Battery and manufacturing method thereof

Abstract

To provide a battery having good discharge capacity characteristics.SOLUTION: A battery that utilizes a deposition and dissolution reaction of metallic lithium as an anode reaction includes an anode current collector, a metal layer, an electrolyte layer, and a cathode active material layer in this order in the thickness direction, the metal layer contains a Li-Mg alloy phase and a Li-In alloy phase.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] The present disclosure relates to batteries and methods for manufacturing the same. [Background technology]

[0002] A battery typically has an electrolyte layer between a positive electrode active material layer and a negative electrode active material layer. In the field of batteries, batteries that utilize a deposition-dissolution reaction of metallic lithium as the negative electrode reaction are known. For example, Patent Document 1 discloses an all-solid-state battery that utilizes a deposition-dissolution reaction of metallic lithium as the negative electrode reaction. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Publication No. 2020-184513 Summary of the Invention [Problem to be solved by the invention]

[0004] Batteries that use the deposition and dissolution reaction of metallic lithium as the anode reaction usually do not provide a typical anode active material layer (a layer containing anode active material particles that absorb and release Li) during battery fabrication, but instead form a anode active material layer (Li-containing layer) during initial charging, which has the advantage of making it easier to improve energy density.However, batteries that use the deposition and dissolution reaction of metallic lithium as the anode reaction have room for further improvement in discharge capacity characteristics.

[0005] The present disclosure has been made in view of the above circumstances, and has as its main object to provide a battery having good discharge capacity characteristics. [Means for solving the problem]

[0006] [1] A battery that utilizes a deposition and dissolution reaction of metallic lithium as a negative electrode reaction, a negative electrode current collector, a metal layer, an electrolyte layer, and a positive electrode active material layer, in this order in the thickness direction; The battery, wherein the metal layer contains a Li-Mg alloy phase and a Li-In alloy phase.

[0007] [2] The battery according to [1], wherein in the metal layer, the Li—In alloy phase is dispersed in the Li—Mg alloy phase.

[0008] [3] The battery according to [1] or [2], wherein in the metal layer, a ratio of In to the total of In and Mg is 5 at % or more and 60 at % or less.

[0009] [4] The battery according to any one of [1] to [3], wherein in the metal layer, the proportion of In to the total of In and Mg is 25 at % or more and 60 at % or less.

[0010] [5] The battery according to any one of [1] to [4], wherein the size of the Li-Mg alloy phase is 0.1 μm or more and 5 μm or less.

[0011] [6] The battery according to any one of [1] to [5], wherein the metal layer does not contain a binder.

[0012] [7] The battery according to any one of [1] to [6], wherein the electrolyte layer is a solid electrolyte layer containing a solid electrolyte.

[0013] [8] The battery according to any one of [1] to [7], wherein the solid electrolyte is a sulfide solid electrolyte.

[0014] [9] A battery that utilizes a deposition and dissolution reaction of metallic lithium as a negative electrode reaction, a negative electrode current collector, a metal layer, an electrolyte layer, and a positive electrode active material layer, in this order in the thickness direction; The battery, wherein the metal layer contains an Mg—In alloy.

[0015]

[10] The battery according to [9], wherein the metal layer has a metal phase of the Mg—In alloy (Mg—In alloy phase).

[0016]

[11] The battery according to [9] or

[10] , wherein the metal layer is a vapor-deposited layer.

[0017]

[12] The battery according to [9], wherein the metal layer contains particles of the Mg—In alloy.

[0018]

[13] A method for manufacturing a battery using a deposition and dissolution reaction of metallic lithium as a negative electrode reaction, a metal layer forming step of forming a metal layer containing an Mg—In alloy phase by a vapor deposition method; an assembling step of assembling the battery having the negative electrode current collector, the metal layer, the electrolyte layer, and the positive electrode active material layer in this order in the thickness direction; A method for manufacturing a battery comprising the steps of:

[0019]

[14]

[13] The method for producing a battery according to

[13] , further comprising a charging step of charging the battery after the assembling step to form a Li-Mg alloy phase and a Li-In alloy phase from the Mg-In alloy phase contained in the metal layer. [Effects of the Invention]

[0020] The battery according to the present disclosure has an advantage of having good discharge capacity characteristics. [Brief explanation of the drawings]

