Negative electrode pieces, electrochemical apparatus and electronic apparatus

Abstract

The present invention provides a negative electrode piece, an electrochemical device, and an electronic device. The negative electrode piece includes a current collector and an active material layer located on the current collector, the active material layer includes a silicon-based material, a carbon material, and a binder. If the mass ratios of two silicons located at different positions and having the same area in the active material layer are X1 and X2, respectively, X2≧X1, and if M=X1 / X2, M≧0.7. If the mass ratios of two lithiums located at different positions and having the same area in the active material layer are Y1 and Y2, respectively, Y2≧Y1, and if N=Y1 / Y2, N≧0.5. The embodiment of the present invention is advantageous in improving the uniformity of the distribution of silicon in the active material layer of the negative electrode piece, thereby improving the volume expansion of the silicon-based material during cycling, and improving the cycle characteristics and safety of the electrochemical device.

Description

Technical Field

[0001] The present invention relates to the field of electrochemical energy storage, and particularly to a negative electrode sheet, an electrochemical device, and an electronic device.

Background Art

[0002] With the development and progress of electrochemical devices (for example, lithium-ion batteries), higher and higher requirements are being placed on their safety and cycle characteristics. The current improvement technologies for electrochemical devices can improve the safety and cycle characteristics of electrochemical devices to a certain extent, but they still do not meet the requirements, and further improvements are expected.

Summary of the Invention

[0003] Embodiments of the present invention provide a negative electrode sheet including a current collector and an active material layer located on the current collector. Here, the active material layer includes a silicon-based material, a carbon material, and a binder. When the mass ratios of silicon at two locations with the same area located at different positions in the active material layer are X1 and X2 respectively, X2≥X1. When M = X1 / X2, M≥0.7; here, when the mass ratios of lithium at two locations with the same area located at different positions in the active material layer are Y1 and Y2 respectively, Y2≥Y1. When N = Y1 / Y2, N≥0.5.

[0004] In some embodiments, the mass fraction of the silicon-based material in the active material layer is 2% to 80%. In some embodiments, the binder includes a lithium salt. In some embodiments, the mass fraction of the binder in the active material layer is 0.5% to 10%. In some embodiments, the silicon-based material is Si, SiO xIt contains at least one of SiO2, SiC, Li2SiO5, Li2SiO3, Li4SiO4, and silicon alloy, and 0.6 ≦ x ≦ 1.5. In some embodiments, the particle size of Si is less than 100 nm. In some embodiments, for the silicon-based material, in the X-ray diffraction pattern, when the maximum intensity value in the range of 2θ being 20.5° - 21.5° is I1, and the maximum intensity value in the range of 2θ being 28.0° - 29.0° is I2, then 0 < I2 / I1 ≦ 1 is satisfied. In some embodiments, the particle size distribution of the silicon-based material satisfies 0.3 ≦ Dn10 / Dv50 ≦ 0.6. In some embodiments, the average particle size of the silicon-based material is 500 nm - 30 μm.

[0005] In some embodiments, the binder contains at least one of carboxymethyl cellulose, polyacrylic acid, polyvinyl pyrrolidone, polyaniline, polyimide, polyamideimide, polysiloxane, polystyrene butadiene rubber, epoxy resin, polyester resin, polyurethane resin, and polyfluorene. In some embodiments, in the active material layer, when the weight loss ratios of thermogravimetric analysis (TG) within 800 °C at two different positions with the same area are Z1 and Z2 respectively, then Z2 ≧ Z1, and when K = Z1 / Z2, then K ≧ 0.7. In some embodiments, the active material layer further contains a conductive agent, and the conductive agent contains at least one of single-walled carbon nanotubes, multi-walled carbon nanotubes, vapor-grown carbon fibers, conductive carbon black, acetylene black, ketjen black, conductive graphite, and graphene. In some embodiments, the mass fraction of the silicon-based material in the active material layer is 2% - 40%. In some embodiments, the carbon material contains graphite.

[0006] Another embodiment of the present invention provides an electrochemical device including a positive electrode sheet, a negative electrode sheet, and a separator, and the separator is provided between the positive electrode sheet and the negative electrode sheet. Here, the negative electrode sheet is any one of the above negative electrode sheets. An embodiment of the present invention further provides an electronic device including the above electrochemical device.

[0007] Embodiments of the present invention are advantageous in improving the uniformity of lithium desorption and insertion by improving the uniformity of silicon dispersion in the active material layer of the negative electrode piece, thereby improving the volume expansion of silicon-based materials during cycling and enhancing the cycle characteristics and safety of electrochemical equipment. [Brief explanation of the drawing]

[0008] [Figure 1] Figure 1 shows a schematic diagram of an electrode assembly in a conventional electrochemical apparatus. [Figure 2] Figure 2 shows cross-sectional views of the negative electrode pieces in several embodiments. [Figure 3] Figure 3 shows a cross-sectional view of the negative electrode piece of Example 1. [Figure 4] Figure 4 shows a cross-sectional view of the negative electrode piece of Example 2. [Figure 5] Figure 5 shows a cross-sectional view of the negative electrode piece of Example 4. [Figure 6] Figure 6 shows a cross-sectional view of the negative electrode piece of Comparative Example 2. [Modes for carrying out the invention]

[0009] The following examples may help those skilled in the art to understand the present invention more fully, but they do not limit the invention in any way.

