Precision administration devices and compositions

Abstract

A composition, the composition comprising: an agrochemical; dingyou glue; and a carrier fluid, where the diidine gum is present in an amount of from 0.001% to 2% by weight, where the carrier fluid comprises water and is present in an amount of from 65% to 95% by weight.

Description

[0001] The present invention relates to an agrochemical composition, a precision application device containing the composition and the use thereof.

[0002] Agrochemicals are biologically active materials, such as herbicides used by farmers and growers to control weeds and fungicides and insecticides used to control insects and fungal pests in, on or around their crops. Typically, agrochemicals are provided as concentrates, diluted with water to form a final composition to be applied before application. Typically, the diluted composition of agrochemicals is applied by spraying. Spraying allows relatively fast coverage of large areas. Depending on the scale of application, the spray liquid can be applied manually, by a special spraying device installed on a tractor, or even by an aircraft. Conventional agrochemical spraying usually relies on the pressurized supply using a diluted agrochemical formulation to produce fan-shaped or cone-shaped fine spray droplets from a nozzle. This allows the diluted agrochemical to be uniformly applied to a relatively large area under the sweep of a sprayer.

[0003] Recently, it has been recognized that for some applications, it may be advantageous to use more targeted agrochemical applications rather than uniformly cover the entire area (such as a field). For example, if individual weeds can be identified by an automated recognition system connected to an automated application system, the system should be able to apply herbicides only to those weeds. Similarly, if individual plants infected by insects or fungi can be identified, it should be possible to treat only those infected plants with insecticides or fungicides. Alternatively, for crops grown with regular row spacing, herbicides can be applied only in the space between rows. For herbicides, this will allow the use of non-selective herbicides (herbicides that kill almost all plants) to target weeds in growing crop plants. For all types of agrochemicals, it is also possible to allow the use of agrochemicals with much lower average levels throughout the field, thereby reducing farmers' costs and reducing the amount of agrochemicals in the environment. This targeted spray application is referred to as 'precision application'.

[0004] 'Precision application' is defined as applying agrochemicals to discrete parts of a target site rather than to an entire area (broadcasting). Types of precision application include, but are not limited to, helmet / band application, variable rate application using prescription maps, and optical spot spraying. Precision application also includes this type of targeted application in non-row crop type applications, such as in-furrow application or orchard spraying. For all types of precision application, the application device will likely require specialized nozzles to more accurately guide the agrochemical product, typically these nozzles will be, but are not limited to, hydraulic nozzles or jet-type nozzles at smaller angles. The most complex of the precision application types is optical spot spraying, which includes an imaging system and an analysis system for determining the application location on top of or in place of standard application equipment.

[0005] Precision application requires a different type of spray pattern than conventional spray patterns. Precision spray, by its nature, is not intended to spread and cover a large area, but rather it must ideally land exactly where it is targeted and nowhere else. This requires a spray pattern that is a small liquid jet or fine droplets in a narrow angle fan, rather than the traditional wide angle fan or cone.

[0006] It has been found that highly accurate doses of liquid agrochemicals applied in water rather than broad spraying introduce problems. The problem is that a significant proportion of the spray liquid tends to bounce off or break off the target as small droplets and land at a distance from the target. This introduces a spread of the agrochemical so that it does not all fall exactly where it is expected, but falls additionally on neighboring plants and soil. This undermines the whole concept of precision application. If non-selective herbicides are being used to target weeds, neighboring crop plants may be damaged or killed. For any agrochemical, additional pesticides need to be applied to make up for the waste caused by the material ending up being used where it is not needed.

[0007] Because most agrochemical compositions contain surfactants and emulsifiers, the problem becomes worse. Some of these surfactants and emulsifiers are included to improve the physical or chemical stability of agrochemical concentrates or to improve and maintain the dispersion of diluted agrochemicals in spray tanks. Other surfactants and emulsifiers are included to increase the biological effect of agrochemicals by improving the ability of the dilute composition to be spread on the surface of the target plant or to penetrate the outer surface of the target plant, insect or fungus. Due to their surfactant properties, when liquid falls on the surface, such materials increase the formation of droplets and therefore make the problem of off-target movement worse. Therefore, it is highly desirable to reduce off-target movement, and we refer to it as reducing the fragmentation of composition herein.

[0008] 'Droplet breakup' is defined as the breakup of a primary droplet of nominal diameter upon impact with a surface, which subsequently results in a higher number of smaller secondary droplets that fall outside the initial impact zone. Thus, 'reduction in breakup' is defined as the percentage reduction in the total number of secondary droplets due to a change in composition or a change compared to a reference composition. Thus, there is a need for low breakup compositions and devices suitable for precision application applications.

[0009] Therefore, in a first aspect of the present invention, a composition is provided, comprising:

[0010] agricultural chemicals;

[0011] diutan gum; and

[0012] a carrier fluid, wherein the diutanol is present in an amount of 0.001% to 2% by weight,

[0013] Wherein the carrier fluid comprises water and is present in an amount of 65% to 95% by weight.

[0014] It has surprisingly been found that the composition according to the invention solves the technical challenges set out above.

[0015] Advantageously, the carrier fluid is present in an amount of 68% to 93% by weight, such as 69% to 92% by weight, 70% to 91% by weight, or 71% to 90% by weight.

[0016] Preferably, the carrier fluid comprises water in an amount of from 80% to 100% or from 80% to 99.5% by weight of the carrier fluid.

[0017] Diutan gum may be present in an amount of 0.01% to 0.20% by weight.

[0018] Advantageously, the agricultural chemical is used at the maximum use rate as indicated on the label for the active ingredient.

[0019] The agricultural chemicals may be used in an amount of 0.0001% to 25% by weight, such as 0.001% to 20% by weight, 0.01% to 5% by weight, or 6% to 15% by weight.

[0020] One or more agrochemicals or salts of agrochemicals selected from those given below are suitable for use in the present invention.

[0021] Suitable herbicides or plant growth regulators can be selected from acetochlor, acifluorfen (including acifluorfen-sodium), bensulfuron, ametryn, amitriptyline, aminopyralid, cypermethrin, atrazine, flubutyric acid-M, benquitrione, bensulfuron-methyl (including bensulfuron-methyl), bentazon, bicyclpyrone, bialaphos, bispyribac-sodium, bixlozone, herbicide, bromoxynil, butachlor, flutolan, mesotrione (including mesotrione-ethyl), chlorsulfuron (including chlorsulfuron-methyl), chlorsulfuron (including chlorsulfuron-ethyl), chlorotoluron, chlorsulfuron, cyproconazole, clacyfos, clethodim , clodinafop-butyl (including clodinafop-butyl), clomazone, clopyralid, cyclopyranil, cyclopyrimorate, cyprosulfuron, cyhalofop-butyl (including cyhalofop-butyl-butyl), 2,4-D (including its choline salt and 2-ethylhexyl ester), 2,4-DB, betaine, dicamba (including its aluminum, aminopropyl, bis-aminopropylmethyl, choline, dichloropropane, diglycolamine, dimethylamine, dimethylammonium, potassium and sodium salts), bisclorac, fluazifop-butyl, fluazifop-butyl, dimethoate, dimethoate-s-propyl, dioxopyritrione, diquat dibromide, diuron, epyrifenacil (including its aluminum, aminopropyl, bis-aminopropylmethyl, choline, dichloropropane, diglycolamine, dimethylamine, dimethylammonium, potassium and sodium salts), diclofenac, diflufenacil ... diflufenacil, dimethoate, dioxopyritrione, diquat dibromide, diuron, epyrifenacil (including its aluminum, aminopropyl, bis-aminopropylmethyl, choline, dichloropropane, diglycolamine, dimethylamine, dimethylammonium, potassium and sodium salts), diclofenac, diflufenacil, diflufenacil, dimethoate, dioxopyritrione, diquat dibromide, diuron, epyrifenacil (including its aluminum, aminopropyl, bis- l), ethofluanid, ethoxyfuran, oxazolidinone (including oxazolidinone-ethyl), fenoxasulfone, benzazol, fenquinotrione, tetrazoline, fluazifop-butyl, bispyribac, florpyrauxifen (including florpyrauxifen-benzyl), fluazifop-butyl (including fluazifop-butyl-butyl), fluazifop-butyl (including fluazifop-sodium), flufenacet, fluazifop-butyl ... Fensulfuron, foramsulfuron, glufosinate (including L-glufosinate and its ammonium salts), glyphosate (including its hydrazine, isopropyl ammonium and potassium salts), halauxifen (including halauxifen-methyl), fluazifop-p-ethyl (including fluazifop-methyl), hexazinone, hydantocidin, imazamox (including R-imazamox), imazapic, imazapic, imazamox, indazine fluazifop-p-ethyl, iodosulfuron (including iodosulfuron-methyl-sodium), iofensulfuron (including iofensulfuron-sodium), ioboxynil, isoproturon, isoxathiapiprolin, lancotrione, MCPA, MCPB,mecoprop-P, mesosulfuron (including mesosulfuron-methyl), mesotrione, metamitron, metazachlor, methizolin, isopropyl metolachlor, sulfamethoxazole, metribuzin, metsulfuron-methyl, propamide, nicosulfuron, norfadine, oxadiazine, oxasulfuron, oxyfluorfen, paraquat dichloride, pendimethalin, penoxsulam, bendiazole, picloram, pinoxaden, pretilachlor, primisulfuron-methyl, promethazine, propanil, cypermethrin, propyrisulfuron, propyrisulfuron, promethazine, procarb, prosulfuron, pyraflufen (including pyraflufen-ethyl) sulfonylurea, pyridazine, pyrimisulfan, pyroxasulfone, formosulfuron, quinclorac, clomeclorac, quizalofop-ethyl (including quizalofop-P-tefuryl), rimisoxafen, sulfonesulfuron, pyrimisoxafen, sethoxydim, simazine, metolachlor, sulfentrazone, sulfonylurea, butyrylsulfuron, tebuthion, tetflupyrolimet, thiencarbazone, thifensulfuron, Fluorosulfuron (tiafenacil), tolpyralate, benpyraclostrobin, triazone, triafamone, wild wheat chlorpyrifos, bensulfuron-methyl, bensulfuron-methyl (including bensulfuron-methyl), triclopyr, trifloxysulfuron (including trifloxysulfuron-sodium), trifludimoxazin, fluralin, flufenac, triazone, [(E)-[2-(trifluoromethyl)phenyl]methyleneamino] 2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy]benzoate, 3-(2-chloro-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro pyrimidin-1 (2H) -yl) phenyl) -5-methyl-4,5-dihydroisoxazole-5-carboxylic acid ethyl ester, 4-hydroxy-1-methoxy-5-methyl-3-[4-(trifluoromethyl)-2-pyridyl] imidazolidin-2-one, 4-hydroxy-1,5-dimethyl-3-[4-(trifluoromethyl)-2-pyridyl] imidazolidin-2-one, 5-ethoxy-4-hydroxy-1-methyl-3-[4-(trifluoromethyl)-2-pyridyl] imidazolidin-2-one, 4-hydroxy-1-methyl-3-[4-(trifluoromethyl)-2-pyridyl] imidazolidin-2-one, 4-hydroxy-1,5-dimethyl-3-[1-methyl-5-(trifluoromethyl) pyrazol-3-yl] imidazolidin-2-one,(4R) 1-(5-tert-butylisoxazol-3-yl)-4-ethoxy-5-hydroxy-3-methyl-imidazolidin-2-one, 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid (including agrochemically acceptable esters thereof, for example, 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid methyl ester, 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid prop-2-ynyl ester and 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid cyanomethyl ester), 3-ethylsulfanyl-N- (1,3,4-oxadiazol-2-yl)-5-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]pyridine-8-carboxamide, 3-(isopropylsulfanylmethyl)-N-(5-methyl-1,3,4-oxadiazol-2-yl)-5-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]pyridine-8-carboxamide, 3-(isopropylsulfonylmethyl)-N-(5-methyl-1,3,4-oxadiazol-2-yl)-5-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]pyridine-8-carboxamide, 3-(ethylsulfonylmethyl)-N-(5-methyl-1,3,4-oxadiazol-2-yl)-5-(trifluoromethyl)- [1,2,4]triazolo[4,3-a]pyridine-8-carboxamide, ethyl 2-[[3-[[3-chloro-5-fluoro-6-[3-methyl-2,6-dioxo-4-(trifluoromethyl)pyrimidin-1-yl]-2-pyridyl]oxy]acetate, 6-chloro-4-(2,7-dimethyl-1-naphthyl)-5-hydroxy-2-methyl-pyridazin-3-one, (2R)-2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridyl)oxy]propanoate, tetrahydrofuran-2-ylmethyl ester, (2R)-2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridyl)oxy]propanoic acid, 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridyl) 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridyl)oxy]propionic acid tetrahydrofuran-2-ylmethyl ester, 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridyl)oxy]propionic acid, 2-fluoro-N-(5-methyl-1,3,4-oxadiazol-2-yl)-3-[(R)-propylsulfinyl]-4-(trifluoromethyl)benzamide, 2-fluoro-N-(5-methyl-1,3,4-oxadiazol-2-yl)-3-propylsulfinyl-4-(trifluoromethyl)benzamide, 6-amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxy-phenyl)pyrimidine-4-carboxylic acid (2-fluorophenyl)methyl ester, 6-amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxy-phenyl)pyrimidine-4-carboxylic acid,3-(3-chlorophenyl)-6-(5-hydroxy-1,3-dimethyl-pyrazole-4-carbonyl)-1,5-dimethyl-quinazoline-2,4-dione, [4-[3-(3-chlorophenyl)-1,5-dimethyl-2,4-dioxo-quinazoline-6-carbonyl]-2,5-dimethyl-pyrazol-3-yl] N,N-diethylcarbamate, 2-[(E)-[2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)pyrimidin-1-yl]phenyl]methyleneamino]oxypropionic acid methyl ester, and (2R)-2-[(E)-[2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)pyrimidin-1-yl]phenyl]methyleneamino]oxypropionic acid methyl ester.

[0022] The above compounds or mixtures can also be used in combination with one or more herbicide safeners. Examples of such safeners include cloquintocet, cloquintocet (including cloquintocet-mexyl), cyclopropylsulfonamide, dichloropropyleneamine, oxadiazole (including oxadiazole-ethyl), chlorpyrifos, fluazifop, oxadiazole, isoxadiazole (including isoxadiazole-ethyl), mefenpyr (including pyrazole oxadiazole-diethyl), metcamifen and oxadionitrile.

