Hot-rolled and annealed sheet for electrical steel sheets and method for manufacturing the same, and method for manufacturing non-oriented electrical steel sheets

Abstract

The present invention provides a hot-rolled annealed sheet for an electrical steel sheet, the hot-rolled annealed sheet being excellent in terms of cold rolling properties (fracture resistance and edge cracking resistance) in a post-process. Provided is a hot-rolled annealed sheet for an electrical steel sheet, the hot-rolled annealed sheet having a component composition that contains, in mass%, 0.010% or less of C, 1.0% to 5.0% inclusive of Si, 0.05% to 5.0% inclusive of Mn, 0.1% or less of P, 0.01% or less of S, 3.0% or less of Al, and 0.0080% or less of N, with the balance being made up of Fe and inevitable impurities. At least at one of the plate width edge parts of the hot-rolled annealed sheet for an electrical steel sheet, the ratio dC / dE of the average crystal grain size dC at the plate width center part to the average crystal grain size dE at a position of 10 mm from the plate width edge part is 1.2 or more.

Description

Technical Field

[0001] The present invention relates to a hot-rolled annealed sheet for electromagnetic steel sheets, a method for producing the same, and a method for producing non-oriented electromagnetic steel sheets.

Background Art

[0002] In recent years, in consideration of the environment such as global warming, reduction of CO2 emissions and energy conservation have been demanded. In the automotive field, development of hybrid electric vehicles (HEVs) that combine an engine and a motor, electric vehicles (EVs) driven only by an electric motor, and fuel cell vehicles (FCEVs) has been promoted. Motors used in the above HEVs, EVs, FCEVs, etc. are generally driven in a high-frequency range advantageous for high-speed rotation in order to improve the motor efficiency. Non-oriented electromagnetic steel sheets are widely used as the core material of the above motors, and in order to achieve high motor efficiency, low iron loss in the high-frequency range is strongly required for the above steel sheets.

[0003] Conventionally, non-oriented electromagnetic steel sheets have been mainly made to reduce iron loss by adding alloy elements such as Si and Al to increase the specific resistance, or by reducing the plate thickness to reduce eddy current loss. However, due to the addition of a large amount of alloy elements, the ductility and toughness of the steel sheet are reduced, and frequent breakage in the cold rolling process has been a problem. As a technique for suppressing breakage of high-alloy steel, for example, Patent Documents 1 and 2 disclose a method for producing a non-oriented electromagnetic steel sheet with a high magnetic flux density that suppresses cracking in cold rolling by cold rolling a rapidly solidified slab at 180°C to 350°C.

Prior Art Documents

Patent Documents

[0004]

Patent Document 1

Patent Document 2

Summary of the Invention

Problems to be Solved by the Invention

[0005] However, in the technologies described in Patent Documents 1 and 2, although cracking can be suppressed by performing cold rolling in the temperature range of 180°C to 350°C, in addition to the difficulty of maintaining the steel sheet at a high temperature during rolling, there is a problem that equipment wear such as seizure of lubricating oil on the rolls is likely to occur.

[0006] The present invention has been made in view of the above problems of the prior art, and an object thereof is to provide a hot-rolled annealed sheet for an electromagnetic steel sheet excellent in cold rolling properties (fracture resistance and ear cracking resistance) in a subsequent process, together with an advantageous manufacturing method therefor.

Means for Solving the Problems

[0007] As a result of intensive studies by the present inventors on solving the above problems, it has been found that in most cases, the starting point of fracture due to cold rolling exists in the region near the edge portion of the hot-rolled annealed sheet (steel strip), and by increasing the fracture resistance of this region, fracture and cracking can be significantly suppressed without increasing the fracture resistance of the entire hot-rolled annealed sheet. Furthermore, as a method for increasing the fracture resistance of this region, by refining the crystal grains in this region and creating a crystal grain size difference from the central portion, the fracture resistance is improved more than when refining the crystal grains of the entire hot-rolled annealed sheet, and it has been found that a decrease in magnetic properties can be prevented.

[0008] The present invention has been made based on such findings and has the following configuration. [1] In mass%, C: 0.010% or less, Si: 1.0% or more and 5.0% or less, Mn: 0.05% or more and 5.0% or less, P: 0.1% or less, S: 0.01% or less, Al: 3.0% or less and N: 0.0080% or less, having a component composition in which the balance consists of Fe and unavoidable impurities, in at least one of the plate width edge portions, Average grain size d at the center of the plate width C The average crystal grain size d at a position 10 mm from the edge of the plate width. E Ratio d C / d E A hot-rolled and annealed sheet for electrical steel sheets that satisfies the requirement of 1.2 or higher. [2] The above component composition is, in mass%, further Zn: 0.0005% or more and 0.020% or less, Mo: 0.002% or more and 0.20% or less, Ni: 0.01% or more and 1.0% or less, Cr: 0.01% or more and 5.0% or less, Cu: 0.005% or more and 1.0% or less, Ca: 0.0001% or more and 0.10% or less, Mg: 0.0001% or more and 0.10% or less, REM: 0.0001% or more and 0.10% or less, Sn: 0.001% or more and 0.20% or less, Sb: 0.001% or more and 0.20% or less, B: 0.0020% or less Ti: 0.010% or less, Nb: 0.0050% or less, V: 0.0050% or less, Pb: 0.0050% or less, Zr: 0.0050% or less, Ta: 0.0020% or less, W: 0.0050% or less, Se: 0.0050% or less, Bi: 0.0050% or less, As: 0.020% or less, Co: 0.10% or less, Ge: 0.030% below and Ga: 0.030% or less Includes one or more species selected from the group consisting of, [1] Hot-rolled annealed sheet for electrical steel sheets. [3] The average crystal grain size at the center of the plate width d C The particle size is 70 μm or more and 300 μm or less, and the average crystal grain size d is located 10 mm from the edge of the plate width. EThe hot-rolled annealed sheet for electromagnetic steel sheet of [1] or [2], having a thickness of 10 μm or more and 200 μm or less. The hot-rolled annealed sheet for electromagnetic steel sheet according to any one of [1] to [3], having a maximum value of the average crystal grain size gradient in the sheet width direction of 0.2 μm / mm or more and 1.5 μm / mm or less. The hot-rolled annealed sheet for electromagnetic steel sheet according to any one of [1] to [4], wherein the position where the average crystal grain size gradient in the sheet width direction is maximum is within 200 mm from the sheet width edge portion. [6] At both sheet width edge portions, the average crystal grain size d of the sheet width central portion C and the average crystal grain size d at the position 10 mm from the sheet width edge portion of the sheet width edge portion E The ratio d C / d E of the hot-rolled annealed sheet for electromagnetic steel sheet according to any one of [1] to [5] satisfies 1.2 or more. [7] A method for manufacturing a hot-rolled annealed sheet for electromagnetic steel sheet according to any one of [1] to [6], comprising a hot rolling step of obtaining a hot-rolled sheet by subjecting a steel material having the composition described in [1] or [2] to hot rolling, and a hot-rolled sheet annealing step of annealing the hot-rolled sheet. In the hot-rolled sheet annealing step, when holding the central portion of the sheet width of the hot-rolled sheet at a holding temperature T1, the maximum reaching temperature T2 at the position 10 mm from the sheet width edge portion of at least one of the sheet width edge portions of the hot-rolled sheet satisfies T1 - T2 ≧ 20°C. A method for manufacturing a hot-rolled annealed sheet for electromagnetic steel sheet. [8] In the hot-rolled sheet annealing step, the holding temperature T1 of the central portion of the sheet width of the hot-rolled sheet is 900°C or more and 1150°C or less, and the holding time t1 at T1 is 1 second or more and 120 seconds or less. A method for manufacturing a hot-rolled annealed sheet for electromagnetic steel sheet according to [7]. [9] In the hot-rolled sheet annealing step, the maximum reaching temperature T2 is 750°C or more and 1000°C or less. A method for manufacturing a hot-rolled annealed sheet for electromagnetic steel sheet according to [7] or [8].

