ANTIMICROBIAL MIXTURE

Abstract

A synergistic antimicrobial mixture comprising a hydroxyacetophenone and an additional antimicrobial agent is suggested. The mixture is particularly useful against Aspergillus brasiliensis.

Description

ANTIMICROBIAL BLEND INVENTION AREA The present invention belongs to the area of ​​antimicrobial agents for personal care, detergents and nutritional products and relates to new antimicrobial agents and their use in various areas of consumer products. BACKGROUND OF THE INVENTION In the cosmetic, pharmaceutical and food industry there is a constant need for agents with antimicrobial properties, in particular for the preservation of otherwise perishable products (such as cosmetics, pharmaceuticals or foodstuffs), but also for direct cosmetics or therapeutic treatment of microorganisms that can have an adverse influence on the body of humans or animals. By way of example, reference can be made to microorganisms that can cause body odor, acne, mycoses or the like. In the aforementioned technical fields, a large number of antimicrobial active compounds are already effectively used, however, alternatives are still being sought to be able to carry out / zcznn / Lznz / E / Yii specific targeted treatments and / or reduce side effects. In this context, however, in the search for alternative agents with an antimicrobial and, in particular, preservative action, it must be taken into account that the substances used in the cosmetic, pharmaceutical and / or food field must be • toxicologically acceptable • easily tolerated by the skin • stable (particularly in conventional cosmetic 10 and / or pharmaceutical formulations) • largely and preferably completely odorless • inexpensive to prepare (ie by using standard processes and / or by from standard precursors 15) • easy to formulate (ie preferably liquid) and should not be detrimental to the final product. In addition, they must have characteristics of antimicrobial activity, which meet the various criteria. They must / zcznn / Lznz / E / Yii • provide broad-spectrum antimicrobial activity against gram-positive and gram-negative bacteria, yeasts, and molds. • show particularly strong activity against the mold A. brasiliensis • be active in different cosmetic formulations at different pH values. / zcznn / Lznz / E / YiAi RELATED PRIOR ART Various publications dealing with various types of active products against microorganisms are known from the state of the art. For example, Schenk et al. evaluated different fungicides for the preservation of wet alfalfa hay (Laboratory Evaluation of Fungicides for Preservation of Wet Hay). 4-Hydroxyacetophenone was among the compounds tested, but it was found not to prevent mold growth and therefore not suitable for hay preservation. Applications in cosmetic formulations are not disclosed (Agronomy Journal, 47, 64-69, 1955). Zauner et al. published beet molasses impurities that inhibit the respiration and fermentation of the yeast Sac4 charomyces cerevisiae (Inhibitory activity of beet molasses impurities and plant protectors on the respiration and fermentation of yeast (Saccharomyces cerevisiae)). Microorganisms other than S. cerevisiae, in particular, molds and bacteria, were not investigated. No reference is given to the potential use of inhibitory substances in the field of cosmetics (Brantweinwirtschaft, 119(9), 154-6, 158-60, 163, 1979). Hirvi et al. investigated the composition of the blueberry aroma and discovered 4-hydroxyaceto-phenone as a component. No antimicrobial activity of the blueberry flavor or any of its components is mentioned (Zeitschrift für Lebensmittel-Untersuchung und -Forschung, 172(5), 365-7, 1981). Alvares et al. studied the anti-inflammatory properties of different components of the Lampaya hieronymi plant. 4-Hydroxyacetophenone was one of the active compounds that reduce subcutaneous inflammation when administered intraperitoneally. The agents were not applied topically and no data on antimicrobial activity is disclosed for any of the compounds presented (II Fármaco, 55, 502-5, 2000). / zcznn / Lznz / E / Yii Schmeda-Hirschmann et al. identified components of Tagetes mendocina that reveal antioxidant activity in an in vitro chemical assay. Among others, 4-hydroxyacetophenone turned out to be one of the active components. No data on antimicrobial activity and no cosmetic applications are disclosed for any of the compounds presented (Zeitschrift für Naturforschung, 59c, 345-353, 2004). In this context, reference is also made to DEOS 3629056 (Celamerck) which discloses the extraction of mixtures of substances, including p-hydroxyacetophenone, from the cuticle of fir needles using apolar solvents. These mixtures of substances are claimed to be effective in counteracting phytopathogenic fungi, ie Cladosporium cucumerinum and Rhizosphaera kalkhoffii. No other microorganisms are included, eg, the non-phytopathogenic yeast C. albicans, or bacteria. Furthermore, no specific application is mentioned, such as the preservation of cosmetic formulation products. US 2008 / 0254130 AA (Bioderm Research) discloses a topical method of treating dysfunction of certain dermal enzymes and treating the skin condition or disorder caused by said dysfunction. The antimicrobial activity of the different derivatives of acetophenone is not described. JP 07 206645 A (POLA) discloses acetophenone derivatives as hair growth agents. Antimicrobial activity of the different acetophenone derivatives is not described. / zcznn / Lznz / E / Yii Document EP 2774481 B1 (SYMRISE) suggests antimicrobial compositions comprising (a) at least one acetophenone derivative of formula (I) wherein R1 represents hydrogen or methyl, and R2 represents hydrogen, hydroxyl or an -OCH3 group, or a cosmetically or pharmaceutically acceptable salt thereof, and (b) at least one second antimicrobial agent. However, it turned out that the synergistic effects between components (a) and (b) are not always significant and are highly dependent on the weight ratios. PROBLEM TO BE RESOLVED The search for suitable (active) substances, which have one or more of the mentioned properties to a suitable extent, is made difficult for the person skilled in the art because on the one hand there is no clear dependency between the chemical structure of a substance, and its biological activity against certain microorganisms (bacteria, yeasts, fungi, small eukaryotes) on the other hand. This makes the testing of substances in laboratory experiments unavoidable. Furthermore, the antimicrobial performance in the cosmetic formulation cannot be derived from standard antimicrobial screening tests, such as growth inhibition experiments as described, for example, in DIN 58940 or ISO 20776. Many antimicrobial substances characterized by minimal inhibitory concentrations (MIC ) lows do not work in more advanced and applied essays. For the preservation of the product, the stimulation test must be used, which is very laborious and time-consuming, according to ISO 11930, the European Pharmacopoeia 7 - 5.1.3 or the United States Pharmacopoeia 35. Furthermore, there is no connection predictable relationship between the chemical structure and other physicochemical parameters relevant to the field of cosmetics, ie toxicological acceptability, skin tolerability, stability, solubility and formulation properties and odor of a substance. Therefore, the problem underlying the present invention has been the development of new antimicrobial agents that meet the complex profile explained above and are particularly active at low concentrations against a / zcznn / Lznz / E / Yii variety of different microorganisms. Another object of the invention has been to provide emulsions comprising said antimicrobial agents with improved stability. / zcznn / Lznz / E / Yii DESCRIPTION OF THE INVENTION The object of the present invention is an antimicrobial mixture comprising or consisting of (a) a first antimicrobial agent selected from the group consisting of at least one acetophenone derivative of formula (I) where Ri represents hydrogen or methyl, and R2 represents hydrogen, hydroxyl, or an OCH3 group, or a cosmetically or pharmaceutically acceptable salt thereof, and (b) at least one second antimicrobial agent selected from the group consisting of preservatives selected from the group consisting of: / zcznn / Lznz / E / YiA 1-(3-chloroallyl)-3,5,7-triaza-l-azoniaadamantane chloride, 1-(4-chlorophenoxy)-1-(IH-imidazol-l-yl)-3,3-dimethyl-2-butanone, l-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2( 1H)-pyridone, 2-aminoethanol (Octopirox) 1,1'-methylene-bis(3-(l-hydroxymethyl-2,4-dioxymidazolidin-5-yl)urea), 1,2-benzisothiazol-3(2H)-one, 1,2-decanediol, 1,2-decanediol, 1,2-dibromo-2,4-dicyanobutane, 1,3-bis(hydroxymethyl)-1-(1,3,4-tris(hydroxy-methyl)-2,5dioxoimidazolidin-4-yl)urea (diazolidinyl urea), 1,3-bis-(hydroxymethyl)-5,5-dimethyl-2,4-imidazolidinedione, 1,3-bis(hydroxy-methyl)-5,5-dimethylimidazolidin-2,4-dione, 1,5-pentanediol, 1,6-bis(4-amidino-2-bromophenoxy)-n-hexane and its salts, 1,6-bis(4-amidino-phenoxy)-n-hexane and its salts, 1,6-hexanediol, 1,8- octanediol, 10-undecylenic acid and its salts, 1—phenoxy-propan-2-ol, 2,2'-methylene-bis(6-bromo-4-chlorophenol), 2,4,4'-Trichloro-2'-hydroxy-diphenyl ether (triclosan), 2,4-Dichlorobenzyl Alcohol, N-(4-chlorophenyl)-Ν'-(3,4dichlorophenyl)-urea, 2,4-Hexadienoic acid (sorbic acid) and its salts (for example, potassium salt), 2-benzyl-4-chlorophenol, 2-benzylheptan-l-ol, 2-bromo-2-(bromomethyl)pentanedinitrile, 2-bromo-2-nitro-l,3-propanediol (Bronopol), 2-butyloctanoic acid, 2-chloroacetamide, chlorhexidine, 2-hydroxybiphenyl ether and its salts, 2-methyl-3(2H)-isothiazolinone and with magnesium chloride and magnesium nitrate, 2-octyl-2H-isothiazol-3-one, / zcznn / Lznz / E / Yii 2-phenoxyethanol, 2-Zinc-sulfidopyridine N-oxide, 3-(4-chlorophenoxy)-1,2-propanediol, 3-(4-chlorphenoxy)-1,2-propanediol (Chlorphenesin), 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, 3-benzyloxy-propan-l,2-diol, 3-iodo-2-propynyl butylcarbamate, 3-phenoxy-propan-1,2-diol, 3-phenoxypropanol, 4,4-dimethyl-1,3-oxazolidine, 4-chloro-3,5-dimethylphenol, 4-chloro-m-cresol, 4-ethylmercury-(II)5-amino-l,3-bis(2-hydroxybenzoic) acid, its salts and esters, 4-hydroxy benzaldehyde, 5-amino-1,3-bis(2-ethylhexyl)-5-methyl-hexahydropyrimidine, 5-bromo-5-nitro-l, 3-dioxane, 5-chloro-2-methyl-3(2H)-isothiazolinone, 5-ethyl-l-aza-3,7-dioxabicyclo(3.3.0)octane, alkyl-(Cg-Cis)-dimethyl-benzylammonium bromide, chloride alkyl-(Cg-Cis)-dimethyl-benzyl-ammonium, alkyl-(Cg-Cis)-dimethyl-benzyl-ammonium saccharinate, / zcznn / Lznz / E / Yii anisic acid and its salts, benzoic acid and parahydroxybenzoic acid , its esters and salts, benzyl alcohol, benzyl benzoate, benzyl hemiformal, benzyloxymethanol, benzyloxymethoxy-methanol hexamethylenetetramine, bis(2-pyridylthio)zinc 1,1'-dioxide, N,N'-(decane-1) dihydrochloride ,10-diyldipyridin-l-yl-4-ylidene)-dioctan-1amine (octenidine dihydrochloride), bromochlorophene, caprylhydroxamic acid, capryloyl glycine, cetylpyridinium chloride, chitosan, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, chlorobutanolum, cinnamic acid and its salts, cinnamic alcohol, / zcznn / Lznz / E / Yii cinnamic aldehyde, / zcznn / Lznz / E / Yii climbazole, dehydracetic acid, diazolidinyl urea, DMDM hydantoin, ethylenediamine tetra acetate (EDTA) ethylenedioxydimethane1, ethyl lauroyl arginate HCL sodium salt of ethylmercury-(II)-thiosalicylic acid, eugenol, farnesol, formaldehyde and paraformaldehyde, formic acid, glutaraldehyde, glyceryl monolaurate, glyceryl caprylate glyceryl caprate hyamines, imidazolidinyl urea, inorganic sulfites and bisulfites, levulinic acid and its salts, N-(3-aminopropyl)-N-dodecylpropan-1,3-diamine, N-alkyl (C12-C22) trimethyl ammonium, N-hydroxymethyl-N-(1,3-di(hydroxymethyl)-2,5dioxoimidazolidin-4-yl)-Ν'-hydroxy-methylurea, aldehyde ortho bromide and chloride -, meta- and paraanisic, perilic acid and its salts, phenylmercury and its salts, poly(hexamethylenediguanide) hydrochloride, propionic acid and its salts, salicylic acid and its salts, pyridine-2-thiol-l-oxide, sodium benzonate Sodium Hydroxymethyl-Aminoacetate, Sodium Hydroxymethylglycinate, Sodium Iodate, Sorbitan Caprylate, Sorbohydroxamic Acid, Tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo[4,5d]imidazole-2,5(1H,3H )-dion, thymol, tropolone, undecenoyl glycine a,a',a-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol, / zcznn / Lznz / E / Yii and their mixtures. The invention is based on the surprising finding that the compounds of the formula (I) according to the invention show very good broad-spectrum activity as an agent for preserving various formulations against microbial spoilage. Furthermore, the compounds of the formula (I) synergistically enhanced the antimicrobial effects at least against selected microorganisms, in particular against mold species of the genus Aspergillus, such as Aspergillus brasiliensis, niger, flavus, fumigatus and also other microorganisms. Molds are known to combat themselves with great difficulty, due to their high tolerance to different pH, temperature, osmotic pressure and nutrient conditions, as well as their ability to resist and degrade different chemicals. In particular, it has been found that the mixtures according to the invention can be used excellently as a mixture of antimicrobial active compounds, in particular for preserving otherwise perishable items. More particularly, it was found that the synergistically active mixtures according to the invention have a good action against the species Staphylococcus epidermidis, Corynebacterium xerosis, Brevibacterium epidermidis, Propionibacterium acnes / zcznn / Lznz / E / YiA and against Trichophyton and Epidermophyton, so that they can be used as agents for treating or combating underarm and foot odor or body odor in general, as anti-acne agents, as anti-dandruff agents and for the treatment of mycoses, in particular dermatomycosis. / zcznn / Lznz / E / Yii ACETOPHENONE DERIVATIVES The acetophenone derivatives according to the present invention represent known compounds that can be obtained by conventional organic chemical methods. It is understood that both ORi and R2 substituents can be located in the ortho, meta or para position towards the methylketo group. Preferably, the species are selected from the group consisting of (la): 2-hydroxyacetophenone (Ib): 3-hydroxyacetophenone OH (Ic): 4-hydroxyacetophenone / zcznn / Lznz / E / YiA or their mixtures. While the definition refers to cosmetically or pharmaceutically acceptable salts of such derivatives, this means that these salts can be safely used for pharmaceutical purposes. This is not to say that the present invention or any aspect thereof is restricted to the use of a compound of formula (I) or a corresponding mixture for pharmaceutical purposes. Generally, if a salt can be used for pharmaceutical purposes, it can also be used for cosmetic purposes or in food or beverage formulations. In particular, the sodium, potassium and ammonium salts of the compounds of formula (I) are considered to be (pharmaceutically) acceptable salts. In some cases, the use of the respective ionic compound or solvate carrier proves to be superior to the unmodified derivative. The (pharmaceutically) acceptable salts (and corresponding solvates) of the compounds of formula (I) can be prepared by standard procedures. Hereinafter, any reference to a compound of formula (I) or a corresponding mixture, as defined above, is to be understood as comprising a further reference to the corresponding (pharmaceutically) acceptable salts thereof. It is also worth mentioning that although those skilled in the art have already addressed the antimicrobial properties of aromatic alcohols, such as benzyl alcohol, 2-phenylethyl alcohol, 3-phenylpropanol, 2-phenoxyethanol, 3-phenoxypropanol, 1-phenoxy -propan-2-ol, 3-phenoxy-propan-1,2diol, benzyloxymethanol and (benzyloxymethoxy)-methanol extensively, there has so far been no indication that mixtures of acetophenone derivatives have significantly enhanced antimicrobial action (at least against selected microorganisms) in the individual case. It was therefore particularly surprising that the mixtures according to the invention show highly synergistic activity, and in the treatment of molds of the genus Aspergillus are significantly superior to • the compounds of formula (I) administered individually or • other antimicrobial active compounds administered individually that are not compounds of the formula (I), in particular diols and aromatic alcohols administered individually, such as for example 1,3-propanediol, methi-Ipropanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2 / zcznn / Lznz / E / Yii octanediol, ethylhexylglycerin, hexoxy-propan-1,2-diol, heptoxy-propan-1,2-diol, octoxy-propan-1,2-diol, 3-benzyloxy-propan-1 ,2-diol, 3-phenylethyloxy-propan-1,2-diol, 3-phenylpropyloxy-propan-1,2-diol, 3-methylbenzyloxy-propan-1,2-diol, 3-phenyl propanol, 2-phenoxyethanol and mixtures of these compounds in the same concentration, in particular with respect to the reduction of the microbial count and the rate of reduction of the microbial count. In a preferred embodiment, the antimicrobial agent comprises or contains two or three of the compounds (la), (Ib) and (Ic), such as 2-hydroxyacetophenone and 3-hydroxyacetophenone, or 2-hydroxyacetophenone and 4-hydroxyacetophenone, or 3- hydroxyacetophenone and 4-hydroxyacetophenone. The mixtures may contain components (a) and (b) in a weight ratio of from about 1:99 to about 99:1, preferably from about 20:80 to about 80:20, and more preferably from about 40:60 to about 60:40. / zcznn / Lznz / E / Yii SECONDARY ANTIMICROBIAL AGENTS Preferred secondary preservatives encompass the compounds listed in Table A. Preferred ratios by weight (4-PAH:Active) with respect to the strongest synergistic effects are also provided: Table A Preferred Secondary Antimicrobial Agents / zcznn / Lznz / E / Yii Ratio by weight 4-HAP: antimi- Secondary preservative secondary crobis preferred Preferred Most preferred Most preferred 1,3-propanediol 1:50 - 1:5 10:1- 25:1 1 : 19 4-isopropyl-3- Methylphenol 10 : 1 - 1 : 10 8:1-1 : 1 4 : 1 Benzyl alcohol 5:1 - 1:5 3:1 - 1:3 1 : 1 Bronopol 2:1 - 1.2 1.5:1 - 1 : 1.5 1 : 1 capryloyl glycine 5:1-1 : 5 1:1-1 : 4 1 : 3 Climbazol, Crinipan 20:1- -5:1 10:1 - 8:1 9 : 1 Ethyl lauroyl arginate HC1 5:1 - 1: 5 3:1 - 1:3 1 : 1 Ethylenediamine tetraacetate 5 : 1 - 1 5 1:1-1 : 4 1 : 3 Glyceryl Caprate 5:1 - 1: 5 3:1 - 1:3 1 : 1 Glyceryl Caprylate 5:1 - 1: 5 3:1 - 1:3 1 : 1 IPBC, 3-iodo-2-propynylbutylcarbamate 150: 50 1 - 1 120:1 - 80:1 99 : 1 PHMB, polyhexamethylene biguanide 10:1- -1:1 5:1 - 2:1 4 : 1 Piroctone Olamine, Octopirox 20:1- -1:1 10:1 - 2:1 9 : 1 Potassium Sorbate 5:1 - 1: 5 3:1 - 1:3 1 : 1 Sodium Benzonate 1:10 - -5:1 1:4 - 2:1 1 : 3 sorbitan caprylate 5:1 - 1: 5 3:1 - 1:3 1 : 1 Triclosan 50:1- - 5:1 25:1- 10:1 19 : 1 Undecenoyl glycine 2:1 - 1.2 1.5:1 - 1:1.5 1 : 1 / zcznn / Lznz / Ε / γΐΛΐ Undecylenic acid, undec-10-enoic acid 10:1 - 1:1 4:1 - 2:1 3 : 1 / zcznn / Lznz / E / Yii Mixtures of 4-hydroxyacetophenone and one of the preferred secondary antimicrobial agents, particularly within the preferred ranges, show additional advantageous effects with respect to storage stability of emulsions at temperatures below 5 and above 25 °C. , which facilitates the preparation of cosmetic products comprising said mixtures. ADDITIVES TO PRESERVATION MIXTURES In a preferred embodiment, the performance of the mixtures is improved by the addition of certain hydroxy compounds, selected from the group consisting of 1,3-propanediol, methylpropanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, ethylhexylglycerin, hexoxypropan-1,2-diol, heptoxy-propan-1,2-diol, octoxy-propan-1,2diol, 3-benzyloxy-propan-1,2-diol, 3-phenylethyloxy-propan-1,2diol, 3-phenylpropyloxy-propan-1,2-diol, 3-methylbenzyloxypropan-1,2-diol, 3-phenyl propanol, 223 phenoxyethanol and its mixtures. In particular, the addition of 2-phenoxyethanol is preferred. The additives may be present in an amount of about 1 to 25, preferably 2 to 20, and more preferably about 5 to 10% by weight. - calculated on total mixtures. PERSONAL CARE COMPOSITIONS Another embodiment of the present invention encompasses a cosmetic or personal care composition comprising an operative amount of at least one acetophenone derivative or its mixtures with additional preservatives and / or antimicrobial agents, which may be present in amounts of about 0 0.01 to about 10, preferably from about 0.05 to about 5, and more preferably from about 0.1 to about 1% by weight. calculated on the total composition. The cosmetic or personal care compositions may contain abrasives, anti-acne agents, anti-aging agents, anti-cellulite agents, anti-dandruff agents, anti-inflammatory agents, irritation-preventing agents, irritation-inhibiting agents, antioxidants, astringents , perspiration inhibiting agents, antiseptic agents, antistatic agents, binders, hampons, ma / zcznn / Lznz / E / Yii fair carriers, chelating agents, cell stimulants, cleansing agents, care agents, depilatory agents, surfactants, deodorant agents, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibres, film-forming agents, fixatives, foaming agents, foam stabilizers, foam preventers, foam boosters, gelling agents, gel-forming agents, anti-foaming agents, hair care, hair fixing agents, hair straightening agents, moisture absorbing agents, moisturizing substances, moisture retaining substances, bleaching agents, strengthening agents, stain removing agents, optical brightening agents, impregnating agents, stain repelling agents dirt, friction-reducing agents, lubricants, moisturizing creams, ointments, opacifying agents, plasticizing agents, coating agents, polishes, glossing agents, polymers, powders, proteins, refatting agents, abrasive agents, silicones, skin softening agents, skin cleansing agents, skin care agents, skin curing agents, skin lightening agents, skin protecting agents, skin softening agents, cooling agents, cooling agents / zcznn / Lznz / E / Yii skin care agents, warming agents, skin warming agents, stabilizers, UV absorbing agents, UV filters, detergents, fabric conditioning agents, suspending agents, skin tanning agents, thickeners, vitamins, oils, waxes, Fats, phospholipids, saturated fatty acids, monounsaturated or polyunsaturated fatty acids, α-hydroxy acids, polyhydroxy-fatty acids, liquefying agents, dyes, color protection agents, pigments, anticorrosives, aromas, flavoring substances, odoriferous substances, polyols, surfactants, electrolytes , organic solvents or silicone derivatives and the like as auxiliaries and additives. / zcznn / Lznz / E / Yii SURFACTANTS Other preferred auxiliaries and additives are anionic and / or amphoteric or zwitterionic or zwitterionic surfactants. Typical examples of anionic surfactants are soaps, alkyl benzene sulphonates, alkane sulphonates, olefin sulphonates, alkyl ether sulphonates, glycerol ether sulphonates, methyl ester sulphonates, sulphurous acids, alkyl sulphates, fatty alcohol ether sulphates, glycerol ether sulphates, fatty acid ether sulphates, hydroxy ether sulphates (mixed monoglyceride ) sulfates, fatty acid amides (ethers) sulfates, mono and dialkyl sulfosuccinates, mono and dialkyl sulfosuccinates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, Nacylamino acids such as, for example, acyl lactylates, acyl tartrates, acyl glutamates and acyl aspartates, alkyl oligoglucoside sulfates, condensates of fatty acids and proteins (particularly wheat-based vegetable products) and alkyl phosphates (ether ). If the anionic surfactants contain polyglycol ether chains, they may have a conventional homolog distribution, although they preferably have a narrow range homolog distribution. Typical examples of amphoteric or zwitterionic surfactants are alkylbetaines, alkylamidobetaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines. The mentioned surfactants are all known compounds. Information on their structure and production can be found in relevant synoptic works, see for example J. Falbe (ed.), Surfactants in Consumar Products, Springer Verlag, Berlin, 1987, pages 54 to 124 or J. Falbe (ed. ), Katalysatoren, Tenside und Mineralóladditive (Catalysts, Surfactants and Mineral Oil Additives), Thieme Verlag, Stuttgart, 1978, pages 123-217. The percentage content of surfactants in the preparations may be 0.1 to 10% by weight and preferably 0.5 to 5% by weight, based on the preparation. B. Oily bodies Suitable oil substances which form the components of the oil-water emulsions are, for example, Guerbet alcohols based on fatty alcohols having 6 to 18, preferably 8 to 10 carbon atoms, esters of SOS-C6 fatty acids -C22 linear with linear or branched Cg-C22-fatty alcohols or Cg-C13-branched carboxylic acid esters with linear or branched Cg-C22-fatty alcohols, such as, for example, myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, myristate stearyl, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, olei / zcznn / Lznz / E / Yiilo oleate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate, stearate behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate and erucyl erucate. Also suitable are esters of linear Cg-C22-fatty acids with branched alcohols, in particular 2-ethylhexanol, esters of Cis-Css-alkylhydroxycarboxylic acids with linear or branched Cs-C22-fatty alcohols, in particular dioctyl malate, esters of linear and / or branched fatty acids with polyhydric alcohols (such as propylene glycol, dimerdiol or trimertriol) and / or Guerbet alcohols, triglycerides based on Cs-Cio-fatty acids, liquid mono- / di- / triglycerides based on Cg-Cis fatty acids, Cs-C22 fatty alcohol esters and / or Guerbet alcohols with aromatic carboxylic acids, in particular benzoic acid, Ci-C12 dicarboxylic acid esters with linear or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C22-Cg-fatty alcohol carbonates, such as eg / zcznn / Lznz / E / Yii dicaprylyl carbonate (Cetiol® CC), Guerbet carbonates, based on fatty alcohols having 6 to 18, preferably 8 to 10 carbon atoms, esters of benzoic acid with linear and / or branched C6-C22-alcohols (for example, Finsolv® TN), linear or branched, symmetrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as, for example, dicaprylylether (Cetiol® OE), ring-opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicones, methicone silicone grades, etc.) and / or aliphatic or naphthenic hydrocarbons, such as, for example, squalane, squalene or dialkylcyclohexanes . / zcznn / Lznz / E / Yii EMULSIFIERS Other surfactants may also be added to preparations as emulsifiers, including, for example: • products of the addition of 2 to 30 moles of ethylene oxide and / or from 0 to 5 moles of propylene oxide on linear Cs-22 fatty alcohols, on C12-22 fatty acids and on alkylphenols containing from 8 to 15 carbon atoms in the alkyl group; • monoesters and diesters of C12 / 18 fatty acids from addition products of 1 to 30 moles of ethylene oxide on glycerol; • glycerol mono- and diesters and sorbitan mono- and diesters of saturated and unsaturated fatty acids containing from 6 to 22 carbon atoms and ethylene oxide addition products thereof; • addition products of 15 to 60 moles of ethylene oxide on castor oil and / or hydrogenated castor oil; • polyol esters and, in particular, polyglycerol esters such as, for example, polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol isostearate dimerate. Mixtures of compounds from several of these classes are also suitable; • addition products of 2 to 15 moles of ethylene oxide on castor oil and / or hydrogenated castor oil; • partial esters based on linear, branched, unsaturated or saturated Ce / 22 fatty acids, ricinoleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (eg sorbitol), alkyl glucosides (eg methylglucoside, butyl glucoside, lauryl glucoside) and polyglucosides (eg cellulose); / zcznn / ίζηζ / Ε / γι • mono-, di- and trialkyl phosphates and mono-, di- and / or tri-PEG-alkyl phosphates and their salts; • wool fat alcohols; • polysiloxane / polyalkyl polyether copolymers and corresponding derivatives; • mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol and / or mixed esters of Cs-22 fatty acids, methylglucose and polyols, preferably glycerol or polyglycerol, • polyalkylene glycols and • glycerol carbonate. Addition products of ethylene oxide and / or propylene oxide on fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters and sorbitan mono- and diesters of fatty acids or on castor oil are known products available in the market. trade. They are homologous mixtures whose average degree of alkoxylation corresponds to the ratio between the amounts of ethylene oxide and / or propylene oxide and the substrate with which the addition reaction is carried out. C12 / 18 fatty acid monoesters and diesters of addition products of ethylene oxide onto glycerol are known as / zcznn / Lznz / E / YiAi lipid layer enhancers for cosmetic formulations. Preferred emulsifiers are described in more detail below: Partial glycerides. Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid monoglyceride, ricinoleic acid diglyceride, linoleic acid, linoleic acid diglyceride, linoleic acid monoglyceride, linolenic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, acid monoglyceride malic, malic acid diglyceride and technical mixtures thereof which may still contain small amounts of triglycerides from the production process. Addition products of 1 to 30 and preferably 5 to 10 mol of ethylene oxide to the mentioned partial glycerides are also suitable. Sorbitan esters. Suitable sorbitan esters are sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, / zcznn / Lznz / E / Yii sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sesquierucate Sorbitan Dierucate, Sorbitan Trierucate, Sorbitan Monoricinoleate, Sorbitan Sesquiricinoleate, Sorbitan Diricinoleate, Sorbitan Triricinoleate, Sorbitan Monohydroxystearate, Sorbitan Sesquiricinoleate, Sorbitan Dihydroxystearate, Sorbitan Trihydroxystearate, Sorbitan Monotartrate, Sorbitan Sesquitartrate , sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and technical mixtures thereof. Addition products of 1 to 30 and preferably 5 to 10 mol of ethylene oxide to the mentioned sorbitan esters are also suitable. Polyglycerol esters. Typical examples of suitable polyglycerol esters are polyglyceryl-2 dipolyhydroxystearate (Dehymuls® PGPH), polyglyceryl-3-diisostearate (Lameform® TGI), polyglyceryl-4 isostearate (Isolan® GI 34), polyglyceryl-3 oleate, diisostearoyl polyglyceryl-3 diisostearate (Isolan® PDI), polyglyceryl-3 methylglucose distearate (Tego Care® 450), polyglyceryl-3 beeswax (Cera Bellina®), polyglyceryl-4 caprate (polyglycerol caprate T2010 / 90), poly / zcznn / Lznz / E / Yii glyceryl-3 cetyl ether (Chimexane® NL), polyglyceryl-3 distearate (Cremophor® GS 32) and polyglyceryl polyricinoleate (Admul® WOL 1403), polyglyceryl dimerate isostearate and mixtures thereof. Examples of other suitable polyol esters are the mono-, di- and triesters of trimethylolpropane or pentaerythritol with lauric acid, coconut fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like optionally reacted with 1 to 30 moles of ethylene oxide. Anionic emulsifiers. Typical anionic emulsifiers are C12-22 aliphatic fatty acids, such as palmitic acid, stearic acid or behenic acid, for example, and C12-22 dicarboxylic acids, such as azelaic acid or sebacic acid, for example. Amphoteric emulsifiers. Other suitable emulsifiers are amphoteric or zwitterionic surfactants. Zwitterionic surfactants are surfactant compounds that contain at least one quaternary ammonium group and at least one carboxylate group and one sulfonate group in the molecule. Particularly suitable zwitterionic surfactants are the so-called betaines, such as N-alkyl-N, N-dimethylammonium glycinates, eg cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N,N / zcznn / Lznz / E / Yii dimethylammonium, for example, cocoacylaminopropyl dimethylammonium glycinate and 2-alkyl-3-carboxymethyl-3-hydroxyethylimidazolines containing 8 to 18 carbon atoms in the alkyl or acyl group and cocoacylaminoethyl hydroxyethyl carboxymethyl glycinate. In particular, the fatty acid amide derivative known under the CTFA name of Cocamidopropyl betaine is preferred. Ampholytic surfactants are also suitable emulsifiers. Ampholytic surfactants are surfactant compounds which, in addition to a Cs / is acyl or alkyl group, contain at least one free amino group and at least one COOH- or -SO3H- group in the molecule and which are capable of forming internal salts. Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkyl sarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids containing about from 8 to 18 carbon atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C12 / 18 acyl sarcosine. / zcznn / Lznz / E / Yii SUPERFATTING AGENTS AND CONSISTENCY FACTORS Superfatting agents can be selected from substances such as, for example, lanolin and lecithin and also polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides, fatty acid alkanolamides also serve as fat stabilizers. foam. The most commonly used consistency factors are fatty alcohols or hydroxyfatty alcohols containing 12 to 22 and preferably 16 to 18 carbon atoms and also partial glycerides, fatty acids or hydroxyfatty acids. A combination of these substances with alkyl oligoglucosides and / or fatty acid N-methylglucamides of the same chain length and / or polyglycerol poly-12-hydroxystearates is preferably used. THICKENERS AND RHEOLOGICAL ADDITIVES Suitable thickeners are polymeric thickeners, such as Aerosil® types (hydrophilic silicas), polysaccharides, more especially xanthan gum, guar-guar, agar-agar, alginates and tyloses, carboxymethylcellulose and hydroxyethylcellulose, also polyethylene glycol monoesters of relative molecular weight / zcznn / High Lznz / E / Yii and diesters of fatty acids, polyacrylates (for example Carbopols® [Goodrich] or Synthalens® [Sigma]), polyacrylamides, polyvinyl alcohol and polyvinylpyrrolidone, surfactants such as, for example, ethoxylated fatty acid glycerides, esters of fatty acids with polyols, eg pentaerythritol or trimethylol propane, ethoxylates and narrow range fatty alcohol electrolytes such as sodium chloride and ammonium chloride. POLYMERS Suitable cationic polymers are, for example, cationic cellulose derivatives, such as, for example, the quaternized hydroxyethylcellulose available from Amerchol under the name Polymer JR 400®, cationic starch, copolymers of diallyl ammonium salts and acrylamides, vinyl pyrrolidone / quaternized vinyl imidazoles such as, for example, Luviquat® (BASF), condensation products of polyglycols and amines, quaternized collagen polypeptides such as, for example, lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat® L, Grünau), wheat polypeptides quaternized, polyethyleneimine, cationic silicone polymers such as, for example, amodimethicone, copolymers of adipic acid and dimethylaminohydroxypropyl diethylenetriamine (Cartareti38ne®, Sandoz), copolymers of acrylic acid with dimethyl diallyl ammonium chloride (Merquat® 550, Chemviron), polyaminopolyamides and their crosslinked water-soluble polymers, cationic chitin derivatives such as, for example, quaternized chitosan, optionally in microcrystalline distribution, condensation products of dihaloalkyls, for example dibromobutane, with bis-dialkylamines, for example bisdimethylamino-1,3-propane , cationic guar gum such as, for example, Jaguar®CBS, Jaguar®C-17, Jaguar®C-16 from Celanese, quaternized ammonium salt polymers such as, for example, Mirapol® A-15, Mirapol® AD- 1, Mirapol® AZ-1 from Miranol and the different types of polyquaternium (for example 6, 7, 32 or 37) that can be found commercially under the trade names Rheocare® CC or Ultragel® 300. Suitable anionic, zwitterionic, amphoteric and nonionic polymers are, for example, vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / Maleic anhydride and its esters, non-crosslinked and polyol-crosslinked polyacrylic acids, acrylamidopropyltrimethylammonium chloride / acrylate copolymers, octylacrylamide / methyl methacrylate / tether / zcznn / Lznz / E / Yii butylaminoethyl / 2-hydroxypropyl methacrylate copolymers, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / dimethylaminoethyl methacrylate / vinylcaprolactam terpolymers and optionally derivatized cellulose ethers and silicones. PEARL WAXES Suitable pearlescent waxes are, for example, alkylene glycol esters, especially ethylene glycol distearate; fatty acid alkanolamides, especially coconut fatty acid diethanolamide; partial glycerides, especially stearic acid monoglyceride; esters of polybasic carboxylic acids, optionally hydroxy-substituted with fatty alcohols containing 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; fatty compounds, such as, for example, fatty alcohols, fatty carbonates, fatty aldehydes, fatty ethers and fatty carbonates, which contain a total of at least 24 carbon atoms, especially laurone and distearylether; fatty acids, such as stearic acid, hydroxystearic acid or behenic acid, ring-opening products of olefin epoxides containing 12 to 22 carbon atoms with fatty alcohols containing 12 to 22 carbon atoms and / or polyols containing from 2 to 15 carbon atoms and from 2 to 10 hi / zeznn / ίζηζ / Ε / γι droxyl groups and mixtures thereof. SILICONES Suitable silicone compounds are, for example, dimethylpolysiloxanes, methylphenylpolysiloxanes, cyclic silicones and amino-, fatty acid-, alcohol-, polyether-, epoxy-, fluorine-, glucoside- and / or alkyl-modified silicone compounds, which can be both liquid and resinous at room temperature. . Other suitable silicone compounds are simethicones, which are mixtures of dimethicones with an average chain length of 200 to 300 dimethylsiloxane units and hydrogenated silicates. A detailed description of suitable volatile silicones can be found in Todd et al. in Cosm. toil. 91, 27 (1976). WAXES AND STABILIZERS In addition to the natural oils used, waxes can also be present in the preparations, more especially natural waxes such as, for example, candelilla wax, carnauba wax, Japan wax, Espartogras wax, cork wax, guaruma wax. , rice oil wax, sugarcane wax, ouricuri wax, Montana wax, beeswax, shellac wax, spermaceti, lanolin (la / zcznn / Lznz / E / Yii na wax) , uropygial fat, ceresin, ozocerite (ground wax), petroleum jelly, paraffin and microwave waxes; chemically modified waxes (hard waxes) such as, for example, Montana ester waxes, sasol waxes, hydrogenated jojoba waxes, and synthetic waxes, such as, for example, polyalkylene waxes and polyethylene glycol waxes. As stabilizers it is possible to use metal salts of fatty acids such as, for example, magnesium, aluminum and / or zinc stearate or ricinoleate. PRIMARY SUN PROTECTION FACTORS Primary sun protection factors in the context of the invention are, for example, organic substances (light filters), liquid or crystalline at room temperature, capable of absorbing ultraviolet radiation and releasing the absorbed energy in the form of wave radiation. longer, for example, heat. The formulations according to the invention advantageously contain at least one UV-A filter and / or at least one UV-B filter and / or a broadband filter and / or at least one inorganic pigment. The formulations according to the invention preferably contain at least one UV-B filter or a broadband filter, more particularly preferably at least one UV-A filter and at least one UV-B filter. / zcznn / Lznz / E / Yii Preferred cosmetic compositions, preferably topical formulations according to the present invention, comprise one, two, three or more sun protection factors selected from the group consisting of 4-aminobenzoic acid and derivatives, salicylic acid derivatives, benzophenone derivatives, dibenzoylmethane derivatives, Diphenyl acrylates, 3-imidazol-4-yl acrylic acid and its esters, benzofuran derivatives, benzylidene malonate derivatives, polymeric UV absorbers containing one or more organosilicon radicals, cinnamic acid derivatives, camphor derivatives, trianilino-s-triazine derivatives, 2-hydroxyphenylbenzotriazole derivatives, phenylbenzimidazole sulfonic acid derivatives and salts thereof, menthyl esters of anthranilic acid, benzotriazole derivatives and indole derivatives. Furthermore, it is advantageous to combine compounds of the formula (I) with active ingredients that penetrate the skin and protect the skin cells from within against sunlight-induced damage and reduce the level of skin matrix metalloproteases. Preferred respective ingredients, termed arylhydrocarbon receptor antagonists, are described in WO 2007 / 128723, incorporated / zcznn / Lznz / E / Yii herein by reference. 2-Benzylidene-5,6-dimethoxy-3,3-dimethylindan-1-one is preferred. The UV filters mentioned below that can be used within the context of the present invention are preferred, but are of course not limiting. UV filters that are preferably used are selected from the group consisting of p-aminobenzoic acid p-Aminobenzoic acid ethyl ester (25 mol) ethoxylated (INCI name: PEG-25 PABA) p-Dimethylaminobenzoic acid 2-ethylhexyl ester p-aminobenzoic acid ethyl ester (2 mol) N-propoxylated p-aminobenzoic acid glycerol ester salicylic acid homomethyl ester (homosalates) (Neo Heliopan HMS) salicylic acid-2-ethylhexyl ester (Neo Heliopan OS) triethanolamine salicylate 4-isopropyl benzyl salicylate / zcznn / Lznz / E / Yii anthranilic acid menthyl ester (Neo Heliopan MA) diisopropyl cinnamic acid ethyl ester p-methoxycinnamic 2-ethylhexylic acid ester (Neo Heliopan AV ) diisopropyl cinnamic acid methyl ester p-methoxycinnamic acid isoamyl ester (Neo Heliopan E 1000) p-methoxycinnamic acid diethanolamine salt p-methoxycinnamic acid isopropyl ester 2-phenylbenzimidazole sulfonic acid and salts (Neo Heliopan Hydro) 3-(4'-trimethylammonium)benzylidene-bornan-2-one methyl sulfate beta-imidazol-4(5)-acrylic acid (urocanic acid) 3-(4'-sulfo)benzylidene-bornan-2-one and salts 3-(4'-methylbenzylidene)-D,L-camphor (Neo Heliopan MBC) 3-benzylidene-D,L-camphor N—[(2 and 4)-[2-(oxoborn-3-ylidene)methyl]benzyl]acrylamide polymer 4,4'-(6- 4-(1,1-dimethyl)aminocarbonyl)phenylamino- 1, 3, 5-triazine-2,4-diyl)diimino -bis-(benzoic acid-2- / zcznn / Lznz / E / Yii ethiihexylester) (Uvasorb HEB) benzylidene malonate polysiloxane (Parsol SLX) glyceryl ethylhexanoate dimethoxycinnamate dipropylene glycol tris(2-ethylhexyl)-4,4',4''-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate salicylate (= 2,4,6-trianilino-(p-carbo2' -ethylhexyl-1'-oxy)-1,3,5-triazine) (Uvinul T150) Broadband filters that are preferably combined with one or more compounds of formula (I) in a preparation according to the present invention are selected from the group consisting of 2-ethylhexyl-2-cyano-3,3-diphenyl acrylate (Neo Heliopan 303) ethyl-2-cyano-3,3'-diphenyl acrylate 2-hydroxy-4-methoxybenzophenone (Neo Heliopan BB) 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid dihydroxy-4-methoxybenzophenone 2,4-dihydroxybenzophenone tetrahydroxybenzophenone 2,2'-dihydroxy-4,4'-dimethoxybenzophenone / zcznn / Lznz / E / Yii 2-hydroxy-4-n-octoxybenzophenone Sodium disodium 2-hydroxy-4-methoxy-4'-methylbenzophenone hydroxymethoxybenzophenone sulfonate-2,2'-dihydroxy-4,4'-dimethoxy-5,5'disulfobenzophenone phenol, 2-(2H-benzotriazol-2-yl) -4-methyl-6-(2-methyl3(1,3,3,3-tetramethyl-l-(trimethylsilyl)oxy)disiloxyanyl)propyl) (Mexoryl XL) 2,2'-mephylene bis-(6-(2H-benzotriazol-2-yl)-4-1,1,3,3tetramethylbutyl)phenol) (Tinosorb M) 2,4-bis-4-(2-ethylhexyloxy) -2-hydroxyphenyl -1,3,5triazine 2,4-bis-(4-(2-ethylhexyloxy)-2-hydroxyphenyl-6-(4methoxyphenyl)-1,3,5-triazine (Tinosorb S) 2,4-Bis(4-(3-sulfonato)-2-hydroxypropyloxy)-2-hydroxyphenyl-6-(4-methoxyphenyl)1,3,5-triazine 2,4-bis-(3-(2) sodium salt -propyloxy)-2-hydroxypropyloxy)-2-hydroxyphenyl -6-(4-methoxyphenyl)-1,3,5-triazine 2,4- bis- 4-(2-ethylhexyloxy)-2-hydroxyphenyl -6- 4-(2 — / zcznn / Lznz / E / Yii methoxyethyl carbonyl)phenylamino-1,3,5-triazine 2,4- bis- 4-(3-(2-propyloxy)-2-hydroxypropyloxy)-2-hydroxyphenyl-6- 4-(2-ethylcarboxyl)phenylamino-1,3,5triazine 2,4-bis-4-(2-ethylhexyloxy)-2-hydroxyphenyl-6-(1methylpyrrol-2-yl)-1,3,5-triazine 2,4-bis-4-tris-(trimethylsiloxysilylpropyloxy)-2hydroxyphenyl-6-(4-methoxyphenyl)-1,3,5-triazine 2,4-bis-4-(2''-methylpropenyloxy)-2-hydroxyphenyl-6-(4methoxyphenyl)-1,3,5-triazine 2,4- bis- 4-(l',l',l',3',5',5',5'-heptamethylsiloxy-2''methylpropyloxy)-2-hydroxyphenyl-6-(4-methoxyphenyl) -1,3,5triazine UV-A filters that are preferably combined with one or more compounds of formula (I) in a preparation according to the present invention are selected from the group consisting of 4-Isopropyl dibenzoyl methane acid and terephthalylidene dibornan sulfonic salts (Mexoryl SX) 4-t-butyl-4'-methoxydibenzoyl methane (avobenzone) / (Neo Heliopan 357) / zcznn / Lznz / E / Yii phenylene bis-benzimidazyl tetrasulfonic acid disodium salt (Neo Heliopan AP) 2,2' -(1,4-phenylene)-bis-(1H-benzimidazole-4,6-disulfonic acid), monosodium salt 2-(4-Diethylamino-2-hydroxybenzoyl)benzoic acid hexyl ester (Uvinul A Plus) indanylidene compounds according to DE 100 55940 Al (= WO 2002 038537 Al) UV filters that are most preferably combined with one or more compounds of formula (I) in a preparation according to the present invention are selected from the group consisting of p-aminobenzoic acid Salicylic acid 3-(4'-trimethylammonium)benzylidene-bornan-2-one methyl sulfate homomethyl ester (Neo Heliopan HMS) 2-hydroxy-4-methoxybenzophenone (Neo Heliopan BB) 2-phenylbenzimidazole sulfonic acid (Neo Heliopan Hydro) terephthalylidene dibornan sulfonic acid and salts (Mexoryl SX) 4-tert-butyl-4'-methoxydibenzoyl methane (Neo Heliopan 357) / zcznn / Lznz / E / Yii 3-(4'-sulfo)benzylidene-bornan-2-one and salts 2-ethylhexyl-2-cyano-3,3-diphenyl acrylate (Neo Heliopan 303) p-Methoxycinnamic 2-ethylhexylic acid N-[(2 and 4)-[2-(oxoborn-3-ylidene)methyl]benzyl]acrylamide ester polymer (Neo Heliopan AV) p-Aminobenzoic acid ethyl ester (25 mol) ethoxylated (INCI name: PEG-25 PABA) p-methoxycinnamic acid isoamyl ester (Neo Heliopan E1000) 2,4,6-trianilino-(p-carbo-2'-ethylhexyl-1'-oxy)-1,3,5triazine (Uvinul T150) phenol, 2-(2H-benzotriazol-2-yl)-4-methyl -6-(2-methyl3(1,3,3,3-tetramethyl-l(trimethylsilyl)oxy)disiloxyanyl)propyl) (Mexoryl XL) 4,4'-(6- 4-(1,1-dimethyl)aminocarbonyl)phenylamino- 1, 3, 5-triazine-2,4-diyl)diimino -bis-(benzoic acid-2ethylhexylester) (Uvasorb HEB) 3-(4'-Methylbenzylidene)-D,L-Camphor (Neo Heliopan MBC) / zcznn / Lznz / E / Yii salidyl-2-ethylhexyl ester 3-benzylidene camphor (Neo Heliopan OS) 4-dimethylaminobenzoic acid 2-ethylhexyl ester (Padimate O) hydroxy-4-methoxybenzophenone-5-sulfonic acid and Na salt 2,2'-methylene bis-(6-(2H-benzotriazol-2-yl)-4-1,1,3,3-tetramethylbutyl)phenol) (Tinosorb M) phenylene bis-benzimidazyl tetrasulfonic acid disodium salt (Neo Heliopan AP) 2,4-bis-(4-(2-ethylhexyloxy)-2-hydroxyphenyl-6-(4-methoxyphenyl)-1,3,5-triazine (Tinosorb S) benzylidene malonate polysiloxane (Parsol SLX) menthyl anthranilate ( Neo Heliopan MA) 2-(4-Diethylamino-2-hydroxybenzoyl)benzoic acid hexyl ester (Uvinul A Plus) indanylidene compounds according to DE 100 55 940 (= WO 02 / 38537). In WO 2005 123101 Al, advantageous primary and also secondary sun protection factors are mentioned. Advantageously, these preparations contain at least one UVA filter and / or at least one UVE filter and / or at least one inorganic pig / zcznn / ίζηζ / Ε / γι filter. The preparations can be presented here in various forms, such as those conventionally used for sunscreen preparations. Therefore, they can be in the form of a solution, an emulsion of the water-in-oil (W / 0) type or of the oil-in-water (O / W) type or a multiple emulsion, for example of the water-in-oil-petticoat type. (W / O / W), a gel, a hydrodispersion, a solid stick or else an aerosol. In another preferred embodiment, a formulation according to the invention contains a total amount of sun protection agents, ie in particular UV filters and / or inorganic pigments (UV filter pigments), so that the formulation according to the invention has a protection factor against light greater than or equal to 2 (preferably greater than or equal to 5). Such formulations according to the invention are particularly suitable for protecting the skin and hair. SECONDARY FACTORS OF SUN PROTECTION In addition to the groups of primary sun protection factors mentioned above, secondary sun protection factors of the antioxidant type can also be used. Secondary sun protection factors of the an / zcznn / Lznz / E / Yii thioxidant type interrupt the photochemical reaction chain that begins when UV rays penetrate the skin. Typical examples are amino acids (eg glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (eg urocanic acid) and derivatives thereof, peptides, such as D,L-carnosine, D-carnosine, L- carnosine and derivatives thereof (for example anserine), carotenoids, carotenes (for example alpha-carotene, beta-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, liponic acid and its derivatives (for example dihydroliponic acid) , aurothioglucose, propylthiouracil, and other thiols (for example, thioredoxin, glutathione, cysteine, cystine, cystamine, and glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl, and lauryl, palmitoyl, oleyl, alpha-linoleyl, cholesteryl, and glyceryl and esters thereof) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and sulfoximine compounds (for example butthionine sulfoximines, homocysteine ​​sulfoximine , butionine sulfones, penta-, hexa-, and heptathionine sulfoximine) in very small compatible doses, also (metallic) chelators (for example, alphahydroxyfatty acids, palmitic acid, phytic acid, lactoferrin), / zcznn / Lznz / E / Yii alpha- hydroxy acids (for example, citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and derivatives thereof (for example, linoleic acid, oleic acid), folic acid and its derivatives, ubguinone and ubiquinol and its derivatives, vitamin C and its derivatives (for example, ascorbyl palmitate, Mg ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (for example, vitamin E acetate), vitamin A and derivatives (vitamin A palmitate) and benzoin resin coniferyl benzoate, rutinic acid and its derivatives, rutin glycosyl, ferulic acid, furfurylidene glycitol, carnosine, butylated hydroxytoluene, butylated hydroxyanisole, resin acid nordihydroguaiac, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (for example, ethanol dispersions), zinc and its derivatives (for example, ZnO, ZnSO4), selenium and its derivatives (for example setenium methionine), estribenes and their derivatives (for example stilbene oxide, transstilbene oxide) and derivatives of these active substances suitable for the purposes of the invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids). / zcznn / Lznz / E / Yii Secondary advantageous inorganic light protection pigments are the finely dispersed metal oxides and metal salts, which are also mentioned in WO 2005 123101 Al. The total amount of inorganic pigments, in particular hydrophobic inorganic micropigments in the finished cosmetic preparation according to the present invention it is advantageously from 0.1 to 30% by weight, preferably from 0.5 to 10.0% by weight, in each case based on the total weight of the preparation. Particulate UV filters or inorganic pigments are also preferred, which can optionally be hydrophobic, such as oxides of titanium (T1O2), zinc (ZnO), iron (Fe2Os), zirconium (ZrO2), silicon (S1O2), manganese (for example, MnO), aluminum (Al2O3), cerium (for example, Ce2O3) and / or mixtures thereof. / zcznn / Lznz / E / Yii ANTI-AGING ASSETS In the context of the invention, anti-aging or biogenic agents are, for example, antioxidants, matrix metalloproteinase inhibitors (MMPI), skin moisturizing agents, glucosamlycan stimulants, anti-inflammatory agents, TRPV1 antagonists and plant extracts. / zcznn / Lznz / E / YiA Amino acid antioxidants (preferably glycine, histidine, tyrosine, tryptophan) and derivatives thereof, imidazoles (preferably urocanic acid) and derivatives thereof, peptides, preferably D,L-carnosine, D-carnosine, L-carnosine and derivatives thereof ( preferably anserine), carnitine, creatine, matrikine peptides (preferably lysyl-threonyl-threonyl-lysyl-serine) and palmitoylated pentapeptides, carotenoids, carotenes (preferably alpha-carotene, beta-carotene, lycopene) and derivatives thereof, lipoic acid and derivatives of the same (preferably dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (preferably thioredoxin, glutathione, cysteine, cystine, cystamine and glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, gammalinoleyl, cholesteryl, glyceryl and their oligoglyceryl esters) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and derivatives thereof (preferably esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and sulfoximine compounds (preferably butthionine sulfoximines, homocysteine ​​sulfoximine, butthionine sulfones, penta-, hexa-, heptathionine sulfoximine) in very low tolerated doses (e.g. pmol to pmol / kg), also (metallic) chelators (preferably alpha-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin, alpha-hydroxy acids (preferably citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts, tannins, bilirubin, biliverdin, EDTA, EGTA and derivatives thereof), unsaturated fatty acids and derivatives thereof (preferably gamma-linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and its derivatives, ubiquinol and its derivatives, vitamin C and derivatives (preferably ascorbyl palmitate, Mg ascorbyl phosphate , ascorbyl acetate, ascorbyl glucoside), tocopherols and derivatives (preferably vitamin E acetate), vitamin A and derivatives (vitamin A palmitate) and benzoic resin coniferyl benzoate, rutinic acid and its derivatives, flavonoids and glycosylated precursors of the same, in particular guercetin and its derivatives, preferably alpha-glucosyl rutin, rosmarinic acid, carnosol, carnosolic acid, resveratrol, caffeic acid and its derivatives, sinapic acid and its derivatives, ferulic acid and its derivatives, curcuminoids, chlorogenic acid and its derivatives, retinoids, preferably retinyl palmitate, retinol or tretinoin, ursolic acid, / zcznn / Lznz / E / Yii levulinic acid, butyl hydroxytoluene, butyl hydroxyanisole, nordihydroguaiac acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, zinc and its derivatives (preferably ZnO, ZnSO4), selenium and its derivatives (preferably selenium methionine), superoxide dismutase, strobenes and their derivatives (preferably stilbene oxide, trans-stilbene oxide) and derivatives (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of these named active substances which are suitable according to the invention or extracts or fractions of plants with an antioxidant effect, preferably green tea, rooibos, honeybush, grape, rosemary, sage, lemon balm, thyme , lavender, olive, oats, cocoa, ginkgo, ginseng, liquorice, honeysuckle, sophora, pueraria, pinus, citrus, Phyllanthus emblica or St. John's wort, grape seeds, wheat germ, Phyllanthus emblica, coenzymes, preferably coenzyme Q10, plastoquinone and menaquinone. Preferred antioxidants are selected from the group consisting of vitamin A and derivatives, vitamin C and derivatives, tocopherol and derivatives, preferably tocopheryl acetate and ubiquinone. Matrix metalloproteinase inhibitors (MMPIs). Preferred compositions comprise matrix metalloproteinase inhibitors, especially those that inhibit collagen enzymatically cleaving matrix metalloproteinases, / zcznn / Lznz / E / Yii selected from the group consisting of: ursolic acid, retinyl palmitate, propyl gallate, precocenes , 6-hydroxy7-methoxy-2,2-dimethyl-l(2H)-benzopyran, 3,4-dihydro-6hydroxy-7-methoxy-2,2-dimethyl-l(2H)-benzopyran, benzamidine hydrochloride, the cysteine ​​proteinase inhibitors Netilmalemide and epsilon-amino-n-caproic acid from serine protease inhibitors: phenylmethylsulfonylfluoride, colhibin (Pentapharm company; INCI: hydrolyzed rice protein), enoterol (Soliance company; INCI: propylene glycol, water, root extract of Oenothera biennis, ellagic acid and ellagitannins, e.g. from pomegranate), phosphoramidone hinokitiol, EDTA, galardin, EquiStat (Collaborative Group company; apple extract, soybean extract, ursolic acid, soy isoflavones and soy protein), sage extracts, MDI (Atrium company; INCI: glycosaminoglycans), fermiskin (Silab / Mawi company; INCI: water and lentinus edodes extract), actimp 1.9.3 (Expanscience / Rahn company; INCI: hydrolyzed lupine protein), lipobelle soyaglycone (Mibelle company; INCI: alcohol, polysorbate 80, lecithin and soy isoflavones), green and black tea extracts and other plant extracts, which are listed in WO 02 069992 Al (see Tables 1-12 therein, incorporated herein by reference) , soybean proteins or glycoproteins, / zcznn / Lznz / E / Yii hydrolyzed proteins from rice, peas or lupins, extracts from plants that inhibit MMPs, preferably extracts from shitake mushrooms, extracts from leaves of the family Rosaceae, subfamily Rosoideae , very particularly blackberry leaf extracts (preferably as described in WO 2005 123101 Al, incorporated herein by reference) such as, for example, SymMatrix (Symrise company, INCI: Maltodextrin, Rubus Fruticosus leaf extract ( Blackberry)). Preferred actives are selected from the group consisting of retinyl palmitate, ursolic acid, extracts from the leaves of the Rosaceae family, Rosoideae subfamily, genistein and daidzein. Skin moisturizing agents. Preferred skin moisturizing agents are selected from the group consisting of alkane diols or alkane triols containing from 3 to 12 carbon atoms, preferably alkane diols-Cs-Cio and alkane triols-Cs-Cio More preferably, skin moisturizing agents from the skin are selected from the group consisting of: glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and 1,2-decanediol . Glycosaminoglycan stimulators. Preferred compositions comprise substances that stimulate the synthesis of / zcznn / Lznz / E / Yii glycosaminoglycans selected from the group consisting of hyaluronic acid and derivatives or salts, Subliskin (Sederma, INCI: Sinorhizobium meliloti yeast filtrate, cetylhydroxyethylcellulose, lecithin), Hyalufix (BASF, INCI: water, butylene glycol, Alpinia galanga leaf extract, xanthan gum, caprylic / capric triglyceride), Stimulhyal (Soliance, INCI: calcium ketogluconate), Syn-Glycan (DSM, INCI: tetradecyl aminobutyroylvalylaminobutyric urea trifluoroacetate , glycerin, magnesium chloride), Kalpariane (Biotech Marine), DC Upregulex (distinctive cosmetic ingredients, INCI: water, butylene glycol, phospholipids, hydrolyzed sericin), glucosamine, N-acetylglucosamine, retinoids, preferably retinol and vitamin A, fruit extract from Arctium lappa, Eriobotrya japonica extract, Genkwanin, N-methyl-Lserine, (-)-alpha-bisabolol or synthetic alpha-bisabolol such as Dragosantol and Dragosantol 100 from Symrise, oat glucan, Echinacea purpurea extract and soy