percent, 1 to 30 weight percent, 2 to 30 weight percent, 3 to 30 weight percent, 4 to 30 weight percent, 5 to 30 weight percent, 6 to 30 weight percent, 7 to 30 weight percent, 8 to 30 weight percent, 9 to 30 weight percent, or 10 to 30 weight percent, based on the total weight of the activated fiber composition.

[0159] In certain embodiments, the activated fiber composition of any of the above embodiments may further include an intumescent material. The intumescent material may expand upon initial use of the composition to provide mechanical support within a product form made from the composition. The intumescent material may also provide other benefits that may be known in the art. The intumescent material may include mica, unexpanded vermiculite, ion-exchanged vermiculite, heat-treated vermiculite, hydrobiotite, alkali metal silicate, talc, clay, expandable graphite, or mixtures thereof.

[0160] In certain embodiments, the expandable material may be present in the activated fiber composition in an amount of up to 50 weight percent, e.g., 1-50 weight percent, 2-50 weight percent, 3-50 weight percent, 4-50 weight percent, 5-50 weight percent, 10-50 weight percent, 15-50 weight percent, 20-50 weight percent, 25-50 weight percent, 30-50 weight percent, 35-50 weight percent, 40-50 weight percent, or 45-50 weight percent, based on the total weight of the activated fiber composition.

[0161] In certain embodiments, the expandable material may be present in the activated fiber composition in an amount of up to 45 weight percent, e.g., 1-45 weight percent, 2-45 weight percent, 3-45 weight percent, 4-45 weight percent, 5-45 weight percent, 10-45 weight percent, 15-45 weight percent, 20-45 weight percent, 25-45 weight percent, 30-45 weight percent, 35-45 weight percent, or 40-45 weight percent, based on the total weight of the activated fiber composition.

[0162] In certain embodiments, the expandable material may be present in the activated fiber composition in an amount of up to 40 weight percent, e.g., 1-40 weight percent, 2-40 weight percent, 3-40 weight percent, 4-40 weight percent, 5-40 weight percent, 10-40 weight percent, 15-40 weight percent, 20-40 weight percent, 25-40 weight percent, 30-40 weight percent, or 35-40 weight percent, based on the total weight of the activated fiber composition.

[0163] In certain embodiments, the expandable material can be present in the activated fiber composition in an amount of up to 35 weight percent, e.g., 1-35 weight percent, 2-35 weight percent, 3-35 weight percent, 4-35 weight percent, 5-35 weight percent, 10-35 weight percent, 15-35 weight percent, 20-35 weight percent, 25-35 weight percent, or 30-35 weight percent, based on the total weight of the activated fiber composition.

[0164] In certain embodiments, the expandable material can be present in the activated fiber composition in an amount of up to 30 weight percent, e.g., 1-30 weight percent, 2-30 weight percent, 3-30 weight percent, 4-30 weight percent, 5-30 weight percent, 10-30 weight percent, 15-30 weight percent, 20-30 weight percent, or 25-30 weight percent, based on the total weight of the activated fiber composition.

[0165] In certain embodiments, the expandable material may be present in the activated fiber composition in an amount of up to 25 weight percent, e.g., 1-25 weight percent, 2-25 weight percent, 3-25 weight percent, 4-25 weight percent, 5-25 weight percent, 10-25 weight percent, 15-25 weight percent, or 20-25 weight percent, based on the total weight of the activated fiber composition.

[0166] In certain embodiments, the expandable material can be present in the activated fiber composition in an amount of up to 20 weight percent, e.g., 1 to 20 weight percent, 2 to 20 weight percent, 3 to 20 weight percent, 4 to 20 weight percent, 5 to 20 weight percent, 10 to 20 weight percent, or 15 to 20 weight percent, based on the total weight of the activated fiber composition.

[0167] In certain embodiments, the expandable material can be present in the activated fiber composition in an amount of up to 15 weight percent, e.g., 1 to 15 weight percent, 2 to 15 weight percent, 3 to 15 weight percent, 4 to 15 weight percent, 5 to 15 weight percent, or 10 to 15 weight percent, based on the total weight of the activated fiber composition.

[0168] In any embodiment, the activated fiber composition may further include a secondary agent incorporated into the inorganic fibers and / or applied to at least a portion of the inorganic fibers. For example, the secondary agent may include an element that selectively captures and releases gases depending on environmental conditions, such as temperature or composition. Non-limiting examples of secondary agents include ceramic-supported barium compounds, including barium carbonate, barium oxide, barium hydroxide, and gamma alumina. These compounds selectively capture nitrous oxide (NOx), which is released when the temperature of the gas stream is sufficiently high. In embodiments in which the activator is a catalyst, the release temperature may be higher than the light-off temperature of the catalyst. As used herein, "light-off temperature" refers to the temperature at which the exhaust gas treatment device can treat the exhaust gas stream such that, upon exiting the exhaust gas treatment device, the exhaust gas stream complies with local regulations and / or industry practices. In any embodiment, the NOx trap material may be positioned in the emission control device including the activated fiber composition before the activator, so that the exhaust gas interacts with the NOx trap material before interacting with the activator. In other embodiments, the NOx trap material may be positioned near the activator. In such an embodiment, the exhaust gas reaches the NOx trap material and the activator at approximately the same time.

[0169] Other non-limiting examples of secondary agents include cerium, lanthanum, barium, and other metals capable of storing oxygen. When included in emission control devices (e.g., those used in the automotive industry), oxygen storage materials can provide a source of oxygen during low-oxygen operation (e.g., during fuel-rich operation) when converting CO to CO2. These oxygen storage materials readily form oxides under oxygen-rich conditions (e.g., lean engine operation) and are released when the oxygen concentration in the air mixture decreases during low-oxygen operation. In emission control devices containing activated fiber compositions, the oxygen storage material can be positioned, for example, near the active agent.

