Air purification device

Abstract

To provide a space purification device that suppresses strong alkalization of an aqueous solution stored in a supply tank after electrolysis, thereby improving safety.SOLUTION: There is provided a space purification device 1 comprising an electrolytic bath 10 for retaining a first aqueous solution L1, a supply tank 20 for retaining a second aqueous solution L2 and supplying chloride ions to the first aqueous solution L1, and a negative ion exchange membrane 30 that connects the electrolytic bath 10 and the supply tank 20 in a manner enabling permeation by negative ions. The second aqueous solution L2 is a metal chloride aqueous solution. Membrane electrolysis is performed, so that the chloride ions contained in the second aqueous solution L2 retained in the supply tank 20 permeate through the negative ion exchange membrane 30 and are supplied to the first aqueous solution L1 retained in the electrolytic bath 10 so as to supplement chloride ions contained in the first aqueous solution L1, which is reduced by membraneless electrolysis. The metal ions contained in the second aqueous solution L2 and hydroxide ions generated by the membrane electrolysis are reacted within the supply tank 20 to form precipitate of a metal hydroxide.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] This invention relates to a space purification device. [Background technology]

[0002] Patent Document 1 discloses an air purification device that uses hypochlorous acid produced by electrolyzing an aqueous sodium chloride solution to remove bacteria, fungi, viruses, odors, and other substances contained in the air. [Prior art documents] [Patent Documents]

[0003] [Patent Document 1] Japanese Patent Publication No. 2019-174032 [Overview of the Initiative] [Problems that the invention aims to solve]

[0004] Incidentally, when generating hypochlorous acid water by electrolysis of a sodium chloride solution in an air purification device, strongly alkaline sodium hydroxide may be produced. When such an air purification device is miniaturized and installed by a contractor at a designated location, it is expected that the contractor may tip over or drop the air purification device when removing it after use or during transportation after removal. In this case, there was a problem that the strongly alkaline sodium hydroxide produced could leak outside the air purification device.

[0005] This invention was made in view of the above problems, and provides a space purification device that suppresses the strong alkalinization of the aqueous solution stored in the supply tank after electrolysis, thereby enhancing safety. [Means for solving the problem]

[0006] The space purification device according to the present invention includes an electrolytic cell for storing a first aqueous solution containing chloride ions and subjecting the first aqueous solution to diaphragm-free electrolysis to generate hypochlorous acid, a supply tank for storing a second aqueous solution containing chloride ions at a higher concentration than the first aqueous solution and supplying chloride ions to the first aqueous solution, and an anion exchange membrane that connects the electrolytic cell and the supply tank so as to be permeable to anions based on the voltage applied between the electrolytic cell and the supply tank. Air introduced from the external space flows through the electrolytic cell and is discharged into the external space together with hypochlorous acid, thereby purifying the space in the external space. The second aqueous solution is an aqueous metal chloride solution containing metal ions and chloride ions, and by performing diaphragm electrolysis through the anion exchange membrane, the chloride ions contained in the first aqueous solution decreased by diaphragm-free electrolysis are supplemented. The chloride ions contained in the second aqueous solution stored in the supply tank are allowed to permeate through the anion exchange membrane and supplied to the first aqueous solution stored in the electrolytic cell. In the supply tank, the metal ions contained in the second aqueous solution are reacted with the hydroxide ions generated by diaphragm electrolysis to form a precipitate of a metal hydroxide.

Advantages of the Invention

[0007] According to the present invention, it is possible to provide a space purification device that suppresses strong alkalization after electrolysis of an aqueous solution and enhances safety.

Brief Description of the Drawings

[0008] [Figure 1] FIG. 1 is a perspective view showing a space purification device according to an embodiment. [Figure 2] FIG. 2 is a front partial cross-sectional view showing the space purification device of FIG. 1. [Figure 3] FIG. 3 is a list of reaction formulas occurring in the diaphragm-free electrolysis section. [Figure 4] FIG. 4 is a reaction formula including the ratio of the current flowing through the diaphragm-free electrolysis section and the current flowing through the diaphragm electrolysis section. [Figure 5] FIG. 5 is a list of reaction formulas occurring in the diaphragm electrolysis section. [Figure 6] FIG. 6 is a block diagram showing a current control unit according to an embodiment. [Modes for carrying out the invention]

[0009] Hereinafter, specific embodiments of the present invention will be described in detail with reference to the drawings. Note that the right-handed xyz coordinate system shown in the diagram is for convenience in explaining the positional relationships of the components. Unless otherwise specified, the positive z-axis direction is vertically upward. Also, the xy-plane is the horizontal plane and is consistent across all drawings.

[0010] <Embodiment> Figure 1 is a perspective view showing a schematic of the air purification device 1 according to an embodiment. The air purification device 1 performs electrolysis of a first aqueous solution L1 containing chloride ions in an electrolytic cell 10, which will be described later, to generate and volatilize hypochlorous acid. The air purification device 1 removes bacteria, fungi, viruses, odors, etc., contained in the air in the space outside the air purification device 1 by releasing the volatilized hypochlorous acid into the space outside the housing B that constitutes the air purification device 1.

[0011] The air purification device 1 is installed indoors. Preferably, the installation location of the air purification device 1 is a place where airflow can occur. More specifically, installation locations for the air purification device 1 include, for example, the inside of an air conditioner, around a fan, around a circulator, around a ceiling fan, inside a humidifier, inside an air purifier, etc.

[0012] The air purification device 1 comprises a housing B, an electrolytic cell 10, a supply tank 20, an anion exchange membrane 30, and a current control unit 40.

[0013] The housing B houses the electrolytic cell 10, the supply tank 20, the anion exchange membrane 30, and the current control unit 40. In other words, the air purification device 1 may be an integrated unit within the housing B. The shape of the housing B can be appropriately changed depending on the location where the air purification device 1 is installed, and may be, for example, rectangular or cylindrical. The air purification device 1 is small enough to be housed inside, for example, an air conditioner, and is approximately 10 cm × 7 cm × 4 cm.

[0014] The electrolytic cell 10 is a tank for storing a first aqueous solution L1 containing chloride ions. The electrolytic cell 10 has a box-like shape, for example. Figure 1 shows the electrolytic cell 10 with the first aqueous solution L1 stored inside. The first aqueous solution L1 is, for example, an aqueous solution in which an electrically conductive electrolyte is dissolved, and specifically, a dilute chloride aqueous solution having a predetermined chloride ion concentration. More specifically, the first aqueous solution L1 is, for example, a sodium chloride aqueous solution or a dilute potassium chloride aqueous solution.

[0015] The "predetermined chloride ion concentration" of the first aqueous solution L1 includes both a chloride ion concentration having a predetermined numerical range and a chloride ion concentration having a predetermined numerical value. More specifically, the chloride ion concentration of the first aqueous solution L1 may be, for example, 1 g / L to 50 g / L, or 10 g / L. In other words, for example, the mass percentage concentration of a dilute sodium chloride aqueous solution or a dilute potassium chloride aqueous solution may be 0.1% to 5%, or 5%. By setting the predetermined chloride ion concentration to the said numerical range or numerical value, it is possible to generate hypochlorous acid necessary for air purification while simultaneously suppressing the generation of chlorine that may be generated.

[0016] The supply tank 20 is a tank for storing the second aqueous solution L2 containing chloride ions. The chloride ions contained in the second aqueous solution L2 in the supply tank 20 permeate the anion exchange membrane 30 and are supplied to the first aqueous solution L1 in the electrolytic cell 10.

