Liquid crystal diffraction elements, optical elements, image display units, head-mounted displays, beam steering, and sensors

Abstract

To provide a liquid crystal diffraction element having high diffraction efficiency regardless of a diffraction angle, an optical element using the same, an image display unit, a head mounted display, a beam steering, and a sensor that use the same.SOLUTION: A liquid crystal diffraction element comprises an optical anisotropic layer formed using a liquid crystal composition containing a liquid crystal compound. The optical anisotropic layer has a liquid crystal alignment pattern in which an orientation of an optical axis derived from the liquid crystal compound changes while continuously rotating along one direction in a plane, and when a length in which the orientation of the optical axis derived from the liquid crystal compound rotates by 180° in the plane is defined as one period, the length of the one period in the liquid crystal alignment pattern gradually changes in the one direction. The optical anisotropic layer has a bright portion and a dark portion that extend from one surface to the other surface in a sectional image obtained by observing a section cut in a thickness direction along the one direction with a scanning electron microscope, the dark portion has two or more angle inflection points and has regions different in an inclination direction of the dark portion in the thickness direction, and an average inclination angle of the dark portion gradually changes along the one direction.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] The present invention relates to a liquid crystal diffraction element that diffracts incident light, an optical element using the same, and an image display unit, head-mounted display, beam steering, and sensor using the same. [Background technology]

[0002] Optical elements that control the direction of light are used in many optical devices or systems. For example, optical elements that control the direction of light are used in various optical devices, such as the backlight of liquid crystal display devices, head-mounted displays (HMDs) such as AR (Augmented Reality) glasses, VR (Virtual Reality) glasses, and MR (Mixed Reality) glasses that overlay virtual images and various information onto the actual view, head-up displays (HUDs), projectors, beam steering, and sensors for detecting objects and measuring the distance to objects.

[0003] As an optical element that controls the direction of light in this way, a liquid crystal diffraction element having an optically anisotropic layer formed using a liquid crystal composition containing a liquid crystal compound has been proposed.

[0004] Patent Document 1 discloses a polarization diffraction grating comprising a substrate and a first polarization diffraction grating layer on the substrate, the first polarization diffraction grating layer containing a molecular structure that is twisted according to a first torsion over a first thickness defined between both sides of the first polarization diffraction grating layer. Patent Document 1 states that the polarization diffraction grating layer can diffract light by aligning liquid crystal molecules in a predetermined orientation pattern. [Prior art documents] [Patent Documents]

[0005] [Patent Document 1] Special Publication No. 2010-525394 [Overview of the project] [Problems that the invention aims to solve]

[0006] Incidentally, liquid crystal diffraction elements, which diffract light by changing the liquid crystal orientation pattern within a plane, are expected to be applied as optical components in various optical devices. However, liquid crystal diffraction elements that diffract light by changing the liquid crystal orientation pattern within a plane have a problem in that the diffraction efficiency decreases as the diffraction angle increases, that is, the intensity of the diffracted light weakens.

[0007] Therefore, in the case of elements that exhibit a lens function by diffracting light by changing the liquid crystal orientation pattern within the plane, where the diffraction angle differs depending on the incident position of light, differences in diffraction efficiency occur depending on the incident position within the element plane. In other words, there was a problem in that regions where transmitted light becomes darker occur depending on the incident position within the element plane.

[0008] The object of the present invention is to solve the problems of the prior art described above, and to provide a liquid crystal diffraction element that has high diffraction efficiency regardless of the diffraction angle, an optical element using the same, and an image display unit, head-mounted display, beam steering, and sensor using the same. [Means for solving the problem]

[0009] To solve this problem, the present invention has the following configuration. [1] comprising an optically anisotropic layer formed using a liquid crystal composition containing a liquid crystal compound, The optically anisotropic layer has a liquid crystal alignment pattern in which the orientation of the optical axis derived from the liquid crystal compound changes while continuously rotating along at least one direction in the plane. When the length of a 180° rotation of the optical axis originating from the liquid crystal compound is defined as one period, the length of one period in the liquid crystal alignment pattern gradually changes along one direction. An optically anisotropic layer, when viewed as a cross-sectional image obtained by scanning an electron microscope of a cross-section cut along one direction in the thickness direction, has bright and dark areas extending from one surface to the other, and the dark areas have inflection points at two or more angles. In the thickness direction, there are regions where the gradient direction of the dark areas is different. A liquid crystal diffraction element in which the average tilt angle of the dark area gradually changes along one direction. [2] A liquid crystal diffraction element as described in [1], wherein the average tilt angle of the dark area increases as the length of one period in the liquid crystal alignment pattern decreases. [3] A liquid crystal diffraction element according to [1] or [2], wherein the number of inflection points in the dark area where the direction of inclination is reversed is odd. [4] A liquid crystal diffraction element according to any of [1] to [3], wherein the number of inflection points in the dark area where the direction of inclination is reversed is one. [5] A liquid crystal diffraction element as described in any of [1] to [3], wherein the number of inflection points in the dark area where the direction of inclination is reversed is three. [6] A liquid crystal diffraction element according to any one of [1] to [5], wherein the liquid crystal orientation pattern of the optical anisotropy layer is a concentric pattern having one direction in which the orientation of the optical axis derived from the liquid crystal compound changes while rotating continuously, in a concentric pattern from the inside outwards. [7] The liquid crystal diffraction element according to [6], wherein the optical anisotropy layer has symmetrical shapes of light and dark areas with respect to the center line in the thickness direction of the optical anisotropy layer in a cross-section of the concentric central portion, and asymmetrical shapes of light and dark areas with respect to the center line in the thickness direction of the optical anisotropy layer in a cross-section of the concentric end portion. [8] The liquid crystal diffraction element according to [6], wherein the optical anisotropy layer has asymmetric shapes of bright and dark areas with respect to the center line in the thickness direction of the optical anisotropy layer in a cross-section of the concentric central portion, and asymmetric shapes of bright and dark areas with respect to the center line in the thickness direction of the optical anisotropy layer in a cross-section of the concentric end portion. [9] Refractive index difference Δn due to refractive index anisotropy of the optically anisotropic layer 550 A liquid crystal diffraction element as described in any of [1] to [8], wherein the ratio is 0.2 or greater.

[10] A liquid crystal diffraction element according to any one of [1] to [9], having a region in the plane where the length of one period in the liquid crystal alignment pattern is 1.0 μm or less.

[11] An optical element having a liquid crystal diffraction element and a circular polarizer as described in any of [1] to

[10] .

[12] The optical element according to

[11] , wherein the circular polarizer consists of a phase difference plate and a polarizer, and the liquid crystal diffraction element, the phase difference plate and the polarizer are arranged in this order.

[13] The optical element according to

[12] , wherein the phase difference plate is a λ / 4 plate.

[14] The optical element according to

[12] or

[13] , wherein the phase difference plate has inverse wavelength dispersion.

[15] An optical element having a liquid crystal diffraction element, a silicon oxide layer, and a support in that order, as described in any of [1] to

[10] .

[16] An optical element having at least one liquid crystal diffraction element as described in any of [1] to

[10] or an optical element as described in any of

[11] to

[15] , and having at least one phase modulation element.

[17] An image display unit having a liquid crystal diffraction element as described in any of [1] to

[10] or an optical element as described in any of

[11] to

[15] .

[18] A head-mounted display having the image display unit described in

[17] .

[19] Beam steering having a liquid crystal diffracting element as described in any of [1] to

[10] or an optical element as described in any of

[11] to

[15] .

[20] A sensor having a liquid crystal diffractometer as described in any of [1] to

[10] or an optical element as described in any of

[11] to

[15] . [Effects of the Invention]

[0010] The present invention solves the problems of the prior art and provides a liquid crystal diffraction element that has high diffraction efficiency regardless of the diffraction angle. [Brief explanation of the drawing]

[0011] [Figure 1]Figure 1 is a conceptual diagram showing an example of the optical anisotropy layer of the liquid crystal diffraction element of the present invention. [Figure 2] Figure 2 is a plan view of the optically anisotropic layer shown in Figure 1. [Figure 3] Figure 3 is a magnified view of the portion indicated by A in Figure 1. [Figure 4] Figure 4 is a magnified view of the portion indicated by B in Figure 1. [Figure 5] Figure 5 is a conceptual diagram showing another example of the optical anisotropy layer of the liquid crystal diffraction element of the present invention. [Figure 6] Figure 6 is a magnified view of the area indicated by C in Figure 5. [Figure 7] Figure 7 is a magnified view of the portion indicated by D in Figure 5. [Figure 8] Figure 8 is a partially enlarged view of the plan view of the optically anisotropic layer. [Figure 9] Figure 9 is a cross-sectional view showing a magnified portion of the optically anisotropic layer. [Figure 10] Figure 10 is a conceptual diagram showing an example of an exposure apparatus for exposing an alignment film. [Figure 11] Figure 11 is a conceptual diagram showing an example of an exposure apparatus for exposing an alignment film that forms the optical anisotropy layer shown in Figure 2. [Figure 12] Figure 12 is a conceptual diagram illustrating the function of the optical anisotropy layer. [Figure 13] Figure 13 is a conceptual diagram illustrating the function of the optical anisotropy layer. [Figure 14] Figure 14 is a conceptual diagram illustrating the operation of the liquid crystal diffraction element shown in Figure 1. [Figure 15] Figure 15 is a conceptual diagram illustrating another example of an optically anisotropic layer. [Figure 16] Figure 16 is a conceptual diagram illustrating another example of an optically anisotropic layer. [Figure 17] Figure 17 is a conceptual diagram illustrating another example of an optically anisotropic layer. [Figure 18] Figure 18 is a conceptual diagram illustrating another example of an optically anisotropic layer. [Modes for carrying out the invention]

[0012] The liquid crystal diffraction element, optical element, image display unit, head-mounted display, beam steering, and sensor of the present invention will be described in detail below based on preferred embodiments shown in the attached drawings.

[0013] In this specification, a numerical range represented by "~" means a range that includes the numbers written before and after "~" as the lower and upper limits, respectively. In this specification, "(meth)acrylate" means "either acrylate or methacrylate, or both."

[0014] In this specification, visible light refers to electromagnetic waves with wavelengths visible to the human eye, specifically light in the wavelength range of 380 to 780 nm. Non-visible light refers to light with wavelengths less than 380 nm and greater than 780 nm.

[0015] In this specification, Re(λ) represents the in-plane retardation at wavelength λ. Unless otherwise specified, wavelength λ is assumed to be 550 nm. In this specification, Re(λ) is the value measured at wavelength λ using AxoScan (manufactured by Axometrics). By inputting the average refractive index ((nx+ny+nz) / 3) and film thickness (d(μm)) into AxoScan, Slow axis direction (°) Re(λ)=R0(λ) This is calculated. Note that R0(λ) is a value displayed by AxoScan, and it means Re(λ).

[0016] [Liquid crystal diffraction element] The liquid crystal diffraction element of the present invention is The device comprises an optically anisotropic layer formed using a liquid crystal composition containing a liquid crystal compound, The optically anisotropic layer has a liquid crystal alignment pattern in which the orientation of the optical axis derived from the liquid crystal compound changes while continuously rotating along at least one direction in the plane. When the length of a 180° rotation of the optical axis originating from the liquid crystal compound is defined as one period, the length of one period in the liquid crystal alignment pattern gradually changes along one direction. An optically anisotropic layer, when viewed as a cross-sectional image obtained by scanning an electron microscope of a cross-section cut along one direction in the thickness direction, has bright and dark areas extending from one surface to the other, and the dark areas have inflection points at two or more angles. In the thickness direction, there are regions where the gradient direction of the dark areas is different. This is a liquid crystal diffraction element in which the average tilt angle of the dark area gradually changes along one direction.

[0017] Figure 1 conceptually shows an example of the liquid crystal diffraction element of the present invention. Figure 2 shows a top view of the liquid crystal diffraction element (optical anisotropy layer) of Figure 1. Figure 1 conceptually represents the bright and dark areas observed due to the liquid crystal phase when the optical anisotropy layer 36a is observed with a scanning electron microscope (SEM).

[0018] The liquid crystal diffraction element 10a in Figures 1 and 2 has an optically anisotropic layer 36a formed using a composition containing a liquid crystal compound. The optically anisotropic layer 36a is formed using a composition containing a liquid crystal compound and has a predetermined liquid crystal orientation pattern in which the optical axis derived from the liquid crystal compound changes while continuously rotating along at least one direction in the plane. In the example shown in Figure 2, the liquid crystal alignment pattern of the liquid crystal layer 36 is a concentric pattern in which the orientation of the optical axis of the liquid crystal compound 40 changes in one direction (arrows A1 to A3) as it rotates continuously, and these directions are concentric circles extending from the inside to the outside. A concentric pattern is a pattern in which the lines connecting liquid crystal compounds with the same optical axis orientation are circular, and the circular line segments are concentric. In other words, the liquid crystal alignment pattern of the optical anisotropic layer 36a shown in Figure 2 is a liquid crystal alignment pattern in which the orientation of the optical axis of the liquid crystal compound 40 changes in one direction as it rotates continuously, and these directions are provided radially from the center of the liquid crystal layer 36.

[0019] In the optically anisotropic layer 36a shown in Figure 2, the optical axis (not shown) of the liquid crystal compound 40 is the longitudinal direction of the liquid crystal compound 40. In the optically anisotropic layer 36a, the orientation of the optical axis of the liquid crystal compound 40 changes while continuously rotating along multiple directions extending outward from the center of the optically anisotropic layer 36a, for example, the direction indicated by arrow A1, the direction indicated by arrow A2, the direction indicated by arrow A3, and so on. Arrows A1, A2, and A3 are the array axes, which will be described later. Figure 1 shows, for example, an image obtained by SEM of a cross-section along arrow A1. SEM images of cross-sections along arrows A2 and A3 are also shown in Figure 1.

[0020] The optically anisotropic layer 36a of the liquid crystal diffraction element 10a has regions in the plane where the period Λ of the liquid crystal alignment pattern is different. Here, the period Λ of the liquid crystal alignment pattern is the length (distance) over which the optical axis of the liquid crystal compound 40 rotates by 180° in one direction in which the orientation of the optical axis changes continuously within the plane of the liquid crystal alignment pattern. Specifically, Figure 1 is a diagram showing a cross-section along arrow A1 in Figure 2, for example, and has a configuration in which, in the direction in which the orientation of the optical axis of the liquid crystal compound 40 changes while continuously rotating, the period Λ gradually shortens as you move from the center outward. That is, in Figure 1, the period Λ2 near the outside is shorter than the period Λ1 near the center. In this invention, the term "gradual change of one period Λ" refers to both a continuous change of one period Λ and a stepwise change of one period Λ.

[0021] As will be explained in detail later, the diffraction angle produced by a liquid crystal diffraction element depends on the period Λ of the liquid crystal orientation pattern; the smaller the period Λ, the larger the diffraction angle.

[0022] If the optical anisotropic layer 36a has a liquid crystal alignment pattern that radiates radially from the center of the optical anisotropic layer 36a in one direction in which the orientation of the optical axis of the liquid crystal compound 40 changes as it rotates continuously, and in each direction the period Λ of the liquid crystal alignment pattern gradually shortens as it moves outward from the center, then circularly polarized light incident on the optical anisotropic layer 36a having this liquid crystal alignment pattern is bent (diffracted) in each local region where the orientation of the optical axis of the liquid crystal compound 40 is different. In this case, the diffraction angle of each differs according to the period of the region in which the circularly polarized light was incident. An optical anisotropic layer 36a having a concentric liquid crystal alignment pattern, that is, a liquid crystal alignment pattern in which the optical axis changes as it rotates radially, can transmit incident light as focused light depending on the direction of rotation of the optical axis of the liquid crystal compound 40 and the direction of the incident circularly polarized light. In other words, by making the liquid crystal alignment pattern of the optical anisotropic layer 36a concentric, the liquid crystal diffraction element 10a functions, for example, as a convex lens.

[0023] In this invention, as shown in Figure 1, the optically anisotropic layer 36a has a bright area 42 and a dark area 44 extending from one surface to the other surface in an SEM image, the dark area 44 has inflection points at two or more angles, and in the thickness direction, there are regions where the inclination direction of the dark area 44 is different, and the average inclination angle of the dark area 44 gradually changes along one direction (arrows A1, A2, A3, etc.) in which the orientation of the optical axis of the liquid crystal compound 40 changes while continuously rotating.

[0024] In the example shown in Figure 1, the optically anisotropic layer 36a has a striped pattern of bright areas 42 and dark areas 44, and each dark area 44 has a change in inclination angle relative to the surface at two locations in the thickness direction. That is, each dark area 44 has two inflection points. Furthermore, in each dark area 44, the inclination direction in the upper region of the figure and the inclination direction in the lower region of the figure are opposite to each other. That is, each dark area 44 has regions with different inclination directions. Specifically, in the part of the optically anisotropic layer 36a to the right of the center shown in Figure 1, the dark area 44 is inclined to the right in the upper region of the figure, and to the left in the lower region of the figure. On the other hand, in the part of the optically anisotropic layer 36a to the left of the center, the dark area 44 is inclined to the left in the upper region of the figure, and to the right in the lower region of the figure.

[0025] Furthermore, in the optically anisotropic layer 36a, if the average tilt angle is defined as the angle that the line connecting the contact points of one surface of each dark area 44 to the other surface makes with the perpendicular to the main surface of the optically anisotropic layer 36a, then the average tilt angle of the dark areas 44 gradually changes along one direction (arrows A1, A2, A3, etc.) in which the orientation of the optical axis of the liquid crystal compound 40 changes as it rotates continuously. Specifically, in the example shown in Figure 1, the average tilt angle of the dark areas 44 near the center is approximately 0°, and the average tilt angle gradually increases as you move outward from the center. That is, in the illustrated example of the optically anisotropic layer 36a, the average tilt angle of the dark areas 44 gradually increases as the period Λ of the liquid crystal alignment pattern gradually shortens. In this invention, the phrase "gradual change in the average tilt angle of the dark area" refers to both a continuous change in the average tilt angle and a stepwise change in the average tilt angle.

[0026] Such an optically anisotropic layer 36a has three regions (37a, 37b, and 37c) in the thickness direction, and it can also be said that the inclination angle of the dark area 44 at the same position in the planar direction is different in each region.

[0027] Here, the orientation of the liquid crystal in the optically anisotropic layer 36a, in which the dark areas have inflection points at two or more angles and the average tilt angle of the dark areas changes gradually, will be explained using Figures 3 and 4. Figure 3 is a conceptual diagram showing an enlarged view of the portion indicated by A in Figure 1, and Figure 4 is a conceptual diagram showing an enlarged view of the portion indicated by B in Figure 1. In other words, Figure 3 is a conceptual diagram showing an enlarged view of the central portion of the optical anisotropy layer 36a, and Figure 4 is a conceptual diagram showing an enlarged view of the outer portion of the optical anisotropy layer 36a. Furthermore, in Figures 3 and 4, the arrangement of the liquid crystal compound 40 and the bright areas 42 and dark areas 44 observed by SEM due to the liquid crystal phase are superimposed. Note that in Figure 4, only the liquid crystal compound 40 oriented parallel to the plane of the paper is shown, but as shown in the enlarged view of the portion enclosed by the dashed line in Figure 4, the liquid crystal compound 40 is arranged to rotate counterclockwise toward the right in the figure.

[0028] As shown in Figures 3 and 4, in the optical anisotropy layer 36a, at any position in the thickness direction, the optical axis originating from the liquid crystal compound 40 (not shown, in the same direction as the longitudinal direction of the liquid crystal compound 40) rotates counterclockwise (leftward when viewed from the top in the figures) outward from the center in the planar direction.

[0029] Furthermore, as shown in Figure 3, in the central portion, the liquid crystal compound 40 is oriented such that it is twisted clockwise (right-handed) in the lower region 37c in the thickness direction, from the top to the bottom in the figure. On the other hand, in the middle region 37b in the thickness direction, the liquid crystal compound 40 is not twisted in the thickness direction, and the liquid crystal compounds 40 stacked in the thickness direction have the same optical axis oriented in the same direction. In other words, the liquid crystal compounds 40 located at the same position in the plane direction have the same optical axis oriented in the same direction. Furthermore, in the upper region 37a in the thickness direction, the liquid crystal compound 40 is oriented so as to twist counterclockwise (leftward) from the top to the bottom in the thickness direction.

[0030] In other words, in the example shown in Figure 3, the torsional state of the liquid crystal compound 40 in the thickness direction is different in regions 37a, 37b, and 37c of the optically anisotropic layer 36a.

[0031] In the SEM image of the optically anisotropic layer 36a, the bright areas 42 and dark areas 44 are observed to connect liquid crystal compounds 40 with the same orientation. As an example, Figure 3 shows that the dark areas 44 are observed to connect liquid crystal compounds 40 whose optical axes are parallel to the plane of the paper.

[0032] Because the torsional state of the liquid crystal compound 40 in the thickness direction is different in regions 37a, 37b, and 37c of the optically anisotropic layer 36a, the bright areas 42 and dark areas 44 in the SEM image have a roughly C-shape, as shown in Figure 3.

[0033] Furthermore, in the example shown in Figure 3, the thickness of region 37a and the thickness of region 37c are approximately the same, and the twist angle in the thickness direction of the liquid crystal compound 40 in region 37a is approximately the same as the twist angle in the thickness direction of the liquid crystal compound 40 in region 37c. Therefore, the dark areas 44 in region 37a and the dark areas 44 in region 37c have opposite tilt directions and the same tilt angle. In region 37b, the liquid crystal compound 40 is not twisted in the thickness direction, so the dark areas 44 are not tilted. Therefore, the average tilt angle of the dark areas 44 in the central part of the optically anisotropic layer 36a is approximately 0°.

[0034] On the other hand, in the outer portion shown in Figure 4, the liquid crystal compound 40 is oriented in the lower region 37c in the thickness direction to twist clockwise (right-handed) from the top to the bottom in the figure. The twist angle in the thickness direction is larger in the outer portion of region 37c compared to the central portion. Furthermore, in the middle region 37b in the thickness direction, the liquid crystal compound 40 is oriented so as to twist clockwise (right-handed) from the top to the bottom in the thickness direction. Furthermore, the torsion angle in the thickness direction in region 37c is different from the torsion angle in the thickness direction in region 37b. Therefore, the dark area 44 in region 37c and the dark area 44 in region 37b have the same inclination direction, but different inclination angles.