[0010] To improve the energy density of an electrochemical apparatus, silicon-based materials can be used for the active material layer of the negative electrode. However, silicon-based materials undergo enormous volume changes, reaching up to 300%, during the cycle, generating enormous mechanical stress (which can reach 1 GPa). This leads to powderization of the silicon-based material particles and delamination between the active material layer and the current collector, thus degrading the cycle characteristics of the electrochemical apparatus. At the same time, silicon-based materials have poor electrical conductivity (powder electronic conductivity < 10). -7This can cause severe polarization (S / cm), further degrading the cycle performance of electrochemical equipment. To mitigate the volume expansion of silicon-based materials, silicon-based materials are usually used in combination with carbon materials (e.g., graphite), but further improvements in the cycle performance and safety of electrochemical equipment are expected.

[0011] By improving the uniformity of silicon dispersion in the negative electrode piece containing silicon-based material, the uniformity of the current distribution in the negative electrode piece can be improved. This results in more uniform expansion and contraction of each region during charging and discharging, reduced polarization, improved cycle characteristics and rate characteristics of the electrochemical apparatus, and is advantageous for improving the expansion of the electrode assembly.

[0012] As shown in Figure 1, a developed cross-sectional view of a conventional electrochemical apparatus is provided. The electrochemical apparatus may include an electrode assembly, which includes a positive electrode piece 10, a negative electrode piece 12, and a separator 11 provided between the positive electrode piece 10 and the negative electrode piece 12.

[0013] In some embodiments, as shown in Figure 2, the negative electrode piece 12 may include a current collector 121 and an active material layer 122 located on the current collector 121. Although Figure 2 shows the active material layer 122 provided on only one side of the current collector 121, this is merely illustrative, and it should be understood that the active material layer 122 may be provided on both sides of the current collector 121. In some embodiments, the active material layer 122 includes a silicon-based material, a carbon material, and a binder.

[0014] In some embodiments, if the mass ratios of silicon atoms located in different places but with the same area in the active material layer 122 are X1 and X2, then X2 ≥ X1, and if M = X1 / X2, then M ≥ 0.7. The closer M is to 1, the more uniform the distribution of silicon in the active material layer 122 is, that is, the more uniform the distribution of the silicon-based material is. By improving the uniformity of silicon dispersion in the active material layer 122, the silicon-based material can be distributed more uniformly in the carbon material. Furthermore, the carbon material can better suppress or mitigate problems caused by the volume expansion of the silicon-based material. In addition, the carbon material, which has excellent conductivity, can better overcome or compensate for the problem of poor conductivity of the silicon-based material. Therefore, the volume expansion of the silicon-based material during the cycle is improved, and the cycle characteristics and safety of the electrochemical apparatus are enhanced.

[0015] In some embodiments, if the mass ratios of lithium at two locations in the active material layer 122 that are located at different points but have the same area are Y1 and Y2, then Y2 ≥ Y1, and if N = Y1 / Y2, then N ≥ 0.5. The larger N is, or the closer N is to 1, the more uniform the distribution of lithium in the active material layer 122 is, that is, the more uniform the insertion and removal of lithium ions during the cycle, which is advantageous for improving the cycle characteristics and safety of the electrochemical apparatus. Furthermore, the uniform distribution of lithium in the active material layer 122 also indicates that the distribution of the material in the active material layer 122 is relatively uniform.

[0016] In some embodiments, the mass fraction of silicon-based material in the active material layer 122 is between 2% and 80%. If the mass fraction of silicon-based material in the active material layer 122 is too low, for example, less than 2%, using silicon-based material to improve the energy density of the electrochemical apparatus has only a limited effect. On the other hand, if the mass fraction of silicon-based material in the active material layer 122 is too high, for example, more than 80%, the active material layer 122 may undergo large volume expansion due to the high content of silicon-based material, which is also detrimental to the stability of the solid electrolyte interface (SEI) film of the negative electrode and may lead to excessive consumption of the electrolyte. In some embodiments, the mass fraction of silicon-based material in the active material layer 122 is between 2% and 40%.

[0017] In some embodiments, the binder in the active material layer 122 contains a lithium salt. In this way, the lithium content in the negative electrode piece 12 can be increased, thereby mitigating lithium loss during the cycle, playing a role in replenishing lithium, and improving the cycle characteristics of the electrochemical apparatus.

[0018] In some embodiments, the mass fraction of the binder in the active material layer 122 is between 0.5% and 10%. If the mass fraction of the binder in the active material layer 122 is too small, for example, less than 0.5%, it is unfavorable for adhesion between materials, and delamination is likely to occur between the active material layer 122 and the current collector 121. If the mass fraction of the binder in the active material layer 122 is too large, for example, more than 10%, it adversely affects the energy density of the electrochemical apparatus.

[0019] In some examples, the silicon-based material is Si, SiO xIt contains at least one of SiO2, SiC, Li2SiO5, Li2SiO3, Li4SiO4, and silicon alloy, and 0.6 ≦ x ≦ 1.5. In some embodiments, the particle size of Si is less than 100 nm. In some embodiments, the carbon material in the active material layer 122 contains graphite. In some embodiments, the binder contains at least one of carboxymethyl cellulose, polyacrylic acid, polyvinyl pyrrolidone, polyaniline, polyimide, polyamideimide, polysiloxane, polystyrene butadiene rubber, epoxy resin, polyester resin, polyurethane resin, and polyfluorene.