[10] In the hot-rolled sheet annealing step, the time t2 during which the position 10 mm from the sheet width edge portion of the hot-rolled sheet is at a temperature of T2 - 50°C or more is 5 seconds or more and 50 seconds or less. A method for manufacturing a hot-rolled annealed sheet for electromagnetic steel sheet according to any one of [7] to [9].

[11] A method for manufacturing a hot-rolled annealed sheet for electrical steel sheets according to any of [7] to

[10] , wherein in the hot-rolled sheet annealing process, the heating suppression region is between the sheet width edge and a position X1 mm from the sheet width edge, and X1 is 20 mm or more and 250 mm or less.

[12] A method for manufacturing a hot-rolled and annealed sheet for electrical steel sheets, wherein at both width edges of the hot-rolled sheet, the maximum temperature T2 reached at a position 10 mm from the width edge of the sheet satisfies T1-T2 ≥ 20°C, as described in any of [7] to

[11] . A method for manufacturing non-oriented electrical steel sheets, comprising a cold rolling step of cold rolling a hot-rolled and annealed sheet for electrical steel sheets of any of

[13] [1] to [6] to obtain a cold-rolled sheet, and an annealing step of annealing the cold-rolled sheet.

[0009] In the present invention, the plate width edge portion is the edge in the plate width direction, and may be either the left or right edge. [Effects of the Invention]

[0010] According to the present invention, a hot-rolled annealed sheet for electrical steel sheets, which exhibits excellent cold-rolling properties (fracture resistance and edge crack resistance) in subsequent processes, is provided along with an advantageous manufacturing method. Electrical steel sheets manufactured using the hot-rolled annealed sheet of the present invention have sufficiently avoided a decrease in magnetic properties. In particular, by using the hot-rolled annealed sheet of the present invention in the manufacture of non-oriented electrical steel sheets, it is possible to provide non-oriented electrical steel sheets with high magnetic flux density, high frequency, and low iron loss, and by using these non-oriented electrical steel sheets, high efficiency of motors can be achieved. Furthermore, even if the non-oriented electrical steel sheet is subjected to strain-relieving annealing for the purpose of reducing the increase in iron loss due to distortion during punching, the above effect is not affected in any way. [Modes for carrying out the invention]

[0011] The details of the present invention, along with the reasons for its limitations, will be described below.

[0012] [Hot-rolled annealed sheet] <Component composition> The component composition of the hot-rolled annealed sheet of the present invention will be described below. The units for the elemental content in the component composition are all "mass%", but unless otherwise specified, they will be simply referred to as "%".

[0013] C: 0.010% or less Carbon (C) is an element that forms carbides and adversely affects iron loss characteristics. In particular, the adverse effect becomes significant when it exceeds 0.010%, so C should be kept below 0.010%. Preferably, it should be below 0.004%. There is no specific lower limit for C, but since excessively reducing C leads to increased costs, it is preferable to keep it at around 0.0001%.

[0014] Si: 1.0% or more and 5.0% or less Si has the effect of increasing the resistivity of steel and reducing iron loss, and also increases the strength of steel through solid solution strengthening. To obtain these effects, the Si content should be 1.0% or more. On the other hand, if it exceeds 5.0%, the magnetic flux density decreases significantly, so the upper limit should be 5.0% or less. Therefore, the Si content should be in the range of 1.0% to 5.0%. Preferably, it is in the range of 1.5% to less than 4.5%, and more preferably in the range of 2.0% to less than 4.0%.

[0015] Mn: 0.05% or more and 5.0% or less Like silicon, manganese (Mn) is a useful element for increasing the resistivity and strength of steel. To achieve this effect, the Mn content should be 0.05% or higher. On the other hand, exceeding 5.0% may promote the deposition of MnC and degrade the magnetic properties, so the upper limit should be 5.0%. Therefore, the Mn content should be between 0.05% and 5.0%, preferably between 0.1% and 3.0%.

[0016] P:0.1% or less P is a useful element used to adjust the strength (hardness) of steel. However, if the concentration exceeds 0.1%, toughness decreases and cracking is more likely to occur during processing, so the upper limit is set at 0.1%. There is no specific lower limit, but since excessively reducing P leads to increased costs, it is preferable to set it at 0.001%. More preferably, it is in the range of 0.003% to 0.08%.

[0017] S: 0.01% or less S is an element that forms fine precipitates and adversely affects iron loss characteristics. In particular, the adverse effect becomes significant when it exceeds 0.01%, so it should be kept below 0.01%. More preferably below 0.005%. There is no specific lower limit, but since excessively reducing S leads to increased costs, it is preferable to keep it at 0.0001%. More preferably, it is in the range of 0.0003% to 0.0080%.

