A self-rotating ultra / micro-gravity - micro-interface synergistic enhanced catalytic hydrogenation device for petroleum resin and its usage method

Abstract

The present invention discloses a self-rotating ultra / micro gravity-micro interface synergistic enhanced catalytic hydrogenation device for petroleum resin and its usage method. The reaction device includes: a cylindrical heat exchanger, which is provided with a first petroleum resin solution inlet, a material outlet, a second petroleum resin solution inlet, and a hydrogen inlet; a coil reactor, which includes a coil, the coil is in a cylindrical spiral shape, and the coil is located inside the cylindrical heat exchanger; the left and right ends of the coil are respectively communicated with the first petroleum resin solution inlet and the material outlet; the coil is provided with a first material port communicated with the second petroleum resin solution inlet and a second material port communicated with the hydrogen inlet; a preheater, which is communicated with the first petroleum resin solution inlet and the second petroleum resin solution inlet; a first fluid conveyor; a second fluid conveyor; and the usage method of the reaction device. By adopting the reaction device of the present invention, it has a simple structure and reliable operation, and can achieve the industrial production goals of high efficiency, low energy consumption and low investment.

Description

Technical Field

[0001] The present invention relates to the field of chemical engineering technology, and particularly relates to a self-rotating super / micro-gravity - micro-interface synergistic enhanced catalytic hydrogenation device for petroleum resin and a method for using the same. Background Art

[0002] Petroleum resin is a thermoplastic resin obtained by polymerizing C5 - C9 fractions by-products in the process of ethylene production from naphtha cracking. However, petroleum resin contains a large number of unsaturated double bonds, which are prone to oxidation or substitution reactions, resulting in poor photothermal stability and darker color, severely limiting its application range. By hydrogenating and modifying petroleum resin, high-quality hydrogenated petroleum resin can be obtained, and its chromaticity, stability, and miscibility can be greatly improved, and it is widely used in fine chemical fields such as food packaging, pressure-sensitive adhesives, and sanitary products. As a macromolecular polymer with a relative molecular mass of 300 - 3000, petroleum resin has the characteristics of large molecular diameter and high solution viscosity, and there is an obvious resistance to its diffusion in the solution, resulting in difficulty for petroleum resin molecules to approach the active components in the catalyst. Therefore, it is difficult to efficiently hydrogenate petroleum resin. Currently, some invention patents have been applied for the technology of catalytic hydrogenation of petroleum resin as follows.

[0003] CN106832127B discloses an industrial manufacturing method of hydrogenated petroleum resin. This method adopts a two-stage hydrogenation and combined alkali washing and neutralization process. Under the condition of the presence of a suitable hydrogenation catalyst and solvent, the petroleum resin obtained by polymerizing cracked C5 and C9 fractions undergoes a hydrogenation reaction. The unsaturated components in the petroleum resin are hydrogenated to reduce the double bond content, the colored groups are hydrogenated to decolorize, and the residual chlorine in the polymerization process is removed by hydrogenation. After alkali washing, water washing, injection of stabilizer, and solvent removal, a light-colored or colorless hydrogenated petroleum resin is obtained.

[0004] CN106832127B discloses a method for preparing hydrogenated C9 petroleum resin by directional hydrogenation, including: (1) mixing C9 petroleum resin with a mixed solvent evenly and then removing impurities through an Al2O3 packing bed; (2) feeding the pretreated resin liquid into a first-stage hydrogenation reactor loaded with Ni / Mo / W Al2O3 catalyst for hydrogenation reaction to obtain a first-stage hydrogenated resin liquid; (3) feeding the above first-stage hydrogenated resin liquid into a pressure stabilizing flash distillation tower, and obtaining a desulfurized resin liquid at the bottom of the tower; (4) mixing the desulfurized resin liquid with hydrocracking jet fuel evenly and then feeding it into a second-stage hydrogenation reactor for hydrogenation reaction to obtain a second-stage hydrogenated resin liquid; (5) feeding the second-stage hydrogenated resin liquid into a vacuum distillation tower, and obtaining hydrogenated C9 petroleum resin at the bottom of the tower.

[0005] CN105772042B provides a C5 petroleum resin hydrogenation catalyst and its preparation method. The C5 petroleum resin hydrogenation catalyst consists of a carrier and an active component supported on the carrier. The carrier is silica, and the active component is nickel phosphide and ruthenium phosphide. Based on the mass of the silica carrier, the loading amount of nickel phosphide is 10 wt% - 20 wt% calculated as nickel, and the loading amount of ruthenium phosphide is 0.5 wt% - 1 wt% calculated as ruthenium.

[0006] CN104877077B discloses a method for preparing hydrogenated C9 petroleum resin, belonging to the technical field of resin hydrogenation. Using a Ni / ZnO catalyst as a hydrogenation adsorption desulfurization catalyst and a supported metal catalyst as a hydrogenation decolorization catalyst, the resin is subjected to a hydrogenation reaction in a two-stage fixed-bed continuous hydrogenation mode. Due to the use of the Ni / ZnO hydrogenation adsorption desulfurization catalyst, the service life of the supported metal catalyst is ensured.

