Herbicide mixture containing L-glufosinate or a salt thereof and a secondary herbicide.

Abstract

To provide a herbicidal mixture that shows a higher activity in burndown programs, in industrial vegetation management and forestry, in vegetable and perennial crops and in turf and lawn, and a method for controlling undesirable vegetation.SOLUTION: A herbicidal mixture comprises the following: a) L-glufosinate and / or its salt as compound I; and b) at least one herbicidal compound II, which is triaziflam. L-glufosinate comprises more than 70 wt.% of L-enantiomer. The weight ratio between compound I and compound II is 1000: 1-1: 500.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to L-glufosinate or a salt thereof, and chlorthiamid, diclobenil, flupoxam, indaziflam, isoxaben, triaziflam, and 1-cyclohexyl-5-pentafluorophenyloxy-14-[1,2,4,6]thiatriazine-3-ylamine (CAS 175899-01-1), diflufenzopyr, diflufenzopyr-sodium, naptalam and naptalam-sodium, bromobutide, chlorflurenol, chlorflurenol-methyl, cinmethylin, cumyluron, cyclopyrimorate (CAS 499223-49-3) and its salts and esters, dalapon, dazomet, difenzoquat, difenzoquat-methylsulfate, dimethipin, DSMA, dymron, endothal and its salts, etobenzanid, flurenol, flurenol-butyl, flurprimidol, fosamine, fosamine-ammonium, indanofan, maleic hydrazide, mefluidide, metam, methiozolin (CAS403640-27-7), methyl azide, methyl bromide, methyl-dymron, methyl iodide, MSMA, oleic acid, oxaziclomefone, pelargonic acid, pyributicarb, quinoclamine, tridiphane; a herbicide mixture comprising a herbicide compound II selected from bilanaphos (bialaphos) and bilanaphos-sodium. The present invention further relates to methods for controlling unwanted vegetation in burndown programs, industrial vegetation management and forestry, vegetable crops and perennial crops, and turf and lawns.

Background Art

[0002] Burndown, i.e., the complete removal of weeds from the soil by the application of herbicides before crop planting or before emergence, is an important tool in modern weed management. Weeds present at planting generally grow much more rapidly than the crop, thus competing very early in the growing season and causing damage to the crop and reducing crop yields. Therefore, it is desirable to plant the crop in a weed-free seedbed or to ensure that essentially no weeds are present when the crop emerges. Burndown may also necessarily involve weed control in fallow fields.

[0003] In industrial weed management and forestry, it is desirable to control weeds over a wide area over a long period of time. In some cases, it is also desirable to control larger weeds or taller species such as shrubs or trees. Examples of industrial weed management include the management of railway and public road land, fence lines, and non-cultivated land (e.g., industrial and construction sites, gravel areas, roads or footpaths). Examples of forestry include the removal of existing forests or shrublands, the removal of regeneration after mechanical logging, or the management of weeds under forestry plantations. In the latter case, it may be desirable to shield the desired trees from contact with the spray solution containing the herbicide mixture according to the present invention.

[0004] Examples of vegetable crops include eggplant (aubergine), legumes, bell peppers, cabbage, chili peppers, cucumbers, eggplants, lettuce, melons, onions, potatoes, sweet potatoes, spinach, and tomatoes. For weed control in vegetable crops, it may be desirable to shield these crops from contact with the spray solution containing the herbicide mixture according to the present invention.

[0005] Perennial crops include tree crops, nut crops and vine crops such as almonds, apples, apricots, avocados, cashews, cherries, Christmas trees, durians, oranges, dragon fruit, grapes, guavas, longans, mangoes, olives, papayas, peaches, pears and other pomegranates, pistachios, plums, pomegranates, pomelos and quince, as well as citrus crops such as clementines, grapefruits, lemons, limes, mandarins and nectarines, and nut crops such as hazelnuts, macadamia nuts and walnuts; and plantation crops such as bananas, cocoa, coconuts, coffee, oil palms, peppers and other seeds, plantains, rubber, sugarcane and tea. Also included are ornamental plants such as azaleas, rhododendrons and roses, and nurseries. For weed control in perennial crops, it may be desirable to shield these crops from contact with a spray solution containing the herbicide mixture according to the present invention.

[0006] Furthermore, the compositions according to the present invention can also be used for weed control in turf and lawn areas, provided that the desired grass species are resistant to the herbicide mixture. In particular, such mixtures can be used in desired grass species that have been made resistant to glufosinate by mutagenesis or genetic engineering.

[0007] Glufosinate and its salts exhibit excellent post-emergence activity against numerous weeds, making them non-selective systemic herbicides suitable for use in burn-down programs, industrial vegetation management and forestry, vegetable and perennial crops, and turf and lawn areas. However, glufosinate alone often results in insufficient weed control, frequently requiring multiple applications and / or higher doses. Furthermore, glufosinate's effectiveness against some weeds is not entirely sufficient.

[0008] Therefore, it is often recommended to apply glufosinate in combination with at least one additional herbicide. However, the effectiveness of such combinations is often insufficient, and high application rates are still required to achieve acceptable weed control. Furthermore, the reliability and persistence of such combinations are highly dependent on weathering conditions, and controlling escaped weed species is indeed difficult. Moreover, because the herbicidal activity of these mixtures lasts only a short time, effective burndown is only possible within a small timeframe before crop planting.

[0009] Accordingly, the object of the present invention is to provide herbicide mixtures that enable efficient and reliable control of grass weeds and broadleaf weeds in burn-down programs, industrial vegetation management and forestry, vegetable crops and perennial crops, and turf and lawn. Furthermore, the persistence of the herbicidal activity of the mixtures should be long enough to achieve weed control over a sufficiently long period, thereby enabling more flexible application. The mixtures should also have low toxicity to humans or other mammals. The mixtures should also exhibit a rapid action on harmful plants; that is, these mixtures should cause damage to harmful plants more quickly than the application of individual herbicides.

[0010] Glufosinate is a racemic mixture of two enantiomers, of which only one exhibits sufficient herbicidal activity (see, e.g., US 4265654 and JP92448 / 83). Various methods are known for preparing L-glufosinate (and each salt), but mixtures known in the art do not specify stereochemistry, implying the presence of a racemic mixture (e.g., WO2013154396). [Prior art documents] [Patent Documents]

[0011] [Patent Document 1] US 4265654 [Patent Document 2] JP92448 / 83 [Patent Document 3] WO2013154396 [Overview of the project]

[0012] Surprisingly, mixtures of L-glufosinate or its salt with herbicide compound II were found to exhibit higher activity compared to L-glufosinate alone in burn-down programs, industrial vegetation management and forestry, vegetable crops and perennial crops, as well as turf and lawn.

[0013] Surprisingly, mixtures of L-glufosinate or its salt with herbicide compound II were found to exhibit higher activity in burn-down programs, industrial vegetation management and forestry, vegetable crops and perennial crops, as well as turf and lawn, compared to mixtures of racemic glufosinate with herbicide compound II.

[0014] Therefore, the present invention is 1) L-glufosinate or a salt thereof as compound I, 2) Herbicide compound II as compound II, selected from the group consisting of the following: chlorthiamide, diclobenyl, flupoxam, indadiflame, isoxaben, triaziflame, 1-cyclohexyl-5-pentafluorophenyloxy-14-[1,2,4,6]thiatriazine-3-ylamine (CAS 175899-01-1), diflufenzopyr, diflufenzopyr-sodium, naptaram and naptaram-sodium, bromobutide, chlorflurenol, chlorflurenol-methyl, scinmethiline, cumylon, cyclopyrimorate (CAS 499223-49-3) and its salts and esters, darapone, dazomet, diphenzocort, diphenzocort-methylsulfate, dimethipine, DSMA, dimuron, endotal and its salts, etobenzanide, flurenol, flurenol-butyl, flurprimidol, hosamine, hosamine-ammonium, indanophan, maleate hydrazide, mefluidide, metam, methiozoline (CAS 403640-27-7), methyl azide, methyl bromide, methyl dimuron, methyl iodide, MSMA, oleic acid, oxadiclomefone, pelargonic acid, pyributicarb, quinoclamin, tridiphan; viranaphos (biaraphos) and viranaphos-sodium Regarding the herbicide mixture.

[0015] In a preferred embodiment, the above invention relates to the herbicide mixture comprising an L-enantiomer of L-glufosinate in an amount of more than 70% by weight. [Modes for carrying out the invention]

[0016] Glufosinate [the generic name for DL-4-[hydroxyl(methyl)phosphinoyl]-DL-homoalaninate] and its salts (e.g., glufosinate-ammonium), as well as their herbicidal activity, are described, for example, by F. Schwerdtle et al. in Z. Pflanzenkr. Pflanzenschutz, 1981, Sonderheft IX, pp. 431-440. Glufosinate and its salts as racemates are commercially available, for example, from Bayer Cropscience under the trade names Basta® and Liberty®.

[0017] The L-glufosinate used in the present invention comprises more than 70% by weight of the L-enantiomer; preferably more than 80% by weight of the L-enantiomer; more preferably more than 90% of the L-enantiomer, and most preferably more than 95% of the L-enantiomer, and can be prepared as referred to above. The L-glufosinate can be prepared according to methods known in the art, for example, as described in WO2006 / 104120, US5530142, EP0127429 and J. Chem. Soc. Perkin Trans. 1, 1992, 1525-1529.

[0018] L-glufosinate (also known as glufosinate-P) is (2S)-2-amino-4-[hydroxy(methyl)phosphinoyl]butyric acid (CAS Registry No. 35597-44-5). Related salts of L-glufosinate are ammonium (2S)-2-amino-4-(methylphosphinato)butyric acid (CAS Registry No. 73777-50-1), which is L-glufosinate-ammonium (also known as glufosinate-P-ammonium); sodium (2S)-2-amino-4-(methylphosphinato)butyric acid (CAS Registry No. 70033-13-5), which is L-glufosinate-sodium (also known as glufosinate-P-sodium); and potassium (2S)-2-amino-4-(methylphosphinato)butyric acid, which is L-glufosinate-potassium (also known as glufosinate-P-potassium).

[0019] Compound II, as well as their pesticidal action and their production methods, are generally known, among other documents, for example, in Pesticide Manual V5.2 (ISBN 978 1 901396 85 0) (2008 - 2011).

[0020] In the mixture of the present invention, the weight ratio of Compound I to Compound II is preferably 1000:1 to 1:500, more preferably 400:1 to 1:40, even more preferably 500:1 to 1:250, particularly 200:1 to 1:20, still more preferably 100:1 to 1:10, and most preferably 50:1 to 1:5.

[0021] Furthermore, mixtures containing L - glufosinate - ammonium or L - glufosinate - sodium as the L - glufosinate salt, or L - glufosinate as the free acid, are preferred. Particularly preferred is the mixture containing L - glufosinate - ammonium as the L - glufosinate salt.

[0022] Preferred Compound II is diclobenyl, diflufenzoppil, diflufenzoppil - sodium, simetryn, bromobutide, cyclopyrimorate (CAS 499223 - 49 - 3) and its salts and esters, endothal and oxadiargyl.

[0023] Even more preferred Compound II is triaziflam, indanofan, methiozolin and oxadiargyl.

[0024] Even more preferred Compound II is triaziflam, indanofan and methiozolin.

[0025] In one embodiment of the present invention, Compound II is triaziflam.

[0026] In another embodiment of the present invention, Compound II is indanofan.

[0027] In another embodiment of the present invention, compound II is methiozoline.

[0028] Accordingly, a preferred mixture of the present invention is a mixture of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt or L-glufosinate as a free acid and herbicide compound II selected from the group consisting of diclobenyl, diflufenzopyr, diflufenzopyr-sodium, simmethiline, bromobutide, cyclopyrimorate (CAS 499223-49-3) and their salts and esters, endotar and oxadiclomefone.

[0029] The mixture of the present invention is more preferably a mixture of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt or L-glufosinate as a free acid and herbicide compound II selected from the group consisting of triaziflam, indanophan, methiozoline and oxadiclomefone, more preferably herbicide compound II selected from the group consisting of triaziflam, indanophan and methiozoline.

[0030] All preferred mixtures are listed in Table 2, where the following abbreviations from Table 1 are used:

[0031] [Table 1] TIFF0007844516000002.tif18170

[0032] [Table 2]

[0033] A preferred mixture of the present invention is a mixture of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt, or L-glufosinate as a free acid, and at least one compound II selected from the group consisting of diclobenyl, diflufenzopyr, diflufenzopyr-sodium, and simmethyline.

[0034] A preferred mixture of the present invention is a mixture of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt or L-glufosinate as a free acid and at least one compound II selected from the group consisting of scinmethiline, oxadiclomefone, indadiflame, triaziflame, indanophan, and methiozoline.

[0035] A preferred mixture of the present invention is a mixture of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt or L-glufosinate as a free acid and at least one compound II selected from the group consisting of triaziphram, indanophan, and methiozoline.

[0036] In one embodiment of the present invention, the mixture is a mixture of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt, or L-glufosinate as a free acid, and triaziphram.

[0037] In another embodiment of the present invention, the mixture is a mixture of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt, or L-glufosinate as a free acid, and indanophan.

[0038] In another embodiment of the present invention, the mixture is a mixture of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt, or L-glufosinate as a free acid, and methiozoline.

[0039] Therefore, preferred mixtures are M-1, M-2, M-3, M-4, M-13, M-14, M-15, M-16, M-25, M-26, M-27, and M-28. Similarly preferred are M-8, M-20, and M-32.

[0040] Even more preferable are mixtures M-1, M-2, M-3, and M-4.

[0041] In further embodiments, preferred mixtures are M-4, M-8, M-9, M-10, M-11, M-12, M-16, M-20, M-21, M-22, M-23, M-24, M-28, M-32, M-33, M-24, M-35, and M-36.

[0042] Further preferred mixtures are M-10, M-11, M-12, M-22, M-23, M-24, M-34, M-35, and M-36.

[0043] In one embodiment, the mixture is M-10, M-22, or M-34, preferably M-10.

[0044] In another embodiment, the mixture is M-11, M-23, or M-35, preferably M-11.

[0045] In another embodiment, the mixture is M-12, M-24, or M-36, preferably M-12.

[0046] All of the mixtures mentioned above will be referred to herein hereafter as "the mixtures of the present invention."

[0047] The mixture of the present invention may further contain one or more insecticides, fungicides, and herbicides.

