Gasoline modifier, preparation method therefor and use thereof, and clean and environmentally friendly gasoline containing same

By adding specific ratios of 3# or 5# white oil, gasoline purification synergist and isocitorol to gasoline, the problem of existing gasoline detergents increasing combustion deposition is solved, and the effects of efficiency enhancement, fuel saving, carbon cleaning and emission reduction are achieved, and the product is safe and environmentally friendly.

WO2025092335A1PCT designated stage expired Publication Date: 2025-05-08BEIJING SHISHANG NEW MATERIAL TECH CO LTD

Patent Information

Application Number
PCT/CN2024/122171
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2023-11-03
Filing Date
2024-09-29
Publication Date
2025-05-08

AI Technical Summary

Technical Problem

While removing carbon deposits from the engine, existing gasoline detergents will increase combustion deposition. Most of them are chemical preparations, containing non-petroleum components, which are harmful to the engine and cannot achieve overall clean and environmentally friendly effects.

Method used

A new gasoline modifier is used, which includes 10-30 parts of 3# or 5# white oil, 5-30 parts of gasoline depletion synergist and 40-85 parts of isooctanol. The liquid substance formed by gasoline purification and synergist through the esterification reaction includes 2-ethylhexylphosphate, hydroxyethyldiphosphonic acid and its derivatives. The diluted liquid is a ratio of high-purity formaldehyde to oligomeric water clusters. By changing the physical properties of gasoline, the effects of efficiency enhancement, fuel saving, carbon cleaning and emission reduction are achieved.

Benefits of technology

The gasoline modifier can effectively remove carbon deposits from the engine without increasing combustion deposition, improve engine combustion efficiency, enhance power, reduce exhaust pollutant emissions, save gasoline, and contain no harmful elements, which is safe and environmentally friendly.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure PCTCN2024122171-FTAPPB-I100001
    Figure PCTCN2024122171-FTAPPB-I100001
  • Figure PCTCN2024122171-FTAPPB-I100002
    Figure PCTCN2024122171-FTAPPB-I100002
  • Figure PCTCN2024122171-FTAPPB-I100003
    Figure PCTCN2024122171-FTAPPB-I100003
Patent Text Reader

Abstract

A gasoline modifier, a preparation method therefor and a use thereof, and a clean and environmentally friendly gasoline containing same. By volume, the gasoline modifier comprises 10-30 parts of No. 3 or No. 5 white oil, 5-50 parts of a gasoline detergent synergist and 40-85 parts of isooctyl alcohol; the gasoline detergent synergist comprises a stock liquid and a diluent liquid; the stock liquid is a liquid substance formed by mixing 2-ethylhexyl phosphate and etidronic acid in a weight ratio of 1.8-3:1 and heating to perform an esterification reaction; and / or the stock liquid comprises 2-ethylhexanol, phosphite ester, 2-ethylhexyl acetate, polyisobutylene succinic anhydride and ethylhexyl phosphate; the diluent liquid is formed by mixing formaldehyde having a content greater than 99% with oligomeric water clusters in a weight ratio of 1:4-3:7; and the weight percentage of the stock solution in the gasoline detergent synergist is 0.8%-1.3% white oil. The gasoline modifier is a pure petroleum product. When added to gasoline, it can change the physical properties of the gasoline, and achieve the effects of increasing efficiency, saving fuel, removing carbon and reducing emissions.
Need to check novelty before this filing date? Find Prior Art

Description

Gasoline modifier, preparation method, application and clean environmentally friendly gasoline containing same Technical Field

[0001] The present invention relates to the field of gasoline modification, in particular to a gasoline modifier, a preparation method and application thereof, and clean and environmentally friendly gasoline containing the gasoline modifier. Background Art

[0002] The rapid increase in my country's vehicle ownership and the widespread use of electronically controlled direct fuel injection (EDFI) in engines are placing higher demands on fuel quality. Olefins and some heavy aromatics in gasoline are susceptible to oxidation and condensation reactions at high temperatures, further forming carbon deposits and gum in the engine, severely impacting engine performance and causing power loss, increased emissions, and increased fuel consumption. The engine's fuel nozzles, intake valves, and combustion chamber are the most vulnerable areas for deposit formation. Fourth-generation gasoline detergents, represented by polyisobutylene amine compounds, can effectively remove deposits formed in engine fuel injectors, intake valves, and other areas, but they inevitably increase combustion deposits. This is primarily due to the high thermal stability of the polyisobutylene group, which is resistant to decomposition at high temperatures. After the fuel enters the combustion chamber, some of the undecomposed detergent is adsorbed and accumulates on the combustion chamber's inner walls, forming deposits, which in turn increases the formation of carbon deposits in the combustion chamber.