[0021] [Figure 1] FIG. 1 is a schematic cross-sectional view illustrating a battery according to the present disclosure. [Figure 2] FIG. 2 is an explanatory diagram illustrating a state of a battery during charging according to the present disclosure. [Figure 3]FIG. 2 is an explanatory diagram illustrating a state of a battery during discharge according to the present disclosure. [Figure 4] FIG. 1 is a flow diagram illustrating a method for manufacturing a battery according to the present disclosure. [Figure 5] 1 shows the results of charge-discharge tests on the evaluation cells produced in Examples 1 to 5 and Comparative Examples 1 and 2. [Figure 6] 1 shows the results of charge-discharge tests on the evaluation cells produced in Examples 1 to 5 and Comparative Examples 1 and 2. [Figure 7] 1 is a cross-sectional SEM image of the evaluation cell produced in Example 3. DETAILED DESCRIPTION OF THE INVENTION

[0022] The battery and its manufacturing method according to the present disclosure will be described in detail below with reference to the drawings. The drawings are schematic, and the size and shape of each part are appropriately exaggerated for ease of understanding.

[0023] A.Battery 1A and 1B are schematic cross-sectional views illustrating a battery according to the present disclosure, with Fig. 1A being a schematic cross-sectional view illustrating the battery before the first charge, and Fig. 1B being a schematic cross-sectional view illustrating the battery after the first charge.

[0024] As shown in FIGS. 1(a) and 1(b), the battery 10 includes a negative electrode current collector 1, a metal layer 2, an electrolyte layer 3, and a positive electrode active material layer 4 arranged in a thickness direction D T In the battery 10 shown in FIG. 1(a), the metal layer 2 contains an Mg—In alloy in the battery 10 before the first charge. The metal layer 2 is typically a vapor-deposited layer having an Mg—In alloy phase. When the battery 10 shown in FIG. 1(a) is charged, the Mg—In alloy phase reacts with Li, and a Li—Mg alloy phase and a Li—In alloy phase are formed from the Mg—In alloy phase. As shown in FIG. 1(b), the metal layer 2 contains a Li—Mg alloy phase and a Li—In alloy phase in the battery 10 after the first charge.

[0025] According to the present disclosure, since the metal layer contains Mg and In, the battery has good discharge capacity characteristics. As described above, in a battery that uses a deposition-dissolution reaction of metallic lithium as the anode reaction, a typical anode active material layer (e.g., a layer containing anode active material particles that absorb and release Li) is not usually provided during battery fabrication, and anode active material layer (Li-containing layer) is formed during initial charging, which has the advantage of making it easy to improve energy density. On the other hand, there is room for further improvement in the discharge capacity characteristics of a battery that uses a deposition-dissolution reaction of metallic lithium as the anode reaction.

[0026] In contrast, in the present disclosure, a metal layer containing Mg and In is used. By using such a metal layer, good discharge capacity characteristics can be obtained. It is presumed that the reason good discharge capacity characteristics can be obtained is that the use of a metal layer containing Mg and In can suppress an increase in resistance in the negative electrode at the end of discharge. Hereinafter, the effects obtained in the present disclosure will be described in detail with reference to FIGS. 2 and 3.

[0027] As shown in FIG. 2(a), the battery 10 includes a negative electrode current collector 1, a metal layer 2, an electrolyte layer 3, a positive electrode active material layer 4, and a positive electrode current collector 5, in this order in the thickness direction. The metal layer 2 includes an Mg-In alloy phase. Next, as shown in FIG. 2(b), when charging of the battery 10 begins, a Li-In alloy phase is first formed from part of the Mg-In alloy phase. Because In has a higher reaction potential for Li insertion / extraction than Mg, In reacts with Li before Mg reacts, forming the Li-In alloy phase. Next, as shown in FIGS. 2(c) and 2(d), as charging of the battery 10 progresses, a Li-Mg alloy phase is formed in addition to the Li-In alloy phase. Because the Li-In alloy phase forms before the Li-Mg alloy phase, the Li-In alloy phase is dispersed in the Li-Mg alloy phase.