[0007] The above patents all utilize special mechanical equipment and precision instruments to generate super / micro-gravity - micro-interfaces, ultrasonic waves, microwaves, and the action of rotating disks to strengthen the chemical engineering transfer process. Therefore, the energy consumption, equipment investment, and operation difficulty are all relatively large. Summary of the Invention

[0008] The purpose of the present invention is to provide a self-rotating super / micro-gravity - micro-interface synergistic strengthening petroleum resin catalytic hydrogenation device and its usage method, thereby overcoming the disadvantages in the prior art that special mechanical equipment and precision instruments are required to generate super / micro-gravity - micro-interface effects to strengthen the chemical engineering transfer process, resulting in relatively large energy consumption, equipment investment, and operation difficulty.

[0009] To achieve the above object, the present invention provides a self-rotating ultra / micro-gravity - micro-interface synergistic enhanced catalytic hydrogenation device for petroleum resin, comprising: a cylindrical heat exchanger, with a first petroleum resin solution inlet and a material outlet provided at its left and right ends respectively, a first heat exchange fluid inlet and a first heat exchange fluid outlet provided on the left and right sides of the cylindrical heat exchanger respectively, and at least two second petroleum resin solution inlets spaced apart and provided on the side wall of the cylindrical heat exchanger; and at least three hydrogen inlets spaced apart and provided on the side wall of the cylindrical heat exchanger; a coiled tube reactor, which includes a coiled tube, the coiled tube being in a cylindrical spiral shape, the coiled tube being located inside the cylindrical heat exchanger, and the axis of the coiled tube being distributed in the left-right direction; the left end of the coiled tube is connected to the first petroleum resin solution inlet, and the right end of the coiled tube is connected to the material outlet; two first material ports each connected to one of the second petroleum resin solution inlets are provided along the length direction of the coiled tube, and three second material ports each connected to one of the hydrogen inlets are provided along the length direction of the coiled tube; a preheater, with a second heat exchange fluid inlet and a second heat exchange fluid outlet provided on its side wall, and the outlets of the material channels of the preheater are respectively connected to the first petroleum resin solution inlet and each of the second petroleum resin solution inlets; a first fluid conveyor, which is connected to the inlet of the material channel of the preheater and is used to convey petroleum resin solution into the preheater; and a second fluid conveyor, which is respectively connected to each of the hydrogen inlets and is used to convey hydrogen into the coiled tube.

[0010] Preferably, in the above technical solution, two of the hydrogen inlets are located above the cylindrical heat exchanger, and the other hydrogen inlet is located below the cylindrical heat exchanger; one of the second petroleum resin solution inlets is located above the cylindrical heat exchanger and between the two hydrogen inlets, and the other second petroleum resin solution inlet is located to the left of the hydrogen inlet below the cylindrical heat exchanger.

[0011] Preferably, in the above technical solution, the diameter of the coiled tube is 3 mm to 100 mm, the number of turns of the coiled tube is 1 turn to 500 turns, and the diameter of each turn of the coiled tube is 50 mm to 1200 mm.

[0012] Preferably, in the above technical solution, the diameter of the cylindrical heat exchanger is 70 mm to 1250 mm, and the length is 500 mm to 60000 mm.

[0013] Preferably, in the above technical solution, two rows of baffle groups are provided inside the cylindrical heat exchanger, each row of the baffle groups includes a plurality of baffles spaced apart in the left-right direction, and the baffles of the two rows of baffle groups are arranged staggered with each other.

[0014] Preferably, in the above technical solution, the distance between two adjacent baffles is 50 mm to 500 mm.

[0015] A method for using a self-rotating ultra / micro-gravity - micro-interface synergistic enhanced catalytic hydrogenation device for petroleum resin as described above, comprising the following steps:

[0016] 1) The first heat exchange fluid inlet and the first heat exchange fluid outlet of the cylindrical heat exchanger are connected to a device for providing a cold fluid, and the second heat exchange fluid inlet and the second heat exchange fluid outlet of the preheater are connected to a device for providing a hot fluid for heat exchange; the petroleum resin solution is transported to the preheater for preheating by the first fluid conveyor and then transported into the coil; and hydrogen is transported into the coil by the second fluid conveyor; the flow rate V of the petroleum resin solution transported by the first fluid conveyor and the flow rate V of the hydrogen transported by the second fluid conveyor are determined by the value of β, and the specific calculation formula is as follows:

[0017] The centrifugal acceleration is G = Rω 2 (1)

[0018] The gravitational acceleration of the earth is g = 9.81 m / s 2 (2)

[0019] Ultra / micro-gravity factor

[0020] In the formula: G - centrifugal acceleration, m / s 2 ;

[0021] R - radius of circular motion, that is, the radius of each circle of the coil, m;

[0022] g - gravitational acceleration of the earth, m / s 2 ;

[0023] ω - angular velocity of circular motion, that is, the angular velocity of the material moving in the coil, 1 / s;

[0024] β - ultra / micro-gravity factor;

[0025] N - rotational speed of circular motion, r / min;

[0026] π - pi;

[0027] V - linear velocity of circular motion, that is, the flow rate of the material in the coil, m / s;

[0028] Among them, R is a known value, and β takes a specific value so that the material is in a microgravity or hypergravity state in the coil reactor;

[0029] 2) The petroleum resin solution flowing in from the first petroleum resin solution inlet and each second petroleum resin solution inlet, and the hydrogen flowing in from the hydrogen inlet are mixed and reacted in the coil.

