Solid powder cosmetics

Abstract

To provide a solid powder cosmetic that can be easily taken by a user with an applicator and highly adheres to the skin, offering a lasting cosmetic effect, and also having excellent impact resistance.SOLUTION: A solid powder cosmetic is prepared by removing a solvent from a mixture of the solvent and a cosmetic base, the cosmetic base containing following components (A)-(E): (A) fluorine-modified silicone oil, (B) silicone wax, (C) silicone oil (excluding components (A) and (B)), (D) a compound having a hydrophilic group and a lipophilic group in each molecule, with the lipophilic group being of a two-chain type, and (E) powder.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a solid powder cosmetic preparation. [Background technology]

[0002] Powder cosmetics, which are cosmetics blended with powder, are widely used as makeup cosmetics such as foundation, face powder, blush, eye shadow, eyebrow pencil, etc. Among these, many solid powder cosmetics that are molded into a solid form have been put on the market in terms of portability and texture.

[0003] Methods for molding solid powder cosmetics include a dry molding method in which a powdered composition is filled into a container such as a metal dish and then pressurized, and a wet molding method in which a solvent such as a volatile compound is added to a cosmetic base containing powder and oil to form a slurry, which is then filled into a container such as a metal dish and then molded by removing the solvent. Solid powder cosmetics obtained by the wet molding method have a smooth feel when used because the powder is systematically arranged to achieve a higher density when the solvent is removed from the slurried cosmetic base. However, when the solvent used in the wet molding method is removed, cracks can occur on the surface or gaps can form between the container and the powder cosmetic due to shrinkage, resulting in poor impact resistance.

[0004] Various means have been proposed to improve such impact resistance. Patent Document 1 discloses a solid powder cosmetic obtained by wet molding a cosmetic base containing fluorine-treated talc, hydrophobically treated silica, hydrophobically treated fine particle titanium dioxide, and a water-holding oil agent. [Prior art documents] [Patent documents]

[0005] [Patent Document 1] Japanese Patent Application Laid-Open No. 2018-177640 Summary of the Invention [Problem to be solved by the invention]

[0006] Various studies have been conducted to date on improving the impact resistance of solid powder cosmetics obtained by wet molding as described above. However, attempts to improve impact resistance usually result in the cosmetics becoming harder, which makes it difficult for the cosmetics to be removed when the user tries to take the solid powder cosmetic with their fingers or an applicator (poor cosmetic removal), making it difficult for the appropriate amount of cosmetic to be applied to the fingers or applicator.

[0007] Furthermore, after applying a solid powder cosmetic to the skin, the powder adheres to the skin, forming a cosmetic film, thereby achieving the cosmetic effect of the powder. Therefore, for solid powder cosmetics, adhesion of the cosmetic to the skin (excellent adhesion) is extremely important for achieving the cosmetic effect. Furthermore, the ability to maintain the cosmetic film formed by the adhered cosmetic for a long period of time is a fundamental performance, and therefore improvements in this performance are always desired by users.

[0008] However, solid powder cosmetics obtained by wet molding have not been sufficient in terms of achieving both improved impact resistance and a good feel when used (particularly the texture of the solid powder cosmetics, the adhesion of the solid powder cosmetics, and the durability of the cosmetic effect).

[0009] Therefore, an object of the present invention is to provide a solid powder cosmetic that has good flowability to an applicator, high adhesion to the skin, long-lasting cosmetic effects, and excellent impact resistance. [Means for solving the problem]

[0010] The present invention relates to the following components (A) to (E): (A) Fluorine-modified silicone oil (B) Silicone wax (C) Silicone oil (excluding components (A) and (B)) (D) A compound having a hydrophilic group and a lipophilic group in one molecule, and the lipophilic group is of a double-chain type. (E) Powder The solid powder cosmetic is obtained by removing the solvent from a mixture of a cosmetic base containing the above compound and a solvent. [Effects of the Invention]

[0011] The solid powder cosmetic of the present invention exhibits good adhesion to applicators, high adhesion of the cosmetic to the skin, long-lasting cosmetic effects, and excellent impact resistance. DETAILED DESCRIPTION OF THE INVENTION

[0012] Hereinafter, embodiments of the present invention will be described. However, the present invention is not limited to the following embodiments. In this specification, the range "X to Y" includes X and Y and means "X or more and Y or less." Furthermore, unless otherwise specified, operations and measurements of physical properties, etc. are performed under conditions of room temperature (20 to 25°C) and relative humidity of 45 to 55% RH.

[0013] A first embodiment of the present invention comprises the following components (A) to (E): (A) Fluorine-modified silicone oil (B) Silicone wax (C) Silicone oil (excluding components (A) and (B)) (D) A compound having a hydrophilic group and a lipophilic group in one molecule, and the lipophilic group is of a double-chain type. (E) Powder The solid powder cosmetic is obtained by removing the solvent from a mixture of a cosmetic base containing the above-mentioned compound and a solvent. The solid powder cosmetic of the first embodiment exhibits good adhesion to an applicator, high adhesion of the cosmetic to the skin, long-lasting cosmetic effects, and excellent impact resistance (reduction of cracking and shrinkage after solvent removal).

[0014] The detailed mechanism by which the cosmetic material of the present embodiment exhibits the above-described effects is unknown, but is thought to be as follows: Note that the following mechanism does not in any way limit the technical scope of the present invention.

[0015] In the wet molding method, a slurry-like composition is used, the viscosity of which is reduced using a solvent when the composition is filled into a container. The solvent is ultimately removed by absorption into an absorbent pad or drying. The inventors noted that if the solvent is difficult to remove from the slurry-like composition, it can lead to shrinkage and cracking of the final solid powder cosmetic. The use of oils (A) to (C) and component (D) reduces the compatibility between the solvent and the composition, improving solvent removal, and is therefore thought to improve the impact resistance of the final solid powder cosmetic. In particular, component (A) is fluorine-modified to be water- and oil-repellent, which is thought to reduce its compatibility with hydrocarbon oils and water, which are commonly used as solvents, and significantly improve solvent removal. However, for component (A) to exert its effects, it is important to combine it with a silicone oil (see Comparative Example 6 below). This is thought to be because the silicone oil of component (C) is necessary for component (A) to be uniformly dispersed within the formulation. Furthermore, because solvent removal is good, impact resistance is improved, and there is no particular need to increase the hardness of the formulation, such as by increasing the pressing pressure during production. Therefore, it is thought that the resulting solid powder cosmetic will not harden and that the cosmetic will have good toning. With regard to the toning of the cosmetic, components (B) and (D) also play an important role, and the blending of components (B) and (D) improves the toning of the cosmetic. This is because components (B) and (D) can improve the binding between powder particles, ensuring strength without the need for high pressing pressure during production, and it is thought that the resulting solid powder cosmetic will not harden and that the cosmetic will have good toning.

[0016] Furthermore, by using component (B), which is highly compatible with components (A) and (C), the wax is dispersed evenly around the powder, which is thought to improve the durability of the cosmetic effect. Furthermore, component (D) not only has high adhesion to the powder as mentioned above, but also has good compatibility with the oils in components (A) to (C), and furthermore, it adheres well to the skin, so it is thought to play an important role in forming and maintaining a uniform cosmetic film.

[0017] As used herein, the term "solid powder cosmetic" refers to a solid cosmetic containing powder (powder) as the main component. Here, "main component" refers to a composition containing 50% or more by mass of powder (powder). In this embodiment, the powder (powder) content is preferably greater than 60% by mass, more preferably 70% or more by mass, and even more preferably 80% or more by mass. The upper limit of the powder (powder) content is 100% by mass, but taking into account other components blended into the cosmetic, it is usually 99.9% by mass or less, and may be 99.5% by mass or less, or even 99% by mass or less.

[0018] Hereinafter, each component contained in the cosmetic of the first embodiment will be described.

[0019] (Component (A): Fluorine-modified silicone oil) Fluorine-modified silicone oil is an organopolysiloxane having at least one fluoroalkyl group in the molecule as an organic group. Specific examples of the fluoroalkyl group include fluorine-substituted alkyl groups such as trifluoropropyl, nonafluorohexyl, and heptadecylfluorodecyl, with trifluoropropyl being particularly preferred. The fluoroalkyl group-containing organopolysiloxane may be linear, branched, or cyclic. Furthermore, the fluorine-modified silicone oil may be modified with other substituents in addition to the fluorine modification.

[0020] An example of the fluorine-modified silicone oil is a linear fluorine-modified silicone oil having a fluoroalkyl group on the side chain, as represented by the following formula (1).

