Herbicidal mixture comprising l-glufosinate or its salt and a second herbicide

Abstract

To provide a herbicidal mixture exhibiting higher activity in burndown programs, industrial vegetation management and forestry, vegetable and perennial crops, and turf and lawn.SOLUTION: (a) L-glufosinate and / or its salts as compound I; and (b) at least one herbicidal compound II which is cinmethylin, wherein L-glufosinate comprises more than 70% by weight of the L-enantiomer and wherein the weight ratio of compound I to compound II is from 1000:1 to 1:500.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a compound containing L-glufosinate or a salt thereof and chlorthiamid, dichlobenil, flupoxam, indaziflam, isoxaben, triaziflam, 1-cyclohexyl-5-pentafluorophenyloxy-14-[1,2,4,6]thiatriazin-3-ylamine (CAS 10111122-00001), and a compound containing ...). 175899-01-1, diflufenzopyr, diflufenzopyr-sodium, naptalam and naptalam-sodium, bromobutide, chlorflurenol, chlorflurenol-methyl, cinmethylin, cumyluron, cyclopyrimorate (CAS 175899-01-1), 499223-49-3 and its salts and esters, dalapon, dazomet, difenzoquat, difenzoquat-methylsulfate, dimethipin, DSMA, dymron, endothal and its salts, etobenzanid, flurenol, flurenol-butyl, flurprimidol, fosamine, fosamine-ammonium, indanofan, maleic hydrazide, mefluidide, metam, methiozolin (CAS 10144-10-1),and a herbicide compound II selected from the group consisting of methyl azide, methyl bromide, methyl-dymron, methyl iodide, MSMA, oleic acid, oxaziclomefone, pelargonic acid, pyributicarb, quinoclamine, tridiphane; bilanaphos (bialaphos) and bilanaphos-sodium. The present invention further relates to methods for controlling undesirable vegetation in burndown programs, industrial vegetation management and forestry, vegetable and perennial crops, and turf and lawn. [Background technology]

[0002] Burndown, i.e., the complete removal of weeds from the soil by application of herbicides before crop planting or pre-emergence, is an important tool in modern weed management. Weeds present at planting generally outgrow the crop and thus compete very early in the growing season, thereby damaging the crop and reducing crop yield. Therefore, it is desirable to plant the crop in a weed-free seedbed or to ensure that the crop is essentially weed-free when it emerges. Burndown can also entail weed control in fallow fields.

[0003] In industrial weed management and forestry, it is desirable to control a wide range of weeds over a long period of time. It may also be desirable to control large weeds or taller species such as shrubs or trees. Industrial weed management includes, for example, railroad and highway right-of-way management, fence lines, and non-cultivated areas (for example, industrial and construction sites, gravel areas, roads or sidewalks, etc.). Forestry includes, for example, the removal of existing forests or shrublands, the removal of regeneration after mechanical deforestation, or the control of weeds under forestry plantations. In the latter case, it may be desirable to shield the desired trees from contact with the spray solution containing the herbicide mixture according to the present invention.

[0004] Vegetable crops include, for example, eggplant, beans, peppers, cabbage, chilies, cucumbers, eggplant, lettuce, melons, onions, potatoes, sweet potatoes, spinach, tomatoes, etc. For weed control in vegetable crops, it may be desirable to shield the crops from contact with spray solutions containing the herbicidal mixtures according to the invention.

[0005] Perennial crops include tree, nut, and vine crops such as almonds, apples, apricots, avocados, cashews, cherries, Christmas trees, durian, oranges, dragon fruit, grapes, guavas, longans, mangoes, olives, papayas, peaches, pears and other pome fruits, pistachios, plums, pomegranates, pomelos, and quince, as well as citrus crops such as clementines, grapefruits, lemons, limes, mandarins, and nectarines, and also nut crops such as hazelnuts, macadamia nuts, and walnuts; and plantation crops such as bananas, cocoa, coconuts, coffee, oil palm, pepper and other seeds, plantain, rubber, sugarcane, and tea. Also included are ornamental plants and nurseries such as azaleas, rhododendrons, and roses. For weed control in perennial crops, it may be desirable to shield these crops from contact with spray solutions containing herbicidal mixtures according to the invention.

[0006] Compositions according to the invention can also be used for weed control in turf and lawn, provided that the desired grass species are tolerant to the herbicidal mixtures. In particular, such mixtures can be used in desired grasses that have been made tolerant to glufosinate by mutagenesis or genetic engineering.

[0007] Glufosinate and its salts are non-selective systemic herbicides that have excellent post-emergence activity against many weeds and can therefore be used in burndown programs, industrial vegetation management and forestry, vegetable and perennial crops, and turf and lawn. However, single applications of glufosinate often result in insufficient weed control, and multiple applications and / or high doses are often required. Furthermore, the effectiveness of glufosinate against some weeds is not completely sufficient.

[0008] Therefore, it is often recommended to apply glufosinate in combination with at least one additional herbicide.However, the effectiveness of such combinations is often insufficient, and high application rates are still required to achieve acceptable weed control.In addition, the reliability and durability of such combinations are highly dependent on weathering conditions, and it is certainly difficult to control weed species that may escape.In addition, the herbicidal activity of these mixtures only lasts for a short time, so effective burndown is only possible within a short time frame before planting crops.

[0009] Therefore, an object of the present invention is to provide a herbicidal mixture that allows for efficient and reliable control of grass weeds and broadleaf weeds in burndown programs, industrial vegetation management and forestry, vegetable and perennial crops, and turf and lawn. Furthermore, the duration of herbicidal activity of the mixture should be long enough to achieve weed control over a sufficient period of time, thereby allowing for more flexible application. The mixture should also have low toxicity to humans or other mammals. The mixture should also exhibit rapid action against harmful plants, i.e., the mixture should cause damage to harmful plants more quickly than the application of the individual herbicides.

[0010] Glufosinate is a racemate of two enantiomers, only one of which exhibits sufficient herbicidal activity (see, for example, US 4265654 and JP92448 / 83). Various methods are known for preparing L-glufosinate (and respective salts), but mixtures known in the art do not specify the stereochemistry, implying that a racemate exists (e.g., WO2013154396). [Prior art documents] [Patent documents]

[0011] [Patent Document 1] US 4265654 [Patent Document 2] JP92448 / 83 [Patent Document 3] WO2013154396 Summary of the Invention

[0012] Surprisingly, it has been found that mixtures of L-glufosinate or a salt thereof with herbicide Compound II exhibit greater activity in burndown programs, industrial vegetation management and forestry, vegetable crops and perennial crops, and turf and turf when compared to L-glufosinate alone.

[0013] Surprisingly, it has been found that mixtures of L-glufosinate or a salt thereof and herbicide compound II exhibit greater activity in burndown programs, industrial vegetation management and forestry, vegetable crops and perennial crops, and turf and turf when compared to mixtures of racemic glufosinate and herbicide compound II.

[0014] Therefore, the present invention provides 1) L-glufosinate or a salt thereof as compound I; 2) Herbicide compounds II as compound II selected from the group consisting of chlorthiamid, dichlobenil, flupoxam, indaziflam, isoxaben, triaziflam, 1-cyclohexyl-5-pentafluorophenyloxy-14-[1,2,4,6]thiatriazin-3-ylamine (CAS 175899-01-1), diflufenzopyr, diflufenzopyr-sodium, naptalam and naptalam-sodium, bromobutide, chlorflurenol, chlorflurenol-methyl, cinmethylin, cumyluron, cyclopyrimorate (CAS 499223-49-3) and its salts and esters, dalapon, dazomet, difenzoquat, difenzoquat-methylsulfate, dimethipine, DSMA, dymron, endothal and its salts, etobenzanide, flurenol, flurenol-butyl, flurprimidol, fosamine, fosamine-ammonium, indanofan, maleic hydrazide, mefluidide, metam, methiozoline (CAS 403640-27-7), methyl azide, methyl bromide, methyl-dymron, methyl iodide, MSMA, oleic acid, oxaziclomefone, pelargonic acid, pyributicarb, quinoclamine, tridiphane; viranaphos (bialaphos) and viranaphos-sodium and herbicide mixtures with

[0015] In a preferred embodiment, the above-mentioned invention relates to the above-mentioned herbicidal mixture, wherein L-glufosinate comprises more than 70% by weight of the L-enantiomer. DETAILED DESCRIPTION OF THE INVENTION

[0016] Glufosinate (common name DL-4-[hydroxyl(methyl)phosphinoyl]-DL-homoalaninate) and its salts (e.g., glufosinate-ammonium), as well as its herbicidal activity, are described, for example, by F. Schwerdtle et al. in Z. Pflanzenkr. Pflanzenschutz, 1981, Sonderheft IX, pp. 431-440. Racemic glufosinate and its salts are commercially available, for example, from Bayer Cropscience under the trade names Basta™ and Liberty™.

[0017] The L-glufosinate used in the present invention contains more than 70% by weight of the L-enantiomer, preferably more than 80% by weight of the L-enantiomer, more preferably more than 90% by weight of the L-enantiomer, and most preferably more than 95% by weight of the L-enantiomer, and can be prepared as described above. L-glufosinate can be prepared according to methods known in the art, for example, as described in WO2006 / 104120, US5530142, EP0127429, and J. Chem. Soc. Perkin Trans. 1, 1992, 1525-1529.

[0018] L-glufosinate (also known as glufosinate-P) is (2S)-2-amino-4-[hydroxy(methyl)phosphinoyl]butyrate (CAS Registry Number 35597-44-5). Related salts of L-glufosinate are L-glufosinate-ammonium (also known as glufosinate-P-ammonium), which is ammonium (2S)-2-amino-4-(methylphosphinato)butyrate (CAS Registry Number 73777-50-1); L-glufosinate-sodium (also known as glufosinate-P-sodium), which is sodium (2S)-2-amino-4-(methylphosphinato)butyrate (CAS Registry Number 70033-13-5); and L-glufosinate-potassium (also known as glufosinate-P-potassium), which is potassium (2S)-2-amino-4-(methylphosphinato)butyrate.

[0019] Compounds II, as well as their pesticidal activity and methods for their preparation, are generally known, for example from Pesticide Manual V5.2 (ISBN 978 1 901396 85 0) (2008-2011), among other documents.

[0020] In the mixture of the present invention, the weight ratio of compound I to compound II is preferably 1000:1 to 1:500, 400:1 to 1:40, more preferably 500:1 to 1:250, in particular 200:1 to 1:20, even more preferably 100:1 to 1:10, and most preferably 50:1 to 1:5.

[0021] Furthermore, a mixture containing L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt, or L-glufosinate as the free acid, is preferred. Particularly preferred is a mixture containing L-glufosinate-ammonium as an L-glufosinate salt.

[0022] Preferred compounds II are dichlobenil, diflufenzopyr, diflufenzopyr-sodium, cinmethylin, bromobutide, cyclopyrimorate (CAS 499223-49-3) and its salts and esters, endothal and oxaziclomefone.

[0023] More preferred compounds II are triaziflam, indanofan, methiozoline and oxaziclomefone.

[0024] More preferred compounds II are triaziflam, indanofan and methiozoline.

[0025] In one embodiment of the present invention, compound II is triaziflam.

[0026] In another embodiment of the present invention, compound II is indanofan.

[0027] In another embodiment of the present invention, compound II is methiozoline.

[0028] Therefore, preferred mixtures of the present invention are mixtures of L-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts or L-glufosinate as the free acid with a herbicide compound II selected from the group consisting of dichlobenil, diflufenzopyr, diflufenzopyr-sodium, cinmethylin, bromobutide, cyclopyrimorate (CAS 499223-49-3) and its salts and esters, endothal and oxaziclomefone.

[0029] Even more preferably, the mixture of the present invention is a mixture of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt or L-glufosinate as the free acid with a herbicide compound II selected from the group consisting of triaziflam, indanofan, methiozolin and oxaziclomefone, preferably a herbicide compound II selected from the group consisting of triaziflam, indanofan and methiozolin.

[0030] All preferred mixtures are listed in Table 2, where the following abbreviations from Table 1 are used:

[0031] [Table 1] TIFF2026032025000002.tif18170

[0032] [Table 2]

[0033] Preferred mixtures of the present invention are mixtures of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt or L-glufosinate as the free acid with at least one compound II selected from the group consisting of dichlobenil, diflufenzopyr, diflufenzopyr-sodium and cinmethylin.

[0034] Preferred mixtures of the present invention are mixtures of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt or L-glufosinate as the free acid with at least one compound II selected from the group consisting of cinmethylin, oxaziclomefone, indaziflam, triaziflam, indanofan and methiozoline.

[0035] Preferred mixtures of the present invention are mixtures of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt or L-glufosinate as the free acid with at least one compound II selected from the group consisting of triaziflam, indanofan and methiozoline.

[0036] In one embodiment of the present invention, the mixture is a mixture of L-glufosinate salts, L-glufosinate-ammonium or L-glufosinate-sodium, or L-glufosinate as the free acid, with triaziflam.

[0037] In another embodiment of the invention, the mixture is a mixture of L-glufosinate-ammonium or L-glufosinate-sodium as an L-glufosinate salt or L-glufosinate as the free acid, and indanofan.

[0038] In another embodiment of the invention, the mixture is a mixture of L-glufosinate salts, L-glufosinate-ammonium or L-glufosinate-sodium, or L-glufosinate as the free acid, with methiozolin.

[0039] Thus, preferred are mixtures M-1, M-2, M-3, M-4, M-13, M-14, M-15, M-16, M-25, M-26, M-27 and M-28. Likewise preferred are M-8, M-20 and M-32.

[0040] Further preferred are mixtures M-1, M-2, M-3 and M-4.

[0041] In a further embodiment, preferred mixtures are M-4, M-8, M-9, M-10, M-11, M-12, M-16, M-20, M-21, M-22, M-23, M-24, M-28, M-32, M-33, M-24, M-35, M-36.

[0042] More preferred mixtures are M-10, M-11, M-12, M-22, M-23, M-24, M-34, M-35, and M-36.

[0043] In one embodiment, the mixture is M-10, M-22 or M-34, preferably M-10.

[0044] In another embodiment, the mixture is M-11, M-23 or M-35, preferably M-11.

[0045] In another embodiment, the mixture is M-12, M-24 or M-36, preferably M-12.

[0046] All the mixtures mentioned above will hereinafter be referred to as "mixtures of the invention".

[0047] The mixtures of the present invention may further comprise one or more insecticides, fungicides, herbicides.

