Sulfonamide compound and noxious arthropod control composition containing same

Abstract

Provided is a compound represented by formula (I) [in the formula, Q represents a group or the like represented by formula Q1, R2a and R2b are the same or different from each other, and each represents a C1-C6 alkyl group or the like which may be substituted with one or more halogen atoms, and Het represents a group or the like represented by formula Het1], or an N oxide thereof, which has an excellent control effect on harmful arthropods. # imgabs0 #

Description

Technical Field

[0001] This patent application claims priority and benefits under the Paris Convention based on Japanese Patent Application No. 2022-165593 (filed on October 14, 2022), and all the contents described in the above application are incorporated into this specification by reference.

[0002] The present invention relates to a sulfonamide compound and a harmful arthropod control composition containing the sulfonamide compound. Background Art

[0003] Various compounds have been studied for the purpose of controlling harmful arthropods. For example, Patent Document 1 describes that a certain compound has a pest control effect.

[0004] Prior art literature

[0005] Patent Literature

[0006] Patent Document 1: International Publication No. 2016 / 052455 Summary of the Invention

[0007] Problems to be solved by the invention

[0008] An object of the present invention is to provide a compound having excellent control effect on harmful arthropods.

[0009] Means for solving problems

[0010] The inventors of the present application have conducted studies to find a compound having an excellent control effect on harmful arthropods, and as a result, have found that a compound represented by the following formula (I) has an excellent control effect on harmful arthropods.

[0011] That is, the present invention is as follows.

[0012] [1] A compound represented by formula (I) (hereinafter referred to as Compound N of the present invention) or an N-oxide thereof (hereinafter referred to as Compound (I) or an N-oxide thereof as Compound of the present invention).

[0013] [Chemical Formula 1]

[0014]

[0015] [Where,

[0016] Q shown in the following formula represents a group represented by formula Q1, a group represented by formula Q2, a group represented by formula Q4, a group represented by formula Q5, a group represented by formula Q6, or a group represented by formula Q7 (# represents a bonding site to a sulfur atom, ● represents a bonding site to Het),

[0017] [Chemical Formula 2]

[0018]

[0019] [Chemical Formula 3]

[0020]

[0021] A 1 Indicates NR 5a , oxygen atoms or sulfur atoms,

[0022] G 1 , G 2 , G 3 and G 4 The combination of:

[0023] G 1 is a nitrogen atom or CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c combination of;

[0024] G 1 CR 3a , G 2 is a nitrogen atom, G 3 CR 3d , G 4 CR 3c combination of;

[0025] G 1 CR 3a , G 2 CR 3b , G 3 is a nitrogen atom, G 4 CR 3c or

[0026] G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 is a combination of nitrogen atoms,

[0027] W 1 represents an oxygen atom or a sulfur atom,

[0028] R 2a and R 2bare the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom,

[0029] R 2a and R 2b Together with the nitrogen atom to which they are bound, they may form an aziridinyl, azetidinyl, pyrrolidinyl or piperidinyl group,

[0030] R 3a 、R 3b 、R 3c 、R 3d 、R 3f 、R 3i and R 3k are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group B, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group E, a phenyl group which may be substituted by one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group H, or 12 NR 11 R 12 NR 11a R 12a NR 24 NR 11 R 12 NR 24 OR 11 NR 11 C(O)R 13 NR 24 NR 11 C(O)R 13 NR 11 C(O)OR 14 NR 24 NR 11 C(O)OR 14 NR 11 C(O)NR 31 R 32 NR 24 NR 11 C(O)NR 31 R 32 、N=CHNR 31 R 32 、N=S(O) p R 15 R 16 、C(O)R 13 、C(O)OR 17 、C(O)NR 31 R 32 、C(O)NR 11S(O)2R 23 , CR 30 =NOR 17 NR 11 CR 24 =NOR 17 、S(O) q R 23 , cyano group, nitro group, hydrogen atom or halogen atom,

[0031] R 3e represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group H, or a hydrogen atom,

[0032] When Q is a group represented by formula Q1, R 3a 、R 3b and R 3d The two adjacent substituents in the group may form, together with the two carbon atoms to which they are bonded, a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, or a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring may be substituted with one or more substituents selected from Group H}, or a triazole ring which may be substituted with one or more substituents selected from Group I,

[0033] p represents 0 or 1,

[0034] q represents 0, 1 or 2,

[0035] R 30 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a halogen atom, or an OR 35 NR 36 R 37 , or hydrogen atoms,

[0036] R 17 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group D, or a hydrogen atom,

[0037] R 12 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, a C3-C7 cycloalkenyl group which may be substituted by one or more substituents selected from Group J, a phenyl group which may be substituted by one or more substituents selected from Group D, a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, a hydrogen atom, or S(O)2R23 ,

[0038] R 23 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from Group D,

[0039] R 11a and R 12a Together with the nitrogen atom to which they are bonded, they represent a 3- to 7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from Group E,

[0040] R 13 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from Group D, or a hydrogen atom,

[0041] R 14 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D},

[0042] R 15 and R 16 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms,

[0043] R 31 represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom,

[0044] R 32 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, or a hydrogen atom,

[0045] Het represents a group represented by formula Het1, a group represented by formula Het2, a group represented by formula Het3, a group represented by formula Het4, a group represented by formula Het5, or a group represented by formula Het6,

[0046] [Chemical Formula 4]

[0047]

[0048] A 2represents an oxygen atom, a sulfur atom, or NR 5b ,

[0049] A 3 Represents nitrogen atom or CR 4b ,

[0050] A 4 Represents nitrogen atom or CR 4c ,

[0051] A 5 Represents nitrogen atom or CR 4d ,

[0052] A 6 represents an oxygen atom, a sulfur atom, or NR 20 ,

[0053] W 2 represents an oxygen atom or a sulfur atom,

[0054] R 4b 、R 4c 、R 4d and R 6a The same or different, representing a C1-C6 chain hydrocarbon group, nitro group, OR 18 NR 18 R 19 , cyano group, amino group, halogen atom or hydrogen atom,

[0055] R 20 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, or a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted by one or more halogen atoms,

[0056] T represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C3-C5 alkenyloxy)C2-C5 alkyl group, a (C3-C5 alkynyloxy)C2-C5 alkyl group, or a (C1-C5 alkyl)-S(O) group. w -(C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) w -(C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) w -(C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O)w -(C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) w -(C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) w -(C2-C5 alkyl) group, and the (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms}, (C3-C7 cycloalkyl)C1-C3 alkyl substituted with one or more substituents selected from Group G, C3-C7 cycloalkyl substituted with one or more substituents selected from Group G, OR 1 、S(O) v R 1 、OS(O)2R 1 、CH2OR 1 NR 1 R 29 、C(O)R 1 、C(O)NR 1 R 29 NR 29 C(O)R 1 、N=CR 1 R 30 , a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12,

[0057] [Chemical Formula 5]

[0058]

[0059] [Chemical Formula 6]

[0060]

[0061] [Chemical Formula 7]

[0062]

[0063] X 1 Represents nitrogen atom or CR 1a ,

[0064] X 2 Represents nitrogen atom or CR 1b ,

[0065] X 3 Represents nitrogen atom or CR 1c ,

[0066] X 4 Represents nitrogen atom or CR 1d ,

[0067] X 5 Represents nitrogen atom or CR 1e ,

[0068] R 1x represents a C1-C5 chain hydrocarbon group substituted by one or more halogen atoms, OR 7 、OS(O)2R 7 、S(O) m R 7 NR 8 S(O)2R 7 or halogen atoms,

[0069] R 1a 、R 1b 、R 1c 、R 1d and R 1e are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom,

[0070] Y 1 Indicates NR 25 , oxygen atoms or sulfur atoms,

[0071] Y 2 Represents nitrogen atom or CR 26 ,

[0072] Y 3 Represents nitrogen atom or CR 27 ,

[0073] Y 4 Represents nitrogen atom or CR 28 ,

[0074] R 5a 、R 5b and R 25 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom,

[0075] R 26 、R 27 and R 28are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom,

[0076] R 1y represents a C1-C5 chain hydrocarbon group substituted by one or more halogen atoms, OR 7 、OS(O)2R 7 、S(O) m R 7 NR 8 S(O)2R 7 , cyano or halogen atoms,

[0077] R 1ay and R 7 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group substituted by one or more halogen atoms,

[0078] m and v are the same or different and represent 0, 1 or 2.

[0079] w and t are the same or different from each other and represent 0, 1 or 2,

[0080] R 1 represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C3-C5 alkenyloxy)C2-C5 alkyl group, a (C3-C5 alkynyloxy)C2-C5 alkyl group, or a (C1-C5 alkyl)-S(O) group. t -(C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) t -(C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) t -(C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) t -(C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) t -(C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) t -(C2-C5 alkyl) group, and said (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms, (C3-C7 cycloalkyl)C1-C3 alkyl substituted with one or more substituents selected from Group G, or C3-C7 cycloalkyl substituted with one or more substituents selected from Group G,

[0081] R 18 and R 35 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms,

[0082] R 8 、R 11 、R 19 、R 24 、R 29 、R 36 and R 37 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a hydrogen atom.

[0083] Group B: The group consisting of C1-C6 alkoxy groups which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfanyl groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl groups which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl groups which may be substituted by one or more halogen atoms, cyano groups, hydroxyl groups and halogen atoms.

[0084] Group C: A group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, and a halogen atom.

[0085] Group D: C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, hydroxyl group, C1-C6 alkoxy group which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, sulfanyl group, C1-C6 alkylsulfanyl group which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl group which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl group which may be substituted by one or more halogen atoms, amino group, NHR group 21 NR 21 R 22 、C(O)R 21 、OC(O)R 21 、C(O)OR 21 , cyano, nitro and halogen atoms.

[0086] R 21 and R 22 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted with one or more halogen atoms.

[0087] Group E: The group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, a halogen atom, an oxo group, a hydroxyl group, a cyano group and a nitro group.

[0088] Group F: C1-C6 alkoxy group which may be substituted with one or more halogen atoms, phenyl group which may be substituted with one or more substituents selected from Group D, 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from Group D, C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, 3-7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from Group C, amino group, NHR group 21 NR 21 R 22 , a group consisting of halogen atoms and cyano groups.

[0089] Group G: a group consisting of a halogen atom, a C1-C6 haloalkyl group, and a cyano group.

[0090] Group H: C1-C6 alkyl which may be substituted with one or more halogen atoms, OR 10 NR 9 R 10 、C(O)R 10 、C(O)NR 9 R 10 、OC(O)R 9 、OC(O)OR 9 NR 10 C(O)R 9 NR 10 C(O)OR 9 、C(O)OR 10 , a halogen atom, a nitro group, a cyano group, an amino group and a 5- or 6-membered aromatic heterocyclic group.

[0091] R 9 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms,

[0092] R 10 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom.

[0093] Group I: The group consisting of a C2-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, a C2-C6 alkylcarbonyl group which may be substituted by one or more halogen atoms, a C2-C6 alkoxycarbonyl group which may be substituted by one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms, a methyl group, and a di(C1-C4 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms.

[0094] Group J: A group consisting of a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a halogen atom, and a cyano group.

[0095] [2] The compound according to [1] or its N-oxide, wherein Q is a group represented by formula Q4 or a group represented by formula Q7.

[0096] [3] The compound according to [1] or its N-oxide, wherein Q is a group represented by formula Q5 or a group represented by formula Q6.

[0097] [4] The compound according to [1] or its N-oxide, wherein Q is a group represented by formula Q1 or a group represented by formula Q2.

[0098] [5] The compound according to [1] or its N-oxide, wherein Q is a group represented by the formula Q5.

[0099] [6] The compound or N-oxide thereof as described in [5], wherein G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c .

[0100] [7] The compound or N-oxide thereof according to any one of [1] to [6], wherein Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d .

[0101] [8] A composition for controlling harmful arthropods, comprising an inactive carrier and the compound or N-oxide thereof according to any one of [1] to [7].

[0102] [9] A composition comprising one or more components selected from the group consisting of group (a), group (b), group (c), and group (d), and the compound or N-oxide thereof according to any one of [1] to [7],

[0103] Group (a): a group consisting of insecticidal active ingredients, acaricidal active ingredients and nematicidal active ingredients;

[0104] Group (b): bactericidal active ingredients;

[0105] Group (c): plant growth regulating ingredients;

[0106] Group (d): repellent ingredients.

[0107]

[10] A method for controlling harmful arthropods, comprising applying an effective amount of the compound or N-oxide thereof according to any one of [1] to [7], or an effective amount of the composition according to [9], to the harmful arthropods or to a habitat of the harmful arthropods.

[0108]

[11] Seeds or vegetative propagation organs, which contain an effective amount of the compound or N-oxide thereof according to any one of [1] to [7] or an effective amount of the composition according to [9].

[0109] Effects of the Invention

[0110] According to the present invention, harmful arthropods can be controlled. DETAILED DESCRIPTION

[0111] The substituents in the present invention are explained.

[0112] The halogen atom refers to a fluorine atom, a chlorine atom, a bromine atom or an iodine atom.

[0113] When the substituent is substituted with two or more halogen atoms or substituents, these halogen atoms or substituents may be the same or different.

[0114] In this specification, the expression "CX-CY" means that the number of carbon atoms is X to Y. For example, the expression "C1-C6" means that the number of carbon atoms is 1 to 6.

[0115] The chain hydrocarbon group refers to an alkyl group, an alkenyl group or an alkynyl group.

[0116] Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a 1,1-dimethylpropyl group, a 1,2-dimethylpropyl group, a 1-ethylpropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group.

[0117] Examples of the alkenyl group include ethenyl, 1-propenyl, 2-propenyl, 1-methyl-1-propenyl, 1-methyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1-ethyl-2-propenyl, 3-butenyl, 4-pentenyl, and 5-hexenyl.

[0118] Examples of the alkynyl group include ethynyl, 1-propynyl, 2-propynyl, 1-methyl-2-propynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 2-butynyl, 4-pentynyl, and 5-hexynyl.

[0119] Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a tert-butoxy group, a pentyloxy group, and a hexyloxy group.

[0120] Examples of the alkenyloxy group include a 2-propenyloxy group, a 2-butenyloxy group, and a 5-hexenyloxy group.

[0121] Examples of the alkynyloxy group include a 2-propynyloxy group, a 2-butynyloxy group, and a 5-hexynyloxy group.

[0122] Examples of the cycloalkyl group include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a cycloheptyl group.

[0123] Examples of the cycloalkenyl group include a cyclopropenyl group, a cyclobutenyl group, a cyclopentenyl group, a cyclohexenyl group, and a cycloheptenyl group.

[0124] Examples of the 3- to 7-membered non-aromatic heterocyclic group include aziridinyl, oxirane, thiirane, azetidinyl, oxetanyl, thietanyl, pyrrolidinyl, tetrahydrofuranyl, tetrahydrothiophenyl, piperidinyl, pyranyl, dihydropyranyl, tetrahydropyranyl, tetrahydrothiopyranyl, azepanyl, oxepanyl, thiepanyl, pyrazolinyl, pyrazolidinyl, imidazolinyl, imidazolidinyl, oxazolinyl, thiazolinyl, oxazolidinyl, thiazolidinyl, isoxazolinyl, isoxazolidinyl, isothiazolinyl, isothiazolidinyl, dioxolyl, dioxane, morpholinyl, thiomorpholinyl, and piperazinyl.

[0125] Examples of the 5- or 6-membered aromatic heterocyclic group include pyrrolyl, furyl, thienyl, pyrazolyl, imidazolyl, triazolyl, tetrazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, triazinyl and tetrazinyl.

[0126] Examples of the 6-membered aromatic heterocyclic group include a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, and a tetrazinyl group.

[0127] Examples of the (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms include cyclopropylmethyl, (2-fluorocyclopropyl)methyl, cyclopropyl(fluoro)methyl, and (2-fluorocyclopropyl)(fluoro)methyl.

[0128] Examples of the (C1-C5 alkoxy)C2-C5 alkyl group include a 2-methoxyethyl group, a 3-methoxypropyl group, and a 3-ethoxypropyl group.

[0129] The so-called (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted with one or more halogen atoms means a group in which (C3-C7 cycloalkyl) and / or (C1-C6 alkyl) may be substituted with one or more halogen atoms, and examples thereof include (2,2-difluorocyclopropyl)methyl, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl, 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl, (2,2-difluorocyclopropyl)propyl, (2,2-difluorocyclopropyl)butyl, (2,2-difluorocyclopropyl)pentyl, and (2,2-difluorocyclopropyl)hexyl.

[0130] The (C3-C7 cycloalkyl)C1-C3 alkyl group substituted with one or more substituents selected from group G refers to a group in which (C3-C7 cycloalkyl) and / or (C1-C3 alkyl) are substituted with one or more substituents selected from group G, and examples thereof include (2,2-difluorocyclopropyl)methyl, [1-(trifluoromethyl)cyclopropyl]methyl, [2-(trifluoromethyl)cyclopropyl]methyl, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl, 2-cyclopropyl-3,3,3-trifluoropropyl, and 1,1,2,2-tetrafluoro-2-[2-(trifluoromethyl)cyclopropyl]ethyl.

[0131] Examples of the alkylsulfanyl group include a methylsulfanyl group, an ethylsulfanyl group, a propylsulfanyl group, and an isopropylsulfanyl group.

[0132] Examples of the alkylsulfinyl group include a methylsulfinyl group, an ethylsulfinyl group, a propylsulfinyl group, and an isopropylsulfinyl group.

[0133] Examples of the alkylsulfonyl group include a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, and an isopropylsulfonyl group.

[0134] Examples of the alkylcarbonyl group include an acetyl group, a propionyl group, a 2-methylpropionyl group, and a hexanoyl group.

[0135] Examples of the alkoxycarbonyl group include a methoxycarbonyl group, an ethoxycarbonyl group, an isopropoxycarbonyl group, and a pentyloxycarbonyl group.

[0136] Examples of the N-oxide of the compound represented by formula (I) include compounds represented by the following formula.

[0137] [Chemical Formula 8]

[0138]

[0139] [In the formula, the symbols have the same meanings as above.]

[0140] The compounds of the present invention may exist in one or more stereoisomers. Examples of stereoisomers include enantiomers, diastereomers, and geometric isomers. The compounds of the present invention include individual stereoisomers and mixtures of stereoisomers in any ratio.

[0141] The compounds of the present invention may form acid addition salts. Examples of acids that form acid addition salts include inorganic acids such as hydrogen chloride, phosphoric acid, and sulfuric acid, and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid. Acid addition salts can be obtained by mixing the compounds of the present invention with an acid.

[0142] As an embodiment of the compound N of the present invention, the following compounds can be mentioned.

[0143] [Embodiment 1] In the compound N of the present invention, Q is a group represented by the formula Q4 or a group represented by the formula Q7.

[0144] [Embodiment 2] In the compound N of the present invention, Q is a group represented by the formula Q5 or a group represented by the formula Q6.

[0145] [Embodiment 3] In the compound N of the present invention, Q is a group represented by the formula Q1 or a group represented by the formula Q2.

[0146] [Embodiment 4] In the compound N of the present invention, Q is a group represented by the formula Q5.

[0147] [Embodiment 5] In the compound N of the present invention, Q is of the formula Q5, G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c of compounds.

[0148] [Embodiment 6] In the compound N of the present invention, Q is of the formula Q5, G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c , R 3a is a hydrogen atom, R 3bis a C1-C6 chain hydrocarbon group, a hydrogen atom or a halogen atom which may be substituted by one or more substituents selected from Group B, 3c is a hydrogen atom, R 3d A compound comprising a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from Group B, a hydrogen atom or a halogen atom.

[0149] [Embodiment 7] In the compound N of the present invention, Q is a compound of the formula Q5, G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c , R 3a is a hydrogen atom, R 3b is a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group B, or a halogen atom, R 3c is a hydrogen atom, R 3d A compound containing hydrogen atoms.

[0150] [Embodiment 8] In the compound N of the present invention, Q is a compound of the formula Q5, G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c , R 3a 、R 3c and R 3d is a hydrogen atom, R 3b A compound containing a halogen atom.

[0151] [Embodiment 9] In the compound N of the present invention, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d of compounds.

