Stable pyrethroid agrochemical compositions

Abstract

The present invention provides a stable oil in water agrochemical composition of pyrethroid that is compatible with fertilizers, to the use of particle size reducing adjuvants for the stabilization of said oil in water agrochemical compositions, to a method of the preparation of the stable oil in water pyrethroid agrochemical compositions, and to a method for controlling insect pest by the aforementioned oil in water agrochemical compositions.

Description

[0001] STABLE PYRETHROID AGROCHEMICAL COMPOSITIONS

[0002] This application claims benefit of U. S. Provisional Application No. 63 / 715,571, filed November 3, 2024, the entire content of which is hereby incorporated by reference herein.

[0003] Throughout this application various publications are referenced. The disclosures of these documents in their entireties are hereby incorporated by reference into this application in order to more fully describe the state of the art to which this invention pertains.

[0004] FIELD OF INVENTION

[0005] The present invention relates to a stable oil in water agrochemical composition of pyrethroid that is compatible with fertilizers, to the use of particle size reducing adjuvants for the stabilization of said oil in water agrochemical compositions, to a method of the preparation of the stable oil in water pyrethroid agrochemical compositions, and to a method for controlling insect pest by the aforementioned oil in water agrochemical compositions.

[0006] BACKGROUND

[0007] Agrochemical formulations containing pesticides are found to be an effective way for treating crops fields against various types of pests by introducing the active ingredients in a measured and controlled manner as part of the formulated system. A good formulation system enables not only to evenly distribute the active ingredient on the target surface, but also to assure that it will remains stable over time, which will eventually lead to the desired protective effect.

[0008] There are several types of agrochemical formulations, commonly used in the field, wherein emulsion concentrate (EC) or water containing emulsions (EW) are used widely due to many advantages. Pesticides in the form of emulsifiable concentrates or soluble liquids in which the solid active ingredient is dissolved, are preferred by the user since they are easy to handle, measure and mix under field conditions. In addition, in most cases, the dissolved pesticides tend to show high efficacy on the field of application, however, the greatest disadvantage of said compositions containing dissolved pesticides is of being based on high content of an organic, mostly aromatic solvents, or other heavy organic solvent systems and thus unfavorable on toxicological and environmental grounds.

[0009] Synthetic pyrethroids insecticides pertain to the group of sodium channel modulator insecticides. This group was first introduced in the 1980's and exhibit a good efficacy together with low toxicity in comparison with the previously commonly used insecticides such as organophosphates and carbamates. Pyrethroids insecticides mainly divided into two arbitrary groups: liquid or low melting point pyrethroids and solid pyrethroids. tau-Fluvalinate, [cyano-(3-phenoxyphenyl) methyl] (2R)-2-[2-chloro-4-(trifluoromethyl) anilino]-3-methylbutanoate, is a liquid pyrethroid insecticide which represent the two diastereomers of (2R)-f luvalinate. Those diastereomers are characterized by possessing a valine-based C atom in its absolute R configuration, while the second chiral center can be either R or S.

[0010]

[0011] tau-Fluvalinate appears as a viscous liquid, and it is known to be soluble in certain organic solvents, and therefore water immiscible. This characteristic significantly limits the types of formulations which can be designed for it.

[0012] For example, AU2017903843 described an emulsifiable and / or dispersible concentrate formulation comprising the solid pyrethroid a / p a-cypermethrin, at a concentration of at least about 125 g / L, a surfactant in an amount of 40 g / L (alkoxylated oil, alkylbenzenesulphonate, etc.), and two or more solvents in an amount of 500-800 g / L (aromatic hydrocarbons, heavy aromatic solvents, N-methyl-pyrrolidone etc.).

[0013] AU2017903843 is limited to the solid pyrethroid a / p a-cypermethrin only, (melting point - 78-81 °C) and high amount of at least 50% per weight of heavy organic solvents. The use of high amounts of heavy organic solvents is unfavorable in terms of environmental and toxicological issues. In addition, AU2017903843 is silent about the stabilization of liquid or low melting point pyrethroids and particle size of the composition.

[0014] IN283140 described an agrochemical composition (EC, CG, WDG) comprising an insecticidal ly effective amount of at least one synthetic pyrethroid pesticide in an amount of from 2% to 25% (exemplified actives: cypermethrin, (EC), permethrin (EC, CG), fenvalerate (EC, Dust) and lambda cyhalothrin (WDG)), biodiesel waste solvent in an amount 4%-50% (which includes among others glycerin, methyl esters etc., and combination thereof), a surfactant (ethoxylated castor oil), one or more agrochemical adjuvant, optionally another organic solvent and a co-surfactant.

[0015] The concept of IN283140 relies on the reduction of the amount of the common organic solvent regularly utilized in formulated systems and / or replacement of the common organic solvent regularly utilized in formulated systems by a biodegradable solvent such as biodiesel waste solvent. Moreover, IN283140 exemplified few pyrethroids with mixed melting points (high and low), and did not include tau-Fluvalinate.

[0016] GB2481881 described a liquid formulation for controlling arthropod infestation, comprising i) suspended electret wax particles that have an eukaryote tissue adhering capability, with mean diameter of >10pm (the particles are selected from different waxes such as carnauba wax, beeswax, etc.) ii) at least one chemical agent with an activity against arthropods, encapsulated in the electret wax surface (including among others pyrethroids such as: tau-Fluvalinate and / ambc / a-cyhalothrin). GB2481881 further referred to a method of preparation of the said formulation. GB2481881 referred to a liquid formulation in which the active substance is fused inside a solid wax type matrixed particle. This type of formulation seems to suffer from lower efficacy comparing to liquid formulation since the trapped active substance is less available in terms of direct action. Moreover, it is most likely that those solid wax particles which stay in the field for an extended period of time, increase the risk of leakage of the active substance into the soil and the surrounding instead of being naturally degrade. The introduction of an agrochemical formulation into the field is in most cases implemented by tank-mixing the appropriate pesticide together with up to 6 or more additional products, such as micronutrients, fertilizers, adjuvants etc. This practice of tank-mixing is most favorable in terms of cost efficacy since fewer applications are required compared to single applications of each component separately. Nevertheless, in some cases the combination of a vast variety of materials may cause incompatibility issues, typically established as phase separation, agglomeration, and clogs formation within the tank-mix container. In such an unfortunate situation, the formation of an uneven mixture especially if repeated over time, will cause harsh economic consequences due to the need to discard the defective materials which can no longer be applied. In addition, there is also a need to take care of the damaged equipment caused by clogging formation, etc.

[0017] Boron fertilizers are considered as essential plant nutrients which are required for the development of plant cell wall and proper plant growth. The right balance of Boron in a plant is crucial, for preventing boron deficiency, and, at the same time, for avoiding Boron toxicity characterized by seedling toxicity and decreasing of crop yield.

[0018] Boron is found naturally in soils and in a variety of minerals such as kernite, ulexite, colemonite, and datolite. Even so, the availability of Boron to the plant through mineralbased sources is quite limited due to solubility matters. The main parameters which affect boron availability in soils are the type of the soil, and the amount of rainfall in the area. While boron deficiency tends to occur in sandy soils, acidic soils, and high-rainfall environments through significant Boron leaching loss, on the other hand, Boron toxicity appears in semi-arid areas.

[0019] There are several solutions in the field that try to overcome the instability and incompatibility arise when combining several types of components in a tank-mix.

[0020] US9908821 described an agrochemical spray which contains citric acid and glutamic acid as chelating agents for enhancing the compatibility and stability of pesticide compositions (glyphosate, 2,4-D, dicamba, bentazone and atrazine-based compositions) in the presence of fertilizers such as metal oxides (zinc oxide) and phosphate. In this case, the application demonstrates the addition of those two acids as chelating agents whose function is to prevent the possible precipitation of the metal ions. US9908821 is silent concerning the stabilization of tau-fluvalinate and demonstrate the stabilization of some agrochemical composition in the presence of zinc oxide solely.

[0021] W02014008472 described a seed, soil, or plant treatment composition comprising a mineral lactate compound (cobalt lactate); and a pesticide (glyphosate or trifloxystrobin and imidacloprid), an inorganic fertilizer (nitrogen, phosphorous, potassium fertilizers (NPK)), a biological fertilizer and combination thereof. The role of W02014008472 relays on the implementation of a mineral chelating substance (a mineral lactate), added in order to prevent the strong chelating tendency between the pesticide such as glyphosate and a micronutrients. By providing this additional lactate chelating agent the plants are able to absorb the available micronutrients more effectively. Although W02014008472 demonstrated a combined mixture of a pesticide, a micronutrient and a fertilizer, W02014008472 pursued to solve a particular problem derived from the association between a micronutrient and some pesticides, by the addition of a lactate moiety.

[0022] W02016109630 described an agricultural formulation comprising at least one insecticide selected from the group consisting of pyrethroid (bifenthrin) and a neonicotinoid (chlothianidin), and at least one polymeric dispersant (hydrophobically modified polyacrylate dispersant, polystyrene dispersant, polyvinyl pyrrolidone and methyl vinyl ether / maleic acid half ester dispersant) that allow crop grower to apply insecticides and fertilizers at the same time (Nitrogen, phosphorous, potassium and combination thereof). Nevertheless, W02016109630 is silent regarding tau-fluvalinate and Boron containing fertilizers.

[0023] Therefore, there is still a need in the field for the development of stabilized pyrethroids compositions, and boron compatible pyrethroids compositions, in particular tau-fluvalinate compositions. SUMMARY OF THE INVENTION

[0024] The present invention provides a stable oil in water pyrethroid agrochemical composition, comprising:

[0025] a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0026] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0027] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof;

[0028] e) optionally a droplet size reducing adjuvant; and

[0029] f) water;

[0030] wherein the drop size d90 of the oil phase is less than 2 μm.

[0031] The present invention provides a stable oil in water pyrethroid agrochemical composition, comprising:

[0032] a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0033] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0034] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; and

[0035] f) water;

[0036] wherein the drop size d90 of the oil phase is less than 2 μm.

[0037] The present invention provides a liquid fertilizer compatible pesticide composition comprising:

[0038] a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0039] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0040] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof;

[0041] e) optionally a droplet size reducing adjuvant; and

[0042] f) water;

[0043] wherein the drop size d90 of the oil phase is less than 2 μm.

[0044] The present invention is also directed to a liquid fertilizer compatible pesticide composition comprising:

[0045] a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0046] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof;

[0047] e) a droplet size reducing adjuvant; and

[0048] f) water;

[0049] wherein the drop size d90 of the oil phase is less than 2 μm.

[0050] The present invention provides a liquid fertilizer compatible pesticide composition comprising:

[0051] 1) a stable oil in water pyrethroid agrochemical composition, comprising:

[0052] a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition;

[0053] b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0054] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0055] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof;

[0056] e) optionally a droplet size reducing adjuvant; and

[0057] f) water;

[0058] wherein the drop size d90 of the oil phase is less than 2 pm; and

[0059] 2) a fertilizer. The present invention provides a liquid fertilizer compatible pesticide composition comprising:

[0060] 1) a stable oil in water pyrethroid agrochemical composition, comprising:

[0061] a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition;

[0062] b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0063] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0064] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof;

[0065] e) a droplet size reducing adjuvant; and

[0066] f) water;

[0067] wherein the drop size d90 of the oil phase is less than 2 pm; and

[0068] 2) a fertilizer.

[0069] This invention provides use of the droplet size reducing adjuvant e) for the stabilization of oil in water agrochemical compositions comprising pyrethroids.

[0070] This invention provides a method of the preparation of the stable oil in water pyrethroid agrochemical compositions, and a method for controlling insect pest using the aforementioned oil in water agrochemical compositions. DETAILED DESCRIPTION OF INVENTION

[0071] DEFINITIONS:

[0072] Prior to setting forth the present subject matter in detail, it may be helpful to provide definitions of certain terms to be used herein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as is commonly understood by one of skill in the art to which this subject matter pertains. The following definitions are provided for clarity.

[0073] The term "a" or "an" as used herein includes the singular and the plural, unless specifically stated otherwise. Therefore, the terms "a," "an," or "at least one" can be used interchangeably in this application.

