A plate for a carbon dioxide catalytic conversion reactor
By designing plate components that are easy to install and electrically connect, and ensuring sufficient contact between carbon dioxide gas and the plate by optimizing the structure, the problems of inconvenient installation of the plate and insufficient contact between carbon dioxide in the prior art are solved, and the catalytic conversion efficiency of carbon dioxide is improved.
Patent Information
- Application Number
- CN202211321536.4
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2022-10-26
- Publication Date
- 2025-05-27
- Estimated Expiration
- 2042-10-26
AI Technical Summary
In existing carbon dioxide electrocatalytic conversion reactors, the electrode plates are inconvenient to install and disassemble, and the electrode plates are not in sufficient contact with carbon dioxide, which affects the conversion efficiency.
A plate for a carbon dioxide catalytic conversion reactor is designed, including a cathode plate assembly and anode plate assembly. The plate assembly is designed through the structure of the push inner rod and the push spring to achieve convenient installation and electrical connection of the plate, and through the structure of the uniform side tube and the ventilation branch tube, ensuring full contact between the carbon dioxide gas and the plate.
Through this design, the installation and electrical connection of the electrode plates are more convenient, and the contact between the carbon dioxide gas and the electrode plates is more sufficient, which improves the catalytic conversion efficiency of carbon dioxide.
Smart Images

Figure CN115537858B_ABST
Abstract
Description
Technical Field
[0001] The invention belongs to the technical field of carbon dioxide catalytic conversion, and in particular relates to an electrode plate for a carbon dioxide catalytic conversion reactor. Background Art
[0002] Global warming has made carbon dioxide the most concerned greenhouse gas, and carbon dioxide emission reduction, capture and utilization technologies have also become the most concerned high-tech today.
[0003] The existing technology has the following problems: the electrocatalytic conversion of carbon dioxide is an important technology for the utilization of carbon dioxide. Its principle is roughly as follows: water undergoes an oxidation reaction at the anode to generate hydrogen ions and oxygen. The hydrogen ions migrate to the cathode through a mass transfer process and participate in the electrocatalytic reduction reaction of carbon dioxide at the cathode to generate formic acid and side reaction products. The anode and cathode here refer to the plates connected to the positive and negative electrodes of an external power supply, respectively. The positive electrode plate generates hydrogen ions and oxygen, and the negative electrode plate participates in the electrocatalytic reduction reaction of carbon dioxide. The existing positive and negative electrodes are mostly directly arranged in the carbon dioxide catalytic conversion reactor, lacking the necessary reasonable design, which leads to inconvenience in the installation and removal of the plates on the one hand, and insufficient contact between the plates and carbon dioxide on the other hand. Summary of the invention
[0004] In order to solve the problems raised in the above background technology, the present invention provides an electrode plate for a carbon dioxide catalytic conversion reactor, which has the characteristic of fully contacting carbon dioxide.
[0005] To achieve the above object, the present invention provides the following technical solution: an electrode plate for a carbon dioxide catalytic conversion reactor, comprising a carbon dioxide catalytic conversion reactor assembly, wherein a cathode electrode plate assembly and an anode electrode plate assembly are arranged on the carbon dioxide catalytic conversion reactor assembly, wherein the cathode electrode plate assembly is arranged in the cathode chamber of the carbon dioxide catalytic conversion reactor assembly, and the anode electrode plate assembly is arranged in the anode chamber of the carbon dioxide catalytic conversion reactor assembly;
[0006] The carbon dioxide catalytic conversion reactor assembly comprises a conversion reactor end cover and a conversion reactor rear cover, an intermediate cavity cover is arranged between the conversion reactor end cover and the conversion reactor rear cover, a proton exchange membrane is arranged inside the intermediate cavity cover, and a feed end pipe is arranged at the top of both ends of the intermediate cavity cover, a carbon dioxide inlet end pipe is arranged outside the conversion reactor end cover, and a gas equalization side pipe is fixedly arranged on the inner wall of the conversion reactor end cover, the gas equalization side pipe is connected to a plurality of carbon dioxide exhaust pipes through a ventilation branch pipe, a ventilation check valve is arranged on the ventilation branch pipe, an exhaust slit is arranged on the carbon dioxide exhaust pipe, and a mounting arm slide rod is fixedly arranged at the four corners of the inner wall of the conversion reactor end cover, and a mounting nut is threadedly arranged at the end of the mounting arm slide rod;
[0007] The cathode plate assembly includes a plate fixing outer cover and a plate. An inner wall at one end of the plate fixing outer cover is fixedly provided with a plurality of pushing outer tubes. A pushing inner rod is slidably arranged inside the pushing outer tube. A pushing spring is arranged between the pushing outer tube and the pushing inner rod. A U-shaped mounting socket plate is fixedly arranged at the end of the pushing inner rod. An outer wall at the other end of the plate fixing outer cover is fixedly provided with an end inner groove socket cap. An outer fixing end cap tube is fixedly arranged on one side of the end inner groove socket cap. An electrically connected pushing inner rod is slidably arranged inside the outer fixing end cap tube. A tightening spring is arranged between the electrically connected pushing inner rod and the outer fixing end cap tube. An electrically connected end wire is arranged on the electrically connected pushing inner rod. One end of the plate is fixedly provided with a plate electrical connection end head plate, and a head plate limiting groove is arranged on the plate electrical connection end head plate.
