Cleansing cosmetics

Abstract

To provide an aqueous cleansing cosmetic obtained by combining a specific polyglycerol fatty acid ester which has a high cleaning effect on a makeup cosmetic such as a mascara, an eye makeup. a lipstick and a foundation, a cosmetic having high water proofness and sebum of the skin.SOLUTION: There is provided an aqueous cleansing cosmetic having an excellent cleaning effect by combining a specific polyglycerol fatty acid ester and further blending a stabilizer.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to an aqueous cleansing cosmetic composition having excellent cleansing ability by combining a specific polyglycerol fatty acid ester. [Background technology]

[0002] Cleansing cosmetics for removing makeup cosmetics are available in various formulations such as oil type, cream type, gel type, and lotion type, and are selected and used according to consumer preferences. Oil type and cream type containing oily components are compatible with makeup and have high cleansing performance even against highly waterproof makeup stains. Lotion type cleansing cosmetics that do not contain oily components or contain a small amount of oily components are preferred because they have a less oily feel during use and a refreshing feel after use, and there is a certain demand for them. However, lotion type cleansing cosmetics have a problem that they contain almost no oily components, so they have low cleansing performance and cannot fully remove highly waterproof mascara, eye makeup, lipstick, etc. In recent years, aqueous cleansing cosmetics containing nonionic surfactants to improve cleansing performance have been proposed (Patent Document 1, Patent Document 2). However, even with these technologies, the cleansing performance against highly waterproof makeup stains is still insufficient, and further improvements are required. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] JP 2011-037782 A [Patent Document 2] JP 2011-126805 A Summary of the Invention [Problem to be solved by the invention]

[0004] The object of the present invention is to provide an aqueous cleansing cosmetic composition that has excellent cleansing performance by combining a specific polyglycerol fatty acid ester, and that further contains a stabilizer to exhibit excellent stability over time. [Means for solving the problem]

[0005] Means for Solving the Problems The present inventors have conducted intensive research to solve the above problems, and as a result have discovered that by combining specific polyglycerol fatty acid esters and adjusting the blending ratio, it is possible to provide a cleansing cosmetic composition that has excellent cleansing effect despite being an aqueous cleansing cosmetic composition, and by further incorporating a stabilizer, a cleansing cosmetic composition that has excellent stability, thereby completing the present invention. Effect of the Invention

[0006] The present invention provides an excellent aqueous cleansing cosmetic that can thoroughly remove sebum from the skin, makeup cosmetics, cosmetics having high waterproof properties, and the like, by selecting and combining specific polyglycerol fatty acid esters, and further provides an aqueous cleansing cosmetic that is extremely stable over time by blending a stabilizer therein. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0007] Component (A) according to the present invention is one or more polyglycerol fatty acid esters selected from linear or branched, saturated or unsaturated fatty acid residues having 6 to 10 carbon atoms, and examples of the fatty acid include caproic acid, caprylic acid, caprylic / capric acid, and ethylhexanoic acid.

[0008] Furthermore, component (B) is one or more polyglycerol fatty acid esters selected from linear or branched, saturated or unsaturated fatty acid residues having 12 to 14 carbon atoms, and examples of the fatty acid include lauric acid and myristic acid.

[0009] The degree of polymerization of the polyglycerols of components (A) and (B) according to the present invention is 3 to 10. The polyglycerol fatty acid ester of the present invention can be obtained by esterification using an existing synthesis method, and the esterification rate of the fatty acid of component (A) is 7 to 25%, and the esterification rate of the fatty acid of component (B) is 7 to 18%, relative to 1 mole of the polyglycerol.