[0003] Currently, similar additives (detergents) on the market are mostly chemical agents containing non-petroleum ingredients, which can be harmful to engines over time. Due to their single ingredient composition, their overall cleaning performance varies, failing to achieve a comprehensive cleaning and environmentally friendly solution. While some detergents can effectively remove deposits formed on engine fuel injectors, intake valves, and other areas, they inevitably increase combustion deposits.

[0004] Therefore, it is clear that the above-mentioned existing detergents still have inconveniences and defects, and are in urgent need of further improvement. How to create a new gasoline modifier that can not only achieve the effect of carbon removal, but also achieve the effects of increasing efficiency, saving fuel, and reducing emissions has become a goal that the industry needs to improve.

[0005] Summary of the Invention

[0006] The technical problem to be solved by the present invention is to provide a new gasoline modifier, its preparation method, application and clean and environmentally friendly gasoline containing it, so that it can not only achieve the effect of carbon removal, but also achieve the effects of efficiency improvement, fuel saving and emission reduction, thereby overcoming the shortcomings of the existing technology.

[0007] In order to solve the above technical problems, the present invention adopts the following technical solutions:

[0008] In a first aspect, the present invention provides a gasoline modifier comprising, by volume, 10-30 parts of 3# or 5# white oil, 5-30 parts of gasoline detergent synergist, and 40-85 parts of isooctyl alcohol;

[0009] The gasoline detergent synergist comprises a stock solution and a diluent liquid; the stock solution is a liquid substance formed by mixing 2-ethylhexyl phosphate and hydroxyethylidene diphosphonic acid in a weight ratio of 1.8-3:1, heating and performing an esterification reaction; and / or the stock solution comprises 2-ethylhexanol, phosphite, 2-ethylhexyl acetate, succinic anhydride and ethylhexyl phosphate; the diluent liquid is formed by mixing formaldehyde with a content of >99% and oligomeric water clusters in a weight ratio of 1:4-3:7; the weight percentage of the stock solution in the gasoline detergent synergist is 0.8%-1.3%.

[0010] The 2-ethylhexyl phosphate is in liquid form with a molecular formula of C24H54O8P2; the hydroxyethylidene diphosphonic acid is in dry powder form with a molecular formula of C2H8O7P2. The structural formula of ethylhexyl phosphate is as follows:

[0011] It often exists in the form of a dimer with the following structural formula:

[0012] That is, the 2-ethylhexyl phosphate is in the form of a blend of a monoester and a dimer.

[0013] The structural formula of hydroxyethylidene diphosphonic acid is as follows:

[0014] The above two organic compounds both have phosphoric acid structures, so according to the principle of like dissolves like, the mixture can be dissolved when heated. Both organic compounds have relatively active carboxyl and hydroxyl groups, so an esterification reaction will occur.

[0015] After heating reaction, the two organic substances generate reactants which basically contain 2-ethylhexanol, phosphite, 2-ethylhexyl acetate, polyisobutylene succinic anhydride and the remaining ethylhexyl phosphate which does not participate in the reaction.

