Water droplet estimation device, and fuel cell vehicle

Abstract

To more easily estimate the presence or absence of water droplets in a cathode off-gas flow path of a fuel cell.SOLUTION: A water droplet estimating device in a cathode off-gas flow path according to an embodiment of the present disclosure includes one or more processors, and one or more memories communicatively connected to the one or more processors, and estimates the presence or absence of water droplets on the downstream side of a back pressure valve in the cathode off-gas flow path of a fuel cell, the processor obtains temperature of cathode off gas on the upstream side of the back pressure valve, obtains the temperature of the cathode off gas via a temperature sensor disposed on the downstream side of the back pressure valve, estimates the amount of water in the cathode off gas evaporated before and after the back pressure valve on the basis of the temperature difference between the cathode off gas on the upstream side and downstream side of the back pressure valve, and determines the presence or absence of water droplets on the downstream side of the back pressure valve.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] This disclosure relates to a water droplet estimation technique in the cathode-off gas flow path of a fuel cell system applied, for example, to a vehicle. [Background technology]

[0002] Generally, fuel cell systems generate electrical energy by supplying hydrogen gas to one electrode (fuel electrode) and oxygen gas to the other electrode (air electrode), and then reacting these gases together.

[0003] As a result of the reaction in the fuel cell, the gas emitted from the cathode (also called "cathode-off gas") contains water. Therefore, in order to achieve stable operation of the fuel cell, for example in low-temperature environments, it is important to accurately estimate the presence or absence of water droplets in the cathode-off gas. [Prior art documents] [Patent Documents]

[0004] [Patent Document 1] Japanese Patent Publication No. 2010-272372 [Patent Document 2] Japanese Patent Publication No. 2009-206003 [Overview of the Initiative] [Problems that the invention aims to solve]

[0005] However, not only in the aforementioned patent documents, but also in current technology, the following challenges exist. For example, Patent Document 1 mentioned above estimates the amount of residual water in the discharge pipe based on the gas temperature near the inlet and outlet of the discharge pipe from which cathode-off gas is discharged, as well as the amount of water generated by the fuel cell during power generation. However, due to the influence of the fuel cell's previous operating history and the time lag until the water generated by power generation reaches the exhaust, it has the problem that it cannot be applied to estimating the amount of water droplets generated in the exhaust in real time.

[0006] Furthermore, while Patent Document 2, mentioned above, basically uses the same method as Patent Document 1, installing a temperature sensor and a pressure sensor downstream of the back pressure valve to determine whether the discharged moisture has been sufficiently vaporized, it requires installing a relatively large number of sensors downstream of the back pressure valve, which increases costs and has the problem of not yet being able to provide a simple and accurate method for estimating the presence or absence of water droplets.

[0007] This disclosure has been made in view of the above-mentioned problems as an example, and aims to provide a water droplet estimation device for the cathode-off gas flow path of a fuel cell that can more easily estimate the presence or absence of water droplets in the cathode-off gas flow path. [Means for solving the problem]

[0008] To solve the above problems, the water droplet estimation device for the cathode off-gas flow path of a fuel cell according to the present disclosure comprises one or more processors and one or more memories communicately connected to the one or more processors, and is a water droplet estimation device for estimating the presence or absence of water droplets downstream of a back pressure valve in the cathode off-gas flow path of a fuel cell, wherein the processors acquire the temperature of the cathode off-gas upstream of the back pressure valve, acquire the temperature of the cathode off-gas via a temperature sensor located downstream of the back pressure valve, estimate the amount of moisture in the cathode off-gas evaporated before and after the back pressure valve based on the temperature difference of the cathode off-gas upstream and downstream of the back pressure valve, and determine the presence or absence of water droplets downstream of the back pressure valve. [Effects of the Invention]

[0009] According to this disclosure, it is possible to estimate the presence or absence of water droplets in the cathode-off gas flow path with high temporal resolution and low cost by focusing on the amount of water evaporation before and after the back pressure valve. [Brief explanation of the drawing]

[0010] [Figure 1]It is a block diagram of a fuel cell system mounted on a fuel cell vehicle according to an embodiment. [Figure 2] It is a functional block diagram including a control device (ECU) according to an embodiment. [Figure 3] It is a flowchart showing a water droplet estimation method according to an embodiment.