[0010] The esterification rates of components (A) and (B) according to the present invention are calculated based on the average degree of polymerization (n) of polyglycerol calculated from the hydroxyl value according to the Inorganic Chemical Substances Standards Method using the following formula 1, and the number of moles of fatty acid added to polyglycerol (M) based on formula 2. OHV=56110(n+2) / (74n+18) (Formula 1) Esterification rate (%) = (M / (n+2)) x 100 (Equation 2) OHV: Hydroxyl value of polyglycerol n: average degree of polymerization of polyglycerol M: The number of moles of fatty acid added to polyglycerol

[0011] Component (A) according to the present invention is not particularly limited, and examples thereof include triglyceryl caproate, triglyceryl caprylate, triglyceryl ethylhexanoate, triglyceryl caprate, tetraglyceryl caproate, tetraglyceryl caprylate, tetraglyceryl ethylhexanoate, tetraglyceryl caprate, pentaglyceryl caproate, pentaglyceryl caprylate, pentaglyceryl ethylhexanoate, pentaglyceryl caprate, and hexaglyceryl caproate. Examples of the glyceryl triglyceride include hexaglyceryl caprylate, hexaglyceryl ethylhexanoate, hexaglyceryl caprate, hexaglyceryl dicaprate, caprylic / capric acid triglyceride, decaglyceryl caproate, decaglyceryl dicaproate, decaglyceryl caprylate, decaglyceryl dicaprylate, decaglyceryl ethylhexanoate, decaglyceryl diethylhexanoate, decaglyceryl caprate, and decaglyceryl dicaprate, and one or more of these can be used. Preferred are triglyceryl caproate, triglyceryl caprylate, triglyceryl ethylhexanoate, triglyceryl caprate, (caprylic / capric acid) triglyceryl, tetraglyceryl caprate, tetraglyceryl caprylate, pentaglyceryl caproate, hexaglyceryl caprate, hexaglyceryl dicaprate, decaglyceryl caproate, and decaglyceryl dicaprylate. Component (A) according to the present invention is a polyglycerol fatty acid ester in the form of a monoester or diester.

[0012] Component (B) according to the present invention is not particularly limited, and examples thereof include triglyceryl laurate, tetraglyceryl laurate, hexaglyceryl laurate, decaglyceryl laurate, decaglyceryl dilaurate, triglyceryl myristate, tetraglyceryl myristate, hexaglyceryl myristate, decaglyceryl myristate, decaglyceryl dimyristate, and the like, and one or more of these can be used in the present invention. Preferred are triglyceryl laurate, tetraglyceryl laurate, hexaglyceryl laurate, decaglyceryl laurate, decaglyceryl dilaurate, hexaglyceryl myristate, and decaglyceryl myristate. Component (B) according to the present invention is a monoester or diester polyglycerol fatty acid ester. Commercially available products include NIKKOL Hexaglyn 1-L, NIKKOL Decaglyn 1-L, NIKKOL Decaglyn 1-M, and the like.

[0013] The excellent cleansing performance (cleaning ability) of the present invention can only be exhibited by using the components (A) and (B) in combination, and the excellent cleansing performance of the present invention cannot be exhibited by using only component (A) or only component (B).

[0014] The blending ratio of component (A) and component (B) blended in the aqueous cleansing cosmetic composition of the present invention is not particularly limited, but excellent cleansing performance is exhibited when component (A):component (B)=9:1 to 1:9, and preferably, component (A):component (B)=8:2 to 2:8.