[0018] Al: 3.0% or less Al, like Si, is a useful element that increases the resistivity of steel and reduces iron loss. To obtain such effects, it is preferable to include 0.005% or more. More preferably 0.010% or more, and even more preferably 0.015% or more. On the other hand, if it exceeds 3.0%, it may promote nitriding on the surface of the steel sheet and degrade the magnetic properties, so the upper limit is set at 3.0%. More preferably 2.0% or less.

[0019] N: 0.0080% or less N is an element that forms fine precipitates and adversely affects iron loss characteristics. In particular, the adverse effect becomes significant when it exceeds 0.0080%, so it should be kept below 0.0080%. Preferably it is below 0.003%. There is no specific lower limit, but since excessively reducing N leads to increased costs, it is preferable to keep it at 0.0005%. More preferably it is in the range of 0.0008% to 0.0030%.

[0020] The component composition of the present invention may further contain one or more elements selected from Zn, Mo, Ni, Cr, Cu, Ca, Mg, REM, Sn, and Sb within the following ranges, depending on the required properties.

[0021] Zn: 0.0005% or more and 0.020% or less Zn is an element that is effective in improving magnetic flux density and reducing iron loss by improving texture. To obtain such effects, the Zn content should be 0.0005% or more. On the other hand, if the Zn content exceeds 0.020%, the effect saturates and unnecessarily increases costs, so the upper limit is set at 0.020%. Therefore, when Zn is included, the Zn content is preferably in the range of 0.0005% to 0.020%, and more preferably 0.0005% to 0.0050%.

[0022] Mo: 0.002% or more and 0.20% or less Mo has the effect of forming fine carbides in steel, thereby increasing the strength of the steel sheet. To obtain this effect, the Mo content should be 0.01% or more. On the other hand, if the Mo content exceeds 0.20%, excessive carbide formation occurs, and the iron loss deteriorates, so the upper limit should be 0.20%. Therefore, when Mn is included, the Mo content is preferably in the range of 0.01% to 0.20%.

[0023] Ni: 0.01% or more and 1.0% or less Ni is an element that improves the toughness of steel and can be included as appropriate. To obtain this effect, the Ni content should be 0.01% or more. However, the effect of Ni saturates when the content exceeds 1.0%, so the upper limit should be 1.0%. Therefore, when Ni is included, the Ni content is preferably in the range of 0.01% to 0.01%.

[0024] Cr: 0.01% or more and 5.0% or less Cr has the effect of increasing the resistivity of steel and reducing iron loss. To obtain such an effect, the Cr content should be 0.05% or more. On the other hand, if the Cr content exceeds 5.0%, the magnetic flux density decreases significantly along with the decrease in saturation magnetic flux density, so the upper limit should be 5.0%. Therefore, when Cr is included, the Cr content is preferably in the range of 0.01% to 5.0%, and more preferably 0.05% to 5.0%.

[0025] Cu: 0.01% or more and 1.0% or less Cu is an element that improves the toughness of steel and can be included as appropriate. To obtain this effect, the Cu content should be 0.01% or more. However, the effect saturates when Cu exceeds 1.0%, so the upper limit should be 1.0%. Therefore, when Cu is included, the Cu content is preferably in the range of 0.01% to 1.0%.

[0026] Ca: 0.0001% or more and 0.10% or less Ca is an element that contributes to reducing iron loss by fixing sulfur as a sulfide. To obtain this effect, the Ca content should be 0.0001% or more. On the other hand, if Ca exceeds 0.10%, the effect saturates, leading to an unnecessary increase in costs, so the upper limit should be set at 0.10%. Therefore, when Ca is included, the Ca content is preferably in the range of 0.0001% to 0.10%.

[0027] Mg: 0.0001% or more and 0.10% or less Magnesium (Mg) is an element that contributes to reducing iron loss by fixing sulfur (S) as a sulfide. To obtain this effect, the Mg content should be 0.0001% or more. On the other hand, if the Mg content exceeds 0.10%, the effect saturates, leading to an unnecessary increase in costs, so the upper limit should be set at 0.10%. Therefore, when Mg is included, the Mg content is preferably in the range of 0.0001% to 0.10%.

[0028] REM: 0.0001% or more and 0.10% or less REM is a group of elements that fix sulfur (S) as a sulfide, contributing to the reduction of iron loss. To obtain this effect, the REM content should be 0.0001% or more. On the other hand, if the REM content exceeds 0.10%, the effect saturates, leading to an unnecessary increase in costs, so the upper limit is set at 0.10%. Therefore, when REM is included, it is preferable that the REM content is in the range of 0.0001% to 0.10%.

[0029] Sn: 0.001% or more and 0.20% or less Sn (Tin) is an element that is effective in improving magnetic flux density and reducing iron loss by improving texture. To obtain such effects, the Sn content should be 0.001% or more. On the other hand, if the Sn content exceeds 0.20%, the effect saturates, leading to an unnecessary increase in costs, so the upper limit should be set at 0.20%. Therefore, when Sn is included, the Sn content is preferably in the range of 0.001% to 0.20%.

[0030] Sb: 0.001% or more and 0.20% or less Sb is an effective element for improving magnetic flux density and reducing iron loss by improving texture. To obtain these effects, the Sb content should be 0.001% or higher. On the other hand, if the Sb content exceeds 0.20%, the effect saturates, leading to an unnecessary increase in costs; therefore, the upper limit should be 0.20%. Accordingly, when Sb is included, the Sb content is preferably in the range of 0.001% to 0.20%.

[0031] The component composition of the present invention may further contain one or more selected from B, Ti, Nb, V, Pb, Zr, Ta, W, Se, Bi, As, Co, Ge, and Ga.

[0032] B: 0.0020% or less B is an element that contributes to improving the strength of steel sheets by refining the steel sheet structure. However, if added at a concentration exceeding 0.0020%, nitrides precipitate in the steel during operation, increasing iron loss. Therefore, when B is included, the upper limit of the B content should be 0.0020%. The B content may also be 0%.

[0033] Ti: 0.010% or less Ti is an element that contributes to improving the strength of steel sheets by refining the steel sheet structure. However, adding more than 0.010% leads to excessive precipitation of carbides in the steel, increasing iron loss. Therefore, when Ti is included, the upper limit of the Ti content should be 0.010%. The Ti content may also be 0%.

