Composition comprising triglycerides

Abstract

The invention relates to a composition comprising certain triglycerides with a low content of cyclopropenoid fatty acid acyl (CPFA) groups and tocopherol as well as the use of this composition, especially in cosmetic applications, and a method for treating baobab oil.

Description

[0001] 202300186 Foreign Filing 1 Composition comprising triglycerides Field of the invention The invention relates to a composition comprising certain triglycerides with a low content of cyclopropenoid fatty acid (CPFA) acyl groups while maintaining a high content of tocopherol as well as the use of this composition, especially in cosmetic applications, and a method for treating baobab oil. Prior art Baobab oil is used in the cosmetics industry because of its caring, skin soothing, moisturizing and antioxidant effects. It is extracted from the seed of the baobab fruit. The natural baobab oil obtained by pressing the seeds typically contains 5–7% triglycerides with cyclopropenoid fatty acid (CPFA) acyl groups. Due to its toxicity potential, it is hardly used in the food industry and only to a very limited extent in the cosmetics industry, because the toxic cyclopropenoid fatty acids are released by hydrolysis of the triglyceride. In baobab oil market products the content of triglycerides with cyclopropenoid fatty acid acyl groups is commonly unchanged compared to the natural oil. Treatment of baobab oil by heat, possibly combined with steam, can destroy CPFA acyl groups, but also reduces the residual amounts of vitamins, other tocopherols and phytosterols that are valuable as active ingredients. In refined and even deodorized variants of baobab oil, the content of triglycerides with cyclopropenoid fatty acid acyl groups is therefore often reduced, but still at a toxicologically critical level of more than 1%. Also, polycyclic aromatic hydrocarbons (PAH), which are known to be cancerogenic in some cases, are frequently generated by a harsh temperature treatment. The typical procedures for triglyceride exploitation and refinement are described in Ullmann’s Encyclopedia of Industrial Chemistry by Alfred Thomas, Bertrand Matthäus and Hans-Jochen Fiebig in the chapter „Fats and Fatty Oils“, published on September 30th, 2015. The object of the present invention was therefore to provide a baobab oil, especially for the cosmetics industry, that has a significantly lower content of triglycerides with cyclopropenoid fatty acid acyl groups but still comprises tocopherols at high amounts, which is beneficial for the oxidative stability. 202300186 Foreign Filing 2 Description of the invention it was found that the disadvantages from the prior art described above can be overcome by subjecting the baobab oil to a certain temperature treatment while passing water steam through the oil. The instant invention thus provides a composition comprising certain triglycerides with a low content of cyclopropenoid fatty acid acyl (CPFA) groups and a high content of tocopherols as well as the use of this composition, especially in cosmetic applications, and a method for treating baobab oil. An advantage of the present invention is that the baobab oil according to the instant invention has a reduced toxicity potential. An advantage of the present invention is that the baobab oil according to the instant invention has a high viscosity. An advantage of the present invention is that the baobab oil according to the instant invention has a feeling of higher richness on the skin. An advantage of the present invention is that the baobab oil according to the instant invention has a more pronounced velvetiness on the skin. An advantage of the present invention is that the baobab oil according to the instant invention has a higher oxidation stability. An advantage of the present invention is that the baobab oil according to the instant invention provides an improved stability of a cosmetic formulation. An advantage of the present invention is that the baobab oil according to the instant invention has a more neutral odor. The instant invention encompasses a composition comprising a triglyceride mixture with a distribution of fatty acid acyl groups in the triglycerides of 18 wt-% to 34 wt-%, preferably 20 wt-% to 30 wt-%, more preferably 21 wt-% to 28 wt-%, palmitoyl, 0.5 wt-% to 10 wt-%, preferably 1.0 wt-% to 9.0 wt-%, more preferably 2.0 wt-% to 7.0 wt-%, stearoyl, 28 wt-% to 44 wt-%, preferably 30 wt-% to 42 wt-%, more preferably 31 wt-% to 41 wt-%, oleoyl, 18 wt-% to 34 wt-%, preferably 21 wt-% to 31 wt-%, more preferably 22 wt-% to 30 wt-%, linoleoyl, less than a total of 1.0 wt-%, preferably 0.01 wt-% to 0.7 wt-%, more preferably 0.05 wt-% to 0.4 wt-%, cyclopropenoid fatty acid acyl groups, wherein the weight percents refer to all fatty acid acyl groups comprised in all triglycerides comprised in the composition, characterised in that the composition comprises 202300186 Foreign Filing 3 100 ppm to 2000 ppm, preferably 200 ppm to 1500 ppm, more preferably 300 ppm to 1250 ppm, most preferably 400 ppm to 1100 ppm, tocopherol, wherein the ppm refer to the total composition. Unless stated otherwise, all percentages (%) given are percentages by mass, the same applies to part per million (ppm) and part per billion (ppb). The cyclopropenoid fatty acid acyl groups preferably most abundant in the composition according to the instant invention are those of sterculic acid [8-(2-octyl-1-cyclopropenyl) octanoic acid] and malvalic acid [7-(2-octyl-1-cyclopropenyl) heptanoic acid]. The content of the CPFAs is analyzed by GC after complete saponification of the triglycerides. ISO 15884 is the preferred method. Another suitable method is described in “Upendo L. Msalilwa, Edna E. Makule, Linus K. Munishi, Patrick A. Ndakidemi, Physicochemical Properties, Fatty Acid Composition, and the Effect of Heating on the Reduction of Cyclopropenoid Fatty Acids on Baobab (Adansonia digitata L.) Crude Seed Oil. Journal of Lipids 2020, 1-13”. The term “tocopherol” in the context of the instant invention encompasses α-tocopherol, β- tocopherol, γ-tocopherol and δ-tocopherol. The respective molecular structures are in accordance with “Kolter T, Tocopherole, RD-20-01995 (2011) in Böckler F.;Dill, RÖMPP [Online], Stuttgart, Georg Thieme Verlag [September 2023]. The amount of tocopherol in the composition is determined by HPLC. Suitable methods are described in “A.M. Lampi, Analysis of tocopherols and tocotrienols by HPLC, Selected Topics in the Analysis of Lipids, The AOCS lipid library, 2011”. Due to the similarity of the structures of β-tocopherol and γ-tocopherol (same molecular weight and polarity), their amount is determined as the sum of both substances. The major tocopherol content comprised in the composition according to the instant invention preferably is due to β-tocopherol and γ-tocopherol. A preferred composition according to the instant invention comprises less than 100 ppb, preferably 0.1 to 60 ppb, more preferably 0.5 to 25 ppb, most preferably 1.0 to 10 ppb, in total of the group of polycyclic aromatic hydrocarbons (PAH) selected from phenantrene, anthracene, fluoranthene, pyrene, benzo(a)anthracen, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene and benzo(a)pyrene, wherein the ppb refer to the total composition. A suitable method for the analysis of PAH in oils is described in “H. Ekner, K. Dreij, I. Sadiktsis, Determination of polycyclic aromatic hydrocarbons in commercial olive oils by HPLC / GC / MS – Occurrence, composition and sources. Food Control 2022, 132, 108528". 202300186 Foreign Filing 4 A preferred composition according to the instant invention comprises a triglyceride mixture with a distribution of fatty acid acyl groups in the triglycerides of 21 wt-% to 28 wt-% palmitoyl, 2.0 wt-% to 7.0 wt-% stearoyl, 31 wt-% to 41 wt-% oleoyl, 22 wt-% to 30 wt-% linoleoyl, 0.01 wt-% to 0.5 wt-%, more preferably 0.05 wt-% to 0.4 wt-%, cyclopropenoid fatty acid acyl groups, wherein the weight percents refer to all fatty acid acyl groups comprised in all triglycerides comprised in the composition, characterised in that the composition comprises 400 ppm to 1100 ppm tocopherol, preferably in the distribution of at least 20 ppm of α-tocopherol, at least 350 ppm of β-tocopherol and γ-tocopherol in sum and at least 30 ppm of δ-tocopherol, and less than 2 ppb of benzo(a)pyrene. wherein the ppm and ppb refer to the total composition. A preferred composition according to the invention is characterized in that the triglyceride content of the composition is from 90 wt-% to 99.95 wt-%, preferably 95 wt-% to 99.92 wt-%, wherein the weight percents refer to the total composition. A preferred composition according to the invention is characterized in that it has an iodine value of 70.0 g I / 100 g to 100 g I / 100 g, preferably 75.0 g I / 100 g to 95.0 g I / 100 g. A suitable method for determining the iodine value in the context of the present invention is EN 14111:2003. A preferred composition according to the invention is characterized in that it has an acid value of between 0.01 mg KOH / g and 8.0 mg KOH / g, preferably between 0.02 mg KOH / g and 2.0 mg KOH / g. Suitable methods for determining the acid value are in particular those according to DGF C-V 2, DIN EN ISO 2114, Ph. Eur.2.5.1, ISO 3682 and ASTM D 974. A preferred composition according to the invention is characterized in that it has a saponification value of between 175 mg KOH / g and 210 mg KOH / g, preferably between 180 mg KOH / g and 205 mg KOH / g. 202300186 Foreign Filing 5 Suitable detection methods for determining the saponification value are in particular those according to DGF C-V 3, DIN EN ISO 3681 and Ph. Eur.2.5.6. It is preferable in accordance with the invention that the composition of the instant invention has a viscosity at 25 °C of 71 mPas to 200 mPas, preferably 72 mPas to 175 mPas, more preferably 73 mPas to 150 mPas, most preferably 74 mPas to 140 mPas. A suitable method for determining the viscosity is using a rheometer (MCR 302, Anton Paar Germany) with a plate-plate measuring system in the shear rate range of 0.1 -100 s-1. The upper plate has a diameter of 40 mm, the gap distance is 0.5 mm, the measuring temperature is 25°C. A preferred composition according to the invention is characterized in that it does not comprise a cosmetic preservative, especially none of the ones selected from the group of phenoxyethanol, parabens, isothiazolinones and benzyl alcohols. The compositions according to the instant invention are preferably obtained by the method described hereinbelow; the present invention thus further provides a process of treating a baobab oil comprising the steps of A) providing a baobab oil, B) heating and keeping said baobab oil at a temperature in the range of 90 °C to 270 °C, preferably 190 °C to 250 °C, more preferably 200 °C to 230 °C, C) running water steam through said baobab oil, preferably continuously. Any kind of baobab oil can be provided in the process of the instant invention, the baobab oil can be an unrefined or a refined baobab oil. In a preferred process according to the instant invention said baobab oil is provided in process step A) by isolating oil from baobab seeds, preferably by cold pressing. The term “cold pressing” in the context of the instant invention is referring to a temperature range of 1 to 80 °C, preferably the common ambient temperature without providing further thermal energy during the pressing process. More preferably, this temperature range is 10 °C to 48 °C, whereby the temperature is measured in the shadow. In process step A), the crude oil is preferably refined and bleached prior to starting process step B). A preferred process according to the instant invention is characterised in that in process step B) the temperature is kept in said range for a period of time from 0.1 hours to 24 hours, preferably from 0.3 hour to 15 hours, more preferably from 1 hour to 12 hours. 202300186 Foreign Filing 6 Preferably, in the process according to the instant invention process step C) is conducted in parallel to process step B). A preferred process according to the instant invention is characterised in that process step C) is carried out over a period of time corresponding to at least 80 %, more preferably between 90 % and 100 % of the time period the temperature is kept in said range of process step B). A more preferred process according to the instant invention is characterised in that process step C) is carried out under reduced pressure, thus at less than 1 atm. A preferred pressure range is 0.1 to 200 mbar, more preferably 0.5 to 100 mbar, most preferably 1 to 50 mbar. A preferred process according to the instant invention is characterised in that in process step C) said water steam is run through said baobab oil, preferably in a batch process, at a rate of 0.05 to 2.5 wt-% per hour, preferably 0,1 to 1.5 wt-% water steam per hour, more preferably 0.15 to 1.0 wt- % water steam per hour and most preferably 0.2 to 0.6 wt-% water steam per hour, wherein the wt- % of water steam relate to the amount of oil that is treated. The composition according to the instant invention bears many beneficial properties when applied to the skin and / or hair: It is quickly absorbed, without weighing down the skin and hair and does not leave a greasy sheen. It very well softens and nourishes skin and hair of any type. It helps to restore the lipid barrier of the epidermis, increases skin elasticity, has anti-aging properties and antioxidant properties. It makes the skin velvety and improves skin turgor. It also helps in the fight against scars and stretch marks and can prevent the formation of stretch marks during pregnancy. It also soothes the skin after sunburn and relieves irritation. It relieves rosacea. It can be used as part of care formulations for chemically treated, dry and frizzy hair that need generous conditioning before straightening. It improves the appearance of split hair and returns healthy shine to hair and nails. Thus, it ideal for the care of sensitive and irritated skin, for restoration and strengthening of nails, treatment of excessive dryness, brittleness and splitting of hair and to heal skin cracks and prevent scarring. Consequently, the instant invention further provides the use of a composition according to the instant invention for the preparation of a cosmetic, dermatologic, feed, food and / or pharmaceutical formulation, preferably for topic applications, especially cosmetic formulations for topic applications. 202300186 Foreign Filing 7 In preferred use according to the invention at least one additional component selected from the group of emollients, emulsifiers, thickeners / viscosity regulators / stabilizers, UV light protection filters, antioxidants, hydrotropes, solids and fillers, film formers, pearlescence additives, deodorant and antiperspirant active ingredients, insect repellents, self-tanning agents, conditioning agents, perfumes, dyes, odour absorbers, superfatting agents, other solvents are co-used when preparing the formulation. Substances which can be used as exemplary representatives of the individual groups are known to those skilled in the art and can be found for example in German application DE 102008001788.4. This patent application is hereby incorporated as reference and thus forms part of the disclosure. As regards further optional components and the amounts used of these components, reference is made expressly to the relevant handbooks known to those skilled in the art, for example K. Schrader, “Grundlagen und Rezepturen der Kosmetika [Cosmetics – fundamentals and formulations]”, 2ndedition, pages 329 to 341, Hüthig Buch Verlag Heidelberg. The amounts of the particular additives are determined by the intended use. Typical boundary formulations for the respective applications are known prior art and are contained for example in the brochures of the manufacturers of the particular base and active ingredients. These existing formulations can generally be adopted unchanged. However, if required, for adjustment and optimization, the desired modifications can be undertaken by simple tests without complication. The examples adduced hereinafter describe the present invention by way of example, without any intention that the invention, the scope of application of which is apparent from the entirety of the description and the claims, be restricted to the embodiments specified in the examples. 202300186 Foreign Filing 8 Examples: 1: Composition comprising triglycerides according to the instant invention A cold-pressed and refined baobab oil was heated to 210°C and water vapor was passed through it under reduced pressure at a rate of 0.5 % / h in relation to the amount of oil. After 10 hours, the oil was cooled down to 25 °C. The contained product had a viscosity of 79.7 mPa s, a tocopherol content of 956 ppm (72 ppm α-tocopherol, 765 ppm β- + γ-tocopherol and 119 ppm δ-tocopherol), a total cyclopropenoid fatty acid content of 0.29% (0.22 % malvalic acid and 0.07 % sterculic acid) and in sum a content of phenantrene, anthracene, fluoranthene, pyrene, benzo(a)anthracen, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene and benzo(a)pyrene of 1.5 ppb. Example 2: Composition comprising triglycerides not according to the instant invention A cold-pressed crude baobab oil with a viscosity of 67.5 mPa s at 25 °C, a tocopherol content of 803 ppm (26 ppm α-tocopherol, 739 ppm β- + γ-tocopherol and 38 ppm δ-tocopherol), a total cyclopropenoid fatty acid content of 6.1 % (4.9 % malvalic acid and 1.2 % sterculic acid) and in sum a content of phenantrene, anthracene, fluoranthene, pyrene, benzo(a)anthracen, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene and benzo(a)pyrene of 8.4 ppb served as a non-inventive example. Example 3: Composition comprising triglycerides not according to the instant invention A commercial, cold-pressed and refined baobab oil with a viscosity of 70.3 mPa s at 25 °C, a tocopherol content of 312 ppm (10 ppm α-tocopherol, 283 ppm β- + γ-tocopherol and 19 ppm δ- tocopherol) and a total cyclopropenoid fatty acid content of 1.4 % (1.1 % malvalic acid and 0.3 % sterculic acid) served as a non-inventive example.