[0048] The mixtures of the present invention can be converted into conventional types of pesticide mixtures, such as solutions, emulsions, suspensions, dusts, powders, pastes, granules, compacts, capsules, and mixtures thereof. Examples of mixture types are suspensions (e.g., SC, OD, FS), emulsifiable concentrates (e.g., EC), emulsions (e.g., EW, EO, ES, ME), capsules (e.g., CS, ZC), pastes, pastilles, wettable powders or wettable dusts (e.g., WP, SP, WS, DP, DS), compacts (e.g., BR, TB, DT), granules (e.g., WG, SG, GR, FG, GG, MG), insecticide products (e.g., LN), and gel formulations for treating plant propagation materials such as seeds (e.g., GF). These and other mixture types are defined in the "Catalogue of Pesticide Formulation Types and International Coding System" (Technical Monograph No. 2, 6th Edition, May 2008, CropLife International).

[0049] The mixtures are prepared by known methods, such as those described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005).

[0050] Suitable auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetting agents, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesives, thickeners, moisturizing agents, repellents, attractants, feeding stimulants, compatibilizers, bactericides, antifreeze agents, antifoaming agents, colorants, tackifiers and binders.

[0051] Suitable solvents and liquid carriers are water and organic solvents (medium- to high-boiling mineral oil fractions, such as kerosene, diesel, etc.), oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons (e.g., toluene, paraffins, tetrahydronaphthalene, alkylated naphthalenes), alcohols (e.g., ethanol, propanol, butanol, benzyl alcohol, cyclohexanol), glycols, DMSO, ketones (e.g., cyclohexanone), esters (e.g., lactate esters, carbonate esters, fatty acid esters, gamma-butyrolactone), fatty acids, phosphonate esters, amines, amides (e.g., N-methylpyrrolidone, fatty acid dimethylamides), and mixtures thereof.

[0052] Suitable solid carriers or fillers are mineral earths such as silicates, silica gel, talc, kaolin, limestone, lime, chalk, clay, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides such as cellulose, starch; fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea; products of plant origin such as grain flour, bark flour, wood flour, nut shell flour and mixtures thereof.

[0053] Suitable surfactants are surface-active compounds such as anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifiers, dispersants, solubilizers, wetting agents, penetration enhancers, protective colloids, or adjuvants. Examples of surfactants are listed in McCutcheon's, Vol. 1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Edition or North American Edition).

[0054] Suitable anionic surfactants are alkali salts, alkaline earth salts, or ammonium salts of sulfonates, sulfates, phosphates, and carboxylates, and mixtures thereof. Examples of sulfonates include alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignin sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecylbenzene and tridecylbenzene, sulfonates of naphthalene and alkylnaphthalenes, sulfosuccinates, or sulfosuccinamates. Examples of sulfates include sulfates of fatty acids and oils, sulfates of ethoxylated alkylphenols, sulfates of alcohols, sulfates of ethoxylated alcohols, or sulfates of fatty acid esters. Examples of phosphates include phosphate esters. Examples of carboxylates include alkyl carboxylates and carboxylated alcohols or alkylphenol ethoxylates.

[0055] Suitable nonionic surfactants include alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof. Examples of alkoxylates include compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids, or fatty acid esters, which are alkoxylated with 1 to 50 equivalents. Ethylene oxide and / or propylene oxide (preferably ethylene oxide) can be used for alkoxylation. Examples of N-substituted fatty acid amides include fatty acid glucamides or fatty acid alkanolamides. Examples of esters include fatty acid esters, glycerol esters, or monoglycerides. Examples of sugar-based surfactants include sorbitan, ethoxylated sorbitan, sucrose esters, glucose esters, or alkyl polyglucosides. Examples of polymeric surfactants include homopolymers or copolymers of vinylpyrrolidone, vinyl alcohol, or vinyl acetate.

[0056] Suitable cationic surfactants are quaternary surfactants, such as quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines. Suitable amphoteric surfactants are alkylbetaines and imidazolines. Suitable block polymers are AB or ABA block polymers containing polyethylene oxide and polypropylene oxide blocks, or ABC block polymers containing alkanol, polyethylene oxide, and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are polyacrylic acid or alkali salts of polyacid comb polymers. Examples of polybases are polyvinylamine or polyethyleneamine.

[0057] Suitable adjuvants are compounds that have negligible or no pesticidal activity themselves, but enhance the biological performance of the mixture of the present invention against the target. Examples include surfactants, mineral or vegetable oils, and other adjuvants. Further examples are listed by Knowles in "Adjuvants and additives," Agrow Reports DS256, T&F Informa UK, 2006, Chapter 5.

[0058] Suitable thickening agents are polysaccharides (eg xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or unmodified), polycarboxylates and silicates.

[0059] Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.

[0060] Suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerin.

[0061] Suitable antifoaming agents are silicones, long chain alcohols and salts of fatty acids.

[0062] Suitable colorants (e.g., red, blue, or green) are low-water-soluble pigments and water-soluble dyes. Examples are inorganic colorants (e.g., iron oxide, titanium oxide, ferricyanide) and organic colorants (e.g., alizarin colorants, azo colorants, and phthalocyanine colorants).

[0063] Suitable tackifiers or binders are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylates, biological or synthetic waxes, and cellulose ethers.

[0064] Examples of mixture types and their preparation are as follows: i) Water-soluble concentrates (SL, LS) 10-60% by weight of the mixture according to the invention and 5-15% by weight of a wetting agent (e.g., alcohol alkoxylate) are dissolved in water and / or a water-soluble solvent (e.g., alcohol) to make 100% by weight. The active substance dissolves upon dilution with water.

[0065] ii) Dispersible Concentrates (DC) 5 to 25% by weight of the mixture of the present invention and 1 to 10% by weight of a dispersant (e.g., polyvinylpyrrolidone) are dissolved in an organic solvent (e.g., cyclohexanone) to make a total of 100% by weight. Dilution with water gives a dispersion.

[0066] iii) Emulsifying Concentrates (EC) 15 to 70% by weight of the mixture of the present invention and 5 to 10% by weight of an emulsifier (e.g., calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in a water-insoluble organic solvent (e.g., aromatic hydrocarbon) to make 100% by weight. Upon dilution with water, an emulsion is obtained.

[0067] iv) Emulsifying agents (EW, EO, ES) 5 to 40% by weight of the mixture of the present invention and 1 to 10% by weight of an emulsifier (e.g., calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in 20 to 40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbon). This mixture is added to water using an emulsifier to make a 100% by weight mixture and form a uniform emulsion. The emulsion is obtained by diluting with water.

[0068] v) Suspension agents (SC, OD, FS) In a stirred ball mill, 20-60% by weight of the mixture of the invention is milled with 2-10% by weight of dispersants and wetting agents (e.g., sodium lignosulfonate and alcohol ethoxylates), 0.1-2% by weight of a thickener (e.g., xanthan gum), and up to 100% by weight of water, resulting in a fine suspension of the active substance. Dilution with water results in a stable suspension of the active substance. For FS type mixtures, up to 40% by weight of a binder (e.g., polyvinyl alcohol) is added.

[0069] vi) Water-dispersible granules and water-soluble granules (WG, SG) 50-80% by weight of the mixture of the present invention is mixed with up to 100% by weight of dispersants and wetting agents (e.g., sodium lignosulfonate and alcohol ethoxylates), and the mixture is milled and prepared in specialized equipment (e.g., extruders, spray towers, fluidized beds) as water-dispersible or water-soluble granules. Dilution with water gives a stable dispersion or solution of the active substance.

[0070] vii) Water-dispersible powders and water-soluble powders (WP, SP, WS) In a rotor-stator mill, 50-80% by weight of the inventive mixture is milled with 1-5% by weight of a dispersant (e.g., sodium lignosulfonate), 1-3% by weight of a wetting agent (e.g., alcohol ethoxylate), and up to 100% by weight of a solid carrier (e.g., silica gel). Dilution with water results in a stable dispersion or solution of the active substance.

[0071] viii) Gel preparations (GW, GF) When 5-25% by weight of the mixture of the present invention is milled in a stirred ball mill with 3-10% by weight of a dispersing agent (e.g., sodium lignosulfonate), 1-5% by weight of a thickener (e.g., carboxymethylcellulose), and up to 100% by weight of water, a fine suspension of the active substance is obtained. Dilution with water gives a stable suspension of the active substance.

[0072] ix) Microemulsifiers (ME) 5-20 wt% of the inventive mixture is added to 5-30 wt% of an organic solvent blend (e.g., fatty acid dimethylamide and cyclohexanone), 10-25 wt% of a surfactant blend (e.g., alcohol ethoxylate and arylphenol ethoxylate), and up to 100 wt% of water. The mixture is stirred for 1 hour, spontaneously forming a thermodynamically stable microemulsion.

[0073] x) Microcapsules (CS) An oil phase containing 5 to 50% by weight of the inventive mixture, 0 to 40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbon), and 2 to 15% by weight of an acrylic monomer (e.g., methyl methacrylate, methacrylic acid, and diacrylate or triacrylate) is dispersed in an aqueous solution of a protective colloid (e.g., polyvinyl alcohol). Radical polymerization initiated by a radical initiator forms poly(meth)acrylate microcapsules. Alternatively, an oil phase containing 5 to 50% by weight of the inventive mixture, 0 to 40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbon), and an isocyanate monomer (e.g., diphenylmethene-4,4'-diisocyanate) is dispersed in an aqueous solution of a protective colloid (e.g., polyvinyl alcohol). Addition of a polyamine (e.g., hexamethylenediamine) results in the formation of polyurea microcapsules. The total amount of the monomers is 1 to 10% by weight. The weight percentages are relative to the total CS mixture.

[0074] xi) Dustable powder (DP, DS) 1 to 10% by weight of the mixture of the present invention is finely ground and thoroughly mixed with up to 100% by weight of a solid carrier (eg, finely ground kaolin).

[0075] xii) Granules (GR, FG) 0.5 to 30% by weight of the mixture of the present invention is finely ground and combined with up to 100% by weight of a solid carrier (e.g., silicate). Granulation is achieved by extrusion, spray drying or in the fluidized bed.

[0076] xiii) Ultra-low volume liquid (UL) 1 to 50% by weight of the mixture of the present invention is dissolved in up to 100% by weight of an organic solvent (eg, an aromatic hydrocarbon).

[0077] The mixture types i) to xiii) may optionally contain further auxiliaries such as 0.1 to 1% by weight of bactericides, 5 to 15% by weight of antifreeze agents, 0.1 to 1% by weight of antifoaming agents, and 0.1 to 1% by weight of colorants.

[0078] The resulting pesticidal mixture generally contains 0.01 to 95% by weight, preferably 0.1 to 90% by weight, in particular 0.5 to 75% by weight, of the active substance. The active substance is used in a purity of 90% to 100%, preferably 95% to 100% (according to NMR spectroscopy).

[0079] For the treatment of plant propagation materials (especially seeds), seed treatment solutions (LS), suspoemulsions (SE), flowable concentrates (FS), dry treatment powders (DS), water-dispersible slurry powders (WS), water-soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC), and gels (GF) are commonly used. The mixtures, after 2- to 10-fold dilution, provide active substance concentrations of 0.01 to 60% by weight, preferably 0.1 to 40% by weight, in ready-to-use preparations. Application can be carried out before or during sowing. Methods for applying the mixtures of the present invention and their mixtures to plant propagation materials (especially seeds) include dressing, coating, pelleting, dusting, soaking, and in-furrow application. Preferably, the mixtures of the present invention or mixtures thereof are applied to the plant propagation material by a method that does not induce germination, such as seed dressing, seed pelleting, seed coating and seed dusting, respectively.

[0080] The present invention also relates to herbicidal formulations comprising the herbicidally active mixture as defined herein and at least one carrier material, such as a liquid and / or solid carrier material.

[0081] Various types of oils, wetting agents, adjuvants, fertilizers or micronutrients, and further pesticides (e.g. herbicides, insecticides, fungicides, growth regulators, safeners) can be added as premixes to the active substances or the mixtures according to the invention containing them, or, if appropriate, can be added just before use (tank mix). These agents can be mixed with the mixtures according to the invention in a weight ratio of 1:100 to 100:1, preferably 1:10 to 10:1.

[0082] The user typically applies the mixture according to the invention from a predosage device, a backpack sprayer, a spray tank, a spray plane, or an irrigation system. Typically, the pesticidal mixture is brought to the desired application concentration with water, buffers, and / or further auxiliaries, thus obtaining a ready-to-use spray solution or pesticidal mixture according to the invention. Typically, 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray solution are applied per hectare of agriculturally useful area.

[0083] As outlined above, the present invention also relates to the use of the mixtures defined herein for controlling undesirable vegetation in burndown programs, industrial vegetation management and forestry, vegetable crops and perennial crops, and turf and lawn, wherein the mixtures of the present invention can be applied pre-emergence or post-emergence, i.e., before, during and / or after the emergence of undesirable plants. Preferred is application as a post-emergence treatment (i.e., during and / or after the emergence of undesirable plants). Here, the mixtures of the present invention are applied to the location where the crop is to be planted before planting or emergence of the crop.

[0084] Therefore, the present invention also relates to a method for burndown treatment of undesirable vegetation in a crop, comprising applying the mixture of the present invention to the locus where the crop is to be planted before planting (or sowing) or emergence of the crop, wherein the mixture of the present invention is applied to the undesirable vegetation or its locus.

[0085] The present invention therefore relates to a method for controlling undesirable vegetation in this way, which method comprises applying a mixture of the present invention to a location where undesirable vegetation is present or expected to be present, wherein application can be carried out before, during and / or after emergence of the undesirable vegetation, preferably during and / or after emergence.

[0086] As used herein, the terms "control" and "eliminate" are synonymous.

[0087] As used herein, the terms "undesirable vegetation," "undesirable species," "undesirable plants," "harmful plants," "undesirable weeds," or "noxious weeds" are synonyms.

[0088] As used herein, the term "locus" means an area, typically a field, where vegetation or plants are growing or will grow.

[0089] In such a burn-down program, the mixture of the present invention can be applied before sowing (planting) the crop or after sowing (or planting), but is applied before crop emergence, particularly before sowing. The mixture of the present invention is preferably applied before sowing the crop. For burn-down, the mixture of the present invention will generally be applied up to 9 months, often up to 6 months, preferably up to 4 months before planting the crop. Burn-down application can be carried out up to 1 day before crop emergence, preferably the day before sowing / planting the crop, preferably at least 1 day, preferably at least 2 days, particularly at least 4 days before planting, or 6 months to 1 day before emergence, particularly 4 months to 2 days before emergence, more preferably 4 months to 4 days before emergence. Of course, within that time frame, burn-down application can be repeated one or more times, for example 1, 2, 3, 4 or 5 times.