[0015] The stabilizer of component (C) according to the present invention refers to anionic surfactants, cationic surfactants, amphoteric surfactants, fatty acids, amino acid esters, hydrolyzed collagen esters, alkyl ether carboxylic acids, alkyl phosphoric acids, and polyoxyethylene alkyl ether phosphates, and these may be blended singly or in combination of two or more types. Specifically, sodium caproyl lactylate, sodium (caproyl / lauroyl) lactylate, sodium lauroyl lactylate, sodium isostearoyl lactylate, sodium stearoyl lactylate, calcium stearoyl lactylate, sodium behenoyl lactylate, sodium caproyl methyl taurate, potassium methyl cocoyl taurate, sodium methyl cocoyl taurate, sodium methyl cocoyl taurate, sodium lauroyl methyl taurate, sodium myristoyl methyl taurate, sodium palmitoyl methyl taurate, sodium stearoyl methyl taurate, sodium methyl oleoyl taurate, sodium cocoyl alanine, TEA-cocoyl alanine, sodium methyl cocoyl alanine, potassium lauroyl methyl alanine, sodium lauroyl methyl alanine, TEA-lauroyl methyl alanine, sodium myristoyl methyl alanine, potassium cocoyl hydrolyzed collagen, sodium cocoyl hydrolyzed collagen, TEA-cocoyl hydrolyzed collagen, potassium cocoyl sarcosine, and sodium cocoyl sarcosine. Sodium cocoyl sarcosine, TEA-cocoyl sarcosine, potassium lauroyl sarcosine, sodium lauroyl sarcosine, TEA-lauroyl sarcosine, sodium myristoyl sarcosine, sodium palmitoyl sarcosine, oleoyl sarcosine, sodium oleoyl sarcosine, potassium cocoyl glutamate, sodium cocoyl glutamate, TEA-cocoyl glutamate, potassium lauroyl glutamate, sodium lauroyl glutamate, TEA-lauroyl glutamate, potassium myristoyl glutamate, myri Sodium stoyl glutamate, magnesium palmitoyl glutamate, potassium stearoyl glutamate, sodium stearoyl glutamate, sodium acyl (C12,14) aspartate, TEA acyl (C12,14) aspartate, potassium lauryl aspartate, sodium lauryl aspartate, TEA lauryl aspartate, potassium lauryl aspartate taurine, TEA lauryl aspartate taurine, sodium lauroyl aspartate, zinc lauroyl aspartate,Potassium myristyl aspartate, sodium myristyl aspartate, TEA myristyl aspartate, potassium myristyl aspartate taurine, TEA myristyl aspartate taurine, potassium cocoyl glycine, sodium cocoyl glycine, TEA cocoyl glycine, sodium lauroyl glycine, potassium laureth-3 carboxylate, sodium laureth-3 carboxylate, potassium laureth-4 carboxylate, sodium laureth-4 carboxylate, potassium laureth-5 carboxylate, sodium laureth-5 carboxylate, potassium laureth-6 carboxylate, sodium laureth-6 carboxylate, sodium laureth-8 carboxylate , potassium laureth-10 carboxylate, sodium laureth-11 carboxylate, sodium laureth-12 carboxylate, sodium laureth-13 carboxylate, sodium laureth-14 carboxylate, sodium laureth-16 carboxylate, sodium laureth-17 carboxylate, potassium trideceth-3 carboxylate, sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, potassium trideceth-7 carboxylate, sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, potassium trideceth-15 carboxylate, trideceth-15 carbo Sodium phosphate, potassium trideceth-19 carboxylate, sodium trideceth-19 carboxylate, (C12-14)s-pareth-8 carboxylate, sodium olefin (C14-16) sulfonate, potassium lauryl phosphate, sodium lauryl phosphate, disodium lauryl phosphate, sodium laureth-2 phosphate, sodium laureth-4 phosphate, sodium dilaureth-4 phosphate, sodium trilaureth-4 phosphate, sodium dilaureth-10 phosphate, sodium lauryl sulfate, potassium lauryl sulfate, TEA lauryl sulfate, ammonium lauryl sulfate, sodium cocoglyceryl