[0035] On the other hand, in the upper region 37a in the thickness direction, the liquid crystal compound 40 is oriented to twist counterclockwise (leftward) from the top to the bottom in the thickness direction. Therefore, region 37a is tilted in the opposite direction to regions 37c and 37b. Also, the twist angle in the thickness direction is smaller in the outer part of region 37a compared to the central part. Therefore, the absolute value of the tilt angle of the dark area 44 in region 37a is smaller than the absolute value of the tilt angle of the dark area 44 in region 37c.

[0036] Therefore, the average tilt angle of the dark area 44 in the outer portion of the optical anisotropy layer 36a is a value other than 0°.

[0037] In the example shown in Figure 1, regions 37a, 37b, and 37c of the optically anisotropic layer 36a have a configuration in which the period Λ of the liquid crystal alignment pattern gradually shortens from the center outward. Furthermore, in region 37c, the right-handed twist in the thickness direction increases from the center outward, in region 37b, the right-handed twist in the thickness direction increases from the center outward, and in region 37a, the left-handed twist in the thickness direction decreases from the center outward. This can be described as adding a right-handed twist to the thickness direction twist at the center as it moves outward in each region.

[0038] By configuring the one-period Λ of the liquid crystal alignment pattern in regions 37a, 37b, and 37c, and the twist angle in the thickness direction in this manner, it is possible to create a configuration in which the average tilt angle of the dark area 44 is approximately 0° in the center and gradually increases towards the outside.

[0039] As shown in Figure 1, in such an optically anisotropic layer 36a, the shapes of the bright areas 42 and dark areas 44 are symmetrical with respect to the center line in the thickness direction of the optically anisotropic layer 36a in the cross-section of the concentric central part, and the shapes of the bright areas 42 and dark areas 44 are asymmetrical with respect to the center line in the thickness direction of the optically anisotropic layer 36a in the cross-section of the concentric ends.

[0040] As mentioned above, liquid crystal diffraction elements that diffract light by changing the liquid crystal orientation pattern in a plane have a problem in that the diffraction efficiency decreases as the diffraction angle increases, that is, the intensity of the diffracted light weakens. Specifically, in the diffraction of light by an optically anisotropic layer having a liquid crystal orientation pattern in which the direction of the optical axis of the liquid crystal compound changes while continuously rotating in a plane, there is a problem in that the diffraction efficiency decreases as the diffraction angle increases, that is, the intensity of the diffracted light weakens. Therefore, if the optically anisotropic layer is configured to have regions with different lengths for one period in which the direction of the optical axis of the liquid crystal compound rotates 180° in a plane, the diffraction angle will differ depending on the incident position of the light, resulting in a difference in the amount of diffracted light depending on the incident position in the plane. In other words, there is a problem in that regions where the transmitted and diffracted light becomes darker will occur depending on the incident position in the plane.

[0041] In contrast, the liquid crystal diffraction element of the present invention has a configuration in which the length of one period in the liquid crystal orientation pattern of the optical anisotropy layer gradually changes along one direction, thereby changing the diffraction angle of light in the plane. In the SEM image of the optical anisotropy layer, the dark areas observed have two or more inflection points, and there are regions in the thickness direction where the slope direction of the dark areas differs, and the average slope angle of the dark areas gradually changes along this direction in accordance with the direction of change of one period in the liquid crystal orientation pattern. By having such a configuration in the optical anisotropy layer, it is possible to suppress the decrease in diffraction efficiency even in regions where the diffraction angle is large. As a result, a liquid crystal diffraction element can be made in which the diffraction efficiency is high regardless of the diffraction angle and the amount of transmitted light is uniform.

[0042] Furthermore, the liquid crystal diffraction element of the present invention has such an optically anisotropic layer 36a, that is, a bright area 42 and a dark area 44 extending from one surface to the other surface in a cross-sectional SEM image, and the dark area 44 has inflection points at two or more angles and has regions with different gradient directions in the thickness direction, thereby reducing the wavelength dependence of the diffraction efficiency and enabling the diffraction of light with a similar diffraction efficiency regardless of wavelength.

[0043] As described above, a liquid crystal diffraction element having an optical anisotropic layer having a liquid crystal orientation pattern in which the orientation of the optical axis derived from the liquid crystal compound rotates continuously in at least one direction can diffract incident light at different diffraction angles depending on the wavelength over a wide wavelength range, such as the entire visible light spectrum. However, according to the inventors' studies, conventional liquid crystal diffraction elements having a liquid crystal alignment pattern have dark areas that are tilted relative to the surface (main surface) in cross-sectional SEM images, but they do not have inflection points where the angle changes, or, as shown in Patent Document 1, they have only one inflection point. Therefore, conventional liquid crystal diffraction elements have a large wavelength dependence of diffraction efficiency; for example, the diffraction efficiency of red and green light is high, but the diffraction efficiency of blue light is lower compared to the other two colors.

[0044] In contrast, the liquid crystal diffraction element of the present invention has a low wavelength dependence of diffraction efficiency, as the dark area 44 observed in the cross-sectional SEM image has two or more inflection points at different angles, and has regions with different gradient directions in the thickness direction. This allows it to diffract light with similar diffraction efficiency regardless of wavelength. Moreover, it can diffract light with high diffraction efficiency regardless of wavelength.

[0045] In the example shown in Figure 1, the optical anisotropy layer 36a is configured to have two inflection points where the tilt angle of each dark area 44 changes, but it is not limited to this configuration, and each dark area 44 may have three or more inflection points.

[0046] Furthermore, in the example shown in Figure 1, the optical anisotropic layer 36a has one inflection point where the slope direction is reversed in each dark area 44, except for the dark area 44 located in the center in the left-right direction. Specifically, in each dark area 44, the slope direction in region 37a and the slope direction in region 37b are opposite. Therefore, the inflection point located at the interface between region 37a and region 37b is the inflection point where the slope direction is reversed.

[0047] In the present invention, each dark area 44 is not limited to having one inflection point where the inclination direction is reversed, but may have two or more inflection points where the inclination direction is reversed. It is preferable that there be an odd number of inflection points where the inclination direction is reversed.

[0048] Figure 5 shows a conceptual representation of another example of the liquid crystal diffraction element of the present invention. Figure 5 conceptually represents the bright and dark areas observed due to the liquid crystal phase when the optical anisotropy layer 36b is observed with a scanning electron microscope (SEM). The liquid crystal diffraction element 10b shown in Figure 5 is an example that has an optical anisotropy layer 36b having three inflection points where the dark area is folded back in the opposite direction of the gradient.

[0049] The liquid crystal diffraction element 10b in Figure 5 has an optically anisotropic layer 36b formed using a composition containing a liquid crystal compound. The optically anisotropic layer 36b is formed using a composition containing a liquid crystal compound and has a predetermined liquid crystal orientation pattern in which the optical axis derived from the liquid crystal compound changes while continuously rotating along at least one direction in the plane. The plan view of the optically anisotropic layer 36b is the same as in Figure 2.

[0050] The optical anisotropy layer 36b of the liquid crystal diffraction element 10b has regions in the plane where the period Λ of the liquid crystal orientation pattern differs. That is, in Figure 5, the period Λ2 near the outside is shorter than the period Λ1 near the center. The optically anisotropic layer 36b, like the optically anisotropic layer 36a, has a concentric liquid crystal alignment pattern, and because the period Λ of the liquid crystal alignment pattern changes from the center outward, it functions as a convex lens.

[0051] Here, as shown in Figure 5, the optically anisotropic layer 36b has a bright area 42 and a dark area 44 extending from one surface to the other surface in the SEM image, the dark area 44 has inflection points at three angles, and in the thickness direction, there are regions where the inclination direction of the dark area 44 is different, and the average inclination angle of the dark area 44 gradually changes along one direction in which the orientation of the optical axis of the liquid crystal compound 40 changes as it rotates continuously.

[0052] In the example shown in Figure 5, the optically anisotropic layer 36b has a striped pattern of bright areas 42 and dark areas 44, and each dark area 44 has a changing inclination angle relative to the surface at three locations in the thickness direction. That is, each dark area 44 has three inflection points. Furthermore, in each dark area 44, the inclination direction of the dark area 44 in regions 37d, 37e, 37f, and 37g from the top of the figure alternates. That is, each dark area 44 has regions with different inclination directions. In addition, each dark area 44 has three inflection points where the inclination direction reverses.

[0053] Specifically, in the portion to the right of the center of the optical anisotropy layer 36b shown in Figure 5, in the upper region 37d in the figure, the dark area 44 is tilted to the right; in region 37e, the dark area 44 is tilted to the left; in region 37f, the dark area 44 is tilted to the right; and in region 37g, the dark area 44 is tilted to the left. On the other hand, in the portion to the left of the center of the optical anisotropy layer 36b, in the upper region 37d in the figure, the dark area 44 is tilted to the left; in region 37e, the dark area 44 is tilted to the right; in region 37f, the dark area 44 is tilted to the left; and in region 37g, the dark area 44 is tilted to the right.

[0054] Furthermore, in the optically anisotropic layer 36b, the average tilt angle of each dark area 44 gradually changes along one direction in which the orientation of the optical axis of the liquid crystal compound 40 changes as it rotates continuously. Specifically, in the example shown in Figure 5, the average tilt angle of the dark area 44 near the center is approximately 0°, and the average tilt angle gradually increases as you move outward from the center. In other words, in the illustrated example of the optically anisotropic layer 36b, the average tilt angle of the dark areas 44 gradually increases as the period Λ of the liquid crystal alignment pattern gradually shortens.

[0055] Such an optically anisotropic layer 36b has four regions (37d, 37e, 37f, 37g) in the thickness direction, and it can also be said that the inclination angle of the dark area 44 at the same position in the plane direction is different in each region.

[0056] The orientation of the liquid crystal in the optically anisotropic layer 36b will be explained using Figures 6 and 7. Figure 6 is a conceptual diagram showing an enlarged view of the portion indicated by C in Figure 5, and Figure 7 is a conceptual diagram showing an enlarged view of the portion indicated by D in Figure 5. In other words, Figure 6 is a conceptual diagram showing an enlarged view of the central portion of the optical anisotropy layer 36b, and Figure 7 is a conceptual diagram showing an enlarged view of the outer portion of the optical anisotropy layer 36b. Furthermore, in Figures 6 and 7, the arrangement of the liquid crystal compound 40 and the bright areas 42 and dark areas 44 observed by SEM due to the liquid crystal phase are superimposed. Note that in Figure 7, only the liquid crystal compound 40 oriented parallel to the plane of the paper is shown, but as shown in the enlarged view of the portion enclosed by the dashed line in Figure 7, the liquid crystal compound 40 is arranged to rotate counterclockwise toward the right in the figure.

[0057] As shown in Figures 6 and 7, in the optical anisotropy layer 36a, at any position in the thickness direction, the optical axis originating from the liquid crystal compound 40 (not shown, in the same direction as the longitudinal direction of the liquid crystal compound 40) rotates counterclockwise (leftward when viewed from the top in the figures) outward from the center in the planar direction.

[0058] Furthermore, as shown in Figure 6, in the central portion, the liquid crystal compound 40 is oriented such that it is twisted clockwise (right-handed) in the thickness direction from the top to the bottom in the figure in the lower region 37g. On the other hand, in region 37f, the liquid crystal compound 40 is oriented so as to be twisted counterclockwise (leftward) in the thickness direction from the top to the bottom in the figure. Furthermore, in region 37e, the liquid crystal compound 40 is oriented so as to be twisted clockwise (right-handed) in the thickness direction from the top to the bottom in the figure. Furthermore, in the upper region 37d in the thickness direction, the liquid crystal compound 40 is oriented so as to twist counterclockwise (leftward) from the top to the bottom in the figure in the thickness direction.

[0059] In other words, in the example shown in Figure 6, the torsional state of the liquid crystal compound 40 in the thickness direction differs in regions 37d to 37g of the optically anisotropic layer 36b.

[0060] Because the torsional state of the liquid crystal compound 40 in the thickness direction is different in regions 37a, 37b, and 37c of the optically anisotropic layer 36a, the bright areas 42 and dark areas 44 in the SEM image have a roughly W shape, as shown in Figure 6.

[0061] Furthermore, in the example shown in Figure 6, the thickness of region 37d and region 37g are approximately the same, and the torsion angle in the thickness direction of the liquid crystal compound 40 in region 37d is approximately the same as the torsion angle in the thickness direction of the liquid crystal compound 40 in region 37g. Therefore, the dark areas 44 in region 37d and region 37g have opposite tilt directions and the same tilt angle. Also, the thickness of region 37e and region 37f are approximately the same, and the torsion angle in the thickness direction of the liquid crystal compound 40 in region 37e is approximately the same as the torsion angle in the thickness direction of the liquid crystal compound 40 in region 37f. Therefore, the dark areas 44 in region 37e and region 37f have opposite tilt directions and the same tilt angle. Consequently, the average tilt angle of the dark areas 44 in the central part of the optical anisotropy layer 36b is approximately 0°.

[0062] On the other hand, in the outer portion shown in Figure 7, the liquid crystal compound 40 is oriented so as to twist clockwise (right-handed) in the thickness direction from the top to the bottom in the lower region 37g. The twist angle in the thickness direction is larger in the outer portion of region 37g compared to the central portion. Furthermore, in region 37f, the liquid crystal compound 40 is oriented to twist counterclockwise (leftward) in the thickness direction from the top to the bottom in the figure. The twist angle in the thickness direction is larger in the outer part of region 37f compared to the central part. Furthermore, in region 37e, the liquid crystal compound 40 is oriented to twist clockwise (right-handed) in the thickness direction from the top to the bottom in the figure. The twist angle in the thickness direction is larger in the outer part of region 37e compared to the central part. Furthermore, in region 37d, the liquid crystal compound 40 is oriented to twist counterclockwise (leftward) in the thickness direction from the top to the bottom in the figure. In the outer part of region 37d, the twist angle in the thickness direction is smaller than in the central part.

[0063] Therefore, the inclination direction of the dark areas 44 in regions 37g and 37e is different from that of the dark areas 44 in regions 37f and 37d, and the absolute value of the inclination angle of the dark areas 44 in region 37d is smaller than the absolute value of the inclination angle of the dark areas 44 in the other regions. Therefore, the average tilt angle of the dark area 44 in the outer portion of the optical anisotropy layer 36b is a value other than 0°.

[0064] By configuring the period Λ of the liquid crystal alignment pattern in regions 37d to 37g, and the twist angle in the thickness direction in this manner, it is possible to create a configuration in which the average tilt angle of the dark area 44 is approximately 0° in the center and gradually increases towards the outside.

[0065] As shown in Figure 5, in such an optically anisotropic layer 36b, the shapes of the bright areas 42 and dark areas 44 are symmetrical with respect to the center line in the thickness direction of the optically anisotropic layer 36b in the cross-section of the concentric central part, and the shapes of the bright areas 42 and dark areas 44 are asymmetrical with respect to the center line in the thickness direction of the optically anisotropic layer 36b in the cross-section of the concentric ends.

[0066] Thus, even when the optical anisotropy layer 36b is configured such that the bright area 42 and the dark area 44 are roughly W-shaped and have three inflection points where the inclination direction is reversed, it is possible to create a liquid crystal diffraction element that has high diffraction efficiency regardless of the diffraction angle and uniform light intensity regardless of the diffraction angle, even in a configuration where the diffraction angle of light differs within the plane.

[0067] As another example of a central region, an optically anisotropic layer having four regions in the thickness direction corresponding to the inflection point of the dark area 44 is exemplified, as conceptually shown in Figure 16. In this example, in the lowest region, the dark area 44 is inclined towards the upper left of the figure. In the second-to-last region, the dark area 44 is inclined towards the upper left of the figure at a larger angle relative to the surface than in the lowest region. In the third-to-last region, the dark area 44 is inclined towards the upper right of the figure. Furthermore, in the uppermost region, the dark area 44 is inclined towards the upper right of the figure at a smaller angle relative to the surface than in the third-to-last region.

[0068] In other words, the optically anisotropic layer shown in Figure 16 has three inflection points where the angle of the dark area 44 changes, and one inflection point where the direction of the dark area slope is reversed, at the interface between the second-to-last region and the third-to-last region. In the optical anisotropy layer shown in Figure 16, the bottommost region and the topmost region, as well as the second-to-last region and the third-to-last region, have equal thickness. Furthermore, although the slope directions are different, the angle (absolute value of the angle) between the surface of the optical anisotropy layer and the dark area 44 is equal between the bottommost region and the topmost region. Similarly, although the slope directions are different, the angle between the surface of the optical anisotropy layer and the dark area 44 is equal between the second-to-last region and the third-to-last region. In other words, the optically anisotropic layer shown in Figure 16 also has a roughly C-shape in its bright areas 42 and dark areas 44 in the cross-sectional SEM image. Therefore, the shape of the dark areas 44 in the optically anisotropic layer shown in Figure 16 is symmetrical with respect to the center line in the thickness direction.

[0069] The angle of the dark area 44 with respect to the surface of the optically anisotropic layer can be adjusted by the length of one period, which is the length of the optical axis rotating 180° in one direction within the plane, and the magnitude of the twist of the liquid crystal compound 40 which is torsionally oriented in the thickness direction, as will be described later.

[0070] As another example of a central region, an optically anisotropic layer having five regions in the thickness direction, corresponding to the inflection point of the dark area 44, is conceptually shown in Figure 17. In this example, in the bottommost region, the dark area 44 is inclined towards the upper left in the figure. In the second-to-last region, the dark area 44 is inclined towards the upper left in the figure at a larger angle relative to the surface than in the bottommost region. In the third-to-last region, i.e., the central region in the thickness direction, the dark area 44 extends in the thickness direction of the optical anisotropy layer. In the fourth-to-last region, the dark area 44 is inclined towards the upper right in the figure. Furthermore, in the topmost region, the dark area 44 is inclined towards the upper right in the figure at a smaller angle relative to the surface than in the fourth-to-last region.

[0071] In other words, the optically anisotropic layer shown in Figure 17 has four inflection points where the angle of the dark area 44 changes. Furthermore, the slope direction of the dark area 44 is reversed between the bottommost region and the second-to-last region, and between the fourth-to-last region and the topmost region. Therefore, the inflection point located at the interface between the second-to-last region and the fourth-to-last region is the inflection point where the slope direction is reversed. In other words, the optical anisotropic layer shown in Figure 16 has one inflection point where the slope direction is reversed.

[0072] In the optically anisotropic layer shown in Figure 17, the bottommost region and the topmost region, as well as the second-to-last region and the second-to-last region, have equal thickness. In this optically anisotropic layer, the bottom region and the top region have different gradient directions, but the angle between the surface of the optically anisotropic layer and the dark area 44 is equal. Similarly, the second region from the bottom and the fourth region from the bottom have different gradient directions, but the angle between the surface of the optically anisotropic layer and the dark area 44 is equal. Furthermore, in the third region from the bottom, located in the middle, the dark area 44 extends in the thickness direction of the optically anisotropic layer. In other words, the optically anisotropic layer shown in Figure 17 also has a roughly C-shape in its bright areas 42 and dark areas 44 in the cross-sectional SEM image. Therefore, the optically anisotropic layer shown in Figure 4 also has a symmetrical shape in its dark areas 44 with respect to the center line in the thickness direction.

[0073] Furthermore, the optical anisotropy layer of the liquid crystal diffraction element of the present invention can also be configured such that the dark areas 44 change continuously by shortening the spacing between regions in the thickness direction, i.e., the spacing between inflection points in the thickness direction, as conceptually illustrated in Figure 18 by illustrating a configuration having a substantially C-shaped dark area 44 as shown in Figures 16 and 17.

[0074] As described above, in the examples shown in Figures 16 to 18, the average tilt angle of the dark area 44 in the outer portion of the optical anisotropy layer is a value other than 0°. Therefore, it can be said that in the cross-section of the concentric central portion of the optical anisotropic layer, the shapes of the bright areas 42 and dark areas 44 are symmetrical with respect to the center line in the thickness direction of the optical anisotropic layer, while in the cross-section of the concentric end portions, the shapes of the bright areas 42 and dark areas 44 are asymmetrical with respect to the center line in the thickness direction of the optical anisotropic layer.

[0075] In the examples shown in Figures 1 and 5, and Figures 16 to 18, the shapes of the bright and dark areas are symmetrical with respect to the centerline in the thickness direction of the optical anisotropy layer in the cross-section of the concentric central portion, and the shapes of the bright and dark areas are asymmetrical with respect to the centerline in the thickness direction of the optical anisotropy layer in the cross-section of the concentric end portions. However, the configuration is not limited to this, and the shapes of the bright and dark areas are asymmetrical with respect to the centerline in the thickness direction of the optical anisotropy layer in the cross-section of the concentric central portion, and the shapes of the bright and dark areas are asymmetrical with respect to the centerline in the thickness direction of the optical anisotropy layer in the cross-section of the concentric end portions.

[0076] While the optically anisotropic layers described above all utilize rod-shaped liquid crystal compounds, the present invention is not limited to this, and disc-shaped liquid crystal compounds can also be used. In the case of disc-shaped liquid crystal compounds, the optical axis originating from the liquid crystal compound is defined as an axis perpendicular to the disc surface, also known as the phase-advancing axis. Furthermore, in the liquid crystal diffraction element of the present invention, the optical anisotropy layer may be a combination of a rod-shaped liquid crystal compound and a disc-shaped liquid crystal compound, as conceptually shown in Figure 15. By combining a rod-shaped liquid crystal compound and a disc-shaped liquid crystal compound, light can be diffracted with high diffraction efficiency for light incident at different angles. Note that the combination of the rod-shaped liquid crystal compound and the disc-shaped liquid crystal compound is not limited to the configuration conceptually shown in Figure 15, and can be used in various configurations. For example, in Figures 4, 6, 7, 16, 17, and 18, the rod-shaped liquid crystal compound may be a combination of a rod-shaped liquid crystal compound and a disc-shaped liquid crystal compound. Also, for example, in Figure 15 and the above combinations, the rod-shaped liquid crystal compound and the disc-shaped liquid crystal compound may be further subdivided in the thickness direction and stacked.

