Carbon dioxide capture device

Abstract

To provide a configuration which can suppress variations in thermal load across the entire apparatus and enables continuous operation in a carbon dioxide recovery apparatus that performs a desorption process and an adsorption process through thermal control by a heat source unit of a heat pump type.SOLUTION: A heat exchange device 70 of a carbon dioxide recovery apparatus 1 includes a heat source unit 81 of a heat pump type, a heat source high-temperature water circuit 85 that includes a hot water tank 83 that stores hot water and circulates hot water between the hot water tank 83 and the heat source unit 81, a heat source low-temperature water circuit 86 that includes a cold water tank 82 that stores cold water and circulates cold water between the cold water tank 82 and the heat source unit 81, a hot water going line 112a that supplies hot water from the hot water tank 83 to a module 11, a hot water return line 112b that returns hot water after heating in the module 11 to the hot water tank 83, a cold water going line 111a that supplies cold water from the cold water tank 82 to the module 11, and a cold water return line 111b that returns cold water after cooling in the module 11 to the cold water tank 82.SELECTED DRAWING: Figure 5

Description

Technical Field

[0006] , ,

[0001] The present invention relates to a carbon dioxide recovery device.

Background Art

[0002] Conventionally, in a system that heats or cools a target device using a heat medium, a technique of using a heat source device such as a heat pump is known. For example, Patent Document 1 describes this type of technique. Patent Document 1 relates to an energy-saving ventilation and air conditioning system that maintains an air-conditioned space in a predetermined temperature and humidity state.

Prior Art Documents

Patent Documents

[0003]

Patent Document 1

Summary of the Invention

Problems to be Solved by the Invention

[0004] By the way, in a carbon dioxide recovery device that sucks a gas such as air containing carbon dioxide to an adsorbent held by a module, adsorbs it to the adsorbent, and then decompresses and heats the adsorbent to desorb the adsorbed carbon dioxide for carbon dioxide recovery, a heat source device such as a heat pump is also used.

[0005] The heat pump described in Patent Document 1 is premised on generating warm and cold heat at night when the power load is small in consideration of cutting the peak of the power load during the day. If a heat pump type heat source device of the prior art is directly applied to a carbon dioxide recovery device that may operate continuously regardless of day and night, the heat load fluctuation will become large.

[0006] An object of the present invention is to provide a configuration that can suppress the heat load fluctuation of the entire device and enable continuous operation in a carbon dioxide recovery device that performs a desorption step and an adsorption step by heat control of a heat pump type heat source device. [Means for solving the problem]

[0007] (1) The present invention includes a plurality of modules (for example, module 11, described later) which have an adsorbent (for example, adsorbent 12, described later) inside and perform an adsorption step of drawing a gas containing carbon dioxide onto the adsorbent to adsorb the carbon dioxide, and a desorption step of heating the adsorbent while the surrounding area is under reduced pressure to desorb the carbon dioxide, and a heating medium (for example, hot water, described later) which supplies a heating medium to each of the modules and a cooling medium (for example, cold water, described later) which supplies a cooling medium. The system comprises a heat exchanger (for example, a heat exchanger 70 described later) and a flow path control unit (for example, a three-way valve 30a described later) capable of selectively supplying the heating medium or the cooling medium to the module, wherein the heat exchanger includes a heat pump type heat source (for example, a heat source 81 described later) that heats the heating medium and cools the cooling medium, and a heating medium tank (for example, a hot water tank described later) that stores the heating medium heated by the heat source, and the heating medium tank and the heat source A high-temperature water circuit for the heat source (for example, a high-temperature water circuit for the heat source described later, 85) that circulates the heat transfer medium between the heat source and the module, a low-temperature water circuit for the heat source (for example, a low-temperature water circuit for the heat source described later, 86) that circulates the heat transfer medium between the cooling heat transfer medium tank and the heat source, a supply line for the heat transfer medium for the heat source (for example, a hot water supply line described later, 112a) that supplies the heat transfer medium from the heating heat transfer medium tank to the module, and the heating This carbon dioxide recovery device (e.g., carbon dioxide recovery device 1 described later) includes a heating medium return line (e.g., a hot water return line 112b described later) that returns the heating medium used for heating the module to the heating medium tank, a cooling medium supply line (e.g., a chilled water supply line 111a described later) that supplies the cooling medium from the cooling medium tank to the module, and a cooling medium return line (e.g., a chilled water return line 111b described later) that returns the cooling medium used for heating the module to the cooling medium tank after it has been cooled.

[0008] (2) In the carbon dioxide recovery apparatus described in (1) above, the flow path control unit is configured to control the flow path for each of the modules, and may supply the cooling heat transfer medium to the module that performs the adsorption step, and supply the heating heat transfer medium to the module that performs the desorption step.

[0009] (3) In the carbon dioxide recovery apparatus described in (2) above, the flow path control unit may be configured to adjust the flow rate of the cooling medium or the heating medium supplied to the module.

[0010] (4) In the carbon dioxide recovery apparatus described in (3) above, the flow path control unit may relatively increase the flow rate of the heating medium during the initial heating stage of the desorption process, and relatively decrease the flow rate of the heating medium during the temperature maintenance stage after the initial heating stage has elapsed.

[0011] (5) In the carbon dioxide recovery apparatus described in any of (1) to (4) above, the heat source high-temperature water circuit has a heat source supply line on the heat medium side that sends the heat medium from the heating heat medium tank to the heat source (for example, a hot water side heat source supply line 221 described later), and a heat source return line on the heat medium side that returns the heat medium from the heat source to the heating heat medium tank (for example, a hot water side heat source return line 222 described later), and the connection positions of each line in the heating heat medium tank may be set in the order of the heat source return line on the heat medium side, the heat medium supply line, the heat medium supply line on the heat medium side, and the heat medium return line from top to bottom.

[0012] (6) In the carbon dioxide recovery apparatus described in any of (1) to (4) above, the heat source low-temperature water circuit has a cooling heat medium side heat source supply line (for example, a chilled water side heat source supply line 121 described later) that sends the cooling heat medium from the cooling heat medium tank to the heat source, and a cooling heat medium side heat source return line (for example, a chilled water side heat source return line 122 described later) that returns the cooling heat medium from the heat source to the cooling heat medium tank, and the connection positions of each line in the cooling heat medium tank may be set in the order of cooling heat medium return line, cooling heat medium side heat source return line, cooling heat medium supply line, and cooling heat medium side heat source supply line from top to bottom. [Effects of the Invention]

[0013] According to the present invention, in a carbon dioxide recovery apparatus that performs a desorption process and an adsorption process by thermal control of a heat pump type heat source, it is possible to provide a configuration that suppresses fluctuations in the overall thermal load of the apparatus and enables continuous operation. [Brief explanation of the drawing]

[0014] [Figure 1] This is a schematic diagram showing the gas flow configuration of a carbon dioxide capture device according to one embodiment of the present invention. [Figure 2] This is a schematic diagram showing the configuration of the liquid flow in the carbon dioxide recovery device of this embodiment. [Figure 3] This is a schematic diagram showing the gas flow configuration of the carbon dioxide capture device module of this embodiment. [Figure 4] This is a schematic diagram showing the configuration of the liquid flow in the module of the carbon dioxide capture device of this embodiment. [Figure 5] This is a schematic diagram showing the configuration of the heat source circuit of the carbon dioxide capture device of this embodiment. [Figure 6] This is a schematic diagram showing the connection points of each line connected to the hot water tank. [Figure 7] This is a schematic diagram showing the connection points of each line connected to the chilled water tank. [Figure 8]It is a graph showing the time change of the adsorbent temperature and the heat medium flow rate in the desorption process. [Figure 9] It is a graph showing the time change of the heat exchange amount in the desorption process.