[0034] Nb: 0.0050% or less Nb is an element that contributes to improving the strength of steel sheets by refining the steel sheet structure. However, adding more than 0.0050% leads to excessive precipitation of carbides in the steel, increasing iron loss. Therefore, when Nb is included, the upper limit of the Nb content should be 0.0050%. The Nb content may also be 0%.

[0035] V:0.0050% or less V is an element that contributes to improving the strength of steel sheets by refining the steel sheet structure. However, adding more than 0.0050% leads to excessive precipitation of carbides in the steel, increasing iron loss. Therefore, when V is included, the upper limit of the V content should be 0.0050%. The V content may also be 0%.

[0036] Pb: 0.0050% or less While lead (Pb) contributes to improving steel sheet strength by refining the steel sheet structure, adding more than 0.0050% leads to excessive precipitation in the steel, increasing iron loss. Therefore, when Pb is included, the upper limit of the Pb content should be 0.0050%. The Pb content may also be 0%.

[0037] Zr: 0.0050% or less Zr is an element that contributes to improving the strength of steel sheets by refining the steel sheet structure. However, adding more than 0.0050% leads to excessive precipitation of carbides in the steel, increasing iron loss. Therefore, when Zr is included, the upper limit of the Zr content should be 0.0050%. The Zr content may also be 0%.

[0038] Ta: 0.0020% or less Ta (T) is an element that contributes to improving the strength of steel sheets by refining the steel sheet structure. However, adding more than 0.0020% leads to excessive precipitation of carbides in the steel, increasing iron loss. Therefore, when Ta is included, the upper limit of the Ta content should be 0.0020%. The Ta content may also be 0%.

[0039] W: 0.0050% or less W is an element that contributes to improving the strength of steel sheets by refining the steel sheet structure. However, adding more than 0.0050% leads to excessive precipitation of carbides in the steel, increasing iron loss. Therefore, when W is included, the upper limit of the W content should be 0.0050%. The W content may also be 0%.

[0040] Se: 0.0050% or less Se is an element that contributes to improving the strength of steel sheets by refining the steel sheet structure. However, if added at concentrations exceeding 0.0050%, excessive precipitation of MnSe in the steel increases iron loss. Therefore, when Se is included, the upper limit of the Se content should be 0.0050%. The Se content may be 0%.

[0041] Bi:0.0050% or less Bi (Bi) is an element that contributes to improving the strength of steel sheets by refining the steel sheet structure. However, adding more than 0.0050% leads to excessive precipitation in the steel, increasing iron loss. Therefore, when Bi is included, the upper limit of the Bi content should be 0.0050%. The Bi content may also be 0%.

[0042] As: 0.020% or less As contributes to improving the magnetic flux density of steel sheets by improving the texture. However, the effect saturates at concentrations above 0.030%. Therefore, when As is included, the upper limit of the As content should be 0.10%. The As content may also be 0%.

[0043] Co:0.10% or less Co contributes to improving the magnetic flux density of steel plates by increasing the saturation magnetic flux density. However, adding more than 0.10% results in excessively high costs. Therefore, when Co is included, the upper limit of the Co content should be set at 0.10%. The Co content may also be 0%.

[0044] Ge: 0.030% or less Ge contributes to improving the magnetic flux density of steel sheets by improving the texture. However, the effect saturates at concentrations above 0.030%. Therefore, when Ge is included, the upper limit of the Ge content should be set at 0.10%. The Ge content may also be 0%.

[0045] Ga: 0.030% or less Ga contributes to improving the magnetic flux density of steel sheets by improving the texture. However, the effect saturates at concentrations above 0.030%. Therefore, when Ga is included, the upper limit of the Ga content should be 0.10%. The Ga content may also be 0%.

[0046] In the above component composition, the remainder other than the components mentioned above consists of Fe and unavoidable impurities.

[0047] <Microorganism> Next, the microstructure of the hot-rolled and annealed sheet of the present invention will be described.

[0048] (Average crystal grain size at the center of the plate width d C The crystal grain size d at a position 10 mm from the edge of the plate width E Ratio d C / d E (1.2 or higher) According to the inventors' research, it was found that by creating a difference in grain size between the central part of the plate width and the area near the edge of the plate width, fracture and edge cracking during the cold rolling process were suppressed more significantly than when the grain size of the entire hot-rolled and annealed plate was simply made finer. The following reasons are presumed to be for this: Generally, the work hardening rate for plastic deformation decreases as the grain size decreases. When the grain size in the region near the edge of the plate width is smaller than that in the center of the plate width, the work hardening rate in the region near the edge of the plate width is smaller than that in the center of the plate width. This results in a stress acting during rolling that reduces the tension in the region near the edge of the plate width, which is presumed to significantly suppress the occurrence of crack initiation points in the region near the edge of the plate width, thereby reducing fracture and edge cracking.

[0049] Furthermore, our investigations have shown that the difference in crystal grain size between the central part of the plate width and the region near the edge of the plate width is the average crystal grain size d at a position 10 mm from the edge of the plate width. E The average grain size d of the hot-rolled and annealed sheet at the center of the sheet width. C ratio d C / d E It was found that by setting the ratio d to 1.2 or higher, it is possible to produce a hot-rolled and annealed sheet that sufficiently suppresses fracture and edge cracking during cold rolling. C / d E The ratio d is preferably 1.4 or higher, and more preferably 1.6 or higher. C / d E There are no particular restrictions on the upper limit, but for example, it can be 10 or less. For example, in a hot-rolled annealed sheet manufactured using the hot-rolled annealed sheet manufacturing method of the present invention described later, ratio d C / d E It is usually 10 or less. The average grain size d in the center of the width of the hot-rolled and annealed sheet. C and the average crystal grain size d at a position 10 mm from the edge of the plate width E Each of these can be measured by the method described in the examples.

[0050] The hot-rolled and annealed sheet of the present invention has a ratio d at at least one of the sheet width edges. C / d E It is sufficient if the ratio d is 1.2 or higher, but at both board width edges, C / d E A value of 1.2 or higher is effective in reducing fracture in subsequent processes. However, for example, if cracking or fracture occurs unevenly on one side of the edge due to the characteristics of the rolling mill, then only one side should be considered.C / d E Sufficient fracture reduction can sometimes be achieved by ensuring that the ratio is 1.2 or higher.

