Dispersion and cosmetic containing same

Abstract

Provided is a dispersion having excellent dispersibility, especially dispersibility in aqueous media, water resistance, and feel on use (absence of stickiness) that contains components (a)-(d): (a) 10-85 mass% of a hydrophobized inorganic powder having a number-average primary particle size by image analysis of a transmission electron micrograph of more than 200 nm and equal to or less than 700 nm, (b) 1-80 mass% of an aqueous component having two or more alcoholic hydroxyl groups, (c) 1-20 mass% of a polyglycerol-modified silicone that is soluble in component (b), and (d) 0-2 mass% of a polyglycerol-modified silicone that is insoluble in component (b), where the ratio of the content of component (d) to the content of component (c) represented by (d) / (c) is 0.1 or less.

Description

Dispersion and cosmetic containing same

[0001] The present invention relates to a dispersion containing a hydrophobic inorganic powder and a cosmetic preparation containing this dispersion.

[0002] Inorganic powders such as titanium oxide and iron oxide are commonly used in makeup cosmetics. These inorganic powders have the effect of improving the covering power, hiding skin troubles, and making the skin appear brighter and more rosy, thereby improving the overall appearance.

[0003] These inorganic powders are used to prepare dispersions in order to improve the dispersibility and usability of cosmetics. Various techniques for dispersing such hydrophobically treated inorganic powders have been investigated to date (see Patent Document 1). Among these, polyglycerin-modified silicones are known to have high dispersibility in the above-mentioned powders (see Patent Document 2). However, no research has been conducted on the dispersion of inorganic powders in aqueous media using polyglycerin-modified silicones.

[0004] These inorganic powders may be subjected to hydrophobic surface treatment for the purpose of blending them into the oil phase of cosmetics or for improving their water resistance. By blending such hydrophobically surface-treated powders, it is expected that the makeup effect can be maintained even when wet (Patent Document 3). On the other hand, when blending inorganic powders into the aqueous phase, powders that have been hydrophilically surface-treated with silica or the like may be used. However, these hydrophilized powders have issues with water resistance and feel when used. Furthermore, as a method for dispersing hydrophobized powders in water, dispersions of hydrophobized inorganic powders using polyether-modified silicone have been investigated. However, these dispersions of hydrophobized inorganic powders have issues with water resistance and feel when used (Patent Documents 4 and 5).

[0005] Furthermore, a technique for obtaining dispersible powders by surface-treating powders using silicone surfactants is known. However, the dispersion and water resistance of inorganic powders have not been sufficiently investigated (Patent Document 6). For these reasons, there has been a demand for dispersions that have improved dispersibility and water resistance and provide a good feel when incorporated into cosmetics.

[0006] JP 2016-079148 A JP 2004-169015 A JP 2021-001213 A JP 2017-218433 A International Publication No. 2017 / 203846 JP 2020-002031 A

[0007] The present invention has been made in view of the above circumstances, and aims to provide a dispersion that is excellent in dispersibility, particularly in aqueous media, water resistance, and feel in use (non-sticky). Another aim is to provide a cosmetic that incorporates this dispersion and is highly stable and excellent in water resistance and feel in use (non-sticky).

[0008] The present inventors have conducted extensive research to solve the above-mentioned problems, and as a result, have found that a dispersion containing the following components (a) to (d): (a) 10 to 85 mass % of a hydrophobized inorganic powder having a number average primary particle diameter of more than 200 nm but not more than 700 nm, as measured by image analysis of transmission electron micrographs; (b) 1.0 to 80 mass % of an aqueous component having two or more alcoholic hydroxyl groups; (c) 1.0 to 20 mass % of a polyglycerin-modified silicone that is soluble in component (b); and (d) 0 to 2 mass % of a polyglycerin-modified silicone that is insoluble in component (b), wherein the ratio of the content of component (d) to the content of component (c), expressed as (d) / (c), is 0.1 or less, provides a dispersion that is excellent in dispersibility, particularly dispersibility in aqueous media, water resistance, and usability (non-stickiness). Furthermore, they discovered that when incorporated into cosmetics, the resulting cosmetics do not cause problems such as viscosity reduction or gelation, and are highly stable, water-resistant, and have an excellent feel when used (non-sticky), leading to the completion of the present invention.

[0009] Accordingly, the present invention provides the following dispersion and a cosmetic composition containing the same. 1. A dispersion containing the following components (a) to (d): (a) 10 to 85% by mass of a hydrophobized inorganic powder having a number-average primary particle diameter of more than 200 nm and not more than 700 nm as measured by image analysis of transmission electron micrographs; (b) 1 to 80% by mass of an aqueous component having two or more alcoholic hydroxyl groups; (c) 1 to 20% by mass of a polyglycerin-modified silicone soluble in component (b); and (d) 0 to 2% by mass of a polyglycerin-modified silicone insoluble in component (b), wherein the ratio of the content of component (d) to the content of component (c), expressed as (d) / (c), is 0.1 or less. 2. The dispersion according to claim 1, wherein component (a) is an inorganic powder hydrophobized with silicone. 3. The dispersion according to claim 2, wherein the silicone is triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone. 4. The dispersion according to any one of 1 to 3, wherein the content of component (a) is 70 to 85% by mass. 5. The dispersion according to any one of 1 to 4, wherein component (a) is a color pigment. 6. The dispersion according to any one of 1 to 5, wherein component (c) is polyglyceryl-3 disiloxane dimethicone. 7. The dispersion according to any one of 1 to 6, wherein the content of component (c) is 3.0 to 8.0% by mass. 8. The dispersion according to any one of 1 to 7, wherein the ratio of the content of component (c) to the content of component (b), expressed as (c) / (b), is 0.1 to 0.4. 9. A cosmetic preparation containing the dispersion according to any one of 1 to 8.

[0010] According to the present invention, it is possible to provide a dispersion of an inorganic powder that has excellent dispersibility, particularly in aqueous media, and excellent water resistance and a feeling of use (non-stickiness). In particular, it is possible to provide a highly stable dispersion even of titanium oxide fine particles, which are difficult to disperse. Furthermore, by incorporating this dispersion, it is possible to provide a cosmetic that has high stability, excellent water resistance, and a feeling of use (non-stickiness).

[0011] The present invention will be described in detail below. In the present invention, ingredient names may be written as cosmetic names or International Nomenclature of Cosmetic Ingredients (INCI). When the cosmetic name corresponds to the INCI, the cosmetic name or the English name may be omitted.

[0012] [Component (a)] The component (a) of the present invention is a hydrophobized inorganic powder having a number average primary particle diameter of more than 200 nm but not more than 700 nm, as measured by image analysis of transmission electron micrographs, and can be used singly or in combination of two or more types.

[0013] The number average primary particle diameter of component (a) measured by image analysis of a transmission electron microscope photograph is greater than 200 nm and not greater than 700 nm, preferably 220 to 650 nm. 240 to 600 nm is more preferable. A particle diameter greater than 700 nm may result in a heavy feel when used, while a particle diameter of 200 nm or less may result in a dry or squeaky feel, resulting in a poor feel when used. The average primary particle diameter of component (a) of the present invention is the number average diameter measured by image analysis of a transmission electron microscope photograph. When the powder is not spherical, the average value of the minor axis of the particles is taken as the average primary particle diameter.

[0014] The inorganic powder may be any raw material that can be generally incorporated into cosmetics, and may be used alone or in combination of two or more. Specific examples include color pigments. The color pigment is not particularly limited as long as it is a pigment that is normally used for coloring cosmetics, and examples thereof include red iron oxide (display name (INCI: Iron Oxides)), yellow iron oxide (display name (INCI: Iron Oxides)), white titanium oxide (display name (INCI: Titanium Dioxide)), black iron oxide (display name (INCI: Iron Oxides)), ultramarines (display name (INCI: Ultramarines)), ferric ferrocyanide (display name (INCI: Ferric Ferrocyanide, Ferric Ammonium Ferrocyanide)), manganese violet (display name (INCI: Manganese Violet)), cobalt titanate (display name (INCI: Cobalt Titanium Oxide), chromium hydroxide (label name (INCI: Chromium Hydroxide Green)), chromium oxide (label name (INCI: Chromium Oxide Greens)), aluminum / cobalt oxide (label name (INCI: Cobalt Aluminum Oxide)), titanium / titanium oxide sintered product (label name (INCI: Titanium / Titanium Dioxide)), lithium / cobalt titanate (label name (INCI: Lithium Cobalt Titanate)), iron oxide / titanium oxide sintered product (label name), iron oxide-doped titanium oxide (label name (INCI: Iron Oxides, Titanium Any of the following pigments can be used: composites doped with a different metal such as titanium nitride (display name (INCI: Titanium Nitride)), ferrous hydroxide (display name (INCI: Iron Hydroxide)), inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as ochre, colored pigments such as lakes of tar-based pigments and lakes of natural pigments. The shape of the pigment may be spherical, approximately spherical, rod-shaped, spindle-shaped, petal-shaped, strip-shaped, irregular, or the like, and there is no particular limitation on the geometric form as long as it is possible to impart color to the cosmetic.

[0015] In order to reduce cohesion or suppress the activity of the powder, inorganic powders may be surface-treated with silica, hydrous silica, alumina, aluminum hydroxide, or the like before hydrophobization. Note that alumina and aluminum hydroxide are not preferred as the surface treatment agents when blended into cosmetics, as they may inhibit the swelling of the water-soluble polymer compound used in combination or may reduce water resistance. It is preferable to not perform the above treatment before hydrophobization, or to use a composite powder that is surface-treated with hydrous silica, which suppresses the activity of the powder and is less likely to inhibit the swelling of the water-soluble polymer compound.

[0016] The hydrophobic inorganic powder can be obtained by hydrophobic treatment. The hydrophobic treatment agent is not particularly limited as long as it is a known treatment agent generally used in cosmetics. For example, silanes or silylating agents such as triethoxycaprylylsilane (manufactured by Shin-Etsu Chemical Co., Ltd.: AES-3083), aminopropyltriethoxysilane, etc., dimethyl silicone (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-96AK series), methylhydrogen-type polysiloxanes such as hydrogen dimethicone (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-99P, KF-9901, etc.), silicones such as triethoxysilylethyl polydimethylsiloxyethyl dimethicone, triethoxysilylethyl polydimethylsiloxyethyl hexyl dimethicone, etc. Examples of suitable silicones include cone-branched silicones (e.g., KF-9908, KF-9909, etc., manufactured by Shin-Etsu Chemical Co., Ltd.), waxes, paraffins, organic fluorine compounds such as perfluoroalkyl phosphates, surfactants, N-acyl glutamic acid and salts thereof, amino acids such as lauroyl lysine and sodium lauroyl aspartate, esters such as isostearyl sebacate and polyglyceryl triisostearate, metal soaps such as aluminum stearate and magnesium myristate, and isopropyl titanium triisostearate. In particular, silicone treatment is preferred in terms of dispersibility with component (c), and components containing one or more selected from triethoxycaprylylsilane, triethoxysilylethyl polydimethylsiloxyethyl dimethicone, triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone, and hydrogen dimethicone are more preferred, with triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone being most preferred. The hydrophobic treatment method is not particularly limited, and any known method can be used, such as a wet treatment method, a dry treatment method, or a gas phase method.

[0017] Specific examples of color pigments that have been subjected to hydrophobic treatment include the KTP-09 series manufactured by Shin-Etsu Chemical Co., Ltd., particularly KTP-09W, KTP-09R, KTP-09Y, and KTP-09B.

[0018] The content of component (a) in the dispersion is 10 to 85% by mass, preferably 40 to 85% by mass, more preferably 70 to 85% by mass, and even more preferably 75 to 80% by mass. If it is less than 10% by mass, the viscosity of the dispersion may decrease, and the stability over time of the dispersion may decrease. If it is blended in more than 85% by mass, the spreadability during use may decrease, the stability over time of the dispersion may decrease, and the viscosity may increase.

[0019] [Component (b)] The component (b) of the present invention is an aqueous component having two or more alcoholic hydroxyl groups, i.e., a component that dissolves in water at 25° C., and can be used alone or in combination of two or more. By blending component (b), component (c) can be uniformly oriented on the surface of component (a). Specifically, sugar alcohols such as sorbitol (INCI), maltose (INCI), xylitol (INCI), glucose (INCI), glyceryl glucoside (INCI), sodium chondroitin sulfate (display name (INCI: Sodium Chondroitin Sulfate)), methyl gluceth-10 (INCI), methyl gluceth-20 (INCI), hyaluronic acid, phosphatidylglycerol, and phosphatidylinositol, BG (display name (INCI: Butylene Glycol)), PG (display name (INCI: Propylene Glycol)), DPG (display name (INCI: Dipropylene Glycol)), and the like. Glycol), pentylene glycol (INCI), 1,10-decanediol (INCI), octanediol (INCI), 1,2-hexanediol (INCI), and other glycols; and polyhydric alcohols such as erythritol (INCI), glycerin (INCI), diglycerin (INCI), and polyethylene glycol. Of these, glycols such as BG (butylene glycol) and DPG (dipropylene glycol), and polyhydric alcohols such as glycerin are preferred because they dissolve in water in any proportion, and furthermore, they offer a good feel when used and are versatile as a cosmetic ingredient. Glycols having two alcoholic hydroxyl groups in the molecule are particularly preferred.

[0020] The content of component (b) in the dispersion is 1.0 to 80% by mass, preferably 5 to 30% by mass, and more preferably 10 to 25% by mass. From the viewpoint of water resistance, 7 to 15% by mass is more preferable. From the viewpoint of stability over time, 15 to 25% by mass is more preferable, and 15 to 20% by mass is even more preferable. If the content is less than 1.0% by mass, the stability of the dispersion will be poor. By keeping the content at 30% by mass or less, stickiness of the cosmetic can be further suppressed, and the (b) component can be prevented from inhibiting the orientation of component (c) (described below) toward component (a) due to the incorporation of a large amount of component (b), and the viscosity will not become too high, thereby achieving better dispersibility in an aqueous medium.

[0021] [Component (c)] Component (c) of the present invention is a polyglycerin-modified silicone soluble in component (b), and can be used alone or in combination of two or more. By using a polyglycerin-modified silicone soluble in component (b), the polyglycerin-modified silicone can be incorporated into water and function as a dispersant for hydrophobically treated inorganic powders in water. The term "soluble in component (b)" refers to a transparent to translucent state without a boundary when component (c) is mixed with component (b) at a concentration of 20% by mass and then allowed to stand at 25°C. This refers to a "soluble" state, whereas a state where the mixture becomes cloudy or separates into two layers is considered "insoluble." Furthermore, the term "transparent to translucent state" refers to a total light transmittance of 50% or greater when the mixture is filled into a 1 cm thick cell and measured according to the method described in JIS K7361-1:1997. When component (b) is solid at 25°C, it is dissolved at or above its melting point, and the same judgment is made visually.