protein hydrolyzate. Preferred actives are selected from the group consisting of hyaluronic acid and derivatives or salts, retinol and derivatives, (-)-alpha-bisabolol or synthetic alpha-bisabolol such as Dragosantol and Dragosantol 100 from Symrise, oat glucan, extract from Echinacea purpurea, Sinorhizobium meliloti ferment filtrate, calcium ketogluconate / zcznn / Lznz / E / Yii, Alpinia galanga leaf extract and tetradecyl aminobutyroylvalylaminobutyric urea trifluoroacetate. anti-inflammatory agents. The compositions may also contain anti-inflammatory and / or redness and / or itching ameliorating ingredients, in particular corticosteroid-type spheroidal substances selected from the group consisting of hydrocortisone, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone, are advantageously used as anti-inflammatory active substances or active substances to relieve redness and itching, the list of which can be extended by the addition of other steroidal anti-inflammatories. Non-steroidal anti-inflammatory drugs can also be used. Examples that can be cited herein are oxicams such as piroxicam or tenoxicam; salicylates such as aspirin, disalcid, solprin, or fendosal; acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin or clindanac; fenamates such as mefenamic, meclofenamic, flufenamic or niflumic; propionic acid derivatives such as ibuprofen, naproxen, benoxaprofen or pyrazoles such as phenylbutazone, oxyphenylbutazone, febrazone or azapropazone. Anthranilic acid derivatives, in particular the avenanthramides described in WO 2004 047833 Al, are preferred anti-itch ingredients / zcznn / Lznz / E / Yii in a composition according to the present invention. Also useful are natural or naturally occurring anti-inflammatory mixtures of substances or mixtures of substances that relieve redness and / or itching, in particular extracts or fractions of chamomile, Aloe vera, Commiphora species, Rubia species, willow, willow-herb , oats, calendula, arnica, St. John's wort, honeysuckle, rosemary, Passiflora incarnata, witch hazel, ginger or echinacea; preferably selected from the group consisting of extracts or fractions of chamomile, aloe vera, oats, calendula, arnica, honeysuckle, rosemary, witch hazel, ginger or echinacea, and / or pure substances, preferably alphabisabolol, apigenin, apigenin-7-glucoside, gingerols , shogaols, gingerdiols, dehydrogingerdiones, paradol, natural or naturally occurring avenanthramides, preferably tranilast, avenanthramide A, avenanthramide B, avenanthramide C, unnatural or naturally occurring avenanthramides, preferably dihydroavenanthramide D, dihydroavenanthramide E, avenanthramide D, avenanthramide E , avenanthramide F, boswellic acid, phytosterols, glycyrrhizin, glabridin and licochalcone A; preferably selected from the group consisting of alpha-bisabolol, natural avenanthramides, / zcznn / ίζηζ / Ε / γι unnatural avenanthramides, preferably dihydroavenanthramide D (as described in WO 2004 047833 Al), boswellic acid, phytosterols, glycyrrhizin and licochalcone A, and / or allantoin, panthenol, lanolin, (pseudo)ceramides [preferably ceramide 2, hydroxypropyl bispalmitamide MEA, cetyloxypropyl glyceryl methoxypropyl myristamide, N-(1-hexadecanoyl)-4-hydroxy-L-proline (1hexadecyl) ester, hydroxyethyl palmityl oxyhydroxypropyl palmitamide], glycosphingolipids, phytosterols, chitosan, mannose, lactose and β-glucans, in particular oat 1,3-1,4-p-glucan. TRPV1 antagonists. Suitable compounds that reduce the hypersensitivity of skin nerves based on their action as TRPV1 antagonists, comprise, for example, trans-4-tert-butyl cyclohexanol as described in WO 2009 087242 Al, or indirect modulators of TRPV1 via μ receptor activation, for example, acetyl tetrapeptide-15 are preferred. Botanical extracts. The compositions may also contain various plant extracts, such as Ginkgo hilaba extracts. Oleácea europensis, Glyzyrrhiza glabra, Vaccinium myrtillus, Trifolium pratense, Litchi sinensis, Vitis vinifera, Brassica oleracea, Punica granatum, Petroselinium crispum, Centella asiatica, Passí flora incarnata, Medicago sativa, Melissa officinalis, Valeriana officinalis, Castanea sativa, Salix alba and Hapagophytum procumbens. COOLING AGENTS The compositions may also contain one or more substances with a physiological cooling effect (cooling agents), which are hereby preferably selected from the following list: menthol and menthol derivatives (for example L-menthol, D-menthol, racemic menthol, isomenthol, neoisomenthol , neomenthol) menthyl ethers (for example (I-menthoxy)-1,2propanediol, (1-mentoxy)-2-methyl-1,2-propanediol, 1-menthylmethylether), menthyl esters (for example menthyl formate, menthyl, menthyl isobutyrate, menthyl lactates, L-menthyl-L-lactate, L-menthyl-D-lactate, menthyl-(2-methoxy)acetate, menthyl-(2-methoxyethoxy)acetate, menthylpyroglutamate), menthylcarbonates (for example, menthylpropylene glycol carbonate, methylene glycol carbonate, methyl glycerol carbonate or mixtures thereof), the half esters of menthol with a dicarboxylic acid or derivatives thereof (for example, mono-menthyl succinamate, mono-menthyl glutarate, mono-menthylmalonate, 0-menthyl acid ester succinico-N, N / zcznn / Lznz / E / Yii (dimethyl)amide, o-menthyl succinic acid ester amide), menthanecarboxylic acid amides (in this case preferably menthanecarboxylic acid-N-ethylamide [WS3] or N"-(menthanocarbonyl)glycinyl [WS5], as described in US 4,150,052, menthanecarboxylic acid-N-(4-cyanophenyl)amide or menthanecarboxylic acid-N-(4-cyanomethylphenyl)amide as described in WO 2005 049553 Al, methanecarboxylic acid-N(alkoxyalkyl)amides), menthone and menthone derivatives (for example, L-menthone glycerol ketal), 2,3-dimethyl-2-(2-propyl)-butyric acid derivatives (for example, N- 2,3-dimethyl-2-(2-propyl)-butyric acid methylamide [WS23]), isopulegol or its esters (I-(-)-isopulegol, I-(-)-isopulegolacetate), menthane derivatives (for example, p-menthano-3,8-diol), cubebol or synthetic or natural mixtures, containing cubebol, pyrrolidone derivatives of cycloalkyldione derivatives (for example, 3-methyl-2(1-pyrrolidinyl)-2-cyclopentene- 1-one) or tetrahydropyrimidin-2-one (eg icillin or related compounds, as described in WO 2004 / 026840), other carboxamides (eg N-(2-(pyridin2-yl)ethyl)- 3-p-menthanecarboxamide or related compounds), (IR,2S,5R)-N-(4-methoxyphenyl)-5-methyl-2-(1-isopropyl)cyclohexane-carboxamide [WS12], oxamates (preferably those described in document EP 2033688 A2). / zcznn / Lznz / E / Yii / zcznn / Lznz / E / YiA ANTIMICROBIAL AGENTS Suitable antimicrobial agents are, in principle, all substances effective against Gram-positive bacteria, such as 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N'-(3,4- dichlorophenyl)urea, 2,4,4'trichloro-2'-hydroxy-diphenyl ether (triclosan), 4-chloro-3,5dimethyl-phenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3methyl -4-(1-methylethyl)phenol, 2-benzyl-4-chloro-phenol, 3-(4-chlorophenoxy)-1,2-propanediol, 3-iodo-2-propynyl butylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), Antibacterial Fragrances, Thymol, Thyme Oil, Eugenol, Clove Oil, Menthol, Peppermint Oil, Farnesol, Phenoxyethanol, Glycerol Monocaprate, Glycerol Monocaprylate, Glycerol Monolaurate (GML), Diglycerol Monocaprate (DMC) , N-alkyl amides of salicylic acid, such as, for example, n-octylsalicylamide or n-decylsalicylamide. ENZYME INHIBITORS Suitable enzyme inhibitors are, for example, esterase inhibitors. These are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate and, in particular, triethyl citrate (Hydagen CAT). The substances inhibit enzymatic activity, thus reducing odor formation. Other substances suitable as esterase inhibitors are sterol sulfates or phosphates, such as for example lanosterol, cholesterol, campesterol, stigmasterol and sitosterol sulfate or phosphate, dicarboxylic acids and esters thereof, such as for example glutaric acid, glutarate monoethyl, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid and diethyl malonate, hydroxycarboxylic acids and esters thereof, such as, for example, citric acid, malic acid, tartaric acid or diethyl tartrate and zinc glycinate. ODOR ABSORBENTS AND ANTIPERSPIRANT ACTIVE AGENTS Suitable odor absorbers are substances that can absorb and retain odor-forming compounds to a large extent. They lower the partial pressure of the individual components, thereby also reducing their rate of diffusion. It is important that the perfumes are not altered in this process. Odor absorbers are not effective against bacteria. They comprise, for example, as the main component, a / zcznn / Lznz / E / Yii complex zinc salt of ricinoleic acid or specific fragrances, largely odorless, which are known to those skilled in the art as fixatives, such as eg extracts of labdanum or Styrax or certain derivatives of abietic acid. Odor masking agents are fragrances or perfume oils which, in addition to their function as odor masking agents, impart their respective fragrance note to deodorants. Perfume oils which may be mentioned are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers, stems and leaves, fruits, fruit peels, roots, woods, herbs and grasses, needles and branches, resins and balms. Products of animal origin are also suitable, such as, for example, civet and castoreum. Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. Ester-type fragrance compounds are, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styrelyl propionate and benzyl salicylate. . Ethers include, for example, benzyl ethyl ether, and aldehydes include, for example, the linear alkanals having 8 to 18 ato / zcznn / Lznz / E / Yii mos of carbon, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal, ketones include, for example, ionones and methyl cedryl ketone, alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linaol, phenylethyl alcohol and terpineol, and hydrocarbons mainly include terpenes and salves. However, the use of mixtures of different fragrances which together produce a pleasant fragrance note is preferred. Essential oils of relatively low volatility, which are mainly used as aromatic components, are also suitable as perfume oils, for example clary sage oil, chamomile oil, clove oil, lemon balm oil, peppermint oil, lemon leaf oil, cinnamon, linden blossom oil, juniper oil, vetiver oil, olibanum oil, galbanum oil, labdanum oil, and lavender oil. The use of bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, a-hexylcinnamaldehyde, geraniol, benzylacetone, cyclamen aldehyde, linalool, boisambrene forte, ambroxan, indole, hedione, sandelice, lemon oil, oil is preferred. Tangerine, Orange Oil, Allyl Amyl Glycolate, Cyclovertal, Lavender Oil, Sage Oil, β Damascone, Bourbon Geranium Oil, Ci / zcznn / Lznz / E / Yii Chlohexyl Salicylate, Vertofix coeur, iso-E-super, Fixolide NP, evernil, gamma iraldein, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, irotil, and floramat alone or in mixtures. Suitable astringent antiperspirant active ingredients are mainly aluminum, zirconium or zinc salts. Such suitable antihydrotic active ingredients are, for example, aluminum chloride, aluminum chlorohydrate, aluminum dichlorohydrate, aluminum sesguichlorohydrate and complexes thereof, for example with 1,2-propylene glycol, aluminum hydroxyallantoinate, aluminum chloride tartrate, trichlorohydrate. aluminum zirconium, aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate and complex compounds thereof, for example with amino acids such as glycine. FILM FORMERS AND ANTI-DANDRUFF AGENTS Standard film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, acrylic acid series polymers, quaternary cellulose derivatives, collagen, hyaluronic acid and its salts and compounds Similar. / zcznn / Lznz / E / Yii Suitable anti-dandruff agents are piroctone olamine (l-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), Baypival® (Climbazole), Ketoconazole® (4-acetyl -l-{4-[2-(2,4-dichlorophenyl) r-2-(IH-imidazol-lylmethyl)-1,3-dioxylan-c-4-ylmethoxyphenyl}-piperazine, ketoconazole, elubiol, selenium disulfide , colloidal sulfur, polyethylene glycol sorbitan sulfur monooleate, sulfur ricinol polyethoxylate, sulfur tar distillate, salicylic acid (or in combination with hexachlorophene), undecylenic acid, Na salt monoethanolamide sulfosuccinate, Lamepon® UD (protein / condensed undecylenic acid ), zinc pyrithione, aluminum pyrithione, and magnesium pyrithione / magnesium dipyrithione sulfate. CARRIERS AND HYDROTROPES Preferred cosmetic carrier materials are solid or liquid at 25°C and 1013 mbar (including highly viscous substances) such as glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1, 3-butylene glycol, ethanol, water and mixtures of two or more of said liquid carrier materials with water. Optionally, these preparations according to the invention can be produced by using preservatives or solubilizers. Other preferred liquid carrier substances, which can be a component of a preparation according to the invention, are selected from the group consisting of oils such as vegetable oil, neutral oil and mineral oil. Preferred solid carrier materials, which can be a component of a preparation according to the invention, are hydrocolloids, such as starches, degraded starches, chemically or physically modified starches, dextrins, maltodextrins (powdered) (preferably with a dextrose equivalent value of 5 to 25, preferably 10 - 20), lactose, silicon dioxide, glucose, modified celluloses, acacia gum, ghatti gum, tragus, karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar flour, flour carob, alginates, agar, pectin and inulin and mixtures of two or more of these solids, in particular maltodextrins (preferably with a dextrose equivalent value of 15-20), lactose, silicon dioxide and / or glucose. Furthermore, hydrotropes, eg ethanol, isopropyl alcohol or polyols, can be used to improve flow behaviour. Suitable polyols preferably contain from 2 to 15 carbon atoms and at least two hydroxyl groups. The polyols may contain other functional groups, plus / zeznn / Lznz / E / Yii especially amino groups, or they may be nitrogen-modified. Typical examples are • glycerol; • alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1000 Daltons; • technical oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10, such as technical diglycerol mixtures with a diglycerol content of 40 to 50% by weight; • methylol compounds such as, in particular, trimethylol ethane, trimethylol propane, trimethylol butane, pentaerythritol and dipentaerythritol; • lower alkyl glucosides, particularly those containing 1 to 8 carbon atoms in the alkyl group, eg methyl and butyl glucoside; • sugar alcohols containing 5 to 12 carbon atoms, eg sorbitol or mannitol, • sugars containing 5 to 12 carbon atoms, eg glucose or sucrose; / zcznn / ίζηζ / Ε / γι amino sugars, eg glucamine; dialcoholamines, such as diethanolamine or 2-aminopropane-1,3-diol. / zeznn / Lznz / E / YiAi PERFUME OILS AND FRAGRANCES Suitable perfume oils are mixtures of natural and synthetic perfumes. Natural perfumes include flower extracts (iris, lavender, rose, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, caraway, juniper), fruit peel (bergamot , lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus, iris, calmus), woods (pine, sandalwood, guaiac, cedar, rosewood), herbs and grasses (tarragon, entronella, sage, thyme ), needles and branches (spruce, fir, pine, pine), resins and balsams (galbanum, elemi, benzoin, myrrh, olibanum, opoponax). Animal raw materials, eg civet and beaver, can also be used. Typical synthetic perfume compounds are products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. Examples of ester type perfume compounds are benzyl acetate, phenoxyethyl isobutyrate, p-tert-butyl cyclohexylacetate, linalyl acetate, dimethylbenzylcarbinyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, ethylmethyl phenylglycinate , allyl cyclohexyl propionate, styrelyl propionate and benzyl salicylate. Ethers include, for example, benzyl ethyl ether, while aldehydes include, for example, the linear alkanals containing 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial, and bourgeonal. Examples of suitable ketones are ionones, isomethylionone and methyl cedryl ketone. Suitable alcohols are anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol. Hydrocarbons mainly include terpenes and balms. However, it is preferred to use mixtures of different perfume compounds which together produce a pleasant perfume. Other suitable perfume oils are the relatively low volatility essential oils that are used primarily as fragrance components. Some examples are clary sage oil, chamomile oil, clove oil, lemon balm oil, peppermint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil, labdanum oil and lavender oil. The following are preferably used singly / zcznn / Lznz / E / Yii dually or in the form of mixtures: bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, hexylcinnamaldehyde, geraniol, benzyl acetone, cyclamen aldehyde, linalool, Boisambrene Forte, Ambdelroxan, Indole, Hedione, Sandelice, Citrus Oil, Tangerine Oil, Orange Oil, Allyl Amyl Glycolate, Cyclovertal, Lavender Oil, Sage Oil, Damascone, Geranium Oil Bourbon, Cyclohexyl Salicylate, Vertofix Coeur, Iso-ESuper, Fixolide NP, evernil, gamma iraldein, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romillat, irotil, and floramat. / zcznn / Lznz / E / Yii dyes Suitable colorants are any of the substances suitable and approved for cosmetic purposes which are listed, for example, in the publication Kosmetische Fárbemittel of the Farbstoffkommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, pages 81 to 106. Examples include cochineal red A (C.I. 16255), patent blue V (C.I. 42051), indigotine (C.I. 73015), chlorophyllin (C.I. 75810), quinoline yellow (C.I. 47005), titanium dioxide (C.I. 77891), indanthrene blue RS (C.I. 69800) and the Madder Lake (C.I. 58000) . Luminol may also be present as a luminescent dye. Advantageous colored pigments are, for example, titanium dioxide, mica, iron oxides (for example Fe2O3 FesCg, FeO(OH)) and / or tin oxide. Advantageous dyes are, for example, carmine, Berlin blue, chromium oxide green, ultramarine blue and / or manganese violet. The preferred compositions according to the present invention are selected from the group of products for the treatment, protection, care and cleansing of the skin and / or hair or as a make-up product, preferably as a permanent product (that is, one or more compounds of the formula (I) remain on the skin and / or hair for a longer period of time, compared to rinse-off products, so that their moisturizing and / or anti-aging and / or wound healing-promoting action is more pronounced). The formulations according to the invention are preferably in the form of an emulsion, for example W / O (water in oil), O / W (oil in water), W / O / W (water in oil in water), emulsion O / W / O (oil in water-in-oil), BIT emulsion, Pickering emulsion, emulsion with low oil content, micro- or nanoemulsion, a solution e.g. in oil (fatty oils or fatty acid esters, in particular C2 esters / zcznn / Lznz / E / Yii Cso of C6-C32 fatty acids) or silicone oil, dispersion, suspension, cream, lotion or milk, depending on the production method and ingredients, a gel (including hydrogel, hydrodispersion gel, oleogel), spraying (for example, pump spray or propellant spray) or a foam or impregnating solution for cosmetic wipes, a detergent, eg soap, synthetic detergent, liquid wash, shower and bath preparation, bath product (capsule, oil , tablet, salt, bath salt, soap, etc.), effervescent preparation, a skin care product such as an emulsion (as described above), ointment, paste, gel (as described above ), oil, balm, serum, powder (such as face powder, body powder), a mask, pencil, stick, roll-on, pump, spray (foaming, non-foaming, or post-foaming), a deodorant, and / or antiperspirant , rinse and mouthwash, a foot care product (including keratolytics, deodorants), an insect repellent, a sunscreen, after-sun preparation, a shaving product, aftershave balm, lotion Before and after shave, a depilatory agent, a hair care product such as / zcznn / Lznz / E / Yii shampoo (includes 2-in-1 shampoo, anti-dandruff shampoo, baby shampoo, scalp shampoo shampoo concentrate), conditioner, hair tonic, hair water, hair rinse, styling cream, pomade, perm and setting lotion, hairspray, styling aid (such as gel or wax) , hair straightening agent (detangling agent, straightening agent), hair dye such as temporary direct dye hair dye, semi-permanent hair dye, permanent hair dye, hair conditioner, hair mousse, eye care product, make-up, make-up remover or baby product. The formulations according to the invention are particularly preferably in the form of an emulsion, in particular in the form of a W / O, O / W, W / O / W, O / W / O emulsion, PIT emulsion, Pickering emulsion, emulsion with a low oil content, micro or nanoemulsion, a gel (including hydrogel, hydrodispersion gel, oleogel), a solution e.g. in oil (fatty oils or fatty acid esters, in particular C2-C30 esters of C6-C32 fatty acids ) ) or silicone oil, or a spray (for example, pump spray or propellant spray). / zcznn / ίζηζ / Ε / γι Auxiliary substances and additives may be included in amounts of 5 to 99% by weight, preferably 10 to 80% by weight, based on the total weight of the formulation. The amounts of auxiliary agents and cosmetic or dermatological and perfume additives to be used in each case can be easily determined by a person skilled in the art by simple trial and error, depending on the nature of the particular product. The preparations can also contain water in an amount of up to 99% by weight, preferably 5 to 80% by weight, based on the total weight of the preparation. / zcznn / Lznz / E / Yii DETERGENT COMPOSITIONS Another embodiment of the present invention encompasses a detergent composition comprising an operative amount of at least one acetophenone derivative or its mixtures with additional preservatives and / or antimicrobial agents, which may be present in amounts from about 0.01 to about 10, preferably from about 0.05 to about 5 and more preferably from about 0.1 to about 1% by weight. - calculated on the total composition. Detergent compositions according to the present invention may comprise any of the ingredients commonly found in such compositions, such as, for example, anionic, nonionic, cationic, amphoteric or zwitterionic (co-)surfactants, organic solvents, builders, enzymes and additional auxiliaries such as dirt repellents, thickeners, colorants and fragrances or the like. ANIONIC CO-SURFACTANTS As anionic surfactants, surfactants of the sulfonate type, alk(en)yl sulfonates, alkoxylated alk(en)yl sulfates, ester sulfonates and / or soaps are preferably used. Suitable surfactants of the sulfonate type are advantageously C9-13 alkylbenzene sulfonates, olefin sulfonates, ie mixtures of alkene, and hydroxyalkane sulfonates and disulfonates, as obtained, for example, by gaseous sulfur trioxide sulfonation of C12-18 monoolefins. having a terminal or internal double bond and subsequent alkaline or acid hydrolysis of the sulfonation products. Ac(en)yl sulfates. Preferred ak(en)yl sulfates are the alkaline and especially the sodium salts of the sulfuric acid half esters of the C12 fatty alcohols / zcznn / Lznz / E / Yii Chalk, for example, from coconut butter alcohol, tallow alcohol, lauryl, myristyl, cetyl or stearyl alcohol or from C8-C20 oxo alcohols and the half esters of secondary alcohols of these chain lengths. Also preferred are alk(en)yl sulfates of the recited chain lengths which comprise a straight chain synthetic alkyl group made petrochemically. C12-C16 alkyl sulfates and C12-C15 alkyl sulfates as well as C14-C15 alkyl sulfates and C14-C16 alkyl sulfates are particularly preferred for reasons of washing performance. 2,3-Alkyl sulfates, available from Shell Oil Company under the trade name DAN™, are also suitable anionic surfactants. Aqu(en)yl ether sulfates. Sulfuric acid monoesters derived from straight or branched chain C7-C21 alcohols ethoxylated with 1 to 6 moles of ethylene oxide are also suitable, such as 2-methyl branched C9-C11 alcohols with an average of 3.5 moles of ethylene oxide (EO) or C12-C18 fatty alcohols with 1 to 4 EO. Ester sulfonates. Also suitable are alpha-sulfo fatty acid esters (ester sulfonates), for example, the alpha-sulfonated methyl esters of hydrogenated coconut, / zeznn / Lznz / E / Yii palm kernel or tallow acids. soaps. Soaps, in particular, can be considered as other anionic surfactants. Saturated fatty acid soaps are particularly suitable, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, and especially soap mixtures derived from natural fatty acids such as fatty acid coconut oil, fatty acid, palm kernel oil fatty acid or tallow fatty acid. Particularly preferred are those soap mixtures which consist of 50 to 100% by weight of saturated C12-C24 fatty acid soaps and 0 to 50% by weight of oleic acid soap. ether carboxylic acids. Another class of anionic surfactants is the ether carboxylic acids, which can be obtained by treating fatty alcohol ethoxylates with sodium chloroacetate in the presence of basic catalysts. They have the general formula: RO (CH2CH2O)PCH2COOH with R = Ci-Cie and p = 0.1 to 20. Ether carboxylic acids are insensitive to water hardness and have excellent surfactant properties. / zcznn / ίζηζ / Ε / γι (CO)NON-IONIC SURFACTANTS Alkoxylated alcohols. The added nonionic surfactants are preferably alkoxylated and / or propoxylated, particularly primary alcohols preferably having 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of of propylene oxide (PO) per mole of alcohol. In particular, Cs-Cis alkoxylated alcohols are preferred, advantageously ethoxylated and / or propoxylated C10-C15 alkoxylated alcohols, in particular C12-C14 alkoxylated alcohols, with a degree of ethoxylation between 2 and 10, preferably between 3 and 8 and / or a degree of propoxylation between 1 and 6, preferably between 1.5 and 5. The degrees of ethoxylation and propoxylation quoted are statistical mean values ​​which may be an integer or fractional number for a specific product. Preferred alcohol ethoxylates and propoxylates have a narrow homolog distribution (narrow range ethoxylates / propoxylates, NRE / NRP). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples of these are fatty alcohols (tallow) with 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO. Alkyl glycosides (APG®). Furthermore, as additional nonionic surfactants, alkyl glycosides complying with the general formula RO(G)X can be added, for example, as compounds, particularly with anionic surfactants, where R stands for a linear or branched primary aliphatic group / zcznn / Lznz / E / Yii do with methyl, particularly branched with 2-methyl containing 8 to 22, preferably 12 to 18 carbon atoms and G represents a glycose unit containing 5 or 6 carbon atoms, preferably glucose. The degree of oligomerization x, which defines the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10, preferably between 1.1 and 1.4. Fatty acid ester alkoxylates. Another class of preferred nonionic surfactants, which are used as the sole nonionic surfactant or in combination with other nonionic surfactants, in particular together with alkoxylated fatty alcohols and / or alkyl glycosides, are alkoxylated, preferably ethoxylated or alkyl esters of ethoxylated and propoxylated fatty acids preferably containing 1 to 4 carbon atoms in the alkyl chain, more particularly the fatty acid methyl esters described, for example, in Japanese Patent Application JP-A-58 / 217598 or which are preferably produced by the process described in the international patent application WO-A-90 / 13533. In particular, C12-C18 fatty acid methyl esters containing an average of 3 to 15 EO are preferred, in particular containing an average of 5 a / zcznn / Lznz / E / Yii EO. amine oxides. Nonionic surfactants of the amine oxide type may also be suitable, for example N-coco alkyl-N,N-dimethylamine oxide and N-tallow N-alkyl-N,N-dihydroxyethylamine oxide, and alkanolamides of qrasos. The amount in which these nonionic surfactants are used is preferably not more than the amount in which the ethoxylated fatty alcohols are used, and in particular, it is not more than half of said amount. Gemini surfactants. The so-called gemini surfactants can be considered other surfactants. In general, such compounds are understood to mean compounds having two hydrophilic groups and two hydrophobic groups per molecule. As a rule, these groups are separated from each other by a spacer. The spacer is normally a hydrocarbon chain that is intended to be long enough so that the hydrophilic groups are far enough apart to be able to act independently of each other. These types of surfactants are generally characterized by an unusually low critical micelle concentration and the ability to strongly reduce the surface tension of water. However, in rare cases, the term gemini surfactant refers not only to dimeric surfactants, but also to trimeric ones. Suitable surfactants / zcznn / Lznz / E / Yii gemini are, for example, sulfated hydroxy mixed ethers according to German patent application DE 4321022 Al or dimer and bis- and trimer alcohol trisulfates and ether sulfates according to application International patent application WO 96 / 23768 Al. The dimeric and trimeric mixed ethers of end groups reported according to the German patent application DE 19513391 Al are characterized in particular by their bifunctionality and multifunctionality. Gemini polyhydroxy fatty acid amides or polyhydroxy fatty acid amides may also be used, such as those described in the international patent applications WO 95 / 19953 Al, WO 95 / 19954 Al and WO 95 / 19955 Al. / zcznn / Lznz / E / Yii (CO)CATIONIC SURFACTANTS Tetraalkyl ammonium salts. Cationically active surfactants comprise the high molecular weight hydrophobic group necessary for surface activity on the cation upon dissociation in aqueous solution. A group of important representatives of cationic surfactants are tetraalkyl ammonium salts of the general formula: (R1R2R3R4N+)X“. Here R1 represents alk(en)yl Ci-Cs, R2, R3 and R4, independently of each other, for alk(en)yl radicals having 1 to 22 carbon atoms. X is a counterion, preferably selected from the group of halides, alkyl sulfates and alkyl carbonates. Cationic surfactants are particularly preferred, wherein the nitrogen group is substituted with two long acyl groups and two short alk(en)yl groups. esterquats. Another class of cationic surfactants particularly useful as cosurfactants for the present invention is represented by the so-called esterquats. Esterquats are generally understood to be salts of quaternized fatty acid triethanolamine esters. They are known compounds that can be obtained by the relevant methods of preparative organic chemistry. In this sense, reference is made to the international patent application WO 91 / 01295 Al, according to which triethanolamine is partially esterified with fatty acids in the presence of hypophosphorous acid, air is passed through the reaction mixture and then it is quaternize the whole with dimethyl sulfate or ethylene oxide. Furthermore, German patent DE 4308794 C1 describes a process for the production of solid esterquats in which the quaternization of triethanolamine esters is carried out in the presence of suitable dispersants, preferably fatty alcohols. Typical examples of esterquats suitable for use according to the invention are products in which the acyl component is derived / zcznn / Lznz / E / Yii from monocarboxylic acids of the formula RCOOH where RCO is an acyl group containing 6 to 10 carbon atoms. carbon and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and technical mixtures thereof such as, for example, the so-called head fractionated fatty acid. Preferably, esterquats are used whose acyl component is derived from monocarboxylic acids containing 8 to 10 carbon atoms. Other esterquats are those whose acyl component is derived from dicarboxylic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. In general, esterquats whose acyl component is derived from mixtures of monocarboxylic acids containing 6 to 22 carbon atoms and adipic acid are preferably used. The molar ratio of mono and dicarboxylic acids in the final esterquat may be in the range of 1:99 to 99:1 and preferably in the range of 50:50 to 90:10 and more particularly in the range of 70:30 to 80 :twenty. In addition to the quaternized fatty acid triethanolamine ester salts, other suitable esterquats are the quaternized ester salts of / zcznn / Lznz / E / Yii mono / dicarboxylic acid mixtures with diethanolalkylamines or 1,2-dihydroxypropyl dialkylamines. Esterquats can be obtained both from fatty acids and from the corresponding triglycerides mixed with the corresponding dicarboxylic acids. Such a process is proposed in European patent EP 0750606 B1, which is intended to be representative of the relevant prior art. To produce the quaternized esters, mixtures of mono- and dicarboxylic acids and triethanolamine, based on available carboxyl functions, can be used in a 1.1:1 to 3:1 molar ratio. Taking into account the performance properties of esterquats, a ratio of 1.2:1 to 2.2:1 and preferably 1.5:1 to 1.9:1 has proven to be particularly advantageous. Preferred esterquats are technical mixtures of mono-, di-, and triesters with an average degree of esterification of 1.5 to 1.9. / zcznn / Lznz / E / Yii AMPHOTERIC OR ZWITTERIONIC CO-SURFACTANTS Betaines. Amphoteric or ampholytic surfactants possess a plurality of functional groups that can ionize in aqueous solution and therefore, depending on the environmental conditions, give the compounds an anionic or cationic character (see DIN 53900, July 1972). Near the isoelectric point (around pH 4), amphoteric surfactants form internal salts, thus becoming poorly soluble or insoluble in water. Amphoteric surfactants are subdivided into ampholytes and betaines, the latter existing as zwitterions in solution. Ampholytes are amphoteric electrolytes, that is, compounds that possess both acidic and basic hydrophilic groups and therefore behave either as acids or as bases depending on the conditions. Betaines in particular are known surfactants which are mainly produced by carboxyalkylation, preferably carboxymethylation, of amine compounds. The starting materials are preferably condensed with halocarboxylic acids or their salts, more particularly sodium chloroacetate, forming one mole of salt per mole of betaine. The addition of unsaturated carboxylic acids, such as acrylic acid, is also possible. Examples of suitable betaines are the carboxyalkylation products of secondary and, in particular, tertiary amines corresponding to the formula R1R2R3N-(CH2)qCOOX where R1 is an alkyl radical having from 6 to 22 carbon atoms, R2 is hydrogen or an alkyl group. containing 1 to 4 carbon atoms, R3 is an alkyl group containing 1 to 4 carbon atoms, q is a number from 1 to 6, and X is an alkali and / or alkaline earth metal or ammonium. Typical examples / zcznn / Lznz / E / Yii are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, C12 / 14 coconutalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethylamine, oleyldimethylamine, Cig / is tallow alkyldimethylamine and technical mixtures thereof, and in particular dodecyl methylamine, dodecyl dimethylamine, dodecyl ethylmethylamine and their technical mixtures. Alkylamido betaines. Other suitable betaines are the carboxyalkylation products of amidoamines corresponding to the formula R1CO (R3) (R4)-NH-(CH2)P-N-(CH2) qCOOX where R^O is an aliphatic acyl radical having 6 to 22 atoms carbon and 0 or 1 to 3 double bonds, R2 is hydrogen or an alkyl radical having 1 to 4 carbon atoms, R3 is an alkyl radical having 1 to 4 carbon atoms, p is a number from 1 to 6 , q is a number from 1 to 3 and X is an alkali and / or alkaline earth metal or ammonium. Typical examples are reaction products of fatty acids having 6 to 22 carbon atoms, such as caproic acid, caprylic acid, caprinic acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linolic acid, linoleic acid, elaeostearic acid, arachidonic acid, gadoleic acid, behenic acid, erucic acid / zcznn / Lznz / E / Yii and their technical mixtures with N,N-dimethylaminoethylamine, N,N -dimethylaminopropylamine, N,N-diethylaminoethylamine and N,N-diethylaminopropylamine, which are condensed with sodium chloroacetate. Commercially available products include Dehyton® K and Dehyton® PK (Cognis Deutschland GmbH & Co., KG), as well as Tego® Betaine (Goldschmidt). Imidazolines. Other suitable starting materials for betaines to be used for the purposes of the invention are imidazolines. These substances are also known and can be obtained, for example, by the cyclic condensation of 1 or 2 mol of Ce~C22 fatty acids with polyfunctional amines, such as aminoethylethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are the condensation products of the above-mentioned fatty acids with AEEA, preferably lauric acid-based imidazolines, which are subsequently betainized with sodium chloroacetate. Commercially available products include Dehyton® G (Cognis Deutschland GmbH & Co., KG) The amount of (co-)surfactant included in the compositions of the invention is advantageously from 0.1% by weight to 90% by weight, in particular from 10% by weight to 80% by weight and with particular preference from 20 % by weight / zcznn / Lznz / E / Yii at 70% by weight. ORGANIC SOLVENT Light or heavy liquid detergents may comprise organic solvents, preferably those that are miscible with water. As organic solvent, polydiols, ethers, alcohols, ketones, amides and / or esters are preferably used as organic solvent in amounts of 0 to 90% by weight, preferably 0.1 to 70% by weight, in particular 0.1 to 60%. Low molecular weight polar substances are preferred, such as, for example, methanol, ethanol, propylene carbonate, acetone, acetonylacetone, diacetone alcohol, ethyl acetate, 2-propanol, ethylene glycol, propylene glycol, glycerin, diethylene glycol, dipropylene glycol monomethyl ether and dimethylformamide. or their mixtures. ENZYMES Suitable enzymes include, in particular, those of the classes of hydrolases, such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases, and mixtures thereof. In the wash, all these hydrolases help to eliminate stains such as protein, fat or starch and against the formation of grey. In addition, cellulases and other glycosyl hydrolases can contribute to fabric softness and color retention by eliminating pilling and microfibrils. Oxidoreductases can also be added to bleaches or to inhibit color transfer. Enzyme active materials obtained from bacterial or fungal sources such as bacillus subtilis, bacillus licheniformis, streptomyceus griseus and humicola insolens are particularly suitable. Preferably, proteases of the subtilisin type are used and in particular proteases obtained from bacillus lentus. Here, enzyme mixtures are of particular interest, for example, proteases and amylases or proteases and lipases or lipolytic enzymes or proteases and cellulases or cellulases and lipase or lipolytic enzymes or proteases, amylases and lipases or lipolytic enzymes or proteases, lipases or enzymes lipolytic and cellulases, in particular, however, proteases and / or lipase-containing mixtures or mixtures with lipolytic enzymes. Examples of such lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proven to be suitable in certain cases. Suitable amylases particularly include a-amylases, iso-amylases, / zcznn / Lznz / E / Yii pullulanases and pectinases. Cellobiohydrolases, endoglucanases and beta-glucosidases or mixtures thereof, which are also known as cellobiases, are preferred cellulases. As different cellulase types differ in their CMCase and avicelase activities, the required activities can be adjusted by controlled mixtures of cellulases. The content of enzymes or enzyme mixtures can be, for example, from about 0.1 to 5% by weight and preferably from 0.1 to about 3% by weight. / zcznn / Lznz / E / Yii ADJUVANTS Zeolites. As adjuvants, synthetic, fine crystalline zeolites containing bound water can be used, for example, preferably zeolite A and / or P. Zeolite MAP.RTM. (commercial product of the Crosfield company) is particularly preferred as zeolite P. However, zeolite X and mixtures of A, X, Y and / or P are also suitable. A sodium / potassium aluminum silicate cocrystallized from Zeolite A and Zeolite X, which is available as Vegobond® RX. (commercial product of Condea Augusta S.p.A.), is also of particular interest. Preferably, the zeolite can be used as a spray dried powder. If the zeolite is added as a slurry, it may comprise small amounts of nonionic surfactants as stabilizers, for example 1 to 3% by weight, based on zeolite, of 2-ethoxylated C12-C18 fatty alcohols. with 5 ethylene oxide groups, C12-C14 fatty alcohols with 4 to 5 ethylene oxide groups or ethoxylated isotridecanols. Suitable zeolites have a mean particle size of less than 10 pm (test method: volumetric Coulter counter) and preferably comprise 18 to 22% by weight, particularly 20 to 22% by weight of bound water. Apart from this, phosphates can also be used as builders. layered silicates. Suitable substitutes or partial substitutes for phosphates and zeolites are crystalline layered sodium silicates. These types of crystalline layered silicates are described, for example, in the European patent application EP 0164514 Al. Preferred crystalline layered silicates are those obtained, for example, from the process described in the international patent application WO 91 / 08171 Al . amorphous silicates. Preferred builders also include amorphous sodium silicates with a modulus (Na2O:SiO2 ratio) of 1:2 to 1:3.3, preferably 1:2 to 1:2.8 and more preferably 1:2 to 1:2, 6, which dissolve with a delay and exhibit multiple wash cycle properties. The delay in / zcznn / Lznz / E / Yii dissolution compared to conventional amorphous sodium silicates could have been obtained in a number of ways, eg by surface treatment, blending, compression / compaction or excessive drying. In the context of this invention, the term amorphous also means X-ray amorphous. In other words, silicates do not produce any of the sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but rather, at best, one or more maxima of the scattered X-radiation, having a width of several degrees of the diffraction angle. However, particularly good reinforcing properties can even be achieved when the silicate particles produce indistinct or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions between 10 and a few hundred nm in size, with values ​​up to 50 nm at most and especially up to 20 nm being preferred. Amorphous X-ray silicates of this type, which also dissolve retarded compared to conventional water glass, are described, for example, in the German patent application DE 4400024 Al. Compacted / densified amorphous silicates are particularly preferred. Silicates / zcznn / ίζηζ / Ε / γι amorphous compounds and the amorphous silicates on dry X-rays. Phosphates. In addition, the generally known phosphates can also be added as builders, insofar as their use is not to be avoided for ecological reasons. The sodium salts of orthophosphates, pyrophosphates and especially tripolyphosphates are particularly suitable. Generally, its content does not exceed 25% by weight, preferably not more than 20% by weight, each based on the final composition. In some cases it has been shown that tripolyphosphates in particular, already in low amounts up to a maximum of 10% by weight, based on the finished composition, in combination with other builders, leads to a synergistic improvement of the secondary cleaning power. Preferred amounts of phosphates are below 10% by weight, particularly 0% by weight. / zcznn / Lznz / E / Yii ADJUVANTS Polycarboxylic acids. Useful organic builders are, for example, the polycarboxylic acids usable in the form of their polycarboxylic acid sodium salts, wherein the 100 polycarboxylic acids are carboxylic acids that carry more than one acid function. They include, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA) and its derivatives and mixtures thereof. Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids, and mixtures thereof. Organic acids. Acids per se can also be used. In addition to their building effect, acids generally also have the property of an acidifying component and therefore also serve to establish a relatively low and mild pH in detergents or cleaning compositions. In this connection, citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any mixture thereof are particularly mentioned. Other suitable acidifiers are known pH adjusters such as sodium hydrogen carbonate and sodium hydrogen sulphate. polymers. Particularly suitable polymeric builders are polyacrylates, which preferably have a molecular weight of 2,000 to 20,000 g / mol. By virtue of his solu / zeznn / Lznz / E / Yii 101 higher stability, preferred representatives of this group are again the short-chain polyacrylates, which have molecular weights of 2,000 to 10,000 g / mol and, more particularly, 3,000 to 5,000 g / mol. Suitable polymers can also include substances that consist, in part or in full, of vinyl alcohol units or their derivatives. Other suitable copolymeric polycarboxylates are in particular those of aculic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid. Copolymers of acrylic acid with maleic acid, comprising 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid, have proven to be particularly suitable. Their relative molecular weight, on a free acid basis, generally ranges from 2,000 to 70,000 g / mol, preferably from 20,000 to 50,000 g / mol and especially from 30,000 to 40,000 g / mol. The (co)polymeric polycarboxylates can be added as an aqueous solution or preferably as a powder. To improve water solubility, the polymers can also comprise allylsulfonic acids as monomers, such as, for example, allyloxybenzenesulfonic acid and methallylsulfo / zcznn / Lznz / E / Yiinic acid as in EP 0727448 B1. 102 Biodegradable polymers comprising more than two different monomeric units are especially preferred, for example those comprising, as monomers, salts of acrylic acid and maleic acid, and also vinyl alcohol or vinyl alcohol derivatives, as in DE 4300772 Al , or those comprising, as monomers, salts of acrylic acid and of 2-alkylallyl sulfonic acid, as well as sugar derivatives. Other preferred copolymers are those described in German patent applications DE 4303320 Al and DE 4417734 Al and preferably include acrolein and acrylic acid / acrylic acid salts or acrolein and vinyl acetate as monomers. Similarly, other preferred builders are polymeric aminodicarboxylic acids, salts or precursors thereof. In particular, those polyaspartic acids or their salts and derivatives disclosed in the German patent application DE 19540086 Al which have a bleach stabilizing action in addition to "builder" properties are preferred. Other suitable adjuvants are polyacetals which can be obtained by treating dialdehydes with polyol carboxylic acids having 5 to 7 carbon atoms and at least 3 hydroxyl groups, as described in the European patent application EP / zcznn / Lznz / E / Yii 103 0280223 Al. Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and their mixtures and from polycarboxylic acids such as gluconic acid and / or glucoheptonic acid. carbs. Other suitable organic builders are dextrins, for example carbohydrate oligomers or polymers obtainable by partial hydrolysis of starches. Hydrolysis can be carried out using typical processes, eg, acid or enzyme catalyzed processes. The hydrolysis products preferably have average molecular weights in the range of 400 to 500,000 g / mol. A polysaccharide with a dextrose equivalent (DE) of 0.5 to 40 and more particularly 2 to 30 is preferred, DE is an accepted measure of the reducing effect of a polysaccharide compared to dextrose, which has a DE of 100. Both maltodextrins with a DE between 3 and 20 and dry glucose syrups with a DE between 20 and 37 and also so-called yellow dextrins and white dextrins with relatively high molecular weights of 2,000 to 30,000 g / mol can be used. A preferred dextrin is described in British Patent Application 94 19 091. The oxidized derivatives of such dextrins refer to their reaction products with oxidizing compositions that are ca / zcznn / Lznz / E / Yii 104 paces of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function. Such oxidized dextrins and processes for their manufacture are known, for example, from European patent applications EP 0232202 Al. A C6-oxidized product of the saccharide ring can be particularly advantageous. Other suitable builders are oxydisuccinates and other derivatives of disuccinates, preferably ethylenediamine disuccinate. Here, ethylenediamine-N,N'-disuccinamate (EDDS), the synthesis of which is described, for example, in US Pat. No. 3,158,615, is preferably used in the form of its sodium or magnesium salts. In this context, glycerol disuccinates and glycerol trisuccinates are also particularly preferred, such as those described in US 4,524,009. Suitable addition amounts in formulations containing zeolite and / or silicate range from 3 to 15% by weight. lactones. Other useful organic builders are, for example, acetylated hydroxycarboxylic acids and salts thereof which may optionally also be present in the lactone form and contain at least 4 carbon atoms, at least one hydroxyl group and at least two aci / zeznn groups. / Lznz / E / Yii 105 two. Such adjuvants are described, for example, in so / zcznn / Lznz / E / Yii international patent application WO 95 / 20029 Al. DIRT REPELLENTS In addition, the compositions can also comprise components that positively influence the removal of oils and fats from fabrics during washing (so-called dirt repellents). This effect is particularly noticeable when a fabric is dirty and has already been washed several times with a detergent of the invention comprising this oil or grease removal component. Preferred oil and grease removal components include, for example, nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose with a methoxy group content of 15 to 30% by weight and hydroxypropoxy group content of 1 to 15% by weight, each one based on nonionic cellulose ether, as well as polymers of phthalic acid and / or terephthalic acid or their derivatives known from the state of the art, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionic and / or modified derivatives or non-ionically thereof. Of these, the sulfonated derivatives of phthalic acid polymers and terephthalic acid polymers are especially preferred. / zcznn / Lznz / E / YiA 106 INORGANIC SALTS Other suitable ingredients of the composition are water-soluble inorganic salts such as bicarbonates, carbonates, amorphous silicates or mixtures thereof; Alkali carbonate and amorphous silicate, especially sodium silicate with a Na2O:SiO2 molar ratio of 1:1 to 1:4.5, preferably 1:2 to 1:3.5, are used in particular. Preferred compositions comprise alkaline salts, builders and / or builders, preferably sodium carbonate, zeolite, crystalline, layered sodium silicates and / or trisodium citrate, in amounts of 0.5 to 70% by weight, preferably 0.5 to 50%. by weight, in particular from 0.5 to 30% by weight of anhydrous substance. FOAM INHIBITORS Especially when used in automatic washing processes, it can be advantageous to add conventional suds inhibitors to the compositions. Suitable suds inhibitors include, for example, soaps of natural or synthetic origin, which are high in C18-C24 fatty acids. Suitable types of non-surface active foam inhibitors are, for example, organopolysiloxanes and mixtures thereof with microfine silica, optionally silanized and 107 also paraffins, waxes, microcrystalline waxes and mixtures thereof with silanized silica or bis-stearylethylenediamide. Mixtures of various foam inhibitors, for example mixtures of silicones, paraffins or waxes, are also advantageously used. Preferably, the suds inhibitors, especially silicone- and / or paraffin-containing suds inhibitors, are loaded onto a granular, water-soluble or dispersible carrier material. Especially in this case, mixtures of paraffins and bis-tear diamides are preferred. CHELATING AGENTS Polyphosphonic acid salts can be considered chelating or stabilizing agents, particularly for peroxy compounds and enzymes, which are sensitive to heavy metal ions. In this case, the sodium salts of, for example, 1-hydroxyethane-1,1-diphosphonate, diethylenetriaminepentamethylenephosphonate or ethylenediaminetetramethylenephosphonate are used in amounts of 0.1 to 5% by weight. INHIBITORS OF THE FORMATION OF GRAYS 108 The graying inhibitors have the function of keeping the dirt that has been removed from the fibers suspended in the washing liquid, thus preventing the dirt from re-settling. Water-soluble colloids of a predominantly organic nature are suitable for this, for example the water-soluble salts of (co)polymeric carboxylic acids, glue, gelatins, salts of ether carboxylic acids or ether sulfonic acids of starches or celluloses, or salts of acid esters of sulfuric acid from celluloses or starches. Water-soluble polyamides containing acid groups are also suitable for this purpose. In addition, soluble starch preparations and others can be used as the aforementioned starch products, for example, degraded starches, aldehyde starches, etc. Polyvinylpyrrolidone can also be used. However, the use of cellulose ethers such as carboxymethyl cellulose (Na salt), methyl cellulose, hydroxyalkyl celluloses and mixed ethers such as methyl hydroxyethyl cellulose, methyl hydroxypropyl cellulose, methyl carboxymethyl cellulose and mixtures thereof, as well as polyvinyl pyrrolidone, which can be added, by example, in amounts of 0.1 to 5% by weight, based on the / zcznn / Lznz / E / Yii composition. 109 OPTICAL BRIGHTENSERS AND UV ABSORBERS The compositions may comprise, for example, diaminostilbenedisulfonic acid derivatives or alkali metal salts thereof as optical brighteners. Suitable optical brighteners are, for example, salts of 4,4'-bis(2-anilino-4-morpholino-1,3,5-triazinyl-6-amino)stilben-2,2'disulfonic acid or compounds of similar structure containing a diethanolamino group, a methylamino group, an anilino group or a 2-methoxyethylamino group instead of the morpholino group. Brighteners of the substituted diphenylstyrile type may also be present, for example the alkali metal salts of 4,4'-bis(2-sulfostyryl)diphenyl, 4,4'-bis(4-chloro3-sulfostyryl)diphenyl or 4-( 4-chlorostyryl)-4'-(2sulfostyryl)diphenyl. Mixtures of the mentioned rinse aids can also be used. In addition, UV absorbers can also be added. They are compounds with different ultraviolet radiation absorption capacities, which contribute as UV stabilizers as well as to improve the light stability of dyes and pigments, both for textile fibers and for the skin of the user of textile products, protecting it from UV radiation that penetrates the fabric. In general, desac / zcznn / Lznz / E / Yii activator compounds effective without radiation are derivatives of benzophene. 