[0017] The supply tank 20 is a tank for storing the second aqueous solution L2 containing chloride ions and supplying chloride ions to the first aqueous solution L1. Figure 1 shows the state in which the second aqueous solution L2 is stored in the supply tank 20. The chloride ion concentration of the second aqueous solution L2 is higher than that of the first aqueous solution L1. As the solute of the second aqueous solution L2, it is preferable to use a substance that has a GHS (Globally Harmonized System of Classification and Labelling of Chemicals) classification that is as safe as sodium chloride in order to ensure safety in the event of leakage. Specifically, the second aqueous solution L2 is an aqueous metal chloride solution containing metal ions and chloride ions. By performing diaphragm electrolysis on the second aqueous solution L2, as described later, the chloride ions contained in the second aqueous solution L2 react with hydroxide ions produced by diaphragm electrolysis to form a precipitate of metal hydroxide. Preferably, the second aqueous solution L2 is a high-concentration magnesium chloride aqueous solution or a saturated magnesium chloride aqueous solution. When using an aqueous magnesium chloride solution as the second aqueous solution L2, the mass percentage concentration of the aqueous magnesium chloride solution is, for example, 10% to 35%.

[0018] When considering continuous use of the electrolytic cell 10 and the supply tank 20 for 8 hours a day for one year, it is preferable that the volume of the supply tank 20 be approximately 12 times or more than the volume of the electrolytic cell 10. With this volume ratio, the supply tank 20 can store a second aqueous solution L2 containing a sufficient amount of chloride ions to supply the first aqueous solution L1 in the electrolytic cell 10. Therefore, chloride ions can be stably supplied from the second aqueous solution L2 stored in the supply tank 20 to the first aqueous solution L1 stored in the electrolytic cell 10. The amount of first aqueous solution L1 stored in the electrolytic cell 10 is, for example, about 2 to 10 mL.

[0019] The anion exchange membrane 30 is a membrane-like member that connects the electrolytic cell 10 and the supply tank 20 in a way that allows anions to pass through, based on the voltage applied between the electrolytic cell 10 and the supply tank 20. More specifically, when a voltage is applied between the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21, as described later, diaphragm electrolysis is performed through the anion exchange membrane 30. Through diaphragm electrolysis using the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21, chloride ions contained in the second aqueous solution L2 permeate the anion exchange membrane 30 and are supplied to the first aqueous solution L1 (indicated by the negative x-axis direction and thick black arrow).

[0020] The anion exchange membrane 30 in this embodiment is not an anion exchange membrane of the type that allows anions to permeate by osmosis without using electricity. Furthermore, the anion exchange membrane 30 does not allow sodium ions, which are cations, to permeate. More specifically, when chloride ions contained in the second aqueous solution L2 are supplied to the first aqueous solution L1 by diaphragm electrolysis using the electrolytic cell side anode plate 11 and the supply tank side cathode plate 21, sodium ions, which are cations, do not permeate the anion exchange membrane 30. The anion exchange membrane 30 is, for example, a hydrocarbon-based anion exchange membrane, and includes membranes that have properties such as selective permeability of monovalent anions, alkali resistance, and high temperature resistance.

[0021] The anion exchange membrane 30 is positioned between the electrolytic cell 10 and the supply tank 20. For example, the surface of the electrolytic cell 10 facing the supply tank 20 (yz plane on the positive x-axis side) and the surface of the supply tank 20 facing the electrolytic cell 10 (yz plane on the negative x-axis side) may each be formed by a frame-shaped member. If the surfaces of the electrolytic cell 10 and the supply tank 20 facing each other are formed by a frame-shaped member, the anion exchange membrane 30 may be positioned so as to be fitted into the frame-shaped member.

[0022] The current control unit 40 controls the current used for both non-diaphragm electrolysis and diaphragm electrolysis. More specifically, the current control unit 40 controls the current used for non-diaphragm electrolysis, which is performed using a pair of electrolytic cell-side anodes 11 and electrolytic cell-side cathodes 12 located in the electrolytic cell 10. The current control unit 40 also controls the current used for diaphragm electrolysis, which is performed via an anion exchange membrane 30 using a pair of electrolytic cell-side anodes 11 and supply tank-side cathodes 21 across the electrolytic cell 10 and the supply tank 20. The electrolytic cell-side anodes 11 are used for both non-diaphragm electrolysis and diaphragm electrolysis. It is used. That is, the air purification device 1 according to this embodiment has one anode and two cathodes, for a total of three electrodes. Since the supply tank 20 has only a cathode, chlorine is not generated in the supply tank 20 by the chemical reaction described later.

[0023] The details of each component will be explained in more detail below using Figures 1 and 2. As shown in Figure 1, the electrolytic cell 10 includes an electrolytic cell-side anode 11, an electrolytic cell-side cathode 12, wiring 13, wiring 14, an inlet 15, a mixing space 16, and an outlet 17.

[0024] The electrolytic cell anode 11 and the electrolytic cell cathode 12 are a pair of electrodes used for the electrolysis of the first aqueous solution L1. As shown in Figure 1, there is no diaphragm such as an ion exchange membrane between the electrolytic cell anode 11 and the electrolytic cell cathode 12. In other words, the electrolysis of the first aqueous solution L1 performed using the pair of electrolytic cell anodes 11 and the electrolytic cell cathode 12 is diaphragm-free electrolysis. Hypochlorous acid, which is used for air purification, is produced by the diaphragm-free electrolysis of the first aqueous solution L1 performed using the pair of electrolytic cell anodes 11 and the electrolytic cell cathode 12.

[0025] The electrolytic cell-side anode 11 and the electrolytic cell-side cathode 12 each have a plate-like shape. That is, the electrolytic cell-side anode 11 is an electrolytic cell-side anode plate 11 with a plate-like shape, and the electrolytic cell-side cathode 12 is an electrolytic cell-side cathode plate 12 with a plate-like shape. The plate-like shape includes rectangular and rectangular shapes. Hereafter, the electrolytic cell-side anode 11 will also be referred to as the electrolytic cell-side anode plate 11, and the electrolytic cell-side cathode 12 will also be referred to as the electrolytic cell-side cathode plate 12.

[0026] As an example, let's describe the case where the plate-shaped forms of the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 are rectangular. The electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 are arranged with the shorter side of the rectangle aligned with the vertical direction (z-axis direction). This arrangement suppresses the adhesion of bubbles generated by chemical reactions to both sides of the rectangle of each electrode. Furthermore, compared to the case where the longer side of the rectangle is aligned with the vertical direction (z-axis direction), arranging the shorter side with the shorter side aligned with the vertical direction (z-axis direction) suppresses the adhesion of bubbles generated at the lower part (negative z-axis side) of the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 to the upper part (positive z-axis side) of the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12.

[0027] Furthermore, the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 are arranged with their longitudinal directions in a rectangle aligned with the horizontal direction (y-axis direction). In other words, the rectangular planes (yz-planes) of the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 are arranged opposite each other with a predetermined distance between them. This predetermined distance is suitable for electrolysis performed using a pair of electrolytic cell-side anode plates 11 and electrolytic cell-side cathode plates 12.

[0028] The electrolytic cell-side anode plate 11 includes an electrolytic cell-side anode plate immersion portion 11a and an electrolytic cell-side anode plate protrusion portion 11b. Similarly, the electrolytic cell-side cathode plate 12 includes an electrolytic cell-side cathode plate immersion portion 12a and an electrolytic cell-side cathode plate protrusion portion 12b.

[0029] The electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 are inserted into the electrolytic cell 10 from the outside toward the inside. In Figure 1, as an example, the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12 are inserted horizontally (in the direction of the y axis) from the side of the electrolytic cell 10 (on the xz plane side of the negative y axis). The electrolytic cell-side anode plate immersion portion 11a and the electrolytic cell-side cathode plate immersion portion 12a inserted into the electrolytic cell 10 are located on the inside of the electrolytic cell 10 and are entirely immersed in the first aqueous solution L1. In other words, the first aqueous solution L1 is stored in the electrolytic cell 10 so that the entire electrolytic cell-side anode plate immersion portion 11a and the electrolytic cell-side cathode plate immersion portion 12a are immersed. In other words, the first aqueous solution L1 is stored in the electrolytic cell 10 such that the liquid level S1 of the first aqueous solution L1 is above the upper ends (the ends on the positive z-axis side) of the anode plate immersion portion 11a and the cathode plate immersion portion 12a on the electrolytic cell side.