[0021] [ka]

[0022] In formula (1), A represents a fluoroalkyl group, m is an integer, and n is an integer of 1 or more. Examples of the fluoroalkyl group include an alkyl group in which any hydrogen atom in a linear or branched alkyl group having 1 to 20 carbon atoms is substituted with a fluorine atom, preferably an alkyl group in which any hydrogen atom in a linear alkyl group having 1 to 10 carbon atoms is substituted with a fluorine atom, and more preferably an alkyl group in which any hydrogen atom in a linear alkyl group having 1 to 4 carbon atoms is substituted with a fluorine atom. Specific examples of the fluoroalkyl group include trifluoromethyl, pentafluoroethyl, heptafluoropropyl, trifluoro-n-propyl, heptafluoroisopropyl, perfluoro-n-butyl, trifluoro-n-butyl, perfluoro-sec-butyl, perfluoro-tert-butyl, perfluoropentyl, perfluoroneopentyl, and perfluoroisopentyl.

[0023] The kinematic viscosity of the linear fluorine-modified silicone is, for example, 5 to 15,000 mm at 25°C. 2 / s, 50 to 5,000 mm 2 / s.

[0024] Commercially available linear fluorine-modified silicone oils may be used. Specific examples of linear fluorine-modified silicone oils include FL-5, FL-100-100CS, FL-100-450CS, FL-100-1,000CS, X-22-821, and X-22-822 (manufactured by Shin-Etsu Chemical Co., Ltd.), CFF-3400, CFF-3401, and CFF-3402 (manufactured by NUSIL), and FS-1265 (manufactured by Dow Corning Toray Co., Ltd.).

[0025] An example of the fluorine-modified silicone oil is a cyclic fluorine-modified silicone oil having a fluoroalkyl group on the side chain, represented by the following formula (2).

[0026] [ka]

[0027] In formula (2), R1, R2, and R3 each independently represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, or a phenyl group, preferably a hydrogen atom or an alkyl group, more preferably a hydrogen atom, a methyl group, an ethyl group, or a propyl group, and particularly preferably a hydrogen atom or a methyl group. In formula (2), A represents a fluoroalkyl group. Examples and preferred examples of the fluoroalkyl group are as described above. In formula (2), q represents an integer of 0 to 3, r represents an integer of 1 to 6, and (q + r) represents an integer of 3 to 6, preferably q = 0 or 1, and r = 4 or 5, more preferably q = 0, and r = 4 or 5.

[0028] In particular, taking into consideration the transfer of the cosmetic to applicators or fingers, component (A) is preferably a cyclic fluorine-modified silicone oil, and more preferably trifluoropropylcyclopolysiloxane represented by the following formula (2).

[0029] [ka]

[0030] (wherein p is an integer of 3 to 6) Specifically, examples of cyclic fluorine-modified silicone oils include, by INCI name (International Nomenclature Cosmetic Ingredient labeling names), trifluoropropylcyclotetrasiloxane, trifluoropropylcyclopentasiloxane, and the like, and a commercially available product thereof is KF-5002 (manufactured by Shin-Etsu Chemical Co., Ltd.), which is a mixture of trifluoropropylcyclotetrasiloxane and trifluoropropylcyclopentasiloxane.

[0031] As the cyclic fluorine-modified silicone oil, commercially available products may be used, and specific examples include KF-5002 (manufactured by Shin-Etsu Chemical Co., Ltd.).

[0032] The component (A) may be used alone or in combination of two or more types.

[0033] The content of component (A) is preferably 10% by mass or more of the total amount of components (A) to (C) from the viewpoint of suppressing cracking and shrinkage after solvent removal, more preferably 15% by mass or more from the viewpoint of shrinkage suppression, and more preferably 25% by mass or more from the viewpoint of adhesion. Also, the content of component (A) is preferably 60% by mass or less, more preferably 45% by mass or less from the viewpoint of adhesion.

[0034] Furthermore, in consideration of the effects of the present invention, the content of component (A) in the solid powder cosmetic is preferably 0.1 to 10 mass%, more preferably 0.5 to 8 mass%, even more preferably 0.5 to 5 mass%, and particularly preferably more than 1.1 mass% but not more than 4 mass%.

[0035] (Component (B): Silicone wax) Examples of silicone waxes include alkyl-modified silicone waxes, higher fatty acid-modified silicone waxes, and higher alcohol-modified silicone waxes. The silicone waxes may be used alone or in combination. Fluorine-modified silicone waxes are included in component (A).

[0036] As the silicone wax, a silicone wax modified with an alkyl group having 8 to 30 carbon atoms (hereinafter also referred to as alkyl-modified silicone wax) is preferred, as this further enhances the effects of the present invention (especially improving the durability of the cosmetic effect).

[0037] Alkyl-modified silicone wax refers to dimethyl silicone modified with an alkyl group. The alkyl group may be linear or branched. The alkyl group preferably has 8 to 30 carbon atoms, more preferably 12 to 30 carbon atoms, and even more preferably 16 to 24 carbon atoms.

[0038] The alkyl group may be substituted at any position, and the substitution may be at one end, at both ends, random, or the like. Furthermore, a mixture of silicone waxes modified with different alkyl groups may be used. The alkyl-modified silicone wax may also be modified with other substituents in addition to the alkyl group.

[0039] Examples of alkyl-modified silicone waxes include, but are not limited to, alkyl methicone wax, alkyl dimethicone wax, silsesquioxane resin wax, etc. Specific examples of alkyl-modified silicone waxes include stearyl dimethicone, alkyl (C26-28) dimethicone, alkyl (C30-45) methicone, stearoxy dimethicone, behenoxy dimethicone, cetyl dimethicone, alkyl (C30-45) dimethylsilyl polypropyl silsesquioxane, etc. Among these, from the viewpoint of adhesion of the cosmetic to the skin and durability of the cosmetic effect, the silicone wax is preferably stearyl dimethicone, alkyl (C26-28) dimethicone, stearoxy dimethicone, behenoxy dimethicone, cetyl dimethicone, or alkyl (C30-45) methicone, more preferably stearyl dimethicone, alkyl (C26-28) dimethicone, stearoxy dimethicone, behenoxy dimethicone, or cetyl dimethicone, even more preferably stearyl dimethicone, cetyl dimethicone, stearoxy dimethicone, or behenoxy dimethicone, and particularly preferably stearyl dimethicone, cetyl dimethicone, or stearoxy dimethicone.

[0040] The alkyl-modified silicone wax preferably has a melting point of 25 to 50°C from the viewpoint of improving the compatibility of components (A) and (C).

[0041] The alkyl-modified silicone wax may be a commercially available product, and specific examples thereof include DC2503 Cosmetic Wax (melting point 32°C) (manufactured by Toray Dow Corning Co., Ltd.) as stearyl dimethicone, ABIL (registered trademark) Wax 9800 (melting point 40°C), ABIL (registered trademark) Wax 9801 (melting point 40°C), and ABIL (registered trademark) Wax 9840 (melting point 40°C) (manufactured by EVONIK Co., Ltd.) as cetyl dimethicone, BELSIL (registered trademark) CDM 3526 VP (melting point 35°C) (all manufactured by Wacker Asahi Kasei Silicone Co., Ltd.) as alkyl (C26-28) dimethicone, ABIL (registered trademark) Wax 2434 (melting point 25°C) (manufactured by EVONIK Co., Ltd.) as stearoxy dimethicone, and ABIL (registered trademark) Wax as behenoxy dimethicone. Examples include 2440 (melting point 40°C) (manufactured by EVONIK), and cetyl dimethicone such as SF1632 (melting point 30°C) (manufactured by Momentive Performance Materials).

[0042] Considering the adhesion to the skin and the durability of the cosmetic effect, the content of component (B) in the solid powder cosmetic is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, and even more preferably 0.1% by mass or more. Also, considering the transfer of the cosmetic to an applicator or the like, the content is preferably 2% by mass or less, and more preferably 0.8% by mass or less.

[0043] (Component (C): Silicone oil) Examples of silicone oils include dimethylpolysiloxane (dimethicone), methyltrimethicone, methylphenylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, tetramethyltetrahydrogencyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane, diphenylsiloxyphenyltrimethicone, polyether-modified dimethylpolysiloxane, oleyl-modified dimethylpolysiloxane, polyvinylpyrrolidone-modified dimethylpolysiloxane, alkyl-modified dimethylpolysiloxane, phenyl-modified silicone oil, etc. Silicone oils may be used alone or in combination of two or more.

