Oil-in-water cosmetics

Abstract

The present invention provides an oil-in-water cosmetic composition. The present invention is an oil-in-water cosmetic composition which contains (A) a benzotriazole type ultraviolet absorbent, (B) one or more substances that are selected from the group consisting of silicone waxes and silica, and (C) water. With respect to this oil-in-water cosmetic composition, the average particle diameter of silica in the component (B) is 1 μm or more; and the content of the component (C) based on the total amount of this oil-in-water cosmetic composition is 50% by mass or more.

Description

[Technical Field]

[0001] The present invention relates to an oil-in-water cosmetic. [Background technology]

[0002] To protect the human body from ultraviolet rays in various situations in daily life, attempts have been made to incorporate ultraviolet absorbers into cosmetics. However, there have been many challenges in realizing cosmetics that have excellent ultraviolet protection effects and a good feel when used.

[0003] Attempts have been made to achieve UV protection effects and a good feel when used by setting the total amount and blending ratio of higher alcohol and surfactant within a specific range (Patent Document 1), but if the amount of higher alcohol is too high, the application becomes difficult and sticky, which is insufficient. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] Japanese Patent Application Laid-Open No. 2010-189281 Summary of the Invention [Problem to be solved by the invention]

[0005] An object of the present invention is to provide an oil-in-water cosmetic that dries quickly, is easy to apply, and has an excellent feel when used. [Means for solving the problem]

[0006] The present inventors have discovered an oil-in-water cosmetic composition containing (A) a benzotriazole-type ultraviolet absorber, (B) one or more selected from the group consisting of silicone wax and silica, and (C) water, The oil-in-water cosmetic is provided, in which the average particle size of the silica of component (B) is 1 μm or more, and the content of component (C) is 50 mass% or more based on the total amount of the oil-in-water cosmetic.

[0007] It has been found that the present invention makes it possible to obtain an oil-in-water cosmetic that is excellent in quick-drying properties, application properties, feel during use, and emulsification state. The present invention has been completed based on these findings.

[0008] That is, the present invention is [1] An oil-in-water cosmetic comprising (A) a benzotriazole-type ultraviolet absorber, (B) one or more selected from the group consisting of silicone wax and silica, and (C) water, an oil-in-water cosmetic in which the average particle size of the silica of component (B) is 1 μm or more, and the content of component (C) is 50 mass% or more based on the total amount of the oil-in-water cosmetic; [2] (D) The oil-in-water cosmetic composition according to [1], which contains a nonionic surfactant; [3] The oil-in-water cosmetic according to [1] or [2], containing (E) an ultraviolet protection agent (excluding the component (A)); [4] (F) The oil-in-water cosmetic composition according to any one of [1] to [3], which contains an acrylic acid-based polymer; [5] The oil-in-water cosmetic according to [2], wherein the component (D) is at least one selected from the group consisting of polyglycerin fatty acids, sorbitan fatty acid esters, polyoxyethylene fatty acids, sucrose fatty acid esters, polysorbates, polyoxyethylene phytosterols, and silicone surfactants; [6] The oil-in-water cosmetic according to [3], wherein the component (E) is one or more selected from the group consisting of 2-ethylhexyl paramethoxycinnamate, dimethicodiethyl benzalmalonate, diethylaminohydroxybenzoyl hexyl benzoate, 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine, 4-tert-butyl-4'-methoxydibenzoylmethane, ethylhexyl salicylate, phenylbenzimidazole sulfonic acid, paraaminobenzoic acid, zinc oxide, and titanium oxide; [7] The oil-in-water cosmetic according to [4], wherein the component (F) is at least one selected from the group consisting of carbomer, (acrylates / C10-30 alkyl acrylate) crosspolymer, (hydroxyethyl acrylate / sodium acryloyldimethyltaurate) copolymer, (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer, and polyacrylamide; [8] The oil-in-water cosmetic according to any one of [1] to [7], wherein the total content of the component (B) is 0.0001 to 500 parts by mass per 1 part by mass of the total content of the component (A); [9] The oil-in-water cosmetic according to any one of [1] to [8], wherein the total content of component (B) is 0.01 to 10% by mass;

[10] The oil-in-water cosmetic composition according to any one of [1] to [9], which is for sunscreen; etc. [Effects of the Invention]

[0009] The oil-in-water cosmetic of the present invention contains (A) a benzotriazole-type ultraviolet absorber, (B) one or more selected from the group consisting of silicone wax and silica, and (C) 50% or more of water, wherein the average particle size of the silica in component (B) is 1 μm or more, and the content of component (C) is 50% by mass or more based on the total amount of the oil-in-water cosmetic, and therefore has excellent quick-drying properties, application properties, usability, and emulsification state. [Brief explanation of the drawings]

[0010] [Figure 1] The results of evaluation of coating uniformity in Test Example 1 using the compositions of Example 1 and Comparative Example 1 are shown below. DETAILED DESCRIPTION OF THE INVENTION

[0011] Hereinafter, embodiments of the present invention will be described in detail, but the present invention is not limited to the following embodiments.