[0002] 202300186 Foreign Filing 9 Example 4: Composition comprising triglycerides not according to the instant invention A cold-pressed and refined baobab oil was heated to 250°C and water vapor was passed through it under reduced pressure at a rate of 5.0 % / h in relation to the amount of oil. After 1.5 hours, the oil was cooled down to 25 °C. The contained product had a tocopherol content of 59 ppm, a total cyclopropenoid fatty acid content of 1.07 % (0.85 % malvalic acid and 0.22 % sterculic acid) and in sum a content of phenantrene, anthracene, fluoranthene, pyrene, benzo(a)anthracen, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene and benzo(a)pyrene of 231 ppb. Example 5: Oxidative stability test Oxidative stability of the samples was measured using a 892 Professional Rancimat according to its manual (version 8.892.8001EN / 2020-03-11) at 120°C. During the measurement the oxidative decomposition of oils and fats can be monitored. Air is passed through the sample in the reaction vessel at 120°C. Fatty acids are oxidized. At the end of the test, volatile secondary reaction products are formed, which are transported by air stream into the measuring vessel and absorbed in the test solution (deionized water). The continuously recorded electrical conductivity of the test solution increases due to the absorption of the reaction products. This allows their appearance to be detected. The time it takes to detect secondary reaction products is called the induction time. It characterizes the oxidation stability of oils and fats, the higher the induction time the higher the oxidative stability. Induction time in h Example 1, according to the instant invention 5.7 Example 2, not according to the instant invention 4.3 The composition according to the instant invention has a higher oxidative stability than a composition not according to the instant invention.

[0003] 202300186 Foreign Filing 10 Example 6: Storage stability of a water free Hand Bar, given numbers are weight percentages: INCI BAR 1, BAR 2, according to not according the instant to the instant invention, w-% invention, w- % Ricinus Communis (Castor) Seed Oil, Cera Alba, Copernicia Cerifera Cera (and) Ascorbyl Palmitate (and) Tocopherol 47.3 47.3 Rhus Verniciflua Peel Cera, Simmondsia Chinensis Seed Oil, Cetearyl Alcohol, Myristyl Alcohol, Caprylic / Capric Triglyceride, Copernicia Cerifera Cera, Tocopherol, Helianthus Annuus Seed 20 20 Oil Hydrolyzed Sunflower Seed Wax 5 5 Helianthus Annuus Seed Cera, Olea Europaea Oil Unsaponifiables, Rhus Verniciflua Peel, Shorea Robusta Resin 10 10 Example 1, according to the instant invention 15 Example 3, not according to the instant invention 15 Hydrogenated Vegetable Oil 2 2 Tocopherol (and) Helianthus Annuus (Sunflower) Seed Oil 0.2 0.2 Glyceryl Caprylate 0.5 0.5 Processing of Hand Cream Bar: Heat everything to 90 °C. Cool to 80 °C and pour directly into silicone mold. Allow to cool completely in the refrigerator at 4 °C. Storage Stability 25°C, 2 daysok okStorage Stability 25°C, 1 monthok okoil at the ok surface, not Storage Stability 45°C, 2 days ok The above finding is quite surprising, as the bars comprise high amounts of other oils; yet the composition of the instant invention has a beneficial storage effect.

[0004] 202300186 Foreign Filing 11 Example 7: Viscosity of a cream, given numbers are weight percentages: INCICream 1, according to the Cream 2, not according to the instant invention, w-% instant invention, w-% Polyglyceryl-4 A Diisostearate / Polyhydroxyst 1.5 1.5 earate / Sebacate wax paste* 0.7 0.7 Adansonia Digitata Seed Oil, according to the instant invention20(Example 1) Adansonia Digitata Seed Oil, not according to the instant invention20(Example 2) B Aqua 73.8 73.8 Glycerin3 3Magnesium Sulfate 1 1 *wax paste Hydrogenated Castor Oil 7.50% Paraffin (and) Microcristallina Cera 7.50% Ethylhexyl Palmitate 85.00% Processing Spread the wax paste homogeneously in the oil phase for >2 min with MIG at 450 rpm. Add B to A for 2 min, stirring at 450 rpm. Homogenize for 3 min at 1500 rpm (with MIG, 2 blades). Pour emulsion into 2,100 mL jars. Viscosity was measured using a Brookfield DV-I viscometer with spindle C, running at 10 RPM after 10s. Cream 1, according to the instant Cream 2, not according to the invention instant invention Viscosity51 47Example 8: Skin feel of a cream: The sensory of the creams of example 6 are evaluated by a trained sensory panel. At least 5 persons are evaluating the sensory profile of the formulations without knowing the composition of the evaluated samples. The properties the majority of the panelists have described is reported in the table below: 202300186 Foreign Filing 12 Cream 1, according to the instant Cream 2, not according to the invention instant invention Richness on the Skin During distribution: easy During distribution: easy to distribution, 5 Minutes after distribute, 5 Minutes after absorption: medium absorption, rich absorption: high absorption, and caring skin feel medium light Skin feel Example formulations: The following examples demonstrate the applicability of Baobab Oil in different cosmetic formulations and their compatibility with various other ingredients such as emulsifiers, stabilizers, preservatives or active compounds like UV-filters or antimicrobial drugs which are usually challenging to formulate. The application of the invention is not limited to the formulations shown. The preparation of the examples has been done according to common standard methods. Natural body spray Phase Ingredient w / w-% w / w-% w / w-% w / w-% TEGO® Care LTP A (Sorbitan Laurate; Polyglyceryl-4 Laurate; Dilauryl 2.50 3.00 Citrate) TEGO® Care PBS 6 3.00 3.00 (Polyglyceryl-6 Stearate; Polyglyceryl-6 Behenate) Example 1 12.50 14.00 12.00 9.50 Water Ad Ad Ad Ad B 100 100 100 100 Glycerin 3.00 3.00 3.00 4.00 Gellan Gum (Kelcogel CG-HA, CP Kelco) 0.10 0.10 0.10 0.15 dermsosoft® OMP C 2.50 2.50 2.50 2.50 (Methylpropandiol; Caprylyl Glycol; Penylpropanol)

[0005] 202300186 Foreign Filing 13 W / O Cream Phase Ingredient w / w- w / w- w / w- % % % A ISOLAN® PDI (Diisostearoyl Polyglyceryl-3 Dimer Dilinoleate) 3.00 ISOLAN® 17 (Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate (and) 3.00 3.00 Caprylic / Capric Triglyceride (and) Polyglyceryl-3 Oleate (and) Diisostearoyl Polyglyceryl-3 Dimer Dilinoleate) Hydrogenated Castor Oil 0.40 0.40 0.40 Beeswax 0.60 0.60 0.60 TEGOSOFT® CT (Caprylic / Capric Triglyceride) 5.00 5.00 5.00 TEGOSOFT® P (Isopropyl Palmitate) 5.00 5.00 5.00 TEGOSOFT® OER (Oleyl Erucate) 3.00 3.00 3.00 TEGOSOFT® CR (Cetyl Ricinoleate) 0.50 1.00 Prunus Amygdalus Dulcis (Sweet Almond) Oil 3.00 3.00 3.00 Example 1 6.00 6.50 6.00 B ad ad ad Water 100 100 100 Glycerin 5.00 5.00 3.00 C Magnesium Sulfate Heptahydrate 1.00 1.50 0.90 Sodium Benzoate, Potassium Sorbate, Water (Euxyl K 712, 0.50 0.50 0.50 Schülke & Mayr) Citric Acid (10% in water) q.s. q.s. q.s.