Mode for Carrying Out the Invention

[0011] Next, a preferred embodiment for implementing the present disclosure will be described. In addition, for configurations other than those described in detail below, elements and configurations related to known fuel cell systems including the above-mentioned patent documents can be appropriately supplemented and implemented.

[0012] <Fuel cell system 100> First, the configuration of the fuel cell system 100 in a preferred embodiment of the present disclosure will be described with reference to FIG. 1. The fuel cell system 100 in the present embodiment is mounted on a known fuel cell vehicle (FCV) equipped with, for example, a hydrogen tank HT and a fuel cell FC. Hereinafter, an FCV equipped with an electric turbocharger ET will be described as an example, but the electric turbocharger ET is not necessarily essential and may be omitted as appropriate.

[0013] The fuel cell system 100 mounted on the FCV includes a control device 10 (ECU) that controls each part of the vehicle, a fuel cell FC controlled by the control device 10, and a gas intake / exhaust system that supplies anode gas and cathode gas to the fuel cell FC.

[0014] As shown in the figure, the fuel cell FC is connected to an anode gas intake system HIS including known valves and the like from the hydrogen tank HT, and an anode off-gas exhaust system HDS including known valves and the like that discharges anode off-gas from the fuel cell FC, respectively. Further, the fuel cell FC is connected to various known electrical modules EM such as a DC / DC converter, an inverter, a battery, or an electric motor.

[0015] A current sensor AM is provided in the circuit between this electrical module EM and the fuel cell FC, making it possible to measure the current flowing through the fuel cell FC. The voltage generated by the fuel cell FC is detected by a known voltmeter (not shown). In addition, a known coolant system WP through which coolant flows for the purpose of cooling the fuel cell FC is connected to the fuel cell FC in this embodiment.

[0016] Furthermore, the structural configuration of the anode (fuel) gas intake and exhaust system, the configuration and connection configuration of the electrical module EM including the DC / DC converter and battery, and the piping configuration of the coolant system WP are not limited to the configuration shown in Figure 1, and various known installation examples exemplified in the above-mentioned patent documents can be applied without departing from the spirit of this disclosure.

[0017] [Cathode gas system] Next, the structure of the intake and exhaust systems for the cathode gas of the fuel cell (FC) in this embodiment will be described in detail. As shown in Figure 1, the cathode gas intake system (AIS) that supplies oxygen gas (air containing oxygen) to the fuel cell (FC) comprises a known air filter (AF) that takes in air, a known electric turbocharger (ET) that compresses the air taken in by the air filter (AF), and a known intercooler (I / C) that cools the compressed air whose temperature has risen due to compression by the electric turbocharger (ET).

[0018] Furthermore, a known mass flow sensor FM is installed in the piping between the air filter AF and the electric turbocharger ET, making it possible to measure the mass flow rate of the air supplied to the fuel cell FC. As such a mass flow sensor FM, various known mass flow sensors suitable for FCVs can be appropriately applied, such as Karman vortex flow meters and thermal mass flow meters.

[0019] Furthermore, a known pressure sensor PM is installed in the piping between the intercooler I / C and the fuel cell FC, making it possible to measure the inlet pressure of the air supplied to the fuel cell FC. Thus, the pressure of the air supplied to the oxygen electrode of the fuel cell FC is detected by the pressure sensor PM installed near the inlet of the oxygen electrode 21 in the fuel cell FC, and the opening degree of the back pressure valve BPV, described later, is controlled by the control device 10 so that the detected air pressure becomes a predetermined pressure.