[0023] Suitable insecticides may be selected from the group consisting of abamectin, acetamiprid, acetamiprid, acralthrin, acynonapyr, bicyclam, afoxolaner, cotton boll carb, allethrin, α-cypermethrin, cis-cypermethrin, sulfamethoxazole, cypermethrin, triazotin, sulfamethoxazole, benzyl methacrylate, benzpyrimoxan, β-cypermethrin, β-cypermethrin, bifenazate, bifenthrin, binacarb, bioallethrin, S-bioallethrin, bioresmethrin, bistrifluan, bromofenac, bromothiocarb, bromothiocarb-ethyl, buprofezin, butacarb, cadusofos, carbaryl, butacarb, cadusofos, chlorpyrifos ... Sulfadiazon, Batan, CAS No.: 1632218-00-8, CAS No.: 1808115-49-2, CAS No.: 2032403-97-5, CAS No.: 2044701-44-0, CAS No.: 2128706-05-6, CAS No.: 2095470-94-1, CAS No.: 2377084-09-6, CAS No.: 1445683-71-5, CAS No.: 2408220-94-8, CAS No.: 2408220-91-5, CAS No.: 1365070-72-9, CAS No.: 2171099-09-3, CAS No.: 2396747-83-2, CAS No. : 2133042-31-4, CAS No.: 2133042-44-9, CAS No.: 1445684-82-1, CAS No.: 1922957-45-6, CAS No.: 1922957-46-7, CAS No.: 1922957-47-8, CAS No.: 1922957-48-9, CAS No.: 2415706-16-8, CAS No.: 1594624-87-9, CAS No.: 1594637-65-6, CAS No.: 1594626-19-3, CAS No.: 1990457-52-7, CAS No.: 1990457-55-0, CAS No.: 1990457-57 -2, CAS No.: 1990457-77-6, CAS No.: 1990457-66-3, CAS No.: 1990457-85-6, CAS No.: 2220132-55-6, CAS No.: 1255091-74-7, CAS No.: RNA (potato beetle-specific recombinant double-stranded interference GS2), CAS No.: 2719848-60-7, CAS No.: 1956329-03-5, chlorantraniliprole, chlordane, chlorfenapyr, chloranil, chlorfenapyr, chlorfenapyr, clenpyr, cloethocarb, clothianidin, 2-chlorophenyl N-methylcarbamate (CPMC), benzonitrile, cyantraniliprole, cyclobromofenapyr,cyclobutrifluram, pyrethroids, cycloheximide, cytoxan, cyetpyrafen (or etpyrafen), cyfluthrin, cyhalodiamide, cyhalothrin, cypermethrin, cypermethrin, cyproflanilide, cyromazine, deltamethrin, cyprofen, chlorpyrifos, dibrom, diclorof, dichlorothiazide, fluazifop, diflubenzuron, dimpropyridaz, diclofenac, dimethoate, dimethomorph, chlorpyrifos ... Emamectin (or emamectin benzoate), d-emamectin, epsilon-momfluorothrin, epsilon-metothrin, cypermethrin, ethion, ethiprole, ethomethrin, etoxazole, fenamiphos, fenazaquin, pentothrin, fenitrothion, fenmezoditiaz, fumaric acid, fenthiocarb, fenoxycarb, cypermethrin, fenpyroximate, fenthiophos, fenthiophos, fenvalerate, fipronil, flometoquin, flonicamid, pyrimidine, fluazaindolizine, flufenoxam, flubendiamide, fluazifop, fluchloride Fluchlordiniliprole, flucitrinate, flufenoxuron, flucythrinate, fluthiamethoxam, fluthiophene, flufenoxan, flufenoxamide, flupentiofenox, flupyrimin, fluralaner, fluvalinate, fluxametamide, thiathiophene, gamma-cyhalothrin, pyrimidine, chlorfenapyr, benzyl methacrylate, heptafluthrin, hexathiazox, flufenoxan Hydrazone, imicyafos, imidacloprid, imiprodinil, indazapyroxamet, indoxacarb, iodomethane, isoprodinil, isocycloseram, isothiocarb, ivermectin, kappa-bifenthrin, kappa-tefluthrin, lambda-cyhalothrin, lepidomectin, lotilaner, chlorfenuron, metaflumizone, metaldehyde, methomyl, methomyl, methoxyfenozide, methoxyfluthrin, methomyl, cypermethrin ...Oxazosulfyl, parathion-ethyl, permethrin, phenothrin, phosphamidon, piperonyl butoxide, pirimicarb, pyrimidophos-ethyl, pyrimidophos-methyl, polyhedrosis virus, prallethrin, profenofos, profluthrin, propargyl, amitriptyline, propoxur, prothiophos, protrifenbute, pyflubumide, pymetrozine, pyrafluprole, pyridaben, pyridalyl, pyrifluquin uinazon), pyrimidine, pyrimidine, pyraclostrobin, pyrimethrin, resmethrin, sarolaner, selamectin, silafluthrin, spinosad, spinosad, spirobudifen, spirodifen, spiromesifen, spiropidion, spirotetramat, spidoxamat, sulfone cypermethrin, tebufenpyrad, tebufenpyrad, tebupirimiphos, tefluthrin, temephos, Tetrachlorvinphos, tetrachlorvinphos, tetrafluthrin, cypermethrin, flucythramide, θ-cypermethrin, thiamethoxam, thiamethoxam, thiodicarb, long-acting carb, methyl thiocarb, cypermethrin, tigolaner, tiorantraniliprole, tioxazafen, tolfenpyrad, toxaphene, tralomethrin, trafluthrin, triazophos, trichlorfon, trifluenfuronate ), chlorpyrifos, trichlorfon, triflumezopyrim, tyclopyrazoflor, ζ-cypermethrin, seaweed extracts and fermentation products derived from sugar acyl, seaweed extracts and fermentation products derived from sugar acyl (containing urea, amino acids, potassium and molybdenum and EDTA chelated manganese), seaweed extracts and fermented plant products, seaweed extracts and fermented plant products (containing plant hormones, vitamins, EDTA chelated copper, zinc, and iron), azadirachtin, Bacillus ayuzawa (Bacillus aizawai), Bacillus chitinosporus AQ746 (NRRL Accession No. B-21 618), Bacillus firmus, Bacillus kurstaki, Bacillus mycoides AQ726 (NRRL Accession No. B-21664), Bacillus pumilus (NRRL Accession No. B-30087), Bacillus pumilus AQ717 (NRRL Accession No. B-21662), Bacillus species AQ178 (ATCC Accession No. 53522),Bacillus species AQ175 (ATCC Accession No. 55608), Bacillus species AQ177 (ATCC Accession No. 55609), unspecified Bacillus subtilis, Bacillus subtilis AQ153 (ATCC Accession No. 55614), Bacillus subtilis AQ30002 (NRRL Accession No. B-50421), Bacillus subtilis AQ30004 (NRRL Accession No. B-50455), Bacillus subtilis AQ713 (NRRL Accession No. B-21661), Bacillus subtilis AQ743 (NRRL Accession No. B-21665), Bacillus thuringiensis AQ52 (NRRL Accession No. B-21619), Bacillus thuringiensis BD#32 (NRRL Accession No. B-21530), Bacillus thuringiensis subspec. kurstaki BMP 123, Beauveria bassiana, D-limonene, Granulovirus, Harpin, Helicoverpa armigera nuclear polyhedrosis virus, Heliothis cornella nuclear polyhedrosis virus, Heliothis virescens nuclear polyhedrosis virus, Helicoverpa armigera nuclear polyhedrosis virus, Metarhizium species, Muscodor albus 620 (NRRL Accession No. 30547), Muscodor roseus A3-5 (NRRL Accession No. 30548), Neem-based products, Paecilomyces fumosorum, Paecilomyces lilacinus, Pasteuria szabalensis, Pasteuria penetrantis, Pasteuria mycorrhiza, Pasteuria thornei, Pasteuria thornei, p-cymene, Plutella xylostella granulovirus, Plutella xylostella nuclear polyhedrosis virus, polyhedrosis virus, Pyrethrum, QRD 420 (terpenoid blend), QRD 452 (terpenoid blend), QRD 460 (terpenoid blend), Quillaja saponaria, Rhodococcus sphaeroides AQ719 (NRRL Accession No. B-21663), Spodoptera frugiperda nuclear polyhedrosis virus, Streptomyces flavos (NRRL Accession No. 30232), Streptomyces sp. (NRRL Accession No. B-30145), terpenoid blend, and Verticillium sp.;

[0024] an algaecide selected from the group consisting of bethoxazin, copper dioctanoate (170), copper sulfate (172), cybutryne, dichlone (1052), dichlorophen (232), endoxan (295), fentin (347), slaked lime, nabam (566), quinoclamine (714), quinonamid (1379), simazine (730), triphenyltin acetate (347) and triphenyltin hydroxide (347);

[0025] Anthelmintics selected from the group consisting of avermectin (1), fusulin (1011), doramectin, emamectin (291), emamectin benzoate (291), eprinomectin, ivermectin, milbemycinoxime, moxidectin, piperazine, selamectin, spinosad (737) and thiophanate (1435);

[0026] Avicides selected from the group consisting of chloralose (127), endrin (1122), fenthion (346), pyridin-4-amine (23) and strychnine (745);

[0027] Bactericide selected from the group consisting of: 1-hydroxy-1H-pyridine-2-thione (1222), 4-(quinoxalin-2-ylamino)benzenesulfonamide (748), 8-hydroxyquinoline sulfate (446), bronopol (97), copper dioctanoate (170), copper hydroxide (169), cresol, dichlorophen (232), disopyridine (1105), dodecine (1112), fenaminosulf (1144), formaldehyde (404), mercurophen, kasugamycin (483), kasugamycin hydrochloride hydrate (483), nickel bis(dimethyldithiocarbamate) (1308), nitrapyrin (580), octhilinone (590), oxolinic acid (606), oxytetracycline (611), potassium hydroxyquinoline sulfate (446), probenazole (658), streptomycin (744), streptomycin sesquisulfate (744), chlorpheniramine (766), and thimerosal;

[0028] A biological agent selected from the group consisting of: Adoxophyesorana GV (12), Agrobacterium radiobacterium (13), Amblyseius spp. (19), Anagrapha falcifera NPV (28), Anagrus atomus (29), Aphelinus abdominalis (33), Aphidius colemani (34), Aphidoletes aphidimyza (35), Autographa californica NPV (38), Bacillus firmus (48), Bacillus sphaericus Neide (scientific name) (49), Bacillus thuringiensis Berliner (scientific name) (51), Bacillus thuringiensis subsp. aizawai (scientific name) (51), Bacillus thuringiensis subsp. israelensis (scientific name) (51), Bacillus thuringiensis subsp. japonensis (scientific name) (51), Bacillus thuringiensis subsp. kurstaki (scientific name) (51), Bacillus thuringiensis subsp.tenebrionis (scientific name) (51), Beauveria bassiana (53), Beauveria brongniartii (54), Chrysoperla carnea (151), Cryptolaemus montrouzieri (178), Cydia pomonella GV (191), Dacnusa sibirica (212), Diglyphus isaea (254), Encarsia formosa (scientific name) (293), Eretmocerus eremicus (300), Helicoverpa zea NPV (431), Heterorhabditis bacteriophora and H.megidis (433), Hippodamia convergens (442), Leptomastix dactylopii (488), Macrolophus caliginosus (491), Mamestra brassicae NPV (494), Metaphycus helvolus (522), Metarhizium anisopliae var. acridum (scientific name) (523), Metarhizium anisopliae var. anisopliae (scientific name) (523), Neodiprion sertifer NPV and N.lecontei NPV (575), Paecilomyces spp. (596), Paecilomyces fumosoroseus (613), Phytoseiulus persimilis (644), Spodoptera exigua multicapsid multicapsid nuclear polyhedrosis virus (scientific name) (741), Steinernema bibionis (742), Steinernema carpocapsae (742), Steinernema glaseri (742), Steinernema riobrave (742), Steinernema riobravis (742), Steinernema scapterisci (742), Steinernema spp. spp.)(742), Trichogramma spp.(826), Typhlodromusoccidentalis(844) and Verticillium lecanii(848);.