[0022] In terms of chemical structure, the (c) polyglycerin-modified silicone may be block-modified or graft-modified using polyglycerin, with the silicone chain serving as the main chain. From the viewpoint of maintaining uniform dispersibility of component (a) in the cosmetic, a branched-chain type is more preferable. The silicone main chain may have a branched chain such as a silicone chain. Specific examples include polyglyceryl-3 disiloxane dimethicone (INCI). From the viewpoint of water resistance, component (c) is preferably one that dissolves at 25°C when mixed in BG at a concentration of 20% by mass, and does not dissolve at 25°C when mixed in water at a concentration of 20% by mass. The polyglycerin-modified silicone of the present invention may be co-modified with hydrophilic groups other than polyglycerin groups, but at least 50% by mass of the hydrophilic groups are polyglycerin groups. From the viewpoint of water resistance, silicones modified only with polyglycerin groups are preferred.

[0023] Furthermore, the polyglycerin-modified silicone (c) used in the present invention preferably has an HLB (Hydrophile-Lipophile Balance) value of 3 or more and less than 17, more preferably 5 or more and less than 15, and even more preferably 8 or more and less than 12. If the HLB value is less than 3, the affinity for water is low, resulting in reduced dispersibility, and if the HLB value is 17 or more, there is a concern that water resistance may be reduced. The HLB is calculated by "(sum of formula weights of hydrophilic group moieties / total molecular weight) x 20".

[0024] The content of component (c) in the dispersion is 1.0 to 20% by mass, preferably 1 to 15% by mass, more preferably 2 to 10% by mass, and even more preferably 3 to 8% by mass. If the content is less than 1.0% by mass, the stability of the dispersion may be impaired. If the content exceeds 20% by mass, the component (c) may be further oriented to the component (a), or the component (c) that is not oriented to the component (a) may be easily peeled off. As a result, the viscosity of the dispersion itself may increase, and the dispersibility may be affected when dispersed in an aqueous medium.

[0025] Furthermore, the ratio of the content of component (c) to the content of component (b), expressed as (c) / (b), is preferably 0.1 to 1.2. In particular, from the viewpoints of dispersibility and water resistance, a ratio of 0.1 to 0.7 is preferred, and a ratio of 0.1 to 0.4 is even more preferred. By setting this ratio to 0.1 or more, it is possible to prevent component (b) from interfering with the orientation of component (c) toward component (a), thereby further suppressing an increase in viscosity and achieving better stability. By setting the ratio to 1.2 or less, component (c) is sufficiently dispersed in the dispersion medium, making it easier for component (c) to orient toward component (a), further suppressing an increase in viscosity and achieving better stability.

[0026] [Component (d)] The component (d) of the present invention is a polyglycerin-modified silicone that is insoluble in component (b), and can be used alone or in combination of two or more. The definition of "insoluble in component (b)" is as set forth above. Component (d) is a polyglycerin-modified silicone excluding component (c), and examples include non-crosslinked polyglycerin-modified silicones and crosslinked polyglycerin-modified silicones.

[0027] The non-crosslinked polyglycerin-modified silicone of component (d) may be chemically structured such that the silicone main chain is block-modified or graft-modified using polyglycerin. The silicone main chain may have a branched chain such as a silicone chain. Specific examples include polyglyceryl-3 polydimethylsiloxyethyl dimethicone (INCI), lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (INCI), and isostearyl polyglyceryl-3 dimethicone (INCI). Commercially available examples include KF-6104, KF-6106, KF-6105, KF-6180, and KF-6115 manufactured by Shin-Etsu Chemical Co., Ltd.

[0028] Examples of the crosslinked polyglycerin-modified silicone of component (d) include (dimethicone / polyglycerin-3) crosspolymer (INCI), (lauryl dimethicone / polyglycerin-3) crosspolymer (INCI), (polyglycerin-3 / lauryl polydimethylsiloxyethyl dimethicone) crosspolymer (INCI), etc. Examples of commercially available crosslinked silicone surfactants that swell when exposed to a liquid oil include KSG-710, KSG-790, KSG-810, KSG-820, KSG-830, KSG-840, KSG-820Z, KSG-850Z, etc., manufactured by Shin-Etsu Chemical Co., Ltd.

[0029] The blending amount of component (d) in the dispersion is 0 to 2% by mass, preferably 0 to 1% by mass. Component (d) may not be contained. The ratio of the content of component (d) to the content of component (c), expressed as (d) / (c), is 0.1 or less, preferably 0.10 or less, and more preferably 0.08 or less. In particular, from the viewpoint of dispersibility, it is preferably 0.05 or less, and even more preferably 0. If this ratio exceeds 0.1, component (d) interacts with component (c), inhibiting the orientation of component (c) into powder, thereby reducing water dispersibility. Furthermore, the viscosity of the dispersion may increase, potentially affecting stability.

[0030] The total content of components (a), (b), (c), and (d) in the dispersion of the present invention is preferably 80 to 100% by mass, more preferably 90 to 100% by mass, and even more preferably 99 to 100% by mass. By making the total content of components (a), (b), (c), and (d) 80% by mass or more, a dispersion with good stability and usability can be produced, while if the total content is less than 80% by mass, there is a risk of concerns about the stability of the dispersion due to the influence of components other than components (a), (b), (c), and (d).

[0031] The dispersion of the present invention may contain water. When water is contained, the amount of water contained in the dispersion is preferably 0 to 20% by mass, and more preferably no water is contained.

[0032] An antifoaming agent may be added to the dispersion for the purpose of improving handling during preparation, filling, etc. Examples of antifoaming agents include salts such as simethicone (INCI), dimethicone (INCI), sodium chloride (labeled name (INCI: Sodium Chloride)), polyether-modified silicone, etc. Furthermore, oil-based agents such as dimethicone may be used as a pre-emulsified emulsion type, and compound-based agents such as simethicone may be used as a self-emulsifying type pre-mixed with a silicone surfactant, etc. Among these, simethicone and sodium chloride are particularly preferred in terms of foam-breaking and foam-suppressing properties, and simethicone is most preferred in terms of affinity with cosmetic ingredients. The amount of antifoaming agent to be added is preferably 0.0001 to 1% by mass of the total dispersion, more preferably 0.0025 to 0.6% by mass, and even more preferably 0.005 to 0.01% by mass.

[0033] [Dispersion] The dispersion of the present invention can be easily blended into an aqueous medium, and although temporary sedimentation is observed in the dispersibility test in the Examples described below, it has the effect of being uniformly dispersed upon continued stirring.

[0034] [Form of Dispersion] The dispersion of the present invention is preferably in a paste or liquid form. In the case of a paste, the hardness is preferably 1 to 180, more preferably 1 to 100, and even more preferably 1 to 50. In the case of a liquid, the hardness is preferably 10 to 30,000 mPa·s, more preferably 10 to 10,000 mPa·s, and even more preferably 10 to 5,000 mPa·s. If the hardness is higher than 180, handling becomes difficult, and if the viscosity is less than 10 mPa·s, the powder tends to settle, raising concerns about the stability of the dispersion. The hardness is a value measured using a rheometer, for example, a Rheometer RT-2002D·D (manufactured by Rheotec Corporation, measurement probe: 3 mmφ, penetration depth: 10 mm, sample stage rising speed: 5 cm / min, temperature: 25°C, range: 200). The viscosity was measured at 25°C using a Brookfield viscometer (TVB-10 model, manufactured by Toki Sangyo Co., Ltd.) according to the method described in JIS K 7117-1:1999.

[0035] The dispersion of the present invention is preferably water-dispersible. In the present invention, "water-dispersible" means that when 0.5 g of the dispersion is placed in a beaker containing 50 mL of water and stirred for less than 2 minutes, no sedimentation occurs and the dispersion is uniformly dispersed. The time for uniform dispersion is preferably less than 1 minute, more preferably less than 30 seconds.

[0036] [Method for producing dispersion] When preparing the dispersion of the present invention, the method and apparatus therefor are not particularly limited, and can be carried out by a known method. For example, any stirrer, grinder, mixer, medium stirrer, planetary mixer, ribbon blender, disperser, homomixer, jet mill, roll mill, bead mill, high-pressure disperser, etc. can be used. In particular, from the viewpoint of mixing efficiency, it is preferable to use a roll mill for dispersion.

[0037] [Cosmetics] The dispersion of the present invention can be used for various purposes, but is particularly applicable as a raw material for all cosmetics that are applied externally to the skin or hair.

[0038] When the dispersion of the present invention is blended in a cosmetic, the amount is preferably 0.5 to 60% by mass, more preferably 1.0 to 50% by mass, and even more preferably 5.0 to 40% by mass, based on the total mass of the cosmetic. If the amount is less than 0.5% by mass, a sufficient makeup effect cannot be expected, and if the amount is 60% by mass or more, there is a concern that the feel during use may be poor.

[0039] Cosmetics containing the dispersion of the present invention may be in any form, for example, a water-in-oil emulsion cosmetic, an oil-in-water emulsion cosmetic, an aqueous cosmetic, or a multiple emulsion such as a W / O / W type or an O / W / O type. In particular, when used as a dispersion of an oil-in-water emulsion cosmetic, it is easy to apply, and a stable cosmetic having excellent stability, water resistance, and usability can be obtained.

[0040] The cosmetic of the present invention can be in a variety of forms, including liquid, emulsion, cream, solid, paste, gel, powder, pressed, multilayered, mousse, spray, stick, and pencil form. Multilayered cosmetic preparations are those that separate into two or more layers upon standing. They are filled into a container containing a stainless steel ball or the like and are used after shaking. Because the dispersion of the present invention has good dispersibility, it is easy to redisperse even in this formulation. These are called shaking types, and because they are easily stabilized, they provide a cosmetic preparation with an excellent feel in use, but require the effort of shaking. Because the cosmetic of the present invention is preferred for its stability, it can be used without separating into multiple layers. Sprayed cosmetic preparations are sprayed into dispenser containers, aerosol containers, etc., and used by spraying from a nozzle. The cosmetic filled into the dispenser container is sprayed in a mist from the dispenser nozzle. The aerosol container is filled with the cosmetic and a propellant. The propellant is not particularly limited, and examples thereof include various liquefied petroleum gases (LPG), dimethyl ether, nitrogen gas, carbon dioxide gas, etc. These may be used alone or in appropriate combinations of two or more. The dispersion of the present invention has high dispersibility and can therefore be used in such formulations.

[0041] The dispersion of the present invention can be applied to various cosmetics, but is particularly preferred in cosmetics applied to the skin, such as skin care cosmetics, makeup cosmetics, antiperspirant cosmetics, and UV protection cosmetics, and cosmetics applied to the hair, such as hair cosmetics. Examples of skin care cosmetics include lotions, emulsions, creams, cleansers, packs, oil liquids, massage products, beauty serums, beauty oils, detergents, deodorants, hand creams, lip balms, and wrinkle concealers. Examples of makeup cosmetics include makeup bases, concealers, face powders, powder foundations, eye color, eye shadow, mascara, eyeliner, eyebrow pencils, and lipsticks. Examples of antiperspirant cosmetics include roll-on, cream, solution, and stick-type antiperspirant cosmetics. Examples of UV protection cosmetics include sunscreen oils, sunscreen emulsions, and sunscreen creams. Examples of hair cosmetics include shampoos, rinses, treatments, and setting agents. Of these, makeup cosmetics are particularly preferred.

[0042] The cosmetic of the present invention may contain various components commonly used in cosmetics to the extent that the effects of the present invention are not impaired. For example, it may contain (1) an oil, (2) an aqueous component other than component (b), (3) a surfactant other than components (c) and (d), (4) a powder other than component (a), (5) a composition consisting of a crosslinked organopolysiloxane and an oil that is liquid at room temperature, (6) a film-forming agent, and (7) other additives. These may be used alone or in appropriate combinations of two or more. The components exemplified in the dispersion above may also be included. The components contained in the dispersion above may also be blended. However, blending components (a) to (c) of the present invention into a cosmetic without blending the dispersion of the present invention will not achieve the significant effects intended by the present invention.

[0043] (1) Oils The oils may be volatile or non-volatile and may be solid, semi-solid, or liquid at room temperature (25°C). Examples of the oils include silicone oils, silicone waxes, natural animal and vegetable oils and semi-synthetic oils and fats, hydrocarbon oils, higher alcohols, fatty acids, ester oils, fluorine-based oils, and ultraviolet absorbers.

[0044] Silicone Oils Examples of silicone oils include alkyl-modified silicones such as dimethicone (INCI), trisiloxane (INCI), methyl trimethicone (INCI), ethyl trisiloxane (INCI), ethyl methicone (INCI), and hexyl dimethicone (INCI), long-chain alkyl-modified silicones such as caprylyl methicone (INCI), low- to high-viscosity linear or branched organopolysiloxanes such as phenyl trimethicone (INCI), diphenyl dimethicone (INCI), diphenylsiloxy phenyl trimethicone (INCI), tetraphenyldimethyldisiloxane (INCI), and methylhydrogen polysiloxane, cyclotetrasiloxane (INCI), cyclopentasiloxane (INCI), and silicone oils. Examples of the organic solvent include cyclic organopolysiloxanes such as cyclohexasiloxane (INCI), amino-modified organopolysiloxanes such as amodimethicone (INCI) and aminopropyl dimethicone (INCI), pyrrolidone-modified organopolysiloxanes such as PCA dimethicone (INCI), antifoaming agents such as simethicone (INCI), pyrrolidonecarboxylic acid-modified organopolysiloxanes, silicone rubbers such as gummy dimethylpolysiloxanes with a high degree of polymerization, gummy amino-modified organopolysiloxanes, and gummy dimethylsiloxane-methylphenylsiloxane copolymers, as well as low-viscosity organopolysiloxane solutions of silicone gums and rubbers, amino acid-modified silicones, fluorine-modified silicones, silicone resins, and silicone resin solutions. Examples of commercially available silicone oils include KF-96L-1cs, KF-96L-1.5cs, KF-96L-2cs, KF-96A-6cs, KF-4422, KF-4418, KF-54, KF-54HV, KF-56A, and KF-995 manufactured by Shin-Etsu Chemical Co., Ltd.