[0020] In some embodiments, for the silicon-based material in the X-ray diffraction pattern, when the maximum intensity value in the range of 2θ being 20.5° to 21.5° is I1, and the maximum intensity value in the range of 2θ being 28.0° to 29.0° is I2, then 0 < I2 / I1 ≦ 1 is satisfied. In some embodiments, the smaller I2 / I1 is, the smaller the influence on the uniformity of silicon dispersion and lithium uniformity, but there is a significant effect on improving the rate characteristics, cycle characteristics of the electrochemical device, and improving cycle expansion.

[0021] In some embodiments, the particle size distribution of the silicon-based material satisfies 0.3 ≦ Dn10 / Dv50 ≦ 0.6. Dn10 represents the particle size corresponding to the cumulative particle size distribution number reaching 10%, and Dv50 represents the particle size corresponding to the cumulative volume distribution reaching 50%. In some embodiments, if Dn10 / Dv50 of the silicon-based material is too small, the uniformity of silicon dispersion is poor, that is, the M value decreases, the N value also decreases, and the cycle characteristics of the electrochemical device deteriorate. However, the presence of small particle-shaped silicon-based materials is beneficial for improving the rate characteristics of the electrochemical device. Also, if Dn10 / Dv50 is too large, the uniformity of silicon dispersion also deteriorates, and it causes deterioration of the cycle characteristics, rate characteristics, and cycle expansion of the electrochemical device.

[0022] In some embodiments, the average particle size of the silicon-based material is 500 nm to 30 μm. If the average particle size of the silicon-based material is too small, for example, less than 500 nm, the specific surface area of the silicon-based material particles is large, aggregation is likely to occur, and more electrolyte is consumed to form the SEI film. If the average particle size of the silicon-based material is too large, for example, more than 500 nm, the volume expansion of the silicon-based material particles becomes large.

[0023] In some embodiments, in the active material layer 122, if the weight loss rates of thermogravimetric analysis (TG) within 800 °C at two locations with the same area and different positions are Z1 and Z2 respectively, then Z2 ≥ Z1, K = Z1 / Z2, and here, K ≥ 0.7. The larger the K value, the more uniform the distribution of the binder in the active material layer 122, indicating that the distribution of the silicon-based material at this time is also more uniform.

[0024] In some embodiments, the active material layer 122 can further include a conductive agent, and the conductive agent can include at least one of single-walled carbon nanotubes, multi-walled carbon nanotubes, vapor-grown carbon fibers, conductive carbon black, acetylene black, ketjen black, conductive graphite, and graphene.

[0025] In some embodiments, the current collector 121 of the negative electrode sheet 12 can be made of at least one of copper foil, nickel foil, and carbon-based current collectors. In some embodiments, the compression density of the active material layer 122 of the negative electrode sheet 12 is 1.0 g / cm 3 ~1.9 g / cm 3This can be done. If the compressive density of the negative electrode active material layer 122 is too low, the volumetric energy density of the electrochemical device will be lost. If the compressive density of the active material layer 122 is too high, it is unfavorable for lithium ion passage, polarization will increase, affecting the electrochemical properties and making lithium more likely to precipitate during charging of the electrochemical device. It should be understood that the materials disclosed above are illustrative only, and any other suitable material can be used for the active material layer 122. In some embodiments, the mass ratio of the negative electrode active material (e.g., silicon-based material and carbon material), conductive agent and binder in the active material layer 122 can be (70-98):(1-15):(1-15). It should be understood that the above is illustrative only, and any other suitable mass ratio can be used.

[0026] In some embodiments, the present invention also provides a method for preparing negative electrode pieces, the method comprising the steps of: first mixing a silicon-based material and a carbon material to obtain a mixed material; second mixing the mixed material, a conductive agent, a binder and a solvent to obtain a negative electrode slurry; and then applying the negative electrode slurry to a negative electrode current collector and drying it to obtain a negative electrode piece. In some embodiments, the first mixing includes dispersing at a rotational speed of 10 r / min to 100 r / min for 0.5 h to 2 h. If the first mixing time is too short, it is detrimental to uniform mixing of the materials, and if the first mixing time is too long, it is detrimental to improving manufacturing efficiency. In some embodiments, the second mixing includes dispersing at a rotational speed of 300 r / min to 2500 r / min for 0.5 h to 3 h. If the second mixing time is too short, it is detrimental to uniform mixing of the materials, and if the second mixing time is too long, it is detrimental to improving manufacturing efficiency.

[0027] As described above, embodiments of the present invention provide an electrochemical apparatus. The electrochemical apparatus includes an electrode assembly, the electrode assembly including a positive electrode piece 10, a negative electrode piece 12, and a separator 11 provided between the positive electrode piece 10 and the negative electrode piece 12. Here, the negative electrode piece 12 is one of the negative electrode pieces described above.