[0077] Although the liquid crystal diffraction elements 10a and 10b in the illustrated example have only an optical anisotropy layer, they may have other layers. For example, they may have a support and an alignment film for forming the optical anisotropy layer.

[0078] The following describes each component. Figure 9 is a conceptual diagram showing a magnified view of a minute region of a liquid crystal diffraction element including the optical anisotropy layer 36a (region 37c). Figure 8 is a front view of the optical anisotropy layer 36a shown in Figure 9. The liquid crystal diffraction element shown in Figure 9 comprises a support 30, an alignment film 32, and an optical anisotropy layer 36a.

[0079] <<Support>> The support 30 supports the alignment film 32 and the optical anisotropy layer 36a. The support 30 can be any type of sheet material (film, plate) as long as it can support the alignment film and the optical anisotropy layer. The support 30 is preferably a transparent support, and examples include polyacrylic resin films such as polymethyl methacrylate, cellulose resin films such as cellulose triacetate, cycloolefin polymer films (for example, "Arton" (trade name), manufactured by JSR Corporation, "Zeonor" (trade name), manufactured by Nippon Zeon Co., Ltd.), polyethylene terephthalate (PET), polycarbonate, and polyvinyl chloride. The support is not limited to a flexible film, but may also be a non-flexible substrate such as a glass substrate. Furthermore, the support 30 may be multilayered, and examples of multilayered support include one of the above-mentioned supports as a substrate, with other layers provided on the surface of this substrate.

[0080] There are no restrictions on the thickness of the support 30; the thickness should be set appropriately to accommodate the alignment film and the optical anisotropy layer, depending on the application of the liquid crystal diffraction element and the material used to form the support 30. The thickness of the support 30 is preferably 1 to 1000 μm, more preferably 3 to 250 μm, and even more preferably 5 to 150 μm.

[0081] <<Orientation film>> An alignment film 32 is formed on the surface of the support 30. The alignment film 32 is an alignment film used to orient the liquid crystal compound 40 into a predetermined liquid crystal alignment pattern when forming the optical anisotropy layer 36a.

[0082] As described above, in the liquid crystal diffraction element of the present invention, the optical anisotropy layer has a liquid crystal alignment pattern in which the orientation of the optical axis 40A (see Figure 8) originating from the liquid crystal compound 40 changes while continuously rotating along one direction in the plane (the direction of arrow X described later). Therefore, the alignment film is formed so that the optical anisotropy layer can form this liquid crystal alignment pattern. Furthermore, in a liquid crystal alignment pattern, in one direction where the orientation of the optical axis 30A changes while continuously rotating, the length of a 180° rotation of the optical axis 30A is defined as one period Λ (the rotation period of the optical axis).

[0083] In the following explanation, "the orientation of optical axis 40A rotates" will also be simply referred to as "optical axis 40A rotates."

[0084] Various known alignment films can be used. Examples include rubbing-treated films made of organic compounds such as polymers, obliquely vapor-deposited films of inorganic compounds, films having microgrooves, and films formed by accumulating Langmuir-Blodgett (LB) films of organic compounds such as ω-tricosanoic acid, dioctadecylmethylammonium chloride, and methyl stearylate using the Langmuir-Blodgett method.

[0085] An orientation film formed by rubbing can be created by rubbing the surface of a polymer layer several times in a certain direction with paper or cloth. Preferred materials for the orientation film include polyimide, polyvinyl alcohol, polymers having polymerizable groups as described in Japanese Patent Publication No. 9-152509, materials used for forming orientation films as described in Japanese Patent Publication Nos. 2005-97377, 2005-99228, and 2005-128503.

[0086] In the liquid crystal diffraction element of the present invention, a so-called photo-alignment film is preferably used as the alignment film, which is formed by irradiating a photo-alignable material with polarized or unpolarized light. That is, in the liquid crystal diffraction element of the present invention, a photo-alignment film formed by coating a photo-alignment material onto a support 30 is preferably used as the alignment film. Polarized light irradiation can be applied perpendicularly or obliquely to the photo-alignment film, while unpolarized light irradiation can be applied obliquely to the photo-alignment film.

[0087] Examples of photo-alignment materials that can be used in the photo-alignment film applicable to the present invention include those described in Japanese Patent Publication No. 2006-285197, Japanese Patent Publication No. 2007-76839, Japanese Patent Publication No. 2007-138138, Japanese Patent Publication No. 2007-94071, Japanese Patent Publication No. 2007-121721, Japanese Patent Publication No. 2007-140465, Japanese Patent Publication No. 2007-156439, and Japanese Patent Publication No. 20 Azo compounds described in Japanese Patent Publication No. 07-133184, Japanese Patent Publication No. 2009-109831, Japanese Patent No. 3883848 and Japanese Patent No. 4151746, aromatic ester compounds described in Japanese Patent Publication No. 2002-229039, maleimides having photo-orienting units described in Japanese Patent Publication No. 2002-265541 and Japanese Patent Publication No. 2002-317013 Examples of preferred materials include and / or alkenyl-substituted nadiimide compounds, photocrosslinkable silane derivatives described in Japanese Patent No. 4205195 and Japanese Patent No. 4205198, photocrosslinkable polyimides, photocrosslinkable polyamides and photocrosslinkable esters described in Japanese Patent Publication No. 2003-520878, Japanese Patent Publication No. 2004-529220 and Japanese Patent No. 4162850, and photodimerizable compounds described in Japanese Patent Publication No. 9-118717, Japanese Patent Publication No. 10-506420, Japanese Patent Publication No. 2003-505561, International Publication No. 2010 / 150748, Japanese Patent Publication No. 2013-177561 and Japanese Patent Publication No. 2014-12823, particularly cinnamate compounds, chalcone compounds and coumarin compounds. Among these, azo compounds, photocrosslinkable polyimides, photocrosslinkable polyamides, photocrosslinkable esters, cinnamate compounds, and chalcone compounds are particularly suitable for use.

[0088] There are no restrictions on the thickness of the alignment film; the appropriate thickness should be set according to the material used to form the alignment film, so as to obtain the required alignment function. The thickness of the orientation film is preferably 0.01 to 5 μm, and more preferably 0.05 to 2 μm.

[0089] There are no limitations on the method for forming the alignment film, and various known methods depending on the material used to form the alignment film can be used. As an example, one method involves coating the alignment film onto the surface of the support 30, drying it, and then exposing the alignment film with laser light to form an alignment pattern.

[0090] Figure 10 conceptually shows an example of an exposure apparatus that forms an orientation pattern by exposing an orientation film.

[0091] The exposure apparatus 60 shown in Figure 10 comprises a light source 64 equipped with a laser 62, a λ / 2 plate 65 that changes the polarization direction of the laser light M emitted from the laser 62, a beam splitter 68 that separates the laser light M emitted from the laser 62 into two beams MA and MB, mirrors 70A and 70B positioned on the optical paths of the two separated beams MA and MB, respectively, and λ / 4 plates 72A and 72B. Although not shown in the diagram, the light source 64 emits linearly polarized light P0. The λ / 4 plate 72A converts the linearly polarized light P0 (ray MA) into right-circularly polarized light P R λ / 4 plate 72B converts linearly polarized light P0 (ray MB) to left-circularly polarized light P L Convert them to the following:

[0092] A support 30 having an alignment film 32 before the alignment pattern is formed is placed in the exposure section, two light rays MA and MB are made to intersect and interfere on the alignment film 32, and the resulting interference light is irradiated onto the alignment film 32 to expose it. Due to the interference in this process, the polarization state of the light irradiated onto the alignment film 32 changes periodically in an interference fringe pattern. As a result, an alignment pattern in which the alignment state changes periodically is obtained in the alignment film 32. In other words, an alignment film having an alignment pattern in which the alignment state changes periodically (hereinafter also referred to as a patterned alignment film) is obtained. In the exposure apparatus 60, the period of the orientation pattern can be adjusted by changing the intersection angle α of the two light rays MA and MB. That is, in the exposure apparatus 60, by adjusting the intersection angle α, the length of one period (one period Λ) in which the optical axis 40A rotates 180° in one direction in an orientation pattern in which the optical axis 40A originating from the liquid crystal compound 40 rotates continuously along one direction can be adjusted. By forming an optically anisotropic layer on a patterned orientation film having an orientation pattern in which such an orientation state changes periodically, an optically anisotropic layer 36a can be formed having a liquid crystal orientation pattern in which the optical axis 40A originating from the liquid crystal compound 40 rotates continuously in one direction, as will be described later. Furthermore, by rotating the optical axes of the λ / 4 plates 72A and 72B by 90° each, the rotation direction of the optical axis 40A can be reversed.

[0093] As described above, the pattern alignment film has an orientation pattern that aligns liquid crystal compounds such that the orientation of the optical axis of the liquid crystal compound in the optical anisotropy layer formed on the pattern alignment film changes while continuously rotating along at least one direction in the plane. If the orientation axis of the pattern alignment film is the axis along the direction in which the liquid crystal compound is oriented, then the pattern alignment film can be said to have an orientation pattern in which the orientation axis changes while continuously rotating along at least one direction in the plane. The orientation axis of the pattern alignment film can be detected by measuring absorption anisotropy. For example, when linearly polarized light is irradiated onto the pattern alignment film while rotating, and the amount of light transmitted through the pattern alignment film is measured, the direction in which the amount of light is maximum or minimum is observed to gradually change along one direction in the plane.

[0094] In the liquid crystal diffraction element of the present invention, the alignment film is provided as a preferred embodiment and is not an essential component. For example, by forming an orientation pattern on the support 30 using methods such as rubbing the support 30 or processing the support 30 with laser light, it is possible to configure the optical anisotropic layer 36a, etc., to have a liquid crystal orientation pattern in which the orientation of the optical axis 40A originating from the liquid crystal compound 40 changes while continuously rotating along at least one direction in the plane.

[0095] The exposure apparatus for the alignment film 32 is not limited to the example shown in Figure 10. Figure 11 shows another example of an exposure apparatus for exposing the alignment film 32. The exposure apparatus shown in Figure 11 is an example of an exposure apparatus that forms a concentric alignment pattern on the alignment film as shown in Figure 2.

[0096] The exposure apparatus 80 includes a light source 84 equipped with a laser 82, a polarizing beam splitter 86 that splits the laser light M from the laser 82 into S-polarized MS and P-polarized MP, a mirror 90A positioned in the optical path of the P-polarized MP and a mirror 90B positioned in the optical path of the S-polarized MS, a lens 92 positioned in the optical path of the S-polarized MS, the polarizing beam splitter 94, and a λ / 4 plate 96.

[0097] The P-polarized beam MP, split by the polarizing beam splitter 86, is reflected by the mirror 90A and incident on the polarizing beam splitter 94. On the other hand, the S-polarized beam MS, also split by the polarizing beam splitter 86, is reflected by the mirror 90B, focused by the lens 92, and incident on the polarizing beam splitter 94. The P-polarized MP and S-polarized MS beams are combined by the polarizing beam splitter 94 and converted into right-circularly polarized and left-circularly polarized beams according to their polarization direction by the λ / 4 plate 96, and then incident on the alignment film 32 on the support 30. Here, the interference between right-circularly polarized and left-circularly polarized light causes the polarization state of the light irradiated onto the alignment film to change periodically in an interference fringe pattern. As you move from the inside to the outside of the concentric circles, the intersection angle between the left-circularly polarized and right-circularly polarized light changes, resulting in an exposure pattern where the pitch changes from the inside to the outside. This results in a concentric alignment pattern in the alignment film where the alignment state changes periodically.

[0098] In this exposure apparatus 80, the period Λ of the liquid crystal alignment pattern in which the optical axis of the liquid crystal compound 40 rotates continuously by 180° along one direction can be controlled by changing the refractive power of the lens 92 (F number of the lens 92), the focal length of the lens 92, and the distance between the lens 92 and the alignment film 32. Furthermore, by adjusting the refractive power of lens 92 (the F-number of lens 92), the length Λ of one period of the liquid crystal alignment pattern can be changed in one direction in which the optical axis rotates continuously. Specifically, by interfering with parallel light and changing the angle of light divergence by lens 92, the length Λ of one period of the liquid crystal alignment pattern can be changed in one direction in which the optical axis rotates continuously. More specifically, if the refractive power of lens 92 is weakened, the light approaches parallel light, so the length Λ of one period of the liquid crystal alignment pattern gradually shortens from the inside to the outside, and the F number increases. Conversely, if the refractive power of lens 92 is strengthened, the length Λ of one period of the liquid crystal alignment pattern shortens abruptly from the inside to the outside, and the F number decreases.

[0099] Furthermore, depending on the application of the liquid crystal diffraction element, such as when it is desired to create a light intensity distribution in the transmitted light, it is also possible to use a configuration in which there are regions where the period Λ is partially different in the direction of the array axis D, rather than gradually changing the period Λ in the direction of the array axis D. For example, as a method for partially changing the period Λ, one can use a method of scanning and patterning the photo-alignment film while arbitrarily changing the polarization direction of the focused laser light.

[0100] Furthermore, the wavelength of the laser used for exposure of the alignment film can be appropriately set depending on the type of alignment film used. For example, lasers with wavelengths ranging from deep ultraviolet to visible light to infrared can be preferably used. As an example, lasers with wavelengths of 266 nm, 325 nm, 355 nm, 370 nm, 385 nm, 405 nm, and 460 nm can be used, but the method is not limited to the above, and lasers of various wavelengths can be used depending on the type of alignment film.

[0101] After providing an optically anisotropic layer on the alignment film, the optically anisotropic layer may be peeled off and transferred from the alignment film. The transfer may be performed multiple times depending on the bonding surface of the optically anisotropic layer. The peeling and transfer method can be freely selected according to the purpose, but for example, after transferring it once to a substrate with an adhesive layer, it can be re-transferred to the object to be transferred to, and then the substrate can be peeled off so that the interface of the optically anisotropic layer on the alignment film side becomes the object to be transferred to. Alternatively, if the side of the optically anisotropic layer opposite the alignment film is to be transferred to the object, the optically anisotropic layer and the object to be transferred can be bonded together with an adhesive, and then the optically anisotropic layer can be peeled off from the alignment film. When peeling an optically anisotropic layer from an alignment film, it is preferable to adjust the peeling angle and speed to reduce damage (cracks, chips, etc.) to the optically anisotropic layer and the alignment film. Furthermore, the alignment film may be reused as long as it does not cause any problems with orientation. Before applying the optical anisotropy layer on the alignment film, the alignment film can also be washed with an organic solvent or the like.

[0102] <<Optical Anisotropy Layer>> An optically anisotropic layer 36a is formed on the surface of the alignment film 32. In Figure 8, the diagram is simplified to clearly show the structure of the optical anisotropic layer 36a, and therefore only the liquid crystal compound 40 (liquid crystal compound molecules) on the surface of the alignment film are shown. However, as conceptually illustrated in Figure 9, the optical anisotropic layer 36a has a structure in which oriented liquid crystal compounds 40 are stacked, similar to an optical anisotropic layer formed using a composition containing a conventional liquid crystal compound.

[0103] As described above, in the liquid crystal diffraction element of the present invention, the optical anisotropy layer 36a is formed using a composition containing a liquid crystal compound. When the in-plane retardation value is set to λ / 2, the optically anisotropic layer functions as a general λ / 2 plate, that is, it has the function of giving a half-wavelength, or 180°, phase difference to two mutually orthogonal linearly polarized components contained in the light incident on the optically anisotropic layer. In this optically anisotropic layer, the liquid crystal compound is rotated and oriented in the planar direction, so incident circularly polarized light is refracted (diffracted) and transmitted in the direction in which the optical axis is continuously rotating. At that time, the direction of diffraction differs depending on the rotation direction of the incident circularly polarized light. In other words, the optically anisotropic layer transmits circularly polarized light and diffracts this transmitted light. Furthermore, the optical anisotropy layer reverses the direction of rotation of the transmitted circularly polarized light.

[0104] The optically anisotropic layer has a liquid crystal orientation pattern in which the orientation of the optical axis originating from the liquid crystal compound changes while continuously rotating in one direction indicated by arrow D (hereinafter referred to as the array axis D) within the plane of the optically anisotropic layer. In the example shown in Figure 8, the direction of the array axis D is the X direction, and the direction perpendicular to the direction of the array axis D is the Y direction. The optical axis 40A derived from the liquid crystal compound 40 is the axis in the liquid crystal compound 40 where the refractive index is highest, also known as the slow axis. For example, if the liquid crystal compound 40 is a rod-shaped liquid crystal compound, the optical axis 40A is aligned with the long axis of the rod shape. In the following explanation, the optical axis 40A derived from the liquid crystal compound 40 will also be referred to as "the optical axis 40A of the liquid crystal compound 40" or "optical axis 40A". In the optically anisotropic layer, the liquid crystal compound 40 is oriented two-dimensionally within a plane parallel to the direction of arrow X and the direction of Y which is perpendicular to the direction of arrow X. In Figures 1, 3-4, and 5-7, the Y direction is perpendicular to the plane of the paper.

[0105] Figure 8 conceptually shows a plan view of the optically anisotropic layer 36a. In Figure 9, the plan view is a view of the liquid crystal diffraction element from above, that is, a view of the liquid crystal diffraction element from the thickness direction (= the stacking direction of each layer (film)). In other words, it is a view of the optical anisotropy layer 36a from a direction perpendicular to the main plane. Furthermore, in Figure 8, in order to clearly show the configuration of the liquid crystal diffraction element of the present invention, only the liquid crystal compound 40 on the surface of the alignment film 32 is shown. However, as mentioned above, the optical anisotropy layer 36a has a structure in which the liquid crystal compound 40 is stacked from the liquid crystal compound 40 on the surface of the alignment film 32 in the thickness direction, as shown in Figure 9.

[0106] In Figure 8, a portion of the in-plane of the optical anisotropic layer 36a is shown as a representative example. However, apart from the difference in the length of one period (period Λ) of the liquid crystal alignment pattern at each position within the plane of the optical anisotropic layer, the configuration and effects are basically the same.

[0107] The optically anisotropic layer 36a has a liquid crystal orientation pattern in which the orientation of the optical axis 40A originating from the liquid crystal compound 40 changes while continuously rotating along the direction of the array axis D within the plane of the optically anisotropic layer 36a. The statement that the orientation of the optical axis 40A of the liquid crystal compound 40 changes while continuously rotating in the direction of the array axis D (a predetermined one direction) means, specifically, that the angle between the optical axis 40A of the liquid crystal compound 40 arranged along the direction of the array axis D and the direction of the array axis D differs depending on the position in the direction of the array axis D, and that the angle between the optical axis 40A and the direction of the array axis D changes sequentially from θ to θ+180° or θ-180° along the direction of the array axis D. Furthermore, the difference in angle between the optical axes 40A of liquid crystal compounds 40 adjacent to each other in the direction of the array axis D is preferably 45° or less, more preferably 15° or less, and even more preferably a smaller angle.

[0108] On the other hand, in the liquid crystal compound 40 that forms the optical anisotropy layer 36a, in the Y direction perpendicular to the arrangement axis D direction, that is, in the Y direction perpendicular to the direction in which the optical axis 40A rotates continuously, the liquid crystal compound 40 with the same orientation of the optical axis 40A is arranged at equal intervals. In other words, in the liquid crystal compounds 40 that form the optically anisotropic layer 36a, the angle between the direction of the optical axis 40A and the direction of the alignment axis D is equal for liquid crystal compounds 40 that are aligned in the Y direction.

[0109] In the liquid crystal diffraction element of the present invention, in the liquid crystal alignment pattern of such liquid crystal compound 40, the length (distance) over which the optical axis 40A of the liquid crystal compound 40 rotates by 180° in the direction of the array axis D, where the orientation of the optical axis 40A in the plane rotates and changes continuously, is defined as the length of one period Λ in the liquid crystal alignment pattern. In other words, the length of one period in the liquid crystal alignment pattern is defined by the distance over which the angle between the optical axis 40A of the liquid crystal compound 40 and the direction of the array axis D changes from θ to θ+180°. In other words, the distance between the centers of two liquid crystal compounds 40 whose angles with respect to the array axis D are equal in the direction of the array axis D is defined as the length of one period Λ. Specifically, as shown in Figure 8, the distance between the centers of two liquid crystal compounds 40 whose array axis D coincides with the direction of the optical axis 40A is defined as the length of one period Λ. In the following explanation, this length of one period Λ will also be referred to as "period Λ". In the liquid crystal diffraction element of the present invention, the liquid crystal orientation pattern of the optical anisotropy layer repeats this one period Λ in one direction, where the orientation of the array axis D, i.e., the optical axis 40A, changes as it rotates continuously.

[0110] As described above, in the optically anisotropic layer, the liquid crystal compounds arranged in the Y direction have an equal angle between their optical axis 40A and the arrangement axis D direction (the direction in which the optical axis of the liquid crystal compound 40 rotates). The region where these liquid crystal compounds 40, which have an equal angle between their optical axis 40A and the arrangement axis D direction, are arranged in the Y direction is defined as region R. In this case, the in-plane retardation (Re) value in each region R is preferably half a wavelength, i.e., λ / 2. These in-plane retardations are calculated by the product of the refractive index difference Δn due to the refractive index anisotropy of region R and the thickness of the optical anisotropy layer. Here, the refractive index difference due to the refractive index anisotropy of region R in the optical anisotropy layer is defined as the refractive index difference between the refractive index in the direction of the slow axis in the plane of region R and the refractive index in the direction perpendicular to the direction of the slow axis. That is, the refractive index difference Δn due to the refractive index anisotropy of region R is equal to the difference between the refractive index of the liquid crystal compound 40 in the direction of the optical axis 40A and the refractive index of the liquid crystal compound 40 in the direction perpendicular to the optical axis 40A in the plane of region R. In other words, the above refractive index difference Δn is equal to the refractive index difference of the liquid crystal compound.