[0028] Next, as shown in FIG. 3(a), when the charged battery 10 is discharged, Li contained in the metal layer 2 migrates to the positive electrode active material layer 4 via the electrolyte layer 3. Because Mg has a lower reaction potential for Li insertion / extraction than In, Li is first desorbed from the Li-Mg alloy phase. As shown in FIG. 3(b), the Li-In alloy phase has high Li ion conductivity, forming a good ion conduction path. As shown in FIG. 3(c), the Li-In alloy phase is presumably maintained even at the end of discharge, which is presumably responsible for suppressing an increase in the resistance of the negative electrode. As a result, good discharge capacity characteristics are presumably obtained.

[0029] The battery according to the present disclosure can be roughly divided into two embodiments depending on the state of charge (SOC). Hereinafter, the battery according to the present disclosure will be described in a first embodiment and a second embodiment.

[0030] 1. First embodiment 3(a), the battery 10 of the first embodiment includes, in the thickness direction, a negative electrode current collector 1, a metal layer 2, an electrolyte layer 3, and a positive electrode active material layer 4, in this order. Furthermore, the metal layer 2 contains a Li-Mg alloy phase and a Li-In alloy phase.

[0031] (1) Negative electrode The negative electrode in the first embodiment has a negative electrode current collector. Examples of materials for the negative electrode current collector include SUS, copper, nickel, and carbon. Examples of the shape of the negative electrode current collector include a foil shape. The thickness of the negative electrode current collector is, for example, 1 μm or more and 500 μm or less.

[0032] The negative electrode has a metal layer. The metal layer contains a Li-Mg alloy phase and a Li-In alloy phase. The Li-Mg alloy phase is a metal phase of an alloy containing Li and Mg, and may be a metal phase of a binary alloy containing Li and Mg, or a metal phase of an alloy containing other elements in addition to Li and Mg. In the latter case, it is preferable that Li and Mg are the main components of the Li-Mg alloy phase. The "main component" refers to the component with the highest proportion (at%) among the components contained in the metal phase. In the Li-Mg alloy phase, the total proportion of Li and Mg to all elements is, for example, 50 at% or more, or may be 70 at% or more, or may be 90 at% or more.

[0033] The Li-In alloy phase is a metallic phase of an alloy containing Li and In, and may be a metallic phase of a binary alloy containing Li and In, or a metallic phase of an alloy containing other elements in addition to Li and In. In the latter case, it is preferable that Li and In are the main components in the Li-In alloy phase. In the Li-In alloy phase, the total proportion of Li and In to all elements is, for example, 50 at% or more, or may be 70 at% or more, or may be 90 at% or more.

[0034] The metal layer contains both a Li-In alloy phase and a Li-Mg alloy phase. In particular, the Li-In alloy phase is preferably dispersed in the Li-Mg alloy phase in the metal layer. That is, a sea-island structure is preferably formed, with the Li-Mg alloy phase as the sea and the Li-In alloy phase as the islands. This is because an increase in resistance in the negative electrode at the end of discharge can be suppressed. The size of the Li-In alloy phase is not particularly limited, but is, for example, 0.1 μm or more and 5 μm or less. The size of the Li-In alloy phase can be determined from the distribution of In by SEM-EDX. The size of the Li-In alloy phase is the average value measured for the sizes of 100 or more samples.

[0035] In the metal layer, the ratio of In to the total of In and Mg (In / (In+Mg)) is not particularly limited. In / (In+Mg) is, for example, 5 at% or more, and may be 10 at% or more, 15 at% or more, 20 at% or more, or 25 at% or more. If the value of In / (In+Mg) is too small, the effect of In in improving the discharge capacity characteristics may not be fully exhibited. On the other hand, In / (In+Mg) is, for example, 90 at% or less, or may be 80 at% or less, 70 at% or less, or 60 at% or less. If the value of In / (In+Mg) is too large, the effect of Mg in improving the capacity retention rate may not be fully exhibited.

[0036] The metal layer preferably does not contain a conductive material. The metal layer preferably does not contain a binder. A Li phase may be formed inside the metal layer. A precipitated Li layer may be formed between the metal layer and the electrolyte layer. A precipitated Li layer may be formed between the metal layer and the negative electrode current collector.

[0037] The metal layer is usually a dense layer. The porosity of the metal layer (the ratio of the area of ​​voids in the cross section of the metal layer) is, for example, 5% or less, or may be 3% or less, or may be 1% or less. In the first embodiment, the thickness of the metal layer is not particularly limited, but is, for example, 5 μm or more and 30 μm or less.

