Infrared heat shielding type rare earth hafnate-based composite ceramic coating material and preparation method thereof

By introducing spinel-structured oxide dispersed phases into rare earth hafnium-based ceramic materials, an infrared heat-shielding composite ceramic coating was prepared, solving the problem that rare earth hafnium-based ceramics do not shield against infrared thermal radiation, and realizing a ceramic coating material with low thermal conductivity and high infrared heat shielding performance.

CN119330728BActive Publication Date: 2025-11-21HARBIN INST OF TECH
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Patent Information

Application Number
CN202411468448.6
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-10-21
Publication Date
2025-11-21
Estimated Expiration
2044-10-21

AI Technical Summary

Technical Problem

Existing rare earth hafnium salt ceramic materials do not have a shielding effect against infrared thermal radiation, which causes the thermal barrier coating to be penetrated by infrared thermal radiation at high temperatures, and the metal substrate is directly heated by radiation, reducing the service life of the coating material.

Method used

Infrared heat shielding composite ceramic coating materials were prepared by introducing spinel-structured oxides as dispersed phases into rare earth hafnium salt-based phases. The high infrared absorption and emissivity of the dispersed phases were utilized, and the distribution and size of the dispersed phases were controlled by solid-state sintering to enhance the infrared heat shielding performance.

Benefits of technology

It achieves low thermal conductivity (less than 2 W/(m·K) in the 25-800℃ range, high infrared emissivity (greater than 0.85) in the 2.5-14μm band, high absorptivity (greater than 0.8) in the 200-2500nm band, and low transmittance (less than 0.002) in the 400-2500nm band, thereby improving the infrared thermal shielding performance and stability of the material.

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Abstract

The application discloses an infrared heat shielding type rare earth hafnate-based composite ceramic coating material and a preparation method thereof, and belongs to the technical field of thermal barrier coating materials.The application aims to solve the problem that the existing rare earth hafnate ceramic material mainly in pyrochlore / defect fluorite structure has the advantages of low thermal conductivity and high temperature phase stability, but does not have shielding effect on infrared heat radiation, the prepared thermal barrier coating is penetrated by infrared heat radiation at high temperature, the metal substrate is directly radiated and heated, and the working life of the coating material is reduced.The spinel structure ceramic with low infrared transmittance, high infrared emissivity and high infrared absorptivity is used as a dispersed phase to modify the rare earth hafnate-based phase ceramic with pyrochlore / defect fluorite structure, and an infrared heat shielding type composite ceramic coating material with low thermal conductivity, high temperature phase stability and ultralow infrared transmittance is prepared, and the material has a good application prospect.
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