[0006] 202300186 Foreign Filing 14 Anti-Aging day cream Phase Ingredient w / w- w / w- w / w- w / w- % % % % ABIL® EM 90 (Cetyl PEG / PPG-10 / 1 Dimethicone A 3.00 3.00 Triglyceride) ABIL® EM 180 (Cetyl PEG / PPG-10 / 1 Dimethicone 2.00 Triglyceride) ABIL® WE 09 (Polyglyceryl-4 Isostearate; Cetyl 4.00 PEG / PPG-10 / 1 Dimethicone; Hexyl Laurate) TEGOSOFT® AC (Isoamyl Cocoate) 5.00 5.00 4.00 5.00 TEGOSOFT® DEC (Diethylhexyl Carbonate) 6.00 6.00 5.00 5.00 Example 1 7.00 2.00 10.00 8.00 HyaCare® Filler CL (Aqua, Ethylhexyl Stearate, Sodium Hyaluronate Crosspolymer, Polyglyceryl-4 2.50 2.50 2.50 2.50 Diisostearate / Polyhydroxystearate / Sebacate, Sodium Isostearate) Tocopherol 0.50 0.50 0.50 0.50 Methyl Methacrylate Crosspolymer (Covabead LH 85, 2.00 2.00 2.00 2.00 Sensient) ad ad ad ad B Water 100 100 100 100 Sodium Chloride 0.80 0.80 0.80 0.80 Glycerin 4.00 4.00 4.00 4.00 Butylene Glycol 4.00 4.00 4.00 4.00 TEGO® Pep 4-Even (Tetrapeptide-30; Glycerin) 2.50 2.50 2.50 2.50 Sodium Ascorbyl Palmitate 1.50 1.50 1.50 1.50 Urea 2.50 2.50 2.50 2.50 Sodium Bisulfite 0.10 0.10 0.10 0.10 Z Preservative, Perfume q.s. q.s. q.s. q.s.

[0007] 202300186 Foreign Filing 15 Light & caring cream Phase Ingredient w / w-% w / w-% w / w-% A ABIL® EM 90 (Cetyl PEG / PPG-10 / 1 Dimethicone) 2.00 2.00 1.50 ABIL® EM 97 S (Bis-PEG / PPG-14 / 14 Dimethicone (and) 1.00 Dimethicone) TEGOSOFT® OP (Ethylhexyl Palmitate) 5.00 5.00 5.00 TEGOSOFT® CT (Caprylic / Capric Triglyceride) 5.00 7.00 5.00 TEGOSOFT® DEC (Diethylhexyl Carbonate) 10.00 12.00 10.00 Example 1 6.00 2.00 6.00 dermofeel® viscolid (Hydrogenated Vegetable Oil) 0.50 0.50 0.50 B Water ad ad ad 100 100 100 Sodium Chloride 0.50 0.50 0.50 C Phenoxyethanol, Ethylhexylglycerin (euxyl® PE 9010, 0.80 0.80 0.80 Schülke & Mayr) Serum Phase Ingredient w / w- % A TEGO® Care 165 (Glyceryl Stearate; PEG-100 Stearate) 3.00 TEGO® Alkanol 18 (Stearyl Alcohol) 0.50 Isononyl Isononanoate 4.00 Hydrogenated Polyisobutene 3.00 TEGOSOFT® APM (PPG-3 Myristyl Ether) 3.00 Example 1 0.50 Tocopherol 0.50 ad B Aqua 100 Butylene Glycol 5.00 SKINMIMICS® (Ceteareth-25; Glycerin; Cetyl Alcohol; Behenic Acid; Cholesterol; Ceramide NP; Ceramide NS; Ceramide EOS; Ceramide EOP; 2.50 Ceramide AP; Caprooyl Phytosphingosine; Caprooyl Sphingosine) C Polyacrylamide; C13-14 Isoparaffin; Laureth-7 (Sepigel 305, Seppic) 0.75 Z Preservative, Perfume q.s. 202300186 Foreign Filing 16 Body cream Phase Raw material w / w % A Dermofeel NC (Polyglyceryl-3 Distearate; Glyceryl Stearate Citrate) 4.00 Tego®Alkanol 18 (Stearyl Alcohol) 1.50 Tegosoft®CT (Caprylic / Capric Triglyceride) 4.50 Example 1 8.50 Tocopherol 0.50 Varisoft® TA 100 (Distearyldimonium Chloride) 2.50 HyaCare 50 (Hydrolyzed Hyaluronic Acid) 0.20 B Water to 100 Glycerin 7.00 Skinmimics®(Ceteareth-25; Glycerin; Cetyl Alcohol; Behenic Acid; Cholesterol; Ceramide NP; Ceramide NS; Ceramide EOS; Ceramide EOP; Ceramide AP; 1.50 Caprooyl Phytosphingosine; Caprooyl Sphingosine) C Xanthan Gum 0.50 Z Preservative, Perfume q.s.

[0008] 202300186 Foreign Filing 17 Rich natural cream Phase Ingredient w / w- w / w- w / w- w / w- % % % % TEGO® Care PSC 3 (Polyglyceryl-3 A 3.00 Dicitrate / Stearate) Symbiomuls GC (Glyceryl Stearate Citrate; Cetearyl 3.50 Alcohol; Glyceryl Caprylate) Dermofeel NC (Polyglyceryl-3 Distearate (and) 2.50 3.00 Glyceryl Stearate Citrate) TEGIN® M Pellets (Glyceryl Stearate) 0.90 0.30 0.90 0.50 TEGO® Alkanol 1618 (Cetearyl Alcohol) 0.60 0.30 0.60 0.60 TEGOSOFT® P (Isopropyl Palmitate) 3.00 3.00 3.00 3.00 Prunus Amygdalus Dulcis Oil 5.00 5.00 5.00 5.00 TEGOSOFT® CT (Caprylic / Capric Triglyceride) 4.50 4.50 4.50 4.50 Triisostearin 3.50 3.50 3.50 3.50 Example 1 6.00 6.00 6.00 6.00 Water ad ad ad ad B 100 100 100 100 Glycerin 3.00 4.00 3.00 5.00 Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.30 0.30 0.30 0.30 C Sodium hydroxide (10 % in water) q.s. q.s. q.s. q.s. Z Preservative, Perfume q.s. q.s. q.s. q.s.

[0009] 202300186 Foreign Filing 18 Body butter Phase Raw material w / w % A Dermofeel®NC (Polyglyceryl-3 Distearate; Glyceryl Stearate Citrate) 3.00 Tego®Alkanol 1618 (Cetearyl Alcohol) 4.00 Tegin®M Pellets (Glyceryl Stearate) 3.00 Example 1 6.00 Helianthus Annuus (Sunflower) Seed Oil 5.50 Butyrospermum Parkii (Shea) Butter 6.00 Theobroma Cacao (Cocoa) Seed Butter 6.00 dermofeel®Toco 70 non GMO (Tocopherol; Helianthus Annuus (Sunflower) 0.50 Seed Oil) B Water to 100 Glycerin 5.00 Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.50 Z Preservative, Perfume q.s. Low whitening natural Body butter Phase Raw material w / w % A symbio®muls GC MB (Glyceryl Stearate Citrate; Cetearyl Alcohol; Glyceryl 7.00 Caprylate) Helianthus Annuus (Sunflower) Seed Oil 35.00 Example 1 19.00 dermofeel®Toco 70 non GMO (Tocopherol, Helianthus Annuus (Sunflower) 0.50 Seed Oil) B Water To 100 Glycerin 3.00 dermosoft®anisate eco (Sodium Anisate) 0.30 C dermofeel®PA-3 (Sodium Phytate; Aqua; Alcohol) 0.30 Z Perfume q.s. 202300186 Foreign Filing 19 Lip filler Lipstick Phase Raw material w / w % A Tegosoft®G 20 (Octyldodecanol) 15.00 Tegosoft®CT (Caprylic / Capric Triglyceride) 10.00 Tegosoft®OER (Oleyl Erucate) 2.00 Tegosoft®MM (Myristyl Myristate) 5.00 Ricinus Communis Seed Oil (Castor Oil, Aldrich) 31.70 Olus Oil (Cremerlin®PURA, Cremer Care) 10.00 Stearyl Beeswax; Behenyl Beeswax (BW Ester BW67, Koster Keunen) 5.00 Ozokerite (Kahlwax 1899, KahlWax) 5.00 Cera Alba (Kahlwax 8104, KahlWax) 4.00 Euphorbia Cerifera Wax (Kahlwax 2039L, KahlWax) 2.00 Example 1 5.00 B Tocopherol 0.10 Perfume 0.20 HyaCare®Filler CL (Aqua; Ethylhexyl Stearate; Sodium Hyaluronate C Crosspolymer; Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate; 5.00 Sodium Isostearate)

[0010] 202300186 Foreign Filing 20 After Shave Lotion Phase Ingredient w / w- w / w- % % ABIL® Care 85 (Bis-PEG / PPG-16 / 16 PEG / PPG-16 / 16 Dimethicone; A 1.50 Caprylic / Capric Triglyceride) ABIL® Care XL 80 (Bis-PEG / PPG-20 / 5 PEG / PPG-20 / 5 Dimethicone (and) Methoxy PEG / PPG-25 / 4 Dimethicone (and) Caprylic / Capric 1.50 Triglyceride) TEGOSOFT® CT (Caprylic / Capric Triglyceride) 3.00 3.00 Example 1 3.50 3.50 Tocopheryl Acetate 0.50 0.50 Menthyl Lactate (Frescolat ML) 0.50 0.50 B TEGO® SMO 80 V (Polysorbate 80) 0.50 0.50 Aqua ad ad 100 100 Glycerin 2.00 2.00 Alcohol 15.00 15.00 C TEGO® Carbomer 141 (Carbomer) 0.20 0.20 Xanthan Gum 0.10 0.10 Mineral Oil (30 mPas) 1.60 1.60 D Sodium hydroxide (10 % in water) q.s. q.s. Z Preservative, Perfume q.s. q.s.

[0011] 202300186 Foreign Filing 21 O / W Cream Phase Raw material w / w % w / w % w / w % A Tego® Care PSC 3 (Polyglyceryl-3 Dicitrate / Stearate) 3.00 C14-22 Alcohols (and) C12-20 Alkyl Glucoside 4.00 Glyceryl Stearate SE 4.50 Tegin®M Pellets (Glyceryl Stearate) 0.90 0.90 0.90 Tego®Alkanol 18 (Stearyl Alcohol) 0.60 0.60 0.60 Tegosoft®P (Isopropyl Palmitate) 3.00 3.00 3.00 Prunus Amygdalus Dulcis (Sweet Almond) Oil 5.00 5.00 5.00 Tegosoft®CT (Caprylic / Capric Triglyceride) 4.50 4.50 4.50 Triisostearin 3.50 3.50 3.50 Example 1 6.00 6.00 6.00 B Water to 100 to 100 to 100 Glycerin 3.00 3.00 3.00 Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.30 0.30 0.30 C Sodium hydroxide (10% in water) q.s. q.s. q.s. Z Preservative, Perfume q.s. q.s. q.s. Light W / O emulsion Phase Ingredient w / w- % A ISOLAN® GPS (Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate) 3.00 Example 1 6.40 TEGOSOFT® DEC (Diethylhexyl Carbonate) 6.40 Dicaprylyl Carbonate, Stearalkonium Hectorite, Propylene Carbonate 3.00 (Cosmedia® Gel CC, Cognis) B Water ad 100 Glycerin 2.00 Magnesium Sulfate Heptahydrate 1.50 C Phenoxyethanol, Ethylhexylglycerin (euxyl® PE 9010, Schülke & Mayr) 0.70

[0012] 202300186 Foreign Filing 22 Anti-aging hydration cream Phase Ingredient w / w-% A TEGO® Care 450 (Polyglyceryl-3 Methylglucose Distearate) 3.00 TEGIN® M Pellets (Glyceryl Stearate) 2.00 TEGO® Alkanol 18 (Stearyl Alcohol) 1.00 TEGOSOFT® MM (Myristyl Myristate) 1.00 TEGOSOFT® DO (Decyl Oleate) 8.00 Example 1 11.50 Phytosphingosine SLC (Salicyloyl Phytosphingosine) 0.10 B Glycerin 3.00 Aqua ad 100 C TEGO® Carbomer 134 (Carbomer) 0.20 TEGOSOFT® P (Isopropyl Palmitate) 0.80 D Sodium hydroxide (10 % in water) q.s. Z Preservative, Perfume q.s.