[0090] A particular advantage of the mixtures of the present invention is that they have excellent post-emergence herbicidal activity, i.e., they exhibit excellent herbicidal activity against emerged undesirable plants. Thus, in a preferred embodiment of the present invention, the mixtures of the present invention are applied post-emergence, i.e., during and / or after the emergence of undesirable plants. It is particularly advantageous to apply the mixtures of the present invention after emergence, after the undesirable plants begin to develop leaves but before flowering. The mixtures of the present invention are particularly useful for controlling undesirable vegetation that has already developed to a state where it is difficult to control with conventional burndown mixtures (i.e., when individual weeds are greater than 10 cm (4 inches) or even greater than 15 cm (6 inches)) and / or against dense weed populations.

[0091] For the post-emergence treatment of plants, the mixtures of the invention are preferably applied by foliar application.

[0092] If the active compounds I and II are not well tolerated by a particular crop, the application technique can be used in which the herbicidal composition is sprayed using a spraying device in such a way that the active compounds reach the leaves of undesirable plants growing under the crop or the soil surface in the open field, but do not come into contact with the leaves of sensitive crops as much as possible (post-directed, lay-by).In addition, a spray shield can also be used.

[0093] Application can be carried out, for example, by conventional spraying techniques using water as a carrier, typically using spray mixture volumes of 10 to 2000 L / ha, in particular 50 to 1000 L / ha. The required application rate of the mixture of pure active compounds depends on the density of undesired vegetation, the developmental stage of the plants, the climatic conditions of the area where the mixture is used, and the application method. Generally, the application rate of the mixture is 55 to 6000 g / ha, preferably 100 to 5000 g / ha, 200 to 4000 g / ha, more preferably 300 to 3000 g / ha of active ingredient (AI).

[0094] When using the mixture of the present invention in the method of the present invention, the active compounds that exist in the mixture of the present invention can be simultaneously or successively applied to the place where undesirable vegetation may occur.Here, it is not important whether the individual compounds that exist in the mixture of the present invention are formulated together or separately formulated, and whether they are applied together or separately, and also, when applied separately, in what order they are applied.All that is required is that the individual compounds that exist in the mixture of the present invention are applied within the time frame that allows the simultaneous action of active ingredients on undesirable plants.

[0095] As noted above, the mixtures of the present invention have several advantages, namely enhanced herbicidal activity, when compared to mixtures of racemic glufosinate and herbicide Compound II.

[0096] Furthermore, the mixtures of the present invention exhibit sustained herbicidal activity even under severe weathering conditions, which allows for more flexible application in burndown applications and minimizes the risk of weed escape. In addition, the mixtures of the present invention exhibit excellent crop compatibility with certain conventional and herbicide-resistant crops, i.e., the use of the mixtures of the present invention in these crops results in reduced crop damage and / or no increased crop damage. Therefore, the mixtures of the present invention can also be applied after crop emergence. The mixtures of the present invention can also exhibit rapid action against harmful plants, i.e., the mixtures of the present invention can cause more rapid damage to harmful plants compared to mixtures of racemic glufosinate and herbicide compound II.

[0097] Both L-glufosinate alone and the mixtures of the present invention in the methods of the present invention are effective against monocotyledonous weeds, especially annual weeds, such as grass weeds (Grassaceae plants), for example Echinochloa species, such as barnyardgrass (Echinochloa crusgalli var. crus-galli), Echinochloa walteri (Pursh) Heller, jungle rice (Echinochloa colona), Echinochloa crus-pavonis, Echinochloa oryzicola, Digitaria species, such as large crabgrass (Digitaria sanguinalis), large crabgrass (Digitaria horizontalis), sourgrass (Digitaria insularis) or naked crabgrass (Digitaria nuda), Setaria species such as green foxtail (Setaria viridis), giant foxtail (Setaria faberii), yellow foxtail (Setaria glauca or Setaria pumila) or rough foxtail (Setaria verticillata), Sorghum species such as johnsongrass (Sorghum halepense Pers.), Avena species such as wild oat (Avena fatua), Avena sterilis (Avena sterillis or Avena strigosa, Cenchrus species such as field sandbur (Cenchrus pauciflorus) or Cenchrus echinatus, Bromus species such as brome grass (Bromusjaponicus Thunb, Bromus sterilis or Bromus tectorum, Lolium species, Phalaris species such as Phalaris brachystachys, Phalaris minor or Phalaris persicaria, Eriochloa species, Panicum species such as fall panicum (Panicum dichotomiflorum), Panicum fasciculatum or Panicum maximum, Brachiaria species, annual bluegrass (Poa annua), annua, Alopecurus species such as blackgrass (Alopecurus myosuroides), blackgrass (Alopecurus aequalis Sobol) or Japanese knotweed (Alopecurus japonicus Steud), Aegilops species such as goatgrass (Aegilops cylindrica) or Aegylops tauschii, common bran grass (Apera spica-venti), goosegrass (Eleusine indica), horsegrass (Cynodon dactylon), couch grass (Agropyron repens or Elymus repens), bedweed (Agrostis alba), Beckmannia syzigachne (Steud.) Fernald), Chloris species, for example Chloris virgata, Commelina species, for example Commelina benghalensis, Commelina communis, Commelina diffusa or Commelinaerecta, Dactyloctenium aegyptium, Hordeum jubatum, Hordeum leporinum, Imperata cylindrica, Ischaemum rogusum, Ixophorus unisetus, Leerisa hexandra, Leersia japonica, Leptochloa species such as Leptochloa chinensis, Leptochloa fascicularis, Leptochloa filiformis or Leptochloa panicoides, Lolium species such as Lolium multiflorum, ryegrass (Lolium perenne), ryegrass (Lolium persicum) or rigid ryegrass (Lolium rigidum), Luziola subintegra, ragweed (Murdannia nudiflora (L.) Brenan), Oryza latifolia, Oryza rufipogon, Paspalum distichum, Paspalum species, pearl millet (Pennisetum americanum), Peruvian grass (Pennisetum purpureum), timothy grass (Phleum paniculatum), reed (Phragmites australia), and barnyard grass (Ploypogon fugax). N.), Poa species such as annual bluegrass or annual bluegrass (Poa trivialis L.), Puccinellia distans, Rottboellia cochinchinensis, Sclerochloa kengiana (Ohwi)Tzvel., Trichloris crinita, Urochloa or Brachiaria species such as Brachiaria decumbens, Brachiaria plantaginea, Brachiaria platyphylla, Urochloa panicoides, Urochloa ramosa, etc.

[0098] Both L-glufosinate alone and the inventive mixtures are effective against a large number of dicotyledonous weeds, in particular Polygonum species such as wild buckwheat (Polygonum convolvolus), Polygonum pensilvanicum, Polygonum persicaria or prostrate knotweed (Polygonum aviculare), Amaranthus species such as pigweed (Amaranthus retroflexus), Palmer amaranth (Amaranthus palmeri), tall waterhemp (Amaranthus tuberculatus or Amaranthus rudis), redroot pigweed (Amaranthus rudis), and rhododendron amaryllis. pigweed (Amaranthus retroflexus), green amaranth (Amaranthus hybridus), purple amaranth (Amaranthus lividus), prickly amaranth (Amaranthus spinosus) or Amaranthus quitensis, Chenopodium species such as common lambsquarter (Chenopodium album L.), Chenopodium serotinum or quinoa (Chenopodium quinoa), Sida species such as prickly sida (Sida spinosa L.), Ambrosia species such as common ragweed (common ragweed) (Ambrosia artemisiifolia) or giant ragweed (Ambrosiatrifida, Acanthospermum species, Anthemis species, for example Anthemis arvensis or Anthemis cotula, Atriplex species, Cirsium species, for example Cirsium arvense, Convolvulus species, for example field bindweed (Convolvulus arvensis), Conyza species, for example Conyza canadensis (Erigeron canadensis) or hairy fleabane (Conyza bonariensis, Erigeron bonariensis, Cassia species, Datura species such as Datura stramonium, Euphorbia species such as toothed spurge (Euphorbia dentata), Euphorbia hirta, Euphorbia helioscopia or fireplant (Euphorbia heterophylla), Geranium species such as Geranium donianum or Geranium pusillum, Galinsoga species, morning glory glory (Ipomoea spp.), Lamium spp., such as henbit dead-nettle (Lamium amplexicaule), Malva spp., such as dwarf mallow (Malva neglecta) or cheeseweed (Malwa parviflora), Matricaria spp., such as chamomile (Matricaria recutita),chamomilla) or Matricaria inodora, Sysimbrium species, Solanum species such as black nightshade (Solanum nigrum), Xanthium species, Veronica species such as Veronica polita, Viola species, common chickweed (Stellaria media), velvetleaf (Abutilon theophrasti), Sesbania species such as Sesbania exaltata, Sesbania herbacea or hemp sesbania (Sesbania exaltata Cory), Anoda cristata, Bidens species such as Bidens frondosa or Bidens pilosa, Brassica kaber, Capsella species such as Capsella media or Capsella bursa-pastoris, cornflower (Centaurea cyanus), white lamb (Galeopsis tetrahit), Galium aparine, sunflower (Helianthus annuus), purple bush clover (Desmodium tortuosum), Kochia scoparia, Mercurialis annua, Myosotis arvensis, Papaver rhoeas, Raphanus species such as wild radish (Raphanus raphanistrum), Salsola species such as Salsola tragus or Salsola kali, Sinapisarvensis, Sonchus species such as Sonchus asper, Sonchus arvensis or Sonchus oleraceus, Thlaspi arvense, Tagetes minuta, Richardia species such as Richardia scabra or Richardia brasiliensis, Aeschynome species such as Aeschynomene denticulata, Aeschynomene indica or Aeschynomene rudis, Alisma species such as Alisma canaliculatum or Alisma plantago-aquatica, Borrelia species such as Borrelia verticillata, turnip (Brassica rapa), carduus acanthoides, Parietaria debilis, purslane (Portulaca oleracea), Ipomoea species such as Ipomoea grandifolia, morning glory (Ipomoea hederacea), Ipomoea indivisa, morning glory (Ipomoea lacunose), Ipomoea lonchophylla or Ipomoea wrightii, Senna obtusifolia obtusifolia, Sida species such as arrowleaf sida (Sida rhombifolia) or Sida priculisida (American sida), Spermacoce latifolia, Tridax procumbensprocumbens, Trianthema portulacastrum, Parthenium hysterophorus, Portulaca oleracea, Acalypha australis, Ammi majus, Atriplex species, Orobanche species, Mercurialis annua, Strep thistle, Calystegia sepium, Stellaria media, Nettle white, Viola species, Celosia argentea, Melampodium divaricatum, Cleome viscosa, Wood purse verticilatus, Borhevia erecta, Gomphrena species, Nicandra physalodes, Ricinus communis, Geranium dissectum, Alternanthera species such as Alternanthera philoxeroides or Alternanthera tenella, Ammannia species such as Ammania coccinea, Anacamtodon fortunei Mitt., Anagallis arvensis, Aneilema keisak, Arenaria serpyllifolia, Argemone mexicana, Asphodelus tenuifolius, Atriplex patula, Bacopa rotundifolia, Rutabaga (Brassicanapus, Caperonia species such as Caperonia castaneifolia or Caperonia palustris, Cephalanoplos segetum, Corynopsis didymus, Crepis capillaris, Crepis tectorum, Croton lobatus, Descuminia sophia (L.), Descurainia pinnata, Echinodorus grandiflorus, Eclipta alba, Eclipta prostrata, Water hyacinth, crassipes, Eleocharis species, Equisetum arvense, Bindweed (Fallopia convolvulus), Bindweed (Fallopia convolvulus), Heteranthera limosa, Jussiaea species, Kallstroemia maxima, Lactuca serriola, Lathyrus aphaca, Launea mudicaulis, Leucas chinensis, Limnocharis flava, Lindernia dubia, Lindernia pyxidaria, Litospermum arvense, Ludwigia species such as Ludwigia octovallis, Macroptilium lathyroides, Malachium acaticumaquaticum (L.), Melilotus species, Merremia aegyptia, Momordica charantia, Monochoria hastata, Monochoria vaginalis, Mucuna species, Oxalis neaei, Phyllanthus species, Physalis species, Pistia stratiotes, Potamogeton distinctus, Rorippa islandica, Rotala indica, Rotala ramosior, Rumex dentatus, Rumex obtusifolius, Sagittaria montevidensis, Sagittaria pygmaea Miq., Arrowhead (Sagittaria sagittifolia), Arrowhead (Sagittaria trifolia L.), Groundsel (Senecio vulgaris), Sicyos polyacanthus, Silene gallica, Sisymbrium species such as Sisymbrium oficinale, Solanum species, Field clover (Spergula arvensis), Long-legged sumac (Sphenoclea They are also suitable for controlling broadleaf weeds, including Trianthemum spp., Tripleurospermum inodorum, Speedwell spp., e.g. Veronica persica or Persica japonica, Vicia sativa, etc.

[0099] Both L-glufosinate alone and the inventive mixtures have been shown to be effective against Cyperus species, such as purple nutsedge (Cyperus rotundus L.), yellow nutsedge (Cyperus esculentus L.), hime-kugu (Cyperus brevifolius H.), sedgeweed (Cyperus microiria Steud), rice flatsedge (Cyperus iria L.), Cyperus difformis (Cyperus difformis L.), Cyperus ferax (Cyperus flavus), Cyperus serrata (Cyperus ferax), Cyperus flavus (Cyperus flavus), Cyperus serrata (Cyperus ferax), Cyperus ferax ... flavus, Cyperus lanceolatus, Cyperus odoratus, Cyperus rotundus, Cyperus serotinus Rottb., Eleocharis acicularis, Eleocharis kuroguwai, Fimbristylis dichotoma, Fimbristylis miliacea, Scirpus grossus, Scirpus juncoides, Scirpus juncoides Roxb, Scirpus maritimus or Bolboschoenus maritimus, Scirpus or Schoenoplectus It is also suitable for controlling a number of annual and perennial sedge weeds, including Scirpus mucronatus, Scirpus planiculmis Fr. Schmidt, and others.