[0020] On the other hand, as shown in the figure, the cathode off-gas exhaust system ADS, which exhausts the off-gas (cathode off-gas) discharged from the fuel cell FC, is equipped with a known back pressure valve BPV for adjusting the back pressure of the cathode off-gas discharged from the fuel cell FC. The cathode off-gas discharged from the back pressure valve BPV flows into the electric turbocharger ET described above and is then released to the outside. The back pressure valve BPV in this embodiment is equipped with a known opening degree sensor VS capable of detecting the valve opening degree.

[0021] Furthermore, as can be seen from the figure, a known first temperature sensor T is located upstream (inlet) of the back pressure valve BPV in the cathode-off gas exhaust system ADS, capable of detecting the temperature of the cathode-off gas before it passes through the back pressure valve BPV. A A sensor M is provided. In addition, a known second temperature sensor T capable of detecting the temperature of the cathode off gas after it has passed through the back pressure valve BPV is provided on the downstream (outlet) side of the back pressure valve BPV in the cathode off gas exhaust system ADS. B M is provided.

[0022] The control device 10, which will be described later, uses these first temperature sensors T A M, 2nd temperature sensor T B The temperature before and after the back pressure valve (BPV) and the opening degree of the back pressure valve (BPV) can be detected via the M and VS sensors, respectively.

[0023] As described above, this embodiment shows a cathode gas intake and exhaust system via an electric turbocharger ET, but the disclosure is not limited to this form. That is, an electric blower may be used instead of the electric turbocharger ET to supply air taken in from the air filter AF to the fuel cell FC without compression.

[0024] Furthermore, although humidifiers and the like are omitted in this embodiment, known humidifiers and the like that humidify the cathode gas supplied to the fuel cell FC may be added as appropriate. As for the manner in which the air supplied to the fuel cell FC is humidified, for example, a water vapor exchange membrane that reuses moisture in the exhausted air may be used, or various known devices such as membrane humidifiers and sprayers that supply moisture such as pure water to the air may be used.

[0025] [Control device 10] Next, with reference to Figure 2, the configuration of the control device 10 in the fuel cell system 100 of this embodiment will be described. As shown in Figure 2, the control device 10 of this embodiment functions as a water droplet estimation device that estimates the presence or absence of water droplets downstream of the back pressure valve BPV in the cathode-off gas flow path of the fuel cell FC described above.

[0026] More specifically, the control device 10 of this embodiment is composed of a mass flow rate value measurement unit 11, a pressure measurement unit 12, an air temperature acquisition unit 13, a saturated water vapor amount acquisition unit 14, an expansion rate estimation unit 15, a water vapor flow rate estimation unit 16, a water droplet presence determination unit 17, a water droplet adjustment unit 18, and a notification control unit 19, among others. A specific example of such a control device 10 is a known computer device comprising one or more processors configured with known CPUs and one or more memories communicated to these one or more processors.

[0027] The control device 10 in this embodiment may be configured to have a function of controlling the entire fuel cell system 100 described above. As shown in the figure, the control device 10 of this embodiment may also be configured to connect to a known external network NET, such as the Internet, via a communication device 40. Examples of such a communication device 40 include known in-vehicle communication equipment that has the function of communicating information between the FCV and, for example, an external server. Furthermore, the external network NET is not limited to the Internet as described above, but also includes, for example, known information communication networks that can send and receive various types of information between vehicles via wireless communication.

[0028] Furthermore, the control device 10 is configured to receive various signals from sensors 20 mounted on the FCV. An example of such sensors 20 is the first temperature sensor T mentioned above. A M, 2nd temperature sensor T B In addition to the M and opening degree sensor VS, various other known on-board sensors such as outside temperature sensors and vehicle speed sensors that are normally installed in vehicles can be exemplified. Furthermore, the control device 10 is configured to communicate with known navigation devices 30, speakers SP and displays DP, which are respectively installed in the FCV.

[0029] The mass flow rate measurement unit 11 has the function of measuring the mass flow rate in the intake air of the fuel cell FC via the mass flow sensor FM described above. In this embodiment, the mass flow rate of the cathode gas is measured directly using the mass flow sensor FM, but it is also possible to measure the volume flow rate using a known volume flow sensor and then convert it to a mass flow rate using a known method.