[0012] [1. Oil-in-water cosmetics] The oil-in-water cosmetic according to this embodiment is an oil-in-water cosmetic containing (A) a benzotriazole-type ultraviolet absorber (also simply referred to as "component (A)"), (B) one or more selected from the group consisting of silicone wax and silica (also simply referred to as "component (B)"), and (C) water, wherein the average particle size of the silica of component (B) is 1 μm or more, and the content of component (C) relative to the total amount of the oil-in-water cosmetic is 50 mass% or more.

[0013] <Component (A)> The benzotriazole-type ultraviolet absorber is a methylenebis(hydroxyphenyl-benzotriazole) derivative, and methylenebisbenzotriazolyltetramethylbutylphenol is preferred. Commercially available products such as Tinosorb M (manufactured by BASF) and Parsol MAX (manufactured by DSM) can be used. One type may be used alone, or two or more types may be used in combination.

[0014] The content of component (A) in the oil-in-water cosmetic according to this embodiment is not particularly limited and is set appropriately depending on the type of component (A), the types and contents of other blended ingredients, the intended use and formulation of the oil-in-water cosmetic, etc. From the viewpoint of more significantly achieving the effects of the present invention, the content of component (A) may be, for example, 0.01 to 20% by mass, preferably 0.01 to 10% by mass, more preferably 0.03 to 8% by mass, even more preferably 0.05 to 6% by mass, even more preferably 0.08 to 5% by mass, particularly preferably 0.1 to 3% by mass, and most preferably 0.1 to 2% by mass, based on the total amount of the oil-in-water cosmetic.

[0015] <(B) component> The one or more types selected from the group consisting of silicone wax and silica may be used alone or in combination of two or more types. Among the silicone waxes used in component (B), polyether-modified silicone waxes are preferred, with water-soluble polyether-modified silicone waxes being more preferred, with bis-PEG-18 methyl ether dimethyl silane, bis-PEG-15 methyl ether dimethicone, PEG-32 methyl ether dimethicone, and PEG-17 dimethicone being even more preferred, and bis-PEG-18 methyl ether dimethyl silane being the most preferred. Commercially available silicone waxes can be used, including 2501 CosmeticWax (manufactured by Dow Corning Toray Co., Ltd., bis-PEG-18 methyl ether dimethyl silane, melting point 36-42°C), DMC 6038 (manufactured by Wacker Chemical Co., Ltd., bis-PEG-15 methyl ether dimethicone, melting point approximately 30°C), KF-6004 (manufactured by Shin-Etsu Chemical Co., Ltd., PEG-32 methyl ether dimethicone, melting point 45°C), and Silsoft® 895 (manufactured by Momentive, PEG-17 dimethicone). Among the components (B), from the viewpoint of achieving the effects of the present invention more significantly, silica has an average particle size of 1 μm or more, preferably 1 to 20 μm, more preferably 1 to 15 μm, even more preferably 2 to 10 μm, and particularly preferably 2 to 7 μm. The average particle size is the median diameter (D50) measured by laser diffraction. An example of an apparatus used for laser diffraction is the LA960 (manufactured by HORIBA Seisakusho). Silica may be hydrophobic or hydrophilic. Commercially available silica can be used, and examples thereof include SILICA MICRO BEAD P-500, SILICA MICRO BEAD P-4000, SILICA PEARL P-4M, SILICA PEARL 20CG, HCS 160M5, and SILICA MICRO BEAD BA-1 (all manufactured by JGC Catalysts and Chemicals Ltd.), SYLICIA 320 (manufactured by Fuji Silysia Chemical Ltd.), SUNSPHARE H-31, and SUNSPHARE H-51 (all manufactured by AGC Si-Tech Co., Ltd.). If the average particle size of the silica is less than 1 μm, the emulsified state may not be favorable.