[0030] Among them, when β = 1 - 50, it is the micro-gravity field effect; when β > 50, it is the hyper-gravity field effect, and the value of β is selected according to the viscosity, density, temperature and chemical reaction characteristics of the material.

[0031] Compared with the prior art, the present invention has the following beneficial effects:

[0032] 1. The petroleum resin solution of the present invention is pressurized by the first fluid conveyor and then sent to the preheater for preheating, and then conveyed into the coil pipe. Hydrogen is pressurized by the second fluid conveyor and then sent into the coil pipe, so that the two reaction materials perform circumferential rotation flow in the coil pipe to generate centrifugal force. Under the action of the centrifugal force generated by the high-speed self-rotation flow, it can overcome gravity to form a super / micro-gravity - micro interface field, so that the heterogeneous reaction materials form millimeter-sized or micron-sized small liquid droplets and small bubbles, and the aggregation scale of the gas-liquid, gas-liquid-liquid, and gas-liquid-solid interfaces is efficiently regulated from the millimeter-centimeter level to the micron level, so as to strengthen the synergistic-coupling effect of the mixing and reaction processes between fluid phases and achieve the transfer effect of strengthening the reaction system; it is not necessary to use special mechanical equipment to drive the reaction materials to generate centrifugal force by high-speed rotation, but to generate a super / micro-gravity - micro interface through the circumferential rotation flow of the reaction materials in the reaction device to achieve the transfer process of strengthening the reaction system, with simple structure, easy manufacturing, reliable operation, convenient installation and maintenance, and simple operation, and can achieve the industrial production goals of high efficiency, low energy consumption, low pollution and low investment.

[0033] 2. The use method of the reaction device of the present invention is simple and convenient, and can make the petroleum resin solution and hydrogen perform circumferential rotation flow in the coil pipe and maintain the mixing and reaction state in the super / micro-gravity - micro interface field state, increasing the transfer area of the gas-liquid phase interface in the reaction system and promoting the reaction progress. BRIEF DESCRIPTION OF THE DRAWINGS

[0034] Figure 1 is a schematic structural diagram of a self-rotating super / micro-gravity - micro interface synergistic strengthening petroleum resin catalytic hydrogenation device according to the present invention.

[0035] Figure 2 is a schematic structural diagram of a coil reactor according to the present invention.

[0036] Figure 3 is according to the present invention Figure 2 left view schematic diagram.

[0037] Main reference numeral description:

[0038] 1 - First fluid conveyor, 2 - Second heat exchange fluid outlet, 3 - Preheater, 4 - First heat exchange fluid outlet, 5 - Second petroleum resin solution inlet, 6 - Hydrogen inlet, 7 - Cylindrical heat exchanger, 8 - Material outlet, 9 - First heat exchange fluid inlet, 10 - Coiled pipe, 11 - Baffle, 12 - First petroleum resin solution inlet, 13 - Second heat exchange fluid inlet, 14 - Second material port, 15 - First material port. Detailed implementation manners

[0039] The following combines the attached drawings to describe the detailed implementation manners of the present invention. However, it should be understood that the protection scope of the present invention is not limited by the detailed implementation manners.

[0040] Unless otherwise clearly stated, throughout the specification and claims, the term "comprising" or its variations such as "including" or "having" etc. will be understood to include the stated elements or components, without excluding other elements or other components.

[0041] Embodiment 1

[0042] Figures 1 to 3 It shows a structural schematic diagram of a self - rotating super / micro - gravity - micro - interface synergistic enhanced petroleum resin catalytic hydrogenation device according to a preferred embodiment of the present invention. The reaction device includes a cylindrical heat exchanger 7, a coiled - pipe reactor, a preheater 3, a first fluid conveyor 1, and a second fluid conveyor (not shown in the figure).