Embodiments for Carrying Out the Invention

[0015] Hereinafter, embodiments of the present invention will be described with reference to the drawings.

[0016] <Overall Configuration> FIG. 1 is a schematic diagram showing the configuration related to the gas flow of the carbon dioxide recovery device 1 according to an embodiment of the present invention. FIG. 2 is a schematic diagram showing the configuration related to the liquid flow of the carbon dioxide recovery device 1 of the present embodiment. In FIG. 1, the illustration of the configuration related to the liquid flow of the carbon dioxide recovery device 1 is omitted, and in FIG. 2, the illustration of the configuration related to the gas flow of the carbon dioxide recovery device 1 is omitted.

[0017] The carbon dioxide recovery device 1 of the present embodiment is applied to, for example, direct air capture technology (DAC: Direct Air Capture) for recovering carbon dioxide in the atmosphere in order to reduce the carbon dioxide concentration in the atmosphere. The carbon dioxide recovered by the carbon dioxide recovery device 1 is stored underground or reused as fuel or materials.

[0018] As shown in FIGS. 1 and 2, the carbon dioxide recovery device 1 of the present embodiment includes a module unit 10, a fan 61, a vacuum pump 62, a carbon dioxide recovery pump 63, an intercooler 64, a separator 65, a carbon dioxide tank 66, an inert gas tank 69, a heat exchanger 70, and a control device 90.

[0019] As shown in FIG. 1, the carbon dioxide recovery device 1 includes an adsorption line 101, a vacuum line 102, a carbon dioxide line 103, a circulation line 104, and an inert gas supply line 107 as gas flow paths.

[0020] The module unit 10 is composed of multiple modules 11 that adsorb carbon dioxide arranged in parallel. In this embodiment, a total of 16 modules 11 are arranged in a pair of left and right module units 10.

[0021] Figure 3 is a schematic diagram showing the gas flow configuration of module 11 of the carbon dioxide recovery device 1 of this embodiment. Module 11 is a carbon dioxide recovery module comprising an adsorbent 12, a first valve 21, a second valve 22, a third valve 23, a fourth valve 24, a pressure sensor 25, a carbon dioxide sensor 26, and a temperature sensor 27.

[0022] The adsorbent 12 is placed inside the module 11 to adsorb carbon dioxide. The adsorbent 12 is a particulate material that adsorbs carbon dioxide at low temperatures (e.g., in the range of -30°C to 50°C) and desorbs (releases) carbon dioxide at high temperatures (e.g., in the range of 50°C to 110°C) and when the ambient carbon dioxide concentration is low. Examples of such adsorbent 12 include solid amine carbon dioxide adsorbents composed of amines supported on a porous material such as silica.

[0023] The first valve 21 is an on-off valve located at the connection point between the carbon dioxide line 103, which captures carbon dioxide, and module 11. A carbon dioxide capture pump 63 is located in the carbon dioxide line 103. The second valve 22 is an on-off valve located at the connection point between the vacuum line 102, where a vacuum pump 62 is located, and module 11. The third valve 23 is an on-off valve located at the inlet for taking in air, etc., into the interior of module 11. The fourth valve 24 is an on-off valve located at the connection point between the adsorption line 101 and module 11.

[0024] The first valve 21, the second valve 22, the third valve 23, and the fourth valve 24 are all controlled to open and close by the control device 90. The first valve 21, the second valve 22, the third valve 23, and the fourth valve 24 are, for example, normally open butterfly valves.

[0025] The pressure sensor 25 measures the internal pressure of module 11. The carbon dioxide sensor 26 measures the carbon dioxide concentration inside module 11. The temperature sensor 27 measures the temperature of the adsorbent 12. The measurement information from the pressure sensor 25, carbon dioxide sensor 26, and temperature sensor 27 is transmitted to the control device 90.

[0026] Returning to Figure 1, the adsorption line 101 and fan 61 will be described. The adsorption line 101 is branched and connected to each of the modules 11. The fan 61 is positioned at the point where the branched portions of the adsorption line 101 converge. When the fan 61 is driven, it creates a gas flow from "intake" to "exhaust" through the adsorption line 101 to the modules 11. This supplies air into the modules 11. A carbon dioxide concentration sensor 611, a humidity sensor 612, and a temperature sensor 613 are positioned at the exhaust portion of the adsorption line 101 to measure the carbon dioxide, humidity, and temperature exhausted from the adsorption line 101. The measurement information from the carbon dioxide concentration sensor 611, humidity sensor 612, and temperature sensor 613 is transmitted to the control device 90.

[0027] The vacuum line 102 is branched and connected to each of the modules 11. The vacuum pump 62 is located at the point where the branched portions of the vacuum line 102 converge. When driven, the vacuum pump 62 draws gas from inside the modules 11 through the vacuum line 102, bringing the inside of the modules 11 into a vacuum state or close to a vacuum state.

[0028] The carbon dioxide line 103 is branched and connected to each of the modules 11. At the point where the branched sections of the carbon dioxide line 103 converge, a carbon dioxide capture pump 63, an intercooler 64, a separator 65, and a carbon dioxide tank 66 are located.

[0029] The carbon dioxide capture pump 63 applies a suction force to send carbon dioxide flowing through the carbon dioxide line 103 to the carbon dioxide tank 66. A one-way valve 631 is positioned upstream of the carbon dioxide capture pump 63 in the carbon dioxide line 103. This prevents gas from flowing back from the intercooler 64 to the module 11.

[0030] The intercooler 64 is an intermediate cooler that cools the high-temperature gas containing carbon dioxide recovered from module 11 and separates it into gas and liquid.

[0031] The water separated into gas and liquid phases in the intercooler 64 is recovered in the separator 65. The separator 65 is equipped with a first valve 651 and a second valve 652. The first valve 651 opens and closes a path communicating with the gas phase portion of the separator 65. The second valve 652 opens and closes a path communicating with the liquid phase portion of the separator 65.

[0032] The carbon dioxide tank 66 stores the carbon dioxide recovered through the carbon dioxide line 103. A tank valve 661 is located upstream of the carbon dioxide tank 66 in the carbon dioxide line 103. The tank valve 661 is controlled to open and close by the control device 90. Various sensors, such as a pressure sensor 662, a flow sensor 663, a humidity sensor 664, a temperature sensor 665, and a carbon dioxide concentration sensor 666, are located between the tank valve 661 and the carbon dioxide tank 66 in the carbon dioxide line 103.