[0028] In some embodiments, the positive electrode piece 10 includes a positive electrode current collector and a positive electrode active material layer located on the positive electrode current collector. The positive electrode active material layer is provided on one or both sides of the positive electrode current collector. In some embodiments, the positive electrode current collector can be made of Al foil, and of course, other positive electrode current collectors commonly used in the art can also be used. In some embodiments, the thickness of the positive electrode current collector is 1 μm to 200 μm. In some embodiments, the positive electrode active material layer can be applied to only a portion of the positive electrode current collector. In some embodiments, the thickness of the positive electrode current collector can be independently 10 μm to 500 μm. In some embodiments, the positive electrode active material layer contains positive electrode active material. In some embodiments, the positive electrode active material can include at least one of lithium cobalt oxide, lithium manganese oxide, lithium iron phosphate, lithium nickel cobalt manganese oxide, lithium nickel cobalt aluminate, and lithium nickel manganese oxide. In some examples, the positive electrode active material layer further comprises a binder and a conductive agent. In some examples, the binder in the positive electrode active material layer may include at least one of polyvinylidene fluoride, vinylidene fluoride-hexafluoropropylene copolymer, styrene-acrylic acid ester copolymer, styrene-butadiene copolymer, polyamide, polyacrylonitrile, polyacrylate, polyacrylic acid, polyacrylate salt, sodium carboxymethylcellulose, polyvinyl acetate, polyvinylpyrrolidone, polyvinyl ether, polymethyl methacrylate, polytetrafluoroethylene, and polyhexafluoropropylene. In some examples, the conductive agent in the positive electrode active material layer may include at least one of conductive carbon black, Ketjenblack, flake graphite, graphene, carbon nanotubes, and carbon fibers. In some examples, the mass ratio of the positive electrode active material, conductive agent, and binder in the active material layer may be (70-98):(1-15):(1-15). The above is merely an example, and it should be understood that the active material layer can use any other suitable material, thickness, and mass ratio.

[0029] In some embodiments, the separator 11 comprises at least one of polyethylene, polypropylene, polyvinylidene fluoride, polyethylene terephthalate, polyimide, and aramid. For example, polyethylene comprises at least one selected from high-density polyethylene, low-density polyethylene, and ultra-high molecular weight polyethylene. In particular, polyethylene and polypropylene have a good effect in preventing short circuits and can improve battery stability through the turn-off effect. In some embodiments, the thickness of the separator is in the range of about 5 μm to 500 μm.

[0030] In some embodiments, the surface of the separator may further include a porous layer, which is provided on at least one surface of the substrate of the separator, and the porous layer comprises inorganic particles and a binder, the inorganic particles being one selected from alumina (Al2O3), silica (SiO2), magnesium oxide (MgO), titanium oxide (TiO2), hafnium dioxide (HfO2), tin oxide (SnO2), cerium dioxide (CeO2), nickel oxide (NiO), zinc oxide (ZnO), calcium oxide (CaO), zirconium oxide (ZrO2), yttrium oxide (Y2O3), silicon carbide (SiC), boehmite, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, and barium sulfate. In some embodiments, the pores of the separator have a diameter in the range of about 0.01 μm to 1 μm. The binder for the porous layer is at least one selected from polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene copolymer, polyamide, polyacrylonitrile, polyacrylate, polyacrylic acid, polyacrylate, sodium carboxymethylcellulose, polyvinylpyrrolidone, polyvinyl ether, polymethyl methacrylate, polytetrafluoroethylene, and polyhexafluoropropylene. The porous layer on the separator surface can improve the heat resistance, oxidation resistance, and electrolyte permeability of the separator, and enhance the adhesion between the separator and the electrode pieces.

[0031] In some embodiments of the present invention, the electrode assembly of the electrochemical apparatus is a wound electrode assembly or a stacked electrode assembly.

[0032] In some embodiments, the electrochemical apparatus includes a lithium-ion battery, but the present invention is not limited thereto. In some embodiments, the electrochemical apparatus may further include an electrolyte. The electrolyte may be one or more of a gel electrolyte, a solid electrolyte, and an electrolyte solution. The electrolyte solution includes a lithium salt and a non-aqueous solvent. The lithium salt is one or more selected from LiPF6, LiBF4, LiAsF6, LiClO4, LiB(C6H5)4, LiCH3SO3, LiCF3SO3, LiN(SO2CF3)2, LiC(SO2CF3)3, LiSiF6, LiBOB, and lithium difluoroborate. For example, LiPF6 is selected as the lithium salt because it contributes to high ionic conductivity and can improve cycle characteristics.

[0033] The non-aqueous solvent may be a carbonate compound, a carboxylate compound, an ether compound, other organic solvents, or a combination thereof.

[0034] The carbonate compound may be a linear carbonate compound, a cyclic carbonate compound, a fluorocarbonate compound, or a combination thereof. Examples of linear carbonate compounds include diethyl carbonate (DEC), dimethyl carbonate (DMC), dipropyl carbonate (DPC), methylpropyl carbonate (MPC), ethylpropyl carbonate (EPC), ethylmethyl carbonate (MEC), and combinations thereof. Examples of cyclic carbonate compounds include ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate (BC), vinylethylene carbonate (VEC), and combinations thereof. Examples of the aforementioned fluorocarbonate compounds include fluoroethylene carbonate (FEC), 1,2-difluoroethylene carbonate, 1,1-difluoroethylene carbonate, 1,1,2-trifluoroethylene carbonate, 1,1,2,2-tetrafluoroethylene carbonate, 1-fluoro-2-methylethylene carbonate, 1-fluoro-1-methylethylene carbonate, 1,2-difluoro-1-methylethylene carbonate, 1,1,2-trifluoro-2-methylethylene carbonate, trifluoromethylethylene carbonate, and combinations thereof.

