Lightweight concrete facade resistant to freezing cycle

WO2025037289A3PCT designated stage Publication Date: 2025-04-17SADIGH SARABI MOHAMMAD +1
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Patent Information

Application Number
PCT/IB2024/062253
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Filing Date
2024-12-05
Publication Date
2025-04-17

AI Technical Summary

Technical Problem

Traditional concrete facades are prone to cracking, spalling, and reduced lifespan due to repeated freeze-thaw cycles, compromising structural integrity and increasing maintenance costs in cold climates.

Method used

A novel lightweight concrete facade is developed with an optimized mix design incorporating marble dust and calcium dichloride, which enhances compressive strength, reduces permeability, and improves durability against freeze-thaw cycles.

Benefits of technology

The solution significantly increases the facade's resistance to freeze-thaw damage, extends its lifespan, reduces maintenance costs, and lowers environmental impact while maintaining lightweight properties.

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Abstract

This invention relates to a lightweight concrete facade with enhanced resistance to freeze-thaw cycles, designed to address the challenges of durability, strength, and environmental sustainability in construction. By incorporating marble dust as a partial replacement for cement (10-20% by weight), the concrete achieves significant improvements in performance, including a 30-45% increase in compressive strength and a 20-35% reduction in permeability. These enhancements are attributed to the refined microstructure and reduced porosity provided by the marble dust, which minimizes water infiltration and mitigates freeze-thaw damage. The concrete mix further utilizes optimized water-to-cement ratios, saturated surface dry (SSD) aggregates, and optional additives like calcium dichloride to enhance early strength and resistance to environmental stresses. This innovative solution is ideal for use in building facades, infrastructure, and modular construction, particularly in cold climates. The invention also promotes sustainability by repurposing marble industry waste, reducing cement consumption, and lowering the environmental impact of concrete production.
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Description

[0001] Description

[0002] Title of Invention: Lightweight concrete facade resistant to freezing cycle]

[0003] Technical Field

[0004] [ Civil engineering, Architecture, concrete ]

[0005] Background Art

[0006] The durability and performance of building materials are critical factors in modem construction, especially in regions with extreme climates. Facades, as the outermost layer of a building, are particularly susceptible to environmental stressors, including freeze-thaw cycles that can cause significant damage over time. Concrete is widely used for facades due to its strength and versatility, but traditional concrete materials often suffer from cracking, spalling, and reduced lifespan when subjected to repeated freezing and thawing cycles. This not only compromises structural integrity but also increases maintenance costs and environmental impact.

[0007] Lightweight concrete has emerged as a promising alternative due to its reduced density, ease of handling, and potential for energy efficiency in construction. However, existing lightweight concrete formulations are often limited in their ability to withstand freeze-thaw cycles without degradation. The challenge lies in maintaining a balance between reduced weight and enhanced resistance to the mechanical stresses and microcracking caused by water freezing and expanding within the concrete's pores.

[0008] To address this gap, this invention introduces a novel lightweight concrete facade with enhanced resistance to freeze-thaw cycles. By optimizing the mix design and incorporating advanced additives, this invention improves the material's resistance to water penetration, reduces pore size, and enhances its overall durability. This innovation offers a sustainable and cost-effective solution for creating durable facades that maintain their structural and aesthetic integrity in harsh climates.

[0009] The proposed lightweight concrete facade not only extends the lifespan of buildings but also contributes to reducing the environmental impact by lowering material and energy use in construction and maintenance. Its ability to combine lightweight properties with freeze-thaw resistance makes it a valuable advancement for modem construction, particularly in regions prone to severe winters and fluctuating temperatures.

[0010] Summary of Invention

[0011] The invention relates to a novel lightweight concrete facade designed to withstand the damaging effects of freeze-thaw cycles, a common cause of material degradation in cold climates. This innovative material combines the reduced weight of lightweight concrete with advanced resistance to freezing and thawing stresses, making it ideal for use in harsh environmental conditions.

[0012] Key features of the invention include: 1. Optimized Mix Design: A tailored composition of lightweight aggregates, binders, and supplementary materials to achieve high strength-to-weight ratios without compromising durability.

[0013] 2. Freeze-Thaw Resistance: Incorporation of advanced additives such as air-entraining agents, nano-silica, or polymer modifiers to reduce water absorption, refine pore structure, and enhance resistance to microcracking caused by water freezing and expanding within the material.