[0152] [Embodiment 10] In the compound N of the present invention, Het is a group represented by the formula Het4 or a group represented by the formula Het5, and W 2 A compound containing oxygen atoms.

[0153] [Embodiment 11] In the compound N of the present invention, Het is a group represented by the formula Het2 or a group represented by the formula Het3, and A 2 and A 6 is an oxygen atom, R 6aA compound containing hydrogen atoms.

[0154] [Embodiment 12] In the compound N of the present invention, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d ,

[0155] R 4b 、R 4c and R 4d A compound containing hydrogen atoms.

[0156] [Embodiment 13] In Embodiment 1, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d of compounds.

[0157] [Embodiment 14] In Embodiment 2, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d of compounds.

[0158] [Embodiment 15] In Embodiment 3, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d of compounds.

[0159] [Embodiment 16] In Embodiment 4, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d of compounds.

[0160] [Embodiment 17] In Embodiment 5, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A5 is a nitrogen atom or CR 4d of compounds.

[0161] [Embodiment 18] In Embodiment 6, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d of compounds.

[0162] [Embodiment 19] In Embodiment 7, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d of compounds.

[0163] [Embodiment 20] In Embodiment 8, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d of compounds.

[0164] [Embodiment 21] In Embodiment 1, Het is a group represented by the formula Het4 or a group represented by the formula Het5, and W 2 A compound containing oxygen atoms.

[0165] [Embodiment 22] In Embodiment 2, Het is a group represented by the formula Het4 or a group represented by the formula Het5, and W 2 A compound containing oxygen atoms.

[0166] [Embodiment 23] In Embodiment 3, Het is a group represented by the formula Het4 or a group represented by the formula Het5, and W 2 A compound containing oxygen atoms.

[0167] [Embodiment 24] In Embodiment 4, Het is a group represented by the formula Het4 or a group represented by the formula Het5, and W 2 A compound containing oxygen atoms.

[0168] [Embodiment 25] In Embodiment 5, Het is a group represented by the formula Het4 or a group represented by the formula Het5, and W 2 A compound containing oxygen atoms.

[0169] [Embodiment 26] In Embodiment 6, Het is a group represented by the formula Het4 or a group represented by the formula Het5, and W 2 A compound containing oxygen atoms.

[0170] [Embodiment 27] In Embodiment 7, Het is a group represented by the formula Het4 or a group represented by the formula Het5, and W 2 A compound containing oxygen atoms.

[0171] [Embodiment 28] In Embodiment 8, Het is a group represented by the formula Het4 or a group represented by the formula Het5, and W 2 A compound containing oxygen atoms.

[0172] [Embodiment 29] In Embodiment 1, Het is a group represented by the formula Het2 or a group represented by the formula Het3, and A 2 and A 6 is an oxygen atom, R 6a A compound containing hydrogen atoms.

[0173] [Embodiment 30] In Embodiment 2, Het is a group represented by the formula Het2 or a group represented by the formula Het3, and A 2 and A 6 is an oxygen atom, R 6a A compound containing hydrogen atoms.

[0174] [Embodiment 31] In Embodiment 3, Het is a group represented by the formula Het2 or a group represented by the formula Het3, and A 2 and A 6 is an oxygen atom, R 6a A compound containing hydrogen atoms.

[0175] [Embodiment 32] In Embodiment 4, Het is a group represented by the formula Het2 or a group represented by the formula Het3, and A 2 and A 6 is an oxygen atom, R 6a A compound containing hydrogen atoms.

[0176] [Embodiment 33] In Embodiment 5, Het is a group represented by the formula Het2 or a group represented by the formula Het3, and A 2 and A 6 is an oxygen atom, R 6a A compound containing hydrogen atoms.

[0177] [Embodiment 34] In Embodiment 6, Het is a group represented by formula Het2 or a group represented by formula Het3, and A 2 and A 6 is an oxygen atom, R 6a A compound containing hydrogen atoms.

[0178] [Embodiment 35] In Embodiment 7, Het is a group represented by formula Het2 or a group represented by formula Het3, and A 2 and A 6 is an oxygen atom, R 6a A compound containing hydrogen atoms.

[0179] [Embodiment 36] In Embodiment 8, Het is a group represented by the formula Het2 or a group represented by the formula Het3, and A 2 and A 6 is an oxygen atom, R 6a A compound containing hydrogen atoms.

[0180] [Embodiment 37] In Embodiment 1, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d , R 4b 、R 4c and R 4d A compound containing hydrogen atoms.

[0181] [Embodiment 38] In Embodiment 2, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d , R 4b 、R 4c and R 4d A compound containing hydrogen atoms.

[0182] [Embodiment 39] In Embodiment 3, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d , R 4b 、R 4c and R 4d A compound containing hydrogen atoms.

[0183] [Embodiment 40] In Embodiment 4, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d , R 4b、R 4c and R 4d A compound containing hydrogen atoms.

[0184] [Embodiment 41] In Embodiment 5, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d , R 4b 、R 4c and R 4d A compound containing hydrogen atoms.

[0185] [Embodiment 42] In Embodiment 6, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d , R 4b 、R 4c and R 4d A compound containing hydrogen atoms.

[0186] [Embodiment 43] In Embodiment 7, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d , R 4b 、R 4c and R 4d A compound containing hydrogen atoms.

[0187] [Embodiment 44] In Embodiment 8, Het is a group represented by the formula Het1, and A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d , R 4b 、R 4c and R 4d A compound containing hydrogen atoms.

[0188] [Embodiment 45] In the compound N of the present invention, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0189] [Embodiment 46] In the compound N of the present invention, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0190] [Method 47] In method 13, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0191] [Method 48] In method 14, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0192] [Method 49] In method 15, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0193] [Method 50] In method 16, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0194] [Method 51] In method 17, R 2a and R 2bare the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0195] [Method 52] In method 18, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0196] [Method 53] In method 19, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0197] [Method 54] In method 20, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0198] [Method 55] In method 21, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0199] [Method 56] In method 22, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2aand R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0200] [Method 57] In method 23, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0201] [Method 58] In method 24, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0202] [Method 59] In method 25, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0203] [Method 60] In method 26, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0204] [Method 61] In method 27, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0205] [Method 62] In method 28, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0206] [Method 63] In method 29, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0207] [Method 64] In method 30, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0208] [Method 65] In method 31, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0209] [Method 66] In method 32, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0210] [Method 67] In method 33, R 2a and R 2bare the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0211] [Method 68] In method 34, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0212] [Method 69] In method 35, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0213] [Method 70] In method 36, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0214] [Method 71] In method 37, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0215] [Method 72] In method 38, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2aand R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0216] [Method 73] In method 39, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0217] [Method 74] In method 40, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0218] [Method 75] In method 41, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0219] [Method 76] In method 42, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0220] [Method 77] In method 43, R 2a and R 2b are the same or different from each other and are C1-C6 alkyl which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0221] [Method 78] In method 44, R 2a and R 2b is a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atom to which they are bonded, they form a pyrrolidinyl or piperidinyl compound.

[0222] [Method 79] In Method 13, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0223] [Method 80] In method 14, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0224] [Method 81] In method 15, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0225] [Method 82] In method 16, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0226] [Method 83] In method 17, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0227] [Method 84] In method 18, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0228] [Method 85] In method 19, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0229] [Method 86] In method 20, R 2a and R 2bCompounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0230] [Method 87] In method 21, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0231] [Method 88] In method 22, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0232] [Method 89] In method 23, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0233] [Method 90] In method 24, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0234] [Method 91] In method 25, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0235] [Method 92] In method 26, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0236] [Method 93] In method 27, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0237] [Method 94] In method 28, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0238] [Method 95] In method 29, R 2a and R 2bCompounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0239] [Method 96] In method 30, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0240] [Method 97] In method 31, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0241] [Method 98] In method 32, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0242] [Method 99] In method 33, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0243] [Method 100] In method 34, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0244] [Method 101] In method 35, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0245] [Method 102] In method 36, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0246] [Method 103] In method 37, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0247] [Method 104] In method 38, R 2a and R 2bCompounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0248] [Method 105] In method 39, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0249] [Method 106] In method 40, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0250] [Method 107] In method 41, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0251] [Method 108] In method 42, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0252] [Method 109] In method 43, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0253] [Method 110] In method 44, R 2a and R 2b Compounds which are the same or different and are C1-C6 alkyl groups which may be substituted with one or more halogen atoms, or hydrogen atoms.

[0254] [Embodiment 111] In any of Embodiments 1 to 110 or Compound N of the present invention, T is a group represented by Formula T-1, and X 1 CR 1a , X 3 CR 1c , X 4 is a nitrogen atom or CR 1d , X 5 is a nitrogen atom or CR 1e , R 1a 、R 1c and R 1e is a hydrogen atom, R 1d is a C1-C6 chain hydrocarbon group or a halogen atom which may be substituted by one or more halogen atoms, R 1xis a C1-C5 chain hydrocarbon group substituted by one or more halogen atoms, OR 7 、OS(O)2R 7 、S(O) m R 7 NR 8 S(O)2R 7 or halogen atoms.

[0255] [Embodiment 112] In any of Embodiments 1 to 110 or Compound N of the present invention, T is a C1-C10 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, or OR 1 , R 1 A compound which is a C1-C10 chain hydrocarbon group substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C7 cycloalkyl group substituted by one or more substituents selected from group G, or a (C3-C7 cycloalkyl)C1-C3 alkyl group substituted by one or more substituents selected from group G.

[0256] [Embodiment 113] In any of Embodiments 1 to 110 or Compound N of the present invention, T is a group represented by Formula T-8, and Y 2 is a nitrogen atom or CR 26 , Y 3 CR 27 , Y 4 is a nitrogen atom or CR 28 , R 1y A compound which is a C1-C5 chain hydrocarbon group, a cyano group or a halogen atom substituted with one or more halogen atoms.

[0257] [Embodiment 114] In any of Embodiments 1 to 110 or the compound N of the present invention, T is OR 1 , R 1 A compound comprising a C1-C10 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom.

[0258] Next, the method for producing the compound of the present invention will be described.

[0259] Manufacturing method 1

[0260] The compound represented by formula (I) (compound N of the present invention) can be produced by reacting a compound represented by formula (M-1) (hereinafter referred to as compound (M-1)) with a compound represented by formula (M-2) (hereinafter referred to as compound (M-2)).

[0261] [Chemical Formula 9]

[0262]

[0263] [In the formula, the symbols have the same meanings as above.]

[0264] The reaction is usually carried out in a solvent. Examples of the solvent include ethers (hereinafter referred to as ethers) such as tetrahydrofuran (hereinafter referred to as THF), 1,4-dioxane, 1,2-dimethoxyethane (hereinafter referred to as DME), methyl tert-butyl ether (hereinafter referred to as MTBE), and diethyl ether; halogenated hydrocarbons (hereinafter referred to as halogenated hydrocarbons) such as dichloromethane and chloroform; aromatic hydrocarbons (hereinafter referred to as aromatic hydrocarbons) such as toluene and xylene; nitriles (hereinafter referred to as nitriles) such as acetonitrile; water; and mixtures of two or more thereof.

[0265] In the reaction, the compound (M-2) is usually used in a ratio of 0.8 to 10 mol based on 1 mol of the compound (M-1).

[0266] The reaction can be carried out by mixing compound (M-1) and compound (M-2). The reaction can also be carried out in the presence of a base as needed. Examples of the base include alkali metal carbonates such as sodium carbonate and potassium carbonate (hereinafter referred to as alkali metal carbonates); tertiary amines such as triethylamine (hereinafter referred to as tertiary amines); and nitrogen-containing aromatic compounds such as pyridine (hereinafter referred to as nitrogen-containing aromatic compounds). When a base is used in the reaction, the base is usually used in a ratio of 1 to 3 moles relative to 1 mole of compound (M-1).

[0267] The reaction temperature is usually within the range of -20 to 200° C. The reaction time is usually within the range of 0.1 to 24 hours.

[0268] After the reaction is completed, water may be poured into the reaction mixture, followed by extraction with an organic solvent, and post-treatment operations such as drying and concentration of the organic layer may be performed to obtain the compound N of the present invention.

[0269] Compound (M-2) is a commercially available compound or can be produced by a known method.

[0270] Manufacturing method 2

[0271] The compound represented by formula (Ib) (compound N of the present invention) can be produced by reacting a compound represented by formula (M-6) (hereinafter referred to as compound (M-6)) with compound (M-5) in the presence of a metal catalyst.

[0272] [Chemical Formula 10]

[0273]

[0274] [wherein, M represents 9-boranobicyclo[3.3.1]nonane-9-yl, dihydroxyboronyl, 4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl, tributylstannyl or ZnCl, Xa represents a chlorine atom, a bromine atom or an iodine atom, and other symbols have the same meanings as above.

[0275] The reaction is usually carried out in a solvent. Examples of the solvent include ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures of two or more thereof.

[0276] Examples of the metal catalyst used in the reaction include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), 1,1'-bis(diphenylphosphino)ferrocenepalladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(0), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; iron catalysts such as iron(III) chloride and iron(III) acetylacetonate; and copper catalysts such as copper(I) iodide and copper(I) chloride.

[0277] During the reaction, a ligand, a base and / or an inorganic halide may be added as needed.

[0278] Examples of the ligand used in the reaction include triphenylphosphine, Xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline.

[0279] Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases.

[0280] Examples of the inorganic halide used in the reaction include alkali metal fluorides such as potassium fluoride and sodium fluoride; and alkali metal chlorides such as lithium chloride and sodium chloride.

[0281] In the reaction, compound (M-5) is usually used in a ratio of 1 to 10 moles, the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles, the ligand is usually used in a ratio of 0.01 to 1 mole, the base is usually used in a ratio of 0.1 to 5 moles, and the inorganic halide is usually used in a ratio of 0.1 to 5 moles, relative to 1 mole of compound (M-6).

[0282] The reaction temperature is usually within a range of -20°C to 200°C. The reaction time is usually within a range of 0.1 to 24 hours.

[0283] After the reaction is completed, water may be added to the reaction mixture, followed by extraction with an organic solvent, and post-treatment operations such as drying and concentration of the organic layer may be performed to obtain the compound represented by formula (Ib).

[0284] Compound (M-6) is known or can be produced according to the method described in, for example, International Publication No. 2018 / 221720.

[0285] Reference manufacturing method 1

[0286] Compound (M-1) can be produced by reacting a compound represented by formula (M-7) (hereinafter referred to as compound (M-7)) with a chlorinating agent in the presence of chlorosulfonic acid.

[0287] [Chemical Formula 11]

[0288]

[0289] [In the formula, the symbols have the same meanings as above.]

[0290] The reaction can be carried out in a solvent as needed. Examples of the solvent used in the reaction include ethers, aromatic hydrocarbons, aromatic hydrocarbons, and mixtures of two or more thereof.

[0291] Examples of the chlorinating agent used in the reaction include phosphorus oxychloride and thionyl chloride.

[0292] In the reaction, chlorosulfonic acid is usually used in a ratio of 1 to 10 mol, and the chlorinating agent is usually used in a ratio of 1 to 10 mol, based on 1 mol of compound (M-7).

[0293] The reaction temperature is usually within a range of -20°C to 200°C. The reaction time is usually within a range of 0.1 to 24 hours.

[0294] After the reaction is completed, water is added to the reaction mixture, extraction is carried out with an organic solvent, and post-treatment operations such as drying and concentration of the organic layer can be performed to obtain compound (M-1).

[0295] Compound (M-7) is known or can be produced according to the method described in, for example, International Publication No. 2015 / 163478, International Publication No. 2016 / 052455, International Publication No. 2016 / 121969, International Publication No. 2017 / 069105, International Publication No. 2017 / 065228, International Publication No. 2017 / 077911, International Publication No. 2016 / 121970, International Publication No. 2017 / 164108, International Publication No. 2017 / 150209, International Publication No. 2017 / 169894, International Publication No. 2018 / 052119, International Publication No. 2018 / 101424 or International Publication No. 2019 / 189731.

[0296] Reference Manufacturing Method 2

[0297] The compound represented by formula (M-9) (hereinafter referred to as compound (M-9)) can be produced by reacting the compound represented by formula (M-8) (hereinafter referred to as compound (M-8)) with a chlorinating agent in the presence of chlorosulfonic acid.

[0298] [Chemical Formula 12]

[0299]

[0300] [In the formula, the symbols have the same meanings as above.]

[0301] The reaction can be carried out according to the method described in Reference Production Method 1, using Compound (M-8) instead of Compound (M-7).

[0302] Compound (M-8) is a commercially available compound or can be produced by a known method.

[0303] Reference Manufacturing Method 3

[0304] Compound (M-5) can be produced by reacting compound (M-9) with compound (M-2).

[0305] [Chemical Formula 13]

[0306]

[0307] [In the formula, the symbols have the same meanings as above.]

[0308] The reaction can be carried out according to the method described in Production Method 1, using Compound (M-9) instead of Compound (M-1).

[0309] The compound of the present invention may be mixed or used in combination with one or more components (hereinafter referred to as present components) selected from the following group consisting of Group (a), Group (b), Group (c) and Group (d).

[0310] The aforementioned mixed use or combined use means that the compound of the present invention and the present component are used simultaneously, separately, or with a time interval therebetween.

[0311] When the compound of the present invention and the present component are used simultaneously, the compound of the present invention and the present component may be contained in separate preparations or in the same preparation.

[0312] One aspect of the present invention is a composition (hereinafter referred to as composition A) comprising one or more components selected from the group consisting of group (a), group (b), group (c), and group (d) (i.e., the present component) and the compound of the present invention.

[0313] Group (a) is composed of acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphate insecticides), GABA-gated chloride channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamate-gated chloride channel allosteric modulators (e.g., macrolide insecticides), juvenile hormone mimics, multisite inhibitors, chord organ TRPV channel modulators, mite growth inhibitors, and insect midgut lining disruption agents derived from microorganisms. The present invention relates to a group consisting of: a group consisting of: inhibitors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin-based insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, inhibitors of mitochondrial electron transport chain complexes I, II, III, and IV, voltage-dependent sodium channel blockers, acetyl-CoA carboxylase inhibitors, ranolidine receptor modulators (e.g., diamide-based insecticides), chord organ modulators, microbial insecticides, and other insecticidal active ingredients, acaricidal active ingredients, and nematicidal active ingredients. These ingredients are described according to the classification based on the IRAC mechanism of action.

[0314] Group (b) includes nucleic acid synthesis inhibitors (e.g., phenylamide-based fungicides, acylamino acid-based fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiration inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid synthesis and protein synthesis inhibitors (e.g., anilinopyridine-based fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., triazole-based DMI fungicides), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multi-site contact-active fungicides, microbial fungicides, and other fungicidal active ingredients. These ingredients are described according to the FRAC-based mechanism of action.

[0315] Group (c) is a group of plant growth regulating ingredients (including mycorrhizal fungi and rhizobia).

[0316] Group (d) is a group of repellent ingredients.

[0317] Examples of combinations of this component and the compound of the present invention are described below. For example, alanycarb+SX refers to a combination of alanycarb and SX.

[0318] It should be noted that the abbreviation SX refers to any one compound of the present invention selected from the compound group SX1 to SX928. In addition, the ingredients described below are all known ingredients and can be obtained from commercially available preparations or manufactured by known methods. If the ingredient is a microorganism, it can also be obtained from a bacterial collection institution. It should be noted that the numbers in parentheses represent CAS RN (registered trademark).