[0100] Both L-glufosinate alone and the inventive mixtures are also suitable for controlling weeds that are resistant to commonly used herbicides, such as weeds resistant to glyphosate, weeds resistant to auxin inhibitor herbicides such as 2,4-D or dicamba, weeds resistant to photosynthesis inhibitors such as atrazine, weeds resistant to ALS inhibitors such as sulfonylureas, imidazolinones or triazolopyrimidines, weeds resistant to ACCase inhibitors such as clodinafop, clethodim or pinoxaden, or weeds resistant to protoporphyrinogen IX oxidase inhibitors such as sulfentrazone, flumioxazin, fomesafen or acifluorfen, for example, weeds listed in the International Survey of Resistant Weeds (http: / / www.weedscience.org / Summary / SpeciesbySOATable.aspx). In particular, they are effective against resistant weeds listed in the International Survey of Resistant Weeds, such as ACCase-resistant barnyardgrass, oat, black-grass, barnyardgrass, sandgrass, bromegrass, cornweed (Hordeum murinum), Chinese ragweed, green foxtail, corngrass, whitegrass, common bramble, Avena sterilis, Japanese ragweed (Beckmannia szygachne), Bromus diandrus, large crabgrass, Echinocloa oryzoides, barnyardgrass (Echinochloa phyllopogon), reed canary grass, and Phalaris paradoxa, Setaria faberi, Green foxtail, Brachypodium distachyon, Bromus diandrus, Brown brome, Cynosurus echinatus, Large crabgrass, Northern crabgrass (Digitaria ischaemum), Japanese pigweed, Phalaris brachystachysbrachystachis, hornwort (Rotboellia cochinchinensis), crabgrass (Digitaria ciliaris), Ehrharta longiflora, Eriochloa punctata, Leptochloa panicoides, Japanese oak, barnyard grass (Polypogon fugax), Sclerochlora kengiana, Snowdenia polystacha, Sudangrass and Brachiaria plantaginea, ALS inhibitor-resistant barnyard grass, annual bluegrass, wild oat, black-and-white grass, barnyard grass, narrow-leaved amberjack, giant amberjack, Amaranthus rudis, giant ragweed (Conyza sumatrensis), redroot pigweed, and common ragweed (Ambrosia artemisifolia, mugwort, kochia, sea radish, Senecio vernalis, sandgrass, burdock, brome, lamb's quarter, ragwort, cornweed, cornweed, Taiwan ragweed, field daisy, foxtail, barnyard grass (Sisymbrium orientale), corn sorghum, foxtail, black-eye grass (Amaranthus blitum), red-eared amberweed (Amaranthus powellii), common ragwort, Avena sterilis, turnip, Bromus diandrus, and ragwort (Descurainia sophia), large crabgrass, Echinochloa oryzoides, barnyard grass, dayflower, Lactuca seriola, reed canary grass, false setogaya, foxtail, green foxtail, field mustard, American nightshade (Solanum ptycanthum), sowweed, chickweed, American red snapper (Amaranthus blitoides), Japanese hollyhock, blue rhododendron (Amaranthus viridis), giant ragweed, Bidens subalternans, Bromus diandrus, brome, shepherd's purse, knapweed, Cynthia echinatus, Cyperus persica, Fimbristilismiliacea, Lamium amplexicaule, White spotted grass, Cleaver grass (Galium spurium), Sunflower, Hirschfeldia incana, Limnocallis flava, Limnophila erecta, Corn poppy, Parthenium hysterophorus, Phalaris brachystachys, Bindweed, Polygonum lapathifolium, Japanese knotweed, Ranunculus acris, Horned jasmine, Ardisia truncatula, Salsola tragus, Siberian sedge, Golden foxtail, Masson poppy, Cocklebur, Ageratum conyzoides, Ardisia truncatula, Ammannia auriculata auriculata, Lythrum salicaria, Ammannia arvensis, Chamomile, Bacopa rotundifolia, Bifora radians, Blyxa aubertii, Brassica tournefortii, Bromous grass, Bromus secalinus, Purple laurel, Camelina microcarpa, Chamaesyce maculata, Garland chrysanthemum, Celandine (Clidemia hirta), Crepis tectorum, Cuscuta pentagona, Cyperus brevifolis, Cyperus compressus), Chinese cyperus, Chinese cyperus, Chinese cyperus, Damasonium minus, Diplotaxis erucoides, Diplotaxis tenuifolia, Dopatrum junceum, Echium plantagineum, Elatine triandra, Chinese yew, Erucaria hispanicahispanica, Erysimum repandum, Galium tricornutum, Iva xanthifolia, Ixophorus unicetus, Leptolepis lanceolata, Limnophilia sessiliflora, Lindernia micrantha, Lindernia procumbens, Ludwigia prostrata, Matricaria recutita, Mesembryanthemum crystallinum, Monochoria korsakowii, Monochoria vaginalis, Myosoton aquaticum, Neslia paniculata, and rice (Oryza sativa var. sylvatica, Pentzia suffruticosa, Picris hieracioides, Radish (Raphanus sativus), Bird's-eye mustard (Rapistrum rugosum), Dogwood (Rorippa indica), Horse chestnut, Water spruce (Rotala pusilla), Rumex japonicus, Sagittaria guayensis, Sagittaria pygmaea, Arrowhead, Schoenoplectus fluviatilis, Schoenoplectus juncoides, Schoenoplectus wallichii, Siberian stag beetle, Silene japonica, White mustard (Sinapis alba), Sisymbrium terngii thellungii), sorghum (Sorghum bicolor), field clover, shepherd's purse, chamomile (Tripleurospermum perforatum), Vaccaria hispanica (Vaccariahispanica) and wild pea, photosynthesis inhibitor-resistant barnyardgrass, annual bluegrass, black-and-white grass, small barnyard grass, narrow-leaved amaranthus, giant amaranthus, Amaranthus rudis, giant ragweed, amaranthus retroflexus, common ragweed, artemisia, broomflower, sea radish, Senecio vernalis, sandgrass, Japanese ragweed, brome, Chinese milkweed, Chinese lambsquarters, ragweed, Taiwan eye Reeds, field daisies, foxtail, barnyard grass, wild chickweed, common arum, common bracken, kazuno, turnip, large crabgrass, dayflower, reed canary grass, false sedge, foxtail, green foxtail, field mustard, American nightshade, chickweed, American chickweed, red rhododendron, Bidens subalternans, wheatgrass, shepherd's purse, Japanese barnyard grass (Chloris barbata, Cyperus persica, Echinochloa erecta, Sakhalin turnip (Epilobium ciliatum), willow, bindweed, Polygonum orbicularis, Common purslane, common sedge, golden foxtail, nightshade, sowberry, Urochloa panicoides, Vulpia bromoides, velvetleaf, Amaranthus albus, Amaranthus cruentus, Arabidopsis thaliana, flea jasmine, Bidens tripartita, Chinese milkweed, Chenopodium ficifolium, Chenopodium polyspermum, Crypsis sieboldii schoenoides, Datura stramonium, Epilobium tetragonum, Galinsoga ciliata, Matricaria discoidea, Panicum capillare, Panicum lagopus, Polygonum hydopiper, Polygonum pensylvanicum, Polygonummonspeliensis, Rostraria smyrnacea, Rumex acetosella, rough foxtail and Urtica urens, annual bluegrass resistant to PS-I electron transfer inhibitors, large ragweed, mugwort, sandgrass, Japanese ragweed, ragweed, cornweed, Taiwan ragweed, black nightshade, American nightshade, Arctotheca calendula, Japanese onion, Hedyotis verticillata, nightshade, long-legged grass, field bindweed, Crassocephalum crepidioides, Cuphea cartagenensis carthagensis, Erigeron philadelphicus, Gamochaeta pensylvanica, Duckweed (Landoltia punctata), Shepherd's purse (Lepidium virginicum), Mazus fauriei, Mazus pumilus, Mitracarpus hirtus, Sclerochloa dura, Solanum americanum, and Youngia japonica), glyphosate-resistant annual bluegrass, barnyard grass, narrow-leaved amaranthus, giant amaranthus, ragweed, common mugwort, broom flower, sea radish, ragweed, ragweed, corngrass, turnip, Bromus diandrus, Lactuca serriola, common sowweed, Japanese holly, giant ragweed, Japanese crabgrass, common juniper, sunflower, Parthenium hysterophorus, plantain (Plantago lanceolata), Salsola tragus, Urochloa panicoides, small grain barnyard grass (Brachiaria eruciformis), and bromegrass (Bromus rubens), Chloris elata (Chloriselata, Chloris truncata, barnyardgrass, Cynodon hirsutus, Lactuca saligna, Leptochloa virgata, Paspalum paniculatum, and Tridax procumbens, and microtubule assembly inhibitor-resistant barnyardgrass, annual bluegrass, wild oat, black foxtail, common amberjack, green foxtail, western sorghum, common foxtail, Japanese corn, and Fumaria densiflora. densifloria), auxin herbicide-resistant barnyard grass, barnyard grass, narrow amaranthus, Amaranthus rudis, giant ragweed, broom tree, sea radish, Chenopodium album, mustard, ragweed, Lactuca seriola, field mustard, common sowweed, chickweed, cottonwort, cornflower, northern crabgrass, Japanese boxwood, white nettle, dead nettle, white nettle, white spotted grass, cleaver, Hirschfeldia incana, Limnocharis flava, Limnocharis erecta, corn poppy, plantain, mountain buttercup, musk thistle (Carduus nutans), and dwarf thistle (Carduus pycnocephalus, Centaurea soltitialis, Centaurea stoebe, Micranthos species, thorn thistle, desert thistle, giant dogbane It is also suitable for controlling Solanum esculentum (Soliva sessilis) and Long-legged sumac, HPPD inhibitor-resistant Amaranthus retroflexus and Amaranthus rudis, PPO inhibitor-resistant Cabbage, Amaranthus retroflexus, Amaranthus retroflexus, Amaranthus rudis, common ragweed, wild oat, common ragweed, common ragweed, morning glory, cardosum and Senecio vernalis, carotenoid biosynthesis inhibitor-resistant Hydrilla verticillata, sea radish, Senecio vernalis and barnyardgrass, VLCFA inhibitor-resistant black foxglove, wild oat and barnyard grass.

[0101] The mixtures of the present invention are suitable for the control / elimination of common harmful plants in fields planted with useful plants (i.e. in crops). The mixtures of the present invention are generally suitable for the burning down of undesirable vegetation in fields of the following crops: - Cereal crops, e.g. - wheat (Triticum aestivum) and wheat-like crops, for example durum wheat (T. durum), einkorn (T. monococcum), emmer wheat (T. dicoccon) and spelt (T. spelta), cereals (small grain crops) such as rye (Secale cereale), triticale (Tritiosecale), barley (Hordeum vulgare); - maize (corn; Zea mays); - Sorghum (e.g. Sorghum bicolor); - rice (Oryza spp., e.g. Oryza sativa and Oryza glaberrima); and - sugar cane etc. - legumes (Fabaceae), such as soybeans (Glycine max), peanuts (Arachis hypogaea), and cereals such as peas (Pisum sativum), pigeon peas and cowpeas, beans (Vicia faba), Vigna spp. and Phaseolus spp., and lentils (Lens culinaris var.); - Brassicaceae, such as canola (Brassica napus), rapeseed (OSR, Brassica napus), cabbage (B. oleracea var.), mustard (e.g. B. juncea), B. campestris, B. narinosa, B. nigra and B. tournefortii; and turnip (Brassica rapa var.); - other broadleaf crops, such as sunflower, cotton, flax, linseed, sugar beet, potato and tomato; - TNV crops (TNV: trees, nuts and vines), such as grapes, citrus fruits, pome fruits (e.g. apples and pears, coffee, pistachios and oil palm), stone fruits (e.g. peaches, almonds, walnuts, olives, cherries, plums and apricots); - Turf, pasture and rangeland; - Onion and garlic; - bulbous ornamental plants, such as tulips and daffodils; - coniferous and deciduous trees, such as pine, fir, oak, maple, dogwood, hawthorn, crabapple, and buckthorn; and - Garden ornamental plants such as roses, petunias, marigolds and snapdragons.

[0102] The mixtures of the present invention are particularly suitable for burning down undesirable vegetation in the fields of the following crops: small grain crops (such as wheat, barley, rye, triticale and durum wheat, rice, etc.), corn, sugarcane, sorghum, soybeans, linseed crops (such as peas, beans and lentils), peanuts, sunflowers, sugar beets, potatoes, cotton, cruciferous crops (such as rapeseed, canola, mustard, cabbage and turnips), turf, pasture. , pasture, grapes, pome fruits (e.g. apples and pears), stone fruits (e.g. peaches, almonds, walnuts, pecans, olives, cherries, plums and apricots), citrus fruits, coffee, pistachios, garden ornamentals (e.g. roses, petunias, marigolds, snapdragons), bulb ornamentals (e.g. tulips and daffodils), coniferous and deciduous trees (e.g. pine, fir, oak, maple, dogwood, hawthorn, crabapple and buckthorn).

[0103] The mixtures of the present invention are most suitable for burning down undesirable vegetation in the fields of the following crops: small grain crops such as wheat, barley, rye, triticale and durum wheat, rice, corn, sugarcane, soybeans, linseeds (such as peas, beans and lentils), peanuts, sunflowers, cotton, cruciferous crops (such as rapeseed, canola), turf, pasture, rangeland, grapes, stone fruits (such as peaches, almonds, walnuts, pecans, olives, cherries, plums and apricots), citrus fruits and pistachios.

[0104] The present invention further relates to the use of the mixtures as defined herein for controlling undesirable vegetation in crops in burn-down programs, wherein the crops produced by genetic engineering or breeding are resistant to one or more herbicides and / or pathogens such as plant pathogenic fungi and / or to attack by insects; preferably resistant to glufosinate.

[0105] Thus, as used in the present invention, the term "crop plant" as used herein also encompasses (crop) plants that have been modified by mutagenesis or genetic engineering to provide the plant with new traits or to modify traits that are already present.

[0106] Mutagenesis includes techniques such as random mutagenesis using, for example, X-rays or mutagenic chemicals, as well as targeted mutagenesis techniques for generating mutations at specific loci in the plant genome. Targeted mutagenesis techniques often use oligonucleotides or proteins such as CRISPR / Cas, zinc finger nucleases, TALENs, or meganucleases to achieve a targeted effect.