[0008] Preferably, the structure of the anode plate assembly is the same as that of the cathode plate assembly. The anode plate assembly is connected to the positive pole of an external power supply, and the cathode plate assembly is connected to the negative pole of the external power supply.
[0009] Preferably, the conversion reactor end cover, the intermediate cavity cover, and the conversion reactor rear cover are strung together by mounting arm sliding rods to form the outer end housing of the carbon dioxide catalytic conversion reactor. A cathode chamber for carbon dioxide catalytic conversion is formed between the conversion reactor end cover and the intermediate cavity cover. An anode chamber for carbon dioxide catalytic conversion is formed between the conversion reactor rear cover and the intermediate cavity cover. The cathode plate assembly is arranged in the cathode chamber, and the anode plate assembly is arranged in the anode chamber.
[0010] Preferably, the carbon dioxide exhaust pipe is arranged in a U-shaped structure, and one end of the carbon dioxide exhaust pipe is a long pipe structure and the other end is a short pipe structure. The carbon dioxide inlet end pipe is communicated with the air distribution side pipe, and the air distribution side pipe is communicated with the carbon dioxide exhaust pipe through an air vent branch pipe.
[0011] Preferably, the pushing inner rod slides telescopically inside the pushing outer tube. Through the pushing of the pushing spring, the U-shaped mounting socket plate at the end of the pushing inner rod is in a structure of being pushed out and tightened.
[0012] Preferably, the electrically connected pushing inner rod slides telescopically inside the outer fixing end cap tube. Through the pushing of the tightening spring, the elliptical convex head at the end of the electrically connected pushing inner rod is in a structure of being pushed out and tightened.
[0013] Preferably, one end plate body of the plate is limited and inserted into the U-shaped mounting socket plate, and the plate electrical connection end head plate at the other end of the plate is limited and inserted into the end inner groove socket cap. Through the pushing of the tightening spring, the elliptical convex head at the end of the electrically connected pushing inner rod presses against the head plate limiting groove on the plate electrical connection end head plate.
[0014] Preferably, the carbon dioxide exhaust pipe forms a surrounding pipe structure outside the electrode plate, and the carbon dioxide gas inside the carbon dioxide exhaust pipe is evenly distributed on both sides of the electrode plate through the exhaust slits.