[0319] Combination of the present component of the above group (a) with the compound of the present invention:

[0320] Abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetoprole + SX, acrinathrin + SX, acynonapyr + SX, afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha-endosulfan + SX, aluminum phosphide phosphide)+SX, amitraz+SX, azadirachtin+SX, azamethiphos+SX, azinphos-ethyl+SX, azinphos-methyl+SX, azocyclotin+SX, bark of Celastrus angulatus)+SX, bendiocarb+SX, benfluthrin+SX, benfuracarb+SX, bensultap+SX, benzoximate+SX, benzpyrimoxan+SX, beta-cyfluthrin+SX, beta-cypermethrin+SX, bifenazate+SX, bifenthrin+SX, bioallethrin+SX, bioresmethrin+SX, bistrifluron+SX, borax+SX, boric acid acid)+SX, broflanilide+SX, bromopropylate+SX, buprofezin+SX, butocarboxim+SX, butoxycarboxim+SX, cadusafos+SX, calcium phosphidephosphide)+SX, carbaryl+SX, carbofuran+SX, carbosulfan+SX, cartap hydrochloride hydrochloride) + SX, cartap + SX, chinomethionat + SX, chlorantraniliprole + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr + SX, chlorfenvinphos + SX, chlorfluazuron + SX, chlormephos + SX, chloropicrin + SX, chlorpyrifos + SX, chlorpyrifos-methyl + SX, chromafenozide + SX, clofentezine + SX, clothianidin + SX, concanamycin AA) + SX, coumaphos + SX, cryolite + SX, cyanophos + SX, cyantraniliprole + SX, cyclaniliprole + SX, cyclobutrifluram + SX, cycloprothrin + SX, cycloxaprid + SX, cyenopyrafen + SX, cyetpyrafen + SX, cyflumetofen + SX, cyfluthrin + SX, cyhalodiamide + SX, cyhalothrin + SX, cyhexatin + SX, cypermethrin + SX, cyphenothrin + SX, cyproflumizone + SX, flanilide + SX, cyromazine + SX, dazomet + SX, deltamethrin + SX, demeton-S-methyl + SX, diafenthiuron + SX, diazinon + SX, dichlorvos + SX, dichloromezotiaz + SX, dicofol + SX, dicrotophos + SX, diflovidazin + SX, diflubenzuron + SX, dimefluthrin + SX, dimethoate + SX, dimethylvinphos + SX, dimpropyridaz + SX, dinotefuran + SX, disodium octaborate octaborate)+SX, disulfoton+SX, DNOC(2-methyl-4,6-dinitrophenol+SX, doramectin+SX, dried leaves of Dryopterisfilix-mas)+SX, emamectin-benzoate+SX, empenthrin+SX, endosulfan+SX, EPN(O-ethyl O-(4-nitrophenyl)phenylphosphonothioate)+SX, epsilon-metofluthrin+SX, epsilon-momfluorothrin+SX, esfenvalerate+SX, ethiofencarb+SX, ethion+SX, ethiprole+SX, ethoprophos+SX, etofenprox+SX, etoxazole+SX, extract of Artemisia absinthium+SX, extract of neem Azadirachta indica extract + SX, Cassia nigricans extract + SX, butterfly pea extract + SX, Symphytum officinale extract + SX, Chenopodium ambrosioides extract + SX, Tanacetum vulgare extract + SX, Urtica dioica extract + SX, Viscum album extract + SX, famphur + SX, fenamiphos + SX, fenazaquin + SX, fenbutatinoxide)+SX, fenitrothion+SX, fenmezoditiaz+SX, fenobucarb+SX, fenoxycarb+SX, fenpropathrin+SX, fenpyroximate+SX, fenthion+SX, fenvalerate+SX, fipronil+SX, flometoquin+SX, flonicamid+SX, fluacrypyrim+SX, fluazaindolizine+SX, fluazuron+SX, flubendiamide+SX, fluchlordiniliprole+SX, flucycloxuron+SX, flucythrinate+SX, Fluensulfone + SX, flufenoprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flupentiofenox + SX, flupyradifurone + SX, flupyrimin + SX, flupyroxystrobin + SX, fluralaner + SX, fluvalinate + SX, fluxametamide + SX, formetanate + SX, fosthiazate + SX, furamethrin + SX, furathiocarb + SX, gamma-cyhalothrin + SX, GS-omega / kappa HXTX-Hv1a peptide (GS-omega / kappa HXTX-Hv1a peptide) + SX, halfenprox + SX, halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox + SX, potassium salt of hop beta acidacid)+SX, hydramethylnon+SX, hydroprene+SX, imicyafos+SX, imidacloprid+SX, imidaclothiz+SX, imiprothrin+SX, indazapyroxamet+SX, indoxacarb+SX, isocycloseram+SX, isofenphos+SX, isoprocarb+SX, isopropyl-O-(methoxyaminothiophosphoryl) salicylate thoxyaminothiophosphoryl)salicylate)+SX, isoxathion+SX, ivermectin+SX, kadethrin+SX, kappa-tefluthrin+SX, kappa-bifenthrin+SX, kinoprene+SX, lambda-cyhalothrin+SX, ledprona+SX, lenoremycin+SX, lepimectin+SX, lime sulfur sulfur)+SX, lotilaner+SX, lufenuron+SX, machine oil+SX, malathion+SX, mecarbam+SX, meperfluthrin+SX, metaflumizone+SX, metam+SX, methamidophos+SX, methidathion+SX, methiocarb+SX, methomyl+SX, methoprene+SX, methoxychlor+SX, methoxyfenozide+SX, methyl bromide bromide + SX, metofluthrin + SX, metolcarb + SX, metoxadiazone + SX, mevinphos + SX, milbemectin + SX, milbemycinoxime+SX, mivorilaner+SX, modoflaner+SX, momfluorothrin+SX, monocrotophos+SX, moxidectin+SX, naled+SX, nicofluprole+SX, nicotine+SX, nicotine-sulfate+SX, nitenpyram+SX, novaluron+SX, noviflumuron+SX, Chenopodium anthelminticum seed oil (oil of the seeds of Chenopodium anthelminticum)+SX, omethoate+SX, oxamyl+SX, oxazosulfyl+SX, oxydemeton-methyl+SX, parathion+SX, parathion-methyl+SX, permethrin+SX, phenothrin+SX, phenthoate+SX, phorate+SX, phosalone+SX, phosmet et)+SX, phosphamidon+SX, phosphine+SX, phoxim+SX, pirimicarb+SX, pirimiphos-methyl+SX, prallethrin+SX, profenofos+SX, profluthrin+SX, propargite+SX, propetamphos+SX, propoxur+SX, propylene glycol alginateglycolalginate)+SX, prothiofos+SX, pyflubumide+SX, pymetrozine+SX, pyraclofos+SX, pyrethrins+SX, pyridaben+SX, pyridalyl+SX, pyridaphenthion+SX, pyrifluquinazone+SX, pyrimidifen+SX, pyri minostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinalphos + SX, resmethrin + SX, rotenone + SX, ryanodine + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate borate + SX, sodium metaborate + SX, spidoxamat + SX, spinetoram + SX, spinosad + SX, spirobudifen + SX, spirodiclofen + SX, spiromesifen + SX, spiropidion + SX, spirotetramat + SX, sulfiflumin + SX, sulfluramid + SX, sulfotep + SX, sulfoxaflor + SX, sulfur + SX, sulfurylfluoride + SX, tartar emetic emetic)+SX, tau-fluvalinate+SX, tebufenozide+SX, tebufenpyrad+SX, tebupirimfos+SX, teflubenzuron+SX, tefluthrin+SX, temephos+SX, terbufos+SX, terpene components extracted from wormwoodThe constituents of the extract ofchenopodium ambrosioides near ambrosioides+SX、tetrachlorantraniliprole+SX、tetrachlorvinphos+SX、tetradifon+SX、tetramethrin+SX、tetramethylfluthrin+SX、tetraniliprole+SX、theta-cypermethrin+SX、thiacloprid+SX、thiamethoxam+SX、thiocyclam+SX、thiodicarb+SX、thiofanox+SX、thiometon+SX、thiosultap-disodium+SX、thiosultap-sodium ultap-monosodium+SX, tigolaner+SX, tiorantraniliprole+SX, tioxazafen+SX, tolfenpyrad+SX, tralomethrin+SX, transfluthrin+SX, triazamate+SX, triazophos+SX, trichlorfon+SX, trifluenfuronate+SX, triflumezopyrim+SX, triflumuron+SX, trimethacarb+SX, tyclopyrazoflor+SX, umifoxolaner+SX, vamidothion+SX, wood extract of Quassia chinensis extract of Quassia amara)+SX, XMC (3,5-dimethylphenyl N-methylcarbamate)+SX, xylylcarb+SX, zeta-cypermethrin+SX, zinc phosphidephosphide) + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietane-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methyl sulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methylsulfonyl)propionamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methylsulfonyl)propionamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09- 3) + SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylsulfanyl)-2-methylpropane-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfinyl)-2-methylpropane-2-yl]-2 -(pyridin-3-yl)-2H-indazole-4-carboxamide+SX, 7-fluoro-N-[1-(methylsulfonyl)-2-methylpropane-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide+SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide+SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one(2607927-97-7)+SX, BT crop protein Cry1Ab(BT crop protein Cry1Ab)+SX, BT crop protein Cry1Ac(BT crop protein Cry1Ac)+SX, BT crop protein Cry1Fa(BT crop105)+SX, BT crop protein Cry1A.105+SX, BT crop protein Cry2Ab+SX, BT crop protein Vip3A+SX, BT crop protein mCry3A+SX, BT crop protein Cry3Ab+SX, BT crop protein Cry3Ab+SX, BT crop protein Cry3Bb+SX, BT crop protein Cry3Bb+SX, BT crop protein Cry34Ab1 / Cry35Ab1+SX, Adoxophyes orana GV(granulovirus)strain BV-0001+SX, Anticarsia gemmatalis nuclear polyhedrosis virus MNPV (multiple nucleocapsid nucleopolyhedrovirus))+SX, Autographa californica MNPV+SX, Cydia pomonella GV strain V15+SX, Cydia pomonella GV strain V22+SX, Cryptophlebia leucotreta GV+SX, Dendrolimus punctatus cypovirus+SX, Helicoverpa armigera NPV (nucleopolyhedrovirus) strain BV-0003+SX, Helicoverpa zea mays NPV+SX NPV)+SX, Lymantria dispar NPV+SX, Mamestra brassicae NPV+SX, Mamestra configurata NPV+SX, Neodiprion abietis NPV+SX,SX, Neodiprion lecontei NPV+SX, Neodiprion lecontei NPV+SX, Neodiprion sertifer NPV+SX, Nosema locustae+SX, Orgyia pseudotsugata NPV+SX, Pieris rapae GV+SX, Plodia interpunctella GV+SX, Spodoptera exigua MNPV+SX, Spodoptera littoralis MNPV+SX, Spodoptera litura NPV+SX, NPV)+SX, Arthrobotrysdactyloides+SX, Bacillus firmus strain GB-126+SX, Bacillus firmus strain I-1582+SX, Bacillus firmus strain NCIM2637+SX, Bacillus megaterium+SX, Bacillus sp. strain AQ175+SX, Bacillus sp. strain AQ177+SX, Bacillus sp. strain AQ178+SX, Bacillus sphaericus strain 2362 serotype H5a5b 2362serotypeH5a5b)+SX, Bacillus sphaericus strain ABTS1743+SX, Bacillus thuringiensis strain AQ52+SX, Bacillus thuringiensis strain BD#32+SX, Bacillus thuringiensis strain CR-371+SX,CR-371)+SX, Bacillus thuringiensis subsp. Aizawai strain ABTS-1857+SX, Bacillus thuringiensis subsp. Aizawai strain AM65-52+SX, Bacillus thuringiensis subsp. Aizawai strain GC-91+SX, Bacillus thuringiensis subsp. Aizawai strain GC-91+SX, Bacillus thuringiensis subsp. Aizawai strain NB200+SX, Bacillus thuringiensis subsp. Aizawai Serotype H-7+SX H-7)+SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351+SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123+SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306+SX, Bacillus thuringiensis subsp. Kurstaki strain EG2348+SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841+SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841)+SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19+SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19+SX, Bacillus thuringiensis subsp. Kurstaki strain F810+SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1+SX,strain HD-1)+SX, Bacillus thuringiensis subsp. Kurstaki strain PB54+SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11+SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12+SX, Bacillus thuringiensis subsp. Tenebriosis strain NB176+SX, Bacillus thuringiensis subsp. Tenebriosis strain NB176+SX, Bacillus thuringiensis subsp. Thuringiensis strain MPPL002+SX, Bacillus thuringiensis subsp. Morrison strain subsp.morrisoni)+SX, Bacillus thuringiensis var.colmeri+SX, Bacillus thuringiensis var.darmstadiensis strain 24-91+SX, Bacillus thuringiensis var.dendrolimus+SX, Bacillus thuringiensis var.galleriae+SX, Bacillus thuringiensis var.israelensis strain BMP144+SX, Bacillus thuringiensis var.israelensis serotype H-14+SX H-14)+SX, Bacillus thuringiensis var.japonensis strainbuibui)+SX, Bacillus thuringiensis var.sandiego strain M-7M-7)+SX, Bacillus thuringiensis var.7216+SX, Bacillus thuringiensis var.aegypti+SX, Bacillus thuringiensis var.T36+SX, Beauveria bassiana strain ANT-03+SX, Beauveria bassiana strain ATCC74040+SX, Beauveria bassiana strain GHA+SX, Beauveria brongniartii+SX, new heat-killed bacteria A396 strain (Burkholderia rinojensis strain A396)+SX, Chromobacterium subtsugae strain PRAA4-1T+SX, Dactyllela ellipsospora+SX, Dectylaria thaumasia+SX, Hirsutella minnesotensis+SX, Hirsutella rhossiliensis+SX, Hirsutella thompsonii+SX, Lagenidium giganteum+SX, Lecanicillium lecanii strain KV01+SX, Lecanicillium lecanii conidia of strain DAOM198499+SX, Lecanicillium lecanii conidia of strain DAOM198499+SX, Lecanicillium lecanii conidia of strain DAOM216596+SX, conidia of strain DAOM216596)+SX, Lecanicillium muscarium strain Ve6+SX, Metarhizium anisopliae strain F52+SX, Metarhizium anisopliae var. acridum+SX, Metarhizium anisopliae var. microsporum BIPESCO5 / F52 strain (Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52) + SX, Metarhizium flavoviride + SX, Monacrosporium phymatopagum + SX, Paecilomyces fumosoroseus Apopka strain 97 + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain T1 + SX, Paenibacillus popilliae + SX, Pasteuria nishizawae strain Pn1 + SX, Pasteuria penetrans + SX, Pasteuria usgae+SX, Pasteuria thornei+SX, Serratia entomophila+SX, Verticillium chlamydosporium+SX, Verticillium lecani strain NCIM1312+SX, Wolbachia pipientis+SX.

[0321] Combination of the present component of the above group (b) with the compound of the present invention:

[0322] Acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, azaconazole + SX, azoxystrobin + SX, basic copper sulfate sulfate)+SX, benalaxyl+SX, benalaxyl-M+SX, benodanil+SX, benomyl+SX, benthiavalicarb+SX, bethiavalicarb-isopropyl+SX, benzovindiflupyr+SX, binapacryl+SX, biphenyl+SX, bitertanol+SX, bixafen+SX, blasticidin-S+SX, Bordeaux mixture mixture)+SX, boscalid+SX, bromothalonil+SX, bromuconazole+SX, bupirimate+SX, captafol+SX, captan+SX, carbendazim+SX, carboxin+SX, carpropamid+SX, chinomethionat+SX, chitin+SX, chloroinconazide+SX, chloroneb+SX, chlorothalonil+SX, chlozolinate+SX, colletochlorin B+SX, copper(II) acetate+SX, copper(II) hydroxide+SX, copperoxychloride+SX, copper(II) sulfate+SX, coumoxystrobin+SX, cyazofamid+SX, cyflufenamid+SX,Cymoxanil + SX, cyproconazole + SX, cyprodinil + SX, dichlobentiazox + SX, dichlofluanid + SX, diclocymet + SX, diclomezine + SX, dicloran + SX, diethofencarb + SX, difenoconazole + SX, diflumetorim + SX, dimethachlone + SX X, dimethirimol + SX, dimethomorph + SX, dimoxystrobin + SX, diniconazole + SX, diniconazole-M + SX, dinocap + SX, dipotassium hydrogenphosphite + SX, dipymetitrone + SX, dithianon + SX, dodecylbenzenesulphonic acid bis(ethylenediamine)copper(II) complex salt acid bisethylenediamine copper(II) salt)+SX, dodemorph+SX, dodine+SX, edifenphos+SX, enoxastrobin+SX, epoxiconazole+SX, etaconazole+SX, ethaboxam+SX, ethirimol+SX, etridiazole+SX, garlic extract+SX, extract of the cotyledons of lupine plantlets ("BLAD")+SX, extract of Equisetum arvense+SX, extract of Melaleuca alternifolia+SX, extract of Reynoutria sachalinensis+SX, extract of Nasturtium officinale+SX Tropaeolum majus)+SX,Famoxadone + SX, fenamidone + SX, fenaminstrobin + SX, fenarimol + SX, fenbuconazole + SX, fenfuram + SX, fenhexamid + SX, fenoxanil + SX, fenpiclonil + SX, fenpicoxamid + SX, fenpropidin + SX, fenpropimorph + SX, fenpyrazamine + SX, fentin acetate + SX, fentin chloride + SX, and fentin hydroxide. hydroxide)+SX, ferbam+SX, ferimzone+SX, florylpicoxamid+SX, fluazinam+SX, flubeneteram+SX, fludioxonil+SX, flufenoxadiazam+SX, flufenoxystrobin+SX, fluindapyr+SX, flumetylsulforim+SX, flumorph+SX, fluopicolide+SX, fluopyram+SX, fluopimomide+SX, fluoroimide+SX, fluoxapiprolin+SX , fluoxastrobin + SX, fluoxytioconazole + SX, fluquinconazole + SX, flusilazole + SX, flusulfamide + SX, flutianil + SX, flutolanil + SX, flutriafol + SX, fluxapyroxad + SX, folpet + SX, fosetyl + SX, fosetyl-aluminium + SX, fuberidazole + SX, furaxyl + SX, furametpyr + SX, guazatine + SX,Hexaconazole + SX, hymexazole + SX, imazalil + SX, imibenconazole + SX, iminoctadine + SX, iminoctadine triacetate triacetate+SX, inpyrfluxam+SX, iodocarb+SX, ipconazole+SX, ipfentrifluconazole+SX, ipflufenoquin+SX, iprobenfos+SX, iprodione+SX, iprovalicarb+SX, isofetamid+SX, isofluxypram+SX, isoprethiolane+SX, isopyrazam+SX, isotianil+SX, kasugamycin+SX, kresoxim-methyl+SX, laminarin+SX, leaves and bark of oak ofQuercus)+SX, mancozeb+SX, mandestrobin+SX, mandipropamid+SX, maneb+SX, mefentrifluconazole+SX, mepanipyrim+SX, mepronil+SX, meptyldinocap+SX, metalaxyl+SX, metalaxyl-M+SX, metarylpicoxamid+SX, metconazole azole)+SX, methasulfocarb+SX, metiram+SX, metominostrobin+SX, metrafenone+SX, metyltetraprole+SX, myclobutanil+SX, naftifine+SX, nuarimol+SX, octhilinone+SX, ofurac+SX, orysastrobin+SX, oxadixyl+SX,Oxathiapiprolin + SX, oxine-copper + SX, oxolinic acid + SX, oxpoconazole + SX, oxpoconazole fumarate + SX, oxycarboxin + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, penflufen + SX, penthiopyrad + SX, phenamacril + SX, phosphorous acid acid + SX, phthalide + SX, picarbutrazox + SX, picoxystrobin + SX, piperalin + SX, polyoxins + SX, potassium hydrogencarbonate + SX, potassium dihydrogenphosphite + SX, probenazole + SX, prochloraz + SX, procymidone + SX, propamidine + SX, propamocarb + SX, propiconazole + SX, propineb + ​​SX, proquinazid + SX, prothiocarb + SX, prothioconazole + SX, pydiflumetofen + SX, pyraclostrobin + SX, pyrametostrobin + SX, pyraoxystrobin + SX, pyrapropoyne + SX, pyraziflumid + SX, pyrazophos + SX, pyribencarb + SX, pyributicarb + SX, pyridachlometyl + SX, pyrifenox + SX, pyrimethanil + SX, pyrimorph + SX,Pyriofenone + SX, pyrisoxazole + SX, pyroquilon + SX, Quillaja extract + SX, quinconazole + SX, quinofumelin + SX, quinoxyfen + SX, quintozene + SX, Saponins of Chenopodium quinoa + SX, seboctylamine + SX, sedaxane + SX, silthiofam + SX, simeconazole + SX, sodium bicarbonate hydrogencarbonate + SX, spiroxamine + SX, streptomycin + SX, sulfur + SX, tebuconazole + SX, tebufloquin + SX, teclofthalam + SX, tecnazene + SX, terbinafine + SX, tetraconazole + SX, thiabendazole + SX, thifluzamide + SX, thiophanate + SX, thiophanate-methyl + SX, thiram + SX, thymol + SX, tiadinil + SX , tolclofos-methyl + SX, tolfenpyrad + SX, tolprocarb + SX, tolylfluanid + SX, triadimefon + SX, triadimenol + SX, triazoxide + SX, triclopyricarb + SX, tricyclazole + SX, tridemorph + SX, trifloxystrobin + SX, triflumizole + SX, triforine + SX, triticonazole + SX, validamycin + SX, valifenalate + SX,Vinclozolin + SX, yellow mustard powder + SX, zinc thiazole + SX, zineb + ​​SX, ziram + SX, zoxamide + SX, N'-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylformamidine (1202781-91-6) + SX, N'-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylformamidine (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N N-ethyl-N-methylformamidine (1052688-31-9) + SX, N'-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylformamidine (2055589-28-9) + SX, N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylformamidine (2055756-21-1) + SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylformamidine (2062599-39-5) + SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl] 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, (2Z)-3-amino-2-cyano-3- Ethyl phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2) + SX,(1S,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol(1801930-07-3)+SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol(1394057-13-6)+SX, (1R,2S,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol(1801930-08-4)+SX, (1S, 2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-ol(1801930-09-5)+SX, 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate(1791398-02-1)+SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol(2019215-86-0)+SX, 1-(2,4- 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018316-13-5) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)- 1-(triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX, methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8) + SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX,2-(Difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(Difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) + SX, (2E,3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide -yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-54-3) + SX, 5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9) + SX, N-(1-benzyl-3,3,3-trifluoro-1-methylpropyl)-8-fluoroquinoline-3-carboxamide (2132414-00-5) + SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazole- 3-yl]phenyl}methyl)isoxazolin-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolin-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N,2-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N-acetyl-2-(ethylsulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-28-9)+SX,N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(4-bromo-7-fluoroindol-1-yl)butan-2-yl ester + SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(7-bromoindol-1-yl)butan-2-yl ester + SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl ester + SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl ester + SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]- L-alanine 3-(3,5-dichloropyridin-2-yl)butyl-2-yl ester + SX, N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alanine 3-(3,5-dichloropyridin-2-yl)butyl-2-yl ester + SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl ester N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate)+SX、N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate(1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl Ester((1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl Ester N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate) + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide + SX,3,3,3-Trifluoro-N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide+SX, 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide+SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide+SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butanamide+SX, N-methoxy-N-methyl-N'-({4-[5-(trifluoromethyl) )-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N,N-diethyl-N'-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N-methyl-N'-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one+SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one+SX, 4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea methyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1, 2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 5-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylic acid ethyl ester + SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX,N-methoxy-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide+SX, N-methoxy-N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide+SX, N,N-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine+SX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide+SX, 2-[2-chloro-4-(4-chlorophenoxy)benzamide 2-[(trifluoromethyl)-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propionic acid methyl ester + SX, 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propionic acid ethyl ester + SX, 2-[2-(trifluoromethyl)-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propionic acid methyl ester + SX, 1-(2,3-dimethylpyridin-5-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-[2-(difluoromethyl)-3-methylpyridin-5-yl]-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX , 2,2-difluoro-N-[6-({[1-(1-methyl-1H-tetrazol-5-yl)benzimidazol-2-yl]oxy}methyl)pyridin-2-yl]-2-phenoxyacetamide + SX, 1-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile + SX, 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolane-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylic acid ethyl ester + SX, 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylic acid ethyl ester + SX, 6-chloro- 3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX,2-[Cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[Cyano(2,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide + SX, 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methylpropanoyl)(2,6-difluoropyridin-4-yl) amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide+SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide+SX, 2-{[(oxetane-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide+SX, 2-{[(oxolan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide+SX, fluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine pyrimidine-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidine-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidine-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidine-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine + SX,3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, (5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, Pyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[ (E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, oxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide+SX, N-((2S)-1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide+SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide+SX,Methyl ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate+SX, Methyl ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate+SX, Methyl ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate+SX, -2-methylphenyl}methyl)carbamic acid methyl ester + SX, (Z)-2-(5-cyclopentyl-2-methylphenoxy)-3-methoxy-2-propenoic acid methyl ester + SX, (Z)-2-(5-cyclohexyl-2-methylphenoxy)-3-methoxy-2-propenoic acid methyl ester + SX, (Z)-2-[(3-isopropyl-1H-pyrazol-1-yl)-2-methylphenoxy]-3-methoxy-2-propenoic acid methyl ester Ester + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dihydroisoquinoline Methyl-3,4-dihydroisoquinoline + SX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinolin-4(3H)-one + SX, (2Z)-3-methoxy-2-[(4-methyl[1,1'-biphenyl]-3-yl)oxy]-2-propenoic acid methyl ester + SX, radioactive Agrobacterium K1026 strain (Agrobacterium radiobactor strain K1026) + SX, Agrobacterium radiobactor strain K84 + SX, Bacillus amyloliquefaciens strain PTA-4838 (Aveo (trademark) EZ Nematicide) + SX, Bacillus amyloliquefaciens strain AT332 + SX, Bacillus amyloliquefaciens strain B3 + SX, Bacillus amyloliquefaciens strain D747 + SX, Bacillus amyloliquefaciens strain DB101 + SX,Bacillus amyloliquefaciens strain DB102 + SX, Bacillus amyloliquefaciens strain GB03 + SX, Bacillus amyloliquefaciens strain FZB24 + SX, Bacillus amyloliquefaciens strain FZB42 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain MBI600 + SX, Bacillus amyloliquefaciens strain QST713 + SX, Bacillus amyloliquefaciens isolate B246 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain MBI600 + SX, Bacillus amyloliquefaciens strain QST713 + SX, Bacillus amyloliquefaciens isolate B246 + SX, Bacillus amyloliquefaciens strain Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens subsp. plantarum strain D747 + SX, Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus QST2808 + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus strain QST2808 + SX, Bacillus pumilus strain strain QST2808)+SX, Bacillus simplex strain CGF2856+SX,Bacillus subtilis strain AQ153 + SX, Bacillus subtilis strain AQ743 + SX, Bacillus subtilis strain BU1814 + SX, Bacillus subtilis strain D747 + SX, Bacillus subtilis strain DB101 + SX, Bacillus subtilis strain FZB24 + SX, Bacillus subtilis strain GB03 + SX, Bacillus subtilis strain HAI0404 + SX, Bacillus subtilis strain HAI0404)+SX, Bacillus subtilis strain IAB / BS03+SX, Bacillus subtilis strain MBI600+SX, Bacillus subtilis QST30002 / AQ30002+SX, Bacillus subtilis QST30004 / AQ30004+SX, Bacillus subtilis QST713+SX, Bacillus subtilis QST714+SX QST714)+SX, Bacillus subtilis var. Amyloliquefaciens strain FZB24+SX, Bacillus subtilis strain Y1336+SX, Burkholderia cepacia+SX, Burkholderia cepacia type Wisconsin strain J82+SX,Burkholderia cepacia type Wisconsin M54 + SX, Candida oleophila strain O + SX, Candida saitoana + SX, Chaetomium cupreum + SX, Clonostachys rosea + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON / M / 91-8 + SX, Cryptococcus albidus + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, CGE234M403)+SX, Fusarium oxysporum strain Fo47+SX, Gliocladium catenulatum strain J1446+SX, Paenibacillus polymyxa strain AC-1+SX, Paenibacillus polymyxa strain BS-0105+SX, Pantoea agglomerans strain E325+SX, Phlebiopsis gigantea strain VRA1992+SX, Pseudomonas aureofaciens strain TX-1+SX TX-1)+SX, Pseudomonas chlororaphis strain 63-28+SX, Pseudomonas chlororaphis strain AFS009+SX, Pseudomonas chlororaphis strain MA342+SX,Pseudomonas fluorescens strain 1629RS+SX, Pseudomonas fluorescens strain A506+SX, Pseudomonas fluorescens strain CL145A+SX, Pseudomonas fluorescens strain G7090+SX, Pseudomonas sp. strain CAB-02+SX, Pseudomonas syringae strain 742RS+SX, Pseudomonas syringae strain MA-4+SX, Pseudomonas flocculatus+SX PF-A22UL strain + SX, Pseudomonas rhodesia strain HAI-0804 + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Streptomyces griseoviridis strain K61 + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYEC108 + SX, Talaromyces flavus strain SAY-Y-94-01 + SX SAY-Y-94-01)+SX, Talaromyces flavus strain V117b+SX, Trichoderma asperellum strain ICC012+SX, Trichoderma asperellum SKT-1+SX, Trichoderma asperellum strain T25+SX,Trichoderma asperellum strain T34+SX, Trichoderma asperellum strain TV1+SX, Trichoderma atroviride strain CNCM 1-1237+SX, Trichoderma atroviridestrain LC52+SX, Trichoderma atroviridestrain IMI 206040+SX, Trichoderma atroviride strain SC1+SX, Trichoderma atroviride strain SKT-1+SX, Trichoderma atroviride strain T11+SX, Trichoderma gamsii endophytic fungus ICC080+SX strain ICC080)+SX, Trichoderma harzianum strain 21+SX, Trichoderma harzianum strain DB104+SX, Trichoderma harzianum strain DSM 14944+SX, Trichoderma harzianum strain ESALQ-1303+SX, Trichoderma harzianum strain ESALQ-1306+SX, Trichoderma harzianum strain IIHR-Th-2+SX, Trichoderma harzianum strain ITEM908+SX, Trichoderma harzianum kd+SX, Trichoderma harzianum strain ESALQ-1303+SX, Trichoderma harzianum strain ESALQ-1306+SX, Trichoderma harzianum strain IIHR-Th-2+SX, Trichoderma harzianum strain ITEM908+SX, Trichoderma harzianum kd+SX, Trichoderma harzianum strain ESALQ-1306+SX, Trichoderma harzianum strain IIHR-Th-2+SX, Trichoderma harzianum strain ITEM908+SX, Trichoderma harzianum kd+SX, Trichoderma harzianum strain ESALQ-1303+SX, Trichoderma harzianum strain ESALQ-1306+SX, Trichoderma harzianum strain IIHR-Th-2+SX, Trichoderma harzianum strain harzianum strain kd)+SX, Trichoderma harzianum strain MO1 (Trichoderma harzianum strain MO1)+SX, Trichoderma harzianum strain SF (Trichoderma harzianum strain SF)+SX,Trichoderma harzianum strain T22 + SX, Trichoderma harzianum strain T39 + SX, Trichoderma harzianum strain T78 + SX, Trichoderma harzianum strain TH35 + SX, Trichoderma polysporum strain IMI206039 + SX, Trichoderma astromaticum + SX, Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 + SX, Trichoderma viride + SX, Variovorax paradoxus strain CGF4526 CGF4526)+SX, Harpin protein+SX.

[0323] Combination of the present component of the above group (c) with the compound of the present invention:

[0324] 1-Methylcyclopropene+SX, 1,3-diphenylurea+SX, 2,3,5-triiodobenzoic acid+SX, IAA((1H-indol-3-yl)acetic acid)+SX, IBA(4-(1H-indol-3-yl)butyric acid)+SX, MCPA(2-(4-chloro-2-methylphenoxy)acetic acid)+SX, MCPB(4-(4-chloro-2-methylphenoxy)butyric acid)+SX, 4-CPA(4-chlorophenoxyacetic acid) acid + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat-chloride + SX, chlorpropham + SX, choline chloridechloride + SX, cloprop + SX, cyanamide + SX, cyclanilide + SX, daminozide + SX, decan-1-ol + SX, dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat + SX, ethephon + SX, ethychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, formononetin + SX, Gibberellin A A) + SX, Gibberellin A3 + SX, inabenfide + SX, Kinetin + SX, lipochitooligosaccharide SP104 + SX, maleic hydrazide + SX, mefluidide + SX, mepiquat-chloride + SX, oxidized glutathione + SX, paclobutrazol + SX, pendimethalin + SX, prohexadione-calcium + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, sintofen + SX, sodium 1-naphthaleneacetate + SX, sodium cyanate cyanate) + SX, thidiazuron + SX, triapenthenol + SX, tribufos + SX, trinexapac-ethyl + SX, uniconazole-P + SX, 2-(naphthalen-1-yl)acetamide + SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid + SX, 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylic acid methyl ester + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol + SX, Claroideoglomusetunicatum + SX, Claroideoglomus claroideum + SX, Funneliformis mosseae + SX, Gigaspora margarita + SX, Gigaspora rosea + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus monosporum + SX, Paraglomus brasillianum + SX, Rhizophagus clarus + SX, Rhizophagus intraradices RTI-801 + SX, Rhizophagus irregularis DAOM 197198 strain + SX, Azorhizobium caulinodans + SX, Azospirillum amazonense + SX, Azospirillum brasilense XOH strain + SX, Azospirillum brasilense Ab-V5 strain + SX, Azospirillum brasilense Ab-V6 strain + SX, Azospirillum caulinodans + SX, Azospirillumhalopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum + SX, Bradyrhizobium elkanii SEMIA 587 strain + SX, Bradyrhizobium elkanii SEMIA 5019 strain + SX, Bradyrhizobium japonicum TA-11 strain + SX, Bradyrhizobium USDA 110 strain + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Delftia acidovorans RAY209 strain + SX, Mesorhizobium ciceri + SX, Mesorhizobium huaguihuakii)+SX, Mesorhizobium loti+SX, Rhizobium etli+SX, Rhizobium galegae+SX, Rhizobium leguminosarum bv.Phaseoli+SX, Rhizobium leguminosarum bv.Trifolii+SX, Rhizobium leguminosarum bv.Viciae+SX, Rhizobium trifolii+SX, Rhizobium tropici+SX, Sinorhizobium fredii+SX, Sinorhizobium truncatula meliloti)+SX, Zucchini Yellow Mosaik Virus weak strain+SX.

[0325] Combination of the present component of the above group (d) with the compound of the present invention:

[0326] Anthraquinone + SX, DEET + SX, Icaridin + SX.

[0327] The ratio of the compound of the present invention to the present component is not particularly limited, and examples thereof include 1000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, and 1:50 in terms of weight ratio (compound of the present invention:present component).

[0328] The compound of the present invention is effective against harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful mollusks. Examples of harmful arthropods, harmful nematodes, and harmful mollusks include the following.

[0329] Hemiptera: Laodelphax striatellus, Nilaparvatalugens, Sogatella furcifera, Peregrinus maidis, Javesella pellucida, Perkinsiella saccharicida, Tagosodesorizicolus, Stenocranus pacificus, etc. Delphacidae; Nephotettix cincticeps, Nephotettix virescens, Nephotettix nigropictus, Recilia dorsalis, Empoasca onukii, Empoasca fabae, Dalbulus spp. maidis), white-winged brown-veined leafhopper (Cofanaspectra), two-spotted green leafhopper (Amrasca biguttula biguttula), etc.; Aphrophoridae (Aphrophoridae) (Philaenus spumarius), etc.; Cercopidae (Mahanarvaposticata), sugarcane leafhopper (Mahanarva fimbriolata), etc.;Beet aphid (Aphisfabae), soybean aphid (Aphis glycines), cotton aphid (Aphis gossypii), apple aphid (Aphis pomi), spiraea aphid (Aphis spiraecola), peach aphid (Myzus persicae), plum short-tailed aphid (Brachycaudus helichrysi), cabbage aphid (Brevicoryne brassicae), rose apple aphid (Dysaphis plantaginea), cabbage stalked aphid (Lipaphis erysimi), potato long-tailed aphid (Macrosiphum euphorbiae), eggplant ditch aphid (Aulacorthum solani), lettuce aphid (Nasonovia ribisnigri), cereal stalked aphid (Rhopalosiphumpadi), corn aphid (Rhopalosiphum maidis), citrus aphid (Toxoptera citricida), peach pink aphid (Hyalopterus pruni), sorghum aphid (Melanaphis sacchari), Tetraneuranigriabdominalis, Ceratovacuna lanigera, Eriosomalanigerum, Sitobion avenae, and other Aphididae; Daktulosphaira vitifoliae, Phylloxera devastatrix, Phylloxera notabilis, Phylloxera russelae, and other Phylloxeridae; Adelgidae, Adelges tsugae, Adelges piceae, and Aphrastasia pectinatae;Pentatomidae, including the black rice stink bug (Scotinophara lurida), the Malayan black rice stink bug (Scotinophara coarctata), the black-bearded rice stink bug (Nezara antennata), the northern two-star stink bug (Eysarcoris aeneus), the large-spined white-star stink bug (Eysarcoris lewisi), the broad two-star stink bug (Eysarcoris ventralis), the pseudo two-star stink bug (Eysarcoris annamita), the brown-winged stink bug (Halyomorpha halys), the green rice stink bug (Nezara viridula), the brown stink bug (Euschistus heros), the red-banded stink bug (Piezodorus guildinii), the rice stink bug (Oebalus pugnax), the stink bug (Dichelops melacanthus), the wall stink bug (Piezodorus hybneri); the digging brown stink bug (Scaptocoris castanea) and other Cydnidae; Alydidae such as Riptortus clavatus, Leptocorisa chinensis, and Leptocorisa acuta; Coreidae such as Cletus punctiger and Leptoglossus australis; Lygaeidae such as Cavelerius saccharivorus, Togohemipterus, and Blissus leucopterus; Trigonotylus caelestialium, Stenotus rubrovittatus, and Stenodema calcarata), American meadow bug (Lygus lineolaris), and other Miridae; Trialeurodes vaporariorum (Househouse whitefly), Bemisia tabaci (Bemisia tabaci), Dialeurodes citri (Citrus whitefly), Aleurocanthus spiniferus (Blackthorn whitefly), Aleurocanthus camelliae (Camellia whitefly), and Pealius euryae (Whitefly);Tea long round scale (Abgrallaspis cyanophylli), red round scale (Aonidiella aurantii), pear round scale (Diaspidiotusperniciosus), mulberry white scale (Pseudaulacaspis pentagona), arrow-pointed shield scale (Unaspis yanonensis), citrus sharp shield scale (Unaspis citri) and other shield scale families (Diaspididae); red wax scale (Ceroplastes rubens) and other scale families (Coccidae); blowing cotton scale (Icerya purchasi), silver-haired blowing cotton scale (Icerya seychellarum) and other cotton scale families (Margarodidae); Lycoris mealybug (Phenacoccus solani), hibiscus mealybug (Phenacoccussolenopsis), Japanese hip-striped mealybug (Planococcus Pseudococcidae, including Pseudococcus kraunhiae, Pseudococcus comstocki, Planococcus citri, Pseudococcus calceolariae, Pseudococcus longispinus, and Brevennia rehi; Psyllidae, including Diaphorina citri, Trioza erytreae, Cacopsylla pyrisuga, Cacopsylla chinensis, Bactericera cockerelli, and Cacopsylla pyricola; and Corythucha ciliata, Corythucha chrysanthemum. marmorata), Stephanitis nashi, and Stephanitis pyrioides, among others; Cimicidae, including Cimex lectularius and Cimex hemipterus; and Cicadidae, including Quesada gigas.Triatoma infestans, Triatoma rubrofasciata, Triatoma dimidiata, Rhodonius prolixus, and other members of the Reduviidae family.