[0035] Examples of carboxylate compounds include methyl acetate, ethyl acetate, n-propyl acetate, tert-butyl acetate, methyl propionate, ethyl propionate, propyl propionate, γ-butyrolactone, decalactone, valerolactone, mevalonolactone, caprolactone, methyl formate, and combinations thereof.

[0036] Examples of ether compounds include dibutyl ether, tetraethylene glycol dimethyl ether, diethylene glycol dimethyl ether, 1,2-dimethoxyethane, 1,2-diethoxyethane, ethoxymethoxyethane, 2-methyltetrahydrofuran, tetrahydrofuran, and combinations thereof.

[0037] Other examples of organic solvents include dimethyl sulfoxide, 1,2-dioxolane, sulfolane, methylsulfolane, 1,3-dimethyl-2-imidazolidinone, N-methyl-2-pyrrolidone, formamide, dimethylformamide, acetonitrile, trimethyl phosphate, triethyl phosphate, trioctyl phosphate, and phosphate esters, or combinations thereof.

[0038] In some embodiments of the present invention, taking a lithium-ion battery as an example, an electrode member is formed by sequentially winding or stacking a positive electrode piece, a separator, and a negative electrode piece. Then, for example, it is placed in an aluminum plastic film and sealed, an electrolyte is injected, it is formed, and sealed to produce a lithium-ion battery. Next, a performance test is performed on the prepared lithium-ion battery.

[0039] It should be understood that the method for manufacturing the electrochemical apparatus (e.g., lithium-ion battery) described above is merely an example of the present invention. Other methods commonly used in the art can be employed without departing from the scope disclosed herein.

[0040] Embodiments of the present invention further provide electronic devices including the electrochemical apparatus described above. The electronic devices of the embodiments of the present invention are not particularly limited and can be used in any electronic device known in the prior art. In some embodiments, the electronic devices may include, but are not limited to, laptop computers, pen-input computers, mobile computers, e-book players, mobile phones, portable facsimile machines, portable copiers, portable printers, stereo headsets, video recorders, LCD televisions, portable cleaners, portable CD players, MiniDiscs, transceivers, electronic organizers, calculators, memory cards, portable tape recorders, radios, backup power supplies, motors, automobiles, motorcycles, electric bicycles, bicycles, lighting fixtures, toys, game consoles, clocks, power tools, flashlights, cameras, large household batteries, and lithium-ion capacitors.

[0041] To better illustrate the present invention, several specific examples and comparative examples are given below, using lithium-ion batteries as examples.

[0042] Example 1 Preparation of positive electrode pieces: Lithium cobalt oxide as the positive electrode active material, conductive carbon black as the conductive agent, and polyvinylidene fluoride (PVDF) as the binder were dissolved in N-methylpyrrolidone (NMP) solution in a weight ratio of 96.7:1.7:1.6 to form a positive electrode slurry. Aluminum foil was used as the positive electrode current collector, and the positive electrode slurry was applied to the positive electrode current collector at a coating amount of 18.37 mg / cm². 2 The positive electrode pieces were obtained through drying, cold rolling, and punching.

[0043] Preparation of negative electrode pieces: SiO as a silicon-based material, graphite, conductive carbon black as a conductive agent, and polyacrylic acid (PAA) as a binder were dissolved in deionized water in a weight ratio of 100:900:10:25 to form an active material layer slurry. Copper foil was used as the negative electrode current collector, and the negative electrode slurry was applied to the negative electrode current collector at a coating amount of 9.3 mg / cm². 2 The negative electrode pieces were obtained by drying and punching.

[0044] Separator preparation: The separator substrate was made of polyethylene (PE) with a thickness of 8 μm. A 2 μm alumina ceramic layer was applied to each side of the separator substrate. Finally, 2.5 mg of polyvinylidene fluoride (PVDF) was applied to each side of the ceramic layer as a binder and dried.

[0045] Preparation of electrolyte: In an environment with a water content of less than 10 ppm, LiPF6 was added to a non-aqueous organic solvent (propylene carbonate (PC), ethylene carbonate (EC): diethyl carbonate (DEC) = 1:1:1, by weight ratio) to adjust the concentration of LiPF6 to 1.15 mol / L. Then, 12.5 wt% fluoroethylene carbonate (FEC) was added and the mixture was homogeneously mixed to obtain the electrolyte.

[0046] Preparation of lithium-ion battery: A positive electrode piece, a separator, and a negative electrode piece were stacked in order, with the separator interposed between the positive and negative electrode pieces to function as a separator, and the assembly was wound to obtain an electrode assembly. The electrode assembly was placed in an outer aluminum plastic film, moisture was removed at 80°C, the electrolyte was injected and sealed, and a lithium-ion battery was obtained through processes such as formation, degassing, and cutting.

[0047] The examples and comparative examples are based on the steps of Example 1, but with modified parameters. The specific modified parameters are shown in Table 1 below, and the parameters of some of the obtained results are shown in Table 2 below.

[0048] The following describes the measurement methods for each parameter of the present invention.

[0049] Measurement of the silicon content of the negative electrode piece: The electrode assembly was removed and discharged to a full discharge state at 0.5C at a temperature of 25°C (discharge to 3.0V when lithium cobalt oxide is the positive electrode active material; the full discharge voltage for other electrochemical systems was selected by those skilled in the art based on the chemical system). The electrode assembly was then disassembled, the negative electrode piece was removed, and measurements were taken.