[0016] The content of component (B) in the oil-in-water cosmetic according to this embodiment is not particularly limited and is set appropriately depending on the type of component (B), the types and contents of other blended ingredients, the intended use and formulation of the oil-in-water cosmetic, etc. From the perspective of more significantly achieving the effects of the present invention, the content of component (B) is, for example, preferably 0.01 to 10% by mass, more preferably 0.05 to 8% by mass, even more preferably 0.1 to 6% by mass, even more preferably 0.1 to 5% by mass, and particularly preferably 0.1 to 4% by mass, based on the total amount of the oil-in-water cosmetic.

[0017] <(C) component> The water may be ion-exchanged water, distilled water, or the like. The amount of water is not particularly limited and is set appropriately depending on the type and amount of other ingredients, the intended use of the oil-in-water cosmetic, and the formulation. From the perspective of more significantly achieving the effects of the present invention, the amount of component (C) is, for example, preferably 50% by mass or more, more preferably 55% by mass or more, even more preferably 60% by mass or more, and particularly preferably 65% ​​by mass or more, based on the total amount of the oil-in-water cosmetic. For example, if the amount is about 45% by mass or less, the emulsified state may be undesirable. The amount of component (C) is preferably 98% by mass or less, more preferably 96.5% by mass or less, and even more preferably 95% by mass or less, based on the total amount of the oil-in-water cosmetic.

[0018] <(D) component> The oil-in-water cosmetic according to this embodiment may further contain (D) a nonionic surfactant (also referred to simply as "component (D)"). When the oil-in-water cosmetic further contains component (D), the effects of the present invention are more pronounced. There are no particular restrictions on component (D), so long as it is one that is commonly used in cosmetic compositions.

[0019] Examples of component (D) include polyglycerin fatty acids such as polyglyceryl monostearate, polyglyceryl monoisostearate, polyglyceryl diisostearate, and polyglyceryl pentaisostearate; sorbitan fatty acid esters such as sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, diglycerol sorbitan penta-2-ethylhexylate, and diglycerol sorbitan tetra-2-ethylhexylate; and polyoxyethylene fatty acids such as polyethylene glycol monostearate, polyethylene glycol stearate, and polyethylene glycol isostearate. Examples of suitable surfactants include olefin fatty acids; sucrose fatty acid esters; polysorbates such as polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan tristearate, and polyoxyethylene sorbitan oleate; polyoxyethylene phytosterols; and silicone surfactants such as polyoxyethylene-methylpolysiloxane copolymer, polysilicone-13 (poly(oxyethylene-oxypropylene)-butylene-methylpolysiloxane copolymer), lauryl PEG-9 polydimethylsiloxyethyl dimethicone, and PEG-9 polydimethylsiloxyethyl dimethicone. The HLB of component (D) is preferably 1 to 15, more preferably 2 to 13, even more preferably 2 to 11, even more preferably 2 to 10, and particularly preferably 2 to 9. The HLB can be determined by the Griffin method. Commercially available products can be used as component (D).

[0020] The content of component (D) in the oil-in-water cosmetic according to this embodiment is not particularly limited and is set appropriately depending on the type of component (D), the types and contents of other blended ingredients, the intended use and formulation of the oil-in-water cosmetic, etc. From the perspective of more significantly achieving the effects of the present invention, the content of component (D) is, for example, preferably 0.01 to 10% by mass, more preferably 0.05 to 8% by mass, even more preferably 0.05 to 6% by mass, even more preferably 0.05 to 4% by mass, and particularly preferably 0.1 to 2% by mass, based on the total amount of the oil-in-water cosmetic.

[0021] <(E) component> The oil-in-water cosmetic according to this embodiment may further contain (E) an ultraviolet protection agent (also referred to simply as "component (E)"). When the oil-in-water cosmetic further contains component (E), the effects of the present invention are more pronounced. There are no particular restrictions on component (E), as long as it is one that is commonly used in cosmetic compositions.

[0022] (E) Ingredients include 2-ethylhexyl paramethoxycinnamate, dimethicodiethyl benzalmalonate, octocrylene, diethylaminohydroxybenzoyl benzoic acid hexyl ester, paraaminobenzoic acid, 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine, 4 Examples of suitable UV absorbers include one or more oil-soluble UV absorbers selected from the group consisting of 4'-tert-butyl-4'-methoxydibenzoylmethane, homomenthyl salicylate, ethylhexyl salicylate, and octyl salicylate; one or more water-soluble UV absorbers selected from the group consisting of phenylbenzimidazole sulfonic acid and terephthalylidene dicamphor sulfonic acid; and one or more metal oxides selected from the group consisting of zinc oxide, titanium oxide, cerium oxide, and zirconium oxide. Oil-soluble UV absorbers preferably have a water solubility of less than 0.01%. The metal oxides are not particularly limited in terms of shape (e.g., spherical, plate-like, or needle-like), particle size (e.g., mist-like, fine particles, or pigment-grade), or particle structure (e.g., porous or nonporous), and may be surface-treated using a known surface treatment method. Component (E) can be commercially available.