[0016] Among them, the structural formula of 2-ethylhexanol is as follows:

[0017] The structural formula of phosphite is as follows:

[0018] The structural formula of 2-ethylhexyl acetate is as follows:

[0019] The structural formula of succinic anhydride in polyisobutylene succinic anhydride is as follows:

[0020] 2-Ethylhexanol and 2-Ethylhexyl acetate are polymeric dispersants that promote the dispersion of gasoline components, resulting in thorough mixing of gasoline with oxygen in the air and promoting complete combustion. This dispersion also causes the gasoline to form a mist when sprayed, further facilitating its thorough mixing and contact with air. Oligomeric water clusters enhance the effects of these two additives, fully dispersing and atomizing the effective gasoline. By modifying the gasoline's physical properties, they achieve efficiency gains, fuel savings, carbon reduction, and emission reductions. Formaldehyde is more flammable than higher alkanes, and the presence of oligomeric water clusters creates a "micro-explosion" effect, further atomizing and dispersing the gasoline and promoting complete combustion.

[0021] Phosphite and ethylhexyl phosphate act as antioxidants in their mixture. Working together, they form an isolation film in the gasoline combustion chamber, preventing corrosion from oxidizing components, particularly carbon deposits. This effectively inhibits the formation of high-temperature sludge and removes carbon deposits from the oil circuit and engine interior, ensuring smoother fuel flow and more complete atomized combustion, thus conserving gasoline.

[0022] Polyisobutylene succinic anhydride can effectively control carbon deposits in the engine combustion chamber. The mechanism is that polyisobutylene succinic anhydride will adhere to the porous carbon deposits, destroy the carbon adhesion, and decompose the carbon deposits layer by layer.

[0023] In addition, the purpose of adding white oil is to form a protective film on the entire oil circuit wall, preventing the formation of carbon deposits, making the oil circuit more unobstructed and improving the atomization of gasoline. Moreover, white oil burns fully, does not produce carbon deposits, and reduces the emission of harmful substances.

[0024] The main function of isooctyl alcohol is to increase the octane number of gasoline, making the combustion efficiency of the mixed oil high and playing a positive role in energy conservation and consumption reduction of gasoline.

[0025] Based on the above-mentioned mechanism of action, the stock solution can also be directly made of 2-ethylhexanol, phosphite, 2-ethylhexyl acetate, polyisobutylene succinic anhydride and ethylhexyl phosphate. In this case, the content of each component is the same as the content of each component in the liquid substance formed as follows: 2-ethylhexyl phosphate and hydroxyethylidene diphosphonic acid are mixed and heated in a weight ratio of 1.8-3:1 to form a liquid substance by esterification reaction.

[0026] In a second aspect, the present invention provides a method for preparing the above-mentioned gasoline modifier, comprising: mixing 2-ethylhexyl phosphate and hydroxyethylidene diphosphonic acid in a weight ratio of 1.8-3:1, heating and performing an esterification reaction, wherein the liquid substance formed after the reaction is a stock solution; mixing formaldehyde having a content of >99% and oligomeric water clusters in a weight ratio of 1:4-3:7, and mixing to form a diluted liquid; mixing the stock solution and the diluted liquid, wherein the weight percentage of the stock solution is 0.8%-1.3%, and the resulting mixture is a gasoline detergent synergist; and stirring the gasoline detergent synergist with 3# or 5# white oil and isooctyl alcohol in proportion and uniformly mixing to obtain the gasoline modifier.

[0027] Furthermore, the esterification reaction of mixing 2-ethylhexyl phosphate and hydroxyethylidene diphosphonic acid in a weight ratio of 1.8-3:1 by heating includes: placing 2-ethylhexyl phosphate and hydroxyethylidene diphosphonic acid in a weight ratio of 1.8-3:1 in a glass reactor and stirring evenly; the reaction starting temperature is 100°C, the final temperature is 220-230°C, the temperature is gradually increased in the middle, and the water evaporation process is repeated in multiple times; after the reaction is completed, the heating of the reactor is stopped and the temperature is naturally cooled to room temperature, and the substance in the reactor is liquid, which is the original solution.

[0028] Furthermore, the water evaporation process is repeated multiple times, including: first, adjusting the reaction temperature to 100°C, during which the powder is continuously stirred and slowly dissolved to produce water; after maintaining the temperature for a period of time, when no distilled water is produced and evaporated from the reactor, further increasing the reaction temperature to 110°C to evaporate the reaction water; and successively increasing the temperature in steps of 10°C to a final temperature of 220-230°C, and repeating the water evaporation process.

