Softened water treatment device of induced crystallization granulation fluidized bed
By using an induced crystallization granulation fluidized bed softening water treatment device, a highly efficient closed-loop system of crystal fluidization, mass transfer, and self-cleaning is constructed through synchronous multidimensional excitation and reverse rotation structure. This solves the problems of high reagent consumption, high sludge disposal costs, and frequent crystal deposition in high-hardness water treatment, and achieves efficient and stable removal of calcium and magnesium ions and recycling of crystals.
Patent Information
- Application Number
- CN202511106262.0
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2025-08-08
- Publication Date
- 2025-10-17
- Estimated Expiration
- Not applicable · inactive patent
AI Technical Summary
Existing high-hardness water softening technologies suffer from problems such as high reagent consumption, high sludge disposal costs, high resin regeneration frequency, frequent crystallization and deposition, low crystal utilization rate within the device, and unstable treatment efficiency, making it difficult to meet the continuous and stable treatment requirements of high-hardness water.
An induced crystallization granulation fluidized bed softening water treatment device is adopted. Through the linkage of synchronous multi-dimensional excitation system, micro-filter cartridge and insulating shaft reverse rotation structure, cleaning and conveying system and separation filter element, a highly efficient closed-loop system of crystal fluidization, mass transfer, self-cleaning and regeneration is constructed to achieve dynamic adaptation and stable treatment.
It improves the removal rate of calcium and magnesium ions, increases the concentration of crystal particle size distribution, reduces maintenance and operating costs, ensures the stability of treatment efficiency and the recycling rate of crystals, and solves the problems of local reaction dead zones, insufficient mass transfer and clogging in traditional devices.
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Figure CN120794201A_ABST
Abstract
Description
TECHNICAL FIELD
[0001] The present application relates to the technical field of softening water treatment device, in particular to a softening water treatment device of induced crystallization granulation fluidized bed. BACKGROUND
[0002] In the scenes of industrial circulating cooling water system, mine wastewater reuse, high salinity groundwater purification, etc., the softening treatment of high hardness water is the key link to ensure the stable operation of the system. The Ca 2+ , Mg 2+ ions rich in high hardness water can cause a series of problems: in the industrial circulating cooling system, calcium and magnesium ions can form hard scale on the surface of the heat exchanger, which can reduce the heat exchange efficiency by more than 30%, and shorten the equipment maintenance period to 1 / 3 of the traditional operation state. If the high hardness water in the mine wastewater scene is directly discharged, it will cause soil hardening, and if it is reused, it will easily block the pipeline and equipment, which seriously restricts the recycling of water resources. The existing high hardness water softening technology has obvious limitations: the chemical precipitation method needs to add a large amount of reagent, and 5-10 kg of sludge will be produced for every cubic meter of high hardness water treated, which has high subsequent sludge disposal cost and is easy to cause secondary pollution. Ion exchange method relies on resin adsorption, and the regeneration frequency of resin increases significantly in high hardness water environment, which not only consumes a large amount of regeneration reagent, but also produces high-salt wastewater, increasing the processing difficulty. The traditional electrochemical softening device is prone to crystallization and deposition on the surface of the cathode, and the hardness removal efficiency will decrease to less than 50% after 100 hours of operation. In addition, the utilization rate of crystal grains in the device is less than 60%, which is difficult to meet the continuous and stable treatment needs of high hardness water. Therefore, the present application provides a softening water treatment device of induced crystallization granulation fluidized bed to solve the problems in the background art. SUMMARY
[0003] The present application provides a softening water treatment device of induced crystallization granulation fluidized bed to solve the problems in the background art.
[0004] In order to achieve the above object, the technical scheme adopted by the present application is: a kind of induced crystallization granulation fluidized bed softened water treatment device, including cylinder, the inside of the cylinder is equipped with stainless steel cathode layer, stainless steel cathode layer is electrically connected with power negative pole, excitation system is installed on the cylinder, excitation system is connected with the vertical vibration frame of vertical reciprocating motion, vertical vibration frame is slidably connected with translation frame, vertical vibration frame is equipped with the synchronous system of driving vertical vibration frame and translation frame synchronous displacement, synchronous system is drivenly connected with the transmission shaft of alternative positive and negative rotation, translation frame is rotatably installed with micro filter cartridge, micro filter cartridge is rotatably installed with insulated shaft, micro filter cartridge and insulated shaft are all driven by transmission shaft, micro filter cartridge is installed with multiple flow guide rings, the flow guide ring is uniformly distributed with flow guide hole, anode rod is slidably arranged on insulated shaft, adjusting push rod is installed on translation frame, the movable end of adjusting push rod is installed with adjusting frame, anode rod is rotatably installed on adjusting frame, cylinder is equipped with shunt system that distributes cylinder and micro filter cartridge inner chamber in and out water, cylinder is communicated with lifting pipe, lifting pipe and the inner cavity of cylinder are communicated with recovery pipe, lifting pipe is communicated with regeneration pipe, cleaning conveying system is arranged between lifting pipe and regeneration pipe, heating jacket is installed on regeneration pipe, regeneration pipe and the inner cavity of cylinder are communicated with crystal backflow pipe, separation filter element is installed on micro filter cartridge and corresponds the position between crystal backflow pipe and water outlet branch pipe.