[0330] Lepidoptera: Chilo suppressalis, Chilopolychrysus, Scirpophaga innotata, Scirpophaga incertulas, Rupela albina, Cnaphalocrocis medinalis, Marasmia patnalis, Marasmia exigua, Notarcha derogata, Ostrinia furnacalis, Ostrinia nubilalis, Hellulaundalis, Herpetogramma luctuosale, Parapedia siateterrellus, Nymphula depunctalis), sugarcane borer (Diatraea saccharalis), eggplant yellow moth (Leucinodes orbonalis) and other grass borers (Crambidae); small corn borer (Elasmopalpuslignosellus), Indian grain moth (Plodia interpunctella), leather dark moth (Euzophera batangensis), powdery moth (Cadra cautella) and other moths (Pyralidae);Spodoptera litura, Spodoptera exigua, Mythimna separata, Mamestrabrassicae, Sesamia inferens, Spodoptera mauritia, Naranga aenescens, Spodoptera frugiperda, Spodoptera exempta, Spodoptera cosmioides, Spodoptera eridania, Agrotis ipsilon, Agrotis segetum, Autographanigrisigna, Plusia festucae, Chrysodeixis includens, Trichoplusia spp., Heliothis spp. virescens, Heliothis spp., Helicoverpa armigera, Helicoverpa zea, Anticarsia gemmatalis, Alabamaargillacea, Hydraecia immanis, and other Noctuidae species; and Pieridae such as Pieris rapae.Pear borer (Grapholita molesta), sand apple borer (Grapholita dimorpha), soybean borer (Leguminivora glycinivorella), Japanese bean moth (Matsumuraeses azukivora), apple leaf roller (Adoxophyesorana fasciata), tea leaf roller (Adoxophyes honmai), tea long leaf roller (Homona magnanima), apple yellow leaf roller (Archipsfuscocupreanus), apple leaf roller (Cydia pomonella), yellow stem borer (Tetramoera schistaceana), bean shoot borer (Epinotia aporema), citrus fruit fly (Citripestissagittiferella), grape flower wing roller (Lobesia botrana), etc. (Tortricidae); tea leaf roller (Caloptilia theivora), golden leaf roller (Phyllonorycter ringoniella, etc.; Carposinidae, etc.; Lyonetiidae, etc.; Lymantriidae, etc.; Lymantria spp., etc.; Euproctis spp., etc.; Plutellidae, etc.; Anarsialineatella, etc.; Helcystogramma triannulella, etc.; Pectinophora agoutipiella, etc.; Phthorimaea spp., etc.; operculella), tomato moth (Tutaabsoluta), etc. of the Gelechiidae family; American white moth (Hyphantria cunea), etc. of the Arctiidae family; sugarcane borer (Telchin licus), etc. of the Castniidae family;Cossidae, including the aromatic wood borer (Cossus insularis); Geometridae, including the large bridge builder (Ascotis selenaria); Limacodidae, including the beautiful green moth (Parasalepida); Stathmopodidae, including the persimmon moth (Stathmopoda masinissa); Sphingidae, including the ghost moth (Acherontia lachesis); Sesiidae, including Nokonaferalis, Synanthedon hector, and Synanthedon tenuis; Hesperiidae, including the straight-striped rice butterfly (Parnara guttata); and Tineidae, including the clothes moth (Tinea translucens) and the curtain moth (Tineola bisselliella).

[0331] Thysanoptera: Thripidae, including Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Stenchaetothrips biformis, Echinothrips americanus, and Scirtothrips perseae; and Phlaeothripidae, including Haplothrips aculeatus.

[0332] Diptera: Anthomyiidae, such as Delia platura, Delia antiqua, and Pegomya cunicularia; Ulidiidae, such as Tetanops myopaeformis; Agromyzidae, such as Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, and Chromatomyia horticola; Chloropidae, such as Chlorops oryzae; Bactrocera cucurbitae, Bactrocera dorsalis, Bactrocera latifrons, and Bactrocera serrata. oleae), Bactroceratryoni, Ceratitis capitata, Rhagoletis pomonella, Rhacochlaena japonica, etc.; Ephydridae, Hydrellia agriseola, Hydrellia philippina, Hydrelliasasakii, etc.; Drosophilidae, Drosophila suzukii, Drosophilamelanogaster, etc.; Phoridae, Megaselia spiracularis, etc.; Psychodidae, Clogmia albipunctata, etc.; Bradysia edulis, etc. difformis), Bradysia odoriphaga, and other Sciaridae; Mayetiola destructor, Orseolia oryzae, and other Cecidomyiidae; Diopsidae, Diopsis macrophthalma, and other Proboscis eye rope;Glossinidae, including the Central African tsetse fly (Glossina palpalis) and the stinging tsetse fly (Glossina morsitans); Simuliidae, including the Japanese fly (Simulium japonicum) and the hate fly (Simulium damnosum); Phlebotominae; Tipulidae, including the common fly (Tipula aino), the common fly (Tipula oleracea), and the European fly (Tipulapaludosa); Culex pipiens pallens, Culextritae niorhynchus, Culex pipiens f.molestus, Culex quinquefasciatus, Culex pipiens pipiens, Culex vishnui, Aedes albopictus, and Aedes aegypti. aegypti), Anopheles sinensis, Anopheles gambiae, Anopheles stephensi, Anopheles coluzzii, Anopheles albimanus, Anopheles undaicus, Anopheles arabiensis, Anopheles funestus, Anopheles darlingi, Anopheles farauti, Anopheles minimus, etc.; Simulidae, such as Prosimulium yezoensis and Simulium ornatum; Tabanidae, such as Tabanus trigonus; Musca domestica, Muscina rot fly stabulans), Stomoxys calcitrans, Haematobia irritans, etc., Muscidae; Calliphoridae; Sarcophagidae;Chironomidae, including Chironomus plumosus, Chironomus yoshimatsui, and Glyptotendipes tokunagai; and Fannidae.

[0333] Coleoptera: Diabrotica spp. (e.g., Diabrotica virgifera virgifera, Diabrotica undecimpunctata howardi, Diabrotica barberi, Diabrotica virgiferazeae, Diabrotica balteata, Diabrotica speciosa), Cerotoma trifurcata, Oulemamelanopus, Aulacophora femoralis, Phyllotreta striolata, Phyllotreta cruciferae, Phyllotreta pusilla, Psylliodes chrysocephala), Psylliodes punctulata, Leptinotarsa ​​decemlineata, Oulema oryzae, Colaspis brunnea, Chaetocnema pulicaria, Chaetocnema confinis, Epitrix cucumeris, Dicladispa armigera, Myochrous denticollis, Laccoptera quadrimaculata, Epitrix hirtipennis, Phaedon brassicae, Medythianigrobilineata, etc.; Seedcorn beetle (Stenolophus stenolophus) lecontei), corn seed beetle (Clivina impressifrons), etc. Carabidae;Scarabaeidae species such as Anomala cuprea, Anomala rufocuprea, Anomala albopilosa, Popillia japonica, Heptophyllapicea, Rhizotrogus majalis, Tomarus gibbosus, Holotrichia spp., Phyllophaga crinita, and other Phyllophaga spp.; Diloboderus abderus and other Argentine beetles; Anthriibidae species such as Araecerus coffeae; and Cylas ant beetles. formicarius; Bruchidae such as the Brazilian bean weevil (Zabrotessubfasciatus); Scolytidae such as the longitudinal pit tip beetle (Tomicus piniperda) and the coffee berry beetle (Hypothenemus hampei); West Indian sweet potato weevil (Euscepespostfasciatus), alfalfa weevil (Hypera postica), corn weevil (Sitophilus zeamais), rice weevil (Sitophilus oryzae), grain weevil (Sitophilus granarius), rice weevil (Echinocnemus squameus), rice water weevil (Lissorhoptrus oryzophilus), palm weevil (Rhabdoscelus lineaticollis), cotton boll weevil (Anthonomus grandis), parasitic grain weevil (Sphenophorus venatus), southern corn long-beak weevil (Sphenophorus callosus), soybean stem weevil (Sternechus subsignatus), sugarcane weevil (Sphenophorus levis), gourd rust weevil (Scepticus griseus), Scepticus uniformis, Aracanthus mourei, etc.; Aracanthus spp., cotton root borer (Eutinobothrus brasiliensis), etc.;Tenebrionidae, such as Tribolium castaneum, Tribolium confusum, and Alphitobius diaperinus; Coccinellidae, such as Epilachna vigintioctopunctata; Bostrychidae, such as Lyctus brunneus and Rhizopertha dominica; Ptinidae; Cerambycidae, such as Anoplophora malasiaca, Migdolus fryanus, and Aromiabungii; Melanotus okinawensis, Agriotes fuscicollis, and Melanotus horned comb beetles. Elateridae, including Elaphes legatus, Anchastus spp., Conoderus spp., Ctenicera spp., Limonius spp., and Aeolus spp.; Staphylinidae, including Paederus fuscipes; Dermestidae, including Anthrenus verbasci, Dermestes maculates, and Trogoderma granarium; Anobiidae, including Lasioderma serricorne and Stegobium paniceum; Cryptolestes spp., including Cryptolestes spp. ferrugineus) and other flat grain beetles (Laemophloeidae); Saw-beetle beetles (Silvanidae) such as the Suriname saw-beetle (Oryzaephilus surinamensis); Nitidulidae such as the rapeseed beetle (Brassicogethesaeneus).

[0334] Orthoptera: Migratory locust (Locusta migratoria), Moroccan halberd locust (Dociostaurus maroccanus), Australian plague locust (Chortoicetes terminifera), Red-winged locust (Nomadacris septemfasciata), Brown migratory locust (Locustana pardalina), Tree locust (Anacridium melanorhodon), Italian locust (Calliptamus italicus), Long-fronted locust (Melanoplus differentialis), Two-banded grasshopper (Melanoplus bivittatus), Migrant grasshopper (Melanoplus sanguinipes), Red-legged grasshopper (Melanoplus femurrubrum), Clear-winged earth locust (Camnula pellucida), Desert locust (Schistocerca gregaria), Yellow-winged locust (Gastrimargus musicus), Spur-throated locust (Austracris guttulosa), Small-winged rice grasshopper (Oxya The following are some of the family members of the Acrididae family: the Japanese rice locust (Oxya japonica), the Indian yellow-backed locust (Patanga succincta), the African mole cricket (Gryllotalpa orientalis), the Gryllidae family: the house cricket (Acheta domestica), the yellow-faced oil gourd (Teleogryllus emma), and the Tettigoniidae family: the Mormon cricket (Anabrus simplex).

[0335] Hymenoptera: Tenthredinidae, including Athalia rosae and Athalia japonica; Solenopsis spp., including Solenopsis invicta and Solenopsis geminata; Atta spp., including Brown leaf-cutting ants (Attacapiguara); Acromyrmex spp.; Paraponera clavata; Ochetellus glaber; Monomoriumpharaonis; Linepithema humile; Formica japonica; Pristomyrmex punctutus; Pheidole spp. noda), Pheidolemegacephala, Camponotus japonicus, Camponotus obscuripes, and other Camponotus spp., Pogonomyrmex occidentalis, and other Pogonomyrmex spp., Wasmania auropunctata, and other Wasmania spp., and Anoplolepis gracilipes, among others; Vespidae, including the Asian giant hornet (Vespa mandarinia), Vespa simillima, Vespa analis, Vespavelutina, and Polistes jokahamae; and Urocerus occidentalis. gigas) and other tree wasps (Siricidae); Bethylidae.

[0336] Blattodea: German cockroach (Blattella germanica), Ectobiidae; Periplaneta fuliginosa, American cockroach (Periplaneta americana), Australian cockroach (Periplaneta australasiae), Brown cockroach (Periplaneta brunnea), Oriental cockroach (Blattaorientalis), Blattodea; Reticulitermes speratus, Formosan white-spotted termite (Coptotermes formosanus), Incisitermes minor, Cryptotermes domesticus, Odontotermes formosanus, Neotermes koshunensis, Glyptotermes Termites include the Termitidae, such as the white-necked termite (Glyptotermes satsumensis), the Nakajima termite (Glyptotermes nakajimai), the black tree termite (Glyptotermes fuscus), the forest termite (Hodotermopsis sjostedti), the Guangdong termite (Coptotermes guangzhouensis), the yellow-limbed reticulitermes (Reticulitermes amamianus), the Amami termite (Reticulitermes miyatakei), the closed-door reticulitermes (Reticulitermes kanmonensis), the high mountain elephant termite (Nasutitermes takasagoensis), the Nitobe near-twisted termite (Pericapritermes nitobei), the Taiwan crooked termite (Sinocapritermes mushae), and the corner termite (Cornitermes cumulans).

[0337] Order Siphonaptera: Pulicidae (human flea, Pulex irritans), Ctenocephalides felis, Ctenocephalides canis, Xenopsylla cheopis, Echidnophaga gallinacea); Hectopsyllidae (Tunga penetrans); Ceratophyllidae (Nosopsyllus fasciatus).

[0338] Psocodae: Pediculidae (human head louse, Pediculus humanus capitis); Pthiridae (pubic louse, Pthirus pubis); Haematopinus usurysternus (cattle blood louse, Haematopinus suis); Linognathidae (calf jaw louse, Linognathus ovillus (sheep jaw louse, Solenopotescapillatus); Bovicoliidae (cattle hair louse, Bovicola bovis (cattle hair louse, Bovicola ovis (sheep hair louse, Bovicola breviceps, Damalinia forficula, Werneckiella spp.); Trichodectes (dog hair louse, Trichodectes) canis), cat louse (Felicola subrostratus), etc.; Menoponidae, such as Menopon gallinae, Menacanthus stramineus, and Trinoton spp.; Trimenoponidae, such as Cummingsia spp.; Trogiidae, such as Trogium pulsatorium; Liposcelidae (or Liposcelididae), such as Liposcelis corrodens, Liposcelis bostrychophila, Liposcelis pearmani, and Liposcelisentomophila.

[0339] Thysanura: Lepismatidae such as Ctenolepisma villosa and Lepismasaccharina.

[0340] Acari: Tetranychus urticae, Tetranychus kanzawai, Tetranychus evansi, Panonychus citri, Panonychus ulmi, Oligonychus spp., etc. Tetranychidae; Aculops pelekassi, Phyllocoptruta citri, Aculops lycopersici, Calacarus carinatus, Acaphylla theavagrans, Eriophyes chibaensis, Aculus schlechtendali, Aceria diospyri), Aceria tosichella, Shevtchenkella sp., etc.; Tarsonemidae, such as Polyphagotarsonemus latus; Tenuipalpidae, such as Brevipalpus phoenicis; Tuckerellidae;Haemaphysalis longicornis, Haemaphysalis flava, Haemaphysalis japonica, Haemaphysalis campanulata, Dermacentor variabilis, Dermacentor taiwanensis, Dermacentor andersoni, Dermacentor reticulatus, Ixodes ovatus, Ixodes persulcatus, Ixodes scapularis, Ixodes pacificus, Ixodes holocyclus, Ixodes ricinus, Amblyomma americanum, Amblyomma maculatum, Rhipicephalus microplus), Rhipicephalus annulatus, Rhipicephalus sanguineus, Rhipicephalus appendiculatus, Rhipicephalus decoloratus; Argasidae, Argas persicus, Ornithodoros hermsi, Ornithodorosturicata; Acaridae, Tyrophagus putrescentiae, Tyrophagus similis; Pyroglyphidae, Dermatophagoides farinae, Dermatophagoides pteronyssinus; Cheyletus eruditus, Cheyletus malaccus, and other carnivorous mites. malaccensis), Chelacaropsis moorei, Cheyletiella yasguri, and other carnivorous mites (Cheyletidae);Psoroptes ovis, Psoroptes equi, Knemidocoptes mutans, Otodectes cynotis, Chorioptes spp., etc. of the Psoroptidae family; Notoedres cati, Notoedres muris, Sarcoptes scabiei, etc. of the Sarcoptidae family; Listrophorus gibbus, etc. of the Rabbit family; Dermanyssidae, Dermanyssus gallinae, etc.; Ornithonyssus sylviarum, Ornithonyssus bacoti, etc. of the Macronyssidae family; Varroa varroa, etc. jacobsoni) and other Varroidae; Demodicidae such as Demodex canis and Demodex cati; Trombiculidae such as Leptotrombidium akamushi, Leptotrombidium pallidum, and Leptotrombidium scutellare.

[0341] Araneae: Eutichuridae, including the Japanese red-clawed spider (Cheiracanthium japonicum); Theridiidae, including the red-backed spider (Latrodectus hasseltii).

[0342] Polydesmida: Oxidus gracilis, Nedyopus tambanus, etc. Paradoxosomatidae.

[0343] Isopoda: Common beetle (Armadillidium vulgare), etc. Armadillidiidae.

[0344] Class Chilopoda: Scutigeridae, including Thereuonema hilgendorfi; Scolopendridae, including Scolopendra subspinipes; and Ethopolyidae, including Bothropolys rugosus.

[0345] Gastropoda: Limacidae, such as Limax marginatus and Limaxflavus; Philomycidae, such as Meghimatium bilineatum; Ampullariidae, such as Pomacea canaliculata; Lymnaeidae, such as Austropeplea ollula.

[0346] Nematodes: Aphelenchoididae, including the rice stem-tipped nematode Aphelenchoides besseyi; Pratylenchidae, including the coffee short-bodied nematode Pratylenchus coffeae, Pratylenchus brachyurus, Pratylenchus neglectus, and Radopholus similis; Java root-knot nematodes Meloidogyne javanica, southern root-knot nematodes Meloidogyne incognita, guava root-knot nematodes Meloidogyne enterolobii, northern root-knot nematodes Meloidogyne hapla, soybean cyst nematodes Heterodera glycines, and potato golden nematodes Globodera spp. Heteroderidae, such as Potato white nematode (Globodera pallida), and Columbia root-knot nematode (Meloidogyne chitwoodi); Hoplolaimidae, such as Rotylenchulus reniformis; Anguinidae, such as Nothotylenchus acris and Ditylenchus dipsaci; Tylenchulidae, such as Tylenchulus semipenetrans; Longidoridae, such as Xiphinema index; Trichodoridae; and Parasitaphelenchidae, such as Bursaphelenchus xylophilus.

[0347] Harmful insects, harmful mites, and other harmful arthropods, harmful mollusks, and harmful nematodes may be those whose sensitivity to insecticides, acaricides, molluscicides, or nematodes is reduced, or those that are highly resistant to them.

[0348] The method for controlling harmful arthropods of the present invention can be implemented by directly applying an effective amount of the compound of the present invention or composition A to harmful arthropods and / or applying it to the habitats of harmful arthropods (plants, soil, houses, animals, etc.). Examples of the method for controlling harmful arthropods of the present invention include foliage treatment, soil treatment, root treatment, spraying treatment, fumigation treatment, water surface treatment, and seed treatment.

[0349] For the compounds of the present invention or composition A, inactive supports such as solid supports, liquid supports, gaseous supports and surfactants are usually mixed, and preparation adjuvants such as binders, dispersants, stabilizers are added as needed, and formulations are transformed into aqueous suspension formulations, oily suspension formulations, oils, emulsions, emulsion formulations, microemulsion formulations, microcapsule formulations, wettable powders, water-dispersible granules, powders, granules, tablets, aerosols, resin formulations, etc. for use. It is not limited to these preparations, and can be formulated into the formulations described in Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers-271~276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications (Manual on development and use of FAO and WHO pesticide standards, FAO Plant Production and Protection Documents-271~276, compiled by the FAO / WHO Joint Meeting on Pesticide Specifications), 2016, ISSN: 0259-2517 for use.

[0350] These preparations usually contain 0.0001 to 99% of the compound or composition A of the present invention by weight.

[0351] Examples of the solid support include clay (pyrophyllite clay, kaolin clay, etc.), talc, calcium carbonate, diatomaceous earth, zeolite, bentonite, acid clay, attapulgite, white carbon, ammonium sulfate, vermiculite, perlite, pumice, silica sand, fine powders and granules of chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), and resins (polyethylene, polypropylene, polyester, polyurethane, polyamide, polyvinyl chloride, etc.).

[0352] Examples of the liquid carrier include water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, etc.), aromatic hydrocarbons (xylene, phenylxylylethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, methyl oleate, propylene carbonate, etc.), nitriles (acetonitrile, etc.), ethers (ethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, N,N-dimethyloctanamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), lactams (N-methylpyrrolidone, N-octylpyrrolidone, etc.), fatty acids (oleic acid, etc.), and vegetable oils (soybean oil, etc.).

[0353] Examples of the gaseous support include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide.

[0354] Examples of the surfactant include nonionic surfactants (polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyethylene glycol fatty acid ester, etc.) and anionic surfactants (alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, etc.).

[0355] Other formulation adjuvants include binders, dispersants, colorants, and stabilizers, and specific examples include polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, synthetic water-soluble polymers (polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylic acids, etc.), acidic isopropyl phosphate, and butylated hydroxytoluene.