[0029] A soil disinfectant selected from the group consisting of methyl iodide (542) and methyl bromide (537);

[0030] A chemosterilant selected from the group consisting of apholate, bisazir, busulfan, diflubenzuron (250), dimatif, hemel, hempa, metepa, methiotepa, methyl apholate, morzid, penfluron, tepa, thiohempa, thiotepa, tretamine and uredepa;

[0031] An insect pheromone selected from the group consisting of: (E)-dec-5-en-1-yl acetate and (E)-dec-5-en-1-ol (222), (E)-tridec-4-en-1-yl acetate (829), (E)-6-methylhept-2-en-4-ol (541), (E,Z)-tetradec-4,10-dien-1-yl acetate (779), (Z)-dodec-7-en-1-yl acetate (285), (Z)-hexadec-11-enal (436), (Z)-14-hexadec-2-enal (444), (Z)-14-hexadec-2-enal (445), (Z)-2-hexadec-11-enal (446), (Z)-6-methylhept-2-en-4-ol (541). )-1-Hexadecan-11-en-1-yl acetate (437), (Z)-1-Hexadecan-13-en-11-yn-1-yl acetate (438), (Z)-eicos-13-en-10-one (448), (Z)-tetradec-7-en-1-al (782), (Z)-tetradec-9-en-1-ol (783), (Z)-tetradec-9-en-1-yl acetate (784), (7E,9Z)-dodec-7,9-dien-1-yl acetate (283), (9Z,11 E)-tetradec-9,11-dien-1-yl acetate (780), (9Z,12E)-tetradec-9,12-dien-1-yl acetate (781), 14-methyloctadec-1-ene (545), 4-methylnonan-5-ol and 4-methylnonan-5-one (544), alpha-multistriatin, brevicomin, codlelure, codone dlemone (167), cuelure (179), disparlure (277), 1-dodecyl acetate (286), 1-dodecyl acetate (287), 1-dodecyl acetate (284), dominicalure, ethyl 4-methyloctanoate (317), eugenol, frontalin, (Alias; 1:1 mixture of (Z,E) and (Z,Z) isomers of hexadec-7,11-dien-1-yl acetate (420), baited ene mixture (421), baited ene mixture I (421), baited ene mixture II (421), baited ene mixture III (421), baited ene mixture IV (421), hexalure, ipsdienol, ipsenol, scarab sex attractant (481), lineatin, litlure, looplure, medlure, megatomoic acid, methyl eugenol)(540), muscalure(563), 1-octadecyl acetate(588), 1-octadecyl acetate(589), orfralure, oryctalure(317), ostramone, siglure, sordidin(736), sulcatol, 1-tetradecyl acetate(785), trimedlure(839), trimedlure A(839), trimedlure B1(839), trimedlure B2(839), trimedlure C(839) and trunc-call;

[0032] An insect repellent selected from the group consisting of 2-(octylthio)ethanol (591), butopyronoxyl (933), butoxy(polypropylene glycol) (936), dibutyl adipate (1046), dibutyl phthalate (1047), dibutyl succinate (1048), DEET, dimethyl carbate, dimethyl phthalate, ethyl hexanediol (1137), hexylurea, methoquin-butyl (1276), methyl neodecylamide, oxamate and picaridin;

[0033] Molluscicides selected from the group consisting of: di(tributyltin) oxide (913), bromoacetamide, calcium arsenate, chloranil (999), copper acetoarsenite, copper sulfate (172), triphenyltin (347), iron phosphate (352), metaldehyde (518), methiocarb (530), niclosamide (576), niclosamide-ethanolamine (576), pentachlorophenol (623), sodium pentachlorophenoxide (623), tazimcarb (1412), thiodicarb (799), tributyltin oxide (913), trifenmorph (1454), trimethacarb (840), triphenyltin acetate (347) and triphenyltin hydroxide (347), pyriprole [394730-71-3];

[0034] Nematicides selected from the group consisting of: AKD-3088 (compound code), 1,2-dibromo-3-chloropropane (1045), 1,2-dichloropropane (IUPAC / Chemical Abstracts name) (1062), 1,2-dichloropropane and 1,3-dichloropropene (1063), 1,3-dichloropropene (233), 3,4-dichlorotetrahydrothiophene 1,1-dioxide (1065), 3-(4-chlorophenyl)-5-methylrhodanine (980), 5-methyl-6-thioxo-1,3,5-thiadiazine-3 -acetic acid (1286), 6-isopentenylaminopurine (210), avermectin (1), acetothionil, cotton boll carb (15), aldicarb (16), aldicarb (863), AZ60541 (compound code), benclothiaz, benomyl (62), butyl pyridaben, chlorpyrifos (109), carbofuran (118), carbon disulfide (945), carbofuran butylsulfuron (119), chloropicrin (141), chlorpyrifos (145) , dimethoate (999), cytokinin (210), dazomethane (216), DBCP (1045), DCIP (218), diamidafos (1044), dimethoate (1051), dicliphos, dimethoate (262), doramectin, emamectin (291), emamectin benzoate (291), eprinomectin, ethoprophos (312), dibromoethane (316), fenamiphos (326), fenpyrad, fensulfophos (1158), thiazole Phosphorus (408), butyric acid cyclohexane (1196), furfural, GY-81 (research code) (423), cypermethrin, methyl iodide (542), isamidophos (1230), chlorfenapyr (1231), ivermectin, kinetin (210), methyl aphidone (1258), metamectin (519), metamectin potassium salt (519), metamectin sodium salt (519), methyl bromide (537), methyl isothiocyanate (543), milbemycin oxime, moxidectin, Myrothecium verrucosum verrucaria) combination (565), NC-184 (compound code), oxamyl (602), phorate (636), phosphamidon (639), phosphamidon, cypermethrin, selamectin, spinosad (737), terbucarb, terbufos (773), tetrachlorothiophene (IUPAC / Chemical Abstracts name) (1422), thiafenox, cypermethrin (1434), triazophos (820), triazuron, xylenol, YI-5302 (compound code) and zeatin (210), fluensulfone [318290-98-1], fluopyram;

[0035] A nitrification inhibitor selected from the group consisting of potassium ethylxanthate and nitrapyrin (580);

[0036] A plant activator selected from the group consisting of acibenzolar (6), acibenzolar-S-methyl (6), probenazole (658) and Reynoutria sachalinensis extract (720);

[0037] Rodenticide, which is selected from the following substance group: 2-isovaleryl indane-1,3-dione (1246), 4-(quinoxalin-2-ylamino) benzenesulfonamide (748), α-chlorohydrin, aluminum phosphide (640), anto (880), arsenic trioxide (882), barium carbonate (891), bifenthrin (912), brodifacoum (89), bromadiolone (or α-bromadiolone), bromofacitin (92), calcium cyanide (444), chloralose (127), chlorfaxine (140), cholecalciferol (850), chlorfenapyr (1004), chlorfenapyr (1005), chlorfenapyr (175), chlorfenapyr (1009), chlorfenapyr (246), thiazolin (249), difacoum (2 73), calciferol (301), fludioxaline (357), fluoroacetamide (379), fludioxaline (1183), fludioxaline hydrochloride (1183), γ-HCH (430), HCH (430), hydrogen cyanide (444), methyl iodide (542), lindane (430), magnesium phosphide (640), methyl bromide (537), fosfomycin (1318), fosfomycin (1336), phosphine (640), phosphorus, fosfomycin (1341), potassium arsenite, fosfomycin (1371), scilla glycoside (1390), sodium arsenite, sodium cyanide (444), sodium fluoroacetate (735), strychnine (745), thallium sulfate, fosfomycin (851) and zinc phosphide (640);

[0038] A synergist selected from the group consisting of 2-(2-butoxyethoxy)ethyl piperate (934), 5-(1,3-benzodioxol-5-yl)-3-hexylcyclohex-2-enone (903), farnesol with nerolidol (324), MB-599 (research code) (498), MGK 264 (research code) (296), piperonyl butoxide (649), pipertal (1343), propyl isomer (1358), S421 (research code) (724), sesamex (1393), sesasmolin (1394) and sulfoxide (1406),

[0039] An animal repellent selected from the group consisting of anthraquinone (32), chloralose (127), copper cyclopentaneate, copper oxychloride (171), diazinon (227), dicyclopentadiene (chemical name) (1069), guazatine (422), guazatine acetate (422), methiocarb (530), pyridin-4-amine (23), salamine (804), trimethacarb (840), zinc cyclopentaneate and ziram (856);

[0040] a virucidal agent selected from the group consisting of imimanin and ribavirin;

[0041] A wound protection agent selected from the group consisting of mercuric oxide (512), octhilinone (590) and thiophanate-methyl (802);