[0038] As shown in FIG. 3(a), the metal layer 2 may be in direct contact with the negative electrode current collector 1. Similarly, the metal layer 2 may be in direct contact with the electrolyte layer 3. Meanwhile, although not specifically shown, another layer may be disposed between the metal layer and the negative electrode current collector. Similarly, another layer may be disposed between the metal layer and the electrolyte layer. Furthermore, as shown in FIG. 3(c), the metal layer 2 after discharge may contain a Li-Mg alloy phase and a Li-In alloy phase. Depending on the SOC, the metal layer after discharge may contain a Li-free Mg phase and a Li-In alloy phase. Similarly, the metal layer after discharge may contain a Li-free Mg phase and a Li-In phase.

[0039] (2) Positive electrode The positive electrode in the first embodiment has a positive electrode current collector and a positive electrode active material layer. The positive electrode active material layer contains at least a positive electrode active material. The positive electrode active material layer may also contain at least one of an electrolyte, a conductive material, and a binder.

[0040] The positive electrode active material may be, for example, an oxide active material, such as LiCoO2 or LiNi. 1 / 3 Co 1 / 3 Mn 1 / 3 O2, etc., rock salt layered active materials, LiMn2O4, Li4Ti5O 12 and olivine type active materials such as LiFePO4. The positive electrode active material may be in the form of particles. The average particle size (D 50 ) is, for example, 0.5 μm or more and 50 μm or less. 50 ) refers to the volume cumulative particle size measured using a laser diffraction scattering particle size distribution analyzer.

[0041] Examples of the electrolyte include solid electrolytes. Examples of the solid electrolyte include inorganic solid electrolytes such as sulfide solid electrolytes, oxide solid electrolytes, and halide solid electrolytes. The sulfide solid electrolyte preferably contains sulfur (S) as the main component of the anion element. The oxide solid electrolyte preferably contains oxygen (O) as the main component of the anion element. The halide solid electrolyte preferably contains a halogen (X) as the main component of the anion. Among these, sulfide solid electrolytes are preferred.

[0042] The sulfide solid electrolyte preferably contains Li, M (wherein M is at least one of P, Sn, Al, Zn, In, Ge, Si, Sb, Ga, and Bi), and S. The sulfide solid electrolyte may also contain a halogen element such as F, Cl, Br, or I. In the sulfide solid electrolyte, a portion of the S element may be substituted with O.

[0043] The sulfide solid electrolyte may be a glass-based (amorphous) sulfide solid electrolyte, a glass-ceramic sulfide solid electrolyte, or a crystalline sulfide solid electrolyte. Examples of the crystalline phase contained in the sulfide solid electrolyte include an LGPS-type crystalline phase, a Thio-LISICON-type crystalline phase, and an argyrodite-type crystalline phase.

[0044] Examples of sulfide solid electrolytes include Li2S-P2S5, Li2S-P2S5-LiI, Li2S-P2S5-GeS2, Li2S-P2S5-Li2O, Li2S-P2S5-Li2O-LiI, Li2S-P2S5-LiI-LiBr, Li2S-SiS2, Li2S-SiS2-LiI, Li2S-SiS2-LiBr, Li2S-SiS2-LiCl, Li2S-SiS2-B2S3-LiI, Li2S-SiS2-P2S5-LiI, Li2S-B2S3, and Li2S-P2S5-Z m S n (where m and n are positive numbers. Z is Ge, Zn, or Ga.), Li2S-GeS2, Li2S-SiS2-Li3PO4, Li2S-SiS2-Li x MO y (where x and y are positive numbers, and M is one of P, Si, Ge, B, Al, Ga, and In.)

[0045] Other examples of solid electrolytes include organic solid electrolytes such as polymer electrolytes, gel electrolytes, etc. Furthermore, a liquid electrolyte (electrolytic solution) can also be used as the electrolyte.

[0046] Examples of conductive materials include carbon materials. Examples of carbon materials include particulate carbon materials such as acetylene black (AB) and ketjen black (KB); and fibrous carbon materials such as carbon fiber, carbon nanotubes (CNT), and carbon nanofibers (CNF). Examples of binders include rubber-based binders such as butylene rubber (BR) and styrene butadiene rubber (SBR), and fluoride-based binders such as polyvinylidene fluoride (PVDF). The thickness of the positive electrode active material layer is, for example, 1 μm or more and 500 μm or less.