[0074] As used herein, the verb "comprise" and the term "selected from" as is used in this description and in the claims and its conjugations are used in its non-limiting sense to mean that items following the word are included, but items not specifically mentioned are not excluded.

[0075] As used herein, the term "about" when used in connection with a numerical value includes ±10% from the indicated value. In addition, all ranges directed to the same component or property herein are inclusive of the endpoints, are independently combinable, and include all intermediate points and ranges. It is understood that where a parameter range is provided, all integers within that range, and tenths thereof, are also provided by the invention.

[0076] The term "oil in water agrochemical composition" as used herein referred to a stable emulsion of an agrochemical active ingredient(s) in an aqueous phase, intended for dilution with water before use. The active ingredient is normally a liquid and forms the dispersed oil phase, but it is also possible to emulsify a solid or liquid active ingredient dissolved in a water immiscible solvent.

[0077] The term "stable oil in water pyrethroid agrochemical composition" as used herein refers to the oil in water pyrethroid agrochemical composition that possess oil drops of the desired size (wherein the drop size d90 of the oil phase is less than 2μm), that is chemically and physically stable over time, in accordance with the required regulatory standards.

[0078] The term "liquid fertilizer compatible pesticide composition" as used herein refers to an oil in water pyrethroid agrochemical composition that is stable in the presence of a fertilizer. A non-limiting example of said compatible composition refers to a composition that is stable and\or compatible in the presence of a fertilizer such as Boron in an amount of 100 to 3000 gr Boron per hectare.

[0079] The term "boron compatibility" refers to an agrochemical composition that form homogenous dispersion in water and shows no lumps or gummy like material after dilution with water, when combined with fertilizers.

[0080] The term "fertilizer compatibility" refers to an agrochemical composition that form homogenous dispersion in water and shows no lumps or gummy like material after dilution with water, when combined with fertilizers.

[0081] As used herein, the term "effective amount" refers to an amount of the active ingredient that is commercially recommended for use to control and / or prevent pest. The commercially recommended amount for each active ingredient, often specified as application rates of the commercial formulation, may be found on the label accompanying the commercial formulation. The commercially recommended application rates of the commercial formulation may vary depending on factors such as the plant species and the pest to be controlled.

[0082] As used herein, the term "insecticide" broadly refers to compounds or compositions that are used as acaricides, insecticides, insecticide synergists, ixodicides, nematicides, and molluscicides. For chemical classes and applications, as well as specific compounds of each class, see "The Pesticide Manual Thirteenth Edition" (British Crop Protection Council, Hampshire, UK, 2003), as well as "The e-Pesticide Manual, Version 3" (British Crop Protection Council, Hampshire, UK, 2003-04), the contents of each of which are incorporated herein by reference in their entirety. As used herein the term "plant" or "crop" refers, but is not limited to whole plants, plant organs (e.g. leaves, stems, twigs, roots, trunks, limbs, shoots, fruits etc.), plant cells, or plant seeds. This term also encompasses plant crops such as fruits and vegetables. In some embodiments, the term "plant" may include the propagation material thereof, which may include all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers, which can be used for the multiplication of the plant. This includes seeds, tubers, spores, corms, bulbs, rhizomes, sprouts basal shoots, stolons, and buds and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil.

[0083] As used herein the term "plant propagation material" refers, but is not limited to, all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers, which can be used for the multiplication of the plant including tubers, spores, corms, bulbs, rhizomes, sprouts basal shoots, stolons, and buds and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil.

[0084] As used herein, the term "locus" refers, but is not limited to the place on which the plants are growing, the place on which the plant propagation materials of the plants are sown or the place on which the plant propagation materials of the plants will be sown including the areas under cultivation.

[0085] As used herein, the term "treating a plant or a locus against pest" includes, but is not limited to, protecting the plant or locus against pest and / or controlling pest of the plant or locus.

[0086] As used herein the term "pest" refer to any biological factor that can pose a risk or can cause to any minor, or major damage to a plant or plants in general and / or to agricultural crops in particular, which includes but not limited to insects, mites, fungi, weeds, or any combination thereof.

[0087] As used herein the term "ha" refers to hectare. As used herein the term "L\ha" refers to Liter per hectare.

[0088] As used herein the term "dose rate" refers to the amount of the stable oil in water pyrethroid agrochemical composition to be applied per square meter(s) or hectare of spray area.

[0089] As used herein, the term "mixture" or "combination" refers, but is not limited to, a combination in any physical form, e.g., blend, solution, suspension or the like.

[0090] As used herein, the term "composition" refers, but not limited to a composition of two or more components combined together. The term "composition also refers but not limited to solid composition, liquid compositions, formulations, including tank mix.

[0091] As used herein, the term "d90" refers, but not limited to the size of 90% of the oil droplets in the composition.

[0092] As used herein, the term "water immiscible solvent" refers, but not limited to any solvent that its solubility in water is limited to an extent that when observing its solely combination with water at room temperature it forms a phase separation.

[0093] As used herein, the term "droplet size reducing adjuvant" refers, but not limited to any acceptable additive that can help reducing the composition particle size by stabilizing and providing the appropriate energy for this process to occur.

[0094] As used herein, the term "vegetables oil" refers, but not limited to a vegetable oil that is not alkoxylated.

[0095] As used herein, the term "diluted composition" refers, but not limited to the mixture of the stable oil in water pyrethroid agrochemical composition with additional water which is not originally present in the preparation of the oil in water pyrethroid agrochemical composition.

[0096] Agrochemical Compositions: The present invention provides a stable oil in water pyrethroid agrochemical composition, comprising:

[0097] a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0098] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; and

[0099] f) water;

[0100] wherein the drop size d90 of the oil phase is less than 2 μm.

[0101] In some embodiment, the stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 40 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0102] In some embodiment, the stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 30 % to 40 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0103] In some embodiment, the stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 20 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0104] In some embodiment, the stable oil in water pyrethroid agrochemical composition comprises:

[0105] a) pyrethroid in an amount of from 20 % to 25 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0106] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; and

[0107] f) water;

[0108] wherein the drop size d90 of the oil phase is less than 2 μm.

[0109] In some embodiment, the stable oil in water pyrethroid agrochemical composition comprises:

[0110] a) pyrethroid in an amount of from 10 % to 20 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0111] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0112] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; and

[0113] f) water;

[0114] wherein the drop size d90 of the oil phase is less than 2 μm.

[0115] In some embodiment, the stable oil in water pyrethroid agrochemical composition comprises:

[0116] a) pyrethroid in an amount of from 10 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0117] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0118] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; and

[0119] f) water;

[0120] wherein the drop size d90 of the oil phase is less than 2 μm.

[0121] In some embodiment, the stable oil in water pyrethroid agrochemical composition comprises:

[0122] a) pyrethroid in an amount of from 1 % to 10 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0123] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0124] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; and

[0125] f) water;

[0126] wherein the drop size d90 of the oil phase is less than 2 μm. In some embodiment, the stable oil in water pyrethroid agrochemical composition comprises:

[0127] a) pyrethroid in an amount of from 1 % to 20 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0128] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0129] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; and

[0130] f) water;

[0131] wherein the drop size d90 of the oil phase is less than 2 μm.

[0132] In some embodiment, the stable oil in water pyrethroid agrochemical composition comprises:

[0133] a) pyrethroid in an amount of from 1 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0134] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0135] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; and

[0136] f) water;

[0137] wherein the drop size d90 of the oil phase is less than 2 μm.

[0138] In some embodiment, the stable oil in water pyrethroid agrochemical composition comprises:

[0139] a) pyrethroid in an amount of from 1 % to 40 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;

[0140] c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;

[0141] d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; and

[0142] f) water;

[0143] wherein the drop size d90 of the oil phase is less than 2 μm.

[0144] Suitable vegetables oils are selected from for example soybean oil, rape oil, sunflower oil, peanut oil, linseed oil, cottonseed oil, corn oil, castor oil, neem oil and olive oil. Suitable esters of vegetable oils are, for example, ethylhexyl palmitate, ethylhexyl oleate, ethylhexyl myristate, ethylhexyl caprylate, isopropyl myristate, isopropyl palmitate, methyl oleate, methyl palmitate, ethyl oleate, and methyl soyate.

[0145] Suitable aromatic hydrocarbons are selected from, for example, alkyl benzenes such as toluene, xylene, ethylbenzene, octadecylbenzene, dialkylbenzene, and trialkylbenzene, alkyl naphthalenes such as methylnaphthalene, dimethylnaphthalene, dodecylnaphthalene, and tridecylnaphthalene, and phenylxylylethane and 1-phenyl-l-ethylphenylethane, and the mixtures thereof.

[0146] Suitable C16-C18 fatty acid methyl esters are selected from for example methyl oleate, methyl palmitate, methyl linoleate, methyl stearate and the mixtures thereof.

[0147] Suitable poloxamers are selected from nonionic triblock copolymers composed of a central hydrophobic chain of polyoxypropylene (polyfpropylene oxide)) flanked by two hydrophilic chains of polyoxyethylene (polyfethylene oxide)), for example Synperonic™ PE 64 (Croda Europe LTD).

[0148] Suitable poloxamines (Tetronic ®) are X-shaped amphiphilic block copolymers formed by four arms of polyfethylene oxide)-poly(propylene oxide) (PEO-PPO) blocks bonded to a central ethylenediamine moiety.

[0149] Suitable vegetable oil alkoxylate may be a castor oil alkoxylate. The castor oil alkoxylate may be a castor oil ethoxylate, a castor oil propoxylate, a castor oil EO-PO block alkoxylate, a castor oil PO-EO block alkoxylate, or a castor oil which is randomly ethoxylated and propoxylated.

[0150] Suitable polyelectrolytes are selected from copolymers comprising (A) an anchoring moiety and (B) at least one stabilizing moiety.

[0151] In some embodiments, the polyelectrolyte copolymer comprises at least 90% of the anchoring moiety (A) consisting of acrylate derivatives, methacrylate derivatives, styrene derivatives, and any combination thereof.

[0152] In some embodiments, the polyelectrolyte copolymer comprises hydrophilic block copolymer as stabilizing moiety (B).

[0153] In some embodiments, the polyelectrolyte copolymer comprises a stabilizing moiety (B) containing of at least 60% by weight of charged anionic monomers. In some embodiment, the polyelectrolyte copolymer could be prepared according to the methods described in WO2017 / 098325.

[0154] In some embodiments, the polyelectrolyte copolymer is a block copolymer comprising 77% of sodium 2-acryloylamido-2-methylpropane-1-sulfonate (AMPS) monomers and 23% of the ethyl acrylate (EA) monomers.

[0155] In some embodiments, the polyelectrolyte copolymer is a water solution of 30% w / w solution of a block copolymer comprising 77% of sodium 2-acryloylamido-2-methylpropane-1-sulfonate (AMPS) monomers and 23% of ethyl acrylate (EA) monomers, which may be prepared as described in Example 1 of WO2017 / 098325.

[0156] In some embodiments, the polyelectrolyte copolymer is PolyAgro A, which is a di-block copolymer, with a total weight of 17000 g / mol, composed of a hydrophobic block (Anchor block- ANCHOR) and a hydrophilic block (Stabilizing block - STAB). The stabilizing, hydrophilic, block is made of sodium 2-Acryloylamino-2-methylpropane-1-sulfonate (AMPS) monomers, which are 77% of the overall monomers in the polymer. The other 23% of the monomers belongs to the anchor, hydrophobic, block which is made of ethyl acrylate monomers. The total amount of monomers in the polymer (degree of polymerization, DPn) is 85 monomers.

[0157] The polyelectrolyte block copolymer PolyAgro A may be obtained according to the following procedure:

[0158] a) Step 1:

[0159] Into a 2L double jacketed reactor equipped with mechanical agitator and reflux condenser was added 11.26 g of O-ethyl-S-(1-methoxycarbonylethyl)xanthate (CH3CH(CO2CH3))S(C=S)OEt), 264.08g of Ethanol, and 356.32g of De-ionized water and 1400g of AMPS(Na) solution (50% active) and 1.52g of 4,4'-Azobis(4-cyanopentanoic acid). The reactor contents were heated to 70°C under agitation and nitrogen. The reaction mixture was aged at 70°C for a further hour whereupon it was cooled to ambient temperature and discharged. The measured solids content was 37.6% (115°C, 60 mins). GPC Mals : Mn=16300 Mw=2600 IP=1.6.

