Silicone substitute natural additive composition, method for its preparation and use thereof
By preparing a natural composition containing monosaccharides, polysaccharides and their derivatives and alcohols, the negative environmental and health effects of organosilicon are solved, providing an environmentally friendly organosilicon alternative with good rheological properties and sensory aesthetic effects, and at a low cost.
Patent Information
- Application Number
- CN201980100338.5
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2019-09-11
- Publication Date
- 2025-12-09
- Estimated Expiration
- 2039-09-11
AI Technical Summary
Existing organosilicon compounds have negative impacts on the environment and health, and it is difficult to find effective alternatives for diverse applications.
A natural composition was developed using monosaccharides, polysaccharides and their derivatives, alcohols and fatty acid esters as main raw materials. Through a specific ratio and mixing process, a biodegradable organosilicon substitute was prepared, which has good rheological properties and sensory and cosmetic effects.
It provides an environmentally friendly silicone alternative with good rheological properties and sensory aesthetic effects, while reducing negative impacts on health and the environment, and with lower raw material and product costs.
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Abstract
Description
TECHNICAL FIELD
[0001] The present invention relates to a natural additive composition which is able to replace silicones in a wide variety of applications, preferably in the field of cosmetics, pet grooming, skin care. BACKGROUND
[0002] In the last decades, the cosmetic industry has rapidly developed, due to the use of a synthetic component, usually called silicone, in the vast majority of formulations.
[0003] Among the classification of silicones, polydimethylsiloxane (PDMS), also known as dimethicone or dimethyl silicone oil, is a very useful silicone polymer due to its unique rheological properties, light weight, inertness, non-toxicity and non-flammability, which exists in the form of a silicone oil.
[0004] The applications of polydimethylsiloxane are varied, and can be used in contact lenses, medical devices, elastomers, cosmetics usually as shampoos (as polydimethylsiloxane makes the hair brighter and smoother), moisturizers, food (as an antifoaming agent), for caulking, lubricants, or even for heat-resistant tiles or molds.
[0005] PDMS is manufactured in a variety of degrees of polymerization, and can be in the form of a thin, flowable liquid to a thick, rubbery semi-solid.
[0006] PDMS has flexibility and viscoelasticity, providing good sensory properties to the skin and hair in cosmetic applications.
[0007] Another component in the classification of silicones is cyclomethicone, which is cyclic, unlike the linear and non-volatile siloxane dimethyl silicone oil, and when used in the form of a methylsiloxane, cyclomethicone is in the form of a liquid with low viscosity and high volatility, and in addition to being a skin lubricant, it can even be used as a cleaning solvent.
[0008] A polysiloxane is a polymer that includes any synthetic compound composed of siloxane repeat units, which are chains of alternating silicon and oxygen atoms with carbon, hydrogen, and sometimes other elements bonded to them. Polysiloxanes are usually heat-resistant liquids or rubbers, and are used in sealants, adhesives, lubricants, pharmaceuticals, kitchen utensils, and thermal and electrical insulation. Some common forms include silicone oil, silicone grease, silicone rubber, silicone resin, and silicone gum.
[0009] In 2008, the total demand for silicones was close to $12.5 billion, an increase of about 4% from the previous year. In the following years, silicones maintained similar growth, reaching $13.5 billion in 2010. The annual growth was driven by broader applications, the introduction of new products, and the push for more environmentally friendly materials.
[0010] World leading silicone material manufacturers are affiliated with three regional organizations: the Center for European Silicones (CES) located in Brussels, Belgium; the Society for Environmental Health and Safety (SEHSC) located in Herndon, Virginia, USA; and the Society of Industrial and Applied Chemistry, Japan (SIAJ) located in Tokyo, Japan. Dow Corning Silicones, Evonik Industries, Momentive Performance Materials, Milliken and Company (SiVance Specialty Silicones), Shin-Etsu Silicones, Wacker Chemie, Bluer Silicones, JNC Corporation, Wacker Asahikasei Silicone, and Dow Corning Toray represent the collective membership of these organizations. A fourth organization is the Global Silicone Council (GSC) that forms a umbrella structure with the regional organizations. All four organizations are non-profit organizations with no commercial role; their primary mission is to promote silicone safety from a health, safety, and environmental perspective. As the European chemical industry is preparing for the implementation of the basic regulation for Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), the CES will lead the formation of a consortium of silicone, silane, and siloxane manufacturers and importers to facilitate the sharing of data and reduce costs.