[0030] The electrolytic cell-side anode plate protrusion 11b and the electrolytic cell-side cathode plate protrusion 12b are located on the outside of the electrolytic cell 10. Wiring 13 and wiring 14 are lines through which current flows. The electrolytic cell-side anode plate protrusion 11b is electrically connected to the current control unit 40 via wiring 13, and the electrolytic cell-side cathode plate protrusion 12b is electrically connected to the current control unit 40 via wiring 14.

[0031] For example, a platinum-iridium titanium electrode, a platinum electrode, a ruthenium titanium electrode, or an iridium titanium oxide electrode may be used as the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12.

[0032] The inlet 15 is an opening for air from the external space of the housing B to flow in. In other words, the inlet 15 is an opening for air from the external space of the air purification device 1 to flow in. In Figure 1, as an example, the inlet 15 is provided on the upper surface of the electrolytic cell 10 (the xy plane on the positive z-axis side), but it is sufficient that it is positioned above the liquid level S1 of the first aqueous solution L1. The shape of the inlet 15 may be cylindrical, as shown in Figure 1, or it may be rectangular. If the upper surface of the electrolytic cell 10 (the surface on the positive z-axis side) is close to the ceiling surface of the housing B, the inlet 15 may be a hole-like opening provided in a part of the upper surface of the electrolytic cell 10. Alternatively, the inlet 15 and the upper surface of the housing B (the surface on the positive z-axis side) may be formed as a single unit.

[0033] The mixing space 16 is a space formed above the electrolytic cell 10 (positive z-axis side) when the first aqueous solution L1 is stored in the electrolytic cell 10. The mixing space 16 is a space for mixing hypochlorous acid produced by membrane-free electrolysis of the first aqueous solution L1 using a pair of electrolytic cell-side anode plates 11 and electrolytic cell-side cathode plates 12 with air from the external space that flows in from the inlet 15. The hypochlorous acid produced by membrane-free electrolysis contains volatilized and gasified hypochlorous acid gas and hypochlorous acid dissolved in the first aqueous solution L1. The hypochlorous acid gas is contained in the air that flows in from the inlet 15 and flows out into the external space from the outlet 17, which will be described later. The hypochlorous acid dissolved in the first aqueous solution L1 flows out into the external space from the outlet 17, which will be described later, by gas-liquid contact with the air that flows in from the inlet 15.

[0034] The outlet 17 is an opening through which the mixed air, which is a mixture of air flowing in from the inlet 15 and hypochlorous acid generated by the non-diaphragmatic electrolysis of the first aqueous solution L1, flows out to the external space of the housing B. In other words, the outlet 17 is an opening through which the mixed air flows out to the external space of the air purification device 1. In Figure 1, the outlet 17 is provided on the upper surface of the electrolytic cell 10 (the xy plane on the positive z-axis side) as an example, similar to the inlet 15, but it is sufficient that it is positioned above the liquid surface of the first aqueous solution L1. The shape of the outlet 17 is the same as that of the inlet 15, and may be cylindrical or rectangular, for example, as shown in Figure 1. If the upper surface of the electrolytic cell 10 (the surface on the positive z-axis side) is close to the ceiling surface of the housing B, the outlet 17 may be a hole-like opening provided in a part of the upper surface of the electrolytic cell 10. Alternatively, the outlet 17 and the upper surface of the housing B (the surface on the positive z-axis side) may be formed as a single unit.

[0035] The inlet 15 and outlet 17 may be equipped with openable / closable or removable covers (not shown). The covers may be kept closed when transporting, moving, or installing the air purification device 1, and may be opened or removed when using the air purification device 1. Although the inlet 15 and outlet 17 are described as separate configurations, the inlet 15 and outlet 17 may each serve as both an inlet and an outlet, depending on the direction of the airflow into the air purification device 1.

[0036] The air containing hypochlorous acid that flows out from outlet 17 into the space outside the air purification device 1 purifies the space outside. In other words, the air containing hypochlorous acid removes bacteria, fungi, viruses, odors, etc., contained in the air outside the enclosure B.

[0037] The supply tank 20 includes a supply tank-side cathode 21, wiring 22, and an outlet 23. The supply tank-side cathode 21 is an electrode used in conjunction with the electrolytic cell-side anode 11 for the electrolysis of the second aqueous solution L2. As shown in 1, an anion exchange membrane 30 is placed between the electrolytic cell anode 11 and the supply tank cathode 21. That is, the electrolysis of the second aqueous solution L2 performed using the pair of electrolytic cell anodes 11 and supply tank cathode 21 is diaphragm electrolysis. In other words, the electrolytic cell anode 11 is used for both non-diaphragm electrolysis and diaphragm electrolysis. Chloride ions are supplied from the second aqueous solution L2 to the first aqueous solution L1 by the diaphragm electrolysis of the second aqueous solution L2 performed using the pair of electrolytic cell anodes 11 and supply tank cathode 21.

[0038] The supply tank side cathode 21 is a supply tank side cathode plate 21 having a plate-like shape. The plate-like shape includes rectangular and rectangular shapes. Hereafter, the supply tank side cathode 21 will also be referred to as the supply tank side cathode plate 21.

[0039] As an example, we will describe the case where the cathode plate 21 on the supply tank side, like the anode plate 11 on the electrolytic cell side, is rectangular in shape. As shown in Figure 1, the cathode plate 21 on the supply tank side has its shorter side aligned with the vertical direction (z-axis direction) of the rectangle. Also, the cathode plate 21 on the supply tank side has its longer side aligned with the horizontal direction (y-axis direction) of the rectangle.

[0040] The electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21 are in close proximity to the anion exchange membrane 30. In this specification, "proximity" includes both the state in which the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21 are close to the anion exchange membrane 30 with a predetermined distance between them, and the state in which the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21 are in contact with the anion exchange membrane 30.

[0041] Let P1 be the plane (yz plane on the positive x-axis side) of the rectangular plate-shaped section of the electrolytic cell-side anode plate 11 on the anion exchange membrane 30 side. Let P2 be the plane (yz plane on the negative x-axis side) of the rectangular plate-shaped section of the supply tank-side cathode plate 21 on the anion exchange membrane 30 side. Planes P1 and P2 are arranged facing each other across the anion exchange membrane 30. This arrangement allows for a uniform electric field to be generated between the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21.

[0042] The electrolytic cell-side anode plate 11 is positioned between the electrolytic cell-side cathode plate 12 and the anion exchange membrane 30. This arrangement allows for keeping the potential difference between the electrolytic cell-side anode plate 11 and the electrolytic cell-side cathode plate 12, and the potential difference between the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21 small.

[0043] The supply tank side cathode plate 21 comprises a supply tank side cathode plate immersion portion 21a and a supply tank side cathode plate protrusion portion 21b. The supply tank side cathode plate 21 is inserted into the electrolytic cell 10 from the outside toward the inside. In Figure 1, as an example, the supply tank side cathode plate 21 is inserted horizontally (in the direction of the y axis) from the side of the electrolytic cell 10 (on the xz plane side on the negative y axis). The supply tank side cathode plate immersion portion 21a inserted into the supply tank 20 is located on the inside side of the supply tank 20 and is entirely immersed in the second aqueous solution L2. In other words, the second aqueous solution L2 is stored in the supply tank 20 such that the entire supply tank side cathode plate immersion portion 21a is immersed. That is, the second aqueous solution L2 is stored in the supply tank 20 such that the liquid level S2 of the second aqueous solution L2 is above the upper end (the end on the positive z axis side) of the supply tank side cathode plate immersion portion 21a.