[0030] The pressure measurement unit 12 has the function of measuring the gas pressure near the cathode gas flow path inlet to the fuel cell FC via the pressure sensor PM described above. The air temperature acquisition unit 13 uses the first temperature sensor T described above. A The M has the function of measuring the temperature of the cathode off gas at the back pressure valve inlet (i.e., upstream of the back pressure valve BPV) in the cathode off gas flow path of the fuel cell FC. In addition, the air temperature acquisition unit 13 has the function of measuring the temperature of the cathode off gas at the back pressure valve inlet (i.e., upstream of the back pressure valve BPV) via the second temperature sensor T described above. BIt has a function of measuring the temperature of the cathode off-gas at the back-pressure valve outlet (i.e., the downstream side of the back-pressure valve BPV) in the cathode off-gas flow path of the fuel cell FC via M.

[0031] In this embodiment, the first temperature sensor T A measures the cathode off-gas temperature before the back-pressure valve via M, but the present disclosure is not limited to this aspect. For example, the air temperature acquisition unit 13 of the control device 10 may estimate the cathode off-gas temperature at the back-pressure valve inlet based on the temperature of the coolant liquid (cooling water) immediately after flowing out of the fuel cell FC instead of M. This is because the temperature of the cooling water immediately after being discharged from the fuel cell FC can be regarded as being approximately equivalent to the temperature of the cathode off-gas. In such a case, the installation of the first temperature sensor T A M can be omitted, which can contribute to further cost reduction of the fuel cell system 100. A

[0032] The saturated water vapor amount acquisition unit 14 has a function of acquiring the saturated water vapor amount at a predetermined temperature from the saturated water vapor curve data pre-stored in a storage device MD (such as a known memory, HDD, or SSD) electrically connected to the control device 10. The saturated water vapor curve data stored in the storage device MD may have a data structure defined based on a known conversion formula such as the Tetens formula or the Wagner formula, for example, the relationship between the saturated water vapor amount and the air temperature (temperature).

[0033] In addition, in this embodiment, an example where the above-mentioned saturated water vapor curve data is stored in the storage device MD has been described, but the present disclosure is not limited to this form. That is, for example, the saturated water vapor curve data may be stored as a database in an external server such as the cloud, and the saturated water vapor amount acquisition unit 14 may be configured to be able to access the database of the external server via the communication device 40 and the external network NET.

[0034] ​The expansion rate estimation unit 15 has the function of estimating the expansion rate of the cathode-off gas that exits the back pressure valve BPV. More specifically, the expansion rate estimation unit 15 of this embodiment estimates the expansion rate of the cathode-off gas that exits the back pressure valve BPV based on the cathode gas inlet flow rate measured by the mass flow sensor FM, the valve opening of the back pressure valve BPV measured by the opening sensor VS, and the cathode gas inlet pressure measured by the pressure sensor PM (details will be described later).

[0035] The water vapor flow rate estimation unit 16 has the function of estimating the water vapor flow rate evaporated when the cathode-off gas emitted from the fuel cell FC passes through the back pressure valve BPV, using a method described later. The water droplet presence determination unit 17 has the function of determining whether or not water droplets are present on the downstream (outlet) side of the back pressure valve BPV, based on the water vapor flow rate estimated by the water vapor flow rate estimation unit 16 described above and the temperature difference of the cathode off gas before and after the back pressure valve BPV. More specifically, the water droplet presence determination unit 17 of this embodiment determines that all water droplets have evaporated when passing through the back pressure valve if the amount of water vapor evaporated when the cathode off gas passes through the back pressure valve is sufficiently small, while determining that water droplets have not completely evaporated and remain when the amount of water vapor evaporated when passing through the back pressure valve is large (i.e., close to the determination threshold described later). Regarding the determination method using the above-mentioned determination threshold by the water droplet presence determination unit 17, theoretically it is preferable to determine that water droplets remain when the result is equal to the above-mentioned determination threshold. However, considering the accuracy of the sensor, in this embodiment, the criterion is "close to the determination threshold" (the degree of this "closeness" will be described later using specific numerical values). When the above-mentioned theoretical determination method is adopted, the water droplet presence determination unit 17 may determine that no water droplets exist if the measurement result is below the determination threshold, and that there has been some kind of error (such as a measurement error or calculation error) if the measurement result is above the determination threshold.