[0011] Other studies indicate that silicone compounds diffuse into the environment. The cyclic siloxanes D4 and D5, which are specific silicone compounds, are air and water pollutants and have negative effects on the health of animals tested. Cyclic siloxanes D4 and D5 are used in a variety of personal care products. The European Chemicals Agency considers "D4 to be a Persistent Bioaccumulative Toxic (PBT) substance and D5 to be a Very Persistent Very Bioaccumulative (vPvB) substance." Other silicones are readily biodegradable in processes accelerated by a variety of catalysts including clays. In the process of mammalian biodegradation, cyclic silicones are involved in the production of silanol. The resulting silanediols and silanetriols are capable of inhibiting hydrolytic enzymes such as thermolysin, acetylcholinesterase, however, the amount required for inhibition is several orders of magnitude higher than the amount produced by cumulative exposure to cyclic methyl silicone containing consumer products.
[0012] It has been studied that PDMS (polydimethylsiloxane) releases trace amounts of formaldehyde (less than other common materials such as polyethylene) in an oxygen-containing atmosphere at about 200°C. It has been proven that at 200°C, silicones produce less formaldehyde than mineral oil and plastics (less than 3 μg CH2O / (g.h) to 48 μg CH2O / (g.h) for high-consistency silicone rubber, while plastics and mineral oil are about 400 μg CH2O / (g.h)). At about 250°C, all silicones produce a large amount of formaldehyde (1200 μg CH2O / (g.h) to 4,600 μg CH2O / (g.h)). It is considered that these formaldehyde emissions will become a problem for our environment.
[0013] Therefore, there is an urgent need to develop a synthetic compound as a substitute for silicone, which has low biodegradability in the environment and does not generate a continuous emission to the earth.
[0014] These considerations are some of the research that have been questioned worldwide today, and they are also the reason that led the applicant to achieve this important progress. The product according to the present invention is natural and the earth can produce its raw materials on a large scale. The product according to the present invention employs monosaccharides, or polysaccharides, or their derivatives as main raw materials.
[0015] The person skilled in the art has sought to find a substitute for silicone. The published document US2005 / 0260150 describes low-viscosity esters that can be used as a substitute for low-viscosity silicone fluids. The published document US2004 / 0241200 describes mixtures of certain synthetic esters with volatile hydrocarbons for replacing volatile tetramers and cyclic methylsiloxane pentamers. The published document US2009 / 0123398 describes mixtures of hydrocarbon fluids for replacing volatile tetramers and cyclic methylsiloxane pentamers.
[0016] The document EP3360600 relates to a natural silicone substitute for silicone fluids in personal formulations, said formulations comprising a mixture of at least one polymeric ester and at least one non-polymeric ester. The polymeric ester is the esterification product of (i) at least one first dicarboxylic acid, (ii) at least one first monofunctional alcohol or monofunctional carboxylic acid, and (iii) glycerol or a derivative thereof. The non-polymeric ester is the esterification product of (i) at least one second dicarboxylic acid and (ii) at least one second monofunctional alcohol.
[0017] However, none of these inventions solves the main problem: a composition capable of replacing silicones in the most varied applications. It is estimated that this emerging industry will maintain strong growth, therefore the Applicant has developed a natural and biodegradable product, of vegetable origin, which does not pose problems to human or animal health or to the environment, which can be considered a significant innovation. SUMMARY
[0018] OBJECT OF THE INVENTION
[0019] The Applicant has developed a natural product formulation to replace the silicones known on the market. The objective is to solve an increasingly serious worldwide problem that today's entrepreneurs cannot avoid. The environmental impact is a great threat and entrepreneurs must immediately seek various options. We are destroying forests, polluting rivers, polluting the air and we ourselves are certainly harmed. Fortunately, consumer concerns drive entrepreneurs to innovate and seek solutions.
[0020] In the range of silicones that we use, inhale, ingest daily without realizing it, there are some concerns, so some silicones have already been banned in Europe and Canada.
[0021] The Applicant has developed a natural composition capable of replacing silicones in different types of industrial applications, which has the following advantages:
[0022] - good rheological properties;
[0023] - colorless and odorless product;
[0024] - not flammable;
[0025] - natural product, which does not generate non-biodegradable emissions;
[0026] - sustainability;
[0027] - it has good sensory and cosmetic properties after application to the skin and hair, such as: conditioning, softness, ease of combing, smoothing, moisturizing, hair feel and spreadability;
[0028] - low cost of raw materials;
[0029] - low cost of the final product.