110 na, substituted with hydroxyl and / or alkoxy groups, mainly at position(s) 2 and / or 4. Substituted benzotriazoles are also suitable, additionally 3-substituted phenyl acrylates (derived from cinnamic acid), optionally with cyano groups in position 2, salicylates, organic Ni complexes, as well as natural substances such as umbelliferone and endogenous urocanic acid. In a preferred embodiment, the UV absorbers absorb UV-A and UV-B radiation as well as possible UV-C radiation and re-emit light with blue wavelengths, so that they also have an optical brilliance effect. Preferred UV absorbers include triazine derivatives, for example, hydroxyaryl-1,3,5-triazine, sulfonated 1,3,5-triazine, o-hydroxyphenylbenzotriazole and 2-aryl-2H-benzotriazole, as well as bis(anilinotriazinyl-amino )disulfonic stilbene and its derivatives. Ultraviolet absorbing pigments such as titanium dioxide can also be used as UV absorbers / zcznn / ίζηζ / Ε / γι tes. 111 THICKENERS The compositions may also comprise common thickeners and anti-deposition compositions as well as viscosity regulators such as polyacrylates, polycarboxylic acids, polysaccharides and their derivatives, polyurethanes, polyvinylpyrrolidones, castor oil derivatives, polyamine derivatives such as quaternized and / or ethoxylated hexamethylenediamines as well as mixtures thereof. Preferred compositions have a viscosity of less than 10,000 mPa*s, measured with a Brookfield viscometer at a temperature of 20°C and a shear rate of 50 min-1. PERFUMES AND DYES The compositions may comprise other typical detergent and cleaning composition ingredients, such as perfumes and / or dyes, where it is preferred that such dyes leave no or negligible staining on fabrics being washed. Preferred amounts of all added colorants are below 1% by weight, preferably below 0.1% by weight, based on the composition. The compositions may also comprise white pigments such as TIO2. / zeznn / ίζηζ / Ε / γι / zcznn / Lznz / E / YiA 112 FOOD COMPOSITIONS Another embodiment of the present invention encompasses a food composition comprising an operative amount of at least one acetophenone derivative or its mixtures with additional preservatives and / or antimicrobial agents, which may be present in amounts of from about 0.01 to about 10 , preferably from about 0.05 to about 5 and more preferably from about 0.1 to about 1% by weight. - calculated on the total composition. Food compositions according to the invention are all preparations or compositions that are suitable for consumption and are used for nutrition or enjoyment purposes, and are generally products that are intended to be introduced into the human or animal oral cavity to remain there for a period of time. certain time and then able to be eaten (eg ready-to-eat food or food products, see also herein below) or withdrawn from the oral cavity again (eg chewing gum). Such products include substances or products that in a processed, partially processed or unprocessed state will be ingested by humans or animals. They also include substances that 113 are added to orally consumable products during their manufacturing, preparation or treatment and which are intended to be introduced into the human or animal oral cavity. Food compositions according to the invention also include substances which in the unmodified, treated or prepared state are to be ingested by a human or animal and then digested; in that sense, orally consumable products according to the invention also include casings, coatings or other encapsulations that must be swallowed at the same time or are expected to be ingested. The term orally consumable product comprises ready-to-eat foods or foodstuffs, ie foodstuffs or foods that are already complete in terms of substances that are important for taste. The terms ready-to-eat food products and ready-to-eat food also include beverages, as well as ready-to-eat solid or semi-solid food or food products. Examples that can be mentioned are frozen products, which must be thawed and warmed up to serving temperature before consumption. Products such as yogurt or ice cream, as well as chewing gum or hard candies / zcznn / Lznz / E / Yii 114 are also included among food products or ready-to-eat foods. Preferred food compositions according to the invention also include semi-finished products. In the context of the present text, a semi-finished product is to be understood as an orally consumable product which, due to a very high content of flavorings and flavor-imparting substances, is not suitable for use as a ready-to-eat orally consumable product. consumption (especially food products or food). Only by mixing with at least one additional component (for example, by reducing the concentration of flavorings and flavor-imparting substances in question) and, optionally, other process steps (for example, heating, freezing) does the semi-finished product become converted into a ready-to-consume orally consumable product (particularly foodstuffs or food). Examples of semi-finished products that can be mentioned herein are A food composition according to the invention preferably comprises one or more preparations for nutrition or enjoyment purposes. These include, in particular, (reduced calorie) baked goods (for example, bread, dry biscuits, cakes, other baked goods), re / zcznn / Lznz / E / Yii products 115 confectionery (for example, chocolates, chocolate bars, other bar-shaped products, fruit gums, sprinkles, hard and soft candies, chewing gums), non-alcoholic beverages (for example, cocoa, coffee, green tea, tea black, (green, black tea), tea drinks (green, black) fortified with extracts of tea (green, black), rooibos tea, other herbal teas, soft drinks containing fruit, isotonic drinks, soft drinks, nectars, juices fruit and vegetable juice preparations, fruit or vegetable juice preparations), instant drinks (for example, instant cocoa drinks, instant tea drinks, instant coffee drinks), meat products (for example, ham, fresh sausages or meat preparations). raw sausages, fresh or salted, seasoned or marinated meat products), eggs or egg-based products (dried egg, egg white, egg yolk), cereal products (for example, breakfast cereals, muesli bars , pre-cooked and ready-to-eat rice products), dairy products (for example, full-fat, reduced-fat, or fat-free milk beverages, rice pudding, yogurt, kefir, cream cheese, soft cheese, hard cheese, powdered milk milk, whey, butter, buttermilk, products containing partially or completely hydrolyzed milk proteins), elabo / zcznn / Lznz / E / Yii products 116 rados from soy protein or other soy fractions (for example, soy milk and products produced therefrom, beverages containing enzyme-treated or isolated soy protein, beverages containing soy flour, preparations containing soy lecithin, fermented products such as tofu or tempeh or products made therefrom and mixtures with fruit preparations and optionally flavorings), fruit preparations (for example, jams, sorbets, fruit sauces, fruit fillings), Vegetable preparations (for example, ketchup, sauces, dehydrated vegetables, frozen vegetables, precooked vegetables, boiled vegetables), snacks (for example, baked or fried French fries or extruded potato, corn, or peanut-based dough products), based on fat and oil or emulsions thereof (for example mayonnaise, remoulade, dressings, in each case with full or reduced fat), other ready meals and soups (for example dehydrated soups, instant soups, pre-cooked soups), spices, spice mixtures and especially seasonings used, for example, in the field of snacks, sweetener-based preparations, tablets or sachets, other preparations for sweetening or whitening beverages or other foods. Preparations within the scope of the invention / zcznn / Lznz / E / Yii 117 can also be used in the form of semi-finished products for the production of other preparations for the purpose of nutrition or enjoyment. Preparations within the scope of the invention may also be in the form of capsules, tablets (uncoated and coated tablets, for example enteric coatings), dragees, granules, microgranules, mixtures of solids, dispersions in liquid phases, in the form of emulsions. , in the form of powders, in the form of solutions, in the form of pastes, or in the form of other preparations that can be swallowed or chewed, and in the form of food supplements. The preparations can also be in the form of capsules, tablets (uncoated and coated tablets, for example, enteric coatings), dragees, granules, microgranules, mixtures of solids, dispersions in liquid phases, in the form of emulsions, in the form of powders. , in the form of solutions, in the form of pastes, or in the form of other preparations that can be swallowed or chewed, for example in the form of food supplements. Semi-finished products are generally used for the production of preparations ready to use or ready for consumption / zcznn / Lznz / E / Yii for nutrition or enjoyment purposes. 118 Other components of a ready-to-eat preparation or semi-finished product for nutrition or enjoyment purposes may be conventional basic substances, auxiliary substances and additives for food or food for enjoyment, e.g. water, mixtures of raw, fresh or processed substances, vegetable or animal-based (for example, raw, roasted, dried, fermented, smoked and / or boiled meat, bones, cartilage, fish, vegetables, herbs, nuts, vegetable juices, vegetable pastes or mixtures thereof), carbohydrates digestible or indigestible (eg sucrose, maltose, fructose, glucose, dextrins, amylose, amylopectin, inulin, xylans, cellulose, tagatose), sugar alcohols (eg sorbitol, erythritol), natural or hardened fats (eg , tallow, lard, palmin, cocoa fat, hardened vegetable fat), oils (for example, sunflower oil, peanut oil, corn germ oil, olive oil, fish oil, soybean oil, oil sesame), fatty acids or their salts (for example, potassium stearate), proteinogenic or non-proteinogenic amino acids and related compounds (for example, -aminobutyric acid, taurine), peptides (for example, glutathione), natural or processed proteins ( gelatin), enzymes (eg peptidases), nucleic acids, nucleotides, taste correctors for unpleasant taste impressions, other taste modulators for other generally unpleasant taste impressions, other taste-modifying substances (for example, inositol phosphate, nucleotides such as guanosine monophosphate, adenosine monophosphate, or other substances such as sodium glutamate or 2-phenoxypropionic acid), emulsifiers (for example, lecithins, diacylglycerols, acacia), stabilizers (for example, carrageenans, alginates ), preservatives (for example, benzoic acid and its salts, sorbic acid and its salts), antioxidants (for example, tocopherol, ascorbic acid), chelators (for example, citric acid), organic or inorganic acidifying agents (for example, acid acetic acid, phosphoric acid), other bitter substances (for example, quinine, caffeine, limonene, amarogentin, humulone, lupulone, catechins, tannins), substances that prevent enzymatic browning (for example, sulfite, ascorbic acid), essential oils, extracts from plants, natural or synthetic colors or coloring pigments (for example, carotenoids, flavonoids, anthocyanins, chlorophyll and derivatives thereof), spices, trigeminal active substances or plant extracts containing such trigeminal active substances, flavor / zcznn / Lznz / E / Yii 120 synthetic, natural or identical to natural teas or odorizers, as well as odor correctors. Food compositions according to the invention, for example those in the form of preparations or semi-finished products, preferably comprise a flavor composition to complete and refine the flavor and / or aroma. A preparation may comprise as components a solid carrier and a flavoring composition. Suitable flavoring compositions comprise, for example, synthetic, natural or nature-identical flavors, flavorings and flavoring substances, reaction flavorings, smoked flavorings or other flavoring preparations (for example, (partial) protein hydrolysates, preferably protein hydrolysates (partial) having a high arginine content, barbecue flavorings, plant extracts, spices, spice preparations, vegetables and / or vegetable preparations), as well as suitable auxiliary substances and carriers. Particularly suitable herein are flavoring compositions or their components that produce roast meat (especially chicken, fish, shellfish, beef, pork, lamb, sheep, goat), vegetable-like (especially tomato, onion, garlic , celery, leeks, mushrooms, aubergines, seaweed), spicy (in spec / zcznn / Lznz / E / Yii 121 cial black and white pepper, cardamom, nutmeg, capsicum, mustard, and mustard-based products), fried, yeast-like, boiled, fatty, salty, and / or spicy, and may therefore enhance the spicy impression. Flavor compositions generally comprise more than one of the mentioned ingredients. The food compositions of the present invention are preferably selected from the group consisting of • confectionery products, preferably reduced or no calorie confectionery products, preferably selected from the group consisting of muesli bar products, fruit gums, confections, hard candies and gum chewing, • non-alcoholic beverages, preferably selected from the group comprising green tea, black tea, (green, black tea), beverages enriched with tea extracts (green and black), rooibos tea, other herbal teas, non-alcoholic fruit beverages sugar-free or low-sugar alcohol, isotonic drinks, nectars, fruit and vegetable juices, fruit and vegetable juice preparations, • instant drinks, preferably selected from the group consisting of instant tea drinks (green, rooibos, herbal ), / zcznn / Lznz / E / Yii 122 • cereal products, preferably selected from the group consisting of low- and sugar-free breakfast cereals and muesli bars, • dairy products, preferably selected from the group consisting of low-fat and non-fat milk drinks, yoghurt, kefir, whey, buttermilk and ice cream, • products made from soy protein or other soy fractions, preferably selected from the group comprising soy milk, products made from soy milk, beverages containing soy protein isolated or enzymatically treated, drinks containing soy flour, preparations containing soy lecithin, products produced from preparations containing soy lecithin and mixtures with fruit preparations and optionally flavorings, • preparations based on sweeteners, tablets and sachets, • sugar-free confections, • ice cream, with or without milk-based components, preferably without sugar. / zcznn / Lznz / E / YiAi AROMATIC OR FLAVORING COMPOUNDS 123 Aromatic compounds and flavoring agents are well known in the art, they can be added to the flavoring compositions of the invention. These flavoring agents can be chosen from synthetic flavoring liquids and / or oils derived from plant leaves, flowers, fruits, etc., and combinations thereof. Representative flavoring liquids include: artificial, natural, or synthetic fruit flavors such as eucalyptus, lemon, orange, banana, grape, lime, apricot, and grapefruit oils, and fruit essences including apple, strawberry, cherry, orange, pineapple, etc. .; flavors derived from beans and nuts such as coffee, cocoa, cola, peanut, almond, etc.; and flavors derived from roots such as licorice or ginger. The flavoring agent is preferably selected from the group consisting of essential oils and extracts, tinctures and balms, such as, for example, anisole, basil oil, bergamot oil, bitter almond oil, camphor oil, citronella oil, oil of lemon; eucalyptus citriodora oil, eucalyptus oil, fennel oil, grapefruit oil, chamomile oil, peppermint oil, caraway oil, lime oil, tangerine oil, nutmeg oil (especially nutmeg oil in flor = maca oil, mace oil), / zcznn / Lznz / E / Yii 124 Myrrh oil, clove oil, clove oil, orange oil, oregano oil, parsley (seed) oil, peppermint oil, rosemary oil, sage oil (almaro, Dalmatian or Spanish oil ), star anise oil, thyme oil, vanilla extract, juniper oil (especially juniper berry oil), wintergreen oil, cinnamon leaf oil; cinnamon bark oil, and its fractions, or its isolated components. It is of particular advantage if the flavored composition according to the invention comprises at least one flavoring agent, preferably two, three, four, five, six, seven, eight or more flavoring agents chosen from the following group: menthol (preferably 1 menthol and / or racemic menthol), anethole, anisole, anisaldehyde, anisyl alcohol, neomenthol (racemic), eucalyptol (1,8-cineole), menthone (preferably L-menthone), isomenthine (preferably D-isomentone), isopulegol, menthyl acetate (preferably L-menthyl acetate), menthyl propionate, carvone (preferably (-) carvone, optionally as a component of a spearmint oil), methyl salicylate (optionally as a component of a wintergreen oil), eu / acetate zcznn / Lznz / E / Yii 125 genol, isoeugenol methyl ether, beta-homocyclocitral, eugenol, isobutraldehyde, 3-octanol, dimethyl sulfide, hexanol, hexanal, trans-2-hexenal, cis-3-hexenol, 4-terpineol, piperitone, linalool, 8-ocimenyl acetate , isoamyl alcohol, isovaleraldehyde, alpha-pinene, betapinene, limonene (preferably D-limonene, optionally as a component of an essential oil), piperitone, trans-sabinene hydrate, menthofuran, caryophyllene, germacrene D, cinnamaldehyde, peppermint lactone, thymol , gamma-octalactone, gamma-noalactone, gamma-decalactone (1,3E, 5Z)-undecatriene, 2-butanone, ethyl formate, 3-octyl acetate, isoamyl isovalerate, cis- and transcarvyl acetate, p-cimol , damascenone, damascone, cis-rose oxide, trans-rose oxide, phenchol, acetaldehyde diethyl acetal, 1-ethoxyethyl acetate, cis-4-heptenal, cis-jasmone, methyl dihydrojasmonate, 2'hydroxypropiophenone, menthyl methyl ether, mirtenyl acetate, 2-phenylethyl alcohol, 2-phenylethyl isobutyrate, 2-phenylethyl isovalerate, geraniol, nerol and viridiflorol. Especially preferred flavoring or flavoring compounds include menthol, cineol, eugenol, thymol, cinnamic aldehyde, peppermint oil, peppermint oil, / zcznn / Lznz / E / Yii 126 Eucalyptus oil, thyme oil, cinnamon oil, clove oil, fir needle oil, fennel oil, sage oil, aniseed oil, star anise oil, chamomile oil and caraway oil, and mixtures thereof . SWEETENERS The term "sweeteners" as used herein denotes substances having a relative sweetening power of at least 25, based on the sweetening power of sucrose (which consequently has a sweetening power of 1). Sweeteners for use in an orally consumable product (especially foodstuffs, food or medicines) according to the invention (a) are preferably non-cariogenic and / or have an energy content of no more than 5 kcal per gram of the product orally consumable. Advantageous sweeteners in a preferred food composition according to the invention are selected from the following groups: Natural sweeteners, preferably selected from the / zcznn / Lznz / E / Yii group comprising 127 • miraculin, monellin, mabinlin, thaumatin, curculin, brazzein, pentaidine, D-phenylalanine, D-tryptophan and extracts or fractions obtained from natural sources, comprising those amino acids and / or proteins, and the physiologically acceptable salts of those amino acids and / or proteins, especially sodium, potassium, calcium or ammonium salts; • neohesperidin dihydrochalcone, naringin dihydrochalcone, stevioside, steviolbioside, rebaudiosides, in particular rebaudioside A, rebaudioside B, rebaudioside C, rebaudioside D, rebaudioside E, rebaudioside F, rebaudioside G, rebaudioside H, dulcosides and rubusoside, suavioside A, suavioside G, suavioside H, suavioside I, suavioside J, baiyunoside 1, baiyunoside 2, flomisoside 1, flomisoside 2, flomisoside 3 and flomisoside 4, abrusoside A, abrusoside B, abrusoside C, abrusoside D, cyclocarioside A and cyclocarioside I, osladino, polypodoside A, strogin 1, strogin 2, strogin 4, selligueain A, dihydroquercetin-3acetate, perillartin, telosmoside A15, periandrin I-V, pterocaryosides, cyclocaryosides, mukurocyrosides, trans-anethole, trans-cinnamaldehyde, bryosides, brionosides, brionodulcosides, carnosiflosides, scandenosides, gipenosides, trilobatin, phloridizin, / zcznn / Lznz / E / YiAi 128 Dihydroflavanols, hematoxylin, cyanin, chlorogenic acid, albiciasaponin, telosmosides, gaudicaudioside, mogrosides, mogroside V, hernandulcin, monatin, phyllodulcin, glycyrrhetinoic acid and its derivatives, especially glycosides thereof, such as glycyrrhizin, and physiologically acceptable salts of these compounds, especially the sodium, potassium, calcium or ammonium salts; • extracts or concentrated fractions of the extracts, selected from the group comprising extracts of thaumatococcus (katamfe plant), extracts of Stevia ssp. (in particular Stevia rebaudiana), extracts of swingle (Momordica or Siratia grosvenorii, Luo-Han-Guo), extracts of Glycerrhyzia ssp. (in particular Glycerrhyzia glabra), extracts of Rubus ssp. (in particular Rubus suavissimus), extracts of citrus and extracts of Lippia dulcis; Sweet-tasting synthetic substances, preferably selected from the group comprising magap, sodium cyclamate or other physiologically acceptable salts of cyclamic acid, acesulfame K or other physiologically acceptable salts of acesulfame, neohesperidin dihydrochalcone, naringin dihydrochalcone, saccharin, saccharin sodium salt, aspartame , superaspartame, neotame, alitame, advantame, perillartin, sucralose, lugduname, carrelame, sucrononate, and sucrooctate. / zcznn / Lznz / E / Yii 129 THICKENERS Advantageous thickeners in a preferred orally consumable product (especially foodstuffs, food or medicines) according to the invention are selected from the group comprising: cross-linked polyacrylic acids and derivatives thereof, polysaccharides and derivatives thereof, such such as xanthan gum, agar-agar, alginates or tyloses, cellulose derivatives, for example carboxymethyl cellulose or hydroxycarboxymethyl cellulose, fatty alcohols, monoglycerides and fatty acids, polyvinyl alcohol and polyvinylpyrrolidone. According to the invention, an orally consumable product (especially foodstuffs or food) comprising milk thickened with lactic acid bacteria and / or cream thickened with lactic acid bacteria is preferred and is preferably selected from the group comprising yogurt, kefir and quark. A food composition according to the invention comprising milk thickened with lactic acid bacteria and / or cream thickened with lactic acid bacteria is advantageously an orally consumable product comprising a probiotic, wherein the probiotic is preferably selected from the group that comprises Bifidobacterium animalis subsp. lactis BB-12, Bifidobacterium animalis subsp. lactis DN-173 / zcznn / Lznz / E / Yii 130 010, Bifidobacterium animalis subsp. lactis HN019, Lactobacillus acidophilus LA5, Lactobacillus acidophilus NCFM, Lactobacillus johnsonii Lal, Lactobacillus case! immunotass / defensis, Lactobacillus casei Shirota (DSM 20312), Lactobacillus casei CRL431, Lactobacillus reuteri (ATCC 55730) and Lactobacillus rhamnosus (ATCC 53013). ADDITIVES FOR RUBBER. CHEWING Particularly preferred is an orally consumable product (especially a foodstuff, feed or medicament) according to the invention which is a chewing gum and comprises a chewing gum base. The chewing gum base is preferably selected from the group comprising chewing gum bases or base preparations for the preparation of chewing gum. The latter are softer, so bubbles can also be formed with them. Preferred chewing gum bases according to the invention include, in addition to traditionally used natural resins or natural latex chewing gum, elastomers such as polyvinyl acetate (PVA), polyethylene, polyisobutene (low to medium molecular weight ) (PIB), polybutadiene, isobutene-isoprene copolymers (butyl rubber), polyvinylethyl ether (PVE), polyvinylbutyl ether, / zcznn / ίζηζ / Ε / γι copolymers 131 Vinyl esters and vinyl ethers, styrene-butadiene copolymers (styrene-butadiene rubber, SBR) or vinyl elastomers, e.g. based on vinyl acetate / vinyl laurate, vinyl acetate / vinyl stearate or ethylene / vinyl acetate, as well as mixtures of the elastomers mentioned, as described, for example, in EP 0 242 325, US 4,518,615, US 5,093,136, US 5,266,336, US 5,601,858 or US 6,986 .709. Furthermore, the chewing gum bases that are preferably used according to the invention preferably comprise additional components such as, for example, (mineral) fillers, plasticizers, emulsifiers, antioxidants, waxes, fats or fatty oils, such as, for example , hardened (hydrogenated) vegetable or animal fats, mono-, di- or tri-glycerides. Suitable fillers (minerals) are for example calcium carbonate, titanium dioxide, silicon dioxide, talc, aluminum oxide, dicalcium phosphate, tricalcium phosphate, magnesium hydroxide and mixtures thereof. Suitable plasticizers, or adhesion preventers (anti-tack agents), are, for example, lanolin, stearic acid, sodium stearate, ethyl acetate, diacetin (glycerol diacetate), triacetin (glycerol triacetate), triethyl citrate. Suitable waxes are, for example, pa / zcznn / Lznz / E / Yii waxes 132 raffin, candelilla wax, carnauba wax, microcrystalline waxes and polyethylene waxes. Suitable emulsifiers are, for example, phosphatides such as lecithin, mono- and di-glycerides of fatty acids, for example glycerol monostearate. Chewing gums according to the invention (especially as disclosed above) preferably comprise compounds such as sugars of different types, sugar substitutes, other sweet-tasting substances, sugar alcohols (especially sorbitol, xylitol, mannitol), ingredients that have a cooling effect, taste correctors for unpleasant taste impressions, other substances that modulate taste (for example, inositol phosphate, nucleotides such as guanosine monophosphate, adenosine monophosphate or other substances such as sodium glutamate or 2-phenoxypropionic acid), humectants, thickeners, emulsifiers, stabilizers, odor and flavor correctors (for example, eucalyptus-menthol, cherry, strawberry, grapefruit, vanilla, banana, citrus, peach, blackcurrant, tropical fruit, ginger, coffee, cinnamon, combinations (of the flavors mentioned) with flavors of mint, as well as spearmint and mint itself). The combination, among others, of the flavors with other / zcznn / ίζηζ / Ε / γι 133 substances that have cooling, warming, and / or appetizing properties is of particular interest. METHODS OF CONSERVATION AND FIGHT AGAINST BODY ODOR The acetophenone derivatives and the respective mixtures according to the invention display their synergistically enhanced antimicrobial action against a large number of Gram-positive bacteria, Gram-negative bacteria, molds and yeasts, which in particular enables the preservation and antimicrobial treatment of a large number of cosmetic formulations. There is a particularly good action against Gram-positive bacteria, such as Staphylococcus aureus, Staphylococcus epidermidis, Corynebacterium xerosis and Propionibacterium acnes, against Gram-negative bacteria, such as Escherichia coli and Pseudomonas aeruginosa, against yeasts, such as Candida albicans, Malassezia fur and globosa, and precisely -as already mentioned- against fungi, such as species of molds of the genus Aspergillus and others. The very good activity of the mixtures according to the invention against fungi of the genus Aspergillus, a group of fungi that can only be combated with great difficulty, is here to be regarded as particularly advantageous. / zcznn / Lznz / E / Yii 134 Therefore, another object of the present invention relates to a method for preserving a personal care composition, a detergent composition or a food composition by adding an operative amount of at least one acetophenone derivative or mixing it with a second preservative or an antimicrobial agent. Another object of the present invention relates to a method for combating microorganisms by adding an operative amount of at least one acetophenone derivative or mixing it with a second preservative or antimicrobial agent to a personal care, detergent or food composition. The invention also comprises the use of at least one acetophenone derivative or its mixture with a second preservative or an antimicrobial agent as a preservative, in particular for personal care, detergent or food compositions, preferably in amounts of about 0.01 to about 10, preferably about 0.05 to about 5, and more preferably about 0.1 to about 1% by weight. Another object of the present invention relates to a / zcznn / Lznz / E / Yii method for combating microorganisms by adding an operative amount of at least one acetophenone derivative or mixing it with a second preservative or antimicrobial agent. The acetophenone derivatives and their mixtures are particularly useful against microorganisms that cause body odor, acne and / or mycoses. Advantageously, the preservatives or mixtures of preservatives are applied to human skin in concentrations of from 0.01 to about 10, preferably from about 0.05 to about 5, and more preferably from about 0.1 to about 1% by weight, in each case based on the total weight of the cosmetic or pharmaceutical product comprising the mixture. Synergistically active mixtures can be used here (a) prophylactically or (b) as needed. The concentration of the amount of active compound to be applied, for example, daily varies and depends on the physiological state of the subject and on specific parameters of the individual, such as age or body weight. The synergistically active mixtures according to the invention can be used alone or in combination with other antimicrobial active substances. Another object of the present invention therefore comprises a method for treating unpleasant body odour, in particular underarm and foot odour, by topical administration to the skin of an operative amount of al me / zcznn / Lznz / E / Yii 136 us a derivative of acetophenone or its mixture with a second preservative or an antimicrobial agent. Lastly, the invention refers to the use of at least one acetophenone derivative or its mixture with a second preservative or an antimicrobial 5 as a deodorant. It is understood that the explanations and preferred embodiments described above with respect to the acetophenone derivatives and their mixtures mutatis-mutandis also apply to the methods and uses as claimed, so no further repetition is necessary. EXAMPLES EXAMPLE 1 The synergistic activity of 4-hydroxyacetophenone in combination with several secondary antimicrobial agents against the microorganism A. brasiliensis was determined. To calculate the synergism between the compounds of formula (I) and other antimicrobial active ingredients, the Kull equation was used1 2(I) SI = (Cmixture PA) / Ca + (Cmixture PB) / CB Kull, F.C., Eismann, P.C., Sylvestrowicz, H.D., and R.L. Mayer (1961). Mixtures of quaternary ammonium compounds and long-chain fatty acids as antifungal agents. Applied Microbiology 9, 538-541. Steinberg, D.C. (2000). Measuring Synergy. Cosmetics & Toiletries 115 (11), 59-62. / zcznn / Lznz / E / Yii 137 where SI is the synergy index according to Kull11'2) Ca is the cell count for substance A Cb is the cell count for substance B Cmezda is the cell count for the mixture of substances a and b Pa is the proportion of substance A in the mixture PB is the proportion of substance B in the mixture. Antimicrobial activity was assessed by determining the Minimum Inhibitory Concentration (MIC) which represents the lowest concentration of a chemical that prevents the visible growth of a bacterium. / zcznn / Lznz / E / Yii MIC values ​​were determined by preparing solutions of the chemical in vitro at increasing concentrations, incubating the solutions with separate batches of cultured bacteria, and measuring the results with agar dilution or broth microdilution. Results were classified as susceptible (often called sensitive), intermediate, or resistant to a particular antibiotic using a cut-off point. Breakpoints are agreed values, published in the guidelines of a reference body, such as the Institute for Clinical and Laboratory Standards of 138 USA (CLSI), the British Society for Antimicrobial Chemotherapy (BSAC) or the European Committee for Antimicrobial Susceptibility Testing (EUCAST). / zcznn / Lznz / E / Yii Actives (A) Comparison* Inventive Examples MIC 4HAP:A MIC SI 4-hydroxyacetophenone 2500 - - - 1,3-propanediol 200,000 1 : 19 30,000 0.70 4-isopropyl-3-methylphenol 250 4 : 1,700 0.78 Alcohol Benzyl 5000 1 : 1 3000 0.90 Bronopol 2000 1 : 1 2000 0.90 Capryloyl Glycine 60,000 1 : 3 4,000 0.45 Climbazole, Crinipan 64 9 : 1,300 0.58 Ethyl lauroyl arginate HC1 2,000 1 : 1 1,800 0.81 Ethylene Diamine Tetra Acetate (EDTA) 40,000 1 : 3 6,000 0.70 Glyceryl Caprate 2,000 1 : 1 2,000 0.90 139 Glyceryl Caprylate 2,000 1 1 1,500 0.68 IPBC, 3-iodo-2-propynylbutylcarbamate 1 99 : 1 64 0.70 PHMB, Polyhexamethylene Biguanide 250 4 1 500 0.60 Piroctone Olamine, Octopirox 64 9 1 125 0.24 Potassium 5,000 1 1 2,000 0.60 Sodium Benzonate 10,000 1 3 4,000 0.70 Sorbitan Caprylate 4,000 1 1 2,000 0.65 Triclosan 32 19 : 1,300 0.58 Undecenoyl Glycine 5,000 1 1 3,900 0.5 Undecylenic acid, undec-10-enoic acid 500 3 1 1100 0.88 / zcznn / Lznz / E / Yii *) MIC values ​​for assets taken alone *) MIC values ​​for the respective mixtures of active ingredients when combined with 4-hydroxyacetophenone in the respective weight ratio (4-HAP:A) and the resulting synergy index according to Kull. Values ​​<1 represent synergistic activity compared to actives taken alone. 140 The SI synergy index for the combination of 4-hydroxyacetophenone and secondary actives indicates a very strong synergism between these two compounds. FORMULATION EXAMPLES