[0005] As a preferred technical scheme of the present application, the excitation system includes a backrest mounted on the cylinder, a servo motor mounted on the backrest, a half-tooth gear mounted on the output shaft end of the servo motor, a reciprocating tooth plate mounted on the vertical vibration frame and in transmission connection with the half-tooth gear, the vertical vibration frame being slidably connected with the backrest, two return springs mounted on the bottom surface of the vertical vibration frame and fixedly connected with the backrest at the other end.
[0006] As a preferred technical scheme of the present application, the synchronous system includes a synchronous rack mounted on the vertical vibration frame, a synchronous shaft rotatably connected with the backrest and a tensioning block slidably connected with the backrest, the synchronous shaft being mounted with a synchronous gear engaged with the synchronous rack, the side surface of the tensioning block being mounted with a tensioning spring limited by the backrest, the tensioning block being rotatably mounted with a tensioning wheel, two reciprocating wire rods rotatably mounted on the vertical vibration frame, a first transmission tooth belt drivingly connected with the reciprocating wire rods and the tensioning wheel, the hollow sleeve shaft rotatably mounted on the vertical vibration frame, the two reciprocating wire rods being linked through a second transmission tooth belt, the hollow sleeve shaft being drivingly connected with the second transmission tooth belt, the transmission shaft being rotatably mounted on the translation frame and linked with the hollow sleeve shaft.
[0007] As the preferred technical scheme of the present application, the inside of the hollow sleeve shaft is fixed with a through groove with two open ends and in sliding connection with the transmission shaft, the cross sections of the through groove and the transmission shaft are regular polygons, the inside of the insulating shaft is provided with two symmetrically arranged transmission guide grooves, and the anode rod is provided with a guide strip in sliding connection with the transmission guide groove at a position corresponding to the two transmission guide grooves.
[0008] As the preferred technical scheme of the present application, the micro filter cartridge and the insulating shaft are provided with driven bevel gears, the transmission shaft is provided with a transmission bevel gear, the two driven bevel gears are in transmission connection with the transmission bevel gear, and the two driven bevel gears are arranged on the two sides of the transmission bevel gear.
[0009] As the preferred technical scheme of the present application, the shunt system comprises a water inlet main pipe in communication with the bottom of the cylinder body, a liquid outlet port of the water inlet main pipe is in communication with the inner cavity of the micro filter cartridge through a corrugated hose, a water inlet branch pipe is in communication between the water inlet main pipe and the inner cavity of the cylinder body, a water outlet main pipe in communication with the inner cavity of the micro filter cartridge is arranged on the upper part of the cylinder body, and a water outlet branch pipe is in communication between the water outlet main pipe and the inner cavity of the cylinder body.
[0010] As the preferred technical scheme of the present application, the cleaning and conveying system comprises a lifting shaft in rotary connection with the material lifting pipe and a conveying shaft in rotary connection with the regeneration pipe, the material lifting pipe and the regeneration pipe are provided with transmission motors, output shaft ends of the two transmission motors are fixedly connected with the lifting shaft and the conveying shaft respectively, the lifting shaft is provided with helical lifting blades, the helical lifting blades are uniformly provided with vertically arranged liquid drainage holes, the top of the regeneration pipe is communicated with a high-temperature cleaning liquid inlet pipe, the bottom of the regeneration pipe is respectively communicated with a material discharge valve and a sewage discharge valve, the conveying shaft is provided with helical conveying blades, and the regeneration pipe is respectively provided with a crystal material inlet valve and a temperature probe.
[0011] As the preferred technical scheme of the present application, the separation filter core is an arc-shaped ring structure matched with the curvature of the inner wall of the cylinder body, and the outer wall of the separation filter core is provided with an elastic sealing ring matched with the cylinder body.