[0048] The mixtures of the present invention can be converted into conventional types of pesticide mixtures, such as liquids, emulsions, suspensions, powders, powders, pastes, granules, compresses, capsules, and mixtures thereof. Examples of mixture types include suspensions (e.g., SC, OD, FS), emulsifying concentrates (e.g., EC), emulsions (e.g., EW, EO, ES, ME), capsules (e.g., CS, ZC), pastes, pastels, wettable powders or wettable powders (e.g., WP, SP, WS, DP, DS), compresses (e.g., BR, TB, DT), granules (e.g., WG, SG, GR, FG, GG, MG), insecticidal products (e.g., LN), and gel formulations for treating plant propagation materials such as seeds (e.g., GF). These and further mixture types are defined in the "Catalogue of pesticide formulation types and international coding system" (Technical Monograph No. 2, 6th edition, May 2008, CropLife International).

[0049] The above mixtures are prepared by known methods, such as those described in Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.

[0050] Suitable auxiliary agents include solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetting agents, auxiliary agents, solubilizers, penetration enhancers, protective colloids, adhesives, thickeners, humectants, repellents, attractants, feeding stimulants, phase solvents, bactericidal agents, antifreeze agents, defoaming agents, colorants, tackifiers, and binders.

[0051] Suitable solvents and liquid carriers include water and organic solvents (medium to high boiling point mineral oil fractions, e.g., kerosene, diesel oil, etc.), vegetable or animal-derived oils, aliphatic hydrocarbons, cyclic hydrocarbons and aromatic hydrocarbons (e.g., toluene, paraffin, tetrahydronaphthalene, alkylated naphthalene), alcohols (e.g., ethanol, propanol, butanol, benzyl alcohol, cyclohexanol), glycols, DMSO, ketones (e.g., cyclohexanone), esters (e.g., lactic acid esters, carbonate esters, fatty acid esters, gamma-butyrolactone), fatty acids, phosphonic acid esters, amines, amides (e.g., N-methylpyrrolidone, fatty acid dimethylamide), and mixtures thereof.

[0052] Suitable solid carriers or fillers include mineral earths such as silicate, silica gel, talc, kaolin, limestone, lime, chalk, clay, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, and magnesium oxide; polysaccharides such as cellulose and starch; fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, and urea; and plant-derived products such as grain flour, bark flour, wood flour, nut shell powder, and mixtures thereof.

[0053] Suitable surfactants are surface-active compounds such as anionic surfactants, cationic surfactants, nonionic surfactants, and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifiers, dispersants, solubilizers, wetting agents, penetration enhancers, protective colloids, or auxiliary agents. Examples of surfactants are listed in McCutcheon's, Volume 1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International or North American edition).

[0054] Suitable anionic surfactants are sulfonates, sulfates, phosphates, alkali salts, alkaline earth salts or ammonium salts of carboxylates, and mixtures thereof. Examples of sulfonates include alkylaryl sulfonates, diphenyl sulfonates, alpha-olefin sulfonates, lignin sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecylbenzene and tridecylbenzene, sulfonates of naphthalene and alkylnaphthalenes, sulfosuccinates or sulfosuccinates. Examples of sulfates include sulfates of fatty acids and oils, sulfates of ethoxylated alkylphenols, sulfates of alcohols, sulfates of ethoxylated alcohols, or sulfates of fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates and carboxylated alcohols or alkylphenol ethoxylates.

[0055] Suitable nonionic surfactants include alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymer surfactants, and mixtures thereof. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids, or fatty acid esters that are alkoxylated in 1 to 50 equivalents. Ethylene oxide and / or propylene oxide (preferably ethylene oxide) can be used for alkoxylation. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters, or monoglycerides. Examples of sugar-based surfactants are sorbitan, ethoxylated sorbitan, sucrose esters, glucose esters, or alkyl polyglucosides. Examples of polymer surfactants are homopolymers or copolymers of vinylpyrrolidone, vinyl alcohol, or vinyl acetate.

[0056] Suitable cationic surfactants are quaternary surfactants, such as quaternary ammonium compounds having one or two hydrophobic groups, or salts of long-chain primary amines. Suitable amphoteric surfactants are alkyl betaines and imidazolines. Suitable block polymers are AB-type or ABA-type block polymers containing blocks of polyethylene oxide and polypropylene oxide, or ABC-type block polymers containing alkanols, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are polyacrylic acid or alkali salts of polyacid comb-type polymers. Examples of polybases are polyvinylamine or polyethyleneamine.

[0057] Suitable adjuvants are compounds whose own pest-killing activity is negligible or who have no pest-killing activity themselves, but which enhance the biological performance of the mixture of the present invention against the target. Examples include surfactants, mineral oils or vegetable oils, and other adjuvants. Further examples are listed by Knowles in Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, Chapter 5.

[0058] Suitable thickeners include polysaccharides (e.g., xanthan gum, carboxymethylcellulose), inorganic clay (organically modified or unmodified), polycarboxylates, and silicates.

[0059] Suitable bactericides include bronopol and isothiazolinone derivatives, such as alkylisothiazolinone and benzisothiazolinone.

[0060] Suitable antifreezes include ethylene glycol, propylene glycol, urea, and glycerin.

[0061] Suitable defoaming agents include silicones, long-chain alcohols, and fatty acid salts.

[0062] Suitable colorants (e.g., red, blue, or green) are low water-soluble pigments and water-soluble dyes. Examples include inorganic colorants (e.g., iron oxide, titanium dioxide, hexacyanoferrates) and organic colorants (e.g., alizarin colorants, azo colorants, and phthalocyanine colorants).

[0063] Suitable tackifiers or binders include polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylate, biological wax or synthetic wax, and cellulose ether.

[0064] Examples of mixture types and their preparations are as follows: i) Water-soluble concentrates (SL, LS) Dissolve 10-60% by weight of the mixture of the present invention and 5-15% by weight of a wetting agent (e.g., alcohol alkoxylate) in water and / or a water-soluble solvent (e.g., alcohol) to make a total of 100% by weight. The active substance dissolves when diluted with water.

[0065] ii) Dispersible concentrate (DC) Dissolve 5-25% by weight of the mixture of the present invention and 1-10% by weight of a dispersant (e.g., polyvinylpyrrolidone) in an organic solvent (e.g., cyclohexanone) to make a 100% by weight solution. Dilution with water yields a dispersion.

[0066] iii) Emulsifying concentrate (EC) Dissolve 15-70% by weight of the mixture of the present invention and 5-10% by weight of an emulsifier (e.g., calcium dodecylbenzenesulfonate and castor oil ethoxylate) in a water-insoluble organic solvent (e.g., aromatic hydrocarbon) to make a 100% by weight mixture. Diluting with water yields an emulsion.

[0067] iv) Emulsions (EW, EO, ES) Dissolve 5-40% by weight of the mixture of the present invention and 1-10% by weight of an emulsifier (e.g., calcium dodecylbenzenesulfonate and castor oil ethoxylate) in 20-40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbon). Introduce this mixture into water using an emulsifier to make a 100% by weight mixture and obtain a homogeneous emulsion. Diluting with water yields the emulsion.

[0068] v) Suspensions (SC, OD, FS) In a stirred ball mill, 20-60% by weight of the mixture of the present invention is finely ground with 2-10% by weight of a dispersant and wetting agent (e.g., sodium lignosulfonate and alcohol ethoxylate), 0.1-2% by weight of a thickener (e.g., xanthan gum), and up to 100% by weight of water to obtain a fine suspension of the active substance. Dilution with water yields a stable suspension of the active substance. For FS-type mixtures, up to 40% by weight of a binder (e.g., polyvinyl alcohol) is added.

[0069] vi) Water-dispersible granules and water-soluble granules (WG, SG) A mixture of the present invention containing 50-80% by weight is mixed with up to 100% by weight of a dispersant and a wetting agent (e.g., sodium lignosulfonate and alcohol ethoxylate) and finely ground. This mixture is then prepared as a water-dispersible granule or water-soluble granule using a dedicated apparatus (e.g., extruder, spray tower, fluidized bed). Dilution with water yields a stable dispersion or solution of the active substance.

[0070] vii) Water-dispersible powders and water-soluble powders (WP, SP, WS) In a rotor-stator mill, 50-80% by weight of the mixture of the present invention is ground with 1-5% by weight of a dispersant (e.g., sodium lignosulfonate), 1-3% by weight of a wetting agent (e.g., alcohol ethoxylate), and up to 100% by weight of a solid support (e.g., silica gel). Dilution with water yields a stable dispersion or solution of the active substance.

[0071] viii) Gel formulations (GW, GF) When 5 to 25% by weight of the mixture of the present invention is added to a stirred ball mill with 3 to 10% by weight of a dispersant (e.g., sodium lignosulfonate), 1 to 5% by weight of a thickener (e.g., carboxymethylcellulose), and up to 100% by weight of water, and then finely ground, a fine suspension of the active substance is obtained. Dilution with water yields a stable suspension of the active substance.

[0072] ix) Microemulsion agents (ME) Add 5-20% by weight of the mixture of the present invention to 5-30% by weight of an organic solvent blend (e.g., fatty acid dimethylamide and cyclohexanone), 10-25% by weight of a surfactant blend (e.g., alcohol ethoxylate and arylphenol ethoxylate), and up to 100% by weight of water. Stirring this mixture for 1 hour spontaneously produces a thermodynamically stable microemulsion.

[0073] x) Microencapsulated tablets (CS) An oil phase containing 5-50% by weight of the mixture of the present invention, 0-40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbon), and 2-15% by weight of an acrylic monomer (e.g., methyl methacrylate, methacrylic acid, and diacrylate or triacrylate) is dispersed in an aqueous solution of a protective colloid (e.g., polyvinyl alcohol). Radical polymerization initiated by a radical initiator forms poly(meth)acrylate microcapsules. Alternatively, an oil phase containing 5-50% by weight of the mixture of the present invention according to the present invention, 0-40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbon), and an isocyanate monomer (e.g., diphenylmethene-4,4'-diisocyanate) is dispersed in an aqueous solution of a protective colloid (e.g., polyvinyl alcohol). Addition of a polyamine (e.g., hexamethylenediamine) forms polyurea microcapsules. The monomers total 1-10% by weight. The weight percentages refer to the total CS mixture.

[0074] xi) Dustable powder (DP, DS) The mixture of the present invention in an amount of 1 to 10% by weight is finely ground and thoroughly mixed with up to 100% by weight of a solid carrier (e.g., finely ground kaolin).

[0075] xii) Granules (GR, FG) The mixture of the present invention, in an amount of 0.5 to 30% by weight, is finely ground and combined with up to 100% by weight of a solid carrier (e.g., silicate). Granulation is achieved by extrusion, spray drying, or fluidized bed.

[0076] xiii) Ultra-low volume liquid formulation (UL) Dissolve 1 to 50% by weight of the mixture of the present invention in up to 100% by weight of an organic solvent (e.g., aromatic hydrocarbon).

[0077] Mixture types i) to xiii) may optionally contain further additives such as 0.1 to 1% by weight of a bactericide, 5 to 15% by weight of an antifreeze, 0.1 to 1% by weight of an antifoaming agent, and 0.1 to 1% by weight of a coloring agent.

[0078] The resulting pesticide mixture generally contains 0.01 to 95% by weight, preferably 0.1 to 90% by weight, and particularly 0.5 to 75% by weight of the active substance. The active substance is used with a purity of 90% to 100%, preferably 95% to 100% (according to NMR spectroscopy).

[0079] For the purpose of treating plant propagation materials (especially seeds), seed treatment solutions (LS), suspend emulsions (SE), flowable concentrates (FS), drying powders (DS), water-dispersible powders (WS), water-soluble powders (SS), emulsions (ES), emulsifying concentrates (EC), and gels (GF) are commonly used. After dilution 2 to 10 times, these mixtures provide an active substance concentration of 0.01 to 60% by weight, preferably 0.1 to 40% by weight, in a ready-to-use preparation. Application can be carried out before or during sowing. Methods for applying the mixtures of the present invention and these mixtures to plant propagation materials (especially seeds) include dressing, coating, pelleting, dusting, soaking, and in-furrow application. Preferably, the mixtures of the present invention or mixtures thereof are applied to plant propagation material by a method that does not induce germination, such as seed coating, seed pelleting, seed dusting, and seed dusting.

[0080] The present invention also relates to herbicidal formulations comprising a herbicidal active mixture as defined herein and at least one carrier material (e.g., a liquid carrier material and / or a solid carrier material).

[0081] Various types of oils, wetting agents, auxiliaries, fertilizers or micronutrients, and further pesticides (e.g., herbicides, insecticides, fungicides, growth regulators, phytotoxicity reducers) may be added as a premix to the active substance or the mixture of the present invention containing them, or, if appropriate, may be added immediately before use (tank mix). These agents can be mixed with the mixture of the present invention in a weight ratio of 1:100 to 100:1, preferably 1:10 to 10:1.

[0082] The user typically applies the mixture according to the present invention from a predosage device, a backpack sprayer, a spray tank, a spray aircraft, or an irrigation system. Typically, the pesticide mixture is brought to the desired application concentration with water, a buffer, and / or further additives, thus obtaining a ready-to-use spray solution or pesticide mixture according to the present invention. Typically, 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray solution is applied per hectare of agricultural area.

[0083] As outlined above, the present invention also relates to the use of mixtures as defined herein for controlling undesirable vegetation in burn-down programs, industrial vegetation management and forestry, vegetable crops and perennial crops, and turf and lawn, where the mixtures of the present invention may be applied before or after emergence, i.e., before, during and / or after the emergence of undesirable plants. Preferably, application as a post-emergence treatment (i.e., during and / or after the emergence of undesirable plants). Where the mixtures of the present invention are applied to the site where the crops will be planted, before planting or emergence of the crops.

[0084] Accordingly, the present invention also relates to a method for burn-down treatment of undesirable vegetation in crops, comprising applying the mixture of the present invention to the site where crops will be planted before planting (or sowing) or germination of the crops, wherein the mixture of the present invention is applied to the undesirable vegetation or the site thereof.

[0085] Accordingly, the present invention relates to a method for controlling undesirable vegetation, the method comprising applying the mixture of the present invention to a place where undesirable vegetation is present or is expected to be present, wherein the application can be carried out before, during and / or after, preferably during and / or after, the emergence of the undesirable vegetation.

[0086] As used herein, the terms "to control" and "to exterminate" are synonymous.

[0087] As used herein, the terms “undesirable vegetation,” “undesirable species,” “undesirable plants,” “harmful plants,” “undesirable weeds,” or “harmful weeds” are synonymous.

[0088] As used herein, the term “place” means an area where vegetation or plants are growing or will grow, typically a field.