[0107] Genetic engineering typically uses recombinant DNA technology to generate mutations in plant genomes that are not readily obtainable in natural environments through cross-breeding, mutagenesis, or natural recombination. Typically, one or more genes are integrated into a plant's genome to add or improve traits. These integrated genes are also referred to in the art as transgenes, and plants containing such transgenes are called transgenic plants. Plant transformation methods typically result in several transformation events, each of which differs in the genomic locus at which the transgene is integrated. Plants containing a specific transgene at a specific genomic locus are typically described as containing a specific "event," referred to by a specific event name. Traits that have been introduced or modified in plants include herbicide tolerance, insect resistance, increased yield, and tolerance to abiotic conditions such as drought, among others.

[0108] Herbicide resistance has been generated by using mutagenesis and by using genetic engineering. Plants that have been made tolerant to acetolactate synthase (ALS) inhibitor herbicides by conventional mutagenesis and breeding methods include plant varieties sold under the name Clearfield®. However, most herbicide-tolerant traits have been generated by the use of transgenes.

[0109] Herbicide resistance has been generated to glyphosate, glufosinate, 2,4-D, dicamba, oxynil herbicides (such as bromoxynil and ioxynil), sulfonylurea herbicides, ALS inhibitor herbicides, and 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors (such as isoxaflutole and mesotrione).

[0110] Transgenes that have been used to provide herbicide tolerance traits include the following: transgenes for tolerance to glyphosate: cp4 epsps, epsps grg23ace5, mepsps, 2mepsps, gat4601, gat4621, and goxv247; transgenes for tolerance to glufosinate: pat and bar; transgenes for tolerance to 2,4-D: aad-1 and aad-12; transgenes for tolerance to dicamba: dmo; transgenes for tolerance to oxynil herbicides: bxn; transgenes for tolerance to sulfonylurea herbicides: zm-hra, csr1-2, gm-hra, S4-HrA; transgenes for tolerance to ALS inhibitor herbicides: csr1-2;

[0111] Transgenic corn events containing herbicide tolerance genes include, but are not limited to, DAS40278, MON801, MON802, MON809, MON810, MON832, MON87411, MON87419, MON87427, MON88017, MON89034, NK603, GA21, MZHG0JG, HCEM485, VCO-O1981-5 (where the O in the middle "O1981" is written as a stroked O in the original), 676, 678, 680, 33121, 4114, 59122, 98140, Bt10, Bt176, CBH-351, DBT418, DLL25, MS3, MS6, MZIR098, T25, TC1507, and TC6275.

[0112] Transgenic soybean events containing herbicide tolerance genes include, but are not limited to, GTS 40-3-2, MON87705, MON87708, MON87712, MON87769, MON89788, A2704-12, A2704-21, A5547-127, A5547-35, DP356043, DAS44406-6, DAS68416-4, DAS-81419-2, GU262, SYHTOH2 (where the O is written with a stroked O in the original), W62, W98, FG72, and CV127.

[0113] Transgenic cotton events containing herbicide resistance genes include, but are not limited to, 19-51a, 31707, 42317, 81910, 281-24-236, 3006-210-23, BXN10211, BXN10215, BXN10222, BXN10224, MON1445, MON1698, MON88701, MON88913, GHB119, GHB614, LLCotton25, T303-3, and T304-40.

[0114] Transgenic canola events containing herbicide tolerance genes include, but are not limited to, MON88302, HCR-1, HCN10, HCN28, HCN92, MS1, MS8, PHY14, PHY23, PHY35, PHY36, RF1, RF2 and RF3.

[0115] Insect resistance has primarily been generated by transferring bacterial genes encoding insecticidal proteins into plants. The most frequently used transgenes are Bacillus species toxin genes and their synthetic variants, such as cry1A, cry1Ab, cry1Ab-Ac, cry1Ac, cry1A.105, cry1F, cry1Fa2, cry2Ab2, cry2Ae, mcry3A, ecry3.1Ab, cry3Bb1, cry34Ab1, cry35Ab1, cry9C, vip3A(a), and vip3Aa20. However, plant-derived genes have also been transferred to other plants, particularly genes encoding protease inhibitors such as CpTI and pinII. A further approach uses transgenes to generate double-stranded RNA that targets and downregulates insect genes in plants. An example of such a transgene is dvsnf7.

[0116] Transgenic corn events containing genes for insecticidal proteins or double-stranded RNA include, but are not limited to, Bt10, Bt11, Bt176, MON801, MON802, MON809, MON810, MON863, MON87411, MON88017, MON89034, 33121, 4114, 5307, 59122, TC1507, TC6275, CBH-351, MIR162, DBT418, and MZIR098.

[0117] Transgenic soybean events containing genes for insecticidal proteins include, but are not limited to, MON87701, MON87751 and DAS-81419.

[0118] Transgenic cotton events containing genes for insecticidal proteins include, but are not limited to, SGK321, MON531, MON757, MON1076, MON15985, 31707, 31803, 31807, 31808, 42317, BNLA-601, Event1, COT67B, COT102, T303-3, T304-40, GFM Cry1A, GK12, MLS 9124, 281-24-236, 3006-210-23, GHB119, and SGK321.

[0119] Increased yield has been produced by increasing ear biomass using the transgene athb17 present in corn event MON87403 or by enhancing photosynthesis using the transgene bbx32 present in soybean event MON87712.

[0120] Crops with altered oil content have been produced by using the transgenes gm-fad2-1, Pj.D6D, Nc.Fad3, fad2-1A, and fatb1-A. Soybean events containing at least one of these genes are: 260-05, MON87705, and MON87769.

[0121] Tolerance to abiotic conditions, particularly drought, has been generated using the transgene cspB in the maize event MON87460 and the transgene Hahb-4 in the soybean event IND-OO41O-5 (the O here is written as a stroked O in the original text).

[0122] Traits are often combined by combining genes in one transformation event or by combining different events during the breeding process. Preferred combinations of traits are herbicide resistance to different groups of herbicides, insect resistance to different types of insects (especially lepidopteran resistance and coleopteran resistance), herbicide resistance and one or several types of insect resistance, herbicide tolerance and increased yield, and herbicide tolerance and tolerance to abiotic conditions.

[0123] Plants containing specific or stacked traits, as well as the genes and events that provide these traits, are well known in the art. For example, detailed information about mutated or integrated genes and events is available from the International Service for the Acquisition of Agri-biotech Applications (ISAAA) website (http: / / www.isaaa.org / gmapprovaldatabase) and the Center for Environmental Risk Assessment (CERA) website (http: / / cera-gmc.org / GMCropDatabase), as well as patent applications such as EP3028573 and WO2017 / 011288.

[0124] The use of the mixtures of the present invention on crops can produce specific effects on crops containing specific genes or events. These effects can include changes in growth behavior or changes in resistance to biotic or abiotic stress factors. Such effects can include, in particular, increased yield, increased resistance, or resistance to insect pathogens, nematode pathogens, fungal pathogens, bacterial pathogens, mycoplasma pathogens, viral pathogens, or viroid pathogens, as well as early vigor, early or delayed ripening, low or high temperature tolerance, and changes in the spectrum or content of amino acids or fatty acids.

[0125] Also included are plants that contain altered or new components through the use of recombinant DNA technology, particularly to improve feedstock production, such as potatoes that produce increased amounts of amylopectin (e.g., Amflora® potatoes, BASF SE, Germany).

[0126] Preferred are crops that are tolerant to glufosinate, wherein the glufosinate tolerant crop is preferably selected from the group consisting of rice, canola, soybean, corn and cotton plants.