[0051] The following describes preferred embodiments of the hot-rolled and annealed sheet of the present invention. Unless otherwise specified, descriptions relating to the "sheet width edge portion" refer to ratio d C / d E This relates to the edge portion of the board width that satisfies 1.2 or higher.

[0052] (Average crystal grain size at the center of the plate width d C The average crystal grain size d is between 70 μm and 300 μm, and is located 10 mm from the edge of the plate width. E (10 μm to 200 μm) The hot-rolled and annealed sheet of the present invention has an average crystal grain size d at a position 10 mm from the edge of the sheet width. E The average grain size d at the center of the plate width relative to the grain size d C ratio d C / d E The value is controlled to be 1.2 or higher, and the effects of the present invention are not limited by the average grain size value at each position. However, from the point of making the effects of the present invention even more pronounced, d C and d E Each of these is preferably within the following ranges:

[0053] Average grain size d at the center of the plate width C It is preferable that the thickness is between 70 μm and 300 μm. C If the thickness is 70 μm or more, the effect of suppressing the deterioration of the magnetic properties of the electromagnetic steel sheet manufactured using the hot-rolled annealed sheet of the present invention is higher, d C If it is 300 μm or less, ratio d C / d E The fracture suppression effect can be further enhanced by controlling this factor.

[0054] Average crystal grain size d at a position 10 mm from the edge of the plate width E It is preferable that the thickness is between 10 μm and 200 μm. EIf the grain size is 10 μm or larger, the situation in which the plate width edge becomes excessively hard due to enhanced grain refinement, which conversely promotes the formation of fracture initiation points, can be easily avoided. E If it is 200 μm or less, ratio d C / d E The fracture suppression effect can be further enhanced by controlling this factor.

[0055] (Maximum value Δd of the average grain size gradient in the plate width direction) max (0.2 μm / mm to 5.0 μm / mm) According to the inventors' studies, it has been found that avoiding excessively large structural changes in the width direction of the sheet is effective in preventing fracture. To avoid the formation of stress concentration sites during rolling, which promote fracture originating from within the steel sheet, the maximum value of the average grain size gradient in the width direction of the sheet is preferably 5.0 μm / mm or less, more preferably 4.0 μm / mm or less, and even more preferably 3.0 μm / mm or less. On the other hand, ratio d C / d E To obtain a sufficient fracture suppression effect by controlling this, it is preferable that the maximum value of the average grain size gradient in the plate width direction be 0.2 μm / mm or more. The maximum value of the average grain size gradient in the plate width direction can be determined by the method described in the examples.

[0056] (The position X2 where the average grain size gradient in the width direction of the plate is maximum is within 200 mm from the edge of the plate width.) According to the inventors' studies, it has been found that by controlling the distance between the position where the average grain size gradient is maximum and the plate width edge, a sufficient fracture suppression effect can be obtained by reducing the tension at the plate width edge. Therefore, it is preferable that the position where the average grain size gradient in the plate width direction is maximum is within 200 mm from the plate width edge. More preferably, it is within 100 mm, and even more preferably, within 50 mm. The position where the average grain size gradient in the plate width direction is maximum can be determined by the method described in the examples.

[0057] The hot-rolled and annealed sheet of the present invention is used in the manufacture of electrical steel sheets. Electrical steel sheets include non-oriented electrical steel sheets and grain-oriented electrical steel sheets.

[0058] [Method for manufacturing hot-rolled annealed sheets] Next, the method for manufacturing the hot-rolled annealed sheet of the present invention will be described.

[0059] The method for manufacturing a hot-rolled annealed sheet according to the present invention is, in general terms, a method for obtaining the hot-rolled annealed sheet described above by sequentially applying hot rolling and hot-rolled sheet annealing to a steel material having the above-mentioned component composition. In the method for manufacturing a hot-rolled annealed sheet according to the present invention, as long as the steel material satisfies the component composition specified in the present invention and the hot-rolled sheet annealing conditions are within the scope of the present invention, there are no other particular limitations, and known methods can be applied.

[0060] <Steel material> The steel material is not particularly limited as long as it has the component composition described for hot-rolled and annealed sheets. The method for melting the steel material is not particularly limited, and known melting methods using converters or electric furnaces can be employed. Due to productivity issues, it is preferable to form slabs (steel material) by continuous casting after melting, but slabs may also be formed by known casting methods such as ingot-part rolling or thin slab continuous casting.

[0061] <Hot rolling process> The hot rolling process is a process of obtaining a hot-rolled sheet by hot-rolling a steel material having the above-mentioned component composition. The hot rolling process is not particularly limited as long as it is a process of heating a steel material having the above-mentioned component composition and hot-rolling it to obtain a hot-rolled sheet of a predetermined size, and known hot-rolling processes can be applied.

[0062] An example of a hot rolling process is one in which a steel material is heated to a temperature of 1000°C to 1200°C, hot-rolled at a finish rolling exit temperature of 800°C to 950°C, and after the hot rolling is completed, appropriate post-rolling cooling is performed (for example, cooling in the temperature range of 450°C to 950°C at an average cooling rate of 20°C / s to 100°C / s), and the material is wound at a winding temperature of 400°C to 700°C to obtain a hot-rolled sheet of a predetermined size and shape. The width of the obtained hot-rolled sheet can be adjusted by slitting or edge trimming at the entry side of the hot-rolled sheet annealing process. The width of the hot-rolled sheet at the time of entering the annealing furnace in the hot-rolled annealing process is usually between 600 mm and 2000 mm, and the same applies to hot-rolled annealed sheets.

[0063] <Hot-rolled sheet annealing process> The hot-rolled sheet annealing process is a process of heating the hot-rolled sheet and holding it at a high temperature to temper the hot-rolled sheet and obtain a hot-rolled annealed sheet. In the method for manufacturing a hot-rolled annealed sheet of the present invention, the hot-rolled sheet that has undergone the hot-rolling process is heated and held at an appropriate holding temperature T1 necessary for the recrystallization of the hot-rolled sheet at the center of the sheet width and then cooled. At the same time, for at least one edge of the sheet width of the hot-rolled sheet, the maximum temperature T2 reached at a position 10 mm from the edge of the sheet width satisfies the condition that T1-T2 ≥ 20°C. For both edges of the sheet width, the maximum temperature T2 reached at a position 10 mm from the edge of the sheet width may be satisfied with the condition that T1-T2 ≥ 20°C.