[0111] When circularly polarized light is incident on such an optically anisotropic layer 36a, the light is refracted and the direction of the circular polarization is changed. This effect is conceptually illustrated in Figure 12, which illustrates the optical anisotropy layer 36a. In Figures 12 and 13, to simplify the diagrams and clearly show the structure of the liquid crystal diffraction element, the optical anisotropy layer 36a only shows the liquid crystal compound 40 (liquid crystal compound molecules) on the surface of the alignment film. Furthermore, the optically anisotropic layer 36a is defined as having a product value of λ / 2 between the refractive index difference of the liquid crystal compound and the thickness of the optically anisotropic layer.

[0112] As shown in Figure 12, when the product of the refractive index difference of the liquid crystal compound in the optical anisotropy layer 36a and the thickness of the optical anisotropy layer is λ / 2, when left-circularly polarized incident light L1 is incident on the optical anisotropy layer 36a, the incident light L1 passes through the optical anisotropy layer 36a, giving it a phase difference of 180°, and the transmitted light L2 is converted to right-circularly polarized light. Furthermore, since the liquid crystal alignment pattern formed in the optically anisotropic layer 36a is a periodic pattern in the direction of the array axis D, the transmitted light L2 travels in a direction different from the direction of propagation of the incident light L1. In this way, the left-circularly polarized incident light L1 is converted into right-circularly polarized transmitted light L2, which is tilted by a certain angle in the direction of the array axis D with respect to the direction of incidence.

[0113] On the other hand, as shown in Figure 13, when the product of the refractive index difference of the liquid crystal compound in the optical anisotropy layer 36a and the thickness of the optical anisotropy layer 36a is λ / 2, when right-circularly polarized incident light L4 is incident on the optical anisotropy layer 36a, the incident light L4 passes through the optical anisotropy layer 36a, is given a phase difference of 180°, and is converted into left-circularly polarized transmitted light L5. Furthermore, since the liquid crystal alignment pattern formed in the optically anisotropic layer 36a is a periodic pattern in the direction of the array axis D, the transmitted light L5 travels in a direction different from the direction of propagation of the incident light L4. In this case, the transmitted light L5 travels in a different direction from the transmitted light L2, that is, in the direction opposite to the direction of the array axis D with respect to the direction of incidence. Thus, the incident light L4 is converted into transmitted light L5, which is left-circularly polarized and tilted by a certain angle in the direction opposite to the direction of the array axis D with respect to the direction of incidence.

[0114] The optically anisotropic layer 36a can adjust the refraction angles of transmitted light L2 and L5 by changing the period Λ of the formed liquid crystal alignment pattern. Specifically, the shorter the period Λ of the liquid crystal alignment pattern in the optically anisotropic layer 36a, the stronger the interference between light passing through adjacent liquid crystal compounds 40, thereby allowing for greater refraction of transmitted light L2 and L5. Furthermore, by reversing the rotation direction of the optical axis 40A of the liquid crystal compound 40, which rotates along the array axis D, the direction of refraction of transmitted light can be reversed. That is, in the example shown in Figures 12 and 13, the rotation direction of the optical axis 40A toward the array axis D is clockwise, but by changing this rotation direction to counterclockwise, the direction of refraction of transmitted light can be reversed.

[0115] Furthermore, as described above, the optically anisotropic layer 36a has regions where the optical axis twists and rotates in the thickness direction of the optically anisotropic layer, and has regions where the twist angle and / or twist direction in the thickness direction are different.

[0116] In the optically anisotropic layer 36a, the in-plane retardation values ​​of multiple regions R are preferably half a wavelength, but for incident light with a wavelength of 550 nm, the in-plane retardation of multiple regions R in the optically anisotropic layer 36a is Re(550) = Δn 550It is preferable that Δn × d is within the range defined by the following formula (1). Here, Δn 550 is the refractive index difference due to the refractive index anisotropy of the region R when the wavelength of the incident light is 550 nm, and d is the thickness of the optically anisotropic layer 36a. 200 nm ≦ Δn 550 × d ≦ 350 nm ··· (1) That is, if the in-plane retardation Re(550) = Δn × d of the plurality of regions R of the optically anisotropic layer 36a satisfies the formula (1), a sufficient amount of the circularly polarized light component of the light incident on the optically anisotropic layer 36a can be converted into circularly polarized light traveling in a direction inclined in the forward or reverse direction with respect to the array axis D direction. The in-plane retardation Re(550) = Δn 550 × d, if it satisfies the formula (1), can convert a sufficient amount of the circularly polarized light component of the light incident on the optically anisotropic layer 36a into circularly polarized light traveling in a direction inclined in the forward or reverse direction with respect to the array axis D direction. The in-plane retardation Re(550) = Δn 550 × d is more preferably 225 nm ≦ Δn 550 × d ≦ 340 nm, and even more preferably 250 nm ≦ Δn 550 × d ≦ 330 nm. Note that the above formula (1) is the range for incident light with a wavelength of 550 nm, but the in-plane retardation Re(λ) = Δn × d of the plurality of regions R of the optically anisotropic layer for incident light with a wavelength of λ nm is preferably within the range defined by the following formula (1-2) and can be set as appropriate. λ × d is preferably within the range defined by the following formula (1-2) and can be set as appropriate. 0.7 × (λ / 2) nm ≦ Δn λ × d ≦ 1.3 × (λ / 2) nm ··· (1-2)

[0117] Also, the value of the in-plane retardation of the plurality of regions R in the optically anisotropic layer 36a can be used outside the range of the above formula (1). Specifically, by setting Δn 550 × d < 200 nm or 350 nm < Δn 550 × d, the light traveling in the same direction as the traveling direction of the incident light and the light traveling in a direction different from the traveling direction of the incident light can be separated. When Δn 550 × d approaches 0 nm or 550 nm, the component of the light traveling in the same direction as the traveling direction of the incident light increases, and the component of the light traveling in a direction different from the traveling direction of the incident light decreases.

[0118] Furthermore, the in-plane retardation Re(450) = Δn for each region R of the optical anisotropy layer 36a for incident light with a wavelength of 450 nm is also given. 450 ×d and the in-plane retardation Re(550) = Δn of region R in the optical anisotropy layer 36a for incident light with a wavelength of 550 nm. 550 It is preferable that ×d satisfies the following equation (2). Here, Δn 450 This represents the refractive index difference due to the refractive index anisotropy of region R when the wavelength of the incident light is 450 nm. (Δt 450 ×d) / (Δn 550 ×d)<1.0···(2) Equation (2) indicates that the liquid crystal compound 40 contained in the optical anisotropic layer 36a has inverse dispersion properties. That is, when equation (2) is satisfied, the optical anisotropic layer 36a can handle incident light of a broadband wavelength.

[0119] The optically anisotropic layer consists of a cured layer of a liquid crystal composition containing a rod-shaped liquid crystal compound or a disc-shaped liquid crystal compound, and has a liquid crystal alignment pattern in which the optical axis of the rod-shaped liquid crystal compound or the optical axis of the disc-shaped liquid crystal compound is oriented as described above.

[0120] The optically anisotropic layer is formed by creating an alignment film having the orientation pattern described above on a support, and then coating and curing a liquid crystal composition on this alignment film. The structure of the optically anisotropic layer, in which the optical axis of the liquid crystal compound twists and rotates in the thickness direction of the optically anisotropic layer, can be formed by adding a chiral agent to the liquid crystal composition. Furthermore, a configuration in which the twist angle in the thickness direction differs for each region within the plane can be formed by adding a photoreactive chiral agent to the liquid crystal composition, coating the liquid crystal composition on the alignment film, and then irradiating each region with a different amount of light to make the HTP (helical twisting power) of the photoreactive chiral agent different for each region.

[0121] Specifically, in an optically anisotropic layer, a configuration in which the twist angle in the thickness direction differs for each region within the plane can be formed by using a chiral agent that undergoes reverse isomerization, dimerization, and isomerization and dimerization upon irradiation with light, thereby changing the helical twisting power (HTP). This can be achieved by irradiating the liquid crystal composition forming the optically anisotropic layer with light of a wavelength that changes the HTP of the chiral agent, varying the irradiation amount for each region, either before curing or during curing of the liquid crystal composition. For example, by using a chiral agent whose HTP decreases upon light irradiation, the HTP of the chiral agent decreases upon light irradiation. Here, by changing the amount of light irradiation in each region, for example, in regions with a high irradiation dose, the HTP decreases significantly, and the induction of helices decreases, so the twist angle of the twisted structure becomes smaller. On the other hand, in regions with a low irradiation dose, the decrease in HTP is small, so the twist angle of the twisted structure becomes larger.

[0122] There are no particular limitations on the method of changing the amount of light irradiation for each region; methods such as irradiating light through a gradient mask, changing the irradiation time for each region, or changing the irradiation intensity for each region can be used. A gradient mask is a mask in which the transmittance of light changes within the surface.

[0123] Furthermore, in order to create an optically anisotropic layer in which the dark areas have two or more inflection points, regions in the thickness direction where the gradient direction of the dark areas differs, and the average gradient angle of the dark areas gradually changes along this direction in accordance with the change direction of one period of the liquid crystal alignment pattern, it is sufficient to form optically anisotropic layers with different configurations in each region in the thickness direction.

[0124] For example, when forming the optically anisotropic layer 36a shown in Figure 1, first, a liquid crystal composition containing a photoreactive chiral agent that induces right-hand twisting in the thickness direction is applied to a pattern alignment film formed on a support, and light of different intensity levels is irradiated to each region to make the HTP (helical twisting power) of the photoreactive chiral agent different for each region, after which the liquid crystal composition is cured to form region 37c. Next, a liquid crystal composition containing a photoreactive chiral agent is applied on the formed region 37c, and light of different intensity levels is irradiated to each region to make the HTP of the photoreactive chiral agent different for each region, after which the liquid crystal composition is cured to form region 37b. In this case, region 37b may have a different structure from region 37c, and the types and amounts of components contained in the liquid crystal composition may differ from those of region 37c, as may the amount of light irradiated to change the HTP of the photoreactive chiral agent. Furthermore, when the liquid crystal composition is applied to region 37c, the liquid crystal compounds 40 in the liquid crystal composition are arranged in accordance with the arrangement of the liquid crystal compounds 40 present on the surface of region 37c. As a result, a liquid crystal orientation pattern is formed in region 37b as well, in which the period Λ gradually changes by one in the direction of the arrangement axis D.

[0125] Furthermore, a liquid crystal composition containing a photoreactive chiral agent is applied to the formed region 37b, and light of different intensity levels is irradiated to each region to make the HTP of the photoreactive chiral agent different for each region. After that, the liquid crystal composition is cured to form region 37a. In this process, region 37a is formed using a liquid crystal composition containing a photoreactive chiral agent that induces left-hand twisting in the thickness direction. Also, when the liquid crystal composition is applied to region 37b, the liquid crystal compounds 40 in the liquid crystal composition are arranged in accordance with the arrangement of liquid crystal compounds 40 present on the surface of region 37b. As a result, in region 37a as well, a liquid crystal orientation pattern is formed in which the period Λ gradually changes by one in the direction of the arrangement axis D.

[0126] As described above, by forming regions 37a, 37b, and 37c in which the torsional state of the liquid crystal compound 40 in the thickness direction is different, it is possible to form an optical anisotropic layer in which the dark area 44 has inflection points at two or more angles, has regions in the thickness direction where the inclination direction of the dark area 44 is different, and the average inclination angle of the dark area 44 gradually changes along one direction.

[0127] As shown in Figure 3, the optical anisotropic layer of the present invention shows an example where the optical axis originating from the liquid crystal compound at the interface of the optical anisotropic layer is not tilted with respect to the interface of the optical anisotropic layer. However, the optical anisotropic layer of the present invention may have an optical axis originating from the liquid crystal compound that is tilted. For example, as described in WO2019 / 189586 A1, the optical axis originating from the liquid crystal compound may have a pre-tilt angle with respect to the interface of the optical anisotropic layer. Also, as described in WO2020 / 122127 A1, the tilt angle of the optical axis originating from the liquid crystal compound may change in the thickness direction from one interface of the optical anisotropic layer to the other interface. By tilting the optical axis originating from the liquid crystal compound with respect to the interface of the optical anisotropic layer, the phase difference of the optical anisotropic layer can be adjusted, and it can be appropriately adjusted to obtain a high diffraction efficiency.

[0128] Furthermore, the optical anisotropy layer of the present invention may have varying thicknesses within the plane. By changing the thickness of the optical anisotropy layer within the plane, it is possible to appropriately adjust it to obtain high diffraction efficiency for light at different incident positions.

[0129] Furthermore, as shown in the examples in Figures 3 and 4, the thickness of regions 37a, 37b, and 37c of the optical anisotropy layer may be the same or different in the central and outer portions. Not limited to the examples described above, the liquid crystal diffraction element of the present invention may have the same or different thicknesses in each region of the optical anisotropy layer within the plane. The thickness of each region of the optical anisotropy layer can be set as appropriate to achieve the desired performance.

[0130] While the optically anisotropic layer functions as a so-called λ / 2 plate, the present invention includes embodiments in which a laminate comprising a support and an alignment film integrally functions as a λ / 2 plate. Furthermore, the liquid crystal composition for forming the optically anisotropic layer may contain a rod-shaped liquid crystal compound or a disc-shaped liquid crystal compound, and may also contain other components such as leveling agents, orientation control agents, polymerization initiators, and orientation aids.

[0131] -Rod-shaped liquid crystal compound- Preferred rod-shaped liquid crystal compounds include azomethines, azoxys, cyanobiphenyls, cyanophenyl esters, benzoic acid esters, cyclohexanecarboxylic acid phenyl esters, cyanophenylcyclohexanes, cyanosubstituted phenylpyrimidines, alkoxysubstituted phenylpyrimidines, phenyldioxanes, trans, and alkenylcyclohexylbenzonitriles. In addition to the low molecular weight liquid crystal molecules described above, high molecular weight liquid crystal molecules can also be used.

[0132] It is more preferable to fix the orientation of the rod-shaped liquid crystal compound by polymerization, and as polymerizable rod-shaped liquid crystal compounds, compounds described in Makromol. Chem., Vol. 190, p. 2255 (1989), Advanced Materials Vol. 5, p. 107 (1993), U.S. Patent No. 4683327, No. 5622648, No. 5770107, International Publication Nos. 95 / 22586, 95 / 24455, 97 / 00600, 98 / 23580, 98 / 52905, Japanese Patent Publication No. 1-272551, 6-16616, 7-110469, 11-80081, and Japanese Patent Application No. 2001-64627 can be used. Furthermore, as rod-shaped liquid crystal compounds, those described in Japanese Patent Publication No. 11-513019 and Japanese Patent Application Publication No. 2007-279688 can also be preferably used.

[0133] —Disc-shaped liquid crystal compounds— As disc-shaped liquid crystal compounds, those described in Japanese Patent Publication No. 2007-108732 and Japanese Patent Publication No. 2010-244038 can be preferably used. Furthermore, when a disc-shaped liquid crystal compound is used in the optically anisotropic layer, the liquid crystal compound 40 rises in the thickness direction within the optically anisotropic layer, and the optical axis 40A derived from the liquid crystal compound is defined as an axis perpendicular to the disc surface, the so-called phase-advancing axis.

[0134] As for the liquid crystal compound, a liquid crystal compound with high refractive index anisotropy Δn can be preferably used to obtain high diffraction efficiency. By increasing the refractive index anisotropy, it is possible to maintain high diffraction efficiency when the incident angle changes. There are no particular limitations on the liquid crystal compound with high refractive index anisotropy Δn, but compounds exemplified in WO2019 / 182129 A1 and compounds represented by the following general formula (I) can be preferably used. [ka] In general formula (I), P 1 and P 2 Each of these independently represents a hydrogen atom, -CN, -NCS, or a polymerizable group. Sp 1 and Sp 2 Each of these independently represents a single bond or a divalent linking group. However, Sp 1 and Sp 2 This does not represent a divalent linking group containing at least one group selected from the group consisting of aromatic hydrocarbon ring groups, aromatic heterocyclic groups, and aliphatic hydrocarbon ring groups. Z 1 , Z 2 and Z 3These are, independently, single bonds, -O-, -S-, -CHR-, -CHRCHR-, -OCHR-, -CHRO-, -SO-, -SO2-, -COO-, -OCO-, -CO-S-, -S-CO-, -O-CO-O-, -CO-NR-, -NR-CO-, -SCHR-, -CHRS-, -SO-CHR-, -CHR-SO-, -SO2-CHR-, -CHR-SO2-, -CF2O-, -OCF2-, -CF2S-, -SCF2-, -OCHRCHRO-, -SCHRCHRS-, -SO-CHR This represents CHR-SO-, -SO2-CHRCHR-SO2-, -CH=CH-COO-, -CH=CH-OCO-, -COO-CH=CH-, -OCO-CH=CH-, -COO-CHRCHR-, -OCO-CHRCHR-, -CHRCHR-COO-, -CHRCHR-OCO-, -COO-CHR-, -OCO-CHR-, -CHR-COO-, -CHR-OCO-, -CR=CR-, -CR=N-, -N=CR-, -N=N-, -CR=NN=CR-, -CF=CF-, or C≡C-. R represents a hydrogen atom or an alkyl group with 1 to 10 carbon atoms. If there are multiple Rs, they may be the same or different. 1 and Z 2 If there are multiple instances of each, they may be the same or different. 3 They may be the same or different. However, Sp 2 Z connected to 3 This represents a single bond. X 1 and X 2 Each of these independently represents a single bond or an S- bond. Multiple X 1 and X 2 These may be the same or different. However, there may be multiple X 1 and multiple X 2 At least one of these represents -S-. k represents an integer between 2 and 4. m and n each independently represent integers between 0 and 3. Multiple instances of m may be the same or different. A 1 , A 2 , A 3 and A4 Each of these independently represents a group represented by any of the following general formulas (B-1) to (B-7), or a group formed by linking two to three groups represented by any of the following general formulas (B-1) to (B-7). 2 and A 3 These may be the same or different. 1 and A 4 If there are multiple instances of each, they may be identical or different. [ka] In general formulas (B-1) to (B-7), W 1 ~W 18 Each of them is independent of CR 1 Or it represents N, R 1 represents a hydrogen atom or the substituent L listed below. Y 1 ~Y 6 Each of them is independent of NR 2 , represents O or S, R 2 represents a hydrogen atom or the substituent L listed below. G 1 ~G 4 Each of them is independent of CR 3 R 4 , NR 5 , represents O or S, R 3 ~R 5 Each of these independently represents a hydrogen atom or the substituent L described below. M 1 and M 2 Each of them is independent of CR 6 Or it represents N, R 6 represents a hydrogen atom or the substituent L listed below. * indicates the connection position. Substituents L are alkyl groups having 1 to 10 carbon atoms, alkoxy groups having 1 to 10 carbon atoms, alkylamino groups having 1 to 10 carbon atoms, alkylthio groups having 1 to 10 carbon atoms, alkanoyl groups having 1 to 10 carbon atoms, alkanoyloxy groups having 1 to 10 carbon atoms, alkanoylamino groups having 1 to 10 carbon atoms, alkanoylthio groups having 1 to 10 carbon atoms, alkyloxycarbonyl groups having 2 to 10 carbon atoms, alkylaminocarbonyl groups having 2 to 10 carbon atoms, alkylthiocarbonyl groups having 2 to 10 carbon atoms, hydroxyl groups, amino groups, mercapto groups, carboxyl groups, sulfo groups, amide groups, cyano groups, nitro groups, halogen atoms, or polymerizable groups. However, if one of the above groups listed as substituent L has -CH2-, then a group obtained by replacing at least one of the -CH2- in the above group with -O-, -CO-, -CH=CH-, or C≡C- is also included as substituent L. Furthermore, if the group described as substituent L has a hydrogen atom, substituent L also includes a group obtained by replacing at least one of the hydrogen atoms in the group with at least one selected from the group consisting of a fluorine atom and a polymerizable group.

[0135] To maintain high diffraction efficiency when the incident angle changes, the refractive index anisotropy Δn of the liquid crystal compound is important. 550 Preferably 0.15 or higher, 0 . A value of 2 or higher is more preferable, 0.25 or higher is even more preferable, and 0.3 or higher is most preferable.

[0136] Furthermore, the liquid crystal diffraction element of the present invention may have its refractive index anisotropy Δn and average refractive index varied within the plane of the optical anisotropy layer. By varying the refractive index anisotropy Δn and average refractive index of the optical anisotropy layer within the plane, the diffraction efficiency can be appropriately adjusted for light at different incident positions.

[0137] —Photoreactive chiral agents— Photoreactive chiral agents, for example, consist of compounds represented by the following general formula (I), and have the characteristic of being able to control the orientation structure of liquid crystalline compounds and to change the helical pitch of liquid crystalline compounds, i.e., the torsional force (HTP: helical twisting power) of the helical structure, by irradiation with light. That is, they are compounds that induce a change in the torsional force of the helical structure in liquid crystalline compounds, preferably nematic liquid crystalline compounds, by light irradiation (ultraviolet light to visible light to infrared light), and have chiral sites (molecular structural units) and sites that undergo structural changes by light irradiation as necessary sites. Moreover, photoreactive chiral agents represented by the following general formula (I) can particularly significantly change the HTP of liquid crystalline molecules.

[0138] Furthermore, the aforementioned HTP represents the torsional force of the helical structure of the liquid crystal, i.e., HTP = 1 / (pitch × chiral agent concentration [mass fraction]). For example, the helical pitch (one period of the helical structure; μm) of the liquid crystal molecule at a certain temperature is measured, and this value is converted from the concentration of the chiral agent [μm]. -1 This can be determined by the following. When a photoreactive chiral agent forms a selective reflectance color depending on the illuminance of light, the rate of change of HTP (= HTP before irradiation / HTP after irradiation) is preferably 1.5 or more if HTP becomes smaller after irradiation, more preferably 2.5 or more, and preferably 0.7 or less if HTP becomes larger after irradiation, and more preferably 0.4 or less.