[0170] In any embodiment, whether incorporated into or applied onto the inorganic fibers, the secondary agent may comprise 0 to 20 weight percent, based on the total weight of the activated fiber composition. In some embodiments, the secondary agent is present in an amount of 0.001 to 15 weight percent, 0.01 to 10 weight percent, 0.10 to 9 weight percent, 0.25 to 8 weight percent, 0.5 to 7 weight percent, 0.75 to 6 weight percent, 1 to 5 weight percent, 1.5 to 4 weight percent, 1.75 to 3 weight percent, 1 to 2 weight percent, 0.5 to 1.5 weight percent, 0.1 to 1 weight percent, 0.25 to 0.75 weight percent, 0.01 to 0.5 weight percent, or 0.1 to 0.5 weight percent, based on the total weight of the activated fiber composition.

[0171] Fiber assembly Also provided are fibrous assemblies comprising the activated fiber composition of any of the above embodiments. In certain embodiments, the fibrous assemblies can be densified, such as by needling and / or stitching. The fibrous assemblies can include mats, blanket This may include product forms such as board, paper, felt, net-shape products (e.g., formed by vacuum forming a slurry of fibers), or textiles.

[0172] 1A-1H show various shapes of fibrous assemblies that can be formed from the compositions described herein. The fibrous assemblies can be formed via any known method, such as air laying, wet laying (such as a paper-making type process), or vacuum forming.

[0173] composite material Also provided is a composite material comprising the activated fiber composition of any of the above embodiments and a support matrix at least partially supporting the activated fiber composition. The support matrix may comprise known materials used in product forms similar to those described herein.

[0174] For example, inorganic oxide catalyst support materials can be made by compressing loose powders of zeolite, alumina, zirconia, silica, or titania and can contain small amounts of compatible inorganic binders. The porosity and catalyst-carrying capacity of these support materials is controlled, at least in part, by the porosity of the loose powder and the spaces between the loose powders in the compressed structure. The above-described compositions can be incorporated into these support materials to improve the physical properties, such as the mechanical strength, of the support material while also supporting or improving the catalyst-carrying capacity of the support material.

[0175] In certain embodiments, a composite material may include an inorganic oxide support matrix and the activated fiber composition of any of the above embodiments. In certain embodiments, the inorganic oxide support matrix and the activated fiber composition of any of the above embodiments may be selected from similar or different chemical compositions of various components. For example, it may be desirable to select an inorganic oxide support matrix having a chemical composition similar to that of the inorganic fibers present in the activated fiber composition of any of the above embodiments to ensure similar thermal expansion of the materials and reduce the possibility of damage to the composite material during repeated thermal expansion and contraction cycles. The composite material may also include binders and / or other additives to improve the physical / chemical properties of the composite material.

[0176] In certain embodiments, the composite material comprises, based on the total weight of the composite material, up to 99.9 weight percent inorganic oxide support matrix and greater than 0.1 weight percent of the activated fiber composition of any of the above embodiments; up to 99.5 weight percent inorganic oxide support matrix and greater than 0.5 weight percent of the activated fiber composition of any of the above embodiments; up to 99 weight percent inorganic oxide support matrix and greater than 1 weight percent of the activated fiber composition of any of the above embodiments; up to 98 weight percent inorganic oxide support matrix and greater than 2 weight percent of the activated fiber composition of any of the above embodiments; up to 97 weight percent inorganic oxide support matrix and greater than 3 weight percent of the activated fiber composition of any of the above embodiments; up to 96 weight percent inorganic oxide support matrix and greater than 4 weight percent of the activated fiber composition of any of the above embodiments; up to 95 weight percent inorganic oxide support matrix and greater than 5 weight percent of the activated fiber composition of any of the above embodiments; up to 90 weight percent inorganic oxide support matrix and greater than 1 weight percent of the activated fiber composition of any of the above embodiments; up to 85 weight percent inorganic oxide support matrix and more than 15 weight percent activated fiber composition of any of the above embodiments; up to 80 weight percent inorganic oxide support matrix and more than 20 weight percent activated fiber composition of any of the above embodiments; up to 70 weight percent inorganic oxide support matrix and more than 30 weight percent activated fiber composition of any of the above embodiments; up to 60 weight percent inorganic oxide support matrix and more than 40 weight percent activated fiber composition of any of the above embodiments; up to 50 weight percent inorganic oxide support matrix and more than 50 weight percent activated fiber composition of any of the above embodiments; up to 40 weight percent inorganic oxide support matrix and more than 60 weight percent activated fiber composition of any of the above embodiments; up to 30 weight percent inorganic oxide support matrix and more than 70 weight percent activated fiber composition of any of the above embodiments;up to 2 weight percent inorganic oxide support matrix and greater than 98 weight percent activated fiber composition of any of the above embodiments; up to 0.5 weight percent inorganic oxide support matrix and greater than 99.5 weight percent activated fiber composition of any of the above embodiments; up to 10 weight percent inorganic oxide support matrix and greater than 90 weight percent activated fiber composition of any of the above embodiments; up to 5 weight percent inorganic oxide support matrix and greater than 95 weight percent activated fiber composition of any of the above embodiments; up to 4 weight percent inorganic oxide support matrix and greater than 96 weight percent activated fiber composition of any of the above embodiments; up to 3 weight percent inorganic oxide support matrix and greater than 97 weight percent activated fiber composition of any of the above embodiments; up to 2 weight percent inorganic oxide support matrix and greater than 98 weight percent activated fiber composition of any of the above embodiments; up to 1 weight percent inorganic oxide support matrix and greater than 99 weight percent activated fiber composition of any of the above embodiments; up to 0.5 weight percent inorganic oxide support matrix and greater than 99.5 weight percent activated fiber composition of any of the above embodiments; or up to 0.1 weight percent inorganic oxide support matrix and greater than 99.9 weight percent activated fiber composition of any of the above embodiments. ,

[0177] filter element Also provided are filter elements comprising any of the activated fiber compositions of the above embodiments. In certain embodiments, the filter elements may function to remove and / or modify undesirable materials from the exhaust gas stream. In certain embodiments, the filter elements may function primarily to remove undesirable particulate matter from the exhaust gas stream, but may also function to adsorb undesirable gases and / or chemically alter undesirable gases in the exhaust gas stream. As discussed above, the filter elements disclosed herein can replace conventional filter elements, such as ceramic honeycomb filter elements. The filter elements disclosed herein comprising any of the activated fiber compositions of the above embodiments may have one or more of the following advantages over conventional filter elements: reduced cost, reduced size, reduced weight, less backpressure generation, improved filtration performance, fewer temperature limitations, fewer space constraints, and improved catalytic efficiency.