[0013] 202300186 Foreign Filing 23 Light O / W sun care lotion Phase Ingredient w / w-% A AXOL® C 62 Pellets (Glyceryl Stearate Citrate) 2.50 TEGO® Alkanol 1618 (Cetearyl Alcohol) 1.00 Example 1 3.00 TEGOSOFT® XC MB (Phenoxyethyl Caprylate) 4.00 Isoadipate (Diisopropyl Adipate) 3.00 Butyloctyl Salicylate (HallBrite BHB, The HallStar Company) 2.00 Tocopheryl Acetate 0.20 Dimethicone (5 mPas) 1.00 Butyl Methoxydibenzoylmethane 1.50 Diethylamino Hydroxybenzoyl Hexyl Benzoate (Uvinul A Plus, BASF) 4.00 Ethylhexyl Triazone 2.00 Ethylhexyl Salicylate 5.00 Octocrylene 8.00 Ethylhexyl methoxycrylene 1.50 B Titanium Dioxide; Trimethoxycaprylylsilane 1.00 C Glycerin 3.20 EDTA 0.02 Water ad 100 D Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.10 Example 9 0.90 E Sodium Hydroxide (10% in water) q.s Z Preservative, Perfume q.s

[0014] 202300186 Foreign Filing 24 Sun care spray SPF 30 Phase Ingredient w / w-% A TEGO® Care PBS 6 MB (Polyglyceryl-6 Stearate, Polyglyceryl-6 Behenate) 3.00 Example 1 3.00 TEGOSOFT® XC MB (Phenoxyethyl Caprylate) 4.00 Bis-ethylhexyloxyphenol Methoxyphenyl Triazine (Tinosorb S, BASF) 3.00 Butyl Methoxydibenzoylmethane 2.00 Homosalate 4.00 Ethylhexyl Salicylate 4.00 Octocrylene 4.00 TEGO® Feel C 10 (Cellulose) 1.00 B Water ad 100 Gellan Gum (Kelcogel CG-HA, CP Kelco) 0.03 EDTA 0.05 Glycerin 3.00 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.20 C Phenylbenzimidazole Sulfonic Acid 2.00 Tromethamine 0.88 Water 7.12 E Tromethamine (Trisaminomethane, 30% in water) q.s. F dermofeel® OMP (Methylpropanediol, Caprylyl Glycol, Phenylpropanol) 3.00 Cationic hand cream Phase Ingredient w / w-% A VARISOFT® TA 100 (Distearyldimonium Chloride) 3.50 TEGIN® M Pellets (Glyceryl Stearate) 1.50 TEGO® Alkanol 18 (Stearyl Alcohol) 1.00 Example 1 6.00 TEGOSOFT® DEC (Diethylhexyl Carbonate) 13.00 TEGOSOFT® CR (Cetyl Ricinoleate) 1.00 Triisostearin 1.00 B TEGO® Cosmo C 100 (Creatine) 0.50 Glycerin 3.00 Water ad 100 Z Preservative, Parfum q. s. 202300186 Foreign Filing 25 AP / Deo roll-on, PEG- and ACH-free Phase Ingredient w / w- % A TEGO® Care APD 18 (Polyglyceryl-6 Stearate; Polyglyceryl-6 Behenate; C18- 5.00 22 Hydroxyalkyl Hydroxypropyl Guar) TEGOSOFT® LO MB(Lauryl Oleate) 3.00 Example 1 2.00 B ad Water 100 Glycerin 3.00 Potassium Alum 5.00 C Preservative, Perfume q.s. Oil Release Lotion Phase Ingredient w / w- w / w- w / w- % % % TEGO® Care PBS 6 (Polyglyceryl-6 Stearate, A 3.00 3.00 3.00 Polyglyceryl-6 Behenate) TEGOSOFT® DEC (Diethylhexyl Carbonate) 15.00 15.00 15.00 Example 1 5.00 10.00 10.00 TEGOSOFT® LO MB(Lauryl Oleate) 6.00 TEGOSOFT® OER (Oleyl Erucate) 18.00 12.00 16.00 TEGOSOFT® CT (Caprylic / Capric Triglyceride) 20.00 20.00 20.00 TEGOSOFT® AC (Isoamyl Cocoate) 13.00 14.00 10.00 TEGO® Feel C 10 (Cellulose) 1.00 1.00 1.00 ad ad ad B Aqua 100 100 100 Glycerin 3.00 3.00 3.00 Phenoxyethanol, Ethylhexylglycerin (Euxyl PE 9010, C 0.70 0.70 0.70 Schülke & Mayr GmbH) D Citric Acid (10% in water) q.s. q.s. q.s.

[0015] 202300186 Foreign Filing 26 W / O Make-up foundation: Nomenclature according to INCI w / w- w / w- w / w- w / w- w / w- w / w- % % % % % % A ISOLAN® 17 (Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate (and) Caprylic / Capric Triglyceride (and) 4.00 3.00 2.00 3.00 2.00 Polyglyceryl-3 Oleate (and) Diisostearoyl Polyglyceryl-3 Dimer Dilinoleate) ISOLAN® GPS (Polyglyceryl-4 Diisostearate / 1.00 Polyhydroxystearate / Sebacate Dehymuls PGPH (Polyglyceryl-2 1.50 Dipolyhydroxystearate) Cithrol PG3PR (Polyglyceryl-3 Polyricinoleate) 2.00 ABIL® EM 90 (Cetyl PEG / PPG-10 / 1 3.00 1.50 Dimethicone) Dermofeel sensolv (Isoamyl Laurate) 7.00 6.00 5.00 7.00 2.50 6.00 Decyl Cocoate 4.00 4.00 4.00 3.00 Isopropyl Myristate 6.00 6.00 4.50 Caprylic / Capric Triglyceride 4.00 3.00 4.00 Diethylhexyl Carbonate 4.00 5.00 Dimethicone 15.00 Example 1 3.00 2.00 6.00 4.00 TEGOSOFT® LO MB(Lauryl Oleate) 2.00 5.00 5.00 2.00 0.50 CI 77891 (and) Hydrogenated Lecithin 5.00 5.00 5.00 5.00 5.00 5.00 CI 77492 (and) Hydrogenated Lecithin 0.60 0.60 0.60 0.60 0.60 0.60 CI 77491 (and) Hydrogenated Lecithin 0.35 0.35 0.35 0.35 0.35 0.35 CI 77499 (and) Hydrogenated Lecithin 0.10 0.10 0.10 0.10 0.10 0.10 Disteardimonium Hectorite dimethicone, 2.00 2.00 2.00 2.00 2.00 2.00 propylencarbonat B Water ad ad ad ad ad ad 100 100 100 100 100 100 Sodium chloride 1.00 1.00 1.50 Magnesium Sulfate Heptahydrate 1.50 2.00 2.00 Glycerin 3.00 3.00 3.00 5.00 5.00 5.00 C Phenoxyethanol, Caprylyl Glycol 1.00 1.00 1.00 1.00 1.00 1.00 202300186 Foreign Filing 27 Natural lipstick Phase Raw material w / w % to Ricinus Communis Seed Oil (Castor Oil, Aldrich) 100 Example 1 7.50 Dermofeel®sensolv (Isoamyl Laurate) 4.00 Tegosoft®CT (Caprylic / Capric Triglyceride) 1.00 Tegosoft®CR (Cetyl Ricinoleate) 14.00 ISOLAN®GPS (Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate) 2.00 A Hydrogenated Castor Oil 1.00 Cera Alba (Kahlwax 8104, KahlWax) 5.00 Coperniccia Cerifera Cera (Kahlwax 6642, KahlWax) 5.00 Candelilla Cera (Kahlwax 2039L, KahlWax) 5.00 AEROSIL®200 (Silica) 1.00 dermosoft®GMC MB (Glyceryl Caprate) 1.00 dermofeel®Toco 70 non GMO (Tocopherol, Helianthus Annuus (Sunflower) 0.50 Seed Oil) Maltodextrin; Raphanus Sativus Root Extract; Citric Acid (Natpure Xfine 3.00 Radish RR311, Sensient) Raphanus Sativus Root Extract; Maltodextrin; Citric Acid (Natpure Xfine B 6.00 Radish RR318, Sensient) CI 77891; Mica; Silica (Timiron Splendid Red, Merck) 4.00 Mica; Silica (Ronaflair M-Sphere, Merck) 2.00 Z Parfum q.s.