[0139] Next, we will explain compounds represented by general formula (I). General formula (I)

[0140] [ka]

[0141] In the above formula, R represents a hydrogen atom, an alkoxy group having 1 to 15 carbon atoms, an acryloyloxyalkyloxy group having a total of 3 to 15 carbon atoms, and a methacryloyloxyalkyloxy group having a total of 4 to 15 carbon atoms. Examples of the aforementioned alkoxy groups having 1 to 15 carbon atoms include methoxy, ethoxy, propoxy, butoxy, hexyloxy, and dodecyloxy groups. Among these, alkoxy groups having 1 to 12 carbon atoms are preferred, and alkoxy groups having 1 to 8 carbon atoms are particularly preferred.

[0142] Examples of the aforementioned acryloyloxyalkyloxy groups having a total of 3 to 15 carbon atoms include acryloyloxyethyloxy group, acryloyloxybutyloxy group, and acryloyloxydecyloxy group. Among these, acryloyloxyalkyloxy groups having 5 to 13 carbon atoms are preferred, and acryloyloxyalkyloxy groups having 5 to 11 carbon atoms are particularly preferred.

[0143] Examples of the aforementioned methacryloyloxyalkyloxy groups having a total of 4 to 15 carbon atoms include methacryloyloxyethyloxy group, methacryloyloxybutyloxy group, and methacryloyloxydecyloxy group. Among these, methacryloyloxyalkyloxy groups having 6 to 14 carbon atoms are preferred, and methacryloyloxyalkyloxy groups having 6 to 12 carbon atoms are particularly preferred.

[0144] The molecular weight of the photoreactive chiral agent represented by the general formula (I) described above is preferably 300 or more. Furthermore, it is preferable that it has high solubility with the liquid crystalline compound described later, and it is even more preferable that its solubility parameter SP value is similar to that of the liquid crystalline compound.

[0145] The following are specific examples of compounds represented by the general formula (I) mentioned above (exemplary compounds (1) to (15)), but the present invention is not limited to these.

[0146] [ka]

[0147] [ka]

[0148] [ka]

[0149] In the present invention, as a photoreactive chiral agent, for example, a photoreactive optically active compound represented by the following general formula (II) can also be used.

[0150] General formula (II)

[0151] [ka]

[0152] In the above formula, R represents a hydrogen atom, an alkoxy group having 1 to 15 carbon atoms, an acryloyloxyalkyloxy group having a total of 3 to 15 carbon atoms, and a methacryloyloxyalkyloxy group having a total of 4 to 15 carbon atoms. Examples of the aforementioned alkoxy groups having 1 to 15 carbon atoms include methoxy, ethoxy, propoxy, butoxy, hexyloxy, octyloxy, and dodecyloxy groups. Among these, alkoxy groups having 1 to 10 carbon atoms are preferred, and alkoxy groups having 1 to 8 carbon atoms are particularly preferred.

[0153] Examples of the aforementioned acryloyloxyalkyloxy groups having a total of 3 to 15 carbon atoms include acryloyloxy groups, acryloyloxyethyl groups, acryloyloxypropyl groups, acryloyloxyhexyl groups, acryloyloxybutyl groups, and acryloyloxydecyl groups. Among these, acryloyloxyalkyloxy groups having 3 to 13 carbon atoms are preferred, and acryloyloxyalkyloxy groups having 3 to 11 carbon atoms are particularly preferred.

[0154] Examples of the aforementioned methacryloyloxyalkyloxy groups having a total of 4 to 15 carbon atoms include methacryloyloxy groups, methacryloyloxyethyloxy groups, and methacryloyloxyhexyloxy groups. Among these, methacryloyloxyalkyloxy groups having 4 to 14 carbon atoms are preferred, and methacryloyloxyalkyloxy groups having 4 to 12 carbon atoms are particularly preferred.

[0155] The molecular weight of the photoreactive optically active compound represented by the general formula (II) described above is preferably 300 or more. Furthermore, it is preferable that it has high solubility with the liquid crystalline compound described later, and it is even more preferable that its solubility parameter SP value is similar to that of the liquid crystalline compound.

[0156] The following are specific examples of photoreactive optically active compounds represented by the general formula (II) mentioned above (exemplary compounds (21) to (32)), but the present invention is not limited to these.

[0157] [ka]

[0158] [ka]

[0159] [ka]

[0160] Furthermore, photoreactive chiral agents can be used in combination with non-photoreactive chiral agents, such as chiral compounds with a large temperature dependence of torsional force. Examples of known non-photoreactive chiral agents include those described in Japanese Patent Publication No. 2000-44451, Japanese Patent Publication No. 10-509726, WO98 / 00428, Japanese Patent Publication No. 2000-506873, Japanese Patent Publication No. 9-506088, Liquid Crystals (1996, 21, 327), and Liquid Crystals (1998, 24, 219), etc.

[0161] <The function of liquid crystal diffraction elements> As described above, an optically anisotropic layer formed using a composition containing a liquid crystal compound, having a liquid crystal orientation pattern in which the direction of the optical axis 40A rotates along the direction of the array axis D, refracts circularly polarized light. The smaller the period Λ of the liquid crystal orientation pattern, the larger the angle of refraction. Therefore, as shown in the example in Figure 1, when an optical anisotropy layer is formed in which the direction of the optical axis derived from the liquid crystal compound changes while continuously rotating in one direction (arrangement axis D direction), in a concentric circle extending from the inside to the outside, and the period Λ decreases by one from the center to the outside, as shown in Figure 14, light L6 incident near the center of the plane of the optical anisotropy layer 36a is transmitted through the optical anisotropy layer 36a as light L7 with almost no diffraction. Also, light L8 incident in the region between the center and the outer right side in the figure is diffracted toward the center and transmitted through the optical anisotropy layer 36a as light L9. 10 The light is diffracted towards the center at a larger angle, resulting in light L 11 The light passes through the optical anisotropy layer 36a. Also, light L incident on the region between the center and the outer left side in the figure 12 It is diffracted toward the center and becomes light L 13 The light L incident on the outer region on the left side of the figure is transmitted through the optical anisotropy layer 36a. 14 The light is diffracted towards the center at a larger angle, resulting in light L 15 It then transmits through the optically anisotropic layer 36a. Therefore, as shown in Figure 14, the optically anisotropic layer 36a functions as a focusing lens that concentrates the transmitted light.

[0162] In the liquid crystal diffraction element of the present invention, the twist angle in the thickness direction of the liquid crystal compound in the optical anisotropy layer can be appropriately set according to the period Λ of the in-plane liquid crystal orientation pattern.

[0163] Furthermore, in the example shown in Figure 1, the optical anisotropy layer has a configuration having a concentric liquid crystal alignment pattern in which the orientation of the optical axis derived from the liquid crystal compound changes while continuously rotating in one direction, extending from the inside to the outside in a concentric pattern. However, the invention is not limited to this configuration. For example, the optically anisotropic layer may have an array axis D in one direction, with a period Λ gradually changing along this one direction, and the average tilt angle of the dark areas gradually changing along this one direction. Furthermore, the liquid crystal alignment pattern may not be a symmetrical concentric circle pattern from the inside outwards, but rather an asymmetric liquid crystal alignment pattern. In that case, the center of the liquid crystal alignment pattern may be different from the center of the liquid crystal diffraction element. The liquid crystal alignment pattern is not limited to the above configuration and may be set appropriately according to the function required of the liquid crystal diffraction element.

[0164] The liquid crystal diffraction element of the present invention can be used in various applications that transmit light in a direction different from the incident direction, such as optical path changing members, light focusing elements, light diffusion elements in a predetermined direction, and diffraction elements in optical devices.

[0165] The liquid crystal diffraction element of the present invention may transmit and refract visible light, or it may be configured to refract and transmit infrared and / or ultraviolet light.

[0166] The optical element of the present invention comprises the liquid crystal diffraction element and the circular polarizer described above. Some circularly polarized light incident on a liquid crystal diffraction element may pass through the element without being diffracted (zero-order light). This undiffracted circularly polarized light may degrade performance depending on the application. In contrast, combining a liquid crystal diffraction element with a circular polarizer can reduce the amount of light (zero-order light) that passes through the liquid crystal diffraction element without being diffracted. As an example, let's explain a liquid crystal diffraction element and a circular polarizer (with a phase difference plate and a linear polarizer (polarizer) arranged in this order). When right-circularly polarized light is incident on a liquid crystal diffraction element, the incident right-circularly polarized light is diffracted and emitted from the liquid crystal diffraction element. Also, during diffraction, the right-circularly polarized light is converted to left-circularly polarized light. The left-circularly polarized light diffracted by the liquid crystal diffraction element (i.e., primary light) is converted to linearly polarized light by the phase difference plate (quarter-wave plate) of the circular polarizer. The linearly polarized light converted by the phase difference plate is transmitted through the linear polarizer and emitted.

[0167] In this case, if some of the light is not diffracted by the liquid crystal diffraction element, some of the right-circularly polarized light incident on the liquid crystal diffraction element will pass through the element without being diffracted. In the absence of a circular polarizer, the right-circularly polarized light that is not diffracted by the liquid crystal diffraction element will continue to travel in a straight line. Depending on the application, this straight-traveling right-circularly polarized light can be unwanted and degrade performance.

[0168] In contrast, as described above, the optical element can also preferably be used in a form that includes a circular polarizer. When a circular polarizer is included, right-circularly polarized light (i.e., 0th-order light) that is not diffracted by the liquid crystal diffraction element is incident on the phase difference plate of the circular polarizer, converted into linearly polarized light in a direction orthogonal to the above, and then incident on the linear polarizer and absorbed. In other words, right-circularly polarized light that is not diffracted by the liquid crystal diffraction element is absorbed by the circular polarizer. Therefore, the desired 1st-order light in the form of left-circularly polarized light can be transmitted, and the right-circularly polarized light that is not diffracted can be reduced. As a result, it is possible to suppress the degradation of performance due to unwanted light (0th-order light).

[0169] <Polarizing plate> The linear polarizer used in this invention is not particularly limited as long as it is a linear polarizer that transmits linearly polarized light in one polarization direction and absorbs linearly polarized light in the other polarization direction, and conventionally known linear polarizers can be used. The linear polarizer may be an absorbing type linear polarizer or a reflective type linear polarizer.

[0170] Absorbing linear polarizers include iodine-based polarizers, dye-based polarizers utilizing dichroic dyes, and polyene-based polarizers. Iodine-based and dye-based polarizers include coated polarizers and stretched polarizers, both of which are applicable. Among these, polarizers made by adsorbing iodine or a dichroic dye onto polyvinyl alcohol and then stretching it are preferred. Furthermore, as a method for obtaining a polarizer by stretching and dyeing a laminated film in which a polyvinyl alcohol layer is formed on a substrate, examples include those described in Japanese Patent Publication No. 5048120, Japanese Patent Publication No. 5143918, Japanese Patent Publication No. 4691205, Japanese Patent Publication No. 4751481, and Japanese Patent Publication No. 4751486, and these known technologies related to polarizers can also be preferably utilized. As an absorption polarizer, a polarizer in which dichroic dyes are oriented using the orientation properties of liquid crystals without stretching is particularly preferred. The above polarizer has many advantages, such as being able to be made into a very thin layer with a thickness of about 0.1 μm to 5 μm, being resistant to cracking when bent as described in Japanese Patent Publication No. 2019-194685, having small thermal deformation, having excellent durability even in polarizers with high transmittance exceeding 50% as described in Japanese Patent Publication No. 6483486, and having excellent heat moldability. These advantages enable applications requiring high brightness and small size / lightweight design, micro-optical systems, molding for curved surfaces, and flexible parts. Furthermore, it is possible to peel off the support and transfer the polarizer for use. It is also preferable to incorporate absorbing polarizers for the purpose of suppressing stray light in automotive display optics such as head-up displays, optics such as AR glasses and VR glasses, and optical sensors such as LiDAR, facial recognition systems, and polarization imaging.

[0171] As reflective linear polarizers, films made by stretching layers containing two types of polymers, as described in Japanese Patent Application Publication No. 2011-053705, and wire grid polarizers can be used. From the viewpoint of brightness, films made by stretching layers containing polymers are preferred. Commercially available products such as reflective polarizers (product name APF) manufactured by 3M and wire grid polarizers (product name WGF) manufactured by Asahi Kasei Corporation can be suitably used. Alternatively, a reflective linear polarizer combining a cholesteric liquid crystal film and a λ / 4 plate may be used.

[0172] The polarizing plate used in the present invention preferably has a smooth surface. In particular, when applying the polarizing plate to a lens or the like, since even slight surface irregularities may cause image distortion due to the effect of image magnification of the lens, it is desirable that the surface has no irregularities. Specifically, the average arithmetic roughness Ra of the surface is preferably 50 nm or less, more preferably 30 nm or less, still more preferably 10 nm or less, and most preferably 5 nm or less. Also, on the surface of the polarizing plate, the height difference of the surface irregularities within a range of 1 square millimeter is preferably 100 nm or less, more preferably 50 nm or less, and most preferably 20 nm or less. The surface irregularities and the average arithmetic roughness can be measured using a roughness meter, an interferometer, or the like. For example, they can be measured using an interferometer "vertscan" manufactured by Hishikawa System Co., Ltd.

[0173] <Retardation plate> The retardation plate used in the present invention is a retardation plate that converts the phase of the incident polarized light. The retardation plate is arranged by adjusting the direction of the slow axis according to whether it converts the incident polarized light to be close to linearly polarized light or to be close to circularly polarized light. Specifically, the retardation plate may be arranged such that the slow axis is +45° or -45° with respect to the absorption axis of the linearly polarized plate arranged adjacent thereto.

[0174] The retardation plate used in the present invention may be a single-layer type composed of one layer of an optically anisotropic layer, or a multi-layer type composed of a laminate of two or more optically anisotropic layers each having a plurality of different slow axes. Examples of the multi-layer type retardation plate include, but are not limited to, WO13 / 137464, WO2016 / 158300, JP-A-2014-209219, JP-A-2014-209220, WO14 / 157079, JP-A-2019-215416, and WO2019 / 160044.

[0175] From the viewpoint of converting linearly polarized light to circularly polarized light or converting circularly polarized light to linearly polarized light, the retardation plate is preferably a λ / 4 plate.

[0176] There are no restrictions on the λ / 4 plate; various known plates with λ / 4 functionality can be used. Specific examples of λ / 4 plates include those described in U.S. Patent Application Publication 2015 / 0277006.

[0177] For example, embodiments of a λ / 4 plate having a single-layer structure include stretched polymer films and phase difference films having an optically anisotropic layer with λ / 4 functionality on a support. Furthermore, embodiments of a λ / 4 plate having a multi-layer structure include broadband λ / 4 plates formed by laminating a λ / 4 plate and a λ / 2 wave plate.

[0178] There are no particular restrictions on the thickness of the λ / 4 plate, but 1 to 500 μm is preferred, 1 to 50 μm is more preferred, and 1 to 5 μm is even more preferred.

[0179] The phase difference plate used in the present invention preferably has inverse wavelength dispersion. Having inverse wavelength dispersion makes the phase change in the phase difference plate ideal, and thus the conversion between linearly polarized and circularly polarized light becomes ideal.

[0180] In the embodiment of the present invention that combines a liquid crystal diffraction element and a circular polarizer, other optical elements may be used in combination downstream of the circular polarizer. As an example, a phase difference plate may be placed downstream of the circular polarizer. A configuration in which linearly polarized light transmitted through a circular polarizer (with a phase difference plate and a linear polarizer in this order) is converted into circularly polarized, elliptically polarized, and linearly polarized light with different polarization directions by a phase difference plate placed downstream of the circular polarizer is also a preferred use. Alternatively, instead of a phase difference plate, a depolarization layer that eliminates the polarization state of light in at least some wavelength ranges may be used. As the depolarization layer, a high phase difference film (in-plane phase difference of 3000 nm or more) and a light scattering layer can be used. By controlling the polarization state of the light emitted from the circular polarizer in this way, the polarization state can be adjusted according to the application. As another example, an optical element that deflects light may be placed downstream of the circular polarizer. For instance, by placing an optical element that deflects light, such as a lens, downstream of the circular polarizer, the direction of light emitted from the circular polarizer can be changed. By controlling the deflection direction of the light emitted from the circular polarizer in this way, the direction of light emission can be adjusted according to the application.

[0181] <Adhesive layer (tack layer), adhesive> The optical film may include an adhesive layer for bonding each layer. In this specification, "adhesion" is used to include the concept of "tackiness." Examples include water-soluble adhesives, UV-curing adhesives, emulsion adhesives, latex adhesives, mastic adhesives, multilayer adhesives, paste-type adhesives, foam-type adhesives, supported film adhesives, thermoplastic adhesives, hot-melt adhesives, heat-solidifying adhesives, heat-activated adhesives, heat-seal adhesives, thermosetting adhesives, contact-type adhesives, pressure-sensitive adhesives (i.e., adhesives), polymerization adhesives, solvent-type adhesives, solvent-activated adhesives, ceramic adhesives, and the like. Specifically, examples include aqueous solutions of boron compounds, curable epoxy compound adhesives that do not contain aromatic rings in their molecules, as shown in Japanese Patent Publication No. 2004-245925, active energy ray curable adhesives that contain a photopolymerization initiator having a molar extinction coefficient of 400 or more at wavelengths of 360-450 nm as described in Japanese Patent Publication No. 2008-174667, and an ultraviolet curable compound as essential components, and active energy ray curable adhesives that contain, in a total amount of 100 parts by mass of (meth)acrylic compounds as described in Japanese Patent Publication No. 2008-174667, (a) an (meth)acrylic compound having two or more (meth)acryloyl groups in its molecule, (b) an (meth)acrylic compound having a hydroxyl group in its molecule and only one polymerizable double bond, and (c) a phenol ethylene oxide modified acrylate or a nonylphenol ethylene oxide modified acrylate. Depending on the requirements, the various adhesives can be used individually or in combination.

[0182] In laminated optical films, from the viewpoint of reducing unwanted reflections, it is preferable that the refractive index difference between the adhesive layer and adjacent layers is small. Specifically, the refractive index difference between adjacent layers is preferably 0.05 or less, and more preferably 0.01 or less. There are no particular restrictions on the method of adjusting the refractive index of the adhesive layer, but known methods such as adding fine particles of zirconia, silica, acrylic, acrylic-styrene, or melamine, adjusting the refractive index of the resin, and the method described in Japanese Patent Application Publication No. 11-223712 can be used. Furthermore, if adjacent layers have refractive index anisotropy within the plane, it is preferable that the refractive index difference between adjacent layers is 0.05 or less in all directions within the plane. Therefore, the adhesive layer may also have refractive index anisotropy within the plane. When there is a large difference in refractive index between the interfaces to be bonded, the interfacial reflectance can be reduced by creating a distribution of refractive index in the thickness direction of the adhesive layer. Methods for creating a distribution of refractive index in the thickness direction include providing multiple adhesive layers, mixing the interfaces between multiple adhesive layers, and controlling the uneven distribution of materials within the adhesive layer to impart a refractive index distribution.

[0183] Furthermore, the adhesive layer can be applied to one or both of the members to be bonded by any method such as coating, vapor deposition, or transfer. From the viewpoint of increasing adhesive strength, post-treatments such as heat treatment and ultraviolet irradiation can be applied according to the type of adhesive. The thickness of the adhesive layer can be adjusted arbitrarily, but 20 μm or less is preferred, and 0.1 μm or less is even more preferred. One method for forming an adhesive layer of 0.1 μm or less is to vapor-deposit a ceramic adhesive such as silicon dioxide (SiOx layer) onto the bonding surface. The bonding surface of the bonded members can be subjected to surface modification treatments such as plasma treatment, corona treatment, or saponification treatment before bonding, and a primer layer can be applied. Also, if there are multiple bonding surfaces, the type and thickness of the adhesive layer can be adjusted for each bonding surface.

[0184] <Cutting of laminated materials> The fabricated laminate can be cut to a predetermined size. There are no limitations on the method of cutting the laminate; various known methods can be used, such as physically cutting with a cutting tool like a Thomson blade or cutting by irradiating with a laser. When using a laser, it is preferable to select the pulse width (nanosecond, picosecond, femtosecond) and wavelength considering the cutting performance and damage to the material. Furthermore, after processing the laminate into a predetermined shape, for example, the edges may be polished. To improve processability during cutting and suppress dust generation, cutting can be performed with a removable protective film attached. Furthermore, by observing the liquid crystal alignment pattern while cutting, as shown in, for example, Japanese Patent Application Publication No. 2004-141889, the cutting position can be arbitrarily determined. In this case, the liquid crystal alignment pattern can be observed through a polarizing plate or phase difference film to make it more visible. Additionally, if multiple optical elements are provided on a single substrate, it is preferable to cut the multiple optical elements simultaneously.

[0185] <Other processing> To ensure accurate placement of the laminate on the device and to improve the accuracy of the cutting axis and cutting position, markings of any shape can be added as needed. The type of marking can be arbitrarily selected, and methods such as physically applying the markings using laser or inkjet methods, partially changing the orientation of the liquid crystal, or adding partially decolorized or dyed areas can be selected. Furthermore, protective layers (such as gas barrier layers, moisture-blocking layers, ultraviolet absorption layers, and scratch-resistant layers) can be provided as needed to protect the liquid crystal layer. The protective layer can be formed directly on the liquid crystal layer, or it can be provided via an adhesive layer or another optical film. Anti-reflective layers (such as LR layers, AR layers, and moth-eye layers) can be provided to reduce the reflectivity of the surface. Various protective layers can be appropriately selected from known ones. When a gas barrier layer is provided, polyvinyl alcohol is preferred. Polyvinyl alcohol can also function as a polarizer. The ultraviolet absorption layer is a layer containing an ultraviolet absorber, and from the viewpoint of good display performance, an ultraviolet absorber that has excellent absorption ability for ultraviolet light with a wavelength of 370 nm or less and absorbs little visible light with a wavelength of 400 nm or more is preferably used. Only one type of ultraviolet absorber may be used, or two or more types may be used in combination. For example, ultraviolet absorbers described in Japanese Patent Publication No. 2001-72782 and Japanese Patent Publication No. 2002-543265 can be cited. Specific examples of ultraviolet absorbers include oxybenzophenone compounds, benzotriazole compounds, salicylate ester compounds, benzophenone compounds, cyanoacrylate compounds, and nickel complex salt compounds.