[0178] For example, exhaust gas treatment devices, such as catalytic converters, diesel particulate filters, or catalytic diesel particulate filters, are typically included in automobile exhaust systems to reduce the amount of pollutants released into the environment. Currently used exhaust gas treatment devices function well once the temperature reaches light-off, but pollution problems persist during the light-off period. For example, it has been determined that the majority of pollutants released into the environment from an automobile exhaust system containing an exhaust gas treatment device are released during the light-off period.

[0179] As used herein, the light-off temperature is the temperature at which an exhaust gas treatment device can treat an exhaust gas stream such that upon exiting the exhaust gas treatment device, the exhaust gas stream complies with local regulations and / or industry practices. The light-off duration is the time required for the exhaust gas treatment device to reach the light-off temperature.

[0180] If the filter element can withstand high temperatures and be placed closer to the exhaust gas source, the filter element will be heated more quickly by the exhaust gas, thereby reducing the duration of the filter element ignition.

[0181] The filter elements described herein can also be tailored to provide desired backpressure generation, gas flow through the element, and / or filtration performance by modifying the density of the filter element, the orientation of the inorganic fibers within the filter element, and / or the flexibility of the filter element. For example, backpressure generation can be tailored within the range observed in conventional filter elements, such as the 400 cpsi and 900 cpsi ceramic honeycomb filters shown in Figures 12A and 12B, respectively. Typical backpressure generation for these 400 cpsi and 900 cpsi ceramic honeycomb filters, measured on a 2-inch diameter pipe, is shown in Figure 13.

[0182] In certain embodiments, the filter element can include an external support structure. The external support structure can include a mesh, such as a metal mesh or a ceramic mesh. In certain embodiments, the filter element can include a metal wire provided within the filter element, which can increase heat transfer and further reduce the light-off period.

[0183] In certain embodiments, the filter element may further include a binder applied to a portion of the exterior surface of the filter element. The binder may include organic and / or inorganic binders. The organic binder may include a polymer emulsion, a solvent-based polymer, a solvent-free polymer, starch, organic binder fibers, or a mixture thereof. The polymer emulsion may include latex, natural rubber latex, styrene-butadiene latex, butadiene-acrylonitrile latex, a latex of an acrylate / methacrylate polymer / copolymer, or a mixture thereof. The solvent-based polymer may include acrylic, polyurethane, vinyl acetate, cellulose, rubber-based organic polymer, or a combination thereof. The solvent-free polymer may include natural rubber, styrene-butadiene rubber, elastomer, or a combination thereof. The starch may include potato starch, corn starch, or a mixture thereof. The organic binder fiber may include VA fiber, microfibrillated cellulose fiber, or a combination thereof.

[0184] The inorganic binder may include a colloidal inorganic oxide dispersion including silica, alumina, titania, zinc, magnesia, zirconia, or a combination thereof.

[0185] Filter System Also provided is a filter system including a plurality of filter elements according to any of the above embodiments. In certain embodiments, at least two of the plurality of filter elements may differ from one another in at least one of the following: (a) the porosity of the inorganic fibers present in each filter element, (b) the fiber diameter of the inorganic fibers present in each filter element, (c) the fiber length of the inorganic fibers present in each filter element, (d) the fiber composition of the inorganic fibers present in each filter element, (e) the type of active agent present in each filter element, (f) the heat transfer coefficient of each filter element, or (g) the heat resistance of each filter element.

[0186] In certain embodiments, a filter system may include a first filter element positioned proximate to an exhaust gas source and a second filter element positioned downstream from the first filter element, where the first filter element and the second filter element perform different functions of removing and / or modifying undesirable materials from the exhaust gas stream. For example, in certain embodiments, a filter system may include a first filter element positioned proximate to the exhaust gas source that includes a catalytic activator intended to reduce more complex organic gases to carbon dioxide or carbon monoxide, and a second filter element positioned downstream from the first filter element that includes an activator intended to adsorb carbon dioxide and / or carbon monoxide after the reduction reaction is complete.

[0187] catalytic element Also provided is a catalytic element comprising any of the activated fiber compositions described above. The catalytic element would be expected to provide at least the same benefits as the filter element described and discussed above. Because the filter element disclosed above can also provide catalytic functionality, the filter element and catalytic element disclosed herein can have many overlapping uses and functions and thus provide similar benefits.

[0188] In certain embodiments, the catalytic element may include an external support structure. The external support structure may include a mesh, such as a metal mesh and / or a ceramic mesh. In certain embodiments, the catalytic element may further include a metal wire provided within the catalytic element.

[0189] In certain embodiments, the catalyst element may further include a binder applied to a portion of the exterior surface of the catalyst element. The binder may include organic and / or inorganic binders. The organic binder may include a polymer emulsion, a solvent-based polymer, a solvent-free polymer, starch, organic binder fibers, or a mixture thereof. The polymer emulsion may include latex, natural rubber latex, styrene-butadiene latex, butadiene-acrylonitrile latex, a latex of an acrylate / methacrylate polymer / copolymer, or a combination thereof. The solvent-based polymer may include acrylic, polyurethane, vinyl acetate, cellulose, rubber-based organic polymer, or a combination thereof. The solvent-free polymer may include natural rubber, styrene-butadiene rubber, elastomer, or a combination thereof. The starch may include potato starch, corn starch, or a mixture thereof. The organic binder fibers may include PVA fibers, microfibrillated cellulose fibers, or a combination thereof.

[0190] The inorganic binder may include colloidal inorganic oxide dispersions including silica, alumina, titania, zinc, magnesia, zirconia, or mixtures thereof.

[0191] Exhaust system components and exhaust system Also provided is an exhaust conduit comprising an inner lining comprising the activated fiber composition of any of the above embodiments. In certain embodiments, the exhaust conduit may comprise an outer conduit and an inner lining comprising the activated fiber composition of any of the above embodiments.