[0045] In the present invention, when it is desired to solidify the cosmetic, it is preferable to blend an oily component that is solid at 25°C. The oily component that is solid at 25°C preferably has a melting point of 40°C or higher, more preferably 60 to 110°C, and examples thereof include waxes, hydrocarbons, esters, higher alcohols, and higher fatty acids, and is not particularly limited as long as it is a raw material that can be blended into ordinary cosmetic compositions. Specific examples of such waxes include carnauba wax (INCI: Copernicia Cerifera (Carnauba) Wax), sugarcane wax, candelilla wax (INCI: Euphorbia Cerifera (Candelilla) Wax), refined candelilla wax, rice wax, Japan wax, jojoba wax, kapok wax, rice bran wax, white bayberry fruit wax, shea butter, cacao butter, Japan wax (INCI: Rhus Succedanea Fruit Wax), montan wax (INCI: Montan Wax), vegetable waxes such as hydrogenated castor oil isostearate, beeswax, beef tallow, beef bone fat, lard (INCI: Lard), and horse fat (INCI: Horse Fat). Fat), sheep tallow, lanolin (INCI: Lanolin), animal waxes such as butterbur, shellac wax, and spermaceti; semi-synthetic waxes such as lanolin esters, lanolin fatty acid esters, and beeswax acid esters; hydrogenated oils such as hydrogenated castor oil and hydrogenated coconut oil; hydrocarbon waxes such as solid paraffin, polyethylene, ceresin, ozokerite, and microcrystalline wax; wax esters such as synthetic beeswax; amino acid stearyl alcohols such as dioctyldodecyl lauroyl glutamate, dioctyldodecyl lauroyl glutamate, and dioctyldodecyl lauroyl glutamate; fatty acids such as stearic acid and behenic acid; and silicone waxes such as acrylic silicone resins of acrylic-silicone graft or block copolymers (manufactured by Shin-Etsu Chemical Co., Ltd.: acrylic-silicone graft copolymers: KP-561P, 562P, etc.), or derivatives thereof, and it is preferable to use one or more selected from these.

[0046] Natural animal and vegetable oils and semi-synthetic oils Examples of natural animal and vegetable oils and semi-synthetic oils include avocado oil (labeling name (INCI: Persea Gratissima (Avocado) Oil)), linseed oil (labeling name (INCI: Linum Usitatissimum (Linseed) Seed Oil)), almond oil (labeling name (INCI: Prunus Amygdalus Dulcis (Sweet Almond) Oil)), perilla oil (labeling name), olive oil (labeling name (INCI: Olea Europaea (Olive) Fruit Oil)), and American grass oil (labeling name (INCI: Torreya California (California Nutmeg Oil)), Cymbopogon Nardus (Citronella Oil)), Kaya Seed Oil (InCI: Torreya Nucifera Seed Sesame oil (Indication name: INCI: Triticum Vulgare (Wheat) Germ Oil) Seed Oil)), rice germ oil (display name (INCI: Oryza Sativa (Rice)) Germ Oil)), rice bran oil (indication name (INCI: Oryza Sativa (Rice) Bran Oil)), sasanqua oil (indication name (INCI: Camellia Kissi Seed Oil)), safflower oil (indication name (INCI: Carthamus)) Tinctorius (Saffflower Seed Oil)), soybean oil (indication name (INCI: Glycine Soja (Soybean) Oil)), tea seed oil (indication name (INCI: Camellia Sinensis Seed)) Camellia oil), camellia oil (display name (INCI: Camellia Japonica Seed) Oil)), evening primrose oil (indication name (INCI: Oenothera Biennis (Evening Primrose) Oil)), rapeseed oil (indication name),Germ oils such as corn germ oil (display name (INCI: Zea Mays (Corn) Germ Oil)), persic oil (display name), palm oil (display name (INCI: Elaeis Guineensis (Palm) Oil)), palm kernel oil (display name (INCI: Elaeis Guineensis (Palm) Kernel Oil)), castor oil (display name (INCI: Ricinus Communis (Castor) Seed Oil)), sunflower seed oil (display name (INCI: Helianthus Annuus (Sunflower) Seed Oil)), grape seed oil (display name (INCI: Vitis Vinifera (Grape) Seed Oil)), jojoba seed oil (display name (INCI: Simmondsia Chinensis (Jojoba) Seed Oil)), macadamia seed oil (display name (INCI: Macadamia Ternifolia Seed Oil)), meadowfoam oil (display name (INCI: Limnanthes Alba (Meadowfoam) Seed Oil)), cottonseed oil (display name (INCI: Gossypium Herbaceum (Cotton) Seed Oil)), coconut oil (display name (INCI: Cocos Nucifera (Coconut) Oil)), peanut oil (display name (INCI: Arachis Hypogaea (Peanut) Oil)) and other natural vegetable oils, shark liver oil (display name (INCI: Shark Liver Oil)), cod liver oil (display name (INCI: Cod Liver Oil)), fish liver oil (display name (INCI: Fish Liver Oil)), turtle oil (display name (INCI: Turtle Oil)), mink oil (display name (INCI: Mink Oil)), egg yolk oil (display name (INCI: Egg Oil)) and other natural animal oils, hydrogenated coconut oil (display name (INCI: Hydrogenated Coconut Oil)), liquid lanolin (display name (INCI: Lanolin Oil)) and other semi-synthetic oils and fats, etc.

[0047] Hydrocarbon Oils Examples of hydrocarbon oils include linear or branched hydrocarbon oils, and may be volatile or non-volatile hydrocarbon oils. Specific examples include isoparaffins such as olefin oligomers (INCI), (C13,14) isoparaffin (INCI), and alkanes such as isododecane (INCI), undecane (INCI), tridecane (INCI), dodecane (INCI), isohexadecane (INCI), hydrogenated polyisobutene (display name (INCI: Hydrogenated Polyisobutene)), squalane (INCI), mineral oil (INCI), palm alkanes (INCI), and (C13-15) alkanes (INCI).

[0048] Higher Alcohols Examples of higher alcohols include alcohols having preferably 6 or more carbon atoms, more preferably 10 to 30. Specific examples of higher alcohols include lauryl alcohol (INCI), myristyl alcohol (INCI), palmityl alcohol (INCI), stearyl alcohol (INCI), behenyl alcohol (INCI), oleyl alcohol (INCI), isostearyl alcohol (INCI), octyldodecanol (INCI), cholesterol (INCI), phytosterols (INCI), and batyl alcohol (INCI).

[0049] Ester Oils Examples of ester oils include alkyl glycol monoisostearates such as diisobutyl adipate (label name (INCI: Diisobutyl Adipate)), dihexyldecyl adipate (label name (INCI: Diheptylundecyl Adipate)), and isostearyl isostearate (label name (INCI: Isostearyl Isostearate)), isocetyl isostearate (label name (INCI: Isocetyl Isostearate)), trimethylolpropane triisostearate (label name (INCI: Trimethylolpropane Triisostearate)), and glycol diethylhexanoate (label name (INCI: Glycol octyldodecyl esters such as cetyl ethylhexanoate (label name (INCI: Cetyl Ethylhexanoate)), trimethylolpropane triethylhexanoate (label name (INCI: Trimethylolpropane Triethylhexanoate)), pentaerythrityl tetraethylhexanoate (label name (INCI: Pentaerythrityl Tetraethylhexanoate)), and octyldodecyl stearoyloxystearate (label name (INCI: Octyldodecyl Stearoyl Stearate)); oleyl oleate (label name (INCI: Oleyl Stearate)); Oleate), Octyldodecyl oleate (InCI: Octyldodecyl Oleate), Decyl oleate (InCI: Decyl Oleate), Neopentyl glycol dioctanoate (InCI: Neopentyl Glycol Diethylhexanoate), Neopentyl glycol dicaprate (InCI: Neopentyl Glycol Dicaprate), Diisostearyl malate (InCI: Diisostearyl Malate), Triethyl citrate (InCI: Triethyl Citrate),Diethylhexyl succinate (InCI: Diethylhexyl Succinate), Amyl acetate (InCI: Amyl Acetate), Ethyl acetate (InCI: Ethyl Acetate), Butyl acetate (InCI: Butyl Acetate), Isocetyl stearate (InCI: Isocetyl Stearate), Butyl stearate (InCI: Butyl Stearate), Diisopropyl sebacate (InCI: Diisopropyl Sebacate), Diethylhexyl sebacate (InCI: Diethylhexyl Sebacate), cetyl lactate (label name (INCI: Cetyl Lactate)), myristyl lactate (label name (INCI: Myristyl Lactate)), isononyl isononanoate (label name (INCI: Isononyl Isononanoate)), isotridecyl isononanoate (label name (INCI: Isotridecyl Isononanoate)), isopropyl palmitate (label name (INCI: Isopropyl Palmitate)), ethylhexyl palmitate (label name (INCI: Ethylhexyl Isopalmitate)), hexyldecyl palmitate (label name (INCI: Isocetyl Palmitate, Hexyldecyl palmitate esters such as cholesteryl hydroxystearate (label name (INCI: Cholesteryl Hydroxystearate)), myristate esters such as isopropyl myristate (label name (INCI: Isopropyl Myristate)), octyldodecyl myristate (label name (INCI: Octyldodecyl Myristate)), and myristyl myristate (label name (INCI: Myristyl Myristate)); ethylhexyl laurate (label name (INCI: Ethylhexyl Laurate)), hexyl laurate (label name (INCI: Hexyl Laurate));Examples thereof include dioctyldodecyl lauroyl glutamate (label name (INCI: Dioctyldodecyl Lauroyl Glutamate)), isopropyl lauroyl sarcosine (label name (INCI: Isopropyl Lauroyl Sarcosinate)), and coconut caprylate / caprate (label name (INCI: Coco-Caprylate / Caprate)).

[0050] Furthermore, among the ester oils, examples of glyceride oils include triethylhexanoin (labeled name (INCI: )), tri(caprylic / capric)glyceryl (labeled name (INCI: Caprylic / Capric Triglyceride)), cocoglyceryl (INCI), (caprylic / capric / succinic) triglyceryl (labeled name (INCI: Caprylic / Capric / Succinic Triglyceride)), and (caprylic / capric) glycerides (labeled name (INCI: Caprylic / Capric Glycerides)).

[0051] Fluorine-based oils Examples of fluorine-based oils include perfluorodecalin (INCI), perfluorononyl dimethicone (INCI), and perfluoromethylcyclopentane (INCI).

[0052] Ultraviolet absorbers Ultraviolet absorbers include oxybenzone-1 (label name (INCI: Benzophenone-1)), oxybenzone-2 (label name (INCI: Benzophenone-2)), oxybenzone-3 (label name (INCI: Benzophenone-3)), oxybenzone-4 (label name (INCI: Benzophenone-4)), oxybenzone-5 (label name (INCI: Benzophenone-5)), oxybenzone-6 (label name (INCI: Benzophenone-6)), oxybenzone-9 (label name (INCI: Benzophenone-9)), homosalate (INCI), octocrylene (INCI), t-butyl methoxydibenzoylmethane (label name (INCI: Butyl (Inc. Isopropyl alcohol)), ethylhexyl salicylate (Inc. Isopropyl alcohol), diethylamino hydroxybenzoyl hexyl benzoate (Inc. Isopropyl alcohol), polysilicone-15 (Inc. Isopropyl alcohol), dimethoxybenzylidene dioxoimidazolidine octyl propionate (Inc. Isopropyl alcohol), terephthalylidene dicamphorsulfonic acid (Inc. Isopropyl alcohol), Dicamphor Sulfonic Acid), Ethylhexyl Triazone (INCI), Methyl Bis(trimethylsiloxy)silylisopentyl Trimethoxycinnamate (InCI: Isopentyl Trimethoxycinnamate Trisiloxane), Drometrizole Trisiloxane (INCI), Ethylhexyl Dimethyl PABA (InCI: Ethylhexyl Dimethyl PABA), Isopropyl Paramethoxycinnamate (InCI: Isopropyl Methoxycinnamate), Ethylhexyl Methoxycinnamate (InCI: Ethylhexyl Methoxycinnamate),Bis-ethylhexyloxyphenol methoxyphenyl triazine (INCI), phenylbenzimidazole sulfonic acid (label name (INCI: Phenylbenzimidazole Sulfonic Acid)), methylene bisbenzotriazolyl tetramethylbutylphenol (INCI), glyceryl dimethoxycinnamate ethyl hexanoate (label name (INCI: Glyceryl Ethylhexanoate Dimethoxycinnamate)), glyceryl PABA (INCI), methyl diisopropylcinnamate (label name (INCI: Diisopropyl Methyl Cinnamate)), cinoxate (INCI), ethylhexyl dimethoxybenzylidene dioxoimidazolidinepropionate (label name (INCI: Ethylhexyl Dimethoxybenzylidine Dioxoimidazolidine Propionate), etc.

[0053] (2) Aqueous Components Other Than Component (b) The aqueous components are not particularly limited as long as they are aqueous components other than the above-mentioned component (b) that can be typically incorporated into cosmetics. Specific examples include water, lower alcohols preferably having 2 to 5 carbon atoms, such as ethanol (labeled as "INCI: Alcohol") and isopropanol (labeled as "INCI: Isopropyl Alcohol"), and moisturizers such as betaine (INCI), PCA-Na (labeled as "INCI: Sodium PCA"), egg yolk lecithin, soybean lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, and sphingophospholipids. Other examples include water-soluble polymers such as vinyl polymers such as gum arabic, guar gum, carrageenan, agar, quince seed, locust bean gum, xanthan gum, pullulan, sodium carboxymethylcellulose, hydroxyethyl cellulose, and carboxyvinyl polymers, and acrylic polymers such as (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer, (sodium acrylate / sodium acryloyldimethyltaurate) copolymer, (hydroxyethyl acrylate / sodium acryloyldimethyltaurate) copolymer, (acrylamide / sodium acryloyldimethyltaurate) copolymer, and polyacrylamide. Among these, the use of acrylic polymers makes it possible to stabilize oil-in-water cosmetics relatively easily.

[0054] (3) Surfactants Other Than Components (c) and (d) Surfactants include nonionic, anionic, cationic, and amphoteric surfactants, but are not particularly limited thereto. Any surfactant other than the above components (c) and (d) that is commonly used in cosmetics can be used. Among these surfactants, one or more selected from non-crosslinked silicone surfactants or crosslinked silicone surfactants are preferred because they can produce stable cosmetics. In either case, the amount of surfactant blended is preferably 0.1 to 20% by mass of the total cosmetic. A content of 0.1% or more ensures sufficient dispersion and emulsification functions, while a content of 20% by mass or less is preferred because it prevents the cosmetic from feeling sticky after use. The HLB of the surfactant is not limited, but is preferably 2 to 14.5 in order to maintain the water resistance of the cosmetic.