[0186] <Combination of multiple liquid crystal diffraction elements> The liquid crystal diffraction element of the present invention can be used in combination with multiple liquid crystal diffraction elements. For example, as disclosed in Optics Express, Vol.28, No.16 / 3 August 2020, by combining multiple liquid crystal diffraction elements and changing the polarization state of the light incident on the liquid crystal diffraction elements, it is possible to switch between multiple focusing / diverging properties of the emitted light. By combining multiple liquid crystal diffraction elements in this way, it is possible to perform foveated displays in HMDs such as AR glasses and VR glasses.

[0187] <Combination with phase modulation elements> The liquid crystal diffraction element of the present invention can also preferably be used in a configuration combined with a phase modulation element. For example, by combining a switchable λ / 2 plate that can modulate the phase difference with a voltage as disclosed in US10,379,419B1 and the liquid crystal diffraction element of the present invention (used as a passive element), a focus-variable lens having high diffraction efficiency can be realized regardless of the light incident position within the element plane. Further, by combining a plurality of sets of the combination of the phase modulation element and the liquid crystal diffraction element, a plurality of adjustable focal lengths can be increased. By using such a focus-variable lens in AR glasses and VR glasses, the focal position of the display image of the HMD can be arbitrarily changed.

[0188] <Combination with a lens> The liquid crystal diffraction element of the present invention can also preferably be used in a configuration combined with other lens elements. For example, by using the liquid crystal diffraction element of the present invention in the combination of a Fresnel lens and a liquid crystal diffraction element as disclosed in SID 2020 DIGEST, 40-4, pp579-582., the chromatic aberration of the lens can be improved with high diffraction efficiency regardless of the light incident position within the element plane. There is no limitation on the lens to be combined, and combinations with refractive index lenses, US3,443,858, and pancake lenses as disclosed in Optics Express, Vol.29, No4 / 15 February 2021, etc. can also be preferably used. By using an optical system combining such a lens and a liquid crystal diffraction element in AR glasses, VR glasses, etc., the color deviation (chromatic aberration of the lens) of the display image of the HMD can be improved.

[0189] <Combination with a light guide plate> The liquid crystal diffraction element of the present invention can also preferably be used in a configuration combined with a light guide plate. For example, in a combination of a light guide plate and a lens as disclosed in Proc. of SPIE Vol.11062, Digital Optical Technologies 2019, 110620J (16 July 2019), by using the liquid crystal diffraction element of the present invention as the lens, the focal position of the display image emitted from the light guide plate can be changed. By combining it with a light guide plate in this way, the focal position of the display image on HMDs such as AR glasses and VR glasses can be adjusted. Furthermore, when used with AR glasses, as disclosed in Proc. of SPIE Vol.11062, Digital Optical Technologies 2019, 110620J (16 July 2019), by using the liquid crystal diffraction element of the present invention as lenses with different positive and negative polarities on either side of the light guide plate, both the actual scene and the display image output from the light guide plate can be observed without distortion.

[0190] <Combination with image display device> The liquid crystal diffraction element of the present invention can also be preferably used in combination with an image display device. For example, by combining an image display device, such as the one disclosed in Crystals 2021, 11, 107, with a liquid crystal diffractometer (used as a Diffractive Deflection Film), the brightness distribution of the light emitted from the image display device can be adjusted. By combining an image display device with an image display unit in this way, the brightness distribution of HMDs such as AR glasses and VR glasses can be suitably adjusted.

[0191] <Combination with beam steering> The liquid crystal diffraction element of the present invention can also be preferably used in combination with an optical deflection element (beam steering). For example, by using the liquid crystal diffraction element of the present invention as the diffraction element of an optical deflection element, such as those disclosed in WO2019 / 189675, it is possible to increase the deflection angle of the emitted light with high diffraction efficiency. By combining it with an optical deflection element (beam steering) in this way, the illumination angle of light from distance measuring sensors such as LiDAR (Light Detection and Ranging) can be optimally widened.

[0192] Although the liquid crystal diffraction element, optical element, image display unit, head-mounted display, beam steering, and sensor of the present invention have been described in detail above, the present invention is not limited to the examples described above, and various improvements and modifications may be made without departing from the spirit of the present invention. [Examples]

[0193] The features of the present invention will be further described in detail below with reference to examples. The materials, reagents, amounts used, amounts of substance, ratios, processing content, and processing procedures shown in the following examples can be modified as appropriate without departing from the spirit of the present invention. Therefore, the scope of the present invention should not be interpreted as being limited by the specific examples shown below.

[0194] [Comparative Example 1] <Fabrication of liquid crystal diffraction elements> (Support) A glass substrate was prepared as the support.

[0195] (Formation of orientation film) The following orientation film-forming coating solution was applied to the support by spin coating. The support coated with this orientation film-forming coating solution was dried on a 60°C hot plate for 60 seconds to form an orientation film.

[0196] Coating solution for forming alignment films -------------------------------------------------- Photoalignment material A 1.00 parts by mass Water 16.00 parts by mass Butoxyethanol 42.00 parts by mass Propylene glycol monomethyl ether 42.00 parts by mass --------------------------------------------------

[0197] -Photo alignment material A- [ka]

[0198] (Exposure of alignment layer) An alignment film P-1 having a concentric alignment pattern was formed by exposing the alignment film using the exposure apparatus shown in Figure 11. In the exposure apparatus, a laser with a wavelength of 325 nm was used as the laser source. The exposure dose due to interference was 1000 mJ / cm². 2 This was done. Furthermore, by using the exposure apparatus shown in Figure 11, the period of one cycle of the orientation pattern was made to gradually shorten from the center outwards.

[0199] (Formation of optically anisotropic layer) Composition A-1 was prepared as a liquid crystal composition for forming the first optically anisotropic layer. Composition A-1 -------------------------------------------------- Liquid crystal compound L-1 100.00 parts by mass Chiral agent C-1: 0.32 parts by mass Polymerization initiator (BASF, Irgacure OXE01) 1.00 parts by mass Leveling agent T-1: 0.08 parts by mass Methyl ethyl ketone 1050.00 parts by mass --------------------------------------------------

[0200] Liquid crystal compound L-1

[0201] [ka]

[0202] Chiral agent C-1

[0203] [ka]

[0204] Leveling agent T-1

[0205] [ka]

[0206] The optically anisotropic layer was formed by multilayer coating of composition A-1 on the alignment film P-1. Multilayer coating refers to the process of first coating the first layer of composition A-1 onto the alignment film, heating and UV curing to create a liquid crystal immobilization layer, and then repeatedly coating subsequent layers on top of this liquid crystal immobilization layer, heating and UV curing in the same manner. By forming the layer by multilayer coating, the orientation direction of the alignment film is reflected from the bottom surface to the top surface of the optically anisotropic layer even when the total thickness of the optically anisotropic layer is increased.

[0207] First, for the first layer, composition A-1 is applied to the orientation film P-1, the coating is heated to 80°C on a hot plate, and then, under a nitrogen atmosphere, ultraviolet light with a wavelength of 365 nm is applied at 300 mJ / cm² using a high-pressure mercury lamp. 2 By irradiating the coating film with this irradiation dose, the orientation of the liquid crystal compound was fixed.

[0208] For the second and subsequent layers, the liquid crystal immobilization layer was layered on top of this layer, heated under the same conditions as above, and then cured with ultraviolet light to create the liquid crystal immobilization layer. In this way, the layering was repeated until the desired total thickness was achieved, forming an optically anisotropic layer and creating a liquid crystal diffraction element.

[0209] The complex refractive index Δn of the cured layer of liquid crystal composition A-1 was determined by coating liquid crystal composition A-1 onto a support with an alignment film prepared separately for retardation measurement, aligning the liquid crystal compound director horizontally to the substrate, and then fixing it by ultraviolet irradiation. The retardation value and film thickness of the resulting liquid crystal immobilized layer (cured layer) were then measured. Δn can be calculated by dividing the retardation value by the film thickness. The retardation value was measured at the desired wavelength using an Axoscan from Axometrix, and the film thickness was measured using a scanning electron microscope (SEM).

[0210] The optical anisotropy layer ultimately results in Δn of the liquid crystal. 550 The thickness (Re(550)) was 275 nm, and it was confirmed using a polarizing microscope that the surface had a concentric (radial) periodic orientation as shown in Figure 2. In this optically anisotropic layer's liquid crystal orientation pattern, one period in which the optical axis of the liquid crystal compound rotates 180° was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside. Furthermore, the twist angle in the thickness direction of the optically anisotropic layer was 70° (-70°) counterclockwise throughout the entire plane. Unless otherwise specified, Δn 550 Measurements such as '××d' were performed in the same manner.

[0211] Composition A-2 was prepared as a liquid crystal composition to form the second optical anisotropy layer. Composition A-2 -------------------------------------------------- Liquid crystal compound L-1 100.00 parts by mass Chiral agent C-2 0.18 parts by mass Polymerization initiator (BASF, Irgacure OXE01) 1.00 parts by mass Leveling agent T-1: 0.08 parts by mass Methyl ethyl ketone 1050.00 parts by mass --------------------------------------------------

[0212] Chiral agent C-2

[0213] [ka]

[0214] A second optical anisotropic layer was formed in the same manner as the first optical anisotropic layer, except that composition A-2 was used and the thickness of the optical anisotropic layer was adjusted.

[0215] The optical anisotropy layer ultimately results in Δn of the liquid crystal. 550 The thickness (Re(550)) was confirmed to be 275 nm, and the surface exhibited a concentric (radial) periodic orientation as shown in Figure 2, as confirmed by polarizing microscope. Furthermore, the liquid crystal orientation pattern of this optically anisotropic layer was such that the period shortened towards the outward direction. The twist angle in the thickness direction of the optically anisotropic layer was 70° clockwise in the plane.

[0216] [Example 1]

[0217] (Formation of optically anisotropic layer) Compositions B-1, B-2, and B-3 were prepared as liquid crystal compositions for forming an optically anisotropic layer. Composition B-1

[0218] -------------------------------------------------- Liquid crystal compound L-1 100.00 parts by mass Chiral agent C-3 0.23 parts by mass Chiral agent C-4 0.82 parts by mass Polymerization initiator (BASF, Irgacure OXE01) 1.00 parts by mass Leveling agent T-1: 0.08 parts by mass Methyl ethyl ketone 1050.00 parts by mass --------------------------------------------------

[0219] Chiral agent C-3

[0220] [ka]

[0221] Chiral agent C-4

[0222] [ka]

[0223] As a liquid crystal composition for forming the second optical anisotropy layer, composition B-2 was prepared by changing the chiral agent C-3 to 0.54 parts by mass and the chiral agent C-4 to 0.62 parts by mass in composition B-1 of Example 1.

[0224] As a liquid crystal composition for forming the third optical anisotropy layer, composition B-3 was prepared by changing composition B-1 of Example 1 to 0.48 parts by mass of chiral agent C-3 and omitting chiral agent C-4.

[0225] First, the first region was formed by multilayer coating of composition B-1 onto the alignment film P-1. Multilayer coating refers to the process of first coating the first layer of composition B-1 onto the alignment film, heating, cooling, and then UV curing to create a liquid crystal immobilization layer, and then applying subsequent layers on top of that liquid crystal immobilization layer, repeating the process of heating, cooling, and UV curing. By forming the region through multilayer coating, the orientation direction of the alignment film is reflected from the bottom to the top surface of the optical anisotropy layer even when the total thickness of the optical anisotropy layer is increased.

[0226] First, for the first layer, composition B-1 was applied to the alignment film P-1, the coating was heated to 80°C on a hot plate, and then the coating was irradiated with 365nm ultraviolet light from an LED-UV exposure machine. At this time, the amount of ultraviolet light irradiated onto the coating was varied within the plane. Specifically, the amount of light irradiated onto the coating was varied within the plane so that the amount of light increased from the center to the edges. After that, the coating, which had been heated to 80°C on the hot plate, was exposed to 365nm ultraviolet light at a rate of 300mJ / cm² using a high-pressure mercury lamp in a nitrogen atmosphere. 2 By irradiating the coating film with this irradiation dose, the orientation of the liquid crystal compound was fixed.

[0227] For the second and subsequent layers, the liquid crystal immobilization layer was layered on top of this layer, and the liquid crystal immobilization layer was fabricated under the same conditions as above. In this way, the layering was repeated until the desired total thickness was achieved, forming the first region of the optical anisotropy layer. The first region is ultimately the Δn of the liquid crystal. 550 The thickness (Re(550)) was 160 nm, and it was confirmed using a polarizing microscope that the surface had a concentric (radial) periodic orientation as shown in Figure 2. In this optically anisotropic layer's liquid crystal orientation pattern, one period in which the optical axis of the liquid crystal compound rotates by 180° was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside. Furthermore, the twist angle in the thickness direction of the optically anisotropic layer was 80° (-80°) counterclockwise at a distance of approximately 2 mm from the center, and 115° (-115°) counterclockwise at a distance of 25 mm from the center, indicating that the twist angle increased towards the outside. As described above, an optically anisotropic layer in which the twist angle changes within the plane was formed.

[0228] Next, a second region was formed by applying composition B-2 in multiple layers onto the first region. Composition B-2 was applied to the first region, and an optically anisotropic layer was formed in the same manner as in the preparation of the first region of Example 1, except that the amount of ultraviolet light irradiated onto the coating film was changed from the center to the edges (the amount of irradiation was increased from the center to the edges) so that the total thickness was changed to the desired film thickness.

[0229] For the second and subsequent layers, the liquid crystal immobilization layer was layered on top of this layer, and the liquid crystal immobilization layer was fabricated under the same conditions as above. In this way, the layering was repeated until the desired total thickness was achieved, forming the second region of the optical anisotropy layer. This second region ultimately represents the Δn of the liquid crystal. 550 The thickness (Re(550)) was 335 nm, and it was confirmed using a polarizing microscope that the surface had a concentric (radial) periodic orientation as shown in Figure 2. In this optically anisotropic layer's liquid crystal orientation pattern, one period corresponding to a 180° rotation of the optical axis of the liquid crystal compound was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside. Furthermore, the twist angle in the thickness direction of the optically anisotropic layer was 0° at a distance of approximately 2 mm from the center, and 76° (-76°) counterclockwise at a distance of 25 mm from the center, indicating that the twist angle increased towards the outside. As described above, an optically anisotropic layer in which the twist angle changes within the plane was formed.

[0230] Next, a third region was formed by applying composition B-3 in multiple layers onto the second region. Composition B-3 was applied to the second region, and an optically anisotropic layer was formed in the same manner as in the preparation of the first region of Example 1, except that the amount of ultraviolet light irradiated onto the coating film was changed from the center to the edges (the amount of irradiation was increased from the center to the edges) so that the total thickness was changed to the desired film thickness.

[0231] For the second and subsequent layers, the liquid crystal immobilization layer was layered on top of this layer, and the liquid crystal immobilization layer was fabricated under the same conditions as above. In this way, the layering was repeated until the desired total thickness was achieved, forming the third region of the optical anisotropy layer. This third region ultimately represents the Δn of the liquid crystal. 550 The thickness (Re(550)) was 160 nm, and it was confirmed using a polarizing microscope that the surface had a concentric (radial) periodic orientation as shown in Figure 2. In this optically anisotropic layer's liquid crystal orientation pattern, one period in which the optical axis of the liquid crystal compound rotates 180° was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside. Furthermore, the twist angle in the thickness direction of the optically anisotropic layer was 80° clockwise at a distance of approximately 2 mm from the center (twist angle 80°), and 48° clockwise at a distance of 25 mm from the center (twist angle 48°), indicating that the twist angle decreases towards the outside. As described above, an optically anisotropic layer having three regions was formed.

[0232] When the cross-section of the fabricated optically anisotropic layer was observed using a scanning electron microscope (SEM), the bright and dark areas had the shapes shown in Figure 1. Specifically, the dark areas had two inflection points, and the average tilt angle was approximately 0° at the center and increased towards the outside.

[0233] [Example 2]

[0234] (Formation of optically anisotropic layer) As liquid crystal compositions for forming an optically anisotropic layer, compositions C-1, C-2, C-3, and C-4 were prepared by appropriately changing the amounts of chiral agents C-3 and C-4 added to composition B-1 of Example 1.

[0235] First, the first region was formed by multilayer coating of composition C-1 onto the orientation film P-1. Composition C-1 was applied to the alignment film P-1, and the first region of the optical anisotropy layer was formed in the same manner as in the first optical anisotropy layer fabrication of Example 1, except that the amount of ultraviolet light irradiated onto the coating film from the center to the edges was changed so that the total thickness was the desired film thickness. This region ultimately represents the Δn of the liquid crystal. 550 The thickness (Re(550)) was 190 nm, and it was confirmed using a polarizing microscope that the surface had a concentric (radial) periodic orientation as shown in Figure 2. In this optically anisotropic layer's liquid crystal orientation pattern, the period for a 180° rotation of the optical axis of the liquid crystal compound was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside. Furthermore, the twist angle in the thickness direction of the first region of the optically anisotropic layer was 87° (-87°) counterclockwise at a distance of approximately 2 mm from the center, and 115° (-115°) counterclockwise at a distance of 25 mm from the center, indicating that the twist angle increased towards the outside.

[0236] Next, a second region was formed by applying composition C-2 in multiple layers onto the first region. Composition C-2 was applied to the first region, and the second region was formed in the same manner as in the first region of Example 1, except that the amount of ultraviolet light irradiated onto the coating film from the center to the edges was changed so that the total thickness was the desired film thickness. This region ultimately represents the Δn of the liquid crystal. 550The thickness (Re(550)) was 150 nm, and it was confirmed using a polarizing microscope that the surface had a concentric (radial) periodic orientation as shown in Figure 2. In this optically anisotropic layer's liquid crystal orientation pattern, one period in which the optical axis of the liquid crystal compound rotates by 180° was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside. Furthermore, the twist angle in the thickness direction of the second region of the optically anisotropic layer was 14° (14°) clockwise at a distance of approximately 2 mm from the center, and 18° (-18°) counterclockwise at a distance of 25 mm from the center, indicating that the twist angle changed towards the outside.

[0237] Next, a third region was formed by applying composition C-3 in multiple layers onto the second region. Composition C-3 was applied to the second region, and the third region was formed in the same manner as in the preparation of the first region of Example 1, except that the amount of ultraviolet light irradiated onto the coating film from the center to the edges was changed so that the total thickness was the desired film thickness. This region ultimately represents the Δn of the liquid crystal. 550 The thickness (Re(550)) was confirmed to be 150 nm, and the surface had a concentric (radial) periodic orientation as shown in Figure 2, as confirmed by polarizing microscope. In this optically anisotropic layer's liquid crystal orientation pattern, one period in which the optical axis of the liquid crystal compound rotates 180° was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period decreases towards the outside. Furthermore, the twist angle in the thickness direction of the third region of the optically anisotropic layer was 14° (-14°) counterclockwise at a distance of approximately 2 mm from the center and 8° (-8°) counterclockwise at a distance of 25 mm from the center, indicating that the twist angle decreases towards the outside.

[0238] Next, a fourth region was formed by applying composition C-4 in multiple layers onto the third region. Composition C-4 was applied to the third region, and the fourth region was formed in the same manner as in the first region of Example 1, except that the amount of ultraviolet light irradiated onto the coating film from the center to the edges was changed so that the total thickness was the desired film thickness. This region ultimately represents the Δn of the liquid crystal. 550 The thickness (Re(550)) was 190 nm, and it was confirmed using a polarizing microscope that the surface had a concentric (radial) periodic orientation as shown in Figure 2. In this optically anisotropic layer's liquid crystal orientation pattern, the period for a 180° rotation of the optical axis of the liquid crystal compound was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside. Furthermore, the twist angle in the thickness direction of the fourth region of the optically anisotropic layer was 87° clockwise at a distance of approximately 2 mm from the center and 237° clockwise at a distance of 25 mm from the center, indicating that the twist angle increased towards the outside. As described above, an optically anisotropic layer having four regions was formed.

[0239] When the cross-section of the fabricated optically anisotropic layer was observed using a scanning electron microscope (SEM), the bright and dark areas had the shapes shown in Figure 5. Specifically, the dark areas had three inflection points, and the average tilt angle was approximately 0° at the center and increased towards the outside.

[0240] [Example 3]

[0241] (Formation of optically anisotropic layer) As liquid crystal compositions for forming an optically anisotropic layer, compositions D-1, D-2, and D-3 were prepared by appropriately changing the amounts of chiral agents C-3 and C-4 added to composition B-1 of Example 1.

[0242] First, the first region was formed by applying the composition D-1 onto the alignment film P-1 in multiple layers. Next, the second region was formed by applying the composition D-2 onto the first region in multiple layers. Then, the third region was formed by applying the composition D-3 onto the second region in multiple layers.

[0243] In the formation of each region, except that in the preparation of the first region of Example 1, the irradiation amount of ultraviolet light irradiated onto the coating film was changed from the center toward the end and the total thickness was changed to the desired film thickness, an optically anisotropic layer was formed in the same manner.

[0244] It was confirmed by a polarizing microscope that the produced optically anisotropic layer had a concentric (radial) periodic alignment surface as shown in FIG. 2. In the liquid crystal alignment pattern of this optically anisotropic layer, one period in which the optical axis of the liquid crystal compound rotates 180° was 10 μm for one period at a distance of about 2 mm from the center, 1 μm for one period at a distance of 25 mm from the center, and 0.6 μm for one period at a distance of 30 mm from the center, and it was a liquid crystal alignment pattern in which the period became shorter toward the outer direction.