[0192] Also provided is an exhaust conduit comprising the activated fiber composition of any of the above embodiments, filling substantially all of the interior volume of the conduit.

[0193] FIG. 2 illustrates an embodiment of a conduit containing an activated fiber composition described herein. Referring to FIG. 2, a filter element 1 is shown containing an activated fiber composition 10. The activated fiber composition 10 may be enclosed between a first permeable support 11 facing the exhaust stream and a second permeable support 12 facing the first permeable support 11. The first and second permeable supports 11, 12 allow gas to flow therethrough, thereby allowing the gas to contact the activated fiber composition 10. In some embodiments, the first and second permeable supports 11, 12 may be made of mesh, such as a metal mesh or a polymer mesh. The enclosed activated fiber composition 10 may be secured within the conduit 30, for example, by a seal 20. The seal 20 may be any suitable shape and size and, in some embodiments, may be, for example, a gasket or a weld. As shown in FIG. 2, the gas to be treated flows from right to left toward the filter element 1. The front end of the filter element 1 includes a cap 15 that is less permeable than the activated fiber composition 10, so that the gas is forced to flow through the activated fiber composition 10. The treated gas then continues to the left through conduit 30.

[0194] 3, the downstream end of filter element 2 may instead include a filler end 16 containing a loaded activated fiber composition such that the permeability of filler end 16 is less than the permeability of activated fiber composition 10. Filler end 16 may include third and fourth permeable supports 13, 14 to hold filler end 16 in place. Supports 13, 14 may be the same as or similar to supports 11, 12 and may be integrally formed therewith.

[0195] FIG. 4 illustrates an alternative filter element 1 in which the activated fiber composition 10 spans the entire cross-section of the conduit 30, forcing incoming gas to flow (from right to left) through the activated fiber composition 10. While a fiber composition 10 is shown, any number of layers can be used. The first and second permeable supports 11, 12 can be the same as those described above. In some embodiments, the activated fiber composition 10 can be positioned within the conduit 30 at a non-perpendicular angle, as shown in FIG. 5, for example. In the embodiments shown in FIGS. 4 and 5, the shape of the activated fiber composition 10 can be appropriately conformed to the cross-sectional shape of the conduit 30. Additionally, in the embodiments of FIGS. 4 and 5, the seal 20 can be in any suitable form, such as a gasket, weld, adhesive, or any other fastening mechanism. In some embodiments, a seal is not included, and the activated fiber composition 10 is secured in place by a press fit or by screws, nails, or pins inserted into the activated fiber composition 10 from outside the conduit 30.

[0196] Figure 6 illustrates another method of securing the activated fiber composition 10 within the conduit 30. As shown in Figure 6, the activated fiber composition 10 is placed between first and second permeable supports 11, 12, and the encapsulated activated fiber composition is then placed between sealing sections 21 that are connected to respective sections of the conduit 30, connected to one another by any suitable means, thereby securing the encapsulated activated fiber composition.

[0197] Referring to Figure 7, the conduit may include a drum 230 connected to an inlet 231 and an outlet 233. The activated fiber composition 210 may be supported on either side by a first permeable support 211 and a second permeable support 212. As shown in Figure 7, the waste gas is forced through the activated fiber composition 210 due to the activated fiber composition 10 spanning the entire length of the drum 230, which is capped at one end by a cap 215.

[0198] In another embodiment, shown in FIG. 8, a cyclone-style reactor can be used. Specifically, as shown in FIG. 8, waste gas can be fed through inlet 331 to a lower drum 330A, which has a smaller diameter than the upper drum 330B. In the lower drum 330A, a fluidized bed of activated fibers 310A interacts with the waste gas. In the upper drum 330B, loose activated fibers 310B are sparsely present. During operation, waste gas passes from the lower drum 330A to the upper drum 330B, where it is treated by the activated fibers 330A and 330B, and the treated gas exits the reactor through outlet 332.

[0199] Figure 9 illustrates an embodiment in which a conduit 130 is coated with an activated fiber composition 110. As shown in Figure 9, the inner surface of conduit 130A is in contact with the outer surface of activated fiber composition 110A. Additionally, the inner surface of activated fiber composition 110B may include a permeable support 111 for immobilizing activated fiber composition 110.

[0200] In certain embodiments, an exhaust conduit may include an internal structure that impedes the flow of fluid therethrough to increase contact between the fluid and the structure, thereby increasing the activity of the active agent, the internal structure comprising an activated fiber composition described herein. In certain embodiments, the internal structure may comprise a spiral structure comprising the activated fiber composition of any of the above embodiments. Figure 10 shows a conduit 30 with a baffle 40 disposed therein. The baffle 40 may be formed from an activated fiber composition, for example, activated fiber paper. Figure 11 shows a conduit 30 with a spirally oriented activated fiber composition 50 described herein progressing longitudinally through the conduit.

[0201] Also provided is an exhaust gas treatment device including a filter element and / or a catalytic element according to any of the above embodiments, for example, an exhaust gas treatment device for treating the exhaust gas of an automobile engine, used to affect the oxidation of carbon monoxide and hydrocarbons and the reduction of oxides of nitrogen present in the exhaust gas.

[0202] An automotive catalytic converter may include an outer metal housing and a frangible catalyst support structure held within the outer metal housing by a mounting mat. The mounting mat is disposed between the inner surface of the outer metal housing and the outer surface of the frangible catalyst support structure. The frangible catalyst support structure is commonly referred to in the art as a "monolith." The monolith may be made from a ceramic or metallic material. The mounting mat provides sufficient insulation and holding pressure to maintain the frangible catalyst support structure in place during operation of the catalytic converter.

[0203] Diesel particulate traps can be used in automobiles that utilize diesel fuel. Diesel particulate traps typically include an outer metal housing and a frangible particulate filter structure that is held within the outer metal housing by a mounting mat. The mounting mat is positioned between the inner surface of the housing and the outer surface of the particulate filter. Similar to a catalytic converter, the mat provides insulation and retaining pressure to maintain the particulate filter in place within the outer metal housing during operation of the diesel particulate filter.