[0023] The content of component (E) in the oil-in-water cosmetic according to this embodiment is not particularly limited and is set appropriately depending on the type of component (E), the types and contents of other blended ingredients, the intended use and formulation of the oil-in-water cosmetic, etc. From the perspective of more significantly achieving the effects of the present invention, the content of component (E) is, for example, preferably 0.1 to 25% by mass, more preferably 0.5 to 20% by mass, even more preferably 1 to 15% by mass, even more preferably 3 to 15% by mass, and particularly preferably 5 to 15% by mass, based on the total amount of the oil-in-water cosmetic.

[0024] <(F) Component> The oil-in-water cosmetic according to this embodiment may further contain (F) an acrylic acid-based polymer (also simply referred to as "component (F)"). When the oil-in-water cosmetic further contains component (F), the effects of the present invention are more pronounced. There are no particular restrictions on component (F), as long as it is one that is commonly used in cosmetic compositions.

[0025] (F) Ingredients include: (Sodium acrylate / sodium acryloyldimethyltaurate) copolymer, (hydroxyethyl acrylate / sodium acryloyldimethyltaurate) copolymer, (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer, (ammonium acryloyldimethyltaurate / beheneth-25 methacrylate) crosspolymer, (ammonium acryloyldimethyltaurate / steareth-25 methacrylate) crosspolymer, (ammonium acryloyldimethyltaurate / carboxyethylammonium acrylate) crosspolymer, acrylamide / ammonium acrylate copolymer, polyacrylate crosspolymer-6 Examples include polyacrylate crosspolymer-11, polyacrylate-13, (acrylic acid / acryloyldimethyltaurate / dimethylacrylamide) crosspolymer, (sodium acrylate / acryloyldimethyltaurate / dimethylacrylamide) crosspolymer, (acrylates / C10-30 alkyl acrylate) crosspolymer, (acrylates / steareth-20 methacrylate) copolymer, (acrylates / beheneth-25 methacrylate) copolymer, (acrylates / steareth-20 itaconate) copolymer, steareth-10 allyl ether acrylate copolymer, carboxyvinyl polymer (carbomer), and polyacrylamide. Component (F) can be commercially available.

[0026] The content of component (F) in the oil-in-water cosmetic according to this embodiment is not particularly limited and is set appropriately depending on the type of component (F), the types and contents of other blended ingredients, the intended use and formulation of the oil-in-water cosmetic, etc. From the perspective of more significantly achieving the effects of the present invention, the content of component (F) is, for example, preferably 0.01 to 5% by mass, more preferably 0.05 to 4% by mass, even more preferably 0.05 to 3% by mass, even more preferably 0.1 to 3% by mass, and particularly preferably 0.1 to 2% by mass, based on the total amount of the oil-in-water cosmetic.

[0027] The content ratio of component (B) to component (A) in the oil-in-water cosmetic according to this embodiment is not particularly limited, and is set appropriately depending on the types of components (A) and (B), the types and contents of other blended components, the intended use and formulation form of the oil-in-water cosmetic, etc. From the viewpoint of more significantly achieving the effects of the present invention, the content ratio of component (B) to component (A) is, for example, preferably 0.0001 to 500 parts by mass, more preferably 0.0001 to 300 parts by mass, even more preferably 0.0005 to 100 parts by mass, even more preferably 0.0005 to 50 parts by mass, and particularly preferably 0.001 to 10 parts by mass, of the total content of component (B) per 1 part by mass of the total content of component (A) contained in the oil-in-water cosmetic according to this embodiment.

[0028] The oil-in-water cosmetic composition according to this embodiment may contain known ingredients used in cosmetics and quasi-drugs, as long as they do not impair the effects of the present invention. In addition to the above-mentioned components (A) to (F), appropriate amounts of, for example, antioxidants, whitening ingredients, moisturizers, anti-inflammatory ingredients, antibacterial agents, vitamins, amino acids, biological extracts, and various pharmacologically and physiologically active ingredients may be added. Additives such as surfactants (excluding the above-mentioned (D)), preservatives, pH adjusters, chelating agents, stabilizers, buffers, thickeners (excluding the above-mentioned (F)), gelling agents, irritation reducers, antiseptics, colorants, fragrances, and minerals may be added singly or in combination of two or more. Furthermore, the cosmetic composition may contain one or more bases or carriers. These may be selected from known materials and can be prepared using conventional methods.