[0042] Biologically active substances selected from 1,1-bis(4-chloro-phenyl)-2-ethoxyethanol, 2,4-dichlorophenyl benzenesulfonate, 2-fluoro-N-methyl-N-1-naphthylacetamide, 4-chlorophenyl phenyl sulfone, acetothionil, aldicarb, sagofos, fomanphos, amine oxalate, ammonium oxalate, amitraz, cypermethrin, arsenic trioxide, azobenzene, azophos, benomyl, benoxafos, benzyl benzoate, bixafenthion, bromomethrin , bromophenic acid, bromothion, bromopyralid, buprofezin, butanone carbendazim, butanone sulfone carbendazim, butyl pyridaben, calcium polysulfide, octachlorocamphene, chlormethoxam, trithion, cypermethrin, cypermethrin, cypermethrin hydrochloride, cypermethrin, cypermethrin, chlorpyrifos, chlormebuform, chlormebuform hydrochloride, chlorfenapyr, chlorfenapyr, chlorfenapyr, ethyl chlorfenapyr, chlormebuform (chloromebuform), chlorfenapyr, propyl chlorfenapyr, chlorfenapyr, cypermethrin I, cypermethrin II, cypermethrin, closantel, coumaphos, crotamiton, baclofos, Thiazolin, chlorfenapyr, DCPM, DDT, dinex, dinex-O, dinex-S, demeton-methyl, demeton-O, demeton-O-methyl, demeton-S, demeton-S-methyl, demeton-S-methyl, demeton-S-methyl, demeton-S-methyl, chlorfenapyr, dichlorvos, dicliphos, chlorfenapyr, chlorfenapyr, dinex, dinex-diclexine, diclofenac -4, dimethoate-6, ortho-dimethoate, nitropentyl, nitrooctyl ester acaricide, nitrobutyl ester, dimethoate, sulfodiphenyl, dithiosulfuron, DNOC, dofenapyn, doramectin, indolephos, eprinomectin, thiophos, ethidium, anti-mite azole, fenbutatin, fenthiocarb, fenpyrad, fenpyraclostrobin, aminopyraclostrobin, fentrifanil, fluazifop, flufenoxuron, fluazifop, flufenoxam, FMC 1137, fenthion, fenthion hydrochloride, formparanate, γ-HCH, chloranil, benzyl chloranil, hexadecyl cyclopropanecarboxylate, isothiocarb, jasmonate I, jasmonate II, iodine, lindane, propanil, cypermethrin, dithiophos, methylthiophene, cypermethrin, methyl bromide, cypermethrin, chloranil, milbemid, propylamine, monocrotophos, malathion, moxidectin, naled, 4-chloro-2-(2-chloro-2-methyl-propyl)-5-[(6-iodo-3 -pyridyl)methoxy]pyridazine-3-one, fluazifop, nikkomycin, pentocyanamide, pentocyanamide 1:1 zinc chloride complex, omethoate, isothiocarb, sulfone, pp'-DDT, parathion, permethrin, fenthion, phosalone, thiocyanate, phosphamidon, polychloroterpenes, polynactins, chloranil, cypermethrin, propoxur, ethidium, pyrethrin I, pyrethrin II, pyrethrin, pyridazithion, pyrimithiophos,Quinalphos, quintiofos, R-1492, glyphosate, rotenone, octamethrin, clomar, selamectin, thiothion, SSI-121, sulfluramid, sulfotep, sulfur, flumethoxine, τ-fluvalinate, TEPP, tert-butylcarb, tetrachlorothiazide, thiafenox, thiafenox, long-acting carb, methyl thiocarb, thiafenox, thiafenox, thiafenox, thiafenox, thiafenox, thiafenox, triazophos, triazuron, triclofos, triamcinolone, triazuron, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone, triamcinolone , slaked lime, sodium mancozeb, quinone, quinone, simazine, triphenyltin acetate, triphenyltin hydroxide, fosfos, piperazine, thiophanate, chloralose, fenthion, pyridine-4-amine, strychnine, 1-hydroxy-1H-pyridine-2-thione, 4-(quinoxaline-2-ylamino)benzenesulfonamide, 8-hydroxyquinoline sulfate, bronopol, copper hydroxide, cresol, disipirthion, dodesin, sodium sulfone, formaldehyde, mercurygafen, kasugamycin, kasugamycin hydrochloride hydrate, nickel di(dimethyldithiocarbamate), trichloromethylpyridine, octhiothionone, oxolinic acid, oxytetracycline, hydroxyquinoline potassium sulfate, thiabendazole, streptomycin, streptomycin sesquisulfate, chloranthate, thimerosal, cotton brown banded moth GV, radiobacterium, Amblyseius species (Amblyseius spp.), celery armyworm NPV, Anagrus atomus, Aphelinus abdominalis, Aphidius colemani, Aphidoletes aphidimyza, Spodoptera exigua NPV, Bacillus sphaericus, Beauveria brongniartii, Chrysoperla carnea, Cryptolaemus montrouzieri, Codling moth GV, Dacnusasibirica, Diglyphus isaea, Encarsia formosa, Eretmocerus eremicus, Heterorhabditis bacteriophora) and Heterorhabditis megidis, Hippodamia convergens, Leptomastix dactylopii, Macrolophus caliginosus,Cabbage armyworm NPV, Metaphycus helvolus, Metarhizium anisopliae var. acridum, Metarhizium anisopliae var. anisopliae, Neodiprionsertifer NPV and N. lecontei NPV, species of the genus Pseudomonas, Paecilomyces fumosoroseus, Phytoseiulus persimilis, Steinernema bibionis, Steinernema carpocapsae, Steinernema glaseri, Steinernema riobrave), Steinernema riobravis, Steinernema scapterisci, Steinernemas spp., Trichogramma species, Typhlodromus occidentalis, Verticillium lecanii lecanii), oxazolidinone, bis(aziridine)methylaminophosphine sulfide, busulfan, infertile amine, hexamethylmelamine, hexamethylphosphine, methyl tib, methyl thiotib, methyloxazolidinone, infertile amine, flufenuron, tib, hexamethylphosphine thioate, thiotib, trothamide, uredepa, (E)-dec-5-en-1-yl acetate and (E)-dec-5-en-1-ol, (E)-tridec-4-en-1-yl acetate, (E)-6-methylhept-2-en-4-ol, (E,Z)-tetradec-4,10-dien-1-yl acetate, (Z)-dodec-7-en-1-yl acetate, (Z)-hexadecan-11-enal, (Z)-hexadecan-11-en-1-yl acetate, (Z) -13-hexadecene-11-yn-1-yl acetate, (Z)-eicos-13-en-10-one, (Z)-tetradec-7-en-1-al, (Z)-tetradec-9-en-1-ol, (Z)-tetradec-9-en-1-yl acetate, (7E,9Z)-12dec-7,9-dien-1-yl acetate, (9Z,11E)-14dec-9,11-dien-1-yl acetate, (9Z,12E)-14dec-9,12-dien-1-yl acetate, 14-methyloctadec-1-ene, 4-methylnon-5-ol and 4-methylnon-5-one, α-polystyrene, western pine beetle aggregation pheromone, codlelure,Codlemone, cuelure, epoxy nonadecane, 1-dodecyl acetate, 1-dodecyl acetate, 1-dodecyl acetate, 1-dodecyl acetate, 1-dodecyl acetate, 1,10-dienyl acetate, domyl attractant, ethyl 4-methyloctanoate, eugenol, frontalin, eugenol mixture, eugenol mixture I, eugenol mixture II, eugenol mixture III, eugenol mixture IV, hexane attractant, eugenol ... Octadecan-2,13-dien-1-yl acetate, Octadecan-3,13-dien-1-yl acetate, Hecon, Coconut rhinoceros beetle aggregation pheromone, Feilekang, Insect trap, Sudit, Fungi-eating attractant, Tetradec-11-en-1-yl acetate, Mediterranean fruit fly attractant, Mediterranean fruit fly attractant A, Mediterranean fruit fly attractant B1, Mediterranean fruit fly attractant B2, Mediterranean fruit fly attractant C, trunc-call, 2-(octylthio)-ethanol, butopyronoxyl, butoxy (polypropylene glycol), dibutyl adipate, dibutyl phthalate, dibutyl succinate, DEET, dimethyl carbate), dimethyl phthalate, ethyl hexanediol, hexamide, methoquin-butyl, methylneodecanamide, oxamate, picaridin, 1-dichloro-1-nitroethane, 1,1-dichloro-2,2-di(4-ethylphenyl)ethane, 1,2-dichloropropane and 1,3-dichloropropylene, 1-bromo-2-chloroethane, 2,2,2-trichloro-1-(3,4-dichlorophenyl)ethyl acetate, 2-ethylsulfinylethyl methylphosphonate, 2-(1,3-dithiolan-2-yl)phenyl dimethylcarbamate, 2-(2-butoxyethyl)thiocyanate 2-(4,5-dimethyl-1,3-dioxolan-2-yl)phenyl methylcarbamate, 2-(4-chloro-3,5-xylyloxy)ethanol, 2-chlorovinyl diethyl phosphate, 2-imidazolidinone, 2-isovaleryl indan-1,3-dione, 2-methyl (prop-2-ynyl) aminophenyl methylcarbamate, 2-thiocyanatoethyl laurate, 3-bromo-1-chloroprop-1-ene, 3-methyl-1-phenylpyrazol-5-yl dimethylcarbamate, 4-methyl (prop-2-ynyl) amino-3,5-xylyl methylcarbamate, 5,5-dimethyl-3-oxocyclohex-1-enyl dimethylcarbamate, acethion, acrylonitrile, aldrin, alomycin, cypermethrin, α-decadin, aluminum phosphide, cypermethrin, neonicotinoids,Ethidathion, methyl pyrifos, Bacillus thuringiensis delta-endotoxin, barium hexafluorosilicate, barium polysulfide, fumonisin, Bayer 22 / 190, Bayer 22408, β-cyfluthrin, β-cypermethrin, bioethanomethrin, biopermethrin, bis(2-chloroethyl) ether, borax, bromophenazone, bromo-DDT, synchlorfenapyr, cypermethrin, butathiofos, butyl ester, calcium arsenate, Calcium cyanide, carbon disulfide, carbon tetrachloride, cevadine, borneol, chlordane, chlordecone, chloroform, chloropicrin, chloraniloxime, chlorprazophos, cis-resmethrin, cismethrin, clocythrin, copper acetoarsenite, copper arsenate, copper oleate, coumithoate, cryolite, CS 708, benzonitrile, cypermethrin, cypermethrin, d-methrin, DAEP, dazomethane, decarbofuran, diamidafos, isochlorothion, dimethoate, dicresyl, cypermethrin, dieldrin, diethyl 5-methylpyrazol-3-yl phosphate, dilor, tetrafluthrin, dimethoate, pyrethrin, methyl chlorpyrifos, difenocarb, propanol, pentotropol, dinofuranoside, fenthion, vegetable phosphorus, thiopyrafos, DSP, ecdysterone, EI 1642, EMPC, EPBP, etaphos, ethiobencarb, ethyl formate, ethylene dibromide, ethylene dichloride, ethylene oxide, EXD, fenthion, ethylbencarb, fenitrothion, fenoxacrim, cypermethrin, fenthion, ethylfenthion, flucofuron, butylfenthion, phosphonium arsenate, butylfenthion, furathiocarb, pyrethroid, biguanide salt, biguanide acetate, sodium tetrathiocarbonate, halfenprox, HCH, HEOD, heptachlor, thiothion, HHDN, hydrogen cyanide, quinoline carbendazim, IPSP, chlorfenapyr, carbochlorin, isodrin, Isothiophos, transplanting spirit, rice blast spirit, oxathiophos, juvenile hormone I, juvenile hormone II, juvenile hormone III, chlorpentyl, methoprene, lead arsenate, bromophenylphos, acetamiprid, thiathiophos, methylcarbamate m-isopropylphenyl ester, magnesium phosphide, phosphorus azide, methyl aphid, aphid thiophos, mercurous chloride, methyl sulfoxide, metamiprom, metamiprom potassium salt, metamiprom sodium salt, methyl sulfonyl fluoride, butylene amine, methoprene, methyl ether cypermethrin, methoxychlor, methyl isothiocyanate, methyl chloroform, dichloromethane, oxathiophene, ant killer, naphthiophos, naphthalene, NC-170, nicotine, nicotine sulfate, nithiazine, pronicotine, O-5-dichloro-4-iodophenyl O-ethylethyl phosphonothioate,O,O-diethyl O-4-methyl-2-oxo-2H-benzopyran-7-ylphosphonothioate, O,O-diethyl O-6-methyl-2-propylpyrimidin-4-ylphosphonothioate, O,O,O',O'-tetrapropyl dithiodipyrophosphate, oleic acid, p-dichlorobenzene, methyl parathion, pentachlorophenol, pentachlorophenyl laurate, PH 60-38, fenthion, parachlorothion, phosphine, methyl phoxim, methamidophos, polychlorinated dicyclopentadiene isomers, potassium arsenite, potassium thiocyanate, precocious element I, precocious element II, precocious element III, amidophos, profluthrin, fenthion, pyraclostrobin, anti-pyrethroid, quassia, quinalphos-methyl, fenthion, iodophos, resmethrin, rotenone, thiamethoxam, ryanodine, sabadilla, octamidine, clostridium, SI-000 9. Thiacrylonitrile, sodium arsenite, sodium cyanide, sodium fluoride, sodium hexafluorosilicate, sodium pentachlorophenol, sodium selenate, sodium thiocyanate, sulcofuron, sulcofuron-sodium, sulfuryl fluoride, thiopromide, tar, thiamethoxam, TDE, butylpyrimidinphos, dimethoate, cyclopentylthrin, tetrachloroethane, thiochlorvos, cyclohexane, cyclohexane oxalate, cypermethrin, cypermethrin sodium, tralomethrin, trans-permethrin, trichlorfon, trichlorfon-3 metaphos-3), chlorpyrifos, chloranil, tolprocarb, chlorpyrifos-butyl, methoprene, veratridine, veratridine, XMC, zeta-cypermethrin, zinc phosphide, tolfenphos, chlorfluanid, tetrafluanid, bis(tributyltin) oxide, bromoacetamide, iron phosphate, niclosamide-ethanolamine, tributyltin oxide, pyroximate, snail killer, 1,2-dibromo-3-chloropropane, 1,3-dichloropropylene, 3,4-dichlorotetrahydrothiophene 1, 1-dioxide, 3-(4-chlorophenyl)-5-methylrhodanine, 5-methyl-6-thio-1,3,5-thiadiazin-3-yl acetic acid, 6-isopentenylaminopurine, fluorophenyladenine, benclothiaz, cytokinin, DCIP, furfural, isamidophos, kinetin, verrucosporium mycorrhizal composition, tetrachlorothiophene, xylenol, zeatin, potassium ethylxanthate, acibenzolar, acibenzolar-S-methyl, Reynoutria sachalinensis) extract, α-chloroalcohol, antu, barium carbonate, bifenthion, brodifacoum, brodifacoum, brofenthion, chlorfenthion, cholecalciferol, chlorfenthion, chlorfenthion, chlorfenthion, chlorfenthion, chlorfenthion, chlorfenthion, chlorfenthion, chlorfenthion, calciferol, flufenthion, fluoroacetamide, flufenthion, flufenthion hydrochloride, flufenthion, chlorfenthion, phosphorus, phosphorus, flufenthion, flufenthion, chlorfenthion, chlorfenthion, chlorfenthion, chlorfenthion, sodium fluoroacetate, thallium sulfate, flufenthion,2-(2-Butoxyethoxy)ethyl piperate, 5-(1,3-benzodioxol-5-yl)-3-hexylcyclohex-2-enone, farnesol with nerolidol, synergistic acetylenic ether, MGK 264, synergistic ether, synergistic aldehyde, synergistic ester (propyl isomer), S421, Zengxiaosan, sesasmolin, sulfoxide, anthraquinone, copper cyclohexane, copper oxychloride, dicyclopentadiene, serene, zinc cyclohexane, zinc thiram, imanin, ribavirin, chloroinconazide, mercuric oxide, thiophanate-methyl, azaconazole, bifenthrin, fuconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, fenbuconazole, fluquinconazole, flusilazole, flutriafol, furopyram, hexaconazole, imazalil, imipenem, cyproconazole, metconazole, myclobutrazol, paclobutrazol, pyraclostrobin, penconazole, prothioconazole, pyrifenox, prochloraz, propiconazole , pyraconazole, simeconazole, tebuconazole, fluconazole, triadimefon, triadimenol, fluflumizole, triclosan, pyrimidine, chlorfenapyr, flufenapyr, bupirimate, dimethirimol, ethirimol, dodecacyclic morpholine, fenpropidin, fenpropimorph, spiroxaplanol, tridecamorph, cyprodinil, pyrimethanil, fenpiclonil, fludioxonil, benalaxyl, furalaxyl, metalaxyl, R-metalaxyl , furamide, oxadixyl, carbendazim, debacarb, thiabendazole, chlozolinate, dichlozoline, myclozoline, procymidone, vinclozoline, boscalid, carboxin, furamide, flutolanil, oxadixyl, penthiopyrad, thiofuran, dodine, biguanide, azoxystrobin, etherbendazole Amine, enestroburin, enestroburin, flutoxistrobin, fluoxastrobin, kresoxim-methyl, fenoxystrobin, trifloxystrobin, trifloxystrobin, picoxystrobin, pyraclostrobin, pyraclostrobin, pyraclostrobin, ferram, mancozeb, maneb, methanamide, methyl propineb, maneb, captazole, captan, azole, folpet, tolylfluanid, Bordeaux mixture, copper oxide, mancozeb, quinoline copper, phthalocyanine, kefansan, isoflavone, chlorpyrifos, methyl tolclofos, captazole, benzylpyridin, blasticidin-S, chloroneb, chlorothalonil, cyfluthrin, cymoxanil, cybutanil,diclocymet, diclomezine, dicloran, diethofencarb, dimethomorph, flumorph, dithianon, ethaboxam, etridiazole, famoxadone, fenamidone, fenoxanil, ferimzone, fluazinam, fluopicolide, fluopicolide, flusulfamide, fluopicolide, cyclopyraclostrobin oxazolidinone, fosetyl-aluminium, hymexazol, propineb, cyazofamid, methasulfocarb, mefenamic acid, pencycuron, phthalide, polyoxins, propamocarb, pyraclostrobin, proquinazid, pyroquilon, pyriofenone, quinoxyfen, pentachloronitrobenzene, thiazolamide, triazoxide, tricyclazole, triazine, validamycin, valeramide, benzoic acid zoxamide, mandipropamid, flubeneteram, isopyrazam, sedaxane, benzovinflumizone, flutoxazone, 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid (3',4',5'-trifluoro-biphenyl-2-yl)-amide, isoflurane, isoflucypram, dipymetitrone, 6-ethyl-5,7-dioxo-pyrrolo[4,5][1,4]dithiino[1,2-c]isothiazole-3-carbonitrile, 2-(difluoromethyl)- N-[3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide, 4-(2,6-difluorophenyl)-6-methyl-5-phenyl-pyridazine-3-carbonitrile, (R)-3-(difluoromethyl)-1-methyl-N-[1,1,3-trimethylindan-4-yl]pyrazole-4-carboxamide, 4-(2-bromo-4-fluoro-phenyl)-N-(2-chloro-6-fluoro-phenyl)-2,5-dimethyl-pyrazol-3-amine, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, flufenoxam, jiaxiangjunzhi, lvbenmixianan,dichlobentiazox, mandestrobin, 3-(4,4-difluoro-3,4-dihydro-3,3-dimethylisoquinolin-1-yl)quinolone, 2-[2-fluoro-6-[(8-fluoro-2-methyl-3-quinolinyl)oxy]phenyl]propan-2-ol, oxathiapiprolin, tert-butyl N-[6-[[[(1-methyltetrazol-5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridinyl]carbamate, pyraziflumid, inpyrfluxam, triflumethoate rolprocarb), chlorfenthiazol, ipfentrifluconazole, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide, N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine, N'-[4-(4,5-dichlorothiazol-2-yl)oxy-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine, [2-[3-[2-[1-[2-[3,5-bis(difluoromethyl)pyrazol-1-yl]acetyl]-4-piperidinyl]thiazol-4-yl]-4,5-dihydroisoxazole -5-yl]-3-chloro-phenyl] methanesulfonate, N-[6-[[(Z)-[(1-methyltetrazol-5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridinyl]carbamic acid but-3-ynyl ester, N-[[5-[4-(2,4-dimethylphenyl)triazol-2-yl]-2-methyl-phenyl]methyl]carbamic acid methyl ester, 3-chloro-6-methyl-5-phenyl-4-(2,4,6-trifluorophenyl)pyridazine, pyridachlometyl, 3-(difluoromethyl)-1-methyl-N-[1,1,3-trimethylindan-4-yl]pyrazole-4-carboxamide, 1-[2-[[1-(4-chlorophenyl)pyrazole oxazol-3-yl]oxymethyl]-3-methyl-phenyl]-4-methyl-tetrazol-5-one, 1-methyl-4-[3-methyl-2-[[2-methyl-4-(3,4,5-trimethylpyrazol-1-yl)phenoxy]methyl]phenyl]tetrazol-5-one, aminopyrifen, pyrazopyranil, indazolesulfazoline, fluopyrafen, (Z,2E)-5-[1-(4-chlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamine, pyridinepyramide, fenpicoxamid, pyridinepyramide, isobutylethoxyquinoline, isopropylquinoline, fluopyrafen, isopropylthiocyanate,1-[[4-[[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy]phenyl]methyl]pyrazole-3-carboxylic acid ethyl ester (can be prepared by the method described in WO2020 / 056090), 1-[[4-[(Z)-2-ethoxy-3,3,3-trifluoro-prop-1-enyloxy]phenyl]methyl]pyrazole-3-carboxylic acid ethyl ester (can be prepared by the method described in WO 2020 / 056090), N-[[4-[1-(4-cyclopropyl-2,6-difluoro-phenyl)pyrazol-4-yl]-2-methyl-phenyl]methyl]carbamic acid methyl ester (can be prepared by the method described in WO 2020 / 097012), N-[[4-[1-(2,6-difluoro-4-isopropyl-phenyl)pyrazol-4-yl]-2-methyl-phenyl]methyl]carbamic acid methyl ester (can be prepared by the method described in WO 2020 / 097012), 6-chloro-3-(3-cyclopropyl-2-fluoro-phenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoro-ethyl]-5-methyl-pyridazine-4-carboxamide (can be prepared by the method described in WO 2020 / 109391), 6-chloro-N-[2-(2-chloro-4-methyl-phenyl)-2,2-difluoro-ethyl]-3-(3-cyclopropyl-2-fluoro-phenoxy)-5-methyl-pyridazine-4-carboxamide (can be prepared by the method described in WO 2020 / 109391), 6-chloro-3-(3-cyclopropyl-2-fluoro-phenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoro-ethyl]-5-methyl-pyridazine-4-carboxamide (can be prepared by the method described in WO 2020 / 109391), N-[2-[2,4-dichloro-phenoxy]phenyl]-3-(difluoromethyl)-1-methyl-pyrazole-4-carboxamide, N-[2-[2-chloro-4-(trifluoromethyl)phenoxy]phenyl]-3-(difluoromethyl)-1-methyl-pyrazole-4-carboxamide, benzathiostrobin, cyproconazole, 5-amino-1,3,4-thiadiazole-2-thiol zinc salt (2:1), fluopyram, flufenoxadiazam, fluthiazolin, fluopyram, pyrapyrin ropoyne), picarbutrazox, 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-((3R)-1,1,3-trimethylindan-4-yl)pyridine-3-carboxamide, 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile, metyltetraprole,2-(Difluoromethyl)-N-((3R)-1,1,3-trimethylindan-4-yl)pyridine-3-carboxamide, α-(1,1-dimethylethyl)-α-[4'-(trifluoromethoxy)[1,1'-biphenyl]-4-yl]-5-pyrimidinemethanol, fluoxapiprolin, enoxastrobin, (Z)-3-methoxy-2-[2-methyl-5-[4-(trifluoromethyl)triazol-2-yl]phenoxy]prop-2-enoic acid methyl ester, (Z)-3-methyl Oxy-2-[2-methyl-5-(4-propyltriazol-2-yl)phenoxy]prop-2-enoic acid methyl ester, (Z)-2-[5-(3-isopropylpyrazol-1-yl)-2-methyl-phenoxy]-3-methoxy-prop-2-enoic acid methyl ester, (Z)-3-methoxy-2-[2-methyl-5-(3-propylpyrazol-1-yl)phenoxy]prop-2-enoic acid methyl ester, (Z)-3-methoxy-2-[2-methyl-5-[3-(trifluoromethyl)pyrazol-1-yl]phenoxy]prop-2-enoic acid methyl ester (these compounds can be prepared from WO 2020 / 079111), (Z)-2-(5-cyclohexyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoic acid methyl ester, (Z)-2-(5-cyclopentyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoic acid methyl ester (these compounds can be prepared by WO 2020 / 193387), 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile, 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile, 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-thioalkyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile, trinexapac-ethyl, syringostaril, zhongshengmycin, thiophanate-copper, thiazole zinc, amitoline (amectotractin), isopyrim, seboctylamine, N'-[5-bromo-2-methyl-6-[(1S)-1-methyl-2-propoxy-ethoxy]-3-pyridinyl]-N-ethyl-N-methyl-formamidine, N'-[5-bromo-2-methyl-6-[(1R)-1-methyl-2-propoxy-ethoxy]-3-pyridinyl]-N-ethyl-N-methyl-formamidine, N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridinyl]-N-ethyl-N-methyl-formamidine, N'-[5-chloro-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridinyl]-N-ethyl-N-methyl-formamidine,N'-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridinyl]-N-isopropyl-N-methyl-formamidine (these compounds can be prepared from WO 2015 / 155075); N'-[5-bromo-2-methyl-6-(2-propoxypropoxy)-3-pyridinyl]-N-ethyl-N-methyl-formamidine (this compound can be prepared by the method described in IPCOM000249876D); N-isopropyl-N'-[5-methoxy-2-methyl-4-(2,2,2-trifluoro-1-hydroxy-1-phenyl-ethyl)phenyl]-N-methyl-formamidine, N'-[4-(1-cyclopropyl-2,2,2-trifluoro-1-hydroxy-ethyl)-5-methoxy-2-methyl-phenyl]-N-isopropyl-N-methyl-formamidine (these compounds can be prepared by the method described in WO 2018 / 228896); N-ethyl-N'-[5-methoxy-2-methyl-4-[(2-trifluoromethyl)oxetan-2-yl]phenyl]-N-methyl-formamidine, N-ethyl-N'-[5-methoxy-2-methyl-4-[(2-trifluoromethyl)tetrahydrofuran-2-yl]phenyl]-N-methyl-formamidine (these compounds can be prepared by WO 2019 / 110427); N-[(1R)-1-benzyl-3-chloro-1-methyl-but-3-enyl]-8-fluoro-quinoline-3-carboxamide, N-[(1S)-1-benzyl-3-chloro-1-methyl-but-3-enyl]-8-fluoro-quinoline-3-carboxamide, N-[(1R)-1-benzyl-3,3,3-trifluoro-1-methyl-propyl]-8-fluoro-quinoline-3-carboxamide, N-[(1S)-1-benzyl-3,3,3-trifluoro-1-methyl-propyl]-8-fluoro-quinoline-3-carboxamide, N-[(1R)-1-benzyl-3,3,3-trifluoro-1-methyl-propyl]-8-fluoro-quinoline-3-carboxamide, N-[(1R)-1-benzyl-1,3-dimethyl-butyl]-7,8-difluoro-quinoline-3-carboxamide, N-[(1S)- 1-Benzyl-1,3-dimethyl-butyl]-7,8-difluoro-quinoline-3-carboxamide, 8-fluoro-N-[(1R)-1-[(3-fluorophenyl)methyl]-1,3-dimethyl-butyl]quinoline-3-carboxamide, 8-fluoro-N-[(1S)-1-[(3-fluorophenyl)methyl]-1,3-dimethyl-butyl]quinoline-3-carboxamide, N-[(1R)-1-benzyl-1,3-dimethyl-butyl]-8-fluoro-quinoline-3-carboxamide, N-[(1S)-1-benzyl-1,3-dimethyl-butyl]-8-fluoro-quinoline-3-carboxamide, N-((1R)-1-benzyl-3-chloro-1-methyl-but-3-enyl)-8-fluoro-quinoline-3-carboxamide,N-((1S)-1-benzyl-3-chloro-1-methyl-but-3-enyl)-8-fluoro-quinoline-3-carboxamide (these compounds can be prepared from WO 2017 / 153380); 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4,5-trifluoro-3,3-dimethyl-isoquinoline, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4,6-trifluoro-3,3-dimethyl-isoquinoline, 4,4-difluoro-3,3-dimethyl-1-(6-methylpyrazolo[1,5-a]pyridin-3-yl)isoquinoline, 4,4-difluoro-3,3-dimethyl-1-(7-methylpyrazolo[1,5-a]pyridin-3-yl)isoquinoline, 1-(6-chloro-7-methyl-pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-isoquinoline 1-(4,5-dimethylbenzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-isoquinoline, 1-(4,5-dimethylbenzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-isoquinoline, 6-chloro-4,4-difluoro-3,3-dimethyl-1-(4-methylbenzimidazol-1-yl)isoquinoline, 4,4-difluoro-1-(5-fluoro-4-methyl-benzimidazol-1-yl)-3,3-dimethyl-isoquinoline, 3-(4,4-difluoro-3,3-dimethyl-1-isoquinolyl)-7,8-dihydro-6H-cyclopenta[e]benzimidazole (these compounds can be prepared by the method described in WO2017 / 025510); 2016 / 156085); N-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]cyclopropanecarboxamide, N,2-dimethoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, N-ethyl-2-methyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, 1-methoxy-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, oxadiazol-3-yl]phenyl]methyl]urea, 1,3-dimethoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, 3-ethyl-1-methoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, 4,4-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one,5,5-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one, 1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrazole-4-carboxylic acid ethyl ester, N,N-dimethyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-1,2,4-triazol-3-amine (these compounds can be prepared from WO 2017 / 055473, WO 2017 / 055469, WO 2017 / 093348 and WO 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol (this compound can be prepared by the method described in WO 2017 / 029179); 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol (this compound can be prepared by the method described in WO 2017 / 029179); 3-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile (this compound can be prepared by the method described in WO 2-Amino-6-methyl-pyridine-3-carboxylic acid (4-phenoxyphenyl) methyl ester (this compound can be prepared by the method described in WO 2014 / 006945); 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c']bipyrrole-1,3,5,7(2H,6H)-tetraone (this compound can be prepared by the method described in WO 2011 / 138281),N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzenecarboxamide; N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide; (Z,2E)-5-[1-(2,4-dichlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamine (this compound can be prepared by the method described in WO2018 / 153707); N '-(2-chloro-5-methyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine; N'-[2-chloro-4-(2-fluorophenoxy)-5-methyl-phenyl]-N-ethyl-N-methyl-formamidine (this compound can be prepared by the method described in WO2016 / 202742); 2-(difluoromethyl)-N-[(3S)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide (this compound can be prepared by the method described in WO 2014 / 095675); (5-methyl-2-pyridyl)-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methanone, (3-methylisoxazol-5-yl)-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methanone (these compounds can be prepared by the method described in WO 2017 / 220485); 2-oxo-N-propyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]acetamide (this compound can be prepared by the method described in WO 2018 / 065414); 1-[[5-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]-2-thienyl]methyl]pyrazole-4-carboxylic acid ethyl ester (this compound can be prepared by WO 2,2-difluoro-N-methyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]acetamide, N-[(E)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, N-[(Z)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, N-[N-methoxy-C-methyl-carbonimide]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide (these compounds can be prepared by the method described in WO 2018 / 202428);