[0016] 202300186 Foreign Filing 28 Natural Foundation Phase Raw material w / w % A Example 1 5.00 TEGOSOFT LO MB(Lauryl Oleate) 10.00 Tegosoft®DC (Decyl Cocoate) 3.00 Tegosoft®AC (Isoamyl Cocoate) 5.00 Carthamus Tinctorius (Safflower) Seed Oil 500 ISOLAN®GPS (Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate) 4.00 Hydrogenated Castor Oil 7.00 AEROSIL®200 (Silica) 0.30 SPHINGONY®(Sphinganine) 0.10 dermofeel®TocoBalance 0.10 (Tocopherol, Helianthus Annuus (Sunflower) Seed Oil) B Water To 100 Glycerin 5.00 TEGO®Natural Betaine 1.00 Zinc Sulfate 1.50 C CI 77891, Hydrogenated Lecithin (Unipure White LC 981 HLC, Sensient) 5.00 CI 77492, Hydrogenated Lecithin (Unipure Yellow LC 182 HLC, Sensient) 1.20 CI 77491, Hydrogenated Lecithin (Unipure Red LC 381 HLC. Sensient) 0.20 CI 77499, Hydrogenated Lecithin (Unipure Black LC 989 HLC, Sensient) 0.10 Titanium Dioxide (Nano), Alumina; Stearic Acid (Eusolex T-S, Merck KgaA) 3.00 Zinc Oxide (Zano M, EverZinc) 6.00 dermosoft®250 eco (Phenylpropanol) 0.30 Z Parfum q.s. Natural Body Oil Raw material w / w % w / w % w / w % Example 1 35.00 15.00 15.00 TEGOSOFT LO MB(Lauryl Oleate) 20.00 Squalane (C13-15 Alkane) 10.0 10.0 10.0 Helianthus Annuus (Sunflower) Seed Oil 4.00 24.00 4.00 Cocos Nucifera (Coconut) Oil 10.00 10.00 10.00 Limnanthes Alba (Meadowfoam) Seed Oil 15.00 15.00 15.00 Tegosoft®OER MB (Oleyl Erucate) 10.00 10.00 10.00 dermofeel®sensolv MB (Isoamyl Laurate) 15.00 15.00 15.00 dermofeel®Toco 70 non GMO 1.00 1.00 1.00 Transparent Sunscreen 202300186 Foreign Filing 29 Phase Raw material w / w % w / w % A Tego®SP 13 Sun Up (Poly C10-30 Alkyl Acrylate) 2.50 2.50 dermofeel®Toco 70 non GMO 0.50 0.50 (Tocopherol, Helianthus Annuus (Sunflower) Seed Oil) Example 1 5.00 5.00 TEGOSOFT LO MB(Lauryl Oleate) 15.00 Tegosoft®AC (Isoamyl Cocoate) 15.00 dermofeel®sensolv 15.00 15.00 Tegosoft®CT (Caprylic / Capric Triglyceride) to 20.00 Butyl Methoxydibenzoylmethane 3.00 3.00 Ethylhexyl Salicylate 5.00 5.00 Octocrylene 10.00 10.00 Homosalate 10.00 10.00 Alcohol to 100 to 100 Z Preservative, Perfume q.s q.s Cationic Hand Cream Phase Raw material w / w % AVarisoft® TA 100 (Distearyldimonium Chloride)3.50Tegin®M Pellets (Glyceryl Stearate)1.50Tego® Alkanol 18 (Stearyl Alcohol)1.00Example 1 13.00Tegosoft® DEC (Diethylhexyl Carbonate)8.00Tegosoft® CR (Cetyl Ricinoleate)1.00Triisostearin1.00BTego® Cosmo C 100 (Creatine)0.50Glycerin3.00Waterto 100Z Preservative, Perfumeq.s.Natural Body cream with smooth touch Phase Raw material w / w w / w w / w w / w w / w % % % % % A ECOHANCE®PS 3 (Polyglyceryl-3 Distearate) 3.00 3.00 3.00 3.00 3.00 Tego®Alkanol 1618 (Cetearyl Alcohol) 1.00 1.00 1.00 1.80 1.80 Tegosoft®CT (Caprylic / Capric Triglyceride) 7.50 5.50 3.50 4.50 4.50 Dodecane (Plantasens® Flash 80, Clariant) 2.00 2.00 TGOSOFT®LO MB (Lauryl Oleate) 8.50 8.50 Dermofee®sensolv MB (Isoamyl laurate) 1.50 3.50 1.50 Tocopherol 0.50 0.50 0.50 0.50 0.50 Example 1 7.00 0.10 7.00 1.00 0.50 202300186 Foreign Filing 30 TEGO®Care Eco CAT MB (Distearoylisopropyl Dimonium Methosulfate) 3.00 3.00 3.00 Varisoft®TA 100 (Distearyldimonium Chloride) 1.50 1.50 HyaCare 50 (Hydrolyzed Hyaluronic Acid) 0.20 0.20 0.20 0.20 0.20 add add add add add B Aqua to to to to to 100 100 100 100 100 Glycerin 7.00 7.00 7.00 7.00 7.00 Skinmimics®(Ceteareth-25; Glycerin; Cetyl Alcohol; Behenic Acid; Cholesterol; Ceramide NP; Ceramide NS; Ceramide EOS; Ceramide 1.50 1.50 1.50 1.50 1.50 EOP; Ceramide AP; Caprooyl Phytosphingosine; Caprooyl Sphingosine) C Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.50 0.25 Genuvisco Carrageenan CG-131 (Carrageenan) 0.50 0.50 0.25 0.50 dermosoft®Heptyl MB (Heptylglycerin) 2.00 1.00 Z Preservative, Perfume q.s. q.s. q.s. q.s. q.s.

[0017] 202300186 Foreign Filing 31 Deep Comfort silky Body butter Phase Raw material w / w w / w w / w w / w w / w w / w % % % % % % A Dermofeel®NC (Polyglyceryl-3 3.00 3.00 3.00 3.00 Distearate; Glyceryl Stearate Citrate) Sodium Stearoyl Glutamate (Emulgin®3.00 3.00 SG, BASF) Tego®Alkanol 1618 (Cetearyl Alcohol) 4.00 4.00 4.00 4.00 4.00 4.00 Tegin®M Pellets (Glyceryl Stearate) 3.00 3.00 3.00 3.00 3.00 3.00 Example 1 1.00 7.00 7.00 7.00 1.00 0.1 TEGOSOFT®OER (Oleyl Erucate) 6.00 TEGOSOFT®LO MB (Lauryl Oleate) 6.00 6.00 Oenothera BiennisSeed Extract (Life's 2.00 GLA™ '10' n-6 Oil, DSM) Squalane (Plantasens® Squalane, 2.00 Clariant) Helianthus Annuus (Sunflower) Seed Oil 5.50 5.50 5.50 5.50 5.50 5.50 Butyrospermum Parkii (Shea) Butter 6.00 6.00 6.00 4.00 6.00 6.00 Theobroma Cacao (Cocoa) Seed Butter 6.00 6.00 4.00 6.00 6.00 6.00 dermofeel®Toco 70 non GMO (Tocopherol; Helianthus Annuus 0.50 0.50 0.50 0.50 0.50 0.50 (Sunflower) Seed Oil) B add to add to add to add to add to add to Aqua 100 100 100 100 100 100 Glycerin 5.00 5.00 5.00 5.00 5.00 5.00 Xanthan Gum (Keltrol CG-SFT, CP 0.50 0.50 0.50 0.50 0.50 0.50 Kelco) C Vecollage™ Fortify L(Water, Glycerin, 3.00 3.00 sh-Polypeptide-69 (proposed)) Z Preservative, Perfume q.s. q.s. q.s. q.s. q.s. q.s.

[0018] 202300186 Foreign Filing 32 Ultra-comfortable waterproof Sun Spray SPF 30 Phas Raw material w / w-% w / w w / w w / w w / w w / w w / w w / w w / w w / w-% e -% -% -% -% -% -% -% -% A TEGO Care PBS 6 MB (Polyglyceryl-6 Stearate, 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Polyglyceryl-6 Behenate) C12-15 Alkyl Benzoate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 TEGOSOFT® XC MB (Phenoxyethyl Caprylate) 3.00 3.00 TEGO FILMSTAR One MB (Polyglyceryl-3 Stearate / Sebacate 1.50 1.00 3.00 Crosspolymer) LexFilm™ Sun Natural MB (Capryloyl Glycerin / Sebacic 0.50 2.50 Acid Copolymer) TEGOSOFT LO MB (Lauryl Oleate) 2.00 2.00 1.00 1.00 1.00 3.00 3.00 3.00 3.00 3.00 Bis-ethylhexyloxyphenol Methoxyphenyl Triazine 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 (Tinosorb S, BASF) Example 1 8.00 0.5 6.00 6.00 6.00 0.10 3.0 1.00 3.00 0.10 Butyl Methoxydibenzoylmethane 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Homosalate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Ethylhexyl Salicylate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Octocrylene 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 TEGO Feel C 10 (Cellulose) 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 B Water add to add add add add add add add add add to 100 to to to to to to to to 100 100 100 100 100 100 100 100 100 Gellan Gum (Kelcogel CG- HA, CP Kelco) 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 EDTA 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Glycerin 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 C Phenylbenzimidazole Sulfonic Acid 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Tromethamine 0.88 0.88 0.88 0.88 0.88 0.88 0.88 0.88 0.88 0.88 Aqua 7.12 7.12 7.12 7.12 7.12 7.12 7.12 7.12 7.12 7.12 E Tromethamine (Trisaminomethane, 30% in q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. water) F dermofeel OMP (Methylpropanediol, Caprylyl Glycol, 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Phenylpropanol)

[0019] 202300186 Foreign Filing 33 Cationic Foot Crème Phase Raw material w / w-% w / w-% w / w-% A TEGO® Care Eco CAT MB(Distearoylisopropyl Dimonium Methosulfate) 4.00 4.00 4.00 TEGIN® M Pellets MB(Glyceryl Stearate) 3.00 3.00 3.00 Stearyl Alcohol 5.30 5.30 5.30 TEGOSOFT® CT MB(Caprylic / Capric Triglyceride) 7.00 7.00 TEGOSOFT® AC MB(Isoamyl Cocoate) 5.00 5.00 5.00 Exampe 1 1.00 0.1 8.00 Butyrospermum Parkii (Shea) Butter 1.00 1.00 1.00 Vitis Vinifera (Grape) Seed Oil 5.00 5.00 5.00 TEGO® Cosmo P 813 MB(Polyglyceryl-3 Caprylate) 0.10 0.10 0.10 dermofeel® Toco 70 non GMO(Tocopherol; Helianthus Annuus (Sunflower) Seed Oil) 0.20 0.20 0.20 B Water(Aqua) add to 100 add to add to 100 100 Glycerin 5.00 5.00 5.00 Z Verstatil® BOB(Benzyl Alcohol; Caprylyl Glycol; Benzoic Acid) 1.20 Verstatil® PC(Phenoxyethanol; Caprylyl Glycol) 0.70 0.70

[0020] 202300186 Foreign Filing 34 (PEG free) AP / Deo roll-on Phase Raw material w / w- w / w-% w / w- w / w- w / w-% % % % A TEGO®Care APD 18 (Polyglyceryl-6 Stearate; Polyglyceryl-6 Behenate; C18- 5.00 3.50 3.30 3.30 22 Hydroxyalkyl Hydroxypropyl Guar) Steareth-2 3.20 Steareth-20 0.80 Cetearyl Alcohol 1.50 0.5 0.5 TEGOSOFT®CT MB (Caprylic / Capric Triglyceride) 5.7 2.00 Dicaprylyl Ether (Cetiol® OE, BASF) 3.00 TEGOSOFT®LO MB (Lauryl Oleate) 2.50 5.00 0.5 Example 1 2.50 1.00 0.50 0.10 5.00 TEGODEO®PY 88 G (Zinc Ricinoleate) 1.00 1.00 TEGO®Cosmo P 813 MB (Polyglyceryl-3 Caprylate) 0.50 0.50 B add add to add add add to Aqua to 100 to to 100 100 100 100 Glycerin 3.00 3.00 3.00 Potassium Alum 5.00 Aluminum Chlorohydrate 50% aq. 20.00 20.00 Citric Acid, 50% in water q.s. q.s. C Preservative, Perfume q.s. q.s. q.s. q.s. q.s.

[0021] 202300186 Foreign Filing 35 Milky Deo Roll-On for sensitive skin Phase Raw material w / w-% w / w-% w / w-% w / w-% A dermofeel®GSC SG (Glyceryl Stearate Citrate) 0.40 0.40 0.40 0.40 TEGOSOFT®OER MB (Oleyl Erucate)0.50dermosoft®decalact deo MB (Sodium Caproyl / Lauroyl Lactylate; Triethyl Citrate; Salvia 0.30 0.30 0.30 0.30 Officinalis (Sage) Oil) dermosoft®G 3 CY MB (Polyglyceryl-3 Caprylate) 0.30 0.30 0.30 0.30 dermofeel® sensolv MB (Isoamyl Laurate)0.50 0.50 0.50 0.50dermofeel® TEC eco (Triethyl Citrate)5.00 5.00 5.00 5.00TEGODEO® PY 88 G (Zinc Ricinoleate)1.00 1.00 1.00 1.00Example 1 0.10 5.00 0.50 2.00 B add to add to add to add to Aqua 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 Trisodium Citrate Dihydrate (Sodium Citrate)0.30 0.30 0.30 0.30Xanthan Gum FNCSP-PC (Xanthan Gum)0.90 0.90 0.90 0.90Genuvisco Carrageenan CG-131 (Carrageenan)0.10 0.10 0.10 0.10dermosoft®7GA MB (Aqua; Glycerin; 2.60 2.60 2.60 2.60 Heptylglycerin; Sodium Anisate) Citric Acid, 20% sol. in waterq.s. q.s. q.s. q.s.Z Perfume q.s. q.s. q.s. q.s.