[0064] (The highest temperature T2 reached at a position 10mm from the edge of the board width is T1-T2 ≥ 20℃) In the hot-rolled sheet annealing process, the maximum temperature T2 reached at a position 10 mm from the edge of the sheet width is limited to T1-T2 ≥ 20°C. When T1-T2 < 20°C, the difference in grain size between the center of the sheet width and the area near the edge of the sheet width becomes smaller, and the average grain size d in the center of the sheet width becomes smaller. C The average crystal grain size d at a position 10 mm from the edge of the plate width. E ratio d C / d E It is not possible to set it to 1.2 or higher. Preferably, T1-T2 ≥ 35℃, more preferably T1-T2 ≥ 50℃.

[0065] The following describes preferred embodiments of the hot-rolled sheet annealing process in the method for manufacturing hot-rolled annealed sheets of the present invention. Unless otherwise specified, the description of the "sheet width edge portion" refers to the sheet width edge portion that is controlled to satisfy the maximum temperature T2 T1-T2 ≥ 20°C.

[0066] (The holding temperature T1 at the center of the plate width is between 900°C and 1100°C) In the hot-rolled sheet annealing process, it is preferable that the holding temperature T1 in the center of the sheet width be between 900°C and 1100°C. If T1 is 900°C or higher, it is easy to avoid the grain size in the center of the sheet width becoming excessively fine, and if T1 is 1100°C or lower, it is easy to avoid the grain size becoming excessively coarse. Therefore, by setting T1 within the above range, the average grain size d in the center of the sheet width can be set. C The particle size can easily be set to between 70 μm and 300 μm.

[0067] (Holding time t1 at the holding temperature T1 in the center of the plate width is 2 seconds or more and 120 seconds or less) In the hot-rolled sheet annealing process, it is preferable that the holding time t1 at the holding temperature T1 in the center of the sheet width be 2 seconds or more and 120 seconds or less. If t1 is 2 seconds or more, recrystallization and grain growth by hot-rolled sheet annealing will be sufficient, and the average crystal grain size d in the center of the sheet width will be large. C The grain size can easily be set to 70 μm or more, and if t1 is 120 seconds or less, the temperature profile in the plate width direction will not become excessively flat, and the average grain size gradient in the plate width direction can easily be set to 0.2 μm / mm or more.

[0068] (The maximum temperature T2 reached at a position 10 mm from the edge of the board width is between 750°C and 1000°C) In the hot-rolled sheet annealing process, it is preferable that the maximum temperature T2 reached at a position 10 mm from the edge of the sheet width be 750°C or higher and 1000°C or lower. If T2 is 750°C or higher, it is easy to avoid the grain size in the region near the edge of the sheet width becoming excessively fine, and the average grain size d at a position 10 mm from the edge of the sheet width is also fine. EIt can be easily made to 10 μm or more, and if T2 is 1000°C or less, d E It can be easily reduced to 200 μm or less.

[0069] (The time t2 during which the maximum temperature T2 at a position 10mm from the edge of the board is 50°C or higher is between 5 seconds and 50 seconds.) In the hot-rolled sheet annealing process, it is preferable to limit the time t2 during which the maximum temperature T2 (50°C or higher) at a position 10 mm from the edge of the sheet width is 5 seconds or more and 20 seconds or less. If t2 is 5 seconds or more, cooling after the maximum temperature T2 at a position 10 mm from the edge of the sheet width can be appropriately controlled, and the temperature profile in the sheet width direction does not become excessively steep, making it easy to achieve an average grain size gradient of 1.5 μm / mm or less in the sheet width direction. If t2 is 50 seconds or less, the temperature profile in the sheet width direction does not become excessively flat, making it easy to achieve an average grain size gradient of 0.2 μm / mm or more in the sheet width direction.

[0070] (The heat suppression area is between the edge of the plate width and a position X1mm from the edge of the plate width.) In the hot-rolled sheet annealing process, a heating suppression region can be set to intentionally introduce a temperature change in the sheet width direction. Specific methods include preventing overheating by weakening burner heating only in the area near the sheet width edge, preventing overheating by applying an edge cover, applying a temperature rise prevention material that suppresses radiant heating with low emissivity, and preventing temperature rise by reducing emissivity by removing mill scale only in the area near the sheet width edge. Any method that can intentionally introduce a temperature change is acceptable, and is not limited to these. Preferably, the heating suppression region is set between the sheet width edge and a position X1 mm from the sheet width edge, in the range where X1 is between 20 mm and 250 mm. If X1 is 20 mm or more, the temperature rise at a position 10 mm from the sheet width edge due to heat conduction is appropriate, and the T1-T2 can be easily set to 20°C or more. If X1 is 250 mm or less, the position where the average grain size gradient in the sheet width direction is maximum can be easily controlled to be within 200 mm from the sheet width edge. X1 is more preferably 40 mm to 150 mm. The heating suppression region is preferably provided near at least one edge of the plate width, and more preferably near both edges of the plate width.

[0071] <Acid washing process> The method for manufacturing a hot-rolled annealed sheet according to the present invention may include a pickling step. Here, the pickling step is a step of pickling the hot-rolled sheet after the hot-rolled sheet annealing step. The pickling step is not particularly limited as long as it is a step that can pickle the steel sheet to the extent that it can be cold-rolled after pickling, and known pickling steps using hydrochloric acid or sulfuric acid can be applied, for example. When the hot-rolled sheet annealing step is performed, this pickling step may be performed continuously on the same line as the hot-rolled sheet annealing step, or it may be performed on a separate line. The hot-rolled annealed sheet according to the present invention includes both the state before pickling (black scale) and the state after pickling (white scale).

[0072] [Manufacturing method for non-oriented electrical steel sheets] The method for manufacturing non-oriented electrical steel sheets of the present invention generally involves sequentially applying cold rolling and cold annealing to a hot-rolled and annealed sheet of the present invention. In the method for manufacturing non-oriented electrical steel sheets of the present invention, as long as the hot-rolled and annealed sheet of the present invention is used, there are no other particular limitations, and known methods can be applied.