sulfate, sodium myristyl sulfate, sodium cetyl sulfate, laureth sulfate Sodium laureth sulfate, ammonium laureth sulfate, arginine laureth sulfate, TEA laureth sulfate, sodium cocosulfoacetate, sodium lauryl sulfoacetate, disodium sulfoacetate, sodium diethylhexyl sulfosuccinate, sodium dioctyl sulfosuccinate, disodium lauryl sulfosuccinate, disodium cetearyl sulfosuccinate, disodium laureth sulfosuccinate, disodium deceth-5 sulfosuccinate, disodium deceth-6 sulfosuccinate, disodium sulfosuccinate (C12-14) pareth-2, sodium caprylate, potassium caprate, sodium caprate, potassium laurate, sodium laurate, magnesium laurate,Anionic surfactants such as potassium myristate, sodium myristate, magnesium myristate, calcium myristate, potassium palmitate, sodium palmitate, potassium stearate, sodium stearate, magnesium stearate, calcium stearate, potassium isostearate, and sodium isostearate; cationic surfactants such as cocoyl arginine ethyl PCA, benzalkonium chloride, lauroyltrimonium chloride, cetrimonium chloride, steartrimonium chloride, behentrimonium chloride, behentrimonium methosulfate, distearidinium chloride, quaternium-18, quaternium-33, stearamidopropyl dimethylamine, behenamidopropyl dimethylamine, and PPG-1 / PEG-1 stearamine; and (capryl / capramido)propyl behenate. Amphoteric surfactants such as lecithin derivatives including sodium lauroamphoacetate, sodium lauroamphoacetate, sodium cocoamphopropionate, lysolecithin, hydrogenated lysolecithin, hydrogenated lecithin, hydrogenated lecithin, and other phospholipid-containing lecithin derivatives, caproic acid , fatty acids such as caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, and isostearic acid, amino acid esters such as cocoyl methylalanine, lauroyl alanine, myristoyl methylalanine, cocoyl sarcosine, lauroyl sarcosine, cocoyl glutamic acid, lauroyl glutamic acid, myristoyl glutamic acid, stearoyl glutamic acid, lauryl aspartic acid, myristyl aspartic acid, caproyl glycine, undecynoyl glycine, and palmitoyl glycine, hydrolyzed collagen esters such as cocoyl hydrolyzed collagen, laureth-3 carboxylic acid, laureth-4 carboxylic acid, laureth-5 carboxylic acid, and laureth-6 carboxylic acid,Alkyl ether carboxylic acids such as laureth-8 carboxylic acid, laureth-10 carboxylic acid, laureth-11 carboxylic acid, laureth-12 carboxylic acid, laureth-13 carboxylic acid, laureth-14 carboxylic acid, laureth-17 carboxylic acid, trideceth-3 carboxylic acid, trideceth-4 carboxylic acid, trideceth-7 carboxylic acid, trideceth-8 carboxylic acid, trideceth-15 carboxylic acid, and trideceth-19 carboxylic acid; alkyl phosphates such as lauryl phosphate; laureth-1 phosphate, laureth-2 phosphate, laureth-3 phosphate, laureth-4 phosphate, isolaureth-4 phosphate, dilaureth-4 phosphate, trilaureth-4 phosphate, laureth-7 phosphate, and laureth-8 phosphate. Examples of the polyoxyethylene alkyl ether phosphates include polyoxyethylene alkyl ether phosphates such as dilaureth-10 phosphate, and preferred ones are laureth-1 phosphate, trilaureth-4 phosphate, stearamidopropyl dimethylamine, sodium isostearoyl lactylate, betaine, sodium diethylhexyl sulfosuccinate, sodium lauroyl methyl alanine, TEA lauroyl glutamate, sodium cocoamphoacetate, sodium cocoyl methyl taurine, sodium lauroyl methyl taurine, sodium lauroyl sarcosine, cocoyl arginine ethyl PCA, sodium cocoyl methyl taurine, cocamidopropyl betaine, hydroxide lecithin, hydrogenated lecithin, isostearic acid, and sodium isostearate.