[0160] b) Step 2:

[0161] Into a 5L double jacketed reactor equipped with mechanical agitator and reflux condenser was added 2127g of solution prepared in Step 1 and 330g of de-ionized water. The reactor contents were heated to 70°C under agitation and a nitrogen stream. Once 70°C was reached, 106.67g of ethyl acrylate ( E A) was added over 2 hours and a 37.37g of a solution of 10 wt% of 4,4'-Azobis(4-cyanopentanoic acid) was concomitantly added over 2 hours. After the end of the introduction of the initiator solution, the reaction solution was further aged for one hour. Thereafter a shot of 44.85g of a 10 wt% solution of 4,4'-Azobis(4-cyanopentanoic acid) was added and the mixture aged at 70°C for a further hour whereupon it was cooled to ambient temperature and discharged. The measured solids content was 40.0% (115°C, 60 mins). Then ethanol was removed from the polymer solution using a rotary evaporator. Water was back added to achieve a polymer solution with a final solids content of 40.4%.

[0162] 2600g of polymer solution was placed in a 5L double jacketed reactor equipped with mechanical agitator and reflux condenser. The pH of the solution was increased to 8,5 using a 50% solution of NaOH. The mixture was heated to 70°C with stirring whereupon 48.4 of a 30% solution of hydrogen peroxide was added in 1 hour. At the end of the additions, the solution was aged for a further 3h00 whereupon it was cooled and discharged. The residuals monomers were measure by HPLC and GC (AMPS - 22ppm, EA - 2ppm). The measured solids content was 37.5%. The polymer is used in the composition of the present invention as a ready aqua polymer solution at concentration of about 30%w / w.

[0163] Suitable arylsulphonates are selected from aryl sulfonates, alkyl aryl sulfonates, lignosulfonates, naphthalene sulfonates, alkylnathalene sulfonates, benzylsulfonates, alkylbenzene sulfonates and the mixtures thereof. In an embodiment, the sulfonate surfactants include, but are not limited to alkyl naphthalene formaldehyde condensate sulfonate of the formula:

[0164]

[0165] wherein

[0166] R is independently hydrogen, a C1-15 straight or branched chain alkyl or alkenyl group; X is independently hydrogen, an alkali metal, an alkaline earth metal, ammonium, a mono-, di-, or tri- C1-4 alkyl ammonium, or a mono-, di-or tri-C1-4 hydroxyalkyl ammonium moiety. n is from 1 to 25.

[0167] R groups can be present in any position on the naphthalene nucleus.

[0168] Suitable examples of naphthalene sulfonate condensates may include Morwet D-425, Morwet D-500, Morwet D-809 available from NOURYON, Tersperse 2020 available from Indroma and Surfom WG 8168 available from Oxiteno.

[0169] Suitable droplet size reducing adjuvants are selected from the group consisting of AltaHance ™ S, AltaHance ™ 2S, AltaHance ™ 3S, Altastick ™ R, Altastick ™ HG and the mixtures thereof.

[0170] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0171] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 40 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0172] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 30 % to 40 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0173] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 20 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0174] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 20 % to 25 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0175] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 10 % to 20 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0176] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 10 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0177] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 1 % to 10 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0178] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 1 % to 20 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0179] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 1 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0180] In some embodiments, the stable oil in water pyrethroid agrochemical composition comprises: a) pyrethroid in an amount of from 1 % to 40 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0181] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm. In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 40 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0182] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 30 % to 40 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0183] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 20 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0184] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 20 % to 25 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0185] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 10 % to 20 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0186] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 10 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0187] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 1 % to 10 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0188] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 1 % to 20 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0189] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 1 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0190] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 1 % to 40 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0191] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0192] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 40 % to 50 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0193] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 30 % to 40 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0194] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 20 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm. In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 20 % to 25 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0195] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 10 % to 20 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0196] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 10 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0197] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 1% to 10% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0198] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 1% to 20% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0199] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 1 % to 30 % per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0200] In some embodiments, the liquid fertilizer compatible pesticide composition comprises: a) pyrethroid in an amount of from 1% to 40% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm.

[0201] In some embodiments the stable oil in water pyrethroid agrochemical composition as described herein is fertilizer compatible.

[0202] In some embodiments the stable oil in water pyrethroid agrochemical composition as described herein is boron compatible.

[0203] Fertilizers suitable for the purpose of the present invention are selected from but not limited to: nitrate-based fertilizers such as ammonium nitrate (AN) and calcium ammonium nitrate (CAN), urea and urea ammonium nitrate (UAN) aqueous solution, ammonium sulphate and ammonium sulphate nitrate, calcium nitrate, sodium nitrate, Chilean nitrate and anhydrous ammonia; nitric acid; phosphate fertilizers such as single, phosphoric acid, superphosphate (SSP), triple superphosphate (TSP), monoammonium phosphate (MAP), di-ammonium phosphate (DSP) and ammonium polyphosphate liquid; potassium fertilizers such as potassium chloride (KCI), potassium sulphate (K2SO4) or sulphate of potash (SOP), potassium nitrate (KNO3; micronutrient fertilizers such as sulphates, oxysulphates, magnesium sulfate, sulfuric acid, oxides, chelates of boron (B), chloride (Cl), copper (Cu), iron (Fe), manganese (Mn), molybdenum (Mo), nickel (Ni) and zinc (Zn).

[0204] The present invention is also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 50% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0205] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 40% to 50% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0206] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 30% to 40% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0207] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 20% to 30% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0208] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 20% to 25% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0209] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 10% to 20% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 pm; 2) a fertilizer.

[0210] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 10% to 30% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0211] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 10% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 pm; 2) a fertilizer.

[0212] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 20% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 pm; 2) a fertilizer.

[0213] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 30% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0214] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 40% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) optionally a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0215] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 50% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0216] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 40% to 50% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0217] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 30% to 40% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0218] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 20% to 30% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0219] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 20% to 25% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0220] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 10% to 20% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0221] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 30% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0222] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 10% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 pm; 2) a fertilizer.

[0223] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 20% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 pm; 2) a fertilizer.

[0224] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 30% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0225] The present invention also provides a liquid fertilizer compatible pesticide composition comprising: 1) a stable oil in water pyrethroid agrochemical composition, comprising: a) pyrethroid in an amount of from 1% to 40% per weight of total composition; b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons; d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof; e) a droplet size reducing adjuvant; f) water; wherein the drop size d90 of the oil phase is less than 2 μm; 2) a fertilizer.

[0226] In certain embodiments the fertilizer comprises from 100 to 3000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 2000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 1000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 1500 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 900 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 800 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 700 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 600 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 500 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 450 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 200 to 450 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 250 to 450 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 200 to 500 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 300 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 250 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 200 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 150 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 200 to 3000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 300 to 3000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 400 to 3000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 450 to 3000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 500 to 3000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 600 to 3000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 700 to 3000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 800 to 3000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 900 to 3000 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 1000 to 3000gr of Boron per hectare.

[0227] In certain embodiments the fertilizer comprises from 1500 to 3000 gr of Boron per hectare.

[0228] In certain embodiments the fertilizer comprises from 2000 to 3000 gr of Boron per hectare.

[0229] In certain embodiments the fertilizer comprises from 150 to 2500 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 200 to 2000 gr of Boron per hectare, leanIn certain embodiments the fertilizer comprises from 250 to 1500 gr of Boron per hectare.

[0230] In certain embodiments the fertilizer comprises from 350 to 900 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 400 to 800 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 500 to 700 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 500 to 600 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 100 to 450 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 200 to 450 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 300 to 450 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 200 to 400 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 200 to 350 gr of Boron per hectare. In certain embodiments the fertilizer comprises from 200 to 300 gr of Boron per hectare. In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0231] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 2000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0232] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 1000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0233] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 1500 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0234] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 900 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0235] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 800 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0236] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 700 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0237] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 600 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0238] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 500 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0239] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 450 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus. In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 400 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0240] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 300 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0241] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 250 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0242] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 200 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0243] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 150 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0244] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 200 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0245] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 300 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0246] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 400 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0247] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 450 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0248] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 500 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0249] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 600 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0250] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 700 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0251] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 800 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus. In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 900 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0252] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 1000 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0253] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 1500 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0254] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 2000 to 3000 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0255] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 150 to 2500 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0256] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 200 to 2500 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0257] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 350 to 900 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0258] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 400 to 800 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0259] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 500 to 700 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0260] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 500 to 600 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0261] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 100 to 450 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0262] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 200 to 450 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0263] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 300 to 450 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus. In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 200 to 400 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0264] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 200 to 350 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0265] In certain embodiments, a liquid product comprising an agriculturally acceptable mixture of a fertilizer compatible pesticidal composition, and fertilizer containing from 200 to 300 gr of Boron per hectare can be applied simultaneously, separately, or sequentially for control of pests at a locus.

[0266] In certain embodiment, the boron component is selected from but not limited to the group consisting of sodium borate, borax, kernite, disodium octaborate tetrahydrate, sodium tetraborate, anhydrous sodium tetraborate, boric acid, sodium polyborate, calcium borate, sodium-calcium borate, calcium-magnesium borate, colemanite, hydroboracite, ulexite, borosilicates, datolite, howlite, feritted B-silicate, Boron-ethanolamine. As a non-limiting examples of commercially available products, the following boron containing fertilizers and the mixtures thereof can be used: Solubor®, Brassitrel PRO™, Lebosol® Bor, Raps PRO™, Fertileader® Gold, BORONIA LS™, BORONIA Mo™, BORONIA SMO™, BOROZINC™, CHELONIA® B, COLZAFOL® VR, BM® START, BOLERO®.

[0267] In certain embodiment, the boron containing fertilizers are selected from but not limited to: Solubor®, Brassitrel PRO™, Lebosol® Bor, Raps PRO™, Fertileader® Gold, BORONIA LS™, BORONIA Mo™, BORONIA SMO™, BOROZINC™, CHELONIA® B, COLZAFOL® VR, BM® START, BOLERO® or any combination thereof.

[0268] In certain embodiment, the boron containing fertilizers are selected from but not limited to the group consisting of: sodium borate, borax, kernite, disodium octaborate tetrahydrate, sodium tetraborate, anhydrous sodium tetraborate, boric acid, sodium polyborate, calcium borate, sodium-calcium borate, calcium-magnesium borate, colemanite, hydroboracite, ulexite, borosilicates, datolite, howlite, feritted B-silicate, Boron-ethanolamine, or any combination thereof.

[0269] In certain embodiment, the boron containing fertilizer is Solubor®.

[0270] In certain embodiment, the boron containing fertilizer is Brassitrel PRO™.

[0271] In certain embodiment, the boron component is Lebosol® Bor.

[0272] In certain embodiment, the boron component is Raps PRO™.

[0273] In certain embodiment, the boron component is Fertileader® Gold.

[0274] In certain embodiment, the boron component is BORONIA LS™.

[0275] In certain embodiment, the boron component is BORONIA Mo™.

[0276] In certain embodiment, the boron component is BORONIA SMO™.

[0277] In certain embodiment, the boron component is BOROZINC™.

[0278] In certain embodiment, the boron component is CHELONIA® B

[0279] In certain embodiment, the boron component is COLZAFOL® VR.

[0280] In certain embodiment, the boron component is BM® START.

[0281] In certain embodiment, the boron component is BOLERO®.

[0282] In certain embodiment, the pyrethroid a) is selected from the group consisting of tau-fluvalinate, lambda-cyhalothrin, bifenthrin and the mixtures thereof.

[0283] In another embodiment, the pyrethroid a) is tau-fluvalinate and lambda-cyhalothrin. In another embodiment, the pyrethroid a) is tau-fluvalinate and bifenthrin.

[0284] In another embodiment, the pyrethroid a) is lambda-cyhalothrin and bifenthrin.

[0285] In another embodiment, the pyrethroid a) is tau-fluvalinate.

[0286] In another embodiment, the pyrethroid a) is lambda-cyhalothrin.

[0287] In another embodiment, the pyrethroid a) is bifenthrin.

[0288] In some embodiment, the amount of water-immiscible solvent b) is from 0.1 % to 50 % per weight, based on the weight of total composition.