[0050] Preheat the muffle furnace to 400°C. Weigh 0.05g to 1g of the sample and place it in the crucible. Then weigh 1.2g to 1.5g of dry KOH reagent and place it in the crucible. Cover the crucible with the lid and place it in the crucible holder. Once the muffle furnace reaches 400°C, place the crucible holder in the muffle furnace and melt for about 45 minutes (using the criterion that the liquid KOH completely covers the sample). Once the sample has melted, remove the crucible holder and let it cool. At the same time, take an appropriate amount of pure water in a clean beaker and pre-boil it in the electric furnace. Place the cooled crucible and crucible lid into a clean 200ml plastic beaker using nickel tweezers. Approximately 50 ml of boiling water was placed in a beaker, and the crucible lid and crucible were completely wetted with the boiling water. The leaching time was maintained for approximately 60 minutes. The crucible and crucible lid were removed with tweezers, and the inner and outer walls of the crucible and the front and back surfaces of the crucible lid were washed 2-3 times with a bottle of pure water with a low water flow. The sample solution was filtered through medium-speed filter paper into a 100 ml polypropylene (PP) volumetric flask and brought to a final volume. After mixing the final volume solutions, 1 ml of the sample solution was transferred to a 100 ml PP volumetric flask using a pipette or plastic pipette, and then brought to a final volume of 100 ml. Subsequently, ICP measurement was performed.

[0051] Measurement of lithium content in negative electrode pieces: An electrochemical apparatus was used, and the system was discharged to a full discharge state at 0.5C at a temperature of 25°C (discharged to 3.0V when lithium cobalt oxide was used as the positive electrode active material; the full discharge voltage for other electrochemical systems was selected by those skilled in the art based on the chemical system). The electrode assembly was then disassembled, the negative electrode piece was removed, and measurements were taken.

[0052] Five or more positions on the negative electrode were randomly selected and punched out into small circular sheets of the same area. The small circular sheets were placed in a decomposition tank, decomposition reagents were added, and the material was decomposed in a microwave decomposition device. After decomposition was complete, the lid was washed 2-3 times with ultrapure water, and the washing solution was poured into the decomposition tank. ICP measurement was then performed.

[0053] Thermogravimetric analysis (TG) of the negative electrode piece: An electrochemical apparatus was used, and the system was discharged to a full discharge state at 0.5C at a temperature of 25°C (discharged to 3.0V when lithium cobalt oxide was used as the positive electrode active material; the full discharge voltage for other electrochemical systems was selected by those skilled in the art based on the chemical system). The electrode assembly was then disassembled, the negative electrode piece was removed, and measurements were taken.

[0054] Five or more positions on the negative electrode piece were randomly selected and punched out into small circular sheets of the same area. These small circular sheets were placed in a device of model number STA449F3-QMS403C and heated at a heating temperature of 800°C, a heating rate of 10°C / min, and a protective atmosphere of 99.99% pure N2. The purge gas flow rate was 60 mL / min, and the protective gas flow rate was 20 mL / min. During the heating process, a curve showing a gradual decrease in weight with increasing temperature, i.e., a thermal loss curve, was obtained. When heated to 800°C, the percentage of weight loss at that time is the weight loss rate of the negative electrode piece.

[0055] Measurement of the electrical resistance of the negative electrode piece: The electrical resistivity of the electrode piece was measured using the four-probe method. The instrument used for the four-probe measurement was a precision DC voltage and current source (SB118 type), in which four copper plates, each 1.5 cm long, 1 cm wide, and 2 mm thick, were fixed at equal intervals on a single line, with a distance L (1 cm to 2 cm) between the two copper plates in the middle, and the base material used to fix the copper plates was an insulating material. During measurement, the lower ends of the four copper plates were pressed against the electrode piece, a DC current I flowed through the copper plates at both ends, and the voltage V across the two copper plates in the middle was measured. The values ​​of I and V were read three times, and the average value of I and V was taken. V / I was the electrical resistance of the electrode piece measured.

[0056] Measurement of peel strength of negative electrode piece: The adhesive strength of the negative electrode pieces was measured using a tensile strength testing machine. The negative electrode pieces were cut to a size of 15 mm x 2 mm, bonded to a stainless steel plate using 3M double-sided tape, and then placed on a tensile strength testing machine to measure the adhesive strength of the electrode pieces.

[0057] XRD measurement: 1.0g to 2.0g of the sample was weighed and placed in the groove of a glass sample holder, compacted with a glass plate, and smoothed. Measurement was performed using an X-ray diffractometer (BRUKER, D8) in accordance with JJS K 0131-1996 "General Rules for X-ray Diffraction Analysis," with a measurement voltage of 40kV, a current of 30mA, a scanning angle range of 10° to 85°, a scanning step size of 0.0167°, and a time set for each step size of 0.24s. An XRD diffraction pattern was obtained, and from the figure, the maximum intensity value I2 at 2θ = 28.4° and the maximum intensity value I1 at 2θ = 21.0° were obtained, and the ratio of I2 / I1 was calculated.

[0058] Particle size measurement: 0.02 g of the powder sample was added to a 50 mL washed beaker, 20 mL of deionized water was added, and then a few drops of 1% surfactant were added to completely disperse the powder in the water. Ultrasonic cleaning was performed for 5 minutes in a 120 W ultrasonic cleaner, and the particle size distribution was measured using a MasterSizer 2000.