[0036] The water droplet adjustment unit 18 has the function of changing the operating state of the fuel cell FC to reduce the amount of water droplets when the water droplet presence determination unit 17 determines that water droplets are present on the downstream (outlet) side of the back pressure valve BPV. As an example, the water droplet adjustment unit 18 in this embodiment may perform control to heat the fuel cell FC to raise its operating temperature, or control to increase the flow rate of gas flowing into the fuel cell FC.

[0037] The notification control unit 19 has the function of controlling the notification via the speaker SP and display DP described above. For example, the notification control unit 19 can notify the status of the fuel cell FC via the speaker SP or display DP based on the determination result of the water droplet presence determination unit 17. This allows, for example, the owner of a fuel cell vehicle to foresee malfunctions of the fuel cell FC caused by the presence of water droplets in the cathode-off gas flow path, and to take necessary measures such as repairs and inspections as quickly as possible.

[0038] <Method for estimating exhaust humidity> Next, with reference to Figure 3 as appropriate, we will explain the method for estimating the presence or absence of water droplets downstream of the back pressure valve in the cathode-off gas flow path, which is performed by the control device 10 of the fuel cell system 100. Here, we will first outline the mechanism for estimating the presence or absence of water droplets downstream of the back pressure valve in this disclosure. Specifically, the cathode off-gas discharged from the fuel cell FC undergoes a state change of throttling adiabatic expansion (i.e., expansion at isenthalpy) when it passes through the back pressure valve BPV described above. At this time, if off-gas containing water droplets flows into the inlet of the back pressure valve BPV, the pressure decreases and the volume expands as it passes through the back pressure valve BPV. As the off-gas's pressure decreases and its volume expands, the amount of saturated water vapor increases by the amount of this change, causing the water droplets to evaporate, and the sensible heat decreases by the amount of the heat of vaporization, resulting in a decrease in temperature. Therefore, the temperature change ΔT when a cathode-off gas containing water droplets passes through the back pressure valve BPV can be expressed by the following equation 1.

[0039] (Formula 1) JPEG0007841914000001.jpg22165

[0040] However, in equation 1, "Δf H2O,g "The difference in water vapor flow rate before and after the back pressure valve BPV is "ΔH H2O,l→g " is the heat of vaporization of water, "ΔH loss "The enthalpy loss in the back pressure valve BPV is f all " is the total flow rate of the fluid (off-gas) passing through the back pressure valve BPV. "Cp" represents the specific heat of the fluid (off-gas) at the outlet of the back pressure valve (BPV). "ΔT" represents the temperature difference of the fluid (off-gas) before and after the back pressure valve BPV. They are shown respectively.

[0041] Based on the findings of this disclosure, in this embodiment, the calculated amount of evaporated water when passing through the back pressure valve, which is derived from calculations as follows, is compared with the measured amount of evaporated water based on the temperature difference measured by sensors before and after the back pressure valve, and the measured amount of evaporated water (Δf below) is compared with the calculated amount of evaporated water (Δf below) max Whether or not the value is close to ) is used to determine whether water droplets remain without evaporating when the cathode-off gas passes through the back pressure valve BPV.

[0042] More specifically, as shown in Figure 3, in step 1, the control device 10 first acquires the following state information on the upstream (inlet) side of the back pressure valve BPV of the fuel cell FC. That is, the air temperature acquisition unit 13 of the control device 10 acquires, for example, the first temperature sensor T mentioned above. AThe temperature of the cathode-off gas at the back pressure valve BPV inlet is obtained via M and the coolant liquid temperature. Similarly, the mass flow rate measurement unit 11 and pressure measurement unit 12 of the control device 10 obtain the flow rate value and pressure value (absolute pressure) of the cathode-off gas at the upstream (inlet) side of the back pressure valve BPV, respectively, based on, for example, a flow sensor FM, a current sensor AM, and a pressure sensor PM. As a result, the control device 10 obtains information such as, for example, that the pressure at the upstream (inlet) side of the back pressure valve BPV is 250 kPa, a mass flow rate of the cathode-off gas is 2.8 mol / s (this does not include water vapor or oxygen consumed in power generation), and the temperature is 80°C.