[0356] In addition, adjuvants can be used as components that enhance or assist the efficacy of the compounds of the present invention. Specific examples include Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol (registered trademark), Silwet L-77 (registered trademark), BreakThru (registered trademark), Sundance II (registered trademark), Induce (registered trademark), Penetrator (registered trademark), AgriDex (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), and BANOLE (registered trademark).

[0357] In the present invention, examples of the plant include the whole plant, stems and leaves, flowers, ears, fruits, trunks, branches, crowns, seeds, vegetative propagation organs, and seedlings.

[0358] Vegetative propagation organ refers to: among the root, stem, leaf etc. of plant, the position with the ability of growing when this position is cut off from main body and is arranged in soil.As vegetative propagation organ, can enumerate for example tuberous root (tuberous root), creeping root (creeping root), bulb (bulb), corm (corm or solid bulb), tuber (tuber), rhizome (rhizome), stolon (stolon), root support (rhizophore), stem cuttings (cane cuttings), propagation bud (propagule) and vine cuttings (vine cutting).It should be noted that stolon is sometimes also referred to as runner (runner), and propagation bud is also referred to as bulbil, is divided into fleshy bud (broad bud) and bulbil (bulbil).Vine cuttings refer to the slender (general term of leaf and stem, rootless seedling (shoot)) of sweet potato, Japanese yam etc. The term "bulb" also refers to bulbs, corms, tubers, rhizomes, stem cuttings, root tubers, or tubers. Tuber cultivation begins by planting tubers in the soil, but the tubers used are usually called seed potatoes.

[0359] As a method for controlling harmful arthropods by applying an effective amount of the compound or composition A of the present invention to the soil, for example, a method of applying an effective amount of the compound or composition A of the present invention to the soil before or after transplanting plants. More specifically, for example, hole treatment (hole spreading, hole treatment soil mixing), root treatment (root spreading, root soil mixing, root irrigation, root treatment in the late seedling stage), furrow treatment (furrow spreading, furrow soil mixing), furrow treatment (furrow spreading, furrow soil mixing, furrow spreading during the growing period), furrow treatment at sowing (furrow spreading at sowing, furrow soil mixing at sowing), comprehensive treatment (whole soil spreading, whole soil mixing), ridge side treatment, water surface treatment (water surface application, water surface application after water storage), other soil spreading treatments (leaf spreading of granules during the growing period, spreading under the canopy or around the trunk, soil surface spreading, soil surface mixing, hole spreading, ridge ground surface scattering, inter-plant scattering), other irrigation treatments (soil irrigation, irrigation during the seedling period, liquid injection treatment, irrigation at the base of the plant, liquid drip irrigation, chemical solution irrigation), seedling box treatment (seedling box scattering, seedling box irrigation, seedling box liquid accumulation), seedling tray treatment (seedling tray scattering, seedling tray irrigation, seedling tray liquid accumulation), seedling bed treatment (seedling bed scattering, seedling bed irrigation, nursery bed scattering, seedling soaking), bed soil mixing treatment (bed soil mixing, bed soil mixing before sowing, scattering before covering soil at sowing, scattering after covering soil at sowing, covering soil mixing), and other treatments (cultivated soil mixing, turning in, topsoil mixing, rainwater drip soil mixing, planting position treatment, granular calyx scattering, paste fertilizer mixing).

[0360] Examples of seed treatment include treatments of seeds or vegetative propagation organs with the compound or composition A of the present invention. Specifically, examples include: spraying treatments in which a suspension of the compound or composition A of the present invention is atomized and sprayed onto the surface of seeds or vegetative propagation organs; coating treatments in which the compound or composition A of the present invention is applied to seeds or vegetative propagation organs; immersion treatments in which seeds or vegetative propagation organs are immersed in a solution of the compound or composition A of the present invention for a predetermined period of time; and methods in which seeds or vegetative propagation organs are coated with a carrier containing the compound or composition A (coating treatments, pellet coating treatments, etc.). Examples of the vegetative propagation organs include seed potatoes.

[0361] When treating seeds or vegetative propagation organs with composition A, composition A may be prepared as a single formulation for treating the seeds or vegetative propagation organs, or composition A may be prepared as multiple different formulations for treating the seeds or vegetative propagation organs in multiple batches. Examples of methods for treating the seeds or vegetative propagation organs with multiple different formulations include: treating the seeds or vegetative propagation organs with a formulation containing only the compound of the present invention as an active ingredient, allowing the seeds or vegetative propagation organs to air-dry, and then treating the seeds or vegetative propagation organs with a formulation containing the present ingredient; and treating the seeds or vegetative propagation organs with a formulation containing the compound of the present invention and the present ingredient as active ingredients, allowing the seeds or vegetative propagation organs to air-dry, and then treating the seeds or vegetative propagation organs with a formulation containing the present ingredient other than the treated present ingredient.

[0362] The seeds or vegetative propagation organs retaining the compound or composition A of the present invention in the present invention refer to seeds or vegetative propagation organs in a state where the compound or composition A of the present invention is attached to the surface of the seeds or vegetative propagation organs. For the seeds or vegetative propagation organs retaining the compound or composition A of the present invention, materials other than the compound or composition A of the present invention may be attached before or after the compound or composition A of the present invention is attached to the seeds or vegetative propagation organs.

[0363] In addition, when composition A forms a layer on the surface of a seed or a vegetative propagation organ and adheres to it, the layer is formed by one layer or multiple layers. In addition, when formed by multiple layers, each layer is a layer containing one or more active ingredients, or is formed by a layer containing one or more active ingredients and a layer not containing an active ingredient.

[0364] Seeds or vegetative propagation organs containing the compound or composition A of the present invention can be obtained, for example, by applying a formulation containing the compound or composition A of the present invention to seeds or vegetative propagation organs using the aforementioned seed treatment method.

[0365] When the compound or composition A of the present invention is used for controlling harmful arthropods in agricultural fields, the application rate is: 2 The amount of the compound of the present invention is usually 1 to 10,000 g. When treating seeds or vegetative propagation organs, the amount of the compound of the present invention is usually applied in the range of 0.001 to 100 g per kg of seeds or vegetative propagation organs. When the compound of the present invention or composition A is formulated into an emulsion, wettable powder, suspension, etc., it is usually diluted with water to a concentration of 0.01 to 10,000 ppm of the active ingredient and applied. Granules, powders, etc. are usually applied directly.

[0366] Alternatively, the compound or composition A of the present invention can be treated by winding a resin preparation processed into a sheet or string around crops, stretching it near crops, or laying it on the soil around the roots.

[0367] When the compound or composition A of the present invention is used to control harmful arthropods that inhabit houses, the application rate is, when treating on the surface, 1m 2 The amount of the compound of the present invention per treatment area is usually 0.01 to 1000 mg. When the treatment is carried out in space, the amount is per 1 m 3 The amount of the compound of the present invention applied to the treated space is generally 0.01 to 500 mg. When the compound of the present invention or composition A is formulated into an emulsion, wettable powder, suspension, or the like, it is usually diluted with water to a concentration of 0.1 to 10,000 ppm of the active ingredient and applied directly. Alternatively, an oil formulation, aerosol formulation, fumigant, or poison bait formulation may be used.

[0368] The compounds of this invention or composition A are used to prevent and treat external parasites of small animals such as cattle, horses, pigs, sheep, goats, chickens, dogs, cats, rats, mice, etc., and can be used for animals by methods known in veterinary medicine. As a specific method of use, in the case of taking systemic suppression as the purpose, by, for example, tablets, feeds mixed in, suppositories, injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.) are applied, in the case of taking non-systemic suppression as the purpose, by, for example, oils or aqueous liquids are sprayed, poured or sprayed, shampoo formulations are used to wash animals, or resin formulations are made into collars, ear tags and animals are worn. The amount of the compounds of this invention or composition A when applied to animals is generally in the range of 0.1 to 1000 mg relative to animal body weight 1 kg.

[0369] The compound or composition A of the present invention can be used as an agent for controlling harmful arthropods in agricultural lands such as dry fields, paddy fields, lawns, and orchards. Examples of plants include the following.

[0370] Corn (dent, hard, soft, popping, glutinous, sweet, and non-sweet corn), rice (long-grain, short-grain, medium-grain, Japonica, tropical Japonica, Indica, Javanese, upland rice, floating rice, direct-seeded, transplanted, and glutinous rice), wheat (bread wheat (hard, soft, medium, red, and white), durum wheat, spelt, and club wheat, as well as various winter and spring wheat types), barley (two-row barley (= malting barley), six-row barley, naked barley, and various sticky barley types), (winter barley type, spring barley type), rye (winter rye type, spring rye type), triticale (winter triticale type, spring triticale type), oats (winter oat type, spring oat type), sorghum, cotton (upland type, Pima type), soybeans (mature seed harvest varieties, branch bean varieties, green cutting varieties, each indeterminate growth type, determinate growth type, semi-determinate growth type), peanuts, buckwheat, sugar beets (for sugar production, feed, root vegetables, leafy vegetables, fuel), rapeseed (winter rapeseed type, spring rapeseed type), Canadian rapeseed (winter Canadian rapeseed type, spring Canadian rapeseed type), sunflower (for oil extraction, food Vegetables for ornamental purposes (e.g., eggplant, tomato, green pepper, hot pepper, potato), cucurbitaceae vegetables (cucumber, pumpkin, zucchini, watermelon, melon), cruciferous vegetables (radish, turnip, horseradish, kohlrabi, cabbage, cabbage, mustard, broccoli, cauliflower), Asteraceae vegetables (burdock, chamomile, artichoke, lettuce), Liliaceae vegetables (scallion, onion, garlic, asparagus), Umbelliferae vegetables (carrot, parsley, celery, parsnip), Chenopodiaceae vegetables (spinach, pachyderm), Lamiaceae vegetables (perilla, mint), , basil, etc.), strawberry, sweet potato, Japanese yam, taro, pome fruit (apple, pear, Japanese pear, white pear, papaya crabapple, quince, etc.), stone fruit (peach, plum, nectarine, greengage, cherry, apricot, prune, etc.), citrus (Wenzhou mandarin orange, orange, lemon, lime, grapefruit, etc.), nuts (chestnut, walnut, hazelnut, almond, pistachio, cashew, macadamia, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, persimmon, fig, olive, loquat, banana, coffee, date, coconut, ornamental plants, forest plants, lawn grass, forage grass.

[0371] The above-mentioned plants are not particularly limited as long as they are commonly cultivated varieties. The above-mentioned plants also include plants that can be made by natural mating, plants that can be produced by mutation, F1 hybrid plants and genetically modified crops. As genetically modified crops, for example, plants that are endowed with resistance to herbicides such as HPPD (4-hydroxyphenylpyruvate dioxygenase) inhibitors such as isoxazolidinone, ALS (acetolactate synthase) inhibitors such as imazethapyr, thifensulfuron, EPSP (5-enolpyruvylshikimate-3-phosphate synthase) inhibitors, glutamine synthetase inhibitors, PPO (protoporphyrinogen oxidase) inhibitors, bromoxynil or dicamba; plants that can synthesize selective toxins known in Bacillus genus such as Bacillus thuringiensis; plants that can be endowed with specific insecticidal activity by synthesizing gene fragments that are partially identical to endogenous genes from harmful insects and inducing gene silencing (RNAi; RNA interference) in the target harmful insects.

[0372] Example

[0373] Hereinafter, the present invention will be described in more detail using production examples, formulation examples, test examples, and the like, but the present invention is not limited to these examples.

[0374] In this specification, Me represents a methyl group, Et represents an ethyl group, Pr represents a propyl group, i-Pr represents an isopropyl group, t-Bu represents a tert-butyl group, c-Pr represents a cyclopropyl group, Ph represents a phenyl group, Py2 represents a 2-pyridyl group, Py3 represents a 3-pyridyl group, and Py4 represents a 4-pyridyl group. When c-Pr, Ph, Py2, Py3, or Py4 is substituted with a substituent, the substituent and the position of substitution are listed before the symbol. For example, 1-CN-c-Pr represents 1-cyanocyclopropyl, 3,4-F2-Ph represents 3,4-difluorophenyl, 4-S(O)2CF3-Ph represents 4-(trifluoromethanesulfonyl)phenyl, 3-SCF3-Ph represents 3-[(trifluoromethyl)thio]phenyl, 4-CF3-Py2 represents 4-(trifluoromethyl)-2-pyridyl, and 5-NMeCH2CF3-Py2 represents 5-(methyl 2,2,2-trifluoroethylamino)-2-pyridyl.

[0375] First, production examples of the compound of the present invention and its production intermediates are shown.

[0376] Reference Production Example 1

[0377] To a mixture of 2.2 g of 2-(2-bromoacetyl)-5-(2,2,3,3,3-pentafluoropropoxy)pyridine and 5 mL of acetonitrile produced by the method described in International Publication No. 2018 / 052119 was added 0.9 g of 5-(trifluoromethyl)-2-aminopyridine at room temperature, and the mixture was stirred under reflux for 3 hours. The resulting mixture was cooled to room temperature, water was added, and extraction was performed with ethyl acetate. The resulting organic layer was dried over sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.43 g of intermediate 1 represented by the following formula.

[0378] [Chemical Formula 14]

[0379]

[0380] Intermediate 1: 1 H-NMR(CDCl3)δ:8.52(1H,t),8.40(1H,d),8.27(1H,d),8.18(1H,d),7.73(1H,dd),7.38(1H,dd),7.37-7.33(1H,dd),4.53(2H,td).

[0381] Reference Production Example 2

[0382] The compounds produced according to Reference Production Example 1 and their physical properties are shown below.

[0383] [Chemical Formula 15]

[0384]

[0385] Intermediate 2: 1 H-NMR(CDCl3)δ:8.93-8.92(1H,m),8.36(1H,s),8.33(1H,s),8.13(1H,s),7.56(1H,d),7.30(1H,d),4.96-4.88(2H,m).

[0386] [Chemical Formula 16]

[0387]

[0388] Intermediate 3: 1 H-NMR(CDCl3)δ:8.51-8.49(1H,m),8.36(1H,d),8.33(1H,s),7.47-7.40(2H,m),7.21(1H,d),6.21-5.92(1H,m),5.06-4.97(2H,m).

[0389] Production Example 1

[0390] A mixture of 1.0 g of intermediate 2, 1.0 mL of chlorosulfonic acid and 6 mL of phosphorus oxychloride was stirred at 120 ° C for 10 hours. The obtained mixture was concentrated under reduced pressure, and 1 mL of triethylamine, 6 mL of acetonitrile and 6 mL of methylamine (7% tetrahydrofuran solution) were added to the obtained residue and stirred at room temperature for 1 hour. Water was added to the obtained mixture and extracted with ethyl acetate. The obtained organic layer was dried using anhydrous sodium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel column chromatography to obtain 0.40 g of compound 1 of the present invention shown in the following formula.

[0391] [Chemical Formula 17]

[0392]

[0393] Compound 1 of the present invention: 1 H-NMR(CDCl3)δ:9.42(1H,s),9.07(1H,s),8.38(1H,s),7.63(1H,d),7.53(1H,d),7.19-7.14(1H,m),4.94(2H,t),2.72(3H,d).

[0394] Production Example 2

[0395] The compounds produced according to Production Example 1 and their physical properties are shown below.

[0396] [Chemical Formula 18]

[0397]

[0398] Compound 2 of the present invention: 1 H-NMR(CDCl3)δ:9.41(1H,s),9.07(1H,s),8.39(1H,s),7.63(1H,d),7.5 2(1H,d),7.20-7.15(1H,m),4.93(2H,t),3.12-3.04(2H,m),1.13(3H,t).

[0399] [Chemical Formula 19]

[0400]

[0401] Compound 3 of the present invention: 1 H-NMR(CDCl3)δ:9.57(1H,s),8.41(1H,d),7.64(1H,d),7.61-7.56(1H,m),7.51(1H,d),7.28(1H,d),6.04(1H,t),5.01(2H,t),2.75(3H,d).

[0402] [Chemical Formula 20]

[0403]

[0404] Compound 4 of the present invention: 1 H-NMR(CDCl3)δ:9.22(1H,s),7.93(1H,d),7.68(1H,d),7.56(1H,d),7.19(1H,d),6.06(1H,t),5.02(2H,t),2.89(6H,d).

[0405] Next, examples of the compounds of the present invention produced according to any of the production examples described in the Examples and the production methods described in this specification are shown below.

[0406] [Chemical Formula 21]

[0407]

[0408] In the compound represented by formula (L-1) (hereinafter referred to as compound (L-1)), R 2a and R 2b The compounds (hereinafter referred to as compound group SX1) wherein α is a hydrogen atom and T is any substituent described in [Table 1A] to [Table 6A].

[0409] [Table 1]

[0410]

[0411] [Table 2]

[0412]

[0413] In compound (L-1), R 2a is methyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX2).

[0414] In compound (L-1), R 2a is methyl, R 2b The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX3).

[0415] In compound (L-1), R 2a is ethyl, R 2b The compounds wherein is a hydrogen atom and T is any substituent described in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX4).

[0416] In compound (L-1), R 2a is ethyl, R 2b The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX5).

[0417] In compound (L-1), R 2a is propyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent described in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX6).

[0418] In compound (L-1), R 2a is propyl, R 2b The compounds wherein α is a propyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX7).

[0419] In compound (L-1), R 2a is methyl, R 2b The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX8).

[0420] [Chemical Formula 22]

[0421]

[0422] In the compound represented by formula (L-2) (hereinafter referred to as compound (L-2)), R 2a and R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX9).

[0423] In compound (L-2), R 2a is methyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent described in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX10).

[0424] In compound (L-2), R 2a is methyl, R 2b The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX11).

[0425] In compound (L-2), R 2a is ethyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX12).

[0426] In compound (L-2), R2a is ethyl, R 2b The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX13).

[0427] In compound (L-2), R 2a is propyl, R 2b The compounds wherein is a hydrogen atom and T is any substituent described in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX14).

[0428] In compound (L-2), R 2a is propyl, R 2b The compounds wherein α is a propyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX15).

[0429] In compound (L-2), R 2a is methyl, R 2b The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX16).

[0430] [Chemical Formula 23]

[0431]

[0432] In the compound represented by formula (L-3) (hereinafter referred to as compound (L-3)), R 2a and R 2b The compounds wherein is a hydrogen atom and T is any substituent described in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX17).

[0433] In compound (L-3), R 2a is methyl, R 2b The compounds wherein is a hydrogen atom and T is any substituent described in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX18).

[0434] In compound (L-3), R 2a is methyl, R 2b The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX19).

[0435] In compound (L-3), R 2a is ethyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX20).

[0436] In compound (L-3), R2a is ethyl, R 2b The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX21).

[0437] In compound (L-3), R 2a is propyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX22).

[0438] In compound (L-3), R 2a is propyl, R 2b The compounds wherein α is a propyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX23).

[0439] In compound (L-3), R 2a is methyl, R 2b The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX24).

[0440] [Chemical Formula 24]

[0441]

[0442] In the compound represented by formula (L-4) (hereinafter referred to as compound (L-4)), R 2a and R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX25).

[0443] In compound (L-4), R 2a is methyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX26).

[0444] In compound (L-4), R 2a is methyl, R 2b The compounds wherein R is a methyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX27).

[0445] In compound (L-4), R 2a is ethyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX28).

[0446] In compound (L-4), R2a is ethyl, R 2b The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX29).

[0447] In compound (L-4), R 2a is propyl, R 2b The compounds wherein α is a hydrogen atom and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX30).

[0448] In compound (L-4), R 2a is propyl, R 2b The compounds wherein α is a propyl group and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX31).

[0449] In compound (L-4), R 2a is methyl, R 2b The compounds wherein R is ethyl and T is any substituent listed in [Table 1A] to [Table 6A] (hereinafter referred to as compound group SX32).

[0450] [Chemical Formula 25]

[0451]

[0452] In the compound represented by formula (L-5) (hereinafter referred to as compound (L-5)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX33).

[0453] [Table 3]

[0454]

[0455] [Table 4]

[0456]

[0457] [Table 5]

[0458]

[0459] In compound (L-5), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX34).