[0127] Transgenic corn events containing a glufosinate resistance gene include, but are not limited to, the following: 5307 x MIR604 x Bt11 x TC1507 x GA21 x MIR162 (event code: SYN-O53O7-1 x SYN-IR6O4-5 x SYN-BTO11-1 x DAS-O15O7-1 x MON-OOO21-9 x SYN-IR162-4, gene: pat, commercially available, e.g., as Agrisure® Duracade™ 5222) (wherein O other than "MON" is written as an O with a stroke in the original), 59122 (event code: DAS-59122-7, gene: pat, commercially available, e.g., as Herculex™ RW), 5307 x MIR604 x Bt11 x TC1507 x GA21 (Event Code: SYN-O53O7-1 x SYN-IR6O4-5 x SYN-BTO11-1 x DAS-O15O7-1 x MON-OOO21-9, gene: pat, commercially available, for example, as Agrisure® Duracade™ 5122 (where O's other than "MON" are written with a stroked O in the original text), 59122 x NK603 (Event Code: DAS-59122-7 x MON-OO6O3-6, gene: pat, commercially available, for example, as Herculex™ RW Roundup Ready™ 2) (where O's other than "MON" are written with a stroked O in the original text), Bt10 (gene: pat, commercially available, for example, as Bt10), Bt11 (X4334CBR, X4734CBR) (Event code: SYN-BTO11-1, gene: pat, e.g., commercially available as Agrisure™ CB / LL) (where O is written as O with a stroke in the original text), BT11 x 59122 x MIR604 x TC1507 x GA21 (Event code: SYN-BTO11-1 x DAS-59122-7 x SYN-IR6O4-5 x DAS-O15O7-1 xMON-OOO21-9, gene: pat, commercially available, for example, as Agrisure® 3122 (wherein the O other than "MON" is written as a stroked O in the original), Bt11 x GA21 (event code: SYN-BTO11-1 x MON-OOO21-9, gene: pat, commercially available, for example, as Agrisure™ GT / CB / LL) (wherein the O other than "MON" is written as a stroked O in the original), Bt11 x MIR162 (event code: SYN-BTO11-1 x SYN-IR162-4, gene: pat, commercially available, for example, as Agrisure® Viptera™ 2100) (wherein the O is written as a stroked O in the original), Bt11 x MIR162 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x MON-OOO21-9, gene: pat, commercially available, for example, as Agrisure® Viptera™ 3110 (wherein the O other than "MON" is written as a stroked O in the original), BT11 x MIR162 x MIR604 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5, gene: pat, commercially available, for example, as Agrisure® Viptera™ 3100 (wherein the O is written as a stroked O in the original), Bt11 x MIR162 x MIR604 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x MON-OOO21-9, gene: pat, commercially available, for example, as Agrisure® Viptera™ 3111, Agrisure® Viptera™ 4 (wherein the O other than "MON" is written as an O with a stroke in the original text), Bt11 x MIR162 x TC1507 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x DAS-O15O7-1 x MON-OOO21-9, gene: pat, commercially available, for example, as Agrisure® Viptera™ 3111, Agrisure® Viptera™ 4) (wherein the O other than "MON" is written as an O with a stroke in the original text), Bt11 x MIR162 x TC1507 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x DAS-O15O7-1 x MON-OOO21-9, gene: pat, commercially available, for example, as Agrisure® Viptera™3220) (wherein the O other than "MON" is written as a stroked O in the original), Bt11 x MIR604 (event code: SYN-BTO11-1 x SYN-IR6O4-5, gene: pat, commercially available, for example, as Agrisure™ CB / LL / RW) (wherein the O other than "MON" is written as a stroked O in the original), BT11 x MIR604 x GA21 (event code: SYN-BTO11-1 x SYN-IR6O4-5 x MON-OOO21-9, gene: pat, commercially available, for example, as Agrisure™ 3000GT) (wherein the O other than "MON" is written as a stroked O in the original), Bt176 (176) (event code: SYN-EV176-9, gene: bar, commercially available, for example, as NaturGard KnockOut™, Maximizer™), CBH-351 (event code: ACS-ZMOO4-3, gene: bar, commercially available, for example, as Starlink™ Maize (where the O is written as an O with a stroke in the original text), DBT418 (event code: DKB-89614-9, gene: bar, commercially available, for example, as Bt Xtra™ Maize), MON89034 x TC1507 x MON88017 x 59122 (event codes: MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7, gene: pat, commercially available, for example, as Genuity® SmartStax™ (where the O other than "MON" is written as an O with a stroke in the original text), MON89034 x TC1507 x NK603 (event code: MON-89O34-3 x DAS-O15O7-1 x MON-OO6O3-6, gene: pat, e.g., commercially available as Power Core™) (where O's other than "MON" are written as O's with strokes in the original text), NK603 x T25 (event code: MON-OO6O3-6 x ACS-ZMOO3-2, gene: pat, e.g., Roundup Ready™ LibertyLink™ Maize) (where O's other than "MON" are written as O's in the original text), T14 (event code: ACS-ZMOO2-1, gene: pat, e.g., commercially available as Liberty Link™ Maize) (where O's are written as O's in the original text), T25 (event code: ACS-ZMOO3-2, gene: pat, e.g., commercially available as Liberty Link™ Maize) (where O's are written as O's in the original text), T25 x MON810 (event code: ACS-ZMOO3-2 x MON-OO81O-6, gene: pat, e.g., commercially available as Liberty Link™ Yieldgard™ Maize) (where O's other than "MON" are written as O's in the original text), TC1507 (event code: DAS-O15O7-1, gene: pat, e.g., commercially available as Herculex™ I, Herculex™ CB) (wherein the O is written as an O with a stroke in the original text), TC1507 x 59122 x MON810 x MIR604 x NK603 (event code: DAS-O15O7-1 x DAS-59122-7 x MON-OO81O-6 x SYN-IR6O4-5 x MON-OO6O3, gene: pat, e.g., commercially available as Optimum™ Intrasect Xtreme) (wherein the O other than "MON" is written as an O with a stroke in the original text), TC1507 x 59122 (event code: DAS-O15O7-1 x DAS-59122-7, gene: pat, e.g., commercially available as Herculex™ XTRA™) (where O is written as an O in the original text), TC1507 x 59122 x MON810 x NK603 (event code: DAS-O15O7-1 x DAS-59122-7 x MON-OO81O-6 x MON-OO6O3-6, gene: pat, e.g., commercially available as Optimum™ Intrasect XTRA) (where O other than "MON" is written as an O in the original text), TC1507 x 59122 xNK603 (event code: DAS-O15O7-1 x DAS-59122-7 x MON-OO6O3-6, gene: pat, commercially available, for example, as Herculex XTRA™ RR) (where O's other than "MON" are written as O's with a stroke in the original text), TC1507 x MIR604 x NK603 (event code: DAS-O15O7-1 x SYN-IR6O4-5 x MON-OO6O3-6, gene: pat, commercially available, for example, as Optimum™ TRISEct) (where O's other than "MON" are written as O's with a stroke in the original text), TC1507 x MON810 x NK603 (event code: DAS-O15O7-1 x MON-OO81O-6 x MON-OO6O3-6, gene: pat, commercially available, for example, as Optimum™ Intrasect (where O's other than "MON" are written with a stroked O in the original text), TC1507 x NK603 (event code: DAS-O15O7-1 x MON-OO6O3-6, gene: pat, commercially available, for example, as Herculex™ I RR) (where O's other than "MON" are written with a stroked O in the original text), 3272 x Bt11 (event code: SYN-E3272-5 x SYN-BTO11-1, gene: pat) (where O's are written with a stroked O in the original text), 3272 x Bt11 x GA21 (event code: SYN-E3272-5 x SYN-BTO11-1 x MON-OOO21-9, gene:pat) (where O's other than "MON" are written as O's with a stroke in the original text), 3272 x Bt11 x MIR604 (event code:SYN-E3272-5 x SYN-BTO11-1 x SYN-IR6O4-5, gene:pat) (where O's other than "MON" are written as O's with a stroke in the original text), 3272 x BT11 x MIR604 x GA21 (event code:SYN-E3272-5 x SYN-BTO11-1 x SYN-IR6O4-5 x MON-OOO21-9, gene:pat) (where O's other than "MON" are written as O's with a stroke in the original text), 33121(Event Code: DP-O33121-3, Gene: pat) (The O here is written as an O with a stroke in the original text), 4114 (Event Code: DP-OO4114-3, Gene: pat) (The O here is written as an O with a stroke in the original text), 59122 x GA21 (Event Code: DAS-59122-7 x MON-OOO21-9, Gene: pat) (The O here is written as an O with a stroke in the original text except for "MON"), 59122 x MIR604 (Event Code: DAS-59122-7 x SYN-IR6O4-5, Gene: pat) (The O here is written as an O with a stroke in the original text), 5307 x MIR604 x Bt11 x TC1507 x GA21 x MIR162 (Event Code: Gene: pat), 59122 x MIR604 x GA21 (event code: DAS-59122-7 x SYN-IR6O4-5 x MON-OOO21-9, gene: pat) (The O's other than "MON" here are written as O's with a stroke in the original text), 59122 x MIR604 x TC1507 (event code: DAS-59122-7 x SYN-IR6O4-5 x DAS-O15O7-1, gene: pat) (The O's here are written as O's with a stroke in the original text), 59122 x MIR604 x TC1507 x GA21 (event code: gene: pat), (event code: DAS-59122-7 x SYN-IR6O4-5 x DAS-O15O7-1 x MON-OOO21-9, gene:pat) (where O's other than "MON" are written with a stroked O in the original text), 59122 x MON810 (event code:DAS-59122-7 x MON-OO81O-6, gene:pat) (where O's other than "MON" are written with a stroked O in the original text), 59122 x MON810 x NK603 (event code:DAS-59122-7 x MON-OO81O-6 x MON-OO6O3-6, gene:pat) (where O's other than "MON" are written with a stroked O in the original text), 59122 x TC1507 x GA21 (event code:DAS-59122-7 x DAS-O15O7-1 xMON-OOO21-9, gene:pat) (The O other than "MON" is written as a stroked O in the original text), 676 (event code:PH-OOO676-7, gene:pat) (The O is written as a stroked O in the original text), 678 (event code:PH-OOO678-9, gene:pat) (The O is written as a stroked O in the original text), 680 (event code:PH-OOO68O-2, gene:pat), 98140 x 59122 (event code:DP-O9814O-6 x DAS-59122-7, gene:pat) (The O is written as a stroked O in the original text), 98140 x TC1507 (event code:DP-O9814O-6 x DAS-O15O7-1, gene: pat) (where O is written as an O with a stroke in the original text), 98140 x TC1507 x 59122 (event code: DP-O9814O-6 x DAS-O15O7-1 x DAS-59122-7, gene: pat) (where O is written as an O with a stroke in the original text), 59122 x MON88017 (event code: DAS-59122-7 x MON-88O17-3, gene: pat) (where O is written as an O with a stroke in the original text except for "MON"), Bt11 x 59122 (event code: SYN-BTO11-1 x DAS-59122-7, gene: pat) (where O is written as an O with a stroke in the original text), Bt11 x 59122 x GA21 (Event code: SYN-BTO11-1 x DAS-59122-7 x MON-OOO21-9, gene: pat) (O's other than "MON" are written as O's with a stroke in the original text), Bt11 x 59122 x MIR604 (Event code: SYN-BTO11-1 x DAS-59122-7 x SYN-IR6O4-5, gene: pat) (O's other than "MON" are written as O's with a stroke in the original text), Bt11 x 59122 x MIR604 x GA21 (Event code: SYN-BTO11-1 x DAS-59122-7 x SYN-IR6O4-5 x MON-OOO21-9, gene: pat) (O's other than "MON" are written as O's with a stroke in the original text), Bt11 x 59122 xMIR604 x TC1507 (event code: Bt11 x 59122 x MIR604 x TC1507, gene: pat), Bt11 x 59122 x TC1507 (event code: SYN-BTO11-1 x DAS-59122-7 x DAS-O15O7-1, gene: pat) (O here is written as O with a stroke in the original text), Bt11 x 59122 x TC1507 x GA21 (event code: SYN-BTO11-1 x DAS-59122-7 x DAS-O15O7-1 x MON-OOO21-9, gene: pat) (O here is written as O with a stroke in the original text except for "MON"), Bt11 x MIR162 x TC1507 (event code: SYN-BTO11-1 x SYN-IR162-4 x DAS-O15O7-1, gene: pat) (where O is written as O in the original text), Bt11 x MIR604 x TC1507 (event code: SYN-BTO11-1 x SYN-IR6O4-5 x DAS-O15O7-1, gene: pat) (where O is written as O in the original text), Bt11 x TC1507 (event code: SYN-BTO11-1 x DAS-O15O7-1, gene: pat) (where O is written as O in the original text), Bt11 x TC1507 x GA21 (event code SYN-BTO11-1 x DAS-O15O7-1 x MON-OOO21-9, gene: pat), GA21 x T25 (event code: MON-OOO21-9 x ACS-ZMOO3-2, gene: pat) (Os other than "MON" are written as "O" in the original text), MIR162 x TC1507 (event code: SYN-IR162-4 x DAS-O15O7-1, gene: pat) (Os other than "MON" are written as "O" in the original text), MIR162 x TC1507 x GA21 (event code: SYN-IR162-4 x DAS-O15O7-1 x MON-OOO21-9, gene: pat) (Os other than "MON" are written as "O" in the original text), MIR604 x TC1507 (Event Code: SYN-IR6O4-5 x DAS-O15O7-1, Gene: pat) (The O here is written as an O with a stroke in the original text), MON87427 x MON89O34 x TC15O7 x MON88O17 x 59122 (Event Code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7, Gene: pat) (The O other than "MON" here is written as an O with a stroke in the original text), MON89034 x 59122 (Event Code: MON-89O34-3 x DAS-59122-7, Gene: pat) (The O other than "MON" here is written as an O with a stroke in the original text), MON89034 x 59122 x MON88017 (event code: gene: pat), MON89034 x TC1507 (event code: MON-89O34-3 x DAS-59122-7 x MON-88O17-3, gene: pat) (Os other than "MON" here are written as Os with a stroke in the original text), (event code: MON-89O34-3 x DAS-O15O7-1, gene: pat) (Os other than "MON" here are written as Os with a stroke in the original text), MIR604 x TC1507 (event code: SYN-IR6O4-5 x DAS-O15O7-1, gene: pat), MON87427 x MON89O34 x TC15O7 x MON88O17 x59122 (event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7, gene: pat) (Os other than "MON" here are written as Os with a stroke in the original text), MON89034 x 59122 (event code: MON-89O34-3 x DAS-59122-7, gene: pat) (Os other than "MON" here are written as Os with a stroke in the original text), MON89034 x 59122 x MON88017 (event code: gene: pat), MON89034 x TC1507 (event code: MON-89O34-3 x DAS-59122-7 x MON-88O17-3, gene:pat) (O's other than "MON" are written as O's with a stroke in the original text), (event code:MON-89O34-3 x DAS-O15O7-1, gene:pat) (O's other than "MON" are written as O's with a stroke in the original text), DLL25 (B16) (event code:DKB-8979O-5, gene:bar) (O's are written as O's with a stroke in the original text), MIR604 x TC1507 (event code:SYN-IR6O4-5 x DAS-O15O7-1, gene:pat) (O's are written as O's with a stroke in the original text), MON87427 x MON89O34 x TC15O7 x MON88O17 x 59122 (event code:MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7, gene: pat) (Os other than "MON" are written with a stroked O in the original text), MON89034 x 59122 (event code: MON-89O34-3 x DAS-59122-7, gene: pat) (Os other than "MON" are written with a stroked O in the original text), MON89034 x 59122 x MON88017 (event code: MON-89O34-3 x DAS-59122-7 x MON-88O17-3, gene: pat) (Os other than "MON" are written with a stroked O in the original text), MON89034 x TC1507 (event code: MON-89O34-3 xDAS-O15O7-1, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), MON89034 x TC1507 x 59122 (event code: MON-89O34-3 x DAS-O15O7-1 x DAS-59122-7, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), MON89034 x TC1507 x MON88017 (event code: MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), MON89034 x TC1507 x MON88017 x 59122 x DAS40278 (Event Code: MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7 x DAS-4O278-9, Gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), MON89034 x TC1507 x MON88017 x DAS40278 (Event Code: MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7 x DAS-4O278-9, Gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), MON89034 x TC1507 x NK603 x DAS40278 (Event Code: MON-89O34-3 x DAS-O15O7-1 x MON-OO6O3-6 x DAS-4O278-9, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), NK603 x MON810 x 4114 x MIR 604 (event codes: MON-00603-6 x MON-00810-6 x DP004114-3 x SYN-IR604-4, gene: pat), TC1507 x MON810 x MIR604 x NK603 (event codes: DAS-O15O7-1 x MON-OO81O-6 x SYN-IR6O4-5 x MON-OO6O3-6, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), TC1507 x 59122x MON810 (event code: DAS-O15O7-1 x DAS-59122-7 x MON-OO81O-6, gene: pat) (Os other than "MON" are written with a stroked O in the original text), TC1507 x 59122 x MON88017 (event code: DAS-O15O7-1 x DAS-59122-7 x MON-88O17-3, gene: pat) (Os other than "MON" are written with a stroked O in the original text), TC1507 x GA21 (event code: DAS-O15O7-1 x MON-OOO21-9, gene: pat) (Os other than "MON" are written with a stroked O in the original text), TC1507 x MON810 (event code: DAS-O15O7-1 x MON-OO81O-6, gene:pat) (O's other than "MON" are written as O's with a stroke in the original text), TC1507 x MON810 x MIR162 x NK603 (event code:DAS-O15O7-1 x MON-OO81O-6 x SYN-IR162-4 x MON-OO6O3-6, gene:pat) (O's other than "MON" are written as O's with a stroke in the original text), 3272 x Bt11 x MIR604 x TC1507 x 5307 x GA21 (event code:SYN-E3272-5 x SYN-BTO11-1 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), TC1507 x MIR162 x NK603 (event code: DAS-O15O7-1 x SYN-IR162-4 x MON-OO6O3-6, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), TC1507 x MON810 x MIR162 (event code: DAS-O15O7-1 x MON-OO81O-6 x SYN-IR162-4, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), MON87419 (event code: MON87419-8, gene: pat), TC1507 x MON88017(Event code: DAS-O15O7-1 x MON-88O17-3, gene: pat) (The O other than "MON" here is written as an O with a stroke in the original text), TC6275 (Event code: DAS-O6275-8, gene: bar) (The O here is written as an O with a stroke in the original text), MZHG0JG (Event code: SYN-OOOJG-2, gene: pat) (The O here is written as an O with a stroke in the original text), MZIR098 (Event code: SYN-OOO98-3, gene: pat) (The O here is written as an O with a stroke in the original text), Bt11 x MIR162 x MON89034 (Event code: SYN-BTO11-1 x SYN-IR162-4 x MON-89O34-3, gene: pat) (where O's other than "MON" are written as O's with a stroke in the original text), Bt11 x MIR162 x MON89O34 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x MON-89O34-3 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written as O's with a stroke in the original text), 59122 x DAS40278 (event code: DAS-59122-7 x DAS-4O278-9, gene: pat) (where O's other than "MON" are written as O's with a stroke in the original text), 59122 x MON810 x MIR604 (event code: DAS-59122-7 x MON-OO81O-6 x SYN-IR6O4-5, gene:pat) (where O's other than "MON" are written with a stroked O in the original text), 59122 x MON810 x NK603 x MIR604 (event code:DAS-59122-7 x MON-OO81O-6 x MON-OO6O3-6 x SYN-IR6O4-5, gene:pat) (where O's other than "MON" are written with a stroked O in the original text), 59122 x MON88017 x DAS40278 (event code:DAS-59122-7 x MON-88O17-3 x DAS-4O278-9, gene:pat) (where O's other than "MON" are written with a stroked O in the original text), 59122 x NK603 x MIR604 (event code:DAS-59122-7 xMON-OO6O3-6 x SYN-IR6O4-5, gene: pat) (where O's other than "MON" are written as O's with a stroke in the original text), Bt11 x 5307 (event code: SYN-BTO11-1 x SYN-O53O7-1, gene: pat) (where O's other than "MON" are written as O's with a stroke in the original text), Bt11 x 5307 x GA21 (event code: SYN-BTO11-1 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written as O's with a stroke in the original text), Bt11 x MIR162 x 5307 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-O53O7-1, gene: pat) (where O is written as an O with a stroke in the original text), Bt11 x MIR162 x 5307 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN- O53O7-1 x MON-OOO21-9, gene: pat) (where O is written as an O with a stroke in the original text except for "MON"), BT11 x MIR162 x MIR604 x 5307 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x SYN-O53O7-1, gene: pat) (where O is written as an O with a stroke in the original text), Bt11 x MIR162 x MIR604 x 5307 x GA21 (Event Code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x SYN-O53O7-1 x MON-OOO21-9, Gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), Bt11 x MIR162 x MIR604 x MON89034 x 5307 x GA21 (Event Code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x MON-89O34-3 x SYN-O53O7-1 x MON-OOO21-9, Gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), BT11 x MIR162 x MIR604 x TC1507 (Event code: SYN-BTO11-1 xSYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1, gene: pat) (where O is written as O with a stroke in the original text), BT11 x MIR162 x MIR604 x TC1507 x 5307 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (where O is written as O with a stroke in the original text), Bt11 x MIR162 x MIR604 x TC1507 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x MON-OOO21-9, gene:pat) (where O's other than "MON" are written as O's with a stroke in the original text), Bt11 x MIR162 x TC1507 x 5307 (event code:SYN-BTO11-1 x SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1, gene:pat) (where O's are written as O's with a stroke in the original text), BT11 x MIR162 x MIR604 x TC1507 x 5307 (event code:SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, gene:pat) (where O's are written as O's with a stroke in the original text), Bt11 x MIR162 x MIR604 x TC1507 x GA21 (event code: SYN-BTO11-1 x SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x MON-OOO21-9, gene: pat) (O's other than "MON" are written as O's with a stroke in the original text), Bt11 x MIR162 x TC1507 x 5307 (event code: SYN-BTO11-1 x SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (O's are written as O's with a stroke in the original text), Bt11 x MIR162 x TC1507 x 5307 x GA21 (event code: SYN-BTO11-1 xSYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written as O's with a stroke in the original text), Bt11 x MIR604 x 5307 (event code: SYN-BTO11-1 x SYN-IR6O4-5 x SYN-O53O7-1, gene: pat) (where O's other than "MON" are written as O's with a stroke in the original text), Bt11 x MIR604 x 5307 x GA21 (event code: SYN-BTO11-1 x SYN-IR6O4-5 x SYN- O53O7-1 x MON-OOO21-9, gene: pat) (where O's other than "MON" are written as O's with a stroke in the original text), Bt11 x MIR604 x TC1507 x 5307 (event code: SYN-BTO11-1 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (where O is written as an O with a stroke in the original text), Bt11 x MIR604 x TC1507 x GA21 (event code: SYN-BTO11-1 x SYN-IR6O4-5 x DAS-O15O7-1 x MON-OOO21-9, gene: pat) (where O is written as an O with a stroke in the original text except for "MON"), Bt11 x MON89034 (or Bt11 x MON89O34) (event code: SYN-BTO11-1 x MON-89O34-3, gene: pat) (Os other than "MON" here are written as Os with a stroke in the original text), Bt11 x MON89034 x GA21 (event code: SYN-BTO11-1 x MON-89O34-3 x MON-OOO21-9, gene: pat) (Os other than "MON" here are written as Os with a stroke in the original text), Bt11 x MON89O34 x GA21 (event code: SYN-B TO11-1 x MON-89O34-3 x MON-OOO21-9, gene: pat) (O's other than "MON" are written as O's in the original text), Bt11 x TC1507 x 5307 (event code: SYN-BTO11-1 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (O's other than "MON" are written as O's in the original text), Bt11 x TC1507 x 5307 x GA21 (event code: SYN-BTO11-1 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (O's other than "MON" are written as O's in the original text), MIR162 x MIR604 x TC1507 x 5307 (Event Code: SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, Gene: pat) (The O here is written as an O with a stroke in the original text), MIR162 x MIR604 x TC1507 x 5307 x GA21 (Event Code: SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, Gene: pat) (The O here is written as an O with a stroke in the original text except for "MON"), MIR162 x MIR604 x TC1507 x GA21 (Event Code: SYN-IR162-4 x SYN-IR6O4-5 x DAS-O15O7-1 x MON-OOO21-9, gene:pat) (O's other than "MON" are written as O's in the original text), MIR162 x TC1507 x 5307 (event code:SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1, gene:pat) (O's other than "MON" are written as O's in the original text), MIR162 x TC1507 x 5307 x GA21 (event code:SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, gene:pat) (O's other than "MON" are written as O's in the original text), MIR604 x TC1507 x 5307(Event Code: SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, Gene: pat) (The O here is written as an O with a stroke in the original text), MIR162 x TC1507 x 5307 (Event Code: SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1, Gene: pat) (The O here is written as an O with a stroke in the original text), MIR162 x TC1507 x 5307 x GA21 (Event Code: SYN-IR162-4 x DAS-O15O7-1 x SYN-O53O7-1 x MON-OOO21-9, Gene: pat) (The O here is written as an O with a stroke in the original text except for "MON"), MIR604 x TC1507 x 5307 (event code: SYN-IR6O4-5 x DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (O here is written as an O with a stroke in the original text), MIR604 x TC1507 x 5307 xGA21 (event code: SYN-IR6O4-5 x TC1507 x SYN-O53O7-1 x MON-OOO21-9, gene: pat) (O here is written as an O with a stroke in the original text except for "MON"), MIR604 x TC1507 x GA21 (event code: SYN-IR6O4-5 x TC1507 x MON-OOO21-9, gene: pat) (O here is written as an O with a stroke in the original text except for "MON"), MON87427 x 59122 (event code MON-87427-7 x DAS-59122-7, gene: pat), MON87427 x MON89034 x 59122 (event code: MON-87427-7 x MON-89O34-3 x DAS-59122-7, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), MON87427 x MON89034 x MON88017 x 59122 (event code: MON-87427-7 x MON-89O34-3 x MON-88O17-3 x 59122, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), MON87427 x MON89034 x TC1507(Event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1, gene: pat) (Os other than "MON" here are written with a stroked O in the original text), MON87427 x MON89034 x TC1507 x 59122 (Event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x DAS-59122-7, gene: pat) (Os other than "MON" here are written with a stroked O in the original text), MON87427 x MON89034 x TC1507 x MON87411 x 59122 (Event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-87411-9 x DAS-59122-7, gene: pat) (O's other than "MON" are written as O's with a stroke in the original text), MON87427 x MON89034 x TC1507 x MON87411 x 59122 x DAS40278 (event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-87411-9 x DAS-59122-7 x DAS-4O278-9, gene: pat) (O's other than "MON" are written as O's with a stroke in the original text), MON87427 x MON89034 x TC1507 x MON88017 (event code: MON-87427-7 x MON-89O34-3 x DAS-O15O7-1 x MON-88O17-3, gene: pat) (Os other than "MON" are written with a stroked O in the original text), MON87427 x TC1507 (event code: MON-87427-7 x DAS-O15O7-1, gene: pat) (Os other than "MON" are written with a stroked O in the original text), MON87427 x TC1507 x 59122 (event code: MON-87427-7 x DAS-O15O7-1 x DAS-59122-7, gene: pat) (Os other than "MON" are written with a stroked O in the original text), MON87427 x TC1507 x MON88017 (event code: MON-87427-7 x DAS-O15O7-1 xMON-88O17-3, gene:pat) (O's other than "MON" are written with a stroked O in the original text), MON87427 x TC1507 x MON88017 x 59122 (event code:MON-87427-7 x DAS-O15O7-1 x MON-88O17-3 x DAS-59122-7, gene:pat) (O's other than "MON" are written with a stroked O in the original text), MON89034 x 59122 x DAS40278 (event code:MON-89O34-3 x DAS-59122-7 x DAS-4O278-9, gene:pat) (O's other than "MON" are written with a stroked O in the original text), MON89034 x 59122 x MON88017 x DAS40278 (event code: MON-89O34-3 x DAS-59122-7 x MON-88O17-3 x DAS-4O278-9, gene: pat) (Os other than "MON" are written with a stroked O in the original text), MON89034 x TC1507 x 59122 x DAS40278 (event code: MON-89O34-3 x DAS- O15O7-1 x DAS-59122-7 x DAS-4O278-9, gene: pat) (Os other than "MON" are written with a stroked O in the original text), MON89034 x TC1507 x DAS40278 (event code: MON-89O34-3 x DAS-O15O7-1 x DAS-4O278-9, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), MON89034 x TC1507 x NK603 x MIR162 (event code: MON-89O34-3 x DAS-O15O7-1 x MON-OO6O3-6 x SYN-IR162-4, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), TC1507 x 5307 (event code: DAS-O15O7-1 x SYN-O53O7-1, gene: pat) (Os other than "MON" are written as Os with a stroke in the original text), TC1507 x 5307 x GA21 (event code: DAS-O15O7-1 x SYN-O53O7-1 xMON-OOO21-9, gene:pat) (O's other than "MON" are written as O's with a stroke in the original text), TC1507 x 59122 x DAS40278 (event code:DAS-O15O7-1 x DAS-59122-7 x DAS-4O278-9, gene:pat) (O's here are written as O's with a stroke in the original text), TC1507 x 59122 x MON810 x MIR604 (event code:DAS-O15O7-1 x DAS-59122-7 x MON-OO81O-6 x SYN-IR6O4-5, gene:pat) (O's other than "MON" are written as O's with a stroke in the original text), TC1507 x 59122 x MON88017 x DAS40278 (Event Code: DAS-O15O7-1 x DAS-59122-7 x MON-88O17-3 x DAS-4O278-9, Gene: pat) (Os other than "MON" here are written with a stroked O in the original text), TC1507 x 59122 x NK603 x MIR604 (Event Code: Gene: pat), DAS-O15O7-1 x DAS-59122-7 x MON-OO6O3-6 x SYN-IR6O4-5, TC1507 x DAS40278 (Event Code: DAS-O15O7-1 x DAS-4O278-9, Gene: pat) (Os other than "MON" here are written with a stroked O in the original text), TC1507 x MON810 x MIR604 (Event Code: DAS-O15O7-1 x MON-OO81O-6 x SYN-IR6O4-5, gene: pat) (Os other than "MON" here are written as Os with a stroke in the original text), TC1507 x MON810 x NK603 x MIR604 (event code: DAS-O15O7-1 x MON-OO81O-6 x MON-OO6O3-6 x SYN-IR6O4-5, gene: pat) (Os other than "MON" here are written as Os with a stroke in the original text), TC1507 x MON88017 x DAS40278 (event code: DAS-O15O7-1 x MON-88O17-3 xDAS-4O278-9, gene: pat) (where Os other than "MON" are written as Os with a stroke in the original text), and TC1507 x NK603 x DAS40278 (event code: DAS-O15O7-1 x MON-OO6O3-6 x DAS-4O278-9, gene: pat) (where Os other than "MON" are written as Os with a stroke in the original text).