[0029] In a third aspect, the present invention provides an application of a gasoline modifier, wherein the gasoline modifier is the above-mentioned gasoline modifier; or the gasoline modifier prepared by the preparation method of the above-mentioned gasoline modifier.

[0030] The gasoline modifier is a gasoline fuel-saving modifier, which is used to save gasoline; and / or, the gasoline modifier is a gasoline efficiency-enhancing modifier, which is used to improve engine combustion efficiency and enhance engine power; and / or, the gasoline modifier is a gasoline carbon-removing modifier, which is used to clean carbon deposits generated by incomplete combustion inside the engine and prevent new carbon deposits from being generated; and / or, the gasoline modifier is a gasoline emission-reducing modifier, which is used to reduce exhaust pollution.

[0031] In a fourth aspect, the present invention provides a clean and environmentally friendly gasoline containing the above-mentioned gasoline modifier or the gasoline modifier prepared by the above-mentioned method for preparing the gasoline modifier.

[0032] Furthermore, 60-330 ml of gasoline modifier is added to every 40-60 L of gasoline.

[0033] Furthermore, the gasoline is 92# gasoline.

[0034] By adopting the above technical solution, the present invention has at least the following advantages:

[0035] (1) The gasoline modifier of the present invention is a pure petroleum product and a new type of gasoline modifier without harmful elements (the product does not contain prohibited ingredients, sulfur, nitrogen, heavy metals, etc.).

[0036] (2) After the gasoline modifier of the present invention is added to gasoline, it does not change any component index of the crude oil product, but only changes the physical properties of the oil product; it changes the state of the oil molecules in the crude oil product into a small molecule state, so that the droplets atomized during combustion are finer and smaller, fully mixed with air, and fully burned. The molecular weight distribution of the product is narrow, the viscosity is low, and the low-temperature performance is good. At a certain temperature, it decomposes into low-molecular olefins, forming a micro-explosion effect (secondary atomization), making the oil molecules smaller, increasing the contact area between air and oil molecules, and releasing more oxygen to participate in the combustion reaction. Due to the increase in oxygen content, the combustion is more complete, thereby improving the engine combustion efficiency, enhancing engine power, reducing the emission of automobile exhaust pollutants, and saving gasoline. At the same time, the product can clean the carbon deposits produced by the original incomplete combustion and no longer produce new carbon deposits, so that the cylinder body is restored to a clean state and the engine function is restored (such as unstable idling and insensitive throttle).

[0037] (3) After the gasoline modifier of the present invention is added to gasoline, it can achieve the effects of increasing efficiency, saving fuel, removing carbon and reducing emissions by changing the physical properties of gasoline; it can greatly improve the quality of gasoline, improve the sensitivity of gasoline, eliminate engine resonance, stabilize kinetic energy output, and save fuel consumption; it can achieve full combustion of fuel in the engine, thereby reducing automobile exhaust pollutant emissions. DETAILED DESCRIPTION

[0038] Exemplary embodiments of the present invention will be described in more detail below with reference to the accompanying drawings. Although exemplary embodiments of the present invention are shown in the accompanying drawings, it should be understood that the present invention can be implemented in various forms and should not be limited by the embodiments set forth herein. Rather, these embodiments are provided to enable a more thorough understanding of the present invention and to fully convey the scope of the present invention to those skilled in the art.

[0039] Example 1 Preparation of gasoline modifier 1

[0040] Ethylhexyl phosphate and hydroxyethylidene diphosphonic acid were placed in a glass reactor in a ratio of 3:1 and stirred to achieve maximum uniformity. The reaction temperature was initially adjusted to 100°C. During the reaction, the powders were stirred continuously, gradually dissolving and producing water. After a period of time, when no more distilled water evaporated from the reactor, the reaction temperature was raised to 110°C to evaporate the water. The temperature was then gradually increased in 10°C increments to a final temperature of 220-230°C, and the evaporation process was repeated. After the reaction was complete, the reactor was removed from heating and allowed to cool naturally to room temperature. The contents of the reactor were now a liquid stock solution containing 2-ethylhexanol, phosphite, 2-ethylhexyl acetate, polyisobutylene succinic anhydride, and any remaining ethylhexyl phosphate that did not react.