[0043] In the following step 2, the control device 10 acquires the following state information on the downstream (outlet) side of the back pressure valve BPV of the fuel cell FC. That is, the air temperature acquisition unit 13 of the control device 10 acquires, for example, the second temperature sensor T mentioned above. B The temperature of the cathode-off gas on the downstream (outlet) side of the back pressure valve BPV is obtained via M. As a result, the control device 10 obtains information that, for example, the temperature of the gas on the downstream (outlet) side of the back pressure valve BPV is 69.2°C.

[0044] Next, the control device 10 estimates the amount of moisture in the cathode-off gas evaporated before and after the back pressure valve based on the temperature difference between the cathode-off gas on the upstream and downstream sides of the back pressure valve BPV, and determines whether or not there are water droplets on the downstream side (outlet) of the back pressure valve BPV, as described below.

[0045] Specifically, in step 3, the control device 10 estimates the amount of water vapor evaporated when it passes through the back pressure valve BPV using the following method. In other words, the steam flow rate estimation unit 16 of the control device 10 first estimates the steam flow rate f on the upstream (inlet) side of the back pressure valve BPV. in The following is estimated. Here, the pressure (250 kPa, a), mass flow rate (2.8 mol / s), and temperature (80°C) on the upstream (inlet) side of the back pressure valve BPV were obtained in step 1, so the water vapor flow rate estimation unit 16 estimates the saturated water vapor amount at 80°C (292 g / cm³) obtained via the saturated water vapor amount acquisition unit 14. 3Based on this, the water vapor flow rate f on the upstream (inlet) side of the back pressure valve BPV is as shown in Equation 2 below. in It is estimated to be "0.52 mol / s".

[0046] (Formula 2) JPEG0007841914000002.jpg20164

[0047] Next, the expansion rate estimation unit 15 of the control device 10 estimates the expansion rate at the downstream (outlet) side of the back pressure valve BPV from the total flow rate of off-gas entering the back pressure valve BPV (2.8 mol / s + 0.52 mol / s) obtained above, the valve opening degree obtained via the opening degree sensor VS, and the pressure on the upstream (inlet) side of the back pressure valve BPV (250 kPa, a). As a result, the control device 10 estimates, as an example, that the expansion rate at the downstream (outlet) side of the back pressure valve BPV is "5 / 3". If a known pressure sensor is to be installed downstream of the back pressure valve BPV, the control device 10 may also use the value of that pressure sensor to estimate the expansion rate as described above.

[0048] Then, in step 4, the control device 10 estimates whether water droplets are present on the downstream (outlet) side of the back pressure valve BPV, for example, by the method described below. In other words, the water droplet presence determination unit 17 of the control device 10 assumes that the humidity on the downstream (outlet) side of the back pressure valve BPV is 100%, and considers a known calculation formula to determine the water vapor flow rate f on the downstream (outlet) side of the back pressure valve BPV. out The theoretical maximum value f out, max This is estimated as shown in Equation 3 below. In Equation 3 below, "e(T)" is the saturated vapor pressure formula based on the well-known Tetens equation.

[0049] Formula (3) JPEG0007841914000003.jpg21155

[0050] On the other hand, for the sake of simplifying the calculation, the enthalpy loss (ΔH) in the back pressure valve BPV in Equation 1 above is used. loss If we consider ) to be zero, the maximum water vapor flow rate that can be evaporated before and after the back pressure valve BPV is Δf maxThis can be approximated by the following equation 4.