[0015] Compared with the prior art, the beneficial effects of the present invention are as follows: When the present invention is in use, the pushing inner rod slides telescopically inside the pushing outer tube. Through the pushing of the pushing spring, the U-shaped mounting socket plate at the end of the pushing inner rod is in a structure of being pushed out and tightened. When the electrode plate is installed, one end plate body of the electrode plate is limited and inserted into the U-shaped mounting socket plate, and the electrode plate electrical connection end head plate at the other end of the electrode plate is limited and inserted into the end inner groove socket cap. In this way, the installation of the electrode plate is facilitated. At the same time, through the pushing of the tightening spring, the elliptical convex head at the end of the electrical connection pushing inner rod presses against the end head plate limiting groove on the electrode plate electrical connection end head plate. In this way, the electrical connection between the electrode plate and the external power supply is realized through the electrical connection end wire. A gas equalizing side pipe is fixedly arranged on the inner wall of the end cover of the conversion reactor. The gas equalizing side pipe is connected to a plurality of carbon dioxide exhaust pipes through ventilation branch pipes. A ventilation one-way valve is arranged on the ventilation branch pipe. An exhaust slit is arranged on the carbon dioxide exhaust pipe. The carbon dioxide exhaust pipe is arranged in a U-shaped structure, and one end of the carbon dioxide exhaust pipe is a long pipe structure and the other end is a short pipe structure. The carbon dioxide inlet end pipe is communicated with the gas equalizing side pipe. The gas equalizing side pipe is communicated with the carbon dioxide exhaust pipe through the ventilation branch pipe. The carbon dioxide exhaust pipe forms a surrounding pipe structure outside the electrode plate, and the carbon dioxide gas inside the carbon dioxide exhaust pipe is evenly distributed on both sides of the electrode plate through the exhaust slit. Through the setting of this structure, the full contact between the carbon dioxide gas and the electrode plate can be realized. Description of the Drawings
[0016] Figure 1 is a three-dimensional view of the present invention;
[0017] Figure 2 is an exploded view of the present invention;
[0018] Figure 3 is a three-dimensional view of the cathode electrode plate assembly of the present invention;
[0019] Figure 4 is an exploded view of the cathode electrode plate assembly of the present invention;
[0020] Figure 5 is an exploded view of a partial structure of the cathode electrode plate assembly of the present invention;
[0021] Figure 6 is a three-dimensional view of the carbon dioxide catalytic conversion reactor assembly of the present invention;
[0022] Figure 7 is a three-dimensional view of a partial structure of the carbon dioxide catalytic conversion reactor assembly of the present invention;
[0023] In the figure: 100, carbon dioxide catalytic conversion reactor assembly; 101, conversion reactor end cover; 102, intermediate cavity cover; 103, conversion reactor rear cover; 104, mounting arm slide bar; 105, mounting nut; 106, material feeding end pipe; 107, proton exchange membrane; 108, carbon dioxide inlet end pipe; 109, gas equalizing side pipe; 110, ventilation branch pipe; 111, ventilation check valve; 112, carbon dioxide exhaust pipe; 113, exhaust slit; 200, cathode plate assembly; 201, outer plate fixing cover; 202, pushing outer tube; 203, pushing spring; 204, pushing inner rod; 205, U-shaped mounting socket plate; 206, plate; 207, end plate limiting groove; 208, plate electrically connected to end plate; 209, electrically connected end wire; 210, outer fixed end cap tube; 211, end inner groove seat cap; 212, electrically connected pushing inner rod; 213, tightening spring; 300, anode plate assembly. Specific embodiments
[0024] Next, the technical solutions in the embodiments of the present invention will be clearly and completely described in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
[0025] Please refer to Figures 1-7 , the present invention provides the following technical solutions: A plate for a carbon dioxide catalytic conversion reactor, including a carbon dioxide catalytic conversion reactor assembly 100, a cathode plate assembly 200 and an anode plate assembly 300 are arranged on the carbon dioxide catalytic conversion reactor assembly 100, the cathode plate assembly 200 is arranged in the cathode chamber of the carbon dioxide catalytic conversion reactor assembly 100, and the anode plate assembly 300 is arranged in the anode chamber of the carbon dioxide catalytic conversion reactor assembly 100;