[0041] Formaldehyde with a content of >99% is mixed with oligomeric water clusters in a ratio of 1:4 as a diluent.

[0042] The stock solution and the dilution liquid were mixed and stirred, wherein the proportion of the stock solution was 0.8%.

[0043] The obtained mixture is gasoline detergent enhancer 1.

[0044] Take 20ml of 3# white oil, 15ml of gasoline detergent and synergist 1 and 40ml of isooctyl alcohol, stir and mix them evenly to obtain gasoline modifier 1.

[0045] Example 2 Preparation of Gasoline Modifier 2

[0046] Ethylhexyl phosphate and hydroxyethylidene diphosphonic acid were placed in a glass reactor in a ratio of 1.8:1 and stirred until uniform. The reaction temperature was initially set to 100°C. During the reaction, the powders were stirred continuously, gradually dissolving and producing water. After a period of time, when no more distilled water evaporated from the reactor, the temperature was raised to 110°C to evaporate the water. The temperature was then gradually increased in 10°C increments to a final temperature of 220-230°C, and the evaporation process was repeated. After the reaction was complete, the reactor was removed from heating and allowed to cool naturally to room temperature. The contents of the reactor were now a liquid stock solution containing 2-ethylhexanol, phosphite, 2-ethylhexyl acetate, polyisobutylene succinic anhydride, and any remaining ethylhexyl phosphate that did not react.

[0047] Formaldehyde with a content of >99% is mixed with oligomeric water clusters in a ratio of 3:7 as a diluent.

[0048] The original liquid and the diluted liquid are mixed and stirred, wherein the proportion of the original liquid is 1.3%, and the resulting mixture is the gasoline detergent enhancer 2.

[0049] Take 25ml of 3# white oil, 25ml of gasoline detergent and synergist 2 and 60ml of isooctyl alcohol, stir and mix them evenly to obtain gasoline modifier 2.

[0050] Example 3 Preparation of Gasoline Modifier 3

[0051] Ethylhexyl phosphate and hydroxyethylidene diphosphonic acid were placed in a glass reactor in a ratio of 1.8:1 and stirred until uniform. The reaction temperature was initially set to 100°C. During the reaction, the powders were stirred continuously, gradually dissolving and producing water. After a period of time, when no more distilled water evaporated from the reactor, the temperature was raised to 110°C to evaporate the water. The temperature was then gradually increased in 10°C increments to a final temperature of 220-230°C, and the evaporation process was repeated. After the reaction was complete, the reactor was removed from heat and allowed to cool naturally to room temperature. The contents of the reactor were now a liquid stock solution containing 2-ethylhexanol, phosphite, 2-ethylhexyl acetate, polyisobutylene succinic anhydride, and any remaining ethylhexyl phosphate that did not react.

[0052] Formaldehyde with a content of >99% is mixed with oligomeric water clusters in a ratio of 1:4 as a diluent.

[0053] The original liquid and the diluted liquid are mixed and stirred, wherein the proportion of the original liquid is 1.3%, and the resulting mixture is gasoline detergent enhancer 3.

[0054] Take 30ml of 5# white oil, 50ml of gasoline detergent and synergist 3 and 60ml of isooctyl alcohol, stir and mix them evenly to obtain gasoline modifier 3.

[0055] Example 4 Preparation of Gasoline Modifier 4

[0056] Ethylhexyl phosphate and hydroxyethylidene diphosphonic acid were placed in a glass reactor at a ratio of 2.5:1 and stirred until uniform. The reaction temperature was initially set to 100°C. During the reaction, the powders were stirred continuously, gradually dissolving and producing water. After a period of time, when no more distilled water evaporated from the reactor, the temperature was raised to 110°C to evaporate the water. The temperature was then gradually increased in 10°C increments to a final temperature of 220-230°C, and the evaporation process was repeated. After the reaction was complete, the reactor was removed from heating and allowed to cool naturally to room temperature. The contents of the reactor were now a liquid stock solution containing 2-ethylhexanol, phosphite, 2-ethylhexyl acetate, polyisobutylene succinic anhydride, and any remaining ethylhexyl phosphate that did not react.