[0012] Compared with the prior art, the present application has the beneficial effects that: 1. The present invention strengthens the fluidization of grains through synchronous multi-dimensional excitation to solve the problem of local reaction dead corners. Traditional softening water treatment devices often cause reaction dead zones in local areas due to uneven fluidization of grains, insufficient contact between calcium and magnesium ions and grains, and low removal efficiency. The present invention constructs a vertical and horizontal composite excitation mechanism through the linkage and coordination of the excitation system and the synchronization system. In the excitation system, the servo motor drives the half-tooth gear to cooperate with the return spring to realize high-frequency vertical reciprocating motion of the vertical vibration frame. The synchronization system converts the vertical motion into horizontal motion of the translation frame through precise transmission of the synchronous rack, synchronous gear and transmission toothed belt, so that the microfiltration cartridge obtains vertical vibration and horizontal disturbance at the same time. This synchronous multi-dimensional excitation breaks the sedimentation inertia of the grains and expands the movement trajectory of the grains. Compared with traditional static or single-direction vibration structures, the effective contact area between the grains and calcium and magnesium ions in water is increased, the induced crystallization reaction rate is accelerated, the calcium and magnesium ion removal rate is improved, and local reaction dead corners are eliminated; 2. Due to insufficient mass transfer, existing devices are prone to localized excessive supersaturation, resulting in amorphous precipitation and scattered distribution of crystalline particle size. The present invention designs a coaxial counter-rotating structure for the microfiltration cartridge and the insulating shaft. The transmission shaft drives the driven bevel gears on both sides through the transmission bevel gear, causing the microfiltration cartridge and the insulating shaft to rotate in the opposite direction, forming a high-intensity shear flow field in the gap between the two. This flow field, on the one hand, breaks up bubble aggregates and promotes the rapid separation of H2 bubbles in the cathode area, and on the other hand, accelerates the H2 in the anode area. + , ClO - Diffusion to the cathode region, pushing the cathode region OH - The uniform distribution of carbonate ions and the complex turbulent field generated by synchronous excitation reduce the pH distribution deviation in the device and improve the concentration of crystal particle size distribution, effectively solving the problems of low crystallization efficiency and uneven particle size in traditional devices and ensuring the stability of crystal sedimentation separation. 3. The microfiltration holes and diversion holes of traditional devices are easily clogged due to the adhesion of crystal particles, requiring frequent shutdowns for cleaning and high maintenance costs. The present invention constructs a dual anti-clogging mechanism through multi-system linkage. The high-frequency mechanical vibration generated by synchronous multi-dimensional excitation continuously acts on the surface of the microfiltration cartridge, causing tiny crystal particles attached to the surface of the microfiltration pores to fall off. The counter-rotation of the microfiltration cartridge and the insulating shaft generates water shear force, further stripping impurities from the filter pores. At the same time, the periodic pressure changes caused by the synchronous movement can dredge residual impurities in the diversion holes and microfiltration pores. Combined with the precise pore size design of the microfiltration pores of 10-100μm, the coordinated anti-clogging effect of vibration, shear stripping, and pressure dredging is achieved. 4、The prior art is easy to lose with the water flow, and the regeneration treatment efficiency is low, which leads to high cost of crystal seed supplement, the closed loop regeneration system of crystal separation, cleaning, activation and reflux is constructed through the linkage of the cleaning conveying system and the separation filter core, the large particle crystal grains enter the material lifting pipe through the recovery pipe, the spiral lifting blade realizes the separation of the crystal grains and the liquid through the liquid leakage hole, the 90 DEG C high temperature cleaning liquid in the regeneration pipe cooperates with the spiral conveying blade to stir, efficiently removes the impurities on the surface of the crystal grains, the 400 DEG C heating jacket activates the crystal lattice activity, the arc-shaped ring-shaped separation filter core accurately intercepts the small crystal grains, and returns to the reaction zone through the crystal reflux pipe, the system significantly improves the recycling rate of the crystal grains, greatly reduces the crystal seed supplement amount, and effectively reduces the operation cost; 5、The traditional device is fixed in position, the excitation strength is not adjustable, the water hardness fluctuation adaptability is poor, and the treatment effect is unstable, the dynamic adaptation is realized through the cooperation of the adjusting system and the excitation system, the adjusting push rod can accurately control the axial position of the anode rod through the adjusting frame, the exposed area of the anode is changed to adjust the electrolysis reaction strength, the servo motor of the excitation system can adjust the excitation amplitude and frequency in real time, within the specified fluctuation range of the water hardness, the crystallization reaction stability is maintained by strengthening the fluidization and mass transfer efficiency of the crystal grains. BRIEF DESCRIPTION OF DRAWINGS
[0013] Figure 1 It is a whole structure schematic view of a softening water treatment device of an induced crystallization prilling fluidized bed. Figure 2 It is a whole structure schematic view of a softening water treatment device of an induced crystallization prilling fluidized bed. Figure 1 It is a local enlarged structure schematic view of A in the figure. Figure 3 It is a structure schematic view of a transmission motor and a water inlet main pipe. Figure 4 It is a structure schematic view of a transmission motor and a water inlet main pipe. Figure 3 It is a structure schematic view of a transmission motor and a water inlet main pipe. Figure 5 It is a structure schematic view of a transmission motor and a water inlet main pipe. Figure 4 It is a local enlarged structure schematic view of B in the figure. Figure 6 It is a structure schematic view of a transmission motor and a water inlet main pipe. Figure 7 It is a structure schematic view of a transmission motor and a water inlet main pipe. Figure 8 It is a structure schematic view of a transmission motor and a water inlet main pipe. Figure 7 It is a local enlarged structure schematic view of C in the figure. Figure 9 It is a structure schematic view of a transmission motor and a water inlet main pipe. Figure 10 It is a structure schematic view of a transmission motor and a water inlet main pipe. Figure 9 It is a local enlarged structure schematic view of D in the figure.