[0089] In such a burn-down program, the mixture of the present invention may be applied before or after sowing (planting) of the crop, but is applied before crop emergence, especially before sowing. The mixture of the present invention is preferably applied before sowing of the crop. For burn-down, the mixture of the present invention will generally be applied up to 9 months before crop planting, often up to 6 months before, preferably up to 4 months before. Burn-down application can be carried out up to 1 day before crop emergence, preferably on the day before sowing / planting, preferably at least 1 day before planting, preferably at least 2 days before, especially at least 4 days before, or 6 months to 1 day before emergence, especially 4 months to 2 days before emergence, more preferably 4 months to 4 days before emergence. Naturally, within that time frame, burn-down application can be repeated one or more times, for example, 1, 2, 3, 4, or 5 times.

[0090] A particular advantage of the mixtures of the present invention is that they have extremely good post-emergence herbicidal activity, that is, they exhibit excellent herbicidal activity against emerging undesirable plants. Therefore, in preferred embodiments of the present invention, the mixtures of the present invention are applied after emergence, i.e., during and / or after the emergence of undesirable plants. It is particularly advantageous to apply the mixtures of the present invention after emergence, from when the undesirable plants begin to develop leaves until they flower. The mixtures of the present invention are particularly useful for controlling undesirable vegetation that has already developed to a point where conventional burn-down mixtures are difficult to control (i.e., when individual weeds are taller than 10 cm (4 inches) or even taller than 15 cm (6 inches)), and / or against dense weed populations.

[0091] In the case of post-emergence treatment of plants, the mixture of the present invention is preferably applied by foliar application.

[0092] If active compounds I and II are not sufficiently tolerated by certain crops, an application technique can be used in which the herbicide composition is sprayed using a sprayer in such a manner that the active compounds reach the leaves of undesirable plants growing beneath the crop or the soil surface in open fields, but do not come into contact with the leaves of susceptible crops as much as possible (post-directed, lay-by). Furthermore, a spray shield may also be used.

[0093] Application can be carried out, for example, by conventional spraying techniques using water as a carrier, typically with a spray mixture volume of 10-2000 L / ha, particularly 50-1000 L / ha. The required application rate of the pure active compound mixture depends on the density of undesirable vegetation, the stage of plant development, the climatic conditions of the site where the mixture is used, and the application method. Generally, the application rate of the mixture is 55-6000 g / ha, preferably 100-5000 g / ha, 200-4000 g / ha, and more preferably 300-3000 g / ha of the active ingredient (ai).

[0094] When the mixture of the present invention is used in the method of the present invention, the active compounds present in the mixture of the present invention can be applied simultaneously or sequentially to areas where undesirable vegetation may develop. Here, it is not important whether the individual compounds present in the mixture of the present invention are formulated together or separately, whether they are applied together or separately, or, in the case of separate applications, the order in which they are applied. The only requirement is that the individual compounds present in the mixture of the present invention are applied within a time frame that allows for the simultaneous action of the active ingredients on the undesirable plants.

[0095] As described above, the mixture of the present invention has several advantages, namely enhanced herbicidal activity, compared to a mixture of racemic glufosinate and herbicide compound II.

[0096] Furthermore, the mixture of the present invention exhibits sustained herbicidal activity even under severe weathering conditions, which allows for more flexible application in burn-down applications and minimizes the risk of weed escaping. Separately, the mixture of the present invention shows excellent crop compatibility with certain conventional crops and herbicide-resistant crops; that is, the use of the mixture of the present invention in these crops results in reduced crop damage and / or no increased crop damage. Therefore, the mixture of the present invention can also be applied after crop emergence. The mixture of the present invention may also exhibit a rapid action on harmful plants; that is, the mixture of the present invention can cause damage to harmful plants more rapidly compared to a mixture of racemic glufosinate and herbicide compound II.

[0097] Both L-glufosinate alone and the mixture of the present invention in the method of the present invention are effective against monocotyledonous weeds, especially annual weeds, such as grasses (Poaceae plants), such as species of the genus Echinochloa, such as barnyardgrass (Echinochloa crusgalli var. crus-galli), Echinochloa walteri (Pursh) Heller, jungle rice (Echinochloa colona), giant barnyardgrass (Echinochloa crus-pavonis), Echinochloa oryzicola, and species of the genus Digitaria, such as crabgrass (Digitaria sanguinalis), Digitaria sanguinalis (horizontalis), sourgrass (Digitaria insularis) or naked crabgrass (Digitaria nuda), species of the genus Setaria, such as green foxtail (Setaria viridis), giant foxtail (Setaria faberii), yellow foxtail (Setaria glauca or Setaria pumila) or rough foxtail (Setaria verticillata), species of the genus Sorghum, such as johnsongrass (Sorghum halepense Pers.), species of the genus Avena, such as wild oat (Avena fatua), Avena sterilis (Avena (sterillis) or European tea plant (Avena strigosa), species of the genus Cenchrus, such as field sandbur (Cenchrus pauciflorus) or common sandbur (Cenchrus echinatus), species of the genus Bromus, such as Bromus (Bromusjaponicus Thunb), Bromus sterilis or Bromus tectorum, species of the genus Lolium, species of Phalaris, such as Phalaris brachystachys, Phalaris minor or Phalaris persicaria, species of Eriochloa, species of Panicum, such as fall panicum (Panicum dichotomiflorum), Panicum fasciculatum or Guinea millet (Panicum maximum), species of Brachiaria, annual bluegrass (Poa Species of the genus Alopecurus, such as blackgrass (Alopecurus myosuroides), blackgrass (Alopecurus aequalis Sobol), or sedge (Alopecurus japonicus Steud); species of the genus Aegilops, such as goatgrass (Aegilops cylindrica) or sedge (Aegylops tauschii); European bracken (Apera spica-venti); goosegrass (Eleusine indica); gypsum grass (Cynodon dactylon); couchgrass (Agropyron repens or Elymus repens); dwarf bracken (Agrostis alba); and beckmannia. syzigachne (Steud.) Fernald), species of the genus Chloris, e.g., Chloris virgata, species of the genus Commelina, e.g., Commelina benghalensis, Commelina communis, Commelina diffusa or CommelinaLeptochloa erecta), Dactyloctenium aegyptium, Hordeum jubatum, Hordeum leporinum, Imperata cylindrica, Ischaemum rogusum, Ixophorus unisetus, Leerisa hexandra, Leersia japonica, species of the genus Leptochloa, such as Leptochloa chinensis, Leptochloa fascicularis, Leptochloa filiformis or Leptochloa panicoides, species of the genus Lolium, such as Lolium multiflorum), Lolium perenne, Lolium persicum or rigid ryegrass (Lolium rigidum), Luziola subintegra, Murdannia nudiflora (L.) Brenan, Oryza latifolia, Oryza rufipogon, Paspalum distichum, species of Paspalum, Pennisetum americanum, Pennisetum purpureum, Phleum paniculatum, Phragmites australia, Ploypogon fugax. N.), species of the genus Poa, such as Poa trivialis L., Puccinellia distans, Rottboellia cochinchinensis, and Sclerochloa kengiana (Ohwi)It is suitable for controlling numerous harmful plants in crops, including Tzvel., Trichloris crinita, species of the genera Urochloa or Brachiaria, such as Brachiaria decumbens, Brachiaria plantaginea, Brachiaria platyphylla, Urochloa panicoides, and Urochloa ramosa.

[0098] Both L-glufosinate alone and the mixture of the invention are effective against numerous dicotyledonous weeds, particularly species of the genus Polygonum, such as wild buckwheat (Polygonum convolvolus), Polygonum pensilvanicum, Polygonum persicaria, or prostrate knotweed (Polygonum aviculare); species of the genus Amaranthus, such as pigweed (Amaranthus retroflexus), palmer amaranth (Amaranthus palmeri), tall waterhemp (Amaranthus tuberculatus or Amaranthus rudis), and redroot Pigweed (Amaranthus retroflexus), green amaranth (Amaranthus hybridus), purple amaranth (Amaranthus lividus), prickly amaranth (Amaranthus spinosus) or Amaranthus quitensis, species of the genus Chenopodium, such as common lambsquarter (Chenopodium album L.), small lambsquarter (Chenopodium serotinum) or quinoa (Chenopodium quinoa), species of the genus Sida, such as prickly sida (Sida spinosa L.), species of the genus Ambrosia, such as common ragweed (Ambrosia) Ambrosia artemisiifolia (ragweed) or giant ragweed (Ambrosia)Species of the genus *Trifida*, species of *Acanthospermum*, species of the genus *Anthemis*, such as *Anthemis arvensis* or *Anthemis cotula*, species of the genus *Atriplex*, species of the genus *Cirsium*, such as *Cirsium arvense*, species of the genus *Convolvulus*, such as field bindweed (*Convolvulus arvensis*), species of the genus *Conyza*, such as *Conyza canadensis*, *Erigeron canadensis*, or hairy fleabane (*Conyza bonariensis*, *Erigeron*). Species of the genus Cassia (bonariensis), species of the genus Datura, such as Datura stramonium, species of the genus Euphorbia, such as toothed spurge (Euphorbia dentata), Euphorbia hirta, Euphorbia helioscopia or fireplant (Euphorbia heterophylla), species of the genus Geranium, such as Geranium donianum or Geranium pusillum, species of Galinsoga, morning glory (morning Species of the genus Ipomoea (glory), species of Lamium, such as henbit dead-nettle (Lamium amplexicaule), species of Malva, such as dwarf mallow (Malva neglecta) or cheeseweed (Malwa parviflora), species of Matricaria, such as chamomile (Matricaria chamomile)Chamomilla (or Matricaria inodora), species of the genus Sysimbrium, species of the genus Solanum, such as black nightshade (Solanum nigrum), species of the genus Xanthium, species of the genus Veronica, such as speedwell (Veronica polita), species of the genus Viola, common chickweed (Stellaria media), Abutilon theophrasti, species of the genus Sesbania, such as American horned sesbania (Sesbania exaltata), Sesbania herbacea, or hemp sesbania (American horned sesbania (Sesbania exaltata) Cory)), Anoda cristata, species of the genus Bidens, such as Bidens frondosa or Bidens pilosa, Brassica kaber, species of the genus Capsella, such as Capsella media or Capsella bursa-pastoris, Centaurea cyanus, Galeopsis tetrahit, Galium aparine, Helianthus annuus, Desmodium tortuosum, Kochia scoparia, Mercurialis annua, Myosotis Poppies (Papaver rhoeas), species of the genus Raphanus, such as wild radish (Raphanus raphanistrum), species of the genus Salsola, such as Salsola tragus or Salsola kali, and wild mustard (Sinapis)Species of the genus Sonchus, such as sonchus asper, sonchus arvensis, or sonchus oleraceus, thlaspi arvense, tagetes minuta, species of the genus Richardia, such as Richardia scabra or Richardia brasiliensis, species of the genus Aeschynomeme, such as Aeschynomene denticulata, Aeschynomene indica, or Aeschynomene rudis, species of the genus Alisma, such as Alisma Alisma plantago-aquatica (canaliculatum), species of Borrelia, such as Borrelia verticillata, Brassica rapa, Carduus acanthoides, Parietaria debilis, Portulaca oleracea, species of Ipomoea, such as Ipomoea grandifolia, Ipomoea hederacea, Ipomoea indivisa, Ipomoea lacunose, Ipomoea lonchophylla or Ipomoea wrightii, and Senna obtusifolia. (obtusifolia), species of the genus Sida, such as arrowleaf sida (Sida rhombifolia) or prikrysida (American sida), Spermacoce latifolia, and Tridax procambens.(Procumbens), Trianthema portulacastrum, Parthenium hysterophorus, Portulaca oleracea, Acalypha australis, Ammi majus, species of Atriplex, species of Orobanche, Merculalis annua, European spiny thistle, broad-leaved morning glory (Calystegia sepium), Stellaria media, species of Lamium, species of Viola, Celosia argentea, Melampodium divaricatum, Cleome viscosa, Molugo verticilatus), Borhevia erecta, species of Gomphrena, Nicandra physalodes, Ricinus communis, Geranium dissectum, species of Alternanthera, such as Alternanthera philoxeroides or Alternanthera tenella, species of Ammannia, such as Ammania coccinea, Anacamtodon fortunei Mitt., Anagallis arvensis, Aneilema keisak, Arenaria serpyllifolia), Argemone mexicana, Asphodelus tenuifolius, Atriplex patula, Bacopa rotundifolia, Rutabaga (Brassica)napus), species of the genus Caperonia, such as Caperonia castaneifolia or Caperonia palustris, Cephalanoplos segetum, Corynopus didymus, Crepis capillaris, Crepis tectorum, Croton lobatus, Descuminia sophia (L.), Descurainia pinnata, Echinodorus grandiflorus, Eclipta alba, Eclipta prostrata, and Eichhornia crenata. crassipes), species of the genus Eleocharis, horsetail (Equisetum arvense), buckwheat vine (Fallopia convolvulus), buckwheat vine (Fallopia convolvulus), American dwarf vine (Heteranthera limosa), species of the genus Jussiaea, Kallstroemia maxima, Lactuca serriola, Lathyrus aphaca, Launea mudicaulis, Leucas chinensis, Limnocharis flava, American dwarf (arvense), species of the genus Ludwigia, such as Ludwigia octovallis, Macroptilium lathyroides, and Malachium akachicum.Aquaticum (L.), species of the genus Melillotus, Merremia aegyptia, Momordica charantia, Monochoria hasatea, Monochoria vaginalis, species of the genus Mucuna, Oxalis neaei, species of the genus Phylanthus, species of Physalis, Pistia stratiotes, Potamogeton distinctus, Rorippa islandica, Rotala indica, Rotala ramosior, Rumex dentatus), Rumex obtusifolius, Sagittaria montevidensis, Sagittaria pygmaea Miq., Sagittaria sagittifolia, Sagittaria trifolia L., Senecio vulgaris, Sicyos polyacanthus, Silene gallica, species of the genus Sisymbrium, such as Sisymbrium oficinale, species of the genus Solanum, Spergula arvensis, Sphenocrypha japonica It is also suitable for controlling broadleaf weeds, including species of the genus Trianthema (Zeylanica), Tripleurospermum inodorum, and species of the genus Veronica, such as Veronica persica or Veronica polifolia, and Vicia sativa.

[0099] Both L-glufosinate alone and the mixture of the invention are effective against species of the genus Cyperus, such as purple nutsedge (Cyperus rotundus L.), yellow nutsedge (Cyperus esculentus L.), hime-kugu (Cyperus brevifolius H.), sedge weed (Cyperus microiria Steud), rice flatsedge (Cyperus iria L.), difformis (Cyperus difformis L.), edible sedge, golden sedge (Cyperus ferax), and Cyperus flavus (Cyperus flavus), Cyperus lanceolatus, Cyperus odoratus, Cyperus rotundus, Cyperus serotinus Rottb., Eleocharis acicularis, Eleocharis kuroguwai, Fimbristylis dichotoma, Fimbristylis miliacea, Scirpus grossus, Scirpus juncoides, Scirpus juncoides Roxb, Scirpus maritimus or Bolboschoenus maritimus, Scirpus or Schoenoplectus It is also suitable for controlling numerous annual and perennial sedge weeds, including *Cyperus mucronatus* and *Scirpus planiculmis Fr. Schmidt*.