[0016] The combined amount of components (A) and (B) blended in the aqueous cleansing cosmetic composition of the present invention is not particularly limited, but is preferably 2 to 20 mass%, more preferably 3 to 15 mass%, and even more preferably 3 to 10 mass%.

[0017] Component (C) blended in the aqueous cleansing cosmetic of the present invention plays the role of a stabilizer for the cleansing cosmetic, and the blending amount is preferably 0.01 to 1.0 mass %, and more preferably 0.05 to 1.0 mass %.

[0018] The aqueous cleansing cosmetic of the present invention may contain, within the scope of the present invention, components used in ordinary cosmetic preparations, such as oily components, higher alcohols, polyols, thickeners, moisturizing components, whitening components, anti-aging agents, skin roughness prevention agents, and other water-soluble and / or oil-soluble active ingredients, pH adjusters, fragrances, preservatives, etc. For example, examples of the oily components include hydrocarbon oils such as squalane, liquid paraffin, isododecane, hydrogenated farnesene, and C13-15 alkanes, vegetable oils such as jojoba oil, olive oil, sunflower seed oil, apricot kernel oil, macadamia seed oil, and coconut oil, and ester oils such as methylheptyl laurate, cetyl isooctanoate, triethylhexanoin, and tri(caprylic acid / capric acid)glyceryl, and examples of the polyols include glycerin, 1,3-butylene glycol, propylene glycol, dipropylene glycol, pentylene glycol, propene glycol, propylene ... Examples of thickeners include xanthan gum, hydroxyethyl cellulose, hydroxypropyl methylcellulose stearoxy ether, guar gum, carbomer, (acrylates / alkyl acrylate (C10-30)) crosspolymer, and examples of water-soluble and / or oil-soluble active ingredients include plant extracts, vitamin derivatives and their salts, retinol derivatives, tocopherol derivatives, salicylic acid derivatives, etc.

[0019] The formulation of the aqueous cleansing cosmetic composition of the present invention is not particularly limited, but examples thereof include lotion type, gel type, liquid type, and the like.

[0020] The present invention can be used by taking an appropriate amount of the present invention on the hand or finger, spreading it on the area to be used, and washing away sebum from the skin, makeup cosmetics, etc. Alternatively, the present invention can be used by impregnating cloth, cotton, paper, etc. with the present invention to wash away sebum from the skin, makeup cosmetics, etc.

[0021] The present invention will be described in more detail below with reference to examples, but the present invention is not limited thereto. The blending amounts of the present invention and comparative products are shown in mass %. EXAMPLES

[0022] The cleansing performance of the aqueous cleansing cosmetic composition of the present invention was evaluated. 1. Experimental Method The ingredients of the cleansing cosmetics shown in Tables 1 and 2 were measured out and mixed uniformly to prepare Products 1 to 6 of the present invention and Comparative Products 1 to 6. 2. Cleansing performance evaluation method 0.02g of commercially available red lipstick (highly waterproof lipstick) was evenly applied to a slide glass in an area of ​​1.5cm x 1.5cm and dried for 6 hours. This was used as an evaluation sample. Then, 0.05g of each cleansing cosmetic in Tables 1 and 2 was dropped onto the evaluation sample and the sample was rubbed with a finger for 10 seconds. Then, the sample was tapped 10 times with cotton to absorb the red lipstick that had risen to the surface, and the cotton was photographed together with a color chart for image correction, and the color difference (ΔE) of each was measured. The color chart for image correction is used when correcting the color tone and size of a photograph using a personal computer. By photographing this chart together with the subject, the color tone and size can be corrected according to a certain standard, and therefore, color difference errors are less likely to occur. <Evaluation criteria: Cleansing performance> ◎: ΔE≧60 (very high cleansing performance) 〇: 60>ΔE≧40 (high cleansing performance) △: 40>ΔE≧20 (moderate cleansing performance) ×: 20>ΔE (poor cleansing performance)

[0023] 3.Results From the results of Tables 1 and 2, it was confirmed that the products 1 to 6 of the present invention all had a color difference (ΔE) of 60 or more, and had high cleansing performance. On the other hand, the comparative products 1 to 6, which contained only one type of polyglycerol fatty acid ester, all had a ΔE of less than 40, and had poor cleansing performance. This revealed that by combining the specific polyglycerol fatty acid esters of the present invention, component (A) and component (B), it was possible to obtain an aqueous cleansing cosmetic with improved cleansing performance. Furthermore, it was confirmed that the product of the present invention also had high cleansing performance against ordinary makeup cosmetics and skin sebum.