[0026] The carbon dioxide catalytic conversion reactor assembly 100 includes a conversion reactor end cover 101 and a conversion reactor rear cover 103. An intermediate cavity cover 102 is arranged between the conversion reactor end cover 101 and the conversion reactor rear cover 103. A proton exchange membrane 107 is arranged inside the intermediate cavity cover 102. Feed-through end pipes 106 are arranged at the tops of both ends of the intermediate cavity cover 102. A carbon dioxide inlet end pipe 108 is arranged outside the conversion reactor end cover 101. An air distribution side pipe 109 is fixedly arranged on the inner wall of the conversion reactor end cover 101. The air distribution side pipe 109 is connected to a plurality of carbon dioxide exhaust pipes 112 through ventilation branch pipes 110. A ventilation check valve 111 is arranged on the ventilation branch pipe 110. An exhaust slit 113 is arranged on the carbon dioxide exhaust pipe 112. Mounting arm slide rods 104 are fixedly arranged at the four corners of the inner wall of the conversion reactor end cover 101. Mounting nuts 105 are arranged at the ends of the mounting arm slide rods 104 in a threaded manner;
[0027] The cathode plate assembly 200 includes a plate fixing outer cover 201 and a plate 206. A plurality of push outer tubes 202 are fixedly arranged on the inner wall of one end of the plate fixing outer cover 201. Push inner rods 204 are slidably arranged inside the push outer tubes 202. A push spring 203 is arranged between the push outer tubes 202 and the push inner rods 204. A U-shaped mounting socket plate 205 is fixedly arranged at the end of the push inner rod 204. An end inner groove socket cap 211 is fixedly arranged on the outer wall of the other end of the plate fixing outer cover 201. An outer fixed end cap tube 210 is fixedly arranged on one side of the end inner groove socket cap 211. An electrically connected push inner rod 212 is slidably arranged inside the outer fixed end cap tube 210. A tightening spring 213 is arranged between the electrically connected push inner rod 212 and the outer fixed end cap tube 210. An electrically connected end wire 209 is arranged on the electrically connected push inner rod 212. A plate electrical connection end plate 208 is fixedly arranged at one end of the plate 206. An end plate limiting groove 207 is arranged on the plate electrical connection end plate 208.
[0028] In this embodiment, preferably, the structure of the anode plate assembly 300 is the same as that of the cathode plate assembly 200. The anode plate assembly 300 is connected to the positive pole of an external power supply, and the cathode plate assembly 200 is connected to the negative pole of the external power supply.
[0029] In this embodiment, preferably, the conversion reactor end cover 101, the intermediate cavity cover 102, and the conversion reactor rear cover 103 are strung together through the mounting arm slide rods 104 to form the outer end housing of the carbon dioxide catalytic conversion reactor. A cathode chamber for carbon dioxide catalytic conversion is formed between the conversion reactor end cover 101 and the intermediate cavity cover 102. An anode chamber for carbon dioxide catalytic conversion is formed between the conversion reactor rear cover 103 and the intermediate cavity cover 102. The cathode plate assembly 200 is arranged in the cathode chamber, and the anode plate assembly 300 is arranged in the anode chamber.
[0030] In this embodiment, preferably, the carbon dioxide exhaust pipe 112 is arranged in a U-shaped structure, and one end of the carbon dioxide exhaust pipe 112 is a long pipe structure and the other end is a short pipe structure. The carbon dioxide inlet end pipe 108 is communicated with the gas equalizing side pipe 109, and the gas equalizing side pipe 109 is communicated with the carbon dioxide exhaust pipe 112 through the ventilation branch pipe 110.
[0031] In this embodiment, preferably, the push inner rod 204 slides telescopically in the push outer pipe 202. Through the pushing of the push spring 203, the U-shaped mounting socket plate 205 at the end of the push inner rod 204 is in a structure of being pushed out and tightened.
[0032] In this embodiment, preferably, the electrically connected push inner rod 212 slides telescopically in the outer fixed end cap pipe 210. Through the pushing of the tightening spring 213, the elliptical convex head at the end of the electrically connected push inner rod 212 is in a structure of being pushed out and tightened.
[0033] In this embodiment, preferably, one end plate body of the electrode plate 206 is limited and inserted into the U-shaped mounting socket plate 205, and the electrode plate electrical connection end head plate 208 at the other end of the electrode plate 206 is limited and inserted into the end inner groove seat cap 211. Through the pushing of the tightening spring 213, the elliptical convex head at the end of the electrically connected push inner rod 212 presses against the end head plate limiting groove 207 on the electrode plate electrical connection end head plate 208.
[0034] In this embodiment, preferably, the carbon dioxide exhaust pipe 112 forms an enclosing pipe body structure outside the electrode plate 206, and the carbon dioxide gas inside the carbon dioxide exhaust pipe 112 is evenly distributed on both sides of the electrode plate 206 through the exhaust slits 113.