[0030] BRIEF DESCRIPTION OF THE INVENTION
[0031] The silicone replacement natural composition according to the present invention comprises, relative to the total mass of the composition:
[0032] - 0.5 to 80 mass% of polysaccharides, monosaccharides and derivatives thereof;
[0033] (a) 0.5 mass% to 80 mass% of polysaccharides, monosaccharides and derivatives thereof;
[0034] (b) 10 to 99.5 mass% of a monohydric alcohol, a polyhydric alcohol, an unsaturated fatty alcohol, a glyceride;
[0035] (c) 0 to 40 mass% of other components depending on the type of application, which can be grinding agents, lubricants, rheology modifiers, hygroscopic agents, etc.;
[0036] and a process for obtaining such a composition. BRIEF DESCRIPTION OF DRAWINGS
[0037] The appended drawings illustrate the results of experiments of the application:
[0038] - Figure 1 is a comparison chart of the properties after application to the hair and rinsing of the composition according to the application with cyclopentasiloxane and dimethicone;
[0039] - Figure 2 is a comparison chart of the properties after application to dry hair of the composition according to the application with cyclopentasiloxane and dimethicone;
[0040] - Figure 3 is a comparison chart of the properties after application to the hair and rinsing of the composition according to the application with dimethicone 350;
[0041] - Figure 4 is a comparison chart of the properties after application to dry hair of the composition according to the application with dimethicone 350;
[0042] - Figure 5 is a comparison chart of the properties after application to the hair and rinsing of the composition according to the application with dimethicone 1000;
[0043] - Figure 6 is a comparison chart of the properties after application to dry hair of the composition according to the application with dimethicone 1000;
[0044] - Figure 7 shows the skin results of the product according to the application relative to dimethicone 200;
[0045] - Figure 8 is a comparison chart of the properties after application to the hair and rinsing of the composition according to the application with dimethicone 5000;
[0046] - Figure 9 is a comparison chart of the properties after application to dry hair of the composition according to the application with dimethicone 5000;
[0047] - Figure 10Comparison chart of properties after application of the composition according to the application to the hair and rinsing with cyclomethicone and dimethiconol;
[0048] - Figure 11 Comparison chart of properties after application of the composition according to the application to dry hair with cyclomethicone and dimethiconol;
[0049] - Figure 12 Comparison chart of properties after application of the composition according to the application to the hair and rinsing with amodimethicone and trideceth-12 and cetrimonium chloride;
[0050] - Figure 13 Comparison chart of properties after application of the composition according to the application to dry hair with amodimethicone and trideceth-12 and cetrimonium chloride. DETAILED DESCRIPTION
[0051] The present application uses in its composition from 0.5 mass% to 80 mass% of a polysaccharide, a monosaccharide and their derivatives selected from the group comprising sucrose, lactose, fructose, galactose, maltose, arabinose, xylose, mannose, sucrose, sorbitol, glucose, etc., relative to the total mass of the composition. Preferably, glucose is used.
[0052] Corn glucose, also known as glucose syrup, is a food syrup obtained by hydrolysis of corn starch. Corn glucose is mainly a concentrated source of calories and has very low nutritional value. In recent years, corn glucose has become a popular sugar substitute. In recent years, the demand for corn glucose in the food processing industry has also shown strong growth. Corn glucose is mainly used as a key ingredient in commercially available foods to improve the flavor of the food, improve the color of the food, increase the volume of the food and make the food have uniform texture. As an aid to prevent sugar crystallization, corn glucose is widely used in preserves, jams, canned fruits, ice cream, ice cream, beverages, dairy desserts, biscuits, candies, cereals, tomato sauce, sauces, vitamin tonics and cough medicine. According to the IMARC group, in 2018, the entire corn glucose market volume has reached about 3.6 million tons, with a compound annual growth rate (CAGR) of nearly 1% from 2011 to 2018.
[0053] According to the present application, corn glucose can be used as a carbohydrate.
[0054] Glucose is a monosaccharide with the molecular formula C6H 12 O6. Glucose is the most abundant monosaccharide, which is naturally produced by plants and algae mainly during photosynthesis using solar energy from water and carbon dioxide.
[0055] The glucose used in the composition according to the present application can be used in the form of dry glucose syrup obtained by spray-drying a syrup of a carbohydrate concentrate resulting from the partial hydrolysis of starch.