[0044] Among these, from the viewpoint of impact resistance, phenyl-modified silicone oil is preferable as component (C). The phenyl-modified silicone oil is not particularly limited, but examples thereof include triphenyldimethylvinyldisiloxane, diphenylsiloxyphenyltrimethicone, trimethylpentaphenyltrisiloxane, diphenyldimethicone, trimethylsiloxyphenyldimethicone, and phenyltrimethicone. The phenyl-modified silicone oil may be used alone or in combination of two or more.

[0045] Among these, from the viewpoint of impact resistance, it is preferable to use at least diphenylsiloxyphenyl trimethicone, diphenyl dimethicone, and phenyl trimethicone, more preferably diphenylsiloxyphenyl trimethicone and diphenyl dimethicone, and most preferably diphenylsiloxyphenyl trimethicone.

[0046] From the viewpoint of impact resistance, the content of component (C) in the solid powder cosmetic is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and even more preferably 1% by mass or more. Also, from the viewpoint of cosmetic effect, the content of component (C) is preferably 10% by mass or less, more preferably 8% by mass or less, and even more preferably 5% by mass or less.

[0047] (Component (D): A compound having a hydrophilic group and a lipophilic group in one molecule, and the lipophilic group is of a double-chain type) Component (D) is a compound that has both a hydrophilic and lipophilic group in one molecule, and the lipophilic group is two-chain. The presence of the hydrophilic and lipophilic groups allows it to interact with powders, regardless of whether or not the surface is treated with component (E), and is thought to improve the bonding strength between powders. Furthermore, because the lipophilic group is two-chain, it is possible to increase the bonding strength between powders more than with a single-chain type, and at the same time, the lipophilic chains are oriented in a certain direction, which is thought to improve functionality.

[0048] Examples of component (D) include phospholipids, N-acylamino acids or salts thereof, and behendimonium ethyl stearyl phosphate, double-chain biscarboxylate-type amphiphilic compounds (commercially available products include, for example, Gemisurf α142 (dicarboxylic acid having two lauryl groups), manufactured by Chukyo Yushi Co., Ltd.), and bispyridimonium quaternary ammonium salt-type amphiphilic compounds (commercially available products include, for example, Hygenia S-100 (3,3'-(butane-1,4-dioxydimethylene)-N,N-didecyldipyridinium dibromide), manufactured by Tama Chemical Industry Co., Ltd.).

[0049] Among these, from the viewpoints of improving impact resistance and prolonging the duration of cosmetic effects, it is preferable that component (D) be at least one selected from the group consisting of phospholipids, N-acylamino acids or salts thereof, and behendimonium ethyl stearyl phosphate.

[0050] Phospholipids can generally be classified into two types: glycerophospholipids with a glycerin backbone and sphingophospholipids with a sphingosine backbone. Phospholipids as component (D) include glycerophospholipids and sphingophospholipids. Examples of glycerophospholipids include, but are not limited to, phosphatidylcholine (also known as lecithin), phosphatidylethanolamine, phosphatidylserine, phosphatidylinositol, phosphatidylglycerol, and diphosphatidylglycerol. Examples of sphingophospholipids include, but are not limited to, sphingomyelin. One or more of these compounds may be used as the phospholipid in the present invention. Examples of the phospholipid in the present invention include egg yolk phospholipids, soybean phospholipids, or purified products thereof and / or hydrogenated or hydroxide products thereof. Furthermore, the present invention may also include lysophospholipids, in which one of the fatty acids of the phospholipids has been removed. Commercially available products include Resinol S-10E, Resinol S-10EX (manufactured by Nikko Chemicals Co., Ltd.), Basis LS-60HR and Basis LP-20 (manufactured by Nisshin Oillio Group Co., Ltd.).

[0051] An N-acylamino acid is an amino acid in which at least one amino group is acylated with an acyl group. In this specification, an N-acylamino acid or a salt thereof may also be referred to as an N-acylamino acid (salt).

[0052] The acyl group is preferably a saturated or unsaturated, linear, branched, or cyclic acyl group having 6 to 30 carbon atoms, more preferably a saturated or unsaturated, linear or branched acyl group having 8 to 20 carbon atoms, and even more preferably a saturated linear acyl group having 12 to 18 carbon atoms. Note that the number of carbon atoms referred to here refers to the number of carbon atoms present in one acyl group when multiple acyl groups are present. Examples of acyl groups include lauroyl, myristoyl, palmitoyl, stearoyl, isostearoyl, and oleoyl groups.

[0053] Examples of salts include salts with sodium, potassium, magnesium, calcium, aluminum, zinc, monoethanolamine, diethanolamine, triethanolamine, etc., and sodium, magnesium, calcium, and triethanolamine are preferred, sodium and magnesium are more preferred, and sodium is even more preferred.

[0054] The N-acylamino acid (salt) that can be used as component (D) is not particularly limited, but specific examples include lysine dilauroyl glutamate, sodium dilauroyl glutamate lysine, and the like.

[0055] Behendimonium ethyl stearyl phosphate is a compound having the following structure:

[0056] [ka]

[0057] Behendimonium ethyl stearyl phosphate is a phospholipid-like compound in which a nitrogen-containing alcohol is added to a phosphate ester. Because of its structure, it has a very high affinity for the skin, while its relatively small molecular weight allows it to easily interact with powders and bond to their surfaces, helping the powders adhere evenly to the skin. Therefore, incorporating behendimonium ethyl stearyl phosphate into solid powder cosmetics makes it easier for the powder to adhere to the skin (facilitating the formation of a cosmetic film). Furthermore, behendimonium ethyl stearyl phosphate has a good balance of lipophilicity and hydrophilicity, and excellent water- and oil-repellent properties, which can contribute to improved makeup wear.

[0058] The component (D) may be used alone or in combination of two or more types.

[0059] In consideration of adhesion to the skin, the content of component (D) in the solid powder cosmetic is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and even more preferably 0.3% by mass or more. In consideration of impact resistance, the content of component (D) is preferably 5% by mass or less, more preferably 3% by mass or less, and particularly preferably 2.5% by mass or less. In a preferred embodiment of the present invention, the content of component (D) in the solid powder cosmetic is 0.05 to 5% by mass.

[0060] Component (D) may be used as a surface treatment agent for the powder of component (E). In this case, the content of component (D) is not included in the content of component (E).

[0061] The surface treatment of component (E) with component (D) can be carried out by a conventional method. For example, component (D) and the powder to be treated are added to a solvent (e.g., an alcohol such as isopropyl alcohol (IPA) or isoparaffin (e.g., IP Solvent (Idemitsu Kosan)) and stirred in a ball mill or the like. After drying, washing with water, and filtering as necessary to remove impurities, the resulting mixture is dried and pulverized to obtain the desired surface-treated powder. Alternatively, component (D) and another compound serving as a surface treatment agent may be simultaneously used for surface treatment.

[0062] (Component (E): Powder) Powders are blended to impart cosmetic effects such as makeup effects.

[0063] The powder is not particularly limited in terms of shape (e.g., spherical, plate-like, spindle-like, needle-like, etc.), particle size (e.g., mist-like, fine particles, pigment-grade, etc.), particle structure (e.g., porous, non-porous, etc.), etc. Examples of powder include inorganic powders, glitter powders, organic powders, colored pigments, composite powders, polyethylene terephthalate-aluminum-epoxy laminated powder, polyethylene terephthalate-polymethyl methacrylate laminated powder, etc.

[0064] Examples of inorganic powders include carbon black, magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, aluminum silicate, aluminum hydroxide, magnesium silicate, magnesium aluminum silicate, titanium oxide, zinc oxide, aluminum oxide, cerium oxide, magnesium oxide, zirconium oxide, iron oxide, mica, synthetic mica, sericite, synthetic sericite, talc, (fluoride / hydroxide / oxide) / (Mg / K silicon) (calcined talc-potassium silicofluoride), kaolin, silicon carbide, barium sulfate, boron nitride, silica, and glass powder.

[0065] Examples of glittering powders include bismuth oxychloride, titanium mica (titanium oxide coated mica), iron oxide treated mica, iron oxide treated titanium mica, organic pigment treated titanium mica, silicon dioxide / titanium oxide coated mica, titanium oxide coated glass powder, iron oxide / titanium oxide coated glass powder, and aluminum powder.