[0043] Microorganisms, including: Acinetobacter lwoffii, Acremonium fungi, Acremonium acremonium, Acremonium diospyri, Acremonium obclavatum, AdoxGV Agrobacterium radioactive strain K84 Alternaria destruens Parasitium leucophyllum Aspergillus flavus AF36 Aspergillus flavus NRRL 21882 Aspergillus species, Adenophora spp., Azospirillum, ( TAZO ), nitrogen-fixing bacteria, Azotobacter chroocuccum Bionatural Blooming ), Bacillus amyloliquefaciens, Bacillus cereus, Bacillus chitinosporus strain CM-1, Bacillus chitinosporus strain AQ746, Bacillus licheniformis strain HB-2 (Biostart TM ), Bacillus licheniformis strain 3086 ( Green ), Bacillus circulans, Bacillus firmus Bacillus firmus strain I-1582, Bacillus macerans, Bacillus marismortui, Bacillus megaterium, Bacillus mycoides strain AQ726, Bacillus lactis ), Bacillus pumilus species, Bacillus pumilus strain GB34 (Yield ), Bacillus pumilus strain AQ717, Bacillus pumilus strain QST 2808 ( Ballad ), Bacillus sphaericus Bacillus species, Bacillus strain AQ175, Bacillus strain AQ177, Bacillus strain AQ178, Bacillus subtilis strain QST 713 ( ), Bacillus subtilis strain QST 714 Bacillus subtilis strain AQ153, Bacillus subtilis strain AQ743, Bacillus subtilis strain QST3002, Bacillus subtilis strain QST3004, Bacillus subtilis amyloliquefaciens variant strain FZB24 Bacillus thuringiensis Cry 2Ae, Bacillus thuringiensis Cry1Ab, Bacillus thuringiensis aizawai GC 91 Bacillus thuringiensis israelensis Bacillus thuringiensis kurstaki ( Scutella Turilav Dipel ), Bacillus thuringiensis Kurstak BMP 123 Bacillus thuringiensis Kurstak HD-1 Bacillus thuringiensis strain BD#32, Bacillus thuringiensis strain AQ52, Bacillus thuringiensis var.aizawai Bacteria spp. Clavipacter michiganensis bacteriophage Beauveria bassiana Brocaril )、Beauveria bassiana GHA (Mycotrol Mycotrol )、Beauveria brongniartii ( Schweizer ), Beauveria spp., Botrytis cineria, Bradyrhizobium japonicum Brevibacillus brevis, Bacillus thuringiensis tenebrionis BtBooster, Burkholderia cepacia ( Blue ), Burkholderia gladii, Burkholderia gladioli, Burkholderia spp., Canadian thistle fungus (CBHCanadian ), Candida butyri, Candida famata, Candida fructus, Candida glabrata, Candida guilliermondii, Candida melibiosica, Candida oleophila strain O, Candida parapsilosis, Candida pelliculosa, Candida pulcherrima, Candida reukaufii, Candida saitoana Candida sake, Candida spp., Candida tenius, Cedecea dravisae, Cellulomonasflavigena, Chaetomium cochliodes Chaetomium globosum Chromobacterium subtsugae strain PRAA4-1T Cladosporium cladosporioides, Cladosporium oxysporum, Cladosporium chlorocephalum, Cladosporium spp., Cladosporium tenuissimum, Clonostachys rosea Colletotrichum acutatum, Coniothyrium minitans (Cotans ), Coniothyrium spp., Cryptococcus albidus Cryptococcus humicola, Cryptococcus infirmo-miniatus, Cryptococcus laurentii, Cryptophlebia leucotreta granulovirus Cupriaviduscampinensis, Cydia pomonella granulovirus Codling moth granulosis virus Madex Madex Max / ), Cylindrobasidium laeve Cylindrocladium, Debaryomyces hansenii, Drechslera hawaiinensis, Enterobacter cloacae, Enterobacteriaceae, Entomophthoravirulenta Epicoccum nigrum, Epicoccum purpurascens, Epicoccum species, Filobasidium floriforme, Fusarium acuminate, Fusarium chlamysporum, Fusarium oxysporum / Biofox ), Fusarium spp., Fusarium species, Galactomyces geotrichum, Gliocladium catenulatum Gliocladium roseum, Gliocladium species Gliocladium virens Granulovirus Halobacillus halophilus, Halobacillus litoralis, Halobacillus trueperi, Halomonas species, Halomonas subglaciescola, Halovibrio variabilis, Hansenula vinifera, Helicoverpa armigera nuclear polyhedrosis virus Spodoptera exigua nuclear polyhedrosis virus Isoflavone-Formononetin Kloeckner's yeast, Kloeckner's yeast species, Lagenidiumgiganteum Lecanicillium longisporum Lecanicillium muscarium Gypsy moth nuclear polyhedrosis virus Halococcus, Meira geulakonigii, Metarhizium anisopliae Destruxin ), Metschnikowia fruticola Metschnikowia pulcherrima, Microdochium dimerum Micromonospora coerulea, Microsphaeropsis ochracea, foul-smelling white fungus 620 Rosa foetida strain A3-5, Mycorrhizae spp. ( Root ), Verrucospora strain AARC-0255 BROS Ophiostoma piliferum strain D97 Paecilomyces farinosus, Paecilomyces fumosorum Paecilomyces lilacinus (Biostat ), Paecilomyces lilacinus strain 251 (MeloCon ), Paenibacillus polymyxa, BlightBan ), Pantoea species, Pasteurella species Pasteurianishizawae, Penicillium chrysogenum, Penicillium billai Penicillium breviscompactum, Penicillium familiale, Penicillium griseo-yellowensis, Penicillium purpurogenum, Penicillium species, Phlebiopsis gigantean Phosphate-solubilizing bacteria Phytophthora cryptogenomica, Phytophthora palmi Pichia anomala, Pichia guilermondii, Pichia membranaceus, Pichia nails, Pichia stipitis, Pseudomonas aeruginosa, Pseudomonas aureofasciens (Spot-Less ), Pseudomonas cepacia, Pseudomonas chlororaphis Pseudomonas corrugate, Pseudomonas fluorescens strain A506 ), Pseudomonas putida, Pseudomonas reactans, Pseudomonas species, Pseudomonas syringae Pseudomonas aureus, Pseudomonas fluorescens Pseudozyma flocculosa strain PF-A22 UL (Sporodex ), Puccinia canaliculata, Puccinia thlaspeos (Wood ), Pythium oligandrum, Pythium, Rhanella aquatilis, Rhanella spp., Rhizobia Rhizoctonia, Rhodococcus globerulus strain AQ719, Rhodosporidium diobovatum, Rhodosporidium toruloides, Rhodotorula spp., Rhodotorula glutinis, Rhodotorula graminis, Rhodotorula mucilagnosa, Rhodotorularubra, Saccharomyces cerevisiae, Salinococcus roseus, Sclerotinia minor, Sclerotinia minor Scytalidium spp., Scytalidium uredinicola, Spodoptera exigua nuclear polyhedrosis virus Serratia marcescens, Serratia plymuthica, Serratia spp., Sordaria fimicola, Spodoptera littoralis nucleopolyhedrovirus Sporobolomyces roseus, Stenotrophomonas maltophilia, Streptomyces ahygroscopicus, Streptomyces albaduncus, Streptomyces exfoliates, Streptomyces galbus, Streptomyces griseoplanus, Streptomyces griseoviridis Streptomyces lydicus Streptomyces lydicus WYEC-108 Streptomyces violaceus, Tilletiopsis minor, Tilletiopsis spp., Trichoderma asperellum (T34 ), Trichoderma gamsii Trichoderma atroviride Trichoderma hamatum TH382, Trichoderma harzianum rifai Trichoderma harzianum T-22( PlantShield ), Trichoderma harzianum T-39 Trichoderma inhamatum, Trichoderma koningii, Trichoderma species LC 52 Trichoderma lignorum, Trichoderma longibrachiatum, Trichoderma polysporum (Binab ), Trichoderma taxi, Trichoderma virens, Trichoderma virens (formerly known as Gliocladium virens GL-21) Trichoderma viride, Trichoderma viride strain ICC 080 Trichosporon pullulans, Trichosporon spp., Trichothecium spp., Trichothecium roseum, Typhula phacorrhiza strain 94670, Typhula phacorrhiza strain 94671, Ulocladium atrum, Ulocladium oudemansii Ustilago maydis, various bacteria and supplemental micronutrients (Natural ), various fungi (Millennium ), Verticilliumchlamydosporium, Verticillium lecanii Vip3Aa20 Virgibaclillus marismortui, Xanthomonas campestris pv. kenya Xenorhabdus burnetii, Xenorhabdus nematophila;