[0289] In some embodiment, the amount of water-immiscible solvent b) is from 40 % to 50 % per weight, based on the weight of total composition. In some embodiment, the amount of water-immiscible solvent b) is from 45 % to 50 % per weight, based on the weight of total composition.

[0290] In some embodiment, the amount of water-immiscible solvent b) is from 35 % to 40 % per weight, based on the weight of total composition.

[0291] In some embodiment, the amount of water-immiscible solvent b) is from 30 % to 40 % per weight, based on the weight of total composition.

[0292] In some embodiment, the amount of water-immiscible solvent b) is from 20 % to 30 % per weight, based on the weight of total composition.

[0293] In some embodiment, the amount of water-immiscible solvent b) is from 25 % to 30 % per weight, based on the weight of total composition.

[0294] In some embodiment, the amount of water-immiscible solvent b) is from 10 % to 20 % per weight, based on the weight of total composition.

[0295] In some embodiment, the amount of water-immiscible solvent b) is from 15 % to 20 % per weight, based on the weight of total composition.

[0296] In some embodiment, the amount of water-immiscible solvent b) is from 0.1 % to 10 % per weight, based on the weight of total composition.

[0297] In some embodiment, the amount of water-immiscible solvent b) is from 0.1 % to 3 % per weight, based on the weight of total composition.

[0298] In some embodiment, the amount of water-immiscible solvent b) is from 0.1 % to 5 % per weight, based on the weight of total composition.

[0299] In some embodiment, the amount of water-immiscible solvent b) is from 0.1 % to 7 % per weight, based on the weight of total composition.

[0300] In some embodiment, the amount of water-immiscible solvent b) is from 0.1 % to 10 % per weight, based on the weight of total composition.

[0301] In some embodiment, the amount of water-immiscible solvent b) is from 0.1 % to 15 % per weight, based on the weight of total composition.

[0302] In some embodiment, the amount of water-immiscible solvent b) is from 5 % to 7 % per weight, based on the weight of total composition. In some embodiment, the amount of water-immiscible solvent b) is from 7 % to 10 % per weight, based on the weight of total composition.

[0303] In an embodiment, the amount of surfactant (A) is from 0.1 % to 10 % per weight, based on the weight of total composition.

[0304] In an embodiment, the amount of surfactant (A) is from 9 % to 10 % per weight, based on the weight of total composition.

[0305] In an embodiment, the amount of surfactant (A) is from 8 % to 9 % per weight, based on the weight of total composition.

[0306] In an embodiment, the amount of surfactant (A) is from 7 % to 8 % per weight, based on the weight of total composition.

[0307] In an embodiment, the amount of surfactant (A) is from 6 % to 7 % per weight, based on the weight of total composition.

[0308] In an embodiment, the amount of surfactant (A) is from 5 % to 6 % per weight, based on the weight of total composition.

[0309] In an embodiment, the amount of surfactant (A) is from 4 % to 5 % per weight, based on the weight of total composition.

[0310] In an embodiment, the amount of surfactant (A) is from 3 % to 4 % per weight, based on the weight of total composition.

[0311] In an embodiment, the amount of surfactant (A) is from 2 % to 3 % per weight, based on the weight of total composition.

[0312] In an embodiment, the amount of surfactant (A) is from 1 % to 2 % per weight, based on the weight of total composition.

[0313] In an embodiment, the amount of surfactant (A) is from 0.1 % to 1 % per weight, based on the weight of total composition.

[0314] In an embodiment, the amount of surfactant (A) is from 0.1 % to 2 % per weight, based on the weight of total composition.

[0315] In an embodiment, the amount of surfactant (A) is from 0.1 % to 2.5 % per weight, based on the weight of total composition. In an embodiment, the amount of surfactant (A) is from 2 % to 7 % per weight, based on the weight of total composition.

[0316] In an embodiment, the amount of surfactant (A) is from 2 % to 5 % per weight, based on the weight of total composition.

[0317] In an embodiment, the amount of surfactant (A) is from 2 % to 4 % per weight, based on the weight of total composition.

[0318] In an embodiment, the amount of surfactant (B) is from 0.1 % to 10 % per weight, based on the weight of total composition.

[0319] In an embodiment, the amount of surfactant (B) is from 9 % to 10 % per weight, based on the weight of total composition.

[0320] In an embodiment, the amount of surfactant (B) is from 8 % to 9 % per weight, based on the weight of total composition.

[0321] In an embodiment, the amount of surfactant (B) is from 7 % to 8 % per weight, based on the weight of total composition.

[0322] In an embodiment, the amount of surfactant (B) is from 6 % to 7 % per weight, based on the weight of total composition.

[0323] In an embodiment, the amount of surfactant (B) is from 5 % to 6 % per weight, based on the weight of total composition.

[0324] In an embodiment, the amount of surfactant (B) is from 4 % to 5 % per weight, based on the weight of total composition.

[0325] In an embodiment, the amount of surfactant (B) is from 3 % to 4 % per weight, based on the weight of total composition.

[0326] In an embodiment, the amount of surfactant (B) is from 2 % to 3 % per weight, based on the weight of total composition.

[0327] In an embodiment, the amount of surfactant (B) is from 1 % to 2 % per weight, based on the weight of total composition.

[0328] In an embodiment, the amount of surfactant (B) is from 0.1 % to 1 % per weight, based on the weight of total composition. In an embodiment, the amount of surfactant (B) is from 0.1 % to 2 % per weight, based on the weight of total composition.

[0329] In an embodiment, the amount of surfactant (B) is from 0.1 % to 2.5 % per weight, based on the weight of total composition.

[0330] In an embodiment, the amount of surfactant (B) is from 2 % to 7 % per weight, based on the weight of total composition.

[0331] In an embodiment, the amount of surfactant (B) is from 2 % to 5 % per weight, based on the weight of total composition.

[0332] In an embodiment, the amount of surfactant (B) is from 2 % to 4 % per weight, based on the weight of total composition.

[0333] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 1% to 20 % per weight, based on the weight of total composition.

[0334] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 15 % to 20 % per weight, based on the weight of total composition.

[0335] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 5 % to 10 % per weight, based on the weight of total composition.

[0336] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 5 % to 15 % per weight, based on the weight of total composition.

[0337] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 5 % to 20 % per weight, based on the weight of total composition.

[0338] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 10 % to 15 % per weight, based on the weight of total composition.

[0339] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 1 % to 5 % per weight, based on the weight of total composition.

[0340] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 1 % to 4 % per weight, based on the weight of total composition.

[0341] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 1 % to 3 % per weight, based on the weight of total composition. In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 1 % to 2 % per weight, based on the weight of total composition.

[0342] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 1 % to 15 % per weight, based on the weight of total composition.

[0343] In certain embodiment, the amount of the droplet size reducing adjuvant e) is from 7 % to 15 % per weight, based on the weight of total composition.

[0344] In an embodiment the droplet size reduction adjuvant e) is selected from the group consisting of AltaHance ™ S, AltaHance™ 2S, AltaHance™ 3S, Altastick™ R, Altastick™ HG and the mixtures thereof.

[0345] In an embodiment the droplet size reduction adjuvant e) is selected from the group consisting of AltaHance ™ S, AltaHance™ 2S, AltaHance™ 3S, and the mixtures thereof. In an embodiment the droplet size reduction adjuvant e) is selected from the group consisting of AltaHance ™ S, AltaHance™ 2S, and the mixtures thereof.

[0346] In an embodiment the droplet size reduction adjuvant e) is selected from the group consisting of AltaHance ™ S, AltaHance™ 3S, and the mixtures thereof.

[0347] In an embodiment the droplet size reduction adjuvant e) is selected from the group consisting of AltaHance™ 2S, AltaHance™ 3S, and the mixtures thereof.

[0348] In an embodiment the droplet size reduction adjuvant e) is selected from the group consisting of Altastick™ R, Altastick ™ HG and the mixtures thereof.

[0349] In an embodiment the droplet size reduction adjuvant e) is AltaHance ™ S.

[0350] In an embodiment the droplet size reduction adjuvant e) is AltaHance™ 2S.

[0351] In an embodiment the droplet size reduction adjuvant e) is AltaHance™ 3S.

[0352] In an embodiment the droplet size reduction adjuvant e) is Altastick™ R.

[0353] In an embodiment the droplet size reduction adjuvant e) is Altastick ™ HG.

[0354] In some embodiment, the present invention provides the use of the droplet size reducing adjuvant e) for the stabilization of oil in water agrochemical compositions comprising pyrethroids a). In some embodiment, the present invention provides the use of the droplet size reducing adjuvant e) for the stabilization of oil in water agrochemical compositions comprising tau-fluvalinate (a).

[0355] In some embodiment, the present invention provides the use of the droplet size reducing adjuvant e) for the stabilization of oil in water agrochemical compositions comprising lambda-cyhalothrin (a).

[0356] In some embodiment, the present invention provides the use of the droplet size reducing adjuvant e) for the stabilization of oil in water agrochemical compositions comprising bifenthrin (a).

[0357] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:150 to 500:1.

[0358] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:125 to 500:1.

[0359] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:100 to 500:1.

[0360] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:75 to 500:1.

[0361] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:50 to 500:1.

[0362] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:40 to 500:1.

[0363] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:30 to 500:1.

[0364] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:25 to 500:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:15 to 500:1.

[0365] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:10 to 500:1.

[0366] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:5 to 500:1.

[0367] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:2 to 500:1.

[0368] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 3:4 to 500:1.

[0369] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:1 to 500:1.

[0370] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 400:1 to 500:1.

[0371] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 300:1 to 500:1.

[0372] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 200:1 to 500:1.

[0373] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 100:1 to 500:1.

[0374] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 50:1 to 500:1.

[0375] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 25:1 to 500:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 10:1 to 500:1.

[0376] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:1 to 500:1.

[0377] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:150 to 250:1

[0378] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:125 to 250:1.

[0379] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:100 to 250:1.

[0380] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:75 to 250:1.

[0381] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:50 to 250:1.

[0382] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:40 to 250:1.

[0383] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:30 to 250:1.

[0384] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:25 to 250:1.

[0385] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:15 to 250:1.

[0386] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:10 to 250:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:5 to 250:1.

[0387] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:4 to 250:1.

[0388] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:3 to 250:1.

[0389] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:2 to 250:1.

[0390] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 3:4 to 250:1.

[0391] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:1 to 250:1.

[0392] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:150 to 125:1.

[0393] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:125 to 125:1.

[0394] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:100 to 125:1.

[0395] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:75 to 125:1.

[0396] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:50 to 125:1.

[0397] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:40 to 125:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:30 to 125:1.

[0398] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:25 to 125:1.

[0399] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:15 to 125:1.

[0400] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:10 to 125:1.

[0401] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:5 to 125:1.

[0402] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:2 to 125:1.

[0403] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 3:4 to 125:1.

[0404] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:1 to 125:1.

[0405] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 10:1 to 125:1.

[0406] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 25:1 to 125:1.

[0407] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 50:1 to 125:1.

[0408] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 75:1 to 125:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 100:1 to 125:1.

[0409] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:150 to 75:1.

[0410] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:125 to 75:1.

[0411] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:100 to 75:1.

[0412] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:75 to 75:1.

[0413] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1: 50 to 75:1.

[0414] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:40 to 75:1.

[0415] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:30 to 75:1.

[0416] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:25 to 75:1.

[0417] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:15 to 75:1.

[0418] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:10 to 75:1.

[0419] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:5 to 75:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:2 to 75:1.

[0420] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 3:4 to 75:1.

[0421] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:1 to 75:1.

[0422] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 10:1 to 75:1.

[0423] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 25:1 to 75:1.

[0424] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 50:1 to 75:1.

[0425] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:150 to 50:1.

[0426] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:125 to 50:1.

[0427] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:100 to 50:1.

[0428] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:75 to 50:1.

[0429] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:50 to 50:1.

[0430] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:25 to 50:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:40 to 50:1.

[0431] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:30 to 50:1.

[0432] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:25 to 50:1.

[0433] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:15 to 50:1.

[0434] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:10 to 50:1.

[0435] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:5 to 50:1.

[0436] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:2 to 50:1.

[0437] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 3:4 to 50:1.

[0438] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:1 to 50:1.