[0066] Examples of organic powders include metal soap powders such as zinc laurate, zinc myristate, zinc stearate, magnesium laurate, magnesium myristate, and magnesium stearate; nylon, polymethylsilsesquioxane, crosslinked organopolysiloxane polymers, polystyrene, polyurethane, polyethylene, polypropylene, polyethylene terephthalate, polymethacrylates such as methyl methacrylate, and crosslinked polymethacrylates such as methyl methacrylate crosspolymers; complexes of polymethyl methacrylate and polyisoprene; polyacrylic esters; acrylonitrile-methacrylic acid copolymer powders; polytetrafluoroethylene; and (HDI / PPG / polycaprolactone) crosspolymers. Examples of crosslinked organopolysiloxane polymers include partially crosslinked methylpolysiloxanes such as dimethicone / vinyldimethicone crosspolymer, partially crosslinked methylphenylpolysiloxanes such as dimethicone / phenyldimethicone crosspolymer, partially crosslinked polyether-modified silicones such as dimethicone copolyol crosspolymer, partially crosslinked alkyl-modified silicones, and partially crosslinked alkyl-polyether-modified silicones such as lauryldimethicone-PEG crosspolymer. Examples of these crosslinked organopolysiloxane polymers include those with INCI names such as dimethicone / vinyldimethicone crosspolymer, dimethicone / phenylvinyldimethicone crosspolymer, dimethicone / vinyldiphenyldimethicone / methicone crosspolymer, dimethicone / lauryldimethicone crosspolymer, diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane crosspolymer, and vinyldimethicone / methicone silsesquioxane crosspolymer.

[0067] Examples of colored pigments include inorganic red pigments such as red iron oxide (red iron oxide), iron hydroxide, and iron titanate, inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as yellow iron oxide and ochre, inorganic black pigments such as black iron oxide and carbon black, inorganic purple pigments such as manganese violet and cobalt violet, inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide, and cobalt titanate, inorganic blue pigments such as iron blue and ultramarine, lakes of tar-based pigments made with aluminum or the like, lakes of natural pigments, and synthetic resin powders made by combining these powders. Examples of tar dyes include Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228, Red No. 230, Red No. 401, Red No. 505, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Yellow No. 204, Yellow No. 401, Blue No. 1, Blue No. 2, Blue 201, Blue No. 404, Green No. 3, Green 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, and Orange No. 207.

[0068] Examples of composite powders include titanium oxide-coated mica, iron oxide-coated mica, iron oxide-coated titanium-mica, zinc oxide-coated titanium-mica, barium sulfate-coated titanium-mica, organic pigment-treated titanium-mica, silicon dioxide-titanium oxide-coated mica, titanium oxide-coated glass powder, iron oxide-titanium oxide-coated glass powder, titanium oxide-containing silicon dioxide, and zinc oxide-containing silicon dioxide.

[0069] The powder may be surface-treated. Examples of surface treatments include fluorine compound treatment, silica treatment, alumina treatment, aluminum hydroxide treatment, silicone treatment (methicone treatment, hydrogen dimethicone treatment, etc.), silicone resin treatment, pendant treatment, silane coupling agent treatment, titanium coupling agent treatment, silane treatment, oil treatment, N-acylated lysine treatment, polyacrylic acid treatment, metal soap treatment, acrylic resin treatment, and metal oxide treatment. These surface treatments may be used alone or in combination of two or more.

[0070] The amount of the surface treatment agent to be used is preferably 0.1 to 30% by mass, more preferably 0.5 to 20% by mass, and even more preferably 1 to 10% by mass, based on the untreated powder.

[0071] The surface treatment can be carried out by a conventionally known method. For example, a surface treatment agent and powder particles to be treated are added to a solvent, stirred in a ball mill or the like, and then dried, washed with water, and filtered repeatedly as necessary to remove impurities, followed by drying and pulverization to obtain the desired surface-treated powder. Furthermore, several types of compounds that are surface treatment agents can be used simultaneously for surface treatment, or surface treatment can be carried out in advance with one compound and then with another compound.

[0072] The component (E) may be used alone or in combination of two or more types.

[0073] The content of component (E) is 50% by mass or more relative to the cosmetic, but may be 60% by mass or more, 70% by mass or more, or 80% by mass or more. In the case of surface-treated powders, the amount of the powder includes the amount of the surface treatment agent.

[0074] (Other ingredients) In addition to the above components, oils other than components (A) to (C), alcohol, preservatives, antioxidants, cosmetic ingredients, antibacterial agents, fragrances, chelating agents (such as EDTA), UV absorbers, film-forming agents, fragrances, and the like, which are commonly used in cosmetics, may also be appropriately contained within a range that does not impair the effects of the present invention. In consideration of the effects of the present invention, it is preferable that the amount of oils other than components (A) to (C) be as small as possible, and specifically, the amount of oils other than components (A) to (C) relative to the total amount of oils is preferably 30% by mass or less, more preferably 25% by mass or less, and even more preferably 20% by mass or less.

[0075] Furthermore, in the solid powder cosmetic of the present application, the water content is preferably 3% by mass or less, more preferably 1% by mass or less, and preferably substantially free of water. Here, "substantially free of water" means that the content of impurities is acceptable, for example, 0.1% by mass or less.

[0076] The solid powder cosmetic of this embodiment is obtained by removing the solvent from a mixture of a cosmetic base containing components (A) to (E) and the solvent.

[0077] The cosmetic base is prepared by stirring and mixing the above-mentioned components using a device typically used to produce powder cosmetics. More specifically, the cosmetic base is prepared by first mixing components (A) to (C), or optionally an oily component containing component (D), and, if necessary, heating and dissolving the mixture. Meanwhile, a powder containing component (E) and, optionally, a powder surface-treated with component (D) are uniformly mixed. The oily component is added to this mixture, uniformly dispersed, and then pulverized to prepare the cosmetic base.

[0078] Next, a mixture of the cosmetic base and the solvent is prepared. This mixture is usually in a slurry state. Hereinafter, the mixture of the cosmetic base containing components (A) to (E) and the solvent will also be simply referred to as the mixture.

[0079] The solvent used can be either non-volatile or volatile, but a solvent with a boiling point of 260°C or less at normal pressure is preferred. Specific examples of the solvent include aqueous solvents such as low-boiling alcohols such as water, ethyl alcohol, propyl alcohol, isopropyl alcohol, and butyl alcohol, and mixed solvents of water and low-boiling alcohols; and oily solvents such as (low-boiling) hydrocarbon oils such as isododecane, isohexadecane, and light liquid isoparaffin. These can be used alone or in combination as a mixture of two or more.

[0080] The solvent is preferably a hydrocarbon oil or an aqueous solvent, and more preferably a low-boiling hydrocarbon oil such as isododecane, isohexadecane, or light liquid isoparaffin (hydrogenated polyisobutene), as these solvents are more likely to exhibit the effects of the present invention.

[0081] The amount of solvent to be mixed is selected arbitrarily to provide fluidity for filling the pre-molded mixture into a container or tray, but it is preferable to use 10 to 200 parts by mass of solvent per 100 parts by mass of cosmetic base.Within this range, the solvent can be easily removed.

[0082] Furthermore, in this specification, fluidity refers to a state in which, when 30 g of a mixture of a cosmetic base whose main component is powder and a solvent is placed in a container ("Pill Bottle PS-6K" manufactured by Daiichi Glass Co., Ltd.) with an inner diameter of 2.47 cm, a body diameter of 4.05 cm, and an overall height of 7.4 cm, the container is sealed with the attached lid, and then tilted 90 degrees in an environment of 25°C and 1 atmosphere and left to stand for 1 minute, a portion of the mixture adheres to the inside of the lid.

[0083] The mixture obtained above is then filled into a container, such as a metal dish or a resin dish, and is preferably compression molded after filling.

[0084] Next, the solvent is removed. While the removal method is not particularly limited, it is preferable to remove the solvent by placing one or more layers of paper, cloth, or the like in contact with the powder cosmetic filled in the container during and / or after compression molding, and then allowing the solvent to be absorbed. Moderate pressure may be applied when absorbing the solvent. Furthermore, when filling a container or inner tray with a mixture of the cosmetic base and solvent, it is preferable to gently press the mixture using a pad or the like to smooth the surface. During this pressing, a porous press head or absorbent may also be used to absorb the volatile solvent. Furthermore, the solvent can also be removed by drying. The conditions for this are appropriately determined depending on the boiling point and specific heat of the solvent. For example, in the case of light liquid isoparaffin, drying is performed at 50 to 80°C for approximately 5 to 20 hours.