[0460] In compound (L-5), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX35).

[0461] In compound (L-5), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX36).

[0462] In compound (L-5), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX37).

[0463] In compound (L-5), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX38).

[0464] In compound (L-5), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX39).

[0465] In compound (L-5), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX40).

[0466] In compound (L-5), R 2a and R 2b is a hydrogen atom, R 3dis a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX41).

[0467] In compound (L-5), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX42).

[0468] In compound (L-5), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX43).

[0469] In compound (L-5), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX44).

[0470] In compound (L-5), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX45).

[0471] In compound (L-5), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX46).

[0472] In compound (L-5), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX47).

[0473] In compound (L-5), R 2a is methyl, R2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX48).

[0474] [Chemical Formula 26]

[0475]

[0476] In the compound represented by formula (L-6) (hereinafter referred to as compound (L-6)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX49).

[0477] In compound (L-6), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX50).

[0478] In compound (L-6), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX51).

[0479] In compound (L-6), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX52).

[0480] In compound (L-6), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX53).

[0481] In compound (L-6), R 2a is propyl, R 2b is a hydrogen atom, R 3bis a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX54).

[0482] In compound (L-6), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX55).

[0483] In compound (L-6), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX56).

[0484] In compound (L-6), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX57).

[0485] In compound (L-6), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX58).

[0486] In compound (L-6), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX59).

[0487] In compound (L-6), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX60).

[0488] In compound (L-6), R 2a is ethyl, R2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX61).

[0489] In compound (L-6), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX62).

[0490] In compound (L-6), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX63).

[0491] In compound (L-6), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX64).

[0492] [Chemical Formula 27]

[0493]

[0494] In the compound represented by formula (L-7) (hereinafter referred to as compound (L-7)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX65).

[0495] In compound (L-7), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX66).

[0496] In compound (L-7), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX67).

[0497] In compound (L-7), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX68).

[0498] In compound (L-7), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX69).

[0499] In compound (L-7), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX70).

[0500] In compound (L-7), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX71).

[0501] In compound (L-7), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX72).

[0502] In compound (L-7), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX73).

[0503] In compound (L-7), R 2a is methyl, R 2bis a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX74).

[0504] In compound (L-7), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX75).

[0505] In compound (L-7), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX76).

[0506] In compound (L-7), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX77).

[0507] In compound (L-7), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX78).

[0508] In compound (L-7), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX79).

[0509] In compound (L-7), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX80).

[0510] [Chemical Formula 28]

[0511]

[0512] In the compound represented by formula (L-8) (hereinafter referred to as compound (L-8)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX81).

[0513] In compound (L-8), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX82).

[0514] In compound (L-8), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX83).

[0515] In compound (L-8), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX84).

[0516] In compound (L-8), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX85).

[0517] In compound (L-8), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX86).

[0518] In compound (L-8), R 2a is propyl, R 2b is propyl, R3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX87).

[0519] In compound (L-8), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX88).

[0520] In compound (L-8), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX89).

[0521] In compound (L-8), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX90).

[0522] In compound (L-8), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX91).

[0523] In compound (L-8), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX92).

[0524] In compound (L-8), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX93).

[0525] In compound (L-8), R 2ais propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX94).

[0526] In compound (L-8), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX95).

[0527] In compound (L-8), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX96).

[0528] [Chemical Formula 29]

[0529]

[0530] In the compound represented by formula (L-9) (hereinafter referred to as compound (L-9)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX97).

[0531] In compound (L-9), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX98).

[0532] In compound (L-9), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX99).

[0533] In compound (L-9), R 2a is ethyl, R 2b is a hydrogen atom, R 3bis a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX100).

[0534] In compound (L-9), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX101).

[0535] In compound (L-9), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX102).

[0536] In compound (L-9), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX103).

[0537] In compound (L-9), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX104).

[0538] In compound (L-9), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX105).

[0539] In compound (L-9), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX106).

[0540] In compound (L-9), R 2a is methyl, R2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX107).

[0541] In compound (L-9), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX108).

[0542] In compound (L-9), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX109).

[0543] In compound (L-9), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX110).

[0544] In compound (L-9), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX111).

[0545] In compound (L-9), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX112).

[0546] [Chemical formula 30]

[0547]

[0548] In the compound represented by formula (L-10) (hereinafter referred to as compound (L-10)), R 2a and R 2b is a hydrogen atom, R 3bis a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX113).

[0549] In compound (L-10), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX114).

[0550] In compound (L-10), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX115).

[0551] In compound (L-10), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX116).

[0552] In compound (L-10), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX117).

[0553] In compound (L-10), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX118).

[0554] In compound (L-10), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX119).

[0555] In compound (L-10), R 2ais methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX120).

[0556] In compound (L-10), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX121).

[0557] In compound (L-10), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX122).

[0558] In compound (L-10), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX123).

[0559] In compound (L-10), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX124).

[0560] In compound (L-10), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX125).

[0561] In compound (L-10), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX126).

[0562] In compound (L-10), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX127).

[0563] In compound (L-10), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX128).

[0564] [Chemical Formula 31]

[0565]

[0566] In the compound represented by formula (L-11) (hereinafter referred to as compound (L-11)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX129).

[0567] In compound (L-11), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX130).

[0568] In compound (L-11), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX131).

[0569] In compound (L-11), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX132).

[0570] In compound (L-11), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX133).

[0571] In compound (L-11), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX134).

[0572] In compound (L-11), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX135).

[0573] In compound (L-11), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX136).

[0574] In compound (L-11), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX137).

[0575] In compound (L-11), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX138).

[0576] In compound (L-11), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX139).

[0577] In compound (L-11), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX140).

[0578] In compound (L-11), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX141).

[0579] In compound (L-11), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX142).

[0580] In compound (L-11), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX143).

[0581] In compound (L-11), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX144).

[0582] [Chemical Formula 32]

[0583]

[0584] In the compound represented by formula (L-12) (hereinafter referred to as compound (L-12)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX145).

[0585] In compound (L-12), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX146).

[0586] In compound (L-12), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX147).

[0587] In compound (L-12), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX148).

[0588] In compound (L-12), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX149).

[0589] In compound (L-12), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX150).

[0590] In compound (L-12), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX151).

[0591] In compound (L-12), R 2a is methyl, R 2bis ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX152).

[0592] In compound (L-12), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX153).

[0593] In compound (L-12), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX154).

[0594] In compound (L-12), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX155).

[0595] In compound (L-12), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX156).

[0596] In compound (L-12), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX157).

[0597] In compound (L-12), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX158).

[0598] In compound (L-12), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX159).

[0599] In compound (L-12), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX160).

[0600] [Chemical Formula 33]

[0601]

[0602] In the compound represented by formula (L-13) (hereinafter referred to as compound (L-13)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX161).

[0603] In compound (L-13), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX162).

[0604] In compound (L-13), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX163).

[0605] In compound (L-13), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX164).

[0606] In compound (L-13), R2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX165).

[0607] In compound (L-13), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX166).

[0608] In compound (L-13), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX167).

[0609] In compound (L-13), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX168).

[0610] In compound (L-13), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX169).

[0611] In compound (L-13), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX170).

[0612] In compound (L-13), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX171).

[0613] In compound (L-13), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX172).

[0614] In compound (L-13), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX173).

[0615] In compound (L-13), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX174).

[0616] In compound (L-13), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX175).

[0617] In compound (L-13), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX176).

[0618] [Chemical Formula 34]

[0619]

[0620] In the compound represented by formula (L-14) (hereinafter referred to as compound (L-14)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX177).

[0621] In compound (L-14), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX178).

[0622] In compound (L-14), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX179).

[0623] In compound (L-14), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX180).

[0624] In compound (L-14), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX181).

[0625] In compound (L-14), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX182).

[0626] In compound (L-14), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX183).

[0627] In compound (L-14), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX184).

[0628] In compound (L-14), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX185).

[0629] In compound (L-14), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX186).

[0630] In compound (L-14), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX187).

[0631] In compound (L-14), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX188).

[0632] In compound (L-14), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX189).

[0633] In compound (L-14), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX190).

[0634] In compound (L-14), R 2a is propyl, R 2bis propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX191).

[0635] In compound (L-14), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX192).

[0636] [Chemical Formula 35]

[0637]

[0638] In the compound represented by formula (L-15) (hereinafter referred to as compound (L-15)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX193).

[0639] In compound (L-15), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX194).

[0640] In compound (L-15), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX195).

[0641] In compound (L-15), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX196).

[0642] In compound (L-15), R 2a is ethyl, R 2b is ethyl, R 3bis a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX197).

[0643] In compound (L-15), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX198).

[0644] In compound (L-15), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX199).

[0645] In compound (L-15), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX200).

[0646] In compound (L-15), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX201).

[0647] In compound (L-15), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX202).

[0648] In compound (L-15), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX203).

[0649] In compound (L-15), R 2ais ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX204).

[0650] In compound (L-15), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX205).

[0651] In compound (L-15), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX206).

[0652] In compound (L-15), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX207).

[0653] In compound (L-15), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX208).

[0654] [Chemical Formula 36]

[0655]

[0656] In the compound represented by formula (L-16) (hereinafter referred to as compound (L-16)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX209).

[0657] In compound (L-16), R 2a is methyl, R 2bis a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX210).

[0658] In compound (L-16), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX211).

[0659] In compound (L-16), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX212).

[0660] In compound (L-16), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX213).

[0661] In compound (L-16), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX214).

[0662] In compound (L-16), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX215).

[0663] In compound (L-16), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX216).

[0664] In compound (L-16), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX217).

[0665] In compound (L-16), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX218).

[0666] In compound (L-16), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX219).

[0667] In compound (L-16), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX220).

[0668] In compound (L-16), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX221).

[0669] In compound (L-16), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX222).

[0670] In compound (L-16), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX223).

[0671] In compound (L-16), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX224).

[0672] [Chemical Formula 37]

[0673]

[0674] In the compound represented by formula (L-17) (hereinafter referred to as compound (L-17)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX225).

[0675] In compound (L-17), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX226).

[0676] In compound (L-17), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX227).

[0677] In compound (L-17), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX228).

[0678] In compound (L-17), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX229).

[0679] In compound (L-17), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX230).

[0680] In compound (L-17), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX231).

[0681] In compound (L-17), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX232).

[0682] In compound (L-17), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX233).

[0683] In compound (L-17), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX234).

[0684] In compound (L-17), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX235).

[0685] In compound (L-17), R 2a is ethyl, R 2bis a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX236).

[0686] In compound (L-17), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX237).

[0687] In compound (L-17), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX238).

[0688] In compound (L-17), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX239).

[0689] In compound (L-17), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX240).

[0690] [Chemical Formula 38]

[0691]

[0692] In the compound represented by formula (L-18) (hereinafter referred to as compound (L-18)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX241).

[0693] In compound (L-18), R 2a is methyl, R 2b is a hydrogen atom, R 3bis a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX242).

[0694] In compound (L-18), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX243).

[0695] In compound (L-18), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX244).

[0696] In compound (L-18), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX245).

[0697] In compound (L-18), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX246).

[0698] In compound (L-18), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX247).

[0699] In compound (L-18), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX248).

[0700] In compound (L-18), R 2aand R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX249).

[0701] In compound (L-18), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX250).

[0702] In compound (L-18), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX251).

[0703] In compound (L-18), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX252).

[0704] In compound (L-18), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX253).

[0705] In compound (L-18), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX254).

[0706] In compound (L-18), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX255).

[0707] In compound (L-18), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX256).

[0708] [Chemical Formula 39]

[0709]

[0710] In the compound represented by formula (L-19) (hereinafter referred to as compound (L-19)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX257).

[0711] In compound (L-19), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX258).

[0712] In compound (L-19), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX259).

[0713] In compound (L-19), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX260).

[0714] In compound (L-19), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX261).

[0715] In compound (L-19), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX262).

[0716] In compound (L-19), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX263).

[0717] In compound (L-19), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX264).

[0718] In compound (L-19), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX265).

[0719] In compound (L-19), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX266).

[0720] In compound (L-19), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX267).

[0721] In compound (L-19), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX268).

[0722] In compound (L-19), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX269).

[0723] In compound (L-19), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX270).

[0724] In compound (L-19), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX271).

[0725] In compound (L-19), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX272).

[0726] [Chemical Formula 40]

[0727]

[0728] In the compound represented by formula (L-20) (hereinafter referred to as compound (L-20)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX273).

[0729] In compound (L-20), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX274).

[0730] In compound (L-20), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX275).

[0731] In compound (L-20), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX276).

[0732] In compound (L-20), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX277).

[0733] In compound (L-20), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX278).

[0734] In compound (L-20), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX279).

[0735] In compound (L-20), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX280).

[0736] In compound (L-20), R 2a and R 2bis a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX281).

[0737] In compound (L-20), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX282).

[0738] In compound (L-20), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX283).

[0739] In compound (L-20), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX284).

[0740] In compound (L-20), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX285).

[0741] In compound (L-20), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX286).

[0742] In compound (L-20), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX287).

[0743] In compound (L-20), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX288).

[0744] [Chemical Formula 41]

[0745]

[0746] In the compound represented by formula (L-21) (hereinafter referred to as compound (L-21)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX289).

[0747] In compound (L-21), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX290).

[0748] In compound (L-21), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX291).

[0749] In compound (L-21), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX292).

[0750] In compound (L-21), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX293).

[0751] In compound (L-21), R2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX294).

[0752] In compound (L-21), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX295).

[0753] In compound (L-21), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX296).

[0754] In compound (L-21), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX297).

[0755] In compound (L-21), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX298).

[0756] In compound (L-21), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX299).

[0757] In compound (L-21), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX300).

[0758] In compound (L-21), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX301).

[0759] In compound (L-21), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX302).

[0760] In compound (L-21), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX303).

[0761] In compound (L-21), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX304).

[0762] [Chemical Formula 42]

[0763]

[0764] In the compound represented by formula (L-22) (hereinafter referred to as compound (L-22)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX305).

[0765] In compound (L-22), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX306).

[0766] In compound (L-22), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX307).

[0767] In compound (L-22), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX308).

[0768] In compound (L-22), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX309).

[0769] In compound (L-22), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX310).

[0770] In compound (L-22), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX311).

[0771] In compound (L-22), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX312).

[0772] In compound (L-22), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX313).

[0773] In compound (L-22), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX314).

[0774] In compound (L-22), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX315).

[0775] In compound (L-22), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX316).

[0776] In compound (L-22), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX317).

[0777] In compound (L-22), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX318).

[0778] In compound (L-22), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX319).

[0779] In compound (L-22), R 2a is methyl, R 2bis ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX320).

[0780] [Chemical Formula 43]

[0781]

[0782] In the compound represented by formula (L-23) (hereinafter referred to as compound (L-23)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX321).

[0783] In compound (L-23), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX322).

[0784] In compound (L-23), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX323).

[0785] In compound (L-23), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX324).

[0786] In compound (L-23), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX325).

[0787] In compound (L-23), R 2a is propyl, R 2b is a hydrogen atom, R 3bis a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX326).

[0788] In compound (L-23), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX327).

[0789] In compound (L-23), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX328).

[0790] In compound (L-23), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX329).

[0791] In compound (L-23), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX330).

[0792] In compound (L-23), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX331).

[0793] In compound (L-23), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX332).

[0794] In compound (L-23), R 2ais ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX333).

[0795] In compound (L-23), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX334).

[0796] In compound (L-23), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX335).

[0797] In compound (L-23), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX336).

[0798] [Chemical Formula 44]

[0799]

[0800] In the compound represented by formula (L-24) (hereinafter referred to as compound (L-24)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX337).

[0801] In compound (L-24), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX338).

[0802] In compound (L-24), R 2a is methyl, R 2bis methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX339).

[0803] In compound (L-24), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX340).

[0804] In compound (L-24), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX341).

[0805] In compound (L-24), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX342).

[0806] In compound (L-24), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX343).

[0807] In compound (L-24), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX344).

[0808] In compound (L-24), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX345).

[0809] In compound (L-24), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX346).

[0810] In compound (L-24), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX347).

[0811] In compound (L-24), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX348).

[0812] In compound (L-24), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX349).

[0813] In compound (L-24), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX350).

[0814] In compound (L-24), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX351).

[0815] In compound (L-24), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX352).

[0816] [Chemical Formula 45]

[0817]

[0818] In the compound represented by formula (L-25) (hereinafter referred to as compound (L-25)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX353).

[0819] In compound (L-25), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX354).

[0820] In compound (L-25), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX355).

[0821] In compound (L-25), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX356).

[0822] In compound (L-25), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX357).

[0823] In compound (L-25), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX358).

[0824] In compound (L-25), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX359).

[0825] In compound (L-25), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX360).

[0826] In compound (L-25), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX361).

[0827] In compound (L-25), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX362).

[0828] In compound (L-25), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX363).

[0829] In compound (L-25), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX364).

[0830] In compound (L-25), R 2a is ethyl, R 2bis ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX365).

[0831] In compound (L-25), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX366).

[0832] In compound (L-25), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX367).

[0833] In compound (L-25), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX368).

[0834] [Chemical Formula 46]

[0835]

[0836] In the compound represented by formula (L-26) (hereinafter referred to as compound (L-26)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX369).

[0837] In compound (L-26), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX370).

[0838] In compound (L-26), R 2a is methyl, R 2b is methyl, R 3bis a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX371).

[0839] In compound (L-26), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX372).

[0840] In compound (L-26), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX373).

[0841] In compound (L-26), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX374).

[0842] In compound (L-26), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX375).

[0843] In compound (L-26), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX376).

[0844] In compound (L-26), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX377).

[0845] In compound (L-26), R 2ais methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX378).

[0846] In compound (L-26), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX379).

[0847] In compound (L-26), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX380).

[0848] In compound (L-26), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX381).

[0849] In compound (L-26), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX382).

[0850] In compound (L-26), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX383).

[0851] In compound (L-26), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX384).

[0852] [Chemical Formula 47]

[0853]

[0854] In the compound represented by formula (L-27) (hereinafter referred to as compound (L-27)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX385).

[0855] In compound (L-27), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX386).

[0856] In compound (L-27), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX387).

[0857] In compound (L-27), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX388).

[0858] In compound (L-27), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX389).

[0859] In compound (L-27), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX390).

[0860] In compound (L-27), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX391).

[0861] In compound (L-27), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX392).

[0862] In compound (L-27), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX393).

[0863] In compound (L-27), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX394).

[0864] In compound (L-27), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX395).

[0865] In compound (L-27), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX396).

[0866] In compound (L-27), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX397).

[0867] In compound (L-27), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX398).

[0868] In compound (L-27), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX399).

[0869] In compound (L-27), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX400).

[0870] [Chemical Formula 48]

[0871]

[0872] In the compound represented by formula (L-28) (hereinafter referred to as compound (L-28)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX401).

[0873] In compound (L-28), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX402).

[0874] In compound (L-28), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX403).

[0875] In compound (L-28), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX404).

[0876] In compound (L-28), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX405).

[0877] In compound (L-28), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX406).

[0878] In compound (L-28), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX407).

[0879] In compound (L-28), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX408).

[0880] In compound (L-28), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX409).

[0881] In compound (L-28), R 2a is methyl, R 2bis a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX410).

[0882] In compound (L-28), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX411).

[0883] In compound (L-28), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX412).

[0884] In compound (L-28), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX413).

[0885] In compound (L-28), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX414).

[0886] In compound (L-28), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX415).

[0887] In compound (L-28), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX416).

[0888] [Chemical Formula 49]

[0889]

[0890] In the compound represented by formula (L-29) (hereinafter referred to as compound (L-29)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX417).

[0891] In compound (L-29), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX418).

[0892] In compound (L-29), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX419).

[0893] In compound (L-29), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX420).

[0894] In compound (L-29), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX421).

[0895] In compound (L-29), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX422).

[0896] In compound (L-29), R2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX423).

[0897] In compound (L-29), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX424).

[0898] In compound (L-29), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX425).

[0899] In compound (L-29), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX426).

[0900] In compound (L-29), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX427).

[0901] In compound (L-29), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX428).

[0902] In compound (L-29), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX429).

[0903] In compound (L-29), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX430).

[0904] In compound (L-29), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX431).

[0905] In compound (L-29), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX432).