[0439] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 40:1 to 50:1.

[0440] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 30:1 to 50:1.

[0441] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 25:1 to 50:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 10:1 to 50:1.

[0442] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:150 to 25:1.

[0443] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:125 to 25:1.

[0444] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:100 to 25:1.

[0445] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:75 to 25:1.

[0446] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:50 to 25:1.

[0447] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:40 to 25:1.

[0448] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:30 to 25:1.

[0449] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:25 to 25:1.

[0450] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:10 to 25:1.

[0451] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:5 to 25:1.

[0452] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:2 to 25:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 3:4 to 25:1.

[0453] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:1 to 25:1.

[0454] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 5:1 to 25:1.

[0455] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 10:1 to 25:1.

[0456] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 15:1 to 25:1.

[0457] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 20:1 to 25:1.

[0458] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:150 to 10:1.

[0459] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:125 to 10:1.

[0460] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:100 to 10:1.

[0461] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:75 to 10:1.

[0462] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:50 to 10:1.

[0463] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:40 to 10:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:30 to 10:1.

[0464] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:25 to 10:1.

[0465] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:10 to 10:1.

[0466] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:5 to 10:1.

[0467] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:2 to 10:1.

[0468] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 3:4 to 10:1.

[0469] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:1 to 10:1.

[0470] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 5:1 to 10:1.

[0471] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:150 to 5:1.

[0472] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:125 to 5:1.

[0473] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:100 to 5:1.

[0474] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:75 to 5:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:50 to 5:1.

[0475] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:40 to 5:1.

[0476] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:30 to 5:1.

[0477] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:25 to 5:1.

[0478] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:10 to 5:1.

[0479] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:5 to 5:1.

[0480] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:2 to 5:1.

[0481] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 3:4 to 5:1.

[0482] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:1 to 5:1.

[0483] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 2:1 to 5:1.

[0484] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 3:1 to 5:1.

[0485] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 4:1 to 5:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:150 to 1:1.

[0486] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:125 to 1:1.

[0487] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:100 to 1:1.

[0488] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:75 to 1:1.

[0489] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:50 to 1:1.

[0490] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:40 to 1:1.

[0491] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:30 to 1:1.

[0492] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:25 to 1:1.

[0493] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:10 to 1:1.

[0494] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:5 to 1:1.

[0495] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:2 to 1:1.

[0496] In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 3:4 to 1:1. In certain embodiment, the weight ratio between the pyrethroid a) and the water immiscible solvent b) is 1:1.

[0497] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:10 to 500:1.

[0498] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:5 to 500:1.

[0499] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:2 to 500:1.

[0500] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:1 to 500:1.

[0501] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 5:1 to 500:1.

[0502] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 7:1 to 500:1.

[0503] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 8:1 to 500:1.

[0504] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 10:1 to 500:1.

[0505] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 100:1 to 500:1.

[0506] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 50:1 to 500:1.

[0507] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 200:1 to 500:1.

[0508] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 250:1 to 500:1.

[0509] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 400:1 to 500:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:10 to 400:1.

[0510] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:5 to 400:1.

[0511] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:2 to 400:1.

[0512] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:1 to 400:1.

[0513] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 5:1 to 400:1.

[0514] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 7:1 to 400:1.

[0515] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 8:1 to 400:1.

[0516] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 10:1 to 400:1.

[0517] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 50:1 to 400:1.

[0518] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 100:1 to 400:1.

[0519] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 200:1 to 400:1.

[0520] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 250:1 to 400:1.

[0521] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 300:1 to 400:1.

[0522] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is 400:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:10 to 250:1.

[0523] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:5 to 250:1.

[0524] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:2 to 250:1.

[0525] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:1 to 250:1.

[0526] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 2:1 to 250:1.

[0527] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 5:1 to 250:1.

[0528] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 7:1 to 250:1.

[0529] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 8:1 to 250:1.

[0530] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 10:1 to 250:1.

[0531] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 25:1 to 250:1.

[0532] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 50:1 to 250:1.

[0533] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 75:1 to 250:1.

[0534] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 100:1 to 250:1.

[0535] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is 250:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:10 to 100:1.

[0536] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:5 to 100:1.

[0537] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:2 to 100:1.

[0538] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:1 to 100:1.

[0539] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 5:1 to 100:1.

[0540] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 7:1 to 100:1.

[0541] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 8:1 to 100:1.

[0542] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 10:1 to 100:1.

[0543] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 25:1 to 100:1.

[0544] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 50:1 to 100:1.

[0545] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 75:1 to 100:1.

[0546] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is 100:1.

[0547] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:10 to 50:1.

[0548] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:5 to 50:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:2 to 50:1.

[0549] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:1 to 50:1.

[0550] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 2:1 to 50:1.

[0551] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 5:1 to 50:1.

[0552] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 7:1 to 50:1.

[0553] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 8:1 to 50:1.

[0554] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 10:1 to 50:1.

[0555] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 15:1 to 50:1.

[0556] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 25:1 to 50:1.

[0557] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is 50:1.

[0558] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:10 to 25:1.

[0559] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:5 to 25:1.

[0560] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:2 to 25:1.

[0561] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:1 to 25:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 5:1 to 25:1.

[0562] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 7:1 to 25:1.

[0563] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 8:1 to 25:1.

[0564] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 10:1 to 25:1.

[0565] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 15:1 to 25:1.

[0566] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 20:1 to 25:1.

[0567] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is 25:1.

[0568] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:10 to 10:1.

[0569] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:5 to 10:1.

[0570] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:2 to 10:1.

[0571] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:1 to 10:1.

[0572] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 2:1 to 10:1.

[0573] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 5:1 to 10:1.

[0574] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 7:1 to 10:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 8:1 to 10:1.

[0575] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is from 9:1 to 10:1.

[0576] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is 8:1.

[0577] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (A) is 10:1.

[0578] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:10 to 500:1.

[0579] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:5 to 500:1.

[0580] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:2 to 500:1.

[0581] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:1 to 500:1.

[0582] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 5:1 to 500:1.

[0583] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 7:1 to 500:1.

[0584] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 8:1 to 500:1.

[0585] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 10:1 to 500:1.

[0586] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 25:1 to 500:1.

[0587] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 50:1 to 500:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 75:1 to 500:1.

[0588] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 100:1 to 500:1.

[0589] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 200:1 to 500:1.

[0590] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 300:1 to 500:1.

[0591] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 400:1 to 500:1.

[0592] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:10 to 400:1.

[0593] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:5 to 400:1.

[0594] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:2 to 400:1.

[0595] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:1 to 400:1.

[0596] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 2:1 to 400:1.

[0597] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 5:1 to 400:1.

[0598] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 7:1 to 400:1.

[0599] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 8:1 to 400:1.

[0600] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 10:1 to 400:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 15:1 to 400:1.

[0601] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 25:1 to 400:1.

[0602] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 50:1 to 400:1.

[0603] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 75:1 to 400:1.

[0604] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 100:1 to 400:1.

[0605] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 200:1 to 400:1.

[0606] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 300:1 to 400:1.

[0607] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is 400:1.

[0608] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:10 to 250:1.

[0609] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:5 to 250:1.

[0610] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:2 to 250:1.

[0611] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:1 to 250:1.

[0612] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 5:1 to 250:1.

[0613] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 7:1 to 250:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 8:1 to 250:1.

[0614] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 10:1 to 250:1.

[0615] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 25:1 to 250:1.

[0616] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 50:1 to 250:1.

[0617] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 75:1 to 250:1.

[0618] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 100:1 to 250:1.

[0619] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is 250:1.

[0620] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:10 to 100:1.

[0621] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:5 to 100:1.

[0622] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:2 to 100:1.

[0623] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:1 to 100:1.

[0624] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 5:1 to 100:1.

[0625] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 7:1 to 100:1.

[0626] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 8:1 to 100:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 10:1 to 100:1.

[0627] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 25:1 to 100:1.

[0628] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 50:1 to 100:1.

[0629] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 75:1 to 100:1.

[0630] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is 100:1.

[0631] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:10 to 50:1.

[0632] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:5 to 50:1.

[0633] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:2 to 50:1.

[0634] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:1 to 50:1.

[0635] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 5:1 to 50:1.

[0636] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 7:1 to 50:1.

[0637] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 8:1 to 50:1.

[0638] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 10:1 to 50:1.

[0639] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 25:1 to 50:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 15:1 to 50:1.

[0640] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is 50:1.

[0641] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:10 to 25:1.

[0642] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:5 to 25:1.

[0643] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:2 to 25:1.

[0644] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:1 to 25:1.

[0645] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 2:1 to 25:1.

[0646] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 5:1 to 25:1.

[0647] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 7:1 to 25:1.

[0648] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 8:1 to 25:1.

[0649] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 10:1 to 25:1.

[0650] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 15:1 to 25:1.

[0651] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is 25:1.

[0652] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:10 to 10:1. In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:5 to 10:1.

[0653] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:2 to 10:1.

[0654] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:1 to 10:1.

[0655] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 2:1 to 10:1.

[0656] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 5:1 to 10:1.

[0657] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 7:1 to 10:1.

[0658] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is from 8:1 to 10:1.

[0659] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is 8:1.

[0660] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is 9:1.

[0661] In some embodiments the weight ratio between the pyrethroid a) and the surfactant (B) is 10:1.

[0662] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:20 to 50:1.

[0663] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:10 to 50:1.

[0664] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:5 to 50:1.

[0665] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:4 to 50:1. In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:2 to 50:1.

[0666] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:1 to 50:1.

[0667] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 10:1 to 50:1.

[0668] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 20:1 to 50:1.

[0669] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 30:1 to 50:1.

[0670] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 40:1 to 50:1.

[0671] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 45:1 to 50:1.

[0672] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:20 to 40:1.

[0673] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:10 to 40:1.

[0674] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:5 to 40:1.

[0675] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:4 to 40:1.

[0676] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:2 to 40:1.

[0677] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:1 to 40:1.

[0678] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 10:1 to 40:1. In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 20:1 to 40:1.

[0679] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 30:1 to 40:1.

[0680] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is 40:1.

[0681] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:20 to 30:1.

[0682] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:10 to 30:1.

[0683] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:5 to 30:1.

[0684] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:4 to 30:1.

[0685] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:2 to 30:1.

[0686] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:1 to 30:1.

[0687] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 10:1 to 30:1.

[0688] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 20:1 to 30:1.

[0689] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is 30:1.

[0690] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:20 to 20:1.

[0691] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:10 to 20:1. In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:5 to 20:1.

[0692] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:4 to 20:1.

[0693] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:2 to 20:1.

[0694] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:1 to 20:1.

[0695] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 10:1 to 20:1.

[0696] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is 20:1.

[0697] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:20 to 10:1.

[0698] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:10 to 10:1.

[0699] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:5 to 10:1.

[0700] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:4 to 10:1.

[0701] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:2 to 10:1.

[0702] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:1 to 10:1.

[0703] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is 10:1.

[0704] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 2:1 to 10:1. In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 5:1 to 10:1.

[0705] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 7:1 to 10:1.

[0706] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 8:1 to 10:1.

[0707] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:20 to 5:1.

[0708] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:10 to 5:1.

[0709] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:5 to 5:1.

[0710] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:4 to 5:1.

[0711] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:2 to 5:1.

[0712] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:1 to 5:1.

[0713] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 2:1 to 5:1.

[0714] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 3:1 to 5:1.

[0715] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 4:1 to 5:1.

[0716] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is 5:1.

[0717] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:20 to 4:1. In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:10 to 4:1.

[0718] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:5 to 4:1.

[0719] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:4 to 4:1.

[0720] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:2 to 4:1.

[0721] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:1 to 4:1.

[0722] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 2:1 to 4:1.

[0723] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 3:1 to 4:1.

[0724] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is 4:1.

[0725] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:20 to 2:1.

[0726] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:10 to 2:1.

[0727] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:5 to 2:1.

[0728] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:4 to 2:1.

[0729] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:2 to 2:1.

[0730] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:1 to 2:1. In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is 2:1.

[0731] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:20 to 1:1.

[0732] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:10 to 1:1.

[0733] In some embodiment the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:5 to 1:1.

[0734] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:4 to 1:1.

[0735] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:2 to 1:1.