[0085] The solid powder cosmetic of this embodiment can be used in makeup cosmetics such as foundation, face powder, face powder (white powder), concealer, eye color (eye shadow), eyeliner, eyebrow pencil, mascara, blush, lipstick, sunscreen cosmetics, and cosmetic base; skin care cosmetics such as body powder; and preferably, the cosmetic is a makeup cosmetic such as foundation, face powder, face powder, eye color, cosmetic base, sunscreen cosmetics, or blush, in which the effects of the present application are more likely to be exhibited, and more preferably, a foundation, face powder, or face powder, which have a large application area. Furthermore, the method of use can include application by hand or finger, or by impregnating a puff, sponge, or the like with the cosmetic.

[0086] The blending amount of each component in the cosmetic base is the same as the blending amount of each component in the resulting solid powder cosmetic. [Example]

[0087] The effects of the present invention will be explained using the following examples and comparative examples. In the examples, the units "parts" and "%" are sometimes used, but unless otherwise specified, they represent "parts by mass" or "% by mass." Unless otherwise specified, each operation is carried out at room temperature (25°C).

[0088] (Examples 1 to 14, 16, Comparative Examples 1 to 7, 11) A solid powder cosmetic (foundation) was prepared according to the formulation shown in Table 1 below.

[0089] (Manufacturing method) (1) Mix and dissolve components (A), (B), (C), and (D) at 70°C. (2) (1) is added to the powder component (component (E)) and dispersed uniformly. After pulverization, a cosmetic base is obtained. (3) 100 parts by mass of the cosmetic base (2) and 40 parts by mass of the solvent (light liquid isoparaffin or water) are uniformly mixed to prepare a slurry. (4)(3) is filled into a metal plate and compression molded under vacuum. (5) The molded product is dried in a dryer at 70°C for 10 hours to obtain a cosmetic material.

[0090] (Example 15, Comparative Examples 8 to 10) A solid powder cosmetic (foundation) was prepared according to the formulation shown in Table 1 below.

[0091] (Manufacturing method) (1) Mix and dissolve components (A), (B), and (C) at 70°C. (2) After components (D) and (E) are uniformly mixed, (1) is added and dispersed uniformly, and after pulverization, a cosmetic base is obtained. (3) 100 parts by mass of the cosmetic base (2) and 40 parts by mass of the solvent (light liquid isoparaffin) are mixed uniformly to prepare a slurry. (4)(3) is filled into a metal plate and compression molded under vacuum. (5) The molded product is dried in a dryer at 70°C for 10 hours to obtain a cosmetic material.

[0092] (Evaluation method 1: Impact resistance) The appearance of five sheets of each of the powder foundations of the Examples and Comparative Examples after drying was judged according to the following evaluation criteria, with the most frequently rated item being the judged evaluation.

[0093] (crack prevention) (Evaluation criteria): (Judgment) No cracks at all:◎ Cracks less than 1 / 10 of the diameter of the metal plate are observed: 〇 Cracks observed are 1 / 10 or more but less than 1 / 3 of the diameter of the gold plate: △ Cracks measuring 1 / 3 or more of the diameter of the gold plate are observed: × (shrinkage suppression) (Evaluation criteria): (Judgment) No shrinkage observed: Shrinkage less than 0.5mm: YES Shrinkage of 0.5mm or more but less than 1mm: △ Shrinkage of 1mm or more: ×

[0094] (Evaluation method 2: Adequacy of the amount of adhesion to the applicator (Tre)) Each sample was tested by a panel of 20 experts, who each rated it on a four-point scale using the absolute evaluation below, and the average score was calculated from the total scores of all panelists, and judged according to the following criteria. Specifically, each sample filled in a container was taken with an applicator (puff), and the amount of sample that adhered was evaluated to see if it was appropriate for actual use.

[0095] (Evaluation criteria) (Rating): (Evaluation) 4: The amount of adhesive applied to the applicator is appropriate. 3: The amount of product adhering to the applicator is slightly too much or slightly insufficient. 2: Too much or not enough product is adhering to the applicator. 1: Too much or no product adheres to the applicator. <Judgment criteria> (Average score): (Judgment) 3.5 points or above: ◎ 2.5 points or more and less than 3.5 points: Yes Less than 2.5 points: ×.

[0096] (Evaluation method 3: Strength of adhesion to skin (adhesion to skin)) Each sample was tested by a panel of 20 experts, who each rated it on a scale of 1 to 5 using the absolute criteria below. The average score was calculated from the total scores of all panelists and judged according to the following criteria. Specifically, each sample was spread once on the skin using a urethane makeup application mat, and the strength of the cosmetic's adhesion to the skin (the ability to form a cosmetic film) was evaluated.

[0097] (Absolute standard) (Score): (Evaluation result) 5: Very sensitive 4: Feel 3: Somewhat felt 2: Hardly felt 1: No feeling at all <Judgment criteria> (Average score): (Judgment) (Average score): (Judgment) 4.5 points or above: ◎ 3.5 points or more and less than 4.5 points: Yes 2 points or more and less than 3.5 points: △ Less than 2 points: ×.

[0098] (Evaluation method 4: Makeup lasting effect (lasting effect of makeup)) Each sample was tested by a panel of 20 experts, who each rated it on a scale of 1 to 5 using the absolute standards below. The average score was calculated from the total scores of all panelists and judged according to the following criteria. Specifically, an appropriate amount of each sample was applied to the skin, and the makeup wear (i.e., the longevity of the makeup effect) was evaluated 8 hours after application.

[0099] (Absolute standard) (Rating): (Evaluation) 5: The makeup lasts well and the effects of the makeup last for a long time. 4: The makeup lasts well and the effect is noticeable, but it is slightly insufficient. 3: The makeup lasts a little long, and the makeup effect does not last long enough, but it is within the acceptable range. 2: The makeup does not last long, and the makeup effect does not last long enough, which is outside the acceptable range. 1: The makeup lasts very poorly and the makeup effect does not last long enough. <Judgment criteria> (Average score): (Judgment) 4.5 points or above: ◎ 3.5 points or more and less than 4.5 points: Yes 2 points or more and less than 3.5 points: △ Less than 2 points: ×

[0100] [Table 1-1]

[0101] [Table 1-2]

[0102] [Table 2-1]

[0103] [Table 2-2]

[0104] From the above results, the solid powder cosmetics (foundation) of the Examples were excellent in impact resistance, cosmetic wear, skin adhesion, and cosmetic effect durability. On the other hand, Comparative Example 1, which did not contain component (A), was significantly inferior in impact resistance. Comparative Example 2, which did not contain component (B), or Comparative Examples 3 to 5, in which component (B) was replaced with another wax, were significantly inferior in cosmetic effect durability. Furthermore, Comparative Example 6, which did not contain component (C), was significantly inferior in impact resistance. Comparative Example 7, which did not contain component (D), was significantly inferior in skin adhesion and cosmetic effect durability. Comparative Examples 8 to 10, which contained powder treated with other surface treatment agents instead of component (D), or Comparative Example 11, which contained lauroyl lysine instead of component (D), were significantly inferior in cosmetic wear and impact resistance.