[0043] Reference Figures 1 to 3, the left and right ends of the cylindrical heat exchanger 7 are respectively provided with a first petroleum resin solution inlet 12 and a material outlet 8, the left and right sides of the cylindrical heat exchanger 7 are respectively provided with a first heat exchange fluid inlet 9 and a first heat exchange fluid outlet 4, the reaction takes place inside the cylindrical heat exchanger 7, heat is released during the reaction process, and the cold fluid enters and exits the cylindrical heat exchanger 7 to achieve the purpose of controlling the reaction temperature. And the first heat exchange fluid inlet 9 is preferably located below the cylindrical heat exchanger 7, and the first heat exchange fluid outlet 4 is preferably located above the cylindrical heat exchanger 7. At least two second petroleum resin solution inlets 5 are provided on the side wall of the cylindrical heat exchanger 7 at intervals for inputting the petroleum resin solution. At least three hydrogen inlets 6 are provided on the side wall of the cylindrical heat exchanger 7 at intervals for inputting hydrogen. The coiled tube reactor includes a coiled tube 10, and the coiled tube 10 is in a cylindrical spiral shape, which can not only increase the heat exchange area but also enable the material inside the coiled tube 10 to flow in a circular rotation. The coiled tube 10 is located inside the cylindrical heat exchanger 7, and the axis of the coiled tube 10 is distributed in the left-right direction. The left end of the coiled tube 10 is connected to the first petroleum resin solution inlet 12, and the right end of the coiled tube 10 is connected to the material outlet 8. Two first material ports 15 each connected to one of the second petroleum resin solution inlets 5 are provided along the length direction of the coiled tube 10 for facilitating the input of the petroleum resin solution. And three second material ports 14 each connected to one of the hydrogen inlets 6 are provided along the length direction of the coiled tube 10 for facilitating the input of hydrogen. A second heat exchange fluid inlet 13 and a second heat exchange fluid outlet 2 are provided on the side wall of the preheater 3, and the outlets of the material channels of the preheater 3 are respectively connected to the first petroleum resin solution inlet 12 and each of the second petroleum resin solution inlets 5; the hot fluid flows into the preheater 3 through the second heat exchange fluid inlet 13 and flows out from the second heat exchange fluid outlet 2 to preheat the petroleum resin solution flowing through the preheater 3, thereby improving the fluidity of the petroleum resin solution. The first fluid conveyor 1 is connected to the inlet of the material channel of the preheater 3 for conveying the petroleum resin solution into the preheater 3, so that after the petroleum resin solution is preheated in the preheater 3, it is then conveyed into the coiled tube 10, and through the adjustment of the first fluid conveyor 1, the speed of the petroleum resin solution entering the coiled tube 10 can be adjusted, thereby regulating the speed of the petroleum resin solution entering the coiled tube 10.The second fluid conveyor is respectively connected to each hydrogen inlet 6 for conveying hydrogen into the coil 10, and through the action of the second fluid conveyor, the speed of hydrogen entering the coil 10 can be adjusted; so that the two reaction materials rotate circumferentially in the coil 10 to generate centrifugal force, and under the action of the centrifugal force generated by the high-speed self-rotating flow, the gravity can be overcome to form a super / micro-gravity - micro-interface field, so that the heterogeneous reaction materials form millimeter-sized or micron-sized small droplets and small bubbles, and the collective scale of the gas-liquid, gas-liquid-liquid, and gas-liquid-solid interfaces can be efficiently regulated from the millimeter-centimeter level to the micron level to strengthen the synergistic-coupling effect of the mixing and reaction processes between fluid phases and achieve the transfer effect of strengthening the reaction system; there is no need to use special mechanical equipment to drive the reaction materials to generate centrifugal force by high-speed rotation, but the reaction materials rotate circumferentially by themselves in the reaction device to generate a super / micro-gravity - micro-interface to achieve the transfer process of strengthening the reaction system, with simple structure, easy manufacturing, reliable operation, convenient installation and maintenance, and simple operation, and can achieve the industrial production goals of high efficiency, low energy consumption, low pollution, and low investment.

[0044] Reference Figure 1 and Figure 2 , preferably, two of the hydrogen inlets 6 are located above the cylindrical heat exchanger 7 and are spaced apart left and right, and the other hydrogen inlet 6 is located below the cylindrical heat exchanger 7; one of the second petroleum resin solution inlets 5 is located above the cylindrical heat exchanger 7 and between the two hydrogen inlets 6, and the other second petroleum resin solution inlet 5 is located on the left side of the hydrogen inlet 6 below the cylindrical heat exchanger 7, so that the petroleum resin solution and hydrogen can be added to the coil 10 at different positions of the coil 10 to improve the reaction effect.

[0045] Reference Figures 1 to 3 , preferably, the diameter of the coil 10 is 3 mm to 100 mm, the number of turns of the coil 10 is 1 to 500 turns, and the diameter of each turn of the coil 10 is 50 mm to 1200 mm.

[0046] Reference Figures 1 to 3 , preferably, the diameter of the cylindrical heat exchanger 7 is 70 mm to 1250 mm, and the length of the cylindrical heat exchanger 7 is 500 mm to 60000 mm.

[0047] Reference Figures 1 to 3 , preferably, there are two rows of baffle groups up and down in the cylindrical heat exchanger 7, each row of baffle groups includes a plurality of baffles 11 spaced apart in the left-right direction, and the baffles 11 of the two rows of baffle groups are arranged staggeredly to guide the flow direction of the cold fluid in the cylindrical heat exchanger 7 and improve the heat exchange effect. Further preferably, the distance between two adjacent baffles 11 is 50 mm to 500 mm.