[0051] (Formula 4) JPEG0007841914000004.jpg31144

[0052] Furthermore, the steam flow rate on the downstream (outlet) side of the back pressure valve BPV is equal to the steam flow rate f on the upstream (inlet) side of the back pressure valve BPV. in It can also be expressed as shown in equation 5 below using .

[0053] Formula (5) JPEG0007841914000005.jpg23154

[0054] Therefore, the control device 10 determines that the total flow rate (fall) of the fluid (off-gas) passing through the back pressure valve BPV is "2.8+ 0.52 = 3.32 Since mol / s = 0.096 kg / s, the specific heat of the fluid at the outlet side of the back pressure valve BPV is set to "Cp = 1.009 kJ / kg·K", and the heat of vaporization of water is set to "ΔHH2O, l→g = 41.7 kJ / mol·K", and ΔT is calculated based on equations 3, 4, and 5. In this example, ΔT ≈ 10.4°C, and the control device 10 calculates the above-mentioned maximum value Δfmax ≈ 0.024 kg / s.

[0055] Next, the water droplet presence detection unit 17 of the control device 10 calculates that the measured water vapor flow rate Δf is "0.025 kg / s" according to the following equation 6, since the measured temperature difference is 10.8°C (80°C - 69.2°C).

[0056] (Formula 6) JPEG0007841914000006.jpg21147

[0057] The water droplet presence determination unit 17 of the control device 10 then determines the measured water vapor flow rate Δf(0.025) and the calculated maximum value of evaporated water vapor Δf max By comparing (0.024), Δf is Δf maxWhen the value is close to Δf, it is determined that water droplets remain on the downstream (outlet) side of the back pressure valve BPV, and Δf is close to Δf max If the value is smaller, it is assumed that all the water droplets have evaporated on the downstream (outlet) side of the back pressure valve (BPV). Note that Δf is Δf max The threshold for determining whether a value is close to a certain value can be appropriately set through experiments or simulations, for example, by setting the difference between the two values ​​to less than 0.01.

[0058] As described above, the control device 10 of this embodiment determines the presence of water droplets by whether the estimated amount of moisture in the off-gas evaporated before and after the back pressure valve BPV is close to the maximum amount of moisture that can evaporate when passing through the back pressure valve, calculated using the fluid pressure, air flow rate, air temperature, and valve opening at the upstream (inlet) of the back pressure valve BPV. However, this disclosure is not limited to the above form, and for example, among the multiple parameters described above, the valve opening may be replaced with a correlation value with other parameters and omitted. In other words, the control device 10 may calculate the maximum amount of moisture described above using the fluid pressure, air flow rate, air temperature, and valve opening at the upstream (inlet) of the back pressure valve BPV, and at least one of their correlation values. Furthermore, the control device 10 may treat the molecular weight and specific heat of air as values ​​that fluctuate in accordance with the actual composition ratio of the air.

[0059] Then, if it is determined in step 4 that water droplets are present on the downstream (outlet) side of the back pressure valve BPV, in the following step 5, the water droplet adjustment unit 18 of the control device 10 changes the operating state of the fuel cell FC using the method exemplified above to adjust the amount of water droplets on the downstream (outlet) side of the back pressure valve BPV.

[0060] After performing the adjustment of the amount of water droplets as described above in step 5, in the following step 6, the control device 10 determines whether or not the fuel cell FC is showing a tendency to dry out. There are no particular restrictions on the specific method for determining the drying tendency of the fuel cell FC, as long as it does not deviate from the spirit of this disclosure. For example, various known technologies such as the determination methods disclosed in Japanese Patent Application Publication No. 2007-012571 and Japanese Patent Application Publication No. 2015-095305 may be applied.

[0061] Then, in step 6, if the control device 10 determines that the fuel cell FC is prone to drying out, in the following step 7, it interrupts the adjustment of the amount of water droplets by the water droplet adjustment unit 18 or reduces the degree of change in the operating state described above to suppress the reduction of the amount of water droplets. In other words, the control device 10 of this embodiment determines whether or not the fuel cell FC is prone to drying out, and if it determines that the fuel cell FC is prone to drying out, it restricts the control to reduce water droplets downstream of the back pressure valve BPV. On the other hand, if the control device 10 determines in step 6 that the fuel cell FC is not prone to drying out, it proceeds to the following step 8.