[0055] The non-crosslinked silicone surfactant is one in which some of the methyl groups in a linear or branched silicone main chain have been substituted with a hydrophilic group such as polyethylene glycol, and specifically, linear or branched polyoxyethylene-modified organopolysiloxanes, linear or branched polyoxyethylene-polyoxypropylene-modified organopolysiloxanes, linear or branched polyoxyethylene-alkyl-co-modified organopolysiloxanes, linear or branched polyoxyethylene-polyoxypropylene-alkyl-co-modified organopolysiloxanes, and linear or branched pyrrolidone-modified organopolysiloxanes are preferred. Examples include PEG-11 methyl ether dimethicone (INCI), PEG / PPG-20 / 22 butyl ether dimethicone (INCI), PEG-3 dimethicone (INCI), PEG-10 dimethicone (INCI), PEG-9 polydimethylsiloxyethyl dimethicone (INCI), lauryl PEG-9 polydimethylsiloxyethyl dimethicone (INCI), and cetyl PEG / PPG-10 / 1 dimethicone (INCI).

[0056] Examples of commercially available products include KF-6011, KF-6011P, KF-6012, KF-6015, KF-6017, KF-6043, KF-6028, KF-6038, and KF-6048 manufactured by Shin-Etsu Chemical Co., Ltd.

[0057] Examples of crosslinked silicone surfactants include (dimethicone / (PEG-10 / 15)) crosspolymer (INCI), (PEG-15 / lauryl dimethicone) crosspolymer (INCI), (PEG-10 / lauryl dimethicone) crosspolymer (INCI), and (PEG-15 / lauryl polydimethylsiloxyethyl dimethicone) crosspolymer (INCI).

[0058] Furthermore, when a crosslinked silicone surfactant is used, in a composition comprising the crosslinked silicone surfactant and an oil that is liquid at room temperature, the crosslinked silicone surfactant preferably swells with the liquid oil by absorbing more than its own weight of the liquid oil. The liquid oil can be a liquid silicone oil, hydrocarbon oil, ester oil, natural animal or vegetable oil, semi-synthetic oil, or fluorine-based oil, as contained in the optional component (1) oil, and examples thereof include cyclopentasiloxane (INCI), dimethicone (INCI), caprylyl methicone (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (labeled name (INCI: Isotridecyl Isononanoate)), squalane (INCI), etc. Examples of commercially available cross-linked silicone surfactants that swell when exposed to a liquid oil include KSG-210, KSG-240, KSG-270, KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, and KSG-350Z manufactured by Shin-Etsu Chemical Co., Ltd.

[0059] (4) Powders other than component (a) Examples of powders other than component (a) include fine particle metal oxide powders, extender pigments, pearl pigments, metal powders, organic powders, inorganic-organic composite powders, etc. Specific examples are as follows.

[0060] Fine particle inorganic powder The fine particle inorganic powder may be any powder used as an ultraviolet scattering agent having an ultraviolet shielding effect that can be incorporated into ordinary cosmetics, and may be used alone or in combination of two or more. Among these, metal oxides selected from one or more of titanium oxide, zinc oxide, and cerium oxide are preferred. The metal oxide may be a composite powder of two or more of titanium oxide, zinc oxide, and cerium oxide, or may be a composite powder with other powders.

[0061] The number-average primary particle diameter of the inorganic fine particle powder, as determined by image analysis of a transmission electron microscope photograph, is 10 to 200 nm, preferably 150 nm or less. If the particle diameter is greater than 200 nm, the UV protection function is reduced and white residue is left behind. If the particle diameter is less than 10 nm, the product may feel too dry and have a poor feel when used. The average primary particle diameter of the inorganic fine particle powder can be measured using a transmission electron microscope photograph. If the powder is not spherical, the average primary particle diameter is taken as the average value of the long and short axes of the particles. Examples of the shape of the inorganic fine particle powder include spindle-shaped, needle-shaped, straw-like, rectangular, approximately spherical, and rod-shaped.

[0062] The fine inorganic powder may be surface-treated with silica, hydrous silica, alumina, aluminum hydroxide, or the like before hydrophobization treatment in order to reduce cohesion or suppress the activity of the powder. When blended into a cosmetic, if there is a concern that swelling of a water-soluble polymer used in combination with the fine inorganic powder may be inhibited or that water resistance may be reduced, a composite powder that has not been surface-treated with alumina or aluminum hydroxide is preferred. If there is a concern that water resistance may be reduced, a composite powder that has not been surface-treated with silica or hydrous silica is preferred.

[0063] The hydrophobic treatment agent for the fine inorganic powder is not particularly limited as long as it is a known treatment agent commonly used in cosmetics. Examples include silanes or silylating agents such as caprylylsilane (AES-3083, manufactured by Shin-Etsu Chemical Co., Ltd.), silicone oils such as dimethyl silicone (KF-96AK series, manufactured by Shin-Etsu Chemical Co., Ltd.), methyl hydrogen polysiloxanes (KF-99P, KF-9901, etc., manufactured by Shin-Etsu Chemical Co., Ltd.), and branched silicone treatment agents (KF-9908, KF-9909, etc., manufactured by Shin-Etsu Chemical Co., Ltd.), waxes, paraffins, organic fluorine compounds such as perfluoroalkyl phosphates, surfactants, amino acids such as N-acyl glutamic acid, and metal soaps such as aluminum stearate and magnesium myristate. In particular, components containing one or more selected from stearic acid, isostearic acid, and triethoxycaprylylsilane provide good treatment and are preferred in terms of dispersibility. The hydrophobic treatment method is not particularly limited, and any known method can be used, such as a wet treatment method, a dry treatment method, or a gas phase method.

[0064] Commercially available surface-treated inorganic fine particle powders can also be used, such as titanium oxide fine particle powders commercially available under the trade names MT-01, 02, 050OTS, 100Z, 100TV, 100SAS, 150EX, 200ST, 500SAM, 505SAS, 700Z, and 700BS (manufactured by Teika Co., Ltd.), ST-455, 455WS, 457ECS, 457SA, 495M, and 455FA (manufactured by Titanium Industries Co., Ltd.), and STR-100A-LP, 100C-LP, 100W-LP, 100C-LF, and 40-LP (manufactured by Sakai Chemical Industry Co., Ltd.). Fine particle zinc oxide is commercially available under the trade names of MZ-150, 200, 300, 306X, 500HP, 505T, 506X, MZY-203S, 210M3S, TMZ-HA1, MZX-5080TS (manufactured by Teika), FZO-50 (manufactured by Ishihara Sangyo Kaisha), etc.

[0065] Extender pigments include zirconium oxide (labeled as "INCI: Zirconium Dioxide"), zinc oxide (labeled as "INCI: Zinc Oxide"), cerium oxide (labeled as "INCI: Cerium Oxide"), magnesium oxide (labeled as "INCI: Magnesium Oxide"), barium sulfate (labeled as "INCI: Barium Sulfate"), calcium sulfate (labeled as "INCI: Calcium Sulfate"), magnesium sulfate (labeled as "INCI: Magnesium Sulfate"), calcium carbonate (labeled as "INCI: Calcium Carbonate"), magnesium carbonate (labeled as "INCI: Magnesium Sulfate"), and magnesium carbonate (labeled as "INCI: Magnesium Oxide"). Carbonate), Talc (INCI), Mica (INCI), Kaolin (INCI), Synthetic Fluorphlogopite (Display name (INCI: Synthetic Fluorphlogopite)), Synthetic Iron Phlogopite (Display name (INCI: Biotite)), Potassium Silicate (Display name (INCI: Potassium Silicate)), Silica (INCI), Aluminum Silicate (Display name (INCI: Aluminum Silicate)), Magnesium Silicate (Display name (INCI: Magnesium Silicate)), Aluminum / Mg Silicate (Display name (INCI: Magnesium Aluminum Silicate)), Calcium Silicate (Display name (INCI: Calcium Silicate (Al / Ca / Na) (Indication name (INCI: Aluminum Calcium Sodium Silicate)), Silicate (Li / Mg / Na) (Indication name (INCI: Lithium Magnesium Sodium Silicate)), Silicate (Na / Mg) (Indication name (INCI: Sodium Magnesium Silicate)), Borosilicate (Ca / Al) (Indication name (INCI: Calcium Aluminum Borosilicate)), Borosilicate (Ca / Na) (Indication name (INCI: Calcium Sodium Borosilicate), hydroxyapatite (INCI), bentonite (INCI), montmorillonite (INCI), hectorite (INCI), zeolite (INCI),Examples of the fine particles include fine particles made of alumina (INCI), aluminum hydroxide (display name (INCI: Aluminum Hydroxide)), boron nitride (display name (INCI: Boron Nitride)), glass (display name (INCI: Glass)), etc.

[0066] Colored pearl pigments Examples of inorganic colored pearl pigments include pearl agents such as mica (INCI) coated with titanium dioxide (labeled name (INCI: Titanium Dioxide)), synthetic fluorophlogopite (labeled name (INCI: Synthetic Fluorophlogopite)) coated with titanium dioxide (labeled name (INCI: Titanium Dioxide)), bismuth oxychloride (labeled name (INCI: Bismuth Oxychloride)), bismuth oxychloride (labeled name (INCI: Bismuth Oxychloride)) coated with titanium dioxide (labeled name (INCI: Titanium Dioxide)), and titanium dioxide (labeled name (INCI: Titanium Dioxide)). Examples of pearl pigments include talc (INCI) coated with titanium dioxide (INCI: Titanium Dioxide), fish scale foil (display name), and colored mica coated with titanium dioxide (display name (INCI: Titanium Dioxide)), and are not particularly limited and may be untreated or may be subjected to a known surface treatment generally used in cosmetics.

[0067] Metal Powder Examples of the metal powder include fine metal particles made of Al (display name (INCI: Aluminum, Aluminum Powder)), copper (display name (INCI: Copper Powder)), silver (display name (INCI: Silver Powder)), gold (display name (INCI: Gold)), etc.

[0068] Organic Powders Examples of organic powders include powders made of silicone, polyamide, polyacrylic acid / acrylic acid ester, polyester, polyethylene (INCI), polypropylene (INCI), polystyrene (INCI), styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, polyurethane, vinyl resin, urea resin, melamine resin, benzoguanamine, polymethylbenzoguanamine, tetrafluoroethylene, polymethyl methacrylate, cellulose (INCI), silk (INCI), nylon (display name), phenolic resin, epoxy resin, polycarbonate, etc. In particular, examples of silicones include silicone resin particles, polymethylsilsesquioxane (INCI), silicone rubber powder, silicone resin-coated silicone rubber powder, vinyl dimethicone / methicone silsesquioxane crosspolymer (INCI), diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane crosspolymer (INCI), polysilicone-1 crosspolymer (INCI), polysilicone-22 (INCI), etc. Examples of commercially available silicone powders include KMP-590, KMP-591, KMP-592, KMP-597, KMP-598, KSP-100, KSP-101, KSP-102, KSP-105, KSP-100W, KSP-300, KSP-411, KSP-441, KM-9729, and KM-440 manufactured by Shin-Etsu Chemical Co., Ltd.

[0069] Metal soaps are also included, and specific examples thereof include zinc stearate (label name (INCI: Zinc Stearate)), aluminum stearate (label name (INCI: Aluminum Stearate)), calcium stearate (label name (INCI: Calcium Stearate)), magnesium stearate (label name (INCI: Magnesium Stearate)), zinc myristate (label name (INCI: Zinc Myristate)), magnesium myristate (label name (INCI: Magnesium Myristate)), zinc / sodium cetyl phosphate (label name (INCI: Sodium Zinc Cetyl Phosphate)), potassium cetyl phosphate (label name (INCI: Potassium Cetyl Phosphate)), and potassium cetyl phosphate (label name (INCI: Potassium Cetyl Phosphate)). Further, organic pigments may be used, and specific examples thereof include Red 3, Red 104(1) (display name (INCI: Red 28, Red 28 Lake)), Red 106, Red 201 (display name (INCI: Red 6)), Red 202 (display name (INCI: Red 7)), Red 204, Red 205, Red 220 (display name (INCI: Red 34)), Red 226 (display name (INCI: Red 30)), Red 227 (display name (INCI: Red 33, RED 33 Lake)), Red 228 (display name (INCI: Red 36)), Red 230(1) (display name (INCI: Red 22, Red 22)), Lake)), Red 230 (2) (Display name), Red 401 (Display name), Red 505 (Display name), Yellow 4 (Display name (INCI: Yellow 5)), Yellow 5 (Display name (INCI: Yellow 6, Yellow 6) Yellow 202 (1) (Display name (INCI: Yellow 8)), Yellow 203 (Display name (INCI: Yellow 10, Yellow 10 Lake)), Yellow 204 (Display name (INCI: Yellow 11)), yellow 401, blue 1 (display name (INCI:Blue 1, Blue 1 Lake)), blue 2, blue 201, blue 205 (display name (INCI:Blue 4), Blue 404 (display name), Green 3 (display name (INCI: Green 3, Green 3 Lake)), Green 201 (display name (INCI: Green 5)),Coal-tar dyes such as Green 202 (label name (INCI: Green 6)), Green 204 (label name (INCI: Green 8)), Green 205 (label name), Orange 201 (label name (INCI: Orange 5)), Orange 203 (label name (INCI: Pigment Orange 5)), Orange 204 (label name), Orange 205 (label name (INCI: Orange 4, Orange 4 Lake)), Orange 206 (label name (INCI: Orange 10)), and Orange 207 (label name (INCI: Orange 11)); cochineal (INCI), laccaic acid (label name (INCI: Laccaic Acid)); safflower red (label name (INCI: Carthamus tinctorius)); Examples of natural pigments include Lithospermum Officinale Root Extract (labeled as INCI: Lithospermum Tinctorius (Safflor) Flower Extract), Purple Lithospermum Root Extract (labeled as INCI: Lithospermum Officinale Root Extract), Gardenia Yellow (labeled as INCI: Hydrolyzed Gardenia Florida Extract), and Gardenia Blue (labeled as INCI: Hydrolyzed Gardenia Florida Extract).

[0070] Inorganic-organic composite powders Examples of inorganic-organic composite powders include composite powders in which the surface of an inorganic powder is coated with an organic powder by a known or commonly used method.

[0071] The above-mentioned powder may be mixed with component (a) and incorporated into the dispersion of the present invention. The amount of powder other than the above-mentioned (a) in the dispersion of the present invention is preferably 20% by mass or less, preferably 10% by mass or less, more preferably 3% by mass or less, and may even be 0% by mass. Alternatively, a dispersion may be prepared separately from component (a) and incorporated into the cosmetic. The dispersion may or may not contain components (b), (c), and (d). The amount of powder other than the above-mentioned (a) in the cosmetic is preferably 20% by mass or less.