[0245] The first region of the optically anisotropic layer finally had Δn of the liquid crystal 550 × thickness (Re(550)) of 150 nm, and the twist angle in the thickness direction was -83° (left-handed) at a distance of about 2 mm from the center, -114° (left-handed) at a distance of 25 mm from the center, and -161° (left-handed) at a distance of 30 mm from the center, and the twist angle became larger toward the outer direction. The second region of the optically anisotropic layer finally had Δn of the liquid crystal 550 × thickness (Re(550)) of 335 nm, and the twist angle in the thickness direction was -8° (left-handed) at a distance of about 2 mm from the center, -85° (left-handed) at a distance of ************** The third region of the optically anisotropic layer finally had Δn of the liquid crystal 550 It seems there is some incomplete information in the original text for item . The translation is done based on the available content. If you can provide the complete original text, I can ensure a more accurate translation.The thickness (Re(550)) was 170 nm, and the twist angle in the thickness direction was 78° clockwise at a distance of approximately 2 mm from the center, 41° clockwise at a distance of 25 mm from the center, and 19° clockwise at a distance of 30 mm from the center, with the twist angle decreasing towards the outside. As described above, an optically anisotropic layer having three regions was formed.

[0246] When the cross-section of the fabricated optically anisotropic layer was observed using a scanning electron microscope (SEM), the bright and dark areas had the shapes shown in Figure 1. Specifically, the dark areas had two inflection points, and the average tilt angle increased from the center outward.

[0247] [Example 4] (Formation of optically anisotropic layer) As liquid crystal compositions for forming an optically anisotropic layer, compositions E-1, E-2, and E-3 were prepared by changing liquid crystal compound L-1 to 10 parts by mass and liquid crystal compound L-2 to 90 parts by mass in composition B-1 of Example 1, and appropriately changing the amounts of chiral agent C-3, chiral agent C-4, and leveling agent T-1.

[0248] Liquid crystal compound L-2

[0249] [ka]

[0250] First, the first region was formed by multilayer coating of composition E-1 onto the orientation film P-1. Next, the second region was formed by multilayer coating of composition E-2 onto the first region. Then, the third region was formed by multilayer coating of composition E-3 onto the second region.

[0251] In forming each region, the optical anisotropy layer was formed in the same manner as in the first region of Example 1, except that the amount of ultraviolet light irradiated onto the coating film from the center to the edge was changed so that the total thickness was the desired film thickness.

[0252] The fabricated optically anisotropic layer was confirmed to have a concentric (radial) periodic orientation surface as shown in Figure 2 using a polarizing microscope. In this optically anisotropic layer's liquid crystal orientation pattern, one period corresponding to a 180° rotation of the optical axis of the liquid crystal compound was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside.

[0253] The first region of the optical anisotropy layer ultimately corresponds to the Δn of the liquid crystal. 550 When the thickness (Re(550)) was 150 nm, the twist angle in the thickness direction was 83° (-83°) counterclockwise at a distance of approximately 2 mm from the center, 114° (-114°) counterclockwise at a distance of 25 mm from the center, and 161° (-161°) counterclockwise at a distance of 30 mm from the center, showing that the twist angle increased towards the outward direction. The second region of the optical anisotropy layer ultimately corresponds to the Δn of the liquid crystal. 550 The thickness (Re(550)) was 335 nm, and the twist angle in the thickness direction was 8° (-8°) counterclockwise at a distance of approximately 2 mm from the center, 85° (-85°) counterclockwise at a distance of 25 mm from the center, and 137° (-137°) counterclockwise at a distance of 30 mm from the center, showing that the twist angle increased towards the outward direction. The third region of the optical anisotropy layer is ultimately the Δn of the liquid crystal. 550 The thickness (Re(550)) was 170 nm, and the twist angle in the thickness direction was 78° clockwise at a distance of approximately 2 mm from the center, 41° clockwise at a distance of 25 mm from the center, and 19° clockwise at a distance of 30 mm from the center, with the twist angle decreasing towards the outside. As described above, an optically anisotropic layer having three regions was formed.

[0254] When the cross-section of the fabricated optically anisotropic layer was observed using a scanning electron microscope (SEM), the bright and dark areas had the shapes shown in Figure 1. Specifically, the dark areas had two inflection points, and the average tilt angle increased from the center outward.

[0255] [Example 5] (Formation of optically anisotropic layer) Compositions F-1, F-2, and F-3 were prepared as liquid crystal compositions for forming an optically anisotropic layer. Composition F-1

[0256] -------------------------------------------------- Liquid crystal compound L-1 10.00 parts by mass Liquid crystal compound L-2 90.00 parts by mass Chiral agent C-1 0.78 parts by mass Polymerization initiator (BASF, Irgacure OXE01) 1.00 parts by mass Leveling agent T-1: 0.22 parts by mass Methyl ethyl ketone 1050.00 parts by mass --------------------------------------------------

[0257] As a liquid crystal composition for forming the second optical anisotropy layer, composition F-2 was prepared by changing the chiral agent C-1 in composition F-1 of Example 5 to 0.01 parts by mass.

[0258] As a liquid crystal composition for forming the third optical anisotropy layer, composition F-3 was prepared by changing the chiral agent in composition F-1 of Example 5 to the chiral agent C-5 described below, and adding 0.55 parts by mass.

[0259] Chiral agent C-5

[0260] [ka]

[0261] First, the first region was formed by applying the composition F-1 onto the alignment film P-1 in multiple layers. Next, the second region was formed by applying the composition F-2 onto the first region in multiple layers. Next, the third region was formed by applying the composition F-3 onto the second region in multiple layers.

[0262] In the formation of each region, in the production of the first region in Example 1, the optical anisotropic layer was formed in the same manner except that the irradiation amount of the ultraviolet rays irradiated onto the coating film was changed from the center toward the end and the total thickness was changed to the desired film thickness.

[0263] It was confirmed by a polarizing microscope that the produced optical anisotropic layer had a concentric (radial) periodic alignment surface as shown in FIG. 2. In the liquid crystal alignment pattern of this optical anisotropic layer, one period in which the optical axis of the liquid crystal compound rotates 180° was 10 μm for one period at a distance of about 2 mm from the center, 1 μm for one period at a distance of 25 mm from the center, and 0.6 μm for one period at a distance of 30 mm from the center, and it was a liquid crystal alignment pattern in which the period became shorter toward the outer direction.

[0264] In the first region of the optical anisotropic layer, finally, the Δn of the liquid crystal 550 × thickness (Re(550)) became 197 nm, and the twist angle in the thickness direction was -91° (left-handed) at a distance of about 2 mm from the center and -82° (left-handed) at a distance of 25 mm from the center, and the twist angle changed toward the outer direction. In the second region of the optical anisotropic layer, finally, the Δn of the liquid crystal 550 × thickness (Re(550)) became 347 nm, and the twist angle in the thickness direction was -19° (left-handed) at a distance of about 2 mm from the center and -13° (left-handed) at a distance of 25 mm from the center, and the twist angle changed toward the outer direction. In the third region of the optical anisotropic layer, finally, the Δn of the liquid crystal 550The thickness (Re(550)) was 195 nm, and the twist angle in the thickness direction was 69° clockwise at a distance of approximately 2 mm from the center, and 77° clockwise at a distance of 25 mm from the center, indicating that the twist angle changed towards the outward direction. As described above, an optically anisotropic layer having three regions was formed.

[0265] When the cross-section of the fabricated optically anisotropic layer was observed using a scanning electron microscope (SEM), the dark areas had two inflection points, and the average tilt angle changed from the center outward.

[0266] [Example 6] (Formation of optically anisotropic layer) Compositions G-1, G-2, and G-3 were prepared as liquid crystal compositions for forming an optically anisotropic layer.

[0267] As a liquid crystal composition for forming the first optical anisotropy layer, composition G-1 was prepared by appropriately changing the amount of chiral agent C-5 added to composition F-3 of Example 5.

[0268] As a liquid crystal composition for forming the second optical anisotropy layer, composition G-2 was prepared by appropriately changing the amount of chiral agent C-5 added to composition F-3 of Example 5.

[0269] As a liquid crystal composition for forming the third optical anisotropy layer, composition G-3 was prepared by appropriately changing the amount of chiral agent C-1 added to composition F-1 of Example 5.

[0270] First, the first region was formed by multilayer coating of composition G-1 onto the orientation film P-1. Next, the second region was formed by multilayer coating of composition G-2 onto the first region. Then, the third region was formed by multilayer coating of composition G-3 onto the second region.

[0271] In forming each region, the optical anisotropy layer was formed in the same manner as in the first region of Example 1, except that the amount of ultraviolet light irradiated onto the coating film from the center to the edge was changed so that the total thickness was the desired film thickness.

[0272] The fabricated optically anisotropic layer was confirmed to have a concentric (radial) periodic orientation surface as shown in Figure 2 using a polarizing microscope. In this optically anisotropic layer's liquid crystal orientation pattern, one period corresponding to a 180° rotation of the optical axis of the liquid crystal compound was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside.

[0273] The first region of the optical anisotropy layer ultimately corresponds to the Δn of the liquid crystal. 550 The thickness (Re(550)) was 157 nm, and the twist angle in the thickness direction was 88° clockwise at a distance of approximately 2 mm from the center, and 96° clockwise at a distance of 25 mm from the center, indicating that the twist angle changed towards the outward direction. The second region of the optical anisotropy layer ultimately corresponds to the Δn of the liquid crystal. 550 The thickness (Re(550)) was 355 nm, and the twist angle in the thickness direction was 16° clockwise at a distance of approximately 2 mm from the center, and 40° clockwise at a distance of 25 mm from the center, showing that the twist angle changed towards the outward direction. The third region of the optical anisotropy layer is ultimately the Δn of the liquid crystal. 550 The thickness (Re(550)) was 187 nm, and the twist angle in the thickness direction was 76° (-76°) counterclockwise at a distance of approximately 2 mm from the center, and 62° (-62°) counterclockwise at a distance of 25 mm from the center, indicating that the twist angle changed towards the outward direction. As described above, an optically anisotropic layer having three regions was formed.

[0274] When the cross-section of the fabricated optically anisotropic layer was observed using a scanning electron microscope (SEM), the dark areas had two inflection points, and the average tilt angle changed from the center outward.

[0275] [Example 7] (Formation of optically anisotropic layer) Compositions H-1, H-2, and H-3 were prepared as liquid crystal compositions for forming an optically anisotropic layer.

[0276] As a liquid crystal composition for forming the first optical anisotropy layer, composition H-1 was prepared by changing the chiral agent in composition F-1 of Example 5 to chiral agent C-1 and chiral agent C-2, and appropriately changing the amounts of chiral agent C-1 and chiral agent C-2 added.

[0277] As a liquid crystal composition for forming the second optical anisotropy layer, composition H-2 was prepared by changing the chiral agent in composition F-2 of Example 5 to chiral agent C-1 and chiral agent C-2, and appropriately changing the amounts of chiral agents C-1 and C-2 added.

[0278] As a liquid crystal composition for forming the third optical anisotropy layer, composition H-3 was prepared by appropriately changing the amount of chiral agent C-5 added to composition F-3 of Example 5.

[0279] First, the first region was formed by multilayer coating of composition H-1 onto the orientation film P-1. Next, the second region was formed by multilayer coating of composition H-2 onto the first region. Then, the third region was formed by multilayer coating of composition H-3 onto the second region.

[0280] In forming each region, the optical anisotropy layer was formed in the same manner as in the first region of Example 1, except that the amount of ultraviolet light irradiated onto the coating film from the center to the edge was changed so that the total thickness was the desired film thickness.

[0281] The fabricated optically anisotropic layer was confirmed to have a concentric (radial) periodic orientation surface as shown in Figure 2 using a polarizing microscope. In this optically anisotropic layer's liquid crystal orientation pattern, one period corresponding to a 180° rotation of the optical axis of the liquid crystal compound was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside.

[0282] The first region of the optical anisotropy layer ultimately corresponds to the Δn of the liquid crystal. 550 The thickness (Re(550)) was 176 nm, and the twist angle in the thickness direction was 76° (-76°) counterclockwise at a distance of approximately 2 mm from the center, and 14° (-14°) counterclockwise at a distance of 25 mm from the center, indicating that the twist angle changed towards the outward direction. The second region of the optical anisotropy layer ultimately corresponds to the Δn of the liquid crystal. 550 The thickness (Re(550)) was 344 nm, and the twist angle in the thickness direction was 10° clockwise at a distance of approximately 2 mm from the center, and 126° clockwise at a distance of 25 mm from the center, indicating that the twist angle changed towards the outward direction. The third region of the optical anisotropy layer is ultimately the Δn of the liquid crystal. 550 The thickness (Re(550)) was 154 nm, and the twist angle in the thickness direction was 84° clockwise at a distance of approximately 2 mm from the center, and 133° clockwise at a distance of 25 mm from the center, indicating that the twist angle changed towards the outward direction. As described above, an optically anisotropic layer having three regions was formed.

[0283] When the cross-section of the fabricated optically anisotropic layer was observed using a scanning electron microscope (SEM), the dark areas had two inflection points, and the average tilt angle changed from the center outward.

[0284] [Example 8] As liquid crystal compositions for forming an optically anisotropic layer, compositions I-1, I-2, and I-3 were prepared by changing liquid crystal compound L-3 to 100 parts by mass in composition B-1 of Example 1, and appropriately changing the amounts of chiral agent C-3, chiral agent C-4, and leveling agent T-1.

[0285] Liquid crystal compound L-3

[0286] [ka]

[0287] First, the first region was formed by multilayer coating of composition I-1 onto the orientation film P-1. Next, the second region was formed by multilayer coating of composition I-2 onto the first region. Then, the third region was formed by multilayer coating of composition I-3 onto the second region.

[0288] In forming each region, the optical anisotropy layer was formed in the same manner as in the first region of Example 1, except that the amount of ultraviolet light irradiated onto the coating film from the center to the edge was changed, the heating temperature of the coating film when forming the optical anisotropy layer was changed to 55°C, and the total thickness was adjusted to the desired film thickness.

[0289] The fabricated optically anisotropic layer was confirmed to have a concentric (radial) periodic orientation surface as shown in Figure 2 using a polarizing microscope. In this optically anisotropic layer's liquid crystal orientation pattern, one period corresponding to a 180° rotation of the optical axis of the liquid crystal compound was 10 μm at a distance of approximately 2 mm from the center, 1 μm at a distance of 25 mm from the center, and 0.6 μm at a distance of 30 mm from the center, indicating a liquid crystal orientation pattern where the period shortens towards the outside.

[0290] The first region of the optical anisotropy layer ultimately corresponds to the Δn of the liquid crystal. 550When the thickness (Re(550)) was 150 nm, the twist angle in the thickness direction was 83° (-83°) counterclockwise at a distance of approximately 2 mm from the center, 114° (-114°) counterclockwise at a distance of 25 mm from the center, and 161° (-161°) counterclockwise at a distance of 30 mm from the center, showing that the twist angle increased towards the outward direction. The second region of the optical anisotropy layer ultimately corresponds to the Δn of the liquid crystal. 550 The thickness (Re(550)) was 335 nm, and the twist angle in the thickness direction was 8° (-8°) counterclockwise at a distance of approximately 2 mm from the center, 85° (-85°) counterclockwise at a distance of 25 mm from the center, and 137° (-137°) counterclockwise at a distance of 30 mm from the center, showing that the twist angle increased towards the outward direction. The third region of the optical anisotropy layer is ultimately the Δn of the liquid crystal. 550 The thickness (Re(550)) was 170 nm, and the twist angle in the thickness direction was 78° clockwise at a distance of approximately 2 mm from the center, 41° clockwise at a distance of 25 mm from the center, and 19° clockwise at a distance of 30 mm from the center, with the twist angle decreasing towards the outside. As described above, an optically anisotropic layer having three regions was formed.

[0291] When the cross-section of the fabricated optically anisotropic layer was observed using a scanning electron microscope (SEM), the bright and dark areas had the shapes shown in Figure 1. Specifically, the dark areas had two inflection points, and the average tilt angle increased from the center outward.

[0292] Note that the Δn of the liquid crystal layer (liquid crystal compound) in Example 3 550 0.15, Δn of the liquid crystal layer in Example 4 550 0.25, Δn of the liquid crystal layer in Example 8 550 The value was 0.32.

[0293] [evaluation] <Evaluation of diffraction efficiency> The diffraction efficiency of the emitted light was evaluated when light was incident on the fabricated liquid crystal diffraction element from the front (direction at an angle of 0° with respect to the normal). Specifically, laser light with output center wavelengths of 405 nm, 450 nm, 532 nm, and 650 nm was irradiated from a light source and perpendicularly incident onto the fabricated liquid crystal diffraction element. The light intensity of the diffracted light (first-order light) diffracted in the desired direction from the liquid crystal diffraction element, the zero-order light (emitted in the same direction as the incident light) and the -1-order light (light diffracted in the -θ direction when the diffraction angle of the first-order light relative to the zero-order light is θ) emitted in other directions was measured with a photodetector, and the diffraction efficiency at each wavelength was calculated using the following formula. Diffraction efficiency = 1st order light / (1st order light + 0th order light + (-1st order light))

[0294] The average diffraction efficiency was calculated from measurements taken at wavelengths of 405 nm, 450 nm, 532 nm, and 650 nm, and the wavelength dependence of the diffraction efficiency was evaluated according to the following criteria. Furthermore, the laser light was perpendicularly incident onto a circular polarizer corresponding to its wavelength to convert it to circular polarization, and then the light was incident on the fabricated liquid crystal diffraction element for evaluation. Furthermore, evaluations were performed at two locations in the fabricated liquid crystal diffraction element: the center of the concentric circles of the liquid crystal alignment pattern, near the center of the concentric circles (1 period = 10 μm), and near the edges (1 period = 1 μm). A: Average diffraction efficiency is 95% or higher B: Average diffraction efficiency is 90% or higher, but less than 95%. C: Average diffraction efficiency is less than 90% The results are shown in Tables 1 and 2. In Tables 1 and 2, the diffraction angle for light at 532 nm is denoted as diffraction angle (532).

[0295] [Table 1]

[0296] In Examples 5-7, the evaluation was performed with the incident polarization being the opposite of circular polarization compared to Examples 1-4. In this case, the diffraction directions of the primary and -1st primary light in Examples 5-7 were reversed compared to Examples 1-4 (diffracted in a direction where the sign of the light diffracting in the θ direction was reversed). In Example 7, the evaluation was performed near the edge (1 period = 1 μm) with the incident light angle on the liquid crystal diffraction element set to 25°. Comparative examples of Examples 5-7 were evaluated using the liquid crystal diffraction element fabricated in Comparative Example 1. The results were the same as those for Comparative Example 1, as shown in Table 1.

[0297] [Table 2]

[0298] [evaluation] <Evaluation of diffraction efficiency> The diffraction efficiency of the emitted light was evaluated when light was incident on the liquid crystal diffraction elements fabricated in Comparative Example 1, Example 3, Example 4, and Example 8 from the front (direction at an angle of 0° relative to the normal) at an incident angle of ±40° (in 10° increments). Specifically, laser light with output center wavelengths of 405 nm, 450 nm, 532 nm, and 650 nm was irradiated from a light source and incident on the fabricated liquid crystal diffraction element. Of the emitted light, the diffracted light (first-order light) diffracted in the desired direction from the liquid crystal diffraction element, the zero-order light (emitted in the same direction as the incident light) and the -1-order light (light diffracted in the -θ direction when the diffraction angle of the first-order light relative to the zero-order light is θ) were measured with a photodetector, and the diffraction efficiency at each wavelength was calculated using the following formula. Diffraction efficiency = 1st order light / (1st order light + 0th order light + (-1st order light))

[0299] The average diffraction efficiency was calculated from measurements taken at different incident angles at wavelengths of 405 nm, 450 nm, 532 nm, and 650 nm, and the wavelength dependence of the diffraction efficiency was evaluated. Furthermore, the laser light was perpendicularly incident onto a circular polarizer corresponding to its wavelength to convert it to circular polarization, and then the light was incident on the fabricated liquid crystal diffraction element for evaluation. Furthermore, evaluations were performed at three locations in the fabricated liquid crystal diffraction element: the center of the concentric circles of the liquid crystal alignment pattern, near the center of the concentric circles (1 period = 10 μm), near the edge (1 period = 1 μm), and at the edge (0.6 μm).

[0300] The evaluation results showed that, compared to Comparative Example 1, the liquid crystal diffraction elements of Examples 3, 4, and 8 all achieved high diffraction efficiencies (average values).

[0301] Furthermore, the evaluation results showed that the average diffraction efficiency of Example 4 was improved compared to Example 3, and the average diffraction efficiency of Example 8 was even better.

[0302] From the above, the refractive index difference Δn of the liquid crystal layer of the liquid crystal diffraction element 550 It can be seen that a higher value improves the efficiency of light utilization for different angles of incidence.

[0303] <Fabrication of circular polarizing plates> (Fabrication of phase difference plate) A film having a cellulose acylate film, an alignment film, and an optically anisotropic layer C was obtained by a method similar to that of the positive A plate described in paragraphs 0102 to 0126 of Japanese Patent Publication No. 2019-215416. The optically anisotropic layer C is a positive A plate (phase difference plate), and the thickness of the positive A plate is controlled so that Re(550) is 138 nm.

[0304] A circular polarizer was fabricated by bonding the phase difference plate prepared above to a linear polarizer via an adhesive. The phase difference plate was positioned so that the relative angle between its slow axis and the absorption axis of the linear polarizer was 45°.

[0305] <Fabrication of optical elements> Optical elements were fabricated by bonding the circular polarizing plates prepared above to the liquid crystal diffraction elements prepared in Examples 1 to 8. The optical elements were formed by arranging the liquid crystal diffraction elements, phase difference plates, and linear polarizing plates in that order.

[0306] [evaluation] The light intensity of the emitted light was evaluated when light was incident on the fabricated optical element from the front (at an angle of 0° with respect to the normal). Specifically, laser light with output center wavelengths of 405 nm, 450 nm, 532 nm, and 650 nm was irradiated from a light source and perpendicularly incident onto the fabricated optical element. Of the emitted light, the light intensity of the diffracted light (first-order light) diffracted in the desired direction from the liquid crystal diffracting element and the zero-order light (emitted in the same direction as the incident light) emitted in other directions were measured with a photodetector. In addition, the laser light was perpendicularly incident onto a circular polarizer corresponding to the wavelength of the laser light to convert it to circular polarization, and then the light was incident from the liquid crystal diffracting element side of the fabricated optical element for evaluation.