[0014] In the drawings, the components represented by each reference sign are listed as follows: 1. Cylinder; 2. Vertical vibration frame; 3. Translation frame; 4. Drive shaft; 5. Microfiltration cartridge; 6. Insulation shaft; 7. Guide ring; 8. Anode rod; 9. Adjustment push rod; 10. Adjustment frame; 11. Water inlet main pipe; 12. Water inlet branch pipe; 13. Water outlet main pipe; 14. Water outlet branch pipe; 15. Lifting pipe; 16. Recovery pipe; 17. Regeneration pipe; 18. Heating jacket; 19. Crystal reflux pipe; 20. Separation filter element; 21. Back frame; 22. Servo motor; 23. Half-tooth gear; 24. Reset spring Spring; 25. Synchronous rack; 26. Synchronous shaft; 27. Tensioning block; 28. Synchronous gear; 29. Tensioning spring; 30. Tensioning pulley; 31. Reciprocating screw; 32. Hollow sleeve shaft; 33. Lifting shaft; 34. Conveying shaft; 35. Spiral lifting blade; 36. Drain hole; 37. High-temperature cleaning liquid inlet pipe; 38. Discharge valve; 39. Drain valve; 40. Spiral conveying blade; 41. Crystal feed valve; 42. Temperature probe; 43. Diversion hole; 44. Transmission motor; 45. Reciprocating gear plate. DETAILED DESCRIPTION
[0015] The following description is intended to disclose the present invention so that those skilled in the art can implement the present invention. The preferred embodiments described below are merely examples, and those skilled in the art may conceive of other obvious variations.
[0016] like Figures 1-10 As shown, an induced crystallization granulation fluidized bed softening water treatment device includes a cylinder 1, an excitation system is installed on the cylinder 1, the excitation system is connected to a vertical vibration frame 2 that can vertically reciprocate, a translation frame 3 is slidably connected to the vertical vibration frame 2, a synchronization system is provided on the vertical vibration frame 2 for driving the vertical vibration frame 2 and the translation frame 3 to synchronously move, and a transmission shaft 4 that can alternately rotate forward and reverse is connected to the synchronization system; The excitation system includes a back frame 21 mounted on the cylinder 1, a servo motor 22 mounted on the back frame 21, a half-tooth gear 23 mounted on the output shaft end of the servo motor 22, a reciprocating toothed plate 45 drivingly connected to the half-tooth gear 23 mounted on the vertical vibration frame 2, the vertical vibration frame 2 and the back frame 21 being slidably connected, and two return springs 24 mounted on the bottom surface of the vertical vibration frame 2, the other ends of the two return springs 24 being fixedly connected to the back frame 21; The synchronization system includes a synchronization rack 25 mounted on the vertical vibration frame 2, a synchronization shaft 26 rotatably connected to the back frame 21, and a tensioning block 27 slidably connected to the back frame 21. The synchronization shaft 26 is mounted with a synchronization gear 28 that meshes with the synchronization rack 25. The side of the tensioning block 27 is mounted with a tensioning spring 29 limited by the back frame 21. A tensioning pulley 30 is rotatably mounted on the tensioning block 27. Two reciprocating screws 31 are rotatably mounted on the vertical vibration frame 2. A first transmission toothed belt is installed on the synchronization shaft 26. A reciprocating screw 31 and the tensioning pulley 30 are both transmission-connected to the first transmission toothed belt. The first transmission tooth belt is sequentially wound around the pulley on the synchronous shaft 26, the tension pulley 30 and the pulley of the reciprocating screw rod 31; Due to the up-down reciprocating mode of the synchronous rack 25, the synchronous shaft 26 and the transmission shaft 4 are alternately reversed; The hollow sleeve shaft 32 is rotatably installed on the vertical vibration frame 2, the two reciprocating screw rods 31 are connected through the second transmission tooth belt, the hollow sleeve shaft 32 is in transmission connection with the second transmission tooth belt, and the transmission shaft 4 is rotatably installed on the translation frame 3 and connected with the hollow sleeve shaft 32.
[0017] The inside of the hollow sleeve shaft 32 is fixedly provided with a through groove with two open ends and in sliding connection with the transmission shaft 4, the cross sections of the through groove and the transmission shaft 4 are regular polygons, the inside of the insulating shaft 6 is provided with two symmetrically arranged transmission guide grooves, and the anode rod 8 is provided with a guide strip in sliding connection with the transmission guide grooves at positions corresponding to the two transmission guide grooves; When the servo motor 22 drives the half-tooth gear 23 to rotate, intermittent meshing transmission is formed between the half-tooth gear 23 and the vertical vibration frame 2, and the elastic reset action of the reset spring 24 can drive the vertical vibration frame 2 to realize high-frequency vertical reciprocating motion; Through the meshing transmission between the synchronous rack 25 and the synchronous gear 28, the linear motion of the vertical vibration frame 2 is converted into the rotary motion of the synchronous shaft 26, and then the reciprocating screw rod 31 and the hollow sleeve shaft 32 are connected through the transmission tooth belt, so that the vertical excitation and the horizontal excitation are accurately synchronized; The cooperation between the tension pulley 30 and the tension spring 29 ensures the stable transmission of the transmission tooth belt, and the sliding connection between the regular polygon through groove and the transmission shaft 4 ensures the power transmission while being compatible with the excitation displacement; The synchronous excitation motion of the vertical vibration frame 2 and the translation frame 3 can strengthen the flow state of the crystal grains and improve the reaction efficiency; The synchronous multi-dimensional excitation transmits the multi-dimensional excitation force to the micro filter cartridge 5 and the internal crystal grains, so that the crystal grains form a uniform and high-strength suspended flow state in the cathode reaction zone, the up-down pulsation generated by the vertical excitation can break the crystal grain sedimentation inertia and avoid local accumulation; The horizontal disturbance formed by the horizontal excitation expands the crystal grain motion track and increases the collision contact probability with calcium and magnesium ions in water. Compared with the traditional static or single-direction vibration structure, the synchronous motion increases the effective contact area of the crystal grains with the scale-forming ions, accelerates the crystallization reaction rate, improves the removal rate of calcium and magnesium ions, and solves the problem of local reaction dead zone caused by uneven crystal grain flow in the traditional device; On the other hand, the synchronous reciprocating motion optimizes the mass transfer conditions and promotes the crystallization