[0204] As noted above, catalyst support structures in catalytic converters and diesel particulate filters are often very fragile. In fact, these structures are so fragile that even small stresses can be sufficient to crack or crush them. To protect the fragile structure from thermal and mechanical shock and other stresses described above, and to hold the fragile structure in place within the housing to provide thermal insulation and a gas seal, it is known to place at least one ply or layer of mounting or support material within the gap between the fragile structure and the housing. In this way, a mounting mat positioned between the outer housing of an automotive exhaust gas treatment device and the fragile catalyst support structure or particulate filter can exhibit high temperature resistance and exert the necessary holding pressure to maintain the catalyst support structure or particulate filter in place during operation of the device.

[0205] The exhaust gas treatment device is assembled by wrapping a mounting mat around at least a portion of the circumference of a fragile catalyst support structure or diesel particulate filter and placing the wrapped structure within a housing. During wrapping of the catalyst support structure or diesel particulate filter, the mounting mat must bend around the fragile catalyst support structure. Tensile stresses are placed on the mounting mat, which can cause the mounting mat to crack or tear. As can be appreciated, the problem is exacerbated when a heavy base weight mounting mat is used to wrap the fragile structure, or when the wrap is around a tight radius, such as an oval-shaped structure.

[0206] Thus, exhaust gas treatment devices can be improved by using a mounting mat made from the activated fiber composition of any of the above embodiments, or by replacing the entire fragile structural mounting mat assembly with a filter element / catalyst element as described herein. By replacing a conventional mounting mat with a mounting mat including the activated fiber composition of any of the above embodiments, the mounting mat can aid in the catalytic activity of the exhaust gas treatment device. By replacing the entire fragile structural mounting mat assembly with the filter element / catalyst element described herein, the exhaust gas treatment device may become more robust, easier to manufacture, allow for a shorter light-off period, and / or increase catalytic efficiency.

[0207] Also provided is an exhaust system including one or more filter elements and / or one or more catalytic elements according to any of the above embodiments. In certain embodiments, the exhaust system may include at least one of a filter element according to any of the above embodiments; a catalytic element according to any of the above embodiments; an exhaust gas treatment device according to any of the above embodiments; an exhaust conduit according to any of the above embodiments, or any combination thereof. Any exhaust system, such as a muffler for an automobile, may include one or more product forms as described herein.

[0208] Also provided is an apparatus including an internal combustion engine generating exhaust, and an exhaust system according to any of the above embodiments. The apparatus may further include a conduit for conveying exhaust from the internal combustion engine to the exhaust system, the exhaust system being downstream of the internal combustion engine. The exhaust system may include at least one filter element and at least one catalytic element. The filter element may be downstream of the catalytic element, or the catalytic element may be downstream of the filter element. The filter element and the catalytic element may be connected via a conduit according to the above embodiments.

[0209] It should also be understood that the exhaust systems described herein can be used to treat exhaust gases from any process that produces exhaust gases that may need to be treated before they can be released to the external environment. For example, many industrial processes, such as the production of energy from fossil fuels or other fuels, require complex exhaust gas treatment systems that can benefit from the inclusion of the exhaust systems or individual exhaust system components described herein. The devices disclosed herein can replace a single element of such a complex industrial exhaust system, multiple elements of such a system, or the entire system.

[0210] vehicle Vehicles including the above-described device and / or including the above-described exhaust system are also provided. Many jurisdictions require vehicles to comply with exhaust gas regulations. The activated fiber compositions and product forms described herein may provide a more efficient and cost-effective solution for complying with these ever-stricter regulatory requirements.

[0211] Versatile product forms Also provided is a catalyst support material comprising the activated fiber composition of any of the above embodiments. Catalyst support materials are commonly used in the production of chemicals by catalytic processes, such as steam methane reforming to produce hydrogen. When used in catalyst support materials, the activated fiber compositions of the above embodiments may provide advantages such as higher temperature stability, increased available active volume, lower product density, and / or increased distance through the active space. The catalyst support material may be provided in the following reactor configurations: packed bed, fixed bed, fluidized bed, activated filter structure, activated paper, activated fluted paper, slurry bed, and trickle bed.

[0212] Also provided is a paper comprising the activated fiber composition of any of the above embodiments. Also provided is a proton exchange membrane ("PEM") fuel cell comprising the paper. When used in a PEM fuel cell, the paper comprising the activated fiber composition described herein may provide a thin catalyst-coated paper to maximize active volume and / or provide better utilization of catalytic elements (which can be very expensive).

[0213] It will be understood that the embodiments described herein are merely exemplary, and that those skilled in the art can make variations and modifications without departing from the spirit and scope of the present invention. All such variations and modifications are intended to be included within the scope of the present invention as described above. Furthermore, all disclosed embodiments are not necessarily alternatives, as various embodiments of the present invention can be combined to provide the desired result.

[0214] The following embodiments of the present subject matter are disclosed:

[0215] (a)(i) At least 5 m 2 / g, (ii) a porosity of at least 5 volume percent, or (iii) a pore volume of at least 0.005 mL / g, and (b) an activated fiber composition comprising an active agent incorporated into and / or applied to at least a portion of the inorganic fibers.

[0216] Inorganic fibers shall be (i) at least 15 m 2 The inorganic fibers may have at least one of: (i) a surface area of ​​at least 30 m / g; (ii) a porosity of at least 10% by volume; or (iii) a pore volume of at least 0.01 mL / g. 2 The inorganic fibers may have at least one of: (i) a surface area of ​​at least 45 m / g; (ii) a porosity of at least 15% by volume; or (iii) a pore volume of at least 0.03 mL / g. 2 The inorganic fibers may have at least one of: (i) a surface area of ​​at least 60 m / g; (ii) a porosity of at least 20% by volume; or (iii) a pore volume of at least 0.05 mL / g. 2 The inorganic fibers may have at least one of: (i) a surface area of ​​at least 75 m / g; (ii) a porosity of at least 25% by volume; or (iii) a pore volume of at least 0.07 mL / g. 2 The inorganic fibers may have at least one of: (i) a surface area of ​​at least 90 m / g; (ii) a porosity of at least 30% by volume; or (iii) a pore volume of at least 0.09 mL / g. 2 The inorganic fibers may have at least one of: (i) a surface area of ​​5 to 220 m / g; (ii) a porosity of at least 35% by volume; or (iii) a pore volume of at least 0.1 mL / g. 2 The inorganic fibers may have at least one of: (i) a surface area of ​​90 to 220 m / g; (ii) a porosity of 5 to 60 volume percent; or (iii) a pore volume of 0.005 to 0.25 mL / g. 2 / g, (ii) a porosity of 35 to 60 volume %, or (iii) a pore volume of 0.1 to 0.25 mL / g.