[0035] Working principle and usage process of the present invention: When the present invention is in use, the pushing inner rod 204 slides telescopically within the pushing outer tube 202. Through the pushing of the pushing spring 203, the U-shaped mounting socket plate 205 at the end of the pushing inner rod 204 is in a structure of being pushed out and tightened. When the electrode plate 206 is installed, one end plate body of the electrode plate 206 is limited and inserted into the U-shaped mounting socket plate 205, and the electrode electrical connection end head plate 208 at the other end of the electrode plate 206 is limited and inserted into the end inner groove seat cap 211. In this way, the installation of the electrode plate 206 is facilitated. At the same time, through the pushing of the tightening spring 213, the elliptical convex head at the end of the electrical connection pushing inner rod 212 presses against the end head plate limiting groove 207 on the electrode electrical connection end head plate 208. In this way, the electrical connection between the electrode plate 206 and the external power supply is realized through the electrical connection end wire 209. A gas equalizing side tube 109 is fixedly arranged on the inner wall of the conversion reactor end cover 101. The gas equalizing side tube 109 is connected to a plurality of carbon dioxide exhaust pipes 112 through ventilation branch pipes 110. A ventilation one-way valve 111 is arranged on the ventilation branch pipe 110, and an exhaust slit 113 is arranged on the carbon dioxide exhaust pipe 112. The carbon dioxide exhaust pipe 112 is arranged in a U-shaped structure, and one end of the carbon dioxide exhaust pipe 112 is a long pipe structure and the other end is a short pipe structure. The carbon dioxide inlet end pipe 108 is communicated with the gas equalizing side tube 109, and the gas equalizing side tube 109 is communicated with the carbon dioxide exhaust pipe 112 through the ventilation branch pipe 110. The carbon dioxide exhaust pipe 112 forms a surrounding pipe body structure outside the electrode plate 206, and the carbon dioxide gas inside the carbon dioxide exhaust pipe 112 is evenly distributed on both sides of the electrode plate 206 through the exhaust slit 113. Through the setting of this structure, the full contact between the carbon dioxide gas and the electrode plate 206 can be realized.
[0036] Although the embodiments of the present invention have been shown and described, for those of ordinary skill in the art, it can be understood that various changes, modifications, substitutions, and variations can be made to these embodiments without departing from the principles and spirit of the present invention. The scope of the present invention is defined by the appended claims and their equivalents.
Claims
1. A plate for a carbon dioxide catalytic conversion reactor, comprising a carbon dioxide catalytic conversion reactor assembly (100), characterized in that: A cathode plate assembly (200) and an anode plate assembly (300) are arranged on the carbon dioxide catalytic conversion reactor assembly (100). The cathode plate assembly (200) is arranged in the cathode chamber of the carbon dioxide catalytic conversion reactor assembly (100), and the anode plate assembly (300) is arranged in the anode chamber of the carbon dioxide catalytic conversion reactor assembly (100); The carbon dioxide catalytic conversion reactor assembly (100) includes a conversion reactor end cover (101) and a conversion reactor rear cover (103). An intermediate cavity cover (102) is arranged between the conversion reactor end cover (101) and the conversion reactor rear cover (103). A proton exchange membrane (107) is arranged inside the intermediate cavity cover (102), and feed-through end pipes (106) are arranged at the tops of both ends of the intermediate cavity cover (102). A carbon dioxide inlet end pipe (108) is arranged outside the conversion reactor end cover (101), and a gas equalizing side pipe (109) is fixedly arranged on the inner wall of the conversion reactor end cover (101). The gas equalizing side pipe (109) is connected to a plurality of carbon dioxide exhaust pipes (112) through ventilation branch pipes (110). A ventilation check valve (111) is arranged on the ventilation branch pipe (110), and an exhaust slit (113) is arranged on the carbon dioxide exhaust pipe (112). Mounting arm slide rods (104) are fixedly arranged at the four corners of the inner wall of the conversion reactor end cover (101), and mounting nuts (105) are arranged at the ends of the mounting arm slide rods (104) in a threaded manner; The cathode plate assembly (200) includes a plate fixing outer cover (201) and a plate (206). A plurality of push outer tubes (202) are