balance. The synchronous excitation drives the water flow to form a complex turbulent flow field, which on the one hand accelerates the diffusion of H + , ClO - , etc. generated in the anode area to the cathode area, and on the other hand promotes the diffusion of OH -The dynamic mass transfer environment reduces the pH value distribution deviation in the device, the crystal particle size distribution is more concentrated, the low crystallization efficiency and uneven particle size caused by insufficient mass transfer in the traditional device are solved, and the stability of crystal grain sedimentation and separation is improved; At the same time, the synchronous reciprocating motion can enhance the self-cleaning ability and reduce the risk of fouling. The vertical and horizontal combined excitation force continuously acts on the surface of the micro filter cartridge 5. Through high-frequency mechanical vibration, the small crystal particles attached to the surface of the micro filter hole are detached. Combined with the water flow shear force generated by the rotation of the micro filter cartridge 5, a double anti-blocking mechanism is formed. The periodic pressure change generated by the synchronous motion can also dredge the residual impurities in the guide hole 43 and the micro filter hole, avoiding the blockage of the hole. The synchronous reciprocating motion is suitable for water quality fluctuations and improves the operation stability. The strength of the synchronous excitation can be adjusted by the servo motor 22. When the water hardness fluctuates, the excitation amplitude can be increased to strengthen the crystal grain fluidization and mass transfer efficiency, ensuring that the crystallization reaction efficiency is not affected by water quality changes. The micro filter cartridge 5 is rotatably installed on the translation frame 3. The micro filter cartridge 5 is rotatably installed in the micro filter cartridge 5. The micro filter cartridge 5 and the micro filter cartridge 5 are both driven by the transmission shaft 4 and coaxially rotate in opposite directions. The micro filter cartridge 5 and the micro filter cartridge 6 are both installed with driven bevel gears. The transmission shaft 4 is installed with a transmission bevel gear. The two driven bevel gears are both in transmission connection with the transmission bevel gear. The two driven bevel gears are respectively arranged on both sides of the transmission bevel gear. The transmission shaft 4 drives the two driven bevel gears on both sides through the transmission bevel gear, realizing the coaxial opposite rotation of the micro filter cartridge 5 and the micro filter cartridge 6. The coaxial opposite rotation of the micro filter cartridge 5 and the micro filter cartridge 6 can strengthen the interface shear and mass transfer efficiency. The opposite rotation of the micro filter cartridge 5 and the micro filter cartridge 6 forms a high-strength shear flow field in the gap between them. The water flow shear force is significantly improved compared to the one-way rotation structure. This shear effect can break up gas bubble aggregates in the water body, promote the rapid detachment of H2 gas bubbles generated in the cathode reaction zone from the liquid surface, and avoid the blocking of gas bubbles from contacting the crystal grains and ions. On the other hand, it accelerates the diffusion of H + , ClO - to the cathode area, and pushes OH - and carbonate ions to the cathode area, making the distribution of carbonate ions uniform, improving the ion diffusion coefficient in the device compared to the traditional device, and solving the problem of local reaction lag caused by uneven mass transfer in the traditional one-way rotation structure. At the same time, the opposite rotation of the micro filter cartridge 5 and the micro filter cartridge 6 can improve the self-cleaning ability of the micro filter structure. The bidirectional water flow generated by the opposite rotation can effectively strip the small crystal particles attached to the surface of the filter hole. And the reverse rotation of the micro filter cartridge 5 and the insulating shaft 6 can optimize the crystal grain fluidization and crystallization environment. The rotation of the micro filter cartridge 5 drives the water flow in the outer cathode area to form a circulating flow, and the rotation of the insulating shaft 6 generates an inner water flow, which forms a reverse disturbance, so that the crystal grains are in a three-dimensional suspended state in the composite flow field, and the fluidization uniformity is improved; This dynamic environment avoids the accumulation of crystal grains on the cylinder wall, while promoting moderate collisions between crystal grains, accelerating the growth and agglomeration of crystalline particles; Further, the reverse rotation of the micro filter cartridge 5 and the insulating shaft 6 can enhance the electrolysis reaction synergy. The reverse rotation makes the water flow in the anode and cathode reaction areas form a closed loop circulation. The HClO and other oxidizing substances generated in the anode area can oxidize and decompose organic impurities in the water when entering the cathode area, reducing the coverage of organic matter on the active sites of the crystal grains, and improving the retention rate of the crystal grain induction activity. At the same time, the bidirectional rotation enhances the water electrolysis efficiency; The micro filter cartridge 5 is uniformly distributed with micro filter holes, and the micro filter cartridge 5 is installed with a plurality of flow guide rings 7 arranged in a linear array; The flow guide ring 7 is uniformly distributed with flow guide holes 43, and the cross section of the flow guide ring 7 is isosceles trapezoidal. The ratio of the radius of the flow guide ring 7 to the radius of the inner cavity of the cylinder body 1 is 0.75 to 1; The insulating shaft 6 is slidably provided with an anode rod 8; The insulating shaft 6 is internally provided with two symmetrically arranged transmission guide grooves, and the anode rod 8 is installed with a guide strip slidably connected with the two transmission guide grooves at corresponding positions; The micro filter cartridge 5 is an anode reaction area, and the outside of the micro filter cartridge 5 is a cathode reaction area; The translation frame 3 is installed with an adjusting push rod 9, the movable end of the adjusting push rod 9 is installed with an adjusting frame 10, and the anode rod 8 is rotatably installed on the adjusting frame 10; The inner side of the cylinder body 1 is provided with a stainless steel cathode layer, the stainless steel cathode layer is electrically connected with the negative electrode of the power supply, the anode rod 8 is electrically connected with the positive electrode of the power supply, the outer side of the cylinder body 1 is provided with an insulating layer, the insulating layer is an epoxy resin composite material, and the anode rod 8 is a titanium alloy material provided with a titanium-based lead dioxide coating.