[0033] In addition to the carbon dioxide line 103, the carbon dioxide tank 66 is connected to a circulation line 104 that returns ballast to the carbon dioxide recovery pump 63. A flow sensor 667 is located on the circulation line 104. The carbon dioxide tank 66 is also equipped with a pressure relief valve 668 that releases pressure when it exceeds a predetermined pressure.

[0034] Next, the inert gas tank 69 will be described. The inert gas tank 69 stores N2 as an inert gas supplied from the N2 gas cylinder 691 at a pressure above a certain level (for example, 980 kPa). A gas cylinder valve 692 is placed between the inert gas tank 69 and the N2 gas cylinder 691. The inert gas tank 69 is also equipped with a pressure release valve 693 that releases pressure when it exceeds a predetermined level. A pressure sensor 694 is placed inside the inert gas tank 69. The pressure information measured by the pressure sensor 694 is transmitted to the control device 90.

[0035] The inert gas tank 69 is connected to the carbon dioxide line 103 via the inert gas supply line 107. An inert gas valve 695 is located in the inert gas supply line 107. The inert gas valve 695 is opened and closed by the control device 90.

[0036] Referring to Figure 2, the heat exchanger 70 will be described. The heat exchanger 70 supplies thermal energy to heat the inside of each module 11 of the module unit 10 to a predetermined temperature when the module 11 performs the desorption process. The heat exchanger 70 also recovers excess thermal energy when each module 11 performs the adsorption process.

[0037] The heat exchanger 70 of this embodiment includes a heat source circuit 80, a chilled water line 111, a hot water line 112, a three-way valve 30, a bypass path 31, and a bypass valve 32.

[0038] The heat source circuit 80 mainly consists of a heat source 81, a chilled water tank 82, and a hot water tank 83, and performs heat exchange between a cooling heat transfer medium flowing through the chilled water line 111 and a heating heat transfer medium flowing through the hot water line 112. The heat transfer that occurs in the heat source circuit 80 cools the heat transfer medium flowing through the chilled water line 111 and heats the heat transfer medium flowing through the hot water line 112. The heat transfer medium is a liquid such as water. The detailed configuration of the heat source circuit 80 will be described later with reference to Figure 5.

[0039] The chilled water line 111 is a pipe through which chilled water, used as a heat transfer medium for cooling, flows. The chilled water line 111 branches and connects to the upstream and downstream sides of each module 11, connecting the chilled water tank 82 to each module 11. Of the chilled water line 111, the line connected to the upstream side of each module 11 is designated as the chilled water supply line 111a, and the line connected to the downstream side of each module 11 is designated as the chilled water return line 111b.

[0040] The chilled water supply line 111a is connected in parallel to multiple modules 11, and chilled water can be supplied in parallel to each module 11. The chilled water supply line 111a is equipped with a first chilled water circulation water pump 822 and a second chilled water circulation water pump 823. For example, cascade pumps are used for the first chilled water circulation water pump 822 and the second chilled water circulation water pump 823.

[0041] Furthermore, a circulation line 824 is provided in the chilled water supply line 111a that returns water from the downstream side to the upstream side of the second chilled water circulation water pump 823. A safety valve 825 is provided in this circulation line 824. The safety valve 825 relieves pressure when the pressure in the system of the second chilled water circulation water pump 823 and the chilled water line 111 exceeds a certain level, thereby suppressing a pressure rise. By providing the safety valve 825, which relieves pressure abnormalities in the chilled water line 111 system, in parallel with the second chilled water circulation water pump 823, it is possible to achieve both high-flow circulation by the second chilled water circulation water pump 823 and safe operation.

[0042] The chilled water recovery line 111b is also connected in parallel to multiple modules 11, and the chilled water can be recovered in parallel for each module 11 after cooling is complete.

[0043] The hot water line 112 is a pipe through which hot water, used as a heat transfer medium for heating, flows. The hot water line 112 branches and connects to the upstream and downstream sides of each module 11, connecting the hot water tank 83 to each module 11. Of the hot water line 112, the line connected to the upstream side of each module 11 is designated as the hot water supply line 112a, and the line connected to the downstream side of each module 11 is designated as the hot water return line 112b.

[0044] The hot water supply line 112a is connected in parallel to multiple modules 11, and hot water can be supplied in parallel to each module 11. The hot water supply line 112a is equipped with a first hot water circulation water pump 832 and a second hot water circulation water pump 833. For example, cascade pumps are used for the first hot water circulation water pump 832 and the second hot water circulation water pump 833. By using cascade pumps, which generate a large amount of heat when driven, the heat transfer medium passing through the first hot water circulation water pump 832 and the second hot water circulation water pump 833 can be further heated.

[0045] Furthermore, a circulation line 834 is provided in the hot water supply line 112a that returns water from the downstream side to the upstream side of the second hot water circulation water pump 833. A safety valve 835 is provided in this circulation line 834. The safety valve 835 relieves pressure when the pressure in the system of the second hot water circulation water pump 833 and the hot water line 112 exceeds a certain level, thereby suppressing the pressure rise. By providing the safety valve 835, which relieves pressure abnormalities in the hot water line 112 system, in parallel with the second hot water circulation water pump 833, it is possible to achieve both high-flow circulation by the second hot water circulation water pump 833 and safe operation.

[0046] The hot water recovery line 112b is also connected in parallel to multiple modules 11, and the recovery of hot water after heating is completed can be carried out in parallel for each module 11.

[0047] The three-way valve 30 is connected to the chilled water line 111, the hot water line 112, and the module 11. The three-way valve 30 is positioned on both the upstream and downstream sides of the module 11. The three-way valve 30 is configured to allow selection of three states by switching the flow path: a chilled water connection state connecting the chilled water line 111 to the module 11, a hot water connection state connecting the hot water line 112 to the module 11, and a disconnection state that disconnects the chilled water line 111 and the hot water line 112 from the module 11.

[0048] The flow path switching of the three-way valve 30 is controlled by the control device 90. A heat transfer medium is introduced into module 11 through the three-way valve 30 located on the upstream side, and the heat transfer medium is returned to the heat source 81 side through the three-way valve 30 located on the downstream side.

[0049] The bypass path 31 is a flow path that allows the movement of the heat transfer medium between modules 11. The bypass path 31 connects two modules 11. The modules 11 connected by the bypass path 31 may be adjacent modules or modules located at a distance from each other.

[0050] The bypass valve 32 is located in the bypass path 31. The bypass valve 32 is located in each of the multiple bypass paths 31. The bypass valve 32 is opened and closed by the control device 90.

[0051] Figure 4 is a schematic diagram showing the configuration of the liquid flow in module 11 of the carbon dioxide recovery device 1 of this embodiment. In the following description, the three-way valve 30 located on the upstream side of module 11 will be referred to as three-way valve 30a, and the three-way valve 30 located on the downstream side of module 11 will be referred to as three-way valve 30b.