[0100] Both L-glufosinate alone and the mixture of the invention are also suitable for controlling weeds that are resistant to commonly used herbicides, such as weeds resistant to glyphosate, weeds resistant to auxin inhibitor herbicides, such as 2,4-D or dicamba, weeds resistant to photosynthesis inhibitors, such as atrazine, weeds resistant to ALS inhibitors, such as sulfonylurea, imidazolinone or triazolopyrimidine, weeds resistant to ACCase inhibitors, such as clodinahop, cretodym or pinoxadene, or weeds resistant to protoporphyrinogen IX oxidase inhibitors, such as sulfenthrazone, flumioxazine, homeaphen or acifoulphen, such as weeds listed in the International Survey of Resistant Weeds (http: / / www.weedscience.org / Summary / SpeciesbySOATable.aspx). In particular, these include ACCase-resistant weeds listed in the International Survey of Resistant Weeds, such as barnyard grass, wild oat, foxtail millet, dwarf barnyard grass, sedge grass, common brown grass, wheatgrass (Hordeum murinum), Taiwanese japonica, foxtail grass, sorghum halepense, barnyard grass, European bracken, Avena sterilis, Beckmannia szygachne, Bromus diandrus, crabgrass, Echinocloa oryzoides, barnyard grass (Echinochloa phyllopogon), dwarf canary grass, and false sedge (Phalaris) paradoxa), Setaria faberi, foxtail grass, Brachypodium distachyon, Blomus diandrus, wild tea grass, Cynosurus echinatus, Japanese pampas grass, northern pampas grass (Digitaria ischaemum), sedge grass, Phalaris brachystachysBrachystachis, Rotboellia cochinchinensis, Digitaria ciliaris, Ehrharta longiflora, Eriochloa punctata, Leptochlora panicoides, Elymus, Polypogon fugax, Sclerochlora kengiana, Snowdenia polystacha, Sudan grass and Brachiaria plantaginea, ALS inhibitor-resistant barnyard grass, annual bluegrass, wild oat, wild oat, small barnyard grass, slender blue marigold, large blue marigold, Amaranthus rudis, giant conyza (Conyza sumatrensis), blue marigold, ragweed (Ambrosia) Artemisifolia), Erigeron annuus, Kochia kochia, Sea radish, Senecio vernalis, Seto sedge, Bidens pilosa, Chlorophytum chinense, Laurel, Erigeron annuus, Wheatgrass, Taiwanese gentian, Senecio vulgaris, Foxtail grass, Sisymbrium orientale, Sorghum halepense, Sparrow's hornbeam, Amaranthus blitum, Amaranthus powellii, European bracken, Avena sterilis, Turnip, Blomus theandrus, Descurainia japonica Sophia), Digitaria sanguinalis, Echinocloa oryzoides, Barnyard grass, Epipactis thunbergii, Lactuca seriola, Phragmites australis, Setaria viridis, Setaria viridis, Setaria japonica, Solanum ptycanthum, Sow thistle, Chickweed, Amaranthus blitoides, Amaranthus viridis, Amaranthus viridis, Ambrosia trifoliata, Bidens subalternans, Blomus diandrus, Camellia japonica, Capsella bursa-pastoris, Cornflower, Sinothurus echinatus, Cyperus rotundus, Fimbristilismiliacea), Lamium amplexicaule, Galium spurium, Galium aparine, sunflower, Hirschfeldia incana, Limnocallis flava, Limnophila erecta, poppy, Parthenium histerophorus, Phalaris brachystachys, buckwheat vine, Polygonum lapathifolium, Polygonum humile, Ranunculus acris, horned leucobryum, Sagittaria trifolia, Sarsola tragus, dwarf sedge, golden foxtail, prickly sowthistle, cocklebur, Ageratum conyzoides, Sagittaria trifolia, Sagittaria sagittifolia, Ammannia auriculata auriculata), narrow-leaved loosestrife, Ammannia arvensis, false chamomile, Bacopa rotundifolia, Bifora radians, marsh marigold, Brassica tournefortii, sparrow's tea flea, black tea flea (Bromus secalinus), dog's purple, Camelina microcarpa, Chamaesyce maculata, garland chrysanthemum, American daisy (Clidemia hirta), Crepis tectrum, American dodder (Cuscuta pentagona), dwarf sedge (Cyperus brevifolis), sedge sedge (Cyperus Compressus), Edible Cyperus, Small Cyperus, Golden Cyperus, Damassonium minus, Diplotaxis erucoides, Roba Garlic (Diplotaxis tenuifolia), Dopatrum junceum, Plantago asiatica (Echium plantagineum), Stellaria media (Elatine triandra), Euonymus alatus, Erucaria hispanicaHispanica), Erysimum repandum, Galium tricornutum, Iva xanthifolia, Ixophorus unisetus, Lamium amplexicaule, Limnophila sessiliflora, Lindernia micrantha, Lindernia procumbens, Ludwigia prostrata, Matricaria recutita, Mesembryanthemum crystallinum, Monochoria korsakowii, Monochoria vaginalis, Myosoton aquaticum, Neslia paniculata, Rice (Oryza sativa var. sylvatica), Pentzia suffruticosa, Picrins hieracioides, Raphanus sativus, Rapistrum rugosum, Rorippa indica, Rotala pusilla, Rumex japonicus, Sagittaria guayensis, Sagittaria trifolia, Sagittaria japonica, Schoenoplectus fluviatilis, Schoenoplectus juncoides, Schoenoplectus wallichii, Silene japonica, Sinapis alba, Sisymbrium ternugii thellungii), sorghum bicolor, field clover, shepherd's purse, dog chamomile (Tripleurospermum perforatum), Vaccaria hispanicaHispanica) and Vicia cracca, photosynthesis inhibitor-resistant barnyard grass, annual bluegrass, wild oak, dwarf barnyard grass, slender blue marigold, large blue marigold, Amaranthus rudis, giant wild aster, blue marigold, ragweed, dwarf edelweiss, kochia scoparia, sea radish, Senecio vernalis, Setaria viridis, Bidens pilosa, horse tea fern, white laver, wild aster, Taiwanese eye Reeds, ragwort, foxtail grass, dog's-foot vine, wild amaranth, long-leaved blue amaranth, European bracken, herring roe, turnip, crabgrass, red bellflower, small canary grass, false sedge, autumn foxtail grass, foxtail grass, wild rose, black nightshade, chickweed, American amaranth, blue amaranth, Bidens subalternans, mint kamojigusa, shepherd's purse, striped beard grass (Chloris) Barbata), Cyperus barbata, Echinochloa erecta, Epilobium ciliatum, Salix gracilistyla, Fiddlehead vine, Polygonum cuspidatum, Polygonum humile, Portulaca oleracea, Polygonum erythrorhizon, Golden foxtail, Solanum nigrum, Prickly sowthistle, Urochlora panicoides, Vulpia bromoides, Amaranthus albus, Amaranthus cruentus, Arabidopsis thaliana, Styrax japonica, Bidens tripartita, Chenopodium ficifolium, Chenopodium polyspermum, Crypsis schoenoides), Datura stramonium, Epilobium tetragonum, Galinsoga ciliata, Matricaria discoidea, Panicum capillare, Panicum stramonium, Plantago lagopus, Polygonum hydopiper, Polygonum pensylvanicum, Polygonummonspeliensis), Rostraria smyrnacea, Rumex acetosella, Setaria viridis and Urtica urens, PS-I electron conversion inhibitor-resistant Poa annua, Erigeron annuus, Erigeron philadelphicus, Setaria viridis, Bidens pilosa, Erigeron annuus, Amaranthus thunbergii, Arctotheca calendula, Epilobium angustifolium, Hedyotis verticillata, Solanum nigrum, Corylus sieboldiana, Convolvulus morsaria, Crassocephalum crepidioides, Cuphea cartagenensis Carthagensis), Erigeron philadelphicus, Gamochaeta pensylvanica, Landoltia punctata, Lepidium virginicum, Mazus fauriei, Mazus pumilus, Mitracarpus hirtus, Sclerochloa dura, Solanum americanum, and Youngia japonica), glyphosate-resistant annual bluegrass, small millet, narrow-leaved amaranth, large-leaved amaranth, amaranth rudis, giant foxtail grass, ragweed, dwarf edelweiss, broom cypress, sea radish, beggar-ticks, foxtail grass, wheatgrass, sorghum, turnip, Bromus diandrus, Lactuca ceriola, sow thistle, amaranth, giant ragweed, Japanese crape myrtle, broad-leaved rush, sunflower, Parthenium histerophora, broadleaf plantain (Plantago lanceolata), Sarsola tragus, Urochlora panicoides, small foxtail grass (Brachiaria eruciformis), chebocha finch (Bromus rubens), Chloris elataelata), Chloris truncata, Ophiopogon, Cynodon hirsutus, Lactuca saligna, Leptochloa virgata, Paspalum paniculatum and Tridax procambens, Microtubule assembly inhibitor-resistant barnyard grass, annual bluegrass, wild oat, wild hawkweed, long-horned amaranthus, foxtail grass, sorghum, hawkweed, cudweed and Fumaria densiflora densiflora), auxin herbicide-resistant barnyard grass, dwarf barnyard grass, narrow-leaved amaranth, amaranth rudis, giant horse chestnut, kochia cypress, sea radish, white laver (Chenopodimum album), dog's-foot rooster, whale grass, lactuca seriola, wild rose, sow thistle, chickweed, cotton grass, cornflower, northern crabgrass, dwarf henbit, red deadnettle, white star galar, double galar, Hirschfeldia incana, Limnocharis flava, Limnocharis erecta, common poppy, broadleaf plantain, mountain buttercup, musk thistle (Carduus nutans), dwarf thorny thistle (Carduus Pycnocephalus, Centaurea soltitialis, Centaurea stoebe, species of the genus Micranthos, European spiny thistle, striped spiderwort, giant snowflake It is also suitable for controlling Soliva sessilis and Euphorbia trigona, HPPD inhibitor-resistant Amaranthus lanceolata and Amaranthus rudis, PPO inhibitor-resistant Amaranthus japonica, Amaranthus lanceolata, Amaranthus lanceolata, Amaranthus rudis, Ragweed, Wild oat, Horseweed, Whale grass, Euonymus alatus and Senecio vernalis, Carotenoid biosynthesis inhibitor-resistant Hydrilla verticillata, Wild radish, Senecio vernalis and Barnyard grass, and VLCFA inhibitor-resistant Epipactis thunbergii, Wild oat and Barnyard grass.

[0101] The mixture of the present invention is suitable for controlling / manipulating common pests in fields where useful plants are planted (i.e., in crops). The mixture of the present invention is generally suitable for burn-down of undesirable vegetation in fields of the following crops: - Cereal crops, for example - Wheat (Triticum aestivum) and wheat-like crops, such as durum wheat (T. durum), einkorn wheat (T. monococcum), emmer wheat (T. dicoccon), and spelt wheat (T. spelta), rye (Secale cereale), rye wheat (Tritiosecale), and barley (Hordeum vulgare), and other cereal crops (small grain crops); - Maize (corn); Zea mays); - Sorghum (for example, sorghum bicolour); - Rice (Oryza spp. species, e.g., Oryza sativa and Oryza glaberrima); and - sugar cane etc. - Leguminous plants (Fabaceae), such as soybeans (Glycine max), peanuts (Arachis hypogaea), and cereals, such as Pisum sativum, pigeon peas and cowpeas, broad beans (Vicia faba), legumes of the genera Vigna and Phaseolus, and lentils (lens culinaris var.), etc.; - Brassicaceae family, such as canola (Brassica napus), rapeseed (OSR, Brassica napus), cabbage (B. oleracea var.), mustard (e.g., B. juncea), B. campestris, B. narinosa, B. nigra, and B. tournefortii; and turnip (Brassica rapa var.), etc.; - Other broadleaf crops, such as sunflowers, cotton, flax, linseed, sugar beets, potatoes, and tomatoes; - TNV crops (TNV: trees, nuts, and vines), such as grapes, citrus fruits, pome fruits (e.g., apples and pears, coffee, pistachios, and oil palm), and drupes (e.g., peaches, almonds, walnuts, olives, cherries, plums, and apricots); - Turf, pastures, and grazing land; - Onions and garlic; - Bulbous ornamental plants, such as tulips and daffodils; - Coniferous and deciduous trees, such as pine, fir, oak, maple, dogwood, hawthorn, crabapple, and buckthorn; and - Garden ornamental plants, such as roses, petunias, marigolds, and snapdragons.

[0102] The mixture of the present invention is particularly suitable for burn-down of undesirable vegetation in the fields of the following crops: small grain crops (e.g., wheat, barley, rye, rye wheat and durum wheat, rice, etc.), corn, sugarcane, sorghum, soybeans, cereals (e.g., peas, beans and lentils), peanuts, sunflowers, sugar beets, potatoes, cotton, cruciferous crops (e.g., rapeseed, canola, mustard, cabbage and turnips), turf, and pasture grass. Pastures, grapes, pomelo (e.g., apples and pears), drupes (e.g., peaches, almonds, walnuts, pecans, olives, cherries, plums and apricots), citrus fruits, coffee, pistachios, ornamental garden plants (e.g., roses, petunias, marigolds, snapdragons), bulbous ornamental plants (e.g., tulips and daffodils), conifers and deciduous trees (e.g., pine, fir, oak, maple, dogwood, hawthorn, crabapple and buckthorn).

[0103] The mixture of the present invention is most suitable for burn-down of undesirable vegetation in the fields of the following crops: small grain crops, e.g., wheat, barley, rye, rye and durum wheat; rice, maize, sugarcane, soybeans; cereals (e.g., peas, beans and lentils); peanuts; sunflowers; cotton; cruciferous crops (e.g., rapeseed, canola); turf; pasture; grazing land; grapes; drupes (e.g., peaches, almonds, walnuts, pecans, olives, cherries, plums and apricots); citrus fruits and pistachios.

[0104] The present invention further relates to the use of a mixture as defined herein for controlling undesirable vegetation in crops in a burn-down program, wherein the crop produced herein by genetic engineering or breeding is resistant to one or more herbicides and / or pathogens such as plant pathogenic fungi and / or insect attacks; preferably resistant to glufosinate.

