Long-life high-selectivity titanium nitride / tungsten etching solution

By optimizing the composition of the etching solution, the problems of low selectivity, slow speed, and short lifespan of titanium nitride and tungsten etching solutions in the existing technology have been solved, achieving etching effects with high selectivity and long lifespan, thus improving the efficiency and quality of integrated circuit manufacturing.

CN119614200BActive Publication Date: 2026-06-23HUBEI SINOPHORUS ELECTRONIC MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HUBEI SINOPHORUS ELECTRONIC MATERIALS CO LTD
Filing Date
2024-11-12
Publication Date
2026-06-23

AI Technical Summary

Technical Problem

Existing titanium nitride and tungsten etchants cannot simultaneously meet the requirements of high selectivity, high speed and long life, especially in integrated circuit manufacturing, where it is difficult to achieve a titanium nitride etching rate greater than 10A/min, a selectivity greater than 500 and an etching life greater than 24h.

Method used

An etching solution composed of a specific ratio of acidic medium, dispersant, complexing agent, accelerator, and stabilizer, including 30-70% acidic medium, 10-25% dispersant, 1-10% complexing agent, 0.1-1% accelerator, 0.01-0.1% stabilizer, and the balance being deionized water, optimizes the etching environment to improve the etching rate and selectivity of titanium nitride, reduce the etching rate of tungsten, and extend the life of the etching solution.

Benefits of technology

The etching selectivity ratio of titanium nitride to tungsten was improved to 500~1000, the etching rate of titanium nitride was maintained at 10~25A/min, the stability and lifespan of the etching solution were significantly improved, and the etching process was more efficient and consistent.

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Abstract

The application discloses a long-life high-selectivity-ratio titanium nitride / tungsten etching solution, which comprises the following raw materials in mass fraction: 30-70% of an acidic medium; 10-25% of a diffusing agent; 1-10% of a complexing agent; 0.1-1% of a promoter; 0.01-0.1% of a stabilizer; and the balance of deionized water. The etching solution can improve the selectivity ratio of titanium nitride / tungsten to 500-1000 and the etching life to 24 hours while ensuring that the etching rate of titanium nitride is 10-25 A / min.
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