[0048] Example 2

[0049] Reference Figures 1 to 3 , such as the usage method of the self-rotating ultra / micro-gravity - micro-interface synergistic enhanced catalytic hydrogenation device for petroleum resin in Example 1, the operation steps are as follows:

[0050] 1) The first heat exchange fluid inlet 9 and the first heat exchange fluid outlet 4 of the cylindrical heat exchanger 7 are connected to the device providing the cold fluid. The diameter of the cylindrical heat exchanger 7 is 240 mm, the length of the cylindrical heat exchanger 7 is 1800 mm, and there are 8 baffles 11 in the cylindrical heat exchanger 7. The distance between adjacent two baffles 11 is 200 mm, which is used to cool the reaction materials in the coiled pipe 10. The diameter of the coiled pipe 10 is 10 mm, the number of turns of the coiled pipe 10 is 20 turns, and the diameter of each turn of the coiled pipe 10 is 200 mm. And the second heat exchange fluid inlet 13 and the second heat exchange fluid outlet 2 of the preheater 3 are connected to the device providing the hot fluid for heat exchange to preheat the petroleum resin solution flowing through the preheater 3, so as to improve the fluidity of the petroleum resin solution. The petroleum resin solution is transported into the preheater 3 for preheating by the first fluid conveyor 1 and then transported into the coiled pipe 10; and hydrogen is transported into the coiled pipe 10 by the second fluid conveyor, so that the petroleum resin solution and hydrogen can be mixed and reacted in the coiled pipe 10. The flow rate V of the petroleum resin solution transported by the first fluid conveyor 1 and the flow rate V of the hydrogen transported by the second fluid conveyor are determined by the value of β, and through the action of the first fluid conveyor 1 and the second fluid conveyor, the flow rate V of each petroleum resin solution and the flow rate V of hydrogen are controlled to be 2.22 m / s. The specific calculation formula is as follows:

[0051] The centrifugal acceleration is G = Rω 2 (1)

[0052] The gravitational acceleration of the earth is g = 9.81 m / s 2 (2)

[0053] Ultra / micro-gravity factor

[0054] In the formula: G - centrifugal acceleration, m / s 2 ; R - radius of circular motion, that is, the radius of each turn of the coiled pipe 10, m; g - gravitational acceleration of the earth, m / s 2 ; ω - angular velocity of circular motion, that is, the angular velocity of the material moving in the coiled pipe 10, 1 / s; β - ultra / micro-gravity factor; N - rotational speed of circular motion, r / min; π - pi; V - linear velocity of circular motion, that is, the flow rate of the material in the coiled pipe 10, m / s.

[0055] Among them, β and r are known values. β takes specific numerical values to make the material in a microgravity or hypergravity state in the fluid reactor. When the centrifugal acceleration G is 1 to 50 times the gravitational acceleration g of the earth, that is, when β = 1 to 50, it is the microgravity field effect. When the centrifugal acceleration G is greater than 50 times the gravitational acceleration g of the earth, that is, when β > 50, it is the hypergravity field effect. The value of β is selected according to the viscosity, density, temperature and chemical reaction characteristics of the material. The material in the hypergravity / microgravity field forms millimeter-sized or micron-sized small droplets and small bubbles of the heterogeneous reaction material, efficiently promoting the mixing between the phases of the heterogeneous reaction material and strengthening the mass transfer process.

[0056] Specifically, the petroleum resin solution and hydrogen enter the coil 10 and are in a microgravity state, with β = 5. At this time, G = 49.05 m / s 2 , V = 2.22 m / s, which is the velocity of the petroleum resin solution and hydrogen entering the coil 102.

[0057] 2) The petroleum resin solution flowing in from the first petroleum resin solution inlet 12 and each second petroleum resin solution inlet 5, and the hydrogen flowing in from the hydrogen inlet 6 rotate circumferentially in the coil 102 to generate centrifugal force. Under the action of the centrifugal force generated by the high-speed self-rotating flow, it can overcome gravity to form a hypergravity / microgravity-micro interface field, achieving the strengthening of the mass transfer process of the reaction system. During this process, the petroleum resin solution and hydrogen are fully mixed and reacted. After the reaction is completed, the resulting reactants are discharged from the material outlet 8. During the reaction, the cold fluid enters from the first heat exchange fluid inlet 9, exchanges heat with the reaction material in the coil 10, and then flows out through the first heat exchange fluid outlet 4 to cool the reaction material in the coil 10.

[0058] Example 3

[0059] Reference Figures 1 to 3 , such as the usage method of the self-rotating hypergravity / microgravity-micro interface synergistic strengthening petroleum resin catalytic hydrogenation device in Example 1, the operation steps are as follows:

[0060] 1) The first heat exchange fluid inlet 9 and the first heat exchange fluid outlet 4 of the cylindrical heat exchanger 7 are connected to the device providing the cold fluid. The diameter of the cylindrical heat exchanger 7 is 550 mm, the length of the cylindrical heat exchanger 7 is 6000 mm, and there are 14 baffles 11 provided inside the cylindrical heat exchanger 7. The distance between two adjacent baffles 11 is 400 mm, which is used to cool the reaction material in the cooling coil 10. The pipe diameter of the coil 10 is 40 mm, the number of turns of the coil 10 is 100 turns, and the diameter of each turn of the coil 10 is 500 mm. Moreover, the second heat exchange fluid inlet 13 and the second heat exchange fluid outlet 2 of the preheater 3 are connected to the device providing the hot fluid for heat exchange to preheat the petroleum resin solution flowing through the preheater 3, thereby improving the fluidity of the petroleum resin solution. The petroleum resin solution is transported to the preheater 3 for preheating by the first fluid conveyor 1 and then transported into the coil 10; and hydrogen is transported into the coil 10 by the second fluid conveyor so that the petroleum resin solution and hydrogen can be mixed and reacted in the coil 10. The flow rate V of the petroleum resin solution transported by the first fluid conveyor 1 and the flow rate V of the hydrogen transported by the second fluid conveyor are determined by the value of β. Through the functions of the first fluid conveyor 1 and the second fluid conveyor, the flow rate V of each petroleum resin solution and the flow rate V of hydrogen are controlled to be 10.54 m / s. The specific calculation formula is as follows:

[0061] The centrifugal acceleration is G = Rω 2 (1)

[0062] The acceleration of gravity of the earth is g = 9.81 m / s 2 (2)

[0063] Super / micro gravity factor

[0064] In the formula: G - centrifugal acceleration, m / s 2 ; R - radius of circular motion, that is, the radius of each turn of the coil 10, m; g - acceleration of gravity of the earth, m / s 2 ; ω - angular velocity of circular motion, that is, the angular velocity of the material moving in the coil 10, 1 / s; β - super / micro gravity factor; N - rotational speed of circular motion, r / min; π - pi; V - linear velocity of circular motion, that is, the flow rate of the material in the coil 10, m / s.

[0065] Among them, β and r are known values. β takes specific numerical values to make the material in a microgravity or hypergravity state in the fluid reactor. When the centrifugal acceleration G is 1 to 50 times the gravitational acceleration g of the earth, that is, when β = 1 to 50, it is the microgravity field effect. When the centrifugal acceleration G is greater than 50 times the gravitational acceleration g of the earth, that is, when β > 50, it is the hypergravity field effect. The value of β is selected according to the viscosity, density, temperature and chemical reaction characteristics of the material. The material in the hyper / microgravity field forms millimeter-sized or micron-sized small droplets and small bubbles of the heterogeneous reaction material, efficiently promoting the mixing between the phases of the heterogeneous reaction material and strengthening the transfer process.

[0066] Specifically, the petroleum resin solution and hydrogen enter the coil 10 and are in a microgravity state, with β = 45. At this time, G = 441.45 m / s 2 , V = 10.54 m / s, which is the speed of the petroleum resin solution and hydrogen entering the coil 102.

[0067] 2) The petroleum resin solution flowing in from the first petroleum resin solution inlet 12 and each second petroleum resin solution inlet 5, and the hydrogen flowing in from the hydrogen inlet 6 rotate circumferentially in the coil 102 to generate centrifugal force. Under the action of the centrifugal force generated by the high-speed self-rotating flow, it can overcome gravity to form a hyper / microgravity-micro interface field, achieving the strengthening of the transfer process of the reaction system. And during this process, the petroleum resin solution and hydrogen are fully mixed and reacted. After the reaction is completed, the obtained reactants are discharged from the material outlet 8. During the reaction, the cold fluid enters from the first heat exchange fluid inlet 9, exchanges heat with the reaction material in the coil 10, and then flows out through the first heat exchange fluid outlet 4 to cool the reaction material in the coil 10.

[0068] Example 4

[0069] Reference Figures 1 to 3 , such as the usage method of the self-rotating hyper / microgravity-micro interface synergistic strengthening petroleum resin catalytic hydrogenation device in Example 1, the operation steps are as follows:

[0070] 1) The first heat exchange fluid inlet 9 and the first heat exchange fluid outlet 4 of the cylindrical heat exchanger 7 are connected to a device that provides a cold fluid. The diameter of the cylindrical heat exchanger 7 is 960 mm, and the length of the cylindrical heat exchanger 7 is 35000 mm. There are 69 baffles 11 inside the cylindrical heat exchanger 7, and the distance between two adjacent baffles 11 is 500 mm, which is used to cool the reaction material in the cooling coil 10. The pipe diameter of the coil 10 is 10 mm, the number of turns of the coil 10 is 400 turns, and the diameter of each turn of the coil 10 is 900 mm. Moreover, the second heat exchange fluid inlet 13 and the second heat exchange fluid outlet 2 of the preheater 3 are connected to a device that provides a hot fluid for heat exchange to preheat the petroleum resin solution flowing through the preheater 3, thereby improving the fluidity of the petroleum resin solution. The petroleum resin solution is transported to the preheater 3 for preheating by the first fluid conveyor 1 and then transported into the coil 10; and hydrogen is transported into the coil 10 by the second fluid conveyor so that the petroleum resin solution and hydrogen can be mixed and reacted in the coil 10. The flow rate V of the petroleum resin solution transported by the first fluid conveyor 1 and the flow rate V of the hydrogen transported by the second fluid conveyor are determined by the value of β. Through the action of the first fluid conveyor 1 and the second fluid conveyor, the flow rate V of each petroleum resin solution and the flow rate V of hydrogen are controlled to be 17.63 m / s. The specific calculation formula is as follows:

[0071] The centrifugal acceleration is G = Rω 2 (1)

[0072] The acceleration of gravity of the earth is g = 9.81 m / s 2 (2)

[0073] Ultra / micro gravity factor

[0074] In the formula: G - centrifugal acceleration, m / s 2 ; R - radius of circular motion, that is, the radius of each turn of the coil 10, m; g - acceleration of gravity of the earth, m / s 2 ; ω - angular velocity of circular motion, that is, the angular velocity of the material moving in the coil 10, 1 / s; β - ultra / micro gravity factor; N - rotational speed of circular motion, r / min; π - pi; V - linear velocity of circular motion, that is, the flow rate of the material in the coil 10, m / s.