[0072] Ultraviolet absorbing / scattering agent A dispersion in which particles that absorb and scatter ultraviolet light are dispersed in an oil agent in advance can also be used. The oil agent can be a liquid silicone oil, hydrocarbon oil, ester oil, natural animal or vegetable oil, semi-synthetic oil, or fluorine-based oil, which is included in the optional component (1) oil agent. Specific examples of dispersions in which particles that absorb and scatter ultraviolet light are dispersed in an oil agent in advance include the SPD series (product name) manufactured by Shin-Etsu Chemical Co., Ltd., in particular SPD-T5, SPD-T5L, SPD-Z5, SPD-T6, SPD-Z6, SPD-T7, and SPD-Z7L.

[0073] (5) Composition Comprising a Crosslinked Organopolysiloxane and an Oily Agent That Is Liquid at Room Temperature In a composition comprising a crosslinked organopolysiloxane and an oily agent that is liquid at room temperature, it is preferred that the crosslinked organopolysiloxane swells with the liquid oil in an amount equal to or greater than its own weight. As the liquid oil agent, liquid silicone oil, hydrocarbon oil, ester oil, natural animal and vegetable oil, semi-synthetic oil, or fluorine-based oil in the optional component (1) oil agent can be used, and examples thereof include cyclopentasiloxane (INCI), dimethicone (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (display name (INCI: Isotridecyl Isononanoate)), squalane (INCI), and coco-caprylate / caprate (display name (INCI: Coco-Caprylate·Caprate)).

[0074] Unlike the crosslinked silicone surfactant of component (3) described above, component (5) is a compound that does not have a polyether or polyglycerin structure in its molecular structure, and specific examples include (dimethicone / vinyl dimethicone) crosspolymer (INCI), (dimethicone / phenyl vinyl dimethicone) crosspolymer (INCI), (vinyl dimethicone / lauryl dimethicone) crosspolymer (INCI), (lauryl polydimethylsiloxyethyl dimethicone / bis vinyl dimethicone) crosspolymer (INCI), etc. Examples of commercially available compositions comprising a crosslinked organopolysiloxane and an oil that is liquid at room temperature include KSG-15, KSG-1510, KSG-16, KSG-1610, KSG-19, KSG-016F, KSG-18A, KSG-41A, KSG-42A, KSG-43, KSG-44, KSG-45, KSG-042Z, KSG-045Z, KSG-048Z, and KM-116, all manufactured by Shin-Etsu Chemical Co., Ltd.

[0075] (6) Film-Forming Agents Film-forming agents are primarily formulated for the purpose of further maintaining the durability of the cosmetic's effects. While there are no particular limitations, silicone-based compositions are preferred from the perspective of imparting water repellency. Specifically, trimethylsiloxysilicate, acrylic-silicone film-forming agents, silicone-modified norbornene, silicone-modified pullulan, silicone-modified polyvinyl alcohol, and the like can be used. Examples of silicone-based film-forming agents include trimethylsiloxysilicate (labeled as (INCI: Trimethylsiloxysilicate), (Acrylates / Dimethicone) Copolymer (INCI), (Norbornene / Tris(trimethylsiloxy)silylnorbornene) Copolymer (INCI), tri(trimethylsiloxy)silylpropylcarbamate pullulan (labeled as (INCI: Trimethylsiloxysilylcarbamoyl Pullulan)), and the like.

[0076] The film-forming agent may be dissolved in a liquid oil at room temperature before blending into the cosmetic. Examples of the liquid oil include liquid silicone oils, hydrocarbon oils, ester oils, natural animal and vegetable oils, semi-synthetic oils, and fluorine-based oils, all of which are included in the optional component (1) oil. Specific examples of commercially available silicone film-forming agents include KF-7312J, KP-545, KP-549, KP-543, NBN-30-ID, TSPL-30-ID, and TSPL-30-D5 manufactured by Shin-Etsu Chemical Co., Ltd.

[0077] (7) Other additives Examples of other additives include oil-soluble gelling agents, preservatives / disinfectants, antiperspirants, fragrances, salts, antioxidants, pH adjusters, chelating agents, cooling agents, anti-inflammatory agents, skin-beautifying ingredients (skin-whitening agents, cell activators, skin roughness improving agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, and inclusion compounds.

[0078] Oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate, and zinc myristate; amino acid derivatives such as lauroyl glutamic acid (labeled as "Lauroyl Glutamic Acid" by INCI) and α,γ-di-n-butylamine; dextrin palmitate (labeled as "Dextrin Palmitate" by INCI), dextrin isostearate (labeled as "Dextrin Isostearate" by INCI), dextrin myristate (labeled as "Dextrin Myristate" by INCI), inulin stearate (labeled as "Stearoyl Inulin" by INCI), and dextrin (palmitate / ethylhexanoate) (labeled as "Dextrin" by INCI). dextrin fatty acid esters such as dextrin palmitate / ethylhexanoate); sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate and fructooligosaccharide 2-ethylhexanoate; benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol; disteardimonium hectorite (INCI), stearalkonium hectorite (INCI), organically modified clay minerals of hectorite; and stearalkonium bentonite (INCI).

[0079] Preservatives and disinfectants Examples of preservatives and disinfectants include alkyl parahydroxybenzoate, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, imidazolidinyl urea, salicylic acid, isopropylmethylphenol, carbolic acid, parachlormetacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, iodopropynyl butylcarbamate, polylysine, bisabolol, ethylhexylglycerin, glyceryl caprylate, caprylhydroxamic acid, hexyl dimethylolpropionate, polyaminopropyl biguanide, photosensitizers, silver, plant extracts, etc. Preservatives can be used alone or in combination of two or more. In particular, polylysine, bisabolol, ethylhexylglycerin, glyceryl caprylate, caprylhydroxamic acid, hexyl dimethylolpropionate, polyaminopropyl biguanide, ethylhexylglycerin, and phenoxyethanol are preferred because they are easy to incorporate into cosmetics and are expected to have a preservative effect, and ethylhexylglycerin, phenoxyethanol, and glyceryl caprylate are particularly preferred in terms of their compatibility with the dispersion of the present invention. The incorporation of a preservative is expected to inhibit bacterial contamination and improve the shelf life of the dispersion.

[0080] Antiperspirants include aluminum hydroxyhalides such as chlorohydroxy aluminum, aluminum halides such as aluminum chloride, aluminum allantoin, tannic acid, persimmon tannin, sulfate (Al / K), zinc oxide, zinc paraphenolsulfonate, burnt alum, tetrachloro(Al / zirconium) hydrate, trichlorohydrex glycine (Al / zirconium), etc. Particularly preferred components that exhibit high effectiveness are aluminum hydroxyhalides, aluminum halides, and complexes or mixtures of these with zirconyl oxyhalides and zirconyl hydroxyhalides (for example, tetrachloro(Al / zirconium) hydrate, trichlorohydrex glycine (Al / zirconium)).

[0081] Fragrances Fragrances include natural fragrances and synthetic fragrances. Natural fragrances include plant-based fragrances isolated from flowers, leaves, wood, peels, etc.; and animal-based fragrances such as musk and civet. Synthetic fragrances include hydrocarbons such as monoterpenes, alcohols such as aliphatic alcohols and aromatic alcohols, aldehydes such as terpene aldehydes and aromatic aldehydes, ketones such as alicyclic ketones, esters such as terpene esters, lactones, phenols, oxides, nitrogen-containing compounds, and acetals.

[0082] Salts Examples of salts include inorganic salts, organic acid salts, amine salts, and amino acid salts. Examples of inorganic salts include sodium, potassium, magnesium, calcium, aluminum, zirconium, and zinc salts of inorganic acids such as hydrochloric acid, sulfuric acid, carbonic acid, and nitric acid; examples of organic acid salts include salts of organic acids such as acetic acid, dehydroacetic acid, citric acid, malic acid, succinic acid, ascorbic acid, and stearic acid; examples of amine salts and amino acid salts include salts of amines such as triethanolamine and salts of amino acids such as glutamic acid. Other examples include salts of hyaluronic acid, chondroitin sulfate, aluminum zirconium glycine complexes, and acid-alkali neutral salts used in cosmetic formulations. Sodium chloride is particularly preferred in terms of solubility, feel during use, and foaming suppression. When incorporated in large quantities, it may inhibit the swelling of water-soluble polymers.

[0083] Antioxidants Examples of antioxidants include, but are not limited to, carotenoids, ascorbic acid and its salts, ascorbyl stearate, tocopherol, tocopherol acetate, tocopherol, p-t-butylphenol, butylhydroxyanisole, dibutylhydroxytoluene, phytic acid, ferulic acid, thiotaurine, hypotaurine, sulfites, erythorbic acid and its salts, chlorogenic acid, epicatechin, epigallocatechin, epigallocatechin gallate, apigenin, campherol, myricetin, quercetin, etc. One type of antioxidant may be used alone, or two or more types may be used in combination.

[0084] pH Adjusting Agents Examples of pH adjusting agents include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium bicarbonate, and ammonium bicarbonate.

[0085] Chelating Agents Examples of chelating agents include alanine, edetate sodium salt, sodium polyphosphate, sodium metaphosphate, phosphoric acid, and the like.

[0086] Cooling agents include L-menthol, camphor, menthyl lactate, and the like.

[0087] Anti-inflammatory Agents Examples of anti-inflammatory agents include allantoin, glycyrrhizinic acid and its salts, glycyrrhetinic acid and stearyl glycyrrhetinate, tranexamic acid, and azulene.

[0088] Skin-beautifying ingredients Examples of skin-beautifying ingredients include whitening agents such as placenta extract, arbutin, glutathione, and saxifrage extract; cell activators such as royal jelly, photosensitizers, cholesterol derivatives, and calf blood extract; rough skin improving agents; blood circulation promoters such as nonylic acid valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantharides tincture, ichthammol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, and γ-oryzanol; skin astringents such as zinc oxide and tannic acid; and antiseborrheic agents such as sulfur and thianthrol.

[0089] Vitamins: Vitamins include vitamin A oil, retinol, retinol acetate, retinol palmitate, and other vitamin A derivatives, riboflavin, riboflavin butyrate, flavin adenine nucleotide, and other vitamin B2 derivatives, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine tripalmitate, and other vitamin B6 derivatives, vitamin B12 and its derivatives, vitamin B15 and its derivatives, L-ascorbic acid, L-ascorbic acid dipalmitate, sodium L-ascorbic acid-2-sulfate, and dipotassium L-ascorbic acid phosphate diester. vitamin C such as ergocalciferol and cholecalciferol; vitamin D such as α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol nicotinate, and dl-α-tocopherol succinate; nicotinic acids such as nicotinic acid, benzyl nicotinate, and nicotinamide; vitamin H, vitamin P, pantothenic acids such as calcium pantothenate, D-pantothenyl alcohol, pantothenyl ethyl ether, and acetylpantothenyl ethyl ether; and biotin.

[0090] Amino acids include glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, and tryptophan.

[0091] Nucleic Acids Examples of nucleic acids include deoxyribonucleic acid.

[0092] Hormones include estradiol and ethenylestradiol.

[0093] Inclusion Compounds Examples of inclusion compounds include cyclodextrin.

[0094] The present invention will be specifically described below with reference to examples and comparative examples, but the present invention is not limited to the following examples. In the following examples, unless otherwise specified, "%" in the composition indicates % by mass, ratio indicates mass ratio, and the blending amount described with the product name is the blending amount of the blended product.

[0095] [Solubility of aqueous dispersant] The solubility of the aqueous dispersant when it was dissolved in water and BG at 20% is shown in the following Table 1. [Evaluation criteria] A: Soluble D: Not soluble "A" was considered to be acceptable.

[0096] [Solubilization of aqueous dispersants]

[0097] [Examples and Comparative Examples: Dispersions] Dispersions were obtained using a roll mill based on the compositions shown in Tables 2 and 3 below. The dispersibility of the obtained dispersions was evaluated according to the following evaluation criteria. The results are also shown in the tables. The dispersions in all of the following examples had a hardness in the range of 1 to 100.

[0098] [Preparation of Dispersion] A: Dispersion can be prepared. D: Dispersion cannot be prepared. "A" was rated as pass.

[0099] [Evaluation of Water Dispersibility] 0.5 g of the dispersion in the table below was placed in a beaker containing 50 mL of water with a metal spatula, stirred, and evaluated. A: Uniformly dispersed without settling when stirred for less than 30 seconds B: Uniformly dispersed when stirred for 30 seconds or more but less than 1 minute C: Uniformly dispersed when stirred for 1 minute or more but less than 2 minutes D: Not uniformly dispersed even when stirred for 2 minutes or more A rating of "C" or higher was considered acceptable.

[0100] [Water resistance evaluation] 0.1 g of the dispersion obtained above was applied to a 5 cm x 5 cm area of ​​artificial leather, and after drying at 25°C for 24 hours, its water resistance was evaluated according to the following evaluation criteria. The results were judged according to the following criteria. [Judgment criteria] A: Does not come off even when exposed to running water for 1 minute or more B: Does not come off even when exposed to running water for 30 seconds or more but less than 1 minute C: Comes off in 10 seconds or more but less than 30 seconds when exposed to running water D: Comes off in less than 10 seconds when exposed to running water A rating of "C" or higher was considered a pass.

[0101] [Evaluation of Usability] Ten expert panelists evaluated the usability (non-stickiness) upon application according to the following evaluation criteria. The results were judged based on the average of the 10 panelists' ratings and in accordance with the following criteria. [Evaluation Criteria] 5 points: Very good 4 points: Good 3 points: Fair 2 points: Slightly poor 1 point: Poor [Judgment Criteria] A: Average score of 4.5 points or more B: Average score of 3.5 points or more but less than 4.5 points C: Average score of 2.5 points or more but less than 3.5 points D: Average score less than 2.5 points A rating of "C" or higher was considered a pass.

[0102]

[0103] (Note 1) Shin-Etsu Chemical Co., Ltd.: Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone-treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black (number average primary particle size: 210 to 400 nm) (d) Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone: insoluble in component (b)

[0104] As is clear from Table 2, all of the Examples of the present invention produced dispersions (slurries) with good water dispersibility. On the other hand, Comparative Example 1, which did not contain component (c), and Comparative Example 2, which contained an excessive amount of component (a), as shown in Table 3, failed to produce a dispersion. Comparative Examples 3 and 4, in which the amount of component (c) was outside the range of the present invention, produced dispersions, but had poor water dispersibility and a feeling of use. Comparative Examples 5 to 10, which used surfactants other than component (c), either failed to produce a dispersion, or produced dispersions that were clearly poor in water resistance. Furthermore, Comparative Example 11, which contained component (d) and had a (d) / (c) ratio of greater than 0.10, exhibited poor water dispersibility.

[0105] Dispersions of Examples 14 to 18 were obtained using a high-pressure disperser based on the compositions shown in Table 4. All of the obtained dispersions were excellent in water dispersibility, water resistance, and usability.