[0047] Examples of materials for the positive electrode current collector include SUS, aluminum, nickel, and carbon. Examples of the shape of the positive electrode current collector include foil. The thickness of the positive electrode current collector is, for example, 1 μm or more and 500 μm or less.

[0048] (3) Electrolyte layer The electrolyte layer in the first embodiment contains at least an electrolyte. The electrolyte is the same as that described above in "(2) Positive electrode." In particular, the electrolyte layer preferably contains a solid electrolyte as the electrolyte. That is, the electrolyte layer is preferably a solid electrolyte layer containing a solid electrolyte. A battery having a solid electrolyte layer may be referred to as an all-solid-state battery. The solid electrolyte layer may also contain a binder in addition to the solid electrolyte. The binder is the same as that described above in "(2) Positive electrode." The thickness of the electrolyte layer is, for example, 1 μm or more and 500 μm or less.

[0049] (4)Battery The battery according to the first embodiment includes a negative electrode current collector, a metal layer, an electrolyte layer, and a positive electrode active material layer, arranged in this order in the thickness direction. Furthermore, the battery typically includes an exterior housing that houses these components. Examples of the exterior housing include a laminate-type exterior housing and a case-type exterior housing.

[0050] The use of the battery is not particularly limited, but examples include power sources for vehicles such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), electric vehicles (BEVs), gasoline-powered vehicles, and diesel-powered vehicles. In particular, it is preferable to use the battery as a driving power source for hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), or electric vehicles (BEVs). The battery may also be used as a power source for mobile objects other than vehicles (for example, trains, ships, and aircraft), and may also be used as a power source for electrical appliances such as information processing devices.

[0051] 2. Second embodiment As shown in Fig. 2(a), the battery 10 of the second embodiment includes, in the thickness direction, a negative electrode current collector 1, a metal layer 2, an electrolyte layer 3, and a positive electrode active material layer 4, in this order. The metal layer 2 contains an Mg-In alloy. Details of the components other than the metal layer 2 are the same as those described in the first embodiment.

[0052] The metal layer contains an Mg—In alloy. The Mg—In alloy is an alloy containing Mg and In, and may be a binary alloy containing Mg and In, or an alloy containing other elements in addition to Mg and In. In the latter case, it is preferable that Mg and In are the main components of the Mg—In alloy. In the Mg—In alloy, the total proportion of Mg and In to all elements is, for example, 50 at% or more, or may be 70 at% or more, or may be 90 at% or more.

[0053] The metal layer may have a metal phase of an Mg—In alloy (Mg—In alloy phase) or may contain Mg—In alloy particles. The Mg—In alloy particles have an average particle size D 50Preferably, the nanoparticles have a diameter of 1 μm or less. In the metal layer, the ratio of In to the total of In and Mg (In / (In+Mg)) is not particularly limited. The preferred range of In / (In+Mg) is the same as that described in the first embodiment. In addition, it is preferable that the metal layer does not contain a conductive material. In addition, it is preferable that the metal layer does not contain a binder. In the second embodiment, the metal layer usually does not contain Li.

[0054] The metal layer is usually a dense layer. The porosity of the metal layer (the ratio of the area of ​​voids in the cross section of the metal layer) is, for example, 5% or less, or may be 3% or less, or may be 1% or less. The metal layer may also be a vapor-deposited film. The metal layer is preferably in close contact with the negative electrode current collector. That is, the metal layer is preferably disposed so as to cover the surface of the negative electrode current collector. A member having a negative electrode current collector and a metal layer disposed on the negative electrode current collector may be referred to as a coated current collector. In the second embodiment, the thickness of the metal layer is not particularly limited, but may be, for example, 30 nm to 5 μm, or 100 nm to 3 μm, or 500 nm to 2 μm.

[0055] The battery in the second embodiment has a negative electrode current collector, a metal layer, an electrolyte layer, and a positive electrode active material layer, in that order in the thickness direction. Furthermore, the battery typically has an exterior housing that houses these components. The configuration other than the metal layer is the same as that described above in "1. First embodiment."