[0075] Among them, β and r are known values. β takes specific numerical values to make the material in a microgravity or hypergravity state in the fluid reactor. When the centrifugal acceleration G is 1 to 50 times the acceleration of gravity g of the earth, that is, when β = 1 to 50, it is a microgravity field effect. When the centrifugal acceleration G is greater than 50 times the acceleration of gravity g of the earth, that is, when β > 50, it is a hypergravity field effect. The value of β is selected according to the viscosity, density, temperature and chemical reaction characteristics of the material. The material in the hyper / microgravity field makes the heterogeneous reaction materials form millimeter-sized or micron-sized small droplets and small bubbles, efficiently promoting the mixing between the phases of the heterogeneous reaction materials and strengthening the transfer process.

[0076] Specifically, the petroleum resin solution and hydrogen enter the coil 10 and are in a hypergravity state, with β = 70. At this time, G = 686.7 m / s 2 , V = 17.63 m / s, which is the velocity of the petroleum resin solution and hydrogen entering the coil 102.

[0077] 2) The petroleum resin solution flowing in from the first petroleum resin solution inlet 12 and each second petroleum resin solution inlet 5, and the hydrogen flowing in from the hydrogen inlet 6 rotate circumferentially in the coil 102 to generate centrifugal force. Under the action of the centrifugal force generated by the high-speed self-rotating flow, it can overcome gravity to form a hyper / microgravity-micro interface field, achieving the strengthening of the transfer process of the reaction system. And during this process, the petroleum resin solution and hydrogen are fully mixed and reacted. After the reaction is completed, the obtained reactants are discharged from the material outlet 8. During the reaction, the cold fluid enters from the first heat exchange fluid inlet 9, exchanges heat with the reaction material in the coil 10, and then flows out through the first heat exchange fluid outlet 4 to cool the reaction material in the coil 10.

[0078] Example 5

[0079] Reference Figures 1 to 3 , such as the usage method of the self-rotating hyper / microgravity-micro interface synergistic strengthening petroleum resin catalytic hydrogenation device in Example 1, the operation steps are as follows:

[0080] 1) The first heat exchange fluid inlet 9 and the first heat exchange fluid outlet 4 of the cylindrical heat exchanger 7 are connected to the device that provides the cold fluid. The diameter of the cylindrical heat exchanger 7 is 1250 mm, and the length of the cylindrical heat exchanger 7 is 5000 mm. There are 9 baffles 11 inside the cylindrical heat exchanger 7, and the distance between adjacent two baffles 11 is 500 mm, which is used to cool the reaction material in the cooling coil 10. The pipe diameter of the coil 10 is 100 mm, the number of turns of the coil 10 is 30 turns, and the diameter of each turn of the coil 10 is 1200 mm. Moreover, the second heat exchange fluid inlet 13 and the second heat exchange fluid outlet 2 of the preheater 3 are connected to the device that provides the hot fluid for heat exchange to preheat the petroleum resin solution flowing through the preheater 3, thereby improving the fluidity of the petroleum resin solution. The petroleum resin solution is transported to the preheater 3 for preheating by the first fluid conveyor 1 and then transported into the coil 10; and hydrogen is transported into the coil 10 by the second fluid conveyor so that the petroleum resin solution and hydrogen can be mixed and reacted in the coil 10. The flow rate V of the petroleum resin solution transported by the first fluid conveyor 1 and the flow rate V of the hydrogen transported by the second fluid conveyor are determined by the value of β. Through the action of the first fluid conveyor 1 and the second fluid conveyor, the flow rate V of each petroleum resin solution and the flow rate V of hydrogen are controlled to be 26.6 m / s. The specific calculation formula is as follows:

[0081] The centrifugal acceleration is G = Rω 2 (1)

[0082] The acceleration of gravity of the earth is g = 9.81 m / s 2 (2)

[0083] Ultra / micro gravity factor

[0084] In the formula: G - centrifugal acceleration, m / s 2 ; R - radius of circular motion, that is, the radius of each turn of the coil 10, m; g - acceleration of gravity of the earth, m / s 2 ; ω - angular velocity of circular motion, that is, the angular velocity of the material moving in the coil 10, 1 / s; β - ultra / micro gravity factor; N - rotational speed of circular motion, r / min; π - pi; V - linear velocity of circular motion, that is, the flow rate of the material in the coil 10, m / s.

[0085] Among them, β and r are known values. β takes specific numerical values to make the material in a microgravity or hypergravity state in the fluid reactor. When the centrifugal acceleration G is 1 to 50 times the gravitational acceleration g of the earth, that is, β = 1 to 50, it is the microgravity field effect. When the centrifugal acceleration G is greater than 50 times the gravitational acceleration g of the earth, that is, β > 50, it is the hypergravity field effect. The value of β is selected according to the viscosity, density, temperature and chemical reaction characteristics of the material. The material in the hyper / microgravity field makes the heterogeneous reaction materials form millimeter-sized or micron-sized small droplets and small bubbles, efficiently promoting the mixing between the heterogeneous reaction material phases and strengthening the transfer process.