[0106] (Note 1) Shin-Etsu Chemical Co., Ltd.: Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone-treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black (number average primary particle size: 210 to 400 nm)

[0107] Examples 19 to 34 Paste-like dispersions were prepared according to the formulations shown in Tables 5 and 6. (Production Method) Component (1) was dispersed using a roll to obtain a paste-like dispersion.

[0108] (Note 1) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black (number average primary particle size: 210 to 400 nm) (Note 2) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 disiloxane dimethicone

[0109] (Note 1) Number average primary particle diameter: 250 nm (Note 2) Number average primary particle diameter: 220 nm (Note 3) Number average primary particle diameter: 700 nm (Note 4) Number average primary particle diameter: 500 nm (Note 5) Shin-Etsu Chemical Co., Ltd.: Powder obtained by mixing KTP-09Y, KTP-09R, and KTP-09B in a ratio of 7:2:1 (Note 6) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 disiloxane dimethicone

[0110] [Example 35] Oil-in-water liquid foundation Composition % 1. Glyceryl stearate (SE) 3.0 2. Polysorbate-60 3.5 3. Sorbitan stearate 2.0 4. KF-7312T (Note 1) 3.0 5. Behenyl alcohol 2.0 6. KF-4418 (Note 2) 2.5 7. Octyldodecyl myristate 5.0 8. Coco-alkyl (caprylic / capric acid) 5.0 9. Dimethicone (100cs) 0.5 10. Ethylhexylglycerin 0.1 11. PCA-Na (50% aqueous solution) 0.2 12. Betaine 0.1 13. Glyceryl glucoside 0.5 14. BG 8.5 15. Water Balance 16. KSP-100W (Note 3) 1.0 17. Water 8.0 18. Dispersion of any of Examples 19 to 34 6.0 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: 60% methyl trimethicone solution of trimethylsiloxysilicate (Note 2) Shin-Etsu Chemical Co., Ltd.: Caprylyl methicone (Note 3) Shin-Etsu Chemical Co., Ltd.: Hydrophilic-treated (vinyl dimethicone / methicone silsesquioxane) crosspolymer

[0111] (Production Method) A: Components 1 to 9 were mixed and heated to dissolve uniformly. B: Components 10 to 15 were mixed and heated. C: Components 17 and 18 were mixed. D: With stirring, the mixture obtained in A was added to the mixture obtained in B and emulsified, and C and component 16 were added and mixed to obtain an oil-in-water liquid foundation. The oil-in-water liquid foundation obtained in this manner was highly stable, had a good non-sticky feel when used, and had excellent water resistance. The dispersions of Examples 19 to 34 were highly stable and easy to handle and pour.

[0112] Example 36 Lipstick Composition % 1. Candelilla wax 3 2. Polyethylene 2 3. Microcrystalline wax 2.5 4. Ceresin 6 5. KP-561P (Note 1) 13 6. Macadamia nut oil 23 7. Diisostearyl malate 8.5 8. Hydrogenated polyisobutene 8.5 9. Isotridecyl isononanoate 15 10. PEG-75 4.5 11. KF-6100 (component (c)) 2.5 12. Red No. 201 0.4 13. Red No. 202 0.4 14. Yellow No. 4 1.6 15. KTP-09W (Note 2) 3 16. KTP-09R (Note 2) 0.7 17. KTP-09B (Note 2) 0.2 18. KF-9909 treated (Note 3) talc 0.719. Mica 4.5 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: (Acrylates / stearyl acrylate / dimethicone methacrylate) copolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, R: red, B: black (number average primary particle size: 210 to 400 nm) (Note 3) Shin-Etsu Chemical Co., Ltd.: triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone

[0113] (Production Method) A: Components 10 and 11 were heated and mixed, and then components 12 to 18 were dispersed using a roll mill to prepare a dispersion of the present invention. B: Components 1 to 9 were mixed uniformly at 90°C. C: The dispersion obtained in A and component 19 were added to the mixture obtained in B, and mixed uniformly at 80°C. The mixture was filled into a mold and slowly cooled to obtain a lipstick. The lipstick obtained in this manner was highly stable, had a good non-sticky feel, and was excellent in water resistance. The dispersion of the present invention prepared in production process A was excellent in stability and was easy to handle and pour. The pigment paste had high affinity with lips, and was also excellent in suppressing secondary adhesion.

[0114] Example 37 Aqueous Gel Composition % 1. Dispersion of Example 14 5.0 2. Ethanol 3.5 3. BG 4.0 4. Glycerin 2.0 5. (Acryloyldimethyltaurate ammonium / VP) copolymer 0.2 6. Xanthan gum 0.2 7. KSP-100W (Note 1) 1.0 8. Phenoxyethanol 0.3 9. Water Balance Total 100.0

[0115] (Note 1) Shin-Etsu Chemical Co., Ltd.: Hydrophilic treated powder of (vinyl dimethicone / methicone silsesquioxane) crosspolymer

[0116] (Production method) A: Components 1 and 2 were mixed uniformly. B: Components 3 to 9 were mixed uniformly. C: The mixture obtained in A was added to the mixture obtained in B above and mixed uniformly. D: The mixture obtained in C was degassed and then filled into a container to obtain an aqueous gel. The aqueous gel obtained in this manner was an aqueous gel (cosmetic) that was highly stable and had excellent water resistance and feel (non-sticky) when used.

[0117] Example 38 Oil-in-Water Cream Composition % 1. KSG-15 (Note 1) 8.0 2. KSG-16 (Note 2) 19.0 3. KSG-45 (Note 3) 5.0 4. Cyclopentasiloxane 10.0 5. BG 3.0 6. KF-6100 (Note 4) 0.6 7. KF-6104 (Note 5) 0.3 8. (Ammonium acryloyldimethyltaurate / VP) copolymer aqueous solution (Note 6) 13.0 9. (Acrylamide / Sodium acryloyldimethyltaurate) copolymer / isohexadecane / Polysorbate 80 aqueous solution (Note 7) 0.6 10. 1% aqueous solution of sodium chloride 8.0 11. Water Balance 12. Dispersion of Example 2 6.0 13. KM-116 10.0 Total 100.0

[0118] (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% cyclopentasiloxane + 4-10% dimethicone / vinyl dimethicone crosspolymer. (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% dimethicone + 20-30% dimethicone / vinyl dimethicone crosspolymer. (Note 3) Shin-Etsu Chemical Co., Ltd.: A mixture of 60-70% coconut alkyl caprylate / caprate + 30-40% vinyl dimethicone / lauryl dimethicone crosspolymer. (Note 4) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 disiloxane dimethicone. (Note 5) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 polydimethylsiloxyethyl dimethicone. (Note 6) Clariant: Aristoflex AVC. (Note 7) Seppic: Simulgel 600

[0119] (Production method) A: Components 1 to 4 were mixed uniformly. B: Components 5 to 11 were mixed uniformly. C: The mixture obtained in A was added to the mixture obtained in B and emulsified, and components 12 and 13 were added and dispersed uniformly. The oil-in-water cream obtained in this manner was a cosmetic preparation that was highly stable and had excellent water resistance and a smooth feel when used (non-sticky).

[0120] Example 39 Water-in-oil Cream Composition % 1. KSG-710 (Note 1) 6 2. KSG-19 (Note 2) 2 3. Dimethicone (6cs) 13.5 4. KF-4418 (Note 3) 5 5. KF-6104 (Note 4) 1 6. KF-6105 (Note 5) 1 7. Dispersion of Example 3 3 8. Sodium citrate 0.2 9. DPG 8 10. Diglycerin 31 1. Water Balance Total 100.0

[0121] (Note 1) Shin-Etsu Chemical Co., Ltd.: Dimethicone (6cs) + (Dimethicone / Polyglycerin-3) Crosspolymer 20-30% Mixture (Note 2) Shin-Etsu Chemical Co., Ltd.: Dimethicone (6cs) + (Dimethicone / Vinyl Dimethicone) Crosspolymer 10-20% Mixture (Note 3) Shin-Etsu Chemical Co., Ltd.: Caprylyl Methicone (Note 4) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone (Note 5) Shin-Etsu Chemical Co., Ltd.: Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone

[0122] (Production method) A: Components 1 to 6 were mixed uniformly. B: Components 7 to 11 were mixed uniformly. C: While stirring, the mixture obtained in B was gradually added to the mixture obtained in A and emulsified. The water-in-oil cream obtained in this manner was a cosmetic preparation that was highly stable, water-resistant, and had an excellent feel when used (non-sticky).

[0123] Example 40 Oil-in-Water Sunscreen Emulsion Composition % 1. KTP-09W (Note 1) 7.5 2. Ethanol 0.5 3. Butylene Glycol 1.0 4. KS-66 (Note 2) 0.001 5. Water 4.999 6. Polyglyceryl-3 Disiloxane Dimethicone (HLB 10) 1.2 7. Ethylhexylglycerin 0.1 8. Ethanol 9.5 9. Butylene Glycol 5.0 10. Sodium Acrylate / Sodium Acryloyldimethyltaurate Copolymer Composition (Note 3) 2.5 11. KSP-100W (Note 4) 2.0 12. Water Balance 13. KF-7312J (Note 5) 1.0 14. KF-56A (Note 6) 3.0 15. Cetyl alcohol 2.0 16. Ethylhexyl methoxycinnamate 5.0 17. Diethylamino hydroxybenzoyl hexyl benzoate 1.0 18. Polyoxyethylene (60) hydrogenated castor oil 1.0 19. KF-6011 (Note 7) 0.52 0. Tocopherol 0.05 Total 100.0

[0124] (Note 1) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated titanium oxide (Note 2) Shin-Etsu Chemical Co., Ltd.: Simethicone (Note 3) SEPPIC: SIMULGEL EG (Note 4) Shin-Etsu Chemical Co., Ltd.: (vinyl dimethicone / methicone silsesquioxane) crosspolymer hydrophilic treated powder (Note 5) Shin-Etsu Chemical Co., Ltd.: 50% trimethylsiloxysilicate cyclopentasiloxane solution (Note 6) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (Note 7) Shin-Etsu Chemical Co., Ltd.: PEG-11 methyl ether dimethicone

[0125] (Production Method) A: Components 1 to 7 were uniformly dispersed using a homomixer. B: Components 8 to 12 were heated to 85°C, and the mixture obtained in A was added and mixed uniformly. C: Components 13 to 20 were heated to 85°C and mixed uniformly. D: The mixture obtained in C was added to the mixture obtained in B and emulsified at 85°C, followed by slow cooling with stirring to obtain an oil-in-water sunscreen emulsion. The oil-in-water sunscreen emulsion obtained in this manner was highly stable, had a good non-sticky feel in use, and excellent water resistance. The dispersion of the present invention prepared by Production Method A was excellent in dispersibility, particularly in aqueous media, water resistance, and feel in use, and was easy to handle and pour into a container.

[0126] Example 41: W / O Shaking Sunscreen Composition % 1. KSG-15 (Note 1) 2 2. KSG-16 (Note 2) 4 3. KF-6104 (Note 3) 0.5 4. Cyclopentasiloxane (remainder) 5. Dimethylpolysiloxane (6cs) 3 6. Isotridecyl isononanoate 4.8 7. KSP-105 (Note 4) 1 8. BG 2 9. Phenoxyethanol appropriate amount 10. Sodium citrate appropriate amount 11. Sodium chloride appropriate amount 12. Water 13 13. SPD-T7 (Note 5) 10 14. SPD-Z5 (Note 6) 10 15. Dispersion of Example 2 3 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: Mixture of 90-96% cyclopentasiloxane + 4-10% (dimethicone / vinyl dimethicone) crosspolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: Mixture of 70-80% dimethicone + 20-30% (dimethicone / vinyl dimethicone) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Note 4) Shin-Etsu Chemical Co., Ltd.: (vinyl dimethicone / methicone silsesquioxane) crosspolymer (Note 5) Shin-Etsu Chemical Co., Ltd.: Dispersion of 45% fine titanium oxide particles in cyclopentasiloxane (Note 6) Shin-Etsu Chemical Co., Ltd.: Dispersion of 60% fine zinc oxide particles in cyclopentasiloxane

[0127] (Production Method) A: Components 1 to 7 were mixed uniformly. B: Components 8 to 12 were mixed uniformly. C: The mixture obtained in B was added to the mixture obtained in A and emulsified. D: Components 13, 14, and 15 were added to the emulsion obtained in C to obtain a W / O shaking sunscreen. The obtained W / O shaking sunscreen was highly stable, had a good non-sticky feel when used, and had excellent water resistance.

[0128] [Example 42] Oil-in-water liquid foundation Composition % 1. Stearic acid 1.0 2. Behenyl alcohol 0.4 3. Glyceryl stearate 0.3 4. Mineral oil 10.0 5. Glyceryl trioctanoate 5.0 6. Sorbitan sesquioleate 0.5 7. Sorbitan monooleate 1.0 8. KF-7312T (Note 1) 1.0 9. KSP-105 (Note 2) 1.0 10. SPD-Z7L (Note 3) 5.0 11. Acrylates copolymer 2.2 12. Triethanolamine 1.0 13. KF-6013 (Note 4) 0.2 14. Alkyl POE palmityl ether phosphate 0.1 15. POE hydrogenated castor oil 0.5 16. Triethoxycaprylylsilane-treated titanium dioxide (Note 5) 8.5 17. Triethoxycaprylylsilane-treated red iron oxide (Note 5) 0.4 18. Triethoxycaprylylsilane-treated yellow iron oxide (Note 5) 1.0 19. Triethoxycaprylylsilane-treated black iron oxide (Note 5) 0.1 20. DPG 6.0 21. Polyglyceryl-3 disiloxane dimethicone (HLB 10) 1.0 22. Water 3.0 23. BG 7.0 24. Preservative appropriate amount 25. Fragrance appropriate amount 26. Water balance Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: Methyl trimethicone solution containing 60% trimethylsiloxysilicate(Note 2) Shin-Etsu Chemical Co., Ltd.: (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: Dimethicone dispersion of 60% fine zinc oxide particles (Note 4) Shin-Etsu Chemical Co., Ltd.: PEG-9 dimethicone (Note 5) (Number average primary particle diameter: 210 to 600 nm)

[0129] (Production Method) A: Components 13 to 15 were mixed with a portion of 23 and heated. B: Components 1 to 10 were mixed and heated. C: Components 11 to 12, the remainder of 23, 24, and 26 were mixed and heated. D: Components 14 to 21 were dispersed using a disper. E: With stirring, the mixture obtained in B was added to the mixture obtained in C and emulsified, the mixture obtained in A was added, and then the mixture obtained in D and component 25 were added to obtain an oil-in-water liquid foundation. The oil-in-water liquid foundation obtained in this manner was highly stable, had a good non-sticky feel when used, and had excellent water resistance. The dispersion of the present invention obtained in step D was highly stable and easy to handle and pour.