[0059] High-temperature cycling test: The measurement temperature was 45°C. The battery was charged to 4.4V with a constant current of 0.7C, then charged to 0.025C with a constant voltage, left to stand for 5 minutes, and then discharged to 3.0V with 0.5C. The capacity obtained in this step was taken as the initial capacity. Cycle measurements were performed by charging at 0.7C and discharging at 0.5C, and the capacity decay curve was obtained by comparing the capacity at each step with the initial capacity.

[0060] Measurement of expansion rate at full charge: The thickness of a new electrode assembly at partial charge was measured using a micrometer. After 400 cycles, the battery was fully charged. The thickness of the battery at this time was measured again using a micrometer and compared to the thickness of the new electrode assembly at the initial partial charge stage to obtain the expansion rate of the fully charged battery.

[0061] Discharge rate measurement: At 25°C, the batteries were discharged to 3.0V at 0.2C, left to stand for 5 minutes, charged to 4.4V at 0.5C, charged to 0.05C at a constant voltage and left to stand for 5 minutes, and the discharge rate was adjusted. Discharge measurements were taken at 0.2C, 0.5C, 1C, 1.5C, and 2.0C, and the discharge capacities for each rate were obtained. The capacities obtained at each rate were compared with the capacities obtained at 0.2C to obtain a ratio, and the rate characteristics were compared by comparing these ratios.

[0062] DC impedance (DCR) measurement: Using a Maccor machine, the actual capacitance of the electrode assembly was measured at 25°C (charged to 4.4V with a constant current of 0.7C, charged to 0.025C with a constant voltage, left standing for 10 minutes, discharged to 3.0V with 0.1C, left standing for 5 minutes). By discharging to a constant charge state (SOC) at 0.1C, measurements were taken every 5ms during a 1s discharge, and the DCR values ​​at different SOCs were calculated.

[0063] Tables 1 and 2 show the parameters and evaluation results for the examples and comparative examples.

[0064] [Table 1-1] [Table 1-2] [Table 1-3]

[0065] [Table 2-1] [Table 2-2] [Table 2-3]

[0066] As can be seen by comparing Examples 1 to 4, decreasing the mass fraction of the silicon-based material is advantageous for improving the uniformity of the dispersion of the silicon-based material in the graphite, and the value of M improves. Also, as the mass fraction of the silicon-based material decreases, the residual lithium content in the negative electrode piece decreases, and the value of N improves. Increasing the mass fraction of the silicon-based material is advantageous for improving the rate characteristics of the electrochemical apparatus, but if the mass fraction of the silicon-based material increases to 40% or more, conductivity becomes insufficient, and conversely, it causes deterioration of the rate characteristics of the electrochemical apparatus. Furthermore, an increase in the mass fraction of the silicon-based material causes deterioration of the cycle characteristics and expansion of the electrochemical apparatus. Figures 3 to 5 show cross-sectional views of the negative electrode pieces of Examples 1, 2, and 4.

[0067] As can be seen by comparing Examples 1, 5, 6, and 7, using the same amounts of sodium carboxymethylcellulose (CMC), polyacrylic acid (PAA), and lithium polyacrylate (PAA-Li) as binders exhibits the same effects and can disperse and adhere silicon-based material particles. When PAA-Li is used, the Li content in the negative electrode piece increases, improving the diffusion rate of Li ions and enhancing the rate characteristics of the electrochemical apparatus.

[0068] As can be seen by comparing Examples 1, 8, 9, 10 and Comparative Example 1, reducing the binder PAA content is advantageous in improving the binder's dispersion effect and thus the rate characteristics of the electrochemical apparatus. However, it worsens the dispersion effect of the silicon-based material, leads to a non-uniform distribution of Li, reduces the adhesive effect, and degrades the electrochemical apparatus's cycle characteristics and expansion. As the binder PAA content increases, too much binder becomes difficult to disperse, the dispersion effect of the silicon-based material deteriorates, and the distribution of Li becomes non-uniform. Too much binder worsens the rate characteristics of the electrochemical apparatus, as well as the electrochemical apparatus's cycle characteristics and the expansion of the electrode assembly.

[0069] As can be seen by comparing Examples 1, 11, 12 and Comparative Example 2, if the mixing time of the silicon-based material and graphite is too short (less than 1.5 hours), the silicon-based material cannot be effectively dispersed, the M and N values ​​decrease, and the rate characteristics, cycle characteristics, and cell expansion of the electrochemical apparatus deteriorate. If the mixing time of the silicon-based material and graphite is 1.5 hours or longer, the silicon-based material can be uniformly dispersed, and further extending the time has little effect on improving the M and N values. Figure 3 shows a cross-sectional view of the negative electrode piece of Example 1, and Figure 6 shows a cross-sectional view of the negative electrode piece of Comparative Example 2. The uniformity of the active material layer in Example 1 is better than that of Comparative Example 2, and it can be seen that some degree of aggregation phenomenon is present in Comparative Example 2.