[0044] As shown in Figure 1, the cathode plate protrusion 21b on the supply tank side is located on the outside of the supply tank 20. The wiring 22 is a wire through which current flows. The cathode plate protrusion 21b on the supply tank side is electrically connected to the current control unit 40 via the wiring 22.

[0045] For example, a platinum-iridium titanium electrode, a platinum electrode, a ruthenium titanium electrode, or an iridium oxide titanium electrode may be used as the cathode plate 21 on the supply tank side.

[0046] The discharge port 23 is an opening for discharging hydrogen gas, generated by the diaphragm electrolysis of the second aqueous solution L2, to the external space of the housing B. The discharge port 23 may be, for example, a check valve. When a check valve is used as the outlet 23, the hydrogen gas inside the supply tank 20 is discharged to the outside space, but the inflow of gases such as air from the outside space can be suppressed. As the diaphragm electrolysis of the second aqueous solution L2 is repeated, hydrogen gas accumulates inside the supply tank 20, and the internal pressure of the supply tank 20 increases. This pressure causes the check valve to open, and the hydrogen gas is discharged to the outside space of the supply tank 20.

[0047] Figure 2 is a front cross-sectional view showing the air purification device 1 of Figure 1. In Figure 2, the housing B shown in Figure 1 is omitted. As shown in Figure 2, the air purification device 1 may further include a water level detection unit 18 and a water supply unit 19. The water level detection unit 18 detects the position of the liquid level S1 in the first aqueous solution L1. The water level detection unit 18 is, for example, a water level sensor. The water level detection unit 18 is positioned above (on the positive z-axis side) the upper ends (the parts on the positive z-axis side) of at least the electrolytic cell side anode plate immersion section 11a, the electrolytic cell side cathode plate immersion section 12a, and the supply tank side cathode plate immersion section 21a.

[0048] The water supply unit 19 supplies water to the electrolytic cell 10 based on the position of the liquid level S1 detected by the water level detection unit 18. More specifically, the water supply unit 19 supplies water to the electrolytic cell 10 so that the water level does not fall below the upper ends (the portion on the positive z-axis side) of the electrolytic cell side anode plate immersion section 11a, the electrolytic cell side cathode plate immersion section 12a, and the supply tank side cathode plate immersion section 21a. The water supply unit 19 may be, for example, a Peltier element that can cool and condense moisture contained in the air into water droplets, or a water tank capable of storing water. The water supply unit 19 only needs to be positioned in a location that can supply water to the electrolytic cell 10, and may be positioned on the upper side, side, or bottom side of the electrolytic cell 10.

[0049] When the air purification device 1 is equipped with a water level detection unit 18 and a water supply unit 19, the electrolytic cell-side anode plate immersion unit 11a and the electrolytic cell-side cathode plate immersion unit 12a can remain immersed in the first aqueous solution L1. Therefore, exposure of the electrolytic cell-side anode plate immersion unit 11a and the electrolytic cell-side cathode plate immersion unit 12a to air as the first aqueous solution L1 decreases can be suppressed, and the electrolysis efficiency of membrane-free electrolysis can be maintained.

[0050] As shown in Figure 2, the air purification device 1 according to this embodiment includes a non-diaphragm electrolytic section E1 and a diaphragm electrolytic section E2. The current control unit 40 can control the chemical reactions occurring in the non-diaphragm electrolytic section E1 and the chemical reactions occurring in the diaphragm electrolytic section E2 by controlling the first current flowing through the non-diaphragm electrolytic section E1 and the second current flowing through the diaphragm electrolytic section E2.

[0051] The diaphragm-free electrolysis unit E1 is provided in the electrolytic cell 10. The diaphragm-free electrolysis unit E1 generates hypochlorous acid by electrolyzing the first aqueous solution L1 without a diaphragm by passing a first current between the electrolytic cell-side anode 11 and the electrolytic cell-side cathode 12. In other words, the diaphragm-free electrolysis unit E1 comprises an electrolytic cell-side anode 11 and an electrolytic cell-side cathode 12.

[0052] The diaphragm electrolysis unit E2 is provided across the electrolytic cell 10 and the supply tank 20. By passing a second current between the electrolytic cell-side anode 11 and the supply tank-side cathode 21, diaphragm electrolysis is performed via the anion exchange membrane 30. In other words, the diaphragm electrolysis unit E2 comprises the electrolytic cell-side anode 11, the supply tank-side cathode 21, and the anion exchange membrane 30.

[0053] Here, we will explain in detail the chemical reactions that occur in the non-diaphragm electrolytic section E1 provided in the electrolytic cell 10 and the chemical reactions that occur in the diaphragm electrolytic section E2 provided across the electrolytic cell 10 and the supply tank 20. The following explanation will describe the case where the first aqueous solution L1 containing chloride ions is a sodium chloride aqueous solution and the second aqueous solution L2 is a magnesium chloride aqueous solution.

[0054] [Diaphragmless electrolysis section E1 (electrolytic cell 10)] Figure 3 shows a list of reaction equations that occur in the non-diaphragm electrolytic section E1. Sodium chloride (NaCl) contained in an aqueous sodium chloride solution reacts with sodium ions (Na) in water. + ) and chloride Ion (Cl - It ionizes into ). When a predetermined voltage is applied to the diaphragm-free electrolytic section E1, current flows, electrons move, and the chemical reaction shown in Figure 3 occurs. • Reaction equation Figure 3(a): Anode 11 on the electrolytic cell side (chlorine generation reaction) At the electrolytic cell anode 11, chloride ions (Cl) ionized in water - ) is an electron (e - It loses its energy and generates chlorine (Cl2). • Reaction equation Figure 3(b): Electrolytic cell side cathode 12 (hydrogen evolution reaction) At the electrolytic cell cathode 12, water (H2O) in the first aqueous solution L1 is converted into electrons (e -receives it, and hydrogen (H2) and hydroxide ions (OH - ) are generated. · Reaction formula diagram 3(c): Electrolytic cell side anode 11 (oxygen generation reaction) In the electrolytic cell side anode 11, electrons (e - ) are taken away from the water (H2O) of the first aqueous solution L1, and oxygen (O2) and hydrogen ions (H + ) are generated. · Reaction formula diagram 3(d): Inside the first aqueous solution L1 (hypochlorous acid generation reaction) In the first aqueous solution L1 of the electrolytic cell 10, the chlorine (Cl2) generated in Fig. 3(a) undergoes a hydrolysis reaction with the water (H2O) of the first aqueous solution L1, and hydrochloric acid (HCl) and hypochlorous acid (HClO) are generated. Hydrochloric acid (HCl) ionizes in an aqueous solution and exists as hydrogen ions (H + ) and chloride ions (Cl - ). · Fig. 3(e): Anion exchange membrane 30 When a voltage is applied to the diaphragm electrolysis section E2 and a current flows, the first aqueous solution L1 stored in the electrolytic cell 10 loses electrons (e - ) due to the reaction. A force to maintain electrical neutrality acts on the first aqueous solution L1 that has lost electrons (e - ), and chloride ions (Cl - ) with a negative charge permeate through the anion exchange membrane 30 from the second aqueous solution L2 stored in the supply tank 20 and are supplied to the first aqueous solution L1 stored in the electrolytic cell 10. In the first aqueous solution L1, it can be said that the electrons (e - ) before the change become chloride ions (Cl - ) after the change. · Reaction formula diagram 3(f): Hypochlorous acid generation reaction (equilibrium reaction formula) The equilibrium reaction formula of the hypochlorous acid generation reaction is shown. Depending on the increase or decrease of Cl - supplied from the second aqueous solution L2, the equilibrium state can shift to the right or to the left. Current control described later is performed so that the Cl - in the electrolytic cell 10 does not apparently increase or decrease. · Formula diagram 3(g): Chloride ion change formula during electrolysis The chlorine (Cl2) produced by reaction equation 3(a) is converted into hydrochloric acid (HCl) and hypochlorous acid (HClO) according to reaction equation 3(d). This can be expressed as a single equation in figure 3(g).