[0105] Accordingly, as used herein, the term "crop" includes (crop) plants that have been modified by mutagenesis or genetic engineering to provide new traits to plants or to alter existing traits.

[0106] Mutagenesis techniques include, for example, random mutagenesis using X-rays or mutagenic chemicals, as well as targeted mutagenesis techniques for inducing mutations at specific gene loci in the plant genome. Targeted mutagenesis techniques often utilize oligonucleotides or proteins such as CRISPR / Cas, zinc finger nucleases, TALENs, or meganucleases to achieve a targeted effect.

[0107] Genetic engineering typically uses recombinant DNA technology to generate mutations in plant genomes that are not readily obtained in natural environments through crossbreeding, mutagenesis, or natural recombination. Typically, one or more genes are incorporated into the plant genome to add or improve traits. These incorporated genes are also referred to as transgenes in the art, and plants containing such transgenes are called transgenic plants. Plant transformation methods usually result in several transformation events, each differing in the genomic locus in which the transgene is incorporated. Plants containing a specific transgene on a particular genomic locus are usually described as containing a specific “event” referred to by a specific event name. Traits introduced or modified in plants include, in particular, herbicide resistance, insect resistance, increased yield, and tolerance to abiotic conditions such as drought.

[0108] Herbicide resistance is produced through mutagenesis and genetic engineering. Plants resistant to acetolactate synthase (ALS) inhibitor herbicides through conventional mutagenesis and breeding methods include plant varieties marketed under the Clearfield® name. However, the majority of herbicide resistance traits are produced through the use of transgenes.

[0109] Herbicide resistance has been developed against glyphosate, glufosinate, 2,4-D, dicamba, oxynyl herbicides (such as bromoxynil and ioxynil), sulfonylurea herbicides, ALS inhibitor herbicides, and 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors (such as isoxaflutol and mesotrione).

[0110] Transgenes used to provide herbicide resistance traits include: transgenes for resistance to glyphosate: cp4 epsps, epsps grg23ace5, mepsps, 2mepsps, gat4601, gat4621 and goxv247; transgenes for resistance to glufosinate: pat and bar; transgenes for resistance to 2,4-D: aad-1 and aad-12; transgene for resistance to dicamba: dmo; transgene for resistance to oxynyl herbicides: bxn; transgenes for resistance to sulfonylurea herbicides: zm-hra, csr1-2, gm-hra, S4-HrA; transgenes for resistance to ALS inhibitor herbicides: csr1-2; transgenes for resistance to HPPD inhibitor herbicides: hppdPF, W336 and avhppd-03.

[0111] Transgenic maize events involving herbicide resistance genes include, but are not excluded, DAS40278, MON801, MON802, MON809, MON810, MON832, MON87411, MON87419, MON87427, MON88017, MON89034, NK603, GA21, MZHG0JG, HCEM485, VCO-O1981-5 (where the O in "O1981" is written with a stroke in the original text), 676, 678, 680, 33121, 4114, 59122, 98140, Bt10, Bt176, CBH-351, DBT418, DLL25, MS3, MS6, MZIR098, T25, TC1507, and TC6275.

[0112] Transgenic soybean events involving herbicide resistance genes include, but are not excluded, GTS 40-3-2, MON87705, MON87708, MON87712, MON87769, MON89788, A2704-12, A2704-21, A5547-127, A5547-35, DP356043, DAS44406-6, DAS68416-4, DAS-81419-2, GU262, SYHTOH2 (where O is written as a stroked O in the original text), W62, W98, FG72, and CV127.

[0113] Transgenic cotton events containing herbicide resistance genes include, but do not exclude, 19-51a, 31707, 42317, 81910, 281-24-236, 3006-210-23, BXN10211, BXN10215, BXN10222, BXN10224, MON1445, MON1698, MON88701, MON88913, GHB119, GHB614, LLCotton25, T303-3, and T304-40.

[0114] Transgenic canola events involving herbicide resistance genes include, but are not excluded, MON88302, HCR-1, HCN10, HCN28, HCN92, MS1, MS8, PHY14, PHY23, PHY35, PHY36, RF1, RF2, and RF3.

[0115] Insect resistance is primarily generated by transgenerating bacterial genes for insecticidal proteins into plants. The most frequently used transgenes are toxin genes from Bacillus species and their synthetic mutants, such as cry1A, cry1Ab, cry1Ab-Ac, cry1Ac, cry1A.105, cry1F, cry1Fa2, cry2Ab2, cry2Ae, mcry3A, ecry3.1Ab, cry3Bb1, cry34Ab1, cry35Ab1, cry9C, vip3A(a), and vip3Aa20. However, plant-derived genes are also transgenerated into other plants, particularly genes encoding protease inhibitors such as CpTI and pinII. A further approach involves using transgenes to generate double-stranded RNAs that target and downregulate insect genes in plants. An example of such a transgene is dvsnf7.

[0116] Transgenic maize events involving the genes or double-stranded RNA of insecticidal proteins include, but are not excluded, Bt10, Bt11, Bt176, MON801, MON802, MON809, MON810, MON863, MON87411, MON88017, MON89034, 33121, 4114, 5307, 59122, TC1507, TC6275, CBH-351, MIR162, DBT418, and MZIR098.

[0117] Transgenic soy events involving genes for insecticidal proteins include, for example, MON87701, MON87751, and DAS-81419, although this does not exclude others.

[0118] Transgenic cotton events containing genes for insecticidal proteins include, but do not exclude, SGK321, MON531, MON757, MON1076, MON15985, 31707, 31803, 31807, 31808, 42317, BNLA-601, Event1, COT67B, COT102, T303-3, T304-40, GFM Cry1A, GK12, MLS 9124, 281-24-236, 3006-210-23, GHB119, and SGK321.

[0119] The increase in yield is achieved by increasing ear biomass using the transgene athb17 present in maize event MON87403, or by enhancing photosynthesis using the transgene bbx32 present in soybean event MON87712.

[0120] Crops containing modified oil content have been created using the transgenes gm-fad2-1, Pj.D6D, Nc.Fad3, fad2-1A, and fatb1-A. Soybean events containing at least one of these genes are 260-05, MON87705, and MON87769.

[0121] Tolerance to abiotic conditions, particularly drought tolerance, is generated by using the transgene cspB contained in the maize event MON87460 and by using the transgene Hahb-4 contained in the soybean event IND-OO41O-5 (where O is written as a stroked O in the original text).

[0122] Traits are often combined by combining genes in a single transformation event or by combining different events during the breeding process. Preferred combinations of traits include herbicide resistance to different groups of herbicides, insect resistance to different types of insects (particularly resistance to lepidopteran and coleopteran insects), herbicide resistance with one or more types of insect resistance, herbicide resistance with increased yield, and herbicide resistance with tolerance to abiotic conditions.

[0123] Plants containing unique or cumulative traits, as well as the genes and events that provide these traits, are well known in the art. For example, detailed information on mutated or incorporated genes and each event is available from the International Service for the Acquisition of Agri-biotech Applications (ISAAA) website (http: / / www.isaaa.org / gmapprovaldatabase) and the Center for Environmental Risk Assessment (CERA) website (http: / / cera-gmc.org / GMCropDatabase), as well as from patent applications such as EP3028573 and WO2017 / 011288.

[0124] The use of the mixture of the present invention on crops may produce crop-specific effects that include certain genes or events. These effects may include changes in growth behavior or changes in resistance to biological or non-biological stressors. Such effects may include, in particular, increased yield, increased resistance, or tolerance to insect pathogens, nematode pathogens, fungal pathogens, bacterial pathogens, mycoplasma pathogens, viral pathogens, or viroid pathogens, as well as early vigor, early or delayed ripening, cold tolerance or heat tolerance, and changes in the spectrum or content of amino acids or fatty acids.

[0125] Furthermore, the use of recombinant DNA technology also includes plants containing modified or new components, particularly to improve raw material production, such as potatoes that produce increased amounts of amylopectin (e.g., Amflora® potato, BASF SE, Germany).

[0126] Preferably, the crops are resistant to glufosinate, and these glufosinate-resistant crops are preferably selected from the group consisting of rice, canola, soybeans, maize, and cotton plants.