[0029] The oil-in-water cosmetic according to this embodiment can be prepared by, for example, mixing and stirring the components according to a conventional method.

[0030] The oil-in-water cosmetic according to this embodiment is not particularly limited in its drug form, and can take any known form as a cosmetic or quasi-drug. Examples of such known forms include solutions, suspensions, emulsions, creams, gels, liniments, ointments, lotions, aerosols, powders, poultices, sheets such as nonwoven fabrics impregnated with a drug solution, and sticks such as lipstick. The cosmetic can also be used in the form of basic cosmetics such as emulsions, creams, body lotions, body creams, and sunscreens, or in the form of makeup cosmetics such as foundations, lipsticks, blushers, eye makeup, powders, manicures, and pedicures. Sunscreen cosmetics are preferred.

[0031] The area to which the oil-in-water cosmetic composition according to this embodiment is applied is not particularly limited, and it can be applied to any of the face, arms, hands, feet, neck, etc. [Example]

[0032] The present invention will be specifically explained below based on test examples, but the present invention is not limited to these. In the following examples, the blending amounts are expressed as mass %.

[0033] [Test Example 1] Oil-in-water compositions having the formulations shown in Table 1 below were prepared according to standard methods and evaluated for quick-drying properties, non-stickiness, and application uniformity. In the table, for "methylenebisbenzotriazolyltetramethylbutylphenol 50% aqueous phase dispersion," when the indicated amount is 3% by mass, half that amount, 1.5% by mass of methylenebisbenzotriazolyltetramethylbutylphenol, is contained in the composition.

[0034] (Evaluation criteria for quick-drying) ◎: When touching the applied area 30 seconds after application, there is no sense of moisture remaining and it feels as if the product has been absorbed into the skin. 〇: When I touched the applied area 30 seconds after applying it to my skin, I felt that there was almost no moisture remaining and it felt like it had absorbed into my skin. △: When I touched the applied area 30 seconds after application, I felt a slight moisture remaining and it didn't seem to have absorbed into my skin. ×: When touching the applied area 30 seconds after application, there is a strong feeling of moisture remaining and it does not seem to have absorbed into the skin.

[0035] (Evaluation criteria for non-stickiness) 〇: When you touch the applied area 30 seconds after applying it to the skin, it does not feel sticky. ×: Sticky feeling when touching the applied area 30 seconds after application to the skin

[0036] (Evaluation criteria for coating uniformity) 3 g of the composition was weighed out onto the artificial leather and applied evenly using a bar coder. The applied area was observed 10 minutes after application. ◎: The unevenness of the artificial leather was covered, and no unevenness was observed throughout the entire application area, allowing for a uniform application. 〇: The unevenness of the artificial leather was covered, and almost no unevenness was observed throughout the entire application area, allowing for a uniform application. △: The unevenness of the artificial leather was not covered, and unevenness was observed in some areas of the applied area, making it impossible to apply evenly. ×: The unevenness of the artificial leather was not covered, unevenness was observed over the entire applied area, and the application was not uniform.

[0037] [Table 1] *1 Tinosorb M (manufactured by BASF) *2 2501 Cosmeticwax (manufactured by Toray Dow Corning) *3 SS-2804 (Dow Corning Toray)

[0038] As shown in Table 1, the composition containing a benzotriazole-type UV absorber and silicone wax was superior in quick-drying, non-stickiness, and uniform application compared to the composition not containing silicone wax. As shown in Figure 1, in Comparative Example 1, the boundary between the skin ridge and skin groove of the artificial leather was clearly observed, the unevenness was not covered, and unevenness was observed in the application on the skin ridge, resulting in an inability to apply uniformly. On the other hand, in Example 1, compared to Comparative Example 1, the skin groove of the artificial leather could be applied, the unevenness was covered, and the application was uniform overall. The composition of the present invention is quick-drying and non-sticky, allowing the UV absorber to exert its UV protection effect immediately after application, and the uniform application allows for high UV protection effect.

[0039] [Test Example 2] Oil-in-water compositions having the formulations shown in Table 2 below were prepared in a conventional manner, and the coating uniformity and ease of spreading were evaluated. The evaluation criteria for coating uniformity were the same as in Test Example 1.