[0052] As shown in Figure 4, module 11 includes an inlet-side flow path 33 connected to an inlet into which the heat transfer medium flows, and an outlet-side flow path 34 connected to an outlet out which the heat transfer medium flows out. The bypass path 31 is connected to the outlet-side flow path 34 of module 11 and also to the inlet-side flow path 33 of another module 11.

[0053] A three-way valve 30a is positioned at the upstream end of the inlet-side flow path 33, and a three-way valve 30b is also positioned at the downstream end of the outlet-side flow path 34. When hot water is connected, the three-way valve 30a is connected to the hot water supply line 112a, and the three-way valve 30b is connected to the hot water return line 112b. When cold water is connected, the three-way valve 30a is connected to the cold water supply line 111a, and the three-way valve 30b is connected to the cold water return line 111b.

[0054] The three-way valves 30a and 30b are configured to allow for flow rate adjustment. This flow rate adjustment function allows for adjustment of the flow rate of hot water when connected to hot water, and adjustment of the flow rate of cold water when connected to cold water.

[0055] A temperature sensor 35 is placed in the inlet channel 33. A temperature sensor 36 and a flow sensor 37 are placed in the outlet channel 34. Measurement information from the temperature sensors 35, 36, and 37 is transmitted to the control device 90.

[0056] Next, the control device 90 will be described. The control device 90 controls the operation of each part of the carbon dioxide capture device 1. The control device 90 controls the operation of devices used for carbon dioxide adsorption and desorption, such as driving and stopping. The control device 90 selectively controls the timing of supplying a heat transfer medium to each module 11 to provide heating and cooling, so that multiple modules 11 can repeatedly perform adsorption and desorption in a time series.

[0057] The control device 90 controls the opening and closing of the first valve 21, second valve 22, third valve 23, and fourth valve 24 provided in each module 11, as well as the opening and closing of each bypass valve 32. The control device 90 also controls the drive of the fan 61, vacuum pump 62, carbon dioxide recovery pump 63, first chilled water circulation water pump 822, second chilled water circulation water pump 823, first hot water circulation water pump 832, second hot water circulation water pump 833, etc., and controls the opening and closing of safety valves 825 and 835.

[0058] The control device 90 is, for example, a computer having a CPU (Central Processing Unit), ROM (Read Only Memory), RAM (Random Access Memory), etc. The control device 90 may consist of one unit or multiple units. The control device 90 may also be configured using electrical circuits such as relays.

[0059] <Carbon dioxide capture> Next, the control device 90 for recovering carbon dioxide will be explained. The carbon dioxide recovery device 1 alternately performs an adsorption process in which carbon dioxide from a gas such as the inhaled atmosphere is adsorbed onto the adsorbent material 12 in the module 11, and a desorption process in which the carbon dioxide adsorbed onto the adsorbent material 12 is desorbed. The desorbed carbon dioxide is stored in the carbon dioxide tank 66, thereby removing and recovering carbon dioxide from the air.

[0060] The adsorption process involves adsorbing carbon dioxide onto the adsorbent material 12 within module 11. During the adsorption process, the third valve 23 and fourth valve 24 of module 11 are opened, and the first valve 21 and second valve 22 are closed. Along with the opening and closing control of the valves, the heat exchanger 70 controls the three-way valves 30a and 30b to a chilled water connection state, allowing chilled water to flow through module 11 and cool the adsorbent material 12 within module 11. A fan 61 is driven, generating a gas flow from upstream to downstream, drawing in a gas containing carbon dioxide (e.g., air) through the third valve 23. The drawn-in gas passes through the adsorbent material 12 within module 11. At this time, the inside of module 11 is at room temperature (25°C) due to the cooling by the chilled water, and the carbon dioxide in the gas is adsorbed onto the adsorbent material 12. Gases other than carbon dioxide, such as nitrogen and oxygen, are exhausted to the outside of the carbon dioxide recovery device 1 through the fourth valve 24 and the adsorption line 101.

[0061] The desorption process is a process of desorbing carbon dioxide from the adsorbent 12 inside the module 11. In the desorption process, the first valve 21, third valve 23, and fourth valve 24 of the module 11 are closed, and the second valve 22 is opened. The vacuum pump 62 is operated to draw air into the inside of the module 11, reducing the pressure to a vacuum state or close to a vacuum state. Along with the opening and closing control of the valves, the heat exchanger 70 controls the three-way valves 30a and 30b to a hot water connection state, and hot water flows inside the module 11 to supply thermal energy and raise the temperature of the adsorbent 12 in the module 11. By controlling the temperature rise of the adsorbent 12, the adsorbent 12 is also heated to a predetermined temperature (for example, 80°C) sufficient for the desorption process, and the carbon dioxide adsorbed on the adsorbent 12 is desorbed. Next, the second valve 22, the third valve 23, and the fourth valve 24 are closed, the first valve 21 is opened, and the carbon dioxide recovery pump 63 is driven, and the carbon dioxide desorbed through the carbon dioxide line 103 is stored in the carbon dioxide tank 66. In this embodiment, of the 16 modules 11, 12 perform the adsorption process and the remaining 4 perform the desorption process, with each process being controlled accordingly.

[0062] <Heat source circuit> Next, the detailed configuration of the heat source circuit 80 will be described with reference to Figure 5. Figure 5 is a schematic diagram showing the configuration of the heat source circuit 80 of the carbon dioxide recovery device 1 of this embodiment.

[0063] As shown in Figure 5, the heat source circuit 80 of this embodiment includes a heat source 81, a high-temperature water circuit 85 including a hot water tank 83, a low-temperature water circuit 86 including a cold water tank 82, and a reservoir tank 88.

[0064] The heat source 81 cools the heat transfer medium introduced from the chilled water tank 82 and heats the medium introduced from the hot water tank 83. The heat source 81 is composed of a heat pump that transfers heat using the compression and expansion of gas.

[0065] The high-temperature water circuit 85 circulates hot water between the hot water tank 83 and the heat source 81. The high-temperature water circuit 85 comprises the hot water tank 83, the hot water side heat source supply line 221, and the hot water side heat source return line 222.

[0066] The hot water tank 83 is a heat storage device that has an insulating function and is capable of storing a heat transfer medium. Preferably, the capacity of the hot water tank 83 is five times or more the maximum flow rate discharged by the hot water circulation water pump 831, which will be described later. By setting the capacity of the hot water tank 83 to be large relative to the flow rate of the heat transfer medium, it is possible to suppress the temperature fluctuation of the hot water (heat transfer medium) during heat load fluctuations to a predetermined temperature range (for example, within ±5°C). In other words, the hot water tank 83 functions as a buffer for heat load fluctuations.

[0067] A temperature sensor 830 for measuring the temperature of the heat transfer medium is placed inside the hot water tank 83. The measurement results from the temperature sensor 830 are output to the control device 90. The hot water tank 83 is connected to the heat source unit 81 via the hot water side heat source supply line 221 and the hot water side heat source return line 222.