[0073] <Cold rolling process> The cold rolling process is a process of cold rolling a hot-rolled, annealed sheet (pickled sheet) that has undergone the above-mentioned pickling process. In the cold rolling process, a cold-rolled sheet is obtained by cold-rolling the hot-rolled, annealed sheet that has undergone the above-mentioned pickling process. The process is not particularly limited as long as a cold-rolled sheet of a predetermined size can be obtained by cold-rolling, and known cold rolling processes can be applied.

[0074] One example of a cold rolling process is a cold rolling process in which a pickled sheet is rolled using a tandem mill with four stands under conditions where the total reduction ratio is 80% or more and less than 95%, to obtain a cold-rolled sheet of a predetermined size and shape.

[0075] <Annealing process> The annealing process involves annealing a cold-rolled sheet that has undergone the cold-rolling process to obtain a cold-rolled annealed sheet. The annealing process is not particularly limited as long as it involves heating, holding, and cooling the cold-rolled sheet to obtain a cold-rolled annealed sheet, and known annealing processes can be applied. Typically, an insulating coating is applied to the surface after the annealing process, but this method and the type of coating are not particularly limited, and known insulating coating processes can be applied.

[0076] An example of an annealing process is one in which a cold-rolled sheet is heated to a temperature of 800°C to 1200°C in a non-oxidizing atmosphere, held for 5 to 60 seconds, and then cooled.

[0077] The above describes the application of the hot-rolled annealed sheet of the present invention to the manufacture of non-oriented electrical steel sheets, but the hot-rolled annealed sheet of the present invention can also be applied to the manufacture of grain-oriented electrical steel sheets. [Examples]

[0078] The present invention will be specifically described below with reference to examples. However, the present invention is not limited to these examples.

[0079] <Manufacturing of hot-rolled and annealed sheets> Molten steel having the component compositions shown in Tables 1 and 2 was melted using commonly known methods and continuously cast to obtain a 230 mm thick slab (steel material). The obtained slab was hot-rolled to obtain a 2.0 mm thick hot-rolled sheet (1200 mm wide). The obtained hot-rolled sheet was hot-rolled annealing and pickling under the conditions shown in Tables 3 and 4 to obtain a hot-rolled annealed sheet (pickled sheet). Heat suppression zones were provided near both edges of the sheet width, and the same control was applied.

[0080] <Manufacturing of cold-rolled sheets> The aforementioned hot-rolled and annealed sheet (pickled sheet) was subjected to cold rolling at room temperature using a reverse rolling mill to obtain a cold-rolled sheet (non-oriented electrical steel sheet) with a thickness of 0.25 mm.

[0081] <Manufacturing of cold-rolled and annealed sheets> The cold-rolled sheet was subjected to annealing by a known method, which involved holding it at 1000°C for 10 seconds in a non-oxidizing atmosphere, and then an insulating coating was applied by a known method to obtain a cold-rolled and annealed sheet (non-oriented electrical steel sheet).

[0082] [Table 1] TIFF0007848943000002.tif233114

[0083] [Table 2]

[0084] [Table 3] TIFF0007848943000005.tif161170

[0085] [Table 4]

[0086] <Rating> (Tissue observation) A specimen for microstructure observation was taken from the center of the sheet width from the obtained hot-rolled and annealed sheet. Additionally, specimens for microstructure observation were taken continuously at 20mm intervals from 10mm to 410mm from one of the sheet width edges. Next, the collected specimens were embedded in resin with the surface perpendicular to the rolling direction (RD surface) as the observation surface, and polished to a mirror finish using colloidal silica polishing. Electron beam backscatter diffraction (EBSD) measurements were performed on the mirrored observation surface to obtain local orientation data. At this time, the step size was 2μm and the measurement area was 10mm. 2 The above concludes the procedure. Note that the measurement can be performed in a single scan covering the entire area, or multiple scan results can be combined using the Combo Scan function. The obtained local orientation data was analyzed using the analysis software: OIM Analysis 8. Prior to data analysis, the coordinate system was rotated so that the A1 axis was the rolling direction, the A2 axis was the direction perpendicular to rolling, and the A3 axis was the direction of the plate surface. In addition, the grain-average data points were selected using the Partition Properties of the analysis software under the condition Formula:GCI[&;5.000,2,0.000,0,0,8.0,1,1,1.0,0;]>0.1, and data points unsuitable for analysis were excluded. At this point, more than 98% of the data points were valid.

[0087] Based on the data adjusted as described above, the following analysis was performed with the following definitions of grain boundaries: Grain Tolerance Angle set to 5°, Minimum Grain Size set to 2, Minimum Anti-Grain Size set to 2, and Multiple Rows Requirement and Anti-Grain Multiple Rows Requirement both set to OFF. For the pre-processed data, the Area Average value obtained using the Grain Size (diameter) function was used as the average crystal grain size. If the average grain size at a position X1 mm from the edge of the plate is D1 μm, and the average grain size at the adjacent measurement point, at a position X1 + 20 mm from the edge of the plate, is D2 μm, then the average grain gradient at a position X1 + 10 mm from the edge is defined as (D2 - D1) / 10 [μm / mm], and the maximum value in the plate width direction is defined as the maximum average grain gradient.

[0088] (Rollability evaluation) The number of edge cracks per 1000m of the obtained cold-rolled sheet was investigated. Edge cracks with a length of 2mm or more were counted as number N. Cold-rolling properties were considered good if the number of edge cracks per 1000m was 2 or less.

[0089] (Evaluation of magnetic properties) From the obtained cold-rolled and annealed sheet, magnetic measurement test specimens measuring 30 mm in width and 280 mm in length were taken with the length direction oriented in the rolling direction and perpendicular to the rolling direction, and the magnetic flux density B of the cold-rolled and annealed sheet was measured by the Epstein method in accordance with JIS C2550-1:2011. 50 and iron loss W 10 / 400 B was measured. 50 The magnetic flux density is considered good if ≥ 1.50(T) and B50 / Bs ≥ 0.81, W 10 / 400 A value of ≤15.0 (W / kg) was considered to indicate good iron loss characteristics.