[0056] The composition also uses 10 to 99.5 mass% of a monohydric alcohol, a polyhydric alcohol, an unsaturated fatty alcohol, a glyceride selected from the group comprising ethylene glycol, propylene glycol, glycerol, butylene glycol, ethylhexylglycerin, octyldiglyceryl, etc. Preferably, propylene glycol and / or glycerol are used.
[0057] The composition can also have another component (c) selected from the group comprising fatty acid derivatives selected from the group comprising lauryl acid, cetyl acid, stearyl acid, myristyl acid, oleyl acid, stearic acid, lauric acid, myristic acid, palmitic acid, oleic acid; linoleic acid. Preferably, isopropyl palmitate and / or isopentyl laurate are used.
[0058] Component (c) can also be an abrasive such as silicon dioxide.
[0059] According to one embodiment of the silicone alternative natural composition according to the present application, the composition comprises, relative to the total mass of the composition:
[0060] (a) 0.5 to 70 mass% of monosaccharides, polysaccharides and their derivatives selected from the group comprising sucrose, lactose, fructose, glucose, galactose, maltose, arabinose, xylose, mannose, sucrose, sorbitol and glucose;
[0061] (b) 10 to 99.5 mass% of ethylene glycol, propylene glycol, glycerol, butylene glycol;
[0062] (c) 0 to 40 mass% of other components depending on the type of application, which can be abrasives, lubricants, rheology modifiers, hygroscopic agents, etc.
[0063] According to another embodiment of the silicone alternative natural composition according to the present application, the composition comprises, relative to the total mass of the composition:
[0064] (a) 0.5 to 70 mass% of glucose;
[0065] (b) 10 to 99.5 mass% of propylene glycol and / or glycerol;
[0066] (c) 0 to 40 mass% of fatty acid esters and / or silicon dioxide.
[0067] According to a preferred embodiment of the silicone alternative natural composition according to the present application, the composition comprises, relative to the total mass of the composition:
[0068] (a) 2 to 60 mass% of glucose;
[0069] (b) 20 to 99.5 mass% of propylene glycol and / or glycerol;
[0070] (c) 0 to 35 mass% of fatty acid ester, silicon dioxide.
[0071] The method for obtaining the natural composition of silicone alternative according to the present application comprises the following steps:
[0072] (a) adding 10 to 99.5 mass% of monohydric alcohol, polyhydric alcohol, unsaturated fatty alcohol, glyceride to the reactor and increasing the temperature to 60 to 80 °C;
[0073] (b) stirring for 30 to 50 minutes, later slowly adding 0.5 to 70 mass% of monosaccharides, polysaccharides and their derivatives until a homogeneous mixture is obtained between 30 to 50 minutes;
[0074] (c) adding 0 to 40 mass% of other components depending on the type of application, such as abrasives, lubricants, fatty acid esters, rheology modifiers, hygroscopic agents, etc. and mixing for 30 to 50 minutes.
[0075] The method for obtaining the natural composition of silicone alternative according to the present application comprises the following steps:
[0076] (a) adding 10 to 99.5 mass% of lubricants and / or solvents selected from the group comprising ethylene glycol, propylene glycol, glycerol, butylene glycol to the reactor and increasing the temperature to 60 to 80 °C;
[0077] (b) stirring for 30 to 50 minutes, later slowly adding 0.5 to 60 mass% of monosaccharides, polysaccharides and their derivatives selected from the group comprising sucrose, lactose, fructose, glucose, galactose, maltose, arabinose, xylose, mannose, sucrose, sorbitol and glucose until a homogeneous mixture is obtained between 30 to 50 minutes;
[0078] (c) adding 0 to 40 mass% of other components depending on the type of application, such as abrasives, lubricants, fatty acid esters, rheology modifiers, hygroscopic agents, etc. and mixing for 30 to 50 minutes.
[0079] Another preferred embodiment of the method for obtaining the natural composition of silicone alternative according to the present application comprises the following steps:
[0080] (a) adding 10% to 99.5% by mass of propylene glycol and / or glycerol to the reactor and increasing the temperature to 60°C to 80°C;
[0081] (b) stirring for 30 to 50 minutes, and later slowly adding 0.5% to 60% by mass of glucose until a homogeneous mixture is obtained in 30 to 50 minutes;
[0082] (c) adding 0 to 40% by weight of fatty acid ester and / or desiccant.
[0083] The glucose is added slowly because it must be added very slowly to achieve good dispersion. The reactor speed can be between 150 rpm and 320 rpm, preferably between 200 rpm and 300 rpm.