[0068] The hot water side heat source supply line 221 is the path through which the heat transfer medium flows from the hot water tank 83 to the heat source unit 81. The hot water side heat source supply line 221 is configured with a valve 301, a hot water side circulation water pump 831, a flow sensor 231, and a temperature sensor 232 arranged in order from upstream. The hot water side circulation water pump 831 is configured, for example, as a centrifugal pump, and circulates the heat transfer medium between the hot water tank 83 and the heat source unit 81. The flow sensor 231 measures the flow rate of the heat transfer medium flowing into the heat source unit 81 and outputs the measurement result to the control device 90. The temperature sensor 233 measures the temperature of the heat transfer medium flowing into the heat source unit 81 and outputs the measurement result to the control device 90.

[0069] The hot water side heat source return line 222 is the path through which the heat transfer medium flows from the heat source 81 to the hot water tank 83. A temperature sensor 233 and a valve 302 are arranged in the hot water side heat source return line 222 in order from the upstream side. The temperature sensor 233 measures the temperature of the hot water flowing out of the heat source 81 and outputs the measurement result to the control device 90.

[0070] The hot water tank 83 is connected to a hot water supply line 112a and a hot water return line 112b. Valve 305, a water filter 234, and valve 306 are located near the hot water tank 83 on the hot water supply line 112a. Valve 303 and valve 304 are located on the hot water return line 112b.

[0071] The connection positions (port positions) of each line in the hot water tank 83 are preferably set considering the temperature stratification of the heat transfer medium (hot water) stored in the hot water tank 83. Figure 6 is a schematic diagram showing the connection positions of each line connected to the hot water tank 83.

[0072] As shown in Figure 6, a temperature stratification is formed in the hot water stored in the hot water tank 83, with the temperature being higher in the upper layers and lower in the lower layers. The connection positions of each line in the hot water tank 83 are set in order from highest to lowest: hot water side heat source return line 222, hot water supply line 112a, hot water side heat source supply line 221, and hot water return line 112b.

[0073] The hot water side heat source return line 222 is the piping to which the hot water (e.g., 82°C) heated by the heat source 81 is returned, and it is returned to the highest temperature portion in the temperature stratification. The hot water supply line 112a is connected to the next highest position after the connection point of the hot water side heat source return line 222, so it sends the hot water heated by the heat source 81 to the upstream side of module 11 while maintaining a high temperature (e.g., 80°C) without significantly lowering the temperature of the hot water.

[0074] The hot water supply line 221 is a pipe for sending the hot water to be heated to the heat source 81, and is connected at the next highest point after the connection point of the hot water supply line 112a. This allows high-temperature hot water to be sent through the hot water supply line 112a, while the hot water supply line 221 maintains a relatively high temperature (e.g., 75°C) of hot water before sending it to the heat source 81. The hot water return line 112b is a pipe that returns the hot water at the relatively lowest temperature (e.g., 72°C) after heating the module 11. Since the hot water return line 112b is connected at the lowest point, it can suppress the amount of low-temperature hot water mixed into the hot water supply line 112a, which requires a higher temperature.

[0075] Next, returning to Figure 5, the low-temperature water circuit 86 of the heat source will be described. The low-temperature water circuit 86 of the heat source circulates chilled water between the chilled water tank 82 and the heat source 81. The low-temperature water circuit 86 of the heat source circulates chilled water between the chilled water tank 82 and the chilled water side heat source return line 122.

[0076] The chilled water tank 82 is a heat storage device that has an insulating function and is capable of storing a heat transfer medium. Preferably, the capacity of the chilled water tank 82 is five times or more the maximum flow rate discharged by the chilled water circulation water pump 821, which will be described later. By setting the capacity of the chilled water tank 82 to be large relative to the flow rate of the heat transfer medium, it is possible to suppress the temperature fluctuation of the chilled water (heat transfer medium) during heat load fluctuations to a predetermined temperature range (for example, within ±5°C). In other words, the chilled water tank 82 functions as a buffer for heat load fluctuations.

[0077] A temperature sensor 820 for measuring the temperature of the heat transfer medium is placed inside the chilled water tank 82. The measurement results from the temperature sensor 820 are output to the control device 90. The chilled water tank 82 is connected to the heat source unit 81 via the chilled water side heat source supply line 121 and the chilled water side heat source return line 122.

[0078] The chilled water side heat source supply line 121 is the path through which the heat transfer medium flows from the chilled water tank 82 to the heat source unit 81. The chilled water side heat source supply line 121 is equipped with a valve 307, a chilled water side circulation water pump 821, a flow sensor 131, and a temperature sensor 132. The chilled water side circulation water pump 821 is configured, for example, as a centrifugal pump, and circulates the heat transfer medium between the chilled water tank 82 and the heat source unit 81. The flow sensor 131 measures the flow rate of the heat transfer medium flowing into the heat source unit 81 and outputs the measurement result to the control device 90. The temperature sensor 132 measures the temperature of the heat transfer medium flowing into the heat source unit 81 and outputs the measurement result to the control device 90.

[0079] Furthermore, a radiator bypass line 123 for cooling the heat transfer medium and a heater bypass line 124 for heating the heat transfer medium are connected to the chilled water side heat source supply line 121. The radiator bypass line 123 and the heater bypass line 124 are temperature control circuits that adjust the temperature of the heat transfer medium flowing into the heat source 81 to an operable temperature when the outside air temperature or heat load fluctuates.

[0080] The radiator bypass line 123 is connected between the chilled water circulation water pump 821 and the flow sensor 131 in the chilled water side heat source supply line 121. A valve 141 and a radiator fan 142 are located in the radiator bypass line 123. The valve 141 can open and close the flow path and adjust the flow rate based on a control signal from the control device 90. The radiator fan 142 is a heat dissipation device that cools the heat transfer medium passing through the radiator bypass line 123. Cooling of the heat transfer medium by the radiator bypass line 123 is mainly performed during high temperatures such as in summer. By cooling the heat transfer medium by the radiator bypass line 123, the temperature of the chilled water introduced into the heat source 81 is controlled to be below a preset threshold.

[0081] The heater bypass line 124 is located between the chilled water circulation water pump 821 and the flow sensor 131 in the chilled water side heat source supply line 121, and is connected inside the radiator bypass line 123. A valve 308 and a heater 150 are located in the heater bypass line 124. The heater 150 is driven by control signals from the control device 90 and relay drive signals, and heats the heat transfer medium flowing through the heater bypass line 124. Heating of the heat transfer medium by the heater bypass line 124 is mainly performed at low temperatures, such as during winter startup. Heating of the heat transfer medium by the heater bypass line 124 controls the temperature of the heat transfer medium introduced into the heat source 81 to be above a preset threshold.

[0082] The chilled water side heat source return line 122 is the path through which the heat transfer medium flows from the heat source 81 to the chilled water tank 82. The chilled water side heat source return line 122 has a temperature sensor 133, valves 309, 310, 311, and 312 arranged in order from the upstream side. The temperature sensor 132 measures the temperature of the chilled water flowing out of the heat source 81 and outputs the measurement result to the control device 90.

[0083] The chilled water tank 82 is connected to a chilled water supply line 111a and a chilled water return line 111b. Near the chilled water tank 82 on the chilled water supply line 111a, there are valves 315, a water filter 134, and valve 316. On the chilled water return line 111b, there are valves 313 and 314.