[0127] Transgenic maize events involving glufosinate resistance genes include, but are not excluded, the following: 5307 x MIR604 x Bt11 x TC1507 x GA21 x MIR162 (event code: SYN-O53O7-1 x SYN-IR6O4-5 x SYN-BTO11-1 x DAS-O15O7-1 x MON-OOO21-9 x SYN-IR162-4, gene: pat, commercially available for example as Agrisure® Duracade® 5222) (where "MON" is not represented by an O with a stroke in the original text), 59122 (event code: DAS-59122-7, gene: pat, commercially available for example as Herculex® RW), 5307 x MIR604 x Bt11 x TC1507 x GA21 (Event code: SYN-O53O7-1 x SYN-IR6O4-5 x SYN-BTO11-1 x DAS-O15O7-1 x MON-OOO21-9, gene: pat, commercially available as, for example, Agrisure(registered trademark) Duracade(trademark) 5122) (wherein the original text, O other than "MON" is written with a stroke), 59122 x NK603 (Event code: DAS-59122-7 x MON-OO6O3-6, gene: pat, commercially available as, for example, Herculex(trademark) RW Roundup Ready(trademark) 2) (wherein the original text, O other than "MON" is written with a stroke), Bt10 (gene: pat, commercially available as, for example, Bt10), Bt11 (X4334CBR, X4734CBR) (Event code: SYN-BTO11-1, gene: pat, for example, commercially available as Agrisure(trademark) CB / LL) (The O here is written as a stroked O in the original text), BT11 x 59122 x MIR604 x TC1507 x GA21 (Event code: SYN-BTO11-1 x DAS-59122-7 x SYN-IR6O4-5 x DAS-O15O7-1 xMON-OOO21-9, gene: pat, commercially available for example as Agrisure(registered trademark) 3122) (where O's other than "MON" are written with a stroke in the original text), Bt11 x GA21 (event code: SYN-BTO11-1 x MON-OOO21-9, gene: pat, commercially available for example as Agrisure(trademark) GT / CB / LL) (where O's other than "MON" are written with a stroke in the original text), Bt11 x MIR162 (event code: SYN-BTO11-1 x SYN-IR162-4, gene: pat, commercially available for example as Agrisure(registered trademark) Viptera(trademark) 2100) (where O's are written with a stroke in the original text), Bt11 x MIR162 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x MON-OOO21-9, gene: pat, commercially available for example as Agrisure(registered trademark) Viptera(trademark) 3110) (where O other than "MON" is written with a stroke in the original text), BT11 x MIR162 x MIR604 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5, gene: pat, commercially available for example as Agrisure(registered trademark) Viptera(trademark) 3100) (where O is written with a stroke in the original text), Bt11 x MIR162 x MIR604 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x MON-OOO21-9, gene: pat, for example, commercially available as Agrisure(registered trademark) Viptera(trademark) 3111, Agrisure(registered trademark) Viptera(trademark) 4) (wherein the original text, O other than "MON" is written as a stroked O), Bt11 x MIR162 x TC1507 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x DAS-O15O7-1 x MON-OOO21-9, gene: pat, for example, Agrisure(trademark) Viptera(Commercially available as 3220) (Here, O other than "MON" is written with a stroke in the original text), Bt11 x MIR604 (Event code: SYN-BTO11-1 x SYN-IR6O4-5, gene: pat, for example, commercially available as Agrisure(trademark) CB / LL / RW) (Here, O is written with a stroke in the original text), BT11 x MIR604 x GA21 (Event code: SYN-BTO11-1 x SYN-IR6O4-5 x MON-OOO21-9, gene: pat, for example, commercially available as Agrisure(trademark) 3000GT) (Here, O other than "MON" is written with a stroke in the original text), Bt176 (176) (Event code: SYN-EV176-9, gene: bar, for example, NaturGard (marketed as KnockOut(trademark), Maximizer(trademark)), CBH-351 (event code: ACS-ZMOO4-3, gene: bar, for example marketed as Starlink(trademark)Maize) (the O here is written with a stroke in the original text), DBT418 (event code: DKB-89614-9, gene: bar, for example marketed as Bt Xtra(trademark)Maize), MON89034 x TC1507 x MON88017 x 59122 (event code: MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7, gene: pat, for example marketed as Genuity(registered trademark)SmartStax(trademark)) (the O here other than "MON" is written with a stroke in the original text), MON89034 x TC1507 x NK603 (Event code: MON-89O34-3 x DAS-O15O7-1 x MON-OO6O3-6, gene: pat, for example, commercially available as Power Core (trademark)) (wherein the original text, O other than "MON" is written as a stroked O), NK603 x T25 (Event code: MON-OO6O3-6 x ACS-ZMOO3-2, gene: pat, for example Roundup Ready (trademark) Liberty(Sold commercially as Link(trademark)Maize) (where O's other than "MON" are written with a stroke in the original text), T14 (Event code: ACS-ZMOO2-1, gene: pat, for example, sold commercially as Liberty Link(trademark)Maize) (where O's other than "MON" are written with a stroke in the original text), T25 (Event code: ACS-ZMOO3-2, gene: pat, for example, sold commercially as Liberty Link(trademark)Maize) (where O's other than "MON" are written with a stroke in the original text), T25 x MON810 (Event code: ACS-ZMOO3-2 x MON-OO81O-6, gene: pat, for example, sold commercially as Liberty Link(trademark)Yieldgard(trademark)Maize) (where O's other than "MON" are written with a stroke in the original text), TC1507 (Event code: DAS-O15O7-1, gene: pat, for example, commercially available as Herculex(trademark) I, Herculex(trademark) CB) (Here, O is written with a stroke in the original text), TC1507 × 59122 × MON810 × MIR604 x NK603 (Event code: DAS-O15O7-1 × DAS-59122-7 × MON-OO81O-6 × SYN-IR6O4-5 x MON-OO6O3, gene: pat, for example, commercially available as Optimum(trademark) Intrasect Xtreme) (Here, O other than "MON" is written with a stroke in the original text), TC1507 x 59122 (Event code: DAS-O15O7-1 x DAS-59122-7, gene: pat, for example Herculex (Commercially available as XTRA (trademark)) (The O here is written as a stroked O in the original text), TC1507 x 59122 x MON810 x NK603 (Event code: DAS-O15O7-1 x DAS-59122-7 x MON-OO81O-6 x MON-OO6O3-6, Gene: pat, for example, commercially available as Optimum (trademark) Intrasect XTRA) (The O here, other than "MON", is written as a stroked O in the original text), TC1507 x 59122 xNK603 (Event code: DAS-O15O7-1 x DAS-59122-7 x MON-OO6O3-6, gene: pat, commercially available for example as Herculex XTRA(trademark)RR) (wherein the original text, O other than "MON" is written with a stroke), TC1507 x MIR604 x NK603 (Event code: DAS-O15O7-1 x SYN-IR6O4-5 x MON-OO6O3-6, gene: pat, commercially available for example as Optimum(trademark)TRIsect) (wherein the original text, O other than "MON" is written with a stroke), TC1507 x MON810 x NK603 (Event code: DAS-O15O7-1 x MON-OO81O-6 x MON-OO6O3-6, gene: pat, commercially available for example as Optimum(trademark) Intrasect) (where O other than "MON" is written with a stroke in the original text), TC1507 x NK603 (event code: DAS-O15O7-1 x MON-OO6O3-6, gene: pat, commercially available for example as Herculex(trademark) I RR) (where O other than "MON" is written with a stroke in the original text), 3272 x Bt11 (event code: SYN-E3272-5 x SYN-BTO11-1, gene: pat) (where O is written with a stroke in the original text), 3272 x Bt11 x GA21 (event code: SYN-E3272-5 x SYN-BTO11-1 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), 3272 x Bt11 x MIR604 (event code: SYN-E3272-5 x SYN-BTO11-1 x SYN-IR6O4-5, gene: pat) (where O's other than "MON" are written with a stroke in the original text), 3272 x BT11 x MIR604 x GA21 (event code: SYN-E3272-5 x SYN-BTO11-1 x SYN-IR6O4-5 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), 33121(Event code: DP-O33121-3, gene: pat) (Here, O is written with a stroke in the original text), 4114 (Event code: DP-OO4114-3, gene: pat) (Here, O is written with a stroke in the original text), 59122 x GA21 (Event code: DAS-59122-7 x MON-OOO21-9, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), 59122 x MIR604 (Event code: DAS-59122-7 x SYN-IR6O4-5, gene: pat) (Here, O is written with a stroke in the original text), 5307 x MIR604 x Bt11 x TC1507 x GA21 x MIR162 (Event code: gene: pat), 59122 x MIR604 x GA21 (Event code: DAS-59122-7 x SYN-IR6O4-5 x MON-OOO21-9, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), 59122 x MIR604 x TC1507 (Event code: DAS-59122-7 x SYN-IR6O4-5 x DAS-O15O7-1, gene: pat) (Here, O is written with a stroke in the original text), 59122 x MIR604 x TC1507 x GA21 (Event code: gene: pat), (Event code: DAS-59122-7 x SYN-IR6O4-5 x DAS-O15O7-1 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), 59122 x MON810 (event code: DAS-59122-7 x MON-OO81O-6, gene: pat) (where O's other than "MON" are written with a stroke in the original text), 59122 x MON810 x NK603 (event code: DAS-59122-7 x MON-OO81O-6 x MON-OO6O3-6, gene: pat) (where O's other than "MON" are written with a stroke in the original text), 59122 x TC1507 x GA21 (event code: DAS-59122-7 x DAS-O15O7-1 xMON-OOO21-9, gene: pat) (where O is written with a stroke in the original text, except for "MON"), 676 (event code: PH-OOO676-7, gene: pat) (where O is written with a stroke in the original text), 678 (event code: PH-OOO678-9, gene: pat) (where O is written with a stroke in the original text), 680 (event code: PH-OOO68O-2, gene: pat), 98140 x 59122 (event code: DP-O9814O-6 x DAS-59122-7, gene: pat) (where O is written with a stroke in the original text), 98140 x TC1507 (event code: DP-O9814O-6 x DAS-O15O7-1, gene: pat) (O here is written with a stroke in the original text), 98140 x TC1507 x 59122 (event code: DP-O9814O-6 x DAS-O15O7-1 x DAS-59122-7, gene: pat) (O here is written with a stroke in the original text), 59122 x MON88017 (event code: DAS-59122-7 x MON-88O17-3, gene: pat) (O here other than "MON" is written with a stroke in the original text), Bt11 x 59122 (event code: SYN-BTO11-1 x DAS-59122-7, gene: pat) (O here is written with a stroke in the original text), Bt11 x 59122 x GA21 (Event code: SYN-BTO11-1 x DAS-59122-7 x MON-OOO21-9, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), Bt11 x 59122 x MIR604 (Event code: SYN-BTO11-1 x DAS-59122-7 x SYN-IR6O4-5, gene: pat) (Here, O is written with a stroke in the original text), Bt11 x 59122 x MIR604 x GA21 (Event code: SYN-BTO11-1 x DAS-59122-7 x SYN-IR6O4-5 x MON-OOO21-9, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), Bt11 x 59122 xMIR604 x TC1507 (Event code: Bt11 x 59122 x MIR604 x TC1507, gene: pat), Bt11 x 59122 x TC1507 (Event code: SYN-BTO11-1 x DAS-59122-7 x DAS-O15O7-1, gene: pat) (Here, O is written with a stroke in the original text), Bt11 x 59122 x TC1507 x GA21 (Event code: SYN-BTO11-1 x DAS-59122-7 x DAS-O15O7-1 x MON-OOO21-9, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), Bt11 x MIR162 x TC1507 (Event code: SYN-BTO11-1 x SYN-IR162-4 x DAS-O15O7-1, gene: pat) (where O is written with a stroke in the original text), Bt11 x MIR604 x TC1507 (event code: SYN-BTO11-1 x SYN-IR6O4-5 x DAS-O15O7-1, gene: pat) (where O is written with a stroke in the original text), Bt11 x TC1507 (event code: SYN-BTO11-1 x DAS-O15O7-1, gene: pat) (where O is written with a stroke in the original text), Bt11 x TC1507 x GA21 (event code D:SYN-BTO11-1 x DAS-O15O7-1 x MON-OOO21-9, Gene: pat), GA21 x T25 (Event code: MON-OOO21-9 x ACS-ZMOO3-2, Gene: pat) (Os other than "MON" here are written with a stroke in the original text), MIR162 x TC1507 (Event code: SYN-IR162-4 x DAS-O15O7-1, Gene: pat) (Os other than "MON" here are written with a stroke in the original text), MIR162 x TC1507 x GA21 (Event code: SYN-IR162-4 x DAS-O15O7-1 x MON-OOO21-9, Gene: pat) (Os other than "MON" here are written with a stroke in the original text), MIR604 x TC1507 (Event code: SYN-IR6O4-5 x DAS-O15O7-1, gene: pat) (Here, O is written with a stroke in the original text), MON87427 x MON89O34 x TC15O7 x MON88O17 x 59122 (Event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON89034 x 59122 (Event code: MON-89O34-3 x DAS-59122-7, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON89034 x 59122 x MON88017 (Event code: gene: pat), MON89034 x TC1507 (Event code: MON-89O34-3 x DAS-59122-7 x MON-88O17-3, gene: pat) (where O other than "MON" is written with a stroke in the original text), (Event code: MON-89O34-3 x DAS-O15O7-1, gene: pat) (where O other than "MON" is written with a stroke in the original text), MIR604 x TC1507 (Event code: SYN-IR6O4-5 x DAS-O15O7-1, gene: pat), MON87427 x MON89O34 x TC15O7 x MON88O17 x59122 (Event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON89034 x 59122 (Event code: MON-89O34-3 x DAS-59122-7, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON89034 x 59122 x MON88017 (Event code: Gene: pat), MON89034 x TC1507 (Event code: MON-89O34-3 x DAS-59122-7 x MON-88O17-3, gene: pat) (where O is written with a stroke in the original text, except for "MON"), (event code: MON-89O34-3 x DAS-O15O7-1, gene: pat) (where O is written with a stroke in the original text, except for "MON"), DLL25 (B16) (event code: DKB-8979O-5, gene: bar) (where O is written with a stroke in the original text), MIR604 x TC1507 (event code: SYN-IR6O4-5 x DAS-O15O7-1, gene: pat) (where O is written with a stroke in the original text), MON87427 x MON89O34 x TC15O7 x MON88O17 x 59122 (event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7, Gene: pat) (Os other than "MON" here are written with a stroke in the original text), MON89034 x 59122 (Event code: MON-89O34-3 x DAS-59122-7, Gene: pat) (Os other than "MON" here are written with a stroke in the original text), MON89034 x 59122 x MON88017 (Event code: MON-89O34-3 x DAS-59122-7 x MON-88O17-3, Gene: pat) (Os other than "MON" here are written with a stroke in the original text), MON89034 x TC1507 (Event code: MON-89O34-3 xDAS-O15O7-1, gene: pat) (Os other than "MON" here are written with a stroke in the original text), MON89034 x TC1507 x 59122 (Event code: MON-89O34-3 x DAS-O15O7-1 x DAS-59122-7, gene: pat) (Os other than "MON" here are written with a stroke in the original text), MON89034 x TC1507 x MON88017 (Event code: MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3, gene: pat) (Os other than "MON" here are written with a stroke in the original text), MON89034 x TC1507 x MON88017 x 59122 x DAS40278 (Event code: MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7 x DAS-4O278-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON89034 x TC1507 x MON88017 x DAS40278 (Event code: MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7 x DAS-4O278-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON89034 x TC1507 x NK603 x DAS40278 (Event code: MON-89O34-3 x DAS-O15O7-1 x MON-OO6O3-6 x DAS-4O278-9, gene: pat) (O other than "MON" here is written with a stroke in the original text), NK603 x MON810 x 4114 x MIR 604 (event code: MON-00603-6 x MON-00810-6 x DP004114-3 x SYN-IR604-4, gene: pat), TC1507 × MON810 × MIR604 × NK603 (event code: DAS-O15O7-1 × MON-OO81O-6 × SYN-IR6O4-5 × MON-OO6O3-6, gene: pat) (O other than "MON" here is written with a stroke in the original text), TC1507 x 59122x MON810 (Event code: DAS-O15O7-1 x DAS-59122-7 x MON-OO81O-6, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), TC1507 x 59122 x MON88017 (Event code: DAS-O15O7-1 x DAS-59122-7 x MON-88O17-3, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), TC1507 x GA21 (Event code: DAS-O15O7-1 x MON-OOO21-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), TC1507 x MON810 (Event code: DAS-O15O7-1 x MON-OO81O-6, gene: pat) (where O other than "MON" is written with a stroke in the original text), TC1507 x MON810 x MIR162 x NK603 (event code: DAS-O15O7-1 x MON-OO81O-6 x SYN-IR162-4 x MON-OO6O3-6, gene: pat) (where O other than "MON" is written with a stroke in the original text), 3272 x Bt11 x MIR604 x TC1507 x 5307 x GA21 (event code: SYN-E3272-5 x SYN-BTO11-1 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), TC1507 x MIR162 x NK603 (event code: DAS-O15O7-1 x SYN-IR162-4 x MON-OO6O3-6, gene: pat) (where O's other than "MON" are written with a stroke in the original text), TC1507 x MON810 x MIR162 (event code: DAS-O15O7-1 x MON-OO81O-6 x SYN-IR162-4, gene: pat) (where O's other than "MON" are written with a stroke in the original text), MON87419 (event code: MON87419-8, gene: pat), TC1507 x MON88017(Event code: DAS-O15O7-1 x MON-88O17-3, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), TC6275 (Event code: DAS-O6275-8, gene: bar) (Here, O is written with a stroke in the original text), MZHG0JG (Event code: SYN-OOOJG-2, gene: pat) (Here, O is written with a stroke in the original text), MZIR098 (Event code: SYN-OOO98-3, gene: pat) (Here, O is written with a stroke in the original text), Bt11 x MIR162 x MON89034 (Event code: SYN-BTO11-1 x SYN-IR162-4 x MON-89O34-3, gene: pat) (where O other than "MON" is written with a stroke in the original text) and Bt11 x MIR162 x MON89O34 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x MON-89O34-3 x MON-OOO21-9, gene: pat) (where O other than "MON" is written with a stroke in the original text), 59122 x DAS40278 (event code: DAS-59122-7 x DAS-4O278-9, gene: pat) (where O is written with a stroke in the original text), 59122 x MON810 x MIR604 (event code: DAS-59122-7 x MON-OO81O-6 x SYN-IR6O4-5, gene: pat) (where O's other than "MON" are written with a stroke in the original text), 59122 x MON810 x NK603 x MIR604 (event code: DAS-59122-7 x MON-OO81O-6 x MON-OO6O3-6 x SYN-IR6O4-5, gene: pat) (where O's other than "MON" are written with a stroke in the original text), 59122 x MON88017 x DAS40278 (event code: DAS-59122-7 x MON-88O17-3 x DAS-4O278-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), 59122 x NK603 x MIR604 (event code: DAS-59122-7 xMON-OO6O3-6 x SYN-IR6O4-5, gene: pat) (where O other than "MON" is written with a stroke in the original text), Bt11 x 5307 (event code: SYN-BTO11-1 x SYN-O53O7-1, gene: pat) (where O is written with a stroke in the original text), Bt11 x 5307 x GA21 (event code: SYN-BTO11-1 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (where O other than "MON" is written with a stroke in the original text), Bt11 x MIR162 x 5307 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-O53O7-1, gene: pat) (Here, O is written with a stroke in the original text), Bt11 x MIR162 x 5307 x GA21 (Event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), BT11 x MIR162 x MIR604 x 5307 (Event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x SYN-O53O7-1, gene: pat) (Here, O is written with a stroke in the original text), Bt11 x MIR162 x MIR604 x 5307 x GA21 (Event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x SYN-O53O7-1 x MON-OOO21-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), Bt11 x MIR162 x MIR604 x MON89034 x 5307 x GA21 (Event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x MON-89O34-3 x SYN-O53O7-1 x MON-OOO21-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), BT11 x MIR162 x MIR604 x TC1507 (Event code: SYN-BTO11-1 x)SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1, gene: pat) (O here is written with a stroke in the original text), BT11 x MIR162 x MIR604 x TC1507 x 5307 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (O here is written with a stroke in the original text), Bt11 x MIR162 x MIR604 x TC1507 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x MON-OOO21-9, gene: pat) (where O is written with a stroke in the original text, except for "MON"), Bt11 x MIR162 x TC1507 x 5307 (event code: SYN-BTO11-1 x SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (where O is written with a stroke in the original text), BT11 x MIR162 x MIR604 x TC1507 x 5307 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (where O is written with a stroke in the original text), Bt11 x MIR162 x MIR604 x TC1507 x GA21 (Event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x MON-OOO21-9, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), Bt11 x MIR162 x TC1507 x 5307 (Event code: SYN-BTO11-1 x SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (Here, O is written with a stroke in the original text), Bt11 x MIR162 x TC1507 x 5307 x GA21 (Event code: SYN-BTO11-1 xSYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (where O is written with a stroke in the original text, except for "MON"), Bt11 x MIR604 x 5307 (event code: SYN-BTO11-1 x SYN-IR6O4-5 x SYN-O53O7-1, gene: pat) (where O is written with a stroke in the original text), Bt11 x MIR604 x 5307 x GA21 (event code: SYN-BTO11-1 x SYN-IR6O4-5 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (where O is written with a stroke in the original text, except for "MON"), Bt11 x MIR604 x TC1507 x 5307 (Event code: SYN-BTO11-1 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (Here, O is written with a stroke in the original text), Bt11 x MIR604 x TC1507 x GA21 (Event code: SYN-BTO11-1 x SYN-IR6O4-5 x DAS-O15O7-1 x MON-OOO21-9, gene: pat) (Here, O other than "MON" is written with a stroke in the original text), Bt11 x MON89034 (or Bt11 x MON89O34) (Event code: SYN-BTO11-1 x MON-89O34-3, gene: pat) (where O's other than "MON" are written with a stroke in the original text), Bt11 x MON89034 x GA21 (event code: SYN-BTO11-1 x MON-89O34-3 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), Bt11 x MON89O34 x GA21 (event code: SYN-B TO11-1 x MON-89O34-3 x MON-OOO21-9, gene: pat) (where O is written with a stroke in the original text, except for "MON"), Bt11 x TC1507 x 5307 (event code: SYN-BTO11-1 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (where O is written with a stroke in the original text), Bt11 x TC1507 x 5307 x GA21 (event code: SYN-BTO11-1 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (where O is written with a stroke in the original text, except for "MON"), MIR162 x MIR604 x TC1507 x 5307 (Event code: SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, Gene: pat) (Here, O is written with a stroke in the original text), MIR162 x MIR604 x TC1507 x 5307 x GA21 (Event code: SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MIR162 x MIR604 x TC1507 x GA21 (Event code: SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), MIR162 x TC1507 x 5307 (event code: SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (where O's other than "MON" are written with a stroke in the original text), MIR162 x TC1507 x 5307 x GA21 (event code: SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), MIR604 x TC1507 x 5307(Event code: SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, Gene: pat) (Here, O is written with a stroke in the original text), MIR162 x TC1507 x 5307 (Event code: SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1, Gene: pat) (Here, O is written with a stroke in the original text), MIR162 x TC1507 x 5307 x GA21 (Event code: SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MIR604 x TC1507 x 5307 (Event code: SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, Gene: pat) (Here, O is written with a stroke in the original text), MIR604 x TC1507 x 5307 xGA21 (Event code: SYN-IR6O4-5 x TC1507 x SYN-O53O7-1 x MON-OOO21-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MIR604 x TC1507 x GA21 (Event code: SYN-IR6O4-5 x TC1507 x MON-OOO21-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON87427 x 59122 (Event code MON-87427-7 x DAS-59122-7, gene: pat), MON87427 x MON89034 x 59122 (event code: MON-87427-7 x MON-89O34-3 x DAS-59122-7, gene: pat) (where O other than "MON" is written with a stroke in the original text), MON87427 x MON89034 x MON88017 x 59122 (event code: MON-87427-7 x MON-89O34-3 x MON-88O17-3 x 59122, gene: pat) (where O other than "MON" is written with a stroke in the original text), MON87427 x MON89034 x TC1507(Event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON87427 x MON89034 x TC1507 x 59122 (Event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x DAS-59122-7, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON87427 x MON89034 x TC1507 x MON87411 x 59122 (Event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-87411-9 x DAS-59122-7, gene: pat) (Os other than "MON" here are written with a stroke in the original text), MON87427 x MON89034 x TC1507 x MON87411 x 59122 x DAS40278 (Event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-87411-9 x DAS-59122-7 x DAS-4O278-9, gene: pat) (Os other than "MON" here are written with a stroke in the original text), MON87427 x MON89034 x TC1507 x MON88017 (Event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3, gene: pat) (where O's other than "MON" are written with a stroke in the original text), MON87427 x TC1507 (event code: MON-87427-7 x DAS-O15O7-1, gene: pat) (where O's other than "MON" are written with a stroke in the original text), MON87427 x TC1507 x 59122 (event code: MON-87427-7 x DAS-O15O7-1 x DAS-59122-7, gene: pat) (where O's other than "MON" are written with a stroke in the original text), MON87427 x TC1507 x MON88017 (event code: MON-87427-7 x DAS-O15O7-1 xMON-88O17-3, gene: pat) (where O's other than "MON" are written with a stroke in the original text), MON87427 x TC1507 x MON88017 x 59122 (event code: MON-87427-7 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7, gene: pat) (where O's other than "MON" are written with a stroke in the original text), MON89034 x 59122 x DAS40278 (event code: MON-89O34-3 x DAS-59122-7 x DAS-4O278-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), MON89034 x 59122 x MON88017 x DAS40278 (Event code: MON-89O34-3 x DAS-59122-7 x MON-88O17-3 x DAS-4O278-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON89034 x TC1507 x 59122 x DAS40278 (Event code: MON-89O34-3 x DAS- O15O7-1 x DAS-59122-7 x DAS-4O278-9, Gene: pat) (Here, O other than "MON" is written with a stroke in the original text), MON89034 x TC1507 x DAS40278 (Event code: MON-89O34-3 x DAS-O15O7-1 x DAS-4O278-9, gene: pat) (where O is written with a stroke in the original text, except for "MON"), MON89034 x TC1507 x NK603 x MIR162 (event code: MON-89O34-3 x DAS-O15O7-1 x MON-OO6O3-6 x SYN-IR162-4, gene: pat) (where O is written with a stroke in the original text, except for "MON"), TC1507 x 5307 (event code: DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (where O is written with a stroke in the original text), TC1507 x 5307 x GA21 (event code: DAS-O15O7-1 x SYN-O53O7-1 xMON-OOO21-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), TC1507 x 59122 x DAS40278 (event code: DAS-O15O7-1 x DAS-59122-7 x DAS-4O278-9, gene: pat) (where O's other than "MON" are written with a stroke in the original text), TC1507 x 59122 x MON810 x MIR604 (event code: DAS-O15O7-1 x DAS-59122-7 x MON-OO81O-6 x SYN-IR6O4-5, gene: pat) (where O's other than "MON" are written with a stroke in the original text), TC1507 x 59122 x MON88017 x DAS40278 (Event code: DAS-O15O7-1 x DAS-59122-7 x MON-88O17-3 x DAS-4O278-9, gene: pat) (O other than "MON" here is written with a stroke in the original text), TC1507 x 59122 x NK603 x MIR604 (Event code: gene: pat), DAS-O15O7-1 x DAS-59122-7 x MON-OO6O3-6 x SYN-IR6O4-5, TC1507 x DAS40278 (Event code: DAS-O15O7-1 x DAS-4O278-9, gene: pat) (O other than "MON" here is written with a stroke in the original text), TC1507 x MON810 x MIR604 (Event code: DAS-O15O7-1 x MON-OO81O-6 x SYN-IR6O4-5, gene: pat) (where O other than "MON" is written with a stroke in the original text), TC1507 x MON810 x NK603 x MIR604 (event code: DAS-O15O7-1 x MON-OO81O-6 x MON-OO6O3-6 x SYN-IR6O4-5, gene: pat) (where O other than "MON" is written with a stroke in the original text), TC1507 x MON88017 x DAS40278 (event code: DAS-O15O7-1 x MON-88O17-3 xDAS-4O278-9, gene: pat) (where O other than "MON" is written with a stroke in the original text), and TC1507 x NK603 x DAS40278 (event code: DAS-O15O7-1 x MON-OO6O3-6 x DAS-4O278-9, gene: pat) (where O other than "MON" is written with a stroke in the original text).