[0055] Figure 4 is a reaction equation that includes the ratio of the current flowing through the non-diaphragm electrolytic section E1 to the current flowing through the diaphragm electrolytic section E2. Here, let "x" be the ratio of the current flowing through the electrolytic cell anode 11 that is used for the chlorine generation reaction in reaction equation Figure 3(a), and let "1-x" be the ratio of the current used for the oxygen generation reaction in reaction equation Figure 3(c). Also, let "y" be the ratio of the current flowing through the electrolytic cell anode 11 that originates from the non-diaphragm electrolytic section E1, and let "1-y" be the ratio of the current originating from the diaphragm electrolytic section E2. Applying the above x and y to reaction equation Figure 3(b)+(c)+(g), and considering the changes shown in Figure 3(e), we obtain reaction equation Figure 4(a).

[0056] When diaphragm-free electrolysis is performed in the diaphragm-free electrolysis section E1, the chloride ions in the electrolytic cell 10 are consumed and thus decrease. However, in the air purification device 1 according to this embodiment, chloride ions are supplied from the second aqueous solution L2 stored in the supply tank 20 to the first aqueous solution L1 stored in the electrolytic cell 10.

[0057] Here, the amount of chloride ions (Cl) consumed by membrane-free electrolysis is transferred from the second aqueous solution L2 stored in the supply tank 20 to the first aqueous solution L1 stored in the electrolytic cell 10. - ) is supplied, and chloride ions (Cl) are supplied in the electrolytic cell 10. - The conditions under which the amount does not appear to increase or decrease are as follows. In this reaction, hypochlorous acid (HClO) volatilizes as a gas and is therefore not shown in reaction equations (b) to (g) in Figure 4. • Reaction equation diagram 4(b): Cl - This shows the conditions under which the apparent value does not increase or decrease. • Equation Figure 4(c): This shows the conditional equations for coefficients x and y, which are derived from the reaction equation Figure 4(b). • Reaction equation diagram 4(d): Substituting equation diagram 4(c) into reaction equation diagram 4(a) results in reaction equation diagram 4(d). • Reaction equation diagram 4(e): Shows a variation of reaction equation diagram 4(d).

[0058] From the reaction equation in Figure 4(e), for example, if two electrons flow through the non-diaphragm electrolytic section E1, one molecule of hypochlorous acid (HClO) is produced. For example, if four electrons flow through the non-diaphragm electrolytic section E1, one molecule of oxygen is produced. For example, if two electrons flow through the non-diaphragm electrolytic section E1, one molecule of hydrogen is produced.

[0059] Furthermore, since the acid dissociation constant of hypochlorous acid (HClO) is approximately 7.5, it is necessary to maintain the pH of the first aqueous solution L1 so that it does not change. In the reaction equation Figure 4(e), hydroxide ions and hydrogen ions, which are the factors causing the change in pH, react to form water and disappear from the reaction equation. Therefore, the amount of chloride ions (Cl) consumed by membraneless electrolysis is transferred from the second aqueous solution L2 stored in the supply tank 20 to the first aqueous solution L1 stored in the electrolytic cell 10. - ) is supplied, and Cl is used in the electrolytic cell 10. - When the apparent value does not increase or decrease, the increase or decrease in pH can also be suppressed.

[0060] As described above, when the number of electrons flowing through the non-diaphragm electrolytic section E1 changes, that is, when the ratio of the current flowing through the non-diaphragm electrolytic section E1 to the current flowing through the diaphragm electrolytic section E2 changes, a change occurs in the amount of chloride ions supplied from the supply tank 20 to the electrolytic cell 10. For example, if the ratio of the current used for non-diaphragm electrolysis changes, the amount of chloride ions (Cl) supplied from the supply tank 20 will change. - ) is supplied and Cl in the electrolytic cell 10 - If the ratio of current is greater than the ratio of current under the condition that there is no apparent increase or decrease (reaction equation Figure 4(f)), the Cl supplied from the supply tank 20 to the electrolytic cell 10 - The supply of Cl in the electrolytic cell 10 decreases. - It decreases.

[0061] Cl in electrolytic cell 10 - As the amount decreases, the electrolysis efficiency of membrane-free electrolysis decreases. If membrane-free electrolysis is continued in a state of reduced electrolysis efficiency, the amount of Cl in the electrolytic cell 10 will gradually decrease. - The amount increases, and Cl increases in the electrolytic cell 10. - It reaches a level where it no longer appears to increase or decrease.

[0062] On the other hand, the amount of current used for non-diaphragm electrolysis is supplied from the supply tank 20 to produce chloride ions (Cl - ) is supplied and Cl in the electrolytic cell 10 - If the current is greater than the current that does not appear to increase or decrease (see reaction equation Figure 4(g) below), the Cl supplied from the supply tank 20 to the electrolytic cell 10 - The supply of Cl in the electrolytic cell 10 increases. - It increases.

[0063] Chloride ions (Cl) in the electrolytic cell 10 - As the amount increases, the electrolysis efficiency of membrane-free electrolysis increases. If membrane-free electrolysis is continued with increased electrolysis efficiency, the amount of Cl in the electrolytic cell 10 gradually increases. - The amount decreases, and Cl decreases in the electrolytic cell 10. - It reaches a level where it no longer appears to increase or decrease.

[0064] Also, Cl in the electrolytic cell 10 - As Cl increases, the equilibrium in reaction equation Figure 3(f) shifts to the left, and the amount of chlorine produced increases. In other words, the Cl in electrolytic cell 10 - By adjusting the current flowing through the non-diaphragm electrolytic section E1 and the current flowing through the diaphragm electrolytic section E2 so that the apparent increase or decrease does not occur, hypochlorous acid can be generated while suppressing the generation of chlorine.

[0065] [Diaphragm electrolysis section E2] Figure 5 shows a list of reaction equations that occur in the diaphragm electrolytic unit E2. The reaction in the second aqueous solution L2 in the supply tank 20 will be explained. The only electrode placed in the supply tank 20 is the supply tank side cathode 21. When a predetermined voltage is applied to the diaphragm electrolytic unit E2, current flows, electrons move, and the chemical reaction shown in Figure 5 occurs. • Reaction equation Figure 5(a): Electrolytic cell side cathode 12 (hydrogen evolution reaction) At the supply tank side cathode 21, water (H2O) in the second aqueous solution L2 is electron (e - ) receives hydrogen (H2) and hydroxide ions (OH - ) is generated. Hydrogen volatilizes as a gas, and hydroxide ions are used in the reaction equation shown in Figure 5(c) below.

[0066] Figure 5(b): Anion exchange membrane 30 When a voltage is applied to the diaphragm electrolytic unit E2 and current flows, chloride ions (Cl) contained in the second aqueous solution L2 stored in the supply tank 20 are released. - ) is supplied to the first aqueous solution L1 through the anion exchange membrane 30, and the second aqueous solution L2 is supplied with electrons (e) through the supply tank side cathode 21. - ) is obtained. In other words, in the second aqueous solution L2, the chloride ions (Cl) before the change are obtained. - ) after the change, electrons (e - It can be said that this is the case.