[0130] Example 43 Oil-in-Water Mascara Composition % 1. Stearic Acid 1.0 2. Cetyl Alcohol 0.5 3. Glyceryl Stearate 0.5 4. Beeswax 7.0 5. Carnauba Wax 2.0 6. Triethylhexanoin 3.0 7. Sorbitan Sesquioleate 0.7 8. Polysorbate 80 1.5 9. KF-6011P (Note 1) 0.5 10. Butylene Glycol 5.0 11. Acrylic Acid / Alkyl Copolymer (Solids 30%) 2.5 12. Polyvinyl Acetate Emulsion (Solids 50%) 25.0 13. Triethanolamine 0.7 14. Dispersion of Example 8 12.5 15. Water Balance Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: PEG-11 methyl ether dimethicone

[0131] (Production Method) A: Components 1 to 9 were heated and stirred. B: Components 10 to 13 and 15 were mixed and heated. C: The mixture obtained in B was added to the mixture obtained in A and emulsified. D: Component 14 was added to C and mixed and dispersed. The oil-in-water mascara obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

[0132] Example 44 Oil-in-water Lipstick Composition % 1. Hydrogenated lecithin 0.3 2. Stearic acid 1.5 3. Beeswax 14.0 4. Triethanolamine 1.2 5. Polysorbate 80 0.5 6. Sorbitan sesquioleate 0.2 7. BG 5.2 8. (Acrylates / VA) copolymer emulsion (43%) 12.0 9. Water Balance 10. Dispersion of Example 6 1.0 11. Dispersion of Example 3 1.0 Total 100.0

[0133] (Production method) A: Components 1 to 3 were heated and dissolved at 100°C. B: Components 4 and a portion of 9 were heated and mixed at 90°C. C: The mixture obtained in B was added to the mixture obtained in A and emulsified. D: The remainder of components 5 to 9 were mixed, and then added to the mixture obtained in C and mixed. E: Components 10 and 11 were mixed, and then added to the mixture obtained in D and mixed. The oil-in-water lipstick obtained in this manner was highly stable, had a good non-sticky feel when used, and had excellent water resistance.

[0134] [Example 45] Oil-in-water eye color Composition % 1. Sorbitan sesquioleate 0.5 2. Polyoxyethylene sorbitan monooleate 1 3. Dimethicone 2cs 5 4. Borosilicate (Calcium / Al) 3 5. Organic pigment appropriate amount 6. Glyceryl stearate 0.5 7. Dextrin palmitate 1 8. Candelilla wax 5 9. Petrolatum 2 10. KF-7312L (Note 1) 1.5 11. KMP-591 (Note 2) 2 12. (Acrylate dimethyl ammonium taurate / VP) copolymer 1 13. BG 1 14. Xanthan gum 5 15. Silica 3 16. Triethanolamine 1.2 17. EDTA 0.1 18. Preservative Appropriate amount 19. Dispersions of Examples 6, 7, and 8 0.25 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: 50% trimethylsiloxysilicate dimethicone 2cs solution (Note 2) Shin-Etsu Chemical Co., Ltd.: Polymethylsilsesquioxane

[0135] (Production Method) A: Components 6 to 11 were heated and dissolved at 100°C. B: Components 1 to 5 were added to the mixture obtained in A and mixed. C: Components 12 to 18 were mixed, and the mixture was added to the mixture obtained in B and emulsified. D: Component 19 was added to C and mixed. The oil-in-water eye color obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

[0136] [Example 46] Oil-in-water base cream Composition % 1. Water balance 2. Glycerin 3.0 3. Microcrystalline wax 3.0 4. Xanthan gum 0.2 5. Pentylene glycol 2.0 6. Butylene glycol 5.0 7. KTP-09W 5.0 8. Butylene glycol 1.0 9. Polyglyceryl-3 polydimethylsiloxyethyl dimethicone (HLB 12) (Note 1) 0.1 10. Polyglyceryl-3 disiloxane dimethicone (HLB 10) 0.7 11. Water 3.3 12. Sucrose cocoate 0.2 13. Sorbitan stearate 3.0 14. PEG-60 glyceryl isostearate 0.5 15. Behenyl alcohol 0.5 16. Ethylhexyl palmitate 3.0 17. KSP-101 (Note 2) 3.0 18. Polysorbate 60 0.3 19. (Hydroxyethyl acrylate / Sodium acryloyldimethyltaurate) copolymer (Note 4) 0.6 Total 100.0

[0137] (Note 1) Dissolved in water and BG (Note 2) Shin-Etsu Chemical Co., Ltd.: (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (Note 3) SEPPIC: SIMULGEL EG

[0138] (Production Method) A: Components 7 to 11 were uniformly dispersed using a roller. B: Components 1 to 6 were mixed uniformly, and then A was mixed and homogenized. C: Components 12 to 16 were heated and dissolved, and component 17 was mixed and homogenized. D: The heated mixture obtained in C was added to the heated mixture obtained in B and homogenized. E: The product obtained in D was cooled to room temperature, and then components 18 and 19 were added and mixed uniformly. The mixture was degassed and then filled into a container. The oil-in-water base cream obtained in this manner was highly stable, had a good non-sticky feel in use, and was excellent in water resistance. The dispersion of the present invention obtained in step A had excellent dispersibility, particularly in aqueous media, water resistance, and feel in use, and was easy to handle and pour.

[0139] [Example 47] W / O concealer Composition % 1. KSG-790 (Note 1) 6 2. KSG-44 (Note 2) 25 3. KSG-15 (Note 3) 15 4. KF-6180 (Note 4) 1 5. KF-4422 (Note 5) 13 6. Hexyl laurate 5 7. Mg sulfate 0.4 8. Sodium citrate 0.1 9. Glycerin 2 10. Pentylene glycol 2 11. Water 17.5 12. Dispersion of Example 9 10 13. Silicone-treated talc 2.4 14. BG 0.45 15. Polyglyceryl-3 disiloxane dimethicone (HLB 10) 0.15 Total 100.0

[0140] (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 65-75% caprylyl methicone and 25-35% dimethicone / polyglycerin-3 crosspolymer. (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 65-75% squalane and 25-35% vinyl dimethicone / lauryl dimethicone crosspolymer. (Note 3) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% cyclopentasiloxane and 4-10% dimethicone / vinyl dimethicone crosspolymer. (Note 4) Shin-Etsu Chemical Co., Ltd.: Isostearyl Polyglyceryl-3 Dimethicone. (Note 5) Shin-Etsu Chemical Co., Ltd.: Ethyl methicone.

[0141] (Production Method) A: Components 13 to 15 were uniformly dispersed using a disper. B: Components 1 to 6 were uniformly mixed. C: Components 8 to 12 were uniformly mixed, and then added portionwise to the mixture obtained in B and emulsified. D: Component 12 and the mixture obtained in A were uniformly mixed with the mixture obtained in C. The W / O concealer obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

[0142] [Example 48] Water-based eyeliner Composition % 1. Alkyl acrylate copolymer emulsion 15 2. Ethanol 2 3. Methylparaben 0.1 4. Water 49.8 5. Butylene Glycol 15 6. Xanthan gum 0.1 7. Dispersion of Example 17 18 Total 100.0

[0143] (Production Method) A: Components 1 to 6 were mixed uniformly. B: Component 7 was mixed uniformly with the mixture obtained in A. The aqueous eyeliner obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

[0144] [Example 49] W / O Cream Foundation Ingredients % 1. KSG-240 (Note 1) 3 2. KSG-15 (Note 2) 7 3. KF-6038 (Note 3) 3 4. Cyclopentasiloxane balance 5. Ethylhexyl methoxycinnamate 4 6. Diethylamino hydroxybenzoyl hexyl benzoate 1 7. Organically modified clay mineral 1.2 8. KP-549 (Note 4) 3 9. KF-56A (Note 5) 10 10. Isotridecyl isononanoate 7 11. Dispersion of Example 9 12.5 12. DPG 5 13. Phenoxyethanol 0.2 14. Sodium citrate appropriate amount 15. Magnesium sulfate appropriate amount 16. Water 30 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 75-85% cyclopentasiloxane + 15-25% (dimethicone / (PEG-10 / 15)) crosspolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% cyclopentasiloxane + 4-10% (dimethicone / vinyl dimethicone) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 polydimethylsiloxyethyl dimethicone (Note 4) Shin-Etsu Chemical Co., Ltd.: A solution of 40% (acrylates / dimethicone) copolymer with methyl trimethicone (Note 5) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone

[0145] (Production method) A: Components 1 to 10 were mixed uniformly. B: Components 11 to 16 were mixed uniformly. C: The mixture obtained in B was added to the mixture obtained in C and emulsified. The obtained W / O cream foundation was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

[0146] [Example 50] W / O Sunscreen Milk Composition % 1. KSG-270 (Note 1) 3.0 2. KSG-18A (Note 2) 3.0 3. KF-6048 (Note 3) 2.0 4. KF-56A (Note 4) 5.0 5. KF-4422 (Note 5) balance 6. Ethylhexyl methoxycinnamate 5.0 7. Ethylhexyl salicylate 2.0 8. Octocrylene 1.0 9. Diethylaminohydroxybenzoylhexyl benzoate 2.0 10. KSP-105 (Note 6) 2.0 11. SPD-T7 (Note 7) 10.0 12. SPD-Z5 (Note 8) 10.0 13. BG 3.0 14. Ethanol 5.0 15. Sodium citrate 0.2 16. Sodium chloride 0.5 17. KSP-100W (Note 9) 3.0 18. Water 17.0 19. Dispersion of Example 2 1.0 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: Mixture of 15-25% diphenylsiloxyphenyl trimethicone + (dimethicone / (PEG-10 / 15)) crosspolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: Mixture of 10-20% diphenylsiloxyphenyl trimethicone + (dimethicone / phenyl vinyl dimethicone) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: Cetyl PEG / PPG-10 / 1 dimethicone (Note 4) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (Note 5) Shin-Etsu Chemical Co., Ltd.: Ethyl trimethicone (Note 6) Shin-Etsu Chemical Co., Ltd.: (vinyl dimethicone / methicone silsesquioxane) crosspolymer(Note 7) Shin-Etsu Chemical Co., Ltd.: 45% fine particle titanium oxide dispersion in cyclopentasiloxane (Note 8) Shin-Etsu Chemical Co., Ltd.: 60% fine particle zinc oxide dispersion in cyclopentasiloxane (Note 9) Shin-Etsu Chemical Co., Ltd.: (vinyl dimethicone / methicone silsesquioxane) crosspolymer hydrophilic treated powder

[0147] (Production Method) A: Components 1 to 10 were mixed uniformly. B: Components 13 to 18 were mixed uniformly, and then component 19 was added and mixed. C: The mixture obtained in B was added to the mixture obtained in A and emulsified. D: Components 11 to 12 were added to the mixture obtained in C and mixed uniformly. The obtained W / O sunscreen emulsion was highly stable, had a good non-sticky feel when used, and had excellent water resistance.

[0148] [Example 51] Spray Foundation Composition % 1. Glyceryl stearate 1 2. Stearic acid 3 3. Behenyl alcohol 0.5 4. Cetyl alcohol 0.5 5. Squalane 3 6. Talc 1 7. Lecithin 0.3 8. BG 13 9. Triethanolamine 1.5 10. Ethanol 5 11. Water Balance 12. Xanthan gum (2% aqueous solution) 12 13. Dispersion of Example 9 3 Total 100.0 (Production method) A: Components 1 to 6 were mixed uniformly at 80°C. B: Components 7 to 11 were mixed uniformly at 80°C. C: The mixture obtained in B was added to the mixture obtained in A and emulsified, and components 12 and 13 were added and mixed at 25°C. D: C was filled into an aerosol container together with a propellant. The resulting spray foundation was highly stable, had a good feel without stickiness when used, and was excellent in water resistance.

[0149] Example 52 Water-based Sunscreen Mist Composition % 1. Dispersion of Example 2 1.0 2. Hydrous silica-coated silicone-treated titanium dioxide fine particle 7.0 3. Polyglyceryl-3 disiloxane dimethicone (HLB 10) 1.4 4. Butylene Glycol 1.4 5. Water Balance 6. Sodium citrate 0.1 7. Citric acid 0.02 8. Ethanol 5.0 9. Butylene Glycol 4.0 10. Glycerin 2.0 11. Fragrance 0.21 2. Ethylhexylglycerin 0.1 Total 100.0

[0150] (Production method) A: Components 2 to 4 and a portion of component 5 were uniformly dispersed using a bead mill. B: The mixture obtained in A, components 1, 6, and 7, and the remainder of component 5 were uniformly mixed. C: Components 8 to 12 were uniformly mixed. D: The mixture obtained in C was added to the mixture obtained in B and mixed uniformly, and then filled into a container. The aqueous sunscreen mist obtained in this manner was highly stable, had a good non-sticky feel when used, and had excellent water resistance.

[0151] [Example 53] Water-based lip color Composition % 1. Carbomer 0.5 2. Butylene Glycol 6 3. Glycerin 8 4. PEG-150 2 5. PEG-60 Hydrogenated Castor Oil 0.5 6. Dimethicone 6cs 0.3 7. Cyclopentasiloxane 1.4 8. Ceteth-30 0.1 9. Acrylates Copolymer (30%) 10 10. Preservative appropriate amount 11. Water balance 12. Potassium hydroxide 0.2 13. KF-9909 (Note 1) Treated Talc 3 14. KF-9909 (Note 1) Treated Mica 7 15. KTP-09W, R, Y, B (Note 2) 10 16. Polyglyceryl-3 disiloxane dimethicone (HLB 10) 1.317. BG 4 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated pigment

[0152] (Production Method) A: Components 13 to 17 were uniformly dispersed using a roller. B: Components 1 to 12 were uniformly mixed. C: The mixture obtained in B was uniformly mixed with the mixture obtained in A. The water-based lip color obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance. The dispersion of the present invention obtained in step A was excellent in dispersibility, particularly in dispersibility in aqueous media, water resistance, and feel when used, and was easy to handle and pour.