[0090] [Table 5] TIFF0007848943000008.tif165170

[0091] [Table 6]

[0092] The results in Tables 5 and 6 show that all hot-rolled and annealed sheets according to the present invention have excellent cold-rolling properties, and furthermore, cold-rolled and annealed sheets obtained by cold-rolling and annealing the hot-rolled and annealed sheets according to the present invention also possess excellent magnetic properties. [Industrial applicability]

[0093] According to the present invention, a hot-rolled annealed sheet for electrical steel sheets, which exhibits excellent cold-rolling properties (fracture resistance and edge cracking resistance) in subsequent processes, is provided along with an advantageous manufacturing method. Electrical steel sheets manufactured using the hot-rolled annealed sheet of the present invention exhibit sufficient avoidance of magnetic property degradation. In particular, by using the hot-rolled annealed sheet of the present invention in the manufacture of non-oriented electrical steel sheets, it is possible to provide non-oriented electrical steel sheets with high magnetic flux density and low iron loss at high frequencies, and by using these non-oriented electrical steel sheets, high efficiency of motors can be achieved. Thus, the present invention has high industrial utility.

Claims

1. In mass percent, C: 0.010% or less, Si: 1.0% or more and 5.0% or less, Mn: 0.05% or more and 5.0% or less, P: 0.1% or less, S: 0.01% or less, Al: 3.0% or less and N: Includes 0.0080% or less, The composition consists of Fe and unavoidable impurities. At least one of the board width edges, Average grain size d at the center of the plate width C The average crystal grain size d at a position 10 mm from the edge of the plate width E Ratio d C / d E A hot-rolled and annealed sheet for non-oriented electrical steel sheets that satisfies the requirement of 1.2 or higher.

2. The aforementioned component composition is expressed in mass%, and further Zn: 0.0005% or more and 0.020% or less, Mo: 0.002% or more and 0.20% or less, Ni: 0.01% or more and 1.0% or less, Cr: 0.01% or more and 5.0% or less, Cu: 0.005% or more and 1.0% or less, Ca: 0.0001% or more and 0.10% or less, Mg: 0.0001% or more and 0.10% or less, REM: 0.0001% or more and 0.10% or less, Sn: 0.001% or more and 0.20% or less, Sb: 0.001% or more and 0.20% or less, B: 0.0020% or less, Ti: 0.010% or less, Nb: 0.0050% or less, V: 0.0050% or less, Pb: 0.0050% or less, Zr: 0.0050% or less, Ta: 0.0020% or less, W: 0.0050% or less, Se: 0.0050% or less, Bi: 0.0050% or less, As: 0.020% or less, Co: 0.10% or less, Ge: 0.030% or less and Ga: 0.030% or less Includes one or more species selected from the group consisting of, The hot-rolled and annealed sheet for non-oriented electrical steel sheets according to claim 1.

3. A hot-rolled and annealed sheet for non-oriented electrical steel sheets according to claim 1, satisfying at least one of the following (1) to (4). (1) The average crystal grain size d in the center of the plate width C The particle size is 70 μm or more and 300 μm or less, and the average crystal grain size d is located 10 mm from the edge of the plate width. E The size is between 10 μm and 200 μm. (2) The maximum value of the average grain size gradient in the plate width direction is 0.2 μm / mm or more and 1.5 μm / mm or less. (3) The position where the average grain size gradient in the plate width direction is maximum is within 200 mm from the plate width edge. (4) At both plate width edge portions, the average crystal grain size d at the center of the plate width C and the average crystal grain size d at a position 10 mm from the plate width edge portion E satisfy a ratio d C / d E of 1.2 or more.

4. A hot-rolled and annealed sheet for non-oriented electrical steel sheets according to claim 2, satisfying at least one of the following (1) to (4). (1) The average crystal grain size d in the center of the plate width C The particle size is 70 μm or more and 300 μm or less, and the average crystal grain size d is located 10 mm from the edge of the plate width. E The size is between 10 μm and 200 μm. (2) The maximum value of the average grain size gradient in the plate width direction is 0.2 μm / mm or more and 1.5 μm / mm or less. (3) The position where the average grain size gradient in the plate width direction is maximum is within 200 mm from the plate width edge. (4) At both plate width edges, the average crystal grain size d in the center of the plate width C The average crystal grain size d at a position 10 mm from the edge of the plate width. E Ratio d C / d E The value is 1.2 or higher.

5. A method for manufacturing a hot-rolled and annealed sheet for non-oriented electrical steel sheets according to any one of claims 1 to 4, comprising: a hot-rolling step of obtaining a hot-rolled sheet by hot-rolling a steel material having the composition according to claim 1 or 2; and a hot-rolled sheet annealing step of hot-rolled sheet annealing the hot-rolled sheet, wherein in the hot-rolled sheet annealing step, the center of the width of the hot-rolled sheet is held at a temperature T 1 When holding the sheet, the highest temperature reached T is located 10 mm from the edge of the sheet width at at least one of the sheet width edges of the hot-rolled sheet. 2 is T 1 -T 2 A method for manufacturing hot-rolled and annealed sheets for non-oriented electrical steel sheets, satisfying a temperature of ≥ 20℃.

6. A method for manufacturing a hot-rolled and annealed sheet for non-oriented electrical steel sheets according to claim 5, satisfying at least one of the following (1) to (5). (1) In the hot-rolled sheet annealing process, the holding temperature T of the center of the sheet width of the hot-rolled sheet 1 The temperature is between 900°C and 1150°C, and the T 1 Retention time t 1 The time is between 1 second and 120 seconds. (2) In the hot rolled sheet annealing process, the maximum temperature T 2 The temperature is between 750°C and 1000°C. (3) In the hot-rolled sheet annealing process, the highest temperature T is reached at a position 10 mm from the edge of the sheet width of the hot-rolled sheet. 2 The time at which the temperature is above -50°C 2 The time is between 5 seconds and 50 seconds. (4) In the hot-rolled sheet annealing process, the heating suppression region is the sheet width edge and X from the sheet width edge. 1 It is between the mm position and X 1 The length is between 20mm and 250mm. (5) At both width edges of the hot-rolled sheet, the highest temperature reached at a position 10 mm from the width edge is T 2 is T 1 -T 2 The temperature must be ≥ 20℃.

7. A method for manufacturing non-oriented electrical steel sheets, comprising a cold rolling step of cold rolling a hot-rolled and annealed sheet for non-oriented electrical steel sheets according to any one of claims 1 to 4 to obtain a cold-rolled sheet, and an annealing step of annealing the cold-rolled sheet.

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