[0022] 202300186 Foreign Filing 36 Renewal Body Oil Release Lotion Phase Raw material w / w-% w / w-% w / w-% w / w-% w / w-% w / w-% TEGO®Care PBS 6 A (Polyglyceryl-6 Stearate, 3.00 1.50 3.00 3.00 Polyglyceryl-6 Behenate) ECOHANCE®PS 3 1.50 3.00 3.00 (Polyglyceryl-3 Distearate) TEGOSOFT®DEC 10.00 10.00 10.00 10.00 10.00 10.00 (Diethylhexyl Carbonate) TEGOSOFT®LO MB (Lauryl 26.00 26.00 26.00 26.00 26.00 16.00 Oleate) TEGOSOFT®OER (Oleyl 10.00 10.00 10.00 10.00 10.00 10.00 Erucate) TEGOSOFT®CT 15.00 15.00 15.00 15.00 (Caprylic / Capric Triglyceride) Example 1 0.50 0.50 0.10 15.00 15.00 10.00 TEGOSOFT®AC (Isoamyl 10.00 10.00 10.00 10.00 10.00 10.00 Cocoate) TEGO®Feel C 10 (Cellulose) 1.00 1.00 1.00 1.00 1.00 1.00 add to add to add to add to add to add to B Aqua 100 100 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 3.00 3.00 Phenoxyethanol, C Ethylhexylglycerin (Euxyl PE 0.70 0.70 0.70 0.70 0.70 0.70 9010, Schülke & Mayr GmbH) D Citric Acid (10% in water) q.s. q.s. q.s. q.s. q.s. q.s.

[0023] 202300186 Foreign Filing 37 Long lasting W / O-Make up foundation Phase Rohstoff w / w- w / w- w / w- w / w- w / w- % % % % % A ISOLAN®17 (Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate (and) Caprylic / Capric Triglyceride (and) 4.00 4.00 3.00 2.00 2.00 Polyglyceryl-3 Oleate (and) Diisostearoyl Polyglyceryl-3 Dimer Dilinoleate) TEGO®FILMSTAR One MB (Polyglyceryl-3 1.50 1.50 1.00 0.50 1.00 Stearate / Sebacate Crosspolymer) ISOLAN®GPS (Polyglyceryl-4 Diisostearate / 1.00 Polyhydroxystearate / Sebacate ABIL®EM 90 (Cetyl PEG / PPG-10 / 1 1.50 1.50 Dimethicone) Dermofeel sensolv (Isoamyl Laurate) 7.00 7.00 6.00 2.50 2.50 Decyl Cocoate 4.00 4.00 4.00 Isopropyl Myristate 6.00 6.00 4.50 4.50 Caprylic / Capric Triglyceride 4.00 3.00 3.00 Diethylhexyl Carbonate 5.00 5.00 TEGOSOFT® LO (Lauryl Oleate) 2.00 2.00 5.00 Example 1 2.00 2.00 5.00 8.00 0.50 CI 77891 (and) Hydrogenated Lecithin 5.00 5.00 5.00 5.00 5.00 (i) (ii) CI 77492 (and) Hydrogenated 0.60 0.60 0.60 0.60 0.60 Lecithin CI 77491 (and) Hydrogenated Lecithin 0.35 0.35 0.35 0.35 0.35 CI 77499 (and) Hydrogenated Lecithin 0.10 0.10 0.10 0.10 0.10 Disteardimonium Hectorite dimethicone, 2.00 2.00 2.00 2.00 2.00 propylencarbonat B Wasser add add add add add to to to to to 100 100 100 100 100 Sodium chloride 1.00 1.00 1.00 Magnesium Sulfate Heptahydrate 2.00 2.00 Glycerin3.00 3.00 3.00 5.00 5.00C Phenoxyethanol, Caprylyl Glycol 1.00 1.00 1.00 1.00 1.00 Vecollage™ Fortify L(Water, Glycerin, sh- 3.00 3.00 Polypeptide-69 (proposed)) 202300186 Foreign Filing 38 W / O sun care - Sun Cream, SPF 50+ Phase Ingredients w / w- w / w- w / w- w / w- w / w- % % % % % A ISOLAN® 17 MB(Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate; Caprylic / Capric Triglyceride; 4.30 4.30 4.30 4.30 4.30 Polyglyceryl-3 Oleate; Diisostearoyl Polyglyceryl-3 Dimer Dilinoleate) Microcrystalline Wax 0.30 0.30 0.30 0.30 0.30 Hydrogenated Castor Oil 0.30 0.30 0.30 0.30 0.30 TEGOSOFT® DEC (Diethylhexyl Carbonate) 8.20 4.20 2.20 2.20 TEGOSOFT® XC (Phenoxyethyl Caprylate)4.00 4.00 4.00 4.00Dermofeel sensolv MB (Isoamyl Laurate) 2.00 2.00 2.00 Example 11.00 0.50 1.00 1.00 5.00TEGO® FILMSTAR One MB (Polyglyceryl-3 Stearate / Sebacate Crosspolymer)0.50 0.50 1.50LexFilm™ Sun Natural MB0.50Uvinul A plus(Diethylamino Hydroxybenzoyl Hexyl Benzoate) 6.00 6.00 6.00 6.00 6.00 Tinosorb S(Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine)7.00 7.00 7.00 7.00 7.00Ethylhexyl Salicylate5.00 5.00 5.00 5.00 5.00Ethylhexyl Methoxycinnamate8.00 8.00 8.00 8.00 8.00Parsol TX(Titanium Dioxide (and) Silica (and) Dimethicone)6.00 6.00 6.00 6.00 6.00Verstatil® BOB(Benzyl Alcohol; Caprylyl Glycol; Benzoic Acid) 1.00 1.00 1.00 1.00 1.00 B Water(Aqua) add add add add add to to to to to 100 100 100 100 100 Glycerin3.00 3.00 3.00 3.00 3.00Zinc Sulfate Heptahydrate1.00 1.00 1.00 1.00 1.00ZPerfumeq.s. q.s. q.s. q.s. q.s. 202300186 Foreign Filing 39 All Day Sun Protection Lotion SPF 30 Phase Ingredient w / w% w / w% w / w% w / w% A TEGO® Care PBS 6 MB(Polyglyceryl-6 Stearate (and) Polyglyceryl-6 Behenate) 3.00 3.00 3.00 3.00 TEGIN® M Pellets MB(Glyceryl Stearate) 0.50 0.50 0.50 0.50 TEGO® Alkanol 1618 MB(Cetearyl Alcohol) 0.50 0.50 0.50 0.50 TEGO® FILMSTAR One MB(Polyglyceryl-3 Stearate / Sebacate Crosspolymer)1.50 1.50 1.50dermofeel® sensolv MB(Isoamyl Laurate) 5.50 0.50 5.50 5.50 TEGOSOFT® LO MB(Lauryl Oleate) 2.50 2.50 2.50 2.50 TEGOSOFT XC MB 2.50 Example 1 1.00 5.00 0.5 0.5 Tinosorb S(Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) 4.00 4.00 4.00 4.00 Diethylamino Hydroxybenzoyl Hexyl Benzoate4.00 4.00 4.00 4.00Ethylhexyl Salicylate1.50 1.50 1.50 1.50Ethylhexyl Triazone 1.00 1.00 1.00 1.00 Eusolex T-S(Titanium Dioxide; Alumina; Stearic Acid) 2.00 2.00 2.00 2.00 dermofeel® Toco 70 non GMO(Tocopherol; Helianthus Annuus (Sunflower) Seed Oil) 0.20 0.20 0.20 0.20 B Water(Aqua) add add add add to to to to 100 100 100 100 Glycerin3.00 3.00 3.00 3.00Disodium EDTA0.05 0.05 0.05 0.05CKeltrol CG-SFT(Xanthan Gum)0.50 0.50 0.50 0.50DWater(Aqua)3.56 3.56 3.56 3.56Phenylbenzimidazole Sulfonic Acid 1.00 1.00 1.00 1.00 Tromethamine0.44 0.44 0.44 0.44E Verstatil® BOB(Benzyl Alcohol; Caprylyl Glycol; Benzoic Acid) 1.20 1.20 1.20 1.20 202300186 Foreign Filing 40 High spreading sustainable lifting Body spray Phase Ingredients w / w% w / w% w / w% w / w% w / w% w / w% A dermofeel® easymuls plus (Glyceryl Oleate Citrate) 3.00 3.00 3.00 3.00 3.00 3.00 TEGOSOFT® LO MB(Lauryl Oleate) 12.00 6.00 12.00 6.00 12.00 5.00 Dermofeel sensolv MB 6.00 6.00 Example 1 1.00 6.00 0.50 1.00 0.1 0.5 B Water(Aqua) add to add to add to add to add to add to 100 100 100 100 100 100 dermosoft® Pentiol eco(Pentylene Glycol) 3.00 3.00 3.00 3.00 3.00 3.00 Kelcogel CG-HA(Gellan Gum) 0.10 0.10 0.10 0.10 0.10 Genuvisco Carrageenan CG- 131 (Carrageenan) 0.10 0.10 C dermosoft® OMP(Methylpropanediol, Caprylyl Glycol, Phenylpropanol)2.50 2.50 2.50 2.50 2.50 2.50Vecollage™ Fortify L(Water, Glycerin, sh-Polypeptide-69 (proposed))3.00D Sodium Hydroxide, 10% sol. in water q.s. q.s. q.s. q.s. q.s. q.s.

[0024] 202300186 Foreign Filing 41 Hydration & Wrinkle reduction O / W sunscreen Phase Ingredients w / w- w / w- w / w- w / w- w / w- w / w- % % % % % % A TEGO® Care PBS 6 MB(Polyglyceryl-6 Stearate (and) Polyglyceryl-6 Behenate) 4.00 4.00 4.00 4.00 4.00 4.00 ABIL® Care XL 80 MB(Bis-PEG / PPG- 20 / 5 PEG / PPG-20 / 5 Dimethicone; Methoxy PEG / PPG-25 / 4 Dimethicone; 0.67 0.67 0.67 Caprylic / Capric Triglyceride) TEGO® SP 13 Sun Up MB(Poly C10-30 Alkyl Acrylate) 1.50 1.50 1.50 1.50 1.50 1.50 TEGIN® M Pellets MB(Glyceryl Stearate) 0.20 0.20 0.20 0.20 0.20 0.20 TEGO® Alkanol 1618 MB(Cetearyl Alcohol) 0.20 0.20 0.20 0.20 0.20 0.20 TEGOSOFT® DEC(Diethylhexyl Carbonate) 7.00 5.00 1.00 2.00 3.00 2.00 TEGOSOFT® XC (Phenoxyethyl Caprylate) 1.00 0.50 5.00 2.00 Dermofeel sensolv MB (Isoamyl Laurate) 2.00 0.70 2.00 Example 1 1.00 0.50 7.00 5.00 0.20 3.00 TEGO® FILMSTAR One MB (Polyglyceryl-3 Stearate / Sebacate 0.5 1.5 Crosspolymer) INQP70TMD(Titanium Dioxide; Isononyl Isononanoate; Polyhydroxystearic Acid; 16.4 16.4 16.4 16.4 16.4 16.4 Hydrogen Dimethicone; Dimethicone) GCP55ZSG(Zinc Oxide; Caprylic / Capric Triglyceride; Polyhydroxystearic Acid; 24.3 24.3 24.3 24.3 24.3 24.3 Stearoyl Glutamic Acid) B Water(Aqua) add add add add add add to to to to to to 100 100 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 3.00 3.00 HyaCare® 50(Hydrolyzed Hyaluronic Acid) 0.10 0.10 0.10 HyaCare®(Sodium Hyaluronate) 0.10 0.10 0.10 TEGO® Pep UP(Tetrapeptide-4, Glycerin, Water) 1.00 1.00 1.00 Xanthan Gum 0.50 0.50 0.50 0.2 0.50 Genuvisco Carrageenan CG-131 (Carrageenan) 0.5 0.2 C dermosoft® OMP(Methylpropanediol, Caprylyl Glycol, Phenylpropanol) 2.50 2.50 2.50 2.50 2.50 2.50