[0062] In step 8, the control device 10 determines whether or not the water droplets present on the downstream (outlet) side of the back pressure valve BPV have evaporated. Specifically, after performing the process to reduce the water droplets as described in step 5, the control device 10 recalculates the amount of water vapor in the off-gas that evaporated before and after the back pressure valve BPV using the method described above. The control device 10 then determines the increase or decrease in the amount of water vapor evaporated when passing through the back pressure valve, and the above Δf max If the level falls below a certain point, it is assumed that all the water droplets have evaporated.

[0063] If it is determined in step 8 that the water droplets have not yet evaporated, the control device 10 returns to step 5 and repeats the water droplet adjustment process described above. On the other hand, if it is determined in step 8 that the water droplets have evaporated, in the following step 9, the control device 10 determines whether or not the fuel cell vehicle system has been turned OFF. If the fuel cell vehicle system has not been turned OFF in step 9, the control device 10 returns to step 1 and executes the above process again.

[0064] According to the fuel cell system and water droplet estimation method of this embodiment described above, it is possible to estimate the presence or absence of water droplets in the cathode-off gas flow path with high accuracy and low cost by focusing on the amount of water evaporation before and after the back pressure valve. While preferred embodiments of the present disclosure have been described in detail above with reference to the attached drawings, the present disclosure is not limited to such examples. It is obvious to any person with ordinary skill in the art to which the present disclosure pertains to attempting further modifications to these embodiments and variations within the scope of the technical idea set forth in the claims, and such modifications will naturally fall within the technical scope of the present disclosure. [Explanation of Symbols]

[0065] 100 control systems 10 Control device FC fuel cell BPV back pressure valve

Claims

1. One or more processors, One or more memories that are communicably connected to one or more of the aforementioned processors, A water droplet estimation device equipped with a water droplet estimation device for estimating the presence or absence of water droplets downstream of a back pressure valve in the cathode off-gas flow path of a fuel cell, The aforementioned processor, The temperature of the cathode-off gas upstream of the back pressure valve is obtained. The temperature of the cathode-off gas is obtained via a temperature sensor located downstream of the back pressure valve. Based on the temperature difference of the cathode off gas on the upstream and downstream sides of the back pressure valve, Let "Δf H2O,g" be the difference in water vapor flow rate before and after the back pressure valve. Let "ΔH H2O,l→g" be the heat of vaporization of water. Let "ΔH loss" be the enthalpy loss in the back pressure valve. "f all" is defined as the total flow rate of the cathode-off gas passing through the back pressure valve. Let "Cp" be the specific heat of the cathode-off gas at the outlet of the back pressure valve. When "ΔT" is defined as the temperature difference of the cathode-off gas before and after the back pressure valve, The amount of moisture in the cathode-off gas evaporated before and after the back pressure valve is estimated according to the following formula (1), and the presence or absence of water droplets downstream of the back pressure valve is determined. A device for estimating water droplets in the cathode-off gas flow path of a fuel cell. (Formula 1):

2. The aforementioned processor, The presence of water droplets is determined by whether the estimated amount of moisture in the cathode-off gas evaporated before and after the back pressure valve is close to the maximum amount of moisture that can evaporate when passing through the back pressure valve, calculated using the inlet air pressure, inlet air flow rate, inlet air temperature, and opening degree of the back pressure valve, and at least one of their correlation values. The water droplet estimation device according to claim 1.

3. The aforementioned processor, Determine whether the fuel cell is prone to drying out. When it is determined that there is a tendency for the water to dry out, the control to reduce water droplets downstream of the back pressure valve is restricted. The water droplet estimation device according to claim 1.

4. Fuel cells and A water droplet estimation device according to claim 1 for estimating the presence or absence of water droplets downstream of a back pressure valve in the cathode off-gas flow path of the fuel cell, Fuel cell vehicles, including those mentioned above.

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