fixedly arranged on the inner wall of one end of the plate fixing outer cover (201). A push inner rod (204) is slidably arranged inside the push outer tube (202). A push spring (203) is arranged between the push outer tube (202) and the push inner rod (204). A U-shaped mounting socket plate (205) is fixedly arranged at the end of the push inner rod (204). An end inner groove socket cap (211) is fixedly arranged on the outer wall of the other end of the plate fixing outer cover (201). An externally fixed end cap tube (210) is fixedly arranged on one side of the end inner groove socket cap (211). An electrically connected push inner rod (212) is slidably arranged inside the externally fixed end cap tube (210). A tightening spring (213) is arranged between the electrically connected push inner rod (212) and the externally fixed end cap tube (210). An electrically connected end wire (209) is arranged on the electrically connected push inner rod (212). A plate electrical connection end head plate (208) is fixedly arranged at one end of the plate (206), and an end head plate limiting groove (207) is arranged on the plate electrical connection end head plate (208); The carbon dioxide exhaust pipe (112) is arranged in a U-shaped structure, and one end of the carbon dioxide exhaust pipe (112) is a long pipe structure and the other end is a short pipe structure. The carbon dioxide inlet end pipe (108) is communicated with the gas equalizing side pipe (109), and the gas equalizing side pipe (109) is communicated with the carbon dioxide exhaust pipe (112) through a ventilation branch pipe (110); The carbon dioxide exhaust pipe (112) forms an enclosed pipe body structure outside the electrode plate (206), and the carbon dioxide gas inside the carbon dioxide exhaust pipe (112) is evenly distributed on both sides of the electrode plate (206) through the exhaust slit (113).
2. A plate for a carbon dioxide catalytic conversion reactor according to claim 1, characterized in that: The structure of the anode plate assembly (300) is the same as that of the cathode plate assembly (200). The anode plate assembly (300) is connected to the positive pole of an external power supply, and the cathode plate assembly (200) is connected to the negative pole of the external power supply.
3. A plate for a carbon dioxide catalytic conversion reactor according to claim 1, characterized in that: The conversion reactor end cover (101), the intermediate cavity cover (102) and the conversion reactor rear cover (103) are strung together through the installation arm slide rod (104) to form the outer end housing of the carbon dioxide catalytic conversion reactor. A cathode chamber for carbon dioxide catalytic conversion is formed between the conversion reactor end cover (101) and the intermediate cavity cover (102), and an anode chamber for carbon dioxide catalytic conversion is formed between the conversion reactor rear cover (103) and the intermediate cavity cover (102). The cathode plate assembly (200) is arranged in the cathode chamber, and the anode plate assembly (300) is arranged in the anode chamber.
4. A plate for a carbon dioxide catalytic conversion reactor according to claim 1, characterized in that: The push-in inner rod (204) slides telescopically in the push-in outer tube (202). Through the push of the push spring (203), the U-shaped mounting socket plate (205) at the end of the push-in inner rod (204) is in a structure of being pushed out and tightened.
5. A plate for a carbon dioxide catalytic conversion reactor according to claim 1, characterized in that: The electrically connected push-in inner rod (212) slides telescopically in the outer fixed end cap tube (210). Through the push of the tightening spring (213), the elliptical convex head at the end of the electrically connected push-in inner rod (212) is in a structure of being pushed out and tightened.
6. A plate for a carbon dioxide catalytic conversion reactor according to claim 1, characterized in that: One end plate body of the electrode plate (206) is limited and inserted into the U-shaped mounting socket plate (205), and the electrode plate electrical connection end head plate (208) at the other end of the electrode plate (206) is limited and inserted into the end inner groove seat cap (211). Through the push of the tightening spring (213), the elliptical convex head at the end of the electrically connected push-in inner rod (212) presses against the end head plate limiting groove (207) on the electrode plate electrical connection end head plate (208).
Citation Information
Patent Citations
Preparation gas recycling device for preparing formic acid by electrolyzing carbon dioxide
CN113897630A
Carbon dioxide electrolytic tank and carbon dioxide electrolytic galvanic pile device
CN114395773A