[0736] In some embodiment, the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is 1:1.

[0737] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:100 to 100:1.

[0738] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:75 to 100:1.

[0739] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:50 to 100:1.

[0740] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:25 to 100:1.

[0741] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:10 to 100:1.

[0742] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:5 to 100:1.

[0743] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:4 to 100:1. In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:2 to 100:1.

[0744] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:1 to 100:1.

[0745] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 5:1 to 100:1

[0746] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 10:1 to 100:1.

[0747] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 25:1 to 100:1.

[0748] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 50:1 to 100:1.

[0749] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 75:1 to 100:1.

[0750] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is 100:1.

[0751] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:100 to 75:1.

[0752] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:75 to 75:1.

[0753] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:50 to 75:1.

[0754] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:25 to 75:1.

[0755] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:10 to 75:1.

[0756] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:5 to 75:1. In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:4 to 75:1.

[0757] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:2 to 75:1.

[0758] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:1 to 75:1.

[0759] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 5:1 to 75:1.

[0760] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 10:1 to 75:1.

[0761] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 25:1 to 75:1.

[0762] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 50:1 to 75:1.

[0763] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is 75:1.

[0764] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:100 to 50:1.

[0765] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:75 to 50:1.

[0766] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:50 to 50:1.

[0767] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:25 to 50:1.

[0768] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:10 to 50:1.

[0769] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:5 to 50:1. In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:4 to 50:1.

[0770] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:2 to 50:1.

[0771] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:1 to 50:1.

[0772] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 5:1 to 50:1.

[0773] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 10:1 to 50:1.

[0774] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 25:1 to 50:1.

[0775] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is 50:1.

[0776] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:100 to 25:1.

[0777] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:75 to 25:1.

[0778] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:50 to 25:1.

[0779] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:25 to 25:1.

[0780] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:10 to 25:1.

[0781] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:5 to 25:1.

[0782] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:4 to 25:1. In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:2 to 25:1.

[0783] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:1 to 25:1.

[0784] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 5:1 to 25:1.

[0785] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 10:1 to 25:1.

[0786] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 15:1 to 25:1.

[0787] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is 25:1.

[0788] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:100 to 10:1.

[0789] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:75 to 10:1.

[0790] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:50 to 10:1.

[0791] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:25 to 10:1.

[0792] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:10 to 10:1.

[0793] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:5 to 10:1.

[0794] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:4 to 10:1.

[0795] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:2 to 10:1. In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:1 to 10:1.

[0796] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 2:1 to 10:1.

[0797] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 5:1 to 10:1.

[0798] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 7:1 to 10:1.

[0799] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 9:1 to 10:1.

[0800] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is 10:1.

[0801] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:100 to 5:1.

[0802] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:75 to 5:1.

[0803] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:50 to 5:1.

[0804] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:25 to 5:1.

[0805] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:10 to 5:1.

[0806] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:5 to 5:1.

[0807] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:4 to 5:1.

[0808] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:2 to 5:1. In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:1 to 5:1.

[0809] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 2:1 to 5:1.

[0810] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 3:1 to 5:1.

[0811] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 4:1 to 5:1.

[0812] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is 5:1.

[0813] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:100 to 2:1.

[0814] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:75 to 2:1.

[0815] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:50 to 2:1.

[0816] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:25 to 2:1.

[0817] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:10 to 2:1.

[0818] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:5 to 2:1.

[0819] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:4 to 2:1.

[0820] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:2 to 2:1.

[0821] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:1 to 2:1. In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is 2:1.

[0822] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:100 to 1:1.

[0823] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:75 to 1:1.

[0824] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:50 to 1:1.

[0825] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:25 to 1:1.

[0826] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:10 to 1:1.

[0827] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:5 to 1:1.

[0828] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:4 to 1:1.

[0829] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is from 1:2 to 1:1.

[0830] In some embodiment, the weight ratio between the surfactant (A) and surfactant (B) is 1:1.

[0831] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:200 to 10:1.

[0832] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:150 to 10:1.

[0833] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:100 to 10:1.

[0834] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:75 to 10:1. In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:50 to 10:1.

[0835] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:20 to 10:1.

[0836] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:10 to 10:1.

[0837] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:7 to 10:1.

[0838] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:5 to 10:1.

[0839] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:2 to 10:1.

[0840] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:1 to 10:1.

[0841] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 2:1 to 10:1.

[0842] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 3:1 to 10:1.

[0843] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 4:1 to 10:1.

[0844] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 5:1 to 10:1.

[0845] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 6:1 to 10:1.

[0846] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 7:1 to 10:1.

[0847] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 8:1 to 10:1. In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 9:1 to 10:1.

[0848] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is 10:1.

[0849] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:200 to 9:1.

[0850] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:150 to 9:1.

[0851] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:100 to 9:1.

[0852] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:75 to 9:1.

[0853] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:50 to 9:1.

[0854] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:20 to 9:1.

[0855] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:10 to 9:1.

[0856] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:7 to 9:1.

[0857] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:5 to 9:1.

[0858] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:2 to 9:1.

[0859] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:1 to 9:1.

[0860] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 2:1 to 9:1. In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 3:1 to 9:1.

[0861] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 4:1 to 9:1.

[0862] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 5:1 to 9:1.

[0863] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 6:1 to 9:1.

[0864] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 7:1 to 9:1.

[0865] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 8:1 to 9:1.

[0866] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is 9:1.

[0867] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:200 to 8:1.

[0868] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:150 to 8:1.

[0869] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:100 to 8:1.

[0870] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:75 to 8:1.

[0871] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:50 to 8:1.

[0872] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:20 to 8:1.

[0873] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:10 to 8:1. In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:7 to 8:1.

[0874] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:5 to 8:1.

[0875] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:2 to 8:1.

[0876] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:1 to 8:1.

[0877] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 2:1 to 8:1.

[0878] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 3:1 to 8:1.

[0879] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 4:1 to 8:1.

[0880] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 5:1 to 8:1.

[0881] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 6:1 to 8:1.

[0882] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 7:1 to 8:1.

[0883] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is 8:1.

[0884] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:200 to 5:1.

[0885] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:150 to 5:1.

[0886] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:100 to 5:1. In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:75 to 5:1.

[0887] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:50 to 5:1.

[0888] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:20 to 5:1.

[0889] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:10 to 5:1.

[0890] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:7 to 5:1.

[0891] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:5 to 5:1.

[0892] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:2 to 5:1.

[0893] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:1 to 5:1.

[0894] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 2:1 to 5:1.

[0895] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 3:1 to 5:1.

[0896] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 4:1 to 5:1.

[0897] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is 5:1.

[0898] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:200 to 2:1.

[0899] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:150 to 2:1. In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:100 to 2:1.

[0900] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:75 to 2:1.

[0901] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:50 to 2:1.

[0902] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:20 to 2:1.

[0903] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:10 to 2:1.

[0904] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:7 to 2:1.

[0905] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:5 to 2:1.

[0906] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:2 to 2:1.

[0907] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:1 to 2:1.

[0908] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is 2:1.

[0909] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:200 to 1:1.

[0910] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:150 to 1:1.

[0911] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:100 to 1:1.

[0912] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:75 to 1:1. In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:50 to 1:1.

[0913] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:20 to 1:1.

[0914] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:10 to 1:1.

[0915] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:7 to 1:1.

[0916] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:5 to 1:1.

[0917] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:2 to 1:1.

[0918] In another embodiment, the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is 1:1.

[0919] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:200 to 10:1.

[0920] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:150 to 10:1.

[0921] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:100 to 10:1.

[0922] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:75 to 10:1.

[0923] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:50 to 10:1.

[0924] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:20 to 10:1.

[0925] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:10 to 10:1. In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:7 to 10:1.

[0926] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:5 to 10:1.

[0927] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:2 to 10:1.

[0928] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:1 to 10:1.

[0929] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 2:1 to 10:1.

[0930] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 3:1 to 10:1.

[0931] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 4:1 to 10:1.

[0932] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 5:1 to 10:1.

[0933] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 6:1 to 10:1.

[0934] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 7:1 to 10:1.

[0935] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 8:1 to 10:1.

[0936] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 9:1 to 10:1.

[0937] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is 10:1.

[0938] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:200 to 9:1. In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:150 to 9:1.

[0939] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:100 to 9:1.

[0940] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:75 to 9:1.

[0941] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:50 to 9:1.

[0942] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:20 to 9:1.

[0943] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:10 to 9:1.

[0944] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:7 to 9:1.

[0945] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:5 to 9:1.

[0946] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:2 to 9:1.

[0947] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:1 to 9:1.

[0948] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 2:1 to 9:1.

[0949] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 3:1 to 9:1.

[0950] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 4:1 to 9:1.

[0951] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 5:1 to 9:1. In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 6:1 to 9:1.

[0952] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 7:1 to 9:1.

[0953] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 8:1 to 9:1.

[0954] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is 9:1.

[0955] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:200 to 8:1.

[0956] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:150 to 8:1.

[0957] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:100 to 8:1.

[0958] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:75 to 8:1.

[0959] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:50 to 8:1.

[0960] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:20 to 8:1.

[0961] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:10 to 8:1.

[0962] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:7 to 8:1.

[0963] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:5 to 8:1.

[0964] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:2 to 8:1. In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:1 to 8:1.

[0965] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 2:1 to 8:1.

[0966] In another embodiment, the weight ratio between the surfactant (B) and the particle size reducing adjuvant e) is from 3:1 to 8:1.

[0967] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 4:1 to 8:1.

[0968] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 5:1 to 8:1.

[0969] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 6:1 to 8:1.

[0970] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 7:1 to 8:1.

[0971] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is 8:1.

[0972] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:200 to 5:1.

[0973] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:150 to 5:1.

[0974] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:100 to 5:1.

[0975] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:75 to 5:1.

[0976] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:50 to 5:1.

[0977] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:20 to 5:1. In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:10 to 5:1.

[0978] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:7 to 5:1.

[0979] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:5 to 5:1.

[0980] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:2 to 5:1.

[0981] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:1 to 5:1.

[0982] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 2:1 to 5:1.

[0983] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 3:1 to 5:1.

[0984] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 4:1 to 5:1.

[0985] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is 5:1.

[0986] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:200 to 2:1.

[0987] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:150 to 2:1.

[0988] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:100 to 2:1.

[0989] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:75 to 2:1.

[0990] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:50 to 2:1. In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:20 to 2:1.

[0991] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:10 to 2:1.

[0992] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:7 to 2:1.

[0993] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:5 to 2:1.

[0994] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:2 to 2:1.

[0995] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:1 to 2:1.

[0996] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is 2:1.

[0997] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:200 to 1:1.

[0998] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:150 to 1:1.

[0999] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:100 to 1:1.

[1000] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:75 to 1:1.

[1001] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:50 to 1:1.

[1002] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:20 to 1:1.

[1003] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:10 to 1:1. In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:7 to 1:1.

[1004] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:5 to 1:1.

[1005] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:2 to 1:1.

[1006] In another embodiment, the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is 1:1.

[1007] Method of Preparation

[1008] The present invention provides a method for preparing the stable oil in water pyrethroid agrochemical composition comprising the following steps:

[1009] Step 1:

[1010] a) preparing an oil phase containing pyrethroid (a), water immiscible organic solvent (b) and water immiscible surfactants (A) and (B), optionally droplet size reducing adjuvant e); b) preparing a water phase containing water-soluble surfactants (A) and (B) with soft water, antifoam and anti-freeze

[1011] Step 2:

[1012] c) addition of an oil phase prepared in Step 1 (a) to the water phase prepared in Step 1 (b) and stirring together until the oil-in-water emulsion with the droplet size d90 < 2 pm is obtained.

[1013] In an embodiment, pyrethroid (a) is added into vessel containing water immiscible solvent, and the mixture is mixed until clear solution is obtained. After that all water immiscible surfactants (e.g. Castor oil 20, Alkamuls AP) and optionally water immiscible adjuvants are added and the resulting mixture stirred to obtain homogenous oil phase. Then water phase containing soft water, anti foam, anti-freeze and water miscible surfactants (A and B), is prepared in another vessel as homogenous water phase. After that the oil phase as prepared is added into the water phase with high shearing until homogenous white emulsion is obtained with d90< 2pm.