[0044] Plant extracts including: pine oil Azadirachtin (Plasma Neem Plant IGR Canola Oil (Lilly Miller ), Chenopodium ambrosioidesnear ambrosioides Chrysanthemum Extract Neem Oil Extract Labiatae essential oil Clove-rosemary-peppermint and thyme oil extract (Garden insect ), Betaine Garlic and lemongrass oil Neem Oil, Catnip (Nepeta cataria) (Catnip Oil), Nepeta catarina, Nicotine, Oregano Oil Pedaliaceae Oil Pyrethrum, Soapbark Tree (Quillaja saponaria) Giant knotweed (Reynoutria sachalinensis) Rotenone (Eco ), Rutaceae plant extracts Soybean oil (Ortho ), tea tree oil (Timorex ), thyme oil, MMF, Rosemary-Sesame-Peppermint-Thyme and Cinnamon Extract Blend (EF ), clove-rosemary and peppermint extract blend (EF ), Clove-Peppermint-Garlic Oil and Mint Blend (Soil ), Kaolin Storage Glucans from Brown Algae

[0045] Pheromones, including: 3M Sprayable Blackheaded Fireworm ), codling moth pheromone (Paramount dispenser-(CM) / Isomate ), Grape leaf roller pheromone (3MMEC-GBM Sprayable ), leaf roller pheromone (3M MEC-LRSprayable )、Muscamone(Snip7Fly Starbar PremiumFly ), 3M oriental fruit moth sprayable ), Peachtree Borer pheromone Tomato Pinworm Pheromone (3M Sprayable ), Entostat powder (extract from palm trees) (Exosex )、(E,Z,Z)-3,8,11-tetradecatrienyl acetate、(Z,Z,E)-7,11,13-hexadecatrienal、(E,Z)-7,9-dodecadien-1-yl acetate、2-methyl-1-butanol、calcium acetate、 Lavandulylsenecioate;

[0046] Macrobial agents, including: Aphidius ervi, Aphidius ervi Acerophagus papaya, two-spotted ladybird Two-spotted ladybug Two-spotted ladybug Ageniaspiscitricola, Amblyseius andersoni Amblyseius californicus Amblyseius cucumeris Bugline ), Pseudoseiidae Bugline Amblyseius ostreatus Amitus hesperidum, Anagrus atomus, Anagyrus fusciventris, Anagyrus kamali, Anagyrus loecki, Anagyrus pseudococci Anicetus benefices, Anisopteromalus calandrae, Anthocoris nemoralis Aphididae Aphelinus asychis, Aphidius colemani Aphidida albicans Aphidida cirrhosae, Aphidida spp. Aphid midge Aphid midge Lingnan yellow aphid wasp, Indian yellow aphid wasp, Aprostocetus hagenowii, Atheta coriaria Bombus species, European bumblebee (Natupol ), European Bombus Cephalonomia stephanoderis, Chilocorus nigritus, Chrysoperla carnea Common lacewings Chrysoperla rufilabris, Cirrospilus ingenuus, Cirrospilus quadristriatus, Citrostichusphyllocnistoides, Closterocerus chamaeleon, species of Closterocerus, Coccidoxenoides perminutus Coccophagus cowperi, Coccophagus lycimnia, Coccophagus lycimnia, Coccophagus lycimnia, Coccophagus lycimnia, Coccophagus lycimnia Japanese square-headed beetle, Siberian ceratosaurus, Siberian ceratosaurus Pea leafminer Small black ladybug (Delphastuscatalinae) Delphastus pusillus, Diachasmimorpha krausii, Diaparsis jucunda, Diaphorencyrtus aligarhensis, Diaphorencyrtus sphaeroides, Diaphorencyrtus sphaeroides Ceratognathus sibirica Species of the genus Encarsia, Encarsia spp. ), Eretmoceruseremicus Encarsia guadeloupae, Encarsia haitiensis, Encarsia guadeloupae Eretmoceris siphonini, Eretmocerus californicus, Eretmocerus eremicus ( Eretline ), Eretmocerus eremicus Henri's aphid wasp, Monroe's aphid wasp ( Eretline ), Eretmocerus siphonini, Exochomus quadripustulatus, Feltiella acarisuga Gall midge Alishan flyminer, Fopius ceratitivorus, Wirless ), Slender-waisted Thrips Galendromus occidentalis, Goniozus legneri, Galendromus occidentalis, Harmonia axyridis Heterorhabditis spp. (Lawn ), Heterorhabditis elegans (NemaShield

[0047] ), Heterorhabditis megidis (Nemasys BioNem Exhibitline )、Hippodamia convergens)、Hypoaspis aculeifer( ), Hypoaspis miles ), Lbalialeucospoides, Lecanoideus floccissimus, Lemophagus errabundus, Leptomastidea abnormis, Leptomastix dactylopii Leptomastix epona, Lindorus lophanthae, Lipolexis oregmae, Luciliacaesar Lysiphlebus testaceipes, Macrolophus caliginosus ( Macroline ), Mesoseiuluslongipes, Metaphycus flavus, Metaphycus lounsburyi, Micromus angulatus Microterys flavus, Muscidifurax raptorellus and Spalangia cameroni Neodryinustyphlocybae, Neoseiulus californicus, Neoseiuluscucumeris Neoseiulus fallacis, Nesideocoristenuis Bronze blackfly (Ophyra aenescens) Orius insidiosus( Oriline ), Hairless Flower Bug (Orius laevigatus) Orius majusculus )、Orius strigicollis Pauesia juniperorum, Pediobius foveolatus, Phasmarhabditis hermaphrodita Phymastichus coffea, Phytoseiulus macropilus, Phytoseiulus persimilis ( Phytoline ), Podisus maculiventris Pseudacteon curvatus, Pseudacteon obtusus, Pseudacteon tricuspis, Pseudaphycus maculipennis, Pseudleptomastix mexicana, Psyllaephagus pilosus, Psyttalia concolor (complex), Quadratichus spp., Rhyzobius lophanthae, Rodolia cardinalis, Rumina decollate, Semielacher petiolatus, Sitobion avenae Steinernema carpocapsae (Nematac BioNem ), Steinernema carinata ( Nemasys BioNem Exhibitline ), Saw Wasp Nematode (Steinernema kraussei) (Nemasys BioNem Exhibitline ), Steinernema riobrave Steinernema scapterisci (Nematac ), Steinernema spp., Steinernematid spp., Guardian ), Stethorus punctillum Tamarixia radiate, Tetrastichus setifer, Thripobius semiluteus, Torymus sinensis, Trichogramma brassicae (Tricholine ), Trichogramma brassicae Trichogramma evanescens, Trichogramma minutum, Trichogramma ostriniae, Trichogramma platneri, Trichogramma retiosum, Xanthopimpla stemmator;

[0048] Other biological agents, including: abscisic acid, Chondrostereum purpureum (Chontrol ), Discosporium Copper Octanoate Delta trap ), Erwinia amylovora (Harpin) ( Ni-HIBIT Gold ), fatty acids derived from natural by-products of extra virgin olive oil Ferric Phosphate Funnel trap ), Grower's Homo-brassonolide, ferric phosphate (Lilly Miller Worry Free Ferramol Slug & Snail )、MCP hail trap ), parasitic insects Microctonus hyperodae, Mycoleptodiscus terrestris Pheromone Net (Thripline ), Potassium bicarbonate Potassium salts of fatty acids Potassium silicate solution Potassium iodide + potassium thiocyanate Spider venom, locust microsporidia (Semaspore Organic Grasshopper ), Trapline Rebell ) and the catch (Takitrapline );

[0049] Safeners such as oxaclorac, oxalic acid (including cloquintocet), cyproconazole, dichloropropane, oxadiazole (including oxadiazole-ethyl), chlorpyrifos, fluazifop, oxadiazole, isoxadiazole (including isoxadiazole-ethyl), pyrazole oxalic acid (including pyrazole oxalic acid-diethyl), oxalylsulfonamide and oxalonitrile.