[0056] B. Battery manufacturing method FIG. 4 is a flow diagram illustrating a method for manufacturing a battery according to the present disclosure. As shown in FIG. 4, a metal layer containing an Mg—In alloy phase is formed by vapor deposition (metal layer forming step). Then, a battery having a negative electrode current collector, a metal layer, an electrolyte layer, and a positive electrode active material layer in this order in the thickness direction is assembled (assembly step). This results in, for example, a battery 10 as shown in FIG. 1(a). The battery is then charged, and a Li—Mg alloy phase and a Li—In alloy phase are formed from the Mg—In alloy phase contained in the metal layer (charging step). This results in, for example, a battery 10 as shown in FIG. 1(b).

[0057] According to the present disclosure, by forming a specific metal layer, a battery having good discharge capacity characteristics can be obtained.

[0058] 1.Metal layer formation process The metal layer forming step in the present disclosure is a step of forming a metal layer containing an Mg—In alloy phase by a vapor deposition method. The metal layer obtained by the vapor deposition method is a vapor-deposited layer.

[0059] Examples of vapor deposition methods include physical vapor deposition (PVD) such as ion plating, sputtering, vacuum deposition, etc. It is preferable to prepare Mg metal and In metal separately and perform binary vapor deposition.

[0060] In the present disclosure, it is preferable to form a metal layer on the negative electrode current collector by a vapor deposition method. This is because the negative electrode current collector has high smoothness, and a metal layer of uniform thickness can be obtained. In this case, the metal layer may be formed directly on the negative electrode current collector. Alternatively, the metal layer may be formed on the negative electrode current collector via another layer (e.g., another vapor deposition layer). In the present disclosure, the metal layer may be formed on the solid electrolyte layer by a vapor deposition method. In this case, the metal layer may be formed directly on the solid electrolyte layer. Alternatively, the metal layer may be formed on the solid electrolyte layer via another layer (e.g., another vapor deposition layer).

[0061] 2. Assembly process The assembly process in the present disclosure is a process of assembling the battery having the negative electrode current collector, the metal layer, the electrolyte layer, and the positive electrode active material layer in this order in the thickness direction. The method for assembling the battery is not particularly limited, and any known method can be used.

[0062] 3.Charging process The charging step in the present disclosure is a step of charging the battery after the assembling step to form a Li-Mg alloy phase and a Li-In alloy phase from the Mg-In alloy phase contained in the metal layer. The charging conditions for the battery are appropriately selected depending on the configuration of the battery.

[0063] 4.Battery The battery obtained through the above-mentioned steps is the same as that described in "A. Battery."

[0064] The present disclosure is not limited to the above-described embodiments. The above-described embodiments are merely examples, and any configuration that is substantially identical to the technical idea described in the claims of the present disclosure and that provides similar effects is included within the technical scope of the present disclosure. [Example]

[0065] [Example 1] (Preparation of positive electrode) Nickel-cobalt lithium aluminum oxide (NCA) was prepared as the positive electrode active material, a Li2-P2S5-based sulfide solid electrolyte containing LiI and LiBr was prepared as the solid electrolyte (SE), a PVDF-based binder was prepared as the binder, and vapor-grown carbon fiber (VGCF) was prepared as the conductive material. Next, each material was added to butyl butyrate in a weight ratio of NCA:SE:binder:conductive material = 84.7:13.4:0.6:1.27 to obtain a positive electrode slurry. The obtained positive electrode slurry was applied to a positive electrode current collector (Al foil) with a coating gap of 225 μm, then pre-dried at 60 °C and dried at 165 °C for 1 hour. This resulted in a positive electrode having a positive electrode current collector and a positive electrode active material layer. The basis weight of the positive electrode active material layer was 18.7 mg / cm. 2The designed capacity of the positive electrode active material layer is 3.0 mAh / cm 2 It was decided.