[0057] Formaldehyde with a content of >99% is mixed with oligomeric water clusters in a ratio of 5:14 as a diluent.

[0058] The original liquid and the diluted liquid are mixed and stirred, wherein the proportion of the original liquid is 1%, and the resulting mixture is the gasoline detergent enhancer 4.

[0059] Take 10ml of 3# white oil, 5ml of gasoline detergent and synergist 4 and 85ml of isooctyl alcohol, stir and mix them evenly to obtain gasoline modifier 4.

[0060] Example 5 Preparation of Gasoline Modifier 5

[0061] 2-Ethylhexyl phosphate and hydroxyethylidene diphosphonic acid were placed in a glass reactor in a ratio of 2:1 and stirred until uniform. The reaction temperature was initially set to 100°C. During the reaction, the powders were stirred continuously, gradually dissolving and producing water. After a period of time, when no more distilled water evaporated from the reactor, the temperature was raised to 110°C to evaporate the water. The temperature was then gradually increased in 10°C increments to a final temperature of 220-230°C, and the evaporation process was repeated. After the reaction was complete, the reactor was de-heated and allowed to cool naturally to room temperature. The contents of the reactor were now a liquid stock solution containing 2-ethylhexanol, phosphite, 2-ethylhexyl acetate, polyisobutylene succinic anhydride, and any remaining ethylhexyl phosphate that did not react.

[0062] Formaldehyde with a content of >99% is mixed with oligomeric water clusters in a ratio of 2:5 as a diluent.

[0063] The stock solution and the dilution liquid are mixed and stirred, wherein the proportion of the stock solution is 1%.

[0064] The obtained mixture is gasoline detergent enhancer 5.

[0065] Take 20ml of 3# white oil, 25ml of gasoline detergent and synergist 5 and 50ml of isooctyl alcohol, stir and mix them evenly to obtain gasoline modifier 5.

[0066] Example 6 Preparation of Clean and Environmentally Friendly Gasoline 1

[0067] At a gas station in the market, mix 40 liters of 92# gasoline of the National VI standard and 1.75 ml of gasoline modifier (20 ml of 3# white oil, 15 ml of gasoline cleaning and enhancing agent 1, 40 ml of isooctyl alcohol) to form clean and environmentally friendly gasoline 1.

[0068] Example 7 Preparation of Clean and Environmentally Friendly Gasoline 2

[0069] At the gas station in the market, 50 liters of National VI standard 92# gasoline, 2,110 ml of gasoline modifier (25 ml of 3# white oil, 25 ml of gasoline cleaning agent 2 and 60 ml of isooctyl alcohol) are mixed and stirred evenly to form clean and environmentally friendly gasoline 2.

[0070] Example 8 Preparation of Clean and Environmentally Friendly Gasoline 3

[0071] At the gas station in the market, 60 liters of National VI standard 92# gasoline and 140 ml of gasoline modifier 3 (30 ml of 3# white oil, 50 ml of gasoline cleaning and enhancing agent 3 and 60 ml of isooctyl alcohol) are mixed and stirred evenly to form clean and environmentally friendly gasoline 3.

[0072] Example 9 Preparation of Clean and Environmentally Friendly Gasoline 4

[0073] At the gas station in the market, 45 liters of 92# gasoline of the National VI standard, 100 ml of gasoline modifier 4 (10 ml of 3# white oil, 5 ml of gasoline cleaning agent 4 and 85 ml of isooctyl alcohol) are mixed and stirred evenly to form clean and environmentally friendly gasoline 4.

[0074] Example 10 Preparation of Clean and Environmentally Friendly Gasoline 5

[0075] At the gas station in the market, 40 liters of 92# gasoline of the National VI standard, 95 ml of gasoline modifier 5 (20 ml of 3# white oil, 25 ml of gasoline cleaning enhancer 5 and 50 ml of isooctyl alcohol) are mixed and stirred evenly to form clean and environmentally friendly gasoline 5.