[0084] The connection positions (port positions) of each line in the chilled water tank 82 are preferably set considering the temperature stratification of the heat transfer medium (chilled water) stored in the chilled water tank 82. Figure 7 is a schematic diagram showing the connection positions of each line connected to the chilled water tank 82.

[0085] As shown in Figure 7, a temperature stratification is formed in the chilled water stored in the chilled water tank 82, with the temperature being higher towards the top and lower towards the bottom. The connection positions of each line in the chilled water tank 82 are set in order from highest to lowest: chilled water return line 111b, chilled water side heat source return line 122, chilled water supply line 111a, and chilled water side heat source supply line 121.

[0086] The chilled water return line 111b is the piping that returns the chilled water at the relatively highest temperature (e.g., 36°C) after cooling module 11. Because the chilled water return line 111b is connected at the highest position, it can suppress the mixing of high-temperature chilled water with the chilled water sent from the chilled water supply line 111a. The chilled water side heat source return line 122 is the piping that returns chilled water (e.g., 30°C) cooled by the heat source 81, and is connected at the next highest position after the connection point of the chilled water return line 111b. The chilled water returning through the chilled water side heat source return line 122 moves to the lower layer of the temperature stratification.

[0087] The chilled water supply line 111a is connected to the next highest position after the chilled water side heat source return line 122, so it sends the chilled water cooled by the heat source 81 to the upstream side of module 11 while maintaining a low temperature (e.g., 31°C) without significantly raising its temperature. The chilled water side heat source supply line 121 is connected to the lowest position and sends the chilled water (e.g., 33°C) that was not sent from the chilled water supply line 111a to module 11 back to the heat source 81.

[0088] Next, returning to Figure 5, we will describe the equipment heat recovery circuit 87, which cools the target equipment such as the intercooler 64, vacuum pump 62, and carbon dioxide recovery pump 63 included in the heat source low-temperature water circuit 86, and also raises the temperature of the heat transfer medium.

[0089] The equipment heat recovery circuit 87 is connected in parallel to the heat source low-temperature water circuit 86. The equipment heat recovery circuit 87 in this embodiment includes a first equipment heat cooling line 126 that exchanges heat with the intercooler 64, and a second equipment heat cooling line 127 that exchanges heat with the vacuum pump 62 and the carbon dioxide recovery pump 63.

[0090] The first equipment heat cooling line 126 has its upstream end connected to the chilled water side heat source return line 122 and its downstream end connected to the chilled water side heat source supply line 121. In this embodiment, the connection point of the upstream end of the first equipment heat cooling line 126 is between valve 309 and valve 310 in the chilled water side heat source return line 122. The connection point of the lower end of the first equipment heat cooling line 126 is between valve 307 and the chilled water side circulation water pump 821 in the chilled water side heat source supply line 121.

[0091] The first equipment thermal cooling line 126 is connected to an intercooler 64 that generates heat from steam condensation, and the intercooler 64 is cooled with chilled water to recover the heat from steam condensation as waste heat. The chilled water is heated by heat exchange with the intercooler 64 and then sent to the chilled water side heat source supply line 121.

[0092] A flow sensor 841 and a temperature sensor 842 are positioned upstream of the intercooler 64 in the first equipment heat cooling line 126, and a temperature sensor 843 and a valve 317 are positioned downstream of the intercooler 64. The flow sensor 841 measures the flow rate of the heat transfer medium before heat exchange with the intercooler 64 and outputs the measurement result to the control device 90. The temperature sensor 842 measures the temperature of the heat transfer medium before heat exchange with the intercooler 64 and outputs the measurement result to the control device 90. The temperature sensor 843 measures the temperature of the heat transfer medium after heat exchange with the intercooler 64 and outputs the measurement result to the control device 90.

[0093] The second equipment heat cooling line 127 has its upstream end connected to the chilled water side heat source return line 122 and its downstream end connected to the chilled water side heat source supply line 121. In this embodiment, the connection point of the upstream end of the second equipment heat cooling line 127 is between valve 310 and valve 311 in the chilled water side heat source return line 122. The connection point of the lower end of the second equipment heat cooling line 127 is between valve 307 and chilled water side circulation water pump 821 in the chilled water side heat source supply line 121, and is upstream of the connection point of the downstream end of the first equipment heat cooling line 126.

[0094] Furthermore, the second equipment thermal cooling line 127 of this embodiment includes a first branch line 127a for cooling the vacuum pump 62 and a second branch line 127b for cooling the carbon dioxide recovery pump 63.

[0095] The first branch line 127a is connected to the vacuum pump 62, and the vacuum pump 62 is cooled by chilled water. The heat transfer medium, heated by heat exchange with the vacuum pump 62, joins the second branch line 127b and is sent to the chilled water side heat source supply line 121.

[0096] A flow sensor 851 and a temperature sensor 852 are positioned upstream of the vacuum pump 62 in the first branch line 127a, and a temperature sensor 853 is positioned downstream of the vacuum pump 62. The flow sensor 851 measures the flow rate of the heat transfer medium before heat exchange with the vacuum pump 62 and outputs the measurement result to the control device 90. The temperature sensor 852 measures the temperature of the heat transfer medium before heat exchange with the vacuum pump 62 and outputs the measurement result to the control device 90. The temperature sensor 853 measures the temperature of the chilled water after heat exchange with the vacuum pump 62 and outputs the measurement result to the control device 90.

[0097] The second branch line 127b is connected to the carbon dioxide recovery pump 63 and cools the carbon dioxide recovery pump 63 with a heat transfer medium. The heat transfer medium is heated through heat exchange with the carbon dioxide recovery pump 63 and then joins the first branch line 127a, and is sent to the chilled water side heat source supply line 121.

[0098] A flow sensor 861 and a temperature sensor 862 are positioned upstream of the carbon dioxide recovery pump 63 in the second branch line 127b, and a temperature sensor 863 is positioned downstream of the carbon dioxide recovery pump 63. The flow sensor 861 measures the flow rate of the heat transfer medium before heat exchange with the carbon dioxide recovery pump 63 and outputs the measurement result to the control device 90. The temperature sensor 862 measures the temperature of the heat transfer medium before heat exchange with the carbon dioxide recovery pump 63 and outputs the measurement result to the control device 90. The temperature sensor 863 measures the temperature of the heat transfer medium after heat exchange with the carbon dioxide recovery pump 63 and outputs the measurement result to the control device 90.

[0099] A pump 870 for cooling equipment is located upstream of the branching point between the first branch line 127a and the second branch line 127b in the second equipment thermal cooling line 127. Valves 318 and 319 are located downstream of the confluence point between the first branch line 127a and the second branch line 127b in the second equipment thermal cooling line 127.

[0100] The equipment cooling pump 870 in this embodiment is composed of a cascade pump with sufficient head to pump the heat transfer medium without being hindered by the high pressure loss of the vacuum pump 62 and the carbon dioxide recovery pump 63, which are the equipment from which heat is recovered. The heat generated by driving the equipment cooling pump 870 is also recovered as waste heat by chilled water.