[0024] [Table 1]

[0025] [Table 2] EXAMPLES

[0026] The cleansing performance and stability of the aqueous cleansing cosmetic composition of the present invention were evaluated. 1. Experimental Method The ingredients of the cleansing cosmetic preparations shown in Table 3 were weighed out and mixed uniformly to prepare invention products 7 to 10 and comparison products 7 to 10. 2. Cleansing performance evaluation 0.02g of commercially available red lipstick (highly waterproof lipstick) was evenly applied to a slide glass in an area of ​​1.5cm x 1.5cm and dried for 6 hours. This was used as an evaluation sample. Then, 0.05g of each cleansing cosmetic composition shown in Table 3 was dropped onto the evaluation sample and the sample was rubbed with a finger for 10 seconds. Then, the sample was tapped 10 times with cotton to absorb the red lipstick that had risen to the surface, and the cotton was photographed together with a color chart for image correction, and the color difference (ΔE) of each was measured. The color chart for image correction is used when correcting the color tone and size of a photograph using a computer. By photographing this chart together with the subject, the color tone and size can be corrected according to a certain standard, and therefore, color difference errors are less likely to occur. <Evaluation criteria: Cleansing performance> ◎: ΔE≧60 (very high cleansing performance) 〇: 60>ΔE≧40 (high cleansing performance) △: 40>ΔE≧20 (moderate cleansing performance) ×: 20>ΔE (poor cleansing performance) 3. Stability assessment Each cleansing cosmetic composition shown in Table 3 was placed in a glass bottle, and the cleansing cosmetic composition was compared immediately after preparation and after 3 months at 45° C., and its stability was visually confirmed. Evaluation was based on the following criteria. <Judgment criteria: stability> ◎: No change in appearance. ×: Separation, heterogeneity, and crystal precipitation were observed after 3 months at 45°C.

[0027] 4.Results From the results in Table 3, it was confirmed that the present invention products 7 to 9 containing component (C) all had high cleansing performance, and it was also revealed that the addition of component (C) significantly improved the stability as a cleansing cosmetic. On the other hand, the comparative products 7 to 9, which did not contain component (C) or contained 1.0 mass% or more of component (C), had high cleansing performance, but their stability as a cleansing cosmetic was poor, with separation and precipitation of crystals being confirmed. In addition, the cleansing performance of the comparative products 10 to 11, in which the esterification rate of the fatty acid of component (B) was 25% or more, was inferior to that of the present invention, but the stability of the comparative product 11 containing component (C) was confirmed to be improved. Therefore, it was revealed that component (C) contributes to the stability of the cleansing cosmetic.

[0028] [Table 3]

[0029] The aqueous cleansing cosmetic preparations of the present invention are shown below. The blending amounts are in mass %. The calculated esterification rate (%) of each component (A) and component (B) in Examples 3 to 10 is shown in parentheses. It was confirmed that each of Examples 3 to 10 exhibits excellent cleansing performance effects using the evaluation methods of Examples 1 and 2, and further confirmed that it has excellent stability over time. EXAMPLES

[0030] Cleansing lotion 1 Caprylic / capric triglyceride (20.00%) 1.50 (mass%) Tetraglyceryl laurate (16.67%) 1.50 Sodium Methyl Cocoyl Taurate 0.10 Glycerin 15.00 Preservatives (appropriate amount) Citric acid (appropriate amount) Sodium citrate (appropriate amount) Purified water remainder Total amount 100.00 (Preparation method) Mix all ingredients uniformly. (Results) Example 3 had very high cleansing performance, and when the cleansing effect was evaluated, the color difference (ΔE) was 63.5. Furthermore, when the stability was confirmed, it was found to have very high stability. EXAMPLES

[0031] Cleansing Lotion 2 Hexaglyceryl dicaprate (25.00%) 3.00 (mass%) Hexaglyceryl Laurate (12.50%) 2.00 Sodium Isostearoyl Lactylate 0.60 Sodium Isostearate 0.03 Propanediol 5.00 PPG-9 Diglyceryl 5.00 Ethylhexylglycerin 0.50 Preservatives (appropriate amount) Citric acid (appropriate amount) Sodium citrate (appropriate amount) Purified water remainder Total amount 100.00 (Preparation method) Mix all ingredients uniformly. (Results) Example 4 had very high cleansing performance, and when the cleansing effect was evaluated, the color difference (ΔE) was 66.1. Furthermore, when the stability was confirmed, it was found to have very high stability. EXAMPLES