[0070] As can be seen by comparing Examples 1, 13, 14 and Comparative Example 3, improving the binder dispersion time is advantageous for improving the uniformity of binder dispersion (improvement of Z value), as well as improving the uniformity of dispersion of silicon-based materials (improvement of M value) and Li dispersion (improvement of N value), which is advantageous for improving the rate characteristics and cycle characteristics of electrochemical equipment and reducing the cycle expansion of electrode assemblies.

[0071] As can be seen from comparing Examples 1, 15, 16, 17 and Comparative Examples 7-12, uniform dispersion of the silicon-based material and the binder are necessary for different silicon-based materials to obtain good rate characteristics, cycle characteristics, and low cell expansion. Different types of materials have large differences in the Li content in the electrode pieces, and when the silicon-based material is SiO or lithium-containing SiO, the Li content in the negative electrode piece is high.

[0072] As can be seen by comparing Examples 1, 18, 19 and Comparative Example 4, a smaller I2 / I1 ratio has less impact on the uniformity of dispersion in silicon-based materials and the uniformity of Li, but it has a significant effect on improving the rate characteristics and cycle characteristics of electrochemical equipment and reducing the expansion of electrode assemblies.

[0073] As can be seen by comparing Examples 1, 20, and 21 and Comparative Examples 5 and 6, if Dn10 / Dv50 is too small, the uniformity of dispersion of the silicon-based material deteriorates (M value decreases), the N value also decreases, and the cycle characteristics of the electrochemical apparatus worsen. However, the presence of small-particulate silicon-based material is advantageous in improving the rate characteristics of the electrochemical apparatus. If Dn10 / Dv50 is too large, the uniformity of dispersion of the silicon-based material also deteriorates, and it also causes deterioration of the cycle characteristics, rate characteristics, and cell expansion of the electrochemical apparatus.

[0074] Therefore, uniformity of dispersion of silicon-based materials and binders (uniformity of dispersion of silicon-based materials simultaneously affects the uniformity of dispersion of Li) has a significant effect on improving the rate characteristics and cycle characteristics of electrochemical equipment and reducing the expansion of electrode assemblies.

[0075] The above description is merely a description of preferred embodiments and the technical principles used in the present invention. Those skilled in the art will understand that the scope of disclosure in this application is not limited to technical solutions formed by specific combinations of the above technical features, but should also encompass other technical solutions formed by any combination of the above technical features or equivalent features. For example, solutions formed by substituting the above features with similar functional technical features disclosed herein.

Claims

1. It includes a current collector and an active material layer located on the current collector, The active material layer comprises a silicon-based material, a carbon material, and a binder. If the mass ratios of silicon in the two active material layers located in different places but with the same area are X1 and X2, then X2 ≥ X1, and if M = X1 / X2, then M ≥ 0.

7. If Y1 and Y2 are the mass ratios of lithium in two active material layers located in different places but with the same area, then Y2 ≥ Y1, and if N = Y1 / Y2, then N ≥ 0.

5. If the two active material layers located in different places but having the same area have weight loss rates of Z1 and Z2 respectively in thermogravimetric analysis (TG) at 800°C, then Z2 ≥ Z1, and if K = Z1 / Z2, then K ≥ 0.

7. The silicon-based material has a maximum intensity value in the X-ray diffraction pattern where 2θ is in the range of 20.5° to 21.5°, which corresponds to I １ Let I be the maximum intensity value where 2θ is in the range of 28.0° to 29.0°. ２ Therefore, 0 < I ２ / I １ ≤ 1, The particle size distribution of the silicon-based material satisfies 0.3 ≤ Dn10 / Dv50 ≤ 0.

6. The Dn10 represents the particle size corresponding to the cumulative particle size distribution reaching 10%, and the Dv50 represents the particle size corresponding to the cumulative volume distribution reaching 50%. The negative electrode piece has an average particle size of 500 nm to 30 μm for the silicon-based material.

2. The negative electrode piece according to claim 1, wherein the mass fraction of the silicon-based material in the active material layer is 2% to 80%.

3. The negative electrode piece according to claim 1, wherein the binder comprises a lithium salt.

4. The negative electrode piece according to claim 1, wherein the mass fraction of the binder in the active material layer is 0.5% to 10%.

5. The silicon-based material is SiO ｘ , SiO ２ , SiC, Li ２ SiO ５ , Li ２ SiO ３ , Li ４ SiO ４ , and includes at least one of silicon alloys. The negative electrode piece according to claim 1, wherein 0.6 ≤ x ≤ 1.

5.

6. The aforementioned negative electrode piece is The binder comprises at least one of the following: carboxymethylcellulose, polyacrylic acid, polyvinylpyrrolidone, polyaniline, polyimide, polyamideimide, polysiloxane, polystyrene-butadiene rubber, epoxy resin, polyester resin, polyurethane resin, and polyfluorene. The active material layer further comprises a conductive agent, the conductive agent comprising at least one of single-walled carbon nanotubes, multi-walled carbon nanotubes, vapor-grown carbon fibers, conductive carbon black, acetylene black, conductive graphite, and graphene. The mass fraction of the silicon-based material in the active material layer is 2% to 40%, The negative electrode piece according to claim 1, wherein the carbon material contains graphite, and at least one of the above.

7. It includes a positive electrode piece, a negative electrode piece, and a separator provided between the positive electrode piece and the negative electrode piece. An electrochemical apparatus in which the negative electrode piece is the negative electrode piece described in any one of claims 1 to 6.

8. An electronic apparatus including the electrochemical apparatus described in claim 7.

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