[0086] Specifically, the petroleum resin solution and hydrogen enter the coil 10 and are in a hypergravity state, and β = 120. At this time, G = 1177.2 m / s 2 , V = 26.6 m / s, which is the speed of the petroleum resin solution and hydrogen entering the coil 102.

[0087] 2) The petroleum resin solution flowing in from the first petroleum resin solution inlet 12 and each second petroleum resin solution inlet 5, and the hydrogen flowing in from the hydrogen inlet 6 rotate circumferentially in the coil 102 to generate centrifugal force. Under the action of the centrifugal force generated by the high-speed self-rotating flow, it can overcome gravity to form a hyper / microgravity-micro interface field, achieving the strengthening of the transfer process of the reaction system. And in this process, the petroleum resin solution and hydrogen are fully mixed and reacted. After the reaction is completed, the obtained reactants are discharged from the material outlet 8. During the reaction, the cold fluid enters from the first heat exchange fluid inlet 9, exchanges heat with the reaction material in the coil 10, and then flows out through the first heat exchange fluid outlet 4 to cool the reaction material in the coil 10.

[0088] The above description of the specific exemplary embodiments of the present invention is for the purpose of illustration and exemplification. These descriptions are not intended to limit the present invention to the precise form disclosed, and obviously, many changes and variations can be made according to the above teachings. The purpose of selecting and describing the exemplary embodiments is to explain the specific principles of the present invention and its practical applications, so that those skilled in the art can implement and utilize various different exemplary embodiments of the present invention, as well as various different selections and changes. The scope of the present invention is intended to be defined by the claims and their equivalents.

Claims

1. A self-rotating super / microgravity-microinterface synergistically enhanced petroleum resin catalytic hydrogenation device, characterized in that: include: A cylindrical heat exchanger having a first petroleum resin solution inlet and a material outlet on its left and right ends, respectively; a first heat exchange fluid inlet and a first heat exchange fluid outlet on its left and right sides, respectively; at least two second petroleum resin solution inlets spaced apart on the sidewall of the cylindrical heat exchanger; and at least three hydrogen inlets spaced apart on the sidewall of the cylindrical heat exchanger; the cylindrical heat exchanger having a diameter of 70 mm to 1250 mm and a length of 500 mm to 60,000 mm; A coil-type reactor, comprising a coil, the coil being cylindrical and spiral-shaped, located within the cylindrical heat exchanger, with the axis of the coil extending in the left-right direction; the left end of the coil being connected to the first petroleum resin solution inlet, and the right end of the coil being connected to the material outlet; the coil being provided with two first material ports along its length, each connected to one of the second petroleum resin solution inlets, and three second material ports along its length, each connected to one of the hydrogen inlets; the coil having a diameter of 3 mm to 100 mm, the number of coil turns being 1 to 500, and the diameter of each coil being 50 mm to 1200 mm; A preheater having a second heat exchange fluid inlet and a second heat exchange fluid outlet on its side wall, wherein the outlet of the material channel of the preheater is respectively connected to the first petroleum resin solution inlet and each of the second petroleum resin solution inlets; a first fluid conveyor, which is in communication with the inlet of the material channel of the preheater and is used to convey the petroleum resin solution into the preheater; as well as A second fluid conveyor is communicated with each of the hydrogen inlets, and is used for conveying hydrogen into the coil.

2. The self-rotating super / microgravity-microinterface synergistically enhanced petroleum resin catalytic hydrogenation device according to claim 1, characterized in that: Two of the hydrogen inlets are located above the cylindrical heat exchanger, and the other hydrogen inlet is located below the cylindrical heat exchanger; one of the second petroleum resin solution inlets is located above the cylindrical heat exchanger and between the two hydrogen inlets, and the other second petroleum resin solution inlet is located to the left of the hydrogen inlet below the cylindrical heat exchanger.

3. The self-rotating super / microgravity-microinterface synergistically enhanced petroleum resin catalytic hydrogenation device according to claim 1, characterized in that: Two upper and lower rows of baffle groups are provided in the cylindrical heat exchanger. Each row of the baffle groups includes a plurality of baffles spaced apart along the left-right direction, and the baffles of the two rows of the baffle groups are staggered with each other.

4. The self-rotating super / microgravity-microinterface synergistically enhanced petroleum resin catalytic hydrogenation device according to claim 3, characterized in that: The distance between two adjacent baffles is 50 mm to 500 mm.

5. A method for using the self-rotating super / microgravity-microinterface synergistically enhanced petroleum resin catalytic hydrogenation device according to claim 1, characterized in that: The following steps are involved: 1) The first heat exchange fluid inlet and the first heat exchange fluid outlet of the cylindrical heat exchanger are connected to a device for providing a cold fluid, and the second heat exchange fluid inlet and the second heat exchange fluid outlet of the preheater are connected to a device for providing a hot fluid for heat exchange; the petroleum resin solution is transported to the preheater for preheating through the first fluid conveyor and then transported to the coil; and transporting hydrogen into the coil via a second fluid conveyor; 2) The petroleum resin solution flowing in from the first petroleum resin solution inlet and each second petroleum resin solution inlet, and the hydrogen flowing in from the hydrogen inlet, are mixed and reacted in the coil.

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