[0032] Cleansing Lotion 3 Triglyceride caproate (20.00%) 2.00 (mass%) Decaglyceryl Laurate (8.33%) 6.00 Stearamidopropyl dimethylamine 0.20 1,3-Butylene glycol 5.00 Polyoxyethylene methyl glucoside 3.00 Betaine 1.00 Preservatives (appropriate amount) Citric acid (appropriate amount) Sodium citrate (appropriate amount) fragrance trace amount Purified water remainder Total amount 100.00 (Preparation method) Mix all ingredients uniformly. (Results) Example 5 had very high cleansing performance, and when the cleansing effect was evaluated, the color difference (ΔE) was 65.8. Furthermore, when the stability was confirmed, it was found to have very high stability. EXAMPLES

[0033] Cleansing Lotion 4 Tetraglyceryl caprylate (16.67%) 2.00 (mass%) Decaglyceryl Laurate (8.33%) 10.00 Diethylhexyl Sodium Sulfosuccinate 0.30 Trilaureth-4 Phosphate 0.05 Dipropylene glycol 3.00 Propanediol 5.00 Potassium sorbate (appropriate amount) Sodium benzoate appropriate amount Phosphoric acid (appropriate amount) Sodium phosphate (appropriate amount) Caprylic / Capric Triglyceride 0.10 Purified water remainder Total amount 100.00 (Preparation method) Mix all ingredients uniformly. (Results) Example 6 had very high cleansing performance, and when the cleansing effect was evaluated, the color difference (ΔE) was 69.2. Furthermore, when the stability was confirmed, it was found to have very high stability. EXAMPLES

[0034] Cleansing liquid 1 Hexaglyceryl caprylate (12.55%) 8.00 (mass%) Decaglyceryl myristate (8.33%) 2.00 Hydrogenated lecithin 0.50 Diglycerin 3.00 Sorbitol 2.00 Glyceryl Undecylenate 1.00 Citric acid (appropriate amount) Sodium citrate (appropriate amount) Aurovisco(tm) CS 7.50 Guar gum 0.05 Purified water remainder Total amount 100.00 * Aurovisco(tm) CS: Slurry containing 2% by weight of sodium phosphate-treated fine fibrous cellulose (manufactured by Oji Holdings Co., Ltd.) (Preparation method) Mix all ingredients uniformly. (Results) Example 7 had very high cleansing performance, and when the cleansing effect was evaluated, the color difference (ΔE) was 67.4. Furthermore, when the stability was confirmed, it was found to have very high stability. EXAMPLES

[0035] Cleansing Liquid 2 Decaglyceryl caprate (7.08%) 5.00 (mass%) Triglyceride myristate (18.00%) 2.00 Sodium Lauroyl Methylalanine 0.40 Isostearic acid 0.01 1,3-Butylene glycol 3.00 Dipropylene glycol 3.00 Glycerin 10.00 Preservatives (appropriate amount) Citric acid (appropriate amount) Sodium citrate (appropriate amount) Hydroxypropyl methylcellulose stearoxy ether 0.10 fragrance trace amount Purified water remainder Total amount 100.00 (Preparation method) Mix all ingredients uniformly. (Results) Example 8 had very high cleansing performance, and when the cleansing effect was evaluated, the color difference (ΔE) was 66.5. Furthermore, when the stability was confirmed, it was found to have very high stability. EXAMPLES

