CuO-CeO2 nanocatalysts rich in oxygen vacancies, their preparation methods, and their application in electrocatalytic carbon dioxide reduction.

By preparing CuO-CeO2 nanocatalysts rich in oxygen vacancies, the problems of insufficient selectivity and stability of copper-based catalysts in the electrocatalytic reduction of carbon dioxide were solved, and the effect of efficient conversion into high-carbon compounds was achieved.

CN115627494BActive Publication Date: 2026-05-29SOUTH CHINA UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SOUTH CHINA UNIV OF TECH
Filing Date
2022-09-16
Publication Date
2026-05-29

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Abstract

The application discloses an X2H2 nano-catalyst rich in oxygen vacancies and a preparation method and application thereof in electrocatalytic reduction of carbon dioxide. The preparation method comprises the following steps: firstly, adding monohydrate citric acid into a solution containing copper salt and cerium salt, evaporating and concentrating the solution to form a sol, and then drying the gel to obtain a gel which is placed in a tube furnace for annealing, so as to obtain the X2H2 nano-catalyst rich in oxygen vacancies. The catalyst can be applied to electrocatalytic reduction of carbon dioxide to generate high-carbon products. The application has the characteristics of simple preparation operation, low cost and excellent performance (the selectivity is as high as 100%) in electrochemical reduction of carbon dioxide to ethylene and ethanol.
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