[0067] • Reaction equation Figure 5(c): Second aqueous solution L2 (magnesium hydroxide precipitation reaction) Magnesium ions (Mg) contained in the second aqueous solution L2, magnesium chloride 2+ ) and the hydroxide ions (OH) generated in the reaction equation Figure 5(a) - ) reacts with the metal hydroxide to form a precipitate of magnesium hydroxide (Mg(OH)2), which is a metal hydroxide precipitate. The solubility product of magnesium hydroxide (Mg(OH)2) is Ksp = 1.2 × 10⁻⁶ -11 (mol / L) 3 It is a substance that is extremely poorly soluble in aqueous solutions with a pH ranging from neutral to alkaline. For example, only 1.2 × 10⁻¹⁶ magnesium hydroxide is soluble in a weakly alkaline aqueous solution with a pH of 10. -3 The concentration is mol / L. In the second aqueous solution L2 of the supply tank 20, hydroxide ions (OH) are generated in the reaction equation Figure 5(a). - ) is used to form a magnesium hydroxide precipitate, and hydroxide ions (OH) are produced in the second aqueous solution L2. - This suppresses the increase in the concentration of ) and the increase in the pH of the second aqueous solution L2.

[0068] Furthermore, when a magnesium chloride aqueous solution is used as the second aqueous solution L2, the pH of the saturated magnesium hydroxide aqueous solution produced after diaphragm electrolysis, where the magnesium hydroxide is saturated, is 10.36, calculated from the solubility product. Therefore, even after performing diaphragm electrolysis for a long period of time, the pH of the second aqueous solution L2 can be maintained at a weakly alkaline state of 10.36 or less. In other words, when a magnesium chloride aqueous solution is used as the second aqueous solution L2, it is possible to suppress the pH of the second aqueous solution L2 from becoming strongly alkaline above pH 11. Therefore, it is possible to provide a space purification device that suppresses the strong alkalinization of the second aqueous solution L2 and enhances safety.

[0069] Furthermore, for example, a contractor may install the air purification device 1 according to this embodiment. After the air purification device 1 has been used, the contractor may overturn or drop the device when removing it or during transportation after removal. In this case, if a magnesium chloride aqueous solution is used as the second aqueous solution L2, the second aqueous solution L2 after the electrolysis reaction is a weakly alkaline magnesium hydroxide aqueous solution. Therefore, even if the second aqueous solution L2 leaks outside the air purification device 1 due to overturning or dropping, safety can be further enhanced compared to an air purification device using a sodium chloride aqueous solution as the second aqueous solution L2.

[0070] The above details describe the chemical reactions that occur in the diaphragm-free electrolytic section E1 provided in the electrolytic cell 10, and the chemical reactions that occur in the diaphragm-containing electrolytic section E2 provided across the electrolytic cell 10 and the supply tank 20.

[0071] The current control unit 40 controls the above chemical reaction. More specifically, it controls the second current to replenish the chloride ions contained in the first aqueous solution L1 that have been reduced by the membraneless electrolysis in the membraneless electrolysis unit E1. By controlling the second current, chloride ions contained in the second aqueous solution L2 are supplied to the first aqueous solution L1 by passing through the anion exchange membrane 30. The details will be explained below with reference to Figure 6.

[0072] Figure 6 is a block diagram of the current control unit 40 according to the embodiment. As shown in Figure 6 The current control unit 40 includes a voltage acquisition unit 41, a calculation unit 42, and an estimation unit 43.

[0073] The voltage acquisition unit 41 acquires the voltage between the electrolytic cell anode 11 and the electrolytic cell cathode 12. The voltage acquisition unit 41 is, for example, a voltmeter. The calculation unit 42 calculates the conductivity of the first aqueous solution L1 based on the voltage acquired by the voltage acquisition unit 41. The estimation unit 43 estimates the chloride ion concentration of the first aqueous solution L1 based on the conductivity of the first aqueous solution L1 calculated by the calculation unit 42.

[0074] The current control unit 40 controls the first current flowing through the non-diaphragm electrolytic unit E1 and the second current flowing through the diaphragm electrolytic unit E2, as shown in Figure 6, in order to maintain the chloride ion concentration of the first aqueous solution L1 at a predetermined concentration. Three examples of current control by the current control unit 40 will be described below.

[0075] [1. When the first and second currents are flowing simultaneously] When the current control unit 40 supplies both the first and second currents simultaneously, it performs the following controls (1) to (3). (1) If the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is lower than a predetermined concentration: The current ratio of the first current and the second current is changed so that the amount of chloride ions supplied from the second aqueous solution L2 to the first aqueous solution L1 through the anion exchange membrane 30 increases. More specifically, the current ratio of the first current is decreased and the current ratio of the second current is increased. (2) If the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is higher than a predetermined concentration: The current ratio of the first current and the second current is changed so that the amount of chloride ions supplied from the second aqueous solution L2 to the first aqueous solution L1 through the anion exchange membrane 30 decreases. More specifically, the current ratio of the first current is increased and the current ratio of the second current is decreased. (3) If the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is a predetermined concentration: the current ratio of the first current and the second current is not changed.

[0076] [2. When the first current flows at a predetermined value and the second current is controlled simultaneously] When the current control unit 40 controls the second current while simultaneously supplying the first current at a predetermined value, it performs the following controls (1) to (3). (1) If the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is lower than a predetermined concentration: A second current is applied so that the amount of chloride ions supplied from the second aqueous solution L2 to the first aqueous solution L1 through the anion exchange membrane 30 increases. (2) If the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is higher than a predetermined concentration: The second current is stopped so that the supply of chloride ions from the second aqueous solution L2 to the first aqueous solution L1 is stopped. (3) If the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is a predetermined concentration: the first current and the second current are not changed.

[0077] [3. When applying the first or second current] When the current control unit 40 supplies the first current or the second current, it performs the following controls (1) to (3). (1) If the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is lower than a predetermined concentration: The first current is stopped and the second current is turned on at the same time so that the amount of chloride ions supplied from the second aqueous solution L2 to the first aqueous solution L1 through the anion exchange membrane 30 increases. (2) If the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is higher than a predetermined concentration: The second current is stopped and the first current is simultaneously turned on so that the supply of chloride ions from the second aqueous solution L2 to the first aqueous solution L1 is stopped. (3) If the chloride ion concentration of the first aqueous solution L1 estimated by the estimation unit 43 is a predetermined concentration: the first current and the second current are not changed.

[0078] As described above, the current control unit 40 controls the first current and the second current, thereby reducing the electrolytic cell 1 By supplying the required amount of chloride ions to the first aqueous solution L1 of 0, the chloride ion concentration of the first aqueous solution L1 can be maintained at a predetermined concentration.

[0079] In the case described above, "1. When the first and second currents are applied simultaneously," the ratio of the first and second currents is changed when there is an increase or decrease in the chloride ion concentration of the first aqueous solution L1. Because the first and second currents are applied simultaneously, the increase or decrease in the chloride ion concentration of the first aqueous solution L1 can be minimized, and it is possible to maintain it at the optimal predetermined concentration.

[0080] In the case described in "2. When the first current is flowing at a predetermined value and the second current is controlled simultaneously," the second current is mainly flowed or stopped when there is an increase or decrease in the chloride ion concentration of the first aqueous solution L1. In the case described in "3. When either the first current or the second current is flowing," one of the first or second currents is flowed and the other is stopped when there is an increase or decrease in the chloride ion concentration of the first aqueous solution L1. Therefore, the chloride ion concentration of the first aqueous solution L1 can be maintained at a predetermined concentration. In cases 2 and 3 above, it is only necessary to control either the first or second current, making current control easy.

[0081] As described above, since chloride ions consumed by the first aqueous solution L1 can be appropriately supplied from the second aqueous solution L2, a space purification device 1 capable of stably generating a desired amount of hypochlorous acid gas can be provided. Therefore, a space purification device 1 can be provided that can stably generate a desired amount of hypochlorous acid gas without supplying an aqueous solution containing chloride ions from an external source for a long period of time, such as one year.

[0082] Alternatively, multiple current control units 40 may be provided to control the first current and the second current separately.