[0018] The stainless steel cathode layer and the anode rod 8 form a high-efficiency electrolysis loop, the polytetrafluoroethylene insulating shaft 6 and the epoxy resin insulating layer ensure the directional performance of the electrochemical reaction, avoid current loss, the transmission guide groove and the guide strip realize the axial adjustment and rotary transmission compatibility of the anode rod 8, and the exposure area of the anode can be accurately controlled through the adjusting push rod 9. This structure solves the problem of unadjustable reaction intensity caused by fixed electrode position in the traditional electrode; The bottom of the cylinder body 1 is communicated with a water inlet main pipe 11, the liquid outlet port of the water inlet main pipe 11 is communicated with the inner cavity of the microfiltration cylinder 5 through a corrugated hose, the water inlet main pipe 11 is communicated with the inner cavity of the cylinder body 1 through a water inlet branch pipe 12, the upper part of the cylinder body 1 is provided with a water outlet main pipe 13 communicated with the inner cavity of the microfiltration cylinder 5, and the water outlet main pipe 13 is communicated with the inner cavity of the cylinder body 1 through a water outlet branch pipe 14; A material lifting pipe 15 is communicated with the cylinder body 1, a recovery pipe 16 is communicated between the material lifting pipe 15 and the inner cavity of the cylinder body 1, a regeneration pipe 17 is communicated with the material lifting pipe 15, a cleaning conveying system is arranged between the material lifting pipe 15 and the regeneration pipe 17, a heating jacket 18 is arranged on the regeneration pipe 17, and a crystal backflow pipe 19 is communicated between the regeneration pipe 17 and the inner cavity of the cylinder body 1; The cleaning conveying system comprises a lifting shaft 33 rotatably connected to the material lifting pipe 15 and a conveying shaft 34 rotatably connected to the regeneration pipe 17, a transmission motor 44 is arranged on each of the material lifting pipe 15 and the regeneration pipe 17, the output shaft ends of the two transmission motors 44 are fixedly connected with the lifting shaft 33 and the conveying shaft 34 respectively, a spiral lifting blade 35 is arranged on the lifting shaft 33, the spiral lifting blade 35 is uniformly provided with vertical liquid drainage holes 36, a high-temperature cleaning liquid inlet pipe 37 is communicated with the top of the regeneration pipe 17, a material discharge valve 38 and a sewage discharge valve 39 are respectively communicated with the bottom of the regeneration pipe 17, a spiral conveying blade 40 is arranged on the conveying shaft 34, and a crystal feeding valve 41 and a temperature probe 42 are respectively arranged on the regeneration pipe 17; In use, the device is provided with a microcontroller; The liquid inlet temperature of the high-temperature cleaning liquid inlet pipe 37 is preferably 90 DEG C, and the working temperature of the heating jacket 18 is preferably 400 DEG C; The spiral lifting blade 35 cooperates with the liquid drainage hole 36 to realize synchronous grain conveying and liquid separation, 90 DEG C high-temperature cleaning liquid is fully contacted with the grain through the stirring of the spiral conveying blade 40, and the surface-attached impurities can be efficiently removed; The high-temperature activation treatment of the 400 DEG C heating jacket 18 restores the lattice activity of the grain, the flow guide hole 43, the microfiltration hole and the liquid drainage hole 36 adopt a hole diameter ratio of 5:1:3, and are respectively matched with the water flow guiding, grain intercepting and liquid draining functions, the system solves the problems of low regeneration efficiency and large loss of the traditional grain, improves the recycling rate of the grain, and reduces the cost of seed supplement; The position between the corresponding crystal backflow pipe 19 of the microfiltration cylinder 5 and the water outlet branch pipe 14 is provided with a separation filter element 20.