[0084] The use of the silicone alternative natural composition according to the present application in cosmetics, pet grooming, skin care, automotive, etc., which are substantially free of silicone. By "substantially free of silicone" it is meant that the formulated formulation does not contain starting compounds containing silicone groups.
[0085] The following are some examples of embodiments of the present application, which are not intended to limit the scope of the present application.
[0086] Example
[0087] Example 1
[0088] The following Table 1 shows the mass ratio of the raw materials used in this example:
[0089] Table 1
[0090] Example 1 12% glucose 88% glycerol Brookfield viscosity at 25°C Max 2,500 cps
[0091] In a jacketed reactor, glycerol was added and the temperature was increased to 80°C. Stirring for 40 minutes, later slowly adding glucose because it must be added very slowly to achieve good dispersion. Mix for 40 minutes until homogeneous and the Brookfield viscosity at 25°C is 2,500 cps. After measuring the viscosity, it was verified that the product had reached the required parameters in this specification. It is important to let it cool to fill the product, passing it through a filter before filling to remove impurities.
[0092] The resulting product was tested on hair, with the comparative results shown in the attached Figure 1 and Figure 2 .
[0093] The Figure 1 graph for comparison of the properties of the composition according to the present application with cyclopentasiloxane and dimethicone, after application to the hair and rinsing.
[0094] TheFigure 2 A comparative graph showing the properties of the composition according to the invention with those of cyclopentasiloxane and dimethyl silicone oil after application to dry hair.
[0095] To obtain the accompanying drawings, a panel was used in which blind testing was conducted by applying the product obtained according to the embodiment to one half of each participant's hair and applying the silicone product to the other half of their hair.
[0096] Each volunteer was asked to label various attributes of the two products (the product according to the present invention and the silicone product) from 1 to 5, as described below, and the results are shown in the attached figure:
[0097] Mark 1 = difference
[0098] Mark 2 = Ordinary
[0099] Mark 3 = Good
[0100] Mark 4 = Excellent
[0101] Mark 5 = Excellent
[0102] The same method is used in other embodiments. In the case of embodiment 4, the method is the same, except that the product is applied to the skin.
[0103] Example 2
[0104] Table 2 below shows the mass ratio of the raw materials used in this embodiment:
[0105] Table 2
[0106] Example 2 9.3% glucose 48% glycerol 42.7% propylene glycol Brookfield viscosity at 25°C Max 400 cps
[0107] In a jacketed reactor, glycerol is added and the temperature is raised to 90°C. Propylene glycol is then added. The mixture is stirred for 40 minutes, followed by the slow addition of glucose, as this must be done very slowly to achieve good dispersion. Mixing continues for 40 minutes until homogeneous, and the Brookfield viscosity at 25°C is 400 cps. Viscosity testing confirms that the product has met the parameters required in this specification. The product can then be filled, passing it through a filter to remove impurities before filling.
[0108] The resulting products were tested on hair, and the comparative results are shown in the appendix to this article. Figure 3 and Figure 4 middle.
[0109] Figure 3 A comparative graph showing the properties of the composition according to the invention and dimethyl silicone oil 350 after application to hair and rinsing.
[0110] Figure 4A comparison chart of the properties of the composition according to the present application with dimethicone 350 after application to dry hair and rinsing.
[0111] Example 3
[0112] The following Table 3 shows the mass ratio of the raw materials used in this example:
[0113] Table 3
[0114] Example 3 33.5% glucose 66.5% propylene glycol Brookfield viscosity at 25°C Max 1,200 cps
[0115] In a jacketed reactor, add propylene glycol and raise the temperature to 80°C. Stir for 45 minutes, then slowly add glucose as it must be added very slowly to achieve good dispersion. Mix for 40 minutes until uniform and have a Brookfield viscosity of 1,200 cps at 25°C. After the viscosity is measured, the product is found to have achieved the parameters required in this specification. The product can then be filled, passing it through a filter to remove impurities before filling.
[0116] The resulting product is tested on the skin, with the comparative results shown in the attached Figure 5 and Figure 6 .
[0117] Figure 5 A comparison chart of the properties of the composition according to the present application with dimethicone 1000 after application to the hair and rinsing.
[0118] Figure 6 A comparison chart of the properties of the composition according to the present application with dimethicone 1000 after application to dry hair.