[0128] Transgenic soy events involving glufosinate resistance genes include, but are not excluded, the following: A2704-12 (event code: ACS-GMOO5-3, gene: pat, commercially available, e.g., Liberty Link® soybean) (where O is written with a stroke in the original text), A2704-21 (event code: ACS-GMOO4-2, gene: pat, commercially available, e.g., Liberty Link® soybean) (where O is written with a stroke in the original text), A5547-127 (event code: ACS-GMOO6-4, gene: pat, commercially available, e.g., Liberty Link® soybean) (where O is written with a stroke in the original text), A5547-35 (event code: ACS-GMOO8-6, gene: pat, e.g., Liberty (Trademarked Link soybean) (The O here is written with a stroke in the original text), GU262 (Event code: ACS-GMOO3-1, Gene: pat, for example, a product marketed as Liberty Link soybean) (The O here is written with a stroke in the original text), W62 (Event code: ACS-GMOO2-9, Gene: pat, for example, a product marketed as Liberty Link soybean) (The O here is written with a stroke in the original text), W98 (Event code: ACS-GMOO1-8, Gene: pat, for example, a product marketed as Liberty Link soybean) (The O here is written with a stroke in the original text), DAS68416-4 (Event code: DAS-68416-4, Gene: pat, for example, a product marketed as Enlist Soybean), DAS44406-6 (Event code: DAS-444O6-6, gene: pat) (The O here is written with a stroke in the original text), DAS68416-4 x MON89788 (Event code: DAS-68416-4 x MON-89788-1, gene: pat), SYHTOH2(Event code: SYN-OOOH2-5, gene: pat) (where O is written with a stroke in the original text), DAS81419 x DAS44406-6 (Event code: DAS-81419-2 x DAS-444O6-6, gene: pat) (where O is written with a stroke in the original text), and FG72 x A5547-127 (Event code: MST-FGO72-3 x ACS-GMOO6-4, gene: pat) (where O is written with a stroke in the original text).

[0129] Transgenic cotton events containing glufosinate resistance genes include, for example, the following, though not excluding others: 3006-210-23 x 281-24-236 x MON1445 (event code: DAS-21O23-5 x DAS-24236-5 x MON-O1445-2, gene: bar, commercially available as, for example, WideStrike(trademark), Roundup Ready(trademark) Cotton) (wherein the original text, O other than "MON" is written as a stroked O), 3006-210-23 x 281-24-236 x MON88913 (event code: DAS-21O23-5 x DAS-24236-5 x MON-88913-8, gene: bar, for example, Widestrike(trademark) Roundup Ready (Commercially available as Flex(trademark)Cotton) (Here, O other than "MON" is written with a stroke in the original text), 3006-210-23 x 281-24-236 x MON88913 x COT102 (Event code: DAS-21O23-5 x DAS-24236-5 x MON-88913-8 x SYN-IR1O2-7, Gene: pat, e.g., Widestrike(trademark) x Roundup Ready Flex(trademark) x VIPCOT(trademark)Cotton) (Here, O other than "MON" is written with a stroke in the original text), GHB614 x LLCotton25 (Event code: BCS-GHOO2-5 x ACS-GHOO1-3, Gene: bar, e.g., GlyTol(trademark)Liberty (Commercially available as Link (trademark)) (The O here is written as a stroked O in the original text), GHB614 x T304-40 x GHB119 (Event code: BCS-GHOO2-5 x BCS-GHOO4-7 x BCS-GHOO5-8, Gene: bar, for example, commercially available as Glytol (trademark) x Twinlink (trademark)) (The O here is written as a stroked O in the original text), LLCotton25(Event code: ACS-GHOO1-3, gene: bar, for example, commercially available as ACS-GHOO1-3) (The O here is written with a stroke in the original text), GHB614 x T304-40 x GHB119 x COT102 (Event code: BCS-GHOO2-5 x BCS-GHOO4-7 x BCS-GHOO5-8 x SYN-IR1O2-7, gene: bar, for example, commercially available as Glytol(trademark) x Twinlink(trademark) x VIPCOT(trademark)Cotton) (The O here is written with a stroke in the original text), LLCotton25 x MON15985 (Event code: ACS-GHOO1-3 x MON-15985-7, gene: bar, for example, Fibermax(trademark) Liberty Link(trademark) Bollgard (Trademarked II) (where O is not in "MON" here, it is written as a stroked O in the original text), T304-40 x GHB119 (Event code: BCS-GHOO4-7 x BCS-GHOO5-8, gene: bar, for example, sold as TwinLink(trademark)Cotton) (where O is written as a stroked O in the original text), GHB614 x T304-40 x GHB119 x COT102 (Event code: BCS-GHOO2-5 x BCS-GHOO4-7 x BCS-GHOO5-8 x SYN-IR1O2-7, gene: bar, for example, sold as Glytol(trademark) x Twinlink(trademark) x VIPCOT(trademark)Cotton) (where O is written as a stroked O in the original text), GHB119 (Event code: BCS-GHOO5-8, gene: bar) (The O here is written with a stroke in the original text), GHB614 x LLCotton25 x MON15985 (Event code: CS-GHOO2-5 x ACS-GHOO1-3 x MON-15985-7, gene: bar) (The O here, other than "MON", is written with a stroke in the original text), MON 887O1-3 (Event code: MON88701, gene: bar) (The O here, other than "MON", is written with a stroke in the original text), T303-3(Event code: BCS-GHOO3-6, gene: bar) (O here is written as a stroked O in the original text), T304-40 (Event code: BCS-GHOO3-6, gene: bar), (Event code: BCS-GHOO4-7, gene: bar) (O here is written as a stroked O in the original text), 81910 (Event code: DAS-81910-7, gene: pat), MON8870 (Event code: MON 887O1-3, gene: bar) (O here other than "MON" is written as a stroked O in the original text), MON88701 x MON88913 (Event code: MON 887O1-3 x MON-88913-8, gene: bar) (O here other than "MON" is written as a stroked O in the original text), MON88701 x MON88913 x MON15985 (Event code: MON 887O1-3 x MON-88913-8 x MON-15985-7, Gene: bar) (Here, O other than "MON" is written with a stroke in the original text), 281-24-236 x 3006-210-23 x COT102 x 81910 (Event code: DAS-24236-5 x DAS-21O23-5 x SYN-IR1O2-7 x DAS-81910-7, Gene: pat) (Here, O is written with a stroke in the original text), COT102 x MON15985 x MON88913 x MON88701 (Event code: SYN-IR1O2-7 x MON-15985-7 x MON-88913-8 x MON 887O1-3, gene: bar) (where O other than "MON" is written with a stroke in the original text), and 3006-210-23 x 281-24-236 x MON88913 x COT102 x 81910 (event code: DAS-21O23-5 x DAS-24236-5 x MON-88913-8 x SYN-IR1O2-7 x DAS-81910-7, gene: pat) (where O other than "MON" is written with a stroke in the original text).