[0105] Example 17: Solid powder cosmetic (foundation) (Ingredients) (Content) 1. Cyclic fluorine-modified silicone oil (ingredient A) (*1) 1.5% 2. Stearyl dimethicone (ingredient B) (*3) 0.4% 3. Diphenylsiloxyphenyl trimethicone (ingredient C) (*5) 2.5% 4. Diphenyl dimethicone (ingredient C) (*6) 0.5% 6. Dimethicone (ingredient C) (*7) 0.5% 6. Behendimonium ethyl stearyl phosphate (ingredient D) (*8) 1.0% 7. Hydrogenated soybean phospholipid (ingredient D) (*9) 0.1% 8. Dilauramidoglutamide lysine (1%) treated mica (ingredient D) (ingredient E) 10.0% 9. Trimethylsiloxysilicate (*11) 0.1% 10. Silica (ingredient E) (*12) 3.0% 11. Silica (ingredient E) (*13) 2.0% 12. (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (ingredient E) (*14) 3.0% 13. Synthetic Iron Phlogopite (Component E) (*15) 7.0% 14. Boron nitride (ingredient E) (*16) 10.0% 15. Mica (ingredient E) (average particle size 19 μm) remaining 16. Amodimethicone 3% Treated Mica (ingredient E) (*17) 5.0% 17. Talc (ingredient E) (*18) 25.0% 18. Polyethylene terephthalate (ingredient E) (*19) 1.0% 19. Bengala (ingredient E) (*20) 0.3% 20. Yellow iron oxide (ingredient E) (*21) 2.0% 21. Black iron oxide (ingredient E) (*22) 0.2% 22. Titanium oxide, aluminum hydroxide (ingredient E) (*23) 5.0% 23. Titanium dioxide treated with 2% isopropyl titanium triisostearate (*24) (ingredient E) 10.0% 24. Hydrogen Dimethicone-Treated Zinc Oxide (ingredient E) (*25) 5.0% 25. Chlorphenesin 0.05% 26. Ethylhexylglycerin (*26) 0.1% 27.Fragrance 0.1% (*11) SR1000 (Momentive Performance Materials Japan) (*12) Silica Microbead P-1505 (JGC Catalysts and Chemicals) (*13) God Ball D11-796C (manufactured by Suzuki Oil Industries Co., Ltd.) (*14) KSP-100 (Shin-Etsu Chemical Co., Ltd.) (*15) PDM-FE(TS) (manufactured by Topy Industries) (*16)CCS102-JA BORON NITRIDE POWDER (Yuka Sangyo Co., Ltd.) (*17) Mica Y-2300WA3 (Yamaguchi Mica Co., Ltd.) (*18) Talc powder EX-15 (Yamaguchi Mica Co., Ltd.) (*19) Snow Leaf P (Oken) (*20) R-516P (manufactured by Titanium Industries Co., Ltd.) (*21) BL-100P (manufactured by Titanium Industries Co., Ltd.) (*22) YP1200P (manufactured by Titanium Industries Co., Ltd.) (*23) TIPAQUE CR-50 (Ishihara Sangyo Kaisha) (*24) ITT-2 TiO2 CR-50 (manufactured by Daito Chemical Industry Co., Ltd.) (*25) XZ-300F-LP (Sakai Chemical Industry Co., Ltd.) (*26) ADEKA NOL GE-RF (manufactured by ADEKA Corporation) (Manufacturing method) A. Components 1 to 9 were heated at 70°C to obtain a solution (or dispersion). B. Ingredients 10 to 24 were mixed to obtain a mixture. C. A and ingredients 25 to 27 were added to the mixture obtained in B to obtain a mixture. D. The mixture obtained in C was pulverized to obtain a powdered cosmetic. E. The powdered cosmetic material obtained in D was mixed with a volatile solvent (hydrogenated polyisobutene) to obtain a slurry. F. The slurry obtained in E was filled into a container and molded, and then the volatile solvent was removed to obtain a solid powder cosmetic.

[0106] In Example 17, the content of component (A) relative to the total amount of components (A) to (C) was 27%, and the content of component (D) was 1.2%. The solid powder cosmetic (foundation) of Example 18 showed no cracking or shrinkage after solvent removal and exhibited good filling and molding properties. Furthermore, the amount of transfer onto the puff was good, and the adhesion to the skin and the durability of the cosmetic effect were also good.

[0107] Example 18: Solid powder cosmetic (foundation) (Ingredients) (Content) 1. Cyclic fluorine-modified silicone oil (ingredient A) (*1) 2.0% 2. Fluorine-modified silicone (ingredient A) (*2) 0.5% 3. Stearoxydimethicone (ingredient B) (*27) 0.2% 4. Diphenylsiloxyphenyl trimethicone (ingredient C) (*5) 2.0% 5. Diphenyl dimethicone (ingredient C) (*6) 1.0% 6. Dimethicone (ingredient C) (*28) 0.1% 7. Squalane 0.01% 8. Dipentaerythrityl hexa(hydroxystearate / stearic acid / rosinate) (*29) 0.01% 9. Sorbitan sesquiisostearate (*30) 0.1% 10. Behendimonium ethyl stearyl phosphate (ingredient D) (*8) 0.5% 11. Silica (ingredient E) (*31) 1.0% 12. Silica (ingredient E) (*32) 0.5% 13. (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (ingredient E) (*33) 0.5% 14. (HDI / PPG / Polycaprolactone) Crosspolymer (98%) / Silica (2%) (Component E) (*34) 0.5% 15.Synthetic phlogopite (component E) (*35) 5.0% 16. Boron nitride (component E) (*36) 2.0% 17. Dimethicone 3% treated red iron oxide / titanium oxide coated mica (ingredient E) (*37) 0.1% 18. Mica (ingredient E) remaining amount 19. Talc (ingredient E) (*18) 10.0% 20. Talc (ingredient E) (*38) 30.0% 21. Zinc laurate-treated talc (ingredient E) (*39) 5.0% 22. Dimethicone-treated talc (ingredient E) (*40) 5.0% 23. Barium sulfate (ingredient E) (*41) 1.0% 24. Zinc Myristate (ingredient E) (*42) 0.1% 25. Bengala (ingredient E) (*20) 0.3% 26. Yellow iron oxide (ingredient E) (*21) 2.0% 27. Black iron oxide (ingredient E) (*22) 0.2% 28. Methicone, aluminum hydroxide, and titanium dioxide treated with hydrated silica (ingredient E) (*43) 1.0% 29. Titanium dioxide treated with 3% perfluorooctyltriethoxysilane (ingredient E) (*44) 10.0% 30. Hydrogen Dimethicone-Treated Zinc Oxide (ingredient E) (*25) 5.0% 31. Phenoxyethanol 0.05% 32. Sodium Hyaluronate 0.02% 33. Glycine 0.02% 34. Mixture of Jasminum Sambac Flower Extract, Grape Leaf Extract, Mentha Piperita Leaf Extract, Bifidobacterium Culture Lysate, Prunus Satsuma Flower Extract, Polyquaternium-51, Rosa Multiflora Fruit Extract, Rugosa Rose Flower Extract, Rosa Izayoi Extract, Tocopheryl Acetate, Water-Soluble Collagen, Royal Jelly Extract, Angelica Root Extract, Rosa Centifolia Flower Extract, Rosa Damascena Flower Water, Rosemary Flower Extract, and Acerola Fruit Extract (Mixture of Cosmetic Ingredients) 0.1% 35.Fragrance 0.1% (*27) ABIL Wax 2434 (Evonik) (*28) KF-96A (10cs) (Shin-Etsu Chemical Co., Ltd.) (*29) Cosmol 168ARV (manufactured by Nisshin Oillio Group) (*30) Cosmol 182V (manufactured by Nisshin Oillio Group) (*31) Silica Microbeads N-1505 (manufactured by JGC Catalysts and Chemicals) (*32) Sunsphere NP-200 (AGC Si-Tech) (*33) KSP-102 (Shin-Etsu Chemical Co., Ltd.) (*34) CS-400 (Toshiko Pigment Co., Ltd.) (*35) PDM-10L (Topy Industries) (*36) SHP-6 (manufactured by Mizushima Ferroalloy Co., Ltd.) (*37) SA-RELIEF COLOR PINK (Miyoshi Chemicals) (*38) Hi-Filler K-5 (Matsumura Sangyo Co., Ltd.) (*39) Talc ZL-6 (manufactured by Toshiki Pigment Co., Ltd.) (*40) SA-Talc JA-46R (Miyoshi Chemicals Co., Ltd.) (*41) Plate-shaped barium sulfate HL (manufactured by Sakai Chemical Industry Co., Ltd.) (*42) Powder Base M (NOF Corporation) (*43) Fine particle titanium dioxide SMT-500SAM (*44) FHS-3 TiO2 MP-1133 (manufactured by Daito Kasei Kogyo Co., Ltd.) (Manufacturing method) A. Components 1 to 10 were heated at 70°C to obtain a solution (or dispersion). B. Components 11 to 30, 32, and 33 were mixed to obtain a mixture. C. A, components 31, 34, and 35 were added to the mixture obtained in B to obtain a mixture. D. The mixture obtained in C was pulverized to obtain a powdered cosmetic. E. The powdered cosmetic material obtained in D was mixed with a volatile solvent (hydrogenated polyisobutene) to obtain a slurry. F. The slurry obtained in E was filled into a container and molded, and then the volatile solvent was removed to obtain a solid powder cosmetic.

[0108] In Example 18, the content of component (A) relative to the total amount of components (A) to (C) was 43%, and the content of component (D) was 0.5%. The solid powder cosmetic (foundation) of Example 19 showed no cracking or shrinkage after solvent removal and exhibited good filling and molding properties. Furthermore, the amount of transfer onto the puff was good, and the adhesion to the skin and the durability of the cosmetic effect were also good.