[0040] (Evaluation criteria for ease of spreading) 32.5 mg of the composition was weighed out and spread on a PMMA plate. 〇: Can be spread smoothly and does not feel any resistance on the fingertips △: Can be spread smoothly and there is almost no resistance to the fingertips ×: Could not spread smoothly and felt resistance on fingertips

[0041] [Table 2] *4 SIRICA MICRO BEAD P-500 (average particle size 2 μm, Lot: 048, manufactured by JGC Catalysts and Chemicals)

[0042] As shown in Table 2, the composition containing a benzotriazole-type UV absorber and silica was superior in coating uniformity and ease of spreading compared to a composition not containing silica. The composition of the present invention can be applied quickly because it is easy to spread, so the UV absorber can exhibit its UV protection effect immediately after application, and the coating uniformity allows for high UV protection effect.

[0043] [Test Example 3] Oil-in-water compositions having the formulations shown in Table 3 below were prepared in a conventional manner, and were evaluated for quick-drying properties, compatibility with the skin, and emulsification state. The evaluation criteria for quick-drying properties were the same as those in Test Example 1.

[0044] (Evaluation criteria for skin compatibility) Two minutes after application, the applied area and the unapplied skin surface were touched with a finger to compare the sensation of the product catching on the finger. ◎: The applied area feels very smooth and does not stick to the fingers compared to the skin surface where the product is not applied. 〇: The applied area feels smooth and does not catch on the fingers compared to the skin surface without application. △: The applied area feels like it catches on the fingers compared to the skin surface without application. ×: The applied area feels more catching on the fingers than the unapplied skin surface.

[0045] (Emulsion state evaluation standard 1: smoothness) Immediately after preparation, 80 g of the composition was placed in a 100 mL beaker, and the appearance of the emulsified state on the surface in contact with air was visually observed. ◎: No irregularities, very smooth 〇: No unevenness, smooth △: Slightly uneven ×: Uneven

[0046] (Emulsion state evaluation standard 2: gloss) Immediately after preparation, 80 g of the composition was placed in a 100 mL beaker, and the appearance of the emulsified state on the surface in contact with air was visually observed. ◎: Very shiny 〇: Shiny △: Slightly shiny ×: No gloss

[0047] [Table 3] *5 Decaglyn 5-ISV (Nikko Chemicals) *6 Tinosorb S (BASF) *7 Parsol MCX (manufactured by DSM) *8 Parsol SLX (manufactured by DSM) *9 Carbopol ETD2020 (manufactured by Lubrizol)

[0048] As shown in Table 3, the compositions containing a benzotriazole-type UV absorber and a silicone wax were superior in quick-drying properties, compatibility with the skin, and emulsification state compared to compositions that did not contain silicone wax or that contained a non-silicone synthetic wax instead of the silicone wax. Because the composition of the present invention is quick-drying and highly compatible with the skin, it is less likely to adhere to clothing or the skin immediately after application, providing a comfortable feel to the user.

[0049] Test Example 4 Oil-in-water compositions having the formulations shown in Table 4 below were prepared according to standard methods, and evaluated for compatibility with skin, friction resistance, and emulsification state. The evaluation criteria for compatibility with skin and emulsification state were the same as those in Test Example 3.

[0050] (Evaluation criteria for friction resistance) ◎: No change was observed even after rubbing the applied area with the fingers 10 times 2 minutes after application to the skin. 〇: There was almost no change even after rubbing the applied area with the fingers 10 times 2 minutes after application to the skin. △: Two minutes after application to the skin, the applied area was rubbed back and forth with the fingers 10 times, and white streaky clumps of the composition were observed. ×: Two minutes after application to the skin, the applied area was rubbed back and forth with the fingers 10 times, and large white streaky clumps of the composition were observed.

[0051] [Table 4] *10 Aerosil 200 (average particle size 12 nm, Lot: 616060881, manufactured by Nippon Aerosil Co., Ltd.) *11 SS-10V (Nikko Chemicals) *12 FZ-2233 (Dow Corning Toray Co., Ltd.)

[0052] As shown in Table 4, the composition containing a benzotriazole-type UV absorber and silica with an average particle size of 2 μm was superior in skin compatibility, friction resistance, and emulsification state compared to a composition containing silica with an average particle size of 12 nm and a composition containing 45% by mass of water. The composition containing silica with an average particle size of 12 nm had a very poor emulsification state, making it impossible to perform other evaluations. The composition of the present invention has high skin compatibility and friction resistance, so it is less likely to adhere to clothing or skin immediately after application, providing the user with a comfortable feel, and these effects last for a long time.