[0101] As explained above, the equipment heat recovery circuit 87 recovers the heat of steam condensation from the intercooler 64 and the waste heat from the vacuum pump 62 and the carbon dioxide recovery pump 63 into a heat transfer medium to cool the target equipment, and also enables the heat transfer medium to flow into the heat source 81 at a high temperature potential due to the heat recovery.

[0102] The equipment heat recovery circuit 87 uses a low-temperature heat transfer medium cooled by the heat source 81 to cool the target equipment: the vacuum pump 62, the carbon dioxide recovery pump 63, and the intercooler 64. After the target equipment (vacuum pump 62, carbon dioxide recovery pump 63, and intercooler 64) is cooled and waste heat is recovered, the chilled water joins the chilled water side heat source supply line 121 through which chilled water discharged from the chilled water tank 82 (for example, the upper, higher-temperature part of the chilled water tank 82) flows, and is introduced into the heat source 81. The chilled water after waste heat recovery is heated to an appropriate temperature range.

[0103] In this embodiment, the chilled water is further adjusted to an appropriate temperature range before entering the heat source 81 by a radiator bypass line 123 for cooling or a heater bypass line 124 for heating. Therefore, even during operation with large fluctuations in heat load, it is possible to smooth out the time-series heat fluctuations and keep the inflow temperature to the heat source 81 constant.

[0104] Next, the configuration of the reservoir tank 88 will be described. The reservoir tank 88 is a tank capable of storing a heat transfer medium. The reservoir tank 88 is connected to both the hot water tank 83 and the chilled water tank 82. A valve 320 is located between the reservoir tank 88 and the hot water tank 83, and another valve 320 is located between the reservoir tank 88 and the chilled water tank 82. When it is necessary to adjust the amount of heat transfer medium stored in the hot water tank 83, the valve 321 is opened, and the heat transfer medium is transferred between the reservoir tank 88 and the hot water tank 83. Similarly, when it is necessary to adjust the amount of heat transfer medium stored in the chilled water tank 82, the valve 321 is opened, and the heat transfer medium is transferred between the reservoir tank 88 and the chilled water tank 82. A level sensor 880 for determining the amount of stored water is located inside the reservoir tank 88. The measurement result of the level sensor 880 is output to the control device 90. The control device 90 uses the measurement results from the level sensor 880 to determine whether the reservoir tank 88 is usable, etc.

[0105] <Flow Control> Next, referring to Figures 8 and 9, the flow rate control by the control device 90 will be explained. Figure 8 is a graph showing the time change of the adsorbent temperature and the heat transfer medium flow rate (hot water flow rate) in the desorption process. Figure 9 is a graph showing the time change of the amount of heat exchanged in the desorption process.

[0106] As shown in Figure 8, the control device 90 controls the opening of the three-way valves 30a and 30b to be large in the initial stages of the desorption process, when the processing heat load is high, so that the flow rate is large. This allows the temperature of the adsorbent 12 to rise quickly and promote desorption. For example, in the initial heating stage at the beginning of the desorption process, the control device 90 controls the opening of the three-way valves 30a and 30b so that the maximum flow rate is about 30 L / min.

[0107] From the middle of the desorption process onward, the heat treatment load decreases, so the opening of the three-way valves 30a and 30b is controlled to be small so that the flow rate is relatively small. For example, during the temperature holding stage from the middle of the desorption process onward, the control device 90 controls the opening of the three-way valves 30a and 30b so that the flow rate is reduced to about 10 L / min so that the temperature difference between the inlet and outlet temperatures of the hot water is about 3°C. As a result, as shown in Figure 9, the amount of heat exchanged from the middle of the desorption process onward can be reduced, and the overall energy loss can be reduced.

[0108] The timing for changing the flow rate in the initial and later stages of the desorption process can be determined based on the hot water inlet temperature detected by the temperature sensor 35, the hot water outlet temperature detected by the temperature sensor 36, and the adsorbent temperature of the adsorbent 12 detected by the temperature sensor 27. For example, the control device 90 adjusts the flow rate using the three-way valves 30a and 30b by utilizing the temperature difference between the hot water inlet and outlet temperatures, hot water and outlet temperature thresholds, and the passage of time.

[0109] In this embodiment, valves 301 to 321 are configured to be automatically controlled by the control device 90, but if automatic control is not required, manually operated valves may be used.

[0110] As described above, the carbon dioxide recovery device 1 of this embodiment comprises a plurality of modules 11 having an adsorbent material 12 inside, which perform an adsorption step of drawing a gas containing carbon dioxide onto the adsorbent material 12 to adsorb carbon dioxide, and a desorption step of heating the adsorbent material 12 while the surrounding area is under reduced pressure to desorb carbon dioxide, a heat exchange device 70 capable of performing heating and cooling by supplying hot water (heating medium) to each of the modules 11 and supplying a cooling medium, and a three-way valve (flow path control unit) 30 capable of selectively supplying hot water or cold water to the modules 11, the heat exchange device 70 comprising a heat pump type heat source 81 that heats the hot water and cools the cold water, and the heat source 81 The system includes a hot water tank (heating medium tank) 83 for storing hot water heated by the system, and a high-temperature heat source water circuit 85 for circulating hot water between the hot water tank 83 and the heat source 81; a cold water tank (cooling medium tank) 82 for storing cold water cooled by the heat source 81, and a low-temperature heat source water circuit 86 for circulating cold water between the cold water tank 82 and the heat source 81; a hot water supply line 112a for supplying hot water from the hot water tank 83 to the module 11; a hot water return line 112b for returning the heated hot water from the module 11 to the hot water tank 83; a cold water supply line 111a for supplying cold water from the cold water tank 82 to the module 11; and a cold water return line 111b for returning the cooled cold water from the module 11 to the cold water tank 82.

[0111] This allows the timing of the adsorption and desorption processes to be staggered across multiple modules 11, thus avoiding a concentration of processing load at any given time. Furthermore, the hot water tank 83 and chilled water tank 82 function as buffers against thermal fluctuations, preventing deterioration of temperature tracking performance due to fluctuations in the required heat quantity, improving equipment efficiency, and reducing power consumption. The amount of heat generated by the heat source 81 and the amount of waste heat recovered from the modules 11 and target equipment can also be kept constant, enabling stable and continuous heat supply, unlike conventional technologies where the heat load varies greatly between day and night. Moreover, since heating of the hot water tank 83 by the heat source 81 and cooling of the chilled water tank 82 by the heat source 81 are constantly performed, the temperature range of the hot or chilled water can be maintained within a certain range without deviating from the required temperature range over time.

[0112] Furthermore, the three-way valves 30a and 30b of this embodiment are configured to control the flow path for each of the modules 11, supplying cold water to the module 11 that performs the adsorption process and supplying hot water to the module 11 that performs the desorption process.

[0113] This makes it possible to control the three-way valve 30a located upstream of each module 11 and the three-way valve 30b located downstream of each module 11 in synchronization with the operating state of each module 11, thereby minimizing the mixing of hot and cold water and reducing heat energy loss.