[0109] Example 19: Solid powder cosmetic (foundation) (Ingredients) (Content) 1. Cyclic fluorine-modified silicone oil (ingredient A) (*1) 1.5% 2. Stearyl dimethicone (ingredient B) (*3) 0.3% 3. Stearoxydimethicone (ingredient B) (*27) 0.1% 4. Diphenylsiloxyphenyl trimethicone (ingredient C) (*5) 3.0% 5. Cetyl ethylhexanoate (*45) 0.2% 6. Mineral oil (*46) 0.01% 7. Ethylhexyl methoxycinnamate 1.0% 8. Behendimonium ethyl stearyl phosphate (ingredient D) (*8) 1.0% 9. Silica (ingredient E) (*12) 5.0% 10. (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (Component E)(*14) 5.0% 11. Polymethyl methacrylate (ingredient E) (*47) 5.0% 12. Boron nitride (component E) (*48) 10.0% 13. Dimethiconol-aminopropyltriethoxysilane-treated mica (Component E)(*49) 20.0% 14. Mica (ingredient E) remaining amount 15. Talc (ingredient E) (*38) 15.0% 16. Bengala (ingredient E) (*20) 0.3% 17. Yellow iron oxide (ingredient E) (*21) 2.0% 18. Black iron oxide (ingredient E) (*22) 0.2% 19. Dimethicone 1% treatment, Al hydroxide 4% treatment, Zinc oxide 0.4% coated titanium dioxide (Component E)(*50) 0.1% 20. Titanium dioxide treated with 3% aluminum hydroxide (ingredient E) (*51) 20.0% 21. Methylparaben 0.15% 22. Ethylparaben 0.03% 23. Propylparaben 0.02% 24. Chlorphenesin 0.01% 25. Ethylhexylglycerin (*26) 0.01% 26.Fragrance 0.1% (*45) Salakos 816T (manufactured by Nisshin Oillio Group) (*46) KLEAROL White Mineral Oil (SONNEBORN, LLC) (*47) Chemisnow MR-5C (manufactured by Soken Chemical Co., Ltd.) (*48) SHP-9 (Mizushima Ferroalloy Co., Ltd.) (*49) SE-MA-23 (Miyoshi Chemicals Co., Ltd.) (*50)MPY-100M (manufactured by Teika) (*51) MP-1133 (manufactured by Teika) (Manufacturing method) A. Components 1 to 8 were heated at 70°C to obtain a solution (or dispersion). B. Components 9 to 23 were mixed to obtain a mixture. C. A and components 24 to 26 were added to the mixture obtained in B to obtain a mixture. D. The mixture obtained in C was pulverized to obtain a powdered cosmetic. E. The powdered cosmetic material obtained in D was mixed with a volatile solvent (purified water) to obtain a slurry. F. The slurry obtained in E was filled into a container and molded, and then the volatile solvent was removed to obtain a solid powder cosmetic.

[0110] In Example 19, the content of component (A) relative to the total amount of components (A) to (C) was 30%, and the content of component (D) was 1.0%. The solid powder cosmetic (foundation) of Example 19 showed no cracking or shrinkage after solvent removal and exhibited good filling and molding properties. Furthermore, the amount of transfer onto the puff was good, and the adhesion to the skin and the durability of the cosmetic effect were also good.

[0111] Example 20: Solid powder type cosmetic (white powder) (Ingredients) (Content) 1. Cyclic fluorine-modified silicone oil (ingredient A) (*1) 1.5% 2. Stearyl dimethicone (ingredient B) (*3) 0.1% 3. Alkyl (C26-28) Dimethicone (ingredient B) (*4) 0.1% 4. Diphenylsiloxyphenyl trimethicone (ingredient C) (*5) 0.1% 5. Diphenyl dimethicone (ingredient C) (*6) 2.0% 6. Dimethicone (ingredient C) (*7) 0.1% 7. Isotridecyl isononanoate (*52) 0.2% 8. Triethylhexanoin (*53) 0.5% 9. Behendimonium ethyl stearyl phosphate (ingredient D) (*8) 2.0% 10. Silica (ingredient E) (*54) 5.0% 11. (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (Component E)(*33) 2.0% 12. Polymethylsilsesquioxane (ingredient E) (*55) 2.0% 13. Polymethyl methacrylate (ingredient E) (*56) 3.0% 14.Synthetic phlogopite (component E) (*57) 2.0% 15. Mica (ingredient E) remaining amount 16. Triethoxycaprylylsilane 2% treated talc (ingredient E) (*58) 5.0% 17. (Fluoride / Hydroxide / Oxide) / (Mg / K / Silicon) (Component E) (*59) 10.0% 18. Bengala (ingredient E) (*20) 0.04% 19. Yellow iron oxide (ingredient E) (*21) 0.2% 20. Black iron oxide (ingredient E) (*22) 0.04% 21. Methicone, aluminum hydroxide, and hydrous silica-treated titanium dioxide (ingredient E) (*43) 1.0% 22. Titanium dioxide treated with 2% triethoxycaprylylsilane (ingredient E) (*60) 10.0% 23. Ceramide 2 0.01% 24. Ceramide 3 0.01% 25. Licorice flavonoids, rosemary leaf extract, apricot kernel oil, rosehip fruit extract, almond oil, corn oil mixture (beauty ingredient mixture) 0.1% 26.Fragrance 0.1% (*52) Salakos 913 (manufactured by Nisshin Oillio Group) (*53) Mtritol GTEH (BASF Japan) (*54) Sunsphere NP-30 (AGC Si-Tech) (*55) Tospearl 2000B* (Momentive Performance Materials Japan) (*56) Matsumoto Microsphere M101 (Matsumoto Yushi Pharmaceutical Co., Ltd.) (*57) SLM-15 (manufactured by Topy Industries) (*58) OTS-2 Talc JA-46R (manufactured by Daito Kasei Kogyo Co., Ltd.) (*59) Micromica MK-200 (Katakura Co-op Agri Co., Ltd.) (*60) OTS-2 TiO2 MP-1133 (manufactured by Daito Chemical Industry Co., Ltd.) (Manufacturing method) A. Components 1 to 9 were heated at 70°C to obtain a solution (or dispersion). B. Ingredients 10 to 24 were mixed to obtain a mixture. C. A, ingredients 25 and 26 were added to the mixture obtained in B to obtain a mixture. D. The mixture obtained in C was pulverized to obtain a powdered cosmetic. E. The powdered cosmetic material obtained in D was mixed with a volatile solvent (hydrogenated polyisobutene) to obtain a slurry. F. The slurry obtained in E was filled into a container and molded, and then the volatile solvent was removed to obtain a solid powder cosmetic.

[0112] In Example 20, the content of component (A) relative to the total amount of components (A) to (C) was 38%, and the content of component (D) was 2.0%. The solid powder cosmetic (white powder) of Example 20 showed no cracking or shrinkage after solvent removal and exhibited good filling and molding properties. Furthermore, the amount of transfer onto the puff was good, and the adhesion to the skin and the durability of the cosmetic effect were also good.

[0113] Example 21: Solid powder cosmetic (blush) (Ingredients) (Content) 1. Cyclic fluorine-modified silicone oil (ingredient A) (*1) 1.5% 2. Stearyl dimethicone (ingredient B) (*3) 1.0% 3. Cetyl dimethicone (ingredient B) (*61) 0.2% 4. Diphenylsiloxyphenyl trimethicone (ingredient C) (*5) 2.5% 5. Diphenyl dimethicone (ingredient C) (*6) 1.0% 6. Dimethicone (ingredient C) (*7) 0.5% 7. Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) (*62) 0.01% 8. Behendimonium ethyl stearyl phosphate (ingredient D) (*8) 2.0% 9. Hydrogenated soybean phospholipid (ingredient D) (*63) 0.1% 10. Silica (ingredient E) (*64) 15.0% 11. Silica (ingredient E) (*65) 5.0% 12. (Diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) crosspolymer (ingredient E) (*66) 10.0% 13. Polymethyl methacrylate (ingredient E) (*67) 10.0% 14. Nylon-12 (ingredient E) (*68) 20.0% 15. Boron nitride (component E) (*69) 10.0% 16. Dimethicone 2% treated talc (ingredient E) (*70) 0.1% 17. Mica (ingredient E) remaining amount 18. Polyethylene terephthalate (ingredient E) (*19) 2.0% 19. Bengala (ingredient E) (*20) 3.0% 20. Red No. 226 5.0% 21. Yellow No. 4 1.0% 22. Mixture of Jasminum Sambac flower extract, Grape leaf extract, Peppermint leaf extract, Bifidobacterium culture lysate, Cherry blossom flower extract, Polyquaternium-51, Rosa multiflora fruit extract, Rugosa rose flower extract, Rosa robur extract, Tocopheryl acetate, Water-soluble collagen, Royal jelly extract, Angelica acutiloba root extract, Rosa centifolia flower extract, Rosa damascena flower water, Rosemary flower extract, Acerola fruit extract (mixture of beauty ingredients) 0.1% 23.Fragrance 0.1% (*61) ABIL Wax 9800 (Evonik) (*62) Plandool-S (Nippon Fine Chemicals Co., Ltd.) (*63) NIKKOL Resinol S-10E (Nikko Chemicals) (*64) Sunsphere NP-100 (AGC Si-Tech) (*65) Cosme Silica CQ4 (Fuji Silysia Chemical) (*66) KSP-300 (Shin-Etsu Chemical Co., Ltd.) (*67) Ganz Pearl GM-2800 (manufactured by AICA Kogyo Co., Ltd.) (*68) Ganz Pearl GPA-550 (manufactured by AICA Kogyo Co., Ltd.) (*69) SHP-3 (Mizushima Ferroalloy Co., Ltd.) (*70)SXI-5 (Miyoshi Kasei Co., Ltd.) (Manufacturing method) A. Components 1 to 9 were heated at 70°C to obtain a solution (or dispersion). B. Components 10 to 21 were mixed to obtain a mixture. C. A, ingredients 22 and 23 were added to the mixture obtained in B to obtain a mixture. D. The mixture obtained in C was pulverized to obtain a powdered cosmetic. E. The powdered cosmetic material obtained in D was mixed with a volatile solvent (hydrogenated polyisobutene) to obtain a slurry. F. The slurry obtained in E was filled into a container and molded, and then the volatile solvent was removed to obtain a solid powder cosmetic.