[0053] Test Example 5 Oil-in-water compositions having the formulations shown in Table 5 below were prepared according to standard methods, and were evaluated for quick-drying properties, skin compatibility, secondary adhesion, and emulsification state. The evaluation criteria for quick-drying properties were the same as those in Test Example 1. The evaluation criteria for skin compatibility and emulsification state were the same as those in Test Example 3.

[0054] (Evaluation criteria for secondary adhesion) 1 g of the composition was applied to the area from the wrist to the center of the elbow and allowed to stand for 10 seconds. 50 square pieces of paper, each 1 cm on a side, were dropped from a height of 10 cm from the applied area. After pressing the applied area once with the palm of the hand, the number of pieces of paper remaining on the applied area was counted. Next, with the applied area facing upward, the hand was moved back and forth horizontally over a distance of 15 cm 10 times, and the number of pieces of paper remaining on the applied area was counted. ◎: When you move your arm, all the paper pieces come off from the applied area. 〇: When you move your arm, more than 90% of the paper pieces come off from the applied area. △: When the arm is moved, more than 90% of the paper pieces remain on the application area. ×: When the arm is moved, more than 90% of the paper pieces remain on the applied area, and traces of the composition soaking into the attached paper pieces can be observed.

[0055] [Table 5]

[0056] The formulations described below are prepared. Formulation Examples 1 to 7 are all oil-in-water cosmetic preparations, and can be prepared by conventional methods. All values ​​represent % by mass.

[0057] Formulation example 1 (oil-in-water UV gel) (Ingredient name) Compounding amount (mass%) Methylenebisbenzotriazolyltetramethylbutylphenol 2 BisPEG-18 methyl ether dimethyl silane 0.5 Ethylhexyl methoxycinnamate 7 Ethylhexyl Triazone 3 Diethylaminohydroxybenzoylhexyl benzoate 3 (Acrylates / C10-30 alkyl acrylate) crosspolymer 0.4 Xanthan gum 0.05 PEG-40 Stearate 0.5 Diethylhexyl succinate 5 1,3-butylene glycol 5 Sodium edetate 0.05 Sodium hyaluronate 0.01 Triethanolamine 0.3 Purified water 73.19

[0058] Formulation example 2 (oil-in-water UV gel) (Ingredient name) Compounding amount (mass%) Methylenebisbenzotriazolyltetramethylbutylphenol 3 BisPEG-18 methyl ether dimethylsilane 3 Polysilicone-15 2 Bis-ethylhexyloxyphenol methoxyphenyl triazine 2 Ethylhexyl Triazone 2 Diethylaminohydroxybenzoylhexyl benzoate 2 Ethylhexyl salicylate 8 (Acrylates / C10-30 alkyl acrylate) crosspolymer 0.4 Xanthan gum 0.05 PEG-40 Stearate 0.5 Polysorbate 60 0.5 Glyceryl tri-2-ethylhexanoate 5 Diethylhexyl succinate 5 1,3-butylene glycol 5 Sodium edetate 0.05 Sodium hyaluronate 0.01 Triethanolamine 0.3 Purified water 61.19

[0059] Formulation example 3 (oil-in-water UV gel cream) (Ingredient name) Compounding amount (mass%) Methylenebisbenzotriazolyltetramethylbutylphenol 2 BisPEG-18 methyl ether dimethylsilane 1 Ethylhexyl methoxycinnamate 7 Hydrophobic treated zinc oxide particles 10 (Acryloyldimethyltaurate ammonium / VP) copolymer 0.5 PEG-40 Stearate 0.5 Polyglyceryl-10 Pentaisostearate 0.5 Isononyl isononanoate 5 1,3-butylene glycol 5 Sodium edetate 0.05 Sodium hyaluronate 0.01 Purified water 68.44

[0060] Formulation example 4 (oil-in-water UV gel cream) (Ingredient name) Compounding amount (mass%) Methylenebisbenzotriazolyltetramethylbutylphenol 2 BisPEG-18 methyl ether dimethylsilane 1 Bis-ethylhexyloxyphenol methoxyphenyl triazine 2 Ethylhexyl Triazone 2 Ethylhexyl salicylate 2 Hydrophobic treated titanium dioxide particles 5 Hydrophobic treated zinc oxide particles 10 (Hydroxyethyl acrylate / Sodium acryloyldimethyl taurate) copolymer 0.5 Polysorbate 80 1 Glyceryl tri-2-ethylhexanoate 10 Talc 1 1,3-butylene glycol 5 Sodium edetate 0.05 Sodium hyaluronate 0.1 Purified water 58.35