[0217] Inorganic fibers must be at least 5m 2 / g, at least 15m 2 / g, at least 30m 2 / g, at least 45m 2 / g, at least 60m 2 / g, at least 75m 2 / g, or at least 90m 2 / g, and / or up to 220m 2 / g of surface area.

[0218] The inorganic fibers can have a porosity of at least 5%, at least 10%, at least 15%, at least 20%, at least 30%, at least 35%, and / or up to 60% by volume.

[0219] The inorganic fibers can have a pore volume of at least 0.005 mL / g, at least 0.01 mL / g, at least 0.03 mL / g, at least 0.05 mL / g, at least 0.07 mL / g, at least 0.09 mL / g, at least 0.1 mL / g, and / or at most 0.25 mL / g.

[0220] The inorganic fibers may have an average pore radius of 20 to 300 Å. The inorganic fibers may have a pore size distribution of 10 to 200 Å. The inorganic fibers may be present in the activated fiber composition in an amount of 20 to 100 weight percent, based on the total weight of the activated fiber composition. The inorganic fibers may include first inorganic fibers and second inorganic fibers, and the first inorganic fibers may have a porosity that is different from the porosity of the second inorganic fibers, and / or the first inorganic fibers may have an average fiber diameter that is different from the average fiber diameter of the second inorganic fibers, and / or the first inorganic fibers may have an average fiber length that is different from the average fiber length of the second inorganic fibers, and / or the first inorganic fibers may have a composition that is different from the composition of the second inorganic fibers.

[0221] The inorganic fibers may have a median fiber diameter of 0.25 to 20 μm, and the standard deviation of the median fiber diameter may be 2 μm or less, or 1 μm or less.

[0222] The inorganic fibers can withstand temperatures of 500° C. or more or up to 1,000° C. The inorganic fibers can include inorganic oxide fibers, ceramic fibers, refractory ceramic fibers, polycrystalline wool fibers, alumina fibers, high alumina fibers, glass fibers, silica fibers, boehmite fibers, low biopersistence fibers, alkaline earth silicate fibers, calcia-alumina fibers, zirconia fibers, titania fibers, or combinations thereof.

[0223] The inorganic fibers may include refractory ceramic fibers containing a fiberization product of 45 to 75 weight percent alumina and 25 to 55 weight percent silica. The inorganic fibers may include alkaline earth silicate fibers containing 60 to 90 weight percent silica, 0 to more than 35 weight percent magnesia, and 5 weight percent or less of a fiberization product of impurities. The inorganic fibers may include alkaline earth silicate fibers containing 45 to 90 weight percent silica, 0 to more than 45 weight percent calcia, 0 to more than 35 weight percent magnesia, and 10 weight percent or less of a fiberization product of impurities. The inorganic fibers may include alkaline earth silicate fibers containing a fiberization product of calcia and silica. The inorganic fibers may include calcia-alumina fibers containing 20 to 80 weight percent calcia and 20 to 80 weight percent alumina. The inorganic fibers may include silica fibers containing 90 weight percent or more silica. The inorganic fibers may include alumina fibers containing 90 weight percent or more alumina. The inorganic fibers may include polycrystalline wool fibers containing a fiberization product of 95 to 97 weight percent alumina and 3 to 5 weight percent silica.

[0224] The activator may include a catalytic activator, a gas trap, or a combination thereof. The catalytic activator may include, in elemental and / or compound form, platinum, rubidium, antimony, copper, silver, palladium, ruthenium, bismuth, zinc, nickel, cobalt, chromium, cerium, titanium, iron, vanadium, gold, and / or manganese, and when the catalytic activator is in compound form, the compound may contain one or more of these elements. The gas trap may include a carbon dioxide trap, a nitrogen oxide (NOx) trap, and / or an adsorbent for trace metals. The carbon dioxide trap may include calcium oxide. The nitrogen oxide (NOx) trap may include a barium-containing compound. The activator may be present in the activated fiber composition in an amount of 0 to greater than 50 weight percent, based on the total weight of the activated fiber composition.

[0225] The activated fiber composition may further comprise secondary inorganic fibers. The secondary inorganic fibers may comprise: (i) 4m 2 / g, (ii) a porosity of less than 4 volume percent, or (iii) a pore volume of less than 0.004 mL / g. The secondary inorganic fibers may be present in the activated fiber composition in an amount of 1 to 80 weight percent, based on the total weight of the activated fiber composition.

[0226] The activated fiber composition may further include organic fibers, metal fibers, and / or carbon fibers, and may further include a binder. The binder may include organic and / or inorganic binders. The organic binder may include a polymer emulsion, a solvent-based polymer, a solvent-free polymer, starch, organic binder fibers, or a mixture thereof. The polymer emulsion may include latex, natural rubber latex, styrene-butadiene latex, butadiene-acrylonitrile latex, a latex of an acrylate / methacrylate polymer / copolymer, or a combination thereof. The solvent-based polymer may include acrylic, polyurethane, vinyl acetate, cellulose, rubber-based organic polymers, or a combination thereof. The solvent-free polymer may include natural rubber, styrene-butadiene rubber, elastomers, or a combination thereof. The starch may include potato starch, corn starch, or a mixture thereof. The organic binder fiber may include polyvinyl alcohol fibers and / or microfibrillated cellulose fibers. The inorganic binder may include a colloidal inorganic oxide dispersion including silica, alumina, titania, zinc, magnesia, zirconia, or mixtures thereof. The binder may be present in the activated fiber composition in an amount of 0.1 to 50 weight percent, based on the total weight of the activated fiber composition.