[0014] 3. Sustainability: Use of eco-friendly components, including recycled materials or industrial by-products, to lower the environmental impact of production and provide a sustainable alternative for facade applications.

[0015] 4. Durability and Longevity: Superior resistance to spalling, cracking, and material fatigue, ensuring structural and aesthetic integrity over extended periods, even under extreme temperature fluctuations.

[0016] This invention addresses a critical need for building materials that are lightweight yet durable, enabling the construction of energy-efficient and resilient structures. Its applications range from residential to commercial and industrial buildings, particularly in regions experiencing severe winters or frequent temperature changes. This lightweight concrete facade offers an innovative, cost-effective, and sustainable solution for enhancing the performance and lifespan of building exteriors.

[0017] Technical Problem

[0018] Technical Problems of Concrete Facades in Freezing Cycles:

[0019] 1. Freeze-Thaw Damage: Water infiltrating the concrete matrix freezes and expands, creating internal stresses that lead to cracking, spalling, and gradual structural deterioration. This is a critical concern for facades in cold climates with frequent temperature fluctuations.

[0020] 2. High Water Absorption and Porosity: Conventional concrete has a porous structure that facilitates moisture infiltration, increasing its vulnerability to freeze-thaw cycles. Unsealed or improperly treated concrete faces an elevated risk of water absorption, exacerbating damage.

[0021] 3. Microstructural Weakening: Repeated freeze-thaw cycles cause the formation of microcracks within the concrete matrix. While often imperceptible initially, these cracks propagate over time, compromising the material's mechanical integrity and lifespan.

[0022] 4. Surface Degradation: The surface layer of concrete facades is particularly prone to scaling and erosion under freeze-thaw cycles. This not only affects aesthetics but also exposes the inner layers to further moisture infiltration and accelerated degradation.

[0023] 5. Thermal Conductivity Issues: Concrete’s high thermal conductivity leads to increased heat loss, particularly in cold climates. This results in larger temperature differentials within the material, intensifying freeze-thaw stresses and further compromising structural performance.

[0024] 6. Maintenance Costs: Freeze-thaw damage necessitates frequent repairs and maintenance, significantly increasing the lifecycle costs of concrete facades in cold and wet environments.

[0025] 7. Sustainability Challenges: Traditional concrete production relies heavily on cement, a material associated with high carbon emissions. Enhancing durability to reduce freezethaw damage without increasing environmental impact remains a critical challenge.

[0026] 8. Design Flexibility: Limitations in the durability and performance of conventional concrete often restrict architectural and aesthetic possibilities for facades in cold climates.

[0027] Innovative Approach to Address These Problems: Incorporating marble dust as a partial replacement for cement addresses many of these issues effectively. Marble dust, a by-product of marble processing, enhances the physical and mechanical properties of concrete by refining its microstructure. Its fine particles reduce porosity, improve water resistance, and increase overall durability under freeze-thaw conditions. Additionally:

[0028] • Durability: Marble dust strengthens the interfacial transition zone (ITZ) within the concrete matrix, reducing microcrack formation during freeze-thaw cycles.

[0029] • Environmental Impact: Replacing a percentage of cement with marble dust lowers carbon emissions, contributing to sustainability.

[0030] • Cost-Effectiveness: By repurposing waste material, the overall cost of production is reduced while improving performance.

[0031] Solution to Problem

[0032] Solution to the Problem:

[0033] Solution leverages innovative mix designs and advanced materials, specifically incorporating marble dust to address the challenges faced by concrete facades in freeze-thaw cycles. The process and findings are based on rigorous laboratory experiments and multiple mix designs, resulting in a highly durable and less permeable concrete composition suitable for cold climates.

[0034] Process and Findings:

[0035] 1. Experimental Approach : o Over 15 mix designs were tested in the laboratory using standard concrete samples. o The water-to-cementitious material ratio was kept constant at 0.4, and marble dust was used as a partial replacement for cement at proportions of 0%, 5%, 10%, 15%, 20%, 19%, 18%, 17%, and 16%. o Coarse aggregates with a maximum size of 9 cm and fine aggregates with a fineness modulus of 2.5 were utilized. To ensure accuracy, aggregates were saturated for one hour and then prepared in a saturated surface dry (SSD) condition before mixing. 2. Optimized Mix Design: o The inclusion of marble dust combined with calcium dichloride significantly improved concrete properties:

[0036] ■ 30-45% increase in compressive strength.

[0037] ■ 20-35% reduction in permeability, enhancing resistance to water infiltration during freeze-thaw cycles.