[0019] The separation filter element 20 is an arc-shaped ring structure matched with the curvature of the inner wall of the cylinder body 1, the filtering surface of the separation filter element 20 is uniformly provided with filtering holes with a hole diameter of 5 microns, and the outer wall of the separation filter element 20 is provided with an elastic sealing ring matched with the cylinder body 1; The filtering surface of the separation filter element 20 is arranged on the bottom surface of the separation filter element 20; The separation filter core 20 with an arc-shaped ring structure is perfectly matched with the inner wall of the cylinder 1, the 5-micron filter hole can accurately intercept the fine grains rising with the water flow, the elastic sealing ring ensures the filtering sealing performance, prevents the leakage of the grains from the edge of the filter core, the structure is arranged between the crystal backflow pipe 19 and the water outlet branch pipe 14, realizes the interception and backflow utilization of the grains, and solves the problem of high grain loss rate of the traditional separation structure.
[0020] The working process of the application starts from the water inlet stage, the water inlet main pipe 11 divides the water to be treated into two paths, which respectively enter the cathode reaction area through the water inlet branch pipe 12 and enter the anode reaction area in the micro filter cylinder 5 through the corrugated hose; Meanwhile, the servo motor 22 in the excitation system drives the half-tooth gear 23 to rotate, and cooperates with the reset spring 24 to make the vertical vibration frame 2 high-frequency vertically reciprocate, the synchronous system converts the vertical movement into the horizontal movement of the horizontal frame 3 through the synchronous rack 25, the synchronous gear 28 and the transmission toothed belt, and realizes the accurate synchronization of the vertical and horizontal excitation, the multi-dimensional excitation is transmitted to the micro filter cylinder 5, the grains in the cathode reaction area form a uniform suspended and fluidized state, the transmission shaft 4 drives the micro filter cylinder 5 and the insulating shaft 6 to rotate in opposite directions through the transmission bevel gear, a shear flow field is formed inside and outside the micro filter cylinder 5, the mass transfer is strengthened and the micro filter hole is cleaned, and the anode rod 8 realizes position adjustment under the control of the adjusting push rod 9 through the cooperation of the transmission guide groove and the guide strip, forms an electrolysis loop with the stainless steel cathode layer, and the OH - , CO3 2- In the water flow guided by the flow guide ring 7, the calcium and magnesium ions crystallize on the surface of the grains; With the reaction, the large-grained crystals enter the lifting pipe 15 through the recovery pipe 16, are transported to the regeneration pipe 17 by the spiral lifting blade 35 of the cleaning conveying system, are cleaned by the 90 DEG C high-temperature cleaning liquid and the 400 DEG C heating jacket 18, and then are returned to the reaction area through the crystal backflow pipe 19, the separation filter core 20 intercepts the fine grains to prevent loss, and finally the treated water is discharged through the water outlet branch pipe 14 and the water outlet main pipe 13; The core logic of the linkage and cooperation of each system is that the excitation system provides a power basis for the grain fluidization, the synchronous system guarantees the coordination of the excitation and the transmission to avoid energy waste, the opposite rotation of the micro filter cylinder 5 and the insulating shaft 6 strengthens the mass transfer and self-cleaning and depends on the pretreatment effect of the excitation system, the electrode system dynamically adjusts the reaction strength according to the water quality through the adjusting push rod 9, the regeneration system converts the large grains generated in the reaction into recyclable crystal seeds, and the separation filter core 20 makes up for the loss of the fine grains caused by the excitation and rotation, to form a closed loop of fluidization, reaction, separation and regeneration.
[0021] The above only describes the preferred embodiments of the application and is not used to limit the application, any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the application should be included in the protection scope of the application.
Claims
1. An induced crystallization granulation fluidized bed softening water treatment device, comprising a cylinder (1), characterized in that: A stainless steel cathode layer is provided on the inner side of the cylinder (1), and the stainless steel cathode layer is electrically connected to the negative electrode of the power supply. An excitation system is installed on the cylinder (1), and a vertical vibration frame (2) capable of vertical reciprocating motion is connected to the excitation system. A translation frame (3) is slidably connected to the vertical vibration frame (2). A synchronization system for driving the vertical vibration frame (2) and the translation frame (3) to synchronously shift is provided on the vertical vibration frame (2). A transmission shaft (4) capable of alternating forward and reverse rotation is connected to the synchronization system. A microfiltration cartridge (5) is rotatably installed on the translation frame (3), and an insulating shaft (6) is rotatably installed in the microfiltration cartridge (5). Both the microfiltration cartridge (5) and the insulating shaft (6) are driven by the transmission shaft (4). A plurality of guide rings (7) are installed on the microfiltration cartridge (5), and guide holes (43) are uniformly distributed on the guide rings (7). An anode rod (8) is slidably connected to the insulating shaft (6). The translation frame (3) is provided with a plurality of guide rings (7). ) is installed with an adjusting push rod (9), the movable end of the adjusting push rod (9) is installed with an adjusting frame (10), the anode rod (8) is rotatably installed on the adjusting frame (10), the cylinder (1) is provided with a diversion system for distributing water in and out of the inner cavity of the cylinder (1) and the microfiltration cylinder (5), the cylinder (1) is connected with a feed pipe (15), a recovery pipe (16) is connected between the feed pipe (15) and the inner cavity of the cylinder (1), the feed pipe (15) is connected with a regeneration pipe (17), a cleaning and conveying system is provided between the feed pipe (15) and the regeneration pipe (17), a heating jacket (18) is installed on the regeneration pipe (17), a crystal return pipe (19) is connected between the regeneration pipe (17) and the inner cavity of the cylinder (1), and a separation filter element (20) is installed on the microfiltration cylinder (5) and at a position corresponding to the crystal return pipe (19) and the outlet branch pipe (14).