[0114] Furthermore, the three-way valves 30a and 30b of this embodiment are configured to adjust the flow rate of cold or hot water supplied to the module 11.

[0115] This allows for control of the heat transfer fluid flow rate according to the required temperature range and operating conditions, enabling more precise control based on actual circumstances and further improving energy efficiency.

[0116] Furthermore, the three-way valves 30a and 30b of this embodiment control the flow rate of hot water to be relatively large during the initial heating stage of the desorption process, and to be relatively small during the temperature maintenance stage after the initial heating stage has elapsed.

[0117] This allows the temperature of the adsorbent 12 to be quickly raised to a predetermined temperature using the required amount of heat during the heating phase, and after the initial heating phase, the supply of hot water is adjusted to a sufficient amount to maintain the temperature. Since no more thermal energy is supplied than necessary during the temperature maintenance phase, the loss of thermal energy in the entire desorption process is reduced, enabling more efficient operation.

[0118] Furthermore, the high-temperature water heat source circuit 85 of this embodiment includes a hot water side heat source supply line 221 that sends hot water from the hot water tank 83 to the heat source unit 81, and a hot water side heat source return line 222 that returns hot water from the heat source unit 81 to the hot water tank 83. The connection positions of each line in the hot water tank 83 are set so that from top to bottom they are in the order of hot water side heat source return line 222, hot water supply line 112a, hot water side heat source supply line 221, and hot water return line 112b.

[0119] This allows the inlet and outlet positions of the hot water to be set according to the temperature stratification of the hot water tank 83, enabling efficient supply of hot water at an appropriate temperature range while suppressing the energy required for heat generation.

[0120] Furthermore, the low-temperature water heat source circuit 86 of this embodiment includes a chilled water side heat source supply line 121 that sends chilled water from the chilled water tank 82 to the heat source unit 81, and a chilled water side heat source return line 122 that returns chilled water from the heat source unit 81 to the chilled water tank 82. The connection positions of each line in the chilled water tank 82 are set so that from top to bottom they are in the order of chilled water return line 111b, chilled water side heat source return line 122, chilled water supply line 111a, and chilled water side heat source supply line 121.

[0121] This allows the inlet and outlet positions of the chilled water to be set according to the temperature stratification of the chilled water tank 82, enabling efficient supply of chilled water at an appropriate temperature range while suppressing the energy required for generating cold energy.

[0122] In the above embodiment, module 11 is connected to other modules 11 by a bypass path 31 in which a bypass valve 32 is located, but the configuration is not limited to this. The bypass path 31 and the bypass valve 32 can also be omitted from the configuration of the above embodiment.

[0123] Although embodiments of the present invention have been described above, the invention is not limited to the embodiments and modifications described above. Furthermore, the effects described in the above embodiments are merely a list of preferred effects and are not limited to those described in the above embodiments. [Explanation of symbols]

[0124] 1. Carbon dioxide capture device 11 modules 12 Adsorbent 62 Vacuum pump 63. Carbon dioxide capture pump 64 Intercooler 70 Heat exchange equipment 80 Heat source circuit 81 Heat source device 82. Chilled water tank (heat transfer fluid tank for cooling) 83. Hot water tank (heat transfer fluid tank for heating) 85 Heat source high temperature water circuit 86 Heat source low temperature water circuit 87 Equipment heat recovery circuit 90 Control device 111 Chilled water line (heat transfer fluid line for cooling) 111a Chilled water line (cooling heat medium line) 111b Chilled water restoration line (cooling heat transfer fluid restoration line) 112 Hot water line (heat transfer medium line) 112a Hot water line (heating medium line) 112b Hot water return line (heat transfer fluid return line)

Claims

1. Multiple modules having an adsorbent inside, which perform an adsorption step of drawing a gas containing carbon dioxide onto the adsorbent to adsorb the carbon dioxide, and a desorption step of heating the adsorbent while the area around it is under reduced pressure to desorb the carbon dioxide, A heat exchanger capable of heating and cooling, which supplies a heating medium to each of the aforementioned modules, A flow path control unit capable of selectively supplying the heating medium or the cooling medium to the module, Equipped with, The heat exchanger described above is A heat pump type heat source that heats the heating medium and cools the cooling medium, A heat source high-temperature water circuit includes a heat transfer medium tank for storing the heat transfer medium heated by the heat source, and circulates the heat transfer medium between the heat transfer medium tank and the heat source. A heat source low-temperature water circuit includes a cooling medium tank for storing the cooling medium cooled by the heat source, and circulates the cooling medium between the cooling medium tank and the heat source. A heating medium supply line that supplies the heating medium from the heating medium tank to the module, A heating medium return line returns the heating medium to the heating medium tank after heating the module, A cooling medium supply line that supplies the cooling medium from the cooling medium tank to the module, A cooling medium return line returns the cooling medium to the cooling medium tank after the module has been cooled. It has, The flow channel control unit is Each of the aforementioned modules is configured to allow control of the flow path, The cooling heat transfer medium is supplied to the module that performs the adsorption process. The heating medium is supplied to the module that performs the desorption process. The flow rate of the cooling or heating medium supplied to the module is adjustable. In the initial stage of the desorption process, the flow rate of the heating medium is increased relatively. During the temperature maintenance stage after the initial heating stage, the flow rate of the heating medium is controlled to be relatively small. Carbon dioxide capture device.

2. A plurality of modules having an adsorbent inside, which perform an adsorption step of drawing a gas containing carbon dioxide onto the adsorbent to adsorb the carbon dioxide, and a desorption step of heating the adsorbent while the area around the adsorbent is under reduced pressure to desorb the carbon dioxide, A heat exchanger capable of heating and cooling, which supplies a heating medium to each of the aforementioned modules, A flow path control unit capable of selectively supplying the heating medium or the cooling medium to the module, Equipped with, The heat exchanger described above is A heat pump type heat source that heats the heating medium and cools the cooling medium, A heat source high-temperature water circuit includes a heat transfer medium tank for storing the heat transfer medium heated by the heat source, and circulates the heat transfer medium between the heat transfer medium tank and the heat source. A heat source low-temperature water circuit includes a cooling medium tank for storing the cooling medium cooled by the heat source, and circulates the cooling medium between the cooling medium tank and the heat source. A heating medium supply line that supplies the heating medium from the heating medium tank to the module, A heating medium return line returns the heating medium to the heating medium tank after heating the module, A cooling medium supply line that supplies the cooling medium from the cooling medium tank to the module, A cooling medium return line returns the cooling medium to the cooling medium tank after the module has been cooled. It has, The aforementioned high-temperature water heat source circuit is A heat transfer medium side heat source supply line that sends the heat transfer medium from the heat transfer medium tank to the heat source, It has a heat source return line on the heat medium side that returns the heat medium from the heat source to the heat medium tank for heating, A carbon dioxide recovery device in which the connection positions of each line of the heating medium tank are set in the order from top to bottom: the heating medium side heat source return line, the heating medium supply line, the heating medium side heat source supply line, and the heating medium return line.

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