[00145] The present invention is further illustrated by the following examples. Unless otherwise indicated, a reference to a substance of formula (1) refers to 4-hydroxyacetophenone (compound of formula (Ic)). However, the substance of the formula (1) can be replaced by any other compound of the formula (I). In particular, 4-hydroxyacetophenone can be replaced by 2-hydroxyacetophenone (compound of formula (la)) or 3-hydroxyacetophenone (compound of formula (Ib)). AI table Perfumed oil P1 (Amounts in % by weight.) / zcznn / Lznz / E / Yii Ingredients Amount AMBRETTOLIDE (LEAN) 10.00 AMBROXIDE 10% in IPM 10.00 BENZYL ACETATE 20.00 BENZYL SALICYLATE 15.00 141 BERGAMOT OIL, without bergapten 60, 00 CALOÑE® 1951 10% in DPG 15, 00 COUMARIN 5, 00 CYCLOGALBANATE® 10% in DPG 10, 00 ALPHA-DAMASCONE 1% in DPG 20, 00 DIHYDROMYRCENOL 10, 00 ETHYL LINALOL 75, 00 ETHYL LINALYL ACETATE 50.00 ETHYL MALTOL 1% in DEP 10.00 ETHYLENE BRASYLATE (LEAN) 80.00 FLOROSA 40.00 GERANYLACETATE 10.00 HEDIONE® HC / 30 35.00 HEDIONE® 210.00 HELIONAL® 15, 00 HELVETOLIDE® (ALICYC) 30, 00 HEXENYLSALICYLATO CIS-3 20, 00 ISO E SUPER® 40, 00 / zcznn / Lznz / E / Yii 142 LEAFOVERT® 10% in DEP 10, 00 LILIAL® 80, 00 LYRAL® 20, 00 TANGERINE OIL 10, 00 STYRALLYL ACETATE 5, 00 SYMROSE® 15, 00 VANILLIN 10% in DEP 20, 00 DIPROPYLENE GLYCOL (DPG) 50, 00 TOTAL: 1,000.00 Table IB / zcznn / Lznz / E / Yii Perfumed oil P2 (Amounts in % by weight.) Ingredients Quantity AMAROCITE® 10, 00 AMBROCENIDE® 10% in DPG 5, 00 AMBROXIDE 15, 00 AURELIONE® (7 / 8-cyclohexadecenone) (MACRO) 70, 00 BERGAMOT OIL, without bergapten 90, 00 CALOÑE® 1951 10% in GD 20.00 143 CARAWAY OIL 10, 00 CITRAL 20, 00 COUMARIN 10, 00 ALPHA-DAMASCONE 1% in DPG 15, 00 DIHYDROMYRCENOL 70, 00 TARAGON OIL 10, 00 ETHYL LINALOL 100,00 ETHYL LINALYLYLACETATE 90, 00 EUGENOL EVERNYL 10, 00 ® 5, 00 FRUCTATE® 5, 00 GERANIUM OIL 5, 00 HEDIONE® HC / 30 100,00 HELIONAL® 10, 00 INDOL 10% in DPG 5, 00 ISO E SUPER® 100,00 KEPHALIS® 5, 00 OIL OF LAVENDER 40, 00 / zcznn / Lznz / E / Yii 144 CITRUS OIL 80, 00 LILIAL® 30, 00 MANDARIN OIL 20, 00 MUSCENONE (LEAN) 5, 00 SANDRANOL® 10, 00 VANILLIN 10% in DPG 5, 00 DIPROPYLENE GLYCOL 30, 00 TOTAL: 1,000.00 CI table Perfumed oil P3 (Amounts in % by weight.) Ingredients Amount CIO ALDEHYDE (n-decanal) 10% in DPG 20.00 CU ALDEHYDE (n-undecanal) 10% in DPG 5.00 C12 ALDEHYDE (n-dodecanal) 10% in DPG 15.00 AMBRETTOLIDE (LEAN) 5, 00 AMBROCENIDE® 1% in DPG 20, 00 AURELIONE® (LEAN) 30, 00 BENZYL ACETATE 30, 00 145 CITRONELLA OIL 15.00 ETHYL VANILLIN 1% in DPG 20.00 ETHYLENE BRASILATE (LEAN) 70.00 FRUCTATE® 10% in DPG 20.00 GERANYL ACETATE 10.00 GLOBALIDE® (LEAN) 30.00 HEDIONE® 30.00 ALPHA-HEXYLCINAMALDEHYDE 90.00 INDOL 10% in DPG 5.00 ISO E SUPER® 120.00 KEPHALIS® 5.00 LINALOL 150.00 LINALLYL ACETATE 60.00 BETA-METHYLNAPHTHYLKETONE 5.00 NEROLIDOL 20.00 NEROLIONE 10% in DPG 20.00 BRAZILIAN ORANGE OIL 100.00 PHENYLETHYL ACETATE 5.00 / zcznn / Lznz / E / Yii 146 PHENYLETHYL ALCOHOL 30.00 TERPINEOL 20.00 DIPROPYLENE GLYCOL 50.00 TOTAL: 1,000.00 / zcznn / Lznz / E / Yii ID Table Perfume oil P4 with scent of white flower (Amounts in % by weight) Ingredients Amount Benzyl acetate 60, 00 Citronella acetate 60, 00 Cyclaman aldehyde (2-methyl-3- (4-isopropylphenyl) 20, 00 Propanal Dipropylene glycol 60, 00 Ethylinalool 40, 00 Florol (2-isobutyl-4-methyltetrahydro -2H-pyran-4-ol) 30.00 Globanone [(E / Z) -8-cyclohexadecen-l-one] 180.00 Hedione (methyldihydrojasmonate) 140.00 147 Hexenyl salicylate. cis-3 10, 00 Vertocitral (2,4-dimethyl-3- 5, 00 cyclohexenecarboxaldehyde) Hydratropaaldehyde. 10% in DPG 5.00 Isodamascone (1-(2.4.4-trimethyl-2-cyclohexen-l-yl)- 5.00 2-buten-l-one. 10% in DPG Isomuscone (cyclohexadecanone) 40.00 Jacinthaflor (2-methyl-4-phenyl-1.3-dioxolane) 10.00 Gis-jasmone 10% in DPG 20.00 Linalool 50.00 Linalyl acetate 30.00 Methyl benzoate 10% in DPG 25.00 para-methyl 10% cresol in DPG 10.00 Nerol 20.00 Phenylpropylaldehyde 5.00 2-phenylethyl alcohol 82.00 Tetrahydrogeraniol 13.00 2,2-dimethyl1-3-cyclohexy1-1-propanol 80.00 Total: 1,000.00 / zcznn / Lznz / E / Yii / zcznn / Lznz / E / YiA 148 Perfumed oils P1. P2. Q3. and P4 from the previous examples were worked up separately in each case in the formulations presented here. Table II Liquid soap, transparent (Amounts in % by weight) Ingredients INCI Name Quantity Tagat 0 2 Glyceryl Oleate PEG20 2.5 Coconut Oil Diethanolamine Condensate DEA Cocamide 5.0 Abil B 8842 Cyciomethleone 0.5 Sodium Lauryl Ether Sulfate. 28% Sodium Laureth Sulfate 35.0 Tego-Betaine L7 Cocamidopropyl Betaine 5.0 Soap. 25% Coconut Acid. Potassium salt. Potassium oleate 20.0 Perfume oil P1. P2. P3 or P4 Fragrance 0.4 Preservative DMDM ​​Hydantoin 0.2 149 Substance of formula (I) Hydroxyacetophenone 0.3 Water Water Add 100 / zcznn / Lznz / E / Yii Table III Syndet soap. liquid (Amounts in % by weight) Ingredients INCI Name Quantity Elfan OS 46 Sodium C14-C16 Olefin Sulfonate 35.5 Armoteric LB Lauryl Betaine 8.0 Elfan SG 10.0 Elfacos GT 282 L Talloweth-60 Myristyl Glycol 3.0 PCL-Liquid 100 Cetearyl Ethylhexanoate 4 , 0 Perfume oil P1. P2. P3 or P4 Fragrance 0.4 Preservative Methylchloroisothiazolinone. 0, 1 150 Methylisothiazolinone Substance of formula (I) Hydroxyacetophenone 0.4 Water Water Add 100 / zcznn / ίζηζ / Ε / γι Table IV Cosmetic lotion for bath gel (Amounts in % by weight) Ingredients INCI Name Quantity Lumerol K 28 Laureth Disodium Sulfosuccinate. Cocamidopropyl betaine. Magnesium lauryl sulfate 33.0 Amphotensid B 4 Cocamidopropyl betaine 10.0 Perlglanzmittel GM 4055 MIPA-Pareth-25 Sulfate. Glycol stearate 4.0 Sodium chloride Sodium chloride 2.0 Avocado oil Persea Gratissima (avocado) oil 3.0 151 Water Water Add 100 Perfume Oil P1. P2. P3 or P4 Fragrance 0.5 Euxyl® K727 Phenoxyethanol. Methyldibromo glutaronitrile. Isothiazolinones 0.3 Substance of formula (I) Hydroxyacetophenone 0.6 / zcznn / ίζηζ / Ε / γι Table V Cosmetic lotion for shower gel with Triclosan (Amounts in % by weight) Ingredients INCI Name Quantity Texapon N 25 Sodium laureth sulfate 37.5 Lamepon S Hydrolyzed collagen with potassium cocoyl 28.0 Lamesoft LMG Hydrogenated tallow glycerides. Hydrolyzed collagen with cocoil TEA 5, 0 152 Lamesoft 156 Glyceryl laurate. TEA cocoyl hydrolyzed collagen 5.0 Sodium chloride Sodium chloride 1.7 Irgasan DP 300 Triclosan 0.5 Water Water Add 100 Perfume oil P1. P2. P3 or P4 Fragrance 0.3 Euxyl® K703 Phenoxyethanol. Benzoic acid. Dehydroacetic acid 0.4 Substance of formula (I) Hydroxyacetophenone 0.4 Table VI / zcznn / Lznz / E / Yii Intimate washing (Amounts in % by weight) Ingredients INCI Name Quantity Tegobetaine HS Cocamidopropyl betaine. Glyceryl laurate 15.0 153 Tagat n 2 Glyceryl laurate PEG20 2.0 Arlacide G Chlorhexidine digluconate 0.1 Rewoquat B 50 Benzalkonium chloride 0.1 Lactic acid. 80% Lactic Acid 0.1 Water Water Add 100 Perfume Oil P1. P2. P3 or P4 Fragrance 0.2 Euxyl® K700 Potassium sorbate. Benzyl alcohol. Phenoxyethanol 0.3 Substance of formula (I) Hydroxyacetophenone 0.5 Table VII Liquid soap (Amounts in % by weight) Ingredient INCI Quantity / zcznn / Lznz / E / Yii 154 Deionized water Water 2.0 Mixture of soap bases Tallow / sodium palmitates 95.8 Titanium dioxide Titanium dioxide 1.0 Perfume oil P1. P2. P3 or P4 Fragrance 1.2 Preservatives Phenoxyethanol 0.5 Substance of formula (I) Hydroxyacetophenone 0.5 / zcznn / Lznz / E / Yii Table VIII Shampoo (Amounts in % and weight) Ingredients Quantity Sodium lauryl ether sulfate (eg Texapon NSO) 12 Cocamidopropyl betaine (eg Dehyton K) 2 Sodium chloride 1.4 Citric acid 1.3 Perfume oil P1. P2. P3 or P4 0.3 Phenoxyethanol, methyl-, ethyl-, butyl- and propylpara- 0.5 155 beno Substance of formula (I) 0, 5 Water Add 100 Table IX / zcznn / ίζηζ / Ε / γι 2 in 1 shampoo (Amounts in % by weight) Ingredients INCI Name Quantity Deionized water Water Add 100 Plantacare PS 10 Sodium Laureth Sulfate. Lauryl Glucoside 20.0 Euperlan PK 771 Glycol Distearate. Sodium lauryl sulfate. Cocamide MEA Laureth10 6.0 Sodium Chloride Sodium Chloride 1.4 Citric Acid Crystalline Monohydrate Citric Acid 0.1 Perfume Oil P1. P2. P3 or P4 Fragrance 0.5 156 Dragocid liquid Phenoxyethanol. Methylparaben. ethylparaben. butylparaben. Propylparaben. Isobutylparaben 0.5 Substance of formula (I) Hydroxyacetophenone 0.5 / zcznn / Lznz / E / Yii Table X Anti-Dandruff Shampoo (Amounts in % by weight) Ingredients Quantity Climbazole 0.50 Sodium laureth sulfate 37.00 Cocamidopropyl betaine 8.00 Caprylic / capric glycerides PEG-6 2.50 Laureth-2 2.00 Water (Aqua). Glycerol. Thymus vulgaris (thyme). Flower / leaf extract 0.50 Rosmarinus Officinalis (rosemary) leaf water. Water (Aqua). butylene glycol. Pentylene glycol 0.50 157 Bisabolol 0.10 Panthenol 0.50 Polyquaternium-10 0.40 Perfume oil P1. P2. P3 or P4 0.50 Phenoxyethanol. Methylparaben. ethylparaben. Butylparaben. Propylparaben. Isobutylparaben 0.70 Substance of formula (I) 0.30 Water (Water) Add 100 / zcznn / Lznz / E / Yii Table XI Hair conditioner with Crinipan. rinse (Amounts in % by weight) Ingredients INCI Name Quantity Lanette® 0 Cetearyl Alcohol 4.00 Dragoxat 89 Ethylhexyl Isononanoate 2.00 Genamin® KDM-P Behentrimonium Chloride 1.00 SF 1550 Phenyl Trimethicone 0.10 Neo Heliopan® BB Benzophenone-3 0.10 158 Crinipan® AD Climbazol 0.80 Glycerol 99.5 P. Glycerol 6.00 Water Water (Water) Add 100 Actipone® Alpha Pulp Water (Water). butylene glycol. Malic acid. Actinidia Chinensis (kiwi) fruit juice. Citrus. Aurantium Dulcis (orange) . Juice. Citrus Paradisi (grapefruit) juice. Pyrus Malus (apple) juice. Trideceth-9. Prunus Amygdalus Dulcís (sweet almond) seed extract 0.50 Extrapone® Bamboo P Propylene glycol. Water water). butylene glycol. Bambusa vulgaris shoot extract 0.50 Sodium hydroxide solution 10 Sodium hydroxide 0.40 Color I Color 0.60 / zcznn / Lznz / E / Yii 159 Color II Color 0.30 Perfume oil Pl. P2. P3 or P4 Fragrance 0.40 Preservative Methylparaben 0.20 Substance of formula (I) Hydroxyacetophenone 0.70 Table XII Zinc pyritrone aerosol hair conditioner, permanent (Amounts in % by weight) Ingredients INCI Name Quantity Monomuls 60-35 C Hydrogenated Palm Glycerides 1.70 Cetiol OE Dicaprylyl Ether 7.20 Abil 100 Dimethicone 3.60 Dehyquart F 75 Distearoylethyl Hydroxyethylmonium. Methosulfate. Cetearyl alcohol 4.00 Eumulgin B1 Ceteareth-12 3.50 Cetiol S Diethylhexylcyclohexane 7.20 D-panthenol Panthenol 0.10 Glycerol 99.5 P. Glycerol 1.50 160 Water Water (Water) Add 100 Actipone® Rosemary Water (Water). Propylene. Glycol. Rosmarinus officinalis. (Rosemary) Leaf Extract 0, 10 Frescolat® ML Cryst. Menthyl lactate 0.50 DragosantollOO Bisabolol 0.10 Zinc Omadine Zinc pyrithione 0.10 Perfume oil Pl. P2. P3 or P4 Fragrance 0.40 Phenonip® Phenoxyethanol. Methylparaben. ethylparaben. butylparaben. Propylparaben. Isobutylparaben 0.30 Substance of formula (I) Hydroxyacetophenone 0.5 / zcznn / Lznz / E / Yii Table XIII UV protection hair conditioner (Amounts in % by weight) 161 Ingredients INCI Name Quantity Renex PEG 6000 PEG-150 2.50 Hair conditioner base Cetyl alcohol. behentrimonium chloride. Triticum vulgare (wheat) bran extract. Linoleic Acid 3.00 PCL-Solid Stearyl Heptanoate. Stearyl Caprylate 0.50 Dow Corning 5200 Laurylmethicone Copolyol 0.50 Natrosol 250 HR Hydroxyethylene Cellulose 0.50 Benzophenone-4 Benzophenone-4 1.00 Neo Heliopan AP Disodiphenylibenzoimidazole Tetrasulfonate 1.00 Amino Methyl Propanol Amino Methyl Propanol 2.00 Cationic emulsion Dow Corning 949 Amodimethicone. Cetrimonium chloride. Tridecet-12 2.00 Perfume oil Pl. P2. P3 or P4 Fragrance 0.80 / zcznn / ίζηζ / Β / γι 162 1,2-hexanediol 1,2-hexanediol 0.50 Substance of formula (I) Hydroxyacetophenone 0.50 Water Water (Water) Add 100 Table XIV / zcznn / Lznz / E / Yii Shower gel (Amounts in % by weight) Ingredients INCI Quantity Deionized water Water Add 100 Plantacare PS 10 Sodium Laureth Sulfate. Lauryl Glucoside 20.0 Sodium Chloride Sodium Chloride 1.4 Citric Acid Crystalline Monohydrate Citric Acid 1.3 Perfume Oil Pl. P2. P3 or P4 Fragrance 0.6 SymDiol®68 1,2-hexanediol. Caprylyl glycol 0.4 163 Substance of formula (I) Hydroxyacetophenone 0.4 / zcznn / Lznz / E / Yii table fifteen Shaving foam (Amounts in % by weight) Ingredients Amount Water dism. 77.2 Triethanolamine 4.0 Edenor L2 SM (Stearic Acid. Palmitic Acid) (Cognis) 5.3 Laureth-2 3 3.0 Stearyl Alcohol 0.5 Sodium Lauryl Sulfate 3.0 Extrapone Seaweed (Water. Propylene Glycol. Iodide Potassium Fucus Vesiculosus Extract) 1.0 Dragosantol (Bisabolol. Farnesol) 0.1 Perfume Oil P1. P2. P3 or P4 1.0 euxyl® K220 (Methylisothiazolinone. Ethylhexylglycerin) 0.6 164 Substance of formula (I) 0.3 propane. Butane 4.2 Bar 4.0 / zcznn / Lznz / E / Yii Table XVI Depilatory cream (Amounts in % by weight) Ingredients Amount Cetearyl alcohol 10.0 Ceteareth-12 2.0 PCL-liquid (Cetearylethylhexanoate. Isopropyl myristate) 3.0 Dragosantol (Bisabolol. Farnesol) 0.1 Edenor L2 SM (Stearic acid. Palmitic acid) 1.0 Deionized water . 52.2 Urea 5.0 Water dism. 10, 0 Calcium thioglycolate 6, 0 Sodium hydroxide solution. 10 % 10.0 Perfume oil P1. P2. P3 or P4 0.5 Neo Dragocid Powder (Methyl paraben. Sorbi- 0.2 165 unique. dehydroacetic acid. Propyl paraben) Substance of formula (I) 0.4 / zcznn / Lznz / E / Yii Table XVII Tonic for after shaving (amounts in % by weight) Ingredients INCI Amount SymSol® PF-3 Water (Water). pentylene glycol. Sodium lauryl sulfoacetate. Sodium oleoyl sarcosinate. Sodium chloride. Disodium sulfoacetate. Sodium oleate. Sodium sulfate . 3.00 SymSitive® 1609 Pentylene Glycol. 4-tbutylcyclohexaneol 1.00 Frescolat® ML Menthyl Lactate 0.30 Glycerol 99.5 P. Glycerol 5.00 Water Water (Aqua) Add 100 Extrapone® Glacier Water GW Glycerol. Water (Aqua) 1.00 166 SymCalmin® Butylene Glycol. pentylene glycol. Hydroxyphenyl propamidobenzoic acid 0.50 Dragosine® Carnosine 0.10 Hydrolite® 5 Pentylene glycol 5.00 Ethanol 96% Denatured alcohol. 5, 00 Color Pigment Color Pigment 0.05 Perfume Oil Pl. P2. P3 or P4 Perfume 0.15 Substance of formula (I) Hydroxyacetophenone 1.00 / zcznn / Lznz / E / Yii Table XVIII Deodorant formulation in roll-on gel form (Amounts in % by weight) Ingredients Quantity 1,3-butylene glycol 2.00 PEG-40 hydrogenated castor oil 2.00 Hydroxyethylcellulose 0.50 167 Perfume oil P1. P2. P3 or P4 0.30 1,3-propanediol 0.50 3-phenylpropanol 0.40 Ethylhexylglycerin 0.10 Substance of formula (I) 0.50 Water Up to 100.00 / zcznn / ίζηζ / Ε / γι Table XIX Transparent roll-on antiperspirant deodorant (Amounts in % by weight) Ingredients INCI Quantity Methocel E4M Premium Hydroxypropylmethylcellulose 0.50 Water Water (Water) Add 100 Neo-PCL Water Soluble N Trideceth-9. PEG-5 ethylhexanoate. Water (Water) 1.00 Solubilizer PEG-40 hydrogenated castor oil. Trideceth-9. 3.00 168 Propylene glycol. Water (Water) Deolite Dimethyl phenylpropanol. Pentylene glycol 0.50 Locron LW Aluminum chlorohydrate 25.00 Aloe Vera Concentrated Gel 10 / 1 Aloe barbadensis leaf juice 1.00 Propylene glycol -1.2 99 P GC Propylene glycol 4.00 Ethanol 96% Denatured alcohol. 30, 00 Perfume oil P1. P2. P3 or P4 Perfume 1.00 Substance of formula (I) Hydroxyacetophenone 0.25 / zcznn / Lznz / E / Yii Table XX Stick deodorant (Amounts in % by weight) Ingredients Quantity Sodium stearate 8.00 169 PPG-3 Myristyl ether 70.00 1,2-propylene glycol 10.00 1,l-dimethyl-3-phenylpropanol 0.20 2-butyloctanoic acid 0.20 Perfume oil P1. P2. P3 or P4 0.60 Heptoxy-1,2-propanediol 0.20 Phenoxyethanol 0.30 Substance of formula (I) 0.50 Water Add 100 / zcznn / ίζηζ / Ε / γι Table XXI Zirconium Suspensoid Antiperspirant Stick (Amounts in % by weight) Ingredients INCI Quantity PCL Liquid 100 Cetearyl Ethylhexanoate up to 100 Silicone Fluid 345 Cyclomethicone 10.00 170 CRODACOL C90 Cetyl Alcohol 8.00 SYNCROWAX HGLC C18-36 Triglyceride 8.00 CRODAMOL PTC Pentaerythritol Tetracaprylate / Caprate 5.00 SYNCROWAX HRC Tribehenin 4.00 VOLPO N5 Oleth-5 1.00 Titanium Dioxide 1.00 Rezal Aluminum 36GPx Tetrachlorohydride GLY 20.00 Dry Fio C Aluminum starch octenyl succinate 22.50 Perfume oil Pl. P2. P3 or P4 Perfume 0.60 Preservative Phenoxyethanol 0.40 Hexoxy-1,2propanediol 0.10 Substance of formula (I) Hydroxyacetophenone 0.40 Table XXII / zcznn / ίζηζ / Β / γι 171 Aerosol deodorant with SymClariol (Amounts in % by weight) / zcznn / Lznz / E / Yii Ingredients INCI Quantity SymClariol® Decylene Glycol 0.50 Solubilizer PEG-40 Hydrogenated Castor Oil. Trideceth-9. Propylene glycol. Water (Aqua) 4.00 Neo-PCL Water Soluble N Trideceth-9. PEG-5 ethylhexanoate. Water 1.50 SymRelief® Bisabolol. Zingiber Officinale (Ginger) Root Extract 0.10 Water Water (Aqua) Add 100 1.2 Propylene Glycol Propylene Glycol 6.00 Perfume Oil P1. P2. P3 or P4 Perfume 0.40 SymDiol® 68 1,2-hexanediol. Caprylyl glycol 0.20 4-hydroxyacetophenone Hydroxyacetophenone 0.40 172 Table XXIII / zcznn / Lznz / E / Yii Antiperspirant formulations (Amounts in % by weight) Ingredients Amounts Reach ΆΖΡ-908 SUF 24.00 Cyclomethicone (pentamer) Add 100 Polydecene (Silkflo 364 NF) 17.50 Neo Heliopan OS (ethylhexyl salicylate) 2.50 L-Menthyl lactate (Frescolate ML) 0.25 Polyethylene 3 , 00 Hydrogenated Castor Oil 2, 00 Promyristil PM-3 7, 00 PEG-8 Distearate 3, 00 Silicon Dioxide (Cab-O-Sil M-5) 1, 00 Stearyl Alcohol 15, 00 Octyldodecanol 0, 10 Oil perfume P1. P2. P3 or P4 0.80 3-phenylpropanol 0.40 Substance of formula (I) 0.60 173 Table XXIV Aerosol deodorant with Triclosan (Amounts in % in pe / zcznn / Lznz / E / Yii so) Ingredients Quantity PEG-40 hydrogenated castor oil 3.00 Ethylhexylglycerol (Octoxyglycerol) 0.80 Etanoi 40.00 Citrate buffer 0.50 1,2-hexanediol / 1,2-octanediol (1:1) - Triclosan (5- chloro-2-(2,4-dichlorophenoxy)phenol) 0.25 2-benzylheptan-l-ol (jasmol) - Perfume oil P1. P2. P3 or P4 0.75 Phenoxyethanol 0.40 Substance of formula (I) 0.40 Water Add 100 Table XXV Lotion 0 / W (Amounts in % by weight) 174 / zcznn / Lznz / E / YiA Ingredients Quantity Paraffin oil 5.00 Isopropyl palmitate 5.00 Cephalic alcohol 2.00 Beeswax 2.00 Ceteareth-20 2.00 Glyceryl stearate PEG-20 1.50 Glycerol 3.00 Perfume oil P1. P2. P3 or P4 0.30 Methylparaben 0.30 Substance of formula (I) 0.60 Water Up to 100.00 Table XXVI Body lotion (Amounts in % by weight) Ingredients Quantity Cetearyl alcohol 2.00 175 Ethylhexyl isononanoate 5.00 Cetearyl ethylhexanoate. Isopropyl myristate 3.00 Glyceryl oleate citrate. Caprylic / Capric Triglyceride 4.00 Water (Water) 79.50 Carbomer 0.30 Sodium Benzonate 0.100 Propylene Glycol 5.00 30% Sodium Hydroxide Solution 0.30 Perfume Oil P1. P2. P3 or P4 0.30 Triethylene glycol. Imidazolidinyl urea. Methylparaben. Propylparaben. Dehydroacetic acid 0.30 Substance of formula (I) 0.20 Table XXVII Cream (Amounts in % by weight) Ingredients Quantity Paraffin oil 10.00 Ozoguerita 4.00 / zcznn / Lznz / E / Yii 176 Vaseline 4.00 Vegetable oil 10.00 Wool fat alcohol 2.00 Aluminum stearate 0.40 Perfume oil P1. P2. P3 or P4 0.70 1,2-pentanediol 2.00 Phenoxyethanol 0.50 Substance of formula (I) 0.50 Water Up to 100.00 Table XXVIII / zcznn / Lznz / E / Yii Cream (Amounts in % by weight) Ingredients INCI Quantity Dracorin® CE Glyceryl Stearate Citrate 1.00 Lanette® 0 Cetearyl Alcohol 2.00 Cutina® GMS-V Glyceryl Stearate 1.00 Tegosoft® MM Myristyl Myristate 1.00 111 Xiameter® PMX-0246. Cyclosiloxane Cyclohexasiloxane (and) cyclopentasiloxane 0.50 Dragoxat® 89 Ethylhexyl isononanoate 2.00 PCL-Liguido 100 Cetearyl ethylhexanoate 4.00 Neutral oil Caprylic / capric triglyceride 4.00 Carbopol® Ultrez 21 Acrylates / C10-alkyl acrylate crosspolymer -30 0.20 Keltrol® CG-T Xanthan Gum 0.10 Water Water (Water) Add 100 Glycerol 99.5 P. Glycerol 3.00 Propylene Glycol -1.2 99 P GC Propylene Glycol 2.00 Sodium Benzonate Sodium Benzonate 0.10 10% sodium hydroxide solution Sodium hydroxide 0.50 Perfume oil P1. P2. P3 or P4 Perfume 0.30 Euxyl® K702 Dehydracetic acid Benzoic acid. phenoxyethanol. Po - 0.30 / zcznn / Lznz / E / Yii 178 Liaminopropyl Biguanide. Ethylhexylglycerin 4-hydroxyacetophenone Hydroxyacetophenone 0.70 Table XXIX Cream for hands and body (Amounts in % by weight) Ingredients INCI 1 Quantity Dracorin® GOC Glyceryl oleate citrate. Caprylic / Capric Triglyceride 2.00 PCL-Solid Stearyl Heptanoate. Stearyl Caprylate 2.50 Lanette® 0 Cetearyl Alcohol 1.50 Cutina® GMS-V Glyceryl Stearate 1.00 Dragoxat® 89 Ethylhexyl Isononanoate 3.00 PCL-Liquid 100 Cetearyl Ethylhexanoate 7.00 Isodrago1® Triisononanoin 4.00 Xiameter® PMX-0345 Cyclosiloxane Cyclopentasiloxane (and) cyclohexasiloxane 0.50 179 Water Water (Water) Add 100 Carbopol® Ultrez 21 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.20 Keltrol® CG-RD Xanthan Gum 0.10 Glycerol 85 P. Glycerol 3.00 DragoBetaGlucan Water (Aqua). butylene glycol. Glycerol. Avena sativa (oat) kernel extract 1.50 Potassium sorbate Potassium sorbate 0.10 10% sodium hydroxide solution Sodium hydroxide 0.50 Perfume oil P1. P2. P3 or P4 Perfume 0.20 Euxyl® K300 Methyl-. Butyl-. Ethyl-. Propyl. Isobutylparaben. phenoxyethanol. 