[0076] The clean, environmentally friendly gasoline 5 obtained in Example 10 was tested on a prototype vehicle against conventional National VI standard 92# gasoline to examine their carbon removal, energy savings, efficiency gains, and emission reductions. The energy savings and emission reductions were measured using the heavy-duty vehicle fuel consumption and exhaust pollutant method (chassis dynamometer method).

[0077] The test results are as follows:

[0078] (1) Carbon removal status

[0079] By comparison, it can be seen that conventional National VI standard 92# gasoline will produce carbon deposits after being used for a period of time; while the National VI standard 92# gasoline with the addition of gasoline modifier burns fully, which can clean up the carbon deposits produced by the original incomplete combustion, and no new carbon deposits will be produced, and the cylinder body will become smooth again.

[0080] (2) Energy saving (fuel saving)

[0081] Table 1 - Fuel consumption test results

[0082] It can be seen from the above table that the fuel-saving performance of cars using National VI Standard 92# gasoline with the addition of gasoline modifiers is significantly improved, and the more times it is used, the better the fuel-saving effect.

[0083] (3) Efficiency improvement

[0084] By comparison, it can be seen that the mileage of the same amount of conventional National VI standard 92# gasoline is shorter; while the mileage of the National VI standard 92# gasoline with the addition of gasoline modifiers continues to increase with the same amount of fuel.

[0085] (4) Emission reduction

[0086] According to the environmental protection requirements and automobile exhaust emission test standards, some vehicles that have used gasoline modifiers for a period of time were tested on the exhaust gas test line to test the emissions of carbon monoxide, hydrocarbons, and nitrogen oxides:

[0087] Table 2 shows the results of the tail gas emission test.

[0088] Pass the above vehicle use test: exhaust emissions are in accordance with the current vehicle annual inspection standards, and emissions are generally reduced by more than 90% compared to before use, except for a few old vehicles, and can fully meet the standards at the inspection station.

[0089] It can be seen from the above embodiments and test results that the present invention achieves the effects of increasing efficiency, saving fuel, removing carbon and reducing emissions by changing the physical properties of gasoline; greatly improves the quality of gasoline, improves the oil sensitivity, eliminates engine resonance, stabilizes kinetic energy output, and saves fuel consumption; and achieves full combustion of the fuel in the engine, thereby reducing automobile exhaust pollutant emissions.

[0090] The above test only shows the clean and environmentally friendly gasoline of Example 10, but it has been verified through experiments that the clean and environmentally friendly gasolines in other examples can all achieve similar effects.

[0091] The above description is only a preferred embodiment of the present invention and does not limit the present invention in any form. Those skilled in the art can make some simple modifications, equivalent changes or modifications based on the technical content disclosed above, which all fall within the scope of protection of the present invention.

Claims

1. A gasoline modifier, characterized in that: By volume, it includes 10-30 parts of 3# or 5# white oil, 5-50 parts of gasoline detergent and synergist, and 40-85 parts of isooctyl alcohol; The gasoline cleaning and enhancing agent includes an original liquid and a diluent liquid; The stock solution is a liquid substance formed by mixing 2-ethylhexyl phosphate and hydroxyethylidene diphosphonic acid in a weight ratio of 1.8-3:1, heating and performing an esterification reaction; and / or the stock solution includes 2-ethylhexanol, phosphite, 2-ethylhexyl acetate, polyisobutylene succinic anhydride and ethylhexyl phosphate; The dilution liquid is formed by mixing formaldehyde having a content of >99% and oligomeric water clusters in a weight ratio of 1:4-3:7; The weight percentage of the stock liquid to the gasoline detergent enhancer is 0.8%-1.3%, and the remainder is dilution liquid.

2. The gasoline modifier according to claim 1, characterized in that The 2-ethylhexyl phosphate is in liquid form, and its molecular formula is C24H54O8P2; the hydroxyethylidene diphosphonic acid is in dry powder form, and its molecular formula is C2H8O7P2.