[0906] [Chemical Formula 50]

[0907]

[0908] In the compound represented by formula (L-30) (hereinafter referred to as compound (L-30)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX433).

[0909] In compound (L-30), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX434).

[0910] In compound (L-30), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX435).

[0911] In compound (L-30), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX436).

[0912] In compound (L-30), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX437).

[0913] In compound (L-30), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX438).

[0914] In compound (L-30), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX439).

[0915] In compound (L-30), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX440).

[0916] In compound (L-30), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX441).

[0917] In compound (L-30), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX442).

[0918] In compound (L-30), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX443).

[0919] In compound (L-30), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX444).

[0920] In compound (L-30), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX445).

[0921] In compound (L-30), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX446).

[0922] In compound (L-30), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX447).

[0923] In compound (L-30), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX448).

[0924] [Chemical Formula 51]

[0925]

[0926] In the compound represented by formula (L-31) (hereinafter referred to as compound (L-31)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX449).

[0927] In compound (L-31), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX450).

[0928] In compound (L-31), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX451).

[0929] In compound (L-31), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX452).

[0930] In compound (L-31), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX453).

[0931] In compound (L-31), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX454).

[0932] In compound (L-31), R 2a is propyl, R 2b is propyl, R3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX455).

[0933] In compound (L-31), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX456).

[0934] In compound (L-31), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX457).

[0935] In compound (L-31), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX458).

[0936] In compound (L-31), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX459).

[0937] In compound (L-31), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX460).

[0938] In compound (L-31), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX461).

[0939] In compound (L-31), R2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX462).

[0940] In compound (L-31), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX463).

[0941] In compound (L-31), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX464).

[0942] [Chemical Formula 52]

[0943]

[0944] In the compound represented by formula (L-32) (hereinafter referred to as compound (L-32)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX465).

[0945] In compound (L-32), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX466).

[0946] In compound (L-32), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX467).

[0947] In compound (L-32), R 2a is ethyl, R2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX468).

[0948] In compound (L-32), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX469).

[0949] In compound (L-32), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX470).

[0950] In compound (L-32), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX471).

[0951] In compound (L-32), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX472).

[0952] In compound (L-32), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX473).

[0953] In compound (L-32), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX474).

[0954] In compound (L-32), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX475).

[0955] In compound (L-32), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX476).

[0956] In compound (L-32), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX477).

[0957] In compound (L-32), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX478).

[0958] In compound (L-32), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX479).

[0959] In compound (L-32), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX480).

[0960] [Chemical Formula 53]

[0961]

[0962] In the compound represented by formula (L-33) (hereinafter referred to as compound (L-33)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX481).

[0963] In compound (L-33), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX482).

[0964] In compound (L-33), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX483).

[0965] In compound (L-33), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX484).

[0966] In compound (L-33), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX485).

[0967] In compound (L-33), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX486).

[0968] In compound (L-33), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX487).

[0969] In compound (L-33), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX488).

[0970] In compound (L-33), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX489).

[0971] In compound (L-33), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX490).

[0972] In compound (L-33), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX491).

[0973] In compound (L-33), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX492).

[0974] In compound (L-33), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX493).

[0975] In compound (L-33), R 2a is propyl, R 2bis a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX494).

[0976] In compound (L-33), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX495).

[0977] In compound (L-33), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX496).

[0978] [Chemical Formula 54]

[0979]

[0980] In the compound represented by formula (L-34) (hereinafter referred to as compound (L-34)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX497).

[0981] In compound (L-34), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX498).

[0982] In compound (L-34), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX499).

[0983] In compound (L-34), R 2a is ethyl, R 2b is a hydrogen atom, R 3bis a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX500).

[0984] In compound (L-34), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX501).

[0985] In compound (L-34), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX502).

[0986] In compound (L-34), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX503).

[0987] In compound (L-34), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX504).

[0988] In compound (L-34), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX505).

[0989] In compound (L-34), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX506).

[0990] In compound (L-34), R 2ais methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX507).

[0991] In compound (L-34), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX508).

[0992] In compound (L-34), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX509).

[0993] In compound (L-34), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX510).

[0994] In compound (L-34), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX511).

[0995] In compound (L-34), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX512).

[0996] [Chemical Formula 55]

[0997]

[0998] In the compound represented by formula (L-35) (hereinafter referred to as compound (L-35)), R 2a and R 2bis a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX513).

[0999] In compound (L-35), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX514).

[1000] In compound (L-35), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX515).

[1001] In compound (L-35), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX516).

[1002] In compound (L-35), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX517).

[1003] In compound (L-35), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX518).

[1004] In compound (L-35), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX519).

[1005] In compound (L-35), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX520).

[1006] In compound (L-35), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX521).

[1007] In compound (L-35), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX522).

[1008] In compound (L-35), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX523).

[1009] In compound (L-35), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX524).

[1010] In compound (L-35), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX525).

[1011] In compound (L-35), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX526).

[1012] In compound (L-35), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX527).

[1013] In compound (L-35), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX528).

[1014] [Chemical Formula 56]

[1015]

[1016] In the compound represented by formula (L-36) (hereinafter referred to as compound (L-36)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX529).

[1017] In compound (L-36), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX530).

[1018] In compound (L-36), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX531).

[1019] In compound (L-36), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX532).

[1020] In compound (L-36), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX533).

[1021] In compound (L-36), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX534).

[1022] In compound (L-36), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX535).

[1023] In compound (L-36), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX536).

[1024] In compound (L-36), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX537).

[1025] In compound (L-36), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX538).

[1026] In compound (L-36), R 2a is methyl, R 2bis methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX539).

[1027] In compound (L-36), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX540).

[1028] In compound (L-36), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX541).

[1029] In compound (L-36), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX542).

[1030] In compound (L-36), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX543).

[1031] In compound (L-36), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX544).

[1032] [Chemical Formula 57]

[1033]

[1034] In the compound represented by formula (L-37) (hereinafter referred to as compound (L-37)), R 2a and R 2b is a hydrogen atom, R 3bis a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX545).

[1035] In compound (L-37), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX546).

[1036] In compound (L-37), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX547).

[1037] In compound (L-37), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX548).

[1038] In compound (L-37), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX549).

[1039] In compound (L-37), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX550).

[1040] In compound (L-37), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX551).

[1041] In compound (L-37), R 2ais methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX552).

[1042] In compound (L-37), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX553).

[1043] In compound (L-37), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX554).

[1044] In compound (L-37), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX555).

[1045] In compound (L-37), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX556).

[1046] In compound (L-37), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX557).

[1047] In compound (L-37), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX558).

[1048] In compound (L-37), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX559).

[1049] In compound (L-37), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX560).

[1050] [Chemical Formula 58]

[1051]

[1052] In the compound represented by formula (L-38) (hereinafter referred to as compound (L-38)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX561).

[1053] In compound (L-38), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX562).

[1054] In compound (L-38), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX563).

[1055] In compound (L-38), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX564).

[1056] In compound (L-38), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX565).

[1057] In compound (L-38), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX566).

[1058] In compound (L-38), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX567).

[1059] In compound (L-38), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX568).

[1060] In compound (L-38), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX569).

[1061] In compound (L-38), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX570).

[1062] In compound (L-38), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3bCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX571).

[1063] In compound (L-38), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX572).

[1064] In compound (L-38), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX573).

[1065] In compound (L-38), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX574).

[1066] In compound (L-38), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX575).

[1067] In compound (L-38), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX576).

[1068] [Chemical Formula 59]

[1069]

[1070] In the compound represented by formula (L-39) (hereinafter referred to as compound (L-39)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3dCompounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX577).

[1071] In compound (L-39), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX578).

[1072] In compound (L-39), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX579).

[1073] In compound (L-39), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX580).

[1074] In compound (L-39), R 2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX581).

[1075] In compound (L-39), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX582).

[1076] In compound (L-39), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX583).

[1077] In compound (L-39), R 2a is methyl, R 2bis ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX584).

[1078] In compound (L-39), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX585).

[1079] In compound (L-39), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX586).

[1080] In compound (L-39), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX587).

[1081] In compound (L-39), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX588).

[1082] In compound (L-39), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX589).

[1083] In compound (L-39), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX590).

[1084] In compound (L-39), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX591).

[1085] In compound (L-39), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX592).

[1086] [Chemical Formula 60]

[1087]

[1088] In the compound represented by formula (L-40) (hereinafter referred to as compound (L-40)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX593).

[1089] In compound (L-40), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX594).

[1090] In compound (L-40), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX595).

[1091] In compound (L-40), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX596).

[1092] In compound (L-40), R2a is ethyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX597).

[1093] In compound (L-40), R 2a is propyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX598).

[1094] In compound (L-40), R 2a is propyl, R 2b is propyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX599).

[1095] In compound (L-40), R 2a is methyl, R 2b is ethyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX600).

[1096] In compound (L-40), R 2a and R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX601).

[1097] In compound (L-40), R 2a is methyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX602).

[1098] In compound (L-40), R 2a is methyl, R 2b is methyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX603).

[1099] In compound (L-40), R 2a is ethyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX604).

[1100] In compound (L-40), R 2a is ethyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX605).

[1101] In compound (L-40), R 2a is propyl, R 2b is a hydrogen atom, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX606).

[1102] In compound (L-40), R 2a is propyl, R 2b is propyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX607).

[1103] In compound (L-40), R 2a is methyl, R 2b is ethyl, R 3d is a hydrogen atom, R 3b Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX608).

[1104] [Chemical Formula 61]

[1105]

[1106] In the compound represented by formula (L-41) (hereinafter referred to as compound (L-41)), R 2a and R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX609).

[1107] In compound (L-41), R 2a is methyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX610).

[1108] In compound (L-41), R 2a is methyl, R 2b is methyl, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX611).

[1109] In compound (L-41), R 2a is ethyl, R 2b is a hydrogen atom, R 3b is a hydrogen atom, R 3d Compounds having any of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX612). ...

Claims

1. A compound represented by formula (I) (hereinafter referred to as Compound N of the present invention) or an N-oxide thereof (hereinafter referred to as Compound (I) or an N-oxide thereof as Compound of the present invention), [Chemical formula 1] In formula (I), Q shown in the following formula represents a group shown in formula Q1, a group shown in formula Q2, a group shown in formula Q4, a group shown in formula Q5, a group shown in formula Q6, or a group shown in formula Q7 (# represents a bonding site with a sulfur atom, ● represents a bonding site with Het), [Chemical formula 2] [Chemical formula 3] A 1 Indicates NR 5a , oxygen atoms or sulfur atoms, G 1 , G 2 , G 3 and G 4 The combination of: G 1 is a nitrogen atom or CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c combination of; G 1 CR 3a , G 2 is a nitrogen atom, G 3 CR 3d , G 4 CR 3c combination of; G 1 CR 3a , G 2 CR 3b , G 3 is a nitrogen atom, G 4 CR 3c or G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 is the combination of nitrogen atoms, W 1 represents an oxygen atom or a sulfur atom, R 2a and R 2b are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, R 2a and R 2b Together with the nitrogen atom to which they are bound, they may form an aziridinyl, azetidinyl, pyrrolidinyl or piperidinyl group, R 3a , R 3b , R 3c , R 3d , R 3f , R 3i and R 3k are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group B, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group E, a phenyl group which may be substituted by one or more substituents selected from group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group H, or an OR 12 NR 11 R 12 NR 11a R 12a NR 24 NR 11 R 12 NR 24 OR 11 NR 11 C(O)R 13 NR 24 NR 11 C(O)R 13 NR 11 C(O)OR 14 NR 24 NR 11 C(O)OR 14 NR 11 C(O)NR 31 R 32 NR 24 NR 11 C(O)NR 31 R 32 、N=CHNR 31 R 32 、N=S(O) p R 15 R 16 、C(O)R 13 、C(O)OR 17 、C(O)NR 31 R 32 、C(O)NR 11 S(O)2R 23 , CR 30 =NOR 17 NR 11 CR 24 =NOR 17 、S(O) q R 23 , cyano group, nitro group, hydrogen atom or halogen atom, R 3e represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group H, or a hydrogen atom, When Q is a group represented by the formula Q1, R 3a , R 3b and R 3d The two adjacent substituents in may form, together with the two carbon atoms to which they are bonded, a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring and the pyrazine ring may be substituted with one or more substituents selected from Group H}, or a triazole ring which may be substituted with one or more substituents selected from Group I, p represents 0 or 1, q represents 0, 1 or 2, R 30 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a halogen atom, or OR 35 NR 36 R 37 , or hydrogen atoms, R 17 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group D, or a hydrogen atom, R 12 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group J, a C3-C7 cycloalkenyl group which may be substituted by one or more substituents selected from group J, a phenyl group which may be substituted by one or more substituents selected from group D, a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group D, a hydrogen atom, or S(O)2R 23 , R 23 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from Group D, R 11a and R 12a Together with the nitrogen atom to which they are bonded, they represent a 3- to 7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from Group E, R 13 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, or a hydrogen atom, R 14 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D}, R 15 and R 16 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, R 31 represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom, R 32 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, or a hydrogen atom, Het represents a group represented by formula Het1, a group represented by formula Het2, a group represented by formula Het3, a group represented by formula Het4, a group represented by formula Het5, or a group represented by formula Het6, [Chemical formula 4] A 2 represents an oxygen atom, a sulfur atom or NR 5b , A 3 Represents nitrogen atom or CR 4b , A 4 Represents nitrogen atom or CR 4c , A 5 Represents nitrogen atom or CR 4d , A 6 represents an oxygen atom, a sulfur atom or NR 20 , W 2 represents an oxygen atom or a sulfur atom, R 4b , R 4c , R 4d and R 6a The same or different, representing a C1-C6 chain hydrocarbon group, nitro group, OR 18 NR 18 R 19 , cyano group, amino group, halogen atom or hydrogen atom, R 20 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, or a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted by one or more halogen atoms, T represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C3-C5 alkenyloxy)C2-C5 alkyl group, a (C3-C5 alkynyloxy)C2-C5 alkyl group, or a (C1-C5 alkyl)-S(O) group. w -(C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) w -(C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) w -(C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) w -(C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) w -(C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) w -(C2-C5 alkyl) group, and the (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms}, (C3-C7 cycloalkyl)C1-C3 alkyl substituted with one or more substituents selected from group G, C3-C7 cycloalkyl substituted with one or more substituents selected from group G, OR 1 、S(O) v R 1 、OS(O)2R 1 、CH2OR 1 NR 1 R 29 、C(O)R 1 、C(O)NR 1 R 29 NR 29 C(O)R 1 、N=CR 1 R 30 , a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, [Chemical formula 5] [Chemical formula 6] [Chemical formula 7] X 1 Represents nitrogen atom or CR 1a , X 2 Represents nitrogen atom or CR 1b , X 3 Represents nitrogen atom or CR 1c , X 4 Represents nitrogen atom or CR 1d , X 5 Represents nitrogen atom or CR 1e , R 1x represents a C1-C5 chain hydrocarbon group substituted with one or more halogen atoms, OR 7 、OS(O)2R 7 、S(O) m R 7 NR 8 S(O)2R 7 or halogen atoms, R 1a , R 1b , R 1c , R 1d and R 1e are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom, Y 1 Indicates NR 25 , oxygen atoms or sulfur atoms, Y 2 Represents nitrogen atom or CR 26 , Y 3 Represents nitrogen atom or CR 27 , Y 4 Represents nitrogen atom or CR 28 , R 5a , R 5b and R 25 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, R 26 , R 27 and R 28 are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a halogen atom or a hydrogen atom, R 1y represents a C1-C5 chain hydrocarbon group substituted with one or more halogen atoms, OR 7 、OS(O)2R 7 、S(O) m R 7 NR 8 S(O)2R 7 , cyano or halogen atoms, R 1ay and R 7 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group substituted by one or more halogen atoms, m and v are the same or different, representing 0, 1 or 2, w and t are the same or different from each other and represent 0, 1 or 2. R 1 represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C3-C5 alkenyloxy)C2-C5 alkyl group, a (C3-C5 alkynyloxy)C2-C5 alkyl group, a (C1-C5 alkyl)-S(O) t -(C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) t -(C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) t -(C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) t -(C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) t -(C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) t -(C2-C5 alkyl) group, and the (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms}, (C3-C7 cycloalkyl)C1-C3 alkyl substituted with one or more substituents selected from group G, or C3-C7 cycloalkyl substituted with one or more substituents selected from group G, R 18 and R 35 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, R 8 , R 11 , R 19 , R 24 , R 29 , R 36 and R 37 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, or a hydrogen atom, Group B: the group consisting of C1-C6 alkoxy groups which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfanyl groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl groups which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl groups which may be substituted by one or more halogen atoms, cyano groups, hydroxyl groups and halogen atoms. Group C: a group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, and a halogen atom, Group D: C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, hydroxyl group, C1-C6 alkoxy group which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, sulfanyl group, C1-C6 alkylsulfanyl group which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl group which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl group which may be substituted by one or more halogen atoms, amino group, NHR 21 NR 21 R 22 、C(O)R 21 、OC(O)R 21 、C(O)OR 21 , cyano, nitro and halogen atoms, R 21 and R 22 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, Group E: the group consisting of C1-C6 chain hydrocarbon groups which may be substituted by one or more halogen atoms, C1-C6 alkoxy groups which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted by one or more halogen atoms, halogen atoms, oxo groups, hydroxyl groups, cyano groups and nitro groups, Group F: C1-C6 alkoxy which may be substituted with one or more halogen atoms, phenyl which may be substituted with one or more substituents selected from group D, 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group D, C3-C7 cycloalkyl which may be substituted with one or more halogen atoms, 3-7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group C, amino, NHR 21 NR 21 R 22 , a group consisting of a halogen atom and a cyano group, Group G: a group consisting of halogen atoms, C1-C6 haloalkyl groups and cyano groups, Group H: C1-C6 alkyl which may be substituted with one or more halogen atoms, OR 10 NR 9 R 10 、C(O)R 10 、C(O)NR 9 R 10 、OC(O)R 9 、OC(O)OR 9 NR 10 C(O)R 9 NR 10 C(O)OR 9 、C(O)OR 10 , a halogen atom, a nitro group, a cyano group, an amino group and a 5- or 6-membered aromatic heterocyclic group, R 9 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, R 10 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, Group I: a group consisting of a C2-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group D, a C2-C6 alkylcarbonyl group which may be substituted by one or more halogen atoms, a C2-C6 alkoxycarbonyl group which may be substituted by one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms, a methyl group, and a di(C1-C4 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms, Group J: A group consisting of a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a halogen atom, and a cyano group.

2. The compound or N-oxide thereof according to claim 1, wherein Q is a group represented by the formula Q4 or a group represented by the formula Q7.

3. The compound or N-oxide thereof according to claim 1, wherein Q is a group represented by the formula Q5 or a group represented by the formula Q6.

4. The compound or N-oxide thereof according to claim 1, wherein Q is a group represented by the formula Q1 or a group represented by the formula Q2.

5. The compound or N-oxide thereof according to claim 1, wherein Q is a group represented by the formula Q5.

6. The compound or N-oxide thereof according to claim 5, wherein G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c .

7. The compound or N-oxide thereof according to any one of claims 1 to 6, wherein Het is a group represented by the formula Het1, A 3 is a nitrogen atom or CR 4b , A 4 CR 4c , A 5 is a nitrogen atom or CR 4d . 8 . A harmful arthropod control composition comprising an inactive carrier and the compound or N-oxide thereof according to claim 1 .

9. A composition comprising one or more components selected from the group consisting of group (a), group (b), group (c) and group (d), and the compound or N-oxide thereof according to any one of claims 1 to 7, Group (a): a group consisting of insecticidal active ingredients, acaricidal active ingredients and nematicidal active ingredients; Group (b): fungicidal active ingredients; Group (c): plant growth regulating ingredients; Group (d): repellent ingredients.

10. A method for controlling harmful arthropods, wherein: An effective amount of the compound or N-oxide thereof according to any one of claims 1 to 7 or an effective amount of the composition according to claim 9 is applied to a harmful arthropod or a habitat of a harmful arthropod.

11. A seed or a vegetative propagation organ, which holds an effective amount of the compound according to any one of claims 1 to 7 or an N-oxide thereof, or an effective amount of the composition according to claim 9.

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