2. The induced crystallization granulation fluidized bed softening water treatment device according to claim 1, characterized in that: The excitation system includes a back frame (21) mounted on the cylinder (1), a servo motor (22) mounted on the back frame (21), a half-tooth gear (23) mounted on the output shaft end of the servo motor (22), a reciprocating toothed plate (45) transmission-connected to the half-tooth gear (23) mounted on the vertical vibration frame (2), the vertical vibration frame (2) is slidably connected to the back frame (21), and two return springs (24) are mounted on the bottom surface of the vertical vibration frame (2), and the other ends of the two return springs (24) are fixedly connected to the back frame (21).
3. The induced crystallization granulation fluidized bed softening water treatment device according to claim 1, characterized in that: The synchronization system comprises a synchronization rack (25) mounted on the vertical vibration frame (2), a synchronization shaft (26) rotatably connected to the back frame (21), and a tensioning block (27) slidably connected to the back frame (21), wherein the synchronization shaft (26) is mounted with a synchronization gear (28) meshing with the synchronization rack (25), a tensioning spring (29) limited by the back frame (21) is mounted on the side of the tensioning block (27), a tensioning wheel (30) is rotatably mounted on the tensioning block (27), and a synchronization gear (28) meshing with the synchronization rack (25) is mounted on the synchronization shaft (26), and a tensioning spring (29) limited by the back frame (21) is mounted on the side of the tensioning block (27). There are two reciprocating screw rods (31), a first transmission toothed belt is installed on the synchronization shaft (26), one of the reciprocating screw rods (31) and the tensioning wheel (30) are both connected to the first transmission toothed belt, a hollow sleeve shaft (32) is rotatably installed on the vertical vibration frame (2), the two reciprocating screw rods (31) are linked through a second transmission toothed belt, the hollow sleeve shaft (32) is connected to the second transmission toothed belt, the transmission shaft (4) is rotatably installed on the translation frame (3), and the transmission shaft (4) is linked to the hollow sleeve shaft (32).
4. The induced crystallization granulation fluidized bed softening water treatment device according to claim 3, characterized in that: A through groove with two ends open and slidably connected to the transmission shaft (4) is fixedly provided inside the hollow sleeve shaft (32), and the cross-sections of the through groove and the transmission shaft (4) are both regular polygons. Two symmetrically arranged transmission guide grooves are provided inside the insulating shaft (6), and guide bars slidably connected to the transmission guide grooves are installed on the anode rod (8) at positions corresponding to the two transmission guide grooves.
5. The induced crystallization granulation fluidized bed softening water treatment device according to claim 1, characterized in that: The microfiltration cartridge (5) and the insulating shaft (6) are both equipped with driven bevel gears, and the transmission shaft (4) is equipped with a transmission bevel gear. The two driven bevel gears are both connected to the transmission bevel gear, and the two driven bevel gears are respectively arranged on both sides of the transmission bevel gear.
6. The induced crystallization granulation fluidized bed softening water treatment device according to claim 1, characterized in that: The diversion system comprises a water inlet main pipe (11) connected to the bottom of the cylinder (1); a liquid outlet port of the water inlet main pipe (11) is connected to the inner cavity of the microfiltration cartridge (5) through a corrugated hose; a water inlet branch pipe (12) is connected between the water inlet main pipe (11) and the inner cavity of the cylinder (1); a water outlet main pipe (13) connected to the inner cavity of the microfiltration cartridge (5) is installed on the upper part of the cylinder (1); and a water outlet branch pipe (14) is connected between the water outlet main pipe (13) and the inner cavity of the cylinder (1).
7. The induced crystallization granulation fluidized bed softening water treatment device according to claim 1, characterized in that: The cleaning and conveying system includes a lifting shaft (33) rotatably connected to the lifting pipe (15) and a conveying shaft (34) rotatably connected to the regeneration pipe (17), the lifting pipe (15) and the regeneration pipe (17) are both equipped with a transmission motor (44), the output shaft ends of the two transmission motors (44) are respectively fixedly connected to the lifting shaft (33) and the conveying shaft (34), the lifting shaft (33) is equipped with a spiral lifting blade (35), and the spiral lifting blade (35) is evenly distributed with vertically arranged drain holes (36), the top of the regeneration pipe (17) is connected to a high-temperature cleaning liquid inlet pipe (37), the bottom of the regeneration pipe (17) is respectively connected to a discharge valve (38) and a sewage valve (39), the conveying shaft (34) is equipped with a spiral conveying blade (40), and the regeneration pipe (17) is respectively equipped with a crystal feed valve (41) and a temperature probe (42).
8. The induced crystallization granulation fluidized bed softening water treatment device according to claim 1, characterized in that: The separation filter element (20) is an arc-shaped annular structure adapted to the curvature of the inner wall of the cylinder (1), and the outer wall of the separation filter element (20) is provided with an elastic sealing ring that fits the cylinder (1).
Citation Information
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