[0036] Cleansing gel 1 Triglyceride ethylhexanoate (20.00%) 10.00 (mass%) Decaglyceryl dilaurate (16.67%) 8.00 Hydroxylated lecithin 1.00 TEA-Lauroyl Glutamate 0.20 Propanediol 3.00 Glycerin 5.00 Octanediol 0.30 Potassium sorbate (appropriate amount) Sodium benzoate appropriate amount Phosphoric acid (appropriate amount) Sodium phosphate (appropriate amount) (Acrylates / Alkyl acrylate (C10-30) Crosspolymer 0.30 Sodium hydroxide trace amount Jojoba oil 0.20 Purified water remainder Total amount 100.00 (Preparation method) Mix all ingredients uniformly. (Results) Example 9 had very high cleansing performance, and when the cleansing effect was evaluated, the color difference (ΔE) was 76.8. Furthermore, when the stability was confirmed, it was found to have very high stability. EXAMPLES

[0037] Cleansing Gel 2 Decaglyceryl dicaprylate (16.67%) 10.00 (mass%) Triglyceride Laurate (18.00%) 5.00 Sodium Cocoamphoacetate 0.70 Pentylene glycol 2.00 1,3-Butylene glycol 5.00 Glycerin 8.00 Hexanediol 0.50 Preservatives (appropriate amount) Phosphoric acid (appropriate amount) Sodium phosphate (appropriate amount) Carbomer 0.20 Sodium hydroxide trace amount Isododecane 5.00 Purified water remainder Total amount 100.00 (Preparation method) Mix all ingredients uniformly. (Results) Example 10 had very high cleansing performance, and when the cleansing effect was evaluated, the color difference (ΔE) was 73.5. Furthermore, when the stability was confirmed, it was found to have very high stability. [Industrial Applicability]

[0038] The cleansing cosmetic of the present invention can provide an aqueous cleansing cosmetic which is composed of a specific polyglycerol fatty acid ester and has an excellent cleansing effect and excellent stability over time.

Claims

1. Component (A) a polyglycerol fatty acid ester having a fatty acid having 6 to 10 carbon atoms, and Component (B) a polyglycerol fatty acid ester having a fatty acid carbon number of 12 to 14, 1. An aqueous cleansing cosmetic composition comprising, as a component (C) stabilizer, 0.01 to 1.0 mass % of one or more selected from laureth-1 phosphate, trilaureth-4 phosphate, stearamidopropyl dimethylamine, sodium isostearoyl lactylate, betaine, sodium diethylhexyl sulfosuccinate, sodium lauroyl methylalanine, TEA lauroyl glutamate, sodium cocoamphoacetate, sodium cocoyl methyl taurine, sodium lauroyl methyl taurine, sodium lauroyl sarcosine, sodium cocoyl methyl taurine, cocamidopropyl betaine, hydroxylated lecithin, isostearic acid, and sodium isostearate, An aqueous cleansing cosmetic composition comprising one or more polyglycerol fatty acid esters selected from polyglycerols (A) and (B) having an average degree of polymerization of 3 to 10, and an esterification rate of fatty acid of component (A) of 7 to 25%, and an esterification rate of fatty acid of component (B) of 7 to 18%, the blending ratio of components (A) and (B) being component (A):component (B)=9:1 to 1:9, and the combined blending amount of components (A) and (B) being 2 to 20 mass% (however, excluding aqueous cleansing cosmetic compositions containing dipropylene glycol and aqueous cleansing cosmetic compositions containing cymen-5-ol).

2. The aqueous cleansing cosmetic composition according to claim 1, wherein component (A) is one or more selected from triglyceryl caproate, triglyceryl caprylate, triglyceryl ethylhexanoate, triglyceryl caprate, triglyceryl (caprylic / capric acid), tetraglyceryl caprate, tetraglyceryl caprylate, pentaglyceryl caproate, hexaglyceryl caprate, hexaglyceryl dicaprate, decaglyceryl caproate and decaglyceryl dicaprylate, and component (B) is one or more selected from triglyceryl laurate, tetraglyceryl laurate, hexaglyceryl laurate, decaglyceryl laurate, decaglyceryl dilaurate, hexaglyceryl myristate and decaglyceryl myristate.

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