[0128] Transgenic soybean events containing a glufosinate tolerance gene include, but are not limited to, the following: A2704-12 (event code: ACS-GMOO5-3, gene: pat, e.g., commercially available as Liberty Link™ soybean) (wherein the O is written as a stroked O in the original), A2704-21 (event code: ACS-GMOO4-2, gene: pat, e.g., commercially available as Liberty Link™ soybean) (wherein the O is written as a stroked O in the original), A5547-127 (event code: ACS-GMOO6-4, gene: pat, e.g., commercially available as Liberty Link™ soybean) (wherein the O is written as a stroked O in the original), A5547-35 (event code: ACS-GMOO8-6, gene: pat, e.g., commercially available as Liberty Link™ soybean) (wherein the O is written as a stroked O in the original), Link™ soybean) (where the O is written as a stroked O in the original), GU262 (event code: ACS-GMOO3-1, gene: pat, e.g., commercially available as Liberty Link™ soybean) (where the O is written as a stroked O in the original), W62 (event code: ACS-GMOO2-9, gene: pat, e.g., commercially available as Liberty Link™ soybean) (where the O is written as a stroked O in the original), W98 (event code: ACS-GMOO1-8, gene: pat, e.g., commercially available as Liberty Link™ soybean) (where the O is written as a stroked O in the original), DAS68416-4 (event code: DAS-68416-4, gene: pat, e.g., commercially available as Enlist™ Soybean), DAS44406-6 (Event code: DAS-444O6-6, Gene: pat) (The O here is written as an O with a stroke in the original text), DAS68416-4 x MON89788 (Event code: DAS-68416-4 x MON-89788-1, Gene: pat), SYHTOH2(event code: SYN-OOOH2-5, gene: pat) (where the O is written as an O in the original text), DAS81419 x DAS44406-6 (event code: DAS-81419-2 x DAS-444O6-6, gene: pat) (where the O is written as an O in the original text), and FG72 x A5547-127 (event code: MST-FGO72-3 x ACS-GMOO6-4, gene: pat) (where the O is written as an O in the original text).

[0129] Transgenic cotton events containing the glufosinate resistance gene include, but are not limited to, the following: 3006-210-23 x 281-24-236 x MON1445 (event code: DAS-21O23-5 x DAS-24236-5 x MON-O1445-2, gene: bar, commercially available as, e.g., WideStrike™, Roundup Ready™ Cotton) (wherein O other than "MON" is written as O with a stroke in the original text), 3006-210-23 x 281-24-236 x MON88913 (event code: DAS-21O23-5 x DAS-24236-5 x MON-88913-8, gene: bar, commercially available as, e.g., Widestrike™, Roundup Ready™ Cotton). Flex™ Cotton) (wherein O other than "MON" is written with a stroked O in the original text), 3006-210-23 x 281-24-236 x MON88913 x COT102 (event codes: DAS-21O23-5 x DAS-24236-5 x MON-88913-8 x SYN-IR1O2-7, gene: pat, e.g., Widestrike™ x Roundup Ready Flex™ x VIPCOT™ Cotton) (wherein O other than "MON" is written with a stroked O in the original text), GHB614 x LLCotton25 (event codes: BCS-GHOO2-5 x ACS-GHOO1-3, gene: bar, e.g., GlyTol™ Liberty Link™) (where O is written as O in the original text), GHB614 x T304-40 x GHB119 (event code: BCS-GHOO2-5 x BCS-GHOO4-7 x BCS-GHOO5-8, gene: bar, e.g., commercially available as Glytol™ x Twinlink™) (where O is written as O in the original text), LLCotton25(event code: ACS-GHOO1-3, gene: bar, e.g. commercially available as ACS-GHOO1-3) (wherein the O is written as a stroked O in the original), GHB614 x T304-40 x GHB119 x COT102 (event code: BCS-GHOO2-5 x BCS-GHOO4-7 x BCS-GHOO5-8 x SYN-IR1O2-7, gene: bar, e.g. commercially available as Glytol™ x Twinlink™ x VIPCOT™ Cotton) (wherein the O is written as a stroked O in the original), LLCotton25 x MON15985 (event code: ACS-GHOO1-3 x MON-15985-7, gene: bar, e.g. commercially available as Fibermax™ Liberty Link™ Bollgard II™) (wherein the O other than "MON" is written as an O in the original text), T304-40 x GHB119 (event code: BCS-GHOO4-7 x BCS-GHOO5-8, gene: bar, commercially available, for example, as TwinLink™ Cotton) (wherein the O is written as an O in the original text), GHB614 x T304-40 x GHB119 x COT102 (event code: BCS-GHOO2-5 x BCS-GHOO4-7 x BCS-GHOO5-8 x SYN-IR1O2-7, gene: bar, commercially available, for example, as Glytol™ x Twinlink™ x VIPCOT™ Cotton) (wherein the O is written as an O in the original text), GHB119 (Event code: BCS-GHOO5-8, gene: bar) (The O here is written as a stroked O in the original text), GHB614 x LLCotton25 x MON15985 (Event code: CS-GHOO2-5 x ACS-GHOO1-3 x MON-15985-7, gene: bar) (The O other than "MON" here is written as a stroked O in the original text), MON 887O1-3 (Event code: MON88701, gene: bar) (The O other than "MON" here is written as a stroked O in the original text), T303-3(Event Code: BCS-GHOO3-6, Gene: bar) (The O here is written as a stroked O in the original text), T304-40 (Event Code: BCS-GHOO3-6, Gene: bar), (Event Code: BCS-GHOO4-7, Gene: bar) (The O here is written as a stroked O in the original text), 81910 (Event Code: DAS-81910-7, Gene: pat), MON8870 (Event Code: MON 887O1-3, Gene: bar) (The O here is written as a stroked O in the original text except for "MON"), MON88701 x MON88913 (Event Code: MON 887O1-3 x MON-88913-8, Gene: bar) (The O here is written as a stroked O in the original text except for "MON"), MON88701 x MON88913 x MON15985 (event code: MON 887O1-3 x MON-88913-8 x MON-15985-7, gene: bar) (The Os other than "MON" here are written as Os with a stroke in the original text), 281-24-236 x 3006-210-23 x COT102 x 81910 (event code: DAS-24236-5 x DAS-21O23-5 x SYN-IR1O2-7 x DAS-81910-7, gene: pat) (The Os here are written as Os with a stroke in the original text), COT102 x MON15985 x MON88913 x MON88701 (event code: SYN-IR1O2-7 x MON-15985-7 x MON-88913-8 x MON 887O1-3, gene: bar) (where O's other than "MON" are written with a stroked O in the original text), and 3006-210-23 x 281-24-236 x MON88913 x COT102 x 81910 (event codes: DAS-21O23-5 x DAS-24236-5 x MON-88913-8 x SYN-IR1O2-7 x DAS-81910-7, gene: pat) (where O's other than "MON" are written with a stroked O in the original text).