0.30 4-hydroxyacetophenone Hydroxyacetophenone 0.30 xxx table Facial cream (Amounts in % by weight) / zcznn / Lznz / E / Yii 180 / zcznn / Lznz / Ε / γΐΛ Ingredients INCI Quantity Emulsiphos® Potassium cetyl phosphate. Hydrogenated Palm Glycerides 1.50 Cutina® GMS-V Glyceryl Stearate 1.70 Lanette® 0 Cetearyl Alcohol 3.00 Tegosoft® MM Myristyl Myristate 1.00 PCL-Liquid 100 Cetearyl Ethylhexanoate 1.00 Isodragol® Triisononanoin 3, 00 Dragoxat® 89 Ethylhexyl isononanoate 4.00 Avocado oil Persea Gratissima (avocado) oil 3.00 Abil® 350 Dimethicone 0.50 Covi-ox® T-70 Tocopherol 0.10 Edeta® BD Disodium EDTA 0.10 Carbopol ® Ultrez 21 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.30 Keltrol® CG-RD Xanthan Gum 0.150 181 Water Water (Water) Add 100 Glycerol 99.5 P. Glycerol 4.00 Propylene Glycol -1.2 99 P GC Propylene Glycol 3.00 SymMatrix® Maltodextrin. Rubus Fruticosus (Blackberry) Leaf Extract 0.50 10% Sodium Hydroxide Solution Sodium Hydroxide 0.50 Perfume Oil P1. P2. P3 or P4 Perfume 0, 30 Euxyl® K712 Sodium benzonate. Potassium sorbate 0.20 4-hydroxyacetophenone Hydroxyacetophenone 0.60 / zcznn / Lznz / E / Yii Table XXXI Moisturizing cream for body care (Amounts in % by weight) 182 Ingredient Amount PEG-7 Hydrogenated Castor Oil 6.00 Cetearyl Ethyl Hexanoate 10.00 Isopropyl Myristate 5.00 Mineral Oil 7.00 Shea Butter {Butyrospermum parkii) 0.50 Aluminum Stearate 0.50 Magnesium Stearate 0 .50 Bisabolol 0.20 Quaternium-18-Hectorite 0.70 Dipropylene glycol 5.0 Magnesium sulfate 0.70 Pentylene glycol 4.00 Perfume oil P1. P2. P3 or P4 0.30 Preservative (phenoxyethanol) 0.20 Substance of formula (I) 0.40 Water desm. 58.90 / zcznn / ίζηζ / Ε / γΐι 183 Table XXXII Anti-wrinkle cream (Amounts in % by weight) / zcznn / Lznz / E / Yii Ingredients Amount Glyceryl Stearate Citrate 1.00 Glyceryl Laurate 1.00 Cetearyl Alcohol (and) Myristyl Myristate 3.00 Cetearyl Ethylhexanoate 4.00 Mineral Oil 4.00 Cyclopentasiloxane. Cyclohexasiloxane 0.50 Acrylates / CIO- alkyl acrylate crosspolymer 0.20 30 Water Add 100 1,2-Hexanediol 2.00 10% sodium hydroxide solution 0.10 Tazetta Narcissus bulb extract 1.00 Oil perfume P1. P2. P3 or P4 0.30 Preservative (phenoxyethanol) 0.50 184 Substance of formula (I) 0.50 / zcznn / Lznz / E / Yii Table XXXIII Functional skin oil for disinfection (Amounts in % by weight) Ingredients INCI Quantity Neutral oil Caprylic / capric triglyceride Add 100 Prunus Dulcís sweet almond oil 20.00 Dragoxat® 89 Ethylhexyl isononanoate 4.00 Isopropyl palmitate Isopropyl palmitate 6.00 PCL-Liquid 100 Cetearyl ethylhexanoate 15.00 Dragosantol® 100 Bisabolol 0.20 Retinyl acetate in oil (1 Mio. le / G) Retinyl acetate 0.50 Vitamin E acetate Tocopheryl acetate 0.50 Covi-ox® T-70 Tocopherol 0.10 Perfume oil P1. Perfume 0.30 185 P2. P3 or P4 Preservative Methyl-. Butyl-. Ethyl-. Propylparaben 0.30 4-hydroxyacetophenone Hydroxyacetophenone 0.40 Table XXXIV / zcznn / Lznz / E / YiAi Cream for septic wounds (Amounts in % by weight) Ingredients (INCI) Quantity Sorbitan isostearate. Hydrogenated castor oil. Ceresina. Beeswax (Cera Alba) 6.00 Vaseline 21.00 Cera Alba 5.00 Cetearyl alcohol 7.00 Prunus Dulcís 7.00 Lanolin 5.00 Liquid paraffin 12.00 Perfume oil P1. P2. P3 or P4 0.30 Water (Aqua) Add 100 186 Panthenol 7.00 Magnesium sulfate 0.70 Pentylene glycol 1.00 Tocopheryl acetate 1.00 Octenidine dihydrochloride 0.10 Phenoxyethanol 0.50 Substance of formula (I) 0.50 / zcznn / Lznz / E / Yii Table XXXV Moisturizing and disinfecting facial mask (Amounts in % by weight) Ingredients INCI Quantity Water Water (Aqua) Add 100 Stabileze QM Crosspolymer PVM / Decadiene Ma 0.50 Biotive® L-Arginine Arginine 0.75 Actipone® Laminaria Saccharina GW Glycerol. Water water). Extract of Laminaria Saccha- 1, 00 187 fight Extrapone® Cucumber Water (Aqua). Propylene glycol. Cucumis Sativus (cucumber) juice 1.00 Glycerol 99.5 P. Glycerol 7.00 Neo Actipone® soap nut shell Sapindus Mukurossi shell extract 0.50 Color I Color 0.01 Hydrolite® 5 Pentylene glycol 5.00 Solubilizing PEG-40 hydrogenated castor oil. Trideceth-9. Water (Aqua) 0, 60 Perfume oil P1. P2. P3 or P4 Perfume 0.08 Preservative Phenoxyethanol 0.40 4-Hydroxyacetophenone Hydroxyacetophenone 0.40 Table XXXVI Spray disinfectant gel (Quantities in % by weight) / zcznn / ίζηζ / Ε / γι 188 Ingredients INCI Quantity Water Water (Aqua) Add 100 Stabileze QM Cross Polymer PVM / Ma Decadiene 0.25 10% Sodium Hydroxide Solution Sodium Hydroxide 0.40 Pure Caffeine Caffeine 0.50 Extrapone® Horse Chestnut Propylene Glycol. Water (Aqua). Glucose. Aesculus Hippocastanum (Horse Chestnut) seed extract. Lactic Acid 1.00 Hydrolite® 5 Pentylene Glycol 3.00 1.3 Butylene Glycol Butylene Glycol 5.00 Biotive® Esculin Sesquihydrate Esculin 0.30 Ethanol 96% Denatured Alcohol. 10.00 Solubilizer PEG-40 hydrogenated castor oil. Trideceth-9. Water 0.50 / zcznn / ίζηζ / Β / γι 189 (Water) Perfume oil P1. P2. P3 or P4 Perfume 0.20 Octenidine dihydrochloride 0.10 Preservative Phenoxyethanol 0.70 4-hydroxyacetophenone Hydroxyacetophenone 0.30 Table XXXVII / zcznn / Lznz / E / Yii Mineral washing and cleaning gel (Amounts in % by weight) Ingredients INCI Quantity Water Water (Aqua) Add 100 Pionier® NP 37 G Sodium Carbomer 1.50 SymSol® PF-3 Water (Water). pentylene glycol. Sodium lauryl sulfoacetate. Sodium oleoyl sarcosinate. Sodium chloride. Disodium sulfoacetate. Sodium oleate. Sulfate 5.00 190 sodium. Hydroviton® 24 Water (Aqua). pentylene glycol. Glycerol. Sodium lactate. Lactic acid. Serine. Urea. Sorbitol. Sodium chloride. Allantoin 1, 00 Extrapone® Silk GW Water (Aqua). Glycerol. Hydrolyzed silk 1.00 Hydrolite® 5 Pentylene glycol 4.00 Actipearls Red Star # DH10402 / 6 Water (Aqua). Propylene glycol. Algin. Gellan gum. Xanthan gum. Calcium chloride. CI 12490 (pigment red 5). Mica (CI 77019). Titanium dioxide (CI 77891) 1.00 Perfume oil P1. P2. P3 or P4 Perfume 0.50 3-phenylpropanol 0.70 4-hydroxyacetophenone Hydroxyacetophenone 0.30 / zcznn / Lznz / E / Yii 191 Table XXXVIII Anti-acne wash (Amounts in % by weight) / zcznn / Lznz / E / Yii Ingredients (INCI) Quantity Water (Water) 45.70 Polyquaternium-7 0.50 Cocamidopropyl Betaine 9,000 9.00 Coconut glucoside 2,000 2.00 Polysorbate 80. Glycerol. Gossypium Herbaceum. Seed oil (cotton). Water (Water) 1, 00 Trideceth-9. PEG-5 ethylhexanoate. Water (Water) 1.00 Glyceret-90 isostearate. Laureth-2 0.50 Sodium laureth sulfate 37,000 37.00 Glycerol. Triticum vulgare (wheat) gluten. Water (Water) 1.00 Sodium Chloride 0.30 Perfume Oil P1. P2. P3 or P4 1.00 Phenoxyethanol. Methylparaben. ethylparaben. Butylparaben. Propylparaben. Isobutylparaben 0.30 Substance of formula (I) 0.50 192 Table XXXIX / zcznn / Lznz / E / Yii Sun protection cosmetic composition (Amounts in % by weight) Ingredient Quantity Ethylhexyl cinnamic acid 7.50 Benzophenone-3 2.00 Soy polyglyceryl dimer 0.80 Sorbitan stearate 1.00 Tocopheryl acetate 0.50 Glyceryl stearate. PEG-100 Stearate 3.00 PEG-40. hydrogenated castor oil 1.00 Titanium dioxide, aluminum oxide hydrate. 3.00 Dimethicone / Methicone Copolymer Butyrospermum parkii (Shea Butter) 1.00 C12-15 Algyl Benzoate 6.50 Butylene Glycol 5.00 Xanthan Gum 0.30 Disodium EDTA 0.10 193 Allantoin 0.10 Polyacrylamide. Isoparaffin C13-14. Laureth-7 1.00 Pentylene glycol 5.00 4-t butylcyclohexanol 1.00 Perfume oil P1. P2. P3 0 P4 0.30 Preservatives (Methyl-. Butyl-. Ethyl-. Propylparaben. Phenoxyethanol) 0.30 Substance of formula (I) 0.60 Water desm. add 100 / zcznn / Lznz / E / Yii XXXX table Sun protection spray (Amounts in % by weight) Ingredients INCI Quantity Water, demineralized Water (water) 69.50 Glycerol Glycerol 4.00 1.3 Butylene Glycol Butylene Glycol 5.00 D-panthenol Panthenol 0.50 194 Lara Care A-200 Galactoarabinan 0.25 Baysilone M Oil 10 Dimethicone 1.00 Edeta BD Disodium EDTA 0.10 Copherol 1250 Tocopheryl Acetate 0.50 Cetiol OE Dicaprylyl Ether 3.00 Neo Heliopan® HMS Homosalate 5.00 Neo Heliopan® AV Ethylhexyl Methoxycinnamate 6.00 Neo Heliopan® 357 Butyl Methoxydibenzoylmethane 1.00 Corapan TQ Diethylhexyl Naphthalate 2.00 Alpha Bisabolol Bisabolol 0.10 Pemulen TR-2 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.25 NaOH. 10% Sodium hydroxide 0.60 Perfume oil P1. P2. P3 or P4 Fragrance 0.20 Phenoxyethanol Phenoxyethanol 0.40 Solbrol M Methylparaben 0.10 Solbrol P Propylparaben 0.10 / zcznn / ίζηζ / Β / γι 195 4-hydroxyacetophenone Hydroxyacetophenone 0.50 Table XXXXI / zcznn / Lznz / E / Yii Sunscreen spray 0 / W. SPE 15-20 (Amounts in % by weight) Ingredients INCI Quantity Dracorin® GOC Glyceryl oleate citrate. Caprylic / Capric Triglyceride 2.00 Corapan® TQ Diethylhexyl 2,6-naphthalate 3.00 Neo Heliopan® HMS Homosalate 7.00 Neo Heliopan® OS Ethylhexyl Salicylate 5.00 Neo Heliopan® 357 Butyl Methoxydibenzoylmethane 3.00 Isoadipate Diisopropyl adipate 6.00 Baysilone® MIO oil Dimethicone 1.00 Edeta® BD Disodium EDTA 0.10 Vitamin E acetate Tocopheryl acetate 0.50 Dragosantol® 100 Bisabolol 0.10 196 Pemulen® TR-2 Acrylates / C10-30 alkyl acrylate crosspolymer 0.25 Water Water (Water) Add 100 Glycerol 99.5 P. Glycerol 4.00 Butylene Glycol Butylene Glycol 5.00 Neo Heliopan® Hydro (103089). used as 25% aqueous solution neutralized with Biotive® L-Arginine Phenylbenzimidazole sulfonic acid 8.00 Biotive® L-Arginine Arginine 0.55 Perfume oil P1. P2. P3 or P4 Fragrance 0.40 Sobrol M Methylparaben 0.30 4-Hydroxyacetophenone Hydroxyacetophenone 0.60 / zcznn / Lznz / E / Yii Table XXXXII Mild sun protection cream (W / 0). SPF 40 (Amounts in % by weight) 1°>Ί Ingredients INCI Quantity Dehymuls PGPH Polyglyceryl-2 Dipolyhydroxystearate 5.00 Copherol 1250 Tocopheryl Acetate 0.50 Permulgin 3220 Ozocerite 0.50 Zinc Stearate Zinc Stearate 0.50 Tegosoft TN C12-15 Alkyd Benzoate 10.00 Neo Heliopan® E1000 Isoamyl-p-methoxycinnamate 2.00 Neo Heliopan® 303 Octocrylene 5.00 Neo Heliopan® MBC 4-methylbenzylidene camphor 3.00 Zinc oxide, neutral Zinc oxide 5.00 Water, distilled Water (water) Add 100 EDETA BD EDTA disodium 0.10 Glycerol Glycerol 4.00 Magnesium sulfate Magnesium sulfate 0.50 Perfume oil P1. P2. P3 or P4 Perfume 0.30 / zcznn / Lznz / E / Yii 198 Symdiol® 68 1,2-hexanediol. Caprylyl glycol 0.30 Substance of formula (I) 0.80 / zcznn / Lznz / E / Yii Table XXXXIII Sun protection milk (W / 0) (Amounts in % by weight) Ingredients INCI Quantity Dehymuls PGPH Polyglyceryl-2 Dipolyhydroxystearate 3.00 Beeswax 8100 Beeswax 1.00 Monomuls 90-0-18 Glyceryl Oleate 1.00 Zinc Stearate Zinc Stearate 1.00 Cetiol SN Cetearyl Isononanoate 5. 00 Cetiol OE Dicaprylyl Ether 5.00 Tegosoft TN C12-15 Alkyl Benzoate 4.00 Vitamin E Tocopherol 0.50 Neo Heliopan® OS Ethylhexyl Salicylate 5.00 199 Neo Heliopan® AV Ethylhexyl methoxycinnamate 7.50 Uvinul T150 Ethylhexyl triazone 1.50 Water, distilled Water (Aqua) Up to 100 Trilon BD Disodium EDTA 0.10 Glycerol Glycerol 5.00 Neo Heliopan® AP 10% solution. neutralized with NaOH Disodium phenyl dibenzimidazole tetrasulfonate 15.00 Perfume oil PI. P2. P3 or P4 Perfume 0.25 Alpha bisabolol Bisabolol 0.10 SymOcide® PT Phenoxyethanol. Tropolone 0.25 4-Hydroxyacetophenone Hydroxyacetophenone 0.25 Table XXXXIV After-sun gel (Amounts in % by weight) INCI Ingredients Amount / zcznn / Lznz / E / Yii 200 SymSol® PF-3 Water (Aqua). pentylene glycol. Sodium lauryl sulfoacetate. Sodium oleoyl sarcosinate. Sodium chloride. Disodium sulfoacetate. Sodium oleate. Sodium sulfate. 3,000 Glycerol 99.5 P. Glycerol 5,000 SymHelios® 1031 Benzylidene Dimethoxydimethylin Danone 0,100 Water Water (Aqua) Add 100 Pemulen® TR-2 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 1,000 D- panthenol 75 W Panthenol 0, 500 SymFinity® 1298 Echinacea purpurea extract 0, 100 Extrapone® Pearl GW Water (Aqua). Glycerol. Hydrolyzed pearl. Xanthan gum 1,000 10% sodium hydroxide solution Sodium hydroxide 2,500 / zcznn / ίζηζ / Β / γι 201 Ethanol 96% Denatured alcohol. 15,000 Perfume oil Pl. P2. P3 or P4 Perfume 0.20 SymOcide® PS Phenoxyethanol. 1,2-hexanediol. Decylene glycol 0.50 4-hydroxyacetophenone Hydroxyacetophenone 0.50 Table XXXXV / zcznn / Lznz / E / Yii After-sun lotion (Amounts in % by weight) Ingredients Quantity Acrylate / C10-30 alkylacrylate crosspolymer 0.4 Cetearylethyl hexanoate 15.0 Bisabolol 0.2 Tocopheryl acetate 1.0 Panthenol 1.0 Alcohol 15.0 Glycerol 3.0 Perfume oil Pl. P2. P3 or P4 0.30 202 1,2-Hexanediol 0.60 Substance of formula (I) 0.30 Pentylene glycol 4.0 Water desm. Add 100 Triethanolamine 0.2 Table XXXXVI / zcznn / Lznz / E / Yii Hair styling gel (Amounts in % by weight) Ingredients Quantity Water Add 100 Crosspolymer PVM / MA Decadiene 0.60 PVP 3.00 Isocetyl stearate 4.00 Ethylhexyl methoxycinnamate 0.50 Aminomethyl propanol 0.40 Perfume oil Pl. P2. P3 or P4 0.60 203 SymDiol® 68T (1,2-hexanediol. 1,2-octanediol. Tropolone) 0.30 Phenoxyethanol 0.20 Substance of formula (I) 0.40 / zcznn / Lznz / E / Yii Table XXXXVII Silicone emulsion (Amounts in % by weight) Ingredients Quantity Potassium cetyl phosphate. Hydrogenated palm glycerides 1.00 Cyclohexasiloxane 4.00 Cetearyl alcohol 1.50 Phenyl trimethicone 3.00 Stearyl heptanoate. Stearyl caprylate 3.00 Dimethicone 1.00 Xanthan gum 0.20 Isoamyl P-methoxycinnamate 5.00 Water Add 100 204 Methylpropanediol 3.00 Perfume oil P1. P2. P3 or P4 0.30 Diazolidinyl urea 0.10 Substance of formula (I) 0.50 / zcznn / Lznz / E / Yii Table XXXXVIII Microemulsion gel (Amounts in % by weight) Ingredient Amount Glycerol Isostearate 1.80 Octoxyglycerol 1.00 Ceteareth-15 5.20 PEG-150 Distearate 1.00 Aluminum Chlorohydrate 5.00 Isotridecilisononanoate 3.30 Cycymethicone 6.60 Perfume Oil P1 . P2. P3 or P4 0.70 euxyl® K145 (Methylchloroisothiazolinone. Methylisothiazolinone. Bronopol) 0.10 205 Substance of formula (I) 0.40 Water Add 100 Table XXXXIX Gel air freshener (Amounts in % by weight) Ingredient Quantity Demineralized water Add 100 Genugel X-6424 (carrageenan) 2.00 Arkopal N 100 or Tergitol NP 10 (Emulsifier) ​​3.50 Perfume oil P1. P2. P3 or P4 0.60 Preventol D 7 (5-chloro-2-methyl-4-isothiazolin-3-one. 2-methyl-2H isothiazol-3-one) 0.10 Substance of formula (I) 0.80 Table L Cleaner. APC liquid. Alkaline pH 8-10 (Amounts in % by weight) 206 Ingredients (INCI) Amount Water 59.06 Trisodium Citrate Dihydrate 3.00 Sodium Laureth Sulfate 30.00 Trideceth-9 5.00 Ethanol 2.00 10% Citric Acid Solution 0.24 Perfume Oil P1. P2. P3 or P4 0.50 Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one 0.10 Hydroxyacetophenone 0.30 LI table Fabric softener (Amounts in % by weight) Ingredients (INCI) Amount Water 72, 10 Dialkyl ammonium ester methosulfate 16, 60 Polydimethylsiloxane 0, 30 / zcznn / ίζηζ / Ε / γι 207 Magnesium chloride 10.00 Perfume oil P1. P2. P3 or P4 0.60 Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one 0.10 Hydroxyacetophenone 0.40 / zcznn / Lznz / E / Yii Table LII Liquid detergent (Amounts in % by weight) Ingredients Quantity Deionized water 39.60 Optical brightener 0.10 Coconut fatty acids (C12-C18) 7.50 50% potassium hydroxide solution 4.30 Propane-1,2-diol 5.00 C12-C15 fatty alcohols . 8 EO 12.00 Na salt of secondary alkyl sulfonates (C13-C17) 17.00 Triethanolamine 2.00 Trisodium citrate dihydrate 5.00 208 Dequest 2066 Diethylenetriamine penta (methylenephosphonic acid) 3.00 Ethanol 3.00 Enzymes 0.70 Perfume oil P1. P2. P3 or P4 0.50 Substance of formula (I) 1.00 / zcznn / Lznz / E / Yii LUI table Liquid detergent concentrate (Amounts in % by weight) Ingredients Quantity Deionized water 12, 9 Coconut fatty acids (C12-C18) 10, 0 C12-C15 fatty alcohols. 8 EO 26.0 Na salt of secondary (C13-C17) alkyl sulfonates 26.5 Triethanolamine 8.5 Na salt of C12-C14 fatty alcohol sulfates 3.0 Ethanol 5.5 209 Urea 4.5 Enzymes 0.9 Citric acid 1.0 Perfume oil P1. P2. P3 or P4 0.7 Substance of formula (I) 0.8 Table LIV / zcznn / Lznz / E / Yii Bathroom cleaner (Amounts in % by weight) Ingredients Amount Water 93.0 Kelzan ASX-T 0.5 Paraffin Sulfonate, Sodium Salt 1.0 Citric Acid 5.0 Color (FD&C Yellow #6) 0.1 Perfume Oil P1. P2. P3 or P4 0.3 Preservative (benzisothiazolinone. Glutaral) 0.05 Substance of formula (I) 0.6 LV table Dishwashing concentrate (Amounts in % by weight) 210 Ingredients Amount Sodium Lauryl Sulfate 31.0 Propane-1,2-diol 6.0 Ethyl Alcohol 96% 7.0 Palm Glycosides 6.0 Coconut Betaine 18.0 Perfume Oil P1. P2. P3 or P4 0.4 Substance of formula (I) 0.5 Water 31, 6 LVI table / zcznn / Lznz / E / Yii Concentrate for dishwashing (Amounts in % by weight) Ingredients Quantity Palm Glycosides 4.0 Sodium Lauryl Sulfate 45.0 Coco Betaine 8.0 Ethyl Alcohol 96% 1.0 Color (C.I. Blue Pigment 15) 0.05 Perfume Oil P1. P2. P3 or P4 0.2 Substance of formula (I) 0.7 Water Add Table LVIII Solution for wet wipes (Amounts in % by weight) 211 Ingredients INCI Amount SymSol® PF-3 Water (Water). pentylene glycol. Sodium lauryl sulfoacetate. Sodium oleoyl sarcosinate. Sodium chloride. Disodium sulfoacetate. Sodium oleate. Sodium sulfate. 2.00 Dragosantol® 100 Bisabolol 0.10 Glycerol 99.5 P. Glycerol 5.00 Water Water (Aqua) Add 100 Hydrolite® 5 Pentylene Glycol 5.00 D-panthenol 75 W Panthenol 0.80 DragoCalm® Water (Aqua). Glycerol. Avena sativa grain extract (oats) 1.00 Witch Hazel distillate Hamamelis virginiana water (Witch Hazel). Water (Aqua). alcohol 1.00 / zcznn / ίζηζ / Ε / γΐι 212 Allplant Essence® Org. Rose Geranium P Flower / Leaf / Stem Water of Pelargonium Graveolens 1, 00 Perfume oil P1. P2. P3 or P4 Perfume 0.10 Preservative Phenoxyethanol 0.30 4-Hydroxyacetophenone Hydroxyacetophenone 0.50 / zcznn / Lznz / E / Yii Wet cleaning wipes Preparation of a composition or mixture to neutralize unpleasant odors and / or disinfect with wet cleaning wipes: The following components are mixed to form a composition or mixture: 30 parts by weight of dipropylene glycol. 25 parts by weight of the substance of the formula (I). 15 parts by weight of isopropyl myristate. 15 parts by weight of triethyl citrate and 15 parts by weight of benzyl benzoate. By use of an emulsifier (Dracorin GOC) a 0.05% aqueous solution is produced from this composition and used to make wet cleaning wipes. Table LVIIIA Mint Flavor PF1 (Amounts in % by weight) 213 / zcznn / Lznz / E / YiA Ingredients Amount Substance of formula (I) Add 1000 Isobutyraldehyde 0.5 3-octanol 0.5 Dimethyl sulfide 0.5 trans-2-Hexenal 1.0 cis-3-hexenol 1.0 4-Terpineol. natural 1.0 Isopulegol 1.0 Piperitone. natural, from eucalyptus 2.0 Linalool 3.0 8-ocimenyl acetate. 10% in triacetin 5.0 Isoamyl alcohol 10.0 Isovaleraldehyde 10.0 alpha-pinene. natural 25.0 beta-pinene. natural 25, 0 Neomenthol. racemic 40.0 214 Eucalyptol (1.8-cineole). natural 50.0 L-menthyl acetate of formula D 70.0 L-menthone 220.0 D-isornentone 50.0 L-menthol 483.5 Nonenolide 1.0 / zcznn / Lznz / E / Yii Table LVIIIB Flavor Wintergreen PF2 (Amounts in % by weight) Ingredients Quantity Substance of the formula (I) 8 Anethole 9 l-menthol (natural or synthetic) 45 Peppermint oil of the piperita type 2 Mint oil of the arvensis type 3 Green mint oil of the spicata type 1 Eugenol 7 215 Eucalyptol 5 Methyl salicylate 20 / zcznn / Lznz / E / Yii Table LVIIIC Isoamyl acetate type flavoring PF3 (Amounts in % by weight) Ingredients Quantity I Quantity II Substance of formula (I) 4 5 Isoamyl acetate 2 2 Ethyl butyrate 0,5-Butyl butyrate - 0,5 Ethyl vanillin 2-Vanillin-1 Frambinon TM [4-(4-hydroxyphenyl) -2-butanone] 0.5 0.5 1-menthol 8 11 Triacetin 80 1,2-propylene glycol 83 216 / zcznn / Lznz / E / YiA Table LVIIID Cinnamon-type fresh flavor PF4 (Amounts in % by weight) Ingredients Amount Substance of the formula (I) 3 Menthlymethylether 3 Cinnamonidehyde 10 Anethole 9 Eugenol 2 1-menthol 40 Peppermint oil type piperita 10 Peppermint oil type arvensis 10 Oil green mint type spicata 8 (IR.2S.5R)-N -ethyl-2-isopropyl-5- methylcyclohexanecarboxamide (WS-3) 2 (IR.2S.5R)-N-[4-cyanomethylphenyl]-2-isopropyl-5- methylcyclohexanecarboxamide 0.5 Menthone glycerol ketal (Frescolat MGA®) 1.5 217 Menthol propylene glycol carbonate (Frescolat MPC®) 1.5 / zcznn / ίζηζ / Ε / γι LIX table Toothpaste (Amounts in % by weight) Ingredients Quantity Water (deionized) Add 100 Sorbitol 70% 45.00 Trisodium Phosphate 0.10 Saccharin 0.20 Sodium Monofluorophosphate 1.14 PEG 1500 5.00 Sident 9 (silica abrasive) 10.00 Sident 22 S (silica thickener) 8.00 Sodium carboxymethylcellulose 1.10 Titanium (IV) oxide 0.50 Water (deionized) 4.50 218 Sodium lauryl sulfate (SLS) 1.50 Flavor (PF1. PF2. PF3 or PF4) 1.00 Solbrol M (sodium salt) (methylparaben) 0.15 4-hydroxyacetophenone 0.40 Table LX / zcznn / Lznz / E / Yii Toothpaste with zinc citrate (Amounts in % by weight) Ingredients Amount Water (deionized) Add 100 Sorbitol 70% 45.00 Trisodium Phosphate 0.10 Saccharin 0.20 Sodium Monofluorophosphate 1.14 PEG 1500 5.00 Sident 9 (silica abrasive) 10.00 Sident 22 S (silica thickener) 8.00 219 Sodium Carboxymethyl Cellulose 1.10 Zinc Citrate 1.00 Titanium Oxide (IV) 0.50 Water (Deionized) 4.50 Sodium Lauryl Sulfate (SLS) 1.50 Flavor (PEI. PF2. PF3 or PF4) 1.00 SymDiol® 68 (1,2-hexanediol. Caprylyl glycol) 0.25 4-hydroxyacetophenone 0.10 / zcznn / ίζηζ / Ε / γι Table LXXI Mouthwash (Amounts in % by weight) Ingredients Quantity Ethyl alcohol 10.00 Cremophor CO 40 (PEG 40 hydrogenated castor oil) 1.00 Flavor (PEI. PF2. PF3 or PF4) 0.25 Water (deionized) Up to 100.00 Sorbitol 70% 5.00 220 Sodium Saccharin 450 0.07 Sodium Fluoride 0.18 Benzoic Acid 0.12 4-Hydroxyacetophenone 0.30 / zcznn / Lznz / E / Yii Table LXIII Gel toothpaste (Amounts in % by weight) Ingredients Quantity Carboxymethylcellulose of Na 0.40 Sorbitol 70%. in water 72.00 Polyethylene glycol (PEG) 1500 3.00 Na saccarinate 0.07 Sodium fluoride 0.24 Flavor (PF1. PF2. PF3 or PF4) 1.00 Abrasive silica 11.00 Thickening silica 6.00 Dodecyl sulfate Sodium (SDS) 1.40 Water, dest Add 221 100 p-Hydroxybenzoic acid ethyl ester (PHB) 0.15 4-hydroxyacetophenone 0.20 / zcznn / Lznz / E / YiAi Table LXIII Toothpaste against plaque (Amounts in % by weight) Ingredients Quantity Carrageenan 0.90 Glycerol 15.00 Sorbitol 70%. in water 25.00 PEG 1000 3.00 Sodium Fluoride 0.24 Tetrapotassium Diphosphate 4.50 Tetrasodium Diphosphate 1.50 Na Saccarinate 0.40 Precipitated Silica 20.00 Titanium Dioxide 1.00 222 Triclosan 0.30 Spearmint flavor (comprising 60% by weight of 1-carvone and 25% by weight of 1-menthol) 1.00 Sodium dodecyl sulfate 1.30 Water, dest Add 100 Benzyl alcohol 0.50 4- hydroxyacetophenone 0.25 Table LXIV / zcznn / Lznz / E / YiAi Toothpaste for sensitive teeth (Amounts in % by weight) Ingredients Quantity Na carboxymethylcellulose 0.70 Xanthan gum 0.50 Glycerol 15.00 Sorbitol 70%. in water 12.00 Potassium nitrate 5.00 Sodium monofluorophosphate 0.80 Sodium saccharinate 0.20 223 Flavor (PF1. PF2. PF3 or PF4) 1.00 Ca carbonate 35.00 Silicon dioxide 1.00 Sodium dodecyl sulfate (SDS) 1.50 Water, dest Add 100 PHB methyl ester and PHB propyl ester 0 .20 Substance of formula (I) 0.50 / zcznn / Lznz / E / Yii Table 65 2-in-1 toothpaste and mouthwash product (Amounts in % by weight) Ingredients Amount Sorbitol 40, 00 Glycerol 20, 00 Ethanol 5, 00 Water Add 100 224 Sodium Monofluorophosphate 0.75 Saccharin 0.20 Sident 9 (Silicon Dioxide Abrasive) 20.00 Sident 22 S (Silicon Dioxide Thickener) 2.00 Sodium Carboxymethylcellulose 0.30 Sodium Lauryl Sulfate (SDS) 1.20 Color (Susp. 1% in water) C.I. Blue pigment 15 0.50 Flavor (PEI. PF2. PF3 or PF4) 0.90 Sodium salt of Solbrol M. (methylparaben. Sodium salt) 0.20 Substance of formula (I) 0.30 Table LXVI Ready-to-use fluoride mouthwash (Amounts in % by weight) Ingredients Amount Ethanol 7.00 Glycerol 12.00 Sodium Fluoride 0.05 / zcznn / Lznz / E / Yii 225 Pluronic F-127® (BASF. Surfactant) 1.40 Na phosphate buffer pH 7.0 1.10 Sodium saccharinate 0.10 Flavor (PF1. PF2. PF3 or PF4) 0.15 Chlorhexidine digluconate 0. 2 Water, dest up to 100 Sorbic acid 0.20 Substance of formula (I) 0.30 Table LXVII Sugar-free chewing gum (Amounts in % by weight) Ingredients Amount Chewing gum base 30, 00 Sorbitol. powder Add 100 Palatinite 9, 50 Xylitol 2, 00 226 Mannitol 3.00 Aspartame 0.10 Acesulfame K 0.10 Emulgum / emulsifier 0.30 Sorbitol 70%. in water 14.00 Glycerol 1.00 Flavor (PEI. PF2. PF3 or PF4) 1.50 Substance of formula (I) 0.20 / zcznn / Lznz / E / Yii 227

Claims

1. An antimicrobial mixture characterized in that it comprises or consists of (a) a first antimicrobial agent selected from group 5 consisting of at least one acetophenone derivative of formula (I) OR! (I) wherein 10 Ri represents hydrogen or methyl, and R2 represents hydrogen, hydroxyl or an OCH3 group, or a cosmetically or pharmaceutically acceptable salt thereof, and 15 (b) at least one second antimicrobial agent selected from the group consisting of preservatives selected from the group consisting of 1-(3-chloroallyl)-3,5,7-triaza-l-azoniaadamantane chloride, 1-(4-chlorophenoxy)-1-(IH-imidazol-l-yl)-3,3-dimethyl-2-butanone, l-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)pyridone, 2-aminoethanol (Octopirox), 1,1'-methylene-bis(3-(1-hydroxymethyl-2,4-dioxymidazolidin-5-yl)urea), 1,2- benzisothiazol-3(2H)-one, 1,2-decanediol, 1,2-decanediol, 1,2-dibromo-2,4-dicyanobutane, 1,3-bis(hydroxymethyl)-l-(l,3,4-tris(hydroxymethyl)-2,5-dioxoimidazolidin-4-yl)urea (diazolidinyl urea), 1,3-bis-(hydroxymethyl)-5,5-dimethyl-2,4-imidazolidindione, 1,3-bis(hydroxymethyl)-5,5-dimethylimidazolidin-2,4-dione, 1,5-pentanediol, 1,6-bis(4-amidino-2-bromophenoxy)-n-hexane and its salts, 1,6-bis(4-amidinophenoxy)-n-hexane and its salts, 1,6-hexanediol, / zcznn / Lznz / E / Yii 229 1,8-octanediol, 1O-undecylenic acid and its salts, 1—phenoxypropan-2-o1, 2,2'-methylene-bis(6-bromo-4-chlorophenol), 2,4,4'-Trichloro-2'-hydroxy-diphenyl ether (triclosan), 2,4-Dichlorobenzyl alcohol, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)-urea, 2-Benzyl-4-chlorophenol, 2-Benzylheptan-1-ol, 2-Bromo-2-(bromomethyl)pentanedinitrile, 2-Bromo-2-nitro-1,3-propanediol (Bronopol), 2-Butyloctanoic acid, 2-Chloroacetamide, Chlorhexidine, 2-Hydroxybiphenyl ether and its salts, 2-Methyl-3(2H)-isothiazolinone and with magnesium chloride and magnesium nitrate, 2-Octyl-2H-isothiazol-3-one, 2-Phenoxyethanol, 2-Zinc-sulfidopyridine N-oxide, Acid 2,4-hexadienoic (sorbic acid) and its salts (e.g., potassium salt), 3-(4-chlorophenoxy)-1,2-propanediol, / zcznn / Lznz / E / Yii 230 3-(4-chlorophenoxy)-1,2-propanediol (Chlorphenesin), 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, 3-benzyloxy-propan-1,2-diol, 3-iodo-2-propynyl butylcarbamate, 3-phenoxy-propan-1,2-diol, 3-phenoxypropanol, 4,4-dimethyl-1,3-oxazolidine, 4-chloro-3,5-dimethylphenol, 4-chloro-m-cresol, 4-ethylmercury-(II)5-amino-1,3-bis(2-hydroxybenzoic acid), its salts and esters, 4-hydroxybenzaldehyde, 4-isopropyl-3-methylphenol (Cymen-5-ol) 5-amino-1,3-bis(2-ethylhexyl)-5-methylhexahydropyrimidine, 5-bromo-5-nitro-1,3-dioxane, 5-chloro-2-methyl-3(2H)-isothiazolinone, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, alkyl-(Cg-Cis)-dimethylbenzylammonium bromide, alkyl-(Cg-Cis)-dimethylbenzylammonium chloride, alkyl-(Cg-Cis)-dimethylbenzylammonium saccharinate, anisic acid and its salts, / zcznn / Lznz / E / Yii 231 benzoic acid and parahydroxybenzoic acid, its asters and salts,benzyl alcohol, benzyl benzoate, benzyl hemiformal, benzyloxymethanol, benzyloxymethoxymethanol, hexamethylenetetramine, bis(2-pyridylthio)zinc 1,1'-dioxide, N,N'-(decane-1,10-diyldipyridin-1-11-4-ylidene)dioctan-l-amine dihydrochloride (octenidine dihydrochloride), bromochlorophene, caprylhydroxamic acid, capryloyl glycine, cetylpyridinium chloride, chitosan, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, chlorobutanol, cinnamic acid and its salts, cinnamic alcohol, cinnamic aldehyde, / zcznn / Lznz / E / Yii 232 climbazole, / zcznn / Lznz / E / Yii dehydracetic acid, diazolidinylurea, DMDM ​​hydantoin, ethylenediamine tetra acetate (EDTA) ethylenedioxy-dimethanol, ethyl lauroyl arginate HCL ethylmercury-(II)-thiosalicylic acid sodium salt, eugenol, farnesol, formaldehyde and paraformaldehyde, formic acid. glutaraldehyde, glyceryl monolaurate, glyceryl caprylate, glyceryl caprate hyamines, imidazolidinylurea,inorganic sulfites and bisulfites, levulinic acid and its salts, N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine, N-alkyl (C12-C22) trimethyl ammonium bromide and chloride, 233 N-hydroxymethyl-N-(1,3-di(hydroxymethyl)-2,5-dioxoimidazolidin-4-yl)-N'-hydroxymethylurea, ortho-, meta- and para-anisic aldehyde, perilic acid and its salts, phenylmercury and its salts, poly(hexamethylenediguanide) hydrochloride, propionic acid and its salts, salicylic acid and its salts, pyridine-2-thiol-1-oxide, sodium benzoate, sodium hydroxymethylaminoacetate, sodium hydroxymethylglycinate, sodium iodate, sorbitan caprylate, sorbohydroxamic acid, tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo[4,5d]imidazole-2,5(1H,3H)-dione, thymol, tropolone, undecenoyl glycine a,a',a-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)triethanol, / zcznn / Lznz / E / Yii 234 and its mixtures. / zcznn / Lznz / E / YiA, 2. The mixture of claim 1, characterized in that the acetophenone derivatives are selected from the group consisting of (a): 2-hydroxyacetophenone (b): 3-hydroxyacetophenone OH (c): 4-hydroxyacetophenone (b) at least a second antimicrobial agent selected from the group consisting of preservatives selected from the group consisting of: 1-(3-chloroallyl)-3,5,7-triaza-l-azonia235 adamantane chloride, 1-(4-chlorophenoxy)-1-(IH-imidazol-l-yl)-3,3-dimethyl-2-butanone, l-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)-pyridone, 2-aminoethanol (Octopirox) 1,1'-methylene-bis(3-(l-hydroxymethyl-2,4-dioximidazolidin-5-yl)urea), 1,2-benzisothiazol-3(2H)-one, 1,2-decanediol, 1,2-decanediol, 1,2-dibromo-2,4-dicyanobutane, 1,3-bis(hydroxymethyl)-1-(1,3,4-tris(hydroxymethyl)-2,5-dioxoimidazolidin-4-yl)urea (diazolidinyl urea), 1,3-bis-(hydroxymethyl)-5,5-dimethyl-2,4-imidazolidindione, 1,3-bis(hydroxymethyl)-5,5-dimethylimidazolidin-2,4-dione, 1,5-pentanediol, 1,6-bis(4-amidino-2-bromophenoxy)-n-hexane and its salts, 1,6-bis(4-amidinophenoxy)-n-hexane and its salts, 1,6-hexanediol, 1,8-octanediol, 1O-undecylenic acid and its salts, 1-phenoxypropan-2-ol, / zcznn / Lznz / E / Yii 236 2,2'-methylene-bis(6-bromo-4-chlorophenol), 2,4,4'-trichloro-2'-hydroxydiphenyl ether (triclosan), 2,4-dichlorobenzyl alcohol, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)-urea, 2,4-hexadienoic acid (sorbic acid) and its salts (e.g., potassium salt), 2-benzyl-4-chlorophenol, 2-benzylheptan-1-ol, 2-bromo-2-(bromomethyl)pentanedinitrile, 2-bromo-2-nitro-1,3-propanediol (Bronopol), 2-butyloctanoic acid, 2-chloroacetamide, chlorhexidine, 2-hydroxybiphenyl ether and its salts, 2-methyl-3(2H)-isothiazolinone and with magnesium chloride and magnesium nitrate, 2-octyl-2H-isothiazol-3-one, 2-phenoxyethanol, 2-zinc-sulfidopyridine N-oxide, 3-(4-chlorophenoxy)-1,2-propanediol, 3-(4-chlorphenoxy)-1,2-propanediol (Chlorphenesin), 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, 3-benzyloxy-propan-l,2-diol, / zeznn / Lznz / E / Yii 237 3-iodo-2-propynyl butylcarbamate, 3-phenoxy-propan-1,2-diol, 3-phenoxypropanol, 4,4-dimethyl-l,3-oxazolidine, 4-chloro-3,5-dimethylphenol, 4-chloro-m-cresol, Acid 4-ethylmercury-(II)5-amino-l,3-bis(2hydroxybenzoic acid), its salts and esters, 4-hydroxy benzaldehyde, 4-isopropyl-3-methylphenol (Cymen-5-ol) 5-amino-l,3-bis(2-ethylhexyl)-5-methyl-hexahydropyrimidine, 5-bromo-5-nitro-l,3-dioxane, 5-chloro-2-methyl-3(2H)-isothiazolinone, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, alkyl-(Cg-Cis)-dimethylbenzylammonium bromide, alkyl-(Cg-Cis)-dimethylbenzylammonium chloride, alkyl-(Cg-Cis)-dimethylbenzylammonium saccharinate, anisic acid and its salts, benzoic acid and parahydroxybenzoic acid, their esters and salts, benzyl alcohol, benzyl benzoate, / zcznn / Lznz / E / Yii 238 benzyl hemiformal, benzyloxymethanol, benzyloxymethoxymethanol, hexamethylenetetramine, bis(2-pyridylthio)zinc 1,1'-dioxide, N,N'-(decane-1,10-diyldipyridin-l-yl-4-ylidene)-dioctan-1-amine (octenidine dihydrochloride), bromochlorophene, caprylhydroxamic acid, capryloyl glycine, cetylpyridinium chloride, chitosan, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, chlorobutanol, cinnamic acid and its salts, cinnamic alcohol, cinnamic aldehyde, climbazole, dehydracetic acid, diazolidinyl urea, DMDM ​​hydantoin, / zcznn / Lznz / E / Yii 239 ethylenediamine tetraacetate (EDTA), ethylenedioxydimethanol, ethyl lauroyl arginate HCl, sodium salt of ethylmercury-(II)-thiosalicylic acid, eugenol, farnesol, formaldehyde and paraformaldehyde, formic acid, glutaraldehyde, glyceryl monolaurate, glyceryl caprylate, glyceryl caprate, hyamines, imidazolidynyl urea, inorganic sulfites and bisulfites, levulinic acid and its salts, N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine, N-alkyl (C12-C22) trimethyl-ammonium bromide and chloride, N-hydroxymethyl-N-(1,3-di(hydroxymethyl)-2,5-dioxoimidazolidin-4-yl)-N'-hydroxymethylurea, ortho-, meta- and para-anisic aldehyde, perilic acid and its salts, phenylmercury and its salts, poly(hexamethylenediguanide) hydrochloride, propionic acid and its salts, salicylic acid and its salts, pyridine-2-thiol-l-oxide, sodium benzoate, sodium hydroxymethylaminoacetate, sodium hydroxymethylglycinate, sodium iodate, sorbitan caprylate, sorbohydroxamic acid, tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo[4,5-d]imidazol-2,5(1H,3H)-dione, thymol, tropolone, undecenoyl glycine a,a',a-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol, / zcznn / Lznz / E / Yii and their mixtures., 3. The mixture of claim 1 and / or 2, characterized in that said second antimicrobial agent is selected from the group consisting of: 241 4-Isopropyl-3-methylphenol Benzyl alcohol Bronopol Capryloyl glycine Climbazole, Crinipan Ethyl lauroyl arginate HC1 Ethylenediamine tetraacetate Glyceryl caprate Glyceryl caprylate 3-Iodo-2-propynylbutylcarbamate Polyhexamethylenebiguanide Piroctone olamine, Octopirox Potassium sorbate Sodium benzoate Sorbitan caprylate Triclosan Undecenoyl glycine 242 Undecylenic acid / zcznn / Lznz / E / YiAi 4. The mixture of any of claims 1 to 3, characterized in that the first and second antimicrobial agent are present in a weight ratio of approximately 1:99 to approximately 99:

1.

5. The mixture of any of claims 1 to 4, characterized in that the primary antimicrobial agent is 4-hydroxyacetophenone, and the first and second antimicrobial agents are present in the following weight ratios: Preferred secondary preservative Weight ratio 4-HAP: Secondary antimicrobials Preferred Most preferred Highest preference 4-isopropyl-3-methylphenol 10:1 - 1:10 8:1 - 1:1 4:1 Benzyl alcohol 5:1 - 1:5 3:1 - 1:3 1:1 Bronopol 2:1 - 1:12 1.5:1 - 1.1 : 1 243 1.5 Capryloylglycine 5:1-1 : 5 1:1-1 : 4 1 : 3 Climbazol, Crinipan 20:1 - 5:1 10:1 - 8:1 9 : 1 Ethyl lauroyl arginate HC1 5:1 - 1:5 3:1 - 1:3 1 : 1 Ethylenediamine tetraacetate 5:1-1 : 5 1:1-1 : 4 1 : 3 Glyceryl caprate 5:1 - 1:5 3:1 - 1:3 1 : 1 Glyceryl caprylate 5:1 - 1:5 3:1 - 1:3 1 : 1 IPBC, 3-iodo-2-propyninbutylcarbamate 150:1 - 50:1 120:1 - 80 :1 99 : 1 PHMB, polyhexamethylenebiguanide 10:1 - 1:1 5:1 - 2:1 4 : 1 Piroctona olamina, Octopirox 20:1 - 1:1 10:1 - 2:1 9 : 1 Sorbate de potasio 5:1 - 1:5 3:1 - 1:3 1 : 1 Benzonato de sodio 1:10 - 5:1 1:4 - 2:1 1 : 3 Caprylato de sorbitán 5:1 - 1:5 3:1 - 1:3 1 : 1 Triclosan 50:1 - 5:1 25:1- 19 : 1 / zcznn / Lznz / Ε / γΐΛΐ 244 10 :1 Undecenoyl glycine 2:1 - 1.2 1,5:1 - 1:1,5 1 : 1 Undecylenic acid 10:1 - 1:1 4:1 - 2:1 3 : 1 / zcznn / Lznz / E / YiAi.

6. A personal care composition, characterized in that it comprises an operative quantity of the mixture of any of claims 1 to 3. 5 7. A detergent composition, characterized in that it comprises an operational quantity of the mixture of any of claims 1 to 3.

8. A food composition, characterized in that it comprises an operational quantity of the mixture of any 10 of claims 1 to 3.

9. The personal care composition of claim 4, the detergent composition of claim 5, or the food composition of claim 6, characterized in that it contains the mixtures of any 15 of claims 1 to 3 in amounts of approximately 0.01 to approximately 10% by weight - calculated on the total composition. 245 10. A method for preserving a personal care composition, a detergent composition, or a food composition, characterized in that it is carried out by adding an operative amount of the mixture of any of claims 1 to 3.

11. A method for combating microorganisms, characterized in that it is carried out by adding an operative amount of the mixture of any of claims 1 to 3 to a personal care, detergent or food composition.

12. A method for combating unwanted body odor, characterized in that it is carried out by topical administration to the human skin of an operative amount of the mixture of any of claims 1 to 3.

13. The use of an operational quantity of the mixture of any of claims 1 to 3, characterized in that it is carried out as a preservative.

14. The use of an operational quantity of the mixture of any of claims 1 to 3, characterized in that it is carried out as a deodorant.