[0066] (Fabrication of solid electrolyte layer) A Li2-P2S5-based sulfide solid electrolyte containing LiI and LiBr was prepared as the solid electrolyte (SE), and a PVDF-based binder was prepared as the binder. Next, each material was added to butyl butyrate in a weight ratio of SE:binder = 92.6:7.4 to obtain a slurry for the solid electrolyte layer. The obtained slurry was coated onto a release film with a coating gap of 325 μm, then pre-dried at room temperature for 3 hours and then dried at 165 °C for 1 hour. This resulted in a laminate with a release film and solid electrolyte layer. The obtained laminate was punched out to a diameter of 14.5 mm, and the solid electrolyte layers of the two punched components were stacked together and then pressed under a pressure of 7 tons. After pressing, the release films on both sides were peeled off to obtain a free-standing solid electrolyte layer.

[0067] (Preparation of negative electrode) A stainless steel foil (SUS foil) was prepared as the negative electrode current collector. A metal layer (1.0 μm thick) containing an Mg-In alloy was formed on the SUS foil by binary deposition using the ion plating method. The target composition of the metal layer was Mg:In ​​= 90:10 (at% basis), but the actual composition was Mg:In ​​= 86:14 (at% basis). This resulted in a negative electrode with a negative electrode current collector and metal layer.

[0068] (Preparation of evaluation cells) The resulting positive electrode was punched out to a diameter of 11.28 mm, and the resulting negative electrode was punched out to a diameter of 14.5 mm. A free-standing solid electrolyte layer was placed between them, and an Al positive electrode tab and a Ni negative electrode tab were attached. The laminate film was then vacuum-sealed. The sealed cell was subjected to a pressure of 392 MPa using cold isostatic pressing (CIP). The cell was then constrained at 1 MPa using a constant pressure jig with a spring inserted to maintain a constant constraining pressure regardless of cell volume change. This resulted in an evaluation cell.

[0069] [Example 2] Except for changing the target composition of the metal layer to Mg:In=67:33 (at %), an evaluation cell was obtained in the same manner as in Example 1. The actual composition of the metal layer was Mg:In=64:36 (at %).

[0070] [Example 3] Except for changing the target composition of the metal layer to Mg:In=50:50 (at %), an evaluation cell was obtained in the same manner as in Example 1. The actual composition of the metal layer was Mg:In=46:54 (at %).

[0071] [Example 4] Except for changing the target composition of the metal layer to Mg:In ​​= 33:67 (at %), an evaluation cell was obtained in the same manner as in Example 1. The actual composition of the metal layer was Mg:In ​​= 34:66 (at %).

[0072] [Example 5] Except for changing the target composition of the metal layer to Mg:In=10:90 (at %), an evaluation cell was obtained in the same manner as in Example 1. The actual composition of the metal layer was Mg:In=12:88 (at %).

[0073] [Comparative Example 1] An evaluation cell was obtained in the same manner as in Example 1, except that a metal layer containing Mg metal was formed as the metal layer.

[0074] Comparative Example 2 An evaluation cell was obtained in the same manner as in Example 1, except that a metal layer containing In metal was formed as the metal layer.

[0075] [evaluation] (Charge / discharge test) The evaluation cells obtained in Examples 1 to 5 and Comparative Examples 1 and 2 were first subjected to a constant current (current density: 0.15 mA / cm ) test in the cutoff voltage range of 4.2 V to 3.0 V. 2 , equivalent to 0.05C) - constant voltage (cutoff current density: 0.03mA / cm 2, equivalent to 0.01C) test, the evaluation cell was charged and discharged at 60°C.

[0076] Next, a cycle test was performed at a cutoff voltage of 4.2 V to 3.0 V at 25°C with a constant current (current density: 0.60 mA / cm 2 , equivalent to 0.05C) - Constant voltage (charging only, cutoff current density: 0.03mA / cm 2 The results are shown in Figure 5. The initial discharge capacity and the discharge capacity after 20 cycles in the cycle test are shown in Table 1 and Figure 6.

[0077] [Table 1]

[0078] As shown in Table 1, FIGS. 5 and 6, Examples 1 to 5 achieved higher discharge capacities than Comparative Examples 1 and 2. More specifically, as shown in FIG. 6, Examples 1 to 5 achieved higher discharge capacities than those estimated from the straight line connecting Comparative Examples 1 and 2. Among Examples 1 to 5, Examples 1 to 3 maintained high discharge capacities even after 20 cycles, demonstrating excellent cycle characteristics. In particular, Examples 2 and 3 were confirmed to have significantly high initial discharge capacities and discharge capacities after 20 cycles.