[0025] 202300186 Foreign Filing 42 Daily wear cationic lotion with UV protection Phase Ingredients w / w% w / w% w / w% w / w% A TEGO® Care Eco CAT MB(Distearoylisopropyl Dimonium 5.00 5.00 5.00 5.00 Methosulfate) TEGIN® M Pellets MB(Glyceryl Stearate) 0.30 0.30 0.30 0.30 TEGO® Alkanol 1618 MB(Cetearyl Alcohol) 5.40 5.40 5.40 5.40 TEGOSOFT® TN(C12-15 Alkyl Benzoate) 4.00 4.00 3.00 TEGOSOFT® DEC (Diethylhexyl Carbonate) 3.00 3.00 3.00 TEGOSOFT® CR MB(Cetyl Ricinoleate) 1.00 1.00 1.00 Example 1 1.00 0.50 8.00 5.00 TEGO® FILMSTAR One MB(Polyglyceryl-3 Stearate / Sebacate Crosspolymer) 1.50 Triisostearin 1.00 1.00 1.00 1.00 Butyl Methoxydibenzoylmethane 3.00 3.00 3.00 3.00 Ethylhexyl Salicylate 4.00 4.00 4.00 4.00 Octocrylene 7.00 7.00 7.00 7.00 B Water(Aqua) add to add to add to add to 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 Tromethamine 0.30 0.30 0.30 0.30 TEGO® Cosmo C 100(Creatine) 0.50 0.50 0.50 0.50 Z Verstatil® TBO(Triethyl Citrate; Caprylyl Glycol; Benzoic Acid) 1.00 1.00 1.00 1.00

[0026] 202300186 Foreign Filing 43 Hydrating Foot Care Cream Phase Ingredients w / w% w / w% w / w% A ISOLAN® PDI(Diisostearoyl Polyglyceryl-3 Dimer Dilinoleate) 3.50 3.50 3.50 dermofeel® viscolid MB(Hydrogenated Palm Oil; Hydrogenated Rapeseed Oil) 1.00 1.00 1.00 Cera Alba 1.00 1.00 1.00 Hydrogenated Castor Oil 1.00 1.00 1.00 Butyrospermum Parkii (Shea) Butter 1.00 1.00 1.00 TEGOSOFT® LO MB(Lauryl Oleate) 10.00 10.00 TEGOSOFT® DC MB(Decyl Cocoate) 6.00 3.00 6.00 Example 1 0.5 4.00 12.00 Prunus Amygdalus Dulcis (Sweet Almond) Oil 6.00 6.00 6.00 Zinc Stearate 1.00 1.00 1.00 Triacetin(Glyceryl Triacetate) 0.50 0.50 0.50 dermofeel® Toco 70 non GMO(Tocopherol; Helianthus Annuus (Sunflower) Seed Oil) 0.20 0.20 0.20 B Water(Aqua) add to add to add to 100 100 100 Glycerin 5.00 5.00 5.00 Butylene Glycol 3.00 3.00 3.00 Sodium Chloride 2.00 2.00 2.00 Verstatil® SL non GMO(Aqua; Sodium Levulinate; Potassium Sorbate) 1.50 1.50 1.50 Panthenol 0.50 0.50 0.50 dermosoft® 250 eco (Phenylpropanol) 0.05 0.05 0.05 C Urea 5.00 5.00 5.00 Water (Aqua) 5.00 5.00 5.00

[0027] 202300186 Foreign Filing 44 Water free Oil for Sun Care, SPF 50 PhaseIngredientw / w% w / w% w / w% w / w% A Diethylhexyl Butamido Triazone 3.00 3.00 3.00 3.00 Ethylhexyl Salicylate 3.00 3.00 3.00 3.00 Ethylhexyl Triazone 3.50 3.50 3.50 3.50 Butyl Methoxydibenzoylmethane 5.00 5.00 5.00 5.00 Diethylamino Hydroxybenzoyl Hexyl Benzoate 8.00 8.00 8.00 8.00 Bis-Ethylhexyloxyphenol Methoxyphenyl Trianzone 8.00 8.00 8.00 8.00 TEGOSOFT® DC MB(Decyl Cocoate) add to 100 add to 100 add to 100 add to 100 TEGOSOFT® XC (Phenoxyethyl Caprylate) 30.00 30.00 30.00 30.00 Example 110.00 5.00 0.1 0.5TEGOSOFT® DEC (Diethylhexyl Carbonate) 10.00 4.50 14.00 15.00 TEGOSOFT® TN(C12-15 Alkyl Benzoate) 5.00 0.50 1.00 14.50 Tegosoft® CT (Caprylic / Capric Triglyceride) 10.00 Ethanol 10.00 dermofeel® E 74 A non GMO (Tocopheryl Acetate, Helianthus Annuus 0.50 0.50 - - (Sunflower) Seed Oil) dermofeel® Toco 70 non GMO (Tocopherol; Helianthus Annuus 0.30 0.30 - - (Sunflower) Seed Oil) Conditioning Balm Phase Ingredient w / w% w / w% A TEGO® Alkanol 1618 MB(Cetearyl 4.40 4.40 Alcohol) Example 1 1.00 0.1 VARISOFT® EQ 65 3.10 3.10 MB(Distearoylethyl Dimonium Chloride; Cetearyl Alcohol) B Water(Aqua) add to 100 add to 100 Glycerin 2.00 2.00 Z dermosoft® Pentiol eco(Pentylene 4.00 4.00 Glycol) Perfume q.s. q.s. 202300186 Foreign Filing 45 Cleansing balm for strongly damaged hair Phase Ingredient w / w% w / w% A Soybean (Glycine Soja) Oil 45.00 45.00 Example 1 5.00 0.1 VARISOFT® EQ 100(Bis-(Isostearoyl / Oleoyl Isopropyl) 1.00 1.00 Dimonium Methosulfate) TEGO® Sulfosuccinate DO 75(Diethylhexyl Sodium 4.00 4.00 Sulfosuccinate) B Water(Aqua) add to 100 add to 100 Jaguar C-162(Hydroxypropyl Guar (and) Hydroxypropyl 0.40 0.40 Guar Hydroxypropyltrimonium Chloride) Glycerin 2.00 2.00 TEGO® Betain F 50(Cocamidopropyl Betaine) 7.90 7.90 REWOPOL® SB FA 30 B MB(Disodium Laureth 7.50 7.50 Sulfosuccinate) Z Verstatil® BL non GMO (Aqua; Sodium Levulinate; Sodium 2.00 2.00 Benzoate) dermosoft® GMCY MB(Glyceryl Caprylate) 0.30 0.30

[0028] 202300186 Foreign Filing 46 High Oil Cream Phase Ingredient w / w% w / w% w / w% A Soybean (Glycine Soja) Oil 45.00 45.00 50.00 Example 1 5.00 5.00 0.10 VARISOFT® EQ 100(Bis- 1.50 1.50 1.50 (Isostearoyl / Oleoyl Isopropyl) Dimonium Methosulfate) ECOHANCE® Remo XP 8.00 8.00 8.00 (Sorbityl / Xylityl Pelargonate) B SOPHANCE® LA-A (Glycolipids) 6.00 RHEANCE® One(Glycolipids) 6.00 6.00 TEGO® Betain F 18.00 18.00 18.00 50(Cocamidopropyl Betaine) Water(Aqua) add to 100 add to 100 add to 100 Glycerin 2.00 2.00 2.00 C Verstatil® TBO(Triethyl Citrate; 0.60 0.60 0.60 Caprylyl Glycol; Benzoic Acid)

[0029] 202300186 Foreign Filing 47 Detangling Milk Phase Ingredient w / w% A VARISOFT® EQ 100(Bis-(Isostearoyl / Oleoyl Isopropyl) Dimonium 1.50 Methosulfate) Example 1 0.10 TEGO® Solve 61 MB(Polyglyceryl-6 Caprylate; Polyglyceryl-3 Cocoate; 2.00 Polyglyceryl-4 Caprate; Polyglyceryl-6 Ricinoleate) B Water(Aqua) add to 100 Glycerin 2.00 Verstatil® TBG MB(Triethyl Citrate; Glyceryl Caprylate; Benzoic Acid) 1.00

[0030] 202300186 Foreign Filing 48 Clear conditioning shampoo Ingredient w / w-% Example 1 0.5 TEXAPON® NSO, BASF, 28%-ig 32.00 (INCI: Sodium Laureth Sulfate) REWODERM® LI S 80, Evonik Nutrition & Care GmbH (INCI: (PEG-200 2.00 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate) Perfume 0.25 Water ad 100.00 TEGO® Cosmo C 100, Evonik Nutrition & Care GmbH, 1.50 (INCI: Creatine) Jaguar C-162, Solvay, 0.20 (INCI: Hydroxypropyl Guar Hydroxypropyltrimonium Chloride) TEGO® Betain F 50, Evonik Nutrition & Care GmbH, 38%-ig 8.00 (INCI: Cocamidopropyl Betaine) NaCl 2.50 Citric Acid, 30%-ig q.s. (pH 5.0) Preservative q.s. Pearlizing shampoo Ingredient w / w-% TEXAPON® NSO, BASF, 28%-ig 32.00 (INCI: Sodium Laureth Sulfate) Example 1 0.20 Perfume 0.15 Water ad 100.00 TEGO® Betain F 50, Evonik Nutrition & Care GmbH, 38%-ig 8.00 (INCI: Cocamidopropyl Betaine) TEGO® Pearl N 300, Evonik Nutrition & Care GmbH, 2.00 (INCI: Glycol Distearate; Laureth-4; Cocamidopropyl Betaine) ANTIL® 171 Evonik Nutrition & Care GmbH, 2.50 (INCI: PEG-18 Glyceryl Oleate / Cocoate) NaCl 0.90 Citric Acid, 30%-ig q.s. (pH 5.5) Preservative q.s. 202300186 Foreign Filing 49 Conditioning shampoo Ingredient w / w-% TEXAPON® NSO, BASF, 28%-ig (INCI: Sodium Laureth Sulfate) 32.00 ANTIL® 200, Evonik Nutrition & Care GmbH, (INCI: PEG-200 Hydrogenated 2.00 Glyceryl Palmate; PEG-7 Glyceryl Cocoate) Perfume 0.25 Water ad 100.00 Polymer JR 400, Amerchol, (INCI: Polyquaternium-10) 0.40 TEGO® Betain F 50, Evonik Nutrition & Care GmbH, 38%-ig (INCI: 8.00 Cocamidopropyl Betaine) Example 1 0.50 TEGO® Pearl N 300, Evonik Nutrition & Care GmbH, 2.00 (INCI: Glycol Distearate; Laureth-4; Cocamidopropyl Betaine) NaCl 0.30 Citric Acid, 30%-ig q.s. (pH 5.5) Preservative q.s.

[0031] 202300186 Foreign Filing 50 Anti-dandruff shampoo Ingredient w / w-% TEXAPON® LS 35, BASF, 30%-ig 24.00 (INCI: Sodium Lauryl Sulfate) TAGAT® CH 40, Evonik Nutrition & Care GmbH, 2.00 (INCI: PEG-40 Hydrogenated Castor Oil) TEGOSOFT® GC, Evonik Nutrition & Care GmbH, 1.00 (INCI: PEG-7 Glyceryl Cocoate) Example 1 0.15 Perfume 0.20 Water ad 100.00 Polymer JR 400, Amerchol, (INCI: Polyquaternium-10) 0.20 TEGO® Betain F 50, Evonik Nutrition & Care GmbH, 38%-ig 16.00 (INCI: Cocamidopropyl Betaine) Hostapon SG, Clariant, (INCI : Sodium Cocoyl Glycinate) 5.00 Microcare ZP, Thor, (INCI: Zinc Pyrithione) 0.200 Octopirox, Clariant, (INCI: Octopirox) 0.10 ABIL® Quat 3272, Evonik Nutrition & Care GmbH, 0.80 (INCI: Quaternium-80) REWOMID® D 212, Evonik Nutrition & Care GmbH, 0.80 (INCI: Cocamide MEA) ANTIL® 500, Evonik Nutrition & Care GmbH, 0.80 (INCI: PEG-200 Glyceryl Stearate) Glycerin 1.50 NaCl 0.90 Citric Acid, 30%-ig q.s. (pH 5.5) Preservative q.s.