[0227] The activated fiber composition may further include an intumescent material, which may include mica, unexpanded vermiculite, ion-exchanged vermiculite, heat-treated vermiculite, hydrobiotite, alkali metal silicate, talc, clay, and / or expandable graphite. The intumescent material may be present in the activated fiber composition in an amount of 1 to 50 weight percent, based on the total weight of the activated fiber composition.

[0228] Also provided is a fiber assembly comprising the activated fiber composition of any of the above embodiments. The fiber assembly can be densified and / or needled and / or stitched.

[0229] Also provided is a composite material comprising the activated fiber composition of any of the above embodiments and a support matrix that at least partially supports the activated fiber composition. The support matrix may comprise an inorganic oxide material.

[0230] Also provided is a filter element comprising any of the activated fiber compositions described above. The filter element may include an external support structure, which may include a mesh. The mesh may include a metal mesh and / or a ceramic mesh. The filter element may also include a binder applied to a portion of the metal wire provided within the filter element and / or the outer surface of the filter element. The binder may be as described above.

[0231] Also provided is a filter system including a plurality of the filter elements described above, wherein at least two of the plurality of filter elements may differ from one another in at least one of the following: (a) the porosity of the inorganic fibers present in each filter element, (b) the fiber diameter of the inorganic fibers present in each filter element, (c) the fiber length of the inorganic fibers present in each filter element, (d) the fiber composition of the inorganic fibers present in each filter element, (e) the type of active agent present in each filter element, (f) the heat transfer coefficient of each filter element, or (g) the heat resistance of each filter element.

[0232] Also provided is a catalytic element comprising the activated fiber composition of any of the above embodiments. The catalytic element may include an external support structure such as those described above, and / or may include a metal wire provided within the catalytic element and / or a binder applied to a portion of the outer surface of the catalytic element. The binder may be as described above.

[0233] Also provided is an exhaust system including one or more filter elements as described above, and / or one or more catalyst elements as described above.

[0234] Example Example 1: Alumina fiber (available from Unifrax I LLC, Tonawanda, NY, USA, under the registered trademark SAFFIL) with a surface area of ​​130 m 2 Four samples of 0.015g of PGM (0.015g / g) were impregnated with various amounts of platinum group metal-containing catalyst ("PGM") to provide activated fiber samples. Specifically, the activated fiber samples had 0.015g of PGM, 0.022g of PGM, 0.0307g of PGM, and 0.0462g of PGM. The PGM was prepared by mixing PtNO3 and PdNO3 solutions to achieve a 2:1 Pt:Pd ratio.

[0235] Each of the activated fiber samples was exposed to gas from an isothermal furnace with an output temperature of 400°C. The gas was then fed into a bank of calibrated gas emission analyzers, which measured the emission concentrations. From these measurements, light-off curves were generated for each of the activated fiber samples, demonstrating conversion performance over a range of times. Figure 14A shows the light-off curve for the conversion of carbon monoxide, and Figure 14B shows the light-off curve for the conversion of volatile organic compounds ("VOCs").

[0236] Example 2: Conventional ceramic honeycomb filters, namely, 400 cpsi and 900 cpsi filters, each 2 inches in diameter, were washcoated with a slurry containing PGM. The PGM content measured in the coated honeycomb filters was 0.0477 g for the 400 cpsi filter and 0.0307 g for the 900 cpsi filter. The filters were evaluated in the same manner as in Example 1. The results, along with the light-off curves for the 0.022 g PGM-activated fiber sample and the 0.0462 g PGM-activated fiber sample of Example 1, are shown in Figures 15A and 15B.

[0237] As shown in Figures 15A and 15B, each of the activated fiber samples outperformed the 900 cpsi filter and significantly outperformed the 400 cpsi filter, even though the 0.022 g PGM-activated fiber sample contained less than 72% of the PGM of the 900 cpsi filter and less than half of the PGM of the 400 cpsi filter.

[0238] Example 3 Alumina fiber (available from Unifrax I LLC, Tonawanda, NY, USA, under the registered trademark SAFFIL) with a surface area of ​​130 m 2 / g) was impregnated with 0.0462 g of PGM to provide an activated fiber sample. A 400 cpsi filter was washcoated with the slurry containing PGM, and the amount of PGM measured on the 400 cpsi filter was 0.0448 g. Each of the activated fiber sample and the 400 cpsi filter was evaluated as described in Example 1.

[0239] The activated fiber samples and 400 cpsi filters were then subjected to accelerated aging by heating in air at 800°C for 24 hours to simulate the harsh conditions experienced in many applications. The aged samples were then evaluated as described in Example 1. The results are shown in Figures 16A and 16B. As shown in Figures 16A and 16B, the aged activated fiber samples exhibited superior durability compared to the 400 cpsi filters. In fact, the aged activated fiber samples had shorter light-off times than both the aged and fresh 400 cpsi filters for both CO conversion and VOC conversion.

Claims

1. At least 15m ２ / g surface area of ​​inorganic fibers; an active agent incorporated into the inorganic fibers and / or applied to at least a portion of the inorganic fibers; and an adsorbent for lead or cadmium incorporated into the inorganic fibers and / or applied to at least a portion of the inorganic fibers; A fiber blanket having the active agent is present in an amount of 1 to 25 weight percent based on the total weight of the fiber blanket; The inorganic fibers have a median fiber diameter of 1 to 10 μm, The inorganic fibers are (i) fibers having 50 weight percent or more silica, and / or (ii) fibers having 50 weight percent or more alumina; and / or (iii) zirconia fibers having less than 1 weight percent titania and The inorganic fibers are (i) fibers having 50 weight percent or more silica; and (ii) fibers having 50 weight percent or more alumina; and (iii) zirconia fibers having less than 1 weight percent titania and the adsorbent for lead or cadmium is an aluminosilicate compound; The fiber blanket is formed by air laying. Fiber blanket.