3. The gasoline modifier according to claim 1 or 2, characterized in that: When the stock solution directly uses 2-ethylhexanol, phosphite, 2-ethylhexyl acetate, polyisobutylene succinic anhydride and ethylhexyl phosphate, the content of each component is the same as the content of each component in the liquid substance formed as follows: 2-ethylhexyl phosphate and hydroxyethylidene diphosphonic acid are mixed and heated in a weight ratio of 1.8-3:1 to form a liquid substance for esterification reaction.

4. A method for preparing a gasoline modifier according to any one of claims 1 to 3, characterized in that: include: 2-ethylhexyl phosphate and hydroxyethylidene diphosphonic acid are mixed and heated in a weight ratio of 1.8-3:1 to carry out an esterification reaction, and the liquid substance formed after the reaction is the stock solution; Formaldehyde having a content of >99% and oligomeric water clusters are mixed in a weight ratio of 1:4-3:7 to form a diluted liquid; The original liquid and the diluent are mixed and stirred, wherein the weight percentage of the original liquid is 0.8%-1.3%, and the obtained mixture is the gasoline detergent enhancer; The gasoline detergent enhancer is mixed evenly with 3# or 5# white oil and isooctyl alcohol in proportion to obtain the gasoline modifier.

5. The method for preparing a gasoline modifier according to claim 4, characterized in that: The esterification reaction of mixing 2-ethylhexyl phosphate and hydroxyethylidene diphosphonic acid in a weight ratio of 1.8-3:1 and heating the mixture comprises: 2-Ethylhexyl phosphate and hydroxyethylidene diphosphonic acid are placed in a glass reactor in a weight ratio of 1.8-3:1 and stirred evenly; the reaction starting temperature is 100°C, the final temperature is 220-230°C, the temperature is gradually increased in the middle, and the water evaporation process is repeated several times; after the reaction is completed, the reactor stops heating and naturally cools to room temperature, and the substance in the reactor is liquid, which is the original solution.

6. The method for preparing a gasoline modifier according to claim 5, characterized in that: The water evaporation process is repeated several times and comprises: First, the reaction temperature is adjusted to 100°C. During the reaction, the powder is continuously stirred and slowly dissolved to produce water. After a period of time, when no distilled water is produced and evaporated from the reactor, the reaction temperature is further increased to 110°C to evaporate the reaction water. The temperature is then increased in steps of 10°C to a final temperature of 220-230°C, and the water evaporation process is repeated.

7. An application of a gasoline modifier, characterized in that: The gasoline modifier is the gasoline modifier according to any one of claims 1 to 3; Or a gasoline modifier prepared by the method for preparing a gasoline modifier according to any one of claims 4 to 6; The gasoline modifier is a gasoline fuel-saving modifier, which is used to save gasoline; And / or, the gasoline modifier is a gasoline efficiency-enhancing modifier, which is used to improve engine combustion efficiency and enhance engine power; And / or, the gasoline modifier is a gasoline carbon removal modifier, which is used to remove carbon deposits generated by incomplete combustion inside the engine and no longer generate new carbon deposits; And / or, the gasoline modifier is a gasoline emission reduction modifier, which is used to reduce exhaust pollution.

8. A clean and environmentally friendly gasoline, characterized in that: A gasoline modifier comprising the gasoline modifier described in any one of claims 1 to 3; or the gasoline modifier described in any one of claims 4 to 6, which is a gasoline modifier prepared by the preparation method.

9. The clean and environmentally friendly gasoline according to claim 8 is characterized in that: Add 60-330ml of gasoline modifier to every 40-60L of gasoline.

10. The gasoline according to claim 8 or 9, characterized in that: The gasoline is 92# gasoline.

Citation Information

Patent Citations

  • Alcohol-based fuel

    CN102504889A

  • Synergistic emission reducing methanol fuel

    CN106367132A

  • Gasoline modifier, preparation method and application thereof, and clean environment-friendly gasoline containing gasoline modifier

    CN117487598A

  • High-activity green detergent as well as preparation method and application thereof

    CN117603742A

  • Phosphorylating thermal stability additive for distilled fuel

    CN1290737A

Cited By

  • Water-based polyol engine air intake synergistic liquid and preparation method thereof

    CN120484858A

  • Preparation method of gasoline blender

    CN120718692A