[0032] 202300186 Foreign Filing 51 Shampoo, PEG-free Ingredient w / w-% TEXAPON® LS 35, BASF, 30% (INCI: Sodium Lauryl Sulfate) 28.00 Water ad 100.00 UCARE Polymer JR-400, Dow Chemicals, 0.10 (INCI: Polyquaternium-10) Jaguar C-162, Solvay, 0.10 (INCI: Hydroxypropyl Guar Hydroxypropyltrimonium Chloride) ANTIL® CM 90, Evonik Nutrition & Care GmbH, 0.50 (INCI: Cocamide MEA) ANTIL® SPA 80, Evonik Nutrition & Care GmbH, 1.00 (INCI: Isostearamide MIPA; Glyceryl Laurate) Xanthan Gum 0.50 Example 1 0.10 Dehyton AB 30, BASF, 31%, (INCI: Coco-Betaine) 8.00 Prifrac 2920, Croda, (INCI: Lauric Acid) 0.50 TEGOSOFT® PC 41, Evonik Nutrition & Care GmbH, 1.00 (INCI: Polyglyceryl-4 Caprate) Glycerin 1.00 Uvinul MS 40, BASF, (INCI: Benzophenon-4) 0.10 Versene 100, The Dow Chemical Company, (INCI: Tetrasodium EDTA) 0.10 Sodium Chloride 1.00 Perfume, preservative q.s. Citric Acid, 30%-ig q.s. (pH 5.0)

[0033] 202300186 Foreign Filing 52 Shampoo, Sulfate-free Ingredient w / w-% Bioterge AS-40 AOS, Stepan, (INCI: Sodium C14-16 Olefin Sulfonate) 30.00 Water ad 100.00 Jaguar C-162, Solvay, 0.15 (INCI: Hydroxypropyl Guar Hydroxypropyltrimonium Chloride) ANTIL® 500 Pellets, Evonik Nutrition & Care GmbH, 0.20 (INCI: PEG-200 Glyceryl Stearate) ANTIL® SPA 80, Evonik Nutrition & Care GmbH, 0.50 (INCI: Isostearamide MIPA; Glyceryl Laurate) Example 1 0.10 Dehyton AB 30, BASF, 31%, (INCI: Coco-Betaine) 8.00 TAGAT® CH 40, Evonik Nutrition & Care GmbH, 1.00 (INCI: PEG-40 Hydrogenated Castor Oil) Glycerin 1.00 Uvinul MS 40, BASF, (INCI: Benzophenon-4) 0.10 Sodium Chloride 1.50 Perfume, preservative q.s. Citric Acid, 30%-ig q.s. (pH 5.5)

[0034] 202300186 Foreign Filing 53 Shampoo, Sulfat-free Ingredient w / w-% TEGO® Betain F 50, Evonik Nutrition & Care GmbH, 38%-ig, (INCI: 22.00 Cocamidopropyl Betaine) Water ad 100.00 Jaguar C-162, Solvay, 0.10 (INCI: Hydroxypropyl Guar Hydroxypropyltrimonium Chloride) ANTIL® 500 Pellets, Evonik Nutrition & Care GmbH, 0.30 (INCI: PEG-200 Glyceryl Stearate) REWOPAL® PEG 6000 DS A, Evonik Nutrition & Care GmbH, 0.50 (INCI: PEG-150 Distearate) Example 1 0.10 Hostapon SG, Clariant, (INCI: Sodium Cocoyl Glycinate) 10.00 TEGO® Solve 61, Evonik Nutrition & Care GmbH, (INCI: Polyglyceryl-6 Caprylate; Polyglyceryl-3 Cocoate; Polyglyceryl-4 Caprate; 1.00 Polyglyceryl-6 Ricinoleate) Glycerin 0.50 Sodium Chloride 1.00 Perfume, preservative q.s. Citric Acid, 30%-ig q.s. (pH 4.8) Rinse-Off Conditioner Ingredient w / w-% Water ad 100.00 VARISOFT® EQ 65, Evonik Nutrition & Care GmbH, 2.00 (INCI: Distearoylethyl Dimonium Chloride; Cetearyl Alcohol) VARISOFT® BT 85, Evonik Nutrition & Care GmbH, 1.00 (INCI: Behentrimonium Chloride) Example 1 0.20 TEGO® Alkanol 1618, Evonik Nutrition & Care GmbH, 5.00 (INCI: Cetearyl Alcohol) Citric Acid, 30%-ig q.s. (pH 4.0) Preservative, Perfume q.s. 202300186 Foreign Filing 54 Rinse-Off Conditioner Ingredient w / w-% Water ad 100.00 TEGIN® M Pellets, Evonik Nutrition & Care GmbH, 1.00 (INCI: Glyceryl Stearate) TEGO® Care PSC 3, Evonik Nutrition & Care GmbH, 0.50 (INCI: Polyglyceryl-3 Dicitrate / Stearate) Jaguar C-162, Solvay, 0.10 (INCI: Hydroxypropyl Guar Hydroxypropyltrimonium Chloride) Example 1 0.70 TEGO® Alkanol 1618, Evonik Nutrition & Care GmbH, 6.00 (INCI: Cetearyl Alcohol) Citric Acid, 30%-ig q.s. (pH 4.5) Preservative, Perfume q.s. Wet wipes impregnation fluid I Ingredient w / w-% Pentylene Glycol 2.0 Glycerin 1.0 TEGO® Solve 61 (Polyglyceryl-6 Caprylate; Polyglyceryl-3 Cocoate; Polyglyceryl-4 2.0 Caprate; Polyglyceryl-6 Ricinoleate) Example 1 0.5 Allantoin 0.2 Maltodextrin 0.5 Chamomilla extract 0.1 Preservative q.s. Perfume q.s. Water ad 100.0 Citric Acid, 30% ad pH 5.5

[0035] 202300186 Foreign Filing 55 Wet wipes impregnation fluid II Ingredient w / w-% TEGO® Solve 61 (Polyglyceryl-6 Caprylate; Polyglyceryl-3 Cocoate; Polyglyceryl-4 1.5 Caprate; Polyglyceryl-6 Ricinoleate) TEGO® Solve 55 (Polyglyceryl-6 Caprylate; Polyglyceryl-4 Caprate; Propylene Glycol) 1.0 Example 1 0.2 Preservative q.s. Perfume 0.1 Propanediol 3.0 ad Water 100.0 Cleansing Micellar Water Ingredient w / w-% Water ad 100.0 TEGOSOFT® PC 41 (Polyglyceryl-4 Caprate) 5.5 Preservative q.s. Example 1 0.3 Glycerin 1.0 Disodium EDTA 0.2 Citric Acid, 30% ad pH 5.5 Micellar Water Ingredient w / w-% REWOTERIC® AM C (Sodium Cocoamphopropionate) 3.0 Example 1 0.6 TEGOSOFT® GMC 6 (PEG-6 Caprylic / Capric Glycerides) 5.0 Water ad 100.0 Glycerin 8.0 Citric Acid ad pH 5.5 Preservative q.s.

Claims

202300186 Foreign Filing 56 Claims 1. Composition comprising a triglyceride mixture with a distribution of fatty acid acyl acyl groups in the triglycerides of 18 wt-% to 34 wt-%, preferably 20 wt-% to 30 wt-%, more preferably 21 wt-% to 28 wt- %, palmitoyl, 0.5 wt-% to 10 wt-%, preferably 1.0 wt-% to 9.0 wt-%, more preferably 2.0 wt-% to 7.0 wt-%, stearoyl, 28 wt-% to 44 wt-%, preferably 30 wt-% to 42 wt-%, more preferably 31 wt-% to 41 wt- %, oleoyl, 18 wt-% to 34 wt-%, preferably 21 wt-% to 31 wt-%, more preferably 22 wt-% to 30 wt- %, linoleoyl, less than a total of 1.0 wt-%, preferably 0.01 wt-% to 0.7 wt-%, more preferably 0.05 wt-% to 0.4 wt-%, cyclopropenoid fatty acid acyl groups, wherein the weight percents refer to all fatty acid acyl groups comprised in all triglycerides comprised in the composition, characterised in that the composition comprises 50 ppm to 2000 ppm, preferably 150 ppm to 1500 ppm, more preferably 250 ppm to 1250 ppm, most preferably 400 ppm to 1100 ppm, tocopherol, wherein the ppm refer to the total composition.

2. Composition according to claim 1 characterised in that it comprises less than 100 ppb, preferably 0.1 to 60 ppb, more preferably 0.5 to 25 ppb, most preferably 1.0 to 10 ppb, in total of the group of polycyclic aromatic hydrocarbons (PAH) selected from phenantrene, anthracene, fluoranthene, pyrene, benzo(a)anthracen, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene and benzo(a)pyrene, wherein the ppb refer to the total composition 3. Composition according to claim 1 or 2 characterised in that the triglyceride content of the composition is from 90 wt-% to 99.95 wt-%, preferably 95 wt-% to 99.92 wt-%, wherein the weight percents refer to the total composition.

4. Composition according to at least one of the preceding claims characterised in that it has an iodine value of 70.0 g I / 100 g to 100 g I / 100 g, preferably 75.0 g I / 100 g to 95.0 g I / 100 g.

5. Composition according to at least one of the preceding claims characterized in that it has an acid value of between 0.01 mg KOH / g and 8.0 mg KOH / g, preferably between 0.02 mg KOH / g and 2.0 mg KOH / g.202300186 Foreign Filing 57 6. Composition according to at least one of the preceding claims characterized in that it has a saponification value of between 175 mg KOH / g and 210 mg KOH / g, preferably between 180 mg KOH / g and 205 mg KOH / g.

7. Composition according to at least one of the preceding claims characterized in that it does not comprise a cosmetic preservative.

8. Process of treating a baobab oil comprising the steps of A) providing a baobab oil, B) heating and keeping said baobab oil at a temperature in the range of 90 °C to 270 °C, C) running water steam through said baobab oil, preferably continuously.

9. Process according to claim 8 characterised in that in process step A) said baobab oil is provided by isolating oil from baobab seeds, preferably by cold pressing.

10. Process according to claim 9 characterised in that in process step A) said baobab seeds are provided with or without decortication, preferably without decortication.

11. Process according to at least any of claims 8 to 10 characterised in that in process step B) the temperature is kept in said range for a period of time from 0.1 hours to 24 hours, preferably from 0.3 hour to 15 hours, more preferably from, 1 hour to 12 hours.

12. Process according to at least any of claims 8 to 11 characterised in that process step C) is conducted in parallel to process step B).

13. Process according to claim 12 characterised in that process step C) is carried out over a period of time corresponding to at least 80 %, more preferably between 90 % and 100 % of the time period the temperature is kept in said range of process step B).

14. Process according to at least any of claims 8 to 13 characterised in that in process step C) said water steam is run through said baobab oil at a rate of 0.05 to 2.5 wt-% water steam per hour, wherein the wt-% of water steam relate to the amount of oil that is treated.

15. Use of a composition according to at least one of the claims 1 to 7 for the preparation of a cosmetic, dermatologic, feed, food and / or pharmaceutical formulation, preferably for topic applications.