[0114] In Example 21, the content of component (A) relative to the total amount of components (A) to (C) was 22%, and the content of component (D) was 2.1%. The solid powder cosmetic (blush) of Example 21 showed no cracking or shrinkage after solvent removal and exhibited good filling and molding properties. Furthermore, the amount of transfer onto the puff was good, and the adhesion to the skin and the durability of the cosmetic effect were also good.

[0115] · Implementation 22: Solid powder cosmetics (eye shadow) (Ingredients) (Content) 1. Cyclic fluorine-modified silicone oil (ingredient A) (*1) 3.0% 2. Stearyl dimethicone (ingredient B) (*3) 0.2% 3. Behenoxydimethicone (ingredient B) (*71) 0.1% 4. Cetyl dimethicone (ingredient B) (*72) 0.1% 5. Diphenylsiloxyphenyl trimethicone (ingredient C) (*5) 2.0% 6. Diphenyl dimethicone (ingredient C) (*6) 1.0% 7. Dimethicone (ingredient C) (*7) 0.5% 8. Dimethicone (ingredient C) (*73) 0.05% 9. Hydrogenated castor oil stearate (*74) 0.1% 10. Sorbitan sesquiisostearate (*30) 0.3% 11. Behendimonium ethyl stearyl phosphate (ingredient D) (*8) 2.5% 12. Silica (ingredient E) (*31) 10.0% 13. Silica (ingredient E) (*32) 10.0% 14. (HDI / PPG / Polycaprolactone) Crosspolymer (98%) / Silica (2%) (Component E) (*34) 15.0% 15.Synthetic phlogopite (component E) (*35) 10.0% 16.Synthetic phlogopite (component E) (*75) 5.0% 17.Synthetic phlogopite (component E) (*76) 5.0% 18. Dimethicone 2% treated talc (*70) 0.5% 19. Mica (component E) (average particle size μm) remaining amount 20. Bengala (ingredient E) (*20) 3.0% 21. Titanium oxide, aluminum hydroxide (ingredient E) (*23) 2.0% 22. Titanium dioxide treated with 3% perfluorooctyltriethoxysilane (ingredient E) (*44) 3.0% 23. Chlorphenesin 0.05% 24. Ethylhexylglycerin (*26) 0.1% 25. Red No. 226 (ingredient E) 2.0% 26. Titanium oxide-coated borosilicate (Ca / Al) (ingredient E) (*77) 4.0% 27. Perfluorooctyltriethoxysilane 2% treated titanium dioxide coated borosilicate (Ca / Al) (ingredient E) (*78) 0.5% 28. Titanium dioxide-coated synthetic phlogopite (ingredient E) (*79) 2.0% 29. Titanium oxide-coated synthetic phlogopite (ingredient E) (*80) 1.0% 30. (PET / Polymethylmethacrylate) Laminate (Component E) (*81) 3.0% 31. Titanium dioxide / silica-coated mica (ingredient E) (*82) 3.0% 32. Titanium dioxide / iron oxide coated mica (ingredient E) (*83) 1.0% 33. Licorice flavonoids, rosemary leaf extract, apricot kernel oil, rosehip fruit extract, almond oil, corn oil mixture (beauty ingredient mixture) 0.1% 34.Fragrance 0.1% (*71) ABIL Wax 2440 (Evonik) (*72) ABIL Wax 9840 (Evonik) (*73) KF-96A (100cs) (Shin-Etsu Chemical Co., Ltd.) (*74) Cast Ride MS (National Mimatsu Co., Ltd.) (*75) PDM-20L (Topy Industries) (*76) PDM-40L (Topy Industries) (*77) Micro Glass Metashine MT1080RR (Nippon Sheet Glass Co., Ltd.) (*78) FHS-2 Metashine MT1080RB (manufactured by Daito Kasei Kogyo Co., Ltd.) (*79) HELIOS R100S (Topy Industries) (*80) HERIOS R10R (manufactured by Topy Industries) (*81) Aurora Flake Red 0.01 (Kakuhachi Gyorin Hakusha) (*82) TIMIRON SPLEMDID RED (Merck) (*83) TIMICA RADIANT GOLD 222G (BASF) (Manufacturing method) A. Components 1 to 11 were heated at 70°C to obtain a solution (or dispersion). B. Components 12 to 22 and 25 to 32 were mixed to obtain a mixture. C. A, components 23, 24, 33, and 34 were added to the mixture obtained in B to obtain a mixture. D. The mixture obtained in C was pulverized to obtain a powdered cosmetic. E. The powdered cosmetic material obtained in D was mixed with a volatile solvent (hydrogenated polyisobutene) to obtain a slurry. F. The slurry obtained in E was filled into a container and molded, and then the volatile solvent was removed to obtain a solid powder cosmetic.

[0116] In Example 22, the content of component (A) relative to the total amount of components (A) to (C) was 43%, and the content of component (D) was 3.0%. The solid powder cosmetic (eye shadow) of Example 22 showed no cracking or shrinkage after solvent removal and exhibited good filling and molding properties. Furthermore, the amount of transfer onto the puff was good, and the adhesion to the skin and the durability of the cosmetic effect were also good.

Claims

1. The following components (A) to (E): (A) Fluorine-modified silicone oil (B) Silicone wax (C) Phenyl-modified silicone oil (excluding component (A) and component (B)) (D) A compound having a hydrophilic group and a lipophilic group in one molecule, and the lipophilic group is of a double-chain type. (E) Powder A solid powder cosmetic obtained by removing the solvent from a mixture of a cosmetic base containing the compound and a solvent, the component (B) is at least one selected from the group consisting of alkyl-modified silicone wax, stearoxy dimethicone, and behenoxy dimethicone; the component (C) is at least one selected from the group consisting of diphenylsiloxyphenyl trimethicone, diphenyl dimethicone, and phenyl trimethicone; The content of the component (A) in the solid powder cosmetic is 0.1 to 10% by mass, The content of the component (B) in the solid powder cosmetic is 0.01 to 2% by mass, The content of the component (C) in the solid powder cosmetic is 0.1 to 10% by mass, A solid powder cosmetic, wherein the content of the component (D) in the solid powder cosmetic is 0.05 to 5% by mass.

2. 2. The solid powder cosmetic preparation according to claim 1, wherein said component (D) is at least one selected from the group consisting of phospholipids, N-acylamino acids or salts thereof, and behendimonium ethyl stearyl phosphate.

3. 3. The solid powder cosmetic preparation according to claim 1, wherein said component (B) is a silicone wax modified with an alkyl group having 8 to 30 carbon atoms.

4. 4. The solid powder cosmetic preparation according to claim 1, wherein the content of component (A) is 10 to 60% by mass based on the total amount of components (A) to (C).

5. The solid powder cosmetic preparation according to any one of claims 1 to 4, wherein the component (A) is a cyclic fluorine-modified silicone oil.

6. 6. The solid powder cosmetic preparation according to claim 1, wherein the component (D) is behendimonium ethyl stearyl phosphate.

7. The solid powder cosmetic preparation according to any one of claims 1 to 6, wherein the solvent is a hydrocarbon oil or an aqueous solvent.

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