[0050] Suitable fungicides may be selected from the group consisting of thiabendazim, fluazinam, bensulfuron, bensulfuron-M (bensulfuron-M), furalaxyl, metalaxyl, metalaxyl-M (metalaxyl-M), dodesin, N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine, N'-[4-(4,5-dichloro-thiazol-2-yloxy)-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine, N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine, ethidium, 3'-chloro-2-methoxy-N-[(3RS)- [tetrahydro-2-oxofuran-3-yl]acetyl-2',6'-dimethylaniline (clozylacon), cyprodinil, myclobutanil, myclobutanil, dithianon, aureomycin, blasticidin-S, biphenyl, dimethoate, chloranil, benzovinflumizole, fluopicolide, hexachlorobenzene, pentachloronitrobenzene, tetrachloronitrobenzene (TCNB), methyl tolclofos, mefenamic acid, 2,6-dichloro-N-(4-trifluoromethylbenzyl)-benzamide, fluopicolide (flupicolide), thiocyanate, sulfaquinoxaline, benomyl, carbendazim, carbendazim hydrochloride, clofenazole, wheat spike, thiabendazole, methyl sulfaquinoxaline Bacillus, benzathiapiprolin, thiabendazole, thiabendazole, acibenzolar, pyraclostrobin, pyraclostrobin (IKF-309), acibenzolar-S-methyl, pyraclostrobin (KIF-7767), butylamine, 3-iodo-2-propynyl n-butylcarbamate (IPBC), iodopropynyl butylcarbamate (isopropyl butylcarbamate), isopropyl butylcarbamate (iodopropynyl butylcarbamate), piperidine, polycarbamate, cymoxanil, trifluoromethoxycarb, 3-(difluoromethyl)-N-(7-fluoro-1,1,3,3-tetramethyl-indan-4-yl)-1-methyl-pyrazole-4-carboxamide, dichlorocyanamide, N-[(5-chloro-2-isopropyl [(2-isopropylphenyl)methyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-pyrazole-4-carboxamide, N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-[(2-isopropylphenyl)methyl]-1-methyl-pyrazole-4-carboxamide, cyclopropane amide, thiophanate-methyl, flumorph, quinoline copper, cymoxanil, cyproconazole, cyazolin, fluthiazol, thiophanate-methyl, thiophanate-methyl, ethidazole, isoproconazole, procymidone, vinclozolin, ethidol sulfonate, o-dimethoate, nitropentyl ester, chlorpyrifos, dimethoate, dimethoate, diphenylamine, chlorpyrifos, 2,6-dimethyl-[1,4]dithiino[2,3-c:5,6-c']dipyrrole-1,3,5,7(2H,6H)-tetraketone, oxythiram, mancozeb, ferram, mancozeb, maneb, metam, metiram or polyram, metiram-zinc, mancozeb, methyl propineb, thiram, vibam (sodium metam), mancozeb, thiram, dimethyl disulfide, pyralid, fosetyl-A, phosetyl-Al (fosetyl-Aluminum), methyl bromide, methyl iodide, methyl isothiocyanate, cyclamic acid, methyl furamide, validamycin, streptomycin, (2RS)-2-bromo-2-(bromomethyl) glutaronitrile (bromothiocyanate nitrile), dodecylguanidine acetate, biguanide salt, biguanide octylamine, biguanide octylamine triacetate, 2,4-D, 2,4-DB, kasugamycin, formic acid, cyclamic acid, oxadiazine ... Qi)), thiophanate-methyl, azole furanil, mandelin, KSF-1002, antibacterial lin, oxadiazine, fenpropimorph, tridemorph, dodecamorph, ethotripsy, triphenyltin acetate, triphenyltin hydroxide, carboxin, oxycarboxin, dithiocarb, oxadiazine, metabendazole, metaphenylphenol, para-phenylphenol, tribromophenol (TBP), 2-[2-[(7,8-difluoro-2-methyl-3-quinolyl)oxy]-6-fluoro-phenyl]propane-2-ol, 2-[2-fluoro-6-[(8-fluoro-2-methyl-3-quinolyl)oxy]phenyl]propane-2-ol, flutolanil, furamide, oxadiazine, flutolanil, oxadiazine, isoproterenol, fenpiclonil, fludioxonil, pencuron, Kewensan, Isoblast, Pyraclostrobin, Phosphorus ...6-trichlorophenyl)ethyl]pyrazole-4-carboxamide, bixafen, fluopyram, furapyram, pyraclostrobin, pentofenpyram, penthiopyram, fluoxazolidinone, aminopyraclostrobin, pyraclostrobin, pyraclostrobin, boscalid, fluopyram, diflulin, chlorfenapyr, 5-fluoro-2-(p-tolylmethoxy)pyrimidine-4-amine, pyrimidine, dimetachlone or dimethaclone, pyroquilon, iodoquinazole, ethoxyquin, quinoxyfen, 4,4,5-trifluoro-3,3-dimethyl-1-(3-quinolyl)isoquinoline, 4,4-difluoro-3,3-dimethyl-1-(3-quinolyl)isoquinoline, 5-fluoro-3,3,4,4-tetramethyl-1- (3-quinolyl)isoquinoline, 9-fluoro-2,2-dimethyl-5-(3-quinolyl)-3H-1,4-benzoxazine, isobutylethoxyquinoline, oxolinic acid, chinomethionate (chinomethionate or oxythioquinox, quinoxymethionate), spiroxabiodinium, (E)-N-methyl-2-[2-(2,5-dimethylphenoxymethyl)phenyl]-2-methoxy-iminoacetamide, (mandespin), azoxystrobin, syringosterone, fenamistrobin, enoxastrobin, fenamistrobin, flutoxanil, flutoxanil, fenamistrobin, mandespin, benzyl Oxystrobin, aminobenzamide, oximestrobin, picoxystrobin, pyraclostrobin, pyraclostrobin, pyraclostrobin, chlorpyrifos, oximestrobin, indazolesulfamide, bacteriostatic, tolylfluanid, but-3-ynyl N-[6-[[(Z)-[(1-methyltetrazol-5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridinyl]carbamate, dazomethane, isothiocyanate, thiocyanate, thiofuran, benzylthiocyanate (TCMTB), thiosilamid, benzylthiocyanate, antifungal, tricyclazole, (.+-.)-cis-1-(4-chlorophenyl)-2-(1H-1,2,4-triazol-1-yl)-cycloheptanol (huanjunzuo), 1-(5-bromo-2-pyridinyl)-2-(2 ,4-difluorophenyl)-1,1-difluoro-3-(1,2,4-triazol-1-yl)propan-2-ol, 2-(1-tert-butyl)-1-(2-chlorophenyl)-3-(1,2,4-triazol-1-yl)-propan-2-ol (TCDP), azaconazole, bifenthrinol (bifenthrinol), branconazole, climbazole, cyproconazole, difenoconazole, dimeconazole, diniconazole, diniconazole-M, fluoxiconazole, ethoconazole, nitrobenzazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imidoazole, ifen trifluconazole, cyproconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, silfluazole, tebuconazole, tetrafluconazole, triadimefon, triadimenol, imidazolin, trichlorfonazole, chlorfluconazole, 2-[[(1R,5S)-5-[(4-fluorophenyl)methyl]-1-hydroxy-2,2-dimethyl-cyclopentyl]methyl]-4H-1,2,4-triazole-3-thione, 2-[[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl]-4H-1,2,4-triazole-3-thione, imidium, propineb, valeramide, 2-benzyl-4-chlorophenol (benzyl chlorophenol), allyl alcohol, oxadiazine, benzalkonium chloride, chloropicrin, cresol, daracide, dichlorophen (dichlorophenol), avenanthrone, pyridinium dithiocarbamate, N-(2-chlorobenzoylethyl)-red lead hexachloride, NNF-0721, octhionyl, oxasulfuron, propaneamidine and propionic acid. ,

[0051] Agrochemicals may be present in the meso form, as well as stereoisomers or enantiomers and, where applicable, various polymorphic modifications.

[0052] More preferably, suitable herbicides include pinoxazoline, fluazifop-butyl, mesotrione, fomesulfuron, trimethylolpropane, cypermethrin, amitraz, dimethoate, pyrimethanil, chlornitril, tetrachloronitrobenzene, methyl tolclofos, chloranil M, 2,4-D, MCPA, 2-methyl-4-chloropropionic acid, clodinafop-butyl, cyhalofop-butyl, dichlorvos-butyl, haloxyfop-butyl, quizalofop-ethyl, indol-3-yl acetic acid, 1 -Naphthylacetic acid, isothiocarb, oxadiazine, dimethyl dichlorvos, benomyl, furafol, dicamba, dichlorvos nitrile, benomyl, imidazobactam, fluazolone, fenfluramide, betaine, acetochlor, alachlor, isopropyl metolachlor, pretilachlor, dimethoate, fenthiocarb, fenthiocarb, butyralid, clethodim, cyclodim, sethoxydim, pendimethalin, telofenol, methylcarbamate, ethyl Oxyfluorfen, acifluorfen, fluazifop-butyl, S-isopropylamine, glyphosate, glufosinate, paraquat, diquat, fluazifop-butyl, bromoxynil, ioxynil, methyl imazapyr, imazapic, imazaquin, imazapic, imazapic, methazaquin, fluazifop-butyl, flufenacet, picloram, amodosulfuron, chlorsulfuron, nicosulfuron, sulfasulfuron , etherbensulfuron-methyl, wild barley, cypermethrin, bensulfuron, cypermethrin, atrazine, simazine, cyanazine, ametryn, promethazine, terbuthion, terbuthion, terbuthion, sulcotrione, isoproturon, linuron, fenugreek, chlorotoluron, metoxuron, iodosulfuron-methyl, mesotrione, fluazifop, flufenacet, fluazifop, clofopyralid, foramsulfuron, XDE-848Rinskor and fluclopyralid-methyl.

[0053] Suitable fungicides include pyraclostrobin, dimethomorph, azoxystrobin, trifloxystrobin, kresoxim-methyl, metalaxyl-M, famoxadone, fenoxystrobin, picoxystrobin, cyprodanil, carbendazim, thiabendazole, dimethomorph, vinclozolin, iprodione, dithiocarbamates, imazalil, prochloraz, fluquinconazole, epoxiconazole, flutriafol, azaconazole, bifenthrin, fuconazole, cyproconazole, difenoconazole, hexaconazole, paclobutrazol, propiconazole, tebuconazole, triadimefon, fungicides, and the like. The compounds of the present invention include trtiticonazole, fenpropimorph, tridemorph, fenpropidin, maneb, methanamide, thiram, thiram zinc, captol, captan, folpet, fluazinam, flutolanil, carboxin, metalaxyl, pyrimidine, ethiclostrazone, fluoxastrobin, fluoxastrobin, orysastrobin, fenoxystrobin, prothioconazole, fluopicolide, bixafen, fluopicolide, prothioconazole, pyraclostrobin, chlorpyrifos, benzovintriazole and xemium.

[0054] Suitable insecticides include thiamethoxam, imidacloprid, acetamiprid, clothianidin, dinotefuran, nitenpyram, fipronil, avermectin, emamectin, tefluthrin, emamectin benzoate, benfenac, carbaryl, fenoxycarb, isoprocarb, pirimicarb, propoxur, methomyl, chlorpromazine, endosulfan, heptachlor, tebufenozide, sulfamethoxam, ethofluthrin, methylpirimphos, aldicarb, methomyl, cypermethrin, bioallethrin, deltamethrin, lambda-cyhalothrin, cyhalothrin, cyfluthrin, cypermethrin, cypermethrin, cypermethrin, cyfluthrin, cypermethrin, cypermethrin, cypermethrin, cyproconazole, oxamectin, flupyralid, flutolanil, inscalis, rynaxypyr, cyantraniliprole, sulfoxaflor and spinetoram.

[0055] Suitable plant growth regulators include paclobutrazol, trinexapac-ethyl and 1-methylcyclopropene.

[0056] Suitable safeners include fenthiocarb, cloquintocet, fenthiocarbamide, dichloropropene, fenthiocarb-ethyl, fenthiocarb, fenthiocarbamide, fluazifop, pyrazoline oxalate-diethyl, MG-191, naphthalene dicarboxylic anhydride and fenthiocarbamide.

[0057] Suitably, the agricultural chemicals are selected from fluazifop, mesotrione, pinoxaden, fomesulfuron, trimethylolpropane, propamid, amitraz, diazinon, pyrimethanil, chloranil, tetrachloronitrobenzene, methyl tolclofos, 2,4-D, MCPA, 2-methyl-4-chloropropionic acid, clodinafop-butyl, cyhalofop-butyl, diclofos-butyl, quinazolin, indol-3-yl acetic acid, 1-naphthylacetic acid, isoxadiazine, oxadiazine, dimethyl dichlorvos, benomyl, furazolidone, dicamba, dichlorvos nitrile, chloranil, imidazolin, fluazolone, fenfluramide, betaine, acetochlor, alachlor, isopropyl metolachlor, pretilachlor, dimethoate, fenthion, butyralid, clethodim, cyclohexane Ketone, sethoxydim, demechlordim, dimethoate, telofenol, oxazolidinone, oxyfluorfen, acisulfuron, oxazolidinone, bromoxynil, ioxynil, methyl imazapyr, imazapic, imazapic, imazapic, methoxyfenazine, fluazifop-butyl, flufenac, chloranil, chlorsulfuron, nicosulfuron, sulfasulfuron, ether bensulfuron, wild wheat, chloranil, bensulfuron, chloranil ... Ester, cyprodinil, carbendazim, thiabendazole, oxadiazine, vinclozolin, isoproconazole, dithiocarbamate, imazalil, prochloraz, fluquinconazole, fluepiconazole, flutriafol, azaconazole, bifenthrin, oxadiazine, cyproconazole, difenoconazole, hexaconazole, paclobutrazol, propiconazole, tebuconazole, triadimefon, triclosan, fenpropimorph, trimorph, fenpropidin, maneb, methanamide, chlorothalonil, thiram, zinc thiram, captol, captan, foltan, fluazinam, flutolanil, carboxin, metalaxyl, pyrimidine sulfonate, ethidin, flutolanil, fluoxastrobin, oxadiazine, fenoxystrobin, fenoxystrobin, prothioconazole, thiamethoxam, imidacloprid, acetamiprid, clothianidin, furan Amine, nitenpyram, fipronil, avermectin, emamectin, benfenac, carbaryl, fenoxycarb, isoprocarb, pirimicarb, propoxur, methomyl, chlorpromazine, chlorpromazine, endosulfan, heptachlor, fenbumid, sulfamethoxam, ethoprofen, methyl pirimiphos, aldicarb, methomyl, cypermethrin, bio-allethrin, deltamethrin, high-efficiency cyhalothrin, tri-cyhalothrin, cyfluthrin, cypermethrin, cypermethrin, fenvalerate, imiprothrin, permethrin, bromofluthrin, paclobutrazol, 1-methylcyclopropene, fenthiocarb, quinoline, fenthiocarb, dichloropropene, fenthiocarb-ethyl, fenthiocarb, fenthiocarb, fluazifop, pyrazole oxalate-diethyl, MG-191, naphthalene dicarboxylic anhydride and fenthiocarb.

[0058] Preferred agrochemical active ingredients are selected from fomesafen (suitably as the sodium salt), mesotrione, nicosulfuron, pinoxaden, pyraclostrobin, epoxiconazole, benzovintriazole and cyantraniliprole.

[0059] Advantageously, the composition comprises one or more surfactants and / or oils (such as mineral oils and / or vegetable oils).

[0060] Surfactants are used as formulation components and as adjuvants and may be present in amounts of 0.00001% to 8% by weight, such as 0.0001% to 5% by weight, 0.001% to 4% by weight, 0.01% to 3% by weight, or even 0.1% to 2% by weight.

[0061] Suitable ionic surfactants are alkali, alkaline earth metal and ammonium salts of aromatic sulfonic acids, for example ligninsulfonic acid, phenolsulfonic acid, naphthalenesulfonic acid, dibutylnaphthalenesulfonic acid or fatty acids, alkyl and alkylarylsulfonates, alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates, and also sulfated salts of cetyl, heptadecanol and stearyl alcohol and fatty alcohol glycol ethers, condensates of sulfonated naphthalene and its derivatives with formaldehyde, condensates of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polycarboxylates or phosphoric esters of alkoxylated alcohols.