[0061] Formulation example 5 (oil-in-water color UV cream) (Ingredient name) Compounding amount (mass%) Methylenebisbenzotriazolyltetramethylbutylphenol 1.5 BisPEG-18 methyl ether dimethylsilane 1 Silica (average particle size 2 μm) 0.5 Ethylhexyl methoxycinnamate 7 Bis-ethylhexyloxyphenol methoxyphenyl triazine 1 Ethylhexyl triazone 0.5 Diethylaminohydroxybenzoylhexyl benzoate 1 (Acrylates / C10-30 alkyl acrylate) crosspolymer 0.2 (Acryloyldimethyltaurate ammonium / VP) copolymer 0.2 Polysorbate 60 1 Polyhydroxystearic acid 0.5 Diphenylsiloxyphenyl Trimethicone 5 Polyglyceryl-2 Triisostearate 0.5 PEG-12 Dimethicone 0.5 Synthetic Fluorogopite 1 Red 226 0.01 Blue 1 0.005 Acrylates Copolymer 1 Hydrophilic titanium dioxide 1 1,3-butylene glycol 5 Sodium hyaluronate 0.01 Triethanolamine 0.2 Purified water 71.375

[0062] Formulation example 6 (oil-in-water UV cream) (Ingredient name) Compounding amount (mass%) Methylenebisbenzotriazolyltetramethylbutylphenol 2 BisPEG-18 methyl ether dimethylsilane 1 Silica (average particle size 18 μm) 1 Ethylhexyl methoxycinnamate 7 Bis-ethylhexyloxyphenol methoxyphenyl triazine 2 Ethylhexyl Triazone 2 Diethylaminohydroxybenzoylhexyl benzoate 2 (Hydroxyethyl acrylate / Sodium acryloyldimethyl taurate) copolymer 0.5 Xanthan gum 0.05 Glyceryl stearate 0.5 PEG-100 Stearate 0.5 Diethylhexyl succinate 5 Caprylyl Methicone 5 1,3-butylene glycol 10 Sodium edetate 0.05 Sodium hyaluronate 0.01 Purified water 61.39

[0063] Formulation example 7 (oil-in-water UV gel) (Ingredient name) Compounding amount (mass%) Methylenebisbenzotriazolyltetramethylbutylphenol 1 BisPEG-18 methyl ether dimethylsilane 1 Silica (average particle size 5 μm) 1 Ethylhexyl methoxycinnamate 7 Bis-ethylhexyloxyphenol methoxyphenyl triazine 2 Diethylaminohydroxybenzoylhexyl benzoate 2 (Acrylates / C10-30 alkyl acrylate) crosspolymer 0.4 Biosaccharide Gum-4 0.5 PEG-40 Stearate 0.5 Polysilicone-13 0.5 Diethylhexyl succinate 5 1,3-butylene glycol 5 Sodium edetate 0.05 Sodium hyaluronate 0.01 Triethanolamine 0.3 Purified water 73.74

Claims

1. An oil-in-water cosmetic comprising (A) a benzotriazole-type ultraviolet absorber, (B) one or more surfactants selected from the group consisting of polyether-modified silicone wax and silica, (C) water, and (D) one or more nonionic surfactants selected from the group consisting of polyglycerin fatty acids, sorbitan fatty acid esters, polyoxyethylene fatty acids, sucrose fatty acid esters, polysorbates, and polyoxyethylene phytosterols, The average particle size of the silica of the component (B) is 1 μm or more, An oil-in-water cosmetic, wherein the content of the component (C) is 50 mass% or more based on the total amount of the oil-in-water cosmetic.

2. 2. The oil-in-water cosmetic according to claim 1, further comprising (E) an ultraviolet protection agent (excluding the component (A)).

3. The oil-in-water cosmetic according to claim 1 or 2, comprising (F) an acrylic acid-based polymer.

4. 3. The oil-in-water cosmetic according to claim 2, wherein component (E) is one or more selected from the group consisting of 2-ethylhexyl paramethoxycinnamate, dimethicodiethyl benzalmalonate, diethylaminohydroxybenzoylbenzoic acid hexyl ester, 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine, 4-tert-butyl-4'-methoxydibenzoylmethane, ethylhexyl salicylate, phenylbenzimidazole sulfonic acid, para-aminobenzoic acid, zinc oxide, and titanium oxide.

5. 3. The oil-in-water cosmetic according to claim 1, wherein the total content of the component (B) is 0.0001 to 500 parts by mass per 1 part by mass of the total content of the component (A).

6. The oil-in-water cosmetic according to any one of claims 1 to 5, wherein the total content of component (B) is 0.01 to 10% by mass.

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