2. The fiber blanket of claim 1 , wherein the activator is a transition metal-containing catalyst.

3. The fiber blanket of claim 2, wherein the active agent is present in an amount of 2 to 20 weight percent based on the total weight of the fiber blanket.

4. The fiber blanket of claim 2 , wherein the activator comprises a platinum group metal-containing catalyst.

5. 3. The fiber blanket of claim 2, further comprising at least one secondary agent selected from a carbon dioxide scavenger or a nitrogen oxide scavenger; The fiber blanket, wherein the secondary agent is incorporated into or applied to at least a portion of the inorganic fibers.

6. 10. The fiber blanket of claim 1, wherein the inorganic fibers have a median fiber diameter of 4 to 10 microns, and less than 0.1 weight percent of the inorganic fibers have a diameter less than 3 microns.

7. 2. The fiber blanket according to claim 1, wherein the inorganic fibers have a melting point of 1500°C or higher.

8. 1. An emission control device, comprising: A fiber blanket formed by air laying, the fiber blanket having a length of at least 15 m ２ a fiber blanket having inorganic fibers having a surface area of ​​1 / g, an activator incorporated into the inorganic fibers and / or applied to at least a portion of the inorganic fibers, and an adsorbent for lead or cadmium incorporated into the inorganic fibers and / or applied to at least a portion of the inorganic fibers; and a permeable support, wherein the fiber blanket is encapsulated within the permeable support, the permeable support allowing fluid communication therethrough; and the active agent is present in an amount of 1 to 25 weight percent based on the total weight of the fiber blanket; The inorganic fibers have a median fiber diameter of 1 to 10 μm, The inorganic fibers are (i) fibers having 50 weight percent or more silica, and / or (ii) fibers having 50 weight percent or more alumina; and / or (iii) zirconia fibers having less than 1 weight percent titania and The inorganic fibers are (i) fibers having 50 weight percent or more silica; and (ii) fibers having 50 weight percent or more alumina; and (iii) zirconia fibers having less than 1 weight percent titania and The adsorbent for lead or cadmium is an aluminosilicate compound. Device.

9. 10. The apparatus of claim 8, wherein the activator is a transition metal-containing catalyst.

10. 10. The device of claim 9, wherein the active agent is present in an amount of 3 to 10 weight percent based on the total weight of the fiber blanket.

11. 10. The apparatus of claim 9, wherein the activator comprises a platinum group metal-containing catalyst.

12. 10. The device of claim 9, further comprising at least one secondary agent selected from a carbon dioxide sequestering agent or a nitrogen oxide sequestering agent; The device, wherein the secondary agent is incorporated into or applied to at least a portion of the inorganic fibers.

13. 9. The device of claim 8, wherein the inorganic fibers have a median fiber diameter of 4 to 10 μm, and less than 0.1 weight percent of the inorganic fibers are less than 3 μm in diameter.

14. 10. The device of claim 9, wherein the inorganic fibers have a melting point of 1500°C or higher.

15. 10. The device of claim 9, wherein the permeable support is a mesh.

16. 16. The device of claim 15, wherein the permeable support is a metal mesh or a polymer mesh.

17. 10. The fiber blanket of claim 1, further comprising a nitrogen oxide scavenger incorporated into or applied to at least a portion of the inorganic fibers; the nitrogen oxide scavenger is at least one selected from the group consisting of barium carbonate, barium oxide, and barium hydroxide; A fiber blanket wherein the nitrogen oxide scavenger is present in an amount of 0.001 to 2 weight percent based on the total weight of the fiber blanket.

18. 11. The device of claim 10, further comprising a nitrogen oxide scavenger incorporated into or applied to at least a portion of the inorganic fibers; the nitrogen oxide scavenger is at least one selected from the group consisting of barium carbonate, barium oxide, and barium hydroxide; The apparatus wherein the nitrogen oxide scavenger is present in an amount of 0.001 to 2 weight percent based on the total weight of the fibrous blanket.

19. The fiber blanket of claim 1, wherein the inorganic fibers have 95 to 97 weight percent alumina and 3 to 5 weight percent silica.

20. 20. The fiber blanket of claim 19, wherein the inorganic fibers have crystalline alumina to promote crystallographic growth, and the crystalline alumina content is less than 1 weight percent.

21. 21. The fiber blanket of claim 20, wherein the inorganic fibers have a pore size distribution of 10 to 200 angstroms.

22. 22. The fiber blanket of claim 21, wherein the inorganic fibers have a pore size distribution of 50 to 150 angstroms.

23. 9. The apparatus of claim 8, wherein the inorganic fibers comprise 95 to 97 weight percent alumina and 3 to 5 weight percent silica.

24. 24. The device of claim 23, wherein the inorganic fibers comprise crystalline alumina to promote crystallographic growth, and the crystalline alumina content is less than 1 weight percent.

25. 25. The device of claim 24, wherein the inorganic fibers have a pore size distribution of 10 to 200 angstroms.

26. 25. The device of claim 24, wherein the inorganic fibers have a pore size distribution of 50 to 150 angstroms.

27. At least 15m ２ / g surface area of ​​inorganic fibers; an active agent incorporated into said inorganic fibers and / or applied to at least a portion of said inorganic fibers; A fiber blanket consisting of: the activator is one or more transition metal-containing catalysts; the active agent is present in an amount of 1 to 25 weight percent based on the total weight of the fiber blanket; The inorganic fibers have a median fiber diameter of 1 to 10 μm, The inorganic fibers are (i) fibers having 50 weight percent or more silica, and / or (ii) fibers having 50 weight percent or more alumina; and / or (iii) zirconia fibers having less than 1 weight percent titania It consists of, and The inorganic fibers are (i) fibers having 50 weight percent or more silica; and (ii) fibers having 50 weight percent or more alumina; and (iii) zirconia fibers having less than 1 weight percent titania and The fiber blanket is formed by air laying. Fiber blanket.

28. 28. The fiber blanket of claim 27, wherein the inorganic fibers have 95 to 97 weight percent alumina and 3 to 5 weight percent silica.

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