[0307] In the optical elements fabricated in Examples 1 to 7 by laminating a circular polarizer to a liquid crystal diffraction element, it was confirmed that the light intensity of the 0th order light could be significantly reduced at all wavelengths compared to before lamination of the circular polarizer, and that the contrast ratio (ratio of light intensity of 1st order light to 0th order light) was improved. In Examples 5 to 7, evaluations were performed by appropriately changing the incident circularly polarized light and the arrangement of the phase difference plate and linear polarizer of the circular polarizer. In Example 7, the evaluation was performed with the incident light angle to the liquid crystal diffraction element set to 25° near the edge (where one period is 1 μm).

[0308] [evaluation] <Evaluation of dependence on incidence angle> The light intensity of the emitted light was evaluated when light was incident on the optical elements using the liquid crystal diffraction elements fabricated in Comparative Example 1, Example 3, Example 4, and Example 8, with the incident angle varied by ±40° (in 10° increments) from the front (direction at an angle of 0° with respect to the normal). Specifically, laser light with output center wavelengths of 405 nm, 450 nm, 532 nm, and 650 nm was irradiated from a light source and incident on the fabricated liquid crystal diffraction element. The light intensity of the diffracted light (first-order light) diffracted in a desired direction from the liquid crystal diffraction element and the zero-order light (emitted in the same direction as the incident light) emitted in other directions were measured with a photodetector.

[0309] The average value of light intensity as a function of the incident angle was calculated from measurements taken at different incident angles at wavelengths of 405 nm, 450 nm, 532 nm, and 650 nm. Furthermore, evaluations were performed at three locations in the fabricated liquid crystal diffraction element: the center of the concentric circles of the liquid crystal alignment pattern, near the center of the concentric circles (period 10 μm), near the edge (period 1 μm), and at the edge (period 1.6 μm). Furthermore, the laser light was perpendicularly incident onto a circular polarizer corresponding to its wavelength to convert it to circular polarization, and then the light was incident from the liquid crystal diffracting element side of the fabricated optical element for evaluation.

[0310] In the optical elements fabricated in Examples 3 to 4 and Example 8, in which a circular polarizer was bonded to the liquid crystal diffraction element, the light intensity of the 0th order light could be significantly reduced at all wavelengths compared to before the bonding of the circular polarizer, and it was confirmed that the contrast ratio (ratio of light intensity of 1st order light to 0th order light) was improved. Furthermore, compared to the optical element using the liquid crystal diffraction element fabricated in Comparative Example 1, the optical elements using the liquid crystal diffraction elements fabricated in Examples 3, 4, and 8 all showed high contrast ratios.

[0311] Furthermore, the evaluation results showed that the average value of the contrast ratio with respect to the incident angle was improved for the optical element using the liquid crystal diffraction element fabricated in Example 4 compared to the optical element using the liquid crystal diffraction element fabricated in Example 3, and the average value of the contrast ratio with respect to the incident angle for the optical element using the liquid crystal diffraction element fabricated in Example 8 was even more improved.

[0312] From the above, even in an optical element in which a circular polarizing plate is bonded to a liquid crystal diffraction element, the refractive index difference Δn of the liquid crystal layer is also 550 It can be seen that a higher value improves the contrast ratio for different angles of incidence.

[0313] <Fabrication of circular polarizing plates> In the aforementioned process of fabricating circular polarizers, a circular polarizer was fabricated in the same manner as described below, except that the linear polarizer (polyvinyl alcohol layer type) was replaced with an absorption polarizer fabricated as described later.

[0314] <Fabrication of optical elements> Optical elements were fabricated by bonding a circular polarizer, made using the absorption polarizer prepared as described below, to the liquid crystal diffraction elements prepared in Examples 1 to 8. The optical elements were formed by arranging the liquid crystal diffraction elements, phase difference plates, and linear polarizers in that order.

[0315] [Fabrication of occlusive polarizers] <Fabrication of transparent support 1> The orientation layer forming coating solution PA1, described later, was continuously applied to a cellulose acylate film (TAC substrate with a thickness of 40 μm; TG40, Fujifilm Corporation) using a wire bar. The support with the coated film was dried with 140°C hot air for 120 seconds, and then polarized ultraviolet irradiation (10 mJ / cm²) was applied to the coating film. 2 By using an ultra-high pressure mercury lamp, a photo-alignment layer PA1 was formed, and a TAC film with a photo-alignment layer was obtained. The film thickness was 0.3 μm.

[0316] ------------------------------------------------------------------ (PA1 coating solution for forming an orientation layer) ------------------------------------------------------------------ 100.00 parts by mass of the polymer PA-1 described below The following acid generator PAG-1: 5.00 parts by mass The following acid generator CPI-110TF: 0.005 parts by mass Xylene 1220.00 parts by mass Methyl isobutyl ketone 122.00 parts by mass ------------------------------------------------------------------

[0317] Polymer PA-1

[0318] [ka]

[0319] Acid Generator PAG-1

[0320] [ka]

[0321] Acid Generator CPI-110TF

[0322] [ka]

[0323] <Formation of light-absorbing anisotropic layer P1> The following light-absorbing anisotropic layer-forming composition P1 was continuously applied to the obtained orientation layer PA1 using a wire bar to form a coated layer P1. Next, the coated layer P1 was heated at 140°C for 30 seconds, and then cooled to room temperature (23°C). Next, it was heated at 90°C for 60 seconds and then cooled again to room temperature. Subsequently, an illuminance of 200 mW / cm was measured using an LED lamp (center wavelength 365 nm). 2 By irradiating for 2 seconds under the specified irradiation conditions, a light-absorbing anisotropic layer P1 was fabricated on the orientation layer PA1. The film thickness was 1.6 μm. This was designated as laminate 1B.

[0324] ------------------------------------------------------------------ Composition of composition P1 for forming a light-absorbing anisotropic layer ------------------------------------------------------------------ • 0.25 parts by mass of the following dichroic substance D-1 • The following dichroic substance D-2: 0.36 parts by mass • The following dichroic substance D-3: 0.59 parts by mass • 2.21 parts by mass of the following polymeric liquid crystalline compound P-1 • 1.36 parts by mass of the following low-molecular-weight liquid crystalline compound M-1 • Polymerization initiator IRGACUREOXE-02 (manufactured by BASF) 0.200 parts by mass • Surfactant F-1: 0.026 parts by mass Cyclopentanone 46.00 parts by mass • Tetrahydrofuran 46.00 parts by mass Benzyl alcohol 3.00 parts by mass ------------------------------------------------------------------

[0325] D-1

[0326] [ka]

[0327] D-2

[0328] [ka]

[0329] D-3

[0330] [ka]

[0331] Polymer liquid crystal compound P-1

[0332] [ka]

[0333] Low molecular liquid crystal compound M-1

[0334] [ka]

[0335] Surfactant F-1

[0336] [ka]

[0337] <Production of UV Adhesive> The following UV adhesive composition was prepared. ───────────────────────────────── UV Adhesive Composition ――――――――――――――――――――――――――――――――― ·CEL2021P (manufactured by Daicel Corporation) 70 parts by mass ·1,4-butanediol diglycidyl ether 20 parts by mass ·2-ethylhexyl glycidyl ether 10 parts by mass ·CPI-100P 2.25 parts by mass ─────────────────────────────────

[0338] CPI-100P

[0339]

Chemical formula

[0340] <Production of Absorption-Type Polarizing Film> Using the above UV adhesive, Technolo S001G (methacrylic resin with a thickness of 50 μm, tanδ peak temperature of 128 °C, manufactured and sold by Sumika Acryl Co., Ltd.) was bonded to the surface of the light absorption anisotropic layer of laminate 1B as the resin substrate S1. Then, only the cellulose acetate film 1 was peeled off to produce an absorption-type polarizing film in which the resin substrate / adhesive layer / light absorption anisotropic layer / orientation layer were arranged in this order. The thickness of the UV adhesive layer was 2 μm.

[0341] The average arithmetic roughness Ra of the obtained absorption-type polarizing film was 10 nm or less. On the other hand, the average arithmetic roughness Ra of the linear polarizing plate (polyvinyl alcohol layer type) was 20 nm or more. As a result, the produced absorption-type polarizing film can reduce the deflection (refraction, scattering, etc.) of light due to the surface unevenness of the polarizing film. Also, when used in an image display device, the distortion of the displayed image can be suppressed. The average arithmetic roughness Ra was measured using the "vertscan" interferometer manufactured by Ryoka Systems Corporation.

[0342] [evaluation] The light intensity of the emitted light was evaluated when light was incident on the fabricated optical element from the front (at an angle of 0° with respect to the normal). Specifically, laser light with output center wavelengths of 405 nm, 450 nm, 532 nm, and 650 nm was irradiated from a light source and perpendicularly incident onto the fabricated optical element. Of the emitted light, the light intensity of the diffracted light (first-order light) diffracted in the desired direction from the liquid crystal diffracting element and the zero-order light (emitted in the same direction as the incident light) emitted in other directions were measured with a photodetector. Furthermore, the laser light was perpendicularly incident onto a circular polarizer corresponding to its wavelength to convert it to circular polarization, and then the light was incident from the liquid crystal diffracting element side of the fabricated optical element for evaluation. In the optical elements fabricated in Examples 1 to 7 by laminating a circular polarizer to a liquid crystal diffraction element, it was confirmed that the light intensity of the 0th order light could be significantly reduced at all wavelengths compared to before lamination of the circular polarizer, and that the contrast ratio (ratio of light intensity of 1st order light to 0th order light) was improved. In Examples 5 to 7, evaluations were performed by appropriately changing the incident circularly polarized light and the arrangement of the phase difference plate and linear polarizer of the circular polarizer. In Example 7, the evaluation was performed with the incident light angle to the liquid crystal diffraction element set to 25° near the edge (where one period is 1 μm).

[0343] [evaluation] <Evaluation of dependence on incidence angle> The light intensity of the emitted light was evaluated when light was incident on the optical elements using the liquid crystal diffraction elements fabricated in Comparative Example 1, Example 3, Example 4, and Example 8, with the incident angle varied by ±40° (in 10° increments) from the front (direction at an angle of 0° with respect to the normal). Specifically, laser light with output center wavelengths of 405 nm, 450 nm, 532 nm, and 650 nm was irradiated from a light source and incident on the fabricated liquid crystal diffraction element. The light intensity of the diffracted light (first-order light) diffracted in a desired direction from the liquid crystal diffraction element and the zero-order light (emitted in the same direction as the incident light) emitted in other directions were measured with a photodetector.

[0344] The average value of light intensity as a function of the incident angle was calculated from measurements taken at different incident angles at wavelengths of 405 nm, 450 nm, 532 nm, and 650 nm. Furthermore, evaluations were performed at three locations in the fabricated liquid crystal diffraction element: the center of the concentric circles of the liquid crystal alignment pattern, near the center of the concentric circles (period 10 μm), near the edge (period 1 μm), and at the edge (period 1.6 μm). Furthermore, the laser light was perpendicularly incident onto a circular polarizer corresponding to its wavelength to convert it to circular polarization, and then the light was incident from the liquid crystal diffraction element side of the fabricated optical element for evaluation.

[0345] In the optical elements fabricated in Examples 3 to 4 and Example 8, in which a circular polarizer was bonded to the liquid crystal diffraction element, the light intensity of the 0th order light could be significantly reduced at all wavelengths compared to before bonding the circular polarizer, and it was confirmed that the contrast ratio (ratio of light intensity of 1st order light to 0th order light) was improved. Furthermore, compared to the optical element using the liquid crystal diffraction element fabricated in Comparative Example 1, the optical elements using the liquid crystal diffraction elements fabricated in Examples 3, 4, and 8 all obtained high contrast ratios.

[0346] Furthermore, the evaluation results showed that the average value of the contrast ratio with respect to the incident angle was improved for the optical element using the liquid crystal diffraction element fabricated in Example 4 compared to the optical element using the liquid crystal diffraction element fabricated in Example 3, and the average value of the contrast ratio with respect to the incident angle for the optical element using the liquid crystal diffraction element fabricated in Example 8 was even more improved.

[0347] From the above, even in an optical element in which a circular polarizing plate is bonded to a liquid crystal diffraction element, the refractive index difference Δn of the liquid crystal layer is also 550 It can be seen that a higher value improves the contrast ratio for different angles of incidence.

[0348] <Change of support structure> The support for the liquid crystal diffraction element can be appropriately changed according to the purpose using the method described below. Furthermore, the method described below makes it possible to reduce the thickness between the liquid crystal diffraction element and the changed support, for example, making the thickness within the surface of the liquid crystal diffraction element uniform relative to the adhesive (thickness: several μm to tens of μm) after changing the support. In this way, even when the support for the liquid crystal diffraction element is changed, the direction of light emitted from the liquid crystal diffraction element can be precisely controlled within the surface by making the thickness within the surface uniform.

[0349] The stacking of the liquid crystal diffraction element and the new support can be carried out, for example, by following the procedure below. (1) A temporary support is bonded to the liquid crystal layer side of the support, alignment film, and liquid crystal diffraction element to be laminated. In this example, Fujimori Industries Co., Ltd.'s MASTACK AS3-304 was used as the temporary support. (2) Next, the support and alignment film that were present from the fabrication stage of the liquid crystal diffraction element are peeled off to expose the interface on the alignment film side of the liquid crystal diffraction element. (3) A silicon oxide layer (SiO) is applied to both the interface on the alignment film side of this liquid crystal diffraction element and the interface of the newly prepared support. x A silicon oxide layer is formed. There are no restrictions on the method of forming the silicon oxide layer, but vacuum deposition is a preferred example. In this example, the silicon oxide layer was formed using a deposition apparatus (model number ULEYES) manufactured by ULVAC, Inc. SiO2 powder was used as the deposition source. There are no restrictions on the thickness of the silicon oxide layer, but 50 nm or less is preferred. In this example as well, the thickness of the silicon oxide film was 50 nm or less. (4) Next, both of the formed silicon oxide films are subjected to plasma treatment, and the formed silicon oxide layers are bonded together at 120°C, after which the temporary support is peeled off.

[0350] By following steps (1) to (4) above, a diffraction element can be fabricated in which a liquid crystal diffraction element and a newly prepared support are stacked. Furthermore, by changing the support to a different liquid crystal diffraction element and repeating steps (1) to (4), a diffraction element can be fabricated in which two or more layers of liquid crystal diffraction elements are stacked.

[0351] In the steps (1) to (4) above, the support for the liquid crystal diffraction element fabricated in Example 1 was changed to a glass substrate with a thickness of 0.3 mm. For comparison, a 25 μm thick adhesive was used to change the support for the liquid crystal diffraction element fabricated in Example 1 to a glass substrate with a thickness of 0.3 mm (the liquid crystal diffraction element was bonded to the glass substrate via the adhesive). In the steps (1) to (4) above, the thickness within the surface of the liquid crystal diffraction element was made more uniform than that of the element fabricated via the adhesive.

[0352] <Fabrication of laminates> Similarly, a laminate of a liquid crystal diffraction element and other optical components can be fabricated. As an example, a laminate of a liquid crystal diffraction element, a phase difference plate, and a polarizing plate was fabricated using the following method. A silicon oxide layer (SiOx layer) was formed on the liquid crystal layer side of a liquid crystal diffraction element having a laminated support, alignment film, and liquid crystal layer, and on the bonding surface side of a phase difference plate bonded to the liquid crystal diffraction element. There are no restrictions on the method of forming the silicon oxide layer, but vacuum deposition is a preferred example. In this example, the silicon oxide layer was formed using a deposition apparatus (model number ULEYES) manufactured by ULVAC, Inc. SiO2 powder was used as the deposition source. There are no restrictions on the thickness of the silicon oxide layer, but 50 nm or less is preferred. In this example as well, the thickness of the silicon oxide film was set to 50 nm or less. Both of the formed silicon oxide films were subjected to plasma treatment, and the silicon oxide layers were bonded together at 120°C. This formed a laminate of the liquid crystal diffraction element and the phase difference plate. Similarly, a polarizing plate layer was bonded onto the phase difference plate, and the support and alignment film were peeled off to produce a laminate consisting of a liquid crystal layer (liquid crystal diffraction element) / phase difference plate / polarizing plate. Furthermore, the liquid crystal diffraction elements fabricated in Examples 1 to 7 were used as the liquid crystal diffraction elements. The phase difference plates used were those used in the fabrication of the circular polarizers described above. Laminates were fabricated using the linear polarizers (polyvinyl alcohol layer type) and absorption polarizers described above, respectively, as polarizers. In an optical element consisting of a laminate of a liquid crystal diffractometer, a phase difference plate, and a polarizer, it was confirmed that the light intensity of the zeroth-order light could be significantly reduced at all wavelengths compared to before lamination of the circular polarizer (a laminate of a phase difference plate and a polarizer), and that the contrast ratio (ratio of light intensity of the first-order light to the zeroth-order light) was improved. Based on the above results, the effects of the present invention are clear. [Explanation of symbols]

[0353] 10a, 10b Liquid crystal diffraction element 30 Support 32-Directional film 36a, 36b Optically anisotropic layers 37a~37g area 40 Liquid crystal compounds 40A optical axis 42 Akabe 44 Dark part 60,80 Exposure equipment 62,82 lasers 64,84 light source 65 λ / 2 plate 68 Beam Splitter 70A, 70B, 90A, 90B Miller 72A,72B,96 λ / 4 board 86,94 Polarizing Beam Splitter 92 lenses Λ, Λ1, Λ21 periodic D, A1~A3 array axis R region M laser light MA,MB rays MP P polarization MS S polarization P O Linear polarization P R Right-hand circular polarization P L Left-hand circular polarization α intersection angle L1, L2, L3~L 15 light

Claims

1. The device comprises an optically anisotropic layer formed using a liquid crystal composition containing a liquid crystal compound, The optically anisotropic layer has a liquid crystal orientation pattern in which the orientation of the optical axis derived from the liquid crystal compound changes while continuously rotating along at least one direction in the plane. When the length of a 180° rotation in the plane of the optical axis originating from the liquid crystal compound is defined as one period, the length of one period in the liquid crystal orientation pattern gradually changes along the one direction. The optically anisotropic layer has, in a cross-sectional image observed with a scanning electron microscope of a cross-section cut in the thickness direction along one direction, a light area and a dark area extending from one surface to the other surface. The dark area has two or more points in the thickness direction where the angle of inclination with respect to the surface changes. In the thickness direction, the dark area has regions with different gradient directions. The average inclination angle of the dark area gradually changes along the aforementioned one direction. The refractive index anisotropy Δn of the liquid crystal compound 550 A liquid crystal diffraction element whose value is 0.2 or higher. Here, the average inclination angle of the dark area is the angle that the line connecting the point of contact between the dark area and one surface of the optical anisotropy layer and the point of contact between the dark area and the other surface makes with the perpendicular to the main surface of the optical anisotropy layer.

2. The liquid crystal diffraction element according to claim 1, wherein the average tilt angle of the dark area increases as the length of one period in the liquid crystal alignment pattern decreases.

3. The liquid crystal diffraction element according to claim 1 or 2, wherein the number of inflection points in the dark area where the direction of inclination is reversed is odd.

4. The liquid crystal diffraction element according to any one of claims 1 to 3, wherein the number of inflection points in the dark area where the direction of inclination is reversed is one.

5. The liquid crystal diffraction element according to any one of claims 1 to 3, wherein the number of inflection points in the dark area where the direction of inclination is reversed is three.

6. The liquid crystal diffraction element according to any one of claims 1 to 5, wherein the liquid crystal orientation pattern of the optical anisotropic layer is a concentric pattern having the one direction in which the orientation of the optical axis derived from the liquid crystal compound changes while continuously rotating, in a concentric pattern from the inside to the outside.

7. The liquid crystal diffraction element according to claim 6, wherein the shape of the bright and dark portions of the optical anisotropic layer is symmetrical with respect to the center line in the thickness direction of the optical anisotropic layer in a cross-section of the concentric central portion, and the shape of the bright and dark portions is asymmetrical with respect to the center line in the thickness direction of the optical anisotropic layer in a cross-section of the concentric end portion.

8. The liquid crystal diffraction element according to claim 6, wherein the shape of the bright and dark portions of the optical anisotropic layer is asymmetrical with respect to the center line in the thickness direction of the optical anisotropic layer in a cross-section of the concentric central portion, and the shape of the bright and dark portions of the optical anisotropic layer is asymmetrical with respect to the center line in the thickness direction of the optical anisotropic layer in a cross-section of the concentric end portion.

9. The refractive index difference Δn due to the refractive index anisotropy of the optical anisotropy layer. 550 A liquid crystal diffraction element according to any one of claims 1 to 8, wherein the value is 0.2 or greater.

10. A liquid crystal diffraction element according to any one of claims 1 to 9, having a region in the plane where the length of one period in the liquid crystal alignment pattern is 1.0 μm or less.

11. An optical element comprising a liquid crystal diffraction element and a circular polarizer according to any one of claims 1 to 10.

12. The optical element according to claim 11, wherein the circular polarizing plate consists of a phase difference plate and a polarizer, and the liquid crystal diffraction element, the phase difference plate and the polarizer are arranged in this order.

13. The optical element according to claim 12, wherein the phase difference plate is a λ / 4 plate.

14. The optical element according to claim 12 or 13, wherein the phase difference plate has reverse wavelength dispersion properties.

15. An optical element comprising a liquid crystal diffraction element, a silicon oxide layer, and a support in that order, as described in any one of claims 1 to 10.

16. An optical element having at least one liquid crystal diffraction element according to any one of claims 1 to 10 or an optical element according to any one of claims 11 to 15, and having at least one phase modulation element.

17. An image display unit having a liquid crystal diffraction element according to any one of claims 1 to 10 or an optical element according to any one of claims 11 to 15.

18. A head-mounted display having the image display unit described in claim 17.

19. A beam steering system having a liquid crystal diffraction element according to any one of claims 1 to 10 or an optical element according to any one of claims 11 to 15.

20. A sensor having a liquid crystal diffraction element according to any one of claims 1 to 10 or an optical element according to any one of claims 11 to 15.

Images