[0038] 3. Smart Resistance Control: o During mixing, a specific proportion of calcium dichloride was introduced as a partial weight replacement for cement without altering the water content. o This unique chemical reaction between cement and calcium dichloride optimized the strength and durability of concrete under freezing conditions.

[0039] 4. Industrial Application: o The innovative reaction process can be integrated directly into cement production at manufacturing plants, enabling large-scale adoption. o The unique combination of materials and their compatibility with traditional concrete components ensures the practical application of this invention.

[0040] 5. Novelty and Defensibility: o The distinct chemical composition and the precise compatibility ratios of calcium di chloride and marble dust with cement are the basis of this patent’s novelty. o Based on extensive research and laboratory validation, the solution addresses a previously unsolved problem, providing an approach without comparable domestic or international alternatives.

[0041] Impact:

[0042] This optimized concrete mix provides a transformative solution to the technical challenges of freeze-thaw damage in concrete facades. By improving strength, reducing permeability, and ensuring industrial scalability, this invention presents a practical and sustainable approach to enhancing the durability and performance of concrete structures in extreme climates.

[0043] Advantageous Effects of Invention

[0044] The invention of a lightweight concrete facade resistant to freeze-thaw cycles, incorporating marble dust and calcium dichloride, provides several unique and advantageous effects:

[0045] 1. Enhanced Freeze-Thaw Resistance: o The optimized mix design reduces water absorption and microcracking, significantly improving the facade’s ability to withstand repeated freeze-thaw cycles without degradation.

[0046] 2. Increased Durability: o Incorporating marble dust and calcium dichloride enhances the compressive strength of concrete by 30-45%, ensuring greater longevity and structural integrity under extreme conditions.

[0047] 3. Improved W ater Resistance : o Reduced permeability by 20-35% protects the facade against water infiltration, minimizing internal stresses caused by freezing water and ensuring long-term performance.

[0048] 4. Lightweight Properties: o The use of lightweight aggregates and marble dust reduces the overall weight of the concrete, making it easier to handle and install while reducing dead loads on structures.

[0049] 5. Cost- Effectiveness: o Utilizing marble dust, a by-product of the marble industry, lowers material costs while repurposing industrial waste, contributing to both economic and environmental benefits.

[0050] 6. Sustainability: o The partial replacement of cement with marble dust reduces carbon emissions associated with cement production, aligning the invention with global sustainability goals.

[0051] 7. Improved Surface Quality: o The inclusion of fine marble dust refines the concrete's surface, offering improved aesthetic appeal and resistance to surface scaling and erosion caused by environmental exposure.

[0052] 8. Industrial Scalability: o The integration of calcium dichloride into the mix can be implemented directly in cement manufacturing plants, enabling large-scale production and adoption of the invention.

[0053] 9. Lower Maintenance Costs: o Increased durability and resistance to environmental stressors reduce the frequency and cost of repairs, extending the service life of the facade and lowering lifecycle costs.

[0054] 10. Architectural Flexibility: o By improving the strength and performance of the concrete while maintaining its lightweight properties, the invention provides greater design flexibility for architects, enabling creative and durable facade designs.

[0055] Conclusion:

[0056] The invention addresses the critical challenges of freeze-thaw cycles, providing a durable, lightweight, and sustainable solution for concrete facades. It enhances structural and aesthetic performance while reducing costs, environmental impact, and maintenance needs, making it a highly advantageous innovation for construction in cold climates.

[0057] Brief Description of Drawings

[0058] [Table 1: Experimental Mix Designs and Results

[0059] This table summarizes the results of various experimental mix designs used to optimize the properties of concrete incorporating marble dust. The data includes: • Water- to-Cement Ratio (w / c): Maintained at a constant value of 0.4 across all experiments.

[0060] • Marble Dust Replacement (%): Ranges from 0% (control mix) to 20%, showing the effect of increasing marble dust on concrete properties.

[0061] • Compressive Strength Improvement (%): Demonstrates up to 40% improvement in load-bearing capacity with 20% marble dust replacement.

[0062] • Permeability Reduction (%): Indicates a significant reduction (up to 30%) in water infiltration, enhancing freeze-thaw resistance.

[0063] This table highlights the optimal mix design (20% marble dust) for achieving the best balance of strength and durability.

[0064] Table 2: Material Characteristics

[0065] This table provides the key properties, functions, and advantages of materials used in the concrete mix:

[0066] • Concrete: Standard compressive strength and porosity metrics, demonstrating its versatility as a construction material.