[0062] Suitable nonionic surfactants are polyoxyethylene octylphenol ethers, alkoxylated alcohols (e.g. ethoxylated isooctyl-, octyl- or nonyl-phenol), alkylphenyl polyglycol ethers, tributylphenyl polyglycol ethers, alkylaryl polyether alcohols, isotridecanol, fatty alcohol / ethylene oxide condensates, ethoxylated castor oil, alkyl polyglycosides, polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers, lauryl alcohol polyglycol ether acetates, sorbitan esters, lignin-sulfite waste liquors and also proteins, denatured proteins, hydrophobically modified starches, polyvinyl alcohols (e.g. ), polyalkoxylates, polyvinylamine, polyethyleneimine, polyvinylpyrrolidone and copolymers or block polymers thereof.

[0063] Organic liquids (oils) can be used as formulation components, as solvents or adjuvants. They can also be added as adjuvants to the spray tank dilution to perform a variety of functions such as, but not exclusively, uptake improvement, spreading, rainfastness enhancement, drift reduction, volatility reduction.

[0064] Suitable oil can be the alkyl ester of oil of plant, mineral and animal origin and these oils, such as vegetable oil and vegetable oil ester and diester (comprising the ester with glycerine and propylene glycol).Some preferred oils are methyl esters, ethyl esters, isopropyl ester, isobutyl ester, butyl ester, hexyl ester and ethylhexyl ester.Others are vegetable oil and ester selected from the group consisting of: methyl oleate, ethyl oleate, methyl palmitate, rapeseed oil methyl ester, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, ethylhexyl oleate, the mixture of ethylhexyl myristate / ethylhexyl laurate, ethylhexyl laurate, the mixture of ethylhexyl caprylate / ethylhexyl caprate, diisopropyl adipate, coconut oil propylene glycol diester, sunflower oil, rapeseed oil, corn oil, soybean oil and alkyl esters thereof, rice bran oil and alkyl esters thereof, olive oil, peanut oil mixed caprylic triglyceride and capric triglyceride and mixed capryl glyceride and capryl glyceride. Also suitable are mineral oils such as Exxsol D100, Solvesso 200ND, and white oils and alkyl esters of phosphoric and phosphonic acids such as trialkyl phosphates, preferably tri(2-ethylhexyl) phosphate.

[0065] Preferably, the one or more surfactants and / or oils are selected from nonionic and ionic surfactants, castor oil ethoxylates, sulfosuccinates, alkyl polyglycosides, polypropylene glycol-polyethylene glycol copolymers and / or ethoxylated trisiloxanes.

[0066] The composition may contain an additional polymer, preferably wherein the selected polymer is a polysaccharide. Advantageously, the additional polymer is selected from one or more of natural and modified guar gum, xanthan gum, natural and / or modified cellulose.

[0067] The compositions as described herein are advantageously suitable for use in precision application devices. Also provided is the use of a composition as described herein in a precision application device.

[0068] In a second aspect of the present invention, there is provided a precision application device and a composition comprising:

[0069] agricultural chemicals;

[0070] polymers; and

[0071] Carrier fluid;

[0072] The polymer is selected from one or more polysaccharides.

[0073] The device comprises a nozzle, preferably a jet nozzle or a small-angle flat fan nozzle. Such a device advantageously doses the sediment at an application rate of 20 to 3000 L / Ha, preferably 200 to 500 L / Ha.

[0074] Advantageously, the composition comprises one or more surfactants and / or oils (such as mineral oils and / or vegetable oils).

[0075] The polymer is preferably selected from one or more of diutan gum, natural and modified guar gum, xanthan gum, natural and / or modified cellulose. Advantageously, the polymer may be present in an amount of 0.001% to 2% by weight, preferably 0.01% to 0.20% by weight.

[0076] Preferably, the carrier fluid comprises water, such as 80% to 100% or 80% to 99.5% water by weight of the carrier fluid.

[0077] Advantageously, the agrochemical is used at the maximum use rate as per the label of the active ingredient. The agrochemical may be used in an amount of 0.0001% to 25% by weight, such as 0.001% to 20% by weight, 0.01% to 5% by weight, or 6% to 15% by weight. The agrochemical is preferably selected from the list defined above.

[0078] Surfactants are used as formulation components and as adjuvants and may be present in amounts of 0.00001% to 8% by weight, such as 0.0001% to 5% by weight, 0.001% to 4% by weight, 0.01% to 3% by weight, or even 0.1% to 2% by weight.

[0079] Suitable ionic surfactants are alkali, alkaline earth metal and ammonium salts of aromatic sulfonic acids, for example ligninsulfonic acid, phenolsulfonic acid, naphthalenesulfonic acid, dibutylnaphthalenesulfonic acid or fatty acids, alkyl and alkylarylsulfonates, alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates, and also sulfated salts of cetyl, heptadecanol and stearyl alcohol and fatty alcohol glycol ethers, condensates of sulfonated naphthalene and its derivatives with formaldehyde, condensates of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polycarboxylates or phosphoric esters of alkoxylated alcohols.

[0080] Suitable nonionic surfactants are polyoxyethylene octylphenol ethers, alkoxylated alcohols (e.g. ethoxylated isooctyl-, octyl- or nonyl-phenol), alkylphenyl polyglycol ethers, tributylphenyl polyglycol ethers, alkylaryl polyether alcohols, isotridecanol, fatty alcohol / ethylene oxide condensates, ethoxylated castor oil, alkyl polyglycosides, polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers, lauryl alcohol polyglycol ether acetates, sorbitan esters, lignin-sulfite waste liquors and also proteins, denatured proteins, hydrophobically modified starches, polyvinyl alcohols (e.g. ), polyalkoxylates, polyvinylamine, polyethyleneimine, polyvinylpyrrolidone and copolymers or block polymers thereof.

[0081] Organic liquids (oils) can be used as formulation components, as solvents or adjuvants. They can also be added as adjuvants to the spray tank dilution to perform a variety of functions such as, but not exclusively, uptake improvement, spreading, rainfastness enhancement, drift reduction, volatility reduction.

[0082] Suitable oil can be the alkyl ester of oil of plant, mineral and animal origin and these oils, such as vegetable oil and vegetable oil ester and diester (comprising the ester with glycerine and propylene glycol).Some preferred oils are methyl esters, ethyl esters, isopropyl ester, isobutyl ester, butyl ester, hexyl ester and ethylhexyl ester.Others are vegetable oil and ester selected from the group consisting of: methyl oleate, ethyl oleate, methyl palmitate, rapeseed oil methyl ester, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, ethylhexyl oleate, the mixture of ethylhexyl myristate / ethylhexyl laurate, ethylhexyl laurate, the mixture of ethylhexyl caprylate / ethylhexyl caprate, diisopropyl adipate, coconut oil propylene glycol diester, sunflower oil, rapeseed oil, corn oil, soybean oil and alkyl esters thereof, rice bran oil and alkyl esters thereof, olive oil, peanut oil mixed caprylic triglyceride and capric triglyceride and mixed capryl glyceride and capryl glyceride. Also suitable are mineral oils such as Exxsol D100, Solvesso 200ND, and white oils and alkyl esters of phosphoric and phosphonic acids such as trialkyl phosphates, preferably tri(2-ethylhexyl) phosphate.

[0083] Preferably, the one or more surfactants and / or oils are selected from nonionic and ionic surfactants, castor oil ethoxylates, sulfosuccinates, alkyl polyglycosides, polypropylene glycol-polyethylene glycol copolymers and / or ethoxylated trisiloxanes.

[0084] In a third aspect of the present invention, there is provided the use of a polymer for reducing the fragmentation of an agrochemical composition, preferably a herbicide composition, wherein the polymer is selected from one or more polysaccharides, such as diutan gum, natural and modified guar gum, xanthan gum, natural and / or modified cellulose.

[0085] Preferably, the fragmentation is reduced by at least 50%, such as at least 60%, 70%, 75%, preferably at least 85% or even at least 90%.

[0086] Unless otherwise stated, amounts of components expressed in percentages are given as percentages by total weight and all embodiments and preferred features may be combined in any combination.

[0087] The invention is defined by the following non-limiting examples.

[0088] Examples

[0089] equipment:

[0090] Spray Nozzle: Use Burkert 6712 Whisper Valve, 0.4mm Orifice, EPDM Seals. Burkert Manifold (694895). 1 / 4" 21G Needle Tip.

[0091] Flat sector: Pulsajet AAB10000AUH-03. Lechler 652.301 (PVDF)

[0092] Table 1

[0093]

[0094]

[0095] method

[0096] Preparation of formulations:

[0097] All polysaccharides were prepared as 1% gels in deionized water by high shear mixing before use.

[0098] The spray solutions were prepared by thoroughly mixing the required amounts of the components as defined in the table below. The balance to 100% by weight in each case was water as carrier fluid.

[0099] Sulfacid Blue 5J was introduced into the spray solution at a final concentration of 0.5% w / w.

[0100] Spray Assessment

[0101] To evaluate the effectiveness of polysaccharides in reducing the breakage of the composition, a custom spray evaluation method was developed. A custom static spray apparatus was built and equipped with a spray nozzle operating at 3.0 ± 0.1 bar. Unless otherwise specified, 10 cm below the nozzle tip was the target surface, a round synthetic fabric substrate (D = 20 mm) on a cylindrical support (20 mm × 80 mm). This surface had a contact angle of 133 ± 2 ° with deionized water and was used to replicate a leaf surface that was difficult to wet.

[0102] The formulation was loaded into the spray equipment and the operating parameters were adjusted to ensure that a 14 ± 1 mg dose of spray solution was applied to the target. Located below the supported target surface was an A4 paper that was used to capture the unretained spray liquid, aided by blue dye for visualization. For each spray scenario, a total of 10 spray events were collected (e.g., repeated 10 times on 10 sheets of paper).

[0103] Compositions 1 to 27 were sprayed with a jet nozzle and compositions 28 to 30 were sprayed with a flat fan nozzle.

[0104] The breakup performance was evaluated in the following manner. 10 A4 capture papers were digitized using a Brother DS-720D scanner operating at 600 dpi. The digitized data was then analyzed using a custom ImageJ macro to verify information on droplet count, coordinates, and area. Performance was evaluated by analyzing the total droplet count, where the reduction in breakage was characterized by a percentage reduction in the total droplet count.

[0105] The results are listed in Tables 2 to 7.

[0106] Figure 1 Digital droplet position data for formulation entries 16, 17, 18 and 21 are provided and demonstrate the significant improvement in performance for the compositions according to the present invention.

[0107] Table 2. Summary of data for Diutan and spray solutions containing H-1 at a fixed concentration of 0.38%. The spray solution also contained 0.25% w / w ammonium sulfate. Empicol ESC 70 was fixed at 0.25%. Nozzle type = spray nozzle

[0108] Table 2

[0109]

[0110] Table 3. Summary of data for diutan gum and various surfactant chemistries. Diutan gum loading was fixed at 0.10% w / w and surfactant loading was fixed at 0.25% w / w. Nozzle Type = Jet Nozzle

[0111] Table 3

[0112]

[0113]

[0114] Table 4. Summary of data for individual and mixed polysaccharides with Touchdown Quattro (TDQ). Total polysaccharide concentration was fixed at 0.10% w / w total, with a mass ratio of 1:1 for binary mixtures. TDQ was fixed at 0.72% w / w. Nozzle type = jet nozzle

[0115] Table 4

[0116]

[0117] Table 5. Summary of data for diutan spray solutions used with EC formulations (Katoun Gold, AI = nonanoic acid). Polysaccharide concentration was fixed at 0.10% w / w and nonanoic acid was fixed at 10% w / w. Nozzle type = spray nozzle

[0118] Table 5

[0119]

[0120] Table 6. Summary of data for diutan spray solutions used with SC (Quadris, AI = azoxystrobin) formulations. Polysaccharide concentration fixed at 0.10% w / w. Quadris fixed at 0.83% w / w. Nozzle type = spray nozzle

[0121] Table 6

[0122]

[0123] Table 7. Summary of data for diutan spray solutions used with Touchdown Quattro. Here, the polysaccharide concentration was fixed at 0.10% w / w and the Touchdown Quattro was fixed at 0.72% w / w. Nozzle type = flat fan. In this case, the target substrate was an ellipse (D = 40 x 80 mm) placed on an elliptical cylindrical support (40 x 80 mm x 80 mm).

[0124] Table 7

[0125]

[0126] It can be seen that the compositions according to the invention demonstrate a significant improvement in terms of reduction in breakage.

[0127] The invention is defined by the claims.

Claims

1. A composition comprising: a.Agricultural chemicals; b. Diutacol; and c. Carrier fluid, wherein the diutan gum is present in an amount of 0.001% to 2% by weight, Wherein the carrier fluid comprises water and is present in an amount of 65% to 95% by weight.

2. The composition according to claim 1, wherein The agrochemical is present in an amount of 0.0001% to 25% by weight.

3. The composition according to claim 1 or 2, wherein The diutan gum is present in an amount of 0.01% to 0.20% by weight.

4. A composition according to any preceding claim comprising one or more surfactants and / or oils.

5. The composition according to claim 4, wherein Nonionic and ionic surfactants, preferably castor oil ethoxylates, sulfosuccinates, alkyl polyglycosides, polypropylene glycol-polyethylene glycol copolymers and / or ethoxylated trisiloxanes.

6. The composition according to any one of the preceding claims, comprising an additional polymer, wherein the polymer is selected from polysaccharides.

7. The composition according to claim 6, wherein The additional polymer is selected from one or more of natural and modified guar gum, xanthan gum, natural and / or modified cellulose.

8. A composition according to any preceding claim which is suitable for use in a precision application device.

9. Use of a composition according to any one of the preceding claims in a precision application device.

10. A precision application device and a composition, the composition comprising: a.Agricultural chemicals; b. polymers; and c. Carrier fluid; The polymer is selected from one or more polysaccharides.

11. The device according to claim 10, comprising a nozzle, preferably a jet nozzle or a small-angle flat fan nozzle.

12. Device according to claim 10 or 11, which doses the sediment at an application rate of 20-3000 L / Ha, preferably 200-500 L / Ha.

13. The device according to any one of claims 10 to 13, wherein: The polymer is selected from diutan gum, natural and modified guar gum, xanthan gum, natural and / or modified cellulose.

14. The device according to any one of claims 10 to 13, wherein: The carrier fluid comprises water.

15. Use of a polymer for reducing breakage of an agrochemical composition, wherein the polymer is selected from one or more polysaccharides.

16. The use according to claim 15, wherein The fragmentation is reduced by at least 50%, preferably at least 85%.

17. The use according to claim 15 or 16, wherein The agrochemical composition is a herbicide composition.

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