[0153] [Example 54] O / W Lip Tint Composition % 1. KSG-45 (Note 1) 8.5 2. Squalane 10 3. Red 218 0.05 4. Red 227 appropriate amount 5. Yellow 5 appropriate amount 6. Sodium acrylate grafted starch 0.2 7. BG 5 8. Preservative appropriate amount 9. Water balance 10. Dispersion of Example 15 0.5 11. Dispersion of Example 18 0.21 2. Acrylates copolymer emulsion 5 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: Mixture of 60-70% coconut alkyl (caprylate / caprate) + 30-40% vinyl dimethicone / lauryl dimethicone crosspolymer

[0154] (Production method) A: Components 1 to 5 were mixed uniformly. B: Components 6 to 9 were mixed uniformly. C: The mixture obtained in A was mixed uniformly with the mixture obtained in B, and components 10 to 12 were added and mixed uniformly. The O / W lip tint obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

[0155] [Example 55] Oil-in-water liquid foundation Composition % 1. Polyglyceryl-10 isostearate 3.0 2. NBN-30-ID (Note 1) 2.0 3. Behenyl alcohol 2.0 4. Dicaprylyl ether 2.5 5. Octyldodecyl myristate 5.0 6. Dimethicone (20cs) 0.5 7. (C9-12) alkane 5.0 8. KF-6115 (Note 2) 0.2 9. KTP-09W (Note 3) 2.1 10. KTP-09Y (Note 3) 0.26 11. KTP-09R (Note 3) 0.11 12. KTP-09B (Note 3) 0.03 13. Ethylhexylglycerin 0.1 14. Glycerin 3.5 15. Butylene Glycol 3.0 16. Water Balance 17. Xanthan gum 0.2 18. (Acryloyldimethyltaurate ammonium / VP) copolymer 0.2 19. Dispersion of Example 9 6.0 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: (Norbornene / tris(trimethylsiloxy)silylnorbornene) copolymer 30% isododecane solution (Note 2) Shin-Etsu Chemical Co., Ltd.: Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, Y: yellow, R: red, B: black (number average primary particle diameter: 210 to 400 nm)

[0156] (Production Method) A: Components 1 to 6 were heated and mixed uniformly. B: Components 13 to 18 were mixed and heated. C: Components 7 to 12 were mixed uniformly and roll processed. D: The mixture obtained in C was added to the mixture obtained in A and mixed uniformly. E: With stirring, the mixture obtained in D was added to the mixture obtained in B and emulsified, and component 19 was added and mixed to obtain an oil-in-water liquid foundation. The oil-in-water liquid foundation obtained in this manner was highly stable, had a good non-sticky feel when used, and had excellent water resistance. The dispersion of Example 9 was stable and easy to handle and dispense.

[0157] [Example 56] Water-in-oil liquid foundation Composition % 1. KSG-330 (Note 1) 3 2. KSG-18A (Note 2) 5 3. KF-6038 (Note 3) 3 4. Dimethicone (2cs) balance 5. Ethylhexyl methoxycinnamate 4 6. Diethylamino hydroxybenzoyl hexyl benzoate 1 7. Organically modified clay mineral 1.2 8. TSPL-30-ID (Note 4) 2 9. KF-56A (Note 5) 10 10. Ethylhexyl palmitate 7 11. KP-578 (Note 6) 0.15 12. KTP-09W (Note 7) 4.3 13. KTP-09Y (Note 7) 0.5 14. 1. KTP-09R (Note 7) 0.2 15. KTP-09B (Note 7) 0.1 16. Dispersion of Example 9 4.0 17. BG 5 18. Phenoxyethanol 0.2 19. Sodium citrate appropriate amount 20. Sodium chloride appropriate amount 21. Water 30 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: Mixture of 75-85% triethylhexanoin + 15-25% (PEG-15 / lauryl dimethicone) crosspolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: Mixture of 80-90% diphenylsiloxyphenyl trimethicone + 10-20% (dimethicone / phenyl vinyl dimethicone) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 polydimethylsiloxyethyl dimethicone(Note 4) Shin-Etsu Chemical Co., Ltd.: Tri(trimethylsiloxy)silylpropylcarbamate pullulan 30% dissolved in isododecane (Note 5) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (Note 6) Shin-Etsu Chemical Co., Ltd.: (Acrylates / ethylhexyl acrylate / dimethicone methacrylate) copolymer (Note 7) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, Y: yellow, R: red, B: black (number average primary particle diameter: 210 to 400 nm)

[0158] (Production Method) A: Components 1 to 9 were mixed and heated to homogeneity. B: Components 16 to 21 were mixed to homogeneity. C: Components 10 to 15 were mixed to homogeneity and processed in a homomixer. D: While stirring, the mixture obtained in B was added to the mixture obtained in A and emulsified, and C was added and mixed to obtain a water-in-oil liquid foundation. The water-in-oil liquid foundation obtained in this manner was highly stable, had a good non-sticky feel when used, and had excellent water resistance. The dispersion of Example 9 was highly stable and easy to handle and pour.

[0159] [Example 57] Oil-in-water liquid foundation Composition % 1. Polyglyceryl-10 myristate 0.5 2. Polyglyceryl-10 isostearate 1.0 3. KF-6043 (Note 1) 1.0 4. Diisopropyl sebacate 2.5 5. Ethylhexyl triazone 0.5 6. Tridecane 5.0 7. Dimethicone (6cs) 0.5 8. KF-6115 (Note 2) 0.2 9. KTP-09W (Note 3) 2.1 10. Ethylhexylglycerin 0.1 11. BG 2.3 12. KF-6100 (Note 4) 0.2 13. KTP-09Y (Note 3) 0.26 14. KTP-09R (Note 3) 0.11 15. KTP-09B (Note 3) 0.03 16. Water Balance 17. (Hydroxyethyl acrylate / Sodium acryloyldimethyltaurate) copolymer 0.2 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: PEG-10 dimethicone (Note 2) Shin-Etsu Chemical Co., Ltd.: Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, Y: yellow, R: red, B: black (number average primary particle size: 210 to 400 nm) (Note 4) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 disiloxane dimethicone

[0160] (Production Method) A: Components 1 to 6 were heated and mixed uniformly. B: Components 10, 16, and 17 were mixed uniformly. C: Components 7 to 9 were mixed uniformly and rolled. D: Components 11 to 15 were mixed uniformly and rolled. E: The mixture obtained in A was mixed with the mixture obtained in C. F: With stirring, the mixture obtained in E was added to the mixture obtained in B and emulsified, and D was added and mixed to obtain an oil-in-water liquid foundation. The oil-in-water liquid foundation obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

[0161] [Example 58] Oil-in-water cream foundation Composition % 1. Polyglyceryl-10 isostearate 3.0 2. KP-550 (Note 1) 2.0 3. X-21-5595 (Note 2) 2.0 4. Dibutyl adipate 2.5 5. Ethylhexyl triazone 0.5 6. Bis-ethylhexyloxyphenol methoxyphenyl triazine 0.5 7. Dodecane 5.0 8. KF-6106 (Note 3) 0.2 9. KTP-09Y (Note 4) 0.26 10. KTP-09R (Note 4) 0.11 11. KTP-09B (Note 4) 0.03 12. Ethylhexylglycerin 0.1 13. Glycerin 3.5 14. BG 3.0 15. Water Balance 16. (PEG-240 / Decyltetradeceth-20 / HDI) Copolymer 0.2 17. KTP-09W (Note 4) 2.1 18. BG 0.45 19. Polyglyceryl-3 disiloxane dimethicone (HLB 10) 0.15 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: (Acrylates / Dimethicone) Copolymer 40% dissolved in isododecane (Note 2) Shin-Etsu Chemical Co., Ltd.: Trimethylsiloxysilicate 60% dissolved in isododecane (Note 3) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Note 4) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, Y: yellow, R: red, B: black (number average primary particle size: 210 to 400 nm)

[0162] (Production method) A: Components 1 to 6 were heated and mixed uniformly. B: Components 12 to 16 were heated and mixed uniformly. C: Components 7 to 11 were mixed uniformly and processed in a high-pressure disperser. D: Components 17 to 19 were mixed uniformly and processed with a roll. E: The mixture obtained in C was mixed with the mixture obtained in A. F: The mixture obtained in D was mixed with the mixture obtained in B. G: With stirring, the mixture obtained in E was added to the mixture obtained in F and emulsified to obtain an oil-in-water cream foundation. The oil-in-water cream foundation obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

[0163] [Example 59] W / O Cream Foundation Composition % 1. KSG-320Z (Note 1) 6 2. KSG-19 (Note 2) 3 3. KSG-43 (Note 3) 1 4. KF-6105 (Note 4) 1 5. Dimethicone (6cs) 13 6. Squalane 5 7. KF-6115 (Note 5) 0.2 8. KTP-09Y (Note 6) 0.26 9. KTP-09R (Note 6) 0.11 10. KTP-09B (Note 6) 0.03 11. Magnesium sulfate 0.4 12. Sodium citrate 0.1 13. Diglycerin 2 14. Pentylene glycol 2 15. Water 17.5 16. Dispersion of Example 14 6 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: Mixture of 70-80% isododecane + 20-30% (PEG-15 / lauryl polydimethylsiloxyethyl dimethicone) crosspolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: Mixture of 80-90% dimethicone + 10-20% (dimethicone / vinyl dimethicone) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: Mixture of 65-75% triethylhexanoin + 25-35% (vinyl dimethicone / lauryl dimethicone) crosspolymer (Note 4) Shin-Etsu Chemical Co., Ltd.: Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Note 5) Shin-Etsu Chemical Co., Ltd.: Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Note 6) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, Y: yellow, R: red, B: black (number average primary particle diameter: 210 to 400 nm)

[0164] (Production method) A: Components 1 to 5 were mixed uniformly. B: Components 11 to 16 were mixed uniformly. C: Components 6 to 10 were mixed uniformly and processed with a high-pressure disperser. D: While stirring, the mixture obtained in B was added to the mixture obtained in A and emulsified, and C was added and mixed to obtain a W / O cream foundation. The W / O cream foundation obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

[0165] [Example 60] W / O Concealer Composition % 1. KSG-840 (Note 1) 6 2. KSG-44 (Note 2) 25 3. KSG-45 (Note 3) 15 4. KF-6180 (Note 4) 1 5. Jojoba seed oil 13 6. Sesame oil 5 7. KF-6115 (Note 5) 0.2 8. KTP-09W (Note 6) 2.1 9. Magnesium sulfate 0.4 10. Sodium citrate 0.1 11. Glycerin 2 12. Pentylene glycol 2 13. Water 17.5 14. KTP-09Y (Note 6) 0.26 15. KTP-09R (Note 6) 0.11 16. KTP-09B (Note 6) 0.03 17. BG 0.45 18. Polyglyceryl-3 disiloxane dimethicone (HLB 10) 0.15 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 65-75% squalane + 25-35% (lauryl dimethicone / polyglycerin-3) crosspolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 65-75% squalane + 25-35% (vinyl dimethicone / lauryl dimethicone) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: A mixture of 60-70% coconut alkyl caprylate / caprate + 30-40% (vinyl dimethicone / lauryl dimethicone) crosspolymer (Note 4) Shin-Etsu Chemical Co., Ltd.: Isostearyl polyglyceryl-3 dimethicone (Note 5) Shin-Etsu Chemical Co., Ltd.: Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone(Note 6) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, Y: yellow, R: red, B: black (number average primary particle diameter: 210 to 400 nm)

[0166] (Production Method) A: Components 1 to 5 were mixed uniformly. B: Components 9 to 13 were mixed uniformly. C: Components 6 to 8 were mixed uniformly and then mixed using a disper. D: Components 14 to 18 were mixed uniformly and then roll processed. E: D was mixed with B. F: With stirring, the mixture obtained in E was added to the mixture obtained in A and emulsified, and C was added and mixed to obtain a W / O concealer. The W / O concealer obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

[0167] [Example 61] Oil-in-water liquid foundation Composition % 1. PEG-60 hydrogenated castor oil 3.0 2. KP-545L (Note 1) 1.0 3. TSPL-30-ID (Note 2) 1.0 4. Isohexadecane 2.5 5. KP-561P (Note 3) 1.0 6. Hydrous silica / hydrogen dimethicone-treated titanium dioxide (Note 4) 8.1 7. KTP-09Y (Note 5) 0.97 8. KTP-09R (Note 5) 0.41 9. KTP-09B (Note 5) 0.12 10. Polyglyceryl-3 disiloxane dimethicone (HLB 10) 1.5 11. BG 8.0 12. Water Balance 13. (Hydroxyethyl acrylate / acryloyldimethyltaurate Na) copolymer 0.2 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: (Acrylates / Dimethicone) Copolymer 40% Dimethicone Solution (Note 2) Shin-Etsu Chemical Co., Ltd.: Tri(trimethylsiloxy)silylpropylcarbamate Pullulan 30% Isododecane Solution (Note 3) Shin-Etsu Chemical Co., Ltd.: (Acrylates / Stearyl Acrylate / Dimethicone Methacrylate) Copolymer (Note 4) Number average primary particle size: 210 to 400 nm (Note 5) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, Y: yellow, R: red, B: black (Number average primary particle size: 210 to 400 nm)

[0168] (Production method) A: Components 1 to 5 were mixed and heated to dissolve uniformly. B: Components 12 and 13 were mixed and heated. C: Components 6 to 11 were mixed and rolled. D: With stirring, the mixture obtained in A was added to the mixture obtained in B and emulsified, and C was added and mixed to obtain an oil-in-water liquid foundation. The oil-in-water liquid foundation obtained in this manner was highly stable, had a good non-sticky feel when used, and was excellent in water resistance.

Claims

1. A dispersion containing the following components (a) to (d): (a) 10 to 85 mass % of a hydrophobic inorganic powder having a number average primary particle size of more than 200 nm but not exceeding 700 nm, as measured by image analysis of transmission electron micrographs; (b) 1 to 80 mass % of an aqueous component having two or more alcoholic hydroxyl groups; (c) 1 to 20 mass % of a polyglycerin-modified silicone that is soluble in component (b); and (d) 0 to 2 mass % of a polyglycerin-modified silicone that is insoluble in component (b), wherein the ratio of the content of component (d) to the content of component (c), expressed as (d) / (c), is 0.1 or less.

2. The dispersion according to claim 1, wherein component (a) is an inorganic powder which has been hydrophobized with silicone.

3. The dispersion of claim 2, wherein said silicone is triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone.

4. The dispersion according to claim 1, wherein the content of component (a) is 70 to 85% by mass.

5. The dispersion of claim 1, wherein component (a) is a colored pigment.

6. The dispersion of claim 1, wherein component (c) is polyglyceryl-3 disiloxane dimethicone.

7. The dispersion according to claim 1, wherein the content of component (c) is 3.0 to 8.0 mass %.

8. The dispersion according to claim 1, wherein the ratio of the content of the component (c) to the content of the component (b), expressed as (c) / (b), is 0.1 to 0.

4.

9. A cosmetic preparation containing the dispersion according to any one of claims 1 to 8.