[1014] This invention provides use of the droplet size reducing adjuvant e) for the stabilization of oil in water agrochemical compositions comprising pyrethroids.

[1015] The invention provides a method of improving compatibility of a pyrethroid composition with fertilizer comprising formulating the pyrethroid composition with a combination of surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons and surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof.

[1016] The pyrethroid composition may further comprise components as described hereinabove.

[1017] Method of Use

[1018] The invention provides a method for controlling an insect pest comprising diluting the stable oil in water pyrethroid agrochemical composition with water to form a diluted composition and contacting the insect pest or its environment with an insecticidally effective amount of said diluted composition.

[1019] In certain embodiment, the ratio between the stable oil in water pyrethroid agrochemical composition with water to form the diluted composition is 1:2000 to 3:4000.

[1020] In some embodiment, the ratio between the stable oil in water pyrethroid agrochemical composition with water to form the diluted composition is 3:5000 to 3:4000.

[1021] In some embodiment, the ratio between the stable oil in water pyrethroid agrochemical composition with water to form the diluted composition is 3:8000 to 3:4000.

[1022] In another embodiment, the ratio between the stable oil in water pyrethroid agrochemical composition with water to form the diluted composition is 1:2500 to 3:5000.

[1023] In some embodiment, the dose rate of the stable oil in water pyrethroid agrochemical composition range between 0.075 L / ha to 0.75 L / ha.

[1024] In another embodiment, the dose rate of the stable oil in water pyrethroid agrochemical composition range between 0.09 L / ha to 0.75 L / ha. In certain embodiment, the dose rate of the stable oil in water pyrethroid agrochemical composition range between 0.15 L / ha to 0.75 L / ha.

[1025] In more preferred embodiment, the dose rate of the stable oil in water pyrethroid agrochemical composition range between 0.25 L / ha to 0.75 L / ha.

[1026] In some embodiment, the dose rate of the stable oil in water pyrethroid agrochemical composition range between 0.075 L / ha to 0.75 L / ha.

[1027] In another embodiment, the dose rate of the stable oil in water pyrethroid agrochemical composition range between 0.09 L / ha to 0.75 L / ha.

[1028] In certain embodiment, the dose rate of the stable oil in water pyrethroid agrochemical composition range between 0.15 L / ha to 0.75 L / ha.

[1029] In more preferred embodiment, the dose rate of the stable oil in water pyrethroid agrochemical composition range between 0.25 L / ha to 0.75 L / ha.

[1030] This invention provides a method for controlling insect pest using the oil in water agrochemical composition of the present invention.

[1031] The present invention provides a method for controlling an insect pest comprising contacting the insect pest or its environment with an insecticidally effective amount of the oil in water agrochemical composition of the present invention.

[1032] The invention provides a method for controlling insect pest using the liquid fertilizer compatible pesticide composition of the present invention.

[1033] The present invention provides a method for controlling an insect pest comprising contacting the insect pest or its environment with an insecticidally effective amount of the liquid fertilizer compatible pesticide composition of the present invention.

[1034] In some embodiment, the stable oil in water pyrethroid agrochemical composition is applied at an amount between 0.075 L / ha to 0.75 L / ha.

[1035] In some embodiment, the stable oil in water pyrethroid agrochemical composition is applied at an amount between 0.09 L / ha to 0.75 L / ha.

[1036] In some embodiment, the stable oil in water pyrethroid agrochemical composition is applied at an amount between 0.15 L / ha to 0.75 L / ha.

[1037] In some embodiment, the stable oil in water pyrethroid agrochemical composition is applied at an amount between 0.25 L / ha to 0.75 L / ha. In some embodiment, the stable oil in water pyrethroid agrochemical composition is applied at an amount between 0.075 L / ha to 0.75 L / ha.

[1038] In some embodiment, the stable oil in water pyrethroid agrochemical composition is applied at an amount between 0.09 L / ha to 0.75 L / ha.

[1039] In some embodiment, the stable oil in water pyrethroid agrochemical composition is applied at an amount between 0.15 L / ha to 0.75 L / ha.

[1040] In some embodiment, the stable oil in water pyrethroid agrochemical composition is applied at an amount between 0.25 L / ha to 0.75 L / ha.

[1041] In some embodiment, the liquid fertilizer compatible pesticide composition is applied at an amount between 0.075 L / ha to 0.75 L / ha.

[1042] In some embodiment, the liquid fertilizer compatible pesticide composition is applied at an amount between 0.09 L / ha to 0.75 L / ha.

[1043] In some embodiment, the liquid fertilizer compatible pesticide composition is applied at an amount between 0.15 L / ha to 0.75 L / ha.

[1044] In some embodiment, the liquid fertilizer compatible pesticide composition is applied at an amount between 0.25 L / ha to 0.75 L / ha.

[1045] In some embodiment, the liquid fertilizer compatible pesticide composition is applied at an amount between 0.075 L / ha to 0.75 L / ha.

[1046] In some embodiment, the liquid fertilizer compatible pesticide composition is applied at an amount between 0.09 L / ha to 0.75 L / ha.

[1047] In some embodiment, the liquid fertilizer compatible pesticide composition is applied at an amount between 0.15 L / ha to 0.75 L / ha.

[1048] In some embodiment, the liquid fertilizer compatible pesticide composition is applied at an amount between 0.25 L / ha to 0.75 L / ha.

[1049] In some embodiments, the method comprises applying the oil in water agrochemical composition in combination with a fertilizer.

[1050] In some embodiments, the oil in water agrochemical composition and the fertilizer are applied simultaneously. In some embodiments, the oil in water agrochemical composition and the fertilizer are applied separately. In some embodiments, the oil in water agrochemical composition and the fertilizer are applied sequentially.

[1051] In some embodiments, the method comprises applying the liquid fertilizer compatible pesticide composition in combination with a fertilizer.

[1052] In some embodiments, the liquid fertilizer compatible pesticide composition and the fertilizer are applied simultaneously. In some embodiments, the liquid fertilizer compatible pesticide composition and the fertilizer are applied separately. In some embodiments, the liquid fertilizer compatible pesticide composition and the fertilizer are applied sequentially.

[1053] Suitable fertilizers are described hereinabove.

[1054] In some embodiments, the fertilizer is applied at an amount from 100 to 3000 gr per hectare. In some embodiments, the fertilizer is applied at an amount from 100 to 500 gr per hectare. In some embodiments, the fertilizer is applied at an amount from 500 to 1000 gr per hectare. In some embodiments, the fertilizer is applied at an amount from 1000 to 1500 gr per hectare. In some embodiments, the fertilizer is applied at an amount from 1500 to 2000 gr per hectare. In some embodiments, the fertilizer is applied at an amount from 2000 to 2500 gr per hectare. In some embodiments, the fertilizer is applied at an amount from 2500 to 3000 gr per hectare.

[1055] In some embodiments, the fertilizer is boron.

[1056] In some embodiments, the boron is applied at an amount from 100 to 3000 gr of Boron per hectare.

[1057] In some embodiments, the boron is applied at an amount from 100 to 2000 gr of Boron per hectare.

[1058] In some embodiments, the boron is applied at an amount from 100 to 1000 gr of Boron per hectare.

[1059] In some embodiments, the boron is applied at an amount from 100 to 1500 gr of Boron per hectare.

[1060] In some embodiments, the boron is applied at an amount from 100 to 900 gr of Boron per hectare. In some embodiments, the boron is applied at an amount from 100 to 800 gr of Boron per hectare.

[1061] In some embodiments, the boron is applied at an amount from 100 to 700 gr of Boron per hectare.

[1062] In some embodiments, the boron is applied at an amount from 100 to 600 gr of Boron per hectare.

[1063] In some embodiments, the boron is applied at an amount from 100 to 500 gr of Boron per hectare.

[1064] In some embodiments, the boron is applied at an amount from 100 to 450 gr of Boron per hectare.

[1065] In some embodiments, the boron is applied at an amount from 200 to 450 gr of Boron per hectare.

[1066] In some embodiments, the boron is applied at an amount from 250 to 450 gr of Boron per hectare.

[1067] In some embodiments, the boron is applied at an amount from 200 to 500 gr of Boron per hectare.

[1068] In some embodiments, the boron is applied at an amount from 100 to 300 gr of Boron per hectare.

[1069] In some embodiments, the boron is applied at an amount from 100 to 250 gr of Boron per hectare.

[1070] In some embodiments, the boron is applied at an amount from 100 to 200 gr of Boron per hectare.

[1071] In some embodiments, the boron is applied at an amount from 100 to 150 gr of Boron per hectare.

[1072] In some embodiments, the boron is applied at an amount from 200 to 3000 gr of Boron per hectare.

[1073] In some embodiments, the boron is applied at an amount from 300 to 3000 gr of Boron per hectare. In some embodiments, the boron is applied at an amount from 400 to 3000 gr of Boron per hectare.

[1074] In some embodiments, the boron is applied at an amount from 450 to 3000 gr of Boron per hectare.

[1075] In some embodiments, the boron is applied at an amount from 500 to 3000 gr of Boron per hectare.

[1076] In some embodiments, the boron is applied at an amount from 600 to 3000 gr of Boron per hectare.

[1077] In some embodiments, the boron is applied at an amount from 700 to 3000 gr of Boron per hectare.

[1078] In some embodiments, the boron is applied at an amount from 800 to 3000 gr of Boron per hectare.

[1079] In some embodiments, the boron is applied at an amount from 900 to 3000 gr of Boron per hectare.

[1080] In certain embodiments the fertilizer comprises from 1000 to 3000gr of Boron per hectare.

[1081] In some embodiments, the boron is applied at an amount from 1500 to 3000 gr of Boron per hectare.

[1082] In some embodiments, the boron is applied at an amount from 2000 to 3000 gr of Boron per hectare.

[1083] In some embodiments, the boron is applied at an amount from 150 to 2500 gr of Boron per hectare.

[1084] In some embodiments, the boron is applied at an amount from 200 to 2000 gr of Boron per hectare.

[1085] In some embodiments, the boron is applied at an amount from 250 to 1500 gr of Boron per hectare.

[1086] In some embodiments, the boron is applied at an amount from 350 to 900 gr of Boron per hectare. In some embodiments, the boron is applied at an amount from 400 to 800 gr of Boron per hectare.

[1087] In some embodiments, the boron is applied at an amount from 500 to 700 gr of Boron per hectare.

[1088] In some embodiments, the boron is applied at an amount from 500 to 600 gr of Boron per hectare.

[1089] In some embodiments, the boron is applied at an amount from 100 to 450 gr of Boron per hectare.

[1090] In some embodiments, the boron is applied at an amount from 200 to 450 gr of Boron per hectare.

[1091] In some embodiments, the boron is applied at an amount from 300 to 450 gr of Boron per hectare.

[1092] In some embodiments, the boron is applied at an amount from 200 to 400 gr of Boron per hectare.

[1093] In some embodiments, the boron is applied at an amount from 200 to 350 gr of Boron per hectare.

[1094] In some embodiments, the boron is applied at an amount from 200 to 300 gr of Boron per hectare.

[1095] Each embodiment disclosed herein is contemplated as being applicable to each of the other disclosed embodiments. Thus, all combinations of the various elements described herein are within the scope of the invention. In addition, when lists are provided, the list is to be considered as a disclosure of any one member of the list.

[1096] Examples are provided below to impede a more complete understanding of the present subject matter. The following examples illustrate the exemplary modes of making and practicing the present invention. However, the scope of the present invention is not limited to specific embodiments disclosed in these Examples, which are for purposes of illustration only. The invention as described more fully in the claims which follow thereafter. Other examples will be apparently constructed by one skilled in the art from consideration of the specification embodiments and examples.

[1097] EXAMPLES: Example 1 - Stable oil in water pyrethroid agrochemical compositions according to the present invention containing 24% (w / w) per weight of a Pyrethroid and different additives were prepared according to Table 1.

[1098] Table 1. Stable oil in water pyrethroid agrochemical compositions:

[1099]

[1100] * Pyrethroid is selected from the list containing tau-fluvalinate, lambda-cyhalothrin, bifenthrin and the mixtures thereof.