[0130] Transgenic canola events involving glufosinate resistance genes include, but are not excluded, the following: HCN10 (Topas 19 / 2) (event code:, gene: bar, commercially available, e.g., Liberty Link(trademark) Independence(trademark)), HCN28 (T45) (event code: ACS-BNOO8-2, gene: pat, commercially available, e.g., InVigor(trademark) Canola) (where O is written with a stroke in the original text), HCN92 (Topas 19 / 2 (event code: ACS-BNOO7-1, gene: bar, commercially available, e.g., Liberty Link(trademark) Innovator(trademark)) (where O is written with a stroke in the original text), MS1 (B91-4) (Event code: ACS-BNOO4-7, gene: bar, commercially available for example as InVigor(trademark) Canola) (The O here is written with a stroke in the original text), MS1 x RF1 (PGS1) (Event code: ACS-BNOO4-7 x ACS-BNOO1-4, gene: bar, commercially available for example as InVigor(trademark) Canola) (The O here is written with a stroke in the original text), MS1 x RF2 (PGS2) (Event code: ACS-BNOO4-7 x ACS-BNOO2-5, gene: bar, commercially available for example as InVigor(trademark) Canola) (The O here is written with a stroke in the original text), MS1 x RF3 (Event code: ACS-BNOO4-7 x ACS-BNOO3-6, gene: bar, commercially available for example as InVigor(trademark) Canola) (the O here is written with a stroke in the original text), MS8 (event code: ACS-BNOO5-8, gene: bar, commercially available for example as InVigor(trademark) Canola) (the O here is written with a stroke in the original text), MS8 x RF3 (event code: ACS-BNOO5-8 xACS-BNOO3-6, gene: bar, commercially available for example as InVigor(trademark) Canola) (where O is written with a stroke in the original text), RF1 (B93-101) (event code: ACS-BNOO1-4, gene: bar, commercially available for example as InVigor(trademark) Canola) (where O is written with a stroke in the original text), RF2 (B94-2) (event code: ACS-BNOO2-5, gene: bar, commercially available for example as InVigor(trademark) Canola) (where O is written with a stroke in the original text), RF3 (event code: ACS-BNOO3-6, gene: bar, commercially available for example as InVigor(trademark) Canola) (where O is written with a stroke in the original text), MS1 x MON88302 (event code: ACS-BNOO4-7 x MON-883O2-9, gene: bar, for example, commercially available as InVigor(trademark) x TruFlex(trademark) Roundup Ready(trademark) Canola) (where O other than "MON" is written with a stroke in the original text), MS8 x MON88302 (event code: ACS-BNOO5-8 x MON-883O2-9, gene: bar, for example, commercially available as InVigor(trademark) x TruFlex(trademark) Roundup Ready(trademark) Canola) (where O other than "MON" is written with a stroke in the original text), RF1 x MON88302 (event code: ACS-BNOO1-4 x MON-883O2-9, gene: bar, for example, commercially available as InVigor(trademark) x TruFlex(trademark) Roundup Ready(trademark) Canola) (where O other than "MON" is written with a stroke in the original text), RF2 x MON88302 (Event code: ACS-BNOO2-5 x MON-883O2-9, Gene: bar, for example, commercially available as InVigor(trademark) x TruFlex(trademark) Roundup Ready(trademark) Canola) (Here, O other than "MON" is written as a stroked O in the original text), HCN28 x MON88302(Event code: ACS-BNOO8-2 x MON-883O2-9, gene: pat, for example, commercially available as InVigor(trademark) x TruFlex(trademark) Roundup Ready(trademark) Canola) (Here, O other than "MON" is written with a stroke in the original text), HCN92 x MON88302 (Event code: ACS-BNOO7-1 x MON-883O2-9, gene: bar, for example, commercially available as Liberty Link(trademark) Innovator(trademark) x TruFlex(trademark) Roundup Ready(trademark) Canola) (Here, O other than "MON" is written with a stroke in the original text), HCR-1 (gene: pat), MON88302 x MS8 x RF3 (Event code: MON-883O2-9 x ACS-BNOO5-8 x ACS-BNOO3-6, gene: bar) (where O's other than "MON" are written with a stroke in the original text), MON88302 x RF3 (event code: MON-883O2-9 x ACS-BNOO3-6, gene: bar) (where O's other than "MON" are written with a stroke in the original text), MS8 x RF3 x GT73 (RT73) (event code: gene: bar), PHY14 (event code: ACS-BNOO5-8 x ACS-BNOO3-6 x MON-OOO73-7, gene: bar) (where O's other than "MON" are written with a stroke in the original text), PHY23 (gene: bar), PHY35 (gene: bar) and PHY36 (gene: bar) and 73496 x RF3 (event code: DP-O73496-4 x ACS-BNOO3-6, gene: bar) (The O here is represented as a stroked O in the original text).

[0131] Transgenic rice events involving glufosinate resistance genes include, but are not excluded, the following: LLRICE06 (event code: ACS-OSOO1-4, commercially available, e.g., as Liberty Link(trademark) rice) (where O is represented by a stroke in the original text), LLRICE601 (event code: BCS-OSOO3-7, commercially available, e.g., as Liberty Link(trademark) rice) (where O is represented by a stroke in the original text), and LLRICE62 (event code: ACS-OSOO2-5, commercially available, e.g., as Liberty Link(trademark) rice) (where O is represented by a stroke in the original text).

[0132] The mixture of the present invention can be applied by conventional methods using techniques familiar to those skilled in the art. Suitable techniques include, for example, spraying, scattering, powdering, spreading, or watering. The type of application will depend on the intended purpose of the well-known method, but in all cases, it is essential to ensure that the active ingredients of the present invention are dispersed as finely as possible.

[0133] In one embodiment, the mixture of the present invention is applied to the application site mainly by spraying, particularly by foliar spraying of an aqueous dilution of the active ingredient of the mixture. Application can be carried out by conventional spraying techniques, for example, using water as a carrier, with a spray volume of about 10 to 2000 L / ha or 50 to 1000 L / ha (e.g., 100 to 500 L / ha). Similar to application of the mixture of the present invention in the form of fine particles, application of the mixture of the present invention is possible by low-volume and ultra-low-volume methods.

[0134] The required application rate of the pure active compound mixture depends on the density of undesirable vegetation, the stage of plant development, the climatic conditions of the site where the mixture is used, and the application method.

[0135] Generally, the application rate of L-glufosinate is typically within the range of 50 g / ha to 3000 g / ha of active substance (ai), preferably 100 g / ha to 2000 g / ha or 200 g / ha to 1500 g / ha of active substance (ai), and the application rate of herbicide compound II is within the range of 1 g / ha to 2000 g / ha of active substance (ai), preferably 5 g / ha to 1500 g / ha, more preferably 25 g / ha to 900 g / ha of active substance (ai).

[0136] The following embodiments illustrate the present invention without imposing any limitations. [Examples]

[0137] Biological examples A synergistic effect can be described as an interaction where the effect of a combination of two or more compounds exceeds the sum of the individual effects of each compound. The existence of a synergistic effect on percentage control between two mixed partners (X and Y) can be calculated using Colby's formula (Colby, SR, 1967, Calculating Synergistic and Antagonistic Responses in Herbicide Combinations, Weeds, 15, 20-22):

[0138]

number

[0139] If the observed control effect of a combination exceeds the predicted (calculated) control effect (E) of the combination, the effect of the combination is synergistic.

[0140] The following tests demonstrate the control efficacy of the compounds, mixtures, or compositions of the present invention against specific weeds. However, the weed control provided by these compounds, mixtures, or compositions is not limited to these species. Synergistic or antagonistic effects between mixtures or compositions were determined using Colby's formula.

[0141] Test method: The cultivation containers used were plastic planters containing loamy sandy soil with approximately 3.0% humus as the base soil. Seeds of the test plants were sown separately for each species and / or resistance biotype. For pre-emergence treatment, the active ingredient, suspended or emulsified in water, was applied immediately after sowing using a fine spray nozzle. The containers were gently watered to promote germination and growth, and then covered with a transparent plastic hood until the plants took root. This cover ensured uniform germination, provided the test plants were not damaged by the active ingredient. For post-emergence treatment, the test plants were first grown to a height of 3-15 cm depending on their growth habit, and then treated for the first time with the active ingredient suspended or emulsified in water. For this purpose, the test plants were either sown directly and grown in the same container, or they were initially grown separately as seedlings and transplanted into the test containers a few days before treatment. The above plants were maintained at 10-25°C or 20-35°C, depending on the species. The test period extended to 20 days after treatment. During this period, the plants were cared for and their response to individual treatments was evaluated. The evaluation was performed using a scale from 0 to 100. "100" meant no plant sprouting or complete destruction of at least the above-ground parts, and "0" meant no damage or normal growth. The data shown are the average of two copies.

[0142] product: L-glufosinate: 5% EC formulation Triaziflam: 5% EC formulation Methiozoline: 250g / L SC preparation

[0143] [Table 3]

[0144] Example 1: Post-emergence treatment with a mixture of L-glufosinate and triaziphram

[0145] [Table 4]

[0146] Example 2: Post-budding treatment with a mixture of L-glufosinate and methiozoline

[0147] [Table 5] Examples of embodiments of the present invention include the following. [Embodiment 1] below: a) L-glufosinate and its salts as compound I; and b) Herbicide compound II A herbicide mixture comprising L-glufosinate in an amount of more than 70% by weight of an L-enantiomer. [Embodiment 2] The herbicide mixture according to Embodiment 1, wherein compound I is selected from the group consisting of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt, and L-glufosinate as a free acid. [Embodiment 3] The herbicide mixture according to Embodiment 1, wherein compound I is L-glufosinate-ammonium. [Embodiment 4] A herbicide mixture according to any one of Embodiments 1 to 3, comprising more than 80% by weight, preferably more than 90% by weight, and more preferably 95% by weight of L-glufosinate L-enantiomer. [Embodiment 5] A herbicide mixture according to any one of Embodiments 1 to 4, wherein compound II is chlorthiamide, diclobenyl, flupoxam, indadiflame, isoxaben, triaziflame, 1-cyclohexyl-5-pentafluorophenyloxy-14-[1,2,4,6]thiatriazine-3-ylamine, diflufenzopyr, diflufenzopyr-sodium, naptaram and naptaram-sodium, bromobutide, chlorflurenol, chlorflurenol-methyl, scinmethiline, cumylon, cyclopyrimorate and its salts and esters, darapon, dazomet, diphen Selected from the group consisting of Zocoat, diphenzocoat-methylsulfate, dimethipine, DSMA, dimuron, endotal and its salts, etobenzanide, flurenol, flurenol-butyl, flurprimidol, hosamine, hosamine-ammonium, indanophan, maleate hydrazide, mefluidide, metam, methiozoline, methyl azide, methyl bromide, methyl dimuron, methyl iodide, MSMA, oleic acid, oxadiclomefone, pelargonic acid, pyributicarb, quinoclamin, tridiphan; viranaphos (biaraphos) and viranaphos-sodium, Preferably, compound II is selected from the group consisting of diclobenyl, diflufenzopyr, diflufenzopyr-sodium, simmethyline, bromobutide, cyclopyrimorate and their salts and esters, endotal and oxadiclomefone. Preferably, the herbicide mixture wherein compound II is selected from the group consisting of diclobenyl, diflufenzopyr, diflufenzopyr-sodium, and simmethyline. [Embodiment 6] A herbicide mixture according to any one of Embodiments 1 to 4, wherein compound II is selected from the group consisting of scinmethiline, oxadiclomefone, indadiflame, triaziflame, indanophan, and methiozoline, Preferably, the herbicide mixture wherein compound II is selected from the group consisting of triaziflame, indanophan, methiozoline, and oxadiclomefone. [Embodiment 7] A herbicide mixture according to any one of Embodiments 1 to 4, wherein compound II is selected from the group consisting of triaziflame, indanophan, and methiozoline. [Embodiment 8] A herbicide mixture according to any one of Embodiments 1 to 7, wherein the weight ratio of compound I to compound II is 1000:1 to 1:500. [Embodiment 9] A pest-killing composition comprising a liquid carrier or a solid carrier and a mixture according to any one of Embodiments 1 to 8. [Embodiment 10] A method for controlling undesirable vegetation, comprising applying a mixture described in any of Embodiments 1 to 8 to a place where undesirable vegetation is present or is expected to be present. [Embodiment 11] The method according to Embodiment 10, comprising applying the mixture described in any of Embodiments 1 to 8 before crop emergence. [Embodiment 12] The method according to Embodiment 10, comprising applying the mixture described in any of Embodiments 1 to 8 before planting the crop. [Embodiment 13] The method according to any one of embodiments 10 to 12, wherein the crop is selected from rice, corn, cereals, cotton, canola, small grains, soybeans, peanuts, sugarcane, sunflowers, plantation crops, tree crops, nuts, and grapes. [Embodiment 14] The method according to any one of embodiments 10 to 13, wherein the crop is selected from glufosinate-tolerant crops. [Embodiment 15] The method according to any one of Embodiments 10 to 14, wherein compounds I and II of the mixture described in any one of Embodiments 1 to 8 are applied simultaneously, i.e., together, separately, or sequentially.

Claims

1. below: a) L-glufosinate and / or its salt as compound I; and b) At least one herbicide compound II which is a triaziflame A herbicide mixture for crops selected from corn, cotton and soybeans, comprising L-glufosinate in an amount of more than 70% by weight of an L-enantiomer, wherein the weight ratio of compound I to compound II is 1000:1 to 1:

500.

2. The herbicide mixture according to claim 1, wherein compound I is selected from the group consisting of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt, and L-glufosinate as a free acid.

3. The herbicide mixture according to claim 1, wherein compound I is L-glufosinate-ammonium.

4. The herbicide mixture according to any one of claims 1 to 3, wherein L-glufosinate comprises more than 80% by weight of an L-enantiomer.

5. The herbicide mixture according to any one of claims 1 to 3, wherein L-glufosinate comprises more than 90% by weight of the L-enantiomer.

6. The herbicide mixture according to any one of claims 1 to 3, wherein L-glufosinate comprises more than 95% by weight of the L-enantiomer.

7. A pest-killing composition comprising a liquid carrier or a solid carrier and a mixture according to any one of claims 1 to 6.

8. A method for controlling undesirable vegetation, comprising applying a mixture according to any one of claims 1 to 6 to a place where undesirable vegetation is present or is expected to be present.

9. The method according to claim 8, comprising applying the mixture according to any one of claims 1 to 6 before the emergence of a crop.

10. The method according to claim 8, comprising applying the mixture according to any one of claims 1 to 6 before planting a crop.

11. The method according to any one of claims 8 to 10, wherein the crop is selected from corn, cotton, and soybeans.

12. The method according to any one of claims 8 to 11, wherein the crop is selected from glufosinate-tolerant crops.

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