[0083] Furthermore, in Figure 2, the inlet 15 and outlet 17 are located on the front left side (negative y-axis and negative x-axis) and the back right side (positive y-axis and positive x-axis) when viewing the electrolytic cell 10 from above, but the arrangement is not limited to this. For example, the positions of the inlet 15 and outlet 17 may be reversed, or they may be in the same position along the x-axis, or they may be in the same position along the y-axis. However, it is preferable to arrange the inlet 15 and outlet 17 so that they are as far apart as possible on the xy plane. By arranging them in this way, the time for the incoming air and hypochlorous acid to mix in the mixing space 16 is extended, so that more hypochlorous acid can be contained in the mixed air.

[0084] Next, we will explain the case where the plane P1 (yz plane on the positive x-axis side) in the plate-shaped rectangle on the anion exchange membrane 30 side of the electrolytic cell-side anode plate 11 and the plane P2 (yz plane on the negative x-axis side) in the plate-shaped rectangle on the anion exchange membrane 30 side of the supply tank-side cathode plate 21 do not face each other. When the planes in each rectangle are arranged parallel to the xy plane, an uneven electric field may be generated between the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21. When an uneven electric field is generated between the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21, the current distribution between the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21 also becomes uneven.

[0085] When the current distribution between the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21 becomes uneven, regions with high and low current density occur. In areas with high current density, the catalyst layer on the surfaces of the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21 (hereinafter also referred to as each electrode plate) deteriorates more easily, while in areas with low current density, the catalyst layer on the surfaces of each electrode plate deteriorates less easily. In other words, when an uneven electric field is generated between the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21, the current distribution becomes uneven, and regions with different current densities can coexist on the same electrode plate simultaneously. Therefore, the deterioration of the catalyst layer due to the use of each electrode plate can occur unevenly. If the degree of deterioration of the catalyst layer on the surface of each electrode plate differs, when electrolysis is repeatedly performed, at a certain point, there may be regions on each electrode plate that are usable as electrodes and regions that have deteriorated to the point where they are unusable. When electrolysis is performed on electrode plates that include regions that cannot be used as electrodes, the electrolysis efficiency tends to decrease. That exists.

[0086] In contrast, the air purification device 1 according to this embodiment has two planes P1 and P2 arranged facing each other via an anion exchange membrane 30. This arrangement allows for a uniform electric field to be generated between the electrolytic cell-side anode plate 11 and the supply tank-side cathode plate 21, resulting in a uniform distribution of current between both electrodes. Therefore, the deterioration of the catalyst layer on the surface of each electrode plate occurs uniformly, and even when electrolysis is performed repeatedly, uneven deterioration of the catalyst layer on the surface of each electrode plate caused by an uneven electric field can be suppressed. Consequently, a decrease in electrolysis efficiency can be suppressed.

[0087] Furthermore, when diaphragm-free electrolysis is performed in an electrolytic cell at room temperature and atmospheric pressure, the electrolyte of the first aqueous solution L1 should be an electrically conductive electrolyte that does not react with each electrode, the electrolytic cell, and the anion exchange membrane, and does not cause a decrease in the concentration of hypochlorous acid by reacting with the anode, and does not react with the electrodes, the electrolytic cell, and the anion exchange membrane. More specifically, in addition to the first aqueous solution described above, other solutions may include, for example, a metal chloride aqueous solution, a hydroxide salt aqueous solution, an acidic salt aqueous solution, a phosphate aqueous solution, or a combination thereof. As a metal chloride aqueous solution, for example, a dilute calcium chloride aqueous solution or a dilute magnesium chloride aqueous solution may be used. As a hydroxide salt aqueous solution, for example, a dilute sodium hydroxide aqueous solution or a dilute potassium hydroxide aqueous solution of 0.4% by weight (0.1 mol / L) or less may be used. As an acidic salt aqueous solution, for example, a dilute hydrochloric acid aqueous solution of 0.4% by weight (0.1 mol / L) or less may be used. As a phosphate aqueous solution, for example, a disodium hydrogen phosphate aqueous solution, a sodium dihydrogen phosphate aqueous solution, a dipotassium hydrogen phosphate aqueous solution, or a potassium dihydrogen phosphate aqueous solution may be used. As a specific example of the combination of the first aqueous solution, pH adjustment may be performed by combining a dilute sodium chloride solution and a dilute sodium hydroxide solution.

[0088] It should be noted that the present invention is not limited to the embodiments described above, and can be modified as appropriate without departing from the spirit of the invention.

[0089] An overview of one aspect of this disclosure is as follows:

[0090] (Item 1) An electrolytic cell for storing a first aqueous solution containing chloride ions, A supply tank for storing a second aqueous solution containing a higher concentration of chloride ions than the first aqueous solution and for supplying chloride ions to the first aqueous solution, The electrolytic cell is provided with an electrolytic cell-side anode and an electrolytic cell-side cathode, The supply tank side cathode provided in the supply tank, An anion exchange membrane connects the electrolytic cell and the supply tank in a way that allows anions to pass through based on the voltage applied between the electrolytic cell anode and the supply tank cathode, A membrane-free electrolysis unit is provided in the electrolytic cell, which generates hypochlorous acid by performing membrane-free electrolysis of the first aqueous solution by passing a first current between the electrolytic cell-side anode and the electrolytic cell-side cathode, The electrolytic cell and the supply tank are connected, and a diaphragm electrolytic unit is provided to perform diaphragm electrolysis via the anion exchange membrane by passing a second current between the anode on the electrolytic cell side and the cathode on the supply tank side, The second aqueous solution is a metal chloride aqueous solution containing metal ions and chloride ions, By performing the aforementioned diaphragm electrolysis, To compensate for the chloride ions contained in the first aqueous solution that have been reduced by the aforementioned non-diaphragm electrolysis, the chloride ions contained in the second aqueous solution stored in the supply tank are supplied to the first aqueous solution stored in the electrolytic cell by passing them through the anion exchange membrane. In the supply tank, metal ions contained in the second aqueous solution react with hydroxide ions generated by the diaphragm electrolysis to form a precipitate of metal hydroxide. Air purification device. (Item 2) The second aqueous solution is an aqueous solution of magnesium chloride. The air purification device described in item 1. (Item 3) The current control unit controls the second current to compensate for the chloride ions contained in the first aqueous solution that have been reduced by the aforementioned non-diaphragm electrolysis, thereby supplying chloride ions contained in the second aqueous solution to the first aqueous solution by passing them through the anion exchange membrane. The current control unit maintains the chloride ion concentration of the first aqueous solution at a predetermined concentration by flowing the first current and the second current in a predetermined ratio. The air purification device described in item 1. (Item 4) The current control unit, A voltage acquisition unit that acquires the voltage between the electrolytic cell anode and the electrolytic cell cathode, A calculation unit that calculates the conductivity of the first aqueous solution based on the voltage acquired by the voltage acquisition unit, The system includes an estimation unit that estimates the concentration of the first aqueous solution based on the conductivity calculated by the calculation unit, The current control unit, The first current and the second current are passed simultaneously. If the chloride ion concentration of the first aqueous solution is lower than a predetermined concentration, the current ratio of the first current and the second current is changed so that the amount of chloride ions supplied from the second aqueous solution through the anion exchange membrane to the first aqueous solution increases. If the chloride ion concentration of the first aqueous solution is higher than the predetermined concentration, the current ratio of the first current and the second current is changed so that the amount of chloride ions supplied from the second aqueous solution through the anion exchange membrane to the first aqueous solution decreases. The air purification device described in item 3. (Item 5) If the chloride ion concentration of the first aqueous solution is the predetermined concentration, the current ratio between the first current and the second current is not changed. The air purification device described in item 4. (Item 6) A voltage acquisition unit that acquires the voltage between the electrolytic cell anode and the electrolytic cell cathode, A calculation unit that calculates the conductivity of the first aqueous solution based on the voltage acquired by the voltage acquisition unit, The system includes an estimation unit that estimates the concentration of the first aqueous solution based on the conductivity calculated by the calculation unit, The current control unit, The first current is flowed at a predetermined value, and at the same time, the second current is controlled. Control of RD2 current is If the chloride ion concentration of the first aqueous solution is lower than a predetermined concentration, the second current is applied so as to increase the amount of chloride ions supplied from the second aqueous solution through the anion exchange membrane to the first aqueous solution. If the chloride ion concentration of the first aqueous solution is higher than the predetermined concentration, the second current is stopped so that the supply of chloride ions from the second aqueous solution to the first aqueous solution is stopped. The air purification device described in item 3. (Item 7) A voltage acquisition unit that acquires the voltage between the electrolytic cell anode and the electrolytic cell cathode, A calculation unit calculates the conductivity of the first aqueous solution based on the voltage acquired by the voltage acquisition unit. and, The system includes an estimation unit that estimates the concentration of the first aqueous solution based on the conductivity calculated by the calculation unit, The current control unit, If the chloride ion concentration of the first aqueous solution is lower than a predetermined concentration, the first current is stopped and the second current is turned on simultaneously, so that the amount of chloride ions supplied from the second aqueous solution through the anion exchange membrane to the first aqueous solution increases. If the chloride ion concentration of the first aqueous solution is higher than a predetermined concentration, The second current is stopped and the first current is simultaneously turned on so that the supply of chloride ions from the second aqueous solution to the first aqueous solution is stopped. The air purification device described in item 3. (Item 8) The electrolytic cell-side anode, the electrolytic cell-side cathode, and the supply tank-side cathode are, respectively, plate-shaped electrolytic cell-side anode plate, electrolytic cell-side cathode plate, and supply tank-side cathode plate. The electrolytic cell-side anode plate and the electrolytic cell-side cathode plate are inserted into the electrolytic cell from outside the electrolytic cell, and the supply tank-side cathode plate is inserted into the supply tank from outside the supply tank. The electrolytic cell-side anode plate comprises an electrolytic cell-side anode plate immersion portion located on the inside of the electrolytic cell and an electrolytic cell-side anode plate protrusion portion located on the outside of the electrolytic cell. The electrolytic cell side cathode plate comprises an electrolytic cell side cathode plate immersion portion located on the inside of the electrolytic cell and an electrolytic cell side cathode plate protrusion portion located on the outside of the electrolytic cell. The supply tank side cathode plate comprises a supply tank side cathode plate immersion portion located on the inside of the supply tank and a supply tank side cathode plate protrusion portion located on the outside of the supply tank. The entirety of the anode plate immersion section on the electrolytic cell side and the cathode plate immersion section on the electrolytic cell side is Immersed in the first aqueous solution, The entire cathode plate immersion section on the supply tank side is, Immersed in the second aqueous solution, The air purification device described in item 1. (Item 9) A water level detection unit for detecting the position of the liquid surface in the first aqueous solution, The system includes a water supply unit that supplies water to the electrolytic cell so that the liquid level detected by the water level detection unit does not fall below the upper ends of the electrolytic cell-side anode plate immersion section and the electrolytic cell-side cathode plate immersion section. A space purification device as described in item 7 or 8. (Item 10) The aforementioned diaphragmless electrolytic section is The electrolytic cell side anode and, The electrolytic cell side cathode comprises, The aforementioned diaphragm electrolytic unit is The electrolytic cell side anode and, The cathode on the supply tank side, The anion exchange membrane comprises, The air purification device described in item 1. (Item 11) A housing for housing the electrolytic cell and the supply tank, Located within the housing above the liquid level of the first aqueous solution stored in the electrolytic cell, and having an inlet through which air flows in from the external space of the housing, A mixing space for mixing the volatilized hypochlorous acid with the air flowing in from the inlet, The system includes an outlet through which the mixed air flows out to the external space. The air purification device described in item 1. [Explanation of Symbols]

[0091] 1. Air purification device 10 Electrolytic cell 11 Electrolyzer side anode 11a Electrolytic cell side anode plate immersion section 11b Protrusion of the anode plate on the side of the electrolytic cell 12 Electrolytic cell side cathode 12a Electrolytic cell side cathode plate immersion section 12b Protrusion of the cathode plate on the side of the electrolytic cell 13 Wiring 14 Wiring 15 Inlet 16 Mixed Space 17 Outlet 18 Water level outlet 19. Water Supply Department 20 supply tanks 21 Supply tank side cathode 21a Supply tank side cathode plate immersion section 21b Protrusion of cathode plate on the supply tank side 22 Wiring 23 Discharge outlet 30 Yin-Yang Exchange Membrane 40 Current Control Unit 41 Electric pressure acquisition part 42 Calculation Department 43. Presumption Section B box L1 First aqueous solution L2, second aqueous solution S1 liquid level S2 liquid level

Claims

1. An electrolytic cell for storing a first aqueous solution containing chloride ions and generating hypochlorous acid by diaphragm-free electrolysis of the first aqueous solution, A supply tank for storing a second aqueous solution containing a higher concentration of chloride ions than the first aqueous solution and for supplying chloride ions to the first aqueous solution, The electrolytic cell and the supply tank are connected by an anion exchange membrane that allows anions to pass through based on a voltage applied between the electrolytic cell and the supply tank, Air introduced from the outside space flows through the electrolytic cell and is released back into the outside space together with the hypochlorous acid, thereby purifying the outside space. The second aqueous solution is a metal chloride aqueous solution containing metal ions and chloride ions, By performing diaphragm electrolysis through the aforementioned anion exchange membrane, To compensate for the chloride ions contained in the first aqueous solution that have been reduced by the aforementioned non-diaphragm electrolysis, the chloride ions contained in the second aqueous solution stored in the supply tank are supplied to the first aqueous solution stored in the electrolytic cell by passing them through the anion exchange membrane. In the supply tank, metal ions contained in the second aqueous solution react with hydroxide ions generated by the diaphragm electrolysis to form a precipitate of metal hydroxide. Air purification device.

2. The second aqueous solution is an aqueous solution of magnesium chloride. The air purification device according to claim 1.

3. The aforementioned diaphragm-free electrolysis is performed by passing a first current. The aforementioned diaphragm electrolysis is performed by passing a second current. The current control unit controls the second current to compensate for the chloride ions contained in the first aqueous solution that have been reduced by the aforementioned non-diaphragm electrolysis, thereby supplying chloride ions contained in the second aqueous solution to the first aqueous solution by passing them through the anion exchange membrane. The current control unit maintains the chloride ion concentration of the first aqueous solution at a predetermined concentration by flowing the first current and the second current in a predetermined ratio. The air purification device according to claim 1.

4. The current control unit, A voltage acquisition unit that acquires the voltage applied to the electrolytic cell, A calculation unit that calculates the conductivity of the first aqueous solution based on the voltage acquired by the voltage acquisition unit, The system includes an estimation unit that estimates the concentration of the first aqueous solution based on the conductivity calculated by the calculation unit, The current control unit, The first current and the second current are passed simultaneously. If the chloride ion concentration of the first aqueous solution is lower than a predetermined concentration, the current ratio of the first current and the second current is changed so that the amount of chloride ions supplied from the second aqueous solution through the anion exchange membrane to the first aqueous solution increases. If the chloride ion concentration of the first aqueous solution is higher than the predetermined concentration, the current ratio of the first current and the second current is changed so that the amount of chloride ions supplied from the second aqueous solution through the anion exchange membrane to the first aqueous solution decreases. The air purification device according to claim 3.

5. If the chloride ion concentration of the first aqueous solution is the predetermined concentration, the current ratio between the first current and the second current is not changed. The air purification device according to claim 4.

6. A housing for housing the electrolytic cell and the supply tank, Located within the housing above the liquid level of the first aqueous solution stored in the electrolytic cell, there is an inlet through which air flows in from the external space of the housing, A mixing space for mixing the volatilized hypochlorous acid with the air flowing in from the inlet, The system includes an outlet through which the mixed air flows out to the external space. The air purification device according to claim 1.

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