[0119] Example 4
[0120] The following Table 4 shows the mass ratio of the raw materials used in this example:
[0121] Table 4
[0122] Example 4 5% glucose 40% glycerol 55% propylene glycol Brookfield viscosity at 25°C Max 250 cps
[0123] In a jacketed reactor, add glycerol and raise the temperature to 90°C. Then, add propylene glycol. Stir for 40 minutes, then slowly add glucose as it must be added very slowly to achieve good dispersion. Mix for 40 minutes until uniform and have a Brookfield viscosity of 250 cps at 25°C. After the viscosity is measured, the product is found to have achieved the parameters required in this specification. The product can then be filled, passing it through a filter to remove impurities before filling.
[0124] The resulting product is tested on the skin, with the comparative results shown in the attached Figure 7 .
[0125] Figure 7 Graph of skin results for the product according to the application versus dimethicone 200.
[0126] Example 5
[0127] Table 5 below shows the mass ratio of the raw materials used in this example:
[0128] Table 5
[0129] Example 5 43.5% glucose 56.5% propylene glycol Brookfield viscosity at 25°C Max 6,000 cps
[0130] In a jacketed reactor, propylene glycol was added and the temperature was raised to 90°C. After 40 minutes of stirring, glucose was slowly added later as it had to be added very slowly to achieve good dispersion. It was mixed for 60 minutes until homogeneous and had a Brookfield viscosity of 8,000 cps at 25°C. As the product was very viscous, it was best to meet the viscosity determination temperature and always pass it through a filter to remove impurities.
[0131] The resulting product was tested on hair, with comparative results shown in the attached Figure 8 and Figure 9 .
[0132] Figure 8 Graph of properties after application of the composition according to the application versus dimethicone 5000 to dry hair and rinsing.
[0133] Figure 9 Graph of properties after application of the composition according to the application versus dimethicone 5000 to dry hair and rinsing.
[0134] Example 6
[0135] Table 6 below shows the mass ratio of the raw materials used in this example:
[0136] Table 6
[0137] Example 6 43% glucose 57% propylene glycol Brookfield viscosity at 25°C Max 8,000 cps
[0138] In a jacketed reactor, propylene glycol was added and the temperature was raised to 90°C. After 40 minutes of stirring, glucose was slowly added later as it had to be added very slowly to achieve good dispersion. It was mixed for 60 minutes until homogeneous and had a Brookfield viscosity of 8,000 cps at 25°C. As the product was very viscous, it was best to meet the viscosity determination temperature and always pass it through a filter to remove impurities.
[0139] The resulting product was tested on hair, with comparative results shown in the attached Figure 10 and Figure 11In.
[0140] Figure 10 Comparison chart of the properties after application of the composition according to the application to dry hair with cyclomethicone and dimethiconol.
[0141] Figure 11 Comparison chart of the properties after application of the composition according to the application to dry hair with cyclomethicone and dimethiconol.
[0142] Example 7
[0143] Table 7 below indicates the mass ratio of the raw materials used in this example:
[0144] Table 7
[0145] Example 7 2% glucose 30% cetrimonium chloride 68% propylene glycol
[0146] In a jacketed reactor, propylene glycol was added and the temperature was raised to 80°C. After 40 minutes of stirring, glucose was added slowly later, as it had to be added very slowly to achieve a good dispersion. It was mixed for 30 minutes, allowed to cool until homogeneous and had a Brookfield viscosity of 400 cps at 25°C. After the addition of cetrimonium chloride, it was stirred for more than 30 minutes. Later, the impurities were removed by a filter, thus preparing the product to be filled.
[0147] The resulting product was subjected to a hair test, the results of which are shown in the attached Figure 12 and Figure 13 .
[0148] Figure 12 Comparison chart of the properties after application of the composition according to the application to dry hair with cyclomethicone and dimethiconol.
[0149] Figure 13 Comparison chart of the properties after application of the composition according to the application to dry hair with cyclomethicone and dimethiconol.
Claims
1. A silicone substitute additive composition for use in the manufacture of skin or hair cosmetics, characterized in that, The composition consists of, relative to the total mass of the composition: (a) 0.5 to 80 mass% of glucose; and (b) 10 to 99.5 mass% of propylene glycol and / or glycerol, wherein the sum of (a) and (b) is 100 mass%; wherein the composition has a Brookfield viscosity in the range of 250 to 8000 cps at 25°C.
2. The silicone replacement additive composition of claim 1, wherein, The composition consists of, relative to the total mass of the composition: (a) 0.5 to 70 mass% of glucose; and (b) 10 to 99.5 mass% of propylene glycol and / or glycerol, wherein the sum of (a) and (b) is 100 mass%.
Citation Information
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