[0079] (SEM observation) The cross section of the evaluation cell obtained in Example 3 was observed using a scanning electron microscope (SEM). Specifically, the cell was initially charged at 60°C under the same conditions as above, and the cross section was then observed using SEM secondary electron images at an applied voltage of 5 kV. The results are shown in Figure 7. As shown in Figure 7, the metal layer disposed between the solid electrolyte layer and the negative electrode current collector increased in thickness from 1.0 μm before the initial charge to approximately 15 μm. This is because Mg and In contained in the metal layer were alloyed with Li. Furthermore, although not shown, elemental mapping analysis using energy dispersive X-ray spectroscopy (EDX) confirmed that Mg was dispersed relatively uniformly in the metal layer. In contrast, In was confirmed to be dispersed locally. That is, it was confirmed that a sea-island structure was formed, with the Li-Mg alloy phase as the sea and the Li-In alloy phase as the islands.

[0080] The reaction potential for Li insertion / extraction of Mg is 0.1 V (vs Li / Li + ), and the reaction potential for Li insertion / extraction of In is 0.1V~0.6V (vs Li / Li + ) in consideration of this relationship, it is presumed that during discharge, Li is first desorbed from the Li-Mg alloy phase, and that the Li-In alloy phase functions as a Li-ion conduction path, resulting in a high discharge capacity. In particular, it is presumed that in Example 3, the state of the locally dispersed Li-In alloy phase was effective for Li-ion conduction. Furthermore, considering the binary phase diagram of the Mg-In alloy, it is presumed that the Mg-In alloy in Example 3 (before the first charge) had a β″ phase and multiple other β phases, and that such a state affected the dispersion state of the Li-In alloy phase after the first charge. [Explanation of symbols]

[0081] 1...Negative electrode current collector 2...metal layer 3...electrolyte layer 4...Cathode active material layer 5...Positive electrode current collector 10...battery

Claims

1. A battery that utilizes a deposition and dissolution reaction of metallic lithium as a negative electrode reaction, a negative electrode current collector, a metal layer, an electrolyte layer, and a positive electrode active material layer, in this order in the thickness direction; The metal layer contains a Li—Mg alloy phase and a Li—In alloy phase.

2. 2. The battery according to claim 1, wherein in the metal layer, the Li—In alloy phase is dispersed relative to the Li—Mg alloy phase.

3. 2. The battery according to claim 1, wherein in the metal layer, a ratio of In to the total of In and Mg is 5 at % or more and 90 at % or less.

4. 2. The battery according to claim 1, wherein in the metal layer, a ratio of In to the total of In and Mg is 25 at % or more and 60 at % or less.

5. 2. The battery according to claim 1, wherein the size of the Li—Mg alloy phase is 0.1 μm or more and 5 μm or less.

6. 10. The battery of claim 1, wherein the metal layer does not contain a binder.

7. The battery according to claim 1 , wherein the electrolyte layer is a solid electrolyte layer containing a solid electrolyte.

8. 10. The battery of claim 1, wherein the solid electrolyte is a sulfide solid electrolyte.

9. A battery that utilizes a deposition and dissolution reaction of metallic lithium as a negative electrode reaction, a negative electrode current collector, a metal layer, an electrolyte layer, and a positive electrode active material layer, in this order in the thickness direction; The battery, wherein the metal layer contains an Mg—In alloy.

10. 10. The battery according to claim 9, wherein the metal layer has a metal phase of the Mg—In alloy (Mg—In alloy phase).

11. The battery of claim 10 , wherein the metal layer is a vapor-deposited layer.

12. 10. The battery of claim 9, wherein the metal layer contains particles of the Mg—In alloy.

13. A method for manufacturing a battery using a deposition and dissolution reaction of metallic lithium as a negative electrode reaction, a metal layer forming step of forming a metal layer containing an Mg—In alloy phase by a vapor deposition method; an assembling step of assembling the battery having the negative electrode current collector, the metal layer, the electrolyte layer, and the positive electrode active material layer in this order in the thickness direction; A method for manufacturing a battery comprising the steps of:

14. 14. The method for producing a battery according to claim 13, further comprising a charging step of charging the battery after the assembling step, to form a Li—Mg alloy phase and a Li—In alloy phase from the Mg—In alloy phase contained in the metal layer.

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