[1101] Tau-fluvalinate is a known compound which is commercially available and could be prepared by several methods, for example as disclosed in "Journal of Agricultural and Food Chemistry", 1985, 33 (3), p 508-514.

[1102] The following compositions were prepared as representative examples of general Table 1.

[1103] Example 1A: tau-Fluvalinate 24% w / w oil in water composition with PolyAgro® A:

[1104]

[1105]

[1106] Example 1B: tau-Fluvalinate 24% w / w oil in water composition with castor oil® 20:

[1107]

[1108] Example 1C: tau-Fluvalinate 24% w / w oil in water composition with Alkamuls® AP:

[1109]

[1110] Example 1D: tau-Fluvalinate 24% w / w oil in water composition with PolyAgro® A and Morwet® D-425:

[1111]

[1112]

[1113] Example 1E: tau-Fluvalinate 24% w / w oil in water composition with PolyAgro® A and Morwet® D-809:

[1114]

[1115] Example 1F: tau-Fluvalinate 24% w / w oil in water composition with Castor oil® 20 and Morwet® D-425:

[1116]

[1117]

[1118] Example 1G: tau-Fluvalinate 24% w / w oil in water composition with Castor oil® 20 and Morwet® 809:

[1119]

[1120] Example 1H: tau-Fluvalinate 24% w / w oil in water composition with Alkamuls® AP and Morwet® 809:

[1121]

[1122]

[1123] Example 1I: tau-Fluvalinate 24% w / w oil in water composition with Castor oil® 20 and Morwet® D-809:

[1124]

[1125] Example 1J: tau-Fluvalinate 24% w / w oil in water composition with Morwet® D-425 and Ethylan® NS-500:

[1126]

[1127]

[1128] Example 1K: tau-Fluvalinate 24% w / w oil in water composition with Morwet® D-809 and Ethylan® NS-500:

[1129]

[1130] Example 1L: tau-Fluvalinate 24% w / w oil in water composition with different surfactant and adjuvants:

[1131]

[1132]

[1133] Example 1M: tau-Fluvalinate 24% w / w oil in water composition with different surfactant:

[1134]

[1135] Example 1N: tau-Fluvalinate 24% w / w oil in water composition with different surfactant and adjuvants:

[1136]

[1137]

[1138] Example 1O: tau-Fluvalinate 24% w / w oil in water composition with different surfactants and adjuvants:

[1139]

[1140] Example 2 - Stable oil in water pyrethroid agrochemical composition containing 24% (w / w) per weight of a Pyrethroid and a particle size reducing adjuvant prepared according to Table 2 was evaluated.

[1141] Table 2. Stable oil in water pyrethroid agrochemical compositions containing a particle size reducing adjuvant:

[1142]

[1143] * Pyrethroid is selected from the list containing tau-fluvalinate, lambda-cyhalothrin, bifenthrin and the mixtures thereof.

[1144] ** particle size reducing adjuvant is selected from the list containing AltaHance ™ S, AltaHance™ 2S, AltaHance™ 3S, Altastick™ R, Altastick ™ HG and the mixtures thereof.

[1145] Tau-fluvalinate is a known compound which is commercially available and could be prepared by several methods, for example as disclosed in "Journal of Agricultural and Food Chemistry", 1985, 33 (3), p 508-514.

[1146] The following compositions were prepared as representative examples of general Table 2.

[1147] Example 2A: tau-Fluvalinate 24% w / w oil in water composition with PolyAgro® A and Altahance™ 2S as particle size reducing adjuvant:

[1148]

[1149]

[1150] Example 2B: tau-Fluvalinate 24% w / w oil in water composition with different surfactants and Altahance™ 2S as particle size reducing adjuvant:

[1151]

[1152] Example 2C: tau-Fluvalinate 24% w / w oil in water composition with different surfactants and Altahance™ 2s as particle size reducing adjuvant:

[1153]

[1154]

[1155] Example 2D: tau-Fluvalinate 24% w / w oil in water composition with different surfactants and Altastick™ HG as particle size reducing adjuvant:

[1156]

[1157]

[1158] Example 2E: tau-Fluvalinate 24% w / w oil in water composition with different surfactants and Altahance™ 2s as particle size reducing adjuvant:

[1159]

[1160] Example 2F: tau-Fluvalinate 24% w / w oil in water composition with Synperonic® PE 64, Powerblox® SN and Altahance™ 2s as particle size reducing adjuvant:

[1161]

[1162]

[1163] Example 3 - Agrochemical liquid product comprising an oil in water pyrethroid agrochemical composition and Lebosol®-Bor for evaluation of boron compatibility of inventive compositions containing tau-fluvalinate.

[1164] The agrochemical liquid products comprising an oil in water pyrethroid agrochemical composition according to the preceding examples 1 and 2 and Lebosol®-Bor were prepared according to the following procedure: 1.25 gr Lebosol®-Bor (0.5% usage percentage) was added into 250 mL of water followed by the addition of 1.25 gr of the following agrochemical compositions: 1C, 1D, 1F, 1N, 1O, 2B, 2C, 2D, 2E and 2F. Then the obtained mixture was stirred until homogenization.

[1165] Table 3 below represents the boron compatibility test results for compositions prepared according to Example 3:

[1166] Table 3. Boron compatibility results for compositions prepared according to Example 3

[1167]

[1168]

[1169] As shown in Table 3 above, all the tested compositions show good results and are compatible with boron containing fertilizer. Example 4 - Comparative examples.

[1170] Example 4A: tau-Fluvalinate 24% w / w oil in water composition with Atlox® 4915:

[1171]

[1172] Example 4B: tau-Fluvalinate 24% w / w oil in water composition with Ethylan® NS-500:

[1173]

[1174] Example 4C: tau-Fluvalinate 24% w / w oil in water composition with Ethylan® NS-500 and Hostaphat® 1306:

[1175]

[1176]

[1177] Example 4D: tau-Fluvalinate 24% w / w oil in water composition with PolyAgro® A, without Synperonic™ PE 64:

[1178]

[1179] Example 4E: tau-Fluvalinate 24% w / w oil in water composition with castor oil® 20 without Synperonic™ PE 64:

[1180]

[1181] Example 5 -Physical and chemical stability of the tested compositions prepared according to the Examples 1-4, measured at 25°C & 54°C after 6 weeks are represented in Table 4 below:

[1182] Table 4: Physical and chemical stability of the tested compositions prepared according to the Examples 1-4.

[1183]

[1184]

[1185] * The measurement was done after 17 days.

[1186] As could be seen in the examples represented above, Inventive compositions are stable over time, keeping the particle size less than 2μm in the condition of the experiment adapted for a potential use in the field.

Claims

1. CLAIMS1. A stable oil in water pyrethroid agrochemical composition, comprising:3.a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition;4.b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof;5.c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;6.d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof;7.e) optionally a droplet size reducing adjuvant; and8.f) water;9.wherein the drop size d90 of the oil phase is less than 2 μm.

2. The stable oil in water pyrethroid agrochemical composition of claim 1, wherein the composition comprises the droplet size reducing adjuvant.

3. A liquid fertilizer compatible pesticide composition comprising:12.a) pyrethroid in an amount of from 1 % to 50 % per weight of total composition;13.b) water immiscible solvent selected from the group consisting of vegetables oils, aromatic hydrocarbons, C16-C18 fatty acid methyl esters and the mixtures thereof; c) surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons;14.d) surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof;15.e) optionally a droplet size reducing adjuvant;16.f) water;17.wherein the drop size d90 of the oil phase is less than 2 μm.

4. The liquid fertilizer compatible pesticide composition of claim 3, wherein the composition comprises the droplet size reducing adjuvant.

5. The liquid fertilizer compatible pesticide composition of claim 3 or 4, wherein the composition comprises a fertilizer.

6. A liquid fertilizer compatible pesticide composition comprising the stable oil in water pyrethroid agrochemical composition of claim 1 or 2, and a fertilizer.

7. The liquid fertilizer compatible pesticide composition of claim 5 or 6, wherein the fertilizer is boron.

8. The liquid fertilizer compatible pesticide composition of claim 7, wherein the composition is formulated for application of Boron at an amount from 100 to 3000 gr of Boron per hectare.

9. The liquid fertilizer compatible pesticide composition of any one of claims 6-8, wherein the stable oil in water pyrethroid agrochemical composition and the fertilizer are applied simultaneously, separately, or sequentially for control of pests at a locus.

10. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-9, wherein the pyrethroid a) is selected from the group consisting of tau-fluvalinate, lambda-cyhalothrin, bifenthrin and the mixtures thereof.

11. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-10, wherein the amount of water-immiscible solvent b) is from 0.1 % to 50 % per weight, based on the weight of total composition.

12. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-11, wherein the amount of surfactant (A) is from 0.1 % to 10 % per weight, based on the weight of total composition.

13. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-12, wherein the amount of surfactant (B) is from 0.1 % to 10 % per weight, based on the weight of total composition.

14. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-13, wherein the amount of the droplet size reducing adjuvant e) is from 1% to 20 % per weight, based on the weight of total composition.

15. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-14, wherein the droplet size reducing adjuvant e) is selected from the group consisting of AltaHance ™ S, AltaHance™ 2S, AltaHance™ 3S, Altastick™ R, Altastick™ HG and the mixtures thereof.

16. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-15, wherein the weight ratio between the pyrethroid a) and the water immiscible solvent b) is from 1:150 to 500:1.

17. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-16, wherein the weight ratio between the pyrethroid a) and the surfactant (A) is from 1:10 to 500:1.

18. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-17, wherein the weight ratio between the pyrethroid a) and the surfactant (B) is from 1:0 to 500:1.

19. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-18, wherein the weight ratio between the pyrethroid a) and the droplet size reducing adjuvant e) is from 1:20 to 50:1.

20. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-19, wherein the weight ratio between the surfactant (A) and surfactant (B) is from 1:100 to 100:1.

21. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-20, wherein the weight ratio between the surfactant (A) and the droplet size reducing adjuvant e) is from 1:200 to 10:1.

22. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-21, wherein the weight ratio between the surfactant (B) and the droplet size reducing adjuvant e) is from 1:200 to 10:1.

23. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-22, wherein the surfactant (A) is an ethylene oxide / propylene oxide block copolymer.

24. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of any one of claims 1-23, wherein the surfactant (B) is a polyelectrolyte copolymer, vegetable oil alkoxylate, or arylsulphonate.

25. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of claim 24, wherein the polyelectrolyte copolymer is a di-block copolymer comprising sodium 2-Acryloylamino-2- methylpropane-1-sulfonate (AMPS) monomers and ethyl acrylate monomers.

26. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of claim 24, wherein the vegetable oil alkoxylate is castor oil alkoxylate.

27. The stable oil in water pyrethroid agrochemical composition or liquid fertilizer compatible pesticide composition of claim 24, wherein the arylsulphonate is alkyl naphthalene sulfonate.

28. Use of a droplet size reducing adjuvant for the stabilization of an oil in water agrochemical compositions comprising a pyrethroid.

29. A method for preparing the stable oil in water pyrethroid agrochemical composition of claim 1, comprising the following steps:41.a) preparing an oil phase containing pyrethroid (a) water immiscible organic solvent (b) and water immiscible surfactants (A) and (B) optionally droplet size reducing adjuvant e);42.b) preparing a water phase containing water-soluble surfactants (A) and (B) with soft water, antifoam and anti-freeze, and c) addition of an oil phase prepared in step a) to the water phase prepared in step b) and stirring together until the oil-in-water emulsion with the droplet size d90 < 2 pm is obtained.

30. A method for controlling an insect pest comprising diluting the composition of any one of claims 1-27 with water to form a diluted composition and contacting the insect pest or its environment with an insecticidally effective amount of the diluted composition.

31. A method for controlling an insect pest comprising contacting the insect pest or its environment with an insecticidally effective amount of the composition of any one of claims 1-27.

32. A method of improving compatibility of a pyrethroid composition with fertilizer comprising formulating the pyrethroid composition with a combination of surfactant (A) selected from poloxamers and / or poloxamines having HLB values in the range from 5 to 18 and an average molecular weight ranging from about 900 to about 20000 Daltons and surfactant (B) selected from the group consisting of vegetable oil alkoxylates, polyelectrolytes, arylsulphonates, alkylaryl sulfonates and the mixtures thereof.

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