[0130] Transgenic canola events comprising a glufosinate resistance gene include, but are not limited to, the following: HCN10 (Topas 19 / 2) (event code: , gene: bar, commercially available, e.g., as Liberty Link™ Independence™), HCN28 (T45) (event code: ACS-BNOO8-2, gene: pat, commercially available, e.g., as InVigor™ Canola) (wherein the O is written as a stroked O in the original), HCN92 (Topas 19 / 2 (event code: ACS-BNOO7-1, gene: bar, commercially available, e.g., as Liberty Link™ Innovator™) (wherein the O is written as a stroked O in the original), MS1 (B91-4) (event code: ACS-BNOO4-7, gene: bar, e.g., commercially available as InVigor™ Canola) (where O is written as a stroked O in the original), MS1 x RF1 (PGS1) (event code: ACS-BNOO4-7 x ACS-BNOO1-4, gene: bar, e.g., commercially available as InVigor™ Canola) (where O is written as a stroked O in the original), MS1 x RF2 (PGS2) (event code: ACS-BNOO4-7 x ACS-BNOO2-5, gene: bar, e.g., commercially available as InVigor™ Canola) (where O is written as a stroked O in the original), MS1 x RF3 (event code: ACS-BNOO4-7 x ACS-BNOO3-6, gene: bar, e.g., commercially available as InVigor™ Canola (where O is written as a stroked O in the original), MS8 (event code: ACS-BNOO5-8, gene: bar, e.g., commercially available as InVigor™ Canola) (where O is written as a stroked O in the original), MS8 x RF3 (event code: ACS-BNOO5-8 xACS-BNOO3-6, gene: bar, commercially available, for example, as InVigor™ Canola (where O is written as a stroked O in the original), RF1 (B93-101) (event code: ACS-BNOO1-4, gene: bar, commercially available, for example, as InVigor™ Canola (where O is written as a stroked O in the original), RF2 (B94-2) (event code: ACS-BNOO2-5, gene: bar, commercially available, for example, as InVigor™ Canola (where O is written as a stroked O in the original), RF3 (event code: ACS-BNOO3-6, gene: bar, commercially available, for example, as InVigor™ Canola (where O is written as a stroked O in the original), MS1 x MON88302 (event code: ACS-BNOO4-7 x MON-883O2-9, gene:bar, commercially available, for example, as InVigor™ x TruFlex™ Roundup Ready™ Canola (wherein the O other than "MON" is written as a stroked O in the original text), MS8 x MON88302 (event code: ACS-BNOO5-8 x MON-883O2-9, gene:bar, commercially available, for example, as InVigor™ x TruFlex™ Roundup Ready™ Canola (wherein the O other than "MON" is written as a stroked O in the original text), RF1 x MON88302 (event code: ACS-BNOO1-4 x MON-883O2-9, gene:bar, commercially available, for example, as InVigor™ x TruFlex™ Roundup Ready™ Canola (wherein the O other than "MON" is written as a stroked O in the original text), RF2 x MON88302 (event code: ACS-BNOO2-5 x MON-883O2-9, gene: bar, e.g., commercially available as InVigor™ x TruFlex™ Roundup Ready™ Canola) (where O's other than "MON" are written as O's with strokes in the original text), HCN28 x MON88302(Event Code: ACS-BNOO8-2 x MON-883O2-9, Gene: pat, e.g., commercially available as InVigor™ x TruFlex™ Roundup Ready™ Canola) (where O's other than "MON" are written with a stroked O in the original text), HCN92 x MON88302 (Event Code: ACS-BNOO7-1 x MON-883O2-9, Gene: bar, e.g., commercially available as Liberty Link™ Innovator™ x TruFlex™ Roundup Ready™ Canola) (where O's other than "MON" are written with a stroked O in the original text), HCR-1 (Genetic: pat), MON88302 x MS8 x RF3 (Event Code: MON-883O2-9 x ACS-BNOO5-8 x ACS-BNOO3-6, gene:bar) (where Os other than "MON" are written as Os with a stroke in the original text), MON88302 x RF3 (event code:MON-883O2-9 x ACS-BNOO3-6, gene:bar) (where Os other than "MON" are written as Os with a stroke in the original text), MS8 x RF3 x GT73 (RT73) (event code:gene:bar), PHY14 (event code:ACS-BNOO5-8 x ACS-BNOO3-6 x MON-OOO73-7, gene:bar) (where Os other than "MON" are written as Os with a stroke in the original text), PHY23 (gene:bar), PHY35 (gene:bar) and PHY36 (gene:bar) and 73496 x RF3 (event code:DP-O73496-4 x ACS-BNOO3-6, gene: bar) (the O here is written as a stroked O in the original text).

[0131] Transgenic rice events comprising a glufosinate tolerance gene include, but are not limited to, the following: LLRICE06 (event code: ACS-OSOO1-4, e.g., commercially available as Liberty Link™ rice) (where the O is written as a stroked O in the original), LLRICE601 (event code: BCS-OSOO3-7, e.g., commercially available as Liberty Link™ rice) (where the O is written as a stroked O in the original), and LLRICE62 (event code: ACS-OSOO2-5, e.g., commercially available as Liberty Link™ rice) (where the O is written as a stroked O in the original).

[0132] The mixture of the present invention can be applied by conventional methods by using techniques that are familiar to those skilled in the art.Suitable techniques include, for example, spraying, dusting, spreading or watering.The application type is determined by the intended purpose in a well-known manner, but in any case, it should ensure that the active ingredient of the present invention is dispersed as finely as possible.

[0133] In one embodiment, the mixture of the present invention is applied to the application site primarily by spraying, particularly by foliar spraying of an aqueous dilution of the active ingredients of the mixture. Application can be carried out by conventional spraying techniques, for example using water as a carrier, with a spray volume of about 10 to 2000 L / ha or 50 to 1000 L / ha (e.g., 100 to 500 L / ha). Application of the mixture of the present invention in the form of fine particles is also possible using low-volume and ultra-low-volume methods.

[0134] The required application rate of the mixture of pure active compounds depends on the density of the undesired vegetation, the development stage of the plants, the climatic conditions where the mixture is used and the method of application.

[0135] In general, the application rate of L-glufosinate is usually within the range of 50 g / ha to 3000 g / ha of active substance (ai), preferably 100 g / ha to 2000 g / ha or 200 g / ha to 1500 g / ha of active substance (ai), and the application rate of herbicide compound II is within the range of 1 g / ha to 2000 g / ha of active substance (ai), preferably 5 g / ha to 1500 g / ha, more preferably 25 g / ha to 900 g / ha of active substance (ai).

[0136] The examples that follow illustrate the invention without imposing any limitations. [Example]

[0137] Biological Examples Synergy can be described as an interaction where the combined effect of two or more compounds exceeds the sum of the individual effects of each compound. The presence of synergy between two mixing partners (X and Y) in terms of percent control can be calculated using Colby's formula (Colby, SR, 1967, Calculating Synergistic and Antagonistic Responses in Herbicide Combinations, Weeds, 15, 20-22):

[0138]

number

[0139] If the observed control effect of the combination exceeds the predicted (calculated) control effect of the combination (E), the effect of the combination is synergistic.

[0140] The following tests demonstrate the control efficacy of the compounds, mixtures or compositions of the present invention against specific weeds. However, the weed control provided by the compounds, mixtures or compositions is not limited to these species. Analysis of synergy or antagonism between mixtures or compositions was determined using Colby's formula.

[0141] Test Method: The cultivation containers used were plastic pots containing loamy sandy soil with approximately 3.0% humus as a base soil. Seeds of the test plants were sown separately for each species and / or resistant biotype. For pre-emergence treatment, the active ingredient, suspended or emulsified in water, was applied using a fine spray nozzle immediately after sowing. The containers were gently irrigated to promote germination and growth, and then covered with a transparent plastic hood until the plants were established. This cover ensured uniform germination of the test plants, unless the active ingredient had damaged them. For post-emergence treatment, the test plants were first grown to a height of 3 to 15 cm, depending on their habit, and then treated with the active ingredient suspended or emulsified in water. For this purpose, the test plants were either directly sown and grown in the same container, or they were first grown separately as seedlings and transplanted into the test containers a few days before treatment. The plants were kept at 10 to 25°C or 20 to 35°C, depending on the species. The test period lasted 20 days after treatment. During this period, the plants were cared for and their response to each treatment was evaluated. Evaluations were made using a scale of 0 to 100, with "100" meaning no emergence or complete destruction of at least the above-ground parts of the plant, and "0" meaning no damage or normal growth. Data shown are the average of two replicates.

[0142] product: L-glufosinate: 5% EC formulation Triaziflam: 5% EC formulation Methiozolin: 250g / L SC formulation

[0143] [Table 3]

[0144] Example 1: Postemergence treatment with a mixture of L-glufosinate and triaziflam

[0145] [Table 4]

[0146] Example 2: Postemergence treatment with a mixture of L-glufosinate and methiozolin

[0147] [Table 5]

Claims

1. below: a) L-glufosinate and its salts as compound I; and b) Herbicide Compound II wherein L-glufosinate comprises more than 70% by weight of the L-enantiomer.

2. 2. The herbicidal mixture of claim 1, wherein compound I is selected from the group consisting of L-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts, and L-glufosinate as the free acid.

3. 2. The herbicidal mixture of claim 1, wherein compound I is L-glufosinate-ammonium.

4. 4. The herbicidal mixture according to claim 1, wherein L-glufosinate comprises more than 80% by weight, preferably more than 90% by weight, even more preferably 95% by weight of the L-enantiomer.

5. 5. Herbicidal mixtures according to any one of claims 1 to 4, wherein compound II is selected from the group consisting of chlorthiamid, dichlobenil, flupoxam, indaziflam, isoxaben, triaziflam, 1-cyclohexyl-5-pentafluorophenyloxy-14-[1,2,4,6]thiatriazin-3-ylamine, diflufenzopyr, diflufenzopyr-sodium, naptalam and naptalam-sodium, bromobutide, chlorflurenol, chlorflurenol-methyl, cinmethylin, cumyluron, cyclopyrimorate and its salts and esters, dalapon, dazomet, difeni selected from the group consisting of difenzoquat, difenzoquat-methylsulfate, dimethipine, DSMA, dymron, endothal and its salts, etobenzanide, flurenol, flurenol-butyl, flurprimidol, fosamine, fosamine-ammonium, indanofan, maleic hydrazide, mefluidide, metam, methiozoline, methyl azide, methyl bromide, methyl-dymron, methyl iodide, MSMA, oleic acid, oxaziclomefone, pelargonic acid, pyributicarb, quinoclamine, tridiphane; viranaphos (bialaphos) and viranaphos-sodium, Preferably, compound II is selected from the group consisting of dichlobenil, diflufenzopyr, diflufenzopyr-sodium, cinmethylin, bromobutide, cyclopyrimorate and its salts and esters, endothal and oxaziclomefone; Preferably, said herbicidal mixtures wherein compound II is selected from the group consisting of dichlobenil, diflufenzopyr, diflufenzopyr-sodium and cinmethylin.

6. 5. The herbicidal mixture according to claim 1, wherein compound II is selected from the group consisting of cinmethylin, oxaziclomefone, indaziflam, triaziflam, indanofan and methiozoline, Preferably, said herbicidal mixture wherein compound II is selected from the group consisting of triaziflam, indanofan, methiozoline and oxaziclomefone.

7. 5. The herbicidal mixture according to any one of claims 1 to 4, wherein compound II is selected from the group consisting of triaziflam, indanofan and methiozoline.

8. 8. The herbicidal mixture according to claim 1, wherein the weight ratio of compound I to compound II is from 1000:1 to 1:

500.

9. A pesticidal composition comprising a liquid or solid carrier and the mixture of any one of claims 1 to 8.

10. 9. A method for controlling undesirable vegetation, comprising applying a mixture according to any one of claims 1 to 8 to a locus where undesirable vegetation is present or expected to be present.

11. 11. The method according to claim 10, comprising the pre-emergence application of a mixture according to any one of claims 1 to 8 to the crop.

12. 11. The method according to claim 10, comprising the application of a mixture according to any one of claims 1 to 8 before planting of the crop.

13. 13. The method of any one of claims 10 to 12, wherein the crop is selected from rice, corn, cereals, cotton, canola, small grains, soybeans, peanuts, sugarcane, sunflowers, plantation crops, tree crops, tree nuts and grapes.

14. The method according to any one of claims 10 to 13, wherein the crop is selected from glufosinate-tolerant crops.

15. 15. The method according to any one of claims 10 to 14, wherein compounds I and II of the mixture according to any one of claims 1 to 8 are applied simultaneously, i.e. together or separately, or successively.

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