[0067] • Water: Describes purity and activation role in cement hydration, ensuring uniformity in the mix.

[0068] • Marble Dust: Outlines its fine particle size and high calcium carbonate content, which enhances durability and sustainability by refining the microstructure.

[0069] • Coarse Aggregates: Bulk material providing strength and dimensional stability.

[0070] • Fine Aggregates: Fills voids to improve workability and surface finish.

[0071] This table illustrates how each material contributes to the overall performance and durability of the optimized concrete mix.

[0072] Table3 : provides a detailed summary of the percentage improvements in concrete properties achieved through the incorporation of marble dust. It includes the following key attributes:

[0073] Highlights from the Table:

[0074] • Compressive Strength: o Improvement of 40% due to enhanced interfacial bonding and reduced microvoids. o Results in greater load-bearing capacity and resistance to structural stress.

[0075] • Durability: o Improvement of 45% attributed to reduced permeability and protection against environmental degradation. o Extends the lifespan of the structure while lowering maintenance costs.

[0076] • Freeze- Thaw Resistance: o Improvement of 35% through reduced water absorption and minimized microcracking. o Protects against cracking and spalling in cold climates, ensuring long-term stability.

[0077] This table emphasizes the practical advantages of marble dust incorporation in concrete, offering clear insights into how it enhances performance in key areas critical for cold climate applications.

[0078] Examples

[0079] Examples of Applications for the Lightweight Concrete Facade Resistant to Freezing Cycle

[0080] 1. Residential Housing in Cold Climates: o Application: Construction of single-family homes and multi-story residential complexes in regions like Alaska, Canada, or Scandinavia, where freeze-thaw cycles are prevalent. o Impact: Ensures long-term durability of facades, reducing maintenance costs and enhancing energy efficiency. rcial Buildings: Application: Facades for office buildings, shopping malls, and hotels in urban areas prone to harsh winters. Impact: Provides an aesthetically appealing, lightweight, and durable solution that withstands environmental stresses while reducing structural loads.ucture Projects: Application: Retaining walls, bridges, and highway sound barriers exposed to frequent freeze-thaw cycles and water infiltration. Impact: Enhances the lifespan of critical infrastructure while reducing repair and rehabilitation costs. icated Modular Construction: Application: Use in modular panels for prefabricated structures, including temporary housing and disaster relief shelters in cold climates. Impact: Allows rapid deployment with durable and lightweight materials that are easy to transport and install. al Facilities: Application: Exterior walls of warehouses, factories, and storage facilities that experience fluctuating temperatures and require low maintenance. Impact: Ensures structural integrity and thermal stability, reducing operational costs. ional and Public Buildings: Application: Facades for schools, sports complexes, and community centers in regions with extreme winters. Impact: Offers a cost-effective solution for public projects while maintaining high performance under environmental stress. al Building Restoration: Application: Retrofitting of existing structures with lightweight concrete facades to improve freeze -thaw resistance without compromising the building’s integrity. Impact: Preserves heritage sites while extending their usability and reducing repair frequency. Construction: Application: Buildings near cold coastlines where saltwater exposure and freeze-thaw cycles cause accelerated degradation. Impact: Combats the combined effects of water infiltration, freezing, and salt- induced corrosion. 9. High- Altitude Developments: o Application: Facades for resorts, research stations, and military bases located in mountainous or high-altitude regions. o Impact: Ensures durability and safety in extreme conditions, where freeze-thaw cycles are intense and frequent.

[0081] 10. Environmentally Sustainable Projects: o Application: Green building projects incorporating recycled materials and sustainable construction practices. o Impact: Marble dust reduces cement usage, aligning with sustainability goals while providing high-performance materials.

[0082] Industrial Applicability

[0083] [The invention is highly applicable across various industrial sectors due to its unique combination of durability, sustainability, and cost-effectiveness. Below are key areas where this invention can be implemented:

[0084] 1. Construction Industry

[0085] • Applications: o Residential, commercial, and industrial building facades. o Prefabricated panels for modular construction. o Structural elements like retaining walls, beams, and slabs.

[0086] • Industrial Benefits: o Reduces maintenance and repair costs due to improved durability. o Lightweight design minimizes structural load, enabling cost savings in construction. o Enhances performance in cold climates, making it ideal for regions with extreme temperature variations.

[0087] 2. Infrastructure Development

[0088] • Applications: o Bridges, highways, and sound barriers exposed to environmental stresses. o Railway sleepers and airport runways requiring freeze-thaw resistance. Industrial Benefits: o Extends the lifespan of critical infrastructure, reducing lifecycle costs. o Improves reliability and safety of infrastructure under severe weather conditions. refabrication Industry

[0089] • Applications: o Precast concrete panels for rapid construction projects. o Modular components for temporary or permanent structures.

[0090] • Industrial Benefits: o Enables faster production and installation due to lightweight and high- performance materials. o Ideal for disaster relief, temporary housing, and remote area projects. nergy and Utility Sectors

[0091] • Applications: o Construction of power plants, storage tanks, and pipelines in cold regions. o Wind turbine foundations and support structures exposed to cyclic loading.

[0092] • Industrial Benefits: o Enhances resistance to environmental stresses, ensuring operational stability. o Reduces maintenance in remote or harsh environments. etrofitting and Rehabilitation

[0093] • Applications: o Strengthening and retrofitting of existing buildings, particularly in cold and coastal regions. o Restoration of historical structures requiring lightweight and durable materials. Industrial Benefits: o Provides a sustainable solution for extending the usability of aging infrastructure. o Allows retrofitting without significant structural modifications.

[0094] 6. Sustainable Construction

[0095] • Applications: o Green building projects focusing on energy efficiency and reduced carbon footprints. o Use of recycled industrial by-products like marble dust in eco-friendly construction.

[0096] • Industrial Benefits: o Reduces reliance on traditional cement, lowering CO2 emissions. o Supports circular economy practices by repurposing marble waste.

[0097] 7. Military and High-Altitude Construction

[0098] • Applications: o Building durable military bases, bunkers, and observation posts in high- altitude or polar regions. o Constructing research stations in remote and extreme climates.

[0099] • Industrial Benefits: o Ensures safety and longevity of structures in challenging conditions. o Provides a lightweight solution for transportation and installation in remote areas.

[0100] Conclusion:

[0101] This invention has broad industrial applicability, particularly in sectors that require durable, sustainable, and lightweight construction materials. Its ability to withstand freeze-thaw cycles, combined with its eco-friendly nature, makes it a highly valuable innovation for both traditional and modem construction practices, j

Claims

ClaimsClaim 1:A lightweight concrete mix for facades resistant to freezing cycles, comprising:• Cementitious material, wherein 10-20% of cement is replaced with marble dust by weight,• Coarse aggregates with a maximum size of 9 cm, and fine aggregates with a fineness modulus of 2.5,• A water-to-cement ratio (w / c) of 0.4, ensuring optimal hydration and workability,• Additives such as calcium dichloride to enhance early strength and freeze-thaw resistance.Claim 2:The lightweight concrete mix of Claim 1, wherein the marble dust improves the concrete's compressive strength by 30-45% compared to conventional concrete.Claim 3:The lightweight concrete mix of Claim 1, wherein the incorporation of marble dust reduces the concrete's permeability by 20-35%, enhancing its resistance to water infiltration and subsequent freezethaw damage.Claim 4:The lightweight concrete mix of Claim 1, wherein the refined microstructure achieved by the marble dust minimizes porosity, thereby improving durability and extending the lifespan of the facade.Claim 5:A method of producing lightweight concrete facades resistant to freeze-thaw cycles, comprising:

1. Preparing aggregates in a saturated surface dry (SSD) condition by pre-soaking them in water,2. Mixing cement, marble dust, aggregates, water, and optional additives in predetermined proportions,3. Curing the concrete under controlled conditions to achieve optimal strength and durability.Claim 6:The method of Claim 5, wherein the curing process includes maintaining humidity and temperature levels to minimize shrinkage and cracking.Claim 7:A concrete facade made from the lightweight concrete mix of Claim 1, designed to withstand severe freeze-thaw cycles without cracking, spalling, or degradation.Claim 8:The concrete facade of Claim 7, wherein the lightweight properties reduce the structural load, enabling cost-effective and sustainable construction practices.Claim 9:The lightweight concrete mix of Claim 1, wherein the marble dust is sourced as a by-product from marble processing, contributing to sustainability and reducing environmental impact.Claim 10:The lightweight concrete mix of Claim 1, suitable for use in:• Residential, commercial, and industrial facades,• Prefabricated panels for modular construction